FN Thomson Reuters Web of Science™ VR 1.0 PT J AU Henriques, A Graham, JT Landsberger, S Ihlefeld, JF Brennecka, GL Brown, DW Forrester, JS Jones, JL AF Henriques, Alexandra Graham, Joseph T. Landsberger, Sheldon Ihlefeld, Jon F. Brennecka, Geoff L. Brown, Donald W. Forrester, Jennifer S. Jones, Jacob L. TI Crystallographic changes in lead zirconate titanate due to neutron irradiation SO AIP ADVANCES LA English DT Article ID NONVOLATILE-MEMORY APPLICATIONS; PZT-TYPE CERAMICS; TECHNOLOGY; MICROELECTRONICS; MAGNESIUM; BATIO3; FILMS; UPSET; PURE AB Piezoelectric and ferroelectric materials are useful as the active element in non-destructive monitoring devices for high-radiation areas. Here, crystallographic structural refinement (i. e., the Rietveld method) is used to quantify the type and extent of structural changes in PbZr0.5Ti0.5O3 after exposure to a 1 MeV equivalent neutron fluence of 1.7x10(15) neutrons/cm(2). The results showa measurable decrease in the occupancy of Pb and O due to irradiation, with O vacancies in the tetragonal phase being created preferentially on one of the two O sites. The results demonstrate a method by which the effects of radiation on crystallographic structure may be investigated. (C) 2014 Author(s). C1 [Henriques, Alexandra] Univ Florida, Dept Mat Sci & Engn, Gainesville, FL 32611 USA. [Graham, Joseph T.] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA. [Landsberger, Sheldon] Univ Texas Austin, Dept Mech Engn, Nucl Engn Teaching Lab, Austin, TX 78712 USA. [Ihlefeld, Jon F.; Brennecka, Geoff L.] Sandia Natl Labs, Elect Opt & Nanomat Dept, Albuquerque, NM 87185 USA. [Brown, Donald W.] Los Alamos Neutron Sci Ctr, Los Alamos, NM 87185 USA. [Forrester, Jennifer S.; Jones, Jacob L.] N Carolina State Univ, Dept Mat Sci & Engn, Raleigh, NC 27695 USA. RP Jones, JL (reprint author), N Carolina State Univ, Dept Mat Sci & Engn, Box 7907, Raleigh, NC 27695 USA. EM jacobjones@ncsu.edu RI Brennecka, Geoff/J-9367-2012; OI Brennecka, Geoff/0000-0002-4476-7655; Forrester, Jennifer/0000-0002-4035-815X FU National Institute for NanoEngineering (NINE); Laboratory Directed Research and Development (LDRD) program at Sandia National Laboratories; U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX A portion of this work was funded under the National Institute for NanoEngineering (NINE) and the Laboratory Directed Research and Development (LDRD) program at Sandia National Laboratories. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. NR 29 TC 2 Z9 2 U1 1 U2 13 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 2158-3226 J9 AIP ADV JI AIP Adv. PD NOV PY 2014 VL 4 IS 11 AR 117125 DI 10.1063/1.4902179 PG 7 WC Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied SC Science & Technology - Other Topics; Materials Science; Physics GA AU4KE UT WOS:000345578800025 ER PT J AU Aliu, E Aune, T Barnacka, A Beilicke, M Benbow, W Berger, K Biteau, J Buckley, JH Bugaev, V Byrum, K Cardenzana, JV Cerruti, M Chen, X Ciupik, L Connaughton, V Cui, W Dickinson, HJ Eisch, JD Errando, M Falcone, A Federici, S Feng, Q Finley, JP Fleischhack, H Fortin, P Fortson, L Furniss, A Galante, N Gillanders, GH Griffin, S Griffiths, ST Grube, J Gyuk, G Hakansson, N Hanna, D Holder, J Hughes, G Humensky, TB Johnson, CA Kaaret, P Kar, P Kertzman, M Khassen, Y Kieda, D Krawczynski, H Krennrich, F Lang, MJ Madhavan, AS Maier, G McArthur, S McCann, A Meagher, K Millis, J Moriarty, P Mukherjee, R Nieto, D de Bhroithe, AO Ong, RA Otte, AN Park, N Pohl, M Popkow, A Prokoph, H Pueschel, E Quinn, J Ragan, K Rajotte, J Reyes, LC Reynolds, PT Richards, GT Roache, E Sembroski, GH Shahinyan, K Smith, AW Staszak, D Telezhinsky, I Tucci, JV Tyler, J Varlotta, A Vassiliev, VV Vincent, S Wakely, SP Weiner, OM Weinstein, A Welsing, R Wilhelm, A Williams, DA Zitzer, B McEnery, JE Perkins, JS Veres, P Zhu, S AF Aliu, E. Aune, T. Barnacka, A. Beilicke, M. Benbow, W. Berger, K. Biteau, J. Buckley, J. H. Bugaev, V. Byrum, K. Cardenzana, J. V. Cerruti, M. Chen, X. Ciupik, L. Connaughton, V. Cui, W. Dickinson, H. J. Eisch, J. D. Errando, M. Falcone, A. Federici, S. Feng, Q. Finley, J. P. Fleischhack, H. Fortin, P. Fortson, L. Furniss, A. Galante, N. Gillanders, G. H. Griffin, S. Griffiths, S. T. Grube, J. Gyuk, G. Hakansson, N. Hanna, D. Holder, J. Hughes, G. Humensky, T. B. Johnson, C. A. Kaaret, P. Kar, P. Kertzman, M. Khassen, Y. Kieda, D. Krawczynski, H. Krennrich, F. Lang, M. J. Madhavan, A. S. Maier, G. McArthur, S. McCann, A. Meagher, K. Millis, J. Moriarty, P. Mukherjee, R. Nieto, D. de Bhroithe, A. O'Faolain Ong, R. A. Otte, A. N. Park, N. Pohl, M. Popkow, A. Prokoph, H. Pueschel, E. Quinn, J. Ragan, K. Rajotte, J. Reyes, L. C. Reynolds, P. T. Richards, G. T. Roache, E. Sembroski, G. H. Shahinyan, K. Smith, A. W. Staszak, D. Telezhinsky, I. Tucci, J. V. Tyler, J. Varlotta, A. Vassiliev, V. V. Vincent, S. Wakely, S. P. Weiner, O. M. Weinstein, A. Welsing, R. Wilhelm, A. Williams, D. A. Zitzer, B. McEnery, J. E. Perkins, J. S. Veres, P. Zhu, S. TI CONSTRAINTS ON VERY HIGH ENERGY EMISSION FROM GRB 130427A SO ASTROPHYSICAL JOURNAL LETTERS LA English DT Article DE gamma-ray burst: individual (GRB 130427A) ID GAMMA-RAY BURSTS; COMPONENT; AFTERGLOWS; SWIFT; TELESCOPE; SPECTRA; MISSION; LIMITS; TEV AB Prompt emission from the very fluent and nearby (z = 0.34) gamma-ray burst GRB130427A was detected by several orbiting telescopes and by ground-based, wide-field-of-view optical transient monitors. Apart from the intensity and proximity of this GRB, it is exceptional due to the extremely long-lived high-energy (100 MeV to 100 GeV) gamma-ray emission, which was detected by the Large Area Telescope on the Fermi Gamma-Ray Space Telescope for similar to 70 ks after the initial burst. The persistent, hard-spectrum, high-energy emission suggests that the highest-energy gamma rays may have been produced via synchrotron self-Compton processes though there is also evidence that the high-energy emission may instead be an extension of the synchrotron spectrum. VERITAS, a ground-based imaging atmospheric Cherenkov telescope array, began follow-up observations of GRB130427A similar to 71 ks (similar to 20 hr) after the onset of the burst. The GRB was not detected with VERITAS; however, the high elevation of the observations, coupled with the low redshift of the GRB, make VERITAS a very sensitive probe of the emission from GRB130427A for E > 100 GeV. The non-detection and consequent upper limit derived place constraints on the synchrotron self-Compton model of high-energy gamma-ray emission from this burst. C1 [Aliu, E.; Errando, M.; Mukherjee, R.] Columbia Univ Barnard Coll, Dept Phys & Astron, New York, NY 10027 USA. [Aune, T.; Ong, R. A.; Popkow, A.; Vassiliev, V. V.] Univ Calif Los Angeles, Dept Phys & Astron, Los Angeles, CA 90095 USA. [Barnacka, A.] Harvard Smithsonian Ctr Astrophys, Cambridge, MA 02138 USA. [Beilicke, M.; Buckley, J. H.; Bugaev, V.; Krawczynski, H.] Washington Univ, Dept Phys, St Louis, MO 63130 USA. [Benbow, W.; Cerruti, M.; Fortin, P.; Galante, N.; Roache, E.] Harvard Smithsonian Ctr Astrophys, Fred Lawrence Whipple Observ, Amado, AZ 85645 USA. [Berger, K.; Holder, J.] Univ Delaware, Dept Phys & Astron, Newark, DE 19716 USA. [Berger, K.; Holder, J.] Univ Delaware, Bartol Res Inst, Newark, DE 19716 USA. [Biteau, J.; Furniss, A.; Johnson, C. A.; Williams, D. A.] Univ Calif Santa Cruz, Santa Cruz Inst Particle Phys, Santa Cruz, CA 95064 USA. [Biteau, J.; Furniss, A.; Johnson, C. A.; Williams, D. A.] Univ Calif Santa Cruz, Dept Phys, Santa Cruz, CA 95064 USA. [Byrum, K.; Zitzer, B.] Argonne Natl Lab, Argonne, IL 60439 USA. [Cardenzana, J. V.; Dickinson, H. J.; Eisch, J. D.; Krennrich, F.; Madhavan, A. S.; Weinstein, A.] Iowa State Univ, Dept Phys & Astron, Ames, IA 50011 USA. [Chen, X.; Federici, S.; Hakansson, N.; Pohl, M.; Telezhinsky, I.; Wilhelm, A.] Univ Potsdam, Inst Phys & Astron, D-14476 Potsdam, Germany. [Chen, X.; Federici, S.; Fleischhack, H.; Hughes, G.; Maier, G.; de Bhroithe, A. O'Faolain; Pohl, M.; Prokoph, H.; Telezhinsky, I.; Vincent, S.; Welsing, R.; Wilhelm, A.] DESY, D-15738 Zeuthen, Germany. [Ciupik, L.; Grube, J.; Gyuk, G.] Adler Planetarium & Astron Museum, Dept Astron, Chicago, IL 60605 USA. [Connaughton, V.] Univ Alabama, Ctr Space Plasma & Aeron Res, Huntsville, AL 35899 USA. [Cui, W.; Feng, Q.; Finley, J. P.; Sembroski, G. H.; Tucci, J. V.; Varlotta, A.] Purdue Univ, Dept Phys & Astron, W Lafayette, IN 47907 USA. [Falcone, A.; Veres, P.] Penn State Univ, Dept Astron & Astrophys, University Pk, PA 16802 USA. [Fortson, L.; Shahinyan, K.] Univ Minnesota, Sch Phys & Astron, Minneapolis, MN 55455 USA. [Gillanders, G. H.; Lang, M. J.; Moriarty, P.] Natl Univ Ireland Galway, Sch Phys, Galway, Ireland. [Griffin, S.; Hanna, D.; Ragan, K.; Rajotte, J.; Staszak, D.; Tyler, J.] McGill Univ, Dept Phys, Montreal, PQ H3A 2T8, Canada. [Griffiths, S. T.; Kaaret, P.] Univ Iowa, Dept Phys & Astron, Iowa City, IA 52242 USA. [Humensky, T. B.; Nieto, D.; Weiner, O. M.] Columbia Univ, Dept Phys, New York, NY 10027 USA. [Kar, P.; Kieda, D.; Smith, A. W.] Univ Utah, Dept Phys & Astron, Salt Lake City, UT 84112 USA. [Kertzman, M.] Depauw Univ, Dept Phys & Astron, Greencastle, IN 46135 USA. [Khassen, Y.; Pueschel, E.; Quinn, J.] Natl Univ Ireland Univ Coll Dublin, Sch Phys, Dublin 4, Ireland. [McArthur, S.; Park, N.; Wakely, S. P.] Univ Chicago, Enrico Fermi Inst, Chicago, IL 60637 USA. [McCann, A.] Univ Chicago, Kavli Inst Cosmol Phys, Chicago, IL 60637 USA. [Meagher, K.; Otte, A. N.; Richards, G. T.] Georgia Inst Technol, Sch Phys, Atlanta, GA 30332 USA. [Meagher, K.; Otte, A. N.; Richards, G. T.] Georgia Inst Technol, Ctr Relativist Astrophys, Atlanta, GA 30332 USA. [Millis, J.] Anderson Univ, Dept Phys, Anderson, IN 46012 USA. [Moriarty, P.] Galway Mayo Inst Technol, Dept Life & Phys Sci, Galway, Ireland. [Reyes, L. C.] Calif Polytech State Univ San Luis Obispo, Dept Phys, San Luis Obispo, CA 94307 USA. [Reynolds, P. T.] Cork Inst Technol, Dept Appl Phys & Instrumentat, Bishopstown, Cork, Ireland. [McEnery, J. E.; Perkins, J. S.] NASA, Goddard Space Flight Ctr, Greenbelt, MD 20771 USA. [McEnery, J. E.; Zhu, S.] Univ Maryland, Dept Phys, College Pk, MD 20742 USA. [McEnery, J. E.; Zhu, S.] Univ Maryland, Dept Astron, College Pk, MD 20742 USA. [Veres, P.] George Washington Univ, Dept Phys, Washington, DC 20052 USA. [Veres, P.] Penn State Univ, Dept Phys, University Pk, PA 16802 USA. [Veres, P.] Penn State Univ, Ctr Particle & Gravitat Astrophys, University Pk, PA 16802 USA. RP Aliu, E (reprint author), Columbia Univ Barnard Coll, Dept Phys & Astron, New York, NY 10027 USA. EM aune@astro.ucla.edu; veres@email.gwu.edu; sjzhu@umd.edu RI Khassen, Yerbol/I-3806-2015; Nieto, Daniel/J-7250-2015; OI Khassen, Yerbol/0000-0002-7296-3100; Nieto, Daniel/0000-0003-3343-0755; Cui, Wei/0000-0002-6324-5772; Barnacka, Anna/0000-0001-5655-4158; Lang, Mark/0000-0003-4641-4201 FU U.S. Department of Energy Office of Science; U.S. National Science Foundation; Smithsonian Institution; NSERC in Canada; Science Foundation Ireland [SFI 10/RFP/AST2748]; STFC in the U.K; NASA [NNX12AE30G] FX VERITAS is supported by grants from the U.S. Department of Energy Office of Science, the U.S. National Science Foundation, and the Smithsonian Institution, by NSERC in Canada, by Science Foundation Ireland (SFI 10/RFP/AST2748) and by STFC in the U.K. Additional support for observations of GRBs comes from NASA grant NNX12AE30G. We acknowledge the excellent work of the technical support staff at the Fred Lawrence Whipple Observatory and at the collaborating institutions in the construction and operation of the instrument. NR 39 TC 8 Z9 8 U1 0 U2 2 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 2041-8205 EI 2041-8213 J9 ASTROPHYS J LETT JI Astrophys. J. Lett. PD NOV 1 PY 2014 VL 795 IS 1 AR L3 DI 10.1088/2041-8205/795/1/L3 PG 6 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA AU2NO UT WOS:000345455500003 ER PT J AU Lee, KG Hennawi, JF Stark, C Prochaska, JX White, M Schlegel, DJ Eilers, AC Arinyo-i-Prats, A Suzuki, N Croft, RAC Caputi, KI Cassata, P Ilbert, O Garilli, B Koekemoer, AM Le Brun, V Le Fevre, O Maccagni, D Nugent, P Taniguchi, Y Tasca, LAM Tresse, L Zamorani, G Zucca, E AF Lee, Khee-Gan Hennawi, Joseph F. Stark, Casey Prochaska, J. Xavier White, Martin Schlegel, David J. Eilers, Anna-Christina Arinyo-i-Prats, Andreu Suzuki, Nao Croft, Rupert A. C. Caputi, Karina I. Cassata, Paolo Ilbert, Olivier Garilli, Bianca Koekemoer, Anton M. Le Brun, Vincent Le Fevre, Olivier Maccagni, Dario Nugent, Peter Taniguchi, Yoshiaki Tasca, Lidia A. M. Tresse, Laurence Zamorani, Gianni Zucca, Elena TI LY alpha FOREST TOMOGRAPHY FROM BACKGROUND GALAXIES: THE FIRST MEGAPARSEC-RESOLUTION LARGE-SCALE STRUCTURE MAP AT Z > 2 SO ASTROPHYSICAL JOURNAL LETTERS LA English DT Article DE cosmology: observations; galaxies: high-redshift; intergalactic medium; quasars: absorption lines; surveys; techniques: spectroscopic ID REST-FRAME ULTRAVIOLET; BARYON ACOUSTIC-OSCILLATIONS; HUBBLE-SPACE-TELESCOPE; DIGITAL SKY SURVEY; INTERGALACTIC MEDIUM; POWER SPECTRUM; SPECTROSCOPIC SURVEY; STAR-FORMATION; COSMOS; REDSHIFT AB We present the first observations of foreground Ly alpha forest absorption fromhigh-redshift galaxies, targeting 24 star-forming galaxies (SFGs) with z similar to 2.3-2.8 within a 5' x 14' region of the COSMOS field. The transverse sightline separation is similar to 2h(-1) Mpc comoving, allowing us to create a tomographic reconstruction of the three-dimensional (3D) Lya forest absorption field over the redshift range 2.20 <= z <= 2.45. The resulting map covers 6h(-1) Mpc x 14h(-1) Mpc in the transverse plane and 230h(-1) Mpc along the line of sight with a spatial resolution of approximate to 3.5h(-1) Mpc, and is the firsthigh-fidelity map of a large-scale structure on similar to Mpc scales at z > 2. Our map reveals significant structures with greater than or similar to 10h(-1) Mpc extent, including several spanning the entire transverse breadth, providing qualitative evidence for the filamentary structures predicted to exist in thehigh-redshift cosmic web. Simulated reconstructions with the same sightline sampling, spectral resolution, and signal-to-noise ratio recover the salient structures present in the underlying 3D absorption fields. Using data from other surveys, we identified 18 galaxies with known redshifts coeval with our map volume, enabling a direct comparison with our tomographic map. This shows that galaxies preferentially occupyhigh-density regions, in qualitative agreement with the same comparison applied to simulations. Our results establish the feasibility of the CLAMATO survey, which aims to obtain Ly alpha forest spectra for similar to 1000 SFGs over similar to 1deg(2) of the COSMOS field, in order to map out the intergalactic medium large-scale structure at < z > similar to 2.3 over a large volume (100h(-1) Mpc)(3). C1 [Lee, Khee-Gan; Hennawi, Joseph F.; Eilers, Anna-Christina] Max Planck Inst Astron, D-69117 Heidelberg, Germany. [Stark, Casey; White, Martin; Nugent, Peter] Univ Calif Berkeley, Dept Astron, Berkeley, CA 94720 USA. [Stark, Casey; White, Martin; Nugent, Peter] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. [Prochaska, J. Xavier] Univ Calif Santa Cruz, Dept Astron & Astrophys, Santa Cruz, CA 95064 USA. [Prochaska, J. Xavier; Schlegel, David J.] Univ Calif Santa Cruz, Lick Observ, Santa Cruz, CA 95064 USA. [Arinyo-i-Prats, Andreu] Univ Barcelona IEEC UB, Inst Ciencies Cosmos, E-08028 Barcelona, Spain. [Suzuki, Nao] Univ Tokyo, Kavli Inst Phys & Math Universe IPMU, Kashiwa, Chiba, Japan. [Croft, Rupert A. C.] Carnegie Mellon Univ, Dept Phys, Pittsburgh, PA 15213 USA. [Caputi, Karina I.] Univ Groningen, Kapteyn Astron Inst, NL-9700 AV Groningen, Netherlands. [Cassata, Paolo] Univ Valparaiso, Fac Ciencias, Inst Fis & Astron, Valparaiso, Chile. [Cassata, Paolo; Ilbert, Olivier; Le Brun, Vincent; Le Fevre, Olivier; Tasca, Lidia A. M.; Tresse, Laurence] Aix Marseille Univ, CNRS, Lab Astrophys Marseille, UMR 7326, F-13388 Marseille, France. [Garilli, Bianca] INAF IASF, I-20133 Milan, Italy. [Koekemoer, Anton M.] Space Telescope Sci Inst, Baltimore, MD 21218 USA. [Maccagni, Dario; Zamorani, Gianni; Zucca, Elena] INAF, Osservatorio Astron Bologna, I-40127 Bologna, Italy. [Taniguchi, Yoshiaki] Ehime Univ, Res Ctr Space & Cosm Evolut, Matsuyama, Ehime 7908577, Japan. RP Lee, KG (reprint author), Max Planck Inst Astron, Konigstuhl 17, D-69117 Heidelberg, Germany. EM lee@mpia.de RI White, Martin/I-3880-2015; Zucca, Elena/O-9396-2015; Croft, Rupert/N-8707-2014; OI White, Martin/0000-0001-9912-5070; Zucca, Elena/0000-0002-5845-8132; Croft, Rupert/0000-0003-0697-2583; Lee, Khee-Gan/0000-0001-9299-5719 FU NERSC Center, Office of Science of the U.S. D.O.E. [DE-AC02-05CH11231] FX K.G.L. and A.C.E. are grateful to the National Geographic Society for travel support through the Waitt Grants program. This research used resources of the NERSC Center, which is supported by the Office of Science of the U.S. D.O.E. under Contract No. DE-AC02-05CH11231. We would like to thank those of Hawaiian ancestry, on whose sacred mountain we were privileged to be guests. NR 44 TC 10 Z9 10 U1 0 U2 2 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 2041-8205 EI 2041-8213 J9 ASTROPHYS J LETT JI Astrophys. J. Lett. PD NOV 1 PY 2014 VL 795 IS 1 AR UNSP L12 DI 10.1088/2041-8205/795/1/L12 PG 7 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA AU2NO UT WOS:000345455500012 ER PT J AU Turhollow, A Perlack, R Eaton, L Langholtz, M Brandt, C Downing, M Wright, L Skog, K Hellwinckel, C Stokes, B Lebow, P AF Turhollow, Anthony Perlack, Robert Eaton, Laurence Langholtz, Matthew Brandt, Craig Downing, Mark Wright, Lynn Skog, Kenneth Hellwinckel, Chad Stokes, Bryce Lebow, Patricia TI The updated billion-ton resource assessment SO BIOMASS & BIOENERGY LA English DT Article DE Biomass; Resource assessment; Crop residues; Forest residues; Energy crops; Supply curves AB This paper summarizes the results of an update to a resource assessment, published in 2005, commonly referred to as the Billion-Ton Study (BTS). The updated results are consistent with the 2005 BTS in terms of overall magnitude. The 2005 BTS projected between 860 and 1240 Tg of biomass available in the 2050 timeframe, while the Billion-Ton Update (BT2), for a price of 66 $ Mg-1, projected between 994 and 1483 Tg in 2030. For the BT2, forest residue biomass potential was determined to be less owing to tighter restrictions on forest residue supply including restrictions due to limited projected increase in traditional harvest for pulpwood and sawlogs. Crop residue potential was also determined to be less because of the consideration of soil carbon and not allowing residue removal from conventionally tilled corn acres. Energy crop potential was estimated to be much greater largely because of land availability and modeling of competition among various competing uses of the land. Generally, the scenario assumptions in the updated assessment are much more plausible to show a "billionton" resource, which would be sufficient to displace 30% or more of the country's present petroleum consumption and provide more than enough biomass to meet the 2022 requirements of the Renewable Fuel Standard. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Turhollow, Anthony; Perlack, Robert; Eaton, Laurence; Langholtz, Matthew; Downing, Mark] Oak Ridge Natl Lab, Div Environm Sci, Oak Ridge, TN 37831 USA. [Brandt, Craig] Oak Ridge Natl Lab, Biosci Sci Div, Oak Ridge, TN 37831 USA. [Wright, Lynn; Lebow, Patricia] WrightLink Consulting, Ten Mile, TN 37880 USA. [Skog, Kenneth] US Forest Serv, Forest Prod Lab, USDA, Madison, WI 53726 USA. [Hellwinckel, Chad] Univ Tennessee, Dept Agr Econ, Knoxville, TN 37996 USA. [Stokes, Bryce] CNJV, Golden, CO 80401 USA. RP Turhollow, A (reprint author), Oak Ridge Natl Lab, Div Environm Sci, POB 2008, Oak Ridge, TN 37831 USA. EM turhollowaf@ornl.gov RI Eaton, Laurence/E-1471-2012; OI Eaton, Laurence/0000-0003-1270-9626; Langholtz, Matthew/0000-0002-8153-7154 FU Office of the Biomass Program, U.S. Department of Energy [DE-AC05-00OR22725] FX Support provided by the Office of the Biomass Program, U.S. Department of Energy under contract DE-AC05-00OR22725. We thank Erin Webb for her review of a draft of this article. NR 6 TC 6 Z9 6 U1 3 U2 18 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0961-9534 EI 1873-2909 J9 BIOMASS BIOENERG JI Biomass Bioenerg. PD NOV PY 2014 VL 70 BP 149 EP 164 DI 10.1016/j.biombioe.2014.09.007 PG 16 WC Agricultural Engineering; Biotechnology & Applied Microbiology; Energy & Fuels SC Agriculture; Biotechnology & Applied Microbiology; Energy & Fuels GA AU0YL UT WOS:000345348000015 ER PT J AU Connatser, RM Lewis, SA Keiser, JR Choi, JS AF Connatser, Raynella M. Lewis, Samuel A., Sr. Keiser, James R. Choi, Jae-Soon TI Measuring bio-oil upgrade intermediates and corrosive species with polarity-matched analytical approaches SO BIOMASS & BIOENERGY LA English DT Article DE Biomass; Capillary electrophoresis; Total acid number; Pyrolysis oil upgrading; Carboxylic acid; Corrosion ID FAST PYROLYSIS; CAPILLARY-ELECTROPHORESIS; BIOMASS; FRACTIONS; FUELS; ACIDS AB Integrating biofuels with conventional petroleum products requires improvements in processing to increase blendability with existing fuels. This work demonstrates analysis techniques for more hydrophilic bio-oil liquids that give improved quantitative and qualitative description of the total acid content and organic acid profiles. To protect infrastructure from damage and reduce the cost associated with upgrading, accurate determination of acid content and representative chemical compound analysis are central imperatives to assessing both the corrosivity and the progress toward removing oxygen and acidity in processed biomass liquids. Established techniques form an ample basis for bio-liquids evaluation. However, early in the upgrading process, the unique physical phases and varied hydrophilicity of many pyrolysis liquids can render analytical methods originally designed for use in petroleum-derived oils inadequate. In this work, the water solubility of the organic acids present in bio-oils is exploited in a novel extraction and titration technique followed by analysis on the water-based capillary electrophoresis (CE) platform. The modification of ASTM D664, the standard for Total Acid Number (TAN), to include aqueous carrier solvents improves the utility of that approach for quantifying acid content in hydrophilic bio-oils. Termed AMTAN (modified Total Acid Number), this technique offers 1.2% relative standard deviation and dynamic range comparable to the conventional ASTM method. The results of corrosion product evaluations using several different sources of real bio-oil are discussed in the context of the unique AMTAN and CE analytical approaches developed to facilitate those measurements. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Connatser, Raynella M.; Lewis, Samuel A., Sr.; Keiser, James R.; Choi, Jae-Soon] Oak Ridge Natl Lab, Oak Ridge, TN 37830 USA. RP Connatser, RM (reprint author), Oak Ridge Natl Lab, NTRC Bldg,2360 Cherahala Blvd, Knoxville, TN 37932 USA. EM connatserrm@ornl.gov OI Choi, Jae-Soon/0000-0002-8162-4207 FU United States Department of Energy's Bioenergy Technologies Office [DE-AC05-00OR22725] FX This work was supported by funds provided by the United States Department of Energy's Bioenergy Technologies Office under contract number DE-AC05-00OR22725. NR 30 TC 3 Z9 3 U1 1 U2 12 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0961-9534 EI 1873-2909 J9 BIOMASS BIOENERG JI Biomass Bioenerg. PD NOV PY 2014 VL 70 BP 557 EP 563 DI 10.1016/j.biombioe.2014.09.003 PG 7 WC Agricultural Engineering; Biotechnology & Applied Microbiology; Energy & Fuels SC Agriculture; Biotechnology & Applied Microbiology; Energy & Fuels GA AU0YL UT WOS:000345348000054 ER PT J AU Nguyen, L Cafferty, KG Searcy, EM Spatari, S AF Nguyen, Long Cafferty, Kara G. Searcy, Erin M. Spatari, Sabrina TI Uncertainties in Life Cycle Greenhouse Gas Emissions from Advanced Biomass Feedstock Logistics Supply Chains in Kansas SO ENERGIES LA English DT Article DE life cycle assessment (LCA); lignocellulosic ethanol LCA; greenhouse gas (GHG) emissions; biomass supply chains; uncertainty in biofuel LCA ID ENVIRONMENTAL SUSTAINABILITY IMPACTS; CORN-STOVER; UNITED-STATES; ETHANOL-PRODUCTION; SWITCHGRASS; DESIGNS; CARBON; SYSTEM; POWER AB To meet Energy Independence and Security Act (EISA) cellulosic biofuel mandates, the United States will require an annual domestic supply of about 242 million Mg of biomass by 2022. To improve the feedstock logistics of lignocellulosic biofuels in order to access available biomass resources from areas with varying yields, commodity systems have been proposed and designed to deliver quality-controlled biomass feedstocks at preprocessing "depots". Preprocessing depots densify and stabilize the biomass prior to long-distance transport and delivery to centralized biorefineries. The logistics of biomass commodity supply chains could introduce spatially variable environmental impacts into the biofuel life cycle due to needing to harvest, move, and preprocess biomass from multiple distances that have variable spatial density. This study examines the uncertainty in greenhouse gas (GHG) emissions of corn stover logistics within a bio-ethanol supply chain in the state of Kansas, where sustainable biomass supply varies spatially. Two scenarios were evaluated each having a different number of depots of varying capacity and location within Kansas relative to a central commodity-receiving biorefinery to test GHG emissions uncertainty. The first scenario sited four preprocessing depots evenly across the state of Kansas but within the vicinity of counties having high biomass supply density. The second scenario located five depots based on the shortest depot-to-biorefinery rail distance and biomass availability. The logistics supply chain consists of corn stover harvest, collection and storage, feedstock transport from field to biomass preprocessing depot, preprocessing depot operations, and commodity transport from the biomass preprocessing depot to the biorefinery. Monte Carlo simulation was used to estimate the spatial uncertainty in the feedstock logistics gate-to-gate sequence. Within the logistics supply chain GHG emissions are most sensitive to the transport of the densified biomass, which introduces the highest variability (0.2-13 g CO(2)e/MJ) to life cycle GHG emissions. Moreover, depending upon the biomass availability and its spatial density and surrounding transportation infrastructure (road and rail), logistics can increase the variability in life cycle environmental impacts for lignocellulosic biofuels. Within Kansas, life cycle GHG emissions could range from 24 g CO(2)e/MJ to 41 g CO(2)e/MJ depending upon the location, size and number of preprocessing depots constructed. However, this range can be minimized through optimizing the siting of preprocessing depots where ample rail infrastructure exists to supply biomass commodity to a regional biorefinery supply system. C1 [Nguyen, Long; Spatari, Sabrina] Drexel Univ, Philadelphia, PA 19104 USA. [Cafferty, Kara G.; Searcy, Erin M.] Idaho Natl Lab, Dept Biofuels & Renewable Energy Technol, Idaho Falls, ID 83415 USA. RP Spatari, S (reprint author), Drexel Univ, Philadelphia, PA 19104 USA. EM lkn25@drexel.edu; kara.cafferty@inl.gov; erin.searcy@inl.gov; spatari@drexel.edu FU Freshman Design fellowship program at Drexel; Agriculture and Food Research Initiative from the United States Department of Agriculture National Institute of Food and Agriculture [2012-68005-19703] FX The authors thank four anonymous reviewers for their insightful comments, which improved this manuscript. Long Nguyen was supported by the Freshman Design fellowship program at Drexel. He thanks Cem Sahin and Aswathi John for the assistance with MATLAB programming, and James G. Mitchell for discussion on this manuscript. This research was supported by Agriculture and Food Research Initiative Competitive Grant No. 2012-68005-19703 from the United States Department of Agriculture National Institute of Food and Agriculture. NR 48 TC 5 Z9 5 U1 3 U2 41 PU MDPI AG PI BASEL PA POSTFACH, CH-4005 BASEL, SWITZERLAND SN 1996-1073 J9 ENERGIES JI Energies PD NOV PY 2014 VL 7 IS 11 BP 7125 EP 7146 DI 10.3390/en7117125 PG 22 WC Energy & Fuels SC Energy & Fuels GA AU4EW UT WOS:000345563200012 ER PT J AU Lee, S Fischer, TB Stokes, MR Klingler, RJ Ilavsky, J McCarty, DK Wigand, MO Derkowski, A Winans, RE AF Lee, Sungwon Fischer, Timothy B. Stokes, M. Rebecca Klingler, Robert J. Ilavsky, Jan McCarty, Douglas K. Wigand, Marcus O. Derkowski, Arkadiusz Winans, Randall E. TI Dehydration Effect on the Pore Size, Porosity, and Fractal Parameters of Shale Rocks: Ultrasmall-Angle X-ray Scattering Study SO ENERGY & FUELS LA English DT Article ID LAYER CLAY-MINERALS; SURFACE-AREA; GAS-ADSORPTION; NEUTRON-SCATTERING; ORGANIC-MATTER; SMECTITE; MONTMORILLONITE; DEHYDROXYLATION; TEMPERATURE; USANS/SANS AB The characterization of pore networks is extremely important in understanding transport and storage phenomena in unconventional gas and oil reservoir rocks. An ultrasmall-angle X-ray scattering (USAXS) measurement has been performed on Silurian black shales from the Baltic Basin, Poland, from a wide range of depths along a burial diagenetic sequence. This study provides insight into the nature of the pore structure, including the pore size distribution, total porosity, and fractal dimensions of the rocks. Samples were measured in both their air-dried state, equilibrated at similar to 50% relative humidity, and prior to dehydration by drying at 200 degrees C to make a comprehensive comparison of the pore structure changes induced by dehydration. Two trends were observed: porosity values decreased with depth as expected from the models of porosity evolution with burial and increased upon sample dehydration. The USAXS-measured porosity values show very good correspondence with the measurements by immersion porosity methods. The increase in porosity upon dehydration was found to be dominated by a volume increase in the pores of 1001000 nm diameter; the pores were filled by capillary water and clay-bound water in the air-dry state and liberated during drying. The geometric irregularities of poreshale rock interfaces have been quantified by fractal dimension. The removal of water from the sample also serves to increase the fractal dimension suggesting that the removal of water molecules increases the surface or mass irregularity. Implications to shale porosity measurement and shale gas models are discussed. C1 [Lee, Sungwon; Klingler, Robert J.; Ilavsky, Jan; Winans, Randall E.] Argonne Natl Lab, Xray Sci Div, Argonne, IL 60439 USA. [Fischer, Timothy B.; Stokes, M. Rebecca; McCarty, Douglas K.; Wigand, Marcus O.] Chevron Energy Technol Co, Houston, TX 77042 USA. [Derkowski, Arkadiusz] Polish Acad Sci, Inst Geol Sci, PL-31002 Krakow, Poland. RP Winans, RE (reprint author), Argonne Natl Lab, Xray Sci Div, 9700 S Cass Ave, Argonne, IL 60439 USA. EM rewinans@anl.gov RI Ilavsky, Jan/D-4521-2013 OI Ilavsky, Jan/0000-0003-1982-8900 FU Chevron Energy Technology Company; National Science Foundation [NSF/CHE-1346572]; U.S. DOE [AC02-06CH11357] FX The authors acknowledge the financial support of Chevron Energy Technology Company. ChemMatCARS Sector 15 is supported by the National Science Foundation under Grant NSF/CHE-1346572. Use of the Advanced Photon Source, an Office of Science User Facility operated for the U.S. Deparnilent of Energy (DOE) Office of Science by Argonne National Laboratory, is supported by the U.S. DOE under Contract DE-AC02-06CH11357. The authors thank Dr. Kevin Gilbert for many helpful discussions. The authors also thank Tomasz Top& and Artur Kufigiewicz for help in the sample collecting campaign and sample handling and performing the immersion porosity measurements. NR 45 TC 5 Z9 6 U1 1 U2 52 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0887-0624 EI 1520-5029 J9 ENERG FUEL JI Energy Fuels PD NOV PY 2014 VL 28 IS 11 BP 6772 EP 6779 DI 10.1021/ef501427d PG 8 WC Energy & Fuels; Engineering, Chemical SC Energy & Fuels; Engineering GA AU2TB UT WOS:000345469300009 ER PT J AU George, A Morgan, TJ Kandiyoti, R AF George, Anthe Morgan, Trevor J. Kandiyoti, Rafael TI Pyrolytic Reactions of Lignin within Naturally Occurring Plant Matrices: Challenges in Biomass Pyrolysis Modeling Due to Synergistic Effects SO ENERGY & FUELS LA English DT Article ID FLUIDIZED-BED REACTOR; FLASH PYROLYSIS; CATALYTIC PYROLYSIS; COAL PYROLYSIS; HEATING RATES; TRANSPORTATION FUELS; CHEMICAL-COMPOSITION; SECONDARY REACTIONS; ORGANOSOLV LIGNIN; BITUMINOUS COALS AB Systematically larger char yields were observed from the pyrolysis of chemically isolated lignins, compared to expected yields from the pyrolysis of lignins embedded in plant material. Naturally occurring lignins are known to be intermeshed with other plant constituents within the composite matrices of lignocellulosic biomass. An attempt was made to simulate their behavior by pyrolyzing pellets prepared from mixtures of lignin and cellulose powders. However, the results gave char yield trends that did not conform to trends observed when pyrolyzing plant derived biomass. These findings are interpreted in terms of entirely different reaction pathways operating when lignins are pyrolyzed within naturally occurring biomass, compared to pure lignins or composite particles made from mixtures of fine powders. It appears that char yield trends from the pyrolysis of lignocellulosic biomass are closely linked to the detailed morphology, as well as the chemical makeup, of the highly oxygenated plant derived material within which the lignin components of plants are embedded. The observed sensitivity of reaction pathways to plant specific structural (morphological) features poses added challenges in formulating realistic ab initio mathematical models for predicting the pyrolysis chemistry of lignocellulosic biomass. C1 [George, Anthe] Sandia Natl Labs, Combust Res Facil, Livermore, CA 94550 USA. [Morgan, Trevor J.] Univ Hawaii Manoa, Hawaii Nat Energy Inst, Honolulu, HI 96822 USA. [Kandiyoti, Rafael] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn, London SW7 2AZ, England. RP George, A (reprint author), Sandia Natl Labs, Combust Res Facil, 7011 East Ave, Livermore, CA 94550 USA. EM ageorge@lbl.gov NR 57 TC 7 Z9 7 U1 1 U2 19 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0887-0624 EI 1520-5029 J9 ENERG FUEL JI Energy Fuels PD NOV PY 2014 VL 28 IS 11 BP 6918 EP 6927 DI 10.1021/ef501459c PG 10 WC Energy & Fuels; Engineering, Chemical SC Energy & Fuels; Engineering GA AU2TB UT WOS:000345469300026 ER PT J AU Beste, A AF Beste, Ariana TI ReaxFF Study of the Oxidation of Softwood Lignin in View of Carbon Fiber Production SO ENERGY & FUELS LA English DT Article ID REACTIVE FORCE-FIELD; MOLECULAR-DYNAMICS SIMULATIONS; INITIAL-STAGE; KRAFT LIGNIN; COMBUSTION; PYROLYSIS; LINKAGES; VALORIZATION; MECHANISM; KINETICS AB We investigate the oxidative, thermal conversion of softwood lignin by performing molecular dynamics simulations based on a reactive force field (ReaxFF). The lignin samples are constructed from coniferyl alcohol units, which are connected through linkages that are randomly selected from a natural distribution of linkages in softwood. The goal of this work is to simulate the oxidative stabilization step during carbon fiber production from lignin precursor. We find that at simulation conditions where stabilization reactions occur, the lignin fragments have already undergone extensive degradation. The 5-5 linkage shows the highest reactivity toward cyclization and dehydrogenation. C1 [Beste, Ariana] Univ Tennessee, Joint Inst Computat Sci, Oak Ridge, TN 37831 USA. [Beste, Ariana] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA. RP Beste, A (reprint author), Univ Tennessee, Joint Inst Computat Sci, Oak Ridge, TN 37831 USA. EM bestea@ornl.gov OI Beste, Ariana/0000-0001-9132-792X FU Oak Ridge National Laboratory by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy FX This research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy. This research was supported by an allocation of advanced computing resources provided by the National Science Foundation. The computations were performed on Kraken at the National Institute for Computational Sciences (http://www.nics.tennessee.edu/). NR 34 TC 4 Z9 5 U1 4 U2 59 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0887-0624 EI 1520-5029 J9 ENERG FUEL JI Energy Fuels PD NOV PY 2014 VL 28 IS 11 BP 7007 EP 7013 DI 10.1021/ef501901p PG 7 WC Energy & Fuels; Engineering, Chemical SC Energy & Fuels; Engineering GA AU2TB UT WOS:000345469300037 ER PT J AU Jensen, KR Voorhees, KJ Dempsey, EA Burton, J Ratcliff, MA McCormick, RL AF Jensen, Kirk R. Voorhees, Kent J. Dempsey, Edward A. Burton, Jonathan Ratcliff, Matthew A. McCormick, Robert L. TI Formation of 2,6-Di-tert-butyl-4-nitrophenol during Combustion of Diesel Fuel Antioxidant Precursors SO ENERGY & FUELS LA English DT Article ID POLYCYCLIC AROMATIC-HYDROCARBONS; MONOCHROMATOR-MASS SPECTROMETRY; PARTICULATE EXTRACTS; NITRO-DERIVATIVES; MUTAGENICITY; DISPOSITION; CONTAMINANT; EMISSIONS; AIRBORNE; DBNP AB Alkylphenolic antioxidants are commonly used as additives to stabilize gasoline, jet, and diesel fuels. The use of antioxidants in diesel, in particular, has become more common because of increased blending of cracked gas oils and blending of biodiesel. Combustion of these phenolic compounds may have unintended consequences. Nitroaromatic compounds are of particular interest because many are listed as known or suspected carcinogens. During the analysis of previously published data, the identity of an unknown peak was confirmed as 2,6-di-tert-butyl-4-nitrophenol (DBNP), an antioxidant derivative. To determine the source of DBNP, particulate matter samples from combustion of conventional diesel fuels spiked with two possible antioxidant precursors were collected and analyzed by electron monochromatormass spectrometry. Results show fuel spiked with either 2,6-di-tert-butylphenol or 4-methyl-2,6-di-tert-butylphenol produced higher levels of DBNP than control samples. Because fuels require antioxidant additives to prevent degradation, careful selection of antioxidants is important. C1 [Jensen, Kirk R.; Voorhees, Kent J.; Dempsey, Edward A.] Colorado Sch Mines, Dept Chem & Geochem, Golden, CO 80401 USA. [Burton, Jonathan; Ratcliff, Matthew A.; McCormick, Robert L.] Natl Renewable Energy Lab, Golden, CO 80401 USA. RP Voorhees, KJ (reprint author), Colorado Sch Mines, Dept Chem & Geochem, Golden, CO 80401 USA. EM kvoorhee@mines.edu RI McCormick, Robert/B-7928-2011 FU Vehicle Technologies Office, Office of Energy Efficiency and Renewable Energy, United States Department of Energy [DE-AC36-99GO10337]; National Renewable Energy Laboratory FX This work was supported by the Vehicle Technologies Office, Office of Energy Efficiency and Renewable Energy, United States Department of Energy, under Contract DE-AC36-99GO10337, with the National Renewable Energy Laboratory. The authors also thank Dr. Nora Traviss, Dr. William Navidi, and Dr. John Dane for their insights. NR 26 TC 0 Z9 0 U1 0 U2 8 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0887-0624 EI 1520-5029 J9 ENERG FUEL JI Energy Fuels PD NOV PY 2014 VL 28 IS 11 BP 7038 EP 7042 DI 10.1021/ef501043s PG 5 WC Energy & Fuels; Engineering, Chemical SC Energy & Fuels; Engineering GA AU2TB UT WOS:000345469300040 ER PT J AU Wagnon, SW Karwat, DMA Wooldridge, MS Westbrook, CK AF Wagnon, Scott W. Karwat, Darshan M. A. Wooldridge, Margaret S. Westbrook, Charles K. TI Experimental and Modeling Study of Methyl trans-3-Hexenoate Autoignition SO ENERGY & FUELS LA English DT Article ID JET-STIRRED REACTOR; RAPID-COMPRESSION FACILITY; REFLECTED SHOCK-WAVES; IGNITION DELAY TIMES; FLOW DIFFUSION FLAME; LOW-TEMPERATURE; DOUBLE-BOND; BIODIESEL SURROGATE; CHEMICAL-KINETICS; N-HEPTANE AB This work presents the results of an experimental and computational study of methyl trans-3-hexenoate autoignition. Experimental autoignition studies were conducted using the University of Michigan rapid compression facility. Pressure time histories were used to determine ignition delay times as a function of test gas composition and experimental conditions. The fuel/oxygen equivalence ratio and dilution level were phi = 0.3 and inert/O-2 = 3.76 (mole basis). End of compression conditions targeted an average pressure of 10.5 atm and temperatures ranging from 884 to 1085 K. A correlation in Arrhenius form was developed by regression analysis of the experimental data, where the ignition delay time is tau(ign) (ms) = 1.4 x 10(6) exp[30 100/((R) over bar T-(cal mol1 K1))] with a R-2 value of 0.99. Gas-sampling experiments were also conducted to measure stable intermediates formed during autoignition. A detailed reaction mechanism was developed and model predictions were compared to the experimental data. While ignition delay time predictions are in excellent agreement with the experimental data, the speciation results highlight uncertainties in the reaction chemistry of unsaturated esters and small hydrocarbon intermediates. C1 [Wagnon, Scott W.; Karwat, Darshan M. A.; Wooldridge, Margaret S.] Univ Michigan, Dept Mech Engn, Ann Arbor, MI 48109 USA. [Karwat, Darshan M. A.; Wooldridge, Margaret S.] Univ Michigan, Dept Aerosp Engn, Ann Arbor, MI 48109 USA. [Westbrook, Charles K.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. RP Wagnon, SW (reprint author), Univ Michigan, Dept Mech Engn, Ann Arbor, MI 48109 USA. EM swagnon@umich.edu OI Wagnon, Scott/0000-0003-2172-5230 FU program of the Office of Basic Energy Sciences, Office of Science, U.S. Depaanient of Energy [DE-SC0002645] FX This material is based on work supported by the program of the Office of Basic Energy Sciences, Office of Science, U.S. Depaanient of Energy, under Award DE-SC0002645. NR 53 TC 3 Z9 3 U1 3 U2 11 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0887-0624 EI 1520-5029 J9 ENERG FUEL JI Energy Fuels PD NOV PY 2014 VL 28 IS 11 BP 7227 EP 7234 DI 10.1021/ef501806s PG 8 WC Energy & Fuels; Engineering, Chemical SC Energy & Fuels; Engineering GA AU2TB UT WOS:000345469300060 ER PT J AU Gao, YF Xu, JM Yang, SC Tang, XM Zhou, Q Ge, J Xu, TF Levinson, R AF Gao, Yafeng Xu, Jiangmin Yang, Shichao Tang, Xiaomin Zhou, Quan Ge, Jing Xu, Tengfang Levinson, Ronnen TI Cool roofs in China: Policy review, building simulations, and proof-of-concept experiments SO ENERGY POLICY LA English DT Article DE Cool roofs; China; Building energy efficiency standards; Energy savings; Emission reductions ID SOLAR REFLECTANCE; ENERGY SAVINGS; COMMERCIAL BUILDINGS; ENVELOPE SURFACES; STRATEGIES; REDUCTION AB While the concept of reflective roofing is not new to China, most Chinese cool roof research has taken place within the past decade. Some national and local Chinese building energy efficiency standards credit or recommend, but do not require, cool roofs or walls. EnergyPlus simulations of standard-compliant Chinese office and residential building prototypes in seven Chinese cities (Harbin, Changchun, Beijing, Chongqing, Shanghai, Wuhan, and Guangzhou) showed that substituting an aged white roof (albedo 0.6) for an aged gray roof (albedo 0.2) yields positive annual load, energy, energy cost, CO2, NO., and SO2 savings in all hot-summer cities (Chongqing, Shanghai, Wuhan, and Guangzhou). Measurements in an office building in Chongqing in August 2012 found that a white coating lowered roof surface temperature by about 20 degrees C, and reduced daily air conditioning energy use by about 9%. Measurements in a naturally ventilated factory in Guangdong Province in August 2011 showed that a white coating decreased roof surface temperature by about 17 degrees C, lowered room air temperature by 1-3 degrees C, and reduced daily roof heat flux by 66%. Simulation and experimental results suggest that cool roofs should be credited or prescribed in building energy efficiency standards for both hot summer/warm winter and hot summer/cold winter climates in China. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Gao, Yafeng; Xu, Jiangmin; Tang, Xiaomin] Chongqing Univ, Fac Urban Construct & Environm Engn, Minist Educ, Key Lab Gorges Reservoir Reg Ecoenvironm 3, Chongqing 400044, Peoples R China. [Yang, Shichao; Zhou, Quan] Guangdong Prov Acad Bldg Res, Guangzhou 510500, Guangdong, Peoples R China. [Ge, Jing; Xu, Tengfang; Levinson, Ronnen] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. RP Levinson, R (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, 1 Cyclotron Rd,MS 90R2000, Berkeley, CA 94720 USA. EM gaoyafeng79@126.com; RML27@cornell.edu FU Integrated Research of Key Technologies of Building Facade System [2010DFA72740-03-06]; Fundamental Research Funds for the Central Universities of China [106112014CDJZR210006, CDJZR12210013]; US-China Clean Energy Research Center Building Energy Efficiency (CERC-BEE) Consortium; Energy Efficiency and Renewable Energy, Office of Building Technology, State, and Community Programs, of the U.S. Department of Energy [DE-AC02-05CH11231] FX The authors would like to express their thanks for financial support from the Integrated Research of Key Technologies of Building Facade System (2010DFA72740-03-06); from the Fundamental Research Funds for the Central Universities of China (No. 106112014CDJZR210006 and No. CDJZR12210013); and from the US-China Clean Energy Research Center Building Energy Efficiency (CERC-BEE) Consortium. The study was further supported by the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Building Technology, State, and Community Programs, of the U.S. Department of Energy under Contract no. DE-AC02-05CH11231. We would also like to thank Changqing LIN (MOHURD Research Institute of Standards and Norms); Hunter XU and Justin CHEN (Dow Chemical); Zhiqiang WANG (Chongqing University); and Tianzhen HONG (Lawrence Berkeley National Laboratory). NR 77 TC 8 Z9 8 U1 4 U2 37 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0301-4215 EI 1873-6777 J9 ENERG POLICY JI Energy Policy PD NOV PY 2014 VL 74 BP 190 EP 214 DI 10.1016/j.enpol.2014.05.036 PG 25 WC Energy & Fuels; Environmental Sciences; Environmental Studies SC Energy & Fuels; Environmental Sciences & Ecology GA AU2TL UT WOS:000345470300020 ER PT J AU Koliba, C DeMenno, M Brune, N Zia, A AF Koliba, Christopher DeMenno, Mercy Brune, Nancy Zia, Asim TI The salience and complexity of building, regulating, and governing the smart grid: Lessons from a statewide public-private partnership SO ENERGY POLICY LA English DT Article DE Smart gird; Energy policy; Public-private partnership; Regulation; Issue salience; Technical complexity ID AMERICAN STATES; DEREGULATION; TECHNOLOGY; METERS AB Smart grid deployment unfolds within a diverse array of multi-institutional arrangements that may be too fragmented and decentralized to allow for the kind of large-scale and coordinated investments needed to properly deploy the smart grid. This case study provides an account of how one state arranged for and eventually deployed smart grid technology to over 85 percent of its resident. The study asks: does the deployment of the smart grid introduce new socio-political variables into the electricity distribution industry? To make sense of the socio-political variables shaping the industry and regulators, the Salience-Complexity Model is used to assess whether the smart grid raises or lowers the level of public scrutiny caste upon the industry (issue salience) and the level of technical capacity needed to execute and utilize the smart grid (technical complexity). The conclusions to be drawn from this study include: smart grid technology heightens the issue salience and the technical complexity of electricity distribution, but that the smart grid will likely not have a significant impact on the restructuring of electricity regulation. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Koliba, Christopher; Zia, Asim] Univ Vermont, Burlington, VT 05405 USA. [DeMenno, Mercy] Sandia Natl Labs, Albuquerque, NM 87123 USA. [Brune, Nancy] Kenny Guinn Ctr Policy Prior, Las Vegas, NV USA. RP Koliba, C (reprint author), Univ Vermont, 103 Morrill Hall, Burlington, VT 05405 USA. EM ckoliba@uvm.edu FU National Science Foundation [DGE-1144388] FX The authors would like to thank representatives from the following organizations for their support for this project: Central Vermont Public Service (CVPS), Green Mountain Power (GMP), Vermont Electric Power Company (VELCO), Vermont Electric Cooperative (VEC), The Vermont Public Service Board, the Vermont Department of Public Service, Sandia National Laboratories, and the University of Vermont. They would also like to thank the reviewers for their thoughtful comments an earlier version of this paper. National Science Foundation grant number DGE-1144388 provided partial support for this research. NR 24 TC 3 Z9 3 U1 3 U2 16 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0301-4215 EI 1873-6777 J9 ENERG POLICY JI Energy Policy PD NOV PY 2014 VL 74 BP 243 EP 252 DI 10.1016/j.enpol.2014.09.013 PG 10 WC Energy & Fuels; Environmental Sciences; Environmental Studies SC Energy & Fuels; Environmental Sciences & Ecology GA AU2TL UT WOS:000345470300024 ER PT J AU Moradi-Pari, E Nasiriani, N Fallah, YP Famouri, P Bossart, S Dodrill, K AF Moradi-Pari, Ehsan Nasiriani, Neda Fallah, Yaser P. Famouri, Parviz Bossart, Steve Dodrill, Keith TI Design, Modeling, and Simulation of On-Demand Communication Mechanisms for Cyber-Physical Energy Systems SO IEEE TRANSACTIONS ON INDUSTRIAL INFORMATICS LA English DT Article DE Communication networks; communication strategy; DNP3; dynamical systems; protocols; PSCAD; smart grid; transient level simulation ID LINEAR PREDICTION; POWER-SYSTEM; REQUIREMENTS AB Advanced communication technology is the enabling factor for distributed sensing and control in smart grid. The performance of communication has a significant effect on the performance of the controllers that manage a power system. This effect is more profound when transient level behavior and critical applications are concerned. In these cases, an important issue is to design control-aware communication strategies for utilizing available communication technologies. Such strategies should describe what needs to be communicated when and between which nodes. In this paper, an "on-demand" strategy is presented that describes how communication subsystems should be configured, almost agnostically to the underlying technologies, to achieve significant performance improvement for the application. The on-demand method relies on the concept of error-dependent communication for tracking dynamical systems over communication networks. The paper also introduces the design of an embedded communication simulator integrated with PSCAD for cosimulation of communication strategies/protocols and power system components. C1 [Moradi-Pari, Ehsan; Nasiriani, Neda; Fallah, Yaser P.; Famouri, Parviz] W Virginia Univ, Dept Comp Sci & Elect Engn, Morgantown, WV 26505 USA. [Bossart, Steve; Dodrill, Keith] Natl Energy Technol Lab, Morgantown, WV 26505 USA. RP Moradi-Pari, E (reprint author), W Virginia Univ, Dept Comp Sci & Elect Engn, Morgantown, WV 26505 USA. EM ehmoradipari@mix.wvu.edu NR 39 TC 7 Z9 8 U1 2 U2 18 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 1551-3203 EI 1941-0050 J9 IEEE T IND INFORM JI IEEE Trans. Ind. Inform. PD NOV PY 2014 VL 10 IS 4 BP 2330 EP 2339 DI 10.1109/TII.2014.2326080 PG 10 WC Automation & Control Systems; Computer Science, Interdisciplinary Applications; Engineering, Industrial SC Automation & Control Systems; Computer Science; Engineering GA AT5PZ UT WOS:000344995800034 ER PT J AU Oakes, MM Baxter, LK Duvall, RM Madden, M Xie, MJ Hannigan, MP Peel, JL Pachon, JE Balachandran, S Russell, A Long, TC AF Oakes, Michelle M. Baxter, Lisa K. Duvall, Rachelle M. Madden, Meagan Xie, Mingjie Hannigan, Michael P. Peel, Jennifer L. Pachon, Jorge E. Balachandran, Siv Russell, Armistead Long, Thomas C. TI Comparing Multipollutant Emissions-Based Mobile Source Indicators to Other Single Pollutant and Multipollutant Indicators in Different Urban Areas SO INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH LA English DT Article DE multipollutant; air pollution; exposure metrics; source apportionment; mobile sources; emissions-based indicators ID POSITIVE MATRIX FACTORIZATION; SEMIVOLATILE ORGANIC-COMPOUNDS; AIR-QUALITY MANAGEMENT; SOURCE-APPORTIONMENT; TIME-SERIES; PARTICULATE MATTER; AMBIENT AIR; PM2.5 CHARACTERIZATION; SPECIATION METHODS; MEASUREMENT ERROR AB A variety of single pollutant and multipollutant metrics can be used to represent exposure to traffic pollutant mixtures and evaluate their health effects. Integrated mobile source indicators (IMSIs) that combine air quality concentration and emissions data have recently been developed and evaluated using data from Atlanta, Georgia. IMSIs were found to track trends in traffic-related pollutants and have similar or stronger associations with health outcomes. In the current work, we apply IMSIs for gasoline, diesel and total (gasoline + diesel) vehicles to two other cities (Denver, Colorado and Houston, Texas) with different emissions profiles as well as to a different dataset from Atlanta. We compare spatial and temporal variability of IMSIs to single-pollutant indicators (carbon monoxide (CO), nitrogen oxides (NOx) and elemental carbon (EC)) and multipollutant source apportionment factors produced by Positive Matrix Factorization (PMF). Across cities, PMF-derived and IMSI gasoline metrics were most strongly correlated with CO (r = 0.31-0.98), while multipollutant diesel metrics were most strongly correlated with EC (r = 0.80-0.98). NOx correlations with PMF factors varied across cities (r = 0.29-0.67), while correlations with IMSIs were relatively consistent (r = 0.61-0.94). In general, single-pollutant metrics were more correlated with IMSIs (r = 0.58-0.98) than with PMF-derived factors (r = 0.07-0.99). A spatial analysis indicated that IMSIs were more strongly correlated (r > 0.7) between two sites in each city than single pollutant and PMF factors. These findings provide confidence that IMSIs provide a transferable, simple approach to estimate mobile source air pollution in cities with differing topography and source profiles using readily available data. C1 [Oakes, Michelle M.; Madden, Meagan; Long, Thomas C.] US EPA, Natl Ctr Environm Assessment, Res Triangle Pk, NC 27711 USA. [Oakes, Michelle M.] Oak Ridge Inst Sci & Educ, Oak Ridge, TN 37831 USA. [Baxter, Lisa K.; Duvall, Rachelle M.] US EPA, Natl Exposure Res Lab, Res Triangle Pk, NC USA. [Xie, Mingjie; Hannigan, Michael P.] Univ Colorado, Coll Engn & Appl Sci, Dept Mech Engn, Boulder, CO 80309 USA. [Xie, Mingjie] Virginia Polytech Inst & State Univ, Dept Civil & Environm Engn, Blacksburg, VA 24061 USA. [Peel, Jennifer L.] Colorado State Univ, Dept Environm & Radiol Hlth Sci, Ft Collins, CO 80523 USA. [Pachon, Jorge E.] La Salle Univ, Program Environm Engn, Bogota, CO USA. [Balachandran, Siv; Russell, Armistead] Georgia Inst Technol, Dept Civil & Environm Engn, Atlanta, GA 30332 USA. [Balachandran, Siv] Union Concerned Scientists, Washington, DC 20006 USA. RP Oakes, MM (reprint author), US EPA, Natl Ctr Environm Assessment, Res Triangle Pk, NC 27711 USA. EM mmoakes17@gmail.com; baxter.lisa@epa.gov; duvall.rachelle@epa.gov; meagankmadden@gmail.com; mingjie.xie@colorado.edu; hannigan@colorado.edu; jennifer.peel@colostate.edu; jpachon@unisalle.edu.co; siv@gatech.edu; ted.russell@ce.gatech.edu; long.tom@epa.gov FU Research Participation Program in the National Center for Environmental Assessment, Office of Research and Development, U.S. Environmental Protection Agency FX The authors wish to thank Michael Breen, Steven J. Dutton, Jennifer Richmond-Bryant, Reeder Sams, and John Vandenberg for their helpful comments in review of this manuscript. The authors also wish to thank Alison Eyth and Adam Reff at the U.S. Environmental Protection Agency for their help retrieving mobile source emissions data. MMO was supported by an appointment to the Research Participation Program in the National Center for Environmental Assessment, Office of Research and Development, U.S. Environmental Protection Agency, administered by the Oak Ridge Institute for Science and Education (ORISE) through an interagency agreement between the U.S. Department of Energy and Environmental Protection Agency. Disclaimer: The views expressed are those of the authors and do not necessarily reflect the views or policies of the U.S. Environmental Protection Agency. NR 38 TC 1 Z9 1 U1 3 U2 30 PU MDPI AG PI BASEL PA POSTFACH, CH-4005 BASEL, SWITZERLAND SN 1660-4601 J9 INT J ENV RES PUB HE JI Int. J. Environ. Res. Public Health PD NOV PY 2014 VL 11 IS 11 BP 11727 EP 11752 DI 10.3390/ijerph111111727 PG 26 WC Environmental Sciences; Public, Environmental & Occupational Health SC Environmental Sciences & Ecology; Public, Environmental & Occupational Health GA AU3RT UT WOS:000345532000044 PM 25405595 ER PT J AU Cheng, MD Allman, SL Ludtka, GM Avens, LR AF Cheng, Meng-Dawn Allman, Steve L. Ludtka, Gerard M. Avens, Larry R. TI Collection of airborne particles by a high-gradient permanent magnetic method SO JOURNAL OF AEROSOL SCIENCE LA English DT Article DE Aerosol; Collection; High-gradient magnetic; Permanent magnet; Separation; Ultrafine particles ID AIR-POLLUTION; SHANGHAI; DUST AB We report on the use of magnetic force in collection of airborne particles by a high-gradient permanent magnetic separation (HGPMS) device. Three aerosol particles of different magnetic susceptibility (NaCl, CuO, and Fe3O4) were generated in the electrical mobility size range of 10-200 nm and were used to study HGPMS collection. One HGPMS matrix element, made of stainless steel wool, was used in the device configuration. Three flow rates were selected to simulate the environmental wind speeds of interest to the study. Magnetic force was found to exhibit an insignificant effect on the separation of NaCI particles, even in the HGPMS configuration. Diffusion was a major mechanism in the removal of the diamagnetic particles; however, diffusion is insignificant under the influence of a high-gradient magnetic field for paramagnetic or ferromagnetic particles. The HGPMS showed high-performance collection (>99%) of paramagnetic CuO and ferromagnetic Fe3O4 particles for particle sizes greater than or equal to 60 nm. As the wind speed increases, the influence of the magnetic force weakens, and the capability to remove particles from the gas stream diminishes. The results suggest that the HGPMS principle could be explored for development of an advanced miniaturized passive aerosol collector. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Cheng, Meng-Dawn] Oak Ridge Natl Lab, Div Environm Sci, Oak Ridge, TN 37831 USA. [Allman, Steve L.] Oak Ridge Natl Lab, BioSci Div, Oak Ridge, TN 37831 USA. [Ludtka, Gerard M.] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA. [Avens, Larry R.] Oak Ridge Natl Lab, Int Secur & Anal Div, Oak Ridge, TN 37831 USA. RP Cheng, MD (reprint author), Oak Ridge Natl Lab, Div Environm Sci, POB 2008,MS 6036, Oak Ridge, TN 37831 USA. EM chengmd@ornl.gov RI Allman, Steve/A-9121-2011; OI Allman, Steve/0000-0001-6538-7048; Cheng, Meng-Dawn/0000-0003-1407-9576 FU Laboratory Directed Research and Development Program of Oak Ridge National Laboratory; U.S. Department of Energy [DE-ACO5-000R22725] FX Bart Murphy manufactured the test magnets used in this project and performed the magnetic field strength measurement using a Hall probe. Shannon Mahurin performed the imaging on CuO particles using the Hitachi HD-2000 STEM available at the Center for Nanophase Materials Sciences at Oak Ridge National Laboratory. The authors greatly appreciated the generous gift of Fe3O4 particles from J.W. Moon and T.J. Phelps, both in the BioSciences Division at ORNL. This work would not be possible without the funding from the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. Department of Energy under Contract no. DE-ACO5-000R22725. The authors also acknowledge useful discussion with Conniesue Oldham and Dennis Mikel of the Office of Air Quality Planning and Standards of the U.S. Environmental Protection Agency. NR 19 TC 1 Z9 1 U1 1 U2 20 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0021-8502 EI 1879-1964 J9 J AEROSOL SCI JI J. Aerosol. Sci. PD NOV PY 2014 VL 77 BP 1 EP 9 DI 10.1016/j.jaerosci.2014.07.002 PG 9 WC Engineering, Chemical; Engineering, Mechanical; Environmental Sciences; Meteorology & Atmospheric Sciences SC Engineering; Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences GA AU2YP UT WOS:000345480700001 ER PT J AU Henderson, SA Tetzlaff, MT Pattanaprichakul, P Fox, P Torres-Cabala, CA Bassett, RL Prieto, VG Richards, HW Curry, JL AF Henderson, Samuel A. Tetzlaff, Michael T. Pattanaprichakul, Penvadee Fox, Patricia Torres-Cabala, Carlos A. Bassett, Roland L. Prieto, Victor G. Richards, Hunter W. Curry, Jonathan L. TI Detection of mitotic figures and G2+tumor nuclei with histone markers correlates with worse overall survival in patients with Merkel cell carcinoma SO JOURNAL OF CUTANEOUS PATHOLOGY LA English DT Article DE biomarker; H3K79me3T80ph; histones; Merkel cell carcinoma; PHH3 ID P63 EXPRESSION; PROGNOSTIC-SIGNIFICANCE; SINGLE INSTITUTION; POLYOMAVIRUS; H3; INDEX; SPECIMENS; ACCURACY; FEATURES; UTILITY AB BackgroundHigh mitotic figure count (MFC) correlates with low survival rate in Merkel cell carcinoma (MCC). However, the prognostic impact of histone biomarkers as surrogates of MFC in MCC is unknown. We evaluated the prognostic significance of the immunodetection of mitotic figures and of G2+ tumor nuclei with histone-associated mitotic markers H3K79me3T80ph (H3KT) and phosphohistone H3 (PHH3) in MCC. MethodsImmunohistochemical analyses of H3KT and PHH3 and proliferative marker Ki-67 were performed in a series of 21 cases of MCC. The significance of the pathologic data and immunoreactivity with these markers was evaluated with Pearson correlation and paired Student t-test. Univariate Cox proportional hazards regression models were performed to assess the relationships between these markers and survival. ResultsH3KT detected a higher number of mitotic figure (p<0.0001) and G2+ tumor nuclei (p<0.0052) than did PHH3. Furthermore, the MFC combined with G2+ tumor nuclei detected with H3KT compared to PHH3 and manual MFC was a significant predictor of impaired survival in patients with MCC (p=0.035;HR=1.0172), corresponding to a 1.72% increased risk of death for each unit increase in H3KT. ConclusionsBiomarker analysis of proliferative rates with histone markers may have relevance in stratifying risk in patients with MCC. C1 [Henderson, Samuel A.; Tetzlaff, Michael T.; Pattanaprichakul, Penvadee; Fox, Patricia; Torres-Cabala, Carlos A.; Bassett, Roland L.; Prieto, Victor G.; Curry, Jonathan L.] Univ Texas MD Anderson Canc Ctr, Houston, TX 77030 USA. [Pattanaprichakul, Penvadee] Mahidol Univ, Siriraj Hosp, Fac Med, Bangkok 10700, Thailand. [Richards, Hunter W.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. RP Curry, JL (reprint author), Univ Texas MD Anderson Canc Ctr MDACC, Unit 85, 1515 Holcombe Blvd, Houston, TX 77030 USA. EM jlcurry@mdanderson.org RI Fox, Patricia/I-2208-2014 OI Fox, Patricia/0000-0002-5264-1876 FU NIH/NCI [P30 CA016672] FX This work was supported in part by the NIH/NCI under award number P30 CA016672. NR 35 TC 3 Z9 4 U1 1 U2 1 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0303-6987 EI 1600-0560 J9 J CUTAN PATHOL JI J. Cutan. Pathol. PD NOV PY 2014 VL 41 IS 11 BP 846 EP 852 DI 10.1111/cup.12383 PG 7 WC Dermatology; Pathology SC Dermatology; Pathology GA AU4PO UT WOS:000345594100006 PM 25263506 ER PT J AU Raghunathan, S Wood, OR Mangat, P Verduijn, E Philipsen, V Hendrickx, E Jonckheere, R Goldberg, KA Benk, MP Kearney, P Levinson, Z Smith, BW AF Raghunathan, Sudharshanan Wood, Obert R., II Mangat, Pawitter Verduijn, Erik Philipsen, Vicky Hendrickx, Eric Jonckheere, Rik Goldberg, Kenneth A. Benk, Markus P. Kearney, Patrick Levinson, Zachary Smith, Bruce W. TI Experimental measurements of telecentricity errors in high-numerical-aperture extreme ultraviolet mask images SO JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B LA English DT Article ID MULTILAYERS AB Nontelecentric illumination in extreme ultraviolet (EUV) lithography leads to pattern shifts through focus called telecentricity errors. As the industry moves toward finer pitch structures and higher numerical apertures (NA) to improve resolution, the effects of telecentricity errors become more significant. These telecentricity errors are dependent on pattern pitch, pattern type, lens aberrations, mask stack, to name a few. In this paper, a novel technique to measure telecentricity errors using EUV mask images from an actinic mask inspection tool, called the SEMATECH High NA Actinic Reticle Review Project (SHARP) is presented. SHARP is SEMATECH's second generation actinic mask imaging tool developed by Lawrence Berkeley National Laboratory. The SHARP can image masks at different numerical aperture settings, even beyond the currently available scanner NA of 0.33 (high-NA EUV) and also has a set of programmable illuminator choices. A tuned multilayer EUV mask blank was fabricated with test structures optimized for imaging on SHARP. The test structures were designed to cover a variety of critical dimensions and pitches. The mask design was fabricated on a tuned multilayer blank optimized for NA > 0.4. The mask was fabricated at Advanced Mask Technology Center and imaged on the SHARP. SHARP images were analyzed in software customized for edge position extraction of features. Pattern shifts through focus were calculated for a variety of pitches under different NA and illumination settings. The results show a monotonic increase in pattern shifts as NA increases. Also, at a given NA, the pattern shift is dependent on pattern pitch. The paper provides a detailed discussion on the experiment setup, analysis of the results and applicability of these results to high volume manufacturing of semiconductor devices using production EUV scanners. (C) 2014 American Vacuum Society. C1 [Raghunathan, Sudharshanan; Wood, Obert R., II; Mangat, Pawitter] GLOBALFOUNDRIES, Malta, NY 12020 USA. [Verduijn, Erik] GLOBALFOUNDRIES, B-3001 Leuven, Belgium. [Philipsen, Vicky; Hendrickx, Eric; Jonckheere, Rik] IMEC VZW, B-3001 Leuven, Belgium. [Goldberg, Kenneth A.; Benk, Markus P.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Ctr X Ray Opt, Berkeley, CA 94720 USA. [Kearney, Patrick] SEMATECH, Albany, NY 12203 USA. [Levinson, Zachary; Smith, Bruce W.] Rochester Inst Technol, Microsyst Engn Program, Rochester, NY 14623 USA. RP Raghunathan, S (reprint author), GLOBALFOUNDRIES, 400 Stonebreak Rd Extens, Malta, NY 12020 USA. EM sudhar.raghunathan@globalfoundries.com FU SEMATECH; Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231] FX Measurements performed on the SHARP EUV microscope were funded by SEMATECH and conducted by the Center for X-Ray Optics at the Lawrence Berkeley National Laboratory Advanced Light Source synchrotron radiation facility. The Advanced Light Source is supported by the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. NR 10 TC 9 Z9 9 U1 0 U2 3 PU A V S AMER INST PHYSICS PI MELVILLE PA STE 1 NO 1, 2 HUNTINGTON QUADRANGLE, MELVILLE, NY 11747-4502 USA SN 1071-1023 J9 J VAC SCI TECHNOL B JI J. Vac. Sci. Technol. B PD NOV PY 2014 VL 32 IS 6 AR 06F801 DI 10.1116/1.4901876 PG 8 WC Engineering, Electrical & Electronic; Nanoscience & Nanotechnology; Physics, Applied SC Engineering; Science & Technology - Other Topics; Physics GA AU3KU UT WOS:000345512800018 ER PT J AU Rahman, A Liu, MZ Black, CT AF Rahman, Atikur Liu, Mingzhao Black, Charles T. TI Block copolymer self assembly for design and vapor-phase synthesis of nanostructured antireflective surfaces SO JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B LA English DT Article ID THIN-FILMS; DEPOSITION; GROWTH; NANOPARTICLES; LITHOGRAPHY; SILICON; ARRAYS AB The authors combine block copolymer self assembly with vapor-phase synthesis for design of antireflective thin film coatings. The nanometer-scale features in patterns formed by cylindrical phase block copolymers provide surface topography for vapor-phase growth of semiconductors and metals by oblique angle physical vapor deposition. The authors control the dimensions and density of the synthesized nanotextures through selection of copolymer molecular weight. A layer of aligned, densely packed germanium wire arrays with diameters much smaller than optical wavelengths acts as an effective optical medium, significantly reducing reflections and improving light coupling into a silicon substrate. A synthesized layer of uniformly sized silver nanoparticles provides antireflection instead through optical excitation of localized surface plasmons. The block copolymer-based synthesis approach allows control of particle shape anisotropy, tuning the frequency of plasmon resonances and expanding the spectral range of antireflection. (C) 2014 American Vacuum Society. C1 [Rahman, Atikur; Liu, Mingzhao; Black, Charles T.] Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11973 USA. RP Rahman, A (reprint author), Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11973 USA. EM ctblack@bnl.gov RI Liu, Mingzhao/A-9764-2011 OI Liu, Mingzhao/0000-0002-0999-5214 FU U.S. Department of Energy, Office of Basic Energy Sciences [DE-AC02-98CH10886] FX Research carried out at the Center for Functional Nanomaterials, Brookhaven National Laboratory, which is supported by the U.S. Department of Energy, Office of Basic Energy Sciences, under Contract No. DE-AC02-98CH10886. NR 30 TC 3 Z9 3 U1 3 U2 33 PU A V S AMER INST PHYSICS PI MELVILLE PA STE 1 NO 1, 2 HUNTINGTON QUADRANGLE, MELVILLE, NY 11747-4502 USA SN 1071-1023 J9 J VAC SCI TECHNOL B JI J. Vac. Sci. Technol. B PD NOV PY 2014 VL 32 IS 6 AR 06FE02 DI 10.1116/1.4896335 PG 5 WC Engineering, Electrical & Electronic; Nanoscience & Nanotechnology; Physics, Applied SC Engineering; Science & Technology - Other Topics; Physics GA AU3KU UT WOS:000345512800031 ER PT J AU Wei, DM Edgar, JH Briggs, DP Retterer, ST Srijanto, B Hensley, DK Meyer, HM AF Wei, Daming Edgar, James H. Briggs, Dayrl P. Retterer, Scott T. Srijanto, Bernadeta Hensley, Dale K. Meyer, Harry M., III TI Atomic layer deposition TiO2-Al2O3 stack: An improved gate dielectric on Ga-polar GaN metal oxide semiconductor capacitors SO JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B LA English DT Article ID INTERFACE PROPERTIES; FILMS; OXIDATION AB This research focuses on the benefits and properties of TiO2-Al2O3 nanostack thin films deposited on Ga2O3/GaN by plasma-assisted atomic layer deposition (PA-ALD) for gate dielectric development. This combination of materials achieved a high dielectric constant, a low leakage current, and a low interface trap density. Correlations were sought between the films' structure, composition, and electrical properties. The gate dielectrics were approximately 15nm thick and contained 5.1 nm TiO2, 7.1nm Al2O3, and 2nm Ga2O3 as determined by spectroscopic ellipsometry. The interface carbon concentration, as measured by x-ray photoelectron spectroscopy depth profile, was negligible for GaN pretreated by thermal oxidation in O-2 for 30 min at 850 degrees C. The RMS roughness slightly increased after thermal oxidation and remained the same after ALD of the nanostack, as determined by atomic force microscopy. The dielectric constant of TiO2-Al2O3 on Ga2O3/GaN was increased to 12.5 compared to that of pure Al2O3 (8-9) on GaN. In addition, the nanostack's capacitance-voltage (C-V) hysteresis was small, with a total trap density of 8.74 x 10(11) cm(-2). The gate leakage current density (J - 2.81 x 10(-8) A/cm(2)) was low at +1V gate bias. These results demonstrate the promising potential of PA-ALD deposited TiO2/Al2O3 for serving as the gate dielectric on Ga2O3/GaN based MOS devices. (C) 2014 American Vacuum Society. C1 [Wei, Daming; Edgar, James H.] Kansas State Univ, Dept Chem Engn, Manhattan, KS 66506 USA. [Briggs, Dayrl P.; Retterer, Scott T.; Srijanto, Bernadeta; Hensley, Dale K.] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Nanofabricat Res Lab, Oak Ridge, TN 37831 USA. [Meyer, Harry M., III] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA. RP Wei, DM (reprint author), Kansas State Univ, Dept Chem Engn, Durland Hall, Manhattan, KS 66506 USA. EM edgarjh@ksu.edu RI Retterer, Scott/A-5256-2011; Hensley, Dale/A-6282-2016; Srijanto, Bernadeta/D-4213-2016 OI Retterer, Scott/0000-0001-8534-1979; Hensley, Dale/0000-0001-8763-7765; Srijanto, Bernadeta/0000-0002-1188-1267 FU Office of Naval Research (ONR) [N00014-09-1-1160]; Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy [CNMS2013-334]; Office of FreedomCAR and Vehicle Technologies, as part of the High Temperature Materials Laboratory User Program, Oak Ridge National Laboratory; U.S. Department of Energy [DE-AC05-00OR22725] FX This study was supported by the Office of Naval Research (ONR) with Grant No. N00014-09-1-1160. Part of this research was conducted at the Center for Nanophase Materials Sciences under proposal ID: CNMS2013-334, which is sponsored at Oak Ridge National Laboratory by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy. The XPS work was sponsored by the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of FreedomCAR and Vehicle Technologies, as part of the High Temperature Materials Laboratory User Program, Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. Department of Energy under Contract No. DE-AC05-00OR22725. NR 30 TC 0 Z9 0 U1 7 U2 32 PU A V S AMER INST PHYSICS PI MELVILLE PA STE 1 NO 1, 2 HUNTINGTON QUADRANGLE, MELVILLE, NY 11747-4502 USA SN 1071-1023 J9 J VAC SCI TECHNOL B JI J. Vac. Sci. Technol. B PD NOV PY 2014 VL 32 IS 6 AR 060602 DI 10.1116/1.4897919 PG 4 WC Engineering, Electrical & Electronic; Nanoscience & Nanotechnology; Physics, Applied SC Engineering; Science & Technology - Other Topics; Physics GA AU3KU UT WOS:000345512800056 ER PT J AU Aryal, D Etampawala, T Perahia, D Grest, GS AF Aryal, Dipak Etampawala, Thusitha Perahia, Dvora Grest, Gary S. TI Phase Behavior of a Single Structured Ionomer Chain in Solution SO MACROMOLECULAR THEORY AND SIMULATIONS LA English DT Article ID SULFONATED PENTABLOCK COPOLYMER; POLYSTYRENE IONOMERS; MOLECULAR-DYNAMICS; BLOCK-COPOLYMERS; MEMBRANES; WATER; CONDUCTIVITY; SIMULATIONS; MORPHOLOGY; POLYMERS AB Structured polymers offer a means to tailor transport pathways within mechanically stable manifolds. The building block of such a membrane is examined, namely a single large pentablock co-polymer that consists of a center block of a randomly sulfonated polystyrene, designed for transport, tethered to poly-ethylene-r-propylene and end-capped by poly-t-butyl styrene, for mechanical stability, using molecular dynamics simulations. The polymer structure in a cyclohexane-heptane mixture, a technologically viable solvent, and in water, a poor solvent for all segments and a ubiquitous substance is extracted. In all solvents the pentablock collapsed into nearly spherical aggregates where the ionic block is segregated. In hydrophobic solvents, the ionic block resides in the center, surrounded by swollen intermix of flexible and end blocks. In water all blocks are collapsed with the sulfonated block residing on the surface. Our results demonstrate that solvents drive different local nano-segregation, providing a gateway to assemble membranes with controlled topology. C1 [Aryal, Dipak; Etampawala, Thusitha; Perahia, Dvora] Clemson Univ, Dept Chem, Clemson, SC 29634 USA. [Grest, Gary S.] Sandia Natl Labs, Albuquerque, NM 87185 USA. RP Perahia, D (reprint author), Clemson Univ, Dept Chem, Clemson, SC 29634 USA. EM dperahi@g.clemson.edu FU DOE [DE-FG02-12ER46843]; Office of Science of the United States Department of Energy [DE-AC02-05CH11231]; U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX The authors gratefully acknowledge financial support from DOE Grant No. DE-FG02-12ER46843. This research used resources at the National Energy Research Scientific Computing Center, which is supported by the Office of Science of the United States Department of Energy under Contract No. DE-AC02-05CH11231. This work was made possible by advanced computational resources deployed and maintained by Clemson Computing and Information Technology. This work was performed, in part, at the Center for Integrated Nanotechnologies, a U.S. Department of Energy and Office of Basic Energy Sciences user facility. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under Contract No. DE-AC04-94AL85000. NR 29 TC 5 Z9 5 U1 5 U2 28 PU WILEY-V C H VERLAG GMBH PI WEINHEIM PA BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY SN 1022-1344 EI 1521-3919 J9 MACROMOL THEOR SIMUL JI Macromol. Theory Simul. PD NOV PY 2014 VL 23 IS 9 BP 543 EP 549 DI 10.1002/mats.201400046 PG 7 WC Polymer Science SC Polymer Science GA AU2IY UT WOS:000345442500001 ER PT J AU Gabelli, SB Boto, A Kuhns, VH Bianchet, MA Farinelli, F Aripirala, S Yoder, J Jakoncic, J Tomaselli, GF Amzel, LM AF Gabelli, Sandra B. Boto, Agedi Kuhns, Victoria Halperin Bianchet, Mario A. Farinelli, Federica Aripirala, Srinivas Yoder, Jesse Jakoncic, Jean Tomaselli, Gordon F. Amzel, L. Mario TI Regulation of the Na(V)1.5 cytoplasmic domain by calmodulin SO NATURE COMMUNICATIONS LA English DT Article ID SODIUM-CHANNEL NA(V)1.5; FACTOR HOMOLOGOUS FACTOR; SOLUTION NMR STRUCTURE; C-TERMINAL DOMAIN; X-RAY STRUCTURES; EF-HAND DOMAIN; APO-CALMODULIN; CARDIAC EXCITABILITY; IQ MOTIF; MODULATION AB Voltage-gated sodium channels (Na-V) underlie the rapid upstroke of action potentials in excitable tissues. Binding of channel-interactive proteins is essential for controlling fast and long-term inactivation. In the structure of the complex of the carboxy-terminal portion of Na(V)1.5 (CTNa(V)1.5) with calmodulin (CaM)-Mg2+ reported here, both CaM lobes interact with the CTNa(V)1.5. On the basis of the differences between this structure and that of an inactivated complex, we propose that the structure reported here represents a non-inactivated state of the CTNaV, that is, the state that is poised for activation. Electrophysiological characterization of mutants further supports the importance of the interactions identified in the structure. Isothermal titration calorimetry experiments show that CaM binds to CTNa(V)1.5 with high affinity. The results of this study provide unique insights into the physiological activation and the pathophysiology of Na-V channels. C1 [Gabelli, Sandra B.; Boto, Agedi; Bianchet, Mario A.; Aripirala, Srinivas; Yoder, Jesse; Amzel, L. Mario] Johns Hopkins Univ, Sch Med, Dept Biophys & Biophys Chem, Struct Enzymol & Thermodynam Grp, Baltimore, MD 21205 USA. [Gabelli, Sandra B.; Kuhns, Victoria Halperin; Farinelli, Federica; Tomaselli, Gordon F.] Johns Hopkins Univ, Sch Med, Dept Med, Div Cardiol, Baltimore, MD 21205 USA. [Gabelli, Sandra B.] Johns Hopkins Univ, Sch Med, Dept Oncol, Baltimore, MD 21287 USA. [Bianchet, Mario A.] Johns Hopkins Univ, Sch Med, Dept Neurol, Baltimore, MD 21287 USA. [Jakoncic, Jean] Brookhaven Natl Lab, Photon Sci Directorate, Natl Synchrotron Light Source, Upton, NY 11973 USA. RP Gabelli, SB (reprint author), Johns Hopkins Univ, Sch Med, Dept Biophys & Biophys Chem, Struct Enzymol & Thermodynam Grp, 725 N Wolfe St,WBSB 608, Baltimore, MD 21205 USA. EM gabelli@jhmi.edu; gtomasel@jhmi.edu; mamzel@jhmi.edu RI Bianchet, Mario/K-2131-2015; Gabelli, Sandra/A-3705-2008 OI Bianchet, Mario/0000-0001-9032-7549; Gabelli, Sandra/0000-0003-1205-5204 FU NIH [HL050411]; US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]; National Institute of General Medical Sciences, National Institute of Health [GM-0080]; US Department of energy [DE AC02-98CH10886]; NHI NIDDK center [P30 DK089502] FX This work was funded in part by NIH HL050411. Use of the Advanced Photon Source at Argonne National Laboratory was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. Use of the Lilly Research Laboratories Collaborative Access Team beamline at Sector 31 of the Advanced Photon Source was provided by Eli Lilly Company, which operates the facility. Data collection was carried out at beamline X6A, funded by the National Institute of General Medical Sciences, National Institute of Health under agreement GM-0080. The NSLS, Brookhaven National Laboratory is supported by the US Department of energy under contract No. DE AC02-98CH10886. We acknowledge the use and services of the JHU SOM Mass Spectrometry and Proteomics Core, supported by the NHI NIDDK center grant P30 DK089502. The rendition of Fig. 8 was contributed by T. Phelps, M.S. NR 44 TC 9 Z9 9 U1 4 U2 12 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 2041-1723 J9 NAT COMMUN JI Nat. Commun. PD NOV PY 2014 VL 5 AR 5126 DI 10.1038/ncomms6126 PG 11 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA AU5BL UT WOS:000345622000001 PM 25370050 ER PT J AU Kuttiyiel, KA Sasaki, K Su, D Wu, LJ Zhu, YM Adzic, RR AF Kuttiyiel, Kurian A. Sasaki, Kotaro Su, Dong Wu, Lijun Zhu, Yimei Adzic, Radoslav R. TI Gold-promoted structurally ordered intermetallic palladium cobalt nanoparticles for the oxygen reduction reaction SO NATURE COMMUNICATIONS LA English DT Article ID MEMBRANE FUEL-CELLS; SUPPORTED PD-CO; ALLOY ELECTROCATALYSTS; SHELL ELECTROCATALYSTS; HEAT-TREATMENT; PARTICLE-SIZE; MONOLAYER; CATALYSTS; PLATINUM; ALKALINE AB Considerable efforts to make palladium and palladium alloys active catalysts and a possible replacement for platinum have had a marginal success. Here we report on a structurally ordered Au10Pd40Co50 catalyst that exhibits comparable activity to conventional platinum catalysts in both acid and alkaline media. Electron microscopic techniques demonstrate that, at elevated temperatures, palladium cobalt nanoparticles undergo an atomic structural transition from core-shell to a rare intermetallic ordered structure with twin boundaries forming stable {111}, {110} and {100} facets via addition of gold atoms. The superior stability of this catalyst compared with platinum after 10,000 potential cycles in alkaline media is attributed to the atomic structural order of PdCo nanoparticles along with protective effect of clusters of gold atoms on the surface. This strategy of making ordered palladium intermetallic alloy nanoparticles can be used in diverse heterogeneous catalysis where particle size and structural stability matter. C1 [Kuttiyiel, Kurian A.; Sasaki, Kotaro; Adzic, Radoslav R.] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA. [Su, Dong] Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11973 USA. [Wu, Lijun; Zhu, Yimei] Brookhaven Natl Lab, Dept Condensed Matter Phys & Mat Sci, Upton, NY 11973 USA. RP Sasaki, K (reprint author), Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA. EM ksasaki@bnl.gov; adzic@bnl.gov FU US Department of Energy, Office of Basic Energy Science, Material Science and Engineering Division, Division of Chemical Sciences, Geosciences and Biosciences Division [DE-AC02-98CH10886]; Synchrotron Catalysis Consortium, US Department of Energy [DE-FG02-05ER15688] FX This research was performed at Brookhaven National laboratory under contract DE-AC02-98CH10886 with the US Department of Energy, Office of Basic Energy Science, Material Science and Engineering Division, Division of Chemical Sciences, Geosciences and Biosciences Division. Beam lines X18A at the NSLS are supported in part by the Synchrotron Catalysis Consortium, US Department of Energy Grant No DE-FG02-05ER15688. NR 53 TC 24 Z9 24 U1 25 U2 201 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 2041-1723 J9 NAT COMMUN JI Nat. Commun. PD NOV PY 2014 VL 5 AR 5185 DI 10.1038/ncomms6185 PG 8 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA AU5BY UT WOS:000345623300001 PM 25373826 ER PT J AU Liu, Z Amani, M Najmaei, S Xu, Q Zou, XL Zhou, W Yu, T Qiu, CY Birdwell, AG Crowne, FJ Vajtai, R Yakobson, BI Xia, ZH Dubey, M Ajayan, PM Lou, J AF Liu, Zheng Amani, Matin Najmaei, Sina Xu, Quan Zou, Xiaolong Zhou, Wu Yu, Ting Qiu, Caiyu Birdwell, A. Glen Crowne, Frank J. Vajtai, Robert Yakobson, Boris I. Xia, Zhenhai Dubey, Madan Ajayan, Pulickel M. Lou, Jun TI Strain and structure heterogeneity in MoS2 atomic layers grown by chemical vapour deposition SO NATURE COMMUNICATIONS LA English DT Article ID METAL DICHALCOGENIDE NANOSHEETS; MONOLAYER MOLYBDENUM-DISULFIDE; TOTAL-ENERGY CALCULATIONS; AUGMENTED-WAVE METHOD; RAMAN-SPECTROSCOPY; UNIAXIAL STRAIN; PHASE GROWTH; THIN MOS2; BASIS-SET; PHOTOLUMINESCENCE AB Monolayer molybdenum disulfide (MoS2) has attracted tremendous attention due to its promising applications in high-performance field-effect transistors, phototransistors, spintronic devices and nonlinear optics. The enhanced photoluminescence effect in monolayer MoS2 was discovered and, as a strong tool, was employed for strain and defect analysis in MoS2. Recently, large-size monolayer MoS2 has been produced by chemical vapour deposition, but has not yet been fully explored. Here we systematically characterize chemical vapour deposition-grown MoS2 by photoluminescence spectroscopy and mapping and demonstrate non-uniform strain in single-crystalline monolayer MoS2 and strain-induced bandgap engineering. We also evaluate the effective strain transferred from polymer substrates to MoS2 by three-dimensional finite element analysis. Furthermore, our work demonstrates that photoluminescence mapping can be used as a non-contact approach for quick identification of grain boundaries in MoS2. C1 [Liu, Zheng] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore. [Liu, Zheng] Nanyang Technol Univ, NOVITAS, Nanoelect Ctr Excellence, Sch Elect & Elect Engn, Singapore 639798, Singapore. [Liu, Zheng] CINTRA CNRS NTU THALES, UMI 3288, Singapore 637553, Singapore. [Amani, Matin; Birdwell, A. Glen; Crowne, Frank J.; Dubey, Madan] US Army, Res Lab, Sensors & Elect Devices Directorate, Adelphi, MD 20783 USA. [Najmaei, Sina; Zou, Xiaolong; Vajtai, Robert; Yakobson, Boris I.; Ajayan, Pulickel M.; Lou, Jun] Rice Univ, Dept Mat Sci & Nanoengn, Houston, TX 77005 USA. [Xu, Quan; Xia, Zhenhai] Univ N Texas, Dept Mat Sci & Engn, Denton, TX 76203 USA. [Xu, Quan] China Univ Petr, Inst New Energy, Beijing 102200, Peoples R China. [Zhou, Wu] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA. [Yu, Ting; Qiu, Caiyu] Nanyang Technol Univ, Sch Phys & Math Sci, Div Phys & Appl Phys, Singapore 637371, Singapore. RP Lou, J (reprint author), Rice Univ, Dept Mat Sci & Nanoengn, Houston, TX 77005 USA. EM madan.dubey.civ@mail.mil; ajayan@rice.edu; jlou@rice.edu RI Liu, Zheng/C-1813-2014; Zhou, Wu/D-8526-2011 OI Liu, Zheng/0000-0002-8825-7198; Zhou, Wu/0000-0002-6803-1095 FU Welch Foundation [C-1716]; NSF [ECCS-1327093, CNS-0821727, OCI-0959097]; U.S. Army Research Office MURI grant [W911NF-11-1-0362]; U.S. Army Research Lab (ARL) Director's Strategic Initiative (DSI) program on interfaces in stacked 2D atomic layered materials; U.S. Office of Naval Research MURI grant [N000014-09-1-1066]; Nanoelectronics Research Corporation [S201006]; Wigner Fellowship through the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory; ORNL's Center for Nanophase Materials Sciences (CNMS); Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. DOE; FAME Center; MARCO, one of six centres of STARnet; DARPA; Singapore National Research Foundation under NRF RF Award [NRF-RF2013-08]; Nanyang Technological University [M4081137.070] FX This work was supported by the Welch Foundation grant C-1716, the NSF grant ECCS-1327093, the U.S. Army Research Office MURI grant W911NF-11-1-0362, the U.S. Army Research Lab (ARL) Director's Strategic Initiative (DSI) program on interfaces in stacked 2D atomic layered materials, the U.S. Office of Naval Research MURI grant N000014-09-1-1066, the Nanoelectronics Research Corporation contract S201006, a Wigner Fellowship through the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. DOE (W.Z.), and through a user project supported by ORNL's Center for Nanophase Materials Sciences (CNMS), which is sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. DOE. This work was also supported in part by the FAME Center, one of six centres of STARnet, a Semiconductor Research Corporation program sponsored by MARCO and DARPA. This work was also supported by the Singapore National Research Foundation under NRF RF Award No. NRF-RF2013-08, the start-up funding from Nanyang Technological University (M4081137.070). The computations were performed at the Cyberinfrastructure for Computational Research funded by NSF under Grant CNS-0821727 and the Data Analysis and Visualization Cyberinfrastructure funded by NSF under Grant OCI-0959097. NR 41 TC 77 Z9 77 U1 22 U2 226 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 2041-1723 J9 NAT COMMUN JI Nat. Commun. PD NOV PY 2014 VL 5 AR 5246 DI 10.1038/ncomms6246 PG 9 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA AU5NJ UT WOS:000345653500001 PM 25404060 ER PT J AU Ren, AM Kosutic, M Rajashankar, KR Frener, M Santner, T Westhof, E Micura, R Patel, DJ AF Ren, Aiming Kosutic, Marija Rajashankar, Kanagalaghatta R. Frener, Marina Santner, Tobias Westhof, Eric Micura, Ronald Patel, Dinshaw J. TI In-line alignment and Mg2+ coordination at the cleavage site of the env22 twister ribozyme SO NATURE COMMUNICATIONS LA English DT Article ID HEPATITIS-DELTA-VIRUS; SELF-CLEAVING RIBOZYMES; GROUP-II INTRON; CRYSTAL-STRUCTURE; HAIRPIN RIBOZYME; STRUCTURAL BASIS; SATELLITE RNA; SPLICING RNA; CATALYSIS; MECHANISMS AB Small self-cleaving nucleolytic ribozymes contain catalytic domains that accelerate site-specific cleavage/ligation of phosphodiester backbones. We report on the 2.9-angstrom crystal structure of the env22 twister ribozyme, which adopts a compact tertiary fold stabilized by co-helical stacking, double-pseudoknot formation and long-range pairing interactions. The U-A cleavage site adopts a splayed-apart conformation with the modelled 2'-O of U positioned for in-line attack on the adjacent to-be-cleaved P-O5' bond. Both an invariant guanosine and a Mg2+ are directly coordinated to the non-bridging phosphate oxygens at the U-A cleavage step, with the former positioned to contribute to catalysis and the latter to structural integrity. The impact of key mutations on cleavage activity identified an invariant guanosine that contributes to catalysis. Our structure of the in-line aligned env22 twister ribozyme is compared with two recently reported twister ribozymes structures, which adopt similar global folds, but differ in conformational features around the cleavage site. C1 [Ren, Aiming; Patel, Dinshaw J.] Mem Sloan Kettering Canc Ctr, Struct Biol Program, New York, NY 10065 USA. [Kosutic, Marija; Frener, Marina; Santner, Tobias; Micura, Ronald] Leopold Franzens Univ, Inst Organ Chem, A-6020 Innsbruck, Austria. [Kosutic, Marija; Frener, Marina; Santner, Tobias; Micura, Ronald] Ctr Mol Biosci Innsbruck CMBI, A-6020 Innsbruck, Austria. [Rajashankar, Kanagalaghatta R.] Cornell Univ, Argonne Natl Lab, Adv Photon Source, Dept Chem & Chem Biol,NE CAT, Argonne, IL 60439 USA. [Westhof, Eric] Univ Strasbourg, CNRS, Inst Mol & Cellular Biol, Architecture & React ARN, F-67084 Strasbourg, France. RP Patel, DJ (reprint author), Mem Sloan Kettering Canc Ctr, Struct Biol Program, New York, NY 10065 USA. EM ronald.micura@uibk.ac.at; pateld@mskcc.org FU National Institute of General Medical Sciences [P41 GM103403]; National Institutes of Health; US DOE [DE-AC02-06CH11357]; US National Institutes of Health [1 U19 CA179564]; Austrian Science Fund FWF [P21641, I1040] FX We thank Dr Dhirendra Simanshu for help with refinement protocols. X-ray diffraction studies were conducted at the Advanced Photon Source on the Northeastern Collaborative Access Team beamlines, which are supported by a grant from the National Institute of General Medical Sciences (P41 GM103403) from the National Institutes of Health. Use of the Advanced Photon Source, an Office of Science User Facility operated for the US Department of Energy (DOE) Office of Science by Argonne National Laboratory, was supported by the US DOE under Contract No. DE-AC02-06CH11357. The research was supported by US National Institutes of Health grant 1 U19 CA179564 to D.J.P. and the Austrian Science Fund FWF (P21641, I1040) to R.M. M.K. is an ESR fellow of the EU FP7Marie Curie ITN RNPnet programme (289007). NR 37 TC 20 Z9 20 U1 2 U2 20 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 2041-1723 J9 NAT COMMUN JI Nat. Commun. PD NOV PY 2014 VL 5 AR 5534 DI 10.1038/ncomms6534 PG 10 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA AU5BP UT WOS:000345622500011 PM 25410397 ER PT J AU Generous, N Fairchild, G Deshpande, A Del Valle, SY Priedhorsky, R AF Generous, Nicholas Fairchild, Geoffrey Deshpande, Alina Del Valle, Sara Y. Priedhorsky, Reid TI Global Disease Monitoring and Forecasting with Wikipedia SO PLOS COMPUTATIONAL BIOLOGY LA English DT Article ID MALARIA SURVEILLANCE; HEALTH INFORMATION; GOOGLE TRENDS; INTERNET; SEARCH; INFLUENZA; QUERIES; OUTBREAK; PATTERNS; BURDEN AB Infectious disease is a leading threat to public health, economic stability, and other key social structures. Efforts to mitigate these impacts depend on accurate and timely monitoring to measure the risk and progress of disease. Traditional, biologically-focused monitoring techniques are accurate but costly and slow; in response, new techniques based on social internet data, such as social media and search queries, are emerging. These efforts are promising, but important challenges in the areas of scientific peer review, breadth of diseases and countries, and forecasting hamper their operational usefulness. We examine a freely available, open data source for this use: access logs from the online encyclopedia Wikipedia. Using linear models, language as a proxy for location, and a systematic yet simple article selection procedure, we tested 14 location-disease combinations and demonstrate that these data feasibly support an approach that overcomes these challenges. Specifically, our proof-of-concept yields models with r(2) up to 0.92, forecasting value up to the 28 days tested, and several pairs of models similar enough to suggest that transferring models from one location to another without retraining is feasible. Based on these preliminary results, we close with a research agenda designed to overcome these challenges and produce a disease monitoring and forecasting system that is significantly more effective, robust, and globally comprehensive than the current state of the art. C1 [Generous, Nicholas; Fairchild, Geoffrey; Deshpande, Alina; Del Valle, Sara Y.; Priedhorsky, Reid] Los Alamos Natl Lab, Def Syst & Anal Div, Los Alamos, NM 87131 USA. RP Generous, N (reprint author), Los Alamos Natl Lab, Def Syst & Anal Div, Los Alamos, NM 87131 USA. EM generous@lanl.gov RI Trivedi, Kruti/E-7558-2015 FU NIH/NIGMS/MIDAS [U01-GM097658-01]; Defense Threat Reduction Agency (DTRA); Joint Science and Technology Office for Chemical and Biological Defense [CB3656, CB10007]; U.S. Department of Energy through the LANL LDRD Program; Department of Energy [DE-AC52-06NA25396] FX This work is supported in part by NIH/NIGMS/MIDAS under grant U01-GM097658-01 and the Defense Threat Reduction Agency (DTRA), Joint Science and Technology Office for Chemical and Biological Defense under project numbers CB3656 and CB10007. Data collected using QUAC; this functionality was supported by the U.S. Department of Energy through the LANL LDRD Program. Computation used HPC resources provided by the LANL Institutional Computing Program. LANL is operated by Los Alamos National Security, LLC for the Department of Energy under contract DE-AC52-06NA25396. Approved for public release: LA-UR similar to 14-22535. The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript. NR 104 TC 18 Z9 18 U1 3 U2 29 PU PUBLIC LIBRARY SCIENCE PI SAN FRANCISCO PA 1160 BATTERY STREET, STE 100, SAN FRANCISCO, CA 94111 USA SN 1553-734X EI 1553-7358 J9 PLOS COMPUT BIOL JI PLoS Comput. Biol. PD NOV PY 2014 VL 10 IS 11 AR e1003892 DI 10.1371/journal.pcbi.1003892 PG 16 WC Biochemical Research Methods; Mathematical & Computational Biology SC Biochemistry & Molecular Biology; Mathematical & Computational Biology GA AU2NE UT WOS:000345454400005 PM 25392913 ER PT J AU Graw, F Balagopal, A Kandathil, AJ Ray, SC Thomas, DL Ribeiro, RM Perelson, AS AF Graw, Frederik Balagopal, Ashwin Kandathil, Abraham J. Ray, Stuart C. Thomas, David L. Ribeiro, Ruy M. Perelson, Alan S. TI Inferring Viral Dynamics in Chronically HCV Infected Patients from the Spatial Distribution of Infected Hepatocytes SO PLOS COMPUTATIONAL BIOLOGY LA English DT Article ID HEPATITIS-C VIRUS; ACTING ANTIVIRAL AGENTS; I INTERFERON RESPONSE; RIPLEYS K-FUNCTION; HEPATOCELLULAR PROLIFERATION; REPLICATION COMPLEX; RNA REPLICATION; POINT-PROCESSES; HUMAN LIVER; CELLS AB Chronic liver infection by hepatitis C virus (HCV) is a major public health concern. Despite partly successful treatment options, several aspects of intrahepatic HCV infection dynamics are still poorly understood, including the preferred mode of viral propagation, as well as the proportion of infected hepatocytes. Answers to these questions have important implications for the development of therapeutic interventions. In this study, we present methods to analyze the spatial distribution of infected hepatocytes obtained by single cell laser capture microdissection from liver biopsy samples of patients chronically infected with HCV. By characterizing the internal structure of clusters of infected cells, we are able to evaluate hypotheses about intrahepatic infection dynamics. We found that individual clusters on biopsy samples range in size from 4-50 infected cells. In addition, the HCV RNA content in a cluster declines from the cell that presumably founded the cluster to cells at the maximal cluster extension. These observations support the idea that HCV infection in the liver is seeded randomly (e. g. from the blood) and then spreads locally. Assuming that the amount of intracellular HCV RNA is a proxy for how long a cell has been infected, we estimate based on models of intracellular HCV RNA replication and accumulation that cells in clusters have been infected on average for less than a week. Further, we do not find a relationship between the cluster size and the estimated cluster expansion time. Our method represents a novel approach to make inferences about infection dynamics in solid tissues from static spatial data. C1 [Graw, Frederik; Ribeiro, Ruy M.; Perelson, Alan S.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Graw, Frederik] Heidelberg Univ, Ctr Modeling & Simulat Biosci, Heidelberg, Germany. [Balagopal, Ashwin; Kandathil, Abraham J.; Ray, Stuart C.; Thomas, David L.] Johns Hopkins Univ, Dept Med, Baltimore, MD USA. RP Graw, F (reprint author), Los Alamos Natl Lab, Los Alamos, NM 87545 USA. EM frederik.graw@bioquant.uni-heidelberg.de; asp@lanl.gov RI Ray, Stuart/B-7527-2008; OI Ray, Stuart/0000-0002-1051-7260; Ribeiro, Ruy/0000-0002-3988-8241 FU U.S. Department of Energy [DE-AC52-06NA25396]; NIH [GM103452, AI078881, OD011095, AI028433, HL109334]; Center for Modeling and Simulation in the Biosciences (BIOMS); National Institute of Health (NIH) [DA016078, AI081544, EY001765]; European Union; Fundacao para a Ciencia e Tecnologia, Portugal [PCOFUND-GA-2009-246542.604605] FX Portions of this work were performed under the auspices of the U.S. Department of Energy under contract DE-AC52-06NA25396 and supported by NIH grants GM103452 (RMR, ASP), AI078881, OD011095, AI028433, and HL109334 (ASP). FG was also funded by the Center for Modeling and Simulation in the Biosciences (BIOMS). The research is also supported by National Institute of Health (NIH) grants DA016078 (DLT and AB) and AI081544 (AB) and EY001765 (WilmerCore Grant). RMR received partial funding from the European Union and from Fundacao para a Ciencia e Tecnologia, Portugal, under grant no PCOFUND-GA-2009-246542.604605. The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript. NR 59 TC 14 Z9 14 U1 0 U2 8 PU PUBLIC LIBRARY SCIENCE PI SAN FRANCISCO PA 1160 BATTERY STREET, STE 100, SAN FRANCISCO, CA 94111 USA SN 1553-734X EI 1553-7358 J9 PLOS COMPUT BIOL JI PLoS Comput. Biol. PD NOV PY 2014 VL 10 IS 11 AR e1003934 DI 10.1371/journal.pcbi.1003934 PG 15 WC Biochemical Research Methods; Mathematical & Computational Biology SC Biochemistry & Molecular Biology; Mathematical & Computational Biology GA AU2NE UT WOS:000345454400023 PM 25393308 ER PT J AU Jonkers, W Leeder, AC Ansong, C Wang, YX Yang, F Starr, TL Camp, DG Smith, RD Glass, NL AF Jonkers, Wilfried Leeder, Abigail C. Ansong, Charles Wang, Yuexi Yang, Feng Starr, Trevor L. Camp, David G., II Smith, Richard D. Glass, N. Louise TI HAM-5 Functions As a MAP Kinase Scaffold during Cell Fusion in Neurospora crassa SO PLOS GENETICS LA English DT Article ID ACTIVATED PROTEIN-KINASE; HYPHAL FUSION; APPRESSORIUM FORMATION; FUNGICIDE RESISTANCE; FUSARIUM-OXYSPORUM; FILAMENTOUS FUNGUS; NUCLEAR-DYNAMICS; GENE; YEAST; NETWORK AB Cell fusion in genetically identical Neurospora crassa germlings and in hyphae is a highly regulated process involving the activation of a conserved MAP kinase cascade that includes NRC-1, MEK-2 and MAK-2. During chemotrophic growth in germlings, the MAP kinase cascade members localize to conidial anastomosis tube (CAT) tips every,8 minutes, perfectly out of phase with another protein that is recruited to the tip: SOFT, a recently identified scaffold for the MAK-1 MAP kinase pathway in Sordaria macrospora. How the MAK-2 oscillation process is initiated, maintained and what proteins regulate the MAP kinase cascade is currently unclear. A global phosphoproteomics approach using an allele of mak-2 (mak-2(Q100G)) that can be specifically inhibited by the ATP analog 1NM-PP1 was utilized to identify MAK-2 kinase targets in germlings that were potentially involved in this process. One such putative target was HAM-5, a protein of unknown biochemical function. Previously, Dham-5 mutants were shown to be deficient for hyphal fusion. Here we show that HAM-5-GFP co-localized with NRC-1, MEK-2 and MAK-2 and oscillated with identical dynamics from the cytoplasm to CAT tips during chemotropic interactions. In the Dmak-2 strain, HAM-5-GFP localized to punctate complexes that did not oscillate, but still localized to the germling tip, suggesting that MAK-2 activity influences HAM-5 function/localization. However, MAK-2-GFP showed cytoplasmic and nuclear localization in a Dham-5 strain and did not localize to puncta. Via co-immunoprecipitation experiments, HAM-5 was shown to physically interact with NRC-1, MEK-2 and MAK-2, suggesting that it functions as a scaffold/transport hub for the MAP kinase cascade members for oscillation and chemotropic interactions during germling and hyphal fusion in N. crassa. The identification of HAM-5 as a scaffold-like protein will help to link the activation of MAK-2 cascade to upstream factors and proteins involved in this intriguing process of fungal communication. C1 [Jonkers, Wilfried; Leeder, Abigail C.; Glass, N. Louise] Univ Calif Berkeley, Dept Plant & Microbial Biol, Berkeley, CA 94720 USA. [Ansong, Charles; Wang, Yuexi; Yang, Feng; Camp, David G., II; Smith, Richard D.] Pacific NW Natl Lab, Richland, WA 99352 USA. [Starr, Trevor L.; Glass, N. Louise] Univ Calif Berkeley, Energy Biosci Inst, Berkeley, CA 94720 USA. RP Jonkers, W (reprint author), Univ Calif Berkeley, Dept Plant & Microbial Biol, Berkeley, CA 94720 USA. EM Lglass@berkeley.edu RI Smith, Richard/J-3664-2012 OI Smith, Richard/0000-0002-2381-2349 FU National Science Foundation [MCB 1121311]; US DOE office of Biological and Environmental Research; NIH [P41 GM103493-11]; Battelle Memorial Institute for the DOE [DE-AC05-76RLO 1830] FX The work in this study was funded by a National Science Foundation grant to NLG (MCB 1121311). Portions of this work were supported by the US DOE office of Biological and Environmental Research, and also NIH grant P41 GM103493-11 (RDS). Proteomics work was performed in the EMSL, a DOE-BER national scientific user facility PNNL. PNNL is a multi-program national laboratory operated by Battelle Memorial Institute for the DOE under contract DE-AC05-76RLO 1830. The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript. NR 79 TC 18 Z9 18 U1 2 U2 9 PU PUBLIC LIBRARY SCIENCE PI SAN FRANCISCO PA 1160 BATTERY STREET, STE 100, SAN FRANCISCO, CA 94111 USA SN 1553-7390 EI 1553-7404 J9 PLOS GENET JI PLoS Genet. PD NOV PY 2014 VL 10 IS 11 AR e1004783 DI 10.1371/journal.pgen.1004783 PG 16 WC Genetics & Heredity SC Genetics & Heredity GA AU2NL UT WOS:000345455200030 PM 25412208 ER PT J AU Bachmann, B Kritcher, AL Benedetti, LR Falcone, RW Glenn, S Hawreliak, J Izumi, N Kraus, D Landen, OL Le Pape, S Ma, T Perez, F Swift, D Doppner, T AF Bachmann, B. Kritcher, A. L. Benedetti, L. R. Falcone, R. W. Glenn, S. Hawreliak, J. Izumi, N. Kraus, D. Landen, O. L. Le Pape, S. Ma, T. Perez, F. Swift, D. Doeppner, T. TI Using penumbral imaging to measure micrometer size plasma hot spots in Gbar equation of state experiments on the National Ignition Facility SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB We have developed an experimental platform for absolute equation of state measurements up to Gbar pressures on the National Ignition Facility (NIF) within the Fundamental Science Program. We use a symmetry-tuned hohlraum drive to launch a spherical shock wave into a solid CH sphere. Streaked radiography is the primary diagnostic to measure the density change at the shock front as the pressure increases towards smaller radii. At shock stagnation in the center of the capsule, we observe a short and bright x-ray self emission from high density (similar to 50 g/cm(3)) plasma at similar to 1 keV. Here, we present results obtained with penumbral imaging which has been carried out to characterize the size of the hot spot emission. This allows extending existing NIF diagnostic capabilities for spatial resolution (currently similar to 10 mu m) at higher sensitivity. At peak emission we find the hot spot radius to be as small as 5.8 +/-1 mu m, corresponding to a convergence ratio of 200. (C) 2014 AIP Publishing LLC. C1 [Bachmann, B.; Kritcher, A. L.; Benedetti, L. R.; Glenn, S.; Hawreliak, J.; Izumi, N.; Landen, O. L.; Le Pape, S.; Ma, T.; Perez, F.; Swift, D.; Doeppner, T.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Falcone, R. W.; Kraus, D.] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA. [Falcone, R. W.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. RP Bachmann, B (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. EM bachmann2@llnl.gov RI lepape, sebastien/J-3010-2015; IZUMI, Nobuhiko/J-8487-2016 OI IZUMI, Nobuhiko/0000-0003-1114-597X FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; LLNL-LDRD [11-ER-050, 13-ERD-073]; SSAA [DE-FG52-06NA26212] FX This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. The authors acknowledge support from LLNL-LDRD Grant Nos. 11-ER-050 and 13-ERD-073 and SSAA Contract No. DE-FG52-06NA26212. NR 9 TC 7 Z9 7 U1 2 U2 25 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D614 DI 10.1063/1.4891303 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000031 PM 25430190 ER PT J AU Baker, KL Glendinning, SG Guymer, TM Martinez, D Moore, AS Dittrich, TR MacLaren, SA Felker, S Seugling, R Doane, D Wallace, R Whiting, N Sorce, C AF Baker, K. L. Glendinning, S. G. Guymer, T. M. Martinez, D. Moore, A. S. Dittrich, T. R. MacLaren, S. A. Felker, S. Seugling, R. Doane, D. Wallace, R. Whiting, N. Sorce, C. TI Single line-of-sight dual energy backlighter for mix width experiments SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID INSTABILITY EXPERIMENTS; NOVA LASER AB We present a diagnostic technique used to spatially multiplex two x-ray radiographs of an object onto a detector along a single line-of-sight. This technique uses a thin, <2 mu m, cosputtered backlighter target to simultaneously produce both Ni and Zn He-alpha emission. A Ni picket fence filter, 500 mu m wide bars and troughs, is then placed in front of the detector to pass only the Ni He-alpha emission in the bar region and both energies in the trough region thereby spatially multiplexing the two radiographs on a single image. Initial experimental results testing the backlighter spectrum are presented along with simulated images showing the calculated radiographic images though the nickel picket fence filter which are used to measure the mix width in an accelerated nickel foam. (C) 2014 AIP Publishing LLC. C1 [Baker, K. L.; Glendinning, S. G.; Martinez, D.; Dittrich, T. R.; MacLaren, S. A.; Felker, S.; Seugling, R.; Doane, D.; Wallace, R.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. [Guymer, T. M.; Moore, A. S.] AWE, Reading RG7 4PR, Berks, England. [Whiting, N.; Sorce, C.] Univ Rochester, Laser Energet Lab, Rochester, NY 14627 USA. RP Baker, KL (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. EM baker7@llnl.gov FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. We would like to acknowledge the OMEGA operations staff for their help with the experiments that were conducted and General Atomics for making the picket fence filter. NR 9 TC 0 Z9 0 U1 0 U2 5 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D621 DI 10.1063/1.4893005 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000038 PM 25430197 ER PT J AU Barrios, MA Regan, SP Fournier, KB Epstein, R Smith, R Lazicki, A Rygg, R Fratanduono, DE Eggert, J Park, HS Huntington, C Bradley, DK Landen, OL Collins, GW AF Barrios, M. A. Regan, S. P. Fournier, K. B. Epstein, R. Smith, R. Lazicki, A. Rygg, R. Fratanduono, D. E. Eggert, J. Park, H. -S. Huntington, C. Bradley, D. K. Landen, O. L. Collins, G. W. TI X-ray area backlighter development at the National Ignition Facility SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID LASER AB 1D spectral imaging was used to characterize the K-shell emission of Z approximate to 30-35 and Z approximate to 40-42 laser-irradiated foils at the National Ignition Facility. Foils were driven with up to 60 kJ of 3 omega light, reaching laser irradiances on target between 0.5 and 20 x 10(15) W/cm(2). Laser-to-X-ray conversion efficiency (CE) into the He-alpha line (plus satellite emission) of 1.0%-1.5% and 0.15%-0.2% was measured for Z approximate to 30-32 and Z approximate to 40-42, respectively. Measured CE into He-alpha (plus satellite emission) of Br (Z = 35) compound foils (either KBr or RbBr) ranged between 0.16% and 0.29%. Measured spectra are compared with 1D non-local thermodynamic equilibrium atomic kinetic and radiation transport simulations, providing a fast and accurate predictive capability. (C) 2014 AIP Publishing LLC. C1 [Barrios, M. A.; Fournier, K. B.; Smith, R.; Lazicki, A.; Rygg, R.; Fratanduono, D. E.; Eggert, J.; Park, H. -S.; Huntington, C.; Bradley, D. K.; Landen, O. L.; Collins, G. W.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Regan, S. P.; Epstein, R.] Univ Rochester, Laser Energet Lab, Rochester, NY 14623 USA. RP Barrios, MA (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. EM barriosgarci1@llnl.gov FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX The authors would like to thank the members of the NIF operations team for their support and effort for these experiments. This work was done under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. NR 25 TC 3 Z9 3 U1 1 U2 21 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D502 DI 10.1063/1.4891713 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000017 PM 25430176 ER PT J AU Beiersdorfer, P Magee, EW Brown, GV Hell, N Trabert, E Widmann, K AF Beiersdorfer, P. Magee, E. W. Brown, G. V. Hell, N. Traebert, E. Widmann, K. TI Extended-range grazing-incidence spectrometer for high-resolution extreme ultraviolet measurements on an electron beam ion trap SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID SOFT-X-RAY; CHARGED IONS; LINES; REGION; SPECTROSCOPY; EMISSION; SPECTRA; FE AB A high-resolution grazing-incidence grating spectrometer has been implemented on the Livermore electron beam ion traps for performing very high-resolution measurements in the soft x-ray and extreme ultraviolet region spanning from below 10 angstrom to above 300 angstrom. The instrument operates without an entrance slit and focuses the light emitted by highly charged ions located in the roughly 50 mu m wide electron beam onto a cryogenically cooled back-illuminated charge-coupled device detector. The measured line widths are below 0.025 angstrom above 100 angstrom, and the resolving power appears to be limited by the source size and Doppler broadening of the trapped ions. Comparisons with spectra obtained with existing grating spectrometers show an order of magnitude improvement in spectral resolution. (C) 2014 AIP Publishing LLC. C1 [Beiersdorfer, P.; Magee, E. W.; Brown, G. V.; Hell, N.; Traebert, E.; Widmann, K.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Hell, N.] Univ Erlangen Nurnberg, Dr Remeis Sternwarte & ECAP, D-96049 Bamberg, Germany. RP Beiersdorfer, P (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. FU (U.S.) Department of Energy (DOE) by LLNL [DE-AC52-07NA27344]; National Aeronautics and Space Administration's (NASA) APRA Program; Bundesministerium fur Wirtschaft und Technologie under DLR [50 OR 1113] FX This work was performed under the auspices of the (U.S.) Department of Energy (DOE) by LLNL under Contract No. DE-AC52-07NA27344 and supported by National Aeronautics and Space Administration's (NASA) APRA Program. N.H. received support from the Bundesministerium fur Wirtschaft und Technologie under DLR Grant No. 50 OR 1113. NR 28 TC 5 Z9 5 U1 0 U2 7 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E422 DI 10.1063/1.4891875 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000170 PM 25430329 ER PT J AU Bell, RE AF Bell, Ronald E. TI Development and operation of a high-throughput accurate-wavelength lens-based spectrometer SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB A high-throughput spectrometer for the 400-820 nm wavelength range has been developed for charge exchange recombination spectroscopy or general spectroscopy. A large 2160 mm(-1) grating is matched with fast f/1.8 200 mm lenses, which provide stigmatic imaging. A precision optical encoder measures the grating angle with an accuracy <= 0.075 arc sec. A high quantum efficiency low-etaloning CCD detector allows operation at longer wavelengths. A patch panel allows input fibers to interface with interchangeable fiber holders that attach to a kinematic mount at the entrance slit. Computer-controlled hardware allows automated control of wavelength, timing, f-number, automated data collection, and wavelength calibration. (C) 2014 AIP Publishing LLC. C1 Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Bell, RE (reprint author), Princeton Plasma Phys Lab, POB 451, Princeton, NJ 08543 USA. EM rbell@pppl.gov FU U. S. Department of Energy [DE-AC02-09CH11466] FX The author would like to acknowledge the support of B. C. Stratton. This work was supported by the U. S. Department of Energy under Contract No. DE-AC02-09CH11466. NR 6 TC 2 Z9 2 U1 2 U2 6 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E404 DI 10.1063/1.4884612 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000152 PM 25430311 ER PT J AU Biewer, TM Hillis, DL AF Biewer, T. M. Hillis, D. L. TI Preface: Proceedings of the 20th Topical Conference on High-Temperature Plasma Diagnostics, Atlanta, Georgia, USA, 1-5 June 2014 SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Editorial Material C1 [Biewer, T. M.; Hillis, D. L.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. RP Biewer, TM (reprint author), Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. NR 0 TC 0 Z9 0 U1 2 U2 5 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D101 DI 10.1063/1.4890410 PG 1 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000001 PM 25430160 ER PT J AU Biewer, TM Shaw, G AF Biewer, T. M. Shaw, G. TI Initial implementation of a Thomson scattering diagnostic for Proto-MPEX SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID SPECTROMETER; SYSTEM AB Internal funds have been used at Oak Ridge National Laboratory to enable the initial installation of a laser based, Thomson scattering (TS) diagnostic on the prototype Material-Plasma Exposure eXperiment (Proto-MPEX). Since the funds are limited in amount and duration, the initial TS system has followed a low cost design and rapid implementation. This paper will discuss the design elements of the initial TS configuration on Proto-MPEX and issues encountered during installation. Avenues of response to system limitations will be discussed, along with considerations for further optimization. The laser system will undergo reconfiguration to enable additional project milestones, e.g., laser induced break-down spectroscopy. (C) 2014 AIP Publishing LLC. C1 [Biewer, T. M.; Shaw, G.] Oak Ridge Natl Lab, Oak Ridge, TN 37830 USA. [Shaw, G.] Univ Tennessee, Bredesen Ctr, Knoxville, TN 37996 USA. RP Biewer, TM (reprint author), Oak Ridge Natl Lab, Oak Ridge, TN 37830 USA. EM biewertm@ornl.gov OI Biewer, Theodore/0000-0001-7456-3509 FU U.S. D.O.E [DE-AC05-00OR22725]; Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, U.S. Department of Energy FX This work was supported by the U.S. D.O.E Contract No. DE-AC05-00OR22725. Research sponsored by the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. Department of Energy. NR 11 TC 2 Z9 2 U1 2 U2 13 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D812 DI 10.1063/1.4886959 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000066 PM 25430225 ER PT J AU Bitter, M Hill, KW Efthimion, PC Delgado-Aparicio, L Pablant, N Lu, J Beiersdorfer, P Chen, H AF Bitter, M. Hill, K. W. Efthimion, P. C. Delgado-Aparicio, L. Pablant, N. Lu, Jian Beiersdorfer, P. Chen, Hui TI A new spectrometer design for the x-ray spectroscopy of laser-produced plasmas with high (sub-ns) time resolution SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB This paper describes a new type of x-ray crystal spectrometer, which can be used in combination with gated x-ray detectors to obtain spectra from laser-produced plasmas with a high (sub-ns) time resolution. The spectrometer consists of a convex, spherically bent crystal, which images individual spectral lines as perfectly straight lines across multiple, sequentially gated, strip detectors. Since the Bragg-reflected rays are divergent, the distance between detector and crystal is arbitrary, so that this distance can be appropriately chosen to optimize the experimental arrangement with respect to the detector parameters. The spectrometer concept was verified in proof-of-principle experiments by imaging the L beta(1)-and L beta(2)-lines of tungsten, at 9.6735 and 9.96150 keV, from a micro-focus x-ray tube with a tungsten target onto a two-dimensional pixilated Pilatus detector, using a convex, spherically bent Si-422 crystal with a radius of curvature of 500 mm. (C) 2014 AIP Publishing LLC. C1 [Bitter, M.; Hill, K. W.; Efthimion, P. C.; Delgado-Aparicio, L.; Pablant, N.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Lu, Jian] Chongqing Univ, Dept Engn, Chongqing 400044, Peoples R China. [Beiersdorfer, P.; Chen, Hui] Lawrence Livermore Natl Lab, Div Phys, Livermore, CA 94550 USA. RP Bitter, M (reprint author), Princeton Plasma Phys Lab, POB 451, Princeton, NJ 08543 USA. EM bitter@pppl.gov FU U.S. Department of Energy [DE-AC02-09CH-11466, DE-AC52-07NA-27344] FX This work was supported by the U.S. Department of Energy through Contract Nos. DE-AC02-09CH-11466 and DE-AC52-07NA-27344. NR 15 TC 0 Z9 0 U1 0 U2 10 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D627 DI 10.1063/1.4894390 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000044 PM 25430203 ER PT J AU Bonura, MA Ruiz, CL Fehl, DL Cooper, GW Chandler, G Hahn, KD Nelson, AJ Styron, JD Torres, JA AF Bonura, M. A. Ruiz, C. L. Fehl, D. L. Cooper, G. W. Chandler, G. Hahn, K. D. Nelson, A. J. Styron, J. D. Torres, J. A. TI A technique for verifying the input response function of neutron time-of-flight scintillation detectors using cosmic rays SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB An accurate interpretation of DD or DT fusion neutron time-of-flight (nTOF) signals from current mode detectors employed at the Z-facility at Sandia National Laboratories requires that the instrument response functions (IRF's) be deconvolved from the measured nTOF signals. A calibration facility that produces detectable sub-ns radiation pulses is typically used to measure the IRF of such detectors. This work, however, reports on a simple method that utilizes cosmic radiation to measure the IRF of nTOF detectors, operated in pulse-counting mode. The characterizing metrics reported here are the throughput delay and full-width-at-half-maximum. This simple approach yields consistent IRF results with the same detectors calibrated in 2007 at a LINAC bremsstrahlung accelerator (Idaho State University). In particular, the IRF metrics from these two approaches and their dependence on the photomultipliers bias agree to within a few per cent. This information may thus be used to verify if the IRF for a given nTOF detector employed at Z has changed since its original current-mode calibration and warrants re-measurement. (C) 2014 AIP Publishing LLC. C1 [Bonura, M. A.; Cooper, G. W.; Nelson, A. J.; Styron, J. D.] Univ New Mexico, Dept Chem & Nucl Engn, Albuquerque, NM 87131 USA. [Ruiz, C. L.; Fehl, D. L.; Chandler, G.; Hahn, K. D.; Torres, J. A.] Sandia Natl Labs, Albuquerque, NM 87111 USA. RP Ruiz, CL (reprint author), Sandia Natl Labs, Albuquerque, NM 87111 USA. EM clruiz@sandia.gov FU U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX Sandia National Laboratories is a multi-program laboratory operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin company, for the U.S. Department of Energy's National Nuclear Security Administration under Contract No. DE-AC04-94AL85000. NR 5 TC 0 Z9 0 U1 0 U2 4 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D633 DI 10.1063/1.4896958 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000050 PM 25430209 ER PT J AU Chen, H Bitter, M Hill, KW Kerr, S Magee, E Nagel, SR Park, J Schneider, MB Stone, G Williams, GJ Beiersdorfer, P AF Chen, Hui Bitter, M. Hill, K. W. Kerr, S. Magee, E. Nagel, S. R. Park, J. Schneider, M. B. Stone, G. Williams, G. J. Beiersdorfer, P. TI A high-resolution imaging x-ray crystal spectrometer for high energy density plasmas SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Adapting a concept developed for magnetic confinement fusion experiments, an imaging crystal spectrometer has been designed and tested for HED plasmas. The instrument uses a spherically bent quartz [211] crystal with radius of curvature of 490.8 mm. The instrument was tested at the Titan laser at Lawrence Livermore National Laboratory by irradiating titanium slabs with laser intensities of 10(19)-10(20) W/cm(2). He-like and Li-like Ti lines were recorded, from which the spectrometer performance was evaluated. This spectrometer provides very high spectral resolving power (E/dE > 7000) while acquiring a one-dimensional image of the source. (C) 2014 AIP Publishing LLC. C1 [Chen, Hui; Magee, E.; Nagel, S. R.; Park, J.; Schneider, M. B.; Stone, G.; Williams, G. J.; Beiersdorfer, P.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Bitter, M.; Hill, K. W.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Kerr, S.] Univ Alberta, Dept Appl Sci, Edmonton, AB T6G 2R3, Canada. RP Chen, H (reprint author), Lawrence Livermore Natl Lab, 7000 East Ave, Livermore, CA 94550 USA. EM chen33@llnl.gov; bitter@pppl.gov OI Kerr, Shaun/0000-0003-4822-564X FU U.S. DOE by LLNL [DE-AC52-07NA27344]; PPPL under DOE [DE-AC02-09CH11466] FX This work was performed under the auspices of the U.S. DOE by LLNL under Contract No. DE-AC52-07NA27344 and was supported at PPPL under DOE Contract No. DE-AC02-09CH11466. NR 16 TC 3 Z9 3 U1 0 U2 6 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E606 DI 10.1063/1.4891053 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000193 PM 25430352 ER PT J AU Chen, X Heidbrink, WW Van Zeeland, MA Kramer, GJ Pace, DC Petty, CC Austin, ME Fisher, RK Hanson, JM Nazikian, R Zeng, L AF Chen, Xi Heidbrink, W. W. Van Zeeland, M. A. Kramer, G. J. Pace, D. C. Petty, C. C. Austin, M. E. Fisher, R. K. Hanson, J. M. Nazikian, R. Zeng, L. TI Using neutral beams as a light ion beam probe (invited) SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID SCINTILLATOR PROBE AB By arranging the particle first banana orbits to pass near a distant detector, the light ion beam probe (LIBP) utilizes orbital deflection to probe internal fields and field fluctuations. The LIBP technique takes advantage of (1) the in situ, known source of fast ions created by beam-injected neutral particles that naturally ionize near the plasma edge and (2) various commonly available diagnostics as its detector. These born trapped particles can traverse the plasma core on their inner banana leg before returning to the plasma edge. Orbital displacements (the forces on fast ions) caused by internal instabilities or edge perturbing fields appear as modulated signal at an edge detector. Adjustments in the q-profile and plasma shape that determine the first orbit, as well as the relative position of the source and detector, enable studies under a wide variety of plasma conditions. This diagnostic technique can be used to probe the impact on fast ions of various instabilities, e.g., Alfven eigenmodes (AEs) and neoclassical tearing modes, and of externally imposed 3D fields, e.g., magnetic perturbations. To date, displacements by AEs and by externally applied resonant magnetic perturbation fields have been measured using a fast ion loss detector. Comparisons with simulations are shown. In addition, nonlinear interactions between fast ions and independent AE waves are revealed by this technique. (C) 2014 AIP Publishing LLC. C1 [Chen, Xi] Oak Ridge Inst Sci & Educ, Oak Ridge, TN 37831 USA. [Heidbrink, W. W.] Univ Calif Irvine, Irvine, CA 92697 USA. [Van Zeeland, M. A.; Pace, D. C.; Petty, C. C.; Fisher, R. K.] Gen Atom Co, San Diego, CA 92186 USA. [Kramer, G. J.; Nazikian, R.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Austin, M. E.] Univ Texas Austin, Austin, TX 78712 USA. [Hanson, J. M.] Columbia Univ, New York, NY 10027 USA. [Zeng, L.] Univ Calif Los Angeles, Los Angeles, CA 90095 USA. RP Chen, X (reprint author), Oak Ridge Inst Sci & Educ, Oak Ridge, TN 37831 USA. EM chenxi@fusion.gat.com FU US Department of Energy (DOE) [DE-AC05-06ER23100, SC-G903402, DE-FC02-04ER54698, DE-AC02-09CH11466m DE-FG03-97ER54415, DE-FG02-04ER54761, DE-FG02-08ER54984] FX This work was supported by the US Department of Energy (DOE) under DE-AC05-06ER23100, SC-G903402, DE-FC02-04ER54698, DE-AC02-09CH11466m DE-FG03-97ER54415, DE-FG02-04ER54761, and DE-FG02-08ER54984. The authors are grateful to the DIII-D team for their support and particularly thank N.G. Bolte, C. J. Lasnier, B. A. Grierson, and R. Cardenas. DIII-D data shown in this paper can be obtained in digital format by following the links at https://fusion.gat.com/global/D3D_DMP. NR 26 TC 3 Z9 3 U1 1 U2 5 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E701 DI 10.1063/1.4889733 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000205 PM 25430364 ER PT J AU Chrystal, C Burrell, KH Grierson, BA Lao, LL Pace, DC AF Chrystal, C. Burrell, K. H. Grierson, B. A. Lao, L. L. Pace, D. C. TI A method for determining poloidal rotation from poloidal asymmetry in toroidal rotation (invited) SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID RADIAL ELECTRIC-FIELD; TOKAMAK PLASMA; DIII-D; TRANSPORT; SPECTROSCOPY; TURBULENCE; VELOCITY AB A new diagnostic has been developed on DIII-D that determines the impurity poloidal rotation from the poloidal asymmetry in the toroidal angular rotation velocity. This asymmetry is measured with recently added tangential charge exchange viewchords on the high-field side of the tokamak midplane. Measurements are made on co- and counter-current neutral beams, allowing the charge exchange cross section effect to be measured and eliminating the need for atomic physics calculations. The diagnostic implementation on DIII-D restricts the measurement range to the core (r/a < 0.6) where, relative to measurements made with the vertical charge exchange system, the spatial resolution is improved. Significant physics results have been obtained with this new diagnostic; for example, poloidal rotation measurements that significantly exceed neoclassical predictions. (C) 2014 AIP Publishing LLC. C1 [Chrystal, C.] Univ Calif San Diego, Dept Phys, La Jolla, CA 92093 USA. [Burrell, K. H.; Lao, L. L.; Pace, D. C.] Gen Atom Co, San Diego, CA 92186 USA. [Grierson, B. A.] Princeton Univ, Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Chrystal, C (reprint author), Univ Calif San Diego, Dept Phys, 9500 Gilman Dr, La Jolla, CA 92093 USA. EM chrystal@fusion.gat.com FU US Department of Energy [DE-FG02-07ER54917, DE-FC02-04ER54698, DE-AC02-09H11466] FX This work was supported by the US Department of Energy under DE-FG02-07ER54917, DE-FC02-04ER54698, and DE-AC02-09H11466. DIII-D data shown in this paper can be obtained in digital format by following the links at https://fusion.gat.com/global/D3D_DMP. NR 29 TC 2 Z9 2 U1 0 U2 7 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E302 DI 10.1063/1.4891601 PG 7 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000148 PM 25430307 ER PT J AU Classen, IGJ Domier, CW Luhmann, NC Bogomolov, AV Suttrop, W Boom, JE Tobias, BJ Donne, AJH AF Classen, I. G. J. Domier, C. W. Luhmann, N. C., Jr. Bogomolov, A. V. Suttrop, W. Boom, J. E. Tobias, B. J. Donne, A. J. H. CA ASDEX Upgrade Team TI Dual array 3D electron cyclotron emission imaging at ASDEX Upgrade SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB In a major upgrade, the (2D) electron cyclotron emission imaging diagnostic (ECEI) at ASDEX Upgrade has been equipped with a second detector array, observing a different toroidal position in the plasma, to enable quasi-3D measurements of the electron temperature. The new system will measure a total of 288 channels, in two 2D arrays, toroidally separated by 40 cm. The two detector arrays observe the plasma through the same vacuum window, both under a slight toroidal angle. The majority of the field lines are observed by both arrays simultaneously, thereby enabling a direct measurement of the 3D properties of plasma instabilities like edge localized mode filaments. (C) 2014 AIP Publishing LLC. C1 [Classen, I. G. J.; Bogomolov, A. V.; Donne, A. J. H.] Dutch Inst Fundamental Energy Res, FOM Inst DIFFER, NL-3430 BE Nieuwegein, Netherlands. [Domier, C. W.; Luhmann, N. C., Jr.] Univ Calif Davis, Dept Appl Sci, Davis, CA 95616 USA. [Suttrop, W.; Boom, J. E.; ASDEX Upgrade Team] Max Planck Inst Plasma Phys, D-85748 Garching, Germany. [Tobias, B. J.] Princeton Plasma Phys Lab, Princeton, NJ 08540 USA. [Donne, A. J. H.] Eindhoven Univ Technol, Dept Appl Phys, NL-5600 MB Eindhoven, Netherlands. RP Classen, IGJ (reprint author), Dutch Inst Fundamental Energy Res, FOM Inst DIFFER, NL-3430 BE Nieuwegein, Netherlands. EM I.G.J.Classen@differ.nl FU European Union [633053]; U.S. DOE [DE-AC02-09CH11466] FX This project has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement number 633053. The views and opinions expressed herein do not necessarily reflect those of the European Commission. UC Davis work is supported by U.S. DOE Grant No. DE-AC02-09CH11466. NR 17 TC 1 Z9 1 U1 1 U2 11 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D833 DI 10.1063/1.4891061 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000087 PM 25430246 ER PT J AU Danly, CR Sjue, S Wilde, CH Merrill, FE Haight, RC AF Danly, C. R. Sjue, S. Wilde, C. H. Merrill, F. E. Haight, R. C. TI Plastic fiber scintillator response to fast neutrons SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB The Neutron Imaging System at NIF uses an array of plastic scintillator fibers in conjunction with a time-gated imaging system to form an image of the neutron emission from the imploded capsule. By gating on neutrons that have scattered from the 14.1 MeV DT energy to lower energy ranges, an image of the dense, cold fuel around the hotspot is also obtained. An unmoderated spallation neutron beamline at the Weapons Neutron Research facility at Los Alamos was used in conjunction with a time-gated imaging system to measure the yield of a scintillating fiber array over several energy bands ranging from 1 to 15 MeV. The results and comparison to simulation are presented. (C) 2014 AIP Publishing LLC. C1 [Danly, C. R.; Sjue, S.; Wilde, C. H.; Merrill, F. E.; Haight, R. C.] Los Alamos Natl Lab, Los Alamos, NM 87544 USA. RP Danly, CR (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87544 USA. OI Merrill, Frank/0000-0003-0603-735X NR 5 TC 0 Z9 0 U1 1 U2 12 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E607 DI 10.1063/1.4891160 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000194 PM 25430353 ER PT J AU Delgado-Aparicio, L Bell, RE Faust, I Tritz, K Diallo, A Gerhardt, SP Kozub, TA LeBlanc, BP Stratton, BC AF Delgado-Aparicio, L. Bell, R. E. Faust, I. Tritz, K. Diallo, A. Gerhardt, S. P. Kozub, T. A. LeBlanc, B. P. Stratton, B. C. TI High-resolution tangential absolute extreme ultraviolet arrays for radiated power density measurements on NSTX-U SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID PLASMAS AB The radiated-power-density diagnostic on the equatorial midplane for the NSTX-U tokamak will be upgraded to measure the radial structure of the photon emissivity profile with an improved radial resolution. This diagnostic will enhance the characterization and studies of power balance, impurity transport, and MHD. The layout and response expected of the new system is shown for different plasma conditions and impurity concentrations. The effect of toroidal rotation driving poloidal asymmetries in the core radiation from high-Z impurities is also addressed. (C) 2014 AIP Publishing LLC. C1 [Delgado-Aparicio, L.; Bell, R. E.; Diallo, A.; Gerhardt, S. P.; Kozub, T. A.; LeBlanc, B. P.; Stratton, B. C.] Princeton Plasma Phys Lab, Princeton, NJ 08540 USA. [Faust, I.] MIT, Plasma Sci & Fus Ctr, Cambridge, MA 02139 USA. [Tritz, K.] Johns Hopkins Univ, Baltimore, MD 21209 USA. RP Delgado-Aparicio, L (reprint author), Princeton Plasma Phys Lab, Princeton, NJ 08540 USA. FU US DOE at MIT [DE-FC02-99ER54512]; US DOE at PPPL [DE-AC02-09CH11466] FX This novel approach will be tested first using the NSTX database and will implemented later for NSTX-U radiated power density measurements. This work was performed under US DOE Contract Nos. DE-FC02-99ER54512 at MIT and DE-AC02-09CH11466 at PPPL. NR 11 TC 0 Z9 0 U1 2 U2 9 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D859 DI 10.1063/1.4894835 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000113 PM 25430272 ER PT J AU Deng, ZD Lu, J Myjak, MJ Martinez, JJ Tian, C Morris, SJ Carlson, TJ Zhou, D Hou, H AF Deng, Z. D. Lu, J. Myjak, M. J. Martinez, J. J. Tian, C. Morris, S. J. Carlson, T. J. Zhou, D. Hou, H. TI Design and implementation of a new autonomous sensor fish to support advanced hydropower development SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID PASSAGE SURVIVAL; JUVENILE SALMON; BAROTRAUMA; TURBINES; FLOW AB Acceleration in development of additional conventional hydropower requires tools and methods to perform laboratory and in-field validation of turbine performance and fish passage claims. The new-generation Sensor Fish has been developed with more capabilities to accommodate a wider range of users over a broader range of turbine designs and operating environments. It provides in situ measurements of three-dimensional (3D) linear accelerations, 3D rotational velocities, 3D orientation, pressure, and temperature at a sampling frequency of 2048 Hz. It also has an automatic floatation system and built-in radio-frequency transmitter for recovery. The relative errors of the pressure, acceleration, and rotational velocity were within +/- 2%, +/- 5%, and +/- 5%, respectively. The accuracy of orientation was within +/- 4 degrees and accuracy of temperature was +/- 2 degrees C. The new-generation Sensor Fish is becoming a major technology and being deployed for evaluating the conditions for fish passage of turbines or other hydraulic structures in both the United States and several other countries. (c) 2014 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License. C1 [Deng, Z. D.; Lu, J.; Myjak, M. J.; Martinez, J. J.; Tian, C.; Morris, S. J.; Carlson, T. J.; Zhou, D.; Hou, H.] Pacific NW Natl Lab, Richland, WA 99332 USA. RP Deng, ZD (reprint author), Pacific NW Natl Lab, POB 999, Richland, WA 99332 USA. RI Deng, Daniel/A-9536-2011; OI Deng, Daniel/0000-0002-8300-8766; Myjak, Mitchell/0000-0002-3807-3542 FU U.S. Department of Energy Wind and Water Power Technologies Office; Electric Power Research Institute FX The study was funded by the U.S. Department of Energy Wind and Water Power Technologies Office and The Electric Power Research Institute. The authors also would like to thank the U.S. Army Corps of Engineers for their support of the field deployment. The study was conducted at Pacific Northwest National Laboratory, operated by Battelle for the U.S. Department of Energy. NR 16 TC 5 Z9 5 U1 2 U2 12 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 115001 DI 10.1063/1.4900543 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000287 PM 25430138 ER PT J AU Doppner, T Kritcher, AL Neumayer, P Kraus, D Bachmann, B Burns, S Falcone, RW Glenzer, SH Hawreliak, J House, A Landen, OL LePape, S Ma, T Pak, A Swift, D AF Doeppner, T. Kritcher, A. L. Neumayer, P. Kraus, D. Bachmann, B. Burns, S. Falcone, R. W. Glenzer, S. H. Hawreliak, J. House, A. Landen, O. L. LePape, S. Ma, T. Pak, A. Swift, D. TI Qualification of a high-efficiency, gated spectrometer for x-ray Thomson scattering on the National Ignition Facility SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID CRYSTALS AB We have designed, built, and successfully fielded a highly efficient and gated Bragg crystal spectrometer for x-ray Thomson scattering measurements on the National Ignition Facility (NIF). It utilizes a cylindrically curved Highly Oriented Pyrolytic Graphite crystal. Its spectral range of 7.4-10 keV is optimized for scattering experiments using a Zn He-alpha x-ray probe at 9.0 keV or Mo K-shell line emission around 18 keV in second diffraction order. The spectrometer has been designed as a diagnostic instrument manipulator-based instrument for the NIF target chamber at the Lawrence Livermore National Laboratory, USA. Here, we report on details of the spectrometer snout, its novel debris shield configuration and an in situ spectral calibration experiment with a Brass foil target, which demonstrated a spectral resolution of E/Delta E = 220 at 9.8 keV. (C) 2014 AIP Publishing LLC. C1 [Doeppner, T.; Kritcher, A. L.; Bachmann, B.; Burns, S.; Hawreliak, J.; House, A.; Landen, O. L.; LePape, S.; Ma, T.; Pak, A.; Swift, D.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Neumayer, P.] Gesell Schwerionenphys, D-64291 Darmstadt, Germany. [Kraus, D.; Falcone, R. W.] Univ Calif Berkeley, Berkeley, CA 94720 USA. [Falcone, R. W.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. [Glenzer, S. H.] SLAC Natl Accelerator Lab, Menlo Pk, CA 94309 USA. RP Doppner, T (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. RI lepape, sebastien/J-3010-2015 FU (U.S.) Department of Energy (DOE) by the Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; Laboratory Directed Research and Development Grant [13-ERD-073] FX We acknowledge support from Dan Kalantar, Tom McCarvillle, and Reg Wood who worked out critically important alignment procedures. We also thank Ulf Zastrau and Vladimir Arkadiev for helpful discussions on graphite coatings, and Sean Felker for technical support building the Brass foil target. This work was performed under the auspices of the (U.S.) Department of Energy (DOE) by the Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. The authors acknowledge support from Laboratory Directed Research and Development Grant No. 13-ERD-073. NR 15 TC 8 Z9 8 U1 2 U2 24 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D617 DI 10.1063/1.4890253 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000034 PM 25430193 ER PT J AU Fan, D Lu, L Li, B Qi, ML E, JC Zhao, F Sun, T Fezzaa, K Chen, W Luo, SN AF Fan, D. Lu, L. Li, B. Qi, M. L. E, J. C. Zhao, F. Sun, T. Fezzaa, K. Chen, W. Luo, S. N. TI Transient x-ray diffraction with simultaneous imaging under high strain-rate loading SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID HOPKINSON PRESSURE BAR; AZ31 MAGNESIUM ALLOY; DEFORMATION; FRACTURE; COMPRESSION AB Real time, in situ, multiframe, diffraction, and imaging measurements on bulk samples under high and ultrahigh strain-rate loading are highly desirable for micro-and mesoscale sciences. We present an experimental demonstration of multiframe transient x-ray diffraction (TXD) along with simultaneous imaging under high strain-rate loading at the Advanced Photon Source beamline 32ID. The feasibility study utilizes high strain-rate Hopkinson bar loading on a Mg alloy. The exposure time in TXD is 2-3 mu s, and the frame interval is 26.7-62.5 mu s. Various dynamic deformation mechanisms are revealed by TXD, including lattice expansion or compression, crystal plasticity, grain or lattice rotation, and likely grain refinement, as well as considerable anisotropy in deformation. Dynamic strain fields are mapped via x-ray digital image correlation, and are consistent with the diffraction measurements and loading histories. (C) 2014 AIP Publishing LLC. C1 [Fan, D.; Lu, L.; Li, B.; E, J. C.; Zhao, F.; Luo, S. N.] Peac Inst Multiscale Sci, Chengdu 610207, Sichuan, Peoples R China. [Lu, L.; Li, B.] Univ Sci & Technol China, Dept Modern Mech, Hefei 230027, Anhui, Peoples R China. [Qi, M. L.] Wuhan Univ Technol, Sch Sci, Wuhan 430070, Hubei, Peoples R China. [Sun, T.; Fezzaa, K.] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA. [Chen, W.] Purdue Univ, Sch Aeronaut & Astronaut, W Lafayette, IN 47907 USA. [Chen, W.] Purdue Univ, Sch Mat Sci Engn, W Lafayette, IN 47907 USA. RP Fan, D (reprint author), Peac Inst Multiscale Sci, Chengdu 610207, Sichuan, Peoples R China. EM sluo@pims.ac.cn RI Luo, Sheng-Nian /D-2257-2010; E, Juncheng/O-1588-2015; OI Luo, Sheng-Nian /0000-0002-7538-0541; E, Juncheng/0000-0001-6061-5734; Li, Bo/0000-0002-0389-7357 FU U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]; National Natural Science Foundation of China; NSAF [11472253, 11172221, U1330111] FX We would like to thank M. Hudspeth, N. Parab, Z. Guo, A. Deriy, and J. Wang for their various help. Use of the Advanced Photon Source and the Center for Nanoscale Materials were supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. This work was supported in part by the National Natural Science Foundation of China and NSAF (Nos. 11472253, 11172221, and U1330111). NR 22 TC 11 Z9 11 U1 7 U2 23 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 113902 DI 10.1063/1.4900861 PG 5 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000268 PM 25430119 ER PT J AU Faust, I Delgado-Aparicio, L Bell, RE Tritz, K Diallo, A Gerhardt, SP LeBlanc, B Kozub, TA Parker, RR Stratton, BC AF Faust, I. Delgado-Aparicio, L. Bell, R. E. Tritz, K. Diallo, A. Gerhardt, S. P. LeBlanc, B. Kozub, T. A. Parker, R. R. Stratton, B. C. TI Two-dimensional AXUV-based radiated power density diagnostics on NSTX-U SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID X-RAY TOMOGRAPHY; ALCATOR C-MOD; TOKAMAKS AB A new set of radiated-power-density diagnostics for the National Spherical Torus Experiment Upgrade (NSTX-U) tokamak have been designed to measure the two-dimensional poloidal structure of the total photon emissivity profile in order to perform power balance, impurity transport, and magnetohydrodynamic studies. Multiple AXUV-diode based pinhole cameras will be installed in the same toroidal angle at various poloidal locations. The local emissivity will be obtained from several types of tomographic reconstructions. The layout and response expected for the new radially viewing poloidal arrays will be shown for different impurity concentrations to characterize the diagnostic sensitivity. The radiated power profile inverted from the array data will also be used for estimates of power losses during transitions from various divertor configurations in NSTX-U. The effect of in-out and top/bottom asymmetries in the core radiation from high-Z impurities will be addressed. (C) 2014 AIP Publishing LLC. C1 [Faust, I.; Parker, R. R.; Stratton, B. C.] MIT, Plasma Sci & Fus Ctr, Cambridge, MA 02139 USA. [Delgado-Aparicio, L.; Bell, R. E.; Diallo, A.; Gerhardt, S. P.; LeBlanc, B.; Kozub, T. A.; Stratton, B. C.] Princeton Plasma Phys Lab, Princeton, NJ 08540 USA. [Tritz, K.] Johns Hopkins Univ, Baltimore, MD 21209 USA. RP Faust, I (reprint author), MIT, Plasma Sci & Fus Ctr, Cambridge, MA 02139 USA. FU (U.S.) Department of Energy (DOE) at MIT [DE-FC02-99ER54512]; (U.S.) Department of Energy (DOE) at PPPL [DE-AC02-09CH11466] FX This work was performed under (U.S.) Department of Energy (DOE) Contract Nos. DE-FC02-99ER54512 at MIT and DE-AC02-09CH11466 at PPPL. NR 9 TC 1 Z9 1 U1 3 U2 6 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D856 DI 10.1063/1.4890254 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000110 PM 25430269 ER PT J AU Field, JE Rygg, JR Barrios, MA Benedetti, LR Doppner, T Izumi, N Jones, O Khan, SF Ma, T Nagel, SR Pak, A Tommasini, R Bradley, DK Town, RPJ AF Field, J. E. Rygg, J. R. Barrios, M. A. Benedetti, L. R. Doeppner, T. Izumi, N. Jones, O. Khan, S. F. Ma, T. Nagel, S. R. Pak, A. Tommasini, R. Bradley, D. K. Town, R. P. J. TI Reconstruction of 2D x-ray radiographs at the National Ignition Facility using pinhole tomography SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Two-dimensional radiographs of imploding fusion capsules are obtained at the National Ignition Facility by projection through a pinhole array onto a time-gated framing camera. Parallax among images in the image array makes it possible to distinguish contributions from the capsule and from the backlighter, permitting correction of backlighter non-uniformities within the capsule radiograph. Furthermore, precise determination of the imaging system geometry and implosion velocity enables combination of multiple images to reduce signal-to-noise and discover new capsule features. (C) 2014 AIP Publishing LLC. C1 [Field, J. E.; Rygg, J. R.; Barrios, M. A.; Benedetti, L. R.; Doeppner, T.; Izumi, N.; Jones, O.; Khan, S. F.; Ma, T.; Nagel, S. R.; Pak, A.; Tommasini, R.; Bradley, D. K.; Town, R. P. J.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. RP Field, JE (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. EM field9@llnl.gov RI IZUMI, Nobuhiko/J-8487-2016; Tommasini, Riccardo/A-8214-2009 OI IZUMI, Nobuhiko/0000-0003-1114-597X; Tommasini, Riccardo/0000-0002-1070-3565 FU (U.S.) Department of Energy (DOE) by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX The authors thank the engineering, target fabrication, and operations teams at the National Ignition Facility who made these experiments possible. This work was performed under the auspices of the (U.S.) Department of Energy (DOE) by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. NR 9 TC 6 Z9 6 U1 0 U2 14 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E503 DI 10.1063/1.4890395 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000186 PM 25430345 ER PT J AU Fimognari, PJ Demers, DR Chen, X Schoch, PM AF Fimognari, P. J. Demers, D. R. Chen, X. Schoch, P. M. TI Resolving small signal measurements in experimental plasma environments using calibrated subtraction of noise signals SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID REDUCTION; MST AB The performance of many diagnostic and control systems within fusion and other fields of research are often detrimentally affected by spurious noise signals. This is particularly true for those (such as radiation or particle detectors) working with very small signals. Common sources of radiated and conducted noise in experimental fusion environments include the plasma itself and instrumentation. The noise complicates data analysis, as illustrated by noise on signals measured with the heavy ion beam probe (HIBP) installed on the Madison Symmetric Torus. The noise is time-varying and often exceeds the secondary ion beam current (in contrast with previous applications). Analysis of the noise identifies the dominant source as photoelectric emission from the detectors induced by ultraviolet light from the plasma. This has led to the development of a calibrated subtraction technique, which largely removes the undesired temporal noise signals from data. The advantages of the technique for small signal measurement applications are demonstrated through improvements realized on HIBP fluctuation measurements. (C) 2014 AIP Publishing LLC. C1 [Fimognari, P. J.; Demers, D. R.] Xantho Technol LLC, Madison, WI 53705 USA. [Chen, X.] Oak Ridge Inst Sci & Educ, Oak Ridge, TN 37830 USA. [Schoch, P. M.] Rensselaer Polytech Inst, Troy, NY 12180 USA. RP Fimognari, PJ (reprint author), Xantho Technol LLC, Madison, WI 53705 USA. EM PJFimognari@XanthoTechnologies.com FU U.S. DOE [DE-SC0006077] FX This work is supported by U.S. DOE Award No. DE-SC0006077. NR 16 TC 3 Z9 3 U1 1 U2 4 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D849 DI 10.1063/1.4891976 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000103 PM 25430262 ER PT J AU Fletcher, LB Lee, HJ Barbrel, B Gauthier, M Galtier, E Nagler, B Doppner, T LePape, S Ma, T Pak, A Turnbull, D White, T Gregori, G Wei, M Falcone, RW Heimann, P Zastrau, U Hastings, JB Glenzer, SH AF Fletcher, L. B. Lee, H. J. Barbrel, B. Gauthier, M. Galtier, E. Nagler, B. Doeppner, T. LePape, S. Ma, T. Pak, A. Turnbull, D. White, T. Gregori, G. Wei, M. Falcone, R. W. Heimann, P. Zastrau, U. Hastings, J. B. Glenzer, S. H. TI Exploring Mbar shock conditions and isochorically heated aluminum at the Matter in Extreme Conditions end station of the Linac Coherent Light Source (invited) SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID RAY THOMSON SCATTERING; FREE-ELECTRON LASER; PHASE-TRANSITION; PLASMAS AB Recent experiments performed at the Matter in Extreme Conditions end station of the Linac Coherent Light Source (LCLS) have demonstrated the first spectrally resolved measurements of plasmons from isochorically heated aluminum. The experiments have been performed using a seeded 8-keV x-ray laser beam as a pump and probe to both volumetrically heat and scatter x-rays from aluminum. Collective x-ray Thomson scattering spectra show a well-resolved plasmon feature that is down-shifted in energy by 19 eV. In addition, Mbar shock pressures from laser-compressed aluminum foils using velocity interferometer system for any reflector have been measured. The combination of experiments fully demonstrates the possibility to perform warm dense matter studies at the LCLS with unprecedented accuracy and precision. (C) 2014 AIP Publishing LLC. C1 [Fletcher, L. B.; Lee, H. J.; Gauthier, M.; Galtier, E.; Nagler, B.; Heimann, P.; Zastrau, U.; Hastings, J. B.; Glenzer, S. H.] SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA. [Fletcher, L. B.; Barbrel, B.; Falcone, R. W.] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94709 USA. [Doeppner, T.; LePape, S.; Ma, T.; Pak, A.; Turnbull, D.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. [White, T.; Gregori, G.] Univ Oxford, Dept Phys, Oxford OX1 3PU, England. [Wei, M.] Gen Atom, San Diego, CA USA. [Zastrau, U.] Univ Jena, Inst Opt & Quantum Elect, D-07743 Jena, Germany. RP Fletcher, LB (reprint author), SLAC Natl Accelerator Lab, 2575 Sand Hill Rd, Menlo Pk, CA 94025 USA. RI gauthier, Maxence/K-2578-2014; lepape, sebastien/J-3010-2015 OI gauthier, Maxence/0000-0001-6608-9325; FU DOE Office of Science, Fusion Energy Science [SF00515]; DOE Office of Basic Energy Sciences, Materials Sciences and Engineering Division [DE-AC02-76SF00515]; VolkswagenStiftung FX This work was performed at the Matter at Extreme Conditions (MEC) instrument of LCLS, supported by the DOE Office of Science, Fusion Energy Science under Contract No. SF00515. This work was partially supported by DOE Office of Basic Energy Sciences, Materials Sciences and Engineering Division, under Contract No. DE-AC02-76SF00515. U.Z. is grateful to the VolkswagenStiftung for his Peter-Paul-Ewald Fellowship. NR 31 TC 1 Z9 1 U1 0 U2 16 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR UNSP 11E702 DI 10.1063/1.4891186 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000206 PM 25430365 ER PT J AU Gauthier, M Fletcher, LB Ravasio, A Galtier, E Gamboa, EJ Granados, E Hastings, JB Heimann, P Lee, HJ Nagler, B Schropp, A Gleason, A Doppner, T LePape, S Ma, T Pak, A MacDonald, MJ Ali, S Barbrel, B Falcone, R Kraus, D Chen, Z Mo, M Wei, M Glenzer, SH AF Gauthier, M. Fletcher, L. B. Ravasio, A. Galtier, E. Gamboa, E. J. Granados, E. Hastings, J. B. Heimann, P. Lee, H. J. Nagler, B. Schropp, A. Gleason, A. Doeppner, T. LePape, S. Ma, T. Pak, A. MacDonald, M. J. Ali, S. Barbrel, B. Falcone, R. Kraus, D. Chen, Z. Mo, M. Wei, M. Glenzer, S. H. TI New experimental platform to study high density laser-compressed matter SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID THOMSON SCATTERING; PLASMAS AB We have developed a new experimental platform at the Linac Coherent Light Source (LCLS) which combines simultaneous angularly and spectrally resolved x-ray scattering measurements. This technique offers a new insights on the structural and thermodynamic properties of warm dense matter. The < 50 fs temporal duration of the x-ray pulse provides near instantaneous snapshots of the dynamics of the compression. We present a proof of principle experiment for this platform to characterize a shock-compressed plastic foil. We observe the disappearance of the plastic semi-crystal structure and the formation of a compressed liquid ion-ion correlation peak. The plasma parameters of shock-compressed plastic can be measured as well, but requires an averaging over a few tens of shots. (C) 2014 AIP Publishing LLC. C1 [Gauthier, M.; Fletcher, L. B.; Ravasio, A.; Galtier, E.; Gamboa, E. J.; Granados, E.; Hastings, J. B.; Heimann, P.; Lee, H. J.; Nagler, B.; Schropp, A.; Falcone, R.; Glenzer, S. H.] SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA. [Ravasio, A.] Ecole Polytech, LULI, Palaiseau, France. [Gleason, A.] Stanford Univ, Dept Geol & Environm Sci, Menlo Pk, CA 94025 USA. [Doeppner, T.; LePape, S.; Ma, T.; Pak, A.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. [MacDonald, M. J.] Univ Michigan, Dept Atmospher Ocean & Space Sci, Ann Arbor, MI 48109 USA. [Ali, S.; Barbrel, B.; Kraus, D.] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94709 USA. [Chen, Z.; Mo, M.] Univ Alberta, Dept Phys, Edmonton, AB T6G 2V4, Canada. [Wei, M.] Gen Atom, Inertial Fus Technol Dept, San Diego, CA USA. RP Gauthier, M (reprint author), SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA. EM maxence.gauthier@stanford.edu RI lepape, sebastien/J-3010-2015; gauthier, Maxence/K-2578-2014; OI gauthier, Maxence/0000-0001-6608-9325; Granados, Eduardo/0000-0002-6549-9303 FU DOE Office of Science, Fusion Energy Science [SF00515]; DOE Office of Science, Fusion Energy Science under FWP [100182]; Peter-Paul-Ewald Fellowship of the VolkswagenStiftung; DOE Office of Basic Energy Sciences, Materials Sciences and Engineering Division [DE-AC02-76SF00515]; U.S. Department of Energy [DE-AC52-07NA27344] FX This work was performed at the Matter at Extreme Conditions (MEC) instrument of LCLS, supported by the DOE Office of Science, Fusion Energy Science under Contract No. SF00515. This work was supported by the DOE Office of Science, Fusion Energy Science under FWP 100182, by the Peter-Paul-Ewald Fellowship of the VolkswagenStiftung, and partially supported by DOE Office of Basic Energy Sciences, Materials Sciences and Engineering Division, under Contract No. DE-AC02-76SF00515. This work was performed under the assistance of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. The targets were supported by Laboratory Directed Research and Development. NR 11 TC 4 Z9 4 U1 1 U2 31 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR UNSP 11E616 DI 10.1063/1.4896175 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000203 PM 25430362 ER PT J AU Gerhardt, SP Erickson, K Kaita, R Lawson, J Mozulay, R Mueller, D Que, W Rahman, N Schneider, H Smalley, G Tresemer, K AF Gerhardt, S. P. Erickson, K. Kaita, R. Lawson, J. Mozulay, R. Mueller, D. Que, W. Rahman, N. Schneider, H. Smalley, G. Tresemer, K. TI Magnetic diagnostics for equilibrium reconstruction and realtime plasma control in NSTX-Upgrade SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID SPHERICAL TORUS EXPERIMENT; RESISTIVE WALL MODE; DIII-D PLASMAS; HIGH-BETA; FEEDBACK STABILIZATION; DISRUPTION PREDICTOR; TOKAMAK PLASMAS; ASDEX UPGRADE; COILS; JET AB This paper describes aspects of magnetic diagnostics for realtime control in National Spherical Torus Experiment-Upgrade (NSTX-U). The sensor arrangement on the upgraded center column is described. New analog and digital circuitry for processing the plasma current Rogowski data are presented. An improved algorithm for estimating the plasma vertical velocity for feedback control is presented. (C) 2014 AIP Publishing LLC. C1 [Gerhardt, S. P.; Erickson, K.; Kaita, R.; Lawson, J.; Mozulay, R.; Mueller, D.; Que, W.; Rahman, N.; Schneider, H.; Smalley, G.; Tresemer, K.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Gerhardt, SP (reprint author), Princeton Plasma Phys Lab, POB 451, Princeton, NJ 08543 USA. EM sgerhard@pppl.gov FU United States Department of Energy (DoE) [DE-AC02-09CH11466] FX This research was funded by the United States Department of Energy (DoE) under Contract No. DE-AC02-09CH11466. NR 43 TC 1 Z9 1 U1 2 U2 13 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E807 DI 10.1063/1.4889781 PG 5 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000213 PM 25430372 ER PT J AU Gomez, MR Hansen, SB Peterson, KJ Bliss, DE Carlson, AL Lamppa, DC Schroen, DG Rochau, GA AF Gomez, M. R. Hansen, S. B. Peterson, K. J. Bliss, D. E. Carlson, A. L. Lamppa, D. C. Schroen, D. G. Rochau, G. A. TI Magnetic field measurements via visible spectroscopy on the Z machine SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Sandia's Z Machine uses its high current to magnetically implode targets relevant to inertial confinement fusion. Since target performance is highly dependent on the applied drive field, measuring magnetic field at the target is essential for accurate simulations. Recently, the magnetic field at the target was measured through splitting of the sodium 3s-3p doublet at 5890 and 5896 angstrom. Spectroscopic dopants were applied to the exterior of the target, and spectral lines were observed in absorption. Magnetic fields in excess of 200 T were measured, corresponding to drive currents of approximately 5 MA early in the pulse. (C) 2014 AIP Publishing LLC. C1 [Gomez, M. R.; Hansen, S. B.; Peterson, K. J.; Bliss, D. E.; Carlson, A. L.; Lamppa, D. C.; Rochau, G. A.] Sandia Natl Labs, Albuquerque, NM 87185 USA. [Schroen, D. G.] Gen Atom Co, San Diego, CA 92121 USA. RP Gomez, MR (reprint author), Sandia Natl Labs, POB 5800, Albuquerque, NM 87185 USA. EM mrgomez@sandia.gov FU U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX The authors would like to thank J. E. Bailey, M. E. Cuneo, and D. B. Sinars for their support of this measurement. They also thank D. J. Ampleford, T. J. Awe, A. J. Harvey-Thompson, B. Jones, P. F. Knapp, and R. D. McBride for allowing ride-along measurements to develop this diagnostic capability on their experiments. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under Contract No. DE-AC04-94AL85000. NR 11 TC 5 Z9 5 U1 1 U2 4 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E609 DI 10.1063/1.4891304 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000196 PM 25430355 ER PT J AU Hager, JD Lanier, NE Kline, JL Flippo, KA Bruns, HC Schneider, M Saculla, M McCarville, T AF Hager, J. D. Lanier, N. E. Kline, J. L. Flippo, K. A. Bruns, H. C. Schneider, M. Saculla, M. McCarville, T. TI A split imaging spectrometer for temporally and spatially resolved titanium absorption spectroscopy SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID DENSITY FOAM TARGETS; RADIATIVELY HEATED FOAM; RAY FRAMING CAMERA; IONIZATION FRONTS; FACILITY; DRIVEN AB We present a temporally and a spatially resolved spectrometer for titanium x-ray absorption spectroscopy along 2 axial symmetric lines-of-sight. Each line-of-sight of the instrument uses an elliptical crystal to acquire both the 2p and 3p Ti absorption lines on a single, time gated channel of the instrument. The 2 axial symmetric lines-of-sight allow the 2p and 3p absorption features to be measured through the same point in space using both channels of the instrument. The spatially dependent material temperature can be inferred by observing the 2p and the 3p Ti absorption features. The data are recorded on a two strip framing camera with each strip collecting data from a single line-of-sight. The design is compatible for use at both the OMEGA laser and the National Ignition Facility. The spectrometer is intended to measure the material temperature behind a Marshak wave in a radiatively driven SiO2 foam with a Ti foam tracer. In this configuration, a broad band CsI back-lighter will be used for a source and the Ti absorption spectrum measured. (C) 2014 AIP Publishing LLC. C1 [Hager, J. D.; Lanier, N. E.; Kline, J. L.; Flippo, K. A.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Bruns, H. C.; Schneider, M.; Saculla, M.; McCarville, T.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. RP Hager, JD (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. EM hager@lanl.gov RI Flippo, Kirk/C-6872-2009; OI Flippo, Kirk/0000-0002-4752-5141; Kline, John/0000-0002-2271-9919 FU U.S. Department of Energy by LANL [DE-AC52-06NA25396] FX This work was performed under the auspices of the U.S. Department of Energy by LANL under Contract No. DE-AC52-06NA25396. NR 21 TC 0 Z9 0 U1 0 U2 12 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D601 DI 10.1063/1.4885843 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000018 PM 25430177 ER PT J AU Hall, GN Izumi, N Tommasini, R Carpenter, AC Palmer, NE Zacharias, R Felker, B Holder, JP Allen, FV Bell, PM Bradley, D Montesanti, R Landen, OL AF Hall, G. N. Izumi, N. Tommasini, R. Carpenter, A. C. Palmer, N. E. Zacharias, R. Felker, B. Holder, J. P. Allen, F. V. Bell, P. M. Bradley, D. Montesanti, R. Landen, O. L. TI AXIS: An instrument for imaging Compton radiographs using the Advanced Radiography Capability on the NIF SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Compton radiography is an important diagnostic for Inertial Confinement Fusion (ICF), as it provides a means to measure the density and asymmetries of the DT fuel in an ICF capsule near the time of peak compression. The AXIS instrument (ARC (Advanced Radiography Capability) X-ray Imaging System) is a gated detector in development for the National Ignition Facility (NIF), and will initially be capable of recording two Compton radiographs during a single NIF shot. The principal reason for the development of AXIS is the requirement for significantly improved detection quantum efficiency (DQE) at high x-ray energies. AXIS will be the detector for Compton radiography driven by the ARC laser, which will be used to produce Bremsstrahlung X-ray backlighter sources over the range of 50 keV-200 keV for this purpose. It is expected that AXIS will be capable of recording these high-energy x-rays with a DQE several times greater than other X-ray cameras at NIF, as well as providing a much larger field of view of the imploded capsule. AXIS will therefore provide an image with larger signal-to-noise that will allow the density and distribution of the compressed DT fuel to be measured with significantly greater accuracy as ICF experiments are tuned for ignition. (C) 2014 AIP Publishing LLC. C1 [Hall, G. N.; Izumi, N.; Tommasini, R.; Carpenter, A. C.; Palmer, N. E.; Zacharias, R.; Felker, B.; Holder, J. P.; Allen, F. V.; Bell, P. M.; Bradley, D.; Montesanti, R.; Landen, O. L.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. RP Hall, GN (reprint author), Lawrence Livermore Natl Lab, 7000 East Ave, Livermore, CA 94550 USA. EM hall98@llnl.gov RI IZUMI, Nobuhiko/J-8487-2016; Tommasini, Riccardo/A-8214-2009 OI IZUMI, Nobuhiko/0000-0003-1114-597X; Tommasini, Riccardo/0000-0002-1070-3565 FU (U.S.) Department of Energy (DOE), National Nuclear Security Administration [DE-AC52-07NA27344 (LLNL-JRNL-555712)] FX Lawrence Livermore National Laboratory is operated by Lawrence Livermore National Security, LLC, for the (U.S.) Department of Energy (DOE), National Nuclear Security Administration under Contract No. DE-AC52-07NA27344 (LLNL-JRNL-555712). NR 10 TC 2 Z9 2 U1 1 U2 12 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D624 DI 10.1063/1.4892558 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000041 PM 25430200 ER PT J AU Hall, GN Burdiak, GC Suttle, L Stuart, NH Swadling, GF Lebedev, SV Smith, RA Patankar, S Suzuki-Vidal, F de Grouchy, P Harvey-Thompson, AJ Bennett, M Bland, SN Pickworth, L Skidmorec, J AF Hall, G. N. Burdiak, G. C. Suttle, L. Stuart, N. H. Swadling, G. F. Lebedev, S. V. Smith, R. A. Patankar, S. Suzuki-Vidal, F. de Grouchy, P. Harvey-Thompson, A. J. Bennett, M. Bland, S. N. Pickworth, L. Skidmorec, J. TI Monochromatic radiography of high energy density physics experiments on the MAGPIE generator SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID RAY; CRYSTALS; PLASMA AB A monochromatic X-ray backlighter based on Bragg reflection from a spherically bent quartz crystal has been developed for the MAGPIE pulsed power generator at Imperial College (1.4 MA, 240 ns) [I. H. Mitchell et al., Rev. Sci. Instrum. 67, 1533 (2005)]. This instrument has been used to diagnose high energy density physics experiments with 1.865 keV radiation (Silicon He-alpha) from a laser plasma source driven by a similar to 7 J, 1 ns pulse from the Cerberus laser. The design of the diagnostic, its characterisation and performance, and initial results in which the instrument was used to radiograph a shock physics experiment on MAGPIE are discussed. (C) 2014 AIP Publishing LLC. C1 [Hall, G. N.; Burdiak, G. C.; Suttle, L.; Stuart, N. H.; Swadling, G. F.; Lebedev, S. V.; Smith, R. A.; Patankar, S.; Suzuki-Vidal, F.; de Grouchy, P.; Harvey-Thompson, A. J.; Bennett, M.; Bland, S. N.; Pickworth, L.; Skidmorec, J.] Univ London Imperial Coll Sci Technol & Med, Blackett Lab, London SW7 2BW, England. RP Hall, GN (reprint author), Lawrence Livermore Natl Lab, 7000 East Ave, Livermore, CA 94550 USA. EM gareth.hall@imperial.ac.uk RI Hall, Gareth/C-4179-2015; Swadling, George/S-5980-2016; OI Swadling, George/0000-0001-8370-8837; Stuart, Nicholas/0000-0003-2882-2500 FU Imperial College Junior Research Fellowship scheme; EPSRC FX The author would like to acknowledge the support of the Imperial College Junior Research Fellowship scheme and the EPSRC. The Author would also like to thank Daniel B. Sinars of Sandia National Laboratories, Albuquerque, for his advice and support. NR 10 TC 2 Z9 3 U1 1 U2 19 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D608 DI 10.1063/1.4890262 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000025 PM 25430184 ER PT J AU Haugh, MJ Wu, M Jacoby, KD Loisel, GP AF Haugh, M. J. Wu, M. Jacoby, K. D. Loisel, G. P. TI Measuring the x-ray resolving power of bent potassium acid phthalate diffraction crystals SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB This report presents the results from measuring the X-ray resolving power of a curved potassium acid phthalate (KAP(001)) spectrometer crystal using two independent methods. It is part of a continuing effort to measure the fundamental diffraction properties of bent crystals that are used to study various characteristics of high temperature plasmas. Bent crystals like KAP(001) do not usually have the same diffraction properties as corresponding flat crystals. Models that do exist to calculate the effect of bending the crystal on the diffraction properties have simplifying assumptions and their accuracy limits have not been adequately determined. The type of crystals that we measured is being used in a spectrometer on the Z machine at Sandia National Laboratories in Albuquerque, New Mexico. The first technique for measuring the crystal resolving power measures the X-ray spectral line width of the characteristic lines from several metal anodes. The second method uses a diode X-ray source and a double crystal diffractometer arrangement to measure the reflectivity curve of the KAP(001) crystal. The width of that curve is inversely proportional to the crystal resolving power. The measurement results are analyzed and discussed. (C) 2014 AIP Publishing LLC. C1 [Haugh, M. J.; Jacoby, K. D.] Natl Secur Technol LLC, Livermore, CA 94550 USA. [Wu, M.; Loisel, G. P.] Sandia Natl Labs, Albuquerque, NM 87123 USA. RP Haugh, MJ (reprint author), Natl Secur Technol LLC, Livermore, CA 94550 USA. EM haughmj@nv.doe.gov FU U.S. Department of Energy [DE-AC52-06NA25946] FX This manuscript has been authored by National Security Technologies, LLC, under Contract No. DE-AC52-06NA25946 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. NR 14 TC 3 Z9 3 U1 0 U2 5 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D619 DI 10.1063/1.4891919 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000036 PM 25430195 ER PT J AU Herrmann, HW Kim, YH Young, CS Fatherley, VE Lopez, FE Oertel, JA Malone, RM Rubery, MS Horsfield, CJ Stoeffl, W Zylstra, AB Shmayda, WT Batha, SH AF Herrmann, H. W. Kim, Y. H. Young, C. S. Fatherley, V. E. Lopez, F. E. Oertel, J. A. Malone, R. M. Rubery, M. S. Horsfield, C. J. Stoeffl, W. Zylstra, A. B. Shmayda, W. T. Batha, S. H. TI Extended performance gas Cherenkov detector for gamma-ray detection in high-energy density experiments SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB A new Gas Cherenkov Detector (GCD) with low-energy threshold and high sensitivity, currently known as Super GCD (or GCD-3 at OMEGA), is being developed for use at the OMEGA Laser Facility and the National Ignition Facility (NIF). Super GCD is designed to be pressurized to <= 400 psi (absolute) and uses all metal seals to allow the use of fluorinated gases inside the target chamber. This will allow the gamma energy threshold to be run as low at 1.8 MeV with 400 psi (absolute) of C2F6, opening up a new portion of the gamma ray spectrum. Super GCD operating at 20 cm from TCC will be similar to 400 x more efficient at detecting DT fusion gammas at 16.7 MeV than the Gamma Reaction History diagnostic at NIF (GRH-6m) when operated at their minimum thresholds. (C) 2014 AIP Publishing LLC. C1 [Herrmann, H. W.; Kim, Y. H.; Young, C. S.; Fatherley, V. E.; Lopez, F. E.; Oertel, J. A.; Batha, S. H.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Malone, R. M.] Natl Secur Technol LLC, Los Alamos, NM 87544 USA. [Rubery, M. S.; Horsfield, C. J.] Atom Weap Estab, Aldermaston RG7 4PR, Berks, England. [Stoeffl, W.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Zylstra, A. B.] MIT, Plasma Sci & Fus Ctr, Cambridge, MA 02139 USA. [Shmayda, W. T.] Univ Rochester, Laser Energet Lab, Rochester, NY 14623 USA. RP Herrmann, HW (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. EM herrmann@lanl.gov NR 9 TC 5 Z9 5 U1 0 U2 9 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E124 DI 10.1063/1.4892553 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000144 PM 25430303 ER PT J AU Hill, KW Bitter, M Delgado-Aparacio, L Efthimion, P Pablant, NA Lu, J Beiersdorfer, P Chen, H Magee, E AF Hill, K. W. Bitter, M. Delgado-Aparacio, L. Efthimion, P. Pablant, N. A. Lu, J. Beiersdorfer, P. Chen, H. Magee, E. TI Characterization of spatially resolved high resolution x-ray spectrometers for high energy density physics and light source experiments SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID SPECTRA AB A high resolution 1D imaging x-ray spectrometer concept comprising a spherically bent crystal and a 2D pixelated detector is being optimized for diagnostics of small sources such as high energy density physics (HEDP) and synchrotron radiation or x-ray free electron laser experiments. This instrument is used on tokamak experiments for Doppler measurements of ion temperature and plasma flow velocity profiles. Laboratory measurements demonstrate a resolving power, E/Delta E of order 10 000 and spatial resolution better than 10 mu m. Initial tests of the high resolution instrument on HEDP plasmas are being performed. c 2014 AIP Publishing LLC. C1 [Hill, K. W.; Bitter, M.; Delgado-Aparacio, L.; Efthimion, P.; Pablant, N. A.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Lu, J.] Chongqing Univ, Minist Educ, Key Lab Optoelect Technol & Syst, Chongqing 400030, Peoples R China. [Beiersdorfer, P.; Chen, H.; Magee, E.] Lawrence Livermore Natl Lab, Phys Div, Livermore, CA 94550 USA. RP Hill, KW (reprint author), Princeton Plasma Phys Lab, POB 451, Princeton, NJ 08543 USA. EM khill@pppl.gov FU (U.S.) Department of Energy (DOE) by Princeton Plasma Physics Laboratory (PPPL) [DE-AC02-09CH-11466]; (U.S.) Department of Energy (DOE) by Lawrence Livermore National Laboratory (LLNL) [DE-AC52-07NA-27344] FX This work was performed under the auspices of the (U.S.) Department of Energy (DOE) by Princeton Plasma Physics Laboratory (PPPL) under Contract No. DE-AC02-09CH-11466 and Lawrence Livermore National Laboratory (LLNL) under Contract No. DE-AC52-07NA-27344. NR 16 TC 4 Z9 4 U1 0 U2 13 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D612 DI 10.1063/1.4890260 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000029 PM 25430188 ER PT J AU Hohenberger, M Albert, F Palmer, NE Lee, JJ Doppner, T Divol, L Dewald, EL Bachmann, B MacPhee, AG LaCaille, G Bradley, DK Stoeckl, C AF Hohenberger, M. Albert, F. Palmer, N. E. Lee, J. J. Doeppner, T. Divol, L. Dewald, E. L. Bachmann, B. MacPhee, A. G. LaCaille, G. Bradley, D. K. Stoeckl, C. TI Time-resolved measurements of the hot-electron population in ignition-scale experiments on the National Ignition Facility SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID PLASMAS AB In laser-driven inertial confinement fusion, hot electrons can preheat the fuel and prevent fusion-pellet compression to ignition conditions. Measuring the hot-electron population is key to designing an optimized ignition platform. The hot electrons in these high-intensity, laser-driven experiments, created via laser-plasma interactions, can be inferred from the bremsstrahlung generated by hot electrons interacting with the target. At the National Ignition Facility (NIF) [G. H. Miller, E. I. Moses, and C. R. Wuest, Opt. Eng. 43, 2841 (2004)], the filter-fluorescer x-ray (FFLEX) diagnostic-a multichannel, hard x-ray spectrometer operating in the 20-500 keV range-has been upgraded to provide fully time-resolved, absolute measurements of the bremsstrahlung spectrum with similar to 300 ps resolution. Initial time-resolved data exhibited significant background and low signal-to-noise ratio, leading to a redesign of the FFLEX housing and enhanced shielding around the detector. The FFLEX x-ray sensitivity was characterized with an absolutely calibrated, energy-dispersive high-purity germanium detector using the high-energy x-ray source at NSTec Livermore Operations over a range of K-shell fluorescence energies up to 111 keV (U K-beta). The detectors impulse response function was measured in situ on NIF short-pulse (similar to 90 ps) experiments, and in off-line tests. (C) 2014 AIP Publishing LLC. C1 [Hohenberger, M.; Stoeckl, C.] Univ Rochester, Laser Energet Lab, Rochester, NY 14623 USA. [Albert, F.; Palmer, N. E.; Doeppner, T.; Divol, L.; Dewald, E. L.; Bachmann, B.; MacPhee, A. G.; LaCaille, G.; Bradley, D. K.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Lee, J. J.] Natl Secur Technol LLC, Livermore, CA 94551 USA. RP Hohenberger, M (reprint author), Univ Rochester, Laser Energet Lab, 250 E River Rd, Rochester, NY 14623 USA. EM mhoh@lle.rochester.edu RI Albert, Felicie/G-2645-2013 FU Department of Energy National Nuclear Security Administration [DE-NA0001944]; University of Rochester; New York State Energy Research and Development Authority; U.S. Department of Energy, National Nuclear Security Administration [DE-AC52-07NA27344]; DOE [LLNL-PROC-655392] FX This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award No. DE-NA0001944, the University of Rochester, and the New York State Energy Research and Development Authority. Lawrence Livermore National Laboratory is operated by Lawrence Livermore National Security, LLC, for the U.S. Department of Energy, National Nuclear Security Administration under Contract No. DE-AC52-07NA27344. The support of DOE does not constitute an endorsement by DOE of the views expressed in this article. (LLNL-PROC-655392.) NR 19 TC 14 Z9 14 U1 1 U2 23 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D501 DI 10.1063/1.4890537 PG 5 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000016 PM 25430175 ER PT J AU Howard, NT Sung, C White, AE AF Howard, N. T. Sung, C. White, A. E. TI Measurement of electron temperature fluctuations using a tunable correlation electron cyclotron emission system on Alcator C-Mod SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID CORE; TRANSPORT AB A tunable correlation electron cyclotron (CECE) system was recently installed on the Alcator C-Mod tokamak to provide local, quantitative measurement of electron temperature fluctuations in the tokamak core. This system represents a significant upgrade from the original CECE system, expanding the measurement capabilities from 4 to 8 total channels, including 2 remotely tunable YIG filters (6-18 GHz; 200 MHz bandwidth). Additional upgrades were made to the optical system to provide enhanced poloidal resolution and allow for measurement of turbulent fluctuations below k(theta)rho(s) < 0.3. These expanded capabilities allow for single shot measurement of partial temperature fluctuation profiles in the region rho = 0.7 - 0.9 (square root of normalized toroidal flux) in a wide variety of plasma conditions. These measurements are currently being used to provide stringent tests of the gyrokinetic model in ongoing model validation efforts. Details of the hardware upgrades, turbulent fluctuation measurements, and ongoing comparisons with simulations are presented. (C) 2014 AIP Publishing LLC. C1 [Howard, N. T.] ORISE, Oak Ridge, TN 37831 USA. [Sung, C.; White, A. E.] MIT, Plasma Sci & Fus Ctr, Cambridge, MA 02139 USA. RP Howard, NT (reprint author), ORISE, Oak Ridge, TN 37831 USA. EM nthoward@psfc.mit.edu NR 14 TC 2 Z9 2 U1 0 U2 9 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D811 DI 10.1063/1.4886422 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000065 PM 25430224 ER PT J AU Huntington, CM Maddox, BR Park, HS Prisbrey, S Remington, BA AF Huntington, C. M. Maddox, B. R. Park, H. -S. Prisbrey, S. Remington, B. A. TI Spectral content of buried Ag foils at 10(16) W/cm(2) laser illumination SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID NATIONAL-IGNITION-FACILITY AB Sources of 5-12 keV thermal He alpha x-rays are readily generated by laser irradiation of mid-Z foils at intensities >10(14) W/cm(2), and are widely used as probes for inertial confinement fusion and high-energy-density experiments. Higher energy 17-50 keV x-ray sources are efficiently produced from "cold" K alpha emission using short pulse, petawatt lasers at intensities >10(18) W/cm(2) [H.-S. Park, B. R. Maddox et al., "High-resolution 17-75 keV backlighters for high energy density experiments," Phys. Plasmas 15(7), 072705 (2008); B. R. Maddox, H. S. Park, B. A. Remington et al., "Absolute measurements of x-ray backlighter sources at energies above 10 keV," ibid. 18(5), 056709 (2011)]. However, when long pulse (>1 ns) lasers are used with Z > 30 elements, the spectrum contains contributions from both K shell transitions and from ionized atomic states. Here we show that by sandwiching a silver foil between layers of high-density carbon, the ratio of K alpha:He alpha in the x-ray spectrum is significant increased over directly illuminated Ag foils, with narrower lines from K-shell transitions. Additionally, the emission volume is more localized for the sandwiched target, producing a more planar x-ray sheet. This technique may be useful for generating probes requiring spectral purity and a limited spatial extent, for example, in incoherent x-ray Thomson scattering experiments. (C) 2014 AIP Publishing LLC. C1 [Huntington, C. M.; Maddox, B. R.; Park, H. -S.; Prisbrey, S.; Remington, B. A.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. RP Huntington, CM (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. EM huntington4@llnl.gov FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. NR 14 TC 0 Z9 0 U1 0 U2 5 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D631 DI 10.1063/1.4895566 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000048 PM 25430207 ER PT J AU Izumi, N Hall, GN Carpenter, AC Allen, FV Cruz, JG Felker, B Hargrove, D Holder, J Kilkenny, JD Lumbard, A Montesanti, R Palmer, NE Piston, K Stone, G Thao, M Vern, R Zacharias, R Landen, OL Tommasini, R Bradley, DK Bell, PM AF Izumi, N. Hall, G. N. Carpenter, A. C. Allen, F. V. Cruz, J. G. Felker, B. Hargrove, D. Holder, J. Kilkenny, J. D. Lumbard, A. Montesanti, R. Palmer, N. E. Piston, K. Stone, G. Thao, M. Vern, R. Zacharias, R. Landen, O. L. Tommasini, R. Bradley, D. K. Bell, P. M. TI Development of a dual MCP framing camera for high energy x-rays SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID DETECTORS AB Recently developed diagnostic techniques at LLNL require recording backlit images of extremely dense imploded plasmas using hard x-rays, and demand the detector to be sensitive to photons with energies higher than 50 keV [R. Tommasini et al., Phys. Phys. Plasmas 18, 056309 (2011); G. N. Hall et al., "AXIS: An instrument for imaging Compton radiographs using ARC on the NIF," Rev. Sci. Instrum. (these proceedings)]. To increase the sensitivity in the high energy region, we propose to use a combination of two MCPs. The first MCP is operated in a low gain regime and works as a thick photocathode, and the second MCP works as a high gain electron multiplier. We tested the concept of this dual MCP configuration and succeeded in obtaining a detective quantum efficiency of 4.5% for 59 keV x-rays, 3 times larger than with a single plate of the thickness typically used in NIF framing cameras. (C) 2014 AIP Publishing LLC. C1 [Izumi, N.; Hall, G. N.; Carpenter, A. C.; Allen, F. V.; Cruz, J. G.; Felker, B.; Hargrove, D.; Holder, J.; Lumbard, A.; Montesanti, R.; Palmer, N. E.; Piston, K.; Stone, G.; Thao, M.; Vern, R.; Zacharias, R.; Landen, O. L.; Tommasini, R.; Bradley, D. K.; Bell, P. M.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Kilkenny, J. D.] Gen Atom Co, San Diego, CA 92121 USA. RP Izumi, N (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. EM izumi2@llnl.gov RI IZUMI, Nobuhiko/J-8487-2016; Tommasini, Riccardo/A-8214-2009 OI IZUMI, Nobuhiko/0000-0003-1114-597X; Tommasini, Riccardo/0000-0002-1070-3565 FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. NR 12 TC 2 Z9 3 U1 2 U2 16 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D623 DI 10.1063/1.4891712 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000040 PM 25430199 ER PT J AU Johnson, MG Frenje, JA Li, CK Seguin, FH Petrasso, RD Bionta, RM Casey, DT Caggiano, JA Hatarik, R Khater, HY Sayre, DB Knauer, JP Sangster, TC Herrmann, HW Kilkenny, JD AF Johnson, M. Gatu Frenje, J. A. Li, C. K. Seguin, F. H. Petrasso, R. D. Bionta, R. M. Casey, D. T. Caggiano, J. A. Hatarik, R. Khater, H. Y. Sayre, D. B. Knauer, J. P. Sangster, T. C. Herrmann, H. W. Kilkenny, J. D. TI Measurements of fuel and ablator rho R in Symmetry-Capsule implosions with the Magnetic Recoil neutron Spectrometer (MRS) on the National Ignition Facility SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID OMEGA AB The Magnetic Recoil neutron Spectrometer (MRS) on the National Ignition Facility (NIF) measures the neutron spectrum in the energy range of 4-20 MeV. This paper describes MRS measurements of DT-fuel and CH-ablator rho R in DT gas-filled symmetry-capsule implosions at the NIF. DT-fuel rho R's of 80-140 mg/cm(2) and CH-ablator rho R's of 400-680 mg/cm(2) are inferred from MRS data. The measurements were facilitated by an improved correction of neutron-induced background in the lowenergy part of the MRS spectrum. This work demonstrates the accurate utilization of the complete MRS-measured neutron spectrum for diagnosing NIF DT implosions. (C) 2014 AIP Publishing LLC. C1 [Johnson, M. Gatu; Frenje, J. A.; Li, C. K.; Seguin, F. H.; Petrasso, R. D.] MIT, Plasma Sci & Fus Ctr, Cambridge, MA 02139 USA. [Bionta, R. M.; Casey, D. T.; Caggiano, J. A.; Hatarik, R.; Khater, H. Y.; Sayre, D. B.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Knauer, J. P.; Sangster, T. C.] Univ Rochester, Laser Energet Lab, Rochester, NY 14623 USA. [Herrmann, H. W.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Kilkenny, J. D.] Gen Atom Co, San Diego, CA 92186 USA. RP Johnson, MG (reprint author), MIT, Plasma Sci & Fus Ctr, 77 Massachusetts Ave, Cambridge, MA 02139 USA. EM gatu@psfc.mit.edu FU U.S. DOE by MIT [DE-NA0001857]; Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work was performed under the auspices of the U.S. DOE by MIT under Contract No. DE-NA0001857 and Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. NR 16 TC 4 Z9 4 U1 1 U2 5 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E104 DI 10.1063/1.4886418 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000124 ER PT J AU Kim, Y Herrmann, HW Jorgenson, HJ Barlow, DB Young, CS Stoeffl, W Casey, D Clancy, T Lopez, FE Oertel, JA Hilsabeck, T Moy, K Batha, SH AF Kim, Y. Herrmann, H. W. Jorgenson, H. J. Barlow, D. B. Young, C. S. Stoeffl, W. Casey, D. Clancy, T. Lopez, F. E. Oertel, J. A. Hilsabeck, T. Moy, K. Batha, S. H. TI Conceptual design of the gamma-to-electron magnetic spectrometer for the National Ignition Facility SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB The Gamma-to-Electron Magnetic Spectrometer (GEMS) diagnostic is designed to measure the prompt gamma-ray energy spectrum during high yield deuterium-tritium (DT) implosions at the National Ignition Facility (NIF). The prompt gamma-ray spectrum will provide "burn-averaged" observables, including total DT fusion yield, total areal density (rho R), ablator rho R, and fuel rho R. These burn-averaged observables are unique because they are essentially averaged over 4 pi, providing a global reference for the line-of-sight-specific measurements typical of x-ray and neutron diagnostics. The GEMS conceptual design meets the physics-based requirements: Delta E/E = 3%-5% can be achieved in the range of 2-25 MeV gamma-ray energy. Minimum DT neutron yields required for 15% measurement uncertainty at low-resolution mode are: 5 x 10(14) DT-n for ablator rho R (at 0.2 g/cm(2)); 2 x 10(15) DT-n for total DT yield (at 4.2 x 10(-5) gamma/n); and 1 x 10(16) DT-n for fuel rho R (at 1 g/cm(2)). (C) 2014 AIP Publishing LLC. C1 [Kim, Y.; Herrmann, H. W.; Jorgenson, H. J.; Barlow, D. B.; Young, C. S.; Lopez, F. E.; Oertel, J. A.; Batha, S. H.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Stoeffl, W.; Casey, D.; Clancy, T.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Hilsabeck, T.] Gen Atom Co, San Diego, CA 92186 USA. [Moy, K.] Natl Secur Technol, Special Technol Lab, Santa Barbara, CA 93111 USA. RP Kim, Y (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. EM yhkim@lanl.gov NR 7 TC 4 Z9 4 U1 1 U2 9 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E122 DI 10.1063/1.4892900 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000142 PM 25430301 ER PT J AU Klein, SR Manuel, MJE Pollock, BB Gillespie, RS Deininger, M Kuranz, CC Keiter, PA Drake, RP AF Klein, S. R. Manuel, M. J. -E. Pollock, B. B. Gillespie, R. S. Deininger, M. Kuranz, C. C. Keiter, P. A. Drake, R. P. TI Construction of a solenoid used on a magnetized plasma experiment SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Creating magnetized jets in the laboratory is relevant to studying young stellar objects, but generating these types of plasmas within the laboratory setting has proven to be challenging. Here, we present the construction of a solenoid designed to produce an axial magnetic field with strengths in the gap of up to 5 T. This novel design was a compact 75 mm x 63 mm x 88 mm, allowing it to be placed in the Titan target chamber. It was robust, surviving over 50 discharges producing fields less than or similar to 5 T, reaching a peak magnetic field of 12.5 T. (C) 2014 AIP Publishing LLC. C1 [Klein, S. R.; Manuel, M. J. -E.; Gillespie, R. S.; Kuranz, C. C.; Keiter, P. A.; Drake, R. P.] Univ Michigan, Dept Atmospher Ocean & Space Sci, Ann Arbor, MI 48109 USA. [Pollock, B. B.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Deininger, M.] Univ Michigan, Med Innovat Ctr, Ann Arbor, MI 48109 USA. RP Klein, SR (reprint author), Univ Michigan, Dept Atmospher Ocean & Space Sci, Ann Arbor, MI 48109 USA. RI Manuel, Mario/L-3213-2015; Drake, R Paul/I-9218-2012 OI Manuel, Mario/0000-0002-5834-1161; Drake, R Paul/0000-0002-5450-9844 FU (U.S.) Department of Energy (DOE), through the NNSA-DS [DE-NA0001840]; (U.S.) Department of Energy (DOE), through SC-OFES Joint Program in High-Energy-Density Laboratory Plasmas [DE-NA0001840]; National Laser User Facility Program [NA0000850]; National Laser User Facility Program through the Laboratory for Laser Energetics, University of Rochester by the NNSA/OICF [DE-FC52-08NA28302] FX This work is funded by the (U.S.) Department of Energy (DOE), through the NNSA-DS and SC-OFES Joint Program in High-Energy-Density Laboratory Plasmas, Grant No. DE-NA0001840, and the National Laser User Facility Program, Grant No. DE-NA0000850, and through the Laboratory for Laser Energetics, University of Rochester by the NNSA/OICF under Cooperative Agreement No. DE-FC52-08NA28302. NR 2 TC 3 Z9 3 U1 2 U2 12 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E812 DI 10.1063/1.4891060 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000218 PM 25430377 ER PT J AU Klepper, CC Martin, EH Isler, RC Colas, L Goniche, M Hillairet, J Panayotis, S Pegourie, B Jacquot, J Lotte, P Colledani, G Biewer, TM Caughman, JB Ekedahl, A Green, DL Harris, JH Hillis, DL Shannon, SC Litaudon, X AF Klepper, C. C. Martin, E. H. Isler, R. C. Colas, L. Goniche, M. Hillairet, J. Panayotis, S. Pegourie, B. Jacquot, J. Lotte, Ph. Colledani, G. Biewer, T. M. Caughman, J. B. Ekedahl, A. Green, D. L. Harris, J. H. Hillis, D. L. Shannon, S. C. Litaudon, X. TI Probing the plasma near high power wave launchers in fusion devices for static and dynamic electric fields (invited) SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID TORE-SUPRA; HEAT-FLUX AB An exploratory study was carried out in the long-pulse tokamak Tore Supra, to determine if electric fields in the plasma around high-power, RF wave launchers could be measured with non-intrusive, passive, optical emission spectroscopy. The focus was in particular on the use of the external electric field Stark effect. The feasibility was found to be strongly dependent on the spatial extent of the electric fields and overlap between regions of strong (>similar to 1 kV/cm) electric fields and regions of plasma particle recycling and plasma-induced, spectral line emission. Most amenable to the measurement was the RF electric field in edge plasma, in front of a lower hybrid heating and current drive launcher. Electric field strengths and direction, derived from fitting the acquired spectra to a model including time-dependent Stark effect and the tokamak-range magnetic field Zeeman-effect, were found to be in good agreement with full-wave modeling of the observed launcher. (C) 2014 AIP Publishing LLC. C1 [Klepper, C. C.; Martin, E. H.; Isler, R. C.; Biewer, T. M.; Caughman, J. B.; Green, D. L.; Harris, J. H.; Hillis, D. L.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. [Martin, E. H.; Shannon, S. C.] N Carolina State Univ, Raleigh, NC 27607 USA. [Colas, L.; Goniche, M.; Hillairet, J.; Panayotis, S.; Pegourie, B.; Jacquot, J.; Lotte, Ph.; Colledani, G.; Ekedahl, A.; Litaudon, X.] CEA, IRFM, F-13108 St Paul Les Durance, France. RP Klepper, CC (reprint author), Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. EM kleppercc@ornl.gov RI Shannon, Steven/O-3420-2014; Klepper, C.Christopher/I-9904-2016; Caughman, John/R-4889-2016; OI Shannon, Steven/0000-0001-8317-6949; Klepper, C.Christopher/0000-0001-9107-8337; Caughman, John/0000-0002-0609-1164; Isler, Ralph/0000-0002-5368-7200 FU US DOE [DE-AC05-00OR22725] FX Valuable feedback on RF physics and RF-edge interactions from Dr. Cornwall Lau, ORNL, is kindly acknowledged, as were valuable discussions with Dr. Ph. Jacquet and Dr. K. Kirov. CCFE, UK, on LH physics. This work was supported in part by the US DOE under Contract No. DE-AC05-00OR22725 with UT-Battelle, LLC. NR 13 TC 0 Z9 0 U1 3 U2 12 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E301 DI 10.1063/1.4890247 PG 5 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000147 PM 25430306 ER PT J AU Konig, R Biel, W Biedermann, C Burhenn, R Cseh, G Czarnecka, A Endler, M Estrada, T Grulke, O Hathiramani, D Hirsch, M Jablonski, S Jakubowski, M Kaczmarczyk, J Kasparek, W Kocsis, G Kornejew, P Kramer-Flecken, A Krychowiak, M Kubkowska, M Langenberg, A Laux, M Liang, Y Lorenz, A Neubauer, O Otte, M Pablant, N Pasch, E Pedersen, TS Schmitz, O Schneider, W Schuhmacher, H Schweer, B Thomsen, H Szepesi, T Wiegel, B Windisch, T Wolf, S Zhang, D Zoletnik, S AF Koenig, R. Biel, W. Biedermann, C. Burhenn, R. Cseh, G. Czarnecka, A. Endler, M. Estrada, T. Grulke, O. Hathiramani, D. Hirsch, M. Jablonski, S. Jakubowski, M. Kaczmarczyk, J. Kasparek, W. Kocsis, G. Kornejew, P. Kraemer-Flecken, A. Krychowiak, M. Kubkowska, M. Langenberg, A. Laux, M. Liang, Y. Lorenz, A. Neubauer, O. Otte, M. Pablant, N. Pasch, E. Pedersen, T. S. Schmitz, O. Schneider, W. Schuhmacher, H. Schweer, B. Thomsen, H. Szepesi, T. Wiegel, B. Windisch, T. Wolf, S. Zhang, D. Zoletnik, S. TI Status of the diagnostics development for the first operation phase of the stellarator Wendelstein 7-X SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB An overview of the diagnostics which are essential for the first operational phase of Wendelstein 7-X and the set of diagnostics expected to be ready for operation at this time are presented. The ongoing investigations of how to cope with high levels of stray Electron Cyclotron Resonance Heating (ECRH) radiation in the ultraviolet (UV)/visible/infrared (IR) optical diagnostics are described. C1 [Koenig, R.; Biedermann, C.; Burhenn, R.; Endler, M.; Grulke, O.; Hathiramani, D.; Hirsch, M.; Jakubowski, M.; Kornejew, P.; Krychowiak, M.; Langenberg, A.; Laux, M.; Lorenz, A.; Otte, M.; Pasch, E.; Pedersen, T. S.; Schneider, W.; Thomsen, H.; Windisch, T.; Zhang, D.] Max Planck Inst Plasma Phys, D-17491 Greifswald, Germany. [Biel, W.; Kraemer-Flecken, A.; Liang, Y.; Neubauer, O.; Schweer, B.] Forschungszentrum Julich, Inst Energy & Climate Res, D-52425 Julich, Germany. [Cseh, G.; Kocsis, G.; Szepesi, T.; Zoletnik, S.] RMI, Wigner RCP, H-1121 Budapest, Hungary. [Czarnecka, A.; Jablonski, S.; Kaczmarczyk, J.; Kubkowska, M.] IFPiLM, PL-01497 Warsaw, Poland. [Estrada, T.] CIEMAT, Lab Nacl Fus, Madrid, Spain. [Kasparek, W.; Wolf, S.] Univ Stuttgart, IGVP, D-70569 Stuttgart, Germany. [Pablant, N.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Schmitz, O.] Univ Wisconsin, Dept Engn Phys, Madison, WI 53706 USA. [Schuhmacher, H.; Wiegel, B.] Phys Tech Bundesanstalt, D-38116 Braunschweig, Germany. RP Konig, R (reprint author), Max Planck Inst Plasma Phys, D-17491 Greifswald, Germany. EM rlk@ipp.mpg.de RI Estrada, Teresa/N-9048-2016; OI Estrada, Teresa/0000-0001-6205-2656; Biel, Wolfgang/0000-0001-6617-6533; Neubauer, Olaf/0000-0002-4516-4397; Kramer-Flecken, Andreas/0000-0003-4146-5085 NR 13 TC 2 Z9 2 U1 0 U2 17 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D818 DI 10.1063/1.4889905 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000072 PM 25430231 ER PT J AU Kraus, D Doppner, T Kritcher, AL Bachmann, B Chapman, DA Collins, GW Glenzer, SH Hawreliak, JA Landen, OL Ma, T Le Pape, S Neumayer, P Swift, DC Falcone, RW AF Kraus, D. Doeppner, T. Kritcher, A. L. Bachmann, B. Chapman, D. A. Collins, G. W. Glenzer, S. H. Hawreliak, J. A. Landen, O. L. Ma, T. Le Pape, S. Neumayer, P. Swift, D. C. Falcone, R. W. TI X-ray continuum emission spectroscopy from hot dense matter at Gbar pressures SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB We have measured the time-resolved x-ray continuum emission spectrum of similar to 30 times compressed polystyrene created at stagnation of spherically convergent shock waves within the Gbar fundamental science campaign at the National Ignition Facility. From an exponential emission slope between 7.7 keV and 8.1 keV photon energy and using an emission model which accounts for reabsorption, we infer an average electron temperature of 375 +/- 21 eV, which is in good agreement with HYDRA-1D simulations. (C) 2014 AIP Publishing LLC. C1 [Kraus, D.; Falcone, R. W.] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA. [Doeppner, T.; Kritcher, A. L.; Bachmann, B.; Collins, G. W.; Hawreliak, J. A.; Landen, O. L.; Ma, T.; Le Pape, S.; Swift, D. C.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Chapman, D. A.] AWE plc, Dept Radiat Phys, Plasma Phys Grp, Reading RG7 4PR, Berks, England. [Chapman, D. A.] Univ Warwick, Ctr Fus Space & Astrophys, Coventry CV4 7AL, W Midlands, England. [Glenzer, S. H.] SLAC Natl Accelerator Lab, Menlo Pk, CA 94309 USA. [Neumayer, P.] GSI Helmholtzzentrum Schwerionenforsch, D-64291 Darmstadt, Germany. RP Kraus, D (reprint author), Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA. EM dominik.kraus@berkeley.edu RI lepape, sebastien/J-3010-2015 FU Lawrence Livermore National Laboratory (LLNL) [DE-AC52-07NA27344]; Laboratory Directed Research and Development (LDRD) [11-ER-050, 13-ERD-073]; SSAA program [DE-FG52-06NA26212] FX This work was performed with the assistance of Lawrence Livermore National Laboratory (LLNL) under Contract No. DE-AC52-07NA27344 and supported by Laboratory Directed Research and Development (LDRD) grants 11-ER-050 and 13-ERD-073. R.W.F. and D.K. acknowledge support from SSAA program Contract No. DE-FG52-06NA26212. NR 7 TC 5 Z9 5 U1 2 U2 21 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D606 DI 10.1063/1.4890263 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000023 PM 25430182 ER PT J AU Lanier, NE Cowan, JS AF Lanier, N. E. Cowan, J. S. TI Absolute calibration of the Agfa Structurix series films at energies between 2.7 and 6.2 keV SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Although photo-emulsion technology is many decades old, x-ray film still remains a key asset for diagnosing hydrodynamic features in High-Energy Density (HED) experiments. For decades, the preferred option had been Kodak's direct exposure film. After its discontinuance in 2004, the push to find alternatives began. In many situations, the Agfa Structurix series offers the most favorable substitute, but being new to the HED community, its characterization was lacking. To remedy this, recent experiments, conducted at Brookhaven's National Synchrotron Light Source, provide absolute, monochromatic calibration data for the Agfa Structurix series films at K-shell backlighter energies between 2.7 and 6.2 keV. Absolute response curves are presented for Agfa D8, D7, D4, D4sc, D3, and D2. Moreover, the transmission of each film type is also measured. (C) 2014 AIP Publishing LLC. C1 [Lanier, N. E.; Cowan, J. S.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. RP Lanier, NE (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. EM nlanier@lanl.gov FU U.S. DOE [DE-AC52-06NA25396] FX The authors are grateful for the valuable support of Bin Dong, A. S. Moore, Ken Moy, and J. Fernandez. This work was conducted for the U.S. DOE Contract No. DE-AC52-06NA25396. NR 10 TC 2 Z9 2 U1 2 U2 5 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D632 DI 10.1063/1.4894838 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000049 PM 25430208 ER PT J AU Lasnier, CJ Allen, SL Ellis, RE Fenstermacher, ME McLean, AG Meyer, WH Morris, K Seppala, LG Crabtree, K Van Zeeland, MA AF Lasnier, C. J. Allen, S. L. Ellis, R. E. Fenstermacher, M. E. McLean, A. G. Meyer, W. H. Morris, K. Seppala, L. G. Crabtree, K. Van Zeeland, M. A. TI Wide-angle ITER-prototype tangential infrared and visible viewing system for DIII-D SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB An imaging system with a wide-angle tangential view of the full poloidal cross-section of the tokamak in simultaneous infrared and visible light has been installed on DIII-D. The optical train includes three polished stainless steel mirrors in vacuum, which view the tokamak through an aperture in the first mirror, similar to the design concept proposed for ITER. A dichroic beam splitter outside the vacuum separates visible and infrared (IR) light. Spatial calibration is accomplished by warping a CAD-rendered image to align with landmarks in a data image. The IR camera provides scrape-off layer heat flux profile deposition features in diverted and inner-wall-limited plasmas, such as heat flux reduction in pumped radiative divertor shots. Demonstration of the system to date includes observation of fast-ion losses to the outer wall during neutral beam injection, and shows reduced peak wall heat loading with disruption mitigation by injection of a massive gas puff. (C) 2014 AIP Publishing LLC. C1 [Lasnier, C. J.; Allen, S. L.; Ellis, R. E.; Fenstermacher, M. E.; McLean, A. G.; Meyer, W. H.; Morris, K.; Seppala, L. G.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. [Crabtree, K.] Univ Arizona, Coll Opt, Tucson, AZ 85721 USA. [Van Zeeland, M. A.] Gen Atom Co, San Diego, CA 92186 USA. RP Lasnier, CJ (reprint author), Lawrence Livermore Natl Lab, POB 808, Livermore, CA 94551 USA. EM lasnier@LLNL.gov FU US Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; US Department of Energy, Office of Science, Office of Fusion Energy Sciences [DE-FC02-04ER54698] FX This work was performed under the auspices of the US Department of Energy by Lawrence Livermore National Laboratory under Award No. DE-AC52-07NA27344. This material is based upon work supported by the US Department of Energy, Office of Science, Office of Fusion Energy Sciences, using the DIII-D National Fusion Facility, a DOE Office of Science user facility, under Award No. DE-FC02-04ER54698. DIII-D data shown in this paper can be obtained in digital format by following the links at https://fusion.gat.com/global/D3D_DMP. NR 4 TC 6 Z9 6 U1 1 U2 15 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D855 DI 10.1063/1.4892897 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000109 PM 25430268 ER PT J AU Lau, C Wilgen, JB Caughman, JB Hanson, GR Hosea, J Perkins, R Ryan, PM Taylor, G AF Lau, C. Wilgen, J. B. Caughman, J. B. Hanson, G. R. Hosea, J. Perkins, R. Ryan, P. M. Taylor, G. TI Using X-mode L, R and O-mode reflectometry cutoffs to measure scrape-off-layer density profiles for upgraded ORNL reflectometer on NSTX-U SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID FUSION PLASMAS; WAVES AB The pre-existing ORNL scrape-off-layer (SOL) reflectometer that operated with the X-mode R-cutoff at 6-27 GHz to measure SOL density profiles on NSTX is being upgraded to be functional at the increased magnetic fields on NSTX-U spherical tokamak. Rather than increasing the operating frequencies to measure the higher X-mode R-cutoff frequencies on NSTX-U, it will be shown that the combined use of the X-mode R, L and O-mode cutoffs at 6-27 GHz can obtain the desired SOL density profiles. The potential capabilities and obstacles of this technique to measure SOL density profiles and possibly SOL magnetic field profiles on NSTX-U will be discussed. (C) 2014 AIP Publishing LLC. C1 [Lau, C.; Wilgen, J. B.; Caughman, J. B.; Hanson, G. R.; Ryan, P. M.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. [Hosea, J.; Perkins, R.; Taylor, G.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Lau, C (reprint author), Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. EM lauch@ornl.gov RI Caughman, John/R-4889-2016 OI Caughman, John/0000-0002-0609-1164 FU U.S. Department of Energy [DE-AC05-00OR22725]; Princeton Plasma Physics Laboratory under DOE [DE-AC02-09CH11466]; U.S. Government [DE-AC05-00OR22725] FX This work was supported at Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. Department of Energy under Contract No. DE-AC05-00OR22725, and at the Princeton Plasma Physics Laboratory under DOE Contract No. DE-AC02-09CH11466. The submitted manuscript has been authored by a contractor of the U.S. Government under Contract No. DE-AC05-00OR22725. NR 14 TC 0 Z9 0 U1 1 U2 11 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D815 DI 10.1063/1.4889739 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000069 PM 25430228 ER PT J AU Liu, D Heidbrink, WW Tritz, K Zhu, YB Roquemore, AL Medley, SS AF Liu, D. Heidbrink, W. W. Tritz, K. Zhu, Y. B. Roquemore, A. L. Medley, S. S. TI Design of solid state neutral particle analyzer array for National Spherical Torus Experiment-Upgrade SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID NATURAL DIAMOND DETECTOR AB A new compact, multi-channel Solid State Neutral Particle Analyzer (SSNPA) diagnostic based on silicon photodiode array has been designed and is being fabricated for the National Spherical Torus Experiment-Upgrade (NSTX-U). The SSNPA system utilizes a set of vertically stacked photodiode arrays in current mode viewing the same plasma region with different filter thickness to obtain fast temporal resolution (similar to 120 kHz bandwidth) and coarse energy information in three bands of >25 keV, >45 keV, and >65 keV. The SSNPA system consists of 15 radial sightlines that intersect existing on-axis neutral beams at major radii between 90 and 130 cm, 15 tangential sightlines that intersect new off-axis neutral beams at major radii between 120 and 145 cm. These two subsystems aim at separating the response of passing and trapped fast ions. In addition, one photodiode array whose viewing area does not intersect any neutral beams is used to monitor passive signals produced by fast ions that charge exchange with background neutrals. (C) 2014 AIP Publishing LLC. C1 [Liu, D.; Heidbrink, W. W.; Zhu, Y. B.] Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA. [Tritz, K.] Johns Hopkins Univ, Dept Phys & Astron, Baltimore, MD 21218 USA. [Roquemore, A. L.; Medley, S. S.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Liu, D (reprint author), Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA. EM deyongl@uci.edu RI Liu, Deyong/Q-2797-2015 OI Liu, Deyong/0000-0001-9174-7078 FU U.S. DOE [DE-AC02-09CH11466, DE-FG02-06ER54867, DE-FG03-02ER54681] FX The authors would like to thank A. Bortolon, D. S. Darrow, V. A. Soukhanovskii, and M. Podesta for helpful discussions and T. Kozub, L. Morris, and S. Z. Jurczynski for technical support. This work is supported by U.S. DOE under Grant Nos. DE-AC02-09CH11466, DE-FG02-06ER54867, and DE-FG03-02ER54681. NR 21 TC 0 Z9 0 U1 1 U2 8 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E105 DI 10.1063/1.4889913 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000125 PM 25430284 ER PT J AU Liu, JX Milbourne, T Bitter, M Delgado-Aparicio, L Dominguez, A Efthimion, PC Hill, KW Kramer, GJ Kung, C Kubota, S Kasparek, W Lu, J Pablant, NA Park, H Tobias, B AF Liu, J. X. Milbourne, T. Bitter, M. Delgado-Aparicio, L. Dominguez, A. Efthimion, P. C. Hill, K. W. Kramer, G. J. Kung, C. Kubota, S. Kasparek, W. Lu, J. Pablant, N. A. Park, H. Tobias, B. TI Alternative optical concept for electron cyclotron emission imaging SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB The implementation of advanced electron cyclotron emission imaging (ECEI) systems on tokamak experiments has revolutionized the diagnosis of magnetohydrodynamic (MHD) activities and improved our understanding of instabilities, which lead to disruptions. It is therefore desirable to have an ECEI system on the ITER tokamak. However, the large size of optical components in presently used ECEI systems have, up to now, precluded the implementation of an ECEI system on ITER. This paper describes a new optical ECEI concept that employs a single spherical mirror as the only optical component and exploits the astigmatism of such a mirror to produce an image with one-dimensional spatial resolution on the detector. Since this alternative approach would only require a thin slit as the viewing port to the plasma, it would make the implementation of an ECEI system on ITER feasible. The results obtained from proof-of-principle experiments with a 125 GHz microwave system are presented. (C) 2014 AIP Publishing LLC. C1 [Liu, J. X.] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA. [Milbourne, T.] Coll William & Mary, Dept Phys, Williamsburg, VA 23185 USA. [Bitter, M.; Delgado-Aparicio, L.; Dominguez, A.; Efthimion, P. C.; Hill, K. W.; Kramer, G. J.; Kung, C.; Pablant, N. A.; Tobias, B.] Princeton Plasma Phys Lab, Princeton, NJ 08540 USA. [Kubota, S.] Univ Calif Los Angeles, Dept Phys, Los Angeles, CA 90095 USA. [Kasparek, W.] Univ Stuttgart, Dept Elect Engn, D-70174 Stuttgart, Germany. [Lu, J.] Chongqing Univ, Dept Phys, Chongqing 400044, Peoples R China. [Park, H.] Ulsan Natl Inst Sci & Technol, Ulsan 689798, South Korea. RP Liu, JX (reprint author), Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA. EM jsliu9@berkeley.edu FU US Department of Energy [DE-AC02-09CH-11466]; Korean NRF [20120005920] FX We gratefully acknowledge the support of this work by the US Department of Energy Contract No. DE-AC02-09CH-11466 and Korean NRF Contract No. 20120005920. NR 13 TC 1 Z9 1 U1 0 U2 10 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D802 DI 10.1063/1.4884902 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000056 PM 25430215 ER PT J AU Lu, J Bitter, M Hill, KW Delgado-Aparicio, LF Efthimion, PC Pablant, NA Beiersdorfer, P Caughey, TA Brunner, J AF Lu, J. Bitter, M. Hill, K. W. Delgado-Aparicio, L. F. Efthimion, P. C. Pablant, N. A. Beiersdorfer, P. Caughey, T. A. Brunner, J. TI X-ray tests of a two-dimensional stigmatic imaging scheme with variable magnifications SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID SPHERICAL CRYSTAL; BENT CRYSTALS; PLASMA; MICROSCOPE AB A two-dimensional stigmatic x-ray imaging scheme, consisting of two spherically bent crystals, one concave and one convex, was recently proposed [M. Bitter et al., Rev. Sci. Instrum. 83, 10E527 (2012)]. The Bragg angles and the radii of curvature of the two crystals of this imaging scheme are matched to eliminate the astigmatism and to satisfy the Bragg condition across both crystal surfaces for a given x-ray energy. In this paper, we consider more general configurations of this imaging scheme, which allow us to vary the magnification for a given pair of crystals and x-ray energy. The stigmatic imaging scheme has been validated for the first time by imaging x-rays generated by a micro-focus x-ray source with source size of 8.4 mu m validated by knife-edge measurements. Results are presented from imaging the tungsten L alpha 1 emission at 8.3976 keV, using a convex Si-422 crystal and a concave Si-533 crystal with 2d-spacings of 2.21707 angstrom and 1.65635 angstrom and radii of curvature of 500 +/- 1 mm and 823 +/- 1 mm, respectively, showing a spatial resolution of 54.9 mu m. This imaging scheme is expected to be of interest for the two-dimensional imaging of laser produced plasmas. (C) 2014 AIP Publishing LLC. C1 [Lu, J.] Chongqing Univ, Minist Educ, Key Lab Optoelect Technol & Syst, Chongqing 400030, Peoples R China. [Bitter, M.; Hill, K. W.; Delgado-Aparicio, L. F.; Efthimion, P. C.; Pablant, N. A.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Beiersdorfer, P.] Lawrence Livermore Natl Lab, Dept Phys, Livermore, CA 94550 USA. [Caughey, T. A.; Brunner, J.] Inrad Opt, Northvale, NJ 07647 USA. RP Lu, J (reprint author), Chongqing Univ, Minist Educ, Key Lab Optoelect Technol & Syst, Chongqing 400030, Peoples R China. EM jlu@pppl.gov FU (U.S.) Department of Energy (DOE) by Princeton Plasma Physics Laboratory (PPPL) [DE-AC02-09CH-11466]; (U.S.) Department of Energy (DOE) by Lawrence Livermore National Laboratory (LLNL) [DE-AC52-07NA-27344] FX This work was performed under the auspices of the (U.S.) Department of Energy (DOE) by Princeton Plasma Physics Laboratory (PPPL) under Contract No. DE-AC02-09CH-11466 and Lawrence Livermore National Laboratory (LLNL) under Contract No. DE-AC52-07NA-27344. NR 16 TC 2 Z9 2 U1 1 U2 10 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D604 DI 10.1063/1.4890248 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000021 PM 25430180 ER PT J AU Lucia, M Kaita, R Majeski, R Bedoya, F Allain, JP Boyle, DP Schmitt, JC St Onge, DA AF Lucia, M. Kaita, R. Majeski, R. Bedoya, F. Allain, J. P. Boyle, D. P. Schmitt, J. C. St Onge, D. A. TI Development progress of the Materials Analysis and Particle Probe SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB The Materials Analysis and Particle Probe (MAPP) is a compact in vacuo surface science diagnostic, designed to provide in situ surface characterization of plasma facing components in a tokamak environment. MAPP has been implemented for operation on the Lithium Tokamak Experiment at Princeton Plasma Physics Laboratory (PPPL), where all control and analysis systems are currently under development for full remote operation. Control systems include vacuum management, instrument power, and translational/rotational probe drive. Analysis systems include onboard Langmuir probes and all components required for x-ray photoelectron spectroscopy, low-energy ion scattering spectroscopy, direct recoil spectroscopy, and thermal desorption spectroscopy surface analysis techniques. (C) 2014 AIP Publishing LLC. C1 [Lucia, M.; Kaita, R.; Majeski, R.; Boyle, D. P.; Schmitt, J. C.; St Onge, D. A.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Bedoya, F.; Allain, J. P.] Univ Illinois, Dept Nucl Plasma & Radiol Engn, Urbana, IL 61801 USA. RP Lucia, M (reprint author), Princeton Plasma Phys Lab, POB 451, Princeton, NJ 08543 USA. EM mlucia@pppl.gov OI Allain, Jean Paul/0000-0003-1348-262X; Boyle, Dennis/0000-0001-8091-8169 FU U.S. DOE [DE-AC02-09CH11466, DE-AC52-07NA27344, DE-SC0010717]; NSF [DGE-0646086] FX This work is supported by U.S. DOE Contract Nos. DE-AC02-09CH11466, DE-AC52-07NA27344, and DE-SC0010717. This material is based upon work supported by the NSF Graduate Research Fellowship under Grant No. DGE-0646086. NR 9 TC 3 Z9 3 U1 0 U2 6 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D835 DI 10.1063/1.4890257 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000089 PM 25430248 ER PT J AU Lyu, B Wang, FD Pan, XY Chen, J Fu, J Li, YY Bitter, M Hill, KW Delgado-Aparicio, LF Pablant, N Lee, SG Shi, YJ Ye, MY Wan, BN AF Lyu, B. Wang, F. D. Pan, X. Y. Chen, J. Fu, J. Li, Y. Y. Bitter, M. Hill, K. W. Delgado-Aparicio, L. F. Pablant, N. Lee, S. G. Shi, Y. J. Ye, M. Y. Wan, B. N. TI Upgrades of imaging x-ray crystal spectrometers for high-resolution and high-temperature plasma diagnostics on EAST SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Upgrade of the imaging X-ray crystal spectrometers continues in order to fulfill the high-performance diagnostics requirements on EAST. For the tangential spectrometer, a new large pixelated two-dimensional detector was deployed on tokamaks for time-resolved X-ray imaging. This vacuum-compatible detector has an area of 83.8 x 325.3 mm(2), a framing rate over 150 Hz, and water-cooling capability for long-pulse discharges. To effectively extend the temperature limit, a double-crystal assembly was designed to replace the previous single crystals for He-like argon line measurement. The tangential spectrometer employed two crystal slices attached to a common substrate and part of He-and H-like Ar spectra could be recorded on the same detector when crystals were chosen to have similar Bragg angles. This setup cannot only extend the measurable Te up to 10 keV in the core region, but also extend the spatial coverage since He-like argon ions will be present in the outer plasma region. Similarly, crystal slices for He-like iron and argon spectra were adopted on the poloidal spectrometer. Wavelength calibration for absolute rotation velocity measurement will be studied using cadmium characteristic L-shell X-ray lines excited by plasma radiation. A Cd foil is placed before the crystal and can be inserted and retracted for in situ wavelength calibration. The Geant4 code was used to estimate X-ray fluorescence yield and optimize the thickness of the foil. (C) 2014 AIP Publishing LLC. C1 [Lyu, B.; Wang, F. D.; Pan, X. Y.; Chen, J.; Fu, J.; Li, Y. Y.; Wan, B. N.] Chinese Acad Sci, Inst Plasma Phys, Hefei 230031, Anhui, Peoples R China. [Pan, X. Y.; Chen, J.; Shi, Y. J.; Ye, M. Y.; Wan, B. N.] Univ Sci & Technol China, Sch Nucl Sci & Technol, Hefei 230026, Anhui, Peoples R China. [Bitter, M.; Hill, K. W.; Delgado-Aparicio, L. F.; Pablant, N.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Lee, S. G.] Natl Fus Res Inst, Taejon 305333, South Korea. [Shi, Y. J.] Natl Fus Res Inst, WCI Fus Theory, Taejon 305333, South Korea. RP Lyu, B (reprint author), Chinese Acad Sci, Inst Plasma Phys, Hefei 230031, Anhui, Peoples R China. EM blu@ipp.ac.cn FU National Magnetic Confinement Fusion Science Program of China [2011GB101004, 2013GB112004]; Natural Science Foundation of China [11175208, 11305212]; JSPS-NRF-NSFC [11261140328] FX This work was supported by National Magnetic Confinement Fusion Science Program of China (2011GB101004 and 2013GB112004), Natural Science Foundation of China (11175208 and 11305212), and JSPS-NRF-NSFC A3 Foresight Program in the field of Plasma Physics (11261140328). NR 9 TC 10 Z9 10 U1 3 U2 22 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E406 DI 10.1063/1.4886387 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000154 PM 25430313 ER PT J AU MacDonald, MJ Keiter, PA Montgomery, DS Biener, MM Fein, JR Fournier, KB Gamboa, EJ Klein, SR Kuranz, CC LeFevre, HJ Manuel, MJE Streit, J Wan, WC Drake, RP AF MacDonald, M. J. Keiter, P. A. Montgomery, D. S. Biener, M. M. Fein, J. R. Fournier, K. B. Gamboa, E. J. Klein, S. R. Kuranz, C. C. LeFevre, H. J. Manuel, M. J. -E. Streit, J. Wan, W. C. Drake, R. P. TI Demonstration of x-ray fluorescence imaging of a high-energy-density plasma SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID FACILITY AB Experiments at the Trident Laser Facility have successfully demonstrated the use of x-ray fluorescence imaging (XRFI) to diagnose shocked carbonized resorcinol formaldehyde (CRF) foams doped with Ti. One laser beam created a shock wave in the doped foam. A second laser beam produced a flux of vanadium He-alpha x-rays, which in turn induced Ti K-shell fluorescence within the foam. Spectrally resolved 1D imaging of the x-ray fluorescence provided shock location and compression measurements. Additionally, experiments using a collimator demonstrated that one can probe specific regions within a target. These results show that XRFI is a capable alternative to path-integrated measurements for diagnosing hydrodynamic experiments at high energy density. (C) 2014 AIP Publishing LLC. C1 [MacDonald, M. J.; Keiter, P. A.; Fein, J. R.; Gamboa, E. J.; Klein, S. R.; Kuranz, C. C.; LeFevre, H. J.; Manuel, M. J. -E.; Wan, W. C.; Drake, R. P.] Univ Michigan, Dept Atmospher Ocean & Space Sci, Ann Arbor, MI 48109 USA. [MacDonald, M. J.; Gamboa, E. J.] SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA. [Montgomery, D. S.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Biener, M. M.; Fournier, K. B.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Streit, J.] Schafer Corp, Livermore, CA 94551 USA. RP MacDonald, MJ (reprint author), Univ Michigan, Dept Atmospher Ocean & Space Sci, Ann Arbor, MI 48109 USA. EM macdonm@umich.edu RI Manuel, Mario/L-3213-2015; Drake, R Paul/I-9218-2012; OI Manuel, Mario/0000-0002-5834-1161; Drake, R Paul/0000-0002-5450-9844; MacDonald, Michael/0000-0002-6295-6978 FU NNSA-DS [DE-NA0001840]; SC-OFES Joint Program in High-Energy-Density Laboratory Plasmas [DE-NA0001840]; DTRA [DTRA-1-10-0077]; National Science Foundation Graduate Research Fellowship Program [2013155705] FX The authors would like to thank the laser operations staff at the Trident Laser Facility for a successful experimental campaign and Robb Gillespie for machining the targets used in the experiments. This work is funded by the NNSA-DS and SC-OFES Joint Program in High-Energy-Density Laboratory Plasmas, Grant No. DE-NA0001840, and by DTRA, Grant No. DTRA-1-10-0077. This material is based upon work supported by the National Science Foundation Graduate Research Fellowship Program under Grant No. 2013155705. NR 8 TC 3 Z9 3 U1 3 U2 10 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E602 DI 10.1063/1.4886388 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000189 PM 25430348 ER PT J AU Macrander, AT Matey, JR AF Macrander, A. T. Matey, J. R. TI A Change in Editorial Policy: Contributed Reviews SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA C1 [Macrander, A. T.; Matey, J. R.] Argonne Natl Lab, APS XFD, Argonne, IL 60439 USA. RP Macrander, AT (reprint author), Argonne Natl Lab, APS XFD, 9700 S Cass Ave,Bldg 432, Argonne, IL 60439 USA. NR 0 TC 0 Z9 0 U1 0 U2 3 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 110401 DI 10.1063/1.4901097 PG 2 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000237 PM 25430088 ER PT J AU Magee, EW Beiersdorfer, P Brown, GV Hell, N AF Magee, E. W. Beiersdorfer, P. Brown, G. V. Hell, N. TI Rare-earth neutral metal injection into an electron beam ion trap plasma SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID EBIT DATA; SPECTROSCOPY AB We have designed and implemented a neutral metal vapor injector on the SuperEBIT high-energy electron beam ion trap at the Lawrence Livermore National Laboratory. A horizontally directed vapor of a europium metal is created using a thermal evaporation technique. The metal vapor is then spatially collimated prior to injection into the trap. The source's form and quantity constraints are significantly reduced making plasmas out of metal with vapor pressures <= 10(-7) Torr at >= 1000 degrees C more obtainable. A long pulsed or constant feed metal vapor injection method adds new flexibility by varying the timing of injection and rate of material being introduced into the trap. (C) 2014 AIP Publishing LLC. C1 [Magee, E. W.; Beiersdorfer, P.; Brown, G. V.; Hell, N.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Hell, N.] Univ Erlangen Nurnberg, Dr Remeis Sternwarte, D-96049 Bamberg, Germany. [Hell, N.] Univ Erlangen Nurnberg, ECAP, D-96049 Bamberg, Germany. RP Magee, EW (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. EM magee1@llnl.gov FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; Bundesministerium fur Wirtschaft und Technologie under DLR [50 OR 1113] FX This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344.; N.H. received additional support from the Bundesministerium fur Wirtschaft und Technologie under DLR grant 50 OR 1113. NR 15 TC 2 Z9 2 U1 0 U2 4 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E820 DI 10.1063/1.4892899 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000226 PM 25430385 ER PT J AU Marrs, RE Brown, GV Emig, JA Heeter, RF AF Marrs, R. E. Brown, G. V. Emig, J. A. Heeter, R. F. TI System for calibrating the energy-dependent response of an elliptical Bragg-crystal spectrometer SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID FRAMING CAMERAS; RAY AB A multipurpose spectrometer (MSPEC) with elliptical crystals is in routine use to obtain x-ray spectra from laser produced plasmas in the energy range 1.0-9.0 keV. Knowledge of the energy-dependent response of the spectrometer is required for an accurate comparison of the intensities of x-ray lines of different energy. The energy-dependent response of the MSPEC has now been derived from the spectrometer geometry and calibration information on the response of its components, including two different types of detectors. Measurements of the spectrometer response with a laboratory x-ray source are used to test the calculated response and provide information on crystal reflectivity and uniformity. (C) 2014 AIP Publishing LLC. C1 [Marrs, R. E.; Brown, G. V.; Emig, J. A.; Heeter, R. F.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. RP Heeter, RF (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. EM heeter1@llnl.gov FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. NR 17 TC 4 Z9 4 U1 0 U2 5 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D626 DI 10.1063/1.4892552 PG 5 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000043 PM 25430202 ER PT J AU Masters, ND Fisher, A Kalantar, D Prasad, R Stolken, JS Wlodarczyk, C AF Masters, N. D. Fisher, A. Kalantar, D. Prasad, R. Stoelken, J. S. Wlodarczyk, C. TI Evaluation of observed blast loading effects on NIF x-ray diagnostic collimators SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB We present the "debris wind" models used to estimate the impulsive load to which x-ray diagnostics and other structures are subject during National Ignition Facility experiments. These models are used as part of the engineering design process. Isotropic models, based on simulations or simplified "expanding shell" models, are augmented by debris wind multipliers to account for directional anisotropy. We present improvements to these multipliers based on measurements of the permanent deflections of diagnostic components: 4x for the polar direction and 2x within the equatorial plane-the latter relaxing the previous heuristic debris wind multiplier. (C) 2014 AIP Publishing LLC. C1 [Masters, N. D.; Fisher, A.; Kalantar, D.; Prasad, R.; Stoelken, J. S.; Wlodarczyk, C.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. RP Masters, ND (reprint author), Lawrence Livermore Natl Lab, 7000 East Ave,POB 808,L-422, Livermore, CA 94550 USA. EM masters6@llnl.gov FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. NR 5 TC 1 Z9 1 U1 0 U2 4 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D628 DI 10.1063/1.4894828 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000045 PM 25430204 ER PT J AU McLean, AG Soukhanovskii, VA Allen, SL Carlstrom, TN LeBlanc, BP Ono, M Stratton, BC AF McLean, A. G. Soukhanovskii, V. A. Allen, S. L. Carlstrom, T. N. LeBlanc, B. P. Ono, M. Stratton, B. C. TI Conceptual design of a divertor Thomson scattering diagnostic for NSTX-U SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID DIII-D; OPERATION; SYSTEM; ASDEX AB A conceptual design for a divertor Thomson scattering (DTS) diagnostic has been developed for the NSTX-U device to operate in parallel with the existing multipoint Thomson scattering system. Higher projected peak heat flux in NSTX-U will necessitate application of advanced magnetics geometries and divertor detachment. Interpretation and modeling of these divertor scenarios will depend heavily on local measurement of electron temperature, T-e, and density, n(e), which DTS provides in a passive manner. The DTS design for NSTX-U adopts major elements from the successful DIII-D DTS system including 7-channel polychromators measuring T-e to 0.5 eV. If implemented on NSTX-U, the divertor TS system would provide an invaluable diagnostic for the boundary program to characterize the edge plasma. (C) 2014 AIP Publishing LLC. C1 [McLean, A. G.; Soukhanovskii, V. A.; Allen, S. L.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Carlstrom, T. N.] Gen Atom Co, San Diego, CA 92186 USA. [LeBlanc, B. P.; Ono, M.; Stratton, B. C.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP McLean, AG (reprint author), Lawrence Livermore Natl Lab, POB 808, Livermore, CA 94550 USA. EM mclean@fusion.gat.com FU U.S. Department of Energy (US DOE) by LLNL [DE-AC52-07N27344]; US DOE [DE-AC02-09CH11466, DE-FC02-04ER54698] FX This work was supported in part under the auspices of the U.S. Department of Energy (US DOE) by LLNL under DE-AC52-07N27344 and by the US DOE under DE-AC02-09CH11466, and DE-FC02-04ER54698. NR 24 TC 2 Z9 2 U1 0 U2 5 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E825 DI 10.1063/1.4894001 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000231 PM 25430390 ER PT J AU Menmuir, S Giroud, C Biewer, TM Coffey, IH Delabie, E Hawkes, NC Sertoli, M AF Menmuir, S. Giroud, C. Biewer, T. M. Coffey, I. H. Delabie, E. Hawkes, N. C. Sertoli, M. CA JET EFDA Contributors TI Carbon charge exchange analysis in the ITER-like wall environment SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Charge exchange spectroscopy has long been a key diagnostic tool for fusion plasmas and is well developed in devices with Carbon Plasma-Facing Components. Operation with the ITER-like wall at JET has resulted in changes to the spectrum in the region of the Carbon charge exchange line at 529.06 nm and demonstrates the need to revise the core charge exchange analysis for this line. An investigation has been made of this spectral region in different plasma conditions and the revised description of the spectral lines to be included in the analysis is presented. C1 Culham Sci Ctr, JET EFDA, Abingdon OX14 3DB, Oxon, England. [Menmuir, S.] KTH Royal Inst Technol, Dept Fus Plasma Phys, Assoc EURATOM VR, Stockholm, Sweden. [Giroud, C.; Hawkes, N. C.] Culham Sci Ctr, CCFE, Abingdon OX14 3DB, Oxon, England. [Biewer, T. M.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. [Coffey, I. H.] Queens Univ Belfast, Astrophys Res Ctr, Belfast BT7 1NN, Antrim, North Ireland. [Delabie, E.] EURATOM, Nieuwegein, Netherlands. [Sertoli, M.] Max Planck Inst Plasma Phys, EURATOM Assoc, D-85748 Garching, Germany. RP Menmuir, S (reprint author), KTH Royal Inst Technol, Dept Fus Plasma Phys, Assoc EURATOM VR, Stockholm, Sweden. EM Sheena.Menmuir@jet.efda.org FU EURATOM FX This work was supported by EURATOM and carried out within the framework of the European Fusion Development Agreement. The views and opinions expressed herein do not necessarily reflect those of the European Commission. NR 11 TC 2 Z9 2 U1 2 U2 9 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E412 DI 10.1063/1.4890118 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000160 PM 25430319 ER PT J AU Merrill, FE Danly, CR Izumi, N Jedlovec, D Fittinghoff, DN Grim, GP Pak, A Park, HS Volegov, PL Wilde, CH AF Merrill, F. E. Danly, C. R. Izumi, N. Jedlovec, D. Fittinghoff, D. N. Grim, G. P. Pak, A. Park, H. -S. Volegov, P. L. Wilde, C. H. TI A concept to collect neutron and x-ray images on the same line of sight at NIF SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Neutron and x-ray images are collected at the National Ignition Facility (NIF) to measure the size and shape of inertial confinement fusion implosions. The x-ray images provide a measure of the size and shape of the hot region of the deuterium-tritium fuel while the neutron images provide a measure of the size and shape of the burning plasma. Although these two types of images are collected simultaneously, they are not collected along the same line of sight (LOS). One 14 MeV neutron image is collected on the NIF equator, and two x-ray images are collected along the polar axis and nearly perpendicular to the neutron imaging line of sight on the equator. Both measurements use pinhole apertures to form the images, but existing x-ray imaging provides time-resolved measurements while the neutron images are time-integrated. Detailed comparisons of the x-ray and neutron images can provide information on the fuel assembly, but these studies have been limited because the implosions are not azimuthally symmetric and the images are collected along different LOS. We have developed a conceptual design of a time-integrated x-ray imaging system that could be added to the existing neutron imaging LOS. This new system would allow these detailed studies, providing important information on the fuel assembly of future implosions. Here we present this conceptual design and the expected performance characteristics. (C) 2014 AIP Publishing LLC. C1 [Merrill, F. E.; Danly, C. R.; Grim, G. P.; Volegov, P. L.; Wilde, C. H.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Izumi, N.; Jedlovec, D.; Fittinghoff, D. N.; Pak, A.; Park, H. -S.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. RP Merrill, FE (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. EM fmerrill@lanl.gov RI IZUMI, Nobuhiko/J-8487-2016 OI IZUMI, Nobuhiko/0000-0003-1114-597X NR 14 TC 3 Z9 3 U1 0 U2 9 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E614 DI 10.1063/1.4891101 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000201 PM 25430360 ER PT J AU Moody, JD Clancy, TJ Frieders, G Celliers, PM Ralph, J Turnbull, DP AF Moody, J. D. Clancy, T. J. Frieders, G. Celliers, P. M. Ralph, J. Turnbull, D. P. TI Hohlraum glint and laser pre-pulse detector for NIF experiments using velocity interferometer system for any reflector SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID INERTIAL CONFINEMENT FUSION; NATIONAL-IGNITION-FACILITY; PHYSICS BASIS; DRIVE; PERFORMANCE AB Laser pre-pulse and early-time laser reflection from the hohlraum wall onto the capsule (termed "glint") can cause capsule imprint and unwanted early-time shocks on indirect drive implosion experiments. In a minor modification to the existing velocity interferometer system for any reflector diagnostic on NIF a fast-response vacuum photodiode was added to detect this light. The measurements show evidence of laser pre-pulse and possible light reflection off the hohlraum wall and onto the capsule. (C) 2014 AIP Publishing LLC. C1 [Moody, J. D.; Clancy, T. J.; Frieders, G.; Celliers, P. M.; Ralph, J.; Turnbull, D. P.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. RP Moody, JD (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. EM moody4@llnl.gov FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. NR 9 TC 0 Z9 1 U1 1 U2 7 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E608 DI 10.1063/1.4887155 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000195 PM 25430354 ER PT J AU Mueller, D Roquemore, AL Jaworski, M Skinner, CH Miller, J Creely, A Raman, P Ruzic, D AF Mueller, D. Roquemore, A. L. Jaworski, M. Skinner, C. H. Miller, J. Creely, A. Raman, P. Ruzic, D. TI In situ measurement of low-Z material coating thickness on high Z substrate for tokamaks SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Rutherford backscattering of energetic particles can be used to determine the thickness of a coating of a low-Z material over a heavier substrate. Simulations indicate that 5 MeV alpha particles from an Am-241 source can be used to measure the thickness of a Li coating on Mo tiles between 0.5 and 15 mu m thick. Using a 0.1 mCi source, a thickness measurement can be accomplished in 2 h of counting. This technique could be used to measure any thin, low-Z material coating (up to 1 mg/cm(2) thick) on a high-Z substrate, such as Be on W, B on Mo, or Li on Mo. By inserting a source and detector on a moveable probe, this technique could be used to provide an in situ measurement of the thickness of Li coating on NSTX-U Mo tiles. A test stand with an alpha source and an annular solid-state detector was used to investigate the measurable range of low-Z material thicknesses on Mo tiles. (C) 2014 AIP Publishing LLC. C1 [Mueller, D.; Roquemore, A. L.; Jaworski, M.; Skinner, C. H.; Miller, J.; Creely, A.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Raman, P.; Ruzic, D.] Univ Illinois, Ctr Plasma Mat Interact, Dept Nucl Plasma & Radiol Engn, Urbana, IL 61801 USA. RP Mueller, D (reprint author), Princeton Plasma Phys Lab, POB 451, Princeton, NJ 08543 USA. EM dmueller@pppl.gov FU U.S.D.O.E. [DE-AC02-09CH11466] FX This work was supported by U.S.D.O.E. under Contract No. DE-AC02-09CH11466. NR 8 TC 1 Z9 1 U1 0 U2 8 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E821 DI 10.1063/1.4893425 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000227 PM 25430386 ER PT J AU Muscatello, CM Domier, CW Hu, X Kramer, GJ Luhmann, NC Ren, X Riemenschneider, P Spear, A Tobias, BJ Valeo, E Yu, L AF Muscatello, C. M. Domier, C. W. Hu, X. Kramer, G. J. Luhmann, N. C., Jr. Ren, X. Riemenschneider, P. Spear, A. Tobias, B. J. Valeo, E. Yu, L. TI Technical overview of the millimeter-wave imaging reflectometer on the DIII-D tokamak SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID FLUCTUATION MEASUREMENTS; MICROWAVE REFLECTOMETRY; TURBULENT FLUCTUATIONS; PLASMAS AB The two-dimensional mm-wave imaging reflectometer (MIR) on DIII-D is a multi-faceted device for diagnosing electron density fluctuations in fusion plasmas. Its multi-channel, multi-frequency capabilities and high sensitivity permit visualization and quantitative diagnosis of density perturbations, including correlation length, wavenumber, mode propagation velocity, and dispersion. The two-dimensional capabilities of MIR are made possible with 12 vertically separated sightlines and four-frequency operation (corresponding to four radial channels). The 48-channel DIII-D MIR system has a tunable source that can be stepped in 500 mu s increments over a range of 56 to 74 GHz. An innovative optical design keeps both on-axis and off-axis channels focused at the cutoff surface, permitting imaging over an extended poloidal region. The integrity of the MIR optical design is confirmed by comparing Gaussian beam calculations to laboratory measurements of the transmitter beam pattern and receiver antenna patterns. Measurements are presented during the density ramp of a plasma discharge to demonstrate unfocused and focused MIR signals. (C) 2014 AIP Publishing LLC. C1 [Muscatello, C. M.; Domier, C. W.; Hu, X.; Luhmann, N. C., Jr.; Ren, X.; Riemenschneider, P.; Spear, A.; Valeo, E.; Yu, L.] Univ Calif Davis, Dept Elect & Comp Engn, Davis, CA 95616 USA. [Kramer, G. J.; Tobias, B. J.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Muscatello, CM (reprint author), Univ Calif Davis, Dept Elect & Comp Engn, 347 Mem Un, Davis, CA 95616 USA. EM cmuscate@ucdavis.edu FU US Department of Energy [DE-FG-02-99ER54531, DE-AC02-09CH11466, DE-FC02-04ER54698] FX This work is supported by US Department of Energy under DE-FG-02-99ER54531, DE-AC02-09CH11466, and DE-FC02-04ER54698. We extend a special appreciation to M. Banducci for his involvement with a number of hardware aspects of the MIR instrument. We are grateful for the tireless efforts of the DIII-D team, particularly R. Boivin and J. Kulchar, who made special accommodations and sacrifices for the installation of MIR. We also thank M. Kriete who assisted with the installation of MIR at DIII-D as a National Undergraduate Fellow of the DOE OFES. The data shown in this paper can be obtained in digital format by following the links at https://fusion.gat.com/global/D3D_DMP. NR 12 TC 12 Z9 12 U1 2 U2 15 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D702 DI 10.1063/1.4889735 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000053 PM 25430212 ER PT J AU Nagayama, T Bailey, JE Loisel, G Rochau, GA Falcon, RE AF Nagayama, T. Bailey, J. E. Loisel, G. Rochau, G. A. Falcon, R. E. TI Parallax diagnostics of radiation source geometric dilution for iron opacity experiments SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Experimental tests are in progress to evaluate the accuracy of the modeled iron opacity at solar interior conditions [J. E. Bailey et al., Phys. Plasmas 16, 058101 (2009)]. The iron sample is placed on top of the Sandia National Laboratories z-pinch dynamic hohlraum (ZPDH) radiation source. The samples are heated to 150-200 eV electron temperatures and 7x 10(21)-4x 10(22) cm(-3) electron densities by the ZPDH radiation and backlit at its stagnation [T. Nagayama et al., Phys. Plasmas 21, 056502 (2014)]. The backlighter attenuated by the heated sample plasma is measured by four spectrometers along +/- 9 degrees with respect to the z-pinch axis to infer the sample iron opacity. Here, we describe measurements of the source-to-sample distance that exploit the parallax of spectrometers that view the half-moon-shaped sample from +/- 9 degrees. The measured sample temperature decreases with increased source-to-sample distance. This distance must be taken into account for understanding the sample heating. (C) 2014 AIP Publishing LLC. C1 [Nagayama, T.; Bailey, J. E.; Loisel, G.; Rochau, G. A.; Falcon, R. E.] Sandia Natl Labs, Albuquerque, NM 87185 USA. RP Nagayama, T (reprint author), Sandia Natl Labs, POB 5800, Albuquerque, NM 87185 USA. FU (U.S.) Department of Energy (DOE) [DE-AC04-94AL85000] FX Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the (U.S.) Department of Energy (DOE) under Contract No. DE-AC04-94AL85000. NR 9 TC 4 Z9 4 U1 0 U2 2 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D603 DI 10.1063/1.4889776 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000020 PM 25430179 ER PT J AU Nagel, SR Hilsabeck, TJ Bell, PM Bradley, DK Ayers, MJ Piston, K Felker, B Kilkenny, JD Chung, T Sammuli, B Hares, JD Dymoke-Bradshaw, AKL AF Nagel, S. R. Hilsabeck, T. J. Bell, P. M. Bradley, D. K. Ayers, M. J. Piston, K. Felker, B. Kilkenny, J. D. Chung, T. Sammuli, B. Hares, J. D. Dymoke-Bradshaw, A. K. L. TI Investigating high speed phenomena in laser plasma interactions using dilation x-ray imager SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB The DIlation X-ray Imager (DIXI) is a new, high-speed x-ray framing camera at the National Ignition Facility (NIF) sensitive to x-rays in the range of approximate to 2-17 keV. DIXI uses the pulse-dilation technique to achieve a temporal resolution of less than 10 ps, a approximate to 10x improvement over conventional framing cameras currently employed on the NIF (approximate to 100 ps resolution), and otherwise only attainable with 1D streaked imaging. The pulse-dilation technique utilizes a voltage ramp to impart a velocity gradient on the signal-bearing electrons. The temporal response, spatial resolution, and x-ray sensitivity of DIXI are characterized with a short x-ray impulse generated using the COMET laser facility at Lawrence Livermore National Laboratory. At the NIF a pinhole array at 10 cm from target chamber center (tcc) projects images onto the photocathode situated outside the NIF chamber wall with a magnification of approximate to 64x. DIXI will provide important capabilities for warm-dense-matter physics, high-energy-density science, and inertial confinement fusion, adding important capabilities to temporally resolve hot-spot formation, x-ray emission, fuel motion, and mix levels in the hot-spot at neutron yields of up to 10(17). We present characterization data as well as first results on electron-transport phenomena in buried-layer foil experiments. (C) 2014 AIP Publishing LLC. C1 [Nagel, S. R.; Bell, P. M.; Bradley, D. K.; Ayers, M. J.; Piston, K.; Felker, B.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Hilsabeck, T. J.; Kilkenny, J. D.; Chung, T.; Sammuli, B.] Gen Atom Co, San Diego, CA 92186 USA. [Hares, J. D.; Dymoke-Bradshaw, A. K. L.] Kentech Instruments Ltd, Wallingford OX10, Oxon, England. RP Nagel, SR (reprint author), Lawrence Livermore Natl Lab, 7000 East Ave, Livermore, CA 94550 USA. EM nagel7@llnl.gov FU U.S. Department of Energy, National Nuclear Security Administration [DE-AC52-07NA27344]; United States Government [LLNL-PROC-655361] FX The authors would like to acknowledge the support of the staff at the Jupiter Laser Facility and thank the Shape Group for providing the modeling results. Lawrence Livermore National Laboratory is operated by Lawrence Livermore National Security, LLC, for the U.S. Department of Energy, National Nuclear Security Administration under Contract No. DE-AC52-07NA27344. Accordingly, the United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this article or allow others to do so, for United States Government purposes. (LLNL-PROC-655361.) NR 12 TC 6 Z9 11 U1 1 U2 32 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E504 DI 10.1063/1.4890396 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000187 PM 25430346 ER PT J AU Oertel, JA Archuleta, TN AF Oertel, J. A. Archuleta, T. N. TI A novel solution to the gated x-ray detector gain droop problem SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Microchannel plate (MCP), microstrip transmission line based, gated x-ray detectors used at the premier ICF laser facilities have a drop in gain as a function of mircostrip length that can be greater than 50% over 40 mm. These losses are due to ohmic losses in a microstrip coating that is less than the optimum electrical skin depth. The electrical skin depth for a copper transmission line at 3 GHz is 1.2 mu m while the standard microstrip coating thickness is roughly half a single skin depth. Simply increasing the copper coating thickness would begin filling the MCP pores and limit the number of secondary electrons created in the MCP. The current coating thickness represents a compromise between gain and ohmic loss. We suggest a novel solution to the loss problem by overcoating the copper transmission line with five electrical skin depths (similar to 6 mu m) of Beryllium. Beryllium is reasonably transparent to x-rays above 800 eV and would improve the carrier current on the transmission line. The net result should be an optically flat photocathode response with almost no measurable loss in voltage along the transmission line. (C) 2014 AIP Publishing LLC. C1 [Oertel, J. A.; Archuleta, T. N.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. RP Oertel, JA (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. EM Oertel@lanl.gov FU (US) Department of Energy by Los Alamos National Laboratory [DE-AC52-06NA25396] FX Special thanks to the dedicated staff at LANL's Diagnostic and Systems Engineering Team who helped support these measurements. This work was conducted under the auspices of the (US) Department of Energy by Los Alamos National Laboratory under Contract No. DE-AC52-06NA25396. NR 10 TC 3 Z9 3 U1 2 U2 6 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D622 DI 10.1063/1.4893006 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000039 PM 25430198 ER PT J AU Opachich, YP Ross, PW MacPhee, AG Hilsabeck, TJ Nagel, SR Huffman, E Bell, PM Bradley, DK Koch, JA Landen, OL AF Opachich, Y. P. Ross, P. W. MacPhee, A. G. Hilsabeck, T. J. Nagel, S. R. Huffman, E. Bell, P. M. Bradley, D. K. Koch, J. A. Landen, O. L. TI High quantum efficiency photocathode simulation for the investigation of novel structured designs SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID RAY PHOTO-CATHODES; WAVELENGTH BAND 1-300; INSULATORS; REGION; MODELS AB A computer model in CST Studio Suite has been developed to evaluate several novel geometrically enhanced photocathode designs. This work was aimed at identifying a structure that would increase the total electron yield by a factor of two or greater in the 1-30 keV range. The modeling software was used to simulate the electric field and generate particle tracking for several potential structures. The final photocathode structure has been tailored to meet a set of detector performance requirements, namely, a spatial resolution of <40 mu m and a temporal spread of 1-10 ps. We present the details of the geometrically enhanced photocathode model and resulting static field and electron emission characteristics. (C) 2014 AIP Publishing LLC. C1 [Opachich, Y. P.; Ross, P. W.; Huffman, E.; Koch, J. A.] Natl Secur Technol LLC, Livermore, CA 94550 USA. [MacPhee, A. G.; Nagel, S. R.; Bell, P. M.; Bradley, D. K.; Landen, O. L.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. [Hilsabeck, T. J.] Gen Atom Co, San Diego, CA 92121 USA. RP Opachich, YP (reprint author), Natl Secur Technol LLC, Livermore, CA 94550 USA. EM opachiyp@nv.doe.gov FU National Security Technologies, LLC [DE-AC52-06NA25946]; U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This paper has been authored by the National Security Technologies, LLC, under Contract No. DE-AC52-06NA25946 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a nonexclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this paper, or allow others to do so, for United States Government purposes, DOE/NV/25946-2099. This work was done under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. NR 16 TC 1 Z9 1 U1 2 U2 11 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D625 DI 10.1063/1.4893942 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000042 PM 25430201 ER PT J AU Pablant, NA Bell, RE Bitter, M Delgado-Aparicio, L Hill, KW Lazerson, S Morita, S AF Pablant, N. A. Bell, R. E. Bitter, M. Delgado-Aparicio, L. Hill, K. W. Lazerson, S. Morita, S. TI Tomographic inversion techniques incorporating physical constraints for line integrated spectroscopy in stellarators and tokamaks SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID PLASMA AB Accurate tomographic inversion is important for diagnostic systems on stellarators and tokamaks which rely on measurements of line integrated emission spectra. A tomographic inversion technique based on spline optimization with enforcement of constraints is described that can produce unique and physically relevant inversions even in situations with noisy or incomplete input data. This inversion technique is routinely used in the analysis of data from the x-ray imaging crystal spectrometer (XICS) installed at the Large Helical Device. The XICS diagnostic records a 1D image of line integrated emission spectra from impurities in the plasma. Through the use of Doppler spectroscopy and tomographic inversion, XICS can provide profile measurements of the local emissivity, temperature, and plasma flow. Tomographic inversion requires the assumption that these measured quantities are flux surface functions, and that a known plasma equilibrium reconstruction is available. In the case of low signal levels or partial spatial coverage of the plasma cross-section, standard inversion techniques utilizing matrix inversion and linear-regularization often cannot produce unique and physically relevant solutions. The addition of physical constraints, such as parameter ranges, derivative directions, and boundary conditions, allow for unique solutions to be reliably found. The constrained inversion technique described here utilizes a modified Levenberg-Marquardt optimization scheme, which introduces a condition avoidance mechanism by selective reduction of search directions. The constrained inversion technique also allows for the addition of more complicated parameter dependencies, for example, geometrical dependence of the emissivity due to asymmetries in the plasma density arising from fast rotation. The accuracy of this constrained inversion technique is discussed, with an emphasis on its applicability to systems with limited plasma coverage. (C) 2014 AIP Publishing LLC. C1 [Pablant, N. A.; Bell, R. E.; Bitter, M.; Delgado-Aparicio, L.; Hill, K. W.; Lazerson, S.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Morita, S.] Natl Inst Nat Sci, Natl Inst Fus Sci, Toki, Gifu 5095292, Japan. RP Pablant, NA (reprint author), Princeton Plasma Phys Lab, POB 451, Princeton, NJ 08543 USA. FU (U.S.) Department of Energy (DOE) [DE-AC02-09CH11466]; Princeton University FX The authors would like to thank M. Reinke for many discussions on inversion methods and M. Goto, T. Oishi, and the LHD experiment group for their support in the installation of the XICS diagnostic and LHD operation. Research supported by the (U.S.) Department of Energy (DOE) under Contract No. DE-AC02-09CH11466 with Princeton University. NR 7 TC 3 Z9 3 U1 2 U2 12 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E424 DI 10.1063/1.4891977 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000172 PM 25430331 ER PT J AU Pak, A Field, JE Benedetti, LR Caggiano, J Hatarik, R Izumi, N Khan, SF Knauer, J Ma, T Spears, BK Town, RPJ Bradley, DK AF Pak, A. Field, J. E. Benedetti, L. R. Caggiano, J. Hatarik, R. Izumi, N. Khan, S. F. Knauer, J. Ma, T. Spears, B. K. Town, R. P. J. Bradley, D. K. TI Diagnosing residual motion via the x-ray self emission from indirectly driven inertial confinement implosions SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID NATIONAL-IGNITION-FACILITY AB In an indirectly driven implosion, non-radial translational motion of the compressed fusion capsule is a signature of residual kinetic energy not coupled into the compressional heating of the target. A reduction in compression reduces the peak pressure and nuclear performance of the implosion. Measuring and reducing the residual motion of the implosion is therefore necessary to improve performance and isolate other effects that degrade performance. Using the gated x-ray diagnostic, the x-ray Bremsstrahlung emission from the compressed capsule is spatially and temporally resolved at x-ray energies of >8.7 keV, allowing for measurements of the residual velocity. Here details of the x-ray velocity measurement and fitting routine will be discussed and measurements will be compared to the velocities inferred from the neutron time of flight detectors. (C) 2014 AIP Publishing LLC. C1 [Pak, A.; Field, J. E.; Benedetti, L. R.; Caggiano, J.; Hatarik, R.; Izumi, N.; Khan, S. F.; Ma, T.; Spears, B. K.; Town, R. P. J.; Bradley, D. K.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Knauer, J.] Univ Rochester, Laser Energet Lab, Rochester, NY 14623 USA. RP Pak, A (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. EM pak5@llnl.gov RI IZUMI, Nobuhiko/J-8487-2016 OI IZUMI, Nobuhiko/0000-0003-1114-597X NR 9 TC 1 Z9 1 U1 0 U2 9 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E605 DI 10.1063/1.4890259 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000192 PM 25430351 ER PT J AU Perez, F Kemp, GE Regan, SP Barrios, MA Pino, J Scott, H Ayers, S Chen, H Emig, J Colvin, JD Bedzyk, M Shoup, MJ Agliata, A Yaakobi, B Marshall, FJ Hamilton, RA Jaquez, J Farrell, M Nikroo, A Fournier, KB AF Perez, F. Kemp, G. E. Regan, S. P. Barrios, M. A. Pino, J. Scott, H. Ayers, S. Chen, H. Emig, J. Colvin, J. D. Bedzyk, M. Shoup, M. J., III Agliata, A. Yaakobi, B. Marshall, F. J. Hamilton, R. A. Jaquez, J. Farrell, M. Nikroo, A. Fournier, K. B. TI The NIF x-ray spectrometer calibration campaign at Omega SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID NATIONAL-IGNITION-FACILITY; LASER AB The calibration campaign of the National Ignition Facility X-ray Spectrometer (NXS) was carried out at the OMEGA laser facility. Spherically symmetric, laser-driven, millimeter-scale x-ray sources of K-shell and L-shell emission from various mid-Z elements were designed for the 2-18 keV energy range of the NXS. The absolute spectral brightness was measured by two calibrated spectrometers. We compare the measured performance of the target design to radiation hydrodynamics simulations. (C) 2014 AIP Publishing LLC. C1 [Perez, F.; Kemp, G. E.; Barrios, M. A.; Pino, J.; Scott, H.; Ayers, S.; Chen, H.; Emig, J.; Colvin, J. D.; Fournier, K. B.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. [Regan, S. P.; Bedzyk, M.; Shoup, M. J., III; Agliata, A.; Yaakobi, B.; Marshall, F. J.; Hamilton, R. A.] Univ Rochester, Laser Energet Lab, Rochester, NY 14623 USA. [Jaquez, J.; Farrell, M.; Nikroo, A.] Gen Atom Co, San Diego, CA 92186 USA. RP Fournier, KB (reprint author), Lawrence Livermore Natl Lab, POB 808, Livermore, CA 94551 USA. EM fournier2@llnl.gov FU (U.S.) Department of Energy (DOE) by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; Defense Threat Reduction Agency under IAA [10027-5009 BASIC] FX The authors thank M. Patel and M. Marinak for their contribution to the simulations. This work was performed under the auspices of the (U.S.) Department of Energy (DOE) by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344 and supported by the Defense Threat Reduction Agency under IAA 10027-5009 BASIC, "DTRA time-resolved x-ray spectrometer for the National Ignition Facility." NR 13 TC 8 Z9 8 U1 0 U2 13 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D613 DI 10.1063/1.4891054 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000030 PM 25430189 ER PT J AU Perez, RV Boeglin, WU Darrow, DS Cecconello, M Klimek, I Allan, SY Akers, RJ Keeling, DL McClements, KG Scannell, R Turnyanskiy, M Angulo, A Avila, P Leon, O Lopez, C Jones, OM Conway, NJ Michael, CA AF Perez, R. V. Boeglin, W. U. Darrow, D. S. Cecconello, M. Klimek, I. Allan, S. Y. Akers, R. J. Keeling, D. L. McClements, K. G. Scannell, R. Turnyanskiy, M. Angulo, A. Avila, P. Leon, O. Lopez, C. Jones, O. M. Conway, N. J. Michael, C. A. TI Investigating fusion plasma instabilities in the Mega Amp Spherical Tokamak using mega electron volt proton emissions SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB The proton detector (PD) measures 3 MeV proton yield distributions from deuterium-deuterium fusion reactions within the Mega Amp Spherical Tokamak (MAST). The PD's compact four-channel system of collimated and individually oriented silicon detectors probes different regions of the plasma, detecting protons (with gyro radii large enough to be unconfined) leaving the plasma on curved trajectories during neutral beam injection. From first PD data obtained during plasma operation in 2013, proton production rates (up to several hundred kHz and 1 ms time resolution) during sawtooth events were compared to the corresponding MAST neutron camera data. Fitted proton emission profiles in the poloidal plane demonstrate the capabilities of this new system. (C) 2014 AIP Publishing LLC. C1 [Perez, R. V.; Boeglin, W. U.; Angulo, A.; Avila, P.; Leon, O.; Lopez, C.] Florida Int Univ, Dept Phys, Miami, FL 33199 USA. [Darrow, D. S.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Cecconello, M.; Klimek, I.] Uppsala Univ, Dept Phys & Astron, SE-75120 Uppsala, Sweden. [Allan, S. Y.; Akers, R. J.; Keeling, D. L.; McClements, K. G.; Scannell, R.; Jones, O. M.; Conway, N. J.] CCFE, Culham Sci Ctr, Abingdon OX14 3DB, Oxon, England. [Turnyanskiy, M.] EFDA CSU Garching, ITER Phys Dept, D-85748 Garching, Germany. [Jones, O. M.] Univ Durham, Dept Phys, Durham DH1 3LE, England. [Michael, C. A.] Australian Natl Univ, Canberra, ACT 0200, Australia. RP Perez, RV (reprint author), Florida Int Univ, Dept Phys, 11200 SW 8 ST,CP204, Miami, FL 33199 USA. EM rvale006@fiu.edu FU (U.S.) Department of Energy (DOE) [DESC0001157, DEAC0209CH11466]; RCUK Energy Programme [EP/I501045]; Swedish Research Council; European Union's (EU) Horizon 2020 programme [210130335]; FIU Graduate & Professional Student Committee; FIU Ronald E. McNair Post-Baccalureate Achievement Program FX This work was supported by: the (U.S.) Department of Energy (DOE) Contract Nos. DESC0001157 and DEAC0209CH11466, the RCUK Energy Programme under Grant No. EP/I501045, the Swedish Research Council, the European Union's (EU) Horizon 2020 programme under Grant Agreement No. 210130335, the FIU Graduate & Professional Student Committee, and the FIU Ronald E. McNair Post-Baccalureate Achievement Program. We would like to thank Nigel Thomas-Davies for his expertise during the PD installation. The views and opinions expressed herein do not necessarily reflect those of the European Commission. NR 11 TC 7 Z9 7 U1 0 U2 3 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D701 DI 10.1063/1.4889736 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000052 PM 25430211 ER PT J AU Pickworth, LA McCarville, T Decker, T Pardini, T Ayers, J Bell, P Bradley, D Brejnholt, NF Izumi, N Mirkarimi, P Pivovaroff, M Smalyuk, V Vogel, J Walton, C Kilkenny, J AF Pickworth, L. A. McCarville, T. Decker, T. Pardini, T. Ayers, J. Bell, P. Bradley, D. Brejnholt, N. F. Izumi, N. Mirkarimi, P. Pivovaroff, M. Smalyuk, V. Vogel, J. Walton, C. Kilkenny, J. TI A Kirkpatrick-Baez microscope for the National Ignition Facility SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID RAY; FUSION AB Current pinhole x ray imaging at the National Ignition Facility (NIF) is limited in resolution and signal throughput to the detector for Inertial Confinement Fusion applications, due to the viable range of pinhole sizes (10-25 mu m) that can be deployed. A higher resolution and throughput diagnostic is in development using a Kirkpatrick-Baez microscope system (KBM). The system will achieve <9 mu m resolution over a 300 mu m field of view with a multilayer coating operating at 10.2 keV. Presented here are the first images from the uncoated NIF KBM configuration demonstrating high resolution has been achieved across the full 300 mu m field of view. (C) 2014 AIP Publishing LLC. C1 [Pickworth, L. A.; McCarville, T.; Decker, T.; Pardini, T.; Ayers, J.; Bell, P.; Bradley, D.; Brejnholt, N. F.; Izumi, N.; Mirkarimi, P.; Pivovaroff, M.; Smalyuk, V.; Vogel, J.; Walton, C.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Kilkenny, J.] Gen Atom Co, San Diego, CA 92121 USA. RP Pickworth, LA (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. EM pickworth1@llnl.gov RI Pivovaroff, Michael/M-7998-2014; IZUMI, Nobuhiko/J-8487-2016; OI Pivovaroff, Michael/0000-0001-6780-6816; IZUMI, Nobuhiko/0000-0003-1114-597X; Pickworth, Louisa/0000-0002-0585-1934 FU Lawrence Livermore National Laboratory [DE-AC52-07NA27344, LLNL-CONF-655227] FX This work was performed by Lawrence Livermore National Laboratory under Contract Nos. DE-AC52-07NA27344 and LLNL-CONF-655227. NR 16 TC 9 Z9 9 U1 4 U2 15 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D611 DI 10.1063/1.4886433 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000028 PM 25430187 ER PT J AU Raman, R Jarboe, TR Nelson, BA Gerhardt, SP Lay, WS Plunkett, GJ AF Raman, R. Jarboe, T. R. Nelson, B. A. Gerhardt, S. P. Lay, W. -S. Plunkett, G. J. TI Design and operation of a fast electromagnetic inductive massive gas injection valve for NSTX-U SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Results from the operation of an electromagnetic valve, that does not incorporate ferromagnetic materials, are presented. Image currents induced on a conducting disc placed near a pancake solenoid cause it to move away from the solenoid and open the vacuum seal. A new and important design feature is the use of Lip Seals for the sliding piston. The pressure rise in the test chamber is measured directly using a fast time response Baratron gauge. The valve injects over 200 Torr l of nitrogen in less than 3 ms, which remains unchanged at moderate magnetic fields. (C) 2014 AIP Publishing LLC. C1 [Raman, R.; Jarboe, T. R.; Nelson, B. A.; Lay, W. -S.; Plunkett, G. J.] Univ Washington, William E Boeing Dept Aeronaut & Astronaut, Seattle, WA 98195 USA. [Gerhardt, S. P.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Raman, R (reprint author), Univ Washington, William E Boeing Dept Aeronaut & Astronaut, Seattle, WA 98195 USA. EM raman@aa.washington.edu FU US DOE [DE-SC0006757, DE-AC02-09CH11466] FX We are grateful to Dr. M. Lehnen of the ITER organization for providing many of the details of the TEXTOR MGI valve and for other helpful recommendations concerning valve installation details on NSTX-U. We would also like to thank Dr. L. Baylor of ORNL for describing the valve experimental set-ups on DIII-D. This work is supported by US DOE Contract Nos. DE-SC0006757 and DE-AC02-09CH11466. NR 6 TC 4 Z9 4 U1 1 U2 5 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E801 DI 10.1063/1.4885545 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000207 PM 25430366 ER PT J AU Ren, X Domier, CW Kramer, G Luhmann, NC Muscatello, CM Shi, L Tobias, BJ Valeo, E AF Ren, X. Domier, C. W. Kramer, G. Luhmann, N. C., Jr. Muscatello, C. M. Shi, L. Tobias, B. J. Valeo, E. TI Process to generate a synthetic diagnostic for microwave imaging reflectometry with the full-wave code FWR2D SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID FUSION PLASMAS; FLUCTUATION MEASUREMENTS; SIMULATION; TURBULENCE AB A synthetic microwave imaging reflectometer (MIR) diagnostic employing the full-wave reflectometer code (FWR2D) has been developed and is currently being used to guide the design of real systems, such as the one recently installed on DIII-D. The FWR2D code utilizes real plasma profiles as input, and it is combined with optical simulation tools for synthetic diagnostic signal generation. A detailed discussion of FWR2D and the process to generate the synthetic signal are presented in this paper. The synthetic signal is also compared to a prescribed density fluctuation spectrum to quantify the imaging quality. An example is presented with H-mode-like plasma profiles derived from a DIII-D discharge, where the MIR focal is located in the pedestal region. It is shown that MIR is suitable for diagnosing fluctuations with poloidal wavenumber up to 2.0 cm(-1) and fluctuation amplitudes less than 5%. (C) 2014 AIP Publishing LLC. C1 [Ren, X.; Domier, C. W.; Luhmann, N. C., Jr.; Muscatello, C. M.] Univ Calif Davis, Millimeter & Microwave Res Ctr, Davis, CA 95616 USA. [Kramer, G.; Shi, L.; Tobias, B. J.; Valeo, E.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Ren, X (reprint author), Univ Calif Davis, Millimeter & Microwave Res Ctr, Davis, CA 95616 USA. EM xren@ucdavis.edu FU U.S. DOE [DE-AC02-09CH11466, DE-FG02-99ER54531, DE-FC02-04ER54698] FX This work is supported by U.S. DOE Grants DE-AC02-09CH11466, DE-FG02-99ER54531, and DE-FC02-04ER54698. NR 14 TC 5 Z9 5 U1 2 U2 5 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D863 DI 10.1063/1.4895100 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000117 PM 25430276 ER PT J AU Rinderknecht, HG Sio, H Frenje, JA Magoon, J Agliata, A Shoup, M Ayers, S Bailey, CG Johnson, MG Zylstra, AB Sinenian, N Rosenberg, MJ Li, CK Seguin, FH Petrasso, RD Rygg, JR Kimbrough, JR Mackinnon, A Bell, P Bionta, R Clancy, T Zacharias, R House, A Doppner, T Park, HS LePape, S Landen, O Meezan, N Robey, H Glebov, VU Hohenberger, M Stoeckl, C Sangster, TC Li, C Parat, J Olson, R Kline, J Kilkenny, J AF Rinderknecht, H. G. Sio, H. Frenje, J. A. Magoon, J. Agliata, A. Shoup, M. Ayers, S. Bailey, C. G. Johnson, M. Gatu Zylstra, A. B. Sinenian, N. Rosenberg, M. J. Li, C. K. Seguin, F. H. Petrasso, R. D. Rygg, J. R. Kimbrough, J. R. Mackinnon, A. Bell, P. Bionta, R. Clancy, T. Zacharias, R. House, A. Doeppner, T. Park, H. S. LePape, S. Landen, O. Meezan, N. Robey, H. Glebov, V. U. Hohenberger, M. Stoeckl, C. Sangster, T. C. Li, C. Parat, J. Olson, R. Kline, J. Kilkenny, J. TI A magnetic particle time-of-flight (MagPTOF) diagnostic for measurements of shock- and compression-bang time at the NIF (invited) SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID NATIONAL-IGNITION-FACILITY AB A magnetic particle time-of-flight (MagPTOF) diagnostic has been designed to measure shock-and compression-bang time using D3He-fusion protons and DD-fusion neutrons, respectively, at the National Ignition Facility (NIF). This capability, in combination with shock-burn weighted areal density measurements, will significantly constrain the modeling of the implosion dynamics. This design is an upgrade to the existing particle time-of-flight (pTOF) diagnostic, which records bang times using DD or DT neutrons with an accuracy better than +/- 70 ps [H. G. Rinderknecht et al., Rev. Sci. Instrum. 83, 10D902 (2012)]. The inclusion of a deflecting magnet will increase D3He-proton signal-to- background by a factor of 1000, allowing for the first time simultaneous measurements of shock and compression-bang times in D3He-filled surrogate implosions at the NIF. (C) 2014 AIP Publishing LLC. C1 [Rinderknecht, H. G.; Sio, H.; Frenje, J. A.; Johnson, M. Gatu; Zylstra, A. B.; Sinenian, N.; Rosenberg, M. J.; Li, C. K.; Seguin, F. H.; Petrasso, R. D.] MIT, Cambridge, MA 02139 USA. [Magoon, J.; Agliata, A.; Shoup, M.; Glebov, V. U.; Hohenberger, M.; Stoeckl, C.; Sangster, T. C.] Univ Rochester, Laser Energet Lab, Rochester, NY 14623 USA. [Ayers, S.; Bailey, C. G.; Rygg, J. R.; Kimbrough, J. R.; Mackinnon, A.; Bell, P.; Bionta, R.; Clancy, T.; Zacharias, R.; House, A.; Doeppner, T.; Park, H. S.; LePape, S.; Landen, O.; Meezan, N.; Robey, H.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Li, C.; Parat, J.] Dexter Magnet Technol, Elk Grove Village, IL 60007 USA. [Olson, R.] Sandia Natl Labs, Albuquerque, NM 87123 USA. [Kline, J.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Kilkenny, J.] Gen Atom Co, San Diego, CA 92121 USA. RP Rinderknecht, HG (reprint author), MIT, 77 Massachusetts Ave, Cambridge, MA 02139 USA. EM hgr@mit.edu RI MacKinnon, Andrew/P-7239-2014; lepape, sebastien/J-3010-2015; OI MacKinnon, Andrew/0000-0002-4380-2906; Kline, John/0000-0002-2271-9919; /0000-0003-4969-5571 FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; U.S. DoE [DE-FG52-09NA29553]; LLNL [B580243]; LLE [414090-G]; Fusion Science Center at the University of Rochester [415023-G]; National Laser Users Facility [DE-NA0000877] FX The authors thank the engineering and operations staff at NIF, LLE, and MIT for their support. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. This work was done in part for H. Rinderknecht's Ph.D. thesis and was supported in part by the U.S. DoE (DE-FG52-09NA29553), LLNL (B580243), LLE (414090-G), the Fusion Science Center at the University of Rochester (415023-G), and the National Laser Users Facility (DE-NA0000877). NR 14 TC 5 Z9 5 U1 0 U2 11 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D901 DI 10.1063/1.4886775 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000120 PM 25430279 ER PT J AU Ross, JS Moody, JD Fiuza, F Ryutov, D Divol, L Huntington, CM Park, HS AF Ross, J. S. Moody, J. D. Fiuza, F. Ryutov, D. Divol, L. Huntington, C. M. Park, H. -S. TI Thomson scattering measurements from asymmetric interpenetrating plasma flows SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Imaging Thomson scattering measurements of collective ion-acoustic fluctuations have been utilized to determine ion temperature and density from laser produced counter-streaming asymmetric flows. Two foils are heated with 8 laser beams each, 500 J per beam, at the Omega Laser facility. Measurements are made 4 mm from the foil surface using a 60 J 2 omega probe laser with a 200 ps pulse length. Measuring the electron density and temperature from the electron-plasma fluctuations constrains the fit of the multi-ion species, asymmetric flows theoretical form factor for the ion feature such that the ion temperatures, ion densities, and flow velocities for each plasma flow are determined. (C) 2014 AIP Publishing LLC. C1 [Ross, J. S.; Moody, J. D.; Fiuza, F.; Ryutov, D.; Divol, L.; Huntington, C. M.; Park, H. -S.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. RP Ross, JS (reprint author), Lawrence Livermore Natl Lab, POB 808, Livermore, CA 94551 USA. EM ross36@llnl.gov FU (U.S.) Department of Energy (DOE) by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work was performed under the auspices of the (U.S.) Department of Energy (DOE) by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. NR 18 TC 0 Z9 0 U1 1 U2 7 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E613 DI 10.1063/1.4891974 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000200 PM 25430359 ER PT J AU Schmitt, JC Bialek, J Lazerson, S Majeski, R AF Schmitt, J. C. Bialek, J. Lazerson, S. Majeski, R. TI Magnetic diagnostics for equilibrium reconstructions with eddy currents on the lithium tokamak experiment SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB The Lithium Tokamak eXperiment is a spherical tokamak with a close-fitting low-recycling wall composed of thin lithium layers evaporated onto a stainless steel-lined copper shell. Long-lived non-axisymmetric eddy currents are induced in the shell and vacuum vessel by transient plasma and coil currents and these eddy currents influence both the plasma and the magnetic diagnostic signals that are used as constraints for equilibrium reconstruction. A newly installed set of re-entrant magnetic diagnostics and internal saddle flux loops, compatible with high-temperatures and lithium environments, is discussed. Details of the axisymmetric (2D) and non-axisymmetric (3D) treatments of the eddy currents and the equilibrium reconstruction are presented. (C) 2014 AIP Publishing LLC. C1 [Schmitt, J. C.; Lazerson, S.; Majeski, R.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Bialek, J.] Columbia Univ, Dept Appl Phys & Appl Math, New York, NY 10027 USA. RP Schmitt, JC (reprint author), Princeton Plasma Phys Lab, POB 451, Princeton, NJ 08543 USA. EM jschmitt@pppl.gov RI Lazerson, Samuel/E-4816-2014 OI Lazerson, Samuel/0000-0001-8002-0121 FU U.S. DOE [DE-AC02-09CH11466, DE-AC05-00OR22725] FX This work was supported by U.S. DOE Contract Nos. DE-AC02-09CH11466 and DE-AC05-00OR22725. NR 7 TC 3 Z9 3 U1 0 U2 10 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E817 DI 10.1063/1.4892159 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000223 PM 25430382 ER PT J AU Schwartz, JA Jaworski, MA Mehl, J Kaita, R Mozulay, R AF Schwartz, J. A. Jaworski, M. A. Mehl, J. Kaita, R. Mozulay, R. TI Electrical detection of liquid lithium leaks from pipe joints SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB A test stand for flowing liquid lithium is under construction at Princeton Plasma Physics Laboratory. As liquid lithium reacts with atmospheric gases and water, an electrical interlock system for detecting leaks and safely shutting down the apparatus has been constructed. A defense in depth strategy is taken to minimize the risk and impact of potential leaks. Each demountable joint is diagnosed with a cylindrical copper shell electrically isolated from the loop. By monitoring the electrical resistance between the pipe and the copper shell, a leak of (conductive) liquid lithium can be detected. Any resistance of less than 2 k Omega trips a relay, shutting off power to the heaters and pump. The system has been successfully tested with liquid gallium as a surrogate liquid metal. The circuit features an extensible number of channels to allow for future expansion of the loop. To ease diagnosis of faults, the status of each channel is shown with an analog front panel LED, and monitored and logged digitally by LabVIEW. (C) 2014 AIP Publishing LLC. C1 [Schwartz, J. A.; Jaworski, M. A.; Mehl, J.; Kaita, R.; Mozulay, R.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Schwartz, JA (reprint author), Princeton Plasma Phys Lab, POB 451, Princeton, NJ 08543 USA. EM jschwart@pppl.gov RI Schwartz, Jacob/L-5744-2015 OI Schwartz, Jacob/0000-0001-9636-8181 FU (U.S.) Department of Energy (DOE) [DE-AC02-09CH11466] FX This work is supported by (U.S.) Department of Energy (DOE) Contract No. DE-AC02-09CH11466. NR 12 TC 0 Z9 0 U1 0 U2 9 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E824 DI 10.1063/1.4894002 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000230 PM 25430389 ER PT J AU Seely, JF Glover, JL Hudson, LT Ralchenko, Y Henins, A Pereira, N Feldman, U Di Stefano, CA Kuranz, CC Drake, RP Chen, H Williams, GJ Park, J AF Seely, J. F. Glover, J. L. Hudson, L. T. Ralchenko, Y. Henins, Albert Pereira, N. Feldman, U. Di Stefano, C. A. Kuranz, C. C. Drake, R. P. Chen, Hui Williams, G. J. Park, J. TI Measurement of high-energy (10-60 keV) x-ray spectral line widths with eV accuracy SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB A high resolution crystal spectrometer utilizing a crystal in transmission geometry has been developed and experimentally optimized to measure the widths of emission lines in the 10-60 keV energy range with eV accuracy. The spectrometer achieves high spectral resolution by utilizing crystal planes with small lattice spacings (down to 2d = 0.099 nm), a large crystal bending radius and Rowland circle diameter (965 mm), and an image plate detector with high spatial resolution (60 mu m in the case of the Fuji TR image plate). High resolution W L-shell and K-shell laboratory test spectra in the 10-60 keV range and Ho K-shell spectra near 47 keV recorded at the LLNL Titan laser facility are presented. The Ho K-shell spectra are the highest resolution hard x-ray spectra recorded from a solid target irradiated by a high-intensity laser. (C) 2014 AIP Publishing LLC. C1 [Seely, J. F.; Feldman, U.] Artep Inc, Ellicott City, MD 21042 USA. [Glover, J. L.; Hudson, L. T.; Ralchenko, Y.; Henins, Albert] NIST, Gaithersburg, MD 20899 USA. [Pereira, N.] Ecopulse Inc, Springfield, VA 22152 USA. [Di Stefano, C. A.; Kuranz, C. C.; Drake, R. P.] Univ Michigan, Ann Arbor, MI 48109 USA. [Chen, Hui; Williams, G. J.; Park, J.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. RP Seely, JF (reprint author), Artep Inc, 2922 Excelsior Springs Court, Ellicott City, MD 21042 USA. EM seelyjf@gmail.com RI Ralchenko, Yuri/E-9297-2016; Drake, R Paul/I-9218-2012; OI Ralchenko, Yuri/0000-0003-0083-9554; Drake, R Paul/0000-0002-5450-9844; Di Stefano, Carlos/0000-0001-6166-3519 FU Defense Threat Reduction Agency [DTRA-1-10-0077]; NNSA-DS; SC-OFES Joint Program in High-Energy-Density Laboratory Plasmas [DE-NA0001840] FX This work was funded by the Defense Threat Reduction Agency, Grant No. DTRA-1-10-0077 and by the NNSA-DS and SC-OFES Joint Program in High-Energy-Density Laboratory Plasmas, Grant No. DE-NA0001840. NR 4 TC 2 Z9 2 U1 2 U2 9 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D618 DI 10.1063/1.4891726 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000035 PM 25430194 ER PT J AU Shaw, G Martin, MZ Martin, R Biewer, TM AF Shaw, G. Martin, M. Z. Martin, R. Biewer, T. M. TI Preliminary design of laser-induced breakdown spectroscopy for proto-Material Plasma Exposure eXperiment SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Laser-induced breakdown spectroscopy (LIBS) is a technique for measuring surface matter composition. LIBS is performed by focusing laser radiation onto a target surface, ablating the surface, forming a plasma, and analyzing the light produced. LIBS surface analysis is a possible diagnostic for characterizing plasma-facing materials in ITER. Oak Ridge National Laboratory has enabled the initial installation of a laser-induced breakdown spectroscopy diagnostic on the prototype Material-Plasma Exposure eXperiment (Proto-MPEX), which strives to mimic the conditions found at the surface of the ITER divertor. This paper will discuss the LIBS implementation on Proto-MPEX, preliminary design of the fiber optic LIBS collection probe, and the expected results. (C) 2014 AIP Publishing LLC. C1 [Shaw, G.; Martin, M. Z.; Martin, R.; Biewer, T. M.] Oak Ridge Natl Lab, Oak Ridge, TN 37830 USA. [Shaw, G.] Univ Tennessee, Knoxville, TN 37996 USA. RP Shaw, G (reprint author), Oak Ridge Natl Lab, Oak Ridge, TN 37830 USA. EM shawgc@ornl.gov OI Martin, Madhavi/0000-0002-6677-2180 FU U.S. D.O.E [DE-AC05-00OR22725]; Laboratory Directed Research and Development Program of Oak Ridge National Laboratory FX This work was supported by the U.S. D.O.E Contract No. DE-AC05-00OR22725. Research sponsored by the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. Department of Energy. NR 20 TC 1 Z9 1 U1 0 U2 20 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D806 DI 10.1063/1.4885472 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000060 PM 25430219 ER PT J AU Smilowitz, L Henson, BF Holmes, M Novak, A Oschwald, D Dolgonos, P Qualls, B AF Smilowitz, L. Henson, B. F. Holmes, M. Novak, A. Oschwald, D. Dolgonos, P. Qualls, B. TI X-ray transmission movies of spontaneous dynamic events SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB We describe a new x-ray radiographic imaging system which allows for continuous x-ray transmission imaging of spontaneous dynamic events. We demonstrate this method on thermal explosions in three plastic bonded formulations of the energetic material octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine. We describe the x-ray imaging system and triggering developed to enable the continuous imaging of a thermal explosion. (C) 2014 AIP Publishing LLC. C1 [Smilowitz, L.; Henson, B. F.; Holmes, M.; Novak, A.; Oschwald, D.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Dolgonos, P.; Qualls, B.] CoRE Labs Med, Englewood, CO 80110 USA. RP Smilowitz, L (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. FU Science Campaign and Surety Programs FX The authors wish to acknowledge support from the Science Campaign and Surety Programs administered by Los Alamos National Laboratory and the Joint Munitions Program administered jointly by the Departments of Energy and Defense. NR 14 TC 3 Z9 3 U1 0 U2 8 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 113904 DI 10.1063/1.4901093 PG 5 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000270 PM 25430121 ER PT J AU Soukhanovskii, VA McLean, AG Allen, SL AF Soukhanovskii, V. A. McLean, A. G. Allen, S. L. TI Near-infrared spectroscopy for divertor plasma diagnosis and control in DIII-D tokamak SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID RECOMBINATION; PROFILES; REGION AB New near infrared (NIR) spectroscopic measurements performed in the DIII-D tokamak divertor plasma suggest new viable diagnostic applications: divertor recycling and low-Z impurity flux measurements, a spectral survey for divertor Thomson scattering (DTS) diagnostic, and T-e monitoring for divertor detachment control. A commercial 0.3 m spectrometer coupled to an imaging lens via optical fiber and a InGaAs 1024 pixel array detector enabled deuterium and impurity emission measurements in the range 800-2300 nm. The first full NIR survey identified D, He, B, Li, C, N, O, Ne lines and provided plasma T-e, n(e) estimates from deuterium Paschen and Brackett series intensity and Stark line broadening analysis. The range 1.000-1.060 mm was surveyed in high-density and neon seeded divertor plasmas for spectral background emission studies for lambda = 1.064 mu m laser-based DTS development. The ratio of adjacent deuterium Paschen-alpha and Brackett Br9 lines in recombining divertor plasmas is studied for divertor T-e monitoring aimed at divertor detachment real-time feedback control. (C) 2014 AIP Publishing LLC. C1 [Soukhanovskii, V. A.; McLean, A. G.; Allen, S. L.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. RP Soukhanovskii, VA (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. EM vlad@llnl.gov FU (U.S.) Department of Energy (DOE) [DE-AC52-07NA27344, DE-AC02-09CH11466] FX The authors would like to thank the entire DIII-D Team for plasma and diagnostic operations. Dr. H. Scott (LLNL) is acknowledged for the CRETIN code. The ARC spectrograph used in this work was on loan from Princeton Plasma Physics Laboratory. This work was supported by the (U.S.) Department of Energy (DOE) under DE-AC52-07NA27344 and DE-AC02-09CH11466. NR 17 TC 1 Z9 1 U1 2 U2 13 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E418 DI 10.1063/1.4891600 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000166 PM 25430325 ER PT J AU Spear, AG Domier, CW Hu, X Muscatello, CM Ren, X Tobias, BJ Luhmann, NC AF Spear, A. G. Domier, C. W. Hu, X. Muscatello, C. M. Ren, X. Tobias, B. J. Luhmann, N. C., Jr. TI 2D microwave imaging reflectometer electronics SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID PLASMAS AB A 2D microwave imaging reflectometer system has been developed to visualize electron density fluctuations on the DIII-D tokamak. Simultaneously illuminated at four probe frequencies, large aperture optics image reflections from four density-dependent cutoff surfaces in the plasma over an extended region of the DIII-D plasma. Localized density fluctuations in the vicinity of the plasma cutoff surfaces modulate the plasma reflections, yielding a 2D image of electron density fluctuations. Details are presented of the receiver down conversion electronics that generate the in-phase (I) and quadrature (Q) reflectometer signals from which 2D density fluctuation data are obtained. Also presented are details on the control system and backplane used to manage the electronics as well as an introduction to the computer based control program. (C) 2014 AIP Publishing LLC. C1 [Spear, A. G.; Domier, C. W.; Hu, X.; Muscatello, C. M.; Ren, X.; Luhmann, N. C., Jr.] Univ Calif Davis, Davis, CA 95616 USA. [Tobias, B. J.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Domier, CW (reprint author), Univ Calif Davis, Davis, CA 95616 USA. EM cwdomier@ucdavis.edu FU U.S. DOE [DE-FG02-99ER54531, DE-FC02-04ER54698] FX This work was supported by U.S. DOE Grant Nos. DE-FG02-99ER54531 and DE-FC02-04ER54698. Special thanks to Professor Jane Gu and Professor Anh-Vu Pham of the Davis MM-Wave Research Center for their help in reviewing the multilayer PCB design. NR 6 TC 0 Z9 0 U1 3 U2 8 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D834 DI 10.1063/1.4891047 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000088 PM 25430247 ER PT J AU Steel, AB Dunn, J Emig, J Beiersdorfer, P Brown, GV Shepherd, R Marley, EV Hoarty, DJ AF Steel, A. B. Dunn, J. Emig, J. Beiersdorfer, P. Brown, G. V. Shepherd, R. Marley, E. V. Hoarty, D. J. TI Development of a ten inch manipulators-based, flexible, broadband two-crystal spectrometer SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB We have developed and implemented a broadband X-ray spectrometer with a variable energy range for use at the Atomic Weapons Establishment's Orion Laser. The spectrometer covers an energy bandwidth of similar to 1-2 keV using two independently mounted, movable Bragg diffraction crystals. Using combinations of cesium hydrogen pthlate, ammonium dihydrogen phosphate, and pentaerythritol crystals, spectra covering the 1.4-2.5, 1.85-3.15, or 3.55-5.1 keV energy bands have been measured. Image plate is used for detection owing to its high dynamic range. Background signals caused by high energy X-rays and particles commonly produced in high energy laser experiments are reduced by a series of tantalum baffles and filters installed between the source and crystal and also between the crystals and detector. (C) 2014 AIP Publishing LLC. C1 [Steel, A. B.; Dunn, J.; Emig, J.; Beiersdorfer, P.; Brown, G. V.; Shepherd, R.; Marley, E. V.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Hoarty, D. J.] Atom Weap Estab, Aldermaston, England. RP Steel, AB (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. EM steel1@llnl.gov FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. NR 8 TC 1 Z9 1 U1 2 U2 9 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D610 DI 10.1063/1.4890671 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000027 PM 25430186 ER PT J AU Strelnikov, N Trakhtenberg, E Vasserman, I Xu, J Gluskin, E AF Strelnikov, N. Trakhtenberg, E. Vasserman, I. Xu, J. Gluskin, E. TI Vertically polarizing undulator with the dynamic compensation of magnetic forces for the next generation of light sources SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB A short prototype (847-mm-long) of an Insertion Device (ID) with the dynamic compensation of ID magnetic forces has been designed, built, and tested at the Advanced Photon Source (APS) of the Argonne National Laboratory. The ID magnetic forces were compensated by the set of conical springs placed along the ID strongback. Well-controlled exponential characteristics of conical springs permitted a very close fit to the ID magnetic forces. Several effects related to the imperfections of actual springs, their mounting and tuning, and how these factors affect the prototype performance has been studied. Finally, series of tests to determine the accuracy and reproducibility of the ID magnetic gap settings have been carried out. Based on the magnetic measurements of the ID B-eff, it has been demonstrated that the magnetic gaps within an operating range were controlled accurately and reproducibly within +/- 1 mu m. Successful tests of this ID prototype led to the design of a 3-m long device based on the same concept. The 3-m long prototype is currently under construction. It represents R&D efforts by the APS toward APS Upgrade Project goals as well as the future generation of IDs for the Linac Coherent Light Source (LCLS). (C) 2014 AIP Publishing LLC. C1 [Strelnikov, N.; Trakhtenberg, E.; Vasserman, I.; Xu, J.; Gluskin, E.] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA. [Strelnikov, N.] Budker Inst Nucl Phys, Novosibirsk 630090, Russia. RP Strelnikov, N (reprint author), Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA. FU U.S. Department of Energy, Basic Energy Sciences, Office of Science [DE-AC02-06CH11357.N] FX This work is supported by the U.S. Department of Energy, Basic Energy Sciences, Office of Science, under Contract No. DE-AC02-06CH11357.N. NR 12 TC 1 Z9 1 U1 0 U2 2 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 113303 DI 10.1063/1.4900544 PG 5 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000255 PM 25430106 ER PT J AU Styron, JD Cooper, GW Ruiz, CL Hahn, KD Chandler, GA Nelson, AJ Torres, JA McWatters, BR Carpenter, K Bonura, MA AF Styron, J. D. Cooper, G. W. Ruiz, C. L. Hahn, K. D. Chandler, G. A. Nelson, A. J. Torres, J. A. McWatters, B. R. Carpenter, Ken Bonura, M. A. TI Predicting the sensitivity of the beryllium/scintillator layer neutron detector using Monte Carlo and experimental response functions SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID SCINTILLATION-COUNTERS; ACTIVATION DETECTOR; CALIBRATION; DECAY AB A methodology for obtaining empirical curves relating absolute measured scintillation light output to beta energy deposited is presented. Output signals were measured from thin plastic scintillator using NIST traceable beta and gamma sources and MCNP5 was used to model the energy deposition from each source. Combining the experimental and calculated results gives the desired empirical relationships. To validate, the sensitivity of a beryllium/scintillator-layer neutron activation detector was predicted and then exposed to a known neutron fluence from a Deuterium-Deuterium fusion plasma (DD). The predicted and the measured sensitivity were in statistical agreement. (C) 2014 AIP Publishing LLC. C1 [Styron, J. D.; Cooper, G. W.; Carpenter, Ken; Bonura, M. A.] Univ New Mexico, Dept Nucl Engn, Albuquerque, NM 87131 USA. [Ruiz, C. L.; Hahn, K. D.; Chandler, G. A.; Nelson, A. J.; Torres, J. A.; McWatters, B. R.] Sandia Natl Labs, Albuquerque, NM 87185 USA. RP Styron, JD (reprint author), Univ New Mexico, Dept Nucl Engn, Albuquerque, NM 87131 USA. EM jdstyro@sandia.gov FU U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX Sandia National Laboratories is a multi-program laboratory operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Company, for the U.S. Department of Energy's National Nuclear Security Administration under Contract No. DE-AC04-94AL85000. NR 21 TC 0 Z9 0 U1 0 U2 4 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E617 DI 10.1063/1.4896176 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000204 PM 25430363 ER PT J AU Swadling, GF Lebedev, SV Hall, GN Patankar, S Stewart, NH Smith, RA Harvey-Thompson, AJ Burdiak, GC de Grouchy, P Skidmore, J Suttle, L Suzuki-Vidal, F Bland, SN Kwek, KH Pickworth, L Bennett, M Hare, JD Rozmus, W Yuan, J AF Swadling, G. F. Lebedev, S. V. Hall, G. N. Patankar, S. Stewart, N. H. Smith, R. A. Harvey-Thompson, A. J. Burdiak, G. C. de Grouchy, P. Skidmore, J. Suttle, L. Suzuki-Vidal, F. Bland, S. N. Kwek, K. H. Pickworth, L. Bennett, M. Hare, J. D. Rozmus, W. Yuan, J. TI Diagnosing collisions of magnetized, high energy density plasma flows using a combination of collective Thomson scattering, Faraday rotation, and interferometry SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID Z-PINCH AB A suite of laser based diagnostics is used to study interactions of magnetised, supersonic, radiatively cooled plasma flows produced using the Magpie pulse power generator (1.4 MA, 240 ns rise time). Collective optical Thomson scattering measures the time-resolved local flow velocity and temperature across 7-14 spatial positions. The scattering spectrum is recorded from multiple directions, allowing more accurate reconstruction of the flow velocity vectors. The areal electron density is measured using 2D interferometry; optimisation and analysis are discussed. The Faraday rotation diagnostic, operating at 1053 nm, measures the magnetic field distribution in the plasma. Measurements obtained simultaneously by these diagnostics are used to constrain analysis, increasing the accuracy of interpretation. (C) 2014 AIP Publishing LLC. C1 [Swadling, G. F.; Lebedev, S. V.; Hall, G. N.; Patankar, S.; Stewart, N. H.; Smith, R. A.; Burdiak, G. C.; de Grouchy, P.; Skidmore, J.; Suttle, L.; Suzuki-Vidal, F.; Bland, S. N.; Kwek, K. H.; Pickworth, L.; Bennett, M.; Hare, J. D.] Univ London Imperial Coll Sci Technol & Med, Plasma Phys Grp, London SW6 7LZ, England. [Harvey-Thompson, A. J.] Sandia Natl Labs, Albuquerque, NM 87185 USA. [Rozmus, W.] Univ Alberta, Dept Phys, Edmonton, AB T6G 2J1, Canada. [Yuan, J.] CAE, Inst Fluid Phys, Key Lab Pulsed Power, Mianyang 621900, Peoples R China. RP Swadling, GF (reprint author), Univ London Imperial Coll Sci Technol & Med, Plasma Phys Grp, London SW6 7LZ, England. EM george.swadling@imperial.ac.uk RI Hall, Gareth/C-4179-2015; Swadling, George/S-5980-2016 OI Swadling, George/0000-0001-8370-8837 FU EPSRC [EP/G001324/1]; DOE [DE-F03-02NA00057, DE-SC-0001063]; Sandia National Laboratories FX This work was supported in part by EPSRC Grant No. EP/G001324/1, by DOE cooperative Agreement Nos. DE-F03-02NA00057 and DE-SC-0001063 and by Sandia National Laboratories. We are pleased to acknowledge joint EPSRC and AWE Aldermaston support for personnel. NR 28 TC 12 Z9 12 U1 2 U2 24 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E502 DI 10.1063/1.4890564 PG 8 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000185 PM 25430344 ER PT J AU Thomas, CE Granstedt, EM Biewer, TM Baylor, LR Combs, SK Meitner, SJ Hillis, DL Majeski, R Kaita, R AF Thomas, C. E. (Tommy), Jr. Granstedt, E. M. Biewer, T. M. Baylor, L. R. Combs, S. K. Meitner, S. J. Hillis, D. L. Majeski, R. Kaita, R. TI Digital holography for in situ real-time measurement of plasma-facing-component erosion SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB In situ, real time measurement of net plasma-facing-component (PFC) erosion/deposition in a real plasma device is challenging due to the need for good spatial and temporal resolution, sufficient sensitivity, and immunity to fringe-jump errors. Design of a high-sensitivity, potentially high-speed, dual-wavelength CO2 laser digital holography system (nominally immune to fringe jumps) for PFC erosion measurement is discussed. (C) 2014 AIP Publishing LLC. C1 [Thomas, C. E. (Tommy), Jr.] Third Dimens Technol LLC, Knoxville, TN 37931 USA. [Granstedt, E. M.] Trialpha Energy, Rancho Santa Margarita, CA 92688 USA. [Biewer, T. M.; Baylor, L. R.; Combs, S. K.; Meitner, S. J.; Hillis, D. L.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. [Majeski, R.; Kaita, R.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Thomas, CE (reprint author), Third Dimens Technol LLC, Knoxville, TN 37931 USA. EM thomasce1@seetrue3d.com FU USDOE [DE-AC02-09CH11466, DE-FG02-07ER84724] FX Partial support from USDOE Contract No. DE-AC02-09CH11466 and USDOE Grant No. DE-FG02-07ER84724 is gratefully acknowledged. NR 6 TC 3 Z9 3 U1 2 U2 12 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D810 DI 10.1063/1.4886435 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000064 PM 25430223 ER PT J AU Tobias, B Grierson, BA Muscatello, CM Ren, X Domier, CW Luhmann, NC Zemedkun, SE Munsat, TL Classen, IGJ AF Tobias, B. Grierson, B. A. Muscatello, C. M. Ren, X. Domier, C. W. Luhmann, N. C., Jr. Zemedkun, S. E. Munsat, T. L. Classen, I. G. J. TI Phase-locking of magnetic islands diagnosed by ECE-imaging SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID NEOCLASSICAL TEARING MODES; WAVE-NUMBER; D TOKAMAK; DIII-D; FREQUENCY; STABILITY; GEOMETRY; SPECTRA; JET AB Millimeter-wave imaging diagnostics identify phase-locking and the satisfaction of 3-wave coupling selection criteria among multiple magnetic island chains by providing a localized, internal measurement of the 2D power spectral density, S(omega, k(pol)). In high-confinement tokamak discharges, these interactions impact both plasma rotation and tearing stability. Nonlinear coupling among neoclassical tearing modes of different n-number, with islands not satisfying the poloidal mode number selection criterion < m, m', m - m'>, contributes to a reduction in core rotation and flow shear in the vicinity of the modes. (C) 2014 AIP Publishing LLC. C1 [Tobias, B.; Grierson, B. A.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Muscatello, C. M.; Ren, X.; Domier, C. W.; Luhmann, N. C., Jr.] Univ Calif Davis, Dept Elect & Comp Engn, Davis, CA 95616 USA. [Zemedkun, S. E.; Munsat, T. L.] Univ Colorado, Dept Elect & Comp Engn, Boulder, CO 80309 USA. [Classen, I. G. J.] Dutch Inst Fundamental Energy Res DIFFER, NL-3430 BE Nieuwegein, Netherlands. RP Tobias, B (reprint author), Princeton Plasma Phys Lab, POB 451, Princeton, NJ 08543 USA. EM bjtobias@pppl.gov FU U.S. Department of Energy [DE-AC02-09CH11466, DE-FG02-99ER54531, DE-SC0003913, DE-FC02-04ER54698] FX This work was supported in part by the U.S. Department of Energy under DE-AC02-09CH11466, DE-FG02-99ER54531, DE-SC0003913, and DE-FC02-04ER54698. We thank the DIII-D team for their support of these experiments. The authors would also like to thank Dr. Michio Okabayashi and Dr. George McKee for their generous contributions. DIII-D data shown in this paper can be obtained in digital format by following the links at https://fusion.gat.com/global/D3D_DMP. NR 26 TC 4 Z9 4 U1 2 U2 8 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D847 DI 10.1063/1.4892438 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000101 PM 25430260 ER PT J AU Tritz, K Diallo, A LeBlanc, BP Sabbagh, S Stutman, D AF Tritz, K. Diallo, A. LeBlanc, B. P. Sabbagh, S. Stutman, D. TI Boundary displacement measurements using multi-energy soft x-rays SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID NSTX; PLASMAS AB The Multi-Energy Soft X-ray (ME-SXR) system on NSTX provides radial profiles of soft X-ray emission, measured through a set of filters with varying thickness, which have been used to reconstruct the electron temperature on fast time scales (similar to 10 kHz). In addition to this functionality, here we show that the ME-SXR system can be used to measure the boundary displacement of the NSTX plasma with a few mm spatial resolution during magnetohydrodyamic (MHD) activity. Boundary displacement measurements can serve to inform theoretical predictions of neoclassical toroidal viscosity, and will be used to investigate other edge phenomena on NSTX-U. For example, boundary measurements using filtered SXR measurements can provide information on pedestal steepness and dynamic evolution leading up to and during edge localized modes (ELMs). Future applications include an assessment of a simplified, filtered SXR edge detection system as well as its suitability for real-time non-magnetic boundary feedback for ELMs, MHD, and equilibrium position control. (C) 2014 AIP Publishing LLC. C1 [Tritz, K.; Stutman, D.] Johns Hopkins Univ, Dept Phys & Astron, Baltimore, MD 21218 USA. [Diallo, A.; LeBlanc, B. P.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Sabbagh, S.] Columbia Univ, Dept Appl Phys & Math, New York, NY 10027 USA. RP Tritz, K (reprint author), Johns Hopkins Univ, Dept Phys & Astron, Baltimore, MD 21218 USA. EM ktritz@pppl.gov RI Stutman, Dan/P-4048-2015 FU Department of Energy (DoE) [DE-FG02-09ER55012]; PPPL by the DoE [DE-AC02-09CH11466] FX The author would like to thank the NSTX team for their assistance and support with work carried out at the Princeton Plasma Physics Laboratory. This work is supported by the Department of Energy (DoE) (Grant No. DE-FG02-09ER55012), and at PPPL by the DoE (Contract No. DE-AC02-09CH11466). NR 14 TC 0 Z9 0 U1 2 U2 13 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E401 DI 10.1063/1.4885476 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000149 PM 25430308 ER PT J AU Turnbull, D Moody, JD Michel, P Ralph, JE Divol, L AF Turnbull, D. Moody, J. D. Michel, P. Ralph, J. E. Divol, L. TI Polarimetry of uncoupled light on the NIF SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Polarimetry has been added to the full aperture backscatter diagnostic on the NIF. Wollaston prisms are used to sample a small region of a beam's backscatter, effectively separating it into two linear polarizations, one of which is parallel to the incident beam. A time-averaged measurement of each polarization is obtained by imaging the separated spots off of a scatter plate. Results have improved understanding of crossed beam energy transfer, glint, and sidescatter, and motivated plans to upgrade to a time-resolved polarimeter measuring the full Stokes vector. (C) 2014 AIP Publishing LLC. C1 [Turnbull, D.] Lawrence Livermore Natl Lab, Natl Ignit Facil, Livermore, CA 94550 USA. Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. RP Turnbull, D (reprint author), Lawrence Livermore Natl Lab, Natl Ignit Facil, Livermore, CA 94550 USA. EM turnbull2@llnl.gov RI Michel, Pierre/J-9947-2012 FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344. NR 6 TC 4 Z9 4 U1 0 U2 12 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E603 DI 10.1063/1.4886392 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000190 PM 25430349 ER PT J AU Wang, ZH Combs, SK Baylor, LR Foust, CR Lyttle, MS Meitner, SJ Rasmussen, DA AF Wang, Zhehui Combs, S. K. Baylor, L. R. Foust, C. R. Lyttle, M. S. Meitner, S. J. Rasmussen, D. A. TI Fast imaging of intact and shattered cryogenic neon pellets SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID DISRUPTION MITIGATION; INJECTION; ITER; JET AB Compact condensed-matter injection technologies are increasingly used in magnetic fusion. One recent application is in disruption mitigation. An imaging system with less-than-100-mu m-and sub-mu s-resolution is described and used to characterize intact and shattered cryogenic neon pellets. Shattered pellets contain fine particles ranging from tens of mu m to about 7 mm. Time-of-flight analyses indicate that pellets could slow down if hitting the wall of the guide tube. Fast high-resolution imaging systems are thus useful to neon and other condensed-matter injector development. (C) 2014 AIP Publishing LLC. C1 [Wang, Zhehui] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Combs, S. K.; Baylor, L. R.; Foust, C. R.; Lyttle, M. S.; Meitner, S. J.; Rasmussen, D. A.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. RP Wang, ZH (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. EM zwang@lanl.gov FU ORNL [DE-AC05-00OR22725] FX We thank Nicodemo Calautti (Visual Instrumentation Corp.), Phiroze Daial (Vision Research), Tsutomu "Tom" Shimada (LANL), and T. Ha (ORNL) for help/discussion about the imaging system development and Don Rej (LANL) for encouragement to carry out the work. This work is supported through a subcontract with ORNL under Contract No. DE-AC05-00OR22725. NR 9 TC 0 Z9 0 U1 1 U2 2 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E805 DI 10.1063/1.4886426 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000211 PM 25430370 ER PT J AU Widmann, K Beiersdorfer, P Magee, EW Boyle, DP Kaita, R Majeski, R AF Widmann, K. Beiersdorfer, P. Magee, E. W. Boyle, D. P. Kaita, R. Majeski, R. TI High-resolution grazing-incidence grating spectrometer for temperature measurements of low-Z ions emitting in the 100-300 angstrom spectral band SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID X-RAY; ELECTRON-BEAM; TRAP AB We have constructed a high-resolution grazing-incidence spectrometer designed for measuring the ion temperature of low-Z elements, such as Li+ or Li2+, which radiate near 199 angstrom and 135 angstrom, respectively. Based on measurements at the Livermore Electron Beam Ion Trap we have shown that the instrumental resolution is better than 48 m angstrom at the 200 angstrom setting and better than 40 m angstrom for the 135-angstrom range. Such a high spectral resolution corresponds to an instrumental limit for line-width based temperature measurements of about 45 eV for the 199 angstrom Li+ and 65 eV for the 135 angstrom Li2+ lines. Recently obtained survey spectra from the Lithium Tokamak Experiment at the Princeton Plasma Physics Laboratory show the presence of these lithium emission lines and the expected core ion temperature of approximately 70 eV is sufficiently high to demonstrate the feasibility of utilizing our high-resolution spectrometer as an ion-temperature diagnostic. (C) 2014 AIP Publishing LLC. C1 [Widmann, K.; Beiersdorfer, P.; Magee, E. W.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Boyle, D. P.; Kaita, R.; Majeski, R.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Widmann, K (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. EM widmann1@llnl.gov FU (U.S.) Department of Energy (DOE) by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; Princeton Plasma Physics Laboratory [DE-AC02-09CH11466] FX This work was performed under the auspices of the (U.S.) Department of Energy (DOE) by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344 and the Princeton Plasma Physics Laboratory under Contract No. DE-AC02-09CH11466. NR 16 TC 2 Z9 2 U1 0 U2 2 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D630 DI 10.1063/1.4894388 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000047 PM 25430206 ER PT J AU Williams, GJ Maddox, BR Chen, H Kojima, S Millecchia, M AF Williams, G. Jackson Maddox, Brian R. Chen, Hui Kojima, Sadaoki Millecchia, Matthew TI Calibration and equivalency analysis of image plate scanners SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB A universal procedure was developed to calibrate image plate scanners using radioisotope sources. Techniques to calibrate scanners and sources, as well as cross-calibrate scanner models, are described to convert image plate dosage into physical units. This allows for the direct comparison of quantitative data between any facility and scanner. An empirical relation was also derived to establish sensitivity response settings for arbitrary gain settings. In practice, these methods may be extended to any image plate scanning system. (C) 2014 AIP Publishing LLC. C1 [Williams, G. Jackson; Maddox, Brian R.; Chen, Hui] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Kojima, Sadaoki] Osaka Univ, Inst Laser Engn, Suita, Osaka 5650871, Japan. [Millecchia, Matthew] Univ Rochester, Laser Energet Lab, Rochester, NY 14623 USA. RP Williams, GJ (reprint author), Lawrence Livermore Natl Lab, 7000 East Ave, Livermore, CA 94550 USA. EM williams270@llnl.gov FU U.S. Department of Energy (DOE) by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; LLNL LDRD program [12-ERD-066]; U.S. Department of Energy Office of Inertial Confinement Fusion [DE-FC52-08NA28302]; University of Rochester; New York State Energy Research and Development Authority FX The authors acknowledge Y. Arikawa from ILE, K. Austin, L. Caldeira, J. Park, and G. Stone from LLNL, and M. Rowland, C. Sorce, and D. Walker from LLE for experimental support. This work was performed under the auspices of the U.S. Department of Energy (DOE) by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344 and funded by the LLNL LDRD program (12-ERD-066). Portions of this work were performed at LLE and supported by the U.S. Department of Energy Office of Inertial Confinement Fusion under Cooperative Agreement No. DE-FC52-08NA28302, the University of Rochester, and the New York State Energy Research and Development Authority. The mention of commercial products does not represent an endorsement by the authors or their institutions. NR 9 TC 2 Z9 2 U1 0 U2 6 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E604 DI 10.1063/1.4886390 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000191 PM 25430350 ER PT J AU Wu, M Moy, K Kruschwitz, C Rochau, G AF Wu, Ming Moy, Ken Kruschwitz, Craig Rochau, Greg TI Characterizations of MCP performance in the hard x-ray range (6-25 keV) SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID MICROCHANNEL PLATES AB MCP detector performance at hard x-ray energies from 6 to 25 keV was recently investigated using NSLS beamline X15A at BNL. Measurements were made with an NSTec Gen-II (H-CA-65) framing camera, based on a Photonis MCP with similar to 10 mu m in diameter pores, similar to 12 mu m center-center spacing, an L/D ratio of 46, and a bias angle of 8 degrees. The MCP characterizations were focused on (1) energy and angle dependent sensitivity, (2) energy and angle dependent spatial resolution, (3) energy dependent gain performance, and (4) energy dependent dynamic range. These measurement corroborated simulation results using a Monte Carlo model that included hard x-ray interactions and the subsequent electron cascade in the MCP. (C) 2014 AIP Publishing LLC. C1 [Wu, Ming; Rochau, Greg] Sandia Natl Labs, Albuquerque, NM 87185 USA. [Moy, Ken] NSTec, Special Technol Labs, Santa Barbara, CA 93111 USA. [Kruschwitz, Craig] Natl Secur Technol LLC, Los Alamos Operat, Los Alamos, NM 87544 USA. RP Wu, M (reprint author), Sandia Natl Labs, POB 5800, Albuquerque, NM 87185 USA. EM minwu@sandia.gov FU U.S. D.O.E. [DE-AC04-94AL85000, DE-AC52-06NA25946] FX This work was supported by the U.S. D.O.E. Contract Nos. DE-AC04-94AL85000 and DE-AC52-06NA25946. NR 7 TC 1 Z9 2 U1 0 U2 5 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D607 DI 10.1063/1.4890293 PG 5 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000024 PM 25430183 ER PT J AU Wurden, GA Oertel, JA Evans, TE AF Wurden, G. A. Oertel, J. A. Evans, T. E. TI An in situ runaway electron diagnostic for DIII-D SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA ID X-RAY IMAGER; SYNCHROTRON-RADIATION; DISRUPTIONS; TRANSPORT AB We are designing a new diagnostic based on laser inverse Compton scattering to study the dynamics of runaway electron formation during killer-pellet triggered disruptions in DIII-D, and their subsequent loss. We can improve the expected S/N ratio by using a high-intensity short-pulse laser combined with gated x-ray imagers. With 80 ps sampling, time-of-flight spatial resolution within the laser chord can be obtained. We will measure the time-resolved spatial profile and energy distribution of the runaway electrons while they are in the core of the tokamak plasma. (C) 2014 AIP Publishing LLC. C1 [Wurden, G. A.; Oertel, J. A.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Evans, T. E.] Gen Atom Co, San Diego, CA 92121 USA. RP Wurden, GA (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. EM wurden@lanl.gov RI Wurden, Glen/A-1921-2017 OI Wurden, Glen/0000-0003-2991-1484 FU US Department of Energy, Office of Science, Office of Fusion Energy Sciences; LANS [DE-AC52-06NA25396]; GA [DE-FC02-04ER54698] FX This work is supported by the US Department of Energy, Office of Science, Office of Fusion Energy Sciences, and LANS Contract No. DE-AC52-06NA25396 and GA Contract No. DE-FC02-04ER54698, and was inspired by a DAHRT discussion with Josh Coleman (LANL). NR 20 TC 0 Z9 0 U1 1 U2 5 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E111 DI 10.1063/1.4890398 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000131 PM 25430290 ER PT J AU Younkin, TR Biewer, TM Klepper, CC Marcus, C AF Younkin, T. R. Biewer, T. M. Klepper, C. C. Marcus, C. TI Description of the prototype diagnostic residual gas analyzer for ITER SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB The diagnostic residual gas analyzer (DRGA) system to be used during ITER tokamak operation is being designed at Oak Ridge National Laboratory to measure fuel ratios (deuterium and tritium), fusion ash (helium), and impurities in the plasma. The eventual purpose of this instrument is for machine protection, basic control, and physics on ITER. Prototyping is ongoing to optimize the hardware setup and measurement capabilities. The DRGA prototype is comprised of a vacuum system and measurement technologies that will overlap to meet ITER measurement requirements. Three technologies included in this diagnostic are a quadrupole mass spectrometer, an ion trap mass spectrometer, and an optical penning gauge that are designed to document relative and absolute gas concentrations. (C) 2014 AIP Publishing LLC. C1 [Younkin, T. R.; Biewer, T. M.; Klepper, C. C.; Marcus, C.] Oak Ridge Natl Lab, Fus & Mat Nucl Syst Div, Oak Ridge, TN 37831 USA. [Younkin, T. R.] Georgia Inst Technol, Woodruff Sch Mech Engn, Nucl & Radiol Engn Program, Atlanta, GA 30332 USA. RP Younkin, TR (reprint author), Oak Ridge Natl Lab, Fus & Mat Nucl Syst Div, Oak Ridge, TN 37831 USA. EM tyounkin@gatech.edu FU US. D.O.E. [DE-AC05-00OR22725] FX This work was supported by the US. D.O.E. Contract No. DE-AC05-00OR22725. NR 7 TC 1 Z9 1 U1 1 U2 7 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11E816 DI 10.1063/1.4892157 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000222 PM 25430381 ER PT J AU Zhu, Y Zhao, Z Liu, WD Xie, J Hu, X Muscatello, CM Domier, CW Luhmann, NC Chen, M Ren, X Tobias, BJ Zhuang, G Yang, Z AF Zhu, Y. Zhao, Z. Liu, W. D. Xie, J. Hu, X. Muscatello, C. M. Domier, C. W. Luhmann, N. C., Jr. Chen, M. Ren, X. Tobias, B. J. Zhuang, G. Yang, Z. TI Optics design for J-TEXT ECE imaging with field curvature adjustment lens SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article; Proceedings Paper CT 20th Topical Conference on High-Temperature Plasma Diagnostics CY JUN 01-05, 2014 CL Atlanta, GA AB Significant progress has been made in the imaging and visualization of magnetohydrodynamic and microturbulence phenomena in magnetic fusion plasmas. Of particular importance has been microwave electron cyclotron emission imaging (ECEI) for imaging T-e fluctuations. Key to the success of ECEI is a large Gaussian optics system constituting a major portion of the focusing of the microwave radiation from the plasma to the detector array. Both the spatial resolution and observation range are dependent upon the imaging optics system performance. In particular, it is critical that the field curvature on the image plane is reduced to decrease crosstalk between vertical channels. The receiver optics systems for two ECEI on the J-TEXT device have been designed to ameliorate these problems and provide good performance with additional field curvature adjustment lenses with a meniscus shape to correct the aberrations from several spherical surfaces. (C) 2014 AIP Publishing LLC. C1 [Zhu, Y.; Zhao, Z.; Liu, W. D.; Xie, J.] Univ Sci & Technol China, Sch Phys, Hefei 230026, Anhui, Peoples R China. [Hu, X.; Muscatello, C. M.; Domier, C. W.; Luhmann, N. C., Jr.; Chen, M.; Ren, X.] Univ Calif Davis, Davis, CA 95616 USA. [Tobias, B. J.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Zhuang, G.; Yang, Z.] Huazhong Univ Sci & Technol, Coll Elect & Elect Engn, Wuhan 430074, Peoples R China. RP Xie, J (reprint author), Univ Sci & Technol China, Sch Phys, Hefei 230026, Anhui, Peoples R China. EM jlxie@ustc.edu.cn RI Liu, Wandong/K-6119-2012 FU National Magnetic Confinement Fusion Energy Program of China [2009GB107001, 2014GB109002]; U.S. DOE [DE-FG02-99ER54531] FX This work was supported by National Magnetic Confinement Fusion Energy Program of China under Contract Nos. 2009GB107001 and 2014GB109002, and by the U.S. DOE Grant No. DE-FG02-99ER54531. NR 10 TC 5 Z9 5 U1 0 U2 7 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD NOV PY 2014 VL 85 IS 11 AR 11D854 DI 10.1063/1.4893352 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA AU5KO UT WOS:000345646000108 PM 25430267 ER PT J AU Ma, Q Chen, X Liu, C Mao, XZ Zhang, HY Ji, F Wu, CG Xi, Y AF Ma Qin Chen Xin Liu Chao Mao XiZeng Zhang HanYuan Ji Fei Wu ChunGuo Xu Ying TI Understanding the commonalities and differences in genomic organizations across closely related bacteria from an energy perspective SO SCIENCE CHINA-LIFE SCIENCES LA English DT Article DE genomic organization; transcription activation frequency; pathway modeling; comparative genomics analysis ID ESCHERICHIA-COLI K-12; SEQUENCE; GENES; COMMENSAL; O157H7; REVEAL; IDENTIFICATION; INFORMATION; ARRANGEMENT; EXPRESSION AB The availability of a large number of sequenced bacterial genomes facilitates in-depth studies about why genes (operons) in a bacterial genome are globally organized the way they are. We have previously discovered that (the relative) transcription-activation frequencies among different biological pathways encoded in a genome have a dominating role in the global arrangement of operons. One complicating factor in such a study is that some operons may be involved in multiple pathways with different activation frequencies. A quantitative model has been developed that captures this information, which tends to be minimized by the current global arrangement of operons in a bacterial (and archaeal) genome compared to possible alternative arrangements. A study is carried out here using this model on a collection of 52 closely related Escherichia coli genomes, which revealed interesting new insights about how bacterial genomes evolve to optimally adapt to their environments through adjusting the (relative) genomic locations of the encoding operons of biological pathways once their utilization and hence transcription activation frequencies change, to maintain the above energy-efficiency property. More specifically we observed that it is the frequencies of the transcription activation of pathways relative to those of the other encoded pathways in an organism as well as the variation in the activation frequencies of a specific pathway across the related genomes that play a key role in the observed commonalities and differences in the genomic organizations of genes (and operons) encoding specific pathways across different genomes. C1 [Ma Qin; Chen Xin; Liu Chao; Mao XiZeng; Zhang HanYuan; Ji Fei; Wu ChunGuo; Xu Ying] Univ Georgia, Dept Biochem & Mol Biol, Computat Syst Biol Lab, Athens, GA 30602 USA. [Ma Qin; Chen Xin; Liu Chao; Mao XiZeng; Zhang HanYuan; Ji Fei; Wu ChunGuo; Xu Ying] Univ Georgia, Inst Bioinformat, Athens, GA 30602 USA. [Ma Qin; Mao XiZeng; Ji Fei; Xu Ying] Oak Ridge Natl Lab, BioEnergy Sci Ctr, Oak Ridge, TN 37831 USA. [Chen Xin; Zhang HanYuan; Wu ChunGuo; Xu Ying] Jilin Univ, Coll Comp Sci & Technol, Changchun 130012, Peoples R China. [Liu Chao] Shandong Univ, Prov Hosp, Jinan 250021, Peoples R China. RP Xi, Y (reprint author), Univ Georgia, Dept Biochem & Mol Biol, Computat Syst Biol Lab, Athens, GA 30602 USA. EM xyn@bmb.uga.edu RI Ma, Qin/O-1525-2013 OI Ma, Qin/0000-0002-3264-8392 FU National Science Foundation [NSF DEB-0830024, NSF MCB-0958172]; US Department of Energy's BioEnergy Science Center grant through the Office of Biological and Environmental Research; Office of Biological and Environmental Research in the DOE Office of Science; US Department of Energy's BioEnergy Science Center FX This work was supported in part by National Science Foundation (#NSF DEB-0830024 and NSF MCB-0958172) and by the US Department of Energy's BioEnergy Science Center grant through the Office of Biological and Environmental Research. The BioEnergy Science Center is a US Department of Energy Bioenergy Research Center supported by the Office of Biological and Environmental Research in the DOE Office of Science. Funding for open access charge: US Department of Energy's BioEnergy Science Center. NR 55 TC 2 Z9 2 U1 0 U2 9 PU SCIENCE PRESS PI BEIJING PA 16 DONGHUANGCHENGGEN NORTH ST, BEIJING 100717, PEOPLES R CHINA SN 1674-7305 EI 1869-1889 J9 SCI CHINA LIFE SCI JI Sci. China-Life Sci. PD NOV PY 2014 VL 57 IS 11 BP 1121 EP 1130 DI 10.1007/s11427-014-4734-y PG 10 WC Biology SC Life Sciences & Biomedicine - Other Topics GA AU3AF UT WOS:000345484700009 PM 25234108 ER PT J AU Sumpter, BG Liang, LB Nicolai, A Meunier, V AF Sumpter, Bobby G. Liang, Liangbo Nicolai, Adrien Meunier, Vincent TI Interfacial Properties and Design of Functional Energy Materials SO ACCOUNTS OF CHEMICAL RESEARCH LA English DT Review ID SELF-ASSEMBLED MONOLAYERS; QUASI-2-DIMENSIONAL ORGANIC SUPERCONDUCTORS; SURFACE-CONFINED POLYMERIZATION; GRAPHENE NANORIBBONS; METAL-SURFACES; BORON-NITRIDE; MOLECULES; INSIGHT; INTERMEDIATE; CONDUCTANCE AB CONSPECTUS: The vital importance of energy to society continues to demand a relentless pursuit of energy responsive materials that can bridge fundamental chemical structures at the molecular level and achieve improved functionality and performance. This demand can potentially be realized by harnessing the power of self-assembly, a spontaneous process where molecules or much larger entities form ordered aggregates as a consequence of predominately noncovalent (weak) interactions. Self-assembly is the key to bottom-up design of molecular devices, because the nearly atomic-level control is very difficult to realize in a top-down, for example, lithographic, approach. However, while function in simple systems such as single crystals can often be evaluated a priori, predicting the function of the great variety of self-assembled molecular architectures is complicated by the lack of understanding and control over nanoscale interactions, mesoscale architectures, and macroscale order. To establish a foundation toward delivering practical solutions, it is critical to develop an understanding of the chemical and physical mechanisms responsible for the self-assembly of molecular and hybrid materials on various support substrates. Typical molecular self-assembly involves noncovalent intermolecular and substrate-molecule interactions. These interactions remain poorly understood, due to the combination of many-body interactions compounded by local or collective influences from the substrate atomic lattice and electronic structure. Progress toward unraveling the underlying physicochemical processes that control the structure and macroscopic physical, chemical, mechanical, electrical, and transport properties of materials increasingly requires tight integration of theory, modeling, and simulation with precision synthesis, advanced experimental characterization, and device measurements. Theory, modeling, and simulation can accelerate the process of materials understanding and design by providing atomic level understanding of the underlying physicochemical phenomena (illuminating connections between experiments). It can also provide the ability to explore new materials and conditions before they are realized in the laboratory. With tight integration and feedback with experiment, it becomes feasible to identify promising materials or processes for targeted energy applications. In this Account, we highlight recent advances and success in using an integrated approach based on electronic structure simulations and scanning probe microscopy techniques to study and design functional materials formed from the self-assembly of molecules into supramolecular or polymeric architectures on substrates. C1 [Sumpter, Bobby G.] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA. [Sumpter, Bobby G.] Oak Ridge Natl Lab, Comp Sci & Math Div, Oak Ridge, TN 37831 USA. [Liang, Liangbo; Nicolai, Adrien; Meunier, Vincent] Rensselaer Polytech Inst, Dept Phys Appl Phys & Astron, Troy, NY 12180 USA. RP Sumpter, BG (reprint author), Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA. EM sumpterbg@ornl.gov; meuniv@rpi.edu RI Meunier, Vincent/F-9391-2010; Liang, Liangbo/H-4486-2011; Sumpter, Bobby/C-9459-2013 OI Meunier, Vincent/0000-0002-7013-179X; Liang, Liangbo/0000-0003-1199-0049; Sumpter, Bobby/0000-0001-6341-0355 FU Center for Nanophase Materials Sciences - Oak Ridge National Laboratory by the Division of Scientific User Facilities, Basic Energy Sciences, U.S. Department of Energy; Office of Naval Research FX B.G.S. and V.M. gratefully acknowledge the support of the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Division of Scientific User Facilities, Basic Energy Sciences, U.S. Department of Energy. A.N. and V.M. also acknowledge the Office of Naval Research for support. NR 74 TC 6 Z9 6 U1 15 U2 102 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0001-4842 EI 1520-4898 J9 ACCOUNTS CHEM RES JI Accounts Chem. Res. PD NOV PY 2014 VL 47 IS 11 SI SI BP 3395 EP 3405 DI 10.1021/ar500180h PG 11 WC Chemistry, Multidisciplinary SC Chemistry GA AT9QU UT WOS:000345262200022 PM 24963787 ER PT J AU Huang, H Yoo, S Qin, H Yu, DT AF Huang, Hao Yoo, Shinjae Qin, Hong Yu, Dantong TI Physics-Based Anomaly Detection Defined on Manifold Space SO ACM TRANSACTIONS ON KNOWLEDGE DISCOVERY FROM DATA LA English DT Article DE Anomaly detection; Laplace operator; heat diffusion; quantum mechanics ID DIFFUSION MAPS; QUANTUM-MECHANICS AB Current popular anomaly detection algorithms are capable of detecting global anomalies but often fail to distinguish local anomalies from normal instances. Inspired by contemporary physics theory (i.e., heat diffusion and quantum mechanics), we propose two unsupervised anomaly detection algorithms. Building on the embedding manifold derived from heat diffusion, we devise Local Anomaly Descriptor (LAD), which faithfully reveals the intrinsic neighborhood density. It uses a scale-dependent umbrella operator to bridge global and local properties, which makes LAD more informative within an adaptive scope of neighborhood. To offer more stability of local density measurement on scaling parameter tuning, we formulate Fermi Density Descriptor (FDD), which measures the probability of a fermion particle being at a specific location. By choosing the stable energy distribution function, FDD steadily distinguishes anomalies from normal instances with any scaling parameter setting. To further enhance the efficacy of our proposed algorithms, we explore the utility of anisotropic Gaussian kernel (AGK), which offers better manifold-aware affinity information. We also quantify and examine the effect of different Laplacian normalizations for anomaly detection. Comprehensive experiments on both synthetic and benchmark datasets verify that our proposed algorithms outperform the existing anomaly detection algorithms. C1 [Huang, Hao; Qin, Hong] SUNY Stony Brook, Dept Comp Sci, Stony Brook, NY 11794 USA. [Yoo, Shinjae; Yu, Dantong] Brookhaven Natl Lab, Computat Sci Ctr, Upton, NY 11973 USA. RP Huang, H (reprint author), SUNY Stony Brook, Dept Comp Sci, Stony Brook, NY 11794 USA. EM hao.huang.1@stonybrook.edu FU National Science Foundation of the United States [IIS-0949467, IIS-1047715, IIS-1049448]; National Natural Science Foundation of China [61190120, 61190121, 61190125]; U.S. Department of Energy [DE-SC0003361] FX This research is supported in part by the National Science Foundation of the United States (No. IIS-0949467, IIS-1047715, and IIS-1049448) and the National Natural Science Foundation of China (No. 61190120, 61190121, and 61190125). It is also supported by the U.S. Department of Energy, Grant No. DE-SC0003361, funded through the American Recovery and Reinvestment Act of 2009. NR 49 TC 1 Z9 1 U1 1 U2 3 PU ASSOC COMPUTING MACHINERY PI NEW YORK PA 2 PENN PLAZA, STE 701, NEW YORK, NY 10121-0701 USA SN 1556-4681 EI 1556-472X J9 ACM T KNOWL DISCOV D JI ACM Trans. Knowl. Discov. Data PD NOV PY 2014 VL 9 IS 2 AR 14 DI 10.1145/2641574 PG 39 WC Computer Science, Information Systems; Computer Science, Software Engineering SC Computer Science GA AT9UK UT WOS:000345271600007 ER PT J AU Zhang, RQ McEwen, JS Kollar, M Gao, F Wang, YL Szanyi, J Peden, CHF AF Zhang, Renqin McEwen, Jean-Sabin Kollar, Marton Gao, Feng Wang, Yilin Szanyi, Janos Peden, Charles H. F. TI NO Chemisorption on Cu/SSZ-13: A Comparative Study from Infrared Spectroscopy and DFT Calculations SO ACS CATALYSIS LA English DT Article DE infrared spectroscopy; DFT; NO chemisorption; oxidation state; Cu/SSZ-13; dehydration; Bronsted acid site ID SELECTIVE CATALYTIC-REDUCTION; CU-EXCHANGED ZEOLITES; AUGMENTED-WAVE METHOD; SSZ-13 ZEOLITE; NITROGEN-OXIDES; ACTIVE-SITES; CU-SSZ-13; AMMONIA; NH3; ABSORPTION AB The locations and energies of Cu ions in a Cu/SSZ-13 zeolite catalyst were investigated by density functional theory (DFT) calculations. For naked Cu2+ ions (i.e., Cu2+ ions with no ligands in their coordination spheres other than zeolite lattice oxygen atoms), the more energetically favorable sites are within a 6-membered ring. However, with the presence of various adsorbates, the energy difference between 6- and 8-membered ring locations greatly diminishes. Specifically, Cu2+ ions are substantially stabilized by -OH ligands (as [Cu-II(OH)](+)), making the extra-framework sites in an 8-membered ring energetically more favorable than 6-membered ring sites. Under fully dehydrated high vacuum conditions with different Si/Al and Cu/Al ratios, three chemisorbed NO species coexist upon exposure of NO to Cu/SSZ-13: NO+, Cu2+NO, and Cu+NO. The relative signal intensities for these bands vary greatly with Si/Al ratios. The vibrational frequency of chemisorbed NO was found to be very sensitive to the location of Cu2+ ions. On the one hand, with the aid from DFT calculations, the nature for these vibrations can be assigned in detail. On the other hand, the relative intensities for various Cu-2+NO species provide a good measure of the nature of Cu2+ ions as functions of Si/Al and Cu/Al ratios and the presence of humidity. These new findings cast doubt on the generally accepted proposal that only Cu2+ ions located in 6-membered rings are catalytically active for NH3SCR. C1 [Zhang, Renqin; McEwen, Jean-Sabin] Washington State Univ, Gene & Linda Voiland Sch Chem Engn & Bioengn, Pullman, WA 99164 USA. [McEwen, Jean-Sabin] Washington State Univ, Dept Phys & Astron, Pullman, WA 99164 USA. [McEwen, Jean-Sabin] Washington State Univ, Dept Chem, Pullman, WA 99164 USA. [Kollar, Marton; Gao, Feng; Wang, Yilin; Szanyi, Janos; Peden, Charles H. F.] Pacific NW Natl Lab, Inst Integrated Catalysis, Richland, WA 99352 USA. RP McEwen, JS (reprint author), Washington State Univ, Gene & Linda Voiland Sch Chem Engn & Bioengn, Pullman, WA 99164 USA. EM js.mcewen@wsu.edu; chuck.peden@pnnl.gov RI Zhang, Renqin/Q-2789-2015 OI Zhang, Renqin/0000-0002-4489-2050 FU Voiland School of Chemical Engineering and Bioengineering; USDA/NIFA through Hatch Project [WNP00807]; U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Program; Department of Energy's Office of Biological and Environmental Research FX For the authors from Washington State University, this work was supported by institutional funds provided to J.-S.M. from the Voiland School of Chemical Engineering and Bioengineering. This work was partially funded by USDA/NIFA through Hatch Project #WNP00807 titled: "Fundamental and Applied Chemical and Biological Catalysts to Minimize Climate Change, Create a Sustainable Energy Future, and Provide a Safer Food Supply". For those of us from Pacific Northwest National Laboratory (PNNL), financial support was provided by the U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Program. A portion of the research (including both computer time for DFT and experimental FTIR work) was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at PNNL. PNNL is a multiprogram national laboratory operated for the U.S. DOE by Battelle. We also thank Ms. Kathy Helling for her useful comments on the manuscript. NR 41 TC 26 Z9 27 U1 11 U2 74 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 2155-5435 J9 ACS CATAL JI ACS Catal. PD NOV PY 2014 VL 4 IS 11 BP 4093 EP 4105 DI 10.1021/cs500563s PG 13 WC Chemistry, Physical SC Chemistry GA AT0QD UT WOS:000344639300036 ER PT J AU Xia, F Zhao, J Etschmann, BE Brugger, J Garvey, CJ Rehm, C Lemmel, H Ilvasky, J Han, YS Pring, A AF Xia, Fang Zhao, Jing Etschmann, Barbara E. Brugger, Joel Garvey, Christopher J. Rehm, Christine Lemmel, Hartmut Ilvasky, Jan Han, Young-Soo Pring, Allan TI Characterization of porosity in sulfide ore minerals: A USANS/SANS study SO AMERICAN MINERALOGIST LA English DT Article DE SANS; USANS; sulfide ore minerals; porosity; mineral replacement reactions ID ANGLE NEUTRON-SCATTERING; X-RAY-SCATTERING; ST PETER SANDSTONE; HYDROTHERMAL CONDITIONS; REPLACEMENT REACTIONS; SUPERGENE ALTERATION; WESTERN-AUSTRALIA; PYRITE; TRANSFORMATION; PENTLANDITE AB Porosity plays a key role in the formation and alteration of sulfide ore minerals, yet our knowledge of the nature and formation of the residual pores is very limited. Herein, we report the application of ultra-small-angle neutron scattering and small-angle neutron scattering (USANS/SANS) to assess the porosity in five natural sulfide minerals (violarite, marcasite, pyrite, chalcopyrite, and bornite) possibly formed by hydrothermal mineral replacement reactions and two synthetic sulfide minerals (violarite and marcasite) prepared experimentally by mimicking natural hydrothermal conditions. USANS/SANS data showed very different pore size distributions for these minerals. Natural violarite and marcasite tend to possess less pores in the small size range (<100 nm) compared with their synthetic counterparts. This phenomenon is consistent with a higher degree of pore healing or diagenetic compaction experienced by the natural violarite and marcasite. Surprisingly, nanometer-sized (<20 nm) pores were revealed for a natural pyrite cube from La Rioga, Spain, and the sample has a pore volume fraction of similar to 7.7%. Both chalcopyrite and bornite from the massive sulfide assemblage of the Olympic Dam deposit in Roxby Downs, South Australia, were found to be porous with a similar pore volume fraction (similar to 15%), but chalcopyrite tends to have a higher proportion of nanometer-size pores centered at similar to 4 nm while bomite tends to have a broader pore size distribution. The specific surface area is generally low for these minerals ranging from 0.94 to 6.28 m(2)/g, and the surfaces are generally rough as surface fractal behavior was observed for all these minerals. This investigation has demonstrated that USANS/SANS is a very useful tool for analyzing porosity in ore minerals. We believe that with this quantified porosity information a deeper understanding of the complex fluid flow behavior within the porous minerals can be expected. C1 [Xia, Fang; Zhao, Jing; Etschmann, Barbara E.; Brugger, Joel; Pring, Allan] S Australian Museum, Dept Mineral, Adelaide, SA 5000, Australia. [Xia, Fang; Etschmann, Barbara E.; Brugger, Joel] Univ Adelaide, Sch Earth & Environm Sci, Adelaide, SA 5005, Australia. [Xia, Fang] CSIRO Mat Sci & Engn, Clayton, Vic 3168, Australia. [Zhao, Jing] Univ Adelaide, Sch Chem Engn, Adelaide, SA 5005, Australia. [Garvey, Christopher J.; Rehm, Christine] Australian Nucl Sci & Technol Org, Bragg Inst, Kirrawee Dc, NSW 2232, Australia. [Lemmel, Hartmut] Inst Laue Langevin, F-38000 Grenoble, France. [Lemmel, Hartmut] Vienna Univ Technol, Atominst, A-1020 Vienna, Austria. [Ilvasky, Jan] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA. [Han, Young-Soo] Korea Atom Energy Res Inst, Div Neutron Sci, Taejon 305353, South Korea. [Pring, Allan] Flinders Univ S Australia, Sch Chem & Phys Sci, Adelaide, SA 5001, Australia. RP Xia, F (reprint author), S Australian Museum, Dept Mineral, N Terrace, Adelaide, SA 5000, Australia. EM allan.pring@flinders.edu.au RI Garvey, Christopher/E-6475-2010; Brugger, Joel/C-7113-2008 OI Garvey, Christopher/0000-0001-6496-7008; Brugger, Joel/0000-0003-1510-5764 FU Australian Institute of Nuclear Science and Engineering (AINSE); National Research Foundation of Korea (NRF) - Korean government [NRF-2001-0031934, NRF-2012M2A2A6004260]; Australian Research Council [DP1095069] FX We appreciate the assistance of Inna Lykova and Gujie Qian with sample preparation, Tae-Hwan Kim from Korea Atomic Energy Research Institute (KAERI) for beamline setup, Australian Institute of Nuclear Science and Engineering (AINSE) for providing travel funding for SANS experiments at Australian Nuclear Science and Technology Organisation (ANSTO) and at KAERI. We also acknowledge the Atominstitut (Vienna University of Technology) for providing USANS beam time at Institut Laue-Langevin (ILL), and ANSTO and KAERI user offices for assistance with beam time scheduling. Operation of the 40 m SANS instrument at HANARO was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (NRF-2001-0031934 and NRF-2012M2A2A6004260). We appreciate associate editor Daniel Harlov and two anonymous reviewers for their constructive comments. This work is funded by Australian Research Council (DP1095069). NR 59 TC 2 Z9 2 U1 1 U2 17 PU MINERALOGICAL SOC AMER PI CHANTILLY PA 3635 CONCORDE PKWY STE 500, CHANTILLY, VA 20151-1125 USA SN 0003-004X EI 1945-3027 J9 AM MINERAL JI Am. Miner. PD NOV-DEC PY 2014 VL 99 IS 11-12 BP 2398 EP 2404 DI 10.2138/am-2014-4845 PG 7 WC Geochemistry & Geophysics; Mineralogy SC Geochemistry & Geophysics; Mineralogy GA AT6OH UT WOS:000345058200028 ER PT J AU Hyun, SP Davis, JA Hayes, KF AF Hyun, Sung Pil Davis, James A. Hayes, Kim F. TI Abiotic U(VI) reduction by aqueous sulfide SO APPLIED GEOCHEMISTRY LA English DT Article ID RAY-ABSORPTION SPECTROSCOPY; URANIUM(VI) REDUCTION; IMMOBILIZATION; GROUNDWATER; MACKINAWITE; IRON; COMPLEXES; CARBONATE; GOETHITE; KINETICS AB Reactions with aqueous sulfide are important in determining uranium (U) geochemistry under sulfate reducing conditions. This paper reports on abiotic reduction of U(VI) by aqueous sulfide under a range of experimental conditions using batch reactors. Dissolved U concentration was measured as a function of time to study the effects of chemical variables including pH, U(VI), S(-II), total dissolved carbonate (CARB = H2CO3* + HCO3 + CO32 ), and Ca2+ concentration on the U(VI) reduction rate. Solid phase reaction products were characterized using X-ray diffraction, X-ray absorption spectroscopy, and transmission electron microscopy. The chemical variables had impacts on the solid phase U(VI) reaction products as well as the reduction rates by aqueous sulfide. The solid U reaction product at circumneutral pH was identified as uraninite (UO2+x(s)). Under basic pH conditions, whether a precipitate occurred depended on Ca2+ and CARB concentrations. U(VI) reduction was faster under higher S(-II) concentrations but was slowed by increased dissolved Ca2+ or CARB concentration. In the absence of dissolved CARB and Ca2+, a rapid decrease in dissolved U concentration occurred at circumneutral pH, while virtually no decrease was observed at pH 10.7 within the experimental timeframe of two days. The U(VI) reduction rate was proportional to the total concentration of free uranyl plus its hydrolysis complexes even at minor to trace concentrations. Dissolved Ca2+ and CARB slow abiotic U(VI) reduction by forming stable Ca-U(VI)-carbonato soluble complexes that are resistant to reaction with aqueous sulfide. U(VI) reduction was slow in a synthetic solution representative of groundwater at a uranium mill tailings site. This study illustrates that abiotic U reduction by aqueous sulfide can significantly vary under typical ranges of chemical conditions in groundwater and newly demonstrates the importance of dissolved Ca2+ in the abiotic U(VI) reduction by aqueous sulfide. The results contribute to our understanding of the impact of sulfate reducing conditions on U speciation in groundwater systems undergoing bioreduction conversion of U(VI) to less mobile U(IV) solid phases. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Hyun, Sung Pil; Hayes, Kim F.] Univ Michigan, Dept Civil & Environm Engn, Ann Arbor, MI 48109 USA. [Hyun, Sung Pil] Korea Inst Geosci & Mineral Resources, Groundwater Dept, Taejon 305350, South Korea. [Davis, James A.] Lawrence Berkeley Natl Lab, Div Earth Sci, Berkeley, CA USA. RP Hyun, SP (reprint author), Korea Inst Geosci & Mineral Resources, 124 Gwahang No, Taejon 305350, South Korea. EM sphyun@kigam.re.kr; jadavis@lbl.gov; ford@umich.edu RI Davis, James/G-2788-2015 FU U.S. Department of Energy (DOE) Office of Science, Environmental Remediation Sciences Program (ERSP); KIGAM's Basic Research Project [14-3218]; DOE Office of Biological and Environmental Research; National Institutes of Health, National Center for Research Resources, Biomedical Technology Program [P41RR001209] FX This research was funded by the U.S. Department of Energy (DOE) Office of Science, Environmental Remediation Sciences Program (ERSP) via two projects "The Integrated Field-scale Subsurface Research Challenge (IFRC) Site at Rifle, Colorado, USA" and "Assessing the Role of Iron Sulfides in the Long Term Sequestration of Uranium by Sulfate-Reducing Bacteria," and in part by KIGAM's Basic Research Project (14-3218). Portions of this research were carried out at the Stanford Synchrotron Radiation Lightsource, a Directorate of SLAC National Accelerator Laboratory and an Office of Science User Facility operated for the U.S. Department of Energy Office of Science by Stanford University. The SSRL Structural Molecular Biology Program is supported by the DOE Office of Biological and Environmental Research, and by the National Institutes of Health, National Center for Research Resources, Biomedical Technology Program (P41RR001209). NR 41 TC 4 Z9 4 U1 4 U2 25 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0883-2927 J9 APPL GEOCHEM JI Appl. Geochem. PD NOV PY 2014 VL 50 BP 7 EP 15 DI 10.1016/j.apgeochem.2014.07.021 PG 9 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA AT4YH UT WOS:000344948100002 ER PT J AU Visser, A Fourre, E Barbecot, F Aquilina, L Labasque, T Vergnaud, V Esser, BK AF Visser, Ate Fourre, Elise Barbecot, Florent Aquilina, Luc Labasque, Thierry Vergnaud, Virginie Esser, Bradley K. CA Participating Labs TI Intercomparison of tritium and noble gases analyses, H-3/He-3 ages and derived parameters excess air and recharge temperature SO APPLIED GEOCHEMISTRY LA English DT Article ID HELIUM-ISOTOPES; SHALLOW GROUNDWATER; TRITIOGENIC HE-3; NATURAL-WATERS; SAMPLES; PALEOTEMPERATURE; VALIDATION; AQUIFER; NEON AB Groundwater age dating with the tritium-helium (H-3/He-3) method has become a powerful tool for hydrogeologists. The uncertainty of the apparent H-3/He-3 age depends on the analytical precision of the H-3 measurement and the uncertainty of the tritiogenic He-3 component. The goal of this study, as part of the groundwater age-dating interlaboratory comparison exercise, was to quantify the analytical uncertainty of the H-3 and noble gas measurements and to assess whether they meet the requirements for H-3/He-3 dating and noble gas paleotemperature reconstruction. Samples for the groundwater dating intercomparison exercise were collected on 1 February, 2012, from three previously studied wells in the Paris Basin (France). Fourteen laboratories participated in the intercomparison for tritium analyses and ten laboratories participated in the noble gas intercomparison. Not all laboratories analyzed samples from every borehole. The reproducibility of the tritium measurements was 13.5%. The reproducibility of the He-3/He-4 ratio and He-4, Ne, Ar, Kr and Xe concentrations was 1.4%, 1.8%, 1.5%, 2.2%, 2.9%, and 2.4% respectively. The uncertainty of the tritium and noble gas measurements results in a typical H-3/He-3 age precision of better than 2.5 years in this case. However, the measurement uncertainties for the noble gas concentrations are insufficient to distinguish the appropriate excess air model if the measured helium concentration is not included. While the analytical uncertainty introduces an unavoidable source of uncertainty in the 3H/3He apparent age estimate, other sources of uncertainty are often much greater and less well defined than the analytical uncertainty. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Visser, Ate; Esser, Bradley K.] Lawrence Livermore Natl Lab, Div Chem Sci, Livermore, CA 94550 USA. [Fourre, Elise] CEA Orme Merisiers, LSCE, F-91191 Gif Sur Yvette, France. [Barbecot, Florent] Univ Quebec, Geotop, Montreal, PQ H3C 3P8, Canada. [Aquilina, Luc; Labasque, Thierry; Vergnaud, Virginie] Geosci Rennes, OSUR, F-35042 Rennes, France. RP Visser, A (reprint author), Lawrence Livermore Natl Lab, Div Chem Sci, 7000 East Ave, Livermore, CA 94550 USA. EM visser3@llnl.gov; Elise.Fourre@lsce.ipsl.fr; barbecot.florent@uqam.ca; luc.aquilina@univ-rennes1.fr; thierry.labasque@univ-rennes1.fr; virginie.vergnaud@univ-rennes1.fr; esser1@llnl.gov RI Visser, Ate/G-8826-2012 FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX Part of this work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. LLNL-JRNL-640319. NR 31 TC 10 Z9 10 U1 0 U2 20 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0883-2927 J9 APPL GEOCHEM JI Appl. Geochem. PD NOV PY 2014 VL 50 BP 130 EP 141 DI 10.1016/j.apgeochem.2014.03.005 PG 12 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA AT4YH UT WOS:000344948100014 ER PT J AU Massoudieh, A Visser, A Sharifi, S Broers, HP AF Massoudieh, Arash Visser, Ate Sharifi, Soroosh Broers, Hans Peter TI A Bayesian modeling approach for estimation of a shape-free groundwater age distribution using multiple tracers SO APPLIED GEOCHEMISTRY LA English DT Article ID ATLANTIC COASTAL-PLAIN; ENVIRONMENTAL TRACERS; HYDROLOGIC TRACERS; SCALE DISPERSION; TRANSIT-TIME; AQUIFER; TRANSPORT; TRITIUM; AR-39; ISOTOPES AB Due to the mixing of groundwaters with different ages in aquifers, groundwater age is more appropriately represented by a distribution rather than a scalar number. To infer a groundwater age distribution from environmental tracers, a mathematical form is often assumed for the shape of the distribution and the parameters of the mathematical distribution are estimated using deterministic or stochastic inverse methods. The prescription of the mathematical form limits the exploration of the age distribution to the shapes that can be described by the selected distribution. In this paper, the use of freeform histograms as groundwater age distributions is evaluated. A Bayesian Markov Chain Monte Carlo approach is used to estimate the fraction of groundwater in each histogram bin. The method was able to capture the shape of a hypothetical gamma distribution from the concentrations of four age tracers. The number of bins that can be considered in this approach is limited based on the number of tracers available. The histogram method was also tested on tracer data sets from Holten (The Netherlands; H-3, He-3, Kr-85, Ar-39) and the La Selva Biological Station (Costa-Rica; SF6, CFCs, H-3, He-4 and C-14), and compared to a number of mathematical forms. According to standard Bayesian measures of model goodness, the best mathematical distribution performs better than the histogram distributions in terms of the ability to capture the observed tracer data relative to their complexity. Among the histogram distributions, the four bin histogram performs better in most of the cases. The Monte Carlo simulations showed strong correlations in the posterior estimates of bin contributions, indicating that these bins cannot be well constrained using the available age tracers. The fact that mathematical forms overall perform better than the freeform histogram does not undermine the benefit of the freeform approach, especially for the cases where a larger amount of observed data is available and when the real groundwater distribution is more complex than can be represented by simple mathematical forms. (C) 2013 Elsevier Ltd. All rights reserved. C1 [Massoudieh, Arash; Sharifi, Soroosh] Catholic Univ Amer, Washington, DC 20064 USA. [Visser, Ate] Lawrence Livermore Natl Lab, Div Chem Sci, Livermore, CA 94550 USA. [Broers, Hans Peter] Deltares, Unit Soil & Groundwater Syst, Utrecht, Netherlands. [Broers, Hans Peter] TNO, Geol Survey Netherlands, Utrecht, Netherlands. [Broers, Hans Peter] Vrije Univ Amsterdam, Crit Zone Hydrol Grp, Amsterdam, Netherlands. RP Massoudieh, A (reprint author), Catholic Univ Amer, Washington, DC 20064 USA. EM massoudieh@cua.edu RI Visser, Ate/G-8826-2012; OI Massoudieh, Arash/0000-0003-0200-2141 FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX Part of this work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. LLNL-JRNL-637575. NR 72 TC 17 Z9 17 U1 0 U2 12 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0883-2927 J9 APPL GEOCHEM JI Appl. Geochem. PD NOV PY 2014 VL 50 BP 252 EP 264 DI 10.1016/j.apgeochem.2013.10.004 PG 13 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA AT4YH UT WOS:000344948100024 ER PT J AU Demirkiran, O Topcu, G Azarpira, A Choudhary, MI AF Demirkiran, Ozlem Topcu, Gulacti Azarpira, Ali Choudhary, M. Iqbal TI Tyrosinase Inhibitory Activity of Chemical Constituents of Euphorbia macrostegia SO CHEMISTRY OF NATURAL COMPOUNDS LA English DT Article DE Euphorbia macrostegia Boiss.; long chain fatty acids; flavonoid glycosides; tyrosinase inhibitory activity; 2-(4-hydroxyphenyl)ethylhentriacontanoate AB The chloroform extract of the aerial parts of E. macrostegia has yielded a new compound, 2-(4-hydroxyphenyl)-ethylhentriacontanoate (1), along with hentriacontan-1-ol (2), lupenone (3), cycloart-22-ene-3,25-diol (4), 3,3',4'-tri-O-methylellagic acid (5), cleomiscosin (6), and glucoclioniasterol (stigmast-5-en-3-O-beta-glucopyranoside) (7), and from the ethyl acetate extract of aerial parts of the plant isoquercetin (8), quercetin-3-O-alpha-arabinofuranoside (avicularin) (9), and rutin (10) have been isolated. Compounds 1-10 were tested for their tyrosinase inhibitory activity, and 2 exhibited an IC50 value of 71.4 mu M, almost comparable to standard kojic acid (IC50 58.2 mu M). Compounds 1-4 also showed good activity with IC50 values of 77.2, 78.6, 71.4, and 77.5 mu M, respectively. C1 [Demirkiran, Ozlem] Trakya Univ, Dept Pharmacognosy, Fac Pharm, TR-22030 Edirne, Turkey. [Topcu, Gulacti] Bezmialem Vakif Univ, Dept Pharmacognosy, Fac Pharm, TR-34093 Fatih Istanbul, Turkey. [Azarpira, Ali; Choudhary, M. Iqbal] Univ Karachi, Int Ctr Chem Sci, HEJ Res Inst Chem, Karachi 75270, Pakistan. [Azarpira, Ali] Univ Wisconsin, DOE Great Lakes Bioenergy Res Ctr, Madison, WI 53726 USA. [Choudhary, M. Iqbal] King Said Univ, Dept Chem, Coll Sci, Riyadh 11451, Saudi Arabia. RP Demirkiran, O (reprint author), Trakya Univ, Dept Pharmacognosy, Fac Pharm, TR-22030 Edirne, Turkey. EM ozlemdemirkiran@trakya.edu.tr RI Topcu, Gulacti/C-8344-2015 OI Topcu, Gulacti/0000-0002-7946-6545 FU International Center for Chemical and Biological Sciences (Pakistan) FX One of the authors (Ozlem Demirkiran) is grateful to the International Center for Chemical and Biological Sciences (Pakistan) for financial support and for providing access to the world class research facilities. NR 17 TC 0 Z9 0 U1 1 U2 23 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0009-3130 EI 1573-8388 J9 CHEM NAT COMPD+ JI Chem. Nat. Compd. PD NOV PY 2014 VL 50 IS 5 BP 810 EP 813 DI 10.1007/s10600-014-1089-3 PG 4 WC Chemistry, Medicinal; Chemistry, Organic SC Pharmacology & Pharmacy; Chemistry GA AT7TH UT WOS:000345139600004 ER PT J AU Lu, ZT Schlosser, P Smethie, WM Sturchio, NC Fischer, TP Kennedy, BM Purtschert, R Severinghaus, JP Solomon, DK Tanhua, T Yokochi, R AF Lu, Z. -T. Schlosser, P. Smethie, W. M., Jr. Sturchio, N. C. Fischer, T. P. Kennedy, B. M. Purtschert, R. Severinghaus, J. P. Solomon, D. K. Tanhua, T. Yokochi, R. TI Tracer applications of noble gas radionuclides in the geosciences SO EARTH-SCIENCE REVIEWS LA English DT Article DE Isotope analysis; Cosmogenic isotope; Noble gas isotope; Groundwater residence time; Ocean ventillation; Old glacial ice ID DATING YOUNG GROUNDWATER; GREAT ARTESIAN BASIN; ENVIRONMENTAL TRACERS; SHALLOW GROUNDWATER; TRANSIENT TRACERS; ICE CORE; SULFUR-HEXAFLUORIDE; ANTHROPOGENIC CO2; DIRECT SIMULATION; SUBDUCTION ZONES AB Noble gas radionuclides, including Kr-81 (t(1/2) = 229,000 years), Kr-85 (t(1/2) = 10.8 years), and Ar-39 (t(1/2) = 269 years), possess nearly ideal chemical and physical properties for studies of earth and environmental processes. Recent advances in Atom Trap Trace Analysis (ATTA), a laser-based atom counting method, have enabled routine measurements of the radiolaypton isotopes, as well as the demonstration of the ability to measure Ar-39 in environmental samples. Here we provide an overview of the ATTA technique, and a survey of recent progress made in several laboratories worldwide. We review the application of noble gas radionuclides in the geosciences and discuss how ATTA can help advance these fields, specifically: determination of groundwater residence times using Kr-81, Kr-85, and Ar-39; dating old glacial ice using Kr-81; and an Ar-39 survey of the main water masses of the oceans, to study circulation pathways and estimate mean residence times. Other scientific questions involving a deeper circulation of fluids in the Earth's crust and mantle are also within the scope of future applications. We conclude that the geoscience community would greatly benefit from an ATTA facility dedicated to this field, with instrumentation for routine measurements, as well as for research on further development of ATTA methods. (C) 2013 Elsevier B.V. All rights reserved. C1 [Lu, Z. -T.] Argonne Natl Lab, Div Phys, Argonne, IL 60439 USA. [Lu, Z. -T.] Univ Chicago, Dept Phys, Chicago, IL 60637 USA. [Lu, Z. -T.] Univ Chicago, Enrico Fermi Inst, Chicago, IL 60637 USA. [Schlosser, P.; Smethie, W. M., Jr.] Columbia Univ, Lamont Doherty Earth Observ, Palisades, NY 10964 USA. [Sturchio, N. C.; Yokochi, R.] Columbia Univ, Dept Earth & Environm Sci, New York, NY 10027 USA. [Schlosser, P.] Columbia Univ, Dept Earth & Environm Engn, New York, NY 10027 USA. [Sturchio, N. C.] Univ Illinois, Dept Earth & Environm Sci, Chicago, IL 60607 USA. [Fischer, T. P.] Univ New Mexico, Dept Earth & Planetary Sci, Albuquerque, NM 87131 USA. [Kennedy, B. M.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Ctr Isotope Geochem, Berkeley, CA 94720 USA. [Purtschert, R.] Univ Bern, Inst Phys, Bern, Switzerland. [Severinghaus, J. P.] Univ Calif San Diego, Dept Geol & Geophys, San Diego, CA 92093 USA. [Solomon, D. K.] Univ Utah, Dept Geol & Geophys, Salt Lake City, UT 84112 USA. [Tanhua, T.] GEOMAR Helmholtz Ctr Ocean Res Kiel, Kiel, Germany. [Yokochi, R.] Univ Chicago, Dept Geophys Sci, Chicago, IL 60637 USA. RP Lu, ZT (reprint author), Argonne Natl Lab, Div Phys, Argonne, IL 60439 USA. EM lu@anl.gov RI Purtschert, Roland/N-7108-2016; Solomon, Douglas/C-7951-2016 OI Purtschert, Roland/0000-0002-4734-7664; Solomon, Douglas/0000-0001-6370-7124 FU Laboratory-Directed Research and Development Program of Argonne National Laboratory; U.S. Department of Energy, Office of Nuclear Physics [DEAC02-06CH11357]; U.S. National Science Foundation [EAR-1231372] FX This paper is the outcome of a workshop supported by the Laboratory-Directed Research and Development Program of Argonne National Laboratory; the U.S. Department of Energy, Office of Nuclear Physics, under contract DEAC02-06CH11357; and the U.S. National Science Foundation under grant EAR-1231372. We are grateful to all participants of the workshop for stimulating discussions, and to those who have made presentations and contributed materials based on which this article is written. The presenters include, in addition to the authors, W. Aeschbach-Hertig, P. Aggarwal, Ch. Buizert, M. Holzer, S.-M. Hu, W. Jiang, R. Kipfer, M. Kohler, W. Kutschera, A. Loose, A.J. Love, P. Mueller, T.M. Parris, F. Ritterbusch, C. Sukenik, and G. Winckler. Some presentations and a complete list of attendees are posted online at http://www.phy.anl.gov/events/tangr2012/. NR 156 TC 17 Z9 17 U1 7 U2 56 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0012-8252 EI 1872-6828 J9 EARTH-SCI REV JI Earth-Sci. Rev. PD NOV PY 2014 VL 138 BP 196 EP 214 DI 10.1016/j.earscirev.2013.09.002 PG 19 WC Geosciences, Multidisciplinary SC Geology GA AT6OL UT WOS:000345058600010 ER PT J AU Shen, CC Liang, WJ Shi, Y Lin, XG Zhang, HY Wu, X Xie, G Chain, P Grogan, P Chu, HY AF Shen, Congcong Liang, Wenju Shi, Yu Lin, Xiangui Zhang, Huayong Wu, Xian Xie, Gary Chain, Patrick Grogan, Paul Chu, Haiyan TI Contrasting elevational diversity patterns between eukaryotic soil microbes and plants SO ECOLOGY LA English DT Article DE Changbai Mountain, China; elevational diversity gradient; eukaryotic soil microbes; fungi; metazoans; protists; pyrosequencing; soil pH ID SPECIES-RICHNESS PATTERNS; COMMUNITY STRUCTURE; FUNGAL COMMUNITIES; CHANGBAI MOUNTAIN; BACTERIAL COMMUNITIES; ALTITUDINAL GRADIENT; MOLECULAR TECHNIQUES; GLOBAL DIVERSITY; NORTHEAST CHINA; TUNDRA SOILS AB The diversity of eukaryotic macroorganisms such as animals and plants usually declines with increasing elevation and latitude. By contrast, the community structure of prokaryotes such as soil bacteria does not generally correlate with elevation or latitude, suggesting that differences in fundamental cell biology and/or body size strongly influence diversity patterns. To distinguish the influences of these two factors, soil eukaryotic microorganism community structure was investigated in six representative vegetation sites along an elevational gradient from forest to alpine tundra on Changbai Mountain in Northeast China, and compared with our previous determination of soil bacterial community structure along the same gradient. Using bar-coded pyrosequencing, we found strong site differences in eukaryotic microbial community composition. However, diversity of the total eukaryotic microorganism community (or just the fungi or protists alone) did not correlate with elevation. Instead, the patterns of diversity and composition in the total eukaryotic microbial community (and in the protist community alone) were closely correlated with soil pH, suggesting that just as for bacteria, acidity is a particularly important determinant of eukaryotic microbial distributions. By contrast, as expected, plant diversity at the same sites declined along our elevational gradient. These results together suggest that elevational diversity patterns exhibited by eukaryotic microorganisms are fundamentally different from those of plants. C1 [Shen, Congcong; Shi, Yu; Lin, Xiangui; Zhang, Huayong; Chu, Haiyan] Chinese Acad Sci, Inst Soil Sci, State Key Lab Soil & Sustainable Agr, Nanjing 210008, Jiangsu, Peoples R China. [Liang, Wenju] Chinese Acad Sci, Inst Appl Ecol, State Key Lab Forest & Soil Ecol, Shenyang 110164, Peoples R China. [Shen, Congcong; Shi, Yu] Univ Chinese Acad Sci, Beijing 100049, Peoples R China. [Wu, Xian] Beijing Forestry Univ, Coll Forestry, Beijing 100083, Peoples R China. [Xie, Gary; Chain, Patrick] Los Alamos Natl Lab, Los Alamos, NM 87544 USA. [Grogan, Paul] Queens Univ, Dept Biol, Kingston, ON K7L 3N6, Canada. RP Chu, HY (reprint author), Chinese Acad Sci, Inst Soil Sci, State Key Lab Soil & Sustainable Agr, East Beijing Rd 71, Nanjing 210008, Jiangsu, Peoples R China. EM hychu@issas.ac.cn RI Shi, Yu/P-3378-2015 OI Shi, Yu/0000-0001-9612-8321 FU National Natural Science Foundation of China [41071167, 41371254, 31170484, 31270656]; Strategic Priority Research Program [XDB15010101]; Hundred Talents Program of the Chinese Academy of Sciences FX We thank Shijie Han, Guanhua Dai, and Xinyu Li for assistance with soil sampling, and Huaibo Sun and Yingying Ni for lab assistance. We also thank Jinbo Xiong and Jun Zeng for useful discussion. This study was conducted at the Research Station of Changbai Mountain Forest Ecosystems, Chinese Academy of Sciences. This work was supported by the National Natural Science Foundation of China to H. Chu (41071167, 41371254), W. Liang (31170484), and X. Xia (31270656), the Strategic Priority Research Program (XDB15010101), and the Hundred Talents Program of the Chinese Academy of Sciences to H. Chu. The authors declare no conflicts of interest. NR 74 TC 17 Z9 21 U1 17 U2 128 PU ECOLOGICAL SOC AMER PI WASHINGTON PA 1990 M STREET NW, STE 700, WASHINGTON, DC 20036 USA SN 0012-9658 EI 1939-9170 J9 ECOLOGY JI Ecology PD NOV PY 2014 VL 95 IS 11 BP 3190 EP 3202 PG 13 WC Ecology SC Environmental Sciences & Ecology GA AU0PO UT WOS:000345326000019 ER PT J AU Velsko, SP Osburn, J Allen, J AF Velsko, Stephan P. Osburn, Joanne Allen, Jonathan TI Forensic interpretation of molecular variation on networks of disease transmission and genetic inheritance SO ELECTROPHORESIS LA English DT Article DE Forensic; Genetics; Inference; Networks; Transmission ID SARS CORONAVIRUS; VIRUS; MUTATIONS; SINGAPORE; EVOLUTION; DYNAMICS; OUTBREAK AB This paper describes the inference-on-networks (ION) framework for forensic interpretat ION of molecular typing data in cases involving allegations of infectious microbial transmission, association of disease outbreaks with alleged sources, and identifying familial relationships using mitochondrial or Y chromosomal DNA. The framework is applicable to molecular typing data obtained using any technique, including those based on electrophoretic separations. A key insight is that the networks associated with disease transmission or DNA inheritance can be used to define specific testable relationships and avoid the ambiguity and subjectivity associated with the criteria used for inferring genetic relatedness now in use. We discuss specific applications of the framework to the 2003 severe acute respiratory syndrome (SARS) outbreak in Singapore and the 2001 foot-and-mouth disease virus (FMDV) outbreak in Great Britain. C1 [Velsko, Stephan P.; Osburn, Joanne; Allen, Jonathan] Lawrence Livermore Natl Lab, Global Secur Directorate, Livermore, CA 94550 USA. RP Velsko, SP (reprint author), Lawrence Livermore Natl Lab, 5508 East Ave, Livermore, CA 94550 USA. EM Velsko2@llnl.gov FU Department of Homeland Security; U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work was supported by a grant from the Department of Homeland Security during 2008 and 2009. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. NR 28 TC 0 Z9 0 U1 1 U2 5 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0173-0835 EI 1522-2683 J9 ELECTROPHORESIS JI Electrophoresis PD NOV PY 2014 VL 35 IS 21-22 SI SI BP 3117 EP 3124 DI 10.1002/elps.201400205 PG 8 WC Biochemical Research Methods; Chemistry, Analytical SC Biochemistry & Molecular Biology; Chemistry GA AT9UP UT WOS:000345272200014 PM 25137141 ER PT J AU Kim, J Struzhkin, VV Ovchinnikov, SG Orlov, Y Shvyd'ko, Y Upton, MH Casa, D Gavriliuk, AG Sinogeikin, SV AF Kim, Jungho Struzhkin, Viktor V. Ovchinnikov, Sergey G. Orlov, Yu. Shvyd'ko, Yu. Upton, M. H. Casa, D. Gavriliuk, Alexander G. Sinogeikin, S. V. TI Pressure-induced spin transition and evolution of the electronic excitations of FeBO3: Resonant inelastic x-ray scattering results SO EPL LA English DT Article ID LOWER-MANTLE; SPECTRA; STATE; EMISSION; COLLAPSE; SYSTEMS; OXIDES; METAL AB A high-pressure resonant inelastic x-ray scattering (RIXS) of FeBO3 at the Fe K pre-edge has been carried out to study the evolution of electronic excitations through the pressure-induced spin transition. Systematic peak shifts with insignificant peak width change are observed with increasing pressure in the high-spin state. An electronic transition occurs in tandem with the high-spin to low-spin transition, observed as the emergence of multiple new low-energy peaks in the spectra. The energy gap is reduced due to these low-energy peaks, not a peak width broadening. The observed electronic excitations are associated with dd excitations, which are calculated using a full-multiplet theory. We consider changes in crystal-field splitting and covalency to explain the observed peak shifts in the high-spin state. The new peaks that emerge upon the high- to low-spin transition are compared with dd excitations for the low-spin configuration. Copyright (C) EPLA, 2014 C1 [Kim, Jungho; Shvyd'ko, Yu.; Upton, M. H.; Casa, D.] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA. [Struzhkin, Viktor V.; Gavriliuk, Alexander G.] Carnegie Inst Sci, Geophys Lab, Washington, DC 20015 USA. [Ovchinnikov, Sergey G.; Orlov, Yu.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia. [Ovchinnikov, Sergey G.] Siberian Fed Univ, Krasnoyarsk 660041, Russia. [Gavriliuk, Alexander G.] Russian Acad Sci Troitsk, Inst Nucl Res, Moscow 142190, Russia. [Gavriliuk, Alexander G.] Russian Acad Sci, Inst Crystallog, Moscow 119333, Russia. [Sinogeikin, S. V.] Carnegie Inst Sci, HPCAT, Argonne, IL 60439 USA. RP Kim, J (reprint author), Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA. EM vstruzhkin@carnegiescience.edu; gavriliuk@mail.ru RI Casa, Diego/F-9060-2016; Gavriliuk, Alexander/G-1317-2011 OI Gavriliuk, Alexander/0000-0003-0604-586X FU DOE [DE-FG02-02ER45955]; U.S. DOE [DE-AC02-06CH11357]; President of Russia Grants [NSh-1044.2012.2, MK-1168.2012.2]; Presidium of the Russian Academy of Sciences Program 2, RFFI [12-02-90410, 12-02-31543]; Siberian Federal University Grant [F11]; Russian Foundation for Basic Research grants from RAS programs [14-0200483, 15-02-03770]; FCP [GK-P891] FX High-pressure work was supported by DOE under Contract No. DE-FG02-02ER45955. The use of the Advanced Photon Source at the Argonne National Laboratory was supported by the U.S. DOE under Contract No. DE-AC02-06CH11357. SGO and YuO acknowledge the President of Russia Grants NSh-1044.2012.2 and MK-1168.2012.2, the Presidium of the Russian Academy of Sciences Program 2, RFFI Grants 12-02-90410 and 12-02-31543, FCP GK-P891, and the Siberian Federal University Grant F11. AGG acknowledges support from the Russian Foundation for Basic Research grants 14-02-00483 and 15-02-03770 from RAS programs "Strongly correlated electron systems", "Elementary particle physics, fundamental nuclear physics and nuclear technologies". NR 47 TC 1 Z9 1 U1 2 U2 19 PU EPL ASSOCIATION, EUROPEAN PHYSICAL SOCIETY PI MULHOUSE PA 6 RUE DES FRERES LUMIERE, MULHOUSE, 68200, FRANCE SN 0295-5075 EI 1286-4854 J9 EPL-EUROPHYS LETT JI EPL PD NOV PY 2014 VL 108 IS 3 AR 37001 DI 10.1209/0295-5075/108/37001 PG 6 WC Physics, Multidisciplinary SC Physics GA AT4ML UT WOS:000344913400026 ER PT J AU Wojtsekhowski, B AF Wojtsekhowski, B. TI On measurement of the isotropy of the speed of light SO EPL LA English DT Article ID POSITION MONITOR SYSTEM; CLOCK SYNCHRONIZATION; BACKGROUND-RADIATION; ANISOTROPY; ELECTRON; FACILITY; TESTS AB Three experimental concepts investigating possible anisotropy of the speed of light are presented. They are based on i) beam deflection in a 180 degrees magnetic arc, ii) narrow resonance production in an electron-positron collider, and iii) the ratio of magnetic moments of an electron and a positron moving in opposite directions. Copyright (C) EPLA, 2014 C1 Thomas Jefferson Natl Accelerator Facil, Newport News, VA 23606 USA. RP Wojtsekhowski, B (reprint author), Thomas Jefferson Natl Accelerator Facil, Newport News, VA 23606 USA. EM bogdanw@jlab.org FU U.S. Department of Energy; U.S. DOE [DE-AC05-060R23177] FX The author takes pleasure in acknowledging helpful discussions with V. G. GURZADYAN of the GRAAL experiment and with C. KEPPEL, B. VLAHOVIC, and V. ZELEVINSKY of the current concepts. He would like to extend thanks to P. EVTUSHENKO and Y. ROBLIN for information on CEBAF parameters. This work was supported by the U.S. Department of Energy. Jefferson Science Associates, LLC, operates Jefferson Lab for the U.S. DOE under U.S. DOE contract DE-AC05-060R23177. NR 20 TC 1 Z9 1 U1 1 U2 5 PU EPL ASSOCIATION, EUROPEAN PHYSICAL SOCIETY PI MULHOUSE PA 6 RUE DES FRERES LUMIERE, MULHOUSE, 68200, FRANCE SN 0295-5075 EI 1286-4854 J9 EPL-EUROPHYS LETT JI EPL PD NOV PY 2014 VL 108 IS 3 AR 31001 DI 10.1209/0295-5075/108/31001 PG 3 WC Physics, Multidisciplinary SC Physics GA AT4ML UT WOS:000344913400008 ER PT J AU Potel, M Wong, PC AF Potel, Mike Wong, Pak Chung TI Visualizing 20 Years of Applications SO IEEE COMPUTER GRAPHICS AND APPLICATIONS LA English DT Editorial Material C1 [Potel, Mike] Wildcrest Associates, Los Altos Hills, CA 94022 USA. [Wong, Pak Chung] Pacific NW Natl Lab, Richland, WA 99352 USA. RP Potel, M (reprint author), Wildcrest Associates, Los Altos Hills, CA 94022 USA. EM potel@wildcrest.com; pak.wong@pnnl.gov NR 2 TC 1 Z9 1 U1 0 U2 1 PU IEEE COMPUTER SOC PI LOS ALAMITOS PA 10662 LOS VAQUEROS CIRCLE, PO BOX 3014, LOS ALAMITOS, CA 90720-1314 USA SN 0272-1716 EI 1558-1756 J9 IEEE COMPUT GRAPH JI IEEE Comput. Graph. Appl. PD NOV-DEC PY 2014 VL 34 IS 6 BP 6 EP 11 PG 6 WC Computer Science, Software Engineering SC Computer Science GA AT6SK UT WOS:000345069000002 PM 25548822 ER PT J AU VanGordon, JA Kovaleski, SD Norgard, P Kwon, JW Dale, GE AF VanGordon, James A. Kovaleski, Scott D. Norgard, Peter Kwon, Jae Wan Dale, Gregory E. TI Method for Approximating Electron Beam Currents Accelerated by a Piezoelectric Transformer SO IEEE TRANSACTIONS ON PLASMA SCIENCE LA English DT Article DE Electron beams; piezoelectric devices; Q factor ID LOSSES AB Piezoelectric transformers (PTs) are currently used to accelerate charged-particle beams for various applications. Beam interactions at the output of the PT can be treated as a parallel RC electrical load. The impedance of the load can affect the output voltage because of the small, finite amount of charge available in the PT; therefore, high-impedance diagnostics are required to characterize the PT. A thermionic electron emitter was used to provide a controllable beam current for testing the effects of electrical loading on the PT. The electron beam was operated in vacuum at pressures of 10(-6)-10(-5) torr. The input mechanical quality factor and the effective output electrical quality factor were used to approximate the electron beam current on the basis on the PTs equivalent electromechanical circuit. The output voltage needed for the output electrical quality factor was measured via bremsstrahlung interactions at the output electrode of the PT. Optical techniques for finding internal operating parameters such as electric field and stress were used to determine the load with curve fitting as a comparison with the quality factor diagnostic. Approximating the electron beam current with such methods will help determining the output power that such PTs can generate for future applications. C1 [VanGordon, James A.; Kovaleski, Scott D.; Norgard, Peter; Kwon, Jae Wan] Univ Missouri, Dept Elect & Comp Engn, Columbia, MO 65211 USA. [Dale, Gregory E.] Los Alamos Natl Lab, High Power Electrodynam Grp, Los Alamos, NM 87544 USA. RP VanGordon, JA (reprint author), Univ Missouri, Dept Elect & Comp Engn, Columbia, MO 65211 USA. EM jav4zc@mail.missouri.edu; kovaleskis@missouri.edu; norgardp@missouri.edu; kwonj@missouri.edu; gedale@lanl.gov OI Norgard, Peter/0000-0002-5332-5998 FU Los Alamos National Laboratory, Los Alamos, NM, USA; Office of Naval Research, Arlington, VA, USA FX This work was supported in part by the Los Alamos National Laboratory, Los Alamos, NM, USA, and in part by the Office of Naval Research, Arlington, VA, USA. NR 22 TC 2 Z9 2 U1 0 U2 2 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 0093-3813 EI 1939-9375 J9 IEEE T PLASMA SCI JI IEEE Trans. Plasma Sci. PD NOV PY 2014 VL 42 IS 11 BP 3579 EP 3584 DI 10.1109/TPS.2014.2356579 PG 6 WC Physics, Fluids & Plasmas SC Physics GA AT6RZ UT WOS:000345067700018 ER PT J AU Tolstukhin, IA Somov, AS Somov, SV Bolozdynya, AI AF Tolstukhin, I. A. Somov, A. S. Somov, S. V. Bolozdynya, A. I. TI Recording of relativistic particles in thin scintillators SO INSTRUMENTS AND EXPERIMENTAL TECHNIQUES LA English DT Article AB Results of investigating an assembly of thin scintillators and silicon photomultipliers for registering relativistic particles with the minimum ionization are presented. A high efficiency of registering relativistic particles using an Ej-212 plastic scintillator, BSF-91A wavelength-shifting fiber (Saint-Gobain), and a silicon photomultiplier (Hamamtsu) is shown. The measurement results are used for creating a scintillation hodoscope of the magnetic spectrometer for registering gamma quanta in the GlueX experiment. C1 [Tolstukhin, I. A.; Somov, S. V.; Bolozdynya, A. I.] Natl Res Nucl Univ Moscow Engn Phys Inst, Moscow 115409, Russia. [Somov, A. S.] Thomas Jefferson Natl Accelerator Facil, Newport News, VA 23606 USA. RP Tolstukhin, IA (reprint author), Natl Res Nucl Univ Moscow Engn Phys Inst, Kashirskoe Sh 31, Moscow 115409, Russia. EM ivantolstukhin@gmail.com FU Jefferson Science Associated LLC; United States Department of Energy [DE_AC05_06OR23177]; National Research Nuclear University Moscow Engineering Physics Institute [11.G34.31.0049]; Russian Federation Education Ministry [11.G34.31.0049] FX This work was fulfilled in cooperation of the National Research Nuclear University Moscow Engineering Physics Institute and Thomas Jefferson National Accelerator Facility within the framework of the GlueX experiment and supported by the Jefferson Science Associated LLC, which carries out the operation of the Thomas Jefferson Accelerator Facility for the United States Department of Energy, contract U.S. DOE no. DE_AC05_06OR23177 and supported in part by the contract of the National Research Nuclear University Moscow Engineering Physics Institute and Russian Federation Education Ministry, project no. 11.G34.31.0049, October 19, 2011. NR 8 TC 2 Z9 2 U1 0 U2 3 PU MAIK NAUKA/INTERPERIODICA/SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013-1578 USA SN 0020-4412 EI 1608-3180 J9 INSTRUM EXP TECH+ JI Instrum. Exp. Tech. PD NOV PY 2014 VL 57 IS 6 BP 658 EP 661 DI 10.1134/S0020441214060153 PG 4 WC Engineering, Multidisciplinary; Instruments & Instrumentation SC Engineering; Instruments & Instrumentation GA AT7UB UT WOS:000345141500002 ER PT J AU Dinan, J Grant, RE Balaji, P Goodell, D Miller, D Snir, M Thakur, R AF Dinan, James Grant, Ryan E. Balaji, Pavan Goodell, David Miller, Douglas Snir, Marc Thakur, Rajeev TI Enabling communication concurrency through flexible MPI endpoints SO INTERNATIONAL JOURNAL OF HIGH PERFORMANCE COMPUTING APPLICATIONS LA English DT Article DE MPI; endpoints; hybrid parallel programming; interoperability; communication concurrency AB MPI defines a one-to-one relationship between MPI processes and ranks. This model captures many use cases effectively; however, it also limits communication concurrency and interoperability between MPI and programming models that utilize threads. This paper describes the MPI endpoints extension, which relaxes the longstanding one-to-one relationship between MPI processes and ranks. Using endpoints, an MPI implementation can map separate communication contexts to threads, allowing them to drive communication independently. Endpoints also enable threads to be addressable in MPI operations, enhancing interoperability between MPI and other programming models. These characteristics are illustrated through several examples and an empirical study that contrasts current multithreaded communication performance with the need for high degrees of communication concurrency to achieve peak communication performance. C1 [Dinan, James] Intel Corp, Hudson, MA 01749 USA. [Grant, Ryan E.] Sandia Natl Labs, Scalable Software Syst Grp, Albuquerque, NM 87185 USA. [Balaji, Pavan] Argonne Natl Lab, Lemont, IL USA. [Goodell, David] Cisco Syst Inc, San Jose, CA USA. [Miller, Douglas] IBM Corp, Rochester, MN USA. [Snir, Marc; Thakur, Rajeev] Argonne Natl Lab, Math & Comp Sci Div, Lemont, IL USA. RP Dinan, J (reprint author), Intel Corp, 75 Reed Rd, Hudson, MA 01749 USA. EM james.dinan@intel.com FU US Department of Energy [DE-AC02-06CH11307]; US Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX This work was supported by the US Department of Energy (contract number DE-AC02-06CH11307). Sandia National Laboratories is a multiprogram laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the US Department of Energy's National Nuclear Security Administration (contract number DE-AC04-94AL85000). NR 29 TC 2 Z9 2 U1 0 U2 0 PU SAGE PUBLICATIONS LTD PI LONDON PA 1 OLIVERS YARD, 55 CITY ROAD, LONDON EC1Y 1SP, ENGLAND SN 1094-3420 EI 1741-2846 J9 INT J HIGH PERFORM C JI Int. J. High Perform. Comput. Appl. PD NOV PY 2014 VL 28 IS 4 SI SI BP 390 EP 405 DI 10.1177/1094342014548772 PG 16 WC Computer Science, Hardware & Architecture; Computer Science, Interdisciplinary Applications; Computer Science, Theory & Methods SC Computer Science GA AT9DS UT WOS:000345228800002 ER PT J AU Barrett, BW Brightwell, R Grant, R Hammond, SD Hemmert, KS AF Barrett, Brian W. Brightwell, Ron Grant, Ryan Hammond, Simon D. Hemmert, K. Scott TI An evaluation of MPI message rate on hybrid-core processors SO INTERNATIONAL JOURNAL OF HIGH PERFORMANCE COMPUTING APPLICATIONS LA English DT Editorial Material DE MPI; Xeon Phi; network; HPC; Message Rate ID IMPLEMENTATION AB Power and energy concerns are motivating chip manufacturers to consider future hybrid-core processor designs that may combine a small number of traditional cores optimized for single-thread performance with a large number of simpler cores optimized for throughput performance. This trend is likely to impact the way in which compute resources for network protocol processing functions are allocated and managed. In particular, the performance of MPI match processing is critical to achieving high message throughput. In this paper, we analyze the ability of simple and more complex cores to perform MPI matching operations for various scenarios in order to gain insight into how MPI implementations for future hybrid-core processors should be designed. C1 [Barrett, Brian W.; Brightwell, Ron; Grant, Ryan] Sandia Natl Labs, Scalable Syst Software, Albuquerque, NM 87185 USA. [Hammond, Simon D.; Hemmert, K. Scott] Sandia Natl Labs, Scalable Comp Architecture, Albuquerque, NM 87185 USA. RP Barrett, BW (reprint author), Sandia Natl Labs, Scalable Syst Software, POB 5800, Albuquerque, NM 87185 USA. EM bwbarre@sandia.gov NR 11 TC 2 Z9 2 U1 0 U2 2 PU SAGE PUBLICATIONS LTD PI LONDON PA 1 OLIVERS YARD, 55 CITY ROAD, LONDON EC1Y 1SP, ENGLAND SN 1094-3420 EI 1741-2846 J9 INT J HIGH PERFORM C JI Int. J. High Perform. Comput. Appl. PD NOV PY 2014 VL 28 IS 4 SI SI BP 415 EP 424 DI 10.1177/1094342014552085 PG 10 WC Computer Science, Hardware & Architecture; Computer Science, Interdisciplinary Applications; Computer Science, Theory & Methods SC Computer Science GA AT9DS UT WOS:000345228800004 ER PT J AU Zounmevo, JA Kimpe, D Ross, R Afsahi, A AF Zounmevo, Judicael A. Kimpe, Dries Ross, Robert Afsahi, Ahmad TI Extreme-scale computing services over MPI: Experiences, observations and features proposal for next-generation message passing interface SO INTERNATIONAL JOURNAL OF HIGH PERFORMANCE COMPUTING APPLICATIONS LA English DT Article DE Message passing interface (MPI); distributed services; storage; fault-tolerance; cancellation ID IO; IMPLEMENTATION; PERFORMANCE; SYSTEMS AB The message passing interface (MPI) is one of the most portable high-performance computing (HPC) programming models, with platform-optimized implementations typically delivered with new HPC systems. Therefore, for distributed services requiring portable, high-performance, user-level network access, MPI promises to be an attractive alternative to custom network portability layers, platform-specific methods, or portable but less performant interfaces such as BSD sockets. In this paper, we present our experiences in using MPI as a network transport for a large-scale distributed storage system. We discuss the features of MPI that facilitate adoption as well as aspects which require various workarounds. Based on use cases, we derive a wish list for both MPI implementations and the MPI forum to facilitate the adoption of MPI by large-scale persistent services. The proposals in the wish list go beyond the sole needs of distributed services; we contend that they will benefit mainstream HPC applications at extreme scales as well. C1 [Zounmevo, Judicael A.; Afsahi, Ahmad] Queens Univ, ECE Dept, Kingston, ON K7L 3N6, Canada. [Kimpe, Dries; Ross, Robert] Argonne Natl Lab, Argonne, IL 60439 USA. RP Zounmevo, JA (reprint author), Queens Univ, ECE Dept, Kingston, ON K7L 3N6, Canada. EM judicael.zounmevo@queensu.ca FU Natural Sciences and Engineering Research Council of Canada [RGPIN/238964-2011]; Canada Foundation for Innovation; Ontario Innovation Trust [7154]; Office of Advanced Scientific Computing Research, Office of Science, U.S. Department of Energy [DE-AC02-06CH11357] FX This work was supported in part by the Natural Sciences and Engineering Research Council of Canada (grant #RGPIN/238964-2011), by the Canada Foundation for Innovation and by the Ontario Innovation Trust (grant #7154). This work was also supported in part by the Office of Advanced Scientific Computing Research, Office of Science, U.S. Department of Energy (contract DE-AC02-06CH11357). NR 26 TC 0 Z9 0 U1 1 U2 1 PU SAGE PUBLICATIONS LTD PI LONDON PA 1 OLIVERS YARD, 55 CITY ROAD, LONDON EC1Y 1SP, ENGLAND SN 1094-3420 EI 1741-2846 J9 INT J HIGH PERFORM C JI Int. J. High Perform. Comput. Appl. PD NOV PY 2014 VL 28 IS 4 SI SI BP 435 EP 449 DI 10.1177/1094342014548864 PG 15 WC Computer Science, Hardware & Architecture; Computer Science, Interdisciplinary Applications; Computer Science, Theory & Methods SC Computer Science GA AT9DS UT WOS:000345228800006 ER PT J AU Sorescu, DC Byrd, EFC Rice, BM Jordan, KD AF Sorescu, Dan C. Byrd, Edward F. C. Rice, Betsy M. Jordan, Kenneth D. TI Assessing the Performances of Dispersion-Corrected Density Functional Methods for Predicting the Crystallographic Properties of High Nitrogen Energetic Salts SO JOURNAL OF CHEMICAL THEORY AND COMPUTATION LA English DT Article ID GENERALIZED GRADIENT APPROXIMATION; X-RAY-STRUCTURE; AUGMENTED-WAVE METHOD; AB-INITIO; EXCHANGE-ENERGY; HYDRAZINIUM SALTS; BASIS-SET; AZIDE; PSEUDOPOTENTIALS; DFT AB Several density functional methods with corrections for long-range dispersion interactions are evaluated for their capabilities to describe the crystallographic lattice properties of a set of 26 high nitrogen-content salts relevant for energetic materials applications. Computations were done using methods that ranged from adding atomatom dispersion corrections with environment-independent and environment-dependent coefficients, to methods that incorporate dispersion effects via dispersion-corrected atom-centered potentials (DCACP), to methods that include nonlocal corrections. Among the functionals tested, the most successful is the nonlocal optPBE-vdW functional of Klimes and Michaelides that predicts unit cell volumes for all crystals of the reference set within the target error range of +/- 3% and gives individual lattice parameters with a mean average percent error of less than 0.81%. The DCACP, Grimmes D3, and Becke and Johnsons exchange-hole (XDM) methods, when used with the BLYP, PBE, and B86b functionals, respectively, are also quite successful at predicting the lattice parameters of the test set. C1 [Sorescu, Dan C.; Jordan, Kenneth D.] US DOE, Natl Energy Technol Lab, Pittsburgh, PA 15236 USA. [Sorescu, Dan C.; Jordan, Kenneth D.] Univ Pittsburgh, Dept Chem & Petr Engn, Pittsburgh, PA 15261 USA. [Byrd, Edward F. C.; Rice, Betsy M.] US Army Res Lab, RDRL WML B, Aberdeen Proving Ground, MD 21005 USA. [Jordan, Kenneth D.] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA. RP Byrd, EFC (reprint author), US Army Res Lab, RDRL WML B, Aberdeen Proving Ground, MD 21005 USA. EM edward.f.byrd2.civ@mail.mil FU DOD Supercomputing Resource Centers (DSRCs); NSF [CHE-1362334] FX We acknowledge with thanks a supercomputing challenge grant at several DOD Supercomputing Resource Centers (DSRCs). Discussions with Dr. Tomas Bucko (Comenius University), Dr. Fabien Tran (Vienna University of Technology), and Dr. Alberto Otero de la Roza (University of California, Merced) on implementation of dispersion interactions in VASP, CP2K, and Quantum Espresso codes are gratefully acknowledged. K.D.J. acknowledges support from NSF through grant number CHE-1362334. NR 84 TC 11 Z9 11 U1 2 U2 24 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1549-9618 EI 1549-9626 J9 J CHEM THEORY COMPUT JI J. Chem. Theory Comput. PD NOV PY 2014 VL 10 IS 11 BP 4982 EP 4994 DI 10.1021/ct5005615 PG 13 WC Chemistry, Physical; Physics, Atomic, Molecular & Chemical SC Chemistry; Physics GA AT4JI UT WOS:000344905300022 PM 26584381 ER PT J AU Osterholz, WR Kucharik, CJ Hedtcke, JL Posner, JL AF Osterholz, William R. Kucharik, Christopher J. Hedtcke, Janet L. Posner, Joshua L. TI Seasonal Nitrous Oxide and Methane Fluxes from Grain- and Forage-Based Production Systems in Wisconsin, USA SO JOURNAL OF ENVIRONMENTAL QUALITY LA English DT Article ID AVAILABLE MEASUREMENT DATA; GREENHOUSE-GAS EMISSIONS; CROPPING SYSTEMS; AGRONOMIC ASSESSMENT; AGRICULTURAL FIELDS; CARBON-DIOXIDE; N2O EMISSIONS; SOIL QUALITY; LONG-TERM; CORN AB Agriculture in the midwestern United States is a major anthropogenic source of nitrous oxide (N2O) and is both a source and sink for methane (CH4), but the degree to which cropping systems differ in emissions of these gases is not well understood. Our objectives were to determine if fluxes of N2O and CH4 varied among cropping systems and among crop phases within a cropping system. We compare N2O and CH4 fluxes over the 2010 and 2011 growing seasons from the six cropping systems at the Wisconsin Integrated Cropping Systems Trial (WICST), a 20-yr-old cropping systems experiment. The study is composed of three grain and three forage cropping systems spanning a spectrum of crop diversity and perenniality that model a wide range of realistic cropping systems that differ in management, crop rotation, and fertilizer regimes. Among the grain systems, cumulative growing season N2O emissions were greater for continuous corn (Zea mays L.) (3.7 kg N2O-N ha(-1)) than corn-soybean [Glycine max (L.) Merr.] (2.0 kg N2O-N ha(-1)) or organic corn-soybean-wheat (Triticum aestivum L.) (1.7 kg N2O-N ha(-1)). Among the forage systems, cumulative growing-season N2O emissions were greater for organic corn-alfalfa (Medicago sativa L.)-alfalfa (2.9 kg N2O-N ha(-1)) and conventional corn-alfalfa-alfalfa-alfalfa (2.5 kg N2O-N ha(-1)), and lower for rotational pasture (1.9 kg N2O-N ha(-1)). Application of mineral or organic N fertilizer was associated with elevated N2O emissions. Yield-scaled emissions (kg N2O-N Mg-1) did not differ by cropping system. Methane fluxes were highly variable and no effect of cropping system was observed. These results suggest that extended and diversified cropping systems could reduce area-scaled N2O emissions from agriculture, but none of the systems studied significantly reduced yield-scaled N2O emissions. C1 [Osterholz, William R.] Iowa State Univ, Dept Agron, Ames, IA 50011 USA. [Kucharik, Christopher J.; Hedtcke, Janet L.; Posner, Joshua L.] Univ Wisconsin, Dept Agron, Madison, WI 53706 USA. [Kucharik, Christopher J.] Univ Wisconsin, Nelson Inst, Ctr Sustainabil & Global Environm, Madison, WI 53726 USA. [Kucharik, Christopher J.] Univ Wisconsin, DOE Great Lakes Bioenergy Res Ctr, Madison, WI 53705 USA. RP Osterholz, WR (reprint author), Iowa State Univ, Dept Agron, 2104 Agron Hall, Ames, IA 50011 USA. EM wosterho@iastate.edu OI Osterholz, William/0000-0003-2218-9396; Kucharik, Christopher/0000-0002-0400-758X FU USDA-ARS (North Central. Region) [03655-12630-003-03]; University of Wisconsin-Madison College of Agricultural and Life Sciences; DOE Great Lakes Bic/energy Research Center (DOE BER Office of Science) [DE-147,02-07ER64494]; DOE OBP Office of Energy Efficiency and Renewable Energy [DE-ACO5-76R1.01830] FX Funding for this research was provided by the USDA-ARS (North Central. Region) via a Specific Cooperative Agreement (03655-12630-003-03) with the U.S. Dairy Forage Research Center and by the University of Wisconsin-Madison College of Agricultural and Life Sciences. Internal support was provided by the University of Wisconsin Arlington Agricultural Research Station. This work was also partially supported by the DOE Great Lakes Bic/energy Research Center (DOE BER Office of Science DE-147,02-07ER64494 and DOE OBP Office of Energy Efficiency and Renewable Energy DE-ACO5-76R1.01830). NR 47 TC 3 Z9 3 U1 6 U2 42 PU AMER SOC AGRONOMY PI MADISON PA 677 S SEGOE RD, MADISON, WI 53711 USA SN 0047-2425 EI 1537-2537 J9 J ENVIRON QUAL JI J. Environ. Qual. PD NOV-DEC PY 2014 VL 43 IS 6 BP 1833 EP 1843 DI 10.2134/jeq2014.02.0077 PG 11 WC Environmental Sciences SC Environmental Sciences & Ecology GA AT7DD UT WOS:000345096000002 PM 25602200 ER PT J AU Abelev, B Adam, J Adamova, D Aggarwal, MM Agnello, M Agostinelli, A Agrawal, N Ahammed, Z Ahmad, N Ahmed, I Ahn, SU Ahn, SA Aimo, I Aiola, S Ajaz, M Akindinov, A Alam, SN Aleksandrov, D Alessandro, B Alexandre, D Alici, A Alkin, A Alme, J Alt, T Altinpinar, S Altsybeev, I Prado, CAG Andrei, C Andronic, A Anguelov, V Anielski, J Anticic, T Antinori, F Antonioli, P Aphecetche, L Appelshauser, H Arbor, N Arcelli, S Armesto, N Arnaldi, R Aronsson, T Arsene, IC Arslandok, M Augustinus, A Averbeck, R Awes, TC Azmi, MD Bach, M Badala, A Baek, YW Bagnasco, S Bailhache, R Bala, R Baldisseri, A Pedrosa, FBDS Baral, RC Barbera, R Barile, F Barnafoldi, GG Barnby, LS Barret, V Bartke, J Basile, M Bastid, N Basu, S Bathen, B Batigne, G Batyunya, B Batzing, PC Baumann, C Bearden, IG Beck, H Bedda, C Behera, NK Belikov, I Bellini, F Bellwied, R Belmont-Moreno, E Belmont, R Bencedi, G Beole, S Berceanu, I Bercuci, A Berdnikov, Y Berenyi, D Berger, ME Bertens, A Berzano, D Betev, L Bhasin, A Bhat, IR Bhati, AK Bhattacharjee, B Bhom, J Bianchi, L Bianchi, N Bianchin, C Bielcik, J Bielcikova, J Bilandzic, A Bjelogrlic, S Blanco, F Blau, D Blume, C Bock, F Bogdanov, A Boggild, H Bogolyubsky, M Bohmer, FV Boldizsar, L Bombara, M Book, J Borel, H Borissov, A Bossu, F Botje, M Botta, E Bottger, S Braun-Munzinger, P Bregant, M Breitner, T Broker, TA Browning, TA Broz, M Bruna, E Bruno, GE Budnikov, D Buesching, H Bufalino, S Buncic, P Busch, O Buthelezi, Z Caffarri, D Cai, X Caines, H Diaz, LC Caliva, A Villar, EC Camerini, P Carena, F Carena, W Castellanos, JC Casula, EAR Catanescu, V Cavicchioli, C Sanchez, CC Cepila, J Cerello, P Chang, B Chapeland, S Charvet, JL Chattopadhyay, S Chattopadhyay, S Chelnokov, V Cherney, M Cheshkov, C Cheynis, B Barroso, VC Chinellato, DD Chochula, P Chojnacki, M Choudhury, S Christakoglou, P Christensen, CH Christiansen, P Chujo, T Chung, SU Cicalo, C Cifarelli, L Cindolo, F Cleymans, J Colamaria, F Colella, D Collu, A Colocci, M Balbastre, GC del Valle, ZC Connors, ME Contreras, JG Cormier, TM Morales, YC Cortese, P Maldonado, IC Cosentino, MR Costa, F Crochet, P Albino, RC Cuautle, E Cunqueiro, L Dainese, A Dang, R Danu, A Das, D Das, I Das, K Das, S Dash, A Dash, S De, S Delagrange, H Deloff, A Denes, E D'Erasmo, G De Caro, A de Cataldo, G de Cuveland, J De Falco, A De Gruttola, D De Marco, N De Pasquale, S de Rooij, R Corchero, MAD Dietel, T Dillenseger, P Divia, R Di Bari, D Di Liberto, S Di Mauro, A Di Nezza, P Djuvsland, O Dobrin, A Dobrowolski, T Gimenez, DD Donigus, B Dordic, O Dorheim, S Dubey, AK Dubla, A Ducroux, L Dupieux, P Majumdar, AKD Ehlers, RJ Elia, D Engel, H Erazmus, B Erdal, HA Eschweiler, D Espagnon, B Esposito, M Estienne, M Esumi, S Evans, D Evdokimov, S Fabris, D Faivre, J Falchieri, D Fantoni, A Fasel, M Fehlker, D Feldkamp, L Felea, D Feliciello, A Feofilov, G Ferencei, J Tellez, AF Ferreiro, EG Ferretti, A Festanti, A Figiel, J Figueredo, MAS Filchagin, S Finogeev, D Fionda, FM Fiore, EM Floratos, E Floris, M Foertsch, S Foka, P Fokin, S Fragiacomo, E Francescon, A Frankenfeld, U Fuchs, U Furget, C Girard, MF Gaardhoje, JJ Gagliardi, M Gago, AM Gallio, M Gangadharan, DR Ganoti, P Garabatos, C Garcia-Solis, E Gargiulo, C Garishvili, I Gerhard, J Germain, M Gheata, A Gheata, M Ghidini, B Ghosh, P Ghosh, SK Gianotti, P Giubellino, P Gladysz-Dziadus, E Glassel, P Ramirez, AG Gonzalez-Zamora, P Gorbunov, S Gorlich, L Gotovac, S Graczykowski, LK Grelli, A Grigoras, A Grigoras, C Grigoriev, V Grigoryan, A Grigoryan, S Grinyov, B Grion, N Grosse-Oetringhaus, JF Grossiord, JY Grosso, R Guber, F Guernane, R Guerzoni, B Guilbaud, M Gulbrandsen, K Gulkanyan, H Gumbo, M Gunji, T Gupta, A Gupta, R Hanratty, LD Hansen, A Harris, JW Hartmann, H Harton, A Hatzifotiadou, D Hayashi, S Heckel, ST Heide, M Helstrup, H Herghelegiu, A Corral, GH Hess, BA Hetland, KF Hippolyte, B Hladky, J Hristov, P Huang, M Humanic, TJ Hutter, D Hwang, DS Ilkaev, R Ilkiv, I Inaba, M Innocenti, GM Ionita, C Ippolitov, M Irfan, M Ivanov, M Ivanov, V Jacholkowski, A Jacobs, PM Jahnke, C Jang, HJ Janik, MA Jayarathna, PHSY Jena, S Bustamante, RTJ Jones, PG Jung, H Jusko, A Kadyshevskiy, V Kalcher, S Kalinak, P Kalweit, A Kamin, J Kang, JH Kaplin, V Kar, S Uysal, AK Karavichev, O Karavicheva, T Karpechev, E Kebschull, U Keidel, R Khan, MM Khan, P Khan, SA Khanzadeev, A Kharlov, Y Kileng, B Kim, B Kim, DW Kim, DJ Kim, JS Kim, M Kim, M Kim, S Kim, T Kirsch, S Kisel, I Kiselev, S Kisiel, A Kiss, G Klay, JL Klein, J Klein-Bosing, C Kluge, A Knichel, ML Knospe, AG Kobdaj, C Kohler, MK Kollegger, T Kolojvari, A Kondratiev, V Kondratyeva, N Konevskikh, A Kovalenko, V Kowalski, M Kox, S Meethaleveedu, GK Kral, J Kralik, I Kramer, F Kravcakova, A Krelina, M Kretz, M Krivda, M Krizek, F Kryshen, E Krzewicki, M Kucera, V Kucheriaev, Y Kugathasan, T Kuhn, C Kuijer, PG Kulakov, I Kumar, J Kurashvili, P Kurepin, A Kurepin, AB Kuryakin, A Kushpil, S Kweon, MJ Kwon, Y de Guevara, PL Fernandes, CL Lakomov, I Langoy, R Lara, C Lardeux, A Lattuca, A La Pointe, SL La Rocca, P Lea, R Leardini, L Lee, GR Legrand, I Lehnert, J Lemmon, RC Lenti, V Leogrande, E Leoncino, M Monzon, IL Levai, P Li, S Lien, J Lietava, R Lindal, S Lindenstruth, V Lippmann, C Lisa, MA Ljunggren, HM Lodato, DF Loenne, PI Loggins, VR Loginov, V Lohner, D Loizides, C Lopez, X Torres, EL Lu, XG Luettig, P Lunardon, M Luparello, G Luzzi, C Ma, R Maevskaya, A Mager, M Mahapatra, DP Mahmood, SM Maire, A Majka, RD Malaev, M Cervantes, IM Malinina, L Mal'Kevich, D Malzacher, P Mamonov, A Manceau, L Manko, V Manso, F Manzari, V Marchisone, M Mares, J Margagliotti, GV Margotti, A Marin, A Markert, C Marquard, M Martashvili, I Martin, NA Martinengo, P Martinez, MI Garcia, GM Blanco, JM Martynov, Y Mas, A Masciocchi, S Masera, M Masoni, A Massacrier, L Mastroserio, A Matyja, A Mayer, C Mazer, J Mazzoni, MA Meddi, F Menchaca-Rocha, A Perez, JM Meres, M Miake, Y Mikhaylov, K Milano, L Milosevic, J Mischke, A Mishra, AN Miskowiec, D Mitra, J Mitu, CM Mlynarz, J Mohammadi, N Mohanty, B Molnar, L Zetina, LM Montes, E Morando, M De Godoy, DAM Moretto, S Morreale, A Morsch, A Muccifora, V Mudnic, E Muhlheim, D Muhuri, S Mukherjee, M Muller, H Munhoz, MG Murray, S Musa, L Musinsky, J Nandi, BK Nania, R Nappi, E Nattrass, C Nayak, K Nayak, TK Nazarenko, S Nedosekin, A Nicassio, M Niculescu, M Nielsen, BS Nikolaev, S Nikulin, S Nikulin, V Nilsen, BS Noferini, F Nomokonov, P Nooren, G Nyanin, A Nystrand, J Oeschler, H Oh, S Oh, SK Okatan, A Olah, L Oleniacz, J Da Silva, ACO Onderwaater, J Oppedisano, C Velasquez, AO Oskarsson, A Otwinowski, J Oyama, K Sahoo, P Pachmayer, Y Pachr, M Pagano, P Paic, G Painke, F Pajares, C Pal, SK Palmeri, A Pant, D Papikyan, V Pappalardo, GS Pareek, P Park, WJ Parmar, S Passfeld, A Patalakha, DI Paticchio, V 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Zhao, C. Zhigareva, N. Zhou, D. Zhou, F. Zhou, Y. Zhuo, Zhou Zhu, H. Zhu, J. Zhu, X. Zichichi, A. Zimmermann, A. Zimmermann, M. B. Zinovjev, G. Zoccarato, Y. Zyzak, M. CA Alice Collaboration TI Measurement of visible cross sections in proton-lead collisions at root s(NN)=5.02 TeV in van der Meer scans with the ALICE detector SO JOURNAL OF INSTRUMENTATION LA English DT Article DE Large detector systems for particle and astroparticle physics; Particle tracking detectors; Heavy-ion detectors AB In 2013, the Large Hadron Collider provided proton-lead and lead-proton collisions at the center-of-mass energy per nucleon pair root s(NN) = 5.02 TeV. Van der Meer scans were performed for both configurations of colliding beams, and the cross section was measured for two reference processes, based on particle detection by the T0 and V0 detectors, with pseudo-rapidity coverage 4.6 < eta < 4.9, -3.3 < eta < -3.0 and 2.8 < eta < 5.1, -3.7 < eta < -1.7, respectively. Given the asymmetric detector acceptance, the cross section was measured separately for the two configurations. The measured visible cross sections are used to calculate the integrated luminosity of the proton-lead and lead-proton data samples, and to indirectly measure the cross section for a third, configuration-independent, reference process, based on neutron detection by the Zero Degree Calorimeters. C1 [Berdnikov, Y.] St Petersburg State Polytech Univ, St Petersburg, Russia. [Khan, M. M.] Aligarh Muslim Univ, Dept Appl Phys, Aligarh, Uttar Pradesh, India. [Malinina, L.] Moscow MV Lomonosov State Univ, DV Skobeltsyn Inst Nucl Phys, Moscow, Russia. [Milosevic, J.] Univ Belgrade, Fac Phys, Belgrade, Serbia. [Milosevic, J.] Vinca Inst Nucl Sci, Belgrade, Serbia. [Oh, S. K.] Konkuk Univ, Seoul, South Korea. [Redlich, K.] Univ Wroclaw, Inst Theoret Phys, PL-50138 Wroclaw, Poland. [Takaki, J. D. Tapia] Univ Kansas, Lawrence, KS 66045 USA. 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W.; Suleymanov, M.; Zaman, A.] COMSATS Inst Informat Technol, Islamabad, Pakistan. [Armesto, N.; Ferreiro, E. G.; Pajares, C.; Salgado, C. A.] Univ Santiago de Compostela, Dept Fis Particulas, Santiago De Compostela, Spain. [Armesto, N.; Ferreiro, E. G.; Pajares, C.; Salgado, C. A.] Univ Santiago de Compostela, IGFAE, Santiago De Compostela, Spain. [Altinpinar, S.; Djuvsland, O.; Fehlker, D.; Huang, M.; Loenne, P. I.; Oeschler, H.; Rehman, A.; Rohrich, D.; Skjerdal, K.; Ullaland, K.; Velure, A.; Wagner, B.; Yang, S.; Zhuo, Zhou] Univ Bergen, Dept Phys & Technol, Bergen, Norway. [Ahmad, N.; Irfan, M.; Khan, M. M.] Aligarh Muslim Univ, Dept Phys, Aligarh 202002, Uttar Pradesh, India. [Gangadharan, D. R.; Humanic, T. J.; Lisa, M. A.; Salzwedel, J.; Steinpreis, M.] Ohio State Univ, Dept Phys, Columbus, OH 43210 USA. [Hwang, D. S.; Kim, S.] Sejong Univ, Dept Phys, Seoul, South Korea. [Batzing, P. C.; Dordic, O.; Lindal, S.; Mahmood, S. M.; Milosevic, J.; Qvigstad, H.; Richter, M.; Roed, K.; Skaali, T. B.; Tveter, T. S.; Wikne, J.; Zhao, C.] Univ Oslo, Dept Phys, Oslo, Norway. [Meddi, F.] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy. [Di Liberto, S.; Mazzoni, M. A.; Meddi, F.] Sezione Ist Nazl Fis Nucl, Rome, Italy. [Casula, E. A. R.; Collu, A.; De Falco, A.; Gumbo, M.; Puddu, G.; Razazi, V.; Terrevoli, C.; Usai, G. L.; Voloshin, K.] Univ Calgary, Dipartimento Fis, Cagliari, Italy. [Casula, E. A. R.; Cicalo, C.; Collu, A.; De Falco, A.; Gumbo, M.; Masoni, A.; Puddu, G.; Razazi, V.; Siddhanta, S.; Terrevoli, C.; Usai, G. L.; Voloshin, K.] Sezione Ist Nazl Fis Nucl, Cagliari, Italy. [Camerini, P.; Lea, R.; Margagliotti, G. V.; Rui, R.; Venaruzzo, M.] Univ Trieste, Dipartmento Fis, I-34127 Trieste, Italy. [Camerini, P.; Fragiacomo, E.; Grion, N.; Lea, R.; Margagliotti, G. V.; Piano, S.; Rachevski, A.; Rui, R.; Venaruzzo, M.] Sezione Ist Nazl Fis Nucl, Trieste, Italy. [Beole, S.; Berzano, D.; Bianchi, L.; Botta, E.; Morales, Y. Corrales; Ferretti, A.; Gagliardi, M.; Gallio, M.; Innocenti, G. M.; Lattuca, A.; Leoncino, M.; Marchisone, M.; Masera, M.; Russo, R.; Shtejer, K.; Vercellin, E.] Univ Turin, Dipartimento Fis, Turin, Italy. [Agnello, M.; Aimo, I.; Alessandro, B.; Arnaldi, R.; Bagnasco, S.; Beole, S.; Berzano, D.; Bianchi, L.; Botta, E.; Bruna, E.; Bufalino, S.; Cerello, P.; Morales, Y. Corrales; De Marco, N.; Feliciello, A.; Ferretti, A.; Gagliardi, M.; Gallio, M.; Innocenti, G. M.; Lattuca, A.; Leoncino, M.; Manceau, L.; Marchisone, M.; Masera, M.; Oppedisano, C.; Prino, F.; Rivetti, A.; Russo, R.; Scomparin, E.; Shtejer, K.; Vercellin, E.] Sezione Ist Nazl Fis Nucl, Turin, Italy. [Agostinelli, A.; Arcelli, S.; Basile, M.; Bellini, F.; Cifarelli, L.; Colocci, M.; Falchieri, D.; Guerzoni, B.; Scioli, G.; Zichichi, A.] Univ Bologna, Dipartimento Fis & Astron, Bologna, Italy. [Agostinelli, A.; Alici, A.; Antonioli, P.; Arcelli, S.; Basile, M.; Bellini, F.; Cifarelli, L.; Cindolo, F.; Colocci, M.; Falchieri, D.; Guerzoni, B.; Hatzifotiadou, D.; Margotti, A.; Nania, R.; Nomokonov, P.; Pesci, A.; Pinazza, O.; Preghenella, R.; Scapparone, E.; Scioli, G.; Williams, M. C. S.; Zampolli, C.; Zichichi, A.] Sezione Ist Nazl Fis Nucl, Bologna, Italy. [Barbera, R.; Jacholkowski, A.; La Rocca, P.; Petta, C.; Riggi, F.; Santagati, G.] Univ Catania, Dipartimento Fis & Astron, Catania, Italy. [Badala, A.; Barbera, R.; Jacholkowski, A.; La Rocca, P.; Palmeri, A.; Pappalardo, G. S.; Petta, C.; Riggi, F.; Santagati, G.] Sezione Ist Nazl Fis Nucl, Catania, Italy. [Caffarri, D.; Festanti, A.; Francescon, A.; Lunardon, M.; Morando, M.; Moretto, S.; Scarlassara, F.; Segato, G.; Soramel, F.; Viesti, G.] Univ Padua, Dipartimento Fis & Astron, Padua, Italy. [Antinori, F.; Caffarri, D.; Dainese, A.; Fabris, D.; Festanti, A.; Francescon, A.; Lunardon, M.; Morando, M.; Moretto, S.; Scarlassara, F.; Segato, G.; Soramel, F.; Toia, A.; Turrisi, R.; Viesti, G.] Sezione Ist Nazl Fis Nucl, Padua, Italy. [De Caro, A.; De Gruttola, D.; De Pasquale, S.; Girard, M. Fusco; Pagano, P.; Virgili, T.] Univ Salerno, Dipartimento Fis ER Caianiello, I-84100 Salerno, Italy. [De Caro, A.; De Gruttola, D.; De Pasquale, S.; Girard, M. Fusco; Pagano, P.; Virgili, T.] Grp Collegato INFN, Salerno, Italy. [Cortese, P.; Ramello, L.; Sitta, M.] Univ Piemonte Orientale, Dipartimento Sci & Innovaz Tecnol, Alessandria, Italy. [Cortese, P.; Ramello, L.; Sitta, M.] Grp Collegato INFN, Alessandria, Italy. [Barile, F.; Bruno, G. E.; Colamaria, F.; Colella, D.; D'Erasmo, G.; Di Bari, D.; Fionda, F. M.; Fiore, E. M.; Ghidini, B.; Mastroserio, A.; Tangaro, M. A.] Dipartimento Interateneo Fis M Merlin, Bari, Italy. [Christiansen, P.; Ljunggren, H. M.; Velasquez, A. 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N.; Basu, S.; Chattopadhyay, S.; Choudhury, S.; De, S.; Dubey, A. K.; Ghosh, P.; Kar, S.; Khan, S. A.; Mitra, J.; Mohanty, B.; Muhuri, S.; Mukherjee, M.; Nayak, T. K.; Pal, S. K.; Saini, J.; Sarkar, D.; Singaraju, R.; Singha, S.; Singhal, V.; Sinha, B. C.; Viyogi, Y. P.] Ctr Variable Energy Cyclotron, Kolkata, India. [Langoy, R.; Lien, J.] Vestfold Univ Coll, Tonsberg, Norway. [Graczykowski, L. K.; Janik, M. A.; Kisiel, A.; Oleniacz, J.; Pawlak, T.; Pluta, J.; Szymanski, M.; Zbroszczyk, H.] Warsaw Univ Technol, Warsaw, Poland. [Belmont, R., III; Cormier, T. M.; Loggins, V. R.; Mlynarz, J.; Prasad, S. K.; Pruneau, C. A.; Pujahari, P.; Putschke, J.; Verweij, M.; Voloshin, S. A.; Yaldo, C. G.] Wayne State Univ, Detroit, MI USA. [Barnafoeldi, G. G.; Bencedi, G.; Berenyi, D.; Boldizsar, L.; Denes, E.; Kiss, G.; Levai, P.; Olah, L.; Pochybova, S.] Hungarian Acad Sci, Wigner Res Ctr Phys, Budapest, Hungary. [Aiola, S.; Aronsson, T.; Caines, H.; Connors, M. E.; Ehlers, R. J.; Harris, J. W.; Ma, R.; Majka, R. D.; Reed, R. J.; Schuster, T.; Smirnov, N.] Yale Univ, New Haven, CT USA. [Kang, J. H.; Kim, B.; Kim, M.; Kim, T.; Kwon, Y.; Song, M.] Yonsei Univ, Seoul 120749, South Korea. [Keidel, R.] Fachhochschule Worms, ZTT, Worms, Germany. RP Abelev, B (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. RI Mitu, Ciprian/E-6733-2011; Sevcenco, Adrian/C-1832-2012; Ahmed, Ijaz/E-9144-2015; Usai, Gianluca/E-9604-2015; Salgado, Carlos A./G-2168-2015; Bregant, Marco/I-7663-2012; Barnby, Lee/G-2135-2010; Barbera, Roberto/G-5805-2012; Bruna, Elena/C-4939-2014; Karasu Uysal, Ayben/K-3981-2015; Pshenichnov, Igor/A-4063-2008; Guber, Fedor/I-4271-2013; Zarochentsev, Andrey/J-6253-2013; Sumbera, Michal/O-7497-2014; Kovalenko, Vladimir/C-5709-2013; Takahashi, Jun/B-2946-2012; Peitzmann, Thomas/K-2206-2012; Kharlov, Yuri/D-2700-2015; Felea, Daniel/C-1885-2012; Barnafoldi, Gergely Gabor/L-3486-2013; Kucera, Vit/G-8459-2014; Krizek, Filip/G-8967-2014; Bielcikova, Jana/G-9342-2014; Vajzer, Michal/G-8469-2014; Wagner, Vladimir/G-5650-2014; Inst. of Physics, Gleb Wataghin/A-9780-2017; Ferreiro, Elena/C-3797-2017; Armesto, Nestor/C-4341-2017; Ferretti, Alessandro/F-4856-2013; Martinez Hernandez, Mario Ivan/F-4083-2010; Vickovic, Linda/F-3517-2017; Fernandez Tellez, Arturo/E-9700-2017; Altsybeev, Igor/K-6687-2013; Vinogradov, Leonid/K-3047-2013; Kondratiev, Valery/J-8574-2013; Vechernin, Vladimir/J-5832-2013; Graczykowski, Lukasz/O-7522-2015; Janik, Malgorzata/O-7520-2015; feofilov, grigory/A-2549-2013; Adamova, Dagmar/G-9789-2014; Christensen, Christian/D-6461-2012; De Pasquale, Salvatore/B-9165-2008; Chinellato, David/D-3092-2012; de Cuveland, Jan/H-6454-2016; Kurepin, Alexey/H-4852-2013; Jena, Deepika/P-2873-2015; Jena, Satyajit/P-2409-2015; Akindinov, Alexander/J-2674-2016; Nattrass, Christine/J-6752-2016; Cosentino, Mauro/L-2418-2014; Suaide, Alexandre/L-6239-2016; Martynov, Yevgen/L-3009-2015; Castillo Castellanos, Javier/G-8915-2013; OI Sevcenco, Adrian/0000-0002-4151-1056; Usai, Gianluca/0000-0002-8659-8378; Salgado, Carlos A./0000-0003-4586-2758; Barnby, Lee/0000-0001-7357-9904; Barbera, Roberto/0000-0001-5971-6415; Bruna, Elena/0000-0001-5427-1461; Karasu Uysal, Ayben/0000-0001-6297-2532; Pshenichnov, Igor/0000-0003-1752-4524; Guber, Fedor/0000-0001-8790-3218; Zarochentsev, Andrey/0000-0002-3502-8084; Sumbera, Michal/0000-0002-0639-7323; Kovalenko, Vladimir/0000-0001-6012-6615; Takahashi, Jun/0000-0002-4091-1779; Peitzmann, Thomas/0000-0002-7116-899X; Felea, Daniel/0000-0002-3734-9439; Ferreiro, Elena/0000-0002-4449-2356; Armesto, Nestor/0000-0003-0940-0783; Ferretti, Alessandro/0000-0001-9084-5784; Martinez Hernandez, Mario Ivan/0000-0002-8503-3009; Vickovic, Linda/0000-0002-9820-7960; Fernandez Tellez, Arturo/0000-0003-0152-4220; Beole', Stefania/0000-0003-4673-8038; Dainese, Andrea/0000-0002-2166-1874; Altsybeev, Igor/0000-0002-8079-7026; Vinogradov, Leonid/0000-0001-9247-6230; Kondratiev, Valery/0000-0002-0031-0741; Vechernin, Vladimir/0000-0003-1458-8055; Janik, Malgorzata/0000-0002-3356-3438; feofilov, grigory/0000-0003-3700-8623; Christensen, Christian/0000-0002-1850-0121; De Pasquale, Salvatore/0000-0001-9236-0748; Chinellato, David/0000-0002-9982-9577; de Cuveland, Jan/0000-0003-0455-1398; Kurepin, Alexey/0000-0002-1851-4136; Jena, Deepika/0000-0003-2112-0311; Jena, Satyajit/0000-0002-6220-6982; Akindinov, Alexander/0000-0002-7388-3022; Nattrass, Christine/0000-0002-8768-6468; Cosentino, Mauro/0000-0002-7880-8611; Suaide, Alexandre/0000-0003-2847-6556; Martynov, Yevgen/0000-0003-0753-2205; Castillo Castellanos, Javier/0000-0002-5187-2779; Paticchio, Vincenzo/0000-0002-2916-1671; Scarlassara, Fernando/0000-0002-4663-8216; Turrisi, Rosario/0000-0002-5272-337X; D'Erasmo, Ginevra/0000-0003-3407-6962 FU Worldwide LHC Computing Grid (WLCG) collaboration; State Committee of Science; World Federation of Scientists (WFS); Swiss Fonds Kidagan, Armenia; Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq); Financiadora de Estudos e Projetos (FINEP); Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP); National Natural Science Foundation of China (NSFC); Chinese Ministry of Education (CMOE); Ministry of Science and Technology of China (MSTC); Ministry of Education and Youth of the Czech Republic; Danish Natural Science Research Council; Carlsberg Foundation; Danish National Research Foundation; European Research Council under the European Community's Seventh Framework Programme; Helsinki Institute of Physics; Academy of Finland; French CNRS-IN2P3; Region Pays de Loire; Region Alsace; Region Auvergne; CEA, France; German BMBF; Helmholtz Association; General Secretariat for Research and Technology, Ministry of Development, Greece; Hungarian OTKA and National Office for Research and Technology (NKTH); Department of Atomic Energy of the Government of India; Department of Science and Technology of the Government of India; Istituto Nazionale di Fisica Nucleare (INFN); Centro Fermi - Museo Storico della Fisica e Centro Studi e Ricerche "Enrico Fermi", Italy; Ministry of Education, Culture, Sports, Science and Technology (MEXT); Japan Society for the Promotion of Science (JSPS), Japan; Joint Institute for Nuclear Research, Dubna; National Research Foundation of Korea (NRF); CONACYT; DGAPA, Mexico; ALFA-EC; EPLANET Program (European Particle Physics Latin American Network); Stichting voor Fundamenteel Onderzoek der Materie (FOM); Nederlandse Organisatie voor Wetenschappelijk Onderzoek (NWO), Netherlands; Research Council of Norway (NFR); Polish Ministry of Science and Higher Education; National Science Centre, Poland; Ministry of National Education/Institute for Atomic Physics; CNCS-UEFISCDI - Romania; Ministry of Education and Science of Russian Federation; Russian Academy of Sciences; Russian Federal Agency of Atomic Energy; Russian Federal Agency for Science and Innovations; Russian Foundation for Basic Research; Ministry of Education of Slovakia; Department of Science and Technology, South Africa; CIEMAT; EELA; Ministerio de Economia y Competitividad (MINECO) of Spain; Xunta de Galicia (Conselleria de Educacion); CEADEN; Cubaenergia, Cuba; IAEA (International Atomic Energy Agency); Swedish Research Council (VR); Knut & Alice Wallenberg Foundation (KAW); Ukraine Ministry of Education and Science; United Kingdom Science and Technology Facilities Council (STFC); United States Department of Energy; United States National Science Foundation; State of Texas; State of Ohio FX The ALICE Collaboration gratefully acknowledges the resources and support provided by all Grid centres and the Worldwide LHC Computing Grid (WLCG) collaboration.; The ALICE Collaboration acknowledges the following funding agencies for their support in building and running the ALICE detector:; State Committee of Science, World Federation of Scientists (WFS) and Swiss Fonds Kidagan, Armenia,; Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq), Financiadora de Estudos e Projetos (FINEP), Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP);; National Natural Science Foundation of China (NSFC), the Chinese Ministry of Education (CMOE) and the Ministry of Science and Technology of China (MSTC);; Ministry of Education and Youth of the Czech Republic;; Danish Natural Science Research Council, the Carlsberg Foundation and the Danish National Research Foundation;; The European Research Council under the European Community's Seventh Framework Programme;; Helsinki Institute of Physics and the Academy of Finland;; French CNRS-IN2P3, the 'Region Pays de Loire', 'Region Alsace', 'Region Auvergne' and CEA, France;; German BMBF and the Helmholtz Association;; General Secretariat for Research and Technology, Ministry of Development, Greece; Hungarian OTKA and National Office for Research and Technology (NKTH);; Department of Atomic Energy and Department of Science and Technology of the Government of India;; Istituto Nazionale di Fisica Nucleare (INFN) and Centro Fermi - Museo Storico della Fisica e Centro Studi e Ricerche "Enrico Fermi", Italy;; The Ministry of Education, Culture, Sports, Science and Technology (MEXT) and Japan Society for the Promotion of Science (JSPS), Japan; Joint Institute for Nuclear Research, Dubna;; National Research Foundation of Korea (NRF);; CONACYT, DGAPA, Mexico, ALFA-EC and the EPLANET Program (European Particle Physics Latin American Network); Stichting voor Fundamenteel Onderzoek der Materie (FOM) and the Nederlandse Organisatie voor Wetenschappelijk Onderzoek (NWO), Netherlands;; Research Council of Norway (NFR);; Polish Ministry of Science and Higher Education;; National Science Centre, Poland;; Ministry of National Education/Institute for Atomic Physics and CNCS-UEFISCDI - Romania;; Ministry of Education and Science of Russian Federation, Russian Academy of Sciences, Russian Federal Agency of Atomic Energy, Russian Federal Agency for Science and Innovations and The Russian Foundation for Basic Research;; Ministry of Education of Slovakia;; Department of Science and Technology, South Africa;; CIEMAT, EELA, Ministerio de Economia y Competitividad (MINECO) of Spain, Xunta de Galicia (Conselleria de Educacion), CEADEN, Cubaenergia, Cuba, and IAEA (International Atomic Energy Agency);; Swedish Research Council (VR) and Knut & Alice Wallenberg Foundation (KAW); Ukraine Ministry of Education and Science;; United Kingdom Science and Technology Facilities Council (STFC);; The United States Department of Energy, the United States National Science Foundation, the State of Texas, and the State of Ohio. NR 31 TC 7 Z9 7 U1 0 U2 44 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 1748-0221 J9 J INSTRUM JI J. Instrum. PD NOV PY 2014 VL 9 AR P11003 DI 10.1088/1748-0221/9/11/P11003 PG 25 WC Instruments & Instrumentation SC Instruments & Instrumentation GA AT6CH UT WOS:000345026000017 ER PT J AU Acciarri, R Carls, B James, C Johnson, B Jostlein, H Lockwitz, S Lundberg, B Raaf, JL Rameika, R Rebel, B Zeller, GP Zuckerbrot, M AF Acciarri, R. Carls, B. James, C. Johnson, B. Jostlein, H. Lockwitz, S. Lundberg, B. Raaf, J. L. Rameika, R. Rebel, B. Zeller, G. P. Zuckerbrot, M. TI Liquid argon dielectric breakdown studies with the MicroBooNE purification system SO JOURNAL OF INSTRUMENTATION LA English DT Article DE Noble liquid detectors (scintillation, ionization, double-phase); Time projection Chambers (TPC); Neutrino detectors ID DETECTOR; STRENGTH; HELIUM AB The proliferation of liquid argon time projection chamber detectors makes the characterization of the dielectric properties of liquid argon a critical task. To improve understanding of these properties, a systematic study of the breakdown electric field in liquid argon was conducted using a dedicated cryostat connected to the MicroBooNE cryogenic system at Fermilab. An electrode sphere-plate geometry was implemented using spheres with diameters of 1.3 mm, 5.0 mm, and 76 mm. The MicroBooNE cryogenic system allowed measurements to be taken at a variety of electronegative contamination levels ranging from a few parts-per-million to tens of parts-pertrillion. The cathode-anode distance was varied from 0.1 mm to 2.5 cm. The results demonstrate a geometric dependence of the electric field strength at breakdown. This study is the first time that the dependence of the breakdown field on stressed cathode area has been shown for liquid argon. C1 [Acciarri, R.; Carls, B.; James, C.; Johnson, B.; Jostlein, H.; Lockwitz, S.; Lundberg, B.; Raaf, J. L.; Rameika, R.; Rebel, B.; Zeller, G. P.; Zuckerbrot, M.] Fermilab Natl Accelerator Lab, Batavia, IL 60510 USA. RP Lockwitz, S (reprint author), Fermilab Natl Accelerator Lab, POB 500, Batavia, IL 60510 USA. EM lockwitz@fnal.gov OI Raaf, Jennifer/0000-0002-4533-929X FU United States Department of Energy [De-AC02-07CH11359] FX Fermilab is operated by Fermi Research Alliance, LLC under Contract No. De-AC02-07CH11359 with the United States Department of Energy. NR 11 TC 6 Z9 6 U1 0 U2 2 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 1748-0221 J9 J INSTRUM JI J. Instrum. PD NOV PY 2014 VL 9 AR P11001 DI 10.1088/1748-0221/9/11/P11001 PG 14 WC Instruments & Instrumentation SC Instruments & Instrumentation GA AT6CH UT WOS:000345026000015 ER PT J AU Bagby, LF Gollapinni, S James, CC Jones, BJP Jostlein, H Lockwitz, S Naples, D Raaf, JL Rameika, R Schukraft, A Strauss, T Weber, MS Wolbers, SA AF Bagby, L. F. Gollapinni, S. James, C. C. Jones, B. J. P. Jostlein, H. Lockwitz, S. Naples, D. Raaf, J. L. Rameika, R. Schukraft, A. Strauss, T. Weber, M. S. Wolbers, S. A. TI Breakdown voltage of metal-oxide resistors in liquid argon SO JOURNAL OF INSTRUMENTATION LA English DT Article DE Voltage distributions; Detector design and construction technologies and materials; Neutrino detectors; Time projection chambers AB We characterized a sample of metal-oxide resistors and measured their breakdown voltage in liquid argon by applying high voltage (HV) pulses over a 3 second period. This test mimics the situation in a HV-divider chain when a breakdown occurs and the voltage across resistors rapidly rise from the static value to much higher values. All resistors had higher breakdown voltages in liquid argon than their vendor ratings in air at room temperature. Failure modes range from full destruction to coating damage. In cases where breakdown was not catastrophic, subsequent breakdown voltages were lower in subsequent measuring runs. One resistor type withstands 131 kV pulses, the limit of the test setup. C1 [Bagby, L. F.; James, C. C.; Jostlein, H.; Lockwitz, S.; Raaf, J. L.; Rameika, R.; Schukraft, A.; Wolbers, S. A.] Fermilab Natl Accelerator Lab, Batavia, IL 60510 USA. [Gollapinni, S.] Kansas State Univ, Dept Phys, Manhattan, KS 66506 USA. [Jones, B. J. P.] MIT, Cambridge, MA 02139 USA. [Naples, D.] Univ Pittsburgh, Dept Phys, Pittsburgh, PA 15260 USA. [Strauss, T.; Weber, M. S.] Univ Bern, Albert Einstein Ctr Fundamental Phys Bern, LHEP, CH-3012 Bern, Switzerland. RP Strauss, T (reprint author), Univ Bern, Albert Einstein Ctr Fundamental Phys Bern, LHEP, Sidlerstr 5, CH-3012 Bern, Switzerland. EM thomas.strauss@lhep.unibe.ch OI Schukraft, Anne/0000-0002-9112-5479; Raaf, Jennifer/0000-0002-4533-929X; Weber, Michele/0000-0002-2770-9031 FU Fermilab; United States Department of Energy [De-AC02-07CH11359] FX We thank Fermilab for providing funding for the liquid argon and the infrastructure for this measurement. Fermilab is operated by Fermi Research Alliance, LLC under Contract No. De-AC02-07CH11359 with the United States Department of Energy. We thank LHEP Bern for providing the Metallux resistors. NR 2 TC 2 Z9 2 U1 0 U2 0 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 1748-0221 J9 J INSTRUM JI J. Instrum. PD NOV PY 2014 VL 9 AR T11004 DI 10.1088/1748-0221/9/11/T11004 PG 10 WC Instruments & Instrumentation SC Instruments & Instrumentation GA AT6CH UT WOS:000345026000038 ER PT J AU Dai, T Han, L Hou, S Liu, M Li, Q Song, H Xia, L Zhang, Z AF Dai, T. Han, L. Hou, S. Liu, M. Li, Q. Song, H. Xia, L. Zhang, Z. TI Low resistance bakelite RPC study for high rate working capability SO JOURNAL OF INSTRUMENTATION LA English DT Article DE Resistive-plate chambers; Trigger detectors AB This paper presentsseries efforts to lower resistance of bakelite electrode plate to improve the RPC capability under high rate working condition. New bakelite material with alkali metallic ion doping has been manufactured and tested. This bakelite is found unstable under large charge flux and need further investigation. Alternatively, a new structure of carbon-embedded bakelite RPC has been developed, which can reduce the effective resistance of electrode by a factor of 10. The prototype of the carbon-embedded chamber could function well under gamma radiation source at event rate higher than 10 kHz/cm(2). The preliminary tests show that this kind of new structure performs as efficiently as traditional RPCs. C1 [Xia, L.] Argonne Natl Lab, Downers Grove Township, IL USA. [Hou, S.] Acad Sinica, Inst Phys, Taipei, Taiwan. [Han, L.; Liu, M.; Li, Q.; Song, H.; Zhang, Z.] Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China. [Dai, T.] Univ Michigan, Ann Arbor, MI 48109 USA. RP Song, H (reprint author), Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China. EM h.song@cern.ch NR 3 TC 1 Z9 1 U1 0 U2 1 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 1748-0221 J9 J INSTRUM JI J. Instrum. PD NOV PY 2014 VL 9 AR C11013 DI 10.1088/1748-0221/9/11/C11013 PG 8 WC Instruments & Instrumentation SC Instruments & Instrumentation GA AT6CH UT WOS:000345026000013 ER PT J AU Moore, MH Waidyawansa, BP Covrig, S Carlini, R Benesch, J AF Moore, M. H. Waidyawansa, B. P. Covrig, S. Carlini, R. Benesch, J. TI Primary beam steering due to field leakage from superconducting SHMS magnets SO JOURNAL OF INSTRUMENTATION LA English DT Article DE Spectrometers; Detector modelling and simulations II (electric fields, charge transport, multiplication and induction, pulse formation, electron emission, etc); Accelerator modelling and simulations (multi-particle dynamics; single-particle dynamics) AB Simulations of the magnetic fields from the Super High Momentum Spectrometer in Hall C at Thomas Jefferson National Accelerator Facility show significant field leakage into the region of the primary beam line between the target and the beam dump. Without mitigation, these remnant fields will steer the unscattered beam enough to limit beam operations at small scattering angles. Presented here are magnetic field simulations of the spectrometer magnets and a solution using optimal placement of a minimal amount of shielding iron around the beam line. C1 [Moore, M. H.; Waidyawansa, B. P.; Covrig, S.; Carlini, R.; Benesch, J.] Thomas Jefferson Natl Accelerator Facil, Newport News, VA 23606 USA. [Moore, M. H.] Old Dominion Univ, Norfolk, VA 23508 USA. RP Moore, MH (reprint author), Thomas Jefferson Natl Accelerator Facil, Newport News, VA 23606 USA. EM mhmoore@jlab.gov FU U.S. Department of Energy [DE-AC05-06OR23177]; United States Government FX Notice: This manuscript has been authored by Jefferson Science Associates, LLC under Contract No. DE-AC05-06OR23177 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non- exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. The authors wish to thank Howard Fenker, Bert Meztger and Stephen Wood for their outstanding support. NR 5 TC 0 Z9 0 U1 1 U2 2 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 1748-0221 J9 J INSTRUM JI J. Instrum. PD NOV PY 2014 VL 9 AR T11002 DI 10.1088/1748-0221/9/11/T11002 PG 13 WC Instruments & Instrumentation SC Instruments & Instrumentation GA AT6CH UT WOS:000345026000036 ER PT J AU Thom, J Lipton, R Heintz, U Johnson, M Narain, M Badman, R Spiegel, L Triphati, M Deptuch, G Kenney, C Parker, S Ye, Z Siddons, DP AF Thom, J. Lipton, R. Heintz, U. Johnson, M. Narain, M. Badman, R. Spiegel, L. Triphati, M. Deptuch, G. Kenney, C. Parker, S. Ye, Z. Siddons, D. P. TI 3D IC for future HEP detectors SO JOURNAL OF INSTRUMENTATION LA English DT Article DE Si microstrip and pad detectors; Electronic detector readout concepts (solid-state); Particle tracking detectors (Solid-state detectors) ID SENSORS AB Three dimensional integrated circuit technologies offer the possibility of fabricating large area arrays of sensors integrated with complex electronics with minimal dead area, which makes them ideally suited for applications at the LHC upgraded detectors and other future detectors. We describe ongoing R&D efforts to demonstrate functionality of components of such detectors. This includes the study of integrated 3D electronics with active edge sensors to produce "active tiles" which can be tested and assembled into arrays of arbitrary size with high yield. C1 [Thom, J.; Badman, R.] Cornell Univ, Ithaca, NY 14850 USA. [Lipton, R.; Johnson, M.; Spiegel, L.; Deptuch, G.; Ye, Z.] Fermilab Natl Accelerator Lab, Batavia, IL USA. [Heintz, U.; Narain, M.] Brown Univ, Providence, RI 02912 USA. [Triphati, M.] Univ Calif Davis, Davis, CA USA. [Kenney, C.] SLAC, Menlo Pk, CA USA. [Parker, S.] Univ Hawaii, Honolulu, HI 96822 USA. [Siddons, D. P.] BNL, Upton, NY USA. RP Thom, J (reprint author), Cornell Univ, Ithaca, NY 14850 USA. EM jt297@cornell.edu FU National Science Foundation [PHY-1307256, ECCS-0335765]; Department of Energy [DE-SC0005268, DE-SC0010010]; United States Department of Energy [De-AC02-07CH11359]; U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-98CH10886] FX We thank the National Science Foundation for their support (grant number PHY-1307256), as well as the Department of Energy (grant number DE-SC0005268 and DE-SC0010010). Work was performed in part at the Cornell NanoScale Facility, a member of the National Nanotechnology Infrastructure Network, which is supported by the National Science Foundation (Grant ECCS-0335765). We also acknowledge the Fermi Research Alliance, LLC under Contract No. De-AC02-07CH11359 with the United States Department of Energy. Work at BNL was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-98CH10886. NR 10 TC 0 Z9 0 U1 1 U2 5 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 1748-0221 J9 J INSTRUM JI J. Instrum. PD NOV PY 2014 VL 9 AR C11005 DI 10.1088/1748-0221/9/11/C11005 PG 8 WC Instruments & Instrumentation SC Instruments & Instrumentation GA AT6CH UT WOS:000345026000005 ER PT J AU Wang, X Setru, SU Xie, J Mane, A Demarteau, M Wagner, R AF Wang, X. Setru, S. U. Xie, J. Mane, A. Demarteau, M. Wagner, R. TI Imaging of large-area microchannel plates using phosphor screens SO JOURNAL OF INSTRUMENTATION LA English DT Article DE Secondary electron emitters and dynodes and their production; Timing detectors; Photon detectors for UV, visible and IR photons (vacuum) (photomultipliers, HPDs, others) ID COUNTING DETECTORS; PHOTODETECTORS; TUBE AB A testing system was built, using UV illumination at 254 nm and a cathodoluminescent phosphor screen, to measure the gain uniformity of large area (20 x 20 cm(2)) microchannel plates. The phosphor screen image is captured with a wide-angle CMOS digital camera (4032 x 3024 pixels) and analyzed. First a reference MCP is illuminated and the generated phosphor screen image is captured with a CCD camera. In a second step, another image is captured with the MCP under test inserted between the reference MCP and the phosphor screen. The ratio of the two images is analyzed and provides a quantitative measure of the relative gain uniformity of the MCP under test. C1 [Wang, X.; Setru, S. U.; Xie, J.; Mane, A.; Demarteau, M.; Wagner, R.] Argonne Natl Lab, Argonne, IL 60439 USA. [Wang, X.] Chinese Acad Sci, Xian Inst Opt & Precis Mech, State Key Lab Transient Opt & Photon, Xian 710119, Shaanxi, Peoples R China. RP Xie, J (reprint author), Argonne Natl Lab, 9700 S Cass Ave, Argonne, IL 60439 USA. EM jxie@anl.gov FU U.S. Department of Energy, Office of Science [DE-AC02-06CH11357]; U.S. Department of Energy, Office of Basic Energy Sciences [DE-AC02-06CH11357]; U.S. Department of Energy, Office of High Energy Physics [DE-AC02-06CH11357]; National Natural Science Foundation of China [11304374] FX The authors would like to thank O. Siegmund and J. McPhate and all the collaborators on the LAPPD project for their valuable guidance. The authors would also like to thank F. Skrzecz, mechanical engineer at ANL, for his work on the engineering support. Work at Argonne National Laboratory was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences and Office of High Energy Physics under contract DE-AC02-06CH11357. One of us (X. W.) would like to thank the National Natural Science Foundation of China (Grant no: 11304374) for its support. NR 18 TC 1 Z9 1 U1 0 U2 5 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 1748-0221 J9 J INSTRUM JI J. Instrum. PD NOV PY 2014 VL 9 AR P11011 DI 10.1088/1748-0221/9/11/P11011 PG 11 WC Instruments & Instrumentation SC Instruments & Instrumentation GA AT6CH UT WOS:000345026000025 ER PT J AU Bao, W McLeod, AS Cabrini, S Neaton, JB Schuck, PJ AF Bao, Wei McLeod, A. S. Cabrini, S. Neaton, J. B. Schuck, P. James TI Elucidating heterogeneity in nanoplasmonic structures using nonlinear photon localization microscopy SO JOURNAL OF OPTICS LA English DT Article DE plasmonics; nonlinear nano-optics; plasmonic antennas; photon localization microscopy ID PLASMONIC NANOSTRUCTURES; SURFACE-PLASMONS; DNA-ORIGAMI; ELECTRON-MICROSCOPY; HOT-ELECTRONS; FIELD; GOLD; NANOPARTICLES; NANOANTENNAS; RESONANCE AB Using nonperturbative photon localization microscopy and electromagnetic simulation, it is observed that localized modes in plasmonic devices are significantly impacted by small, and frequently time-dependent, structural variations on the nanometer scale. This is important because many such devices rely on the concentration of electromagnetic energy at the similar to 10 nm length scale and below for applications ranging from ultrasensitive molecular spectroscopy and detection, to chemical nano-imaging and plasmo-catalysis. In all devices, but particularly those based on noble metals, structural heterogeneity at these length scales is unavoidable, emphasizing the need for characterizing and understanding its effects. By exploiting the two-photon photoluminescence signal, one addresses the specific challenge of probing local electromagnetic fields inside the metal, which directly determine hot carrier generation and photoemission. It is found that heterogeneous nanoscale asperities serve as energy localization centers, and that functional impact is influenced primarily by two factors: position relative to a plasmonic mode volume, and how the asperity affects the smallest critical dimension, such as the size of a nanogap, in the structure. C1 [Bao, Wei; McLeod, A. S.; Cabrini, S.; Neaton, J. B.; Schuck, P. James] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA. [Bao, Wei] Univ Calif Berkeley, Dept Mat Sci & Engn, Berkeley, CA 94720 USA. [Neaton, J. B.] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA. RP Bao, W (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA. EM pjschuck@lbl.gov RI Bao, Wei/B-4520-2014; Neaton, Jeffrey/F-8578-2015; Foundry, Molecular/G-9968-2014 OI Neaton, Jeffrey/0000-0001-7585-6135; FU Office of Science, Office of Basic Energy Sciences, of the US Department of Energy [DE-AC02-05CH11231]; National Science Foundation FX Work at the Molecular Foundry was supported by the Office of Science, Office of Basic Energy Sciences, of the US Department of Energy under Contract No. DE-AC02-05CH11231. We acknowledge use of nanoHUB. org resources provided by the Network for Computational Nanotechnology funded by the National Science Foundation. NR 49 TC 2 Z9 2 U1 1 U2 15 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 2040-8978 EI 2040-8986 J9 J OPTICS-UK JI J. Opt. PD NOV PY 2014 VL 16 IS 11 AR 114014 DI 10.1088/2040-8978/16/11/114014 PG 6 WC Optics SC Optics GA AT4MX UT WOS:000344914500015 ER PT J AU Zhou, X Soppera, O Plain, J Jradi, S Sun, XW Demir, HV Yang, XY Deeb, C Gray, SK Wiederrecht, GP Bachelot, R AF Zhou, Xuan Soppera, Olivier Plain, Jerome Jradi, Safi Sun, Xiao Wei Demir, Hilmi Volkan Yang, Xuyong Deeb, Claire Gray, Stephen K. Wiederrecht, Gary P. Bachelot, Renaud TI Plasmon-based photopolymerization: near-field probing, advanced photonic nanostructures and nanophotochemistry SO JOURNAL OF OPTICS LA English DT Review DE nanoplasmonics; free-radical photopolymerization; nanophotochemistry; hybrid plasmonics ID LOCALIZED SURFACE-PLASMON; NOBLE-METAL NANOPARTICLES; PHOTOCHEMICAL-REACTIONS; RESONANCE SPECTROSCOPY; GOLD NANOPARTICLES; MIE PLASMONS; HOT-SPOTS; LIGHT; PHOTOLITHOGRAPHY; NANOLITHOGRAPHY AB Hybrid nanomaterials are targeted by a rapidly growing group of nanooptics researchers, due to the promise of optical behavior that is difficult or even impossible to create with nanostructures of homogeneous composition. Examples of important areas of interest include coherent coupling, Fano resonances, optical gain, solar energy conversion, photocatalysis, and nonlinear optical interactions. In addition to the coupling interactions, the strong dependence of optical resonances and damping on the size, shape, and composition of the building blocks provides promise that the coupling interactions of hybrid nanomaterials can be controlled and manipulated for a desired outcome. Great challenges remain in reliably synthesizing and characterizing hybrid nanomaterials for nanooptics. In this review, we describe the synthesis, characterization, and applications of hybrid nanomaterials created through plasmon-induced photopolymerization. The work is placed within the broader context of hybrid nanomaterials involving plasmonic metal nanoparticles and molecular materials placed within the length scale of the evanescent field from the metal surface. We specifically review three important applications of free radical photopolymerization to create hybrid nanoparticles: local field probing, photoinduced synthesis of advanced hybrid nanoparticles, and nanophotochemistry. C1 [Zhou, Xuan; Plain, Jerome; Jradi, Safi; Deeb, Claire; Bachelot, Renaud] Univ Technol Troyes, CNRS UMR 6281, ICD LNIO, Troyes, France. [Soppera, Olivier] Univ Haute Alsace, CNRS UMR 7361, Inst Sci Mat Mulhouse IS2M, Mulhouse, France. [Sun, Xiao Wei; Demir, Hilmi Volkan; Yang, Xuyong] Nanyang Technol Univ, Sch Elect & Elect Engn, LUMINOUS Ctr Excellence Semicond Lighting & Displ, Singapore 639798, Singapore. [Gray, Stephen K.; Wiederrecht, Gary P.] Argonne Natl Lab, Ctr Nanoscale Mat, Argonne, IL 60439 USA. [Demir, Hilmi Volkan] Bilkent Univ, Dept Elect & Elect Engn, TR-06800 Ankara, Turkey. RP Zhou, X (reprint author), Univ Technol Troyes, CNRS UMR 6281, ICD LNIO, Troyes, France. EM renaud.bachelot@utt.fr RI Bachelot, Renaud/M-6888-2015; OI Deeb, Claire/0000-0002-1323-0660 FU US. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]; French agency for research (ANR); European community FEDER fund; Region Champagne-Ardenne FX The authors would like to thank current and former colleagues that are (or have been) involved in this project in different ways (fruitful discussion, samples, previous achievements, participation in measurements, etc): P-M Adam, A Bouhelier, F Charra, C Ecoffet, C Fiorini, D Gerard, D Gosztola, L Huang, H Ibn El Ahrach, P K Jain, S Kostcheev, S Marguet, Y Qi, R D Schaller, S Telitel, A Vial and R Vincent. The authors thank the Partner University Funds program (PUF 2010) for partially supporting this work. X Z thanks the China Scholarship Council (CSC). Use of the Center for Nanoscale Materials was supported by the US. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. This work is also supported by the French agency for research (ANR grant HAP-PLE) and by European community FEDER fund and the Region Champagne-Ardenne: Grants HYN-NOV and NANO'MAT. NR 70 TC 2 Z9 2 U1 6 U2 62 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 2040-8978 EI 2040-8986 J9 J OPTICS-UK JI J. Opt. PD NOV PY 2014 VL 16 IS 11 AR 114002 DI 10.1088/2040-8978/16/11/114002 PG 17 WC Optics SC Optics GA AT4MX UT WOS:000344914500003 ER PT J AU Cardenas, RE Stewart, KD Cowgill, DF AF Cardenas, Rosa Elia Stewart, Kenneth D. Cowgill, Donald F. TI Gettering of hydrogen and methane from a helium gas mixture SO JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A LA English DT Article ID IMPURITIES AB In this study, the authors developed an approach for accurately quantifying the helium content in a gas mixture also containing hydrogen and methane using commercially available getters. The authors performed a systematic study to examine how both H-2 and CH4 can be removed simultaneously from the mixture using two SAES St 172 (R) getters operating at different temperatures. The remaining He within the gas mixture can then be measured directly using a capacitance manometer. The optimum combination involved operating one getter at 650 degrees C to decompose the methane, and the second at 110 degrees C to remove the hydrogen. This approach eliminated the need to reactivate the getters between measurements, thereby enabling multiple measurements to be made within a short time interval, with accuracy better than 1%. The authors anticipate that such an approach will be particularly useful for quantifying the He-3 in mixtures that include tritium, tritiated methane, and helium-3. The presence of tritiated methane, generated by tritium activity, often complicates such measurements. (C) 2014 American Vacuum Society. C1 [Cardenas, Rosa Elia] Univ Incarnate Word, Dept Phys, San Antonio, TX 78209 USA. [Stewart, Kenneth D.; Cowgill, Donald F.] Sandia Natl Labs, Livermore, CA 94550 USA. RP Cardenas, RE (reprint author), Univ Incarnate Word, Dept Phys, 4301 Broadway, San Antonio, TX 78209 USA. EM recarde1@uiwtx.edu; dfcowgi@sandia.gov FU Sandia National Laboratories; University of the Incarnate Word; US Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX This work was supported by Sandia National Laboratories and by The University of the Incarnate Word. Sandia is a multi-program laboratory operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the US Department of Energy's National Nuclear Security Administration under Contract No. DE-AC04-94AL85000. The authors wish to thank Tom Felter and Steve Rice for their contributions to this project. NR 5 TC 0 Z9 0 U1 2 U2 5 PU A V S AMER INST PHYSICS PI MELVILLE PA STE 1 NO 1, 2 HUNTINGTON QUADRANGLE, MELVILLE, NY 11747-4502 USA SN 0734-2101 EI 1520-8559 J9 J VAC SCI TECHNOL A JI J. Vac. Sci. Technol. A PD NOV PY 2014 VL 32 IS 6 AR 060602 DI 10.1116/1.4898204 PG 5 WC Materials Science, Coatings & Films; Physics, Applied SC Materials Science; Physics GA AT8YS UT WOS:000345215500002 ER PT J AU Strelcov, E Belianinov, A Sumpter, BG Kalinin, SV AF Strelcov, Evgheni Belianinov, Alexei Sumpter, Bobby G. Kalinin, Sergei V. TI Extracting physics through deep data analysis SO MATERIALS TODAY LA English DT Editorial Material C1 [Strelcov, Evgheni; Belianinov, Alexei; Sumpter, Bobby G.; Kalinin, Sergei V.] Oak Ridge Natl Lab, Inst Funct Imaging Mat, Oak Ridge, TN 37831 USA. RP Strelcov, E (reprint author), Oak Ridge Natl Lab, Inst Funct Imaging Mat, Oak Ridge, TN 37831 USA. EM strelcove@ornl.gov RI Strelcov, Evgheni/H-1654-2013; Sumpter, Bobby/C-9459-2013; Kalinin, Sergei/I-9096-2012; OI Sumpter, Bobby/0000-0001-6341-0355; Kalinin, Sergei/0000-0001-5354-6152; Belianinov, Alex/0000-0002-3975-4112 NR 4 TC 0 Z9 0 U1 4 U2 22 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 1369-7021 EI 1873-4103 J9 MATER TODAY JI Mater. Today PD NOV PY 2014 VL 17 IS 9 BP 416 EP 417 DI 10.1016/j.mattod.2014.10.002 PG 2 WC Materials Science, Multidisciplinary SC Materials Science GA AT9ED UT WOS:000345229800002 ER PT J AU Miao, L Wu, WT Aubry, N Massoudi, M AF Miao, Ling Wu, Wei-Tao Aubry, Nadine Massoudi, Mehrdad TI Falling film flow of a viscoelastic fluid along a wall SO MATHEMATICAL METHODS IN THE APPLIED SCIENCES LA English DT Article DE nonlinear fluids; slag; non-Newtonian fluids; variable viscosity; falling film; viscous dissipation; radiation boundary condition; gasification ID POWER-LAW FLUIDS; GRANULAR-MATERIALS; GLOBAL STABILITY; 2ND-GRADE FLUID; PART II; CONVECTION; DIFFUSION; BEHAVIOR; VECTOR; SLAG AB In this paper, we study the heat transfer in the fully developed flow of a viscoelastic fluid, a slag layer, down a vertical wall. A new constitutive relation for the stress tensor of this fluid is proposed, where the viscosity depends on the volume fraction, temperature, and shear rate. For the heat flux vector, we assume the Fourier's law of conduction with a constant thermal conductivity. The model is also capable of exhibiting normal stress effects. The governing equations are non-dimensionalized and numerically solved to study the effects of various dimensionless parameters on the velocity, temperature, and volume fraction. The effect of the exponent in the Reynolds viscosity model is also discussed. The different cases of shear-thinning and shear-thickening, cooling and heating, are compared and discussed. The results indicate that the viscous dissipation and radiation (at the free surface) cause the temperature to be higher inside the flow domain. Copyright (c) 2013 John Wiley & Sons, Ltd. C1 [Miao, Ling; Wu, Wei-Tao] Carnegie Mellon Univ, Dept Mech Engn, Pittsburgh, PA 15213 USA. [Aubry, Nadine] Northeastern Univ, Dept Mech Engn, Boston, MA 02115 USA. [Massoudi, Mehrdad] US DOE, Natl Energy Technol Lab, Pittsburgh, PA 15236 USA. RP Massoudi, M (reprint author), US DOE, Natl Energy Technol Lab, 626 Cochrans ill Rd,POB 10940, Pittsburgh, PA 15236 USA. EM massoudi@netl.doe.gov NR 58 TC 2 Z9 3 U1 1 U2 11 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0170-4214 EI 1099-1476 J9 MATH METHOD APPL SCI JI Math. Meth. Appl. Sci. PD NOV PY 2014 VL 37 IS 18 BP 2840 EP 2853 DI 10.1002/mma.3021 PG 14 WC Mathematics, Applied SC Mathematics GA AU0LW UT WOS:000345315400002 ER PT J AU Lee, TC Ellin, JR Huang, Q Shrestha, U Gullberg, GT Seo, Y AF Lee, Tzu-Cheng Ellin, Justin R. Huang, Qiu Shrestha, Uttam Gullberg, Grant T. Seo, Youngho TI Multipinhole collimator with 20 apertures for a brain SPECT application SO MEDICAL PHYSICS LA English DT Article DE multipinhole SPECT; brain SPECT; DAT imaging; 123I-ioflupane ID ULTRA-HIGH-RESOLUTION; MULTI-PINHOLE SPECT; PARKINSONS-DISEASE; DOPAMINE TRANSPORTER; SCINTILLATION CAMERA; CLINICAL-DIAGNOSIS; RECONSTRUCTION; SIMULATION; ACCURACY; FEATURES AB Purpose: Several new technologies for single photon emission computed tomography (SPECT) instrumentation with parallel-hole collimation have been proposed to improve detector sensitivity and signal collection efficiency. Benefits from improved signal efficiency include shorter acquisition times and lower dose requirements. In this paper, the authors show a possibility of over an order of magnitude enhancement in photon detection efficiency (from 7.6x10(-5) to 1.6x10(-3)) for dopamine transporter (DaT) imaging of the striatum over the conventional SPECT parallel-hole collimators by use of custom-designed 20 multipinhole (20-MPH) collimators with apertures of 0.75 cm diameter. Methods: Quantifying specific binding ratio (SBR) of I-123-ioflupane or I-123-iometopane's signal at the striatal region is a common brain imaging method to confirm the diagnosis of the Parkinson's disease. The authors performed imaging of a striatal phantom filled with aqueous solution of I-123 and compared camera recovery ratios of SBR acquired between low-energy high-resolution (LEHR) parallel-hole collimators and 20-MPH collimators. Results: With only two-thirds of total acquisition time (20 min against 30 min), a comparable camera recovery ratio of SBR was achieved using 20-MPH collimators in comparison to that from the LEHR collimator study. Conclusions: Their systematic analyses showed that the 20-MPH collimator could be a promising alternative for the DaT SPECT imaging for brain over the traditional LEHR collimator, which could give both shorter scan time and improved diagnostic accuracy. (C) 2014 American Association of Physicists in Medicine. C1 [Lee, Tzu-Cheng; Ellin, Justin R.; Shrestha, Uttam; Seo, Youngho] Univ Calif San Francisco, Dept Radiol & Biomed Imaging, Phys Res Lab, San Francisco, CA 94107 USA. [Huang, Qiu] Shanghai Jiao Tong Univ, Sch Biomed Engn, Shanghai 200030, Peoples R China. [Gullberg, Grant T.] Lawrence Berkeley Natl Lab, Div Life Sci, Dept Radiotracer Dev & Imaging Technol, Berkeley, CA 94702 USA. RP Seo, Y (reprint author), Univ Calif San Francisco, Dept Radiol & Biomed Imaging, Phys Res Lab, San Francisco, CA 94107 USA. EM youngho.seo@ucsf.edu FU National Heart, Lung and Blood Institute [R21 HL083073, R01 HL050663]; National Institute of Biomedical Imaging and Bioengineering [R01 EB012965] FX This work was supported in part by National Heart, Lung and Blood Institute under Grant No. R21 HL083073 (J.D.B. and Y.S.) and Grant No. R01 HL050663 (J.E., U.S., G.T.G., and Y.S.), and National Institute of Biomedical Imaging and Bioengineering under Grant No. R01 EB012965 (T.-C.L. and Y.S.). NR 37 TC 0 Z9 0 U1 2 U2 5 PU AMER ASSOC PHYSICISTS MEDICINE AMER INST PHYSICS PI MELVILLE PA STE 1 NO 1, 2 HUNTINGTON QUADRANGLE, MELVILLE, NY 11747-4502 USA SN 0094-2405 J9 MED PHYS JI Med. Phys. PD NOV PY 2014 VL 41 IS 11 AR 112501 DI 10.1118/1.4897567 PG 7 WC Radiology, Nuclear Medicine & Medical Imaging SC Radiology, Nuclear Medicine & Medical Imaging GA AT5RO UT WOS:000344999800048 PM 25370660 ER PT J AU Batth, TS Singh, P Ramakrishnan, VR Sousa, MML Chan, LJG Tran, HM Luning, EG Pan, EHY Vuu, KM Keasling, JD Adams, PD Petzold, CJ AF Batth, Tanveer S. Singh, Pragya Ramakrishnan, Vikram R. Sousa, Mirta M. L. Chan, Leanne Jade G. Tran, Huu M. Luning, Eric. G. Pan, Eva H. Y. Vuu, Khanh M. Keasling, Jay D. Adams, Paul D. Petzold, Christopher J. TI A targeted proteomics toolkit for high-throughput absolute quantification of Escherichia coli proteins SO METABOLIC ENGINEERING LA English DT Article DE Targeted proteomics; High throughput proteomics; E. coli; Peptide standards; Absolute protein quantification ID CONCATENATED SIGNATURE PEPTIDES; YEAST PROTEOME; EXPRESSION; STANDARD; BIOLOGY; SYSTEMS; DESIGN; PLASMA AB Transformation of engineered Escherichia call into a robust microbial factory is contingent on precise control of metabolism. Yet, the throughput of omics technologies used to characterize cell components has lagged far behind our ability to engineer novel strains. To expand the utility of quantitative proteomics for metabolic engineering, we validated and optimized targeted proteomics methods for over 400 proteins from more than 20 major pathways in E. coli metabolism. Complementing these methods, we constructed a series of synthetic genes to produce concatenated peptides (QconCAT) for absolute quantification of the proteins and made them available through the Addgene plasmid repository (vvww.addgene.org). To facilitate high sample throughput, we developed a fast, analytical flow chromatography method using a 5.5 mm gradient (10 min total run time). Overall this toolkit provides an invaluable resource for metabolic engineering by increasing sample throughput, minimizing development time and providing peptide standards for absolute quantification of E. cob proteins. Ks. (C) 2014 International Metabolic Engineering Society. Published by Elsevier Inc. All rights reserved. C1 [Batth, Tanveer S.; Singh, Pragya; Ramakrishnan, Vikram R.; Sousa, Mirta M. L.; Chan, Leanne Jade G.; Tran, Huu M.; Pan, Eva H. Y.; Vuu, Khanh M.; Keasling, Jay D.; Adams, Paul D.; Petzold, Christopher J.] Joint BioEnergy Inst, Emeryville, CA 94608 USA. [Batth, Tanveer S.; Singh, Pragya; Chan, Leanne Jade G.; Luning, Eric. G.; Pan, Eva H. Y.; Vuu, Khanh M.; Keasling, Jay D.; Adams, Paul D.; Petzold, Christopher J.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Phys Biosci Div, Berkeley, CA 94720 USA. [Ramakrishnan, Vikram R.; Keasling, Jay D.; Adams, Paul D.] Univ Calif Berkeley, Dept Bioengn, Berkeley, CA 94720 USA. [Sousa, Mirta M. L.] Norwegian Univ Sci & Technol NTNU, Dept Canc Res & Mol Med, N-7489 Trondheim, Norway. [Sousa, Mirta M. L.] Prote & Metabol Core Facil PROMEC NTNU, Trondheim, Norway. [Tran, Huu M.] Sandia Natl Labs, Livermore, CA 94550 USA. [Keasling, Jay D.] Univ Calif Berkeley, Dept Biomol & Chem Engn, Berkeley, CA 94720 USA. [Sousa, Mirta M. L.] Cent Norway Reg Hlth Author, Trondheim, Norway. RP Petzold, CJ (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Phys Biosci Div, Berkeley, CA 94720 USA. EM cjpetzold@lbl.gov RI Adams, Paul/A-1977-2013 OI Adams, Paul/0000-0001-9333-8219 FU U.S. Department of Energy, Office of Science, Office of Biological and Environmental Research [DE-AC02-05CH11231] FX This work was part of the DOE joint BioEnergy Institute (http://www.jbei.org) supported by the U.S. Department of Energy, Office of Science, Office of Biological and Environmental Research, through Contract DE-AC02-05CH11231 between Lawrence Berkeley National Laboratory and the U.S. Department of Energy. Targeted proteomics methods in Skyline format and SRM information are available via Panorama located at: (https://panoramaweb.org/labkey/project/JBEI/Escherichia%20coli%20pathwa ys%20manuscript/begin.view?). The QconCAT constructs used in this work are available through Addgene (www.addgene.org/). NR 40 TC 9 Z9 10 U1 0 U2 31 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 1096-7176 EI 1096-7184 J9 METAB ENG JI Metab. Eng. PD NOV PY 2014 VL 26 BP 48 EP 56 DI 10.1016/j.ymben.2014.08.004 PG 9 WC Biotechnology & Applied Microbiology SC Biotechnology & Applied Microbiology GA AT5QZ UT WOS:000344998300005 PM 25205128 ER PT J AU Goh, EB Baidoo, EEK Burd, H Lee, TS Keasling, JD Beller, HR AF Goh, Ee-Been Baidoo, Edward E. K. Burd, Helcio Lee, Taek Soon Keasling, Jay D. Beller, Harry R. TI Substantial improvements in methyl ketone production in E. coli and insights on the pathway from in vitro studies SO METABOLIC ENGINEERING LA English DT Article DE Methyl ketones; Fatty acid; Biofuels; FadM; Beta-oxidation; Acetate ID ESCHERICHIA-COLI; MICROCOCCUS-LUTEUS; GENES; BIOSYNTHESIS; EXPRESSION; CHEMICALS; ACETATE; BIOLOGY; FUELS AB We previously reported development of a metabolic pathway in Escherichia coli for overproduction of medium-chain methyl ketones (MK), which are relevant to the biofuel and flavor-and-fragrance industries. This MK pathway was a re-engineered version of P-oxidation designed to overproduce p-ketoacyl-CoAs and involved overexpression of the fadM thioesterase gene. Here, we document metabolic engineering modifications that have led to a MK titer of 3.4 g/L after similar to 45 h of fed-batch glucose fermentation and attainment of 408 of the maximum theoretical yield (the best values reported to date for MK). Modifications included balancing overexpression of fadR and fadD to increase fatty acid flux into the pathway, consolidation of the pathway from two plasmids into one, codon optimization, and knocking out key acetate production pathways. In vitro studies confirmed that a decarboxylase is not required to convert beta-keto acids into MK and that FadM is promiscuous and can hydrolyze several CoA-thioester pathway intermediates. (C) 2014 International Metabolic Engineering Society. Published by Elsevier Inc. All rights reserved. C1 [Goh, Ee-Been; Baidoo, Edward E. K.; Burd, Helcio; Lee, Taek Soon; Keasling, Jay D.; Beller, Harry R.] Joint BioEnergy Inst, Emeryville, CA 94608 USA. [Beller, Harry R.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Earth Sci, Berkeley, CA 94720 USA. [Goh, Ee-Been; Baidoo, Edward E. K.; Burd, Helcio; Lee, Taek Soon; Keasling, Jay D.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Phys Biosci Div, Berkeley, CA 94720 USA. [Keasling, Jay D.] Univ Calif Berkeley, Dept Biomol & Chem Engn, Berkeley, CA 94720 USA. [Keasling, Jay D.] Univ Calif Berkeley, Dept Bioengn, Berkeley, CA 94720 USA. RP Beller, HR (reprint author), Joint BioEnergy Inst, 5885 Hollis Ave, Emeryville, CA 94608 USA. EM HRBeller@lbl.gov RI Beller, Harry/H-6973-2014 FU Office of Science, Office of Biological and Environmental Research of the U.S. Department of Energy [DE-AC02-05CH11231]; Abengoa FX We thank Pragya Singh and Christopher Petzold (Technology Division, JBEI) for mass spectrometric analysis of protein samples. This work conducted by the Joint BioEnergy Institute was supported by the Office of Science, Office of Biological and Environmental Research of the U.S. Department of Energy under Contract no DE-AC02-05CH11231. E.-B.G. was partially supported by Abengoa. J.D.K. has a financial interest in Amyris and Lygos. NR 27 TC 11 Z9 13 U1 2 U2 26 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 1096-7176 EI 1096-7184 J9 METAB ENG JI Metab. Eng. PD NOV PY 2014 VL 26 BP 67 EP 76 DI 10.1016/j.ymben.2014.09.003 PG 10 WC Biotechnology & Applied Microbiology SC Biotechnology & Applied Microbiology GA AT5QZ UT WOS:000344998300007 PM 25241399 ER PT J AU Haushalter, RW Kim, W Chavkin, TA The, L Garber, ME Nhan, M Adams, PD Petzold, CJ Katz, L Keasling, JD AF Haushalter, Robert W. Kim, Woncheol Chavkin, Ted A. The, Lionadi Garber, Megan E. Nhan, Melissa Adams, Paul D. Petzold, Christopher J. Katz, Leonard Keasling, Jay D. TI Production of anteiso-branched fatty acids in Escherichia coli; next generation biofuels with improved cold-flow properties SO METABOLIC ENGINEERING LA English DT Article DE Biofuels; Synthetic biology; Fatty acids ID BIODIESEL PRODUCTION; FUELS; K-12; TRANSCRIPTION; BIOSYNTHESIS; EXPRESSION; MOLECULES; CHEMICALS; SYNTHASE; COMPLEX AB Microbial fermentation is emerging as an increasingly important resource for the production of fatty acids to serve as precursors for renewable diesel as well as detergents, lubricants and other industrial chemicals, as an alternative to traditional sources of reduced carbon such as petroleum. A major disadvantage of fuels derived from biological sources is their undesirable physical properties such as high cloud and pour points, and high viscosity. Here we report the development of an Escherichia cob strain that efficiently produces anteiso-branched fatty acids, which can be converted into downstream products with lower cloud and pour points than the mixtures of compounds produced via the native metabolism of the cell. This work addresses a serious limitation that must be overcome in order to produce renewable biodiesel and oleochemicals that perform as well as their petroleum-based counterparts. (C) International Metabolic Engineering Society. Published by Elsevier Inc. All rights reserved, C1 [Haushalter, Robert W.; Kim, Woncheol; Nhan, Melissa; Adams, Paul D.; Petzold, Christopher J.; Keasling, Jay D.] Joint BioEnergy Inst, Emeryville, CA 94608 USA. [Haushalter, Robert W.; Kim, Woncheol; Nhan, Melissa; Adams, Paul D.; Petzold, Christopher J.; Keasling, Jay D.] Lawrence Berkeley Natl Lab, Phys Biosci Div, Berkeley, CA 94720 USA. [Chavkin, Ted A.; The, Lionadi; Garber, Megan E.; Katz, Leonard; Keasling, Jay D.] Univ Calif Berkeley, Inst QB3, Emeryville, CA 94608 USA. [Katz, Leonard; Keasling, Jay D.] Univ Calif Berkeley, Synthet Biol Engn Res Ctr, Berkeley, CA 94720 USA. [Adams, Paul D.; Keasling, Jay D.] Univ Calif Berkeley, Dept Bioengn, Dept Biomol & Chem Engn, Berkeley, CA 94720 USA. RP Keasling, JD (reprint author), Joint BioEnergy Inst, 5885 Hollis St,4th Floor, Emeryville, CA 94608 USA. EM jdkeasling@lbl.gov RI Adams, Paul/A-1977-2013 OI Adams, Paul/0000-0001-9333-8219 FU Office of Science, Office of Biological and Environmental Research U.S. Department of Energy [DE-AC02-05CH11231] FX We thank Prof. Charles O. Rock for generously providing bFabH constructs and Prof. James C. Liao for providing strain CRS24 and plasmids pCS49, pAFC3, and pAFC46. We acknowledge Dr. Eric Steen for producing strain JBEI-3111, Dr. Dan Groff for generating plasmid pPhatty, and Vivian Macnguyen, Meghana Rao, Michael Bonilla, and Andrew Brandon for technical assistance. This work conducted by the Joint BioEnergy Institute was supported by the Office of Science, Office of Biological and Environmental Research U.S. Department of Energy under Contract no. DE-AC02-05CH11231. NR 30 TC 14 Z9 15 U1 0 U2 35 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 1096-7176 EI 1096-7184 J9 METAB ENG JI Metab. Eng. PD NOV PY 2014 VL 26 BP 111 EP 118 DI 10.1016/j.ymben.2014.09.002 PG 8 WC Biotechnology & Applied Microbiology SC Biotechnology & Applied Microbiology GA AT5QZ UT WOS:000344998300011 PM 25250846 ER PT J AU Spurgeon, SR AF Spurgeon, Steven R. TI "Paper Factory" produces a blend of science and engineering education SO MRS BULLETIN LA English DT Article C1 Pacific NW Natl Lab, Fundamental & Computat Sci Directorate, Richland, WA 99352 USA. RP Spurgeon, SR (reprint author), Pacific NW Natl Lab, Fundamental & Computat Sci Directorate, Richland, WA 99352 USA. OI Spurgeon, Steven/0000-0003-1218-839X NR 0 TC 0 Z9 0 U1 0 U2 0 PU CAMBRIDGE UNIV PRESS PI NEW YORK PA 32 AVENUE OF THE AMERICAS, NEW YORK, NY 10013-2473 USA SN 0883-7694 EI 1938-1425 J9 MRS BULL JI MRS Bull. PD NOV PY 2014 VL 39 IS 11 BP 945 EP 946 DI 10.1557/mrs.2014.268 PG 2 WC Materials Science, Multidisciplinary; Physics, Applied SC Materials Science; Physics GA AT7ML UT WOS:000345121300012 ER PT J AU Das, S Chigurupati, S Dowding, J Munusamy, P Baer, DR McGinnis, JF Mattson, MP Self, W Seal, S AF Das, Soumen Chigurupati, Srinivasulu Dowding, Janet Munusamy, Prabhakaran Baer, Donald R. McGinnis, James F. Mattson, Mark P. Self, William Seal, Sudipta TI Therapeutic potential of nanoceria in regenerative medicine SO MRS BULLETIN LA English DT Article ID CERIUM OXIDE NANOPARTICLES; OXIDATIVE STRESS; CEO2 NANOPARTICLES; NEURONAL SURVIVAL; CELLS; RADIATION; PROTECT; MICE; NANOSTRUCTURES; PROLIFERATION AB Tissue engineering and regenerative medicine aim to achieve functional restoration of tissue or cells damaged through disease, aging, or trauma. Advancement of tissue engineering requires innovation in the field of three-dimensional scaffolding and functionalization with bioactive molecules. Nanotechnology offers advanced materials with patterned nano-morphologies for cell growth and different molecular substrates that can support cell survival and functions. Cerium oxide nanoparticles (nanoceria) can control intracellular as well as extracellular reactive oxygen and nitrogen species. Recent findings suggest that nanoceria can enhance long-term cell survival, enable cell migration and proliferation, and promote stem cell differentiation. Moreover, the self-regenerative property of nanoceria permits a small dose to remain catalytically active for an extended time. This review summarizes the possibilities and applications of nanoceria in the field of tissue engineering and regenerative medicine. C1 [Das, Soumen] Univ Cent Florida, Nanosci Technol Ctr, Adv Mat Proc Anal Ctr, Orlando, FL 32816 USA. [Chigurupati, Srinivasulu] US FDA, Div Neurotoxicol, Natl Ctr Toxicol Res, Rockville, MD 20857 USA. [Dowding, Janet] Univ Cent Florida, Burnett Sch Biomed Sci, Orlando, FL 32816 USA. [Munusamy, Prabhakaran; Baer, Donald R.] Pacific NW Natl Lab, Environm Mol Sci Lab, Richland, WA 99352 USA. [McGinnis, James F.] Univ Oklahoma, Hlth Sci Ctr, Dept Ophthalmol, Norman, OK 73019 USA. [Mattson, Mark P.] NIA, Neurosci Lab, Intramural Res Program, Bethesda, MD 20892 USA. [Self, William] Univ Cent Florida, Burnett Sch Biomed Sci, Orlando, FL 32816 USA. [Seal, Sudipta] Univ Cent Florida, Adv Mat Proc & Anal Ctr, Nanosci & Technol Ctr, Coll Med, Orlando, FL 32816 USA. RP Das, S (reprint author), Univ Cent Florida, Nanosci Technol Ctr, Adv Mat Proc Anal Ctr, Orlando, FL 32816 USA. EM soumen.das@ucf.edu; srinivasulu.chigurupati@fda.hhs.gov; jdowding42q@gmail.com; prabhakaran.munusamy@pnnl.gov; don.baer@pnnl.gov; James-McGinnis@ouhsc.edu; MattsonM@grc.nia.nih.gov; william.self@ucf.edu; Sudipta.Seal@ucf.edu RI Baer, Donald/J-6191-2013; Self, William/A-6704-2008 OI Baer, Donald/0000-0003-0875-5961; FU National Institute on Aging; NIH NEI [COBRE-P20 RR017703, P30-EY 12190, R21EY018306, R01EY18724, R01EY022111]; National Science Foundation [CBET-0708172]; NIEHS Center [U19 ES019544]; US Department of Energy, Biological and Environmental Research and located at PNNL FX This work was supported, in part, by the intramural research program of the National Institute on Aging. The work by J.F.M. was supported by NIH NEI Grant COBRE-P20 RR017703, P30-EY 12190, R21EY018306, R01EY18724, R01EY022111; National Science Foundation: CBET-0708172; and Research to Prevent Blindness. D.R.B. was supported by the NIEHS Center Grant U19 ES019544. Part of this work was performed using EMSL, a national scientific user facility sponsored by the US Department of Energy, Biological and Environmental Research and located at PNNL. S.S. and W.S. acknowledge NSF and NIH for various aspects of nano-biotechnology research. NR 50 TC 5 Z9 5 U1 3 U2 20 PU CAMBRIDGE UNIV PRESS PI NEW YORK PA 32 AVENUE OF THE AMERICAS, NEW YORK, NY 10013-2473 USA SN 0883-7694 EI 1938-1425 J9 MRS BULL JI MRS Bull. PD NOV PY 2014 VL 39 IS 11 BP 976 EP 983 DI 10.1557/mrs.2014.221 PG 8 WC Materials Science, Multidisciplinary; Physics, Applied SC Materials Science; Physics GA AT7ML UT WOS:000345121300017 ER PT J AU Neaton, JB AF Neaton, Jeffrey B. TI SINGLE-MOLECULE JUNCTIONS Thermoelectricity at the gate SO NATURE NANOTECHNOLOGY LA English DT Editorial Material ID THERMOPOWER C1 [Neaton, Jeffrey B.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA. [Neaton, Jeffrey B.] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA. [Neaton, Jeffrey B.] Kavli Energy NanoSci Inst Berkeley, Berkeley, CA 94720 USA. RP Neaton, JB (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA. EM jbneaton@lbl.gov RI Neaton, Jeffrey/F-8578-2015; Foundry, Molecular/G-9968-2014 OI Neaton, Jeffrey/0000-0001-7585-6135; NR 15 TC 3 Z9 3 U1 0 U2 32 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 1748-3387 EI 1748-3395 J9 NAT NANOTECHNOL JI Nat. Nanotechnol. PD NOV PY 2014 VL 9 IS 11 BP 876 EP 877 DI 10.1038/nnano.2014.256 PG 3 WC Nanoscience & Nanotechnology; Materials Science, Multidisciplinary SC Science & Technology - Other Topics; Materials Science GA AT4YY UT WOS:000344951100006 PM 25370426 ER PT J AU Grierson, BA Burrell, KH Garofalo, AM Solomon, WM Diallo, A O'Mullane, M AF Grierson, B. A. Burrell, K. H. Garofalo, A. M. Solomon, W. M. Diallo, A. O'Mullane, M. TI Response of impurity particle confinement time to external actuators in QH-mode plasmas on DIII-D SO NUCLEAR FUSION LA English DT Article; Proceedings Paper CT 14th InternationalWorkshop on H-mode Physics andTransport Barriers CY OCT 02-04, 2013 CL Fukuoka, JAPAN DE plasma properties; plasma impurities; optical measurements AB A series of quiescent H-mode discharges has been executed with the specific aim of determining the particle confinement time of impurities in the presence of the edge harmonic oscillation. These discharges utilize non-intrinsic, non-recycling fully-stripped fluorine as the diagnostic species monitored by charge-exchange recombination spectroscopy. It is found that the edge harmonic oscillation is an efficient means of impurity expulsion from the core plasma, with impurity exhaust rates comparable to or exceeding those in companion ELMing discharges. As the external torque from neutral beam injection is lowered, the global energy confinement time increases while the impurity confinement time does not display an increase. C1 [Grierson, B. A.; Solomon, W. M.; Diallo, A.] Princeton Univ, Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Burrell, K. H.; Garofalo, A. M.] Gen Atom Co, San Diego, CA 92186 USA. [O'Mullane, M.] Univ Strathclyde, Dept Phys, Glasgow G4 0NG, Lanark, Scotland. RP Grierson, BA (reprint author), Princeton Univ, Princeton Plasma Phys Lab, POB 451, Princeton, NJ 08543 USA. EM bgriers@pppl.gov OI Solomon, Wayne/0000-0002-0902-9876 FU U.S. Department of Energy [DE-AC02-09CH11466, DE-FC02-04ER54698] FX This work supported in part by the U.S. Department of Energy under DE-AC02-09CH11466 and DE-FC02-04ER54698. The originating developer of ADAS is the JET Joint Undertaking. DIII-D data shown in this paper can be obtained in digital format by following the links at https://fusion.gat.com/global/D3D_DMP. NR 11 TC 6 Z9 6 U1 1 U2 3 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0029-5515 EI 1741-4326 J9 NUCL FUSION JI Nucl. Fusion PD NOV PY 2014 VL 54 IS 11 SI SI AR 114011 DI 10.1088/0029-5515/54/11/114011 PG 5 WC Physics, Fluids & Plasmas SC Physics GA AT5DY UT WOS:000344964800012 ER PT J AU Maingi, R AF Maingi, R. TI Enhanced confinement scenarios without large edge localized modes in tokamaks: control, performance, and extrapolability issues for ITER SO NUCLEAR FUSION LA English DT Article; Proceedings Paper CT 14th InternationalWorkshop on H-mode Physics andTransport Barriers CY OCT 02-04, 2013 CL Fukuoka, JAPAN DE edge localized mode; ITER; heat flux; magnetic perturbations; pellets ID DIII-D TOKAMAK; HIGH-FIELD SIDE; ALCATOR C-MOD; ASDEX UPGRADE; H-MODE; PELLET INJECTION; FREQUENCY CONTROL; BALLOONING MODES; PARTICLE LOSSES; POWER THRESHOLD AB Large edge localized modes (ELMs) typically accompany good H-mode confinement in fusion devices, but can present problems for plasma facing components because of high transient heat loads. Here the range of techniques for ELM control deployed in fusion devices is reviewed. Two strategies in the ITER baseline design are emphasized: rapid ELM triggering and peak heat flux control via pellet injection, and the use of magnetic perturbations to suppress or mitigate ELMs. While both of these techniques are moderately well developed, with reasonable physical bases for projecting to ITER, differing observations between multiple devices are also discussed to highlight the needed community R&D. In addition, recent progress in ELM-free regimes, namely quiescent H-mode, I-mode, and enhanced pedestal H-mode is reviewed, and open questions for extrapolability are discussed. Finally progress and outstanding issues in alternate ELM control techniques are reviewed: supersonic molecular beam injection, edge electron cyclotron heating, lower hybrid heating and/or current drive, controlled periodic jogs of the vertical centroid position, ELM pace-making via periodic magnetic perturbations, ELM elimination with lithium wall conditioning, and naturally occurring small ELM regimes. C1 Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. RP Maingi, R (reprint author), Princeton Plasma Phys Lab, Receiving 3,Route 1 North, Princeton, NJ 08543 USA. EM rmaingi@pppl.gov FU US Department of Energy [DE-AC02-09CH11466] FX The author acknowledges discussions with K. Burrell, R. Buttery, T. Evans, S. Gerhardt, A. Garofalo, B. Grierson, R. Hawryluk, A. Hubbard, J. Hughes, Y.M. Jeon, A. Kirk, A. Loarte, Y.F. Liang, D. Orlov, T. Osborne, C. Skinner, W. Solomon, and W. Suttrop. The referees are also thanked, as their comments resulted in substantial improvements. This work was supported by the US Department of Energy under contract DE-AC02-09CH11466. NR 162 TC 7 Z9 7 U1 5 U2 52 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0029-5515 EI 1741-4326 J9 NUCL FUSION JI Nucl. Fusion PD NOV PY 2014 VL 54 IS 11 SI SI AR 114016 DI 10.1088/0029-5515/54/11/114016 PG 34 WC Physics, Fluids & Plasmas SC Physics GA AT5DY UT WOS:000344964800017 ER PT J AU Voronov, DL Warwick, T Padmore, HA AF Voronov, D. L. Warwick, T. Padmore, H. A. TI Multilayer-coated blazed grating with variable line spacing and a variable blaze angle SO OPTICS LETTERS LA English DT Article ID EXTREME-ULTRAVIOLET; EFFICIENCY; SPECTROMETER AB The blazing ability of multilayer-coated blazed gratings (MBGs) was systematically investigated via numerical calculation of the diffraction efficiency with a rigorous electromagnetic simulation code. It was found that the blazing condition is not exact and allows significant deviation from the ideal situation for ultra-dense MBGs. A mismatch of the interfaces of the multilayer (ML) stacks of adjacent grooves results in a modified effective blaze angle, which gives the opportunity to control and tune precisely the blaze angle via a proper choice of ML d-spacing. Also this allows a new kind of x-ray gratings that have a variable line spacing (VLS) as well as a variable blaze angle. Precise adjustment of a local blaze angle of a VLS MBG can be achieved with a laterally graded ML, providing very high diffraction efficiency for the whole area of the grating. (C) 2014 Optical Society of America C1 [Voronov, D. L.; Warwick, T.; Padmore, H. A.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. RP Voronov, DL (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, 1 Cyclotron Rd, Berkeley, CA 94720 USA. EM dlvoronov@lbl.gov FU US Department of Energy [DE-AC02-05CH11231] FX This work was supported by the US Department of Energy under contract number DE-AC02-05CH11231. NR 11 TC 3 Z9 3 U1 5 U2 22 PU OPTICAL SOC AMER PI WASHINGTON PA 2010 MASSACHUSETTS AVE NW, WASHINGTON, DC 20036 USA SN 0146-9592 EI 1539-4794 J9 OPT LETT JI Opt. Lett. PD NOV 1 PY 2014 VL 39 IS 21 BP 6134 EP 6137 DI 10.1364/OL.39.006134 PG 4 WC Optics SC Optics GA AT5MA UT WOS:000344985900012 PM 25361297 ER PT J AU Meinzer, FC Woodruff, DR Marias, DE McCulloh, KA Sevanto, S AF Meinzer, Frederick C. Woodruff, David R. Marias, Danielle E. McCulloh, Katherine A. Sevanto, Sanna TI Dynamics of leaf water relations components in co-occurring iso- and anisohydric conifer species SO PLANT CELL AND ENVIRONMENT LA English DT Article DE anisohydry; drought; isohydry; osmotic potential; turgor ID PRESSURE-VOLUME RELATIONSHIPS; TEMPERATE DECIDUOUS ANGIOSPERMS; NEGATIVE TURGOR PRESSURE; SHRUB LARREA-TRIDENTATA; PINYON-JUNIPER WOODLAND; CHANGE-TYPE DROUGHT; SAP ABSCISIC-ACID; STOMATAL CONDUCTANCE; PROTOPLAST VOLUME; SONORAN DESERT AB Because iso- and anisohydric species differ in stomatal regulation of the rate and magnitude of fluctuations in shoot water potential, they may be expected to show differences in the plasticity of their shoot water relations components, but explicit comparisons of this nature have rarely been made. We subjected excised shoots of co-occurring anisohydric Juniperus monosperma and isohydric Pinus edulis to pressure-volume analysis with and without prior artificial rehydration. In J. monosperma, the shoot water potential at turgor loss (Psi(TLP)) ranged from -3.4 MPa in artificially rehydrated shoots to -6.6 MPa in shoots with an initial. of -5.5 MPa, whereas in P. edulis mean Psi(TLP) remained at similar to -3.0 MPa over a range of initial Psi from -0.1 to -2.3 MPa. The shoot osmotic potential at full turgor and the bulk modulus of elasticity also declined sharply with shoot. in J. monosperma, but not in P. edulis. The contrasting behaviour of J. monosperma and P. edulis reflects differences in their capacity for homeostatic regulation of turgor that may be representative of aniso- and isohydric species in general, and may also be associated with the greater capacity of J. monosperma to withstand severe drought. C1 [Meinzer, Frederick C.; Woodruff, David R.] US Forest Serv, USDA, Pacific NW Res Stn, Corvallis, OR 97331 USA. [Marias, Danielle E.] Oregon State Univ, Dept Forest Ecosyst & Soc, Corvallis, OR 97331 USA. [McCulloh, Katherine A.] Univ Wisconsin, Dept Bot, Madison, WI 53706 USA. [Sevanto, Sanna] Los Alamos Natl Lab, Div Earth & Environm Sci, Los Alamos, NM 87545 USA. RP Meinzer, FC (reprint author), US Forest Serv, USDA, Pacific NW Res Stn, Corvallis, OR 97331 USA. EM rick.meinzer@oregonstate.edu FU Los Alamos National Laboratory [DE-NA0001302]; USDA Forest Service Pacific Northwest Research Station [DE-NA0001302]; NSF [IBN 09-19871] FX This work was supported in part by interagency agreement DE-NA0001302 between Los Alamos National Laboratory and the USDA Forest Service Pacific Northwest Research Station and by NSF grant IBN 09-19871. We are grateful to Lily Cohen, Adam Collins, Turin Dickman, Emily Kluk, Jacob Naranjo and several student interns for assistance with sample collection and field water potential measurements. NR 64 TC 27 Z9 28 U1 8 U2 60 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0140-7791 EI 1365-3040 J9 PLANT CELL ENVIRON JI Plant Cell Environ. PD NOV PY 2014 VL 37 IS 11 BP 2577 EP 2586 DI 10.1111/pce.12327 PG 10 WC Plant Sciences SC Plant Sciences GA AT8UK UT WOS:000345207100012 PM 24661116 ER PT J AU Robert, CAM Ferrieri, RA Schirmer, S Babst, BA Schueller, MJ Machado, RAR Arce, CCM Hibbard, BE Gershenzon, J Turlings, TCJ Erb, M AF Robert, Christelle A. M. Ferrieri, Richard A. Schirmer, Stefanie Babst, Benjamin A. Schueller, Michael J. Machado, Ricardo A. R. Arce, Carla C. M. Hibbard, Bruce E. Gershenzon, Jonathan Turlings, Ted C. J. Erb, Matthias TI Induced carbon reallocation and compensatory growth as root herbivore tolerance mechanisms SO PLANT CELL AND ENVIRONMENT LA English DT Article DE Diabrotica virgifera; (CO2)-C-11; compensatory root growth; plant herbivore interactions ID BELOW-GROUND HERBIVORY; INSECT HERBIVORES; CORN-ROOTWORM; RAPID CHANGES; TEMPORAL-CHANGES; GAS-EXCHANGE; PLANT; RESISTANCE; MAIZE; ACID AB Upon attack by leaf herbivores, many plants reallocate photoassimilates below ground. However, little is known about how plants respond when the roots themselves come under attack. We investigated induced resource allocation in maize plants that are infested by the larvae Western corn rootworm Diabrotica virgifera virgifera. Using radioactive (CO2)-C-11, we demonstrate that root-attacked maize plants allocate more new C-11 carbon from source leaves to stems, but not to roots. Reduced meristematic activity and reduced invertase activity in attacked maize root systems are identified as possible drivers of this shoot reallocation response. The increased allocation of photoassimilates to stems is shown to be associated with a marked thickening of these tissues and increased growth of stem-borne crown roots. A strong quantitative correlation between stem thickness and root regrowth across different watering levels suggests that retaining photoassimilates in the shoots may help root-attacked plants to compensate for the loss of belowground tissues. Taken together, our results indicate that induced tolerance may be an important strategy of plants to withstand belowground attack. Furthermore, root herbivore-induced carbon reallocation needs to be taken into account when studying plant-mediated interactions between herbivores. C1 [Robert, Christelle A. M.; Schirmer, Stefanie; Machado, Ricardo A. R.; Arce, Carla C. M.; Erb, Matthias] Max Planck Inst Chem Ecol, Root Herbivore Interact Grp, D-07745 Jena, Germany. [Robert, Christelle A. M.; Schirmer, Stefanie; Gershenzon, Jonathan] Max Planck Inst Chem Ecol, Dept Biochem, D-07745 Jena, Germany. [Machado, Ricardo A. R.; Arce, Carla C. M.] Max Planck Inst Chem Ecol, Dept Mol Ecol, D-07745 Jena, Germany. [Ferrieri, Richard A.; Babst, Benjamin A.; Schueller, Michael J.] Brookhaven Natl Lab, Dept Biosci, Upton, NY 11973 USA. [Arce, Carla C. M.] Univ Fed Vicosa, Dept Entomol, Vicosa, MG, Brazil. [Hibbard, Bruce E.] Univ Missouri, USDA ARS, Plant Genet Res Unit, Columbia, MO 65211 USA. [Turlings, Ted C. J.] Univ Neuchatel, Lab Fundamental & Appl Res Chem Ecol FARCE, CH-2000 Neuchatel, Switzerland. [Erb, Matthias] Univ Bern, Inst Plant Sci, CH-2013 Bern, Switzerland. RP Erb, M (reprint author), Univ Bern, Inst Plant Sci, Altenbergrain 21, CH-3013 Bern, Switzerland. EM matthias.erb@ips.unibe.ch RI Turlings, Ted/E-8671-2012; Gershenzon, Jonathan/K-1331-2013; Arce, Carla/P-2295-2015; OI Turlings, Ted/0000-0002-8315-785X; Gershenzon, Jonathan/0000-0002-1812-1551; Babst, Benjamin/0000-0001-5657-0633; Erb, Matthias/0000-0002-4446-9834 FU Swiss National Science Foundation [FN 31000AO-107974, 140196]; Marie Curie Intra European Fellowship [273107]; Organismal Biology Doctoral Program of the University of Neuchatel; Brookhaven Science Associates, LLC [DE-AC02-98CH10886]; US Department of Energy, Office of Biological and Environmental Research; Max Planck Society; National Centre of Competence in Research (NCCR) 'Plant Survival', a research programme of the Swiss National Science Foundation FX We are grateful to Wade French and Chad Nielson (USDA-ARS-NCARL, Brookings, SD, USA), and Julie Barry (USDA-ARS, University of Missouri, Columbia, MO, USA) who kindly supplied D. virgifera eggs. We thank Lena Kurz for her help with the tolerance measurements. Research activities by C. A. M. R., T.C.J.T. and M. E. were supported by the Swiss National Science Foundation (FN 31000AO-107974; 140196) and a Marie Curie Intra European Fellowship (grant no. 273107). C. A. M. R. was supported by a travel grant of the Organismal Biology Doctoral Program of the University of Neuchatel to conduct experiments at BNL. This article has been authored by Brookhaven Science Associates, LLC under contract number DE-AC02-98CH10886 with the US Department of Energy, Office of Biological and Environmental Research, which supported R. A. F., B. A. B. and M.J.S. This project was partially funded by the Max Planck Society and the National Centre of Competence in Research (NCCR) 'Plant Survival', a research programme of the Swiss National Science Foundation. NR 48 TC 17 Z9 17 U1 11 U2 73 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0140-7791 EI 1365-3040 J9 PLANT CELL ENVIRON JI Plant Cell Environ. PD NOV PY 2014 VL 37 IS 11 BP 2613 EP 2622 DI 10.1111/pce.12359 PG 10 WC Plant Sciences SC Plant Sciences GA AT8UK UT WOS:000345207100015 PM 24762051 ER PT J AU Song, G Silva, CL Jenkins-Smith, HC AF Song, Geoboo Silva, Carol L. Jenkins-Smith, Hank C. TI Cultural Worldview and Preference for Childhood Vaccination Policy SO POLICY STUDIES JOURNAL LA English DT Article DE childhood vaccination policy; health policy; cultural theory; public opinion ID RISK PERCEPTION; RUBELLA VACCINE; UNITED-STATES; POLITICAL-IDEOLOGY; INTERNET SURVEYS; PERCEIVED RISK; PUBLIC-HEALTH; IMMUNIZATION; MEASLES; AUTISM AB In the face of the reemerging threat of preventable diseases and the simultaneous vaccine risk controversy, what explains variations in Americans' policy preferences regarding childhood vaccinations? Using original data from a recent nationwide Internet survey of 1,213 American adults, this research seeks to explain differing public opinions on childhood vaccination policies and related issues of governance. As Mary Douglas and Aaron Wildavsky's grid-group cultural theory of policy preference formation suggests, cultural biases have a significant impact on the formation of preferences toward various vaccination policies. Hierarchs are in support of mandatory vaccination, oppose religious and philosophical exemption, and believe the government should preside over vaccination-related decisions. Fatalists strike a bold contrast in their opposition to mandatory vaccination policy and support for religious and philosophical exemptions and the role of parents in deciding on vaccinations. Falling between hierarchs and fatalists, egalitarian support for vaccinations is stronger than individualists. C1 [Song, Geoboo] Univ Arkansas, J William Fulbright Coll Arts & Sci, Dept Polit Sci, Fayetteville, AR 72701 USA. [Silva, Carol L.; Jenkins-Smith, Hank C.] Univ Oklahoma, Dept Polit Sci, Norman, OK 73019 USA. [Silva, Carol L.] Univ Oklahoma, Ctr Risk Crisis & Management, Norman, OK 73019 USA. [Jenkins-Smith, Hank C.] Univ Oklahoma, Ctr Energy Secur & Soc, Norman, OK 73019 USA. [Jenkins-Smith, Hank C.] Sandia Natl Labs, Ctr Energy Secur & Soc, Livermore, CA 94550 USA. RP Song, G (reprint author), Univ Arkansas, J William Fulbright Coll Arts & Sci, Dept Polit Sci, Fayetteville, AR 72701 USA. NR 77 TC 5 Z9 5 U1 5 U2 54 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0190-292X EI 1541-0072 J9 POLICY STUD J JI Policy Stud. J. PD NOV PY 2014 VL 42 IS 4 BP 528 EP 554 DI 10.1111/psj.12076 PG 27 WC Political Science; Public Administration SC Government & Law; Public Administration GA AU0YM UT WOS:000345348100004 ER PT J AU Zhang, HJ Maceira, M Roux, P Thurber, C AF Zhang, Haijiang Maceira, Monica Roux, Philippe Thurber, Clifford TI Joint Inversion of Body-Wave Arrival Times and Surface-Wave Dispersion for Three-Dimensional Seismic Structure Around SAFOD SO PURE AND APPLIED GEOPHYSICS LA English DT Article ID SAN-ANDREAS FAULT; DOUBLE-DIFFERENCE TOMOGRAPHY; TRAVEL-TIMES; VELOCITY STRUCTURE; HAYWARD FAULT; GUIDED-WAVES; PARKFIELD; CALIFORNIA; ZONE; ATTENUATION AB We incorporate body-wave arrival time and surface-wave dispersion data into a joint inversion for three-dimensional P-wave and S-wave velocity structure of the crust surrounding the site of the San Andreas Fault Observatory at Depth. The contributions of the two data types to the inversion are controlled by the relative weighting of the respective equations. We find that the trade-off between fitting the two data types, controlled by the weighting, defines a clear optimal solution. Varying the weighting away from the optimal point leads to sharp increases in misfit for one data type with only modest reduction in misfit for the other data type. All the acceptable solutions yield structures with similar primary features, but the smaller-scale features change substantially. When there is a lower relative weight on the surface-wave data, it appears that the solution over-fits the body-wave data, leading to a relatively rough V (s) model, whereas for the optimal weighting, we obtain a relatively smooth model that is able to fit both the body-wave and surface-wave observations adequately. C1 [Zhang, Haijiang] Univ Sci & Technol China, Sch Earth & Space Sci, Lab Seismol & Earths Interior, Hefei 230026, Anhui, Peoples R China. [Maceira, Monica] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Roux, Philippe] Univ Grenoble 1, CNRS, IRD, ISTerre, F-38402 St Martin Dheres, France. [Thurber, Clifford] Univ Wisconsin, Dept Geosci, Madison, WI 53706 USA. RP Zhang, HJ (reprint author), Univ Sci & Technol China, Sch Earth & Space Sci, Lab Seismol & Earths Interior, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China. EM zhang11@ustc.edu.cn RI roux, philippe/B-8538-2014; OI Maceira, Monica/0000-0003-1248-2185 FU Chinese government; Natural Science Foundation of China [41274055]; Fundamental Research Funds for the Central Universities [WK2080000053]; US Department of Energy [DE-NA0001523] FX We thank Yehuda Ben-Zion and Antonio Rovelli for organizing the 40th Workshop of the International School of Geophysics on "Properties and Processes of Crustal Fault Zones'' in Erice, Sicily, which motivated the present work. We are grateful to two anonymous reviewers for their constructive comments, which we hope have led to substantial improvement of the manuscript. This research presented here was partly supported by the Chinese government's executive program for exploring the deep interior beneath the Chinese continent (SinoProbe-02), Natural Science Foundation of China under Grant No. 41274055, and Fundamental Research Funds for the Central Universities (WK2080000053). This research was also supported by DE-NA0001523 from the US Department of Energy. NR 52 TC 9 Z9 10 U1 0 U2 14 PU SPRINGER BASEL AG PI BASEL PA PICASSOPLATZ 4, BASEL, 4052, SWITZERLAND SN 0033-4553 EI 1420-9136 J9 PURE APPL GEOPHYS JI Pure Appl. Geophys. PD NOV PY 2014 VL 171 IS 11 BP 3013 EP 3022 DI 10.1007/s00024-014-0806-y PG 10 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA AT7WD UT WOS:000345144300010 ER PT J AU Johnson, JR Wing, S Delamere, PA AF Johnson, Jay R. Wing, Simon Delamere, Peter A. TI Kelvin Helmholtz Instability in Planetary Magnetospheres SO SPACE SCIENCE REVIEWS LA English DT Review DE Kelvin-Helmholtz; Plasma transport; Planetary magnetospheres ID INTERPLANETARY MAGNETIC-FIELD; KINETIC ALFVEN WAVES; INTERACTION OFMAGNETIC RECONNECTION; MAGNETOPAUSE-BOUNDARY LAYER; DAWN-DUSK ASYMMETRIES; SOLAR-WIND; PLASMA SHEET; GEOTAIL OBSERVATIONS; EARTHS MAGNETOPAUSE; ELECTROMAGNETIC-WAVES AB Kelvin-Helmholtz instability plays a particularly important role in plasma transport at magnetospheric boundaries because it can control the development of a turbulent boundary layer, which governs the transport of mass, momentum, and energy across the boundary. Waves generated at the interface can also couple into body modes in the plasma sheet and inner magnetosphere where they can play an important role in plasma sheet transport and particle energization in the inner magnetosphere. Kinetic and electron-scale effects are important for the development of K-H instability, leading to secondary instabilities and plasma mixing. The development of vortices that entwine magnetosheath field lines with magnetospheric field lines also allows reconnection and the interchange of plasma blobs from open to closed field lines. Dawn-dusk asymmetries in Kelvin-Helmholtz development at planetary boundary layers may result from several effects including plasma corotation, kinetic effects, magnetic geometry, or asymmetric distribution of plasma. Examples are provided throughout the solar system illustrating the pervasive effects of the Kelvin-Helmholtz instability on plasma transport. C1 [Johnson, Jay R.] Princeton Univ, Plasma Phys Lab, Princeton, NJ 08543 USA. [Wing, Simon] Johns Hopkins Univ, Appl Phys Lab, Laurel, MD 20723 USA. [Delamere, Peter A.] Univ Alaska, Inst Geophys, Fairbanks, AK 99775 USA. RP Johnson, JR (reprint author), Princeton Univ, Plasma Phys Lab, POB 451, Princeton, NJ 08543 USA. EM jrj@pppl.gov; simon.wing@jhuapl.edu; peter.delamere@gi.alaska.edu FU NSF [ATM-0802715, AGS-1058456, ATM0902730, AGS-1203299]; NASA [NNX13AE12G, NNH09AM53I, NNH09AK63I, NNH11AR07I]; DOE [DE-AC02-09CH11466]; International Space Science Institute (ISSI) International Teams Program; NSF GEM FX Simon Wing gratefully acknowledges support from NSF Grants ATM-0802715, and AGS-1058456 and NASA Grant NNX13AE12G. Jay Johnson was funded by NASA grants (NNH09AM53I, NNH09AK63I, and NNH11AR07I), NSF Grants ATM0902730 and AGS-1203299, and DOE contract DE-AC02-09CH11466. We acknowledge the support of the International Space Science Institute (ISSI) International Teams Program, which made it possible for a small team of scientists to convene and have in-depth, informal discussions on topics relevant to this paper. Last but not least, we also thank NSF GEM for supporting Plasma entry and transport into and within the magnetotail (PET) Focus Group, which provided a forum for fruitful discussions of the topics covered in this paper. NR 175 TC 16 Z9 16 U1 2 U2 9 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0038-6308 EI 1572-9672 J9 SPACE SCI REV JI Space Sci. Rev. PD NOV PY 2014 VL 184 IS 1-4 BP 1 EP 31 DI 10.1007/s11214-014-0085-z PG 31 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA AU0NJ UT WOS:000345319600001 ER PT J AU Wing, S Johnson, JR Chaston, CC Echim, M Escoubet, CP Lavraud, B Lemon, C Nykyri, K Otto, A Raeder, J Wang, CP AF Wing, S. Johnson, J. R. Chaston, C. C. Echim, M. Escoubet, C. P. Lavraud, B. Lemon, C. Nykyri, K. Otto, A. Raeder, J. Wang, C. -P. TI Review of Solar Wind Entry into and Transport Within the Plasma Sheet SO SPACE SCIENCE REVIEWS LA English DT Review DE Solar wind entry; Particle transport; Double cusp (lobe) reconnection; Kelvin-Helmholtz; Kinetic Alfven wave (KAW); Entropy; Fast flow; Turbulence; Ion to electron temperature ratio; Ion outflow ID INTERPLANETARY MAGNETIC-FIELD; KELVIN-HELMHOLTZ INSTABILITY; LATITUDE BOUNDARY-LAYER; KINETIC ALFVEN WAVES; INTERACTION OFMAGNETIC RECONNECTION; IMPULSIVE PENETRATION MECHANISM; DUAL LOBE RECONNECTION; DAWN-DUSK ASYMMETRIES; GLOBAL MHD SIMULATION; POLAR-CAP BOUNDARY AB The plasma sheet is populated in part by the solar wind plasma. Four solar entry mechanisms are examined: (1) double cusp or double lobe reconnection, (2) Kelvin-Helmholtz Instability (KHI), (3) Kinetic Alfven waves (KAW), and (4) Impulsive Penetration. These mechanisms can efficiently fill the plasma sheet with cold dense ions during northward interplanetary magnetic field (IMF). The solar wind ions appear to have been heated upon entry along the plasma sheet dawn flank. The cold-component (solar wind origin) ion density is higher on the dawn flank than the dusk flank. The asymmetric evolution of the KAW and magnetic reconnection in association with the KHI at the dawn and dusk flank magnetopause may partly produce the dawn-dusk temperature and density asymmetries. Solar wind that crosses the magnetopause lowers the specific entropy (s = p/rho(gamma)) of the plasma sheet along the flanks. Subsequent transport of the cold ions from the flanks to the midnight meridian increases s by a factor of 5. T-i, T-e, s(i), and s(e) increase when the solar wind particles are transported across the magnetopause, but T-i/T-e is roughly conserved. Within the magnetotail, E x B and curvature and gradient drifts play important roles in the plasma transport and can explain the large features seen in the plasma sheet. Turbulence can also play a significant role, particularly in the cold plasma transport from the flanks to the midnight meridian. Total entropy (S = pV(gamma)) conservation provides important constraints on the plasma sheet transport, e.g., fast flows. C1 [Wing, S.] Johns Hopkins Univ, Appl Phys Lab, Laurel, MD 20723 USA. [Johnson, J. R.] Princeton Plasma Phys Lab, Princeton, NJ 08543 USA. [Chaston, C. C.] Univ Calif Berkeley, Berkeley, CA 94720 USA. [Chaston, C. C.] Univ Sydney, Sch Phys, Sydney, NSW 2006, Australia. [Echim, M.] Inst Space Aeron, Brussels, Belgium. [Echim, M.] Inst Space Sci, Magurele, Romania. [Escoubet, C. P.] ESA ESTEC SCI RSSD, Noordwijk, Netherlands. [Lavraud, B.] Univ Toulouse, Inst Rech Astrophys & Planetol, Toulouse, France. [Lavraud, B.] Ctr Natl Rech Sci, Toulouse, France. [Lemon, C.] Aerosp Corp, El Segundo, CA 90245 USA. [Nykyri, K.] Embry Riddle Aeronaut Univ, Daytona Beach, FL USA. [Otto, A.] Univ Alaska, Fairbanks, AL 99701 USA. [Raeder, J.] Univ New Hampshire, Durham, NH 03824 USA. [Wang, C. -P.] Univ Calif Los Angeles, Los Angeles, CA USA. RP Wing, S (reprint author), Johns Hopkins Univ, Appl Phys Lab, Laurel, MD 20723 USA. EM simon.wing@jhuapl.edu RI Echim, Marius/F-1813-2010; OI Echim, Marius/0000-0001-7038-9494; Nykyri, Katariina/0000-0002-6905-9487 FU International Space Science Institute (ISSI), Bern, Switzerland; NSF [ATM-0802715, AGS-1058456, ATM0902730, AGS-1203299, ATM-0902907, AGS-1303579, 0847120, AGS-1003874]; NASA [NNX13AE12G, NNH09AM53I, NNH09AK63I, NNH11AR07I, NNX09AF49G]; DOE [DE-AC02-09CH11466]; NASA THEMIS mission [SA405826326]; Australian Research Council [FT110100316]; European Community [313038/STORM]; Romanian Ministry of National Education, CNCS, UEFISCDI [PN-II-ID PCE-2012-4-0418]; Interuniversity Attraction Poles Programme; Belgian Science Policy Office [IAP P7/08 CHARM]; NSF GEM FX International Space Science Institute (ISSI), Bern, Switzerland funded and hosted our International Team "Plasma entry and transport in the plasma sheet" that led to the publication of this paper. We are especially grateful for the ISSI facility that allows for in-depth, informal, and inspiring discussions. We acknowledge the contribution of Prof. Joseph Lemaire to the mechanism of impulsive penetration in this paper. Simon Wing gratefully acknowledges supports from NSF Grants ATM-0802715, and AGS-1058456 and NASA Grant NNX13AE12G. Jay Johnson was funded by NASA grants (NNH09AM53I, NNH09AK63I, and NNH11AR07I), NSF Grants ATM0902730 and AGS-1203299, and DOE contract DE-AC02-09CH11466. Joachim Raeder acknowledges support from the NASA THEMIS mission (UCB subcontract SA405826326) and NSF grants ATM-0902907 and AGS-1303579. Chris Chaston was supported by NASA grant NNX09AF49G and Australian Research Council FT110100316. Katariina Nykyri was supported by NSF grant 0847120. Marius Echim acknowledges support from the European Community's Seventh Framework Programme (FP7/2007-2013) under grant agreement no 313038/STORM, from the Romanian Ministry of National Education, CNCS, UEFISCDI, project number PN-II-ID PCE-2012-4-0418, and from the Interuniversity Attraction Poles Programme initiated by the Belgian Science Policy Office (IAP P7/08 CHARM). Colby Lemon was supported by NSF grant AGS-1003874. We also thank NSF GEM for supporting Plasma entry and transport into and within the magnetotail (PET) Focus Group, which provided a forum for fruitful discussions of the topics covered in this paper. NR 321 TC 11 Z9 11 U1 3 U2 21 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0038-6308 EI 1572-9672 J9 SPACE SCI REV JI Space Sci. Rev. PD NOV PY 2014 VL 184 IS 1-4 BP 33 EP 86 DI 10.1007/s11214-014-0108-9 PG 54 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA AU0NJ UT WOS:000345319600002 ER PT J AU Niezrecki, C Avitabile, P Chen, JL Sherwood, J Lundstrom, T LeBlanc, B Hughes, S Desmond, M Beattie, A Rumsey, M Klute, SM Pedrazzani, R Werlink, R Newman, J AF Niezrecki, Christopher Avitabile, Peter Chen, Julie Sherwood, James Lundstrom, Troy LeBlanc, Bruce Hughes, Scott Desmond, Michael Beattie, Alan Rumsey, Mark Klute, Sandra M. Pedrazzani, Renee Werlink, Rudy Newman, John TI Inspection and monitoring of wind turbine blade-embedded wave defects during fatigue testing SO STRUCTURAL HEALTH MONITORING-AN INTERNATIONAL JOURNAL LA English DT Article DE Digital image correlation; shearography; fiber-optic sensing; damage detection; composites; wind turbine blade; defect AB The research presented in this article focuses on a 9-m CX-100 wind turbine blade, designed by a team led by Sandia National Laboratories and manufactured by TPI Composites Inc. The key difference between the 9-m blade and baseline CX-100 blades is that this blade contains fabric wave defects of controlled geometry inserted at specified locations along the blade length. The defect blade was tested at the National Wind Technology Center at the National Renewable Energy Laboratory using a schedule of cycles at increasing load level until failure was detected. Researchers used digital image correlation, shearography, acoustic emission, fiber-optic strain sensing, thermal imaging, and piezoelectric sensing as structural health monitoring techniques. This article provides a comparison of the sensing results of these different structural health monitoring approaches to detect the defects and track the resultant damage from the initial fatigue cycle to final failure. C1 [Niezrecki, Christopher; Avitabile, Peter; Chen, Julie; Sherwood, James; Lundstrom, Troy; LeBlanc, Bruce] Univ Massachusetts, Dept Mech Engn, Lowell, MA 01854 USA. [Hughes, Scott; Desmond, Michael] Natl Renewable Energy Lab, Golden, CO USA. [Beattie, Alan; Rumsey, Mark] Sandia Natl Labs, Albuquerque, NM 87185 USA. [Klute, Sandra M.; Pedrazzani, Renee] Luna Innovations Inc, Blacksburg, VA USA. [Werlink, Rudy] NASA, Kennedy Space Ctr, Merritt Isl, FL USA. [Newman, John] Laser Technol Inc, Norristown, PA USA. RP Niezrecki, C (reprint author), Univ Massachusetts, Lowell, MA 01854 USA. EM Christopher_Niezrecki@uml.edu FU US Department of Energy (DOE) [DE-EE001374]; US Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX The authors appreciate the financial support for this work provided by the US Department of Energy (DOE) (DE-EE001374). Any opinions, findings, conclusions, or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of DOE. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the US Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. NR 24 TC 6 Z9 7 U1 1 U2 27 PU SAGE PUBLICATIONS LTD PI LONDON PA 1 OLIVERS YARD, 55 CITY ROAD, LONDON EC1Y 1SP, ENGLAND SN 1475-9217 EI 1741-3168 J9 STRUCT HEALTH MONIT JI Struct. Health Monit. PD NOV PY 2014 VL 13 IS 6 BP 629 EP 643 DI 10.1177/1475921714532995 PG 15 WC Engineering, Multidisciplinary; Instruments & Instrumentation SC Engineering; Instruments & Instrumentation GA AT9EQ UT WOS:000345231200007 ER PT J AU Mascarenas, D Plont, C Brown, C Cowell, M Jameson, NJ Block, J Djidjev, S Hahn, H Farrar, C AF Mascarenas, David Plont, Crystal Brown, Christina Cowell, Martin Jameson, N. Jordan Block, Jessica Djidjev, Stephanie Hahn, Heidi Farrar, Charles TI A vibro-haptic human-machine interface for structural health monitoring SO STRUCTURAL HEALTH MONITORING-AN INTERNATIONAL JOURNAL LA English DT Article DE Haptic; sensory substitution; human echolocation; actuator; human-machine interface; vibro-tactile; vibro-haptic ID SUPPORT VECTOR MACHINES; WIRELESS SENSORS; MONKEY HAND; SKIN; MECHANORECEPTORS; FREQUENCY; VIBRATION; DYNAMICS; STIMULI; EVENTS AB The goal of the structural health monitoring community has been to endow physical systems with a nervous system not unlike those commonly found in living organisms. Typically, the structural health monitoring community has attempted to do this by instrumenting structures with a variety of sensors and then applying various signal processing and classification procedures to the data in order to detect the presence of damage, the location of damage, the severity of damage, and to estimate the remaining useful life of the structure. This procedure has had some success, but we are still a long way from achieving the performance of nervous systems found in biology. This is primarily because contemporary classification algorithms do not have the performance required. In many cases, expert judgment is superior to automated classification. This work introduces a new paradigm. We propose interfacing the human nervous system to the distributed sensor network located on the structure and developing new techniques to enable human-machine cooperation. The results from the field of sensory substitution suggest this should be possible. This study investigates a vibro-haptic human-machine interface for structural health monitoring. The investigation was performed using a surrogate three-story structure. The structure features three nonlinearity-inducing bumpers to simulate damage. Accelerometers are placed on each floor to measure the response of the structure to a harmonic base excitation. The accelerometer measurements are preprocessed. The preprocessed data are then encoded as a vibro-tactile stimulus. Human subjects were then subjected to the vibro-tactile stimulus and asked to characterize the damage in the structure. C1 [Mascarenas, David; Farrar, Charles] Los Alamos Natl Lab, Engn Inst, Los Alamos, NM 87545 USA. [Plont, Crystal; Brown, Christina] Univ New Mexico, Dept Mech Engn, Albuquerque, NM 87131 USA. [Cowell, Martin] Colorado Sch Mines, Dept Mech Engn, Golden, CO 80401 USA. [Jameson, N. Jordan] Univ Maryland, Dept Mech Engn, College Pk, MD 20742 USA. [Block, Jessica] Georgia Inst Technol, Dept Elect Engn, Atlanta, GA 30332 USA. [Djidjev, Stephanie] Univ Calif Berkeley, Dept Comp Sci, Berkeley, CA 94720 USA. [Hahn, Heidi] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. RP Mascarenas, D (reprint author), Los Alamos Natl Lab, Engn Inst, POB 1663, Los Alamos, NM 87545 USA. EM dmascarenas@lanl.gov OI Farrar, Charles/0000-0001-6533-6996 NR 42 TC 7 Z9 7 U1 1 U2 11 PU SAGE PUBLICATIONS LTD PI LONDON PA 1 OLIVERS YARD, 55 CITY ROAD, LONDON EC1Y 1SP, ENGLAND SN 1475-9217 EI 1741-3168 J9 STRUCT HEALTH MONIT JI Struct. Health Monit. PD NOV PY 2014 VL 13 IS 6 BP 671 EP 685 DI 10.1177/1475921714556569 PG 15 WC Engineering, Multidisciplinary; Instruments & Instrumentation SC Engineering; Instruments & Instrumentation GA AT9EQ UT WOS:000345231200010 ER PT J AU Dennis, EA Gundlach-Graham, AW Ray, SJ Enke, CG Barinaga, CJ Koppenaal, DW Hieftje, GM AF Dennis, Elise A. Gundlach-Graham, Alexander W. Ray, Steven J. Enke, Christie G. Barinaga, Charles J. Koppenaal, David W. Hieftje, Gary M. TI Zoom-TOFMS: addition of a constant-momentum-acceleration "zoom" mode to time-of-flight mass spectrometry SO ANALYTICAL AND BIOANALYTICAL CHEMISTRY LA English DT Article DE Mass spectrometry; ICP-MS; Spectroscopy; Instrumentation; Metals; Heavy metals ID ELEMENTAL ANALYSIS; PERFORMANCE; RESOLUTION; ENERGY; CONSTRUCTION; DETECTOR; DESIGN; RANGE AB In this study, we demonstrate the performance of a new mass spectrometry concept called zoom time-of-flight mass spectrometry (zoom-TOFMS). In our zoom-TOFMS instrument, we combine two complementary types of TOFMS: conventional, constant-energy acceleration (CEA) TOFMS and constant-momentum acceleration (CMA) TOFMS to provide complete mass-spectral coverage as well as enhanced resolution and duty factor for a narrow, targeted mass region, respectively. Alternation between CEA- and CMA-TOFMS requires only that electrostatic instrument settings (i.e., reflectron and ion optics) and ion acceleration conditions be changed. The prototype zoom-TOFMS instrument has orthogonal-acceleration geometry, a total field-free distance of 43 cm, and a direct-current glow-discharge ionization source. Experimental results demonstrate that the CMA-TOFMS "zoom" mode offers resolution enhancement of 1.6 times over single-stage acceleration CEA-TOFMS. For the atomic mass range studied here, the maximum resolving power at full-width half-maximum observed for CEA-TOFMS was 1,610 and for CMA-TOFMS the maximum was 2,550. No difference in signal-to-noise (S/N) ratio was observed between the operating modes of zoom-TOFMS when both were operated at equivalent repetition rates. For a 10-kHz repetition rate, S/N values for CEA-TOFMS varied from 45 to 990 and from 67 to 10,000 for CMA-TOFMS. This resolution improvement is the result of a linear TOF-to-mass scale and the energy-focusing capability of CMA-TOFMS. Use of CMA also allows ions outside a given m/z range to be rejected by simple ion-energy barriers to provide a substantial improvement in duty factor. C1 [Dennis, Elise A.; Gundlach-Graham, Alexander W.; Ray, Steven J.; Enke, Christie G.; Hieftje, Gary M.] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA. [Enke, Christie G.] Univ New Mexico, Dept Chem & Chem Biol, Albuquerque, NM 87131 USA. [Barinaga, Charles J.; Koppenaal, David W.] Pacific NW Natl Lab, Richland, WA 99352 USA. RP Hieftje, GM (reprint author), Indiana Univ, Dept Chem, Bloomington, IN 47405 USA. EM hieftje@indiana.edu RI Gundlach-Graham, Alexander/B-6069-2011; OI Gundlach-Graham, Alexander/0000-0003-4806-6255; Ray, Steven/0000-0001-5675-1258 FU National Science Foundation [DBI-1062846]; US Department of Energy [DE-FG02-09ER14980, DE-AC06-76RLO-1830op] FX This work was funded in part by the National Science Foundation through grant DBI-1062846. Partial salary support was provided by the US Department of Energy through grant DE-FG02-09ER14980. The authors would like to thank the Edward G. Blair Mechanical Instrument Services and the Electronic Instrument Services Facilities at Indiana University for their assistance with instrument construction. This work was performed in collaboration with Pacific Northwest National Laboratory, operated for the US Department of Energy by Battelle Memorial Institute under contract DE-AC06-76RLO-1830op. NR 39 TC 4 Z9 4 U1 0 U2 16 PU SPRINGER HEIDELBERG PI HEIDELBERG PA TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY SN 1618-2642 EI 1618-2650 J9 ANAL BIOANAL CHEM JI Anal. Bioanal. Chem. PD NOV PY 2014 VL 406 IS 29 BP 7419 EP 7430 DI 10.1007/s00216-014-7875-8 PG 12 WC Biochemical Research Methods; Chemistry, Analytical SC Biochemistry & Molecular Biology; Chemistry GA AT3UL UT WOS:000344860300002 PM 24866712 ER PT J AU Ho, JM Newcomer, MB Ragain, CM Gascon, JA Batista, ER Loria, JP Batista, VS AF Ho, Junming Newcomer, Michael B. Ragain, Christina M. Gascon, Jose A. Batista, Enrique R. Loria, J. Patrick Batista, Victor S. TI MoD-QM/MM Structural Refinement Method: Characterization of Hydrogen Bonding in the Oxytricha nova G-Quadruplex SO JOURNAL OF CHEMICAL THEORY AND COMPUTATION LA English DT Article ID MOLECULAR-DYNAMICS SIMULATIONS; POLARIZABLE FORCE-FIELD; NMR CHEMICAL-SHIFTS; FREE-ENERGY SIMULATIONS; ADAPTED ADMA APPROACH; ELECTROSTATIC POTENTIALS; GUANINE QUARTETS; ORBITAL METHOD; PROTON-TRANSFER; X-POL AB A generalization of the Moving-Domain Quantum Mechanics/Molecular Mechanics (MoD-QM/MM) hybrid method [Gascon, J. A.; Leung, S. S. F.; Batista, E. R.; Batista, V. S. J. Chem. Theory Comput. 2006, 2, 175186] is introduced to provide a self-consistent computational protocol for structural refinement of extended systems. The method partitions the system into molecular domains that are iteratively optimized as quantum mechanical (QM) layers embedded in their surrounding molecular environment to obtain an ab initio quality description of the geometry and the molecular electrostatic potential of the extended system composed of those constituent fragments. The resulting methodology is benchmarked as applied to model systems that allow for full QM optimization as well as through refinement of the hydrogen bonding geometry in Oxytricha nova guanine quadruplex for which several studies have been reported, including the X-ray structure and NMR data. Calculations of H-1 NMR chemical shifts based on the gauge independent atomic orbital (GIAO) method and direct comparisons with experiments show that solvated MoD-QM/MM structures, sampled from explicit solvent molecular dynamics simulations, allow for NMR simulations in much improved agreement with experimental data than models based on the X-ray structure or those optimized using classical molecular mechanics force fields. C1 [Ho, Junming; Newcomer, Michael B.; Ragain, Christina M.; Gascon, Jose A.; Loria, J. Patrick; Batista, Victor S.] Yale Univ, Dept Chem, New Haven, CT 06520 USA. [Batista, Enrique R.] Los Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USA. [Loria, J. Patrick] Yale Univ, Dept Mol Biophys & Biochem, New Haven, CT 06520 USA. RP Batista, VS (reprint author), Yale Univ, Dept Chem, POB 208107, New Haven, CT 06520 USA. EM victor.batista@yale.edu RI Ho, Junming /A-1070-2012; Gascon, Joaquim/M-3598-2015; Gascon, Jose /N-5702-2016 OI Ho, Junming /0000-0001-9381-924X; Gascon, Joaquim/0000-0002-5045-1585; Gascon, Jose /0000-0002-4176-9030 FU National Science Foundation [NSF CHE-0911520]; National Institutes of Health (NIH) [1R01GM10621-01A1]; Agency for Science, Technology, and Research; NIH; NSF [CHE-0847340, MCB 1121372]; LANL CNLS Summer Program; LDRD program at Los Alamos National Laboratory (LANL); U.S. Department of Energy [DE-AC5206NA25396] FX The authors thank the two reviewers of the manuscript for their valuable comments. V.S.B. acknowledges supercomputer time from the National Energy Research Scientific Computing Center (NERSC) and support from the National Science Foundation (NSF CHE-0911520). Development of the MoD-QM/MM approach was partially funded by the National Institutes of Health (NIH) grant 1R01GM10621-01A1. J.H. acknowledges the Agency for Science, Technology, and Research for support. C.M.R. acknowledges support from the NIH Biophysical Training Grant. J.A.G. acknowledges support from NSF (CHE-0847340). J.P.L. acknowledges support from NSF MCB 1121372. M.B.N. acknowledges support from the LANL CNLS Summer Program and E.R.B. from the LDRD program at Los Alamos National Laboratory (LANL). LANL is operated by Los Alamos National Security, LLC, for the National Nuclear Security Administration of the U.S. Department of Energy under Contract DE-AC5206NA25396 NR 125 TC 5 Z9 5 U1 1 U2 20 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1549-9618 EI 1549-9626 J9 J CHEM THEORY COMPUT JI J. Chem. Theory Comput. PD NOV PY 2014 VL 10 IS 11 BP 5125 EP 5135 DI 10.1021/ct500571k PG 11 WC Chemistry, Physical; Physics, Atomic, Molecular & Chemical SC Chemistry; Physics GA AT4JI UT WOS:000344905300034 PM 26584390 ER PT J AU Nelson, AT Rittman, DR White, JT Dunwoody, JT Kato, M McClellan, KJ AF Nelson, Andrew T. Rittman, Dylan R. White, Joshua T. Dunwoody, John T. Kato, Masato McClellan, Kenneth J. TI An Evaluation of the Thermophysical Properties of Stoichiometric CeO2 in Comparison to UO2 and PuO2 SO JOURNAL OF THE AMERICAN CERAMIC SOCIETY LA English DT Article ID INERT MATRIX FUEL; THERMAL-DIFFUSIVITY MEASUREMENTS; URANIUM-DIOXIDE; SOLID-SOLUTION; PHASE-DIAGRAM; ELECTRICAL-PROPERTIES; HEAT-CAPACITY; MIXED-OXIDE; CONDUCTIVITY; PLUTONIUM AB The thermal conductivity of stoichiometric CeO2 was determined through measurement of thermal expansion from 313 to 1723 K, thermal diffusivity from 298 to 1473 K, and specific heat capacity from 313 to 1373 K. The thermal conductivity was then calculated as the product of the density, thermal diffusivity, and specific heat capacity. The thermal conductivity was found to obey an (A + BT)(-1) relationship with A = 6.776x10(-2) m center dot K center dot W-1 and B = 2.793 x 10(-4) m center dot W-1. Extrapolations of applied models were made to provide suggested data for the specific heat capacity, thermal diffusivity, and thermal conductivity data up to 1723 K. Results of thermal expansion and heat capacity measurements agreed well with the limited low-temperature data available in the literature. The thermal conductivity values provided in the current study are significantly higher than the only high-temperature data located for CeO2. This is attributed to the tendency of CeO2 to rapidly reduce at elevated temperatures given the available partial pressure of O-2 in air at ambient pressure. The CeO2 data are compared to literature values for UO2 and PuO2 to evaluate its suitability as a surrogate in nuclear fuel systems where thermal transport is a primary criterion for performance C1 [Nelson, Andrew T.; Rittman, Dylan R.; White, Joshua T.; Dunwoody, John T.; McClellan, Kenneth J.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Kato, Masato] Japan Atom Energy Agcy, Tokai, Ibaraki 3191194, Japan. RP Nelson, AT (reprint author), Los Alamos Natl Lab, POB 1667, Los Alamos, NM 87545 USA. EM atnelson@lanl.gov OI Nelson, Andrew/0000-0002-4071-3502 FU U.S. Department of Energy, Office of Nuclear Energy Fuel Cycle Research and Development program; U.S. Department of Energy Nuclear Energy University Program [DE-NE0000711]; agency of the United States Government FX The support of the U.S. Department of Energy, Office of Nuclear Energy Fuel Cycle Research and Development program is gratefully acknowledged. Portions of this work were supported by the U.S. Department of Energy Nuclear Energy University Program under contract DE-NE0000711. This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. NR 49 TC 4 Z9 4 U1 1 U2 30 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0002-7820 EI 1551-2916 J9 J AM CERAM SOC JI J. Am. Ceram. Soc. PD NOV PY 2014 VL 97 IS 11 BP 3652 EP 3659 DI 10.1111/jace.13170 PG 8 WC Materials Science, Ceramics SC Materials Science GA AT2QT UT WOS:000344779900049 ER PT J AU Paulauskas, T Buurma, C Colegrove, E Stafford, B Guo, Z Chan, MKY Sun, C Kim, MJ Sivananthan, S Klie, RF AF Paulauskas, Tadas Buurma, Christopher Colegrove, Eric Stafford, Brian Guo, Zhao Chan, Maria K. Y. Sun, Ce Kim, Moon J. Sivananthan, Sivalingam Klie, Robert F. TI Atomic scale study of polar Lomer-Cottrell and Hirth lock dislocation cores in CdTe SO ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES LA English DT Article DE Lomer-Cottrell dislocations; Hirth lock dislocations; stair-rod dislocations; dislocation cores; HAADF; STEM; XEDS; CdTe ID SOLAR-CELLS; SEMICONDUCTORS; DISPLACEMENT; EFFICIENCY; DIAMOND; STRAIN; GLIDE AB Dislocation cores have long dominated the electronic and optical behaviors of semiconductor devices and detailed atomic characterization is required to further explore their effects. Miniaturization of semiconductor devices to nanometre scale also puts emphasis on a material's mechanical properties to withstand failure due to processing or operational stresses. Sessile junctions of dislocations provide barriers to propagation of mobile dislocations and may lead to work-hardening. The sessile Lomer-Cottrell and Hirth lock dislocations, two stable lowest elastic energy stair-rods, are studied in this paper. More specifically, using atomic resolution high-angle annular dark-field imaging and atomic-column-resolved X-ray spectrum imaging in an aberration-corrected scanning transmission electron microscope, dislocation core structures are examined in zinc-blende CdTe. A procedure is outlined for atomic scale analysis of dislocation junctions which allows determination of their identity with specially tailored Burgers circuits and also formation mechanisms of the polar core structures based on Thompson's tetrahedron adapted to reactions of polar dislocations as they appear in CdTe and other zinc-blende solids. Strain fields associated with the dislocations calculated via geometric phase analysis are found to be diffuse and free of `hot spots' that reflect compact structures and low elastic energy of the pure-edge stair-rods. C1 [Paulauskas, Tadas; Buurma, Christopher; Colegrove, Eric; Stafford, Brian; Guo, Zhao; Sivananthan, Sivalingam; Klie, Robert F.] Univ Illinois, Dept Phys, Chicago, IL 60607 USA. [Colegrove, Eric] Natl Renewable Energy Lab, Boulder, CO USA. [Chan, Maria K. Y.] Argonne Natl Lab, Ctr Nanoscale Mat, Argonne, IL 60439 USA. [Sun, Ce; Kim, Moon J.] Univ Texas Dallas, Dept Mat Sci & Engn, Dallas, TX 75230 USA. RP Klie, RF (reprint author), Univ Illinois, Dept Phys, Chicago, IL 60607 USA. EM rfklie@uic.edu RI SUN, CE/G-7946-2012; Kim, Moon/A-2297-2010 OI SUN, CE/0000-0001-6310-8180; FU US Department of Energy Sunshot Program [DOE-EE00005659]; US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357] FX This work was supported by a grant from the US Department of Energy Sunshot Program (DOE-EE00005659). Use of the Center for Nanoscale Materials was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. NR 25 TC 4 Z9 4 U1 4 U2 48 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0108-7673 EI 1600-5724 J9 ACTA CRYSTALLOGR A JI Acta Crystallogr. Sect. A PD NOV PY 2014 VL 70 BP 524 EP 531 DI 10.1107/S2053273314019639 PN 6 PG 8 WC Chemistry, Multidisciplinary; Crystallography SC Chemistry; Crystallography GA AT0AM UT WOS:000344599300002 ER PT J AU Whitfield, RE Welberry, TR Pasciak, M Goossens, DJ AF Whitfield, R. E. Welberry, T. R. Pasciak, M. Goossens, D. J. TI Use of bond-valence sums in modelling the diffuse scattering from PZN (PbZn1/3Nb2/3O3) SO ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES LA English DT Article DE neutron scattering; X-ray scattering; relaxor ferroelectrics; single crystals; short-range order; diffuse scattering; PZN ID INTENSITY POWDER DIFFRACTOMETER; LOCAL-STRUCTURE; MONTE-CARLO; PARAMETERS; REFINEMENT; DISORDER; SYSTEM; WOMBAT; PAIR AB This work extends previous efforts to model diffuse scattering from PZN (PbZn1/3Nb2/3O3). Earlier work [Welberry et al. (2005). J. Appl. Cryst.38, 639-647; Welberry et al. (2006). Phys. Rev. B, 74, 224108] is highly prescriptive, using Monte Carlo simulation with very artificial potentials to induce short-range-order structures which were deduced as necessary from inspection of the data. While this gives valid results for the nature of the local structure, it does not strongly relate these structures to underlying crystal chemistry. In that work, the idea of the bond-valence sum was used as a guide to the expected behaviour of the atoms. This paper extends the use of the bond-valence sum from a qualitative guide to becoming a key aspect of the potential experienced by the atoms, through the idea of the global instability index, whose square has been shown to be proportional to the density functional theory energy of some systems when close to the minimum energy configuration. C1 [Whitfield, R. E.; Welberry, T. R.; Pasciak, M.; Goossens, D. J.] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia. [Whitfield, R. E.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. [Pasciak, M.] Acad Sci Czech Republic, Inst Phys, Prague, Czech Republic. RP Whitfield, RE (reprint author), Australian Natl Univ, Res Sch Chem, GPO Box 4, Canberra, ACT 0200, Australia. EM whitfieldre@ornl.gov RI Pasciak, Marek/G-5983-2014; Welberry, Thomas/H-7847-2014; Whitfield, Ross/P-2452-2015 OI Pasciak, Marek/0000-0002-3902-8874; Welberry, Thomas/0000-0002-6906-9191; Whitfield, Ross/0000-0002-9852-1044 FU Australian Institute of Nuclear Science and Engineering; Australian Research Council; NCI National Facility at the ANU; US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]; Scientific User Facilities Division, Office of Basic Energy Sciences, US Department of Energy FX DJG and REW gratefully acknowledge the support of the Australian Institute of Nuclear Science and Engineering. The support of the Australian Research Council and the NCI National Facility at the ANU is also gratefully acknowledged. Use of the Advanced Photon Source was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, under contract No. DE-AC02-06CH11357. Part of this work was sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, US Department of Energy. NR 34 TC 2 Z9 2 U1 1 U2 51 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0108-7673 EI 1600-5724 J9 ACTA CRYSTALLOGR A JI Acta Crystallogr. Sect. A PD NOV PY 2014 VL 70 BP 626 EP 635 DI 10.1107/S2053273314016143 PN 6 PG 10 WC Chemistry, Multidisciplinary; Crystallography SC Chemistry; Crystallography GA AT0AM UT WOS:000344599300011 ER PT J AU Jorgensen, MRV Hathwar, VR Sist, M Wang, XP Hoffmann, CM Briseno, AL Overgaard, J Iversen, BB AF Jorgensen, Mads R. V. Hathwar, Venkatesha R. Sist, Mattia Wang, Xiaoping Hoffmann, Christina M. Briseno, Alejandro L. Overgaard, Jacob Iversen, Bo B. TI Accurate atomic displacement parameters from time-of-flight neutron-diffraction data at TOPAZ SO ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES LA English DT Article DE hydrogen-atom modelling; anisotropic displacement parameters; neutron diffraction; X-ray structure refinement; electron-density refinement ID X-RAY-DIFFRACTION; WAVE-FUNCTIONS; CHARGE-DENSITIES; REFINEMENT; CRYSTALS; MOLECULE AB Accurate atomic displacement parameters (ADPs) are a good indication of high-quality diffraction data. Results from the newly commissioned time-of-flight Laue diffractometer TOPAZ at the SNS are presented. Excellent agreement is found between ADPs derived independently from the neutron and X-ray data emphasizing the high quality of the data from the time-of-flight Laue diffractometer. C1 [Jorgensen, Mads R. V.; Hathwar, Venkatesha R.; Sist, Mattia; Overgaard, Jacob; Iversen, Bo B.] Aarhus Univ, Dept Chem, Ctr Mat Crystallog, DK-8000 Aarhus C, Denmark. [Jorgensen, Mads R. V.; Hathwar, Venkatesha R.; Sist, Mattia; Overgaard, Jacob; Iversen, Bo B.] Aarhus Univ, INano, DK-8000 Aarhus C, Denmark. [Wang, Xiaoping; Hoffmann, Christina M.] Oak Ridge Natl Lab, Chem & Engn Mat Div, Oak Ridge, TN 37831 USA. [Briseno, Alejandro L.] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA. RP Overgaard, J (reprint author), Aarhus Univ, Dept Chem, Ctr Mat Crystallog, Langelandsgade 140, DK-8000 Aarhus C, Denmark. EM jacobo@chem.au.dk; bo@chem.au.dk RI Wang, Xiaoping/E-8050-2012; hoffmann, christina/D-2292-2016; Jorgensen, Mads Ry Vogel/C-6109-2017; OI Wang, Xiaoping/0000-0001-7143-8112; hoffmann, christina/0000-0002-7222-5845; Jorgensen, Mads Ry Vogel/0000-0001-5507-9615; Overgaard, Jacob/0000-0001-6492-7962 FU Danish National Research Foundation (Center for Materials Crystallography) [DNRF93]; Scientific User Facilities Division, Office of Basic Energy Sciences, US Department of Energy FX This research was supported by the Danish National Research Foundation (Center for Materials Crystallography, DNRF93). Research conducted at ORNL's Spallation Neutron Source was sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, US Department of Energy. We would like to thank the referees for their useful comments. NR 37 TC 6 Z9 6 U1 2 U2 27 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0108-7673 EI 1600-5724 J9 ACTA CRYSTALLOGR A JI Acta Crystallogr. Sect. A PD NOV PY 2014 VL 70 BP 679 EP 681 DI 10.1107/S2053273314015599 PN 6 PG 3 WC Chemistry, Multidisciplinary; Crystallography SC Chemistry; Crystallography GA AT0AM UT WOS:000344599300017 ER PT J AU Mizianty, MJ Fan, X Yan, J Chalmers, E Woloschuk, C Joachimiak, A Kurgan, L AF Mizianty, Marcin J. Fan, Xiao Yan, Jing Chalmers, Eric Woloschuk, Christopher Joachimiak, Andrzej Kurgan, Lukasz TI Covering complete proteomes with X-ray structures: a current snapshot SO ACTA CRYSTALLOGRAPHICA SECTION D-BIOLOGICAL CRYSTALLOGRAPHY LA English DT Article ID PROTEIN CRYSTALLIZATION PROPENSITY; STRUCTURE PREDICTION; SCREENING EFFICIENCY; THERMOTOGA-MARITIMA; ISOELECTRIC POINT; ESCHERICHIA-COLI; WEB SERVER; DATA-BANK; GENOMICS; SEQUENCE AB Structural genomics programs have developed and applied structure-determination pipelines to a wide range of protein targets, facilitating the visualization of macromolecular interactions and the understanding of their molecular and biochemical functions. The fundamental question of whether three-dimensional structures of all proteins and all functional annotations can be determined using X-ray crystallography is investigated. A first-of-its-kind large-scale analysis of crystallization propensity for all proteins encoded in 1953 fully sequenced genomes was performed. It is shown that current X-ray crystallographic knowhow combined with homology modeling can provide structures for 25% of modeling families (protein clusters for which structural models can be obtained through homology modeling), with at least one structural model produced for each Gene Ontology functional annotation. The coverage varies between superkingdoms, with 19% for eukaryotes, 35% for bacteria and 49% for archaea, and with those of viruses following the coverage values of their hosts. It is shown that the crystallization propensities of proteomes from the taxonomic superkingdoms are distinct. The use of knowledge-based target selection is shown to substantially increase the ability to produce X-ray structures. It is demonstrated that the human proteome has one of the highest attainable coverage values among eukaryotes, and GPCR membrane proteins suitable for X-ray structure determination were determined. C1 [Mizianty, Marcin J.; Fan, Xiao; Yan, Jing; Chalmers, Eric; Woloschuk, Christopher; Kurgan, Lukasz] Univ Alberta, Edmonton, AB T6G 2V4, Canada. [Joachimiak, Andrzej] Argonne Natl Lab, Midwest Ctr Struct Genom, Argonne, IL 60439 USA. RP Joachimiak, A (reprint author), Argonne Natl Lab, Midwest Ctr Struct Genom, 9700 S Cass Ave, Argonne, IL 60439 USA. EM andrzejj@anl.gov; lkurgan@ece.ualberta.ca RI Kurgan, Lukasz/B-5721-2009 OI Kurgan, Lukasz/0000-0002-7749-0314 FU National Institutes of Health [GM094585]; US Department of Energy, Office of Biological and Environmental Research [DE-AC02-06CH11357]; Natural Sciences and Engineering Research Council [298328]; University of Alberta FX The authors wish to thank Dr Gyorgy Babnigg at Argonne National Laboratory for useful comments. This work was supported by National Institutes of Health grant GM094585, the US Department of Energy, Office of Biological and Environmental Research under contract DE-AC02-06CH11357, Natural Sciences and Engineering Research Council Discovery grant 298328 and a Dissertation Scholarship awarded by the University of Alberta to MJM. NR 72 TC 4 Z9 5 U1 1 U2 12 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1399-0047 J9 ACTA CRYSTALLOGR D JI Acta Crystallogr. Sect. D-Biol. Crystallogr. PD NOV PY 2014 VL 70 BP 2781 EP 2793 DI 10.1107/S1399004714019427 PN 11 PG 13 WC Biochemical Research Methods; Biochemistry & Molecular Biology; Biophysics; Crystallography SC Biochemistry & Molecular Biology; Biophysics; Crystallography GA AT2UM UT WOS:000344792000001 PM 25372670 ER PT J AU St John, FJ Dietrich, D Crooks, C Pozharski, E Gonzalez, JM Bales, E Smith, K Hurlbert, JC AF St John, Franz J. Dietrich, Diane Crooks, Casey Pozharski, Edwin Gonzalez, Javier M. Bales, Elizabeth Smith, Kennon Hurlbert, Jason C. TI A novel member of glycoside hydrolase family 30 subfamily 8 with altered substrate specificity SO ACTA CRYSTALLOGRAPHICA SECTION D-BIOLOGICAL CRYSTALLOGRAPHY LA English DT Article ID ERWINIA-CHRYSANTHEMI; GLUCURONOXYLAN XYLANOHYDROLASE; XYLANASE; PROTEINS; SEQUENCE; SUGARS AB Endoxylanases classified into glycoside hydrolase family 30 subfamily 8 (GH30-8) are known to hydrolyze the hemicellulosic polysaccharide glucuronoxylan (GX) but not arabinoxylan or neutral xylooligosaccharides. This is owing to the specificity of these enzymes for the alpha-1,2-linked glucuronate (GA) appendage of GX. Limit hydrolysis of this substrate produces a series of aldouronates each containing a single GA substituted on the xylose penultimate to the reducing terminus. In this work, the structural and biochemical characterization of xylanase 30A from Clostridium papyrosolvens (CpXyn30A) is presented. This xylanase possesses a high degree of amino-acid identity to the canonical GH30-8 enzymes, but lacks the hallmark beta 8-alpha 8 loop region which in part defines the function of this GH30 subfamily and its role in GA recognition. CpXyn30A is shown to have a similarly low activity on all xylan substrates, while hydrolysis of xylohexaose revealed a competing transglycosylation reaction. These findings are directly compared with the model GH30-8 enzyme from Bacillus subtilis, XynC. Despite its high sequence identity to the GH30-8 enzymes, CpXyn30A does not have any apparent specificity for the GA appendage. These findings confirm that the typically conserved beta 8-alpha 8 loop region of these enzymes influences xylan substrate specificity but not necessarily alpha-1,4-xylanase function. C1 [St John, Franz J.; Dietrich, Diane; Crooks, Casey] US Forest Serv, Forest Prod Lab, USDA, Madison, WI 53705 USA. [Pozharski, Edwin] Univ Maryland, Dept Biochem & Mol Biol, College Pk, MD 20742 USA. [Gonzalez, Javier M.] Los Alamos Natl Lab, Biosci Div, Los Alamos, NM USA. [Bales, Elizabeth; Smith, Kennon; Hurlbert, Jason C.] Winthrop Univ, Dept Chem Phys & Geol, Rock Hill, SC 29733 USA. RP St John, FJ (reprint author), US Forest Serv, Forest Prod Lab, USDA, 1 Gifford Pinchot Dr, Madison, WI 53705 USA. EM fjstjohn@gmail.com RI St John, Franz/J-8970-2016; OI St John, Franz/0000-0003-3458-5628; Pozharski, Edwin/0000-0001-7012-5376; Gonzalez, Javier M./0000-0002-3298-2235 FU USDA Forest Service, Forest Products Laboratory, Madison, Wisconsin, USA; National Center for Research Resources [5 P20 RR016461] FX This work was primarily supported through the Wood, Fiber and Composites Research area of the USDA Forest Service, Forest Products Laboratory, Madison, Wisconsin, USA. JCH is supported by a grant from the National Center for Research Resources (5 P20 RR016461). JCH would like to acknowledge Dr Chris Davies of the Medical University of South Carolina, Charleston, South Carolina, USA for access to X-ray equipment and assistance in data collection. NR 35 TC 5 Z9 5 U1 1 U2 17 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1399-0047 J9 ACTA CRYSTALLOGR D JI Acta Crystallogr. Sect. D-Biol. Crystallogr. PD NOV PY 2014 VL 70 BP 2950 EP 2958 DI 10.1107/S1399004714019531 PN 11 PG 9 WC Biochemical Research Methods; Biochemistry & Molecular Biology; Biophysics; Crystallography SC Biochemistry & Molecular Biology; Biophysics; Crystallography GA AT2UM UT WOS:000344792000016 PM 25372685 ER PT J AU McAndrew, R Pruitt, RN Kamita, SG Pereira, JH Majumdar, D Hammock, BD Adams, PD Ronald, PC AF McAndrew, Ryan Pruitt, Rory N. Kamita, Shizuo G. Pereira, Jose Henrique Majumdar, Dipali Hammock, Bruce D. Adams, Paul D. Ronald, Pamela C. TI Structure of the OsSERK2 leucine-rich repeat extracellular domain SO ACTA CRYSTALLOGRAPHICA SECTION D-BIOLOGICAL CRYSTALLOGRAPHY LA English DT Article ID CRYSTAL-STRUCTURE; STRUCTURE REFINEMENT; PROTEIN-STRUCTURE; IMMUNE-RESPONSE; PLANT DEFENSE; RECEPTOR; KINASE; BAK1; COMPLEX; PERCEPTION AB Somatic embryogenesis receptor kinases (SERKs) are leucine-rich repeat (LRR)-containing integral membrane receptors that are involved in the regulation of development and immune responses in plants. It has recently been shown that rice SERK2 (OsSERK2) is essential for XA21-mediated resistance to the pathogen Xanthomonas oryzae pv. oryzae. OsSERK2 is also required for the BRI1-mediated, FLS2-mediated and EFR-mediated responses to brassinosteroids, flagellin and elongation factor Tu (EF-Tu), respectively. Here, crystal structures of the LRR domains of OsSERK2 and a D128N OsSERK2 mutant, expressed as hagfish variable lymphocyte receptor (VLR) fusions, are reported. These structures suggest that the aspartate mutation does not generate any significant conformational change in the protein, but instead leads to an altered interaction with partner receptors. C1 [McAndrew, Ryan; Pereira, Jose Henrique; Adams, Paul D.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Phys Biosci Div, Berkeley, CA 94720 USA. [Pruitt, Rory N.; Majumdar, Dipali; Ronald, Pamela C.] Univ Calif Davis, Plant Pathol Fac, Genome Ctr, Davis, CA 95616 USA. [Kamita, Shizuo G.; Hammock, Bruce D.] Univ Calif Davis, Dept Entomol, Davis, CA 95616 USA. [Adams, Paul D.] Univ Calif Berkeley, Dept Bioengn, Berkeley, CA 94720 USA. RP Adams, PD (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Phys Biosci Div, 1 Cyclotron Rd, Berkeley, CA 94720 USA. EM pdadams@lbl.gov RI Adams, Paul/A-1977-2013 OI Adams, Paul/0000-0001-9333-8219 FU US Department of Energy, Office of Science, Office of Biological and Environmental Research [DE-AC02-05CH11231]; NIH [GM55962]; NIEHS [R01 ES002710]; Department of Biotechnology, Government of India Overseas Fellowship; National Institutes of Health, National Institute of General Medical Sciences; Howard Hughes Medical Institute; Office of Science, Office of Basic Energy Sciences of the US Department of Energy [DE-AC02-05CH11231] FX We thank the Wilson laboratory for providing the TLR5-N14VLR-pAcGP67 vector which was used to construct the OsSERK2 expression vector. This work was part of the DOE Joint BioEnergy Institute (JBEI), which is funded by the US Department of Energy, Office of Science, Office of Biological and Environmental Research through contract DE-AC02-05CH11231 between Lawrence Berkeley National Laboratory and the US Department of Energy. This work was also funded by NIH grant No. GM55962 to PCR and NIEHS grant R01 ES002710 to BDH. DM was supported by the Department of Biotechnology, Government of India Overseas Fellowship. The Berkeley Center for Structural Biology is supported in part by the National Institutes of Health, National Institute of General Medical Sciences and the Howard Hughes Medical Institute. The Advanced Light Source is supported by the Director, Office of Science, Office of Basic Energy Sciences of the US Department of Energy under Contract No. DE-AC02-05CH11231. NR 42 TC 1 Z9 2 U1 1 U2 13 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0907-4449 EI 1399-0047 J9 ACTA CRYSTALLOGR D JI Acta Crystallogr. Sect. D-Biol. Crystallogr. PD NOV PY 2014 VL 70 BP 3080 EP 3086 DI 10.1107/S1399004714021178 PN 11 PG 7 WC Biochemical Research Methods; Biochemistry & Molecular Biology; Biophysics; Crystallography SC Biochemistry & Molecular Biology; Biophysics; Crystallography GA AT2UM UT WOS:000344792000027 PM 25372696 ER PT J AU Hengstler-Eger, RM Hoffmann, PB Kirk, MA Petry, W AF Hengstler-Eger, R. M. Hoffmann, P. B. Kirk, M. A. Petry, W. TI Studies of the Microstructural Origins of PWR Fuel Assembly Growth: The Effect of Tensile Stress on Irradiation Defect Formation in Zircaloy-4 SO ATW-INTERNATIONAL JOURNAL FOR NUCLEAR POWER LA English DT Editorial Material C1 [Hengstler-Eger, R. M.; Hoffmann, P. B.] AREVA GmbH, D-91052 Erlangen, Germany. [Kirk, M. A.] Argonne Natl Lab, Lemont, IL USA. [Petry, W.] Tech Univ Munich, Garehing, Germany. [Petry, W.] Forsch Neutronenquelle Heinz Maier Leibnitz, Garehing, Germany. RP Hengstler-Eger, RM (reprint author), AREVA GmbH, Paul Gossen Str 100, D-91052 Erlangen, Germany. NR 12 TC 0 Z9 0 U1 0 U2 4 PU INFORUM VERLAGS-VERWALTUNGSGESELLSCHAFT MBH PI BERLIN PA ROBERT-KOCH-PLATZ 4, BERLIN, 10115, GERMANY SN 1431-5254 J9 ATW-INT J NUCL POWER JI ATW-Int. J. Nucl. Power PD NOV PY 2014 VL 59 IS 11 BP 636 EP 639 PG 4 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AT5KN UT WOS:000344982200009 ER PT J AU Hoefnagels, R Searcy, E Cafferty, K Cornelissen, T Junginger, M Jacobson, J Faaij, A AF Hoefnagels, Ric Searcy, Erin Cafferty, Kara Cornelissen, Thijs Junginger, Martin Jacobson, Jacob Faaij, Andre TI Lignocellulosic feedstock supply systems with intermodal and overseas transportation SO BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR LA English DT Article DE bioenergy; biomass trade; GIS; logistics; pellets ID COST-ANALYSIS; BIOMASS FEEDSTOCK; LOGISTICS; ENERGY; BIOFUELS; ETHANOL; CHAINS; TORREFACTION; PERSPECTIVE; PERFORMANCE AB With growing demand for internationally traded biomass, the logistic operations required to economically move biomass from the field or forest to end-users have become increasingly complex. To design cost effective and sustainable feedstock supply chains, it is important to understand the economics, energy and greenhouse gas (GHG) emissions, their interdependencies, and the related uncertainties of the logistic process operations of international supply chains. This paper presents an approach to assessing lignocellulosic feedstock supply systems at the operational level. For this purpose, the Biomass Logistic Model (BLM) has been linked with the Geographic Information Systems-based Biomass Intermodal Transportation Model (BIT-UU) and extended with inter-continental transport routes. Case studies of herbaceous and woody biomass, produced in the US Midwest and US Southeast, respectively, and shipped to Europe for conversion to Fischer-Tropsch (FT) diesel are included to demonstrate how intermodal transportation and, in particular, overseas shipping integrates with the bioenergy supply chains. For the cases demonstrated, biomass can be supplied at 99 (sic) Mg-1 to 117 (sic) Mg-1 (dry) and converted to FT diesel at 19 (sic) GJ(-1) to 24 (sic) GJ(-1) depending on the feedstock type and location, intermediate (chips or pellets) and size of the FT diesel production plant. With the flexibility to change the design of supply chains as well as input variables, many alternative supply chain cases can be assessed. (C) 2014 Society of Chemical Industry and John Wiley & Sons, Ltd C1 [Hoefnagels, Ric; Cornelissen, Thijs; Junginger, Martin] Univ Utrecht, NL-3584 CD Utrecht, Netherlands. [Searcy, Erin; Cafferty, Kara; Jacobson, Jacob] Idaho Natl Lab, Idaho Falls, ID 83415 USA. [Faaij, Andre] Univ Groningen, NL-9700 AB Groningen, Netherlands. RP Hoefnagels, R (reprint author), Univ Utrecht, Copernicus Inst Sustainable Dev, NL-3584 CD Utrecht, Netherlands. EM e.t.a.hoefnagels@uu.nl RI Faaij, Andre/E-8424-2014; Junginger, Martin/A-2687-2009 OI Junginger, Martin/0000-0002-5010-2051 NR 64 TC 0 Z9 0 U1 1 U2 17 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1932-104X EI 1932-1031 J9 BIOFUEL BIOPROD BIOR JI Biofuels Bioprod. Biorefining PD NOV-DEC PY 2014 VL 8 IS 6 BP 794 EP 818 DI 10.1002/bbb.1497 PG 25 WC Biotechnology & Applied Microbiology; Energy & Fuels SC Biotechnology & Applied Microbiology; Energy & Fuels GA AT1HU UT WOS:000344684800015 ER PT J AU Tolbert, A Akinosho, H Khunsupat, R Naskar, AK Ragauskas, AJ AF Tolbert, Allison Akinosho, Hannah Khunsupat, Ratayakorn Naskar, Amit K. Ragauskas, Arthur J. TI Characterization and analysis of the molecular weight of lignin for biorefining studies SO BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR LA English DT Review DE lignin; average molecular weight; isolation; pre-treatment; characterization ID SIZE-EXCLUSION CHROMATOGRAPHY; MILLED WOOD LIGNIN; GEL-PERMEATION CHROMATOGRAPHY; CELLULOLYTIC ENZYME LIGNIN; ETHANOL ORGANOSOLV PROCESS; FLIGHT MASS-SPECTROMETRY; DILUTE-ACID PRETREATMENT; LASER-LIGHT SCATTERING; STRUCTURAL-CHARACTERIZATION; KRAFT LIGNIN AB The molecular weight of lignin is a fundamental property that influences the recalcitrance of biomass and the valorization of lignin. The determination of the molecular weight of lignin in native biomass is dependent on the bioresources used and the isolation and purification procedures employed. The three most commonly employed isolation methods are milled wood lignin (MWL), cellulolytic enzyme lignin (CEL), and enzymatic mild acidolysis lignin (EMAL). Common characterization techniques for determining the molecular weight of lignin will be addressed, with an emphasis on gel permeation chromatography (GPC). This review also examines the mechanisms behind several biological, physical, and chemical pre-treatments and their impact on the molecular weight of lignin. The number average molecular weight (M-n), weight average molecular weight (M-w) and polydispersity index (D) all vary in magnitude depending on the biomass source, pre-treatment conditions, and isolation method. Additionally, there is a growing body of literature that supports changes in the molecular weight of lignin in response to genetic modifications in the lignin biosynthetic pathways. This review summarizes different procedures for obtaining the molecular weight of lignin that have been used in recent years and highlight future opportunities for applications of lignin. (C) 2014 Society of Chemical Industry and John Wiley & Sons, Ltd C1 [Tolbert, Allison; Akinosho, Hannah; Khunsupat, Ratayakorn] Georgia Inst Technol, Atlanta, GA 30332 USA. [Naskar, Amit K.] Oak Ridge Natl Lab, Oak Ridge, TN USA. [Ragauskas, Arthur J.] Georgia Inst Technol, Sch Chem & Biochem, Inst Paper Sci & Technol, BioEnergy Sci Ctr, Atlanta, GA 30332 USA. RP Ragauskas, AJ (reprint author), Georgia Inst Technol, Sch Chem & Biochem, Inst Paper Sci & Technol, Atlanta, GA 30332 USA. EM arthur.ragauskas@chemistry.gatech.edu OI Ragauskas, Arthur/0000-0002-3536-554X FU Georgia Tech [4000116095, DE-AC05-00OR22725]; US Department of Energy; Laboratory Directed Research and Development Program of Oak Ridge National Laboratory; Paper Science & Engineering (PSE) fellowship program at Institute of Paper Science & Technology (IPST) at Georgia Institute of Technology FX This manuscript has been authored, in part, by Georgia Tech under Subcontract No. 4000116095 and Contract No. DE-AC05-00OR22725 with the US Department of Energy. A.K.N. and R.K. acknowledges research sponsorship by the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the US Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of the manuscript or allow others to do so, for United States Government purposes. A.T. and H.K. are grateful for the financial support from the Paper Science & Engineering (PSE) fellowship program at Institute of Paper Science & Technology (IPST) at Georgia Institute of Technology. NR 171 TC 29 Z9 30 U1 15 U2 110 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1932-104X EI 1932-1031 J9 BIOFUEL BIOPROD BIOR JI Biofuels Bioprod. Biorefining PD NOV-DEC PY 2014 VL 8 IS 6 BP 836 EP 856 DI 10.1002/bbb.1500 PG 21 WC Biotechnology & Applied Microbiology; Energy & Fuels SC Biotechnology & Applied Microbiology; Energy & Fuels GA AT1HU UT WOS:000344684800017 ER PT J AU Wang, D Phan, N Isely, C Bruene, L Bratlie, KM AF Wang, Daniel Ngoc Phan Isely, Christopher Bruene, Lucas Bratlie, Kaitlin M. TI Effect of Surface Modification and Macrophage Phenotype on Particle Internalization SO BIOMACROMOLECULES LA English DT Article ID SELF-ASSEMBLED MONOLAYERS; IN-VITRO; COMPLEMENT ACTIVATION; PROTEIN ADSORPTION; FUNCTIONAL-GROUPS; PHAGOCYTOSIS; NANOPARTICLES; MICROSPHERES; CHEMISTRY; SIZE AB Material properties play a key role in the cellular internalization of polymeric particles. In the present study, we have investigated the effects of material characteristics such as water contact angle, zeta potential, melting temperature, and alternative activation of complement on particle internalization for pro-inflammatory, pro-angiogenic, and naive macrophages by using biopolymers (similar to 600 nm), functionalized with 13 different molecules. Understanding how material parameters influence particle internalization for different macrophage phenotypes is important for targeted delivery to specific cell populations. Here, we demonstrate that material parameters affect the alternative pathway of complement activation as well as particle internalization for different macrophage phenotypes. Here, we show that the quantitative structureactivity relationship method (QSAR) previously used to predict physiochemical properties of materials can be applied to targeting different macrophage phenotypes. These findings demonstrated that targeted drug delivery to macrophages could be achieved by exploiting material parameters. C1 [Wang, Daniel; Bratlie, Kaitlin M.] Iowa State Univ, Dept Mat Sci & Engn, Ames, IA 50011 USA. [Ngoc Phan; Isely, Christopher; Bruene, Lucas; Bratlie, Kaitlin M.] Iowa State Univ, Dept Chem & Biol Engn, Ames, IA 50011 USA. [Bratlie, Kaitlin M.] Ames Natl Lab, Ames, IA 50011 USA. RP Bratlie, KM (reprint author), Iowa State Univ, Dept Mat Sci & Engn, Ames, IA 50011 USA. EM kbratlie@iastate.edu FU National Science Foundation [CBET 1227867]; Roy J. Carver Charitable Trust Grant [13-4265]; NSF ARI-R2 [CMMI-0963224] FX This work was supported by the National Science Foundation under Grant No. CBET 1227867 and the Roy J. Carver Charitable Trust Grant No. 13-4265. The authors also acknowledge support from NSF ARI-R2 (CMMI-0963224) for funding the renovation of the research laboratories used for these studies. NR 44 TC 7 Z9 7 U1 2 U2 19 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1525-7797 EI 1526-4602 J9 BIOMACROMOLECULES JI Biomacromolecules PD NOV PY 2014 VL 15 IS 11 BP 4102 EP 4110 DI 10.1021/bm5011382 PG 9 WC Biochemistry & Molecular Biology; Chemistry, Organic; Polymer Science SC Biochemistry & Molecular Biology; Chemistry; Polymer Science GA AT1WI UT WOS:000344721400024 PM 25268218 ER PT J AU Petridis, L O'Neill, HM Johnsen, M Fan, BX Schulz, R Mamontov, E Maranas, J Langan, P Smith, JC AF Petridis, Loukas O'Neill, Hugh M. Johnsen, Mariah Fan, Bingxin Schulz, Roland Mamontov, Eugene Maranas, Janna Langan, Paul Smith, Jeremy C. TI Hydration Control of the Mechanical and Dynamical Properties of Cellulose SO BIOMACROMOLECULES LA English DT Article ID PARTICLE MESH EWALD; BACTERIAL CELLULOSE; MOLECULAR SIMULATION; CELL-WALLS; WATER; TRANSITIONS; PROTEIN; TEMPERATURE; MODULUS; BIOMASS AB The mechanical and dynamical properties of cellulose, the most abundant biomolecule on earth, are essential for its function in plant cell walls and advanced biomaterials. Cellulose is almost always found in a hydrated state, and it is therefore important to understand how hydration influences its dynamics and mechanics. Here, the nanosecond-time scale dynamics of cellulose is characterized using dynamic neutron scattering experiments and molecular dynamics (MD) simulation. The experiments reveal that hydrated samples exhibit a higher average mean-square displacement above similar to 240 K. The MD simulation reveals that the fluctuations of the surface hydroxymethyl atoms determine the experimental temperature and hydration dependence. The increase in the conformational disorder of the surface hydroxymethyl groups with temperature follows the cellulose persistence length, suggesting a coupling between structural and mechanical properties of the biopolymer. In the MD simulation, 20% hydrated cellulose is more rigid than the dry form, due to more closely packed cellulose chains and water molecules bridging cellulose monomers with hydrogen bonds. This finding may have implications for understanding the origin of strength and rigidity of secondary plant cell walls. The detailed characterization obtained here describes how hydration-dependent increased fluctuations and hydroxymethyl disorder at the cellulose surface lead to enhancement of the rigidity of this important biomolecule. C1 [Petridis, Loukas; Johnsen, Mariah; Schulz, Roland; Smith, Jeremy C.] Oak Ridge Natl Lab, UT ORNL Ctr Mol Biophys, Oak Ridge, TN 37831 USA. [O'Neill, Hugh M.; Langan, Paul] Oak Ridge Natl Lab, Biol & Soft Matter Div, Oak Ridge, TN 37831 USA. [O'Neill, Hugh M.; Langan, Paul] Oak Ridge Natl Lab, Ctr Struct Mol Biol, Oak Ridge, TN 37831 USA. [Mamontov, Eugene] Oak Ridge Natl Lab, Chem & Engn Mat Div, Oak Ridge, TN 37831 USA. [Johnsen, Mariah] Ripon Coll, Ripon, WI 54971 USA. [Fan, Bingxin; Maranas, Janna] Penn State Univ, Dept Chem Engn, University Pk, PA 16802 USA. [Schulz, Roland; Smith, Jeremy C.] Univ Tennessee, Dept Biochem & Cellular & Mol Biol, Knoxville, TN 37996 USA. [Langan, Paul] Univ Toledo, Dept Chem, Toledo, OH 43606 USA. RP Petridis, L (reprint author), Oak Ridge Natl Lab, UT ORNL Ctr Mol Biophys, Oak Ridge, TN 37831 USA. EM petridisl@ornl.gov RI Schulz, Roland/A-1868-2010; Langan, Paul/N-5237-2015; Mamontov, Eugene/Q-1003-2015; smith, jeremy/B-7287-2012; Petridis, Loukas/B-3457-2009 OI Schulz, Roland/0000-0003-1603-2413; Langan, Paul/0000-0002-0247-3122; O'Neill, Hugh/0000-0003-2966-5527; Mamontov, Eugene/0000-0002-5684-2675; smith, jeremy/0000-0002-2978-3227; Petridis, Loukas/0000-0001-8569-060X FU U.S. Department of Energy (DOE), Office of Science Office of Biological and Environmental Research, Genomic Science Program [FWP ERKP752]; U.S. Department of Energy (DOE) Office of Basic Energy Sciences, through support for the Center for LignoCellulose Structure and Formation, an Energy Frontier Research Center [DE-SC0001090]; U.S. Department of Energy (DOE) Office of Basic Energy Sciences through support for research at Oak Ridge National Laboratory's Spallation Neutron Source by the Scientific User Facilities Division; Office of Science of DOE [DE-AC02-05CH11231] FX This research is supported by the U.S. Department of Energy (DOE), Office of Science (i) Office of Biological and Environmental Research, Genomic Science Program, under Award FWP ERKP752 and through support for the Center for Structural Molecular Biology; and (ii) Office of Basic Energy Sciences, through support for the Center for LignoCellulose Structure and Formation, an Energy Frontier Research Center, funded under Award DE-SC0001090 and support for research at Oak Ridge National Laboratory's Spallation Neutron Source by the Scientific User Facilities Division. This research used resources of NERSC, supported by the Office of Science of DOE under Contract No. DE-AC02-05CH11231. NR 47 TC 10 Z9 10 U1 4 U2 61 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1525-7797 EI 1526-4602 J9 BIOMACROMOLECULES JI Biomacromolecules PD NOV PY 2014 VL 15 IS 11 BP 4152 EP 4159 DI 10.1021/bm5011849 PG 8 WC Biochemistry & Molecular Biology; Chemistry, Organic; Polymer Science SC Biochemistry & Molecular Biology; Chemistry; Polymer Science GA AT1WI UT WOS:000344721400029 PM 25325376 ER PT J AU Harvey, JR AF Harvey, John R. TI Reforming the US nuclear weapons enterprise SO BULLETIN OF THE ATOMIC SCIENTISTS LA English DT Article DE Energy Department; Lawrence Livermore; life-extension programs; Los Alamos; national laboratories; NNSA; nuclear weapons complex; Pantex; Sandia; Savannah River; Y-12 AB Management and governance problems within the nuclear weapons enterprise are complex and cross jurisdictional boundaries. These problems have been repeatedly studied and are the target of yet another study, coming to completion as this article was being written. The studies agree on many of the steps that must be taken if the US nuclear weapons complex is to be reformed. What the government needs now is leadership determined to actually implement the necessary changes within the NNSA, its labs and plants, and the Energy Department for reform to succeed. Successful implementation requires the creation of champions who are empowered to effect real change, and institutionalized means of monitoring progress on implementation. Once the recommendations of the latest study are issued, Congress should establish an independent group to monitor progress on implementation. C1 [Harvey, John R.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Harvey, John R.] Stanford Univ, Ctr Int Secur & Arms Control, Stanford, CA 94305 USA. [Harvey, John R.] US Dept Def, Washington, DC USA. RP Harvey, JR (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. NR 2 TC 0 Z9 0 U1 1 U2 5 PU SAGE PUBLICATIONS LTD PI LONDON PA 1 OLIVERS YARD, 55 CITY ROAD, LONDON EC1Y 1SP, ENGLAND SN 0096-3402 EI 1938-3282 J9 B ATOM SCI JI Bull. Atom. Scient. PD NOV-DEC PY 2014 VL 70 IS 6 BP 29 EP 38 DI 10.1177/0096340214555080 PG 10 WC International Relations; Social Issues SC International Relations; Social Issues GA AT0FB UT WOS:000344611500006 ER PT J AU Rosner, R Lordan, R AF Rosner, Robert Lordan, Rebecca TI Why America should move toward dry cask consolidated interim storage of used nuclear fuel SO BULLETIN OF THE ATOMIC SCIENTISTS LA English DT Article DE canister; disposal; dry cask; interim storage; nuclear waste; permanent storage; used fuel AB Despite the recommendations of the 2012 Blue Ribbon Commission Report, the US government has made no substantial progress toward the permanent, or even temporary, consolidated storage of used(1) civilian nuclear fuel. To complicate matters, a November 2013 decision by the United States Court of Appeals (2013) in Washington, DC eliminated the very fee designed to finance used-fuel storagewhich had accumulated over $30 billion so farintroducing a further obstacle (Nuclear Energy Institute, 2014a). It was not supposed to be this way. The 1982 Nuclear Waste Policy Act bound the federal government by law to take custody of all civilian waste from power companies for final disposal, under the assumption that the waste would be permanently stored in a deep geological repository at Nevada's Yucca Mountain and overseen by the Energy Department. The Act obligated the US government to begin accepting waste by 1998, but the government was unable to fulfill this promise, forcing it to remunerate the utility companies for continuing to store the waste and assume liability. This situation cannot continue. As a solution, the commission argues that the US government should establish a widely distributed series of regional, government-run sites that would take in the used fuel from the cooling pools of several reactors, thereby consolidating the interim storage of used fuel and putting this nuclear waste into stronger, safer, more secure, more manageableand ultimately more affordabledry casks, as a first step toward ultimate disposal. Dry casks have withstood earthquakes and floods, and are designed to withstand the heat of fires and the impact of airplanes; the 100-ton structures are hard to steal or damage, and require no cooling systems or power supplies. These are some of the many reasons why making the transition to dry cask-based interim storage should be made as quickly as possible, regardless of one's opinion of civilian nuclear power. C1 [Rosner, Robert] Univ Chicago, Dept Astron & Astrophys, Chicago, IL 60637 USA. [Rosner, Robert] Univ Chicago, Dept Phys, Chicago, IL 60637 USA. [Rosner, Robert; Lordan, Rebecca] Univ Chicago, Harris Sch Publ Policy, Chicago, IL 60637 USA. [Rosner, Robert] Argonne Natl Lab, Argonne, IL 60439 USA. [Rosner, Robert] Energy Policy Inst, Chicago, IL USA. RP Rosner, R (reprint author), Univ Chicago, Dept Astron & Astrophys, Chicago, IL 60637 USA. NR 27 TC 0 Z9 0 U1 4 U2 18 PU SAGE PUBLICATIONS LTD PI LONDON PA 1 OLIVERS YARD, 55 CITY ROAD, LONDON EC1Y 1SP, ENGLAND SN 0096-3402 EI 1938-3282 J9 B ATOM SCI JI Bull. Atom. Scient. PD NOV-DEC PY 2014 VL 70 IS 6 BP 48 EP 62 DI 10.1177/0096340214555107 PG 15 WC International Relations; Social Issues SC International Relations; Social Issues GA AT0FB UT WOS:000344611500008 ER PT J AU Hagos, S Leung, LR Xue, YK Boone, A de Sales, F Neupane, N Huang, M Yoon, JH AF Hagos, Samson Leung, L. Ruby Xue, Yongkang Boone, Aaron de Sales, Fernando Neupane, Naresh Huang, Maoyi Yoon, Jin-Ho TI Assessment of uncertainties in the response of the African monsoon precipitation to land use change simulated by a regional model SO CLIMATE DYNAMICS LA English DT Article DE African monsoon; Land use change; Land cover change; African Easterly Jet; Land degradation; Crop land; Pasture land; Regional model simulations; Land surface models ID DATA ASSIMILATION SYSTEM; SAHEL RAINFALL; PART II; CLIMATE; DROUGHT; PARAMETERIZATION; DESERTIFICATION; DEFORESTATION; CONVECTION; VEGETATION AB Land use and land cover (LULC) over Africa have changed substantially over the last 60 years and this change has been proposed to affect monsoon circulation and precipitation. This study examines the uncertainties of model simulated response in the African monsoon system and Sahel precipitation due to LULC change using a set of regional model simulations with different combinations of land surface and cumulus parameterization schemes. Although the magnitude of the response covers a broad range of values, most of the simulations show a decline in Sahel precipitation due to the expansion of pasture and croplands at the expense of trees and shrubs and an increase in surface air temperature. The relationship between the model responses to LULC change and the climatologists of the control simulations is also examined. Simulations that are climatologically too dry or too wet compared to observations and reanalyses have weak response to land use change because they are in moisture or energy limited regimes respectively. The ones that lie in between have stronger response to the LULC changes, showing a more significant role in land-atmosphere interactions. Much of the change in precipitation is related to changes in circulation, particularly to the response of the intensity and latitudinal position of the African Easterly Jet, which varies with the changes in meridional surface temperature gradients. The study highlights the need for measurements of the surface fluxes across the meridional cross-section of the Sahel to evaluate models and thereby allowing human impacts such as land use change on the monsoon to be projected more realistically. C1 [Hagos, Samson; Leung, L. Ruby; Huang, Maoyi; Yoon, Jin-Ho] Pacific NW Natl Lab, Richland, WA 99352 USA. [Xue, Yongkang; Boone, Aaron; de Sales, Fernando] Univ Calif Los Angeles, Los Angeles, CA USA. [Neupane, Naresh] Univ Texas Austin, Austin, TX 78712 USA. RP Hagos, S (reprint author), Pacific NW Natl Lab, Richland, WA 99352 USA. EM samson.hagos@pnnl.gov RI YOON, JIN-HO/A-1672-2009; Huang, Maoyi/I-8599-2012 OI YOON, JIN-HO/0000-0002-4939-8078; Huang, Maoyi/0000-0001-9154-9485 FU Office of Science of the U.S. Department of Energy; DOE [DE-AC05-76RLO1830] FX The authors thank Dr. Yun Qian for his comments and suggestions. This research was supported by the Office of Science of the U.S. Department of Energy as part of the Regional and Global Climate Modeling Program and Earth System Modeling Program. Computing resources for the simulations are provided by the National Energy Research Scientific Computing Center (NERSC) and Oak Ridge Leadership Computing Facility (OLCF). The Pacific Northwest National Laboratory is operated for DOE by Battelle Memorial Institute under Contract DE-AC05-76RLO1830. The UDel_AirT_Precip data are provided by the NOAA/OAR/ESRL PSD, Boulder, Colorado, USA, from their Web site at http://www.esrl.noaa.gov/psd/. NR 42 TC 9 Z9 9 U1 4 U2 26 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0930-7575 EI 1432-0894 J9 CLIM DYNAM JI Clim. Dyn. PD NOV PY 2014 VL 43 IS 9-10 BP 2765 EP 2775 DI 10.1007/s00382-014-2092-x PG 11 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA AS8DJ UT WOS:000344480100024 ER PT J AU Hack, JJ Papka, ME AF Hack, James J. Papka, Michael E. TI New Frontiers in Leadership Computing SO COMPUTING IN SCIENCE & ENGINEERING LA English DT Editorial Material C1 [Hack, James J.] Oak Ridge Natl Lab, Natl Ctr Computat Sci, Oak Ridge Leadership Comp Facil, Oak Ridge, TN 37831 USA. [Papka, Michael E.] Argonne Natl Lab, Argonne Leadership Comp Facil, Argonne, IL 60439 USA. [Papka, Michael E.] No Illinois Univ, De Kalb, IL 60115 USA. RP Hack, JJ (reprint author), Oak Ridge Natl Lab, Natl Ctr Computat Sci, Oak Ridge Leadership Comp Facil, Oak Ridge, TN 37831 USA. EM jhack@ornl.gov; papka@anl.gov NR 0 TC 0 Z9 0 U1 1 U2 1 PU IEEE COMPUTER SOC PI LOS ALAMITOS PA 10662 LOS VAQUEROS CIRCLE, PO BOX 3014, LOS ALAMITOS, CA 90720-1314 USA SN 1521-9615 EI 1558-366X J9 COMPUT SCI ENG JI Comput. Sci. Eng. PD NOV-DEC PY 2014 VL 16 IS 6 BP 10 EP 12 PG 3 WC Computer Science, Interdisciplinary Applications SC Computer Science GA AT3OM UT WOS:000344843900002 ER PT J AU Rasquin, M Smith, C Chitale, K Seol, ES Matthews, BA Martin, JL Sahni, O Loy, RM Shephard, MS Jansen, KE AF Rasquin, Michel Smith, Cameron Chitale, Kedar Seol, E. Seegyoung Matthews, Benjamin A. Martin, Jeffrey L. Sahni, Onkar Loy, Raymond M. Shephard, Mark S. Jansen, Kenneth E. TI Scalable Implicit Flow Solver for Realistic Wing Simulations with Flow Control SO COMPUTING IN SCIENCE & ENGINEERING LA English DT Article AB An active flow control application on a realistic wing design could be leveraged by a scalable, fully implicit, unstructured, finite-element flow solver and high-performance computing resources. This article describes the active flow control application; summarizes the main features in the implementation of a massively parallel turbulent flow solver, PHASTA; and demonstrates the method's strong scalability at extreme scale. C1 [Rasquin, Michel; Loy, Raymond M.] Argonne Natl Lab, Argonne Leadership Comp Facil, Argonne, IL 60439 USA. [Smith, Cameron] Rensselaer Polytech Inst, Ctr Computat Innovat, Troy, NY 12181 USA. [Smith, Cameron; Shephard, Mark S.] Rensselaer Polytech Inst, Sci Computat Res Ctr, Troy, NY 12181 USA. [Chitale, Kedar; Seol, E. Seegyoung] Rensselaer Polytech Inst, Troy, NY 12181 USA. [Matthews, Benjamin A.; Martin, Jeffrey L.] Univ Colorado Boulder, Boulder, CO USA. [Sahni, Onkar] Rensselaer Polytech Inst, Dept Mech Aerosp & Nucl Engn, Troy, NY 12181 USA. [Jansen, Kenneth E.] Univ Colorado Boulder, Aerosp Engn Dept, Boulder, CO USA. RP Rasquin, M (reprint author), Argonne Natl Lab, Argonne Leadership Comp Facil, Argonne, IL 60439 USA. EM mrasquin@alcf.anl.gov; smithc11@rpi.edu; chitak2@rpi.edu; seols@rpi.edu; benjamin.a.matthews@colorado.edu; jerey.l.martin@colorado.edu; sahni@rpi.edu; rloy@alcf.anl.gov; shephard@rpi.edu; kenneth.jansen@colorado.edu OI Rasquin, Michel/0000-0002-3619-2177 FU Office of Advanced Scientific Computing Research, Office of Science, US Department of Energy [DE-AC02-06CH11357]; US Department of Energy [DE-SC00066117]; National Science Foundation [0749152]; NSF [CNS-0821794]; University of Colorado Boulder FX We thank the Leadership Computing Facility at Argonne National Laboratory for use of its resources. This work was supported by the Office of Advanced Scientific Computing Research, Office of Science, US Department of Energy, under contract DE-AC02-06CH11357; US Department of Energy under grant DE-SC00066117 (FASTMath SciDAC Institute), and in part by the National Science Foundation under grant 0749152. This work used the Janus supercomputer, which is supported by the NSF (award CNS-0821794) and the University of Colorado Boulder. The Janus supercomputer is a joint effort of the University of Colorado Boulder, the University of Colorado Denver, and the National Center for Atmospheric Research. The solution presented here made use of software components provided by Altair Engineering (Acusim), Simmetrix, and Kitware. We thank Daniel Ibanez from Rensselaer Polytechnic Institute for his contribution to the meshing tools used in this work. NR 12 TC 7 Z9 7 U1 0 U2 1 PU IEEE COMPUTER SOC PI LOS ALAMITOS PA 10662 LOS VAQUEROS CIRCLE, PO BOX 3014, LOS ALAMITOS, CA 90720-1314 USA SN 1521-9615 EI 1558-366X J9 COMPUT SCI ENG JI Comput. Sci. Eng. PD NOV-DEC PY 2014 VL 16 IS 6 BP 13 EP 21 PG 9 WC Computer Science, Interdisciplinary Applications SC Computer Science GA AT3OM UT WOS:000344843900003 ER PT J AU Trebotich, D Adams, MF Molins, S Steefel, CI Shen, CP AF Trebotich, David Adams, Mark F. Molins, Sergi Steefel, Carl I. Shen, Chaopeng TI High-Resolution Simulation of Pore-Scale Reactive Transport Processes Associated with Carbon Sequestration SO COMPUTING IN SCIENCE & ENGINEERING LA English DT Article ID EMBEDDED BOUNDARY METHOD; NAVIER-STOKES EQUATIONS; FLOW AB New investigative tools, combined with experiments and computational methods, are being developed to build a next-generation understanding of molecular-to-pore-scale processes in fluid-rock systems. A new numerical simulation modeling capability, known as Chombo-Crunch, resolves flow and transport processes in geometric features obtained from image data of realistic pore space at unprecedented scale and resolution. C1 [Trebotich, David; Adams, Mark F.] Lawrence Berkeley Natl Lab, Computat Res Div, Appl Numer Algorithms Grp, Berkeley, CA 94720 USA. [Molins, Sergi; Steefel, Carl I.] Lawrence Berkeley Natl Lab, Div Earth Sci, Berkeley, CA USA. [Shen, Chaopeng] Penn State Univ, University Pk, PA 16802 USA. RP Trebotich, D (reprint author), Lawrence Berkeley Natl Lab, Computat Res Div, Appl Numer Algorithms Grp, Berkeley, CA 94720 USA. EM dptrebotich@lbl.gov; dptrebotich@lbl.gov; smolins@lbl.gov; smolins@lbl.gov; cshen@engr.psu.edu RI Molins, Sergi/A-9097-2012; Steefel, Carl/B-7758-2010; OI Molins, Sergi/0000-0001-7675-3218; Shen, Chaopeng/0000-0002-0685-1901 FU Office of Advanced Scientific Computing Research; Center for Nanoscale Control of Geologic CO2, an Energy Frontier Research Center - Office of Basic Energy National Laboratory FX This work was funded by the Office of Advanced Scientific Computing Research, in part by the Center for Nanoscale Control of Geologic CO2, an Energy Frontier Research Center funded by the Office of Basic Energy National Laboratory. He was instrumental in interfacing the Crunch Flow geochemistry module with the Chombo flow and transport solver. Molins has a PhD in computational science from the University of California, Berkeley, and in civil engineering from the University of British Columbia. Contact him at smolins@lbl.gov. NR 20 TC 10 Z9 10 U1 0 U2 19 PU IEEE COMPUTER SOC PI LOS ALAMITOS PA 10662 LOS VAQUEROS CIRCLE, PO BOX 3014, LOS ALAMITOS, CA 90720-1314 USA SN 1521-9615 EI 1558-366X J9 COMPUT SCI ENG JI Comput. Sci. Eng. PD NOV-DEC PY 2014 VL 16 IS 6 BP 22 EP 31 PG 10 WC Computer Science, Interdisciplinary Applications SC Computer Science GA AT3OM UT WOS:000344843900004 ER PT J AU Amundson, J Macridin, A Spentzouris, P AF Amundson, James Macridin, Alexandru Spentzouris, Panagiotis TI High-Performance Computing Modeling Advances Accelerator Science for High-Energy Physics SO COMPUTING IN SCIENCE & ENGINEERING LA English DT Article AB Particle accelerators are essential for advancing our understanding of matter, energy, space, and time. Because they exhibit many physical effects on multiple scales, advanced computational tools are essential for accurately modeling them. The authors focus here on Synergia, an accelerator simulation package capable of handling the entire spectrum of beam dynamics simulations. C1 [Amundson, James] Fermilab Natl Accelerator Lab, Sci Software Infrastruct Dept, Batavia, IL 60510 USA. [Macridin, Alexandru] Fermilab Natl Accelerator Lab, Div Comp Sci, Batavia, IL USA. [Spentzouris, Panagiotis] Fermilab Natl Accelerator Lab, Sci Comp Div, Batavia, IL USA. RP Amundson, J (reprint author), Fermilab Natl Accelerator Lab, Sci Software Infrastruct Dept, Batavia, IL 60510 USA. EM amundson@fnal.gov; macridin@fnal.gov; spentz@fnal.gov FU US Department of Energy [De-AC02-07CH11359]; ComPASS project via the Scientific Discovery through Advanced Computing program in the DoE Office of High Energy Physics; Office of Science of the DoE [DE-AC02-06CH11357] FX This work was performed at Fermi lab, operated by Fermi Research Alliance, LLC, under contract De-AC02-07CH11359 with the US Department of Energy. It was also supported by the ComPASS project, funded via the Scientific Discovery through Advanced Computing program in the DoE Office of High Energy Physics. We also used resources from the Argonne Leadership Computing Facility at Argonne National Laboratory, which is supported by the Office of Science of the DoE under contract DE-AC02-06CH11357. NR 14 TC 0 Z9 0 U1 0 U2 2 PU IEEE COMPUTER SOC PI LOS ALAMITOS PA 10662 LOS VAQUEROS CIRCLE, PO BOX 3014, LOS ALAMITOS, CA 90720-1314 USA SN 1521-9615 EI 1558-366X J9 COMPUT SCI ENG JI Comput. Sci. Eng. PD NOV-DEC PY 2014 VL 16 IS 6 BP 32 EP 41 PG 10 WC Computer Science, Interdisciplinary Applications SC Computer Science GA AT3OM UT WOS:000344843900005 ER PT J AU Langer, SH Bhatele, A Still, CH AF Langer, Steven H. Bhatele, Abhinav Still, Charles H. TI pF3D Simulations of Laser-Plasma Interactions in National Ignition Facility Experiments SO COMPUTING IN SCIENCE & ENGINEERING LA English DT Article AB The laser-plasma interaction code pF3D is used to simulate laser-plasma interactions in National Ignition Facility experiments. The optimizations performed on pF3D enable scaling to a million or more processes. Key scalability issue include message passing, disk I/O, and code steering. C1 [Langer, Steven H.; Still, Charles H.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Bhatele, Abhinav] Lawrence Livermore Natl Lab, Ctr Appl Sci Comp, Livermore, CA USA. RP Langer, SH (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. EM langer1@llnl.gov; bhatele@llnl.gov; still1@llnl.gov FU US Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344 (LLNL-JRNL-648736)]; Office of Science of the US Department of Energy [DE-AC02-06CH11357] FX This work was performed under the auspices of the US Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344 (LLNL-JRNL-648736). We thank John Moody of LLNL for the Near Backscatter Imaging (NBI) data. This research used resources of the Argonne Leadership Computing Facility at Argonne National Laboratory, which is supported by the Office of Science of the US Department of Energy under contract DE-AC02-06CH11357. NR 8 TC 1 Z9 1 U1 1 U2 10 PU IEEE COMPUTER SOC PI LOS ALAMITOS PA 10662 LOS VAQUEROS CIRCLE, PO BOX 3014, LOS ALAMITOS, CA 90720-1314 USA SN 1521-9615 EI 1558-366X J9 COMPUT SCI ENG JI Comput. Sci. Eng. PD NOV-DEC PY 2014 VL 16 IS 6 BP 42 EP 50 PG 9 WC Computer Science, Interdisciplinary Applications SC Computer Science GA AT3OM UT WOS:000344843900006 ER PT J AU Yakovenko, AA Wei, ZW Wriedt, M Li, JR Halder, GJ Zhou, HC AF Yakovenko, Andrey A. Wei, Zhangwen Wriedt, Mario Li, Jian-Rong Halder, Gregory J. Zhou, Hong-Cai TI Study of Guest Molecules in Metal Organic Frameworks by Powder X-ray Diffraction: Analysis of Difference Envelope Density SO CRYSTAL GROWTH & DESIGN LA English DT Article ID GAS-ADSORPTION SITES; NEUTRON-DIFFRACTION; CRYSTAL-STRUCTURES; METHANE STORAGE; CARBON-DIOXIDE; REFINEMENT; ACTIVATION; CHEMISTRY; SORPTION; CAPTURE AB The structural characterization of metalorganic frameworks (MOFs) by powder X-ray diffraction can be challenging. Even more difficult are studies of guest solvent or gas molecules inside the MOF pores. Hence, recently we successfully designed several new approaches for structural investigations of porous MOFs. These methods use structure envelopes, which can be easily generated from the structure factors of a few (110) of the most intense low index reflections. However, the most interesting results have been found by using difference envelope density (DED) analysis. DED can be produced by taking the difference between observed and calculated structure envelope densities. The generation and analysis of DED maps are straightforward but allow studying guest molecules in the pores of MOFs by using routine powder X-ray diffraction data. Examples of DED used for studies of solvent molecule location, porosity activation, and gas loading are presented herein. We show that DED analysis is an important technique in the study of hostguest properties in MOFs by providing position, shape, and approximate occupancy of molecules in the MOF pores. C1 [Yakovenko, Andrey A.; Wei, Zhangwen; Wriedt, Mario; Zhou, Hong-Cai] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA. [Yakovenko, Andrey A.; Halder, Gregory J.] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, Argonne, IL 60439 USA. [Wriedt, Mario] Clarkson Univ, Dept Chem & Biomol Sci, Potsdam, NY 13699 USA. [Li, Jian-Rong] Beijing Univ Technol, Dept Chem & Chem Engn, Beijing 100124, Peoples R China. RP Yakovenko, AA (reprint author), Argonne Natl Lab, Adv Photon Source, Xray Sci Div, ANL 9700 South Cass Ave, Argonne, IL 60439 USA. EM ayakovenko@aps.anl.gov; zhou@chem.tamu.edu RI Zhou, Hong-Cai/A-3009-2011; Halder, Gregory/C-5357-2013; Wei, Zhangwen/D-2536-2016; Wriedt, Mario/B-5645-2011; Li, Jian-Rong (Jeff)/G-2781-2010 OI Zhou, Hong-Cai/0000-0002-9029-3788; Wei, Zhangwen/0000-0002-8378-2479; FU U.S. Department of Energy [DE-AR0000249]; Office of Navel Research [N000141310753]; Welch Foundation [A-1725]; U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]; Clarkson University; Postdoc Programme of the German Academic Exchange Service (DAAD) FX This work was supported by the U.S. Department of Energy (DE-AR0000249), the Office of Navel Research (N000141310753), and the Welch Foundation (A-1725). Work done at the Advanced Photon Source at Argonne National Laboratory was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. M.W. acknowledges support from Clarkson University (start-up fund) and the Postdoc Programme of the German Academic Exchange Service (DAAD). A detailed description is given in the Supporting Information. NR 64 TC 10 Z9 10 U1 6 U2 50 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1528-7483 EI 1528-7505 J9 CRYST GROWTH DES JI Cryst. Growth Des. PD NOV PY 2014 VL 14 IS 11 BP 5397 EP 5407 DI 10.1021/cg500525g PG 11 WC Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary SC Chemistry; Crystallography; Materials Science GA AS8RW UT WOS:000344516800011 ER PT J AU Sand, KK Pedersen, CS Sjoberg, S Nielsen, JW Makovicky, E Stipp, SLS AF Sand, K. K. Pedersen, C. S. Sjoberg, S. Nielsen, J. W. Makovicky, E. Stipp, S. L. S. TI Biomineralization: Long-Term Effectiveness of Polysaccharides on the Growth and Dissolution of Calcite SO CRYSTAL GROWTH & DESIGN LA English DT Article ID AQUEOUS-SOLUTION INTERFACE; HUXLEYI LOHMANN KAMPTNER; EMILIANIA-HUXLEYI; ACIDIC POLYSACCHARIDE; SURFACE COMPLEXATION; BIOLOGICAL-CONTROL; CHARGE; MODEL; CRYSTALLIZATION; COCCOLITHS AB Our results demonstrate that in addition to being used for controlling morphology during calcite growth, polysaccharide (PS) that has been designed for biomineralization is also extremely robust, influencing calcite reactions even after millions of years. We investigated calcite (CaCO3) behavior in solutions with very small concentrations of PS that was produced similar to 70 Ma ago by coccolithophorids. We used atomic force microscopy (AFM) and the constant composition method to monitor calcite growth in the presence of this ancient PS. The ancient PS is still very active and has a high affinity for calcite step edges. Adsorption, even at extremely low concentrations (0.5 mu g/mL), results in decreased growth rate and dramatic morphology changes during growth and dissolution. The experimental results are complemented with surface complexation modeling for adsorption of components of polysaccharide from a modern coccolithophorid, Emiliania huxleyi. We generated surface complexation constants for the branch components: malonate: 14.25 +/- 0.17, succinate: 11.91 +/- 0.06, tricarballylate: 14.86 +/- 0.04, and citrate: 15.25 +/- 0.04. The implication is that complex PS could hold promise for smart material engineering and for preventing scaling. C1 [Sand, K. K.; Pedersen, C. S.; Nielsen, J. W.; Stipp, S. L. S.] Univ Copenhagen, Dept Chem, Nanosci Ctr, DK-2100 Copenhagen, Denmark. [Makovicky, E.] Univ Copenhagen, Dept Geog & Geol, DK-2100 Copenhagen, Denmark. [Sjoberg, S.] Umea Univ, Dept Chem, Umea, Sweden. [Sand, K. K.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA. RP Sand, KK (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Mol Foundry, 1 Cyclotron Rd,MS 67-5111, Berkeley, CA 94720 USA. EM kks@nano.ku.dk RI Sand, Karina/P-1008-2014 OI Sand, Karina/0000-0002-0720-7229 FU Nano-Chalk Venture - Danish National Advanced Technology Foundation (HTF); Maersk Oil and Gas A/S; University of Copenhagen; Engineering and Physical Sciences Research Council [EP/I001514/1]; Materials Interface with Biology (MIB) consortium FX We sincerely thank Keld West, Tue Hassenkam, Leonid Lakshtanov, and members of the Nano-GeoScience group for help and discussion. We are also grateful to Finn Engstrom, Karen Henriksen, and Maersk Oil and Gas A/S for choosing and providing the chalk samples. The project was funded by the Nano-Chalk Venture, supported by the Danish National Advanced Technology Foundation (HTF), Maersk Oil and Gas A/S and the University of Copenhagen and the Engineering and Physical Sciences Research Council [Grant Number EP/I001514/1]. This programme grant funds the Materials Interface with Biology (MIB) consortium. NR 42 TC 7 Z9 7 U1 6 U2 46 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1528-7483 EI 1528-7505 J9 CRYST GROWTH DES JI Cryst. Growth Des. PD NOV PY 2014 VL 14 IS 11 BP 5486 EP 5494 DI 10.1021/cg5006743 PG 9 WC Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary SC Chemistry; Crystallography; Materials Science GA AS8RW UT WOS:000344516800020 ER PT J AU Singh, MR Nere, N Tung, HH Mukherjee, S Bordawekar, S Ramkrishna, D AF Singh, Meenesh R. Nere, Nandkishor Tung, Hsien-Hsin Mukherjee, Samrat Bordawekar, Shailendra Ramkrishna, Doraiswami TI Measurement of Polar Plots of Crystal Dissolution Rates Using Hot-Stage Microscopy. Some Further Insights into Dissolution Morphologies SO CRYSTAL GROWTH & DESIGN LA English DT Article ID SLOWNESS SURFACES; KINEMATIC WAVES; CUBIC-CRYSTALS; GROWTH; EVOLUTION; SPHERES; FORMS; SHAPE AB Polar plots are the representations of anisotropic surface properties such as surface energies and growth rates of crystalline materials. The steady-state morphologies of growing crystals are usually obtained from Wulff constructions on the polar plots of growth rates, whereas the morphologies of dissolving crystals are known to have no steady states. Here we show that the dissolving crystal can attain steady-state morphologies under certain conditions. The Wulff construction on the polar plots of dissolution time (or slowness) can be used to identify such steady-state morphologies. It is shown that the dissolving crystal can attain faceted morphology composed of fast dissolving faces. The evolution of dissolving crystals toward faceted morphology involves disappearance of slow-dissolving faces, which also causes vanishing of curvatures from the crystal surface. This article presents a method to experimentally determine polar plots from the dynamic images of crystals obtained from hot-stage microscopy. The method relies on the solution of the characteristics for crystal dissolution. The methodology is demonstrated to obtain polar plots of succinic acid at different subsaturations. C1 [Singh, Meenesh R.; Tung, Hsien-Hsin; Ramkrishna, Doraiswami] Purdue Univ, Sch Chem Engn, W Lafayette, IN 47907 USA. [Nere, Nandkishor; Tung, Hsien-Hsin; Mukherjee, Samrat; Bordawekar, Shailendra] AbbVie Inc, GPRD Proc R&D, Proc Engn & Sci, N Chicago, IL USA. [Singh, Meenesh R.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Joint Ctr Artificial Photosynth, Berkeley, CA 94720 USA. RP Ramkrishna, D (reprint author), Purdue Univ, Sch Chem Engn, W Lafayette, IN 47907 USA. EM ramkrish@purdue.edu OI Singh, Meenesh/0000-0002-3638-8866 FU GPRD-Process Engineering department of AbbVie Inc., North Chicago; McDonnell Douglas Fellowship FX The authors (M.R.S. and D.R.) gratefully acknowledge the funding support from GPRD-Process Engineering department of AbbVie Inc., North Chicago. M.R.S also acknowledges McDonnell Douglas Fellowship administered through Purdue College of Engineering to support this research. NR 30 TC 1 Z9 1 U1 1 U2 10 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1528-7483 EI 1528-7505 J9 CRYST GROWTH DES JI Cryst. Growth Des. PD NOV PY 2014 VL 14 IS 11 BP 5647 EP 5661 DI 10.1021/cg500939t PG 15 WC Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary SC Chemistry; Crystallography; Materials Science GA AS8RW UT WOS:000344516800040 ER PT J AU Li, H Malliakas, CD Liu, ZF Peters, JA Sebastian, M Zhao, LD Chung, DY Wessels, BW Kanatzidis, MG AF Li, Hao Malliakas, Christos D. Liu, Zhifu Peters, John A. Sebastian, Maria Zhao, Lidong Chung, Duck Young Wessels, Bruce W. Kanatzidis, Mercouri G. TI Investigation of Semi-Insulating Cs2Hg6S7 and Cs2Hg6-xCdxS7 Alloy for Hard Radiation Detection SO CRYSTAL GROWTH & DESIGN LA English DT Article ID GAMMA-RAY DETECTION; DIMENSIONAL REDUCTION; CRYSTAL-GROWTH; X-RAY; CDTE; SE; TE; SEMICONDUCTOR; CHALCOGENIDES; CD0.9ZN0.1TE AB A new method is described to synthesize the semiconductor Cs2Hg6S7 and its alloy with Cd. Using the as-synthesized material, large single crystals have been grown by the Bridgman method under an improved set of crystal growth parameters. In addition, Cd alloying in the form of Cs(2)Hg(6)xCd(x)S(7) (x = 0.25, 0.5, 0.75, etc.) as well as doping with In, Cl was investigated and the influence on the electronic properties was studied. Cd alloying increases the band gap of Cs2Hg6S7 from 1.63 to 1.84 eV. Doping with In and Cl however creates electron carriers and changes p-type samples of Cs2Hg6S7 into n type. A 30-fold increase in the resistivity of the single crystals from 2 X 10(6) to 0.65 X 10(8) Omega cm has been achieved. The carrier mobility-lifetime product of the Cs(2)Hg6S7 crystals has been increased to 1.7 X 10(-3) cm2/V for electrons (mu t)(e) and 2.4 X 10(-3) cm2/V for holes (mu t)(h) (HgCl2 doped). The measured (mu t)e value is comparable to the commercial CdZnTe crystal while the (mu t)h is 10 times higher. Detection of Ag X-ray radiation is demonstrated using the as-grown Cs2Hg6S7 crystals. C1 [Li, Hao; Malliakas, Christos D.; Sebastian, Maria; Zhao, Lidong; Kanatzidis, Mercouri G.] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA. [Chung, Duck Young; Kanatzidis, Mercouri G.] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA. [Liu, Zhifu; Peters, John A.; Sebastian, Maria; Wessels, Bruce W.] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA. [Wessels, Bruce W.] Northwestern Univ, Dept Elect Engn & Comp Sci, Evanston, IL 60208 USA. RP Kanatzidis, MG (reprint author), Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA. EM m-kanatzidis@northwestern.edu RI Li, Hao/C-8685-2015; Wessels, Bruce/B-7541-2009 FU Defense Threat Reduction Agency [HDTRA1 09-1-0044]; office of Nonproliferation and Verification Research and Development under the National Nuclear Security Administration of the U.S. Department of Energy [DE-AC02-06CH11357] FX This research was supported by the Defense Threat Reduction Agency through Grant HDTRA1 09-1-0044. At Argonne National Laboratory (by D.Y.C.), work was supported by the office of Nonproliferation and Verification Research and Development under the National Nuclear Security Administration of the U.S. Department of Energy under Contract DE-AC02-06CH11357. NR 42 TC 5 Z9 5 U1 1 U2 11 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1528-7483 EI 1528-7505 J9 CRYST GROWTH DES JI Cryst. Growth Des. PD NOV PY 2014 VL 14 IS 11 BP 5949 EP 5956 DI 10.1021/cg501151r PG 8 WC Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary SC Chemistry; Crystallography; Materials Science GA AS8RW UT WOS:000344516800073 ER PT J AU Bracco, JN Stack, AG Higgins, SR AF Bracco, Jacquelyn N. Stack, Andrew G. Higgins, Steven R. TI Magnesite Step Growth Rates as a Function of the Aqueous Magnesium:Carbonate Ratio SO CRYSTAL GROWTH & DESIGN LA English DT Article ID ATOMIC-FORCE MICROSCOPY; CALCITE GROWTH; DISSOLUTION KINETICS; SOLUTION STOICHIOMETRY; DEGREES-C; CRYSTAL; SURFACE; WATER; MECHANISM; DYNAMICS AB Step velocities of monolayer-height steps on the (101 4) magnesite surface have been measured as functions of the aqueous magnesium:carbonate ratio and saturation index (SI) using a hydrothermal atomic force microscope. At SI = 1.9 and 80-90 degrees C, step velocities were found to be invariant with changes in the magnesium:carbonate ratio, an observation in contrast with standard models for growth and dissolution of ionically bonded, multicomponent crystals. However, at high saturation indices (SI = 2.15), step velocities displayed a ratio dependence, maximized at magnesium:carbonate ratios slightly greater than 1:1. Traditional affinity-based models could not describe growth rates at the higher saturation index. Step velocities also could not be modeled solely through nucleation of kink sites, in contrast to other minerals whose bonding between constituent ions is also dominantly ionic in nature, such as calcite and barite. Instead, they could be described only by a model that incorporates both kink nucleation and propagation. On the basis of observed step morphological changes at these higher saturation indices, the step velocity maximum at SI = 2.15 is likely due to the rate of attachment to propagating kink sites overcoming the rate of detachment from kink sites as the latter becomes less significant under far from equilibrium conditions. C1 [Bracco, Jacquelyn N.; Higgins, Steven R.] Wright State Univ, Dept Chem, Dayton, OH 45435 USA. [Stack, Andrew G.] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA. RP Higgins, SR (reprint author), Wright State Univ, Dept Chem, 3640 Colonel Glenn Highway, Dayton, OH 45435 USA. EM steven.higgins@wright.edu OI Bracco, Jacquelyn/0000-0002-7096-8856 FU U.S. Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division FX This work was supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division. We are grateful to Kevin G. Knauss and Garrett VanNess for their technical assistance. NR 48 TC 8 Z9 8 U1 1 U2 26 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1528-7483 EI 1528-7505 J9 CRYST GROWTH DES JI Cryst. Growth Des. PD NOV PY 2014 VL 14 IS 11 BP 6033 EP 6040 DI 10.1021/cg501203g PG 8 WC Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary SC Chemistry; Crystallography; Materials Science GA AS8RW UT WOS:000344516800083 ER PT J AU Manner, VW Tappan, BC Scott, BL Preston, DN Brown, GW AF Manner, Virginia W. Tappan, Bryce C. Scott, Brian L. Preston, Daniel N. Brown, Geoffrey W. TI Crystal Structure, Packing Analysis, and Structural-Sensitivity Correlations of Erythritol Tetranitrate SO CRYSTAL GROWTH & DESIGN LA English DT Article ID PENTAERYTHRITOL TETRANITRATE; ENERGETIC MATERIALS; DECOMPOSITION; EXPLOSIVES; ESTERS AB The explosive erythritol tetranitrate (ETN) has been known since 1849 and has applications as a vasodilator; however, little is known about its structure and bonding. Here we present the X-ray crystal structure of erythritol tetranitrate (ETN), along with characterization by nuclear magnetic resonance (NMR), infrared spectroscopy (IR), elemental analysis, and X-ray diffraction (XRD). Crystal packing and morphology are discussed in relation to explosive handling sensitivity (impact, spark, and friction testing). We compare the structure and property relationship to a closely related common nitrate ester, pentaerythritol tetranitrate (PETN). C1 [Manner, Virginia W.; Tappan, Bryce C.; Scott, Brian L.; Preston, Daniel N.; Brown, Geoffrey W.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. RP Manner, VW (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. EM vwmanner@lanl.gov; btappan@lanl.gov RI Scott, Brian/D-8995-2017 OI Scott, Brian/0000-0003-0468-5396 FU U.S. Department of Energy [DE-AC52-06NA25396]; Campaign 2 (LANL) FX Los Alamos National Laboratory is operated by LANS, LLC, for the U.S. Department of Energy under contract DE-AC52-06NA25396. The authors acknowledge Campaign 2 (LANL) for support of this work, Stephanie Hagelberg for elemental analysis, Mary Sandstrom for DSC measurements, Kelly L. Parker for the Table of Contents graphic design, G. Kenneth Windier for help with 14N NMR measurements, and Kevin Fleming (Trinity Scientific) for helpful discussions. NR 25 TC 11 Z9 11 U1 1 U2 20 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1528-7483 EI 1528-7505 J9 CRYST GROWTH DES JI Cryst. Growth Des. PD NOV PY 2014 VL 14 IS 11 BP 6154 EP 6160 DI 10.1021/cg501362b PG 7 WC Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary SC Chemistry; Crystallography; Materials Science GA AS8RW UT WOS:000344516800097 ER PT J AU Miara, A Tarr, C Spellman, R Vorosmarty, CJ Macknick, JE AF Miara, Ariel Tarr, Craig Spellman, Rachel Voeroesmarty, Charles J. Macknick, Jordan E. TI The power of efficiency: Optimizing environmental and social benefits through demand-side-management SO ENERGY LA English DT Article DE Demand-side-management; Energy planning; Electricity supply and demand; Environmental policy; Carbon dioxide mitigation; External costs ID AIR-POLLUTION; UNITED-STATES; ENERGY; TECHNOLOGIES; DAMAGES; IMPACTS; SYSTEM; COAL AB Substantial social and environmental benefits can be achieved through regional DSM (demand-side management) strategies. Here, three DSM scenarios that vary in capital investment costs of technology retrofits were tested for the contemporary Northeastern US. These resulted in an 8.3-16.5% decrease in summertime regional electricity consumption. The lower power consumption achieved through DSM was analyzed under an additional five SPR (strategic power reduction) scenarios to explore how the reduced electricity demand could be optimized through different modalities of thermoelectric power production that lower human health risks, thermal water pollution, carbon emissions or system costs (operation and maintenance) of power plants. SPR scenarios show potential to lower health risks to nearly two million people with corresponding avoided external costs of $11 billion per year, lower carbon emissions (31%, maximum) and thermal water pollution (37%, maximum). By internalizing external costs, some unfavorable investments (NPV (net present value) < 0) turned into favorable ones (NPV > 0). Results show that integrating tradeoffs of DSM beyond the building scale unveil considerable social and environmental benefits that are ignored in typical financial valuations. This, in turn, can provide more holistic assessments and identify actionable policy alternatives of value to energy and environmental planners that aim to achieve sustainable development. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Miara, Ariel; Voeroesmarty, Charles J.] CUNY, Environm Crossroads Initiat, New York, NY 10031 USA. [Tarr, Craig; Spellman, Rachel] CUNY, New York, NY 10031 USA. [Voeroesmarty, Charles J.] CUNY, Dept Civil Engn, New York, NY 10031 USA. [Macknick, Jordan E.] Natl Renewable Energy Lab, Golden, CO 80401 USA. RP Miara, A (reprint author), CUNY, Environm Crossroads Initiat, New York, NY 10031 USA. EM amiara00@citymail.cuny.edu FU National Science Foundation [1049181]; Department of Education - Earth Science and Environmental Sustainability (ESES) Graduate Initiative [P031M105] FX This work is supported by the National Science Foundation Grant #1049181 and The Department of Education - Earth Science and Environmental Sustainability (ESES) Graduate Initiative Grant #P031M105. We thank and are grateful to: Prof. Anthony Dvarskas (CCNY), Prof. Sean Ahearn (CUNY), Rebecca Stubbs (NREL), and anonymous reviewers for their suggestions. NR 73 TC 8 Z9 8 U1 5 U2 30 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0360-5442 EI 1873-6785 J9 ENERGY JI Energy PD NOV 1 PY 2014 VL 76 BP 502 EP 512 DI 10.1016/j.energy.2014.08.047 PG 11 WC Thermodynamics; Energy & Fuels SC Thermodynamics; Energy & Fuels GA AS7OH UT WOS:000344444600050 ER PT J AU Gernaat, DEHJ Van Vuuren, DP Van Vliet, J Sullivan, P Arent, DJ AF Gernaat, David E. H. J. Van Vuuren, Detlef P. Van Vliet, Jasper Sullivan, Patrick Arent, Douglas J. TI Global long-term cost dynamics of offshore wind electricity generation SO ENERGY LA English DT Article DE Offshore wind; Renewables; Modelling; Integrated assessment model AB Using the IMAGE/TIMER (The Targets IMage Energy Regional) long-term integrated assessment model, this paper explores the regional and global potential of offshore wind to contribute to global electricity production. We develop long-term cost supply curve for offshore wind, a representation of the potential suitable for inclusion in global integrated assessment models. For this, we combine available data on resource potential and cost estimates to estimate regional and global characteristics of offshore wind electricity generation. We find that for 2050, a baseline scenario would include about 4% of the total electricity production based on offshore wind. The findings also show that in most regions, technical potential is not a limiting factor. In some regions, that have a seriously constrained resource base for onshore wind, offshore wind could provide a key source of renewable energy, including South-East Asia, Indonesia and Brazil. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Gernaat, David E. H. J.; Van Vuuren, Detlef P.] Univ Utrecht, Copernicus Inst Sustainable Dev, NL-3584 CS Utrecht, Netherlands. [Van Vuuren, Detlef P.; Van Vliet, Jasper] PBL Netherlands Environm Assessment Agcy, NL-3720 BA Bilthoven, Netherlands. [Sullivan, Patrick; Arent, Douglas J.] Natl Renewable Energy Lab, Golden, CO 80401 USA. RP Gernaat, DEHJ (reprint author), Univ Utrecht, Copernicus Inst Sustainable Dev, Heidelberglaan 2, NL-3584 CS Utrecht, Netherlands. EM d.e.h.j.gernaat@uu.nl; detlef.vanvuuren@pbl.nl; jasper.vanvliet@pbl.nl; patrick.Sullivan@nrel.gov; doug.Arent@nrel.gov RI van Vuuren, Detlef/A-4764-2009; OI van Vuuren, Detlef/0000-0003-0398-2831; Gernaat, David/0000-0003-4994-1453 NR 40 TC 7 Z9 7 U1 0 U2 6 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0360-5442 EI 1873-6785 J9 ENERGY JI Energy PD NOV 1 PY 2014 VL 76 BP 663 EP 672 DI 10.1016/j.energy.2014.08.062 PG 10 WC Thermodynamics; Energy & Fuels SC Thermodynamics; Energy & Fuels GA AS7OH UT WOS:000344444600065 ER PT J AU Zheng, YA Hu, ZG Wang, JH Wen, Q AF Zheng, Yanan Hu, Zhaoguang Wang, Jianhui Wen, Quan TI IRSP (integrated resource strategic planning) with interconnected smart grids in integrating renewable energy and implementing DSM (demand side management) in China SO ENERGY LA English DT Article DE Low carbon electricity; Integrated resource strategic planning; Interconnected smart grids; Demand side management; Renewable energy; China ID POWER AB The China's electricity consumption was 4966 TWh in 2012, which is the world top electricity consumer. The low carbon electricity is one of the key issues of its sustainable development. IRSP (integrated resource strategic planning) is a useful tool to implement DSM (demand side management) and power planning on the supply side. However, the role of interconnected smart grids with fast growing cross-region transmission is not considered in the IRSP. Therefore, the paper proposes the model of IRSP with interconnected smart grids to integrate more renewable power generation to the grids and implement more DSM projects, which is called as IRSP-sgs (IRSP smart grids) model. Two scenarios are projected to study the impact of cross-region transmission on low carbon electricity by using the IRSP-sgs model until 2025 in China. Results show that the scenario with enhanced cross-region transmission helps to reduce electricity generation by 784.38 TWh and reduce CO2 emission by 999.57 million tons during 2013-2025, since the multi-regional power operation can integrate more than 488.30 TWh renewable generation into the grids and implement more DSM projects to substitute generation. In addition, it also provides tremendous opportunities to improve the stable operation of the power system. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Zheng, Yanan; Hu, Zhaoguang; Wen, Quan] State Grid Energy Res Inst, Beijing 102200, Peoples R China. [Wang, Jianhui] Argonne Natl Lab, Chicago, IL USA. RP Zheng, YA (reprint author), State Grid Energy Res Inst, Beijing 102200, Peoples R China. EM zhengyn@ncepu.edu.cn; huzhaoguang@sgeri.sgcc.com.cn; jianhui.wang@anl.gov; wenquan@sgeri.sgcc.com.cn NR 33 TC 9 Z9 10 U1 2 U2 15 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0360-5442 EI 1873-6785 J9 ENERGY JI Energy PD NOV 1 PY 2014 VL 76 BP 863 EP 874 DI 10.1016/j.energy.2014.08.087 PG 12 WC Thermodynamics; Energy & Fuels SC Thermodynamics; Energy & Fuels GA AS7OH UT WOS:000344444600085 ER PT J AU Chakraborty, P Biner, SB AF Chakraborty, Pritam Biner, S. Bulent TI A unified cohesive zone approach to model the ductile to brittle transition of fracture toughness in reactor pressure vessel steels SO ENGINEERING FRACTURE MECHANICS LA English DT Article DE Ductile brittle transition; Fracture; Cohesive zone model; Reactor pressure vessel; Steel ID CHARPY IMPACT TEST; CUP-CONE FRACTURE; VOID NUCLEATION; CRACK-GROWTH; SIMULATION; DAMAGE; DECOHESION; INTERFACE; SOLIDS; CURVE AB In this study, a unified cohesive zone model is proposed to predict the ductile to brittle transition of fracture toughness in reactor pressure vessel steels. A general procedure is described to obtain the temperature and failure probability dependent cohesive zone model parameters. In order to establish the full master-curve, the procedure requires calibration at two different temperatures with one at the upper shelf for ductile fracture and one near the lower shelf for cleavage failure. In the present study, these calibrations are performed using the experimental fracture toughness values and the flow curves. Subsequently, fracture simulations are performed on one-inch thick compact tension and 3-point bend specimens at different temperatures and the resulting fracture toughness values are compared with experiments. A satisfactory agreement is observed which indicates the viability of such a unified modeling approach. Published by Elsevier Ltd. C1 [Chakraborty, Pritam; Biner, S. Bulent] Idaho Natl Lab, Fuel Modeling & Simulat Dept, Idaho Falls, ID 83402 USA. RP Chakraborty, P (reprint author), Idaho Natl Lab, Fuel Modeling & Simulat Dept, Idaho Falls, ID 83402 USA. EM pritam.chakraborty@inl.gov FU Light Water Reactor Sustainability Program at Idaho National Laboratory FX This work was funded through Light Water Reactor Sustainability Program at Idaho National Laboratory. NR 41 TC 2 Z9 2 U1 4 U2 13 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0013-7944 EI 1873-7315 J9 ENG FRACT MECH JI Eng. Fract. Mech. PD NOV PY 2014 VL 131 BP 194 EP 209 DI 10.1016/j.engfracmech.2014.07.029 PG 16 WC Mechanics SC Mechanics GA AT5MO UT WOS:000344987300012 ER PT J AU Vinikoor-Imler, LC Owens, EO Nichols, JL Ross, M Brown, JS Sacks, JD AF Vinikoor-Imler, Lisa C. Owens, Elizabeth O. Nichols, Jennifer L. Ross, Mary Brown, James S. Sacks, Jason D. TI Evaluating Potential Response-Modifying Factors for Associations between Ozone and Health Outcomes: A Weight-of-Evidence Approach SO ENVIRONMENTAL HEALTH PERSPECTIVES LA English DT Review ID CASE-CROSSOVER ANALYSIS; INDUCED AIRWAY HYPERRESPONSIVENESS; INDUCED PULMONARY INFLAMMATION; EMERGENCY-DEPARTMENT VISITS; INDUCED LUNG INFLAMMATION; NITRIC-OXIDE SYNTHASE; TOLL-LIKE RECEPTOR-4; ASTHMATIC SUBJECTS; MEXICO-CITY; ANTIOXIDANT SUPPLEMENTATION AB Background: Epidemiologic and experimental studies have reported a variety of health effects in response to ozone (O-3) exposure, and some have indicated that certain populations may be at increased or decreased risk of O-3-related health effects. Objectives: We sought to identify potential response-modifying factors to determine whether specific groups of the population or life stages are at increased or decreased risk of O-3-related health effects using a weight-of-evidence approach. Methods: Epidemiologic, experimental, and exposure science studies of potential factors that may modify the relationship between O3 and health effects were identified in U. S. Environmental Protection Agency's 2013 Integrated Science Assessment for Ozone and Related Photochemical Oxidants. Scientific evidence from studies that examined factors that may influence risk were integrated across disciplines to evaluate consistency, coherence, and biological plausibility of effects. The factors identified were then classified using a weight-of-evidence approach to conclude whether a specific factor modified the response of a population or life stage, resulting in an increased or decreased risk of O-3-related health effects. Discussion: We found "adequate" evidence that populations with certain genotypes, preexisting asthma, or reduced intake of certain nutrients, as well as different life stages or outdoor workers, are at increased risk of O-3-related health effects. In addition, we identified other factors (i.e., sex, socioeconomic status, and obesity) for which there was "suggestive" evidence that they may increase the risk of O-3-related health effects. Conclusions: Using a weight-of-evidence approach, we identified a diverse group of factors that should be considered when characterizing the overall risk of health effects associated with exposures to ambient O-3. C1 [Vinikoor-Imler, Lisa C.; Owens, Elizabeth O.; Ross, Mary; Brown, James S.; Sacks, Jason D.] US EPA, NCEA, Res Triangle Pk, NC 27711 USA. [Nichols, Jennifer L.] US EPA, NCEA, Oak Ridge Inst Sci & Educ, Off Res & Dev, Res Triangle Pk, NC 27711 USA. RP Vinikoor-Imler, LC (reprint author), 109 TW Alexander Dr,MD B243-01, Res Triangle Pk, NC 27711 USA. EM vinikoor-imler.lisa@epa.gov FU National Center of Environmental Assessment, Office of Research and Development, U.S. EPA FX This project was supported in part by the appointment of J.L.N. to the Research Participation Program at the National Center of Environmental Assessment, Office of Research and Development, U.S. EPA, administered by the Oak Ridge Institute for Science and Education through an interagency agreement between the U.S. Department of Energy NR 141 TC 8 Z9 8 U1 2 U2 22 PU US DEPT HEALTH HUMAN SCIENCES PUBLIC HEALTH SCIENCE PI RES TRIANGLE PK PA NATL INST HEALTH, NATL INST ENVIRONMENTAL HEALTH SCIENCES, PO BOX 12233, RES TRIANGLE PK, NC 27709-2233 USA SN 0091-6765 EI 1552-9924 J9 ENVIRON HEALTH PERSP JI Environ. Health Perspect. PD NOV PY 2014 VL 122 IS 11 BP 1166 EP 1176 DI 10.1289/ehp.1307541 PG 11 WC Environmental Sciences; Public, Environmental & Occupational Health; Toxicology SC Environmental Sciences & Ecology; Public, Environmental & Occupational Health; Toxicology GA AT2IZ UT WOS:000344759500017 PM 24927060 ER PT J AU Yang, YQ Zhang, ZC Luo, SZ Rao, LF AF Yang, Yanqiu Zhang, Zhicheng Luo, Shunzhong Rao, Linfeng TI Complexation of Np-V Ions with 1,10-Phenanthroline-2,9-dicarboxylic Acid: Spectrophotometric and Microcalorimetric Studies SO EUROPEAN JOURNAL OF INORGANIC CHEMISTRY LA English DT Article DE Actinides; Chelates; N,O ligands; Carboxylate ligands; Coordination modes ID DIPICOLINIC ACID; EQUILIBRIUM-CONSTANTS; EXTRACTION PROPERTIES; DIAMIDES; NEPTUNIUM(V); SELECTIVITY; LIGAND; URANIUM(VI); HYDROLYSIS; CHEMISTRY AB The complexation of Np-V ions with a tetradentate ligand with oxygen and nitrogen donors, 1,10-phenanthroline-2,9-dicarboxylic acid (denoted as H2L), was studied in aqueous solutions by spectrophotometric and calorimetric methods. Np-V ions form a very strong 1:1 complex, NpO2L-, with the stability constant log beta = 11.73 +/- 0.02 in 0.1 M NaClO4 at 25 degrees C. It is a much stronger complex than those of Np-V ions with related ligands such as picolinic acid or dipicolinic acid, as the higher denticity of 1,10-phenanthroline-2,9-dicarboxylic acid results in a larger entropic effect on the complexation. It is expected that the amide derivatives of 1,10-phenanthroline-2,9-dicarboxylic acid would be excellent extractants in the separation of Np-V ions, which are problematic in actinide separation processes owing to their very low extractability by many extractants. C1 [Yang, Yanqiu; Luo, Shunzhong] China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621900, Sichuan, Peoples R China. [Yang, Yanqiu; Zhang, Zhicheng; Rao, Linfeng] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA. RP Luo, SZ (reprint author), China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621900, Sichuan, Peoples R China. EM luoshzh@caep.ac.cn; LRao@lbl.gov FU Office of Science, Office of Basic Energy Science of the U.S. Department of Energy (DOE) at Lawrence Berkeley National Laboratory [DE-AC02-05CH11231]; National Natural Science Foundation of China (NSFC) [91026022] FX The experimental work was supported by the Director, Office of Science, Office of Basic Energy Science of the U.S. Department of Energy (DOE) under contract No. DE-AC02-05CH11231 at Lawrence Berkeley National Laboratory. Y. Y. thanks the National Natural Science Foundation of China (NSFC) (grant number 91026022) for the support in the preparation of the manuscript. NR 36 TC 4 Z9 4 U1 3 U2 22 PU WILEY-V C H VERLAG GMBH PI WEINHEIM PA BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY SN 1434-1948 EI 1099-0682 J9 EUR J INORG CHEM JI Eur. J. Inorg. Chem. PD NOV PY 2014 IS 32 BP 5561 EP 5566 DI 10.1002/ejic.201402520 PG 6 WC Chemistry, Inorganic & Nuclear SC Chemistry GA AT2UL UT WOS:000344791900012 ER PT J AU Harvey, BM Rana, NA Wang, T Li, HL Haltiwanger, RS AF Harvey, Beth M. Rana, Nadia A. Wang, Tong Li, Huilin Haltiwanger, Robert S. TI The Molecular Mechanisms of Fringe Modification on Drosophila Notch: Examining the Structure and Function of Notch EGF Repeats SO GLYCOBIOLOGY LA English DT Meeting Abstract CT Joint Meeting of the Society-for-Glycobiology (SFG) and the Japanese-Society-of-Carbohydrate-Research (JSCR) CY NOV 16-19, 2014 CL Honolulu, HI SP Society For Glycobiology, Japanese Soc Carbohydrate Res C1 [Harvey, Beth M.; Rana, Nadia A.; Haltiwanger, Robert S.] SUNY Stony Brook, Dept Biochem & Cell Biol, Stony Brook, NY 11794 USA. [Wang, Tong; Li, Huilin] Brookhaven Natl Lab, Dept Biol, Upton, NY 11973 USA. NR 0 TC 0 Z9 0 U1 0 U2 0 PU OXFORD UNIV PRESS INC PI CARY PA JOURNALS DEPT, 2001 EVANS RD, CARY, NC 27513 USA SN 0959-6658 EI 1460-2423 J9 GLYCOBIOLOGY JI Glycobiology PD NOV PY 2014 VL 24 IS 11 MA 25 BP 1093 EP 1093 PG 1 WC Biochemistry & Molecular Biology SC Biochemistry & Molecular Biology GA AT1CI UT WOS:000344670300033 ER PT J AU Mohnen, D Biswal, AK Hao, ZY Engle, K Amos, R Tan, L Atmodjo, M Mohanty, SS Ryno, D Sykess, RW AF Mohnen, Debra Biswal, Ajaya K. Hao, Zhangying Engle, Kristen Amos, Robert Tan, Li Atmodjo, Melani Mohanty, Sushree S. Ryno, David Sykess, Robert W. TI Biosynthesis and Mutant Studies Indicate Roles for Pectin and Pectin-containing Proteoglycans in Plant Cell Wall Architectural Integrity and Plant Growth SO GLYCOBIOLOGY LA English DT Meeting Abstract CT Joint Meeting of the Society-for-Glycobiology (SFG) and the Japanese-Society-of-Carbohydrate-Research (JSCR) CY NOV 16-19, 2014 CL Honolulu, HI SP Society For Glycobiology, Japanese Soc Carbohydrate Res C1 [Mohnen, Debra; Biswal, Ajaya K.; Hao, Zhangying; Engle, Kristen; Amos, Robert; Tan, Li; Atmodjo, Melani; Mohanty, Sushree S.; Ryno, David; Sykess, Robert W.] Univ Georgia, Athens, GA 30602 USA. Natl Renewable Energy Lab, Golden, CO USA. Oakridge Natl Lab, Oakridge, TN USA. Noble Fdn Inc, Ardmore, OK USA. NR 0 TC 0 Z9 0 U1 1 U2 2 PU OXFORD UNIV PRESS INC PI CARY PA JOURNALS DEPT, 2001 EVANS RD, CARY, NC 27513 USA SN 0959-6658 EI 1460-2423 J9 GLYCOBIOLOGY JI Glycobiology PD NOV PY 2014 VL 24 IS 11 MA 43 BP 1100 EP 1101 PG 2 WC Biochemistry & Molecular Biology SC Biochemistry & Molecular Biology GA AT1CI UT WOS:000344670300051 ER PT J AU Ebert, B Rautengarten, C Schultink, A Pauly, M Herter, T Mortimer, J Moreno, I Orellana, A Heazlewood, J Scheller, H AF Ebert, Berit Rautengarten, Carsten Schultink, Alex Pauly, Markus Herter, Thomas Mortimer, Jenny Moreno, Ignacio Orellana, Ariel Heazlewood, Joshua Scheller, Henrik TI Identification of novel nucleotide sugar transporters in plants and animals SO GLYCOBIOLOGY LA English DT Meeting Abstract CT Joint Meeting of the Society-for-Glycobiology (SFG) and the Japanese-Society-of-Carbohydrate-Research (JSCR) CY NOV 16-19, 2014 CL Honolulu, HI SP Society For Glycobiology, Japanese Soc Carbohydrate Res C1 [Ebert, Berit; Rautengarten, Carsten; Herter, Thomas; Mortimer, Jenny; Heazlewood, Joshua; Scheller, Henrik] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. [Ebert, Berit] Univ Copenhagen, DK-1168 Copenhagen, Denmark. [Schultink, Alex; Pauly, Markus; Scheller, Henrik] Univ Calif Berkeley, Berkeley, CA 94720 USA. [Moreno, Ignacio; Orellana, Ariel] Univ Andras Bello, Santiago, Chile. RI Ebert, Berit/F-1856-2016; Pauly, Markus/B-5895-2008; Scheller, Henrik/A-8106-2008 OI Ebert, Berit/0000-0002-6914-5473; Pauly, Markus/0000-0002-3116-2198; Scheller, Henrik/0000-0002-6702-3560 NR 0 TC 0 Z9 0 U1 0 U2 5 PU OXFORD UNIV PRESS INC PI CARY PA JOURNALS DEPT, 2001 EVANS RD, CARY, NC 27513 USA SN 0959-6658 EI 1460-2423 J9 GLYCOBIOLOGY JI Glycobiology PD NOV PY 2014 VL 24 IS 11 MA 267 BP 1183 EP 1183 PG 1 WC Biochemistry & Molecular Biology SC Biochemistry & Molecular Biology GA AT1CI UT WOS:000344670300273 ER PT J AU Wang, ZY Chen, H Wang, JH Begovic, M AF Wang, Zhaoyu Chen, Hao Wang, Jianhui Begovic, Miroslav TI Inverter-Less Hybrid Voltage/Var Control for Distribution Circuits With Photovoltaic Generators SO IEEE TRANSACTIONS ON SMART GRID LA English DT Article DE Distributed generators; distribution systems; photovoltaic (PV) generation; reactive power control; voltage control ID DISTRIBUTION-SYSTEM; VOLT/VAR CONTROL; REACTIVE POWER; CAPACITORS; ULTC; COORDINATION; REDUCTION; DISPATCH; SVC AB This paper proposes a hybrid voltage/var control (VVC) architecture for distribution systems with a high PV penetration. The architecture consists of two control loops: coordinated normal control loop and uncoordinated transient cloud movement control loop. In the first loop, hourly dispatches are scheduled for on-load tap changer (OLTC), capacitor banks (CBs), and static var compensators (SVCs) based on forecasted load and PV power output so as to minimize power losses and voltage deviations. The second loop is triggered when large variations of PV power output caused by rapid cloud movement happen. All SVCs and CBs become self-controlled based on local voltage measurements with the single control objective to minimize voltage deviations. SVCs will operate firstly to flatten the voltage profile. If SVCs fail, CBs will switch to provide reactive power support. A time-adaptive delay is applied to each CB to avoid overcompensation. Case studies show the proposed method can optimize the system operation and is effective in voltage regulation with PV generators. C1 [Wang, Zhaoyu; Chen, Hao; Begovic, Miroslav] Georgia Inst Technol, Atlanta, GA 30332 USA. [Wang, Jianhui] Argonne Natl Lab, Lemont, IL 60439 USA. [Begovic, Miroslav] Georgia Inst Technol, Sch Elect Engn, Elect Energy Tech Interest Grp, Atlanta, GA 30332 USA. RP Wang, ZY (reprint author), Georgia Inst Technol, Atlanta, GA 30332 USA. EM zhaoyuwang@gatech.edu; hchen95@gatech.edu; jianhui.wang@anl.gov; miroslav@ece.gatech.edu FU Argonne, a U.S. Department of Energy Office of Science Laboratory [DE AC02-06CH11357] FX The submitted manuscript has been created by UChicago Argonne, LLC, Operator of Argonne National Laboratory ("Argonne"). Argonne, a U.S. Department of Energy Office of Science Laboratory, is operated under Contract DE AC02-06CH11357. The U.S. Government retains for itself, and others acting on its behalf, a paid-up nonexclusive, irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly and display publicly, by or on behalf of the Government. NR 37 TC 4 Z9 4 U1 0 U2 1 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 1949-3053 EI 1949-3061 J9 IEEE T SMART GRID JI IEEE Trans. Smart Grid PD NOV PY 2014 VL 5 IS 6 BP 2718 EP 2728 DI 10.1109/TSG.2014.2324569 PG 11 WC Engineering, Electrical & Electronic SC Engineering GA AS9CY UT WOS:000344542000007 ER PT J AU Wilkerson, KR Smith, JD Hemrick, JG AF Wilkerson, Kelley R. Smith, Jeffrey D. Hemrick, James G. TI Metastability in the MgAl2O4-Al2O3 System SO INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY LA English DT Article ID MAGNESIUM ALUMINATE SPINEL; SOLID-SOLUTIONS; PRECIPITATION; MGO-AL2O3 AB Aluminum oxide must take a spinel form (-Al2O3) at increased temperatures in order for extensive solid solution to form between MgAl2O4 and -Al2O3. The solvus line between MgAl2O4 and Al2O3 has been defined at 79.6 wt% Al2O3 at 1500 degrees C, 83.0 wt% Al2O3 at 1600 degrees C, and 86.5 wt% Al2O3 at 1700 degrees C. A metastable region has been defined at temperatures up to 1700 degrees C which could have significant implications for material processing and properties. Additionally, initial processing could have major implications on final chemistry. C1 [Wilkerson, Kelley R.; Smith, Jeffrey D.] Missouri Univ Sci & Technol, Rolla, MO 65409 USA. [Hemrick, James G.] Oak Ridge Natl Lab, Mech Properties & Mech Grp, Oak Ridge, TN 37831 USA. RP Wilkerson, KR (reprint author), Missouri Univ Sci & Technol, Rolla, MO 65409 USA. EM kelley.wilkerson@alliedmin.com FU Industrial Technologic Program, U.S. Department of Energy [CPS 14954] FX Financial support by the Industrial Technologic Program, U.S. Department of Energy, under award number CPS Agreement no. 14954. NR 25 TC 0 Z9 0 U1 5 U2 10 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1546-542X EI 1744-7402 J9 INT J APPL CERAM TEC JI Int. J. Appl. Ceram. Technol. PD NOV-DEC PY 2014 VL 11 IS 6 BP 1020 EP 1024 DI 10.1111/ijac.12294 PG 5 WC Materials Science, Ceramics SC Materials Science GA AS9YJ UT WOS:000344594000008 ER PT J AU Ansoborlo, E Menager, MT Abergel, RJ AF Ansoborlo, Eric Menager, Marie-Therese Abergel, Rebecca J. TI 11th International Conference on Health Effects of Incorporated Radionuclides INTRODUCTION TO THE SPECIAL ISSUE SO INTERNATIONAL JOURNAL OF RADIATION BIOLOGY LA English DT Editorial Material C1 [Ansoborlo, Eric] Commissariat Energie Atom & Energies Alternat, Radiochem & Proc Dept, Marcoule Ctr, Bagnols Sur Ceze, France. [Menager, Marie-Therese] Commissariat Energie Atom & Energies Alternat, Life Sci Direct, Fontenay Aux Roses, France. [Abergel, Rebecca J.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA. RP Abergel, RJ (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, One Cyclotron Rd,MS 70A-1150, Berkeley, CA 94720 USA. EM rjabergel@lbl.gov RI Eric, Ansoborlo/N-1809-2015 OI Eric, Ansoborlo/0000-0003-0523-3738 NR 23 TC 0 Z9 0 U1 1 U2 7 PU INFORMA HEALTHCARE PI LONDON PA TELEPHONE HOUSE, 69-77 PAUL STREET, LONDON EC2A 4LQ, ENGLAND SN 0955-3002 EI 1362-3095 J9 INT J RADIAT BIOL JI Int. J. Radiat. Biol. PD NOV PY 2014 VL 90 IS 11 SI SI BP 945 EP 947 DI 10.3109/09553002.2014.965603 PG 3 WC Biology; Nuclear Science & Technology; Radiology, Nuclear Medicine & Medical Imaging SC Life Sciences & Biomedicine - Other Topics; Nuclear Science & Technology; Radiology, Nuclear Medicine & Medical Imaging GA AS8GC UT WOS:000344486900001 PM 25363314 ER PT J AU Leggett, R Ansoborlo, E Bailey, M Gregoratto, D Paquet, F Taylor, D AF Leggett, Rich Ansoborlo, Eric Bailey, Michael Gregoratto, Demetrio Paquet, Francois Taylor, David TI Biokinetic data and models for occupational intake of lanthanoids SO INTERNATIONAL JOURNAL OF RADIATION BIOLOGY LA English DT Article DE Lanthanoids; lanthanides; radionuclides; biokinetics; models; workplace; exposure ID RARE-EARTH-ELEMENTS; STABILITY-CONSTANTS; METAL-COMPLEXES; AMINO-ACIDS; RADIOPROMETHIUM 147PM; SOLUBILITY PRODUCTS; CONTINENTAL-CRUST; TECHNICAL REPORT; SIDE-CHAINS; BEAGLE DOGS AB Purpose: This paper reviews data related to the behavior of the lanthanoid elements (lanthanum through lutetium, atomic numbers 57-71) in the human body and proposes biokinetic models for internally deposited radio-lanthanoids in workers. Materials and methods: Published data on the following topics are reviewed and analyzed: Physico-chemical properties of the lanthanoids as indicators of the potential behavior of these elements in body fluids; the concentrations of the stable lanthanoids in the environment and human body; and results of biokinetic studies of radio-lanthanoids in human subjects and laboratory animals. Respiratory and systemic biokinetic models and gastrointestinal absorption fractions are developed or selected in an effort to represent the typical behavior of lanthanoids in adult humans. Results and conclusions: Generic (element-independent) absorption rates from the respiratory and alimentary tracts to blood and systemic biokinetic models are proposed. The systemic models are largely generic but include some element-specific parameter values to reflect regular changes with ionic radius in certain aspects of the behavior of the lanthanoids, particularly fractional deposition in liver and bone and early removal in urine. C1 [Leggett, Rich] Oak Ridge Natl Lab, Div Environm Sci, Oak Ridge, TN 37831 USA. [Ansoborlo, Eric] French Atom Energy Commiss, Radiochem & Proc Dept, St Paul Les Durance, France. [Ansoborlo, Eric] Marcoule Nucl Site, Alternat Energies, Chusclan, France. [Bailey, Michael; Gregoratto, Demetrio] Publ Hlth England, Ctr Radiat Chem & Environm Hazards, Didcot, Oxon, England. [Paquet, Francois] Radioprotect & Nucl Safety Inst, Inst Radioprotect & Surete Nucl, Fontenay Aux Roses, France. [Taylor, David] Cardiff Univ, Dept Chem, Cardiff CF10 3AX, S Glam, Wales. RP Leggett, R (reprint author), Oak Ridge Natl Lab, Div Environm Sci, Bldg 5700, Oak Ridge, TN 37831 USA. EM rwl@ornl.gov RI Eric, Ansoborlo/N-1809-2015 OI Eric, Ansoborlo/0000-0003-0523-3738 FU Office of Radiation and Indoor Air, U. S. Environmental Protection Agency (EPA), under Interagency Agreement DOE [1824 S581-A1, DE-AC05-00OR22725]; UT-Battelle; U.S. Government [DE-AC05-00OR22725] FX The work of the first author was sponsored by the Office of Radiation and Indoor Air, U. S. Environmental Protection Agency (EPA), under Interagency Agreement DOE No. 1824 S581-A1, under contract No. DE-AC05-00OR22725 with UT-Battelle. The submitted manuscript has been authored in part by a contractor of the U.S. Government under contract DE-AC05-00OR22725. Accordingly, the U.S. Government retains a nonexclusive, royalty-free license to publish or reproduce the published form of this contribution, or allow others to do so, for U.S. Government purposes. NR 82 TC 4 Z9 4 U1 7 U2 14 PU INFORMA HEALTHCARE PI LONDON PA TELEPHONE HOUSE, 69-77 PAUL STREET, LONDON EC2A 4LQ, ENGLAND SN 0955-3002 EI 1362-3095 J9 INT J RADIAT BIOL JI Int. J. Radiat. Biol. PD NOV PY 2014 VL 90 IS 11 SI SI BP 996 EP 1010 DI 10.3109/09553002.2014.887868 PG 15 WC Biology; Nuclear Science & Technology; Radiology, Nuclear Medicine & Medical Imaging SC Life Sciences & Biomedicine - Other Topics; Nuclear Science & Technology; Radiology, Nuclear Medicine & Medical Imaging GA AS8GC UT WOS:000344486900008 PM 24475737 ER PT J AU An, DD Villalobos, JA Morales-Rivera, JA Rosen, CJ Bjornstad, KA Gauny, SS Choi, TA Sturzbecher-Hoehne, M Abergel, RJ AF An, Dahlia D. Villalobos, Jonathan A. Morales-Rivera, Joel A. Rosen, Chris J. Bjornstad, Kathleen A. Gauny, Stacey S. Choi, Taylor A. Sturzbecher-Hoehne, Manuel Abergel, Rebecca J. TI Pu-238 elimination profiles after delayed treatment with 3,4,3LI(1,2HOPO) in female and male Swiss-Webster mice SO INTERNATIONAL JOURNAL OF RADIATION BIOLOGY LA English DT Article DE Alpha emitters; plutonium; radiation protection; radionuclides; medical countermeasures; chelation therapy ID RADIONUCLIDE DECORPORATION AGENTS; HYDROXYPYRIDINONATE LIGANDS; MEDICAL COUNTERMEASURES; ACTINIDE DECORPORATION; CHELATING-AGENTS; IN-VIVO; PLUTONIUM; EFFICACY; CONTAMINATION; MOUSE AB Purpose : To characterize the dose-dependent and sex-related efficacy of the hydroxypyridinonate decorporation agent 3,4,3-LI(1,2-HOPO) at enhancing plutonium elimination when post-exposure treatment is delayed. Materials and methods : Six parenteral dose levels of 3,4,3-LI(1,2HOPO) from 1-300 mu mol/kg were evaluated for decorporating plutonium in female and male Swiss-Webster mice administered a soluble citrate complex of (WPu)-W-238 and treated 24 hours later. Necropsies were scheduled at four time-points (2, 4, 8, and 15 days post-contamination) for the female groups and at three time-points (2, 4, and 8 days post-contamination) for the male groups. Results : Elimination enhancement was dose-dependent in the 1-100 mu mol/kg dose range at all necropsy time-points, with some significant reductions in full body and tissue content for both female and male animals. The highest dose level resulted in slight toxicity, with a short recovery period, which delayed excretion of the radionuclide. Conclusions : While differences were noted between the female and male cohorts in efficacy range and recovery times, all groups displayed sustained dose-dependent 238 Pu elimination enhancement after delayed parenteral treatment with 3,4,3-LI(1,2-HOPO), the actinide decorporation agent under development. C1 [An, Dahlia D.; Villalobos, Jonathan A.; Morales-Rivera, Joel A.; Choi, Taylor A.; Sturzbecher-Hoehne, Manuel; Abergel, Rebecca J.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA. [Rosen, Chris J.; Bjornstad, Kathleen A.; Gauny, Stacey S.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Life Sci, Berkeley, CA 94720 USA. RP Abergel, RJ (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, One Cyclotron Rd,MS 70A-1150, Berkeley, CA 94720 USA. EM rjabergel@lbl.gov FU Biomedical Advanced Research and Development Authority (BARDA) at the E. O. Lawrence Berkeley National Laboratory, a U.S. Department of Energy Laboratory [IPIAA12OS99609, DE-AC02-05CH11231] FX This work was supported by the Biomedical Advanced Research and Development Authority (BARDA, Contract #IPIAA12OS99609) at the E. O. Lawrence Berkeley National Laboratory, a U.S. Department of Energy Laboratory under Contract No. DE-AC02-05CH11231. NR 29 TC 4 Z9 4 U1 0 U2 6 PU INFORMA HEALTHCARE PI LONDON PA TELEPHONE HOUSE, 69-77 PAUL STREET, LONDON EC2A 4LQ, ENGLAND SN 0955-3002 EI 1362-3095 J9 INT J RADIAT BIOL JI Int. J. Radiat. Biol. PD NOV PY 2014 VL 90 IS 11 SI SI BP 1055 EP 1061 DI 10.3109/09553002.2014.925150 PG 7 WC Biology; Nuclear Science & Technology; Radiology, Nuclear Medicine & Medical Imaging SC Life Sciences & Biomedicine - Other Topics; Nuclear Science & Technology; Radiology, Nuclear Medicine & Medical Imaging GA AS8GC UT WOS:000344486900016 PM 24937372 ER PT J AU King, W AF King, Wayne TI ADVANCING METAL AM AT ITS MOST FUNDAMENTAL LEVEL SO JOM LA English DT News Item ID SIMULATION; POWDER; MODEL C1 Lawrence Livermore Natl Lab, Accelerated Certificat Additively Manufactured Me, Livermore, CA 94550 USA. RP King, W (reprint author), Lawrence Livermore Natl Lab, Accelerated Certificat Additively Manufactured Me, Livermore, CA 94550 USA. NR 8 TC 1 Z9 1 U1 2 U2 8 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1047-4838 EI 1543-1851 J9 JOM-US JI JOM PD NOV PY 2014 VL 66 IS 11 BP 2202 EP 2203 PG 2 WC Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering; Mineralogy; Mining & Mineral Processing SC Materials Science; Metallurgy & Metallurgical Engineering; Mineralogy; Mining & Mineral Processing GA AT0IA UT WOS:000344618900009 ER PT J AU Deng, M Kollias, P Feng, Z Zhang, CD Long, CN Kalesse, H Chandra, A Kumar, VV Protat, A AF Deng, Min Kollias, Pavlos Feng, Zhe Zhang, Chidong Long, Charles N. Kalesse, Heike Chandra, Arunchandra Kumar, Vickal V. Protat, Alain TI Stratiform and Convective Precipitation Observed by Multiple Radars during the DYNAMO/AMIE Experiment SO JOURNAL OF APPLIED METEOROLOGY AND CLIMATOLOGY LA English DT Article DE Algorithms; Instrumentation; sensors; Radars; Radar observations; Remote sensing; Surface observations ID RADIATION MEASUREMENT PROGRAM; Z-R-RELATIONSHIPS; SIZE DISTRIBUTIONS; RAINDROP SPECTRA; CLOUD; REFLECTIVITY; ATTENUATION; TROPICS; MODEL; TRMM AB In this study, methods of convective/stratiform precipitation classification and surface rain-rate estimation based on the Atmospheric Radiation Measurement Program (ARM) cloud radar measurements were developed and evaluated. Simultaneous and collocated observations of the Ka-band ARM zenith radar (KAZR), two scanning precipitation radars [NCAR S-band/Ka-band Dual Polarization, Dual Wavelength Doppler Radar (S-PolKa) and Texas A&M University Shared Mobile Atmospheric Research and Teaching Radar (SMART-R)], and surface precipitation during the Dynamics of the Madden-Julian Oscillation/ARM MJO Investigation Experiment (DYNAMO/AMIE) field campaign were used. The motivation of this study is to apply the unique long-term ARM cloud radar observations without accompanying precipitation radars to the study of cloud life cycle and precipitation features under different weather and climate regimes. The resulting convective/stratiform classification from KAZR was evaluated against precipitation radars. Precipitation occurrence and classified convective/stratiform rain fractions from KAZR compared favorably to the collocated SMART-R and S-PolKa observations. Both KAZR and S-PolKa radars observed about 5% precipitation occurrence. The convective (stratiform) precipitation fraction is about 18% (82%). Collocated disdrometer observations of two days showed an increased number concentration of small and large raindrops in convective rain relative to dominant small raindrops in stratiform rain. The composite distributions of KAZR reflectivity and Doppler velocity also showed distinct structures for convective and stratiform rain. These evidences indicate that the method produces physically consistent results for the two types of rain. A new KAZR-based, two-parameter [the gradient of accumulative radar reflectivity Z(e) (GAZ) below 1 km and near-surface Z(e)] rain-rate estimation procedure was developed for both convective and stratiform rain. This estimate was compared with the exponential Z-R (reflectivity-rain rate) relation. The relative difference between the estimated and surface-measured rainfall rates showed that the two-parameter relation can improve rainfall estimation relative to the Z-R relation. C1 [Deng, Min] Univ Wyoming, Laramie, WY 82071 USA. [Kollias, Pavlos; Kalesse, Heike] McGill Univ, Montreal, PQ, Canada. [Feng, Zhe; Long, Charles N.] Pacific NW Natl Lab, Richland, WA 99352 USA. [Zhang, Chidong; Chandra, Arunchandra] Univ Miami, Miami, FL USA. [Kumar, Vickal V.; Protat, Alain] Ctr Australian Weather & Climate Res, Melbourne, Vic, Australia. RP Deng, M (reprint author), Univ Wyoming, Dept Atmospher Sci, Dept 3038,1000 East Univ Ave, Laramie, WY 82071 USA. EM mdeng2@uwyo.edu RI Feng, Zhe/E-1877-2015 OI Feng, Zhe/0000-0002-7540-9017 FU Office of Science of the U. S. Department of Energy as part of the Atmospheric Systems Research Program FX This work is supported by the Office of Science of the U. S. Department of Energy as part of the Atmospheric Systems Research Program and uses data from the Atmospheric Radiation Measurement Climate Research Facility. We are grateful for the NCAR S-PolKa team, Texas A&M University SMART-R team, and ARM AMF2 team for providing the quality radar and precipitation data used in this study. The authors thank Drs. Sergey Y. Matrosov from CIRES/University of Colorado and NOAA/ESRL and Samuel Haimov, Dave Leon, and Zhien Wang from University of Wyoming for their suggestion and comments and three anonymous reviewers for their thorough comments and constructive criticisms. NR 58 TC 4 Z9 4 U1 2 U2 18 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 1558-8424 EI 1558-8432 J9 J APPL METEOROL CLIM JI J. Appl. Meteorol. Climatol. PD NOV PY 2014 VL 53 IS 11 BP 2503 EP 2523 DI 10.1175/JAMC-D-13-0311.1 PG 21 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA AT4UL UT WOS:000344938500006 ER PT J AU Gao, F Walter, ED Kollar, M Wang, YL Szanyi, J Peden, CHF AF Gao, Feng Walter, Eric D. Kollar, Marton Wang, Yilin Szanyi, Janos Peden, Charles H. F. TI Understanding ammonia selective catalytic reduction kinetics over Cu/SSZ-13 from motion of the Cu ions SO JOURNAL OF CATALYSIS LA English DT Article DE Selective catalytic reduction; Cu/SSZ-13; Electron paramagnetic resonance; Reaction kinetics; Reaction mechanism ID SSZ-13 ZEOLITE; NO OXIDATION; EXCHANGED SSZ-13; ACTIVE-SITES; NITRIC-OXIDE; CU-SSZ-13; NH3; SCR; IDENTIFICATION; FE-ZSM-5 AB Cu/SSZ-13 catalysts with Si/Al = 6 and various Cu/Al ratios are synthesized with solution ion exchange. Catalysts are characterized with surface area/pore volume measurements, Temperature Programmed Reduction (TPR), and Electron Paramagnetic Resonance (EPR) spectroscopy. Catalytic properties are examined using NO oxidation, ammonia oxidation, and standard ammonia selective catalytic reduction (NH3-SCR) reactions. Prior to full dehydration of the zeolite catalysts, hydrated Cu2+ ions are found to be very mobile as judged from EPR. NO oxidation is catalyzed by O-bridged Cu-dimer species that form at relatively high Cu loadings and in the presence of O-2. For NH3 oxidation on samples with low to intermediate Cu loadings, transient Cu-dimers are the low-temperature (<= 300 degrees C) active centers, while these dissociate to monomers at 350 degrees C and above and become active centers. For the much more complex standard SCR reaction, transient Cu-dimers are the active sites for reaction temperatures <250 degrees C at very low Cu loadings (Cu/Al <= 0.016). Between similar to 250 and 350 degrees C, these Cu-dimers become less stable causing SCR reaction rates to decrease. At temperatures >= 350 degrees C, Cu2+ monomers that had migrated to faces of 6-membered rings are the active sites. At intermediate Cu loadings, monomeric Cu2+ ions are also active in SCR in the low-temperature regime; these are proposed to be located within CHA cages and next to 8-membered rings, likely in the form of [Cu(OH)](+). At high Cu loadings (i.e., more than one Cu2+ ion in each unit cell), stable Cu-dimers form and these do not dissociate at temperatures above 350 degrees C. These moieties effectively occupy CHA cage space and block pore openings causing decreased efficiency of the catalysts. Also these moieties are highly active in catalyzing the NH3 oxidation reaction thus causing SCR selectivities to decrease above similar to 450 degrees C. Finally, our kinetics results strongly support a redox mechanism for standard SCR. Published by Elsevier Inc. C1 [Gao, Feng; Walter, Eric D.; Kollar, Marton; Wang, Yilin; Szanyi, Janos; Peden, Charles H. F.] Pacific NW Natl Lab, Inst Integrated Catalysis, Richland, WA 99352 USA. RP Gao, F (reprint author), Pacific NW Natl Lab, Inst Integrated Catalysis, POB 999, Richland, WA 99352 USA. EM feng.gao@pnnl.gov; janos.szanyi@pnnl.gov; chuck.peden@pnnl.gov RI Walter, Eric/P-9329-2016 FU United States Department of Energy (DOE), Energy Efficiency and Renewable Energy, Vehicle Technologies Office FX The authors gratefully acknowledge the United States Department of Energy (DOE), Energy Efficiency and Renewable Energy, Vehicle Technologies Office for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle. The authors also thank Shari Li (PNNL) for surface area/pore volume measurements, and Bruce W. Arey (PNNL) for SEM measurements. Discussions with Drs. A. Yezerets, K. Kamasamudram, J.H. Li, N. Currier and J.Y. Luo from Cummins, Inc., and H.Y. Chen and H. Hess from Johnson-Matthey are greatly appreciated. NR 40 TC 43 Z9 43 U1 23 U2 169 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0021-9517 EI 1090-2694 J9 J CATAL JI J. Catal. PD NOV PY 2014 VL 319 BP 1 EP 14 DI 10.1016/j.jcat.2014.08.010 PG 14 WC Chemistry, Physical; Engineering, Chemical SC Chemistry; Engineering GA AS7LK UT WOS:000344437400001 ER PT J AU Hibbitts, DD Jimenez, R Yoshimura, M Weiss, B Iglesia, E AF Hibbitts, David D. Jimenez, Rome Yoshimura, Masayuki Weiss, Brian Iglesia, Enrique TI Catalytic NO activation and NO-H-2 reaction pathways SO JOURNAL OF CATALYSIS LA English DT Article DE Nitric oxide reduction; Platinum; Cluster size effects; Kinetic isotope effects; Density functional theory ID SILICA-SUPPORTED RHODIUM; METAL BASED CATALYSTS; GENERALIZED GRADIENT APPROXIMATION; INITIO MOLECULAR-DYNAMICS; FISCHER-TROPSCH SYNTHESIS; AUGMENTED-WAVE METHOD; LEAN-BURN CONDITIONS; NO+H-2 REACTION; SELECTIVE OXIDATION; PT/SIO2 CATALYSTS AB Kinetic and isotopic data on Pt clusters and activation free energy barriers from density functional theory (DFT) on Pt(1 1 1) are used to assess the elementary steps involved in NO-H-2 reactions. Pt clusters 1-10 nm in diameter gave similar turnover rates, indicating that these elementary steps are insensitive to surface-atom coordination. N-O cleavage occurs after sequential addition of two chemisorbed H-atoms (H*) to NO* which are quasi-equilibrated with H-2 and NO co-reactants. The first step is equilibrated and forms HNO*, while the second addition is irreversible and forms *HNOH*; this latter step limits NO-H-2 rates and forms OH* and NH* intermediates that undergo fast reactions to give H2O, N2O, NH3, and N-2. These conclusions are consistent with (i) measured normal H/D kinetic isotope effects; (ii) rates proportional to H-2 pressure, but reaching constant values at higher pressures; (iii) fast H-2-D-2 equilibration during catalysis; and (iv) DFT-derived activation barriers. These data and calculations, taken together, rule out N-O cleavage via N-O* reactions with another NO* (forming O* and N2O) or with vicinal vacancies (forming N* and O*), which have much higher barriers than H*-assisted routes. The cleavage of N-O bonds via *HNOH* intermediates is reminiscent of C-O cleavage in CO-H-2 reactions (via (HCOH)-H-**) and of O-O cleavage in O-2-H-2 reactions (via OOH* or *HOOH*). H*-addition weakens the multiple bonds in NO, CO, and O-2 and allows coordination of each atom to metal surfaces; as a result, dissociation occurs via such assisted routes at all surface coverages relevant in the practice of catalysis. (C) 2014 Published by Elsevier Inc. C1 [Hibbitts, David D.; Jimenez, Rome; Yoshimura, Masayuki; Weiss, Brian; Iglesia, Enrique] Univ Calif Berkeley, Dept Chem Engn, Berkeley, CA 94720 USA. [Iglesia, Enrique] EO Lawrence Berkeley Natl Lab, Berkeley, CA USA. [Jimenez, Rome] Univ Concepcion, Dept Chem Engn, Concepcion, Chile. [Weiss, Brian] Exxon Mobil Res & Eng Co, Corp Res Strateg, Annandale, NJ USA. RP Iglesia, E (reprint author), Univ Calif Berkeley, Dept Chem Engn, Berkeley, CA 94720 USA. EM iglesia@berkeley.edu RI Iglesia, Enrique/D-9551-2017; Hibbitts, David/J-5507-2014 OI Iglesia, Enrique/0000-0003-4109-1001; Hibbitts, David/0000-0001-8606-7000 FU GM; Red Doctoral REDOC.CTA, MINEDUC Project at Universidad de Concepcion [UCO1202]; FONDECYT, Chile [1101005] FX Financial support from GM and technical discussions with Dr. Wei Li (GM) are gratefully acknowledged. Computational resources provided by XSEDE (CHE130022). RJ acknowledges financial support from Red Doctoral REDOC.CTA, MINEDUC Project UCO1202 at Universidad de Concepcion and FONDECYT Grant 1101005, Chile, during sabbatical research at UC Berkeley. NR 50 TC 3 Z9 3 U1 5 U2 62 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0021-9517 EI 1090-2694 J9 J CATAL JI J. Catal. PD NOV PY 2014 VL 319 BP 95 EP 109 DI 10.1016/j.jcat.2014.07.012 PG 15 WC Chemistry, Physical; Engineering, Chemical SC Chemistry; Engineering GA AS7LK UT WOS:000344437400010 ER PT J AU Gonzalez-Dominguez, J Marques, OA Martin, MJ Tourino, J AF Gonzalez-Dominguez, Jorge Marques, Osni A. Martin, Maria J. Tourino, Juan TI A 2D algorithm with asymmetric workload for the UPC conjugate gradient method SO JOURNAL OF SUPERCOMPUTING LA English DT Article DE Conjugate gradient; PGAS; UPC; Performance optimization; Data distribution ID NAS PARALLEL BENCHMARKS AB This paper examines four different strategies, each one with its own data distribution, for implementing the parallel conjugate gradient (CG) method and how they impact communication and overall performance. Firstly, typical 1D and 2D distributions of the matrix involved in CG computations are considered. Then, a new 2D version of the CG method with asymmetric workload, based on leaving some threads idle during part of the computation to reduce communication, is proposed. The four strategies are independent of sparse storage schemes and are implemented using Unified Parallel C (UPC), a Partitioned Global Address Space (PGAS) language. The strategies are evaluated on two different platforms through a set of matrices that exhibit distinct sparse patterns, demonstrating that our asymmetric proposal outperforms the others except for one matrix on one platform. C1 [Gonzalez-Dominguez, Jorge] Johannes Gutenberg Univ Mainz, Parallel & Distributed Architectures Grp, D-55122 Mainz, Germany. [Marques, Osni A.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Computat Res Div, Berkeley, CA 94720 USA. [Martin, Maria J.; Tourino, Juan] Univ A Coruna, Comp Architecture Grp, La Coruna, Spain. RP Gonzalez-Dominguez, J (reprint author), Johannes Gutenberg Univ Mainz, Parallel & Distributed Architectures Grp, D-55122 Mainz, Germany. EM j.gonzalez@uni-mainz.de; OAMarques@lbl.gov; mariam@udc.es; juan@udc.es RI Martin, Maria/M-5167-2015; Gonzalez-Dominguez, Jorge/H-7371-2016 OI Martin, Maria/0000-0002-9153-0909; Gonzalez-Dominguez, Jorge/0000-0002-2602-4874 FU Ministry of Economy and Competitiveness of Spain [TIN2013-42148-P]; FEDER funds of the EU [TIN2013-42148-P]; Galician Government (Consolidation Program of Competitive Reference Groups) [GRC2013/055]; U.S. Department of Energy [DE-AC03-76SF00098] FX This work was funded by the Ministry of Economy and Competitiveness of Spain and FEDER funds of the EU (Project TIN2013-42148-P), by the Galician Government (Consolidation Program of Competitive Reference Groups GRC2013/055) and by the U.S. Department of Energy (Contract No. DE-AC03-76SF00098). NR 22 TC 0 Z9 0 U1 0 U2 1 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0920-8542 EI 1573-0484 J9 J SUPERCOMPUT JI J. Supercomput. PD NOV PY 2014 VL 70 IS 2 BP 816 EP 829 DI 10.1007/s11227-014-1300-0 PG 14 WC Computer Science, Hardware & Architecture; Computer Science, Theory & Methods; Engineering, Electrical & Electronic SC Computer Science; Engineering GA AS9GY UT WOS:000344552400026 ER PT J AU Farina, EK Austin, KG Lieberman, HR AF Farina, Emily K. Austin, Krista G. Lieberman, Harris R. TI Concomitant Dietary Supplement and Prescription Medication Use Is Prevalent among US Adults with Doctor-Informed Medical Conditions SO JOURNAL OF THE ACADEMY OF NUTRITION AND DIETETICS LA English DT Article DE Dietary supplements; Prescription medications; Interactions; Chronic disease; Medical conditions ID ALTERNATIVE MEDICINE; UNITED-STATES; PRIMARY-CARE; DRUG-INTERACTIONS; OLDER-ADULTS; COMPLEMENTARY AB Information on patterns of concomitant dietary supplement (DS) and prescription medication (PM) use among US adults is limited. Thus, the prevalence of concomitant DS and PM use as a function of doctor-informed medical conditions (DIMC) was determined in a cross-sectional, observational study of a nationally representative sample of noninstitutionalized, civilian adults aged >= 20 years in the United States (N=9,950) from the 2005-2008 National Health and Nutrition Examination Survey (NHANES). Data were weighted for the complex, multistage, probability sampling design. Approximately one third (34.3%) of all US adults reported concomitant DS and PM use (approximately one in three adults). The prevalence of use was significantly higher among those with vs without a DIMC (47.3% vs 17.3%). Adults with a DIMC were more than two and a half times more likely to concomitantly use DS and PM than adults without a DIMC, after adjustment for sex, age, education, and household income. Multivitamin plus other ingredient(s), followed by antacids and multivitamin plus botanical ingredient(s), were the most prevalent DS categories used with a PM among those with and without a DIMC. The most prevalent PM categories used with a DS were cardiovascular agents (among those with a DIMC) and hormones (among those without a DIMC). These findings demonstrate that presence of a DIMC may be a risk factor for concomitant DS and PM use among US adults. Multivitamins containing nonvitamin or mineral ingredients are more commonly used than standard multivitamins with PM by US adults. This may be an emerging trend that warrants further consideration. C1 [Farina, Emily K.; Austin, Krista G.] Oak Ridge Associated Univ, Oak Ridge Inst Sci & Educ, Belcamp, MD USA. [Farina, Emily K.; Austin, Krista G.; Lieberman, Harris R.] US Army, Environm Med Res Inst, Mil Nutr Div, Natick, MA 01760 USA. RP Farina, EK (reprint author), US Army, Environm Med Res Inst, Bldg 42,Kansas St, Natick, MA 01760 USA. EM emily.k.farina.ctr@mail.mil FU US Army Medical Research and Material Command (USAMRMC); Department of Defense Center Alliance for Dietary Supplement Research FX This work was supported by the US Army Medical Research and Material Command (USAMRMC), Department of Defense Center Alliance for Dietary Supplement Research, and an appointment to the Postgraduate Research Participation Program administered by the Oak Ridge Institute for Science and Education through an interagency agreement between the US Department of Energy and USAMRMC. The opinions or assertions contained herein are the private views of the author and are not to be construed as official or as reflecting the views of the Army or the Department of Defense. Human subjects participated after giving their free and informed voluntary consent. The investigators adhered to the policies for protection of human subjects as prescribed in Army Regulation 70-25, and the research was conducted in adherence with the provisions of 32 CFR Part 219. Citations of commercial organizations and trade names in this report do not constitute an official Department of the Army endorsement or approval of the products or services of these organizations. Approved for public release. NR 29 TC 10 Z9 10 U1 2 U2 7 PU ELSEVIER SCIENCE INC PI NEW YORK PA 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA SN 2212-2672 EI 2212-2680 J9 J ACAD NUTR DIET JI J. Acad. Nutr. Diet. PD NOV PY 2014 VL 114 IS 11 BP 1784 EP + DI 10.1016/j.jand.2014.01.016 PG 9 WC Nutrition & Dietetics SC Nutrition & Dietetics GA AS8CE UT WOS:000344477100012 PM 24703929 ER PT J AU Marjanovic, N Wharton, S Chow, FK AF Marjanovic, Nikola Wharton, Sonia Chow, Fotini K. TI Investigation of model parameters for high-resolution wind energy forecasting: Case studies over simple and complex terrain SO JOURNAL OF WIND ENGINEERING AND INDUSTRIAL AERODYNAMICS LA English DT Article DE High-resolution simulations; Terrain complexity; Ramping event; Wind energy forecasts ID ATMOSPHERIC BOUNDARY-LAYER; NUMERICAL SIMULATIONS; VERTICAL DIFFUSION; WEATHER RESEARCH; WRF MODEL; PART I; TURBULENCE; VALLEY; TEMPERATURE; SENSITIVITY AB Wind power forecasting, turbine micrositing, and turbine design require high-resolution simulations of atmospheric flow. Case studies at two West Coast North American wind farms, one with simple and one with complex terrain, are explored using the Weather Research and Forecasting (WRF) model. Both synoptically and locally driven events that include some ramping are considered. The performance of the model with different grid nesting configurations, turbulence closures, and grid resolutions is investigated through comparisons with observation data. For the simple terrain site, no significant improvement in the simulation results is found when using higher resolution. In contrast, for the complex terrain site, there is significant improvement when using higher resolution, but only during the locally driven event. This suggests the possibility that computational resources could be spared under certain conditions, for example when the topography is adequately resolved at coarser resolutions. Physical parameters such as soil moisture have a very large effect, but mostly for the locally forced events for both simple and complex terrain. The effect of the PBL scheme choice varies significantly depending on the meteorological forcing and terrain. On average, prognostic TKE equation schemes perform better than non-local eddy viscosity schemes. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Marjanovic, Nikola; Chow, Fotini K.] Univ Calif Berkeley, Dept Civil & Environm Engn, Berkeley, CA 94720 USA. [Marjanovic, Nikola; Wharton, Sonia] Lawrence Livermore Natl Lab, Atmospher Earth & Energy Div, Livermore, CA 94551 USA. RP Marjanovic, N (reprint author), Univ Calif Berkeley, Dept Civil & Environm Engn, MC 1710, Berkeley, CA 94720 USA. EM nikola_marjanovic@berkeley.edu FU Department of Energy's Wind and Water Power Program Office [EB2502010]; DOE, National Nuclear Security Administration [DE-AC52-07NA27344] FX The authors express great appreciation to Iberdrola Renewables, Inc. for the collection, provision, and insightful discussion of the wind farm datasets. The authors also thank Julie Lundquist for initiating this project. This work is funded by the Department of Energy's Wind and Water Power Program Office under the Renewable Systems Interconnect Support program (BNR Code EB2502010) and the Lawrence Scholar Program. LLNL is operated by Lawrence Livermore National Security, LLC, for the DOE, National Nuclear Security Administration under Contract DE-AC52-07NA27344. IM release number: LLNL-JRNL-611332. NR 39 TC 6 Z9 6 U1 1 U2 23 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0167-6105 EI 1872-8197 J9 J WIND ENG IND AEROD JI J. Wind Eng. Ind. Aerodyn. PD NOV PY 2014 VL 134 BP 10 EP 24 DI 10.1016/j.jweia.2014.08.007 PG 15 WC Engineering, Civil; Mechanics SC Engineering; Mechanics GA AS7LS UT WOS:000344438200002 ER PT J AU Kebukawa, Y Zolensky, ME Kilcoyne, ALD Rahman, Z Jenniskens, P Cody, GD AF Kebukawa, Yoko Zolensky, Michael E. Kilcoyne, A. L. David Rahman, Zia Jenniskens, Peter Cody, George D. TI Diamond xenolith and matrix organic matter in the Sutter's Mill meteorite measured by C-XANES SO METEORITICS & PLANETARY SCIENCE LA English DT Article ID RAY-ABSORPTION SPECTROSCOPY; INTERSTELLAR DIAMONDS; CHONDRITE; CARBON; FILMS; EXCITATION; RESOLUTION; POLYMERS; ORIGIN; PLASMA AB The Sutter's Mill (SM) meteorite fell in El Dorado County, California, on April 22, 2012. This meteorite is a regolith breccia composed of CM chondrite material and at least one xenolithic phase: oldhamite. The meteorite studied here, SM2 (subsample 5), was one of three meteorites collected before it rained extensively on the debris site, thus preserving the original asteroid regolith mineralogy. Two relatively large (10 mu m sized) possible diamond grains were observed in SM2-5 surrounded by fine-grained matrix. In the present work, we analyzed a focused ion beam (FIB) milled thin section that transected a region containing these two potential diamond grains as well as the surrounding fine-grained matrix employing carbon and nitrogen X-ray absorption near-edge structure (C-XANES and N-XANES) spectroscopy using a scanning transmission X-ray microscope (STXM) (Beamline 5.3.2 at the Advanced Light Source, Lawrence Berkeley National Laboratory). The STXM analysis revealed that the matrix of SM2-5 contains C-rich grains, possibly organic nanoglobules. A single carbonate grain was also detected. The C-XANES spectrum of the matrix is similar to that of insoluble organic matter (IOM) found in other CM chondrites. However, no significant nitrogen-bearing functional groups were observed with N-XANES. One of the possible diamond grains contains a Ca-bearing inclusion that is not carbonate. C-XANES features of the diamond-edges suggest that the diamond might have formed by the CVD process, or in a high-temperature and -pressure environment in the interior of a much larger parent body. C1 [Kebukawa, Yoko; Cody, George D.] Carnegie Inst Sci, Geophys Lab, Washington, DC 20015 USA. [Kebukawa, Yoko] Hokkaido Univ, Dept Nat Hist Sci, Sapporo, Hokkaido 0600810, Japan. [Zolensky, Michael E.] NASA, Johnson Space Ctr, Houston, TX 77058 USA. [Kilcoyne, A. L. David] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA. [Rahman, Zia] Jacobs Sverdrup, Houston, TX 77058 USA. [Jenniskens, Peter] SETI Inst, Mountain View, CA 94043 USA. [Jenniskens, Peter] NASA, Ames Res Ctr, Moffett Field, CA 94035 USA. RP Kebukawa, Y (reprint author), Yokohama Natl Univ, Fac Engn, Yokohama, Kanagawa 2408501, Japan. EM kebukawa@ynu.ac.jp RI Kilcoyne, David/I-1465-2013 FU Office of Science, Department of Energy [DE-AC02-05CH11231]; NASA; JSPS; NASA Ames Research Center FX We thank George Flynn, Monica Grady, Hikaru Yabuta, and the Associate Editor Christine Floss for their careful reviews and constructive comments. STXM-XANES data were acquired at beamline 5.3.2.2 at the ALS, which is supported by the Director of the Office of Science, Department of Energy, under Contract No. DE-AC02-05CH11231. We gratefully acknowledge support from NASA Astrobiology and Origins of the Solar System Programs. Y. K. gratefully acknowledges support through the JSPS Postdoctoral Fellowships. The Sutter's Mill recovery was supported by NASA Ames Research Center. NR 41 TC 2 Z9 2 U1 2 U2 7 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1086-9379 EI 1945-5100 J9 METEORIT PLANET SCI JI Meteorit. Planet. Sci. PD NOV PY 2014 VL 49 IS 11 BP 2095 EP 2103 DI 10.1111/maps.12312 PG 9 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA AT1ZZ UT WOS:000344731500012 ER PT J AU Kim, HS Willett, JW Jain-Gupta, N Fiebig, A Crosson, S AF Kim, Hye-Sook Willett, Jonathan W. Jain-Gupta, Neeta Fiebig, Aretha Crosson, Sean TI The Brucella abortus virulence regulator, LovhK, is a sensor kinase in the general stress response signalling pathway SO MOLECULAR MICROBIOLOGY LA English DT Article ID SIGMA-FACTOR MIMICRY; BLUE-LIGHT; BACILLUS-SUBTILIS; TRANSDUCTION PATHWAYS; 2-COMPONENT SYSTEM; HISTIDINE KINASE; CAULOBACTER-CRESCENTUS; STRUCTURAL BASIS; PROTEIN; PHYR AB In the intracellular pathogen Brucella abortus, the general stress response (GSR) signalling system determines survival under acute stress conditions in vitro, and is required for long-term residence in a mammalian host. To date, the identity of the Brucella sensor kinase(s) that function to perceive stress and directly activate GSR signalling have remained undefined. We demonstrate that the flavin-binding sensor histidine kinase, LovhK (bab2_0652), functions as a primary B. abortusGSR sensor. LovhK rapidly and specifically phosphorylates the central GSR regulator, PhyR, and activates transcription of a set of genes that closely overlaps the known B. abortusGSR regulon. Deletion of lovhK severely compromises cell survival under defined oxidative and acid stress conditions. We further show that lovhK is required for cell survival during the early phase of mammalian cell infection and for establishment of long-term residence in a mouse infection model. Finally, we present evidence that particular regions of primary structure within the two N-terminal PAS domains of LovhK have distinct sensory roles under specific environmental conditions. This study elucidates new molecular components of a conserved signalling pathway that regulates B. abortus stress physiology and infection biology. C1 [Kim, Hye-Sook; Willett, Jonathan W.; Jain-Gupta, Neeta; Fiebig, Aretha; Crosson, Sean] Univ Chicago, Dept Biochem & Mol Biol, Chicago, IL 60637 USA. [Crosson, Sean] Univ Chicago, Comm Microbiol, Chicago, IL 60637 USA. [Kim, Hye-Sook; Willett, Jonathan W.; Jain-Gupta, Neeta; Crosson, Sean] Univ Chicago, Argonne Natl Lab, Howard Taylor Ricketts Lab, Chicago, IL 60637 USA. RP Crosson, S (reprint author), Univ Chicago, Dept Biochem & Mol Biol, 920 E 58Th St, Chicago, IL 60637 USA. EM scrosson@uchicago.edu OI Willett, Jonathan/0000-0002-5467-4145 FU National Institute of Allergy and Infectious Diseases (NIAID), National Institutes of Health (NIH) [U19AI107792, R01AI107159]; NIH [F32GM109661] FX We thank members of the Crosson Lab for discussions and guidance for this study. Robert Foreman generated plasmids to produce B. abortus Delta rpoE1, Delta rpoH1, and Delta dps mutant strains. This project has been funded in whole or in part with Federal funds from the National Institute of Allergy and Infectious Diseases (NIAID), National Institutes of Health (NIH), Grant No. U19AI107792 and R01AI107159 to S.C. J.W.W. is supported by a NIH Ruth Kirschstein Postdoctoral fellowship (F32GM109661). The authors of this study have no conflict of interest to declare. NR 48 TC 14 Z9 14 U1 0 U2 5 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0950-382X EI 1365-2958 J9 MOL MICROBIOL JI Mol. Microbiol. PD NOV PY 2014 VL 94 IS 4 BP 913 EP 925 DI 10.1111/mmi.12809 PG 13 WC Biochemistry & Molecular Biology; Microbiology SC Biochemistry & Molecular Biology; Microbiology GA AT3YO UT WOS:000344871800015 PM 25257300 ER PT J AU Stolley, RM Helm, ML AF Stolley, Ryan M. Helm, Monte L. TI LIGHT-HARVESTING MATERIALS Soft support for energy conversion SO NATURE CHEMISTRY LA English DT News Item C1 [Stolley, Ryan M.; Helm, Monte L.] Pacific NW Natl Lab, Ctr Mol Electroanal, Div Phys Sci, Richland, WA 99352 USA. RP Stolley, RM (reprint author), Pacific NW Natl Lab, Ctr Mol Electroanal, Div Phys Sci, POB 999,K2-57, Richland, WA 99352 USA. EM Monte.Helm@pnnl.gov OI Helm, Monte/0000-0003-4728-8833 NR 4 TC 3 Z9 3 U1 2 U2 23 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 1755-4330 EI 1755-4349 J9 NAT CHEM JI Nat. Chem. PD NOV PY 2014 VL 6 IS 11 BP 949 EP 950 DI 10.1038/nchem.2088 PG 2 WC Chemistry, Multidisciplinary SC Chemistry GA AS8BS UT WOS:000344476000002 PM 25343594 ER PT J AU Robertson, GP Grace, PR Izaurralde, RC Parton, WP Zhang, XS AF Robertson, G. Philip Grace, Peter R. Izaurralde, R. Cesar Parton, William P. Zhang, Xuesong TI CO2 emissions from crop residue-derived biofuels SO NATURE CLIMATE CHANGE LA English DT Letter ID SOIL ORGANIC-CARBON; MODEL C1 [Robertson, G. Philip] Michigan State Univ, Dept Plant Soil & Microbial Sci, Hickory Corners, MI 49060 USA. [Robertson, G. Philip] Michigan State Univ, WK Kellogg Biol Stn, Hickory Corners, MI 49060 USA. [Robertson, G. Philip; Izaurralde, R. Cesar; Zhang, Xuesong] Michigan State Univ, Great Lakes Bioenergy Res Ctr, E Lansing, MI 48824 USA. [Grace, Peter R.] Queensland Univ Technol, Inst Future Environm, Brisbane, Qld 4000, Australia. [Izaurralde, R. Cesar] Univ Maryland, Dept Geog Sci, College Pk, MD 20740 USA. [Izaurralde, R. Cesar] Texas A&M Univ, Texas AgriLife Res, Temple, TX 76502 USA. [Parton, William P.] Colorado State Univ, Nat Resource Ecol Lab, Ft Collins, CO 80521 USA. [Zhang, Xuesong] Univ Maryland, Pacific NW Natl Lab, Joint Global Change Res Inst, College Pk, MD 20740 USA. RP Robertson, GP (reprint author), Michigan State Univ, Dept Plant Soil & Microbial Sci, Hickory Corners, MI 49060 USA. EM robert30@msu.edu RI zhang, xuesong/B-7907-2009; OI Robertson, G/0000-0001-9771-9895 NR 9 TC 1 Z9 1 U1 4 U2 19 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 1758-678X EI 1758-6798 J9 NAT CLIM CHANGE JI Nat. Clim. Chang. PD NOV PY 2014 VL 4 IS 11 BP 933 EP 934 PG 3 WC Environmental Sciences; Environmental Studies; Meteorology & Atmospheric Sciences SC Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences GA AT0AD UT WOS:000344598400004 ER PT J AU Durack, PJ Gleckler, PJ Landerer, FW Taylor, KE AF Durack, Paul J. Gleckler, Peter J. Landerer, Felix W. Taylor, Karl E. TI Quantifying underestimates of long-term upper-ocean warming SO NATURE CLIMATE CHANGE LA English DT Article ID SEA-LEVEL RISE; BUDGET; TRENDS AB The global ocean stores more than 90% of the heat associated with observed greenhouse-gas-attributed global warming(1-4). Using satellite altimetry observations and a large suite of climate models, we conclude that observed estimates of 0-700 dbar global ocean warming since 1970 are likely biased low. This underestimation is attributed to poor sampling of the Southern Hemisphere, and limitations of the analysis methods that conservatively estimate temperature changes in data-sparse regions(5-7). We find that the partitioning of northern and southern hemispheric simulated sea surface height changes are consistent with precise altimeter observations, whereas the hemispheric partitioning of simulated upper-ocean warming is inconsistent with observed in-situ-based ocean heat content estimates. Relying on the close correspondence between hemispheric-scale ocean heat content and steric changes, we adjust the poorly constrained Southern Hemisphere observed warming estimates so that hemispheric ratios are consistent with the broad range of modelled results. These adjustments yield large increases (2.2-7.1 x 10(22) J 35 yr(-1)) to current global upper-ocean heat content change estimates, and have important implications for sea level, the planetary energy budget and climate sensitivity assessments. C1 [Durack, Paul J.; Gleckler, Peter J.; Taylor, Karl E.] Lawrence Livermore Natl Lab, Program Climate Model Diag & Intercomparison, Livermore, CA 94550 USA. [Landerer, Felix W.] CALTECH, Jet Prop Lab, Pasadena, CA 91109 USA. RP Durack, PJ (reprint author), Lawrence Livermore Natl Lab, Program Climate Model Diag & Intercomparison, Livermore, CA 94550 USA. EM pauldurack@llnl.gov RI Taylor, Karl/F-7290-2011; Durack, Paul/A-8758-2010; OI Taylor, Karl/0000-0002-6491-2135; Durack, Paul/0000-0003-2835-1438; Landerer, Felix/0000-0003-2678-095X FU US Department of Energy, Office of Science, Climate and Environmental Sciences Division, Regional and Global Climate Modeling Program [DE-AC52-07NA27344]; NASA ROSES Physical Oceanography [NNN13D462T]; NASA Sea Level Change Team (NSLCT) FX The work of P.J.D., P.J.G. and K.E.T. from Lawrence Livermore National Laboratory is a contribution to the US Department of Energy, Office of Science, Climate and Environmental Sciences Division, Regional and Global Climate Modeling Program under contract DE-AC52-07NA27344. The work of F.W.L. was performed at the Jet Propulsion Laboratory, California Institute of Technology and is supported by NASA ROSES Physical Oceanography grant NNN13D462T and the NASA Sea Level Change Team (NSLCT). We thank numerous colleagues from the Program for Climate Model Diagnosis and Intercomparison (PCMDI) for valuable feedback and input into this project. We also thank J. Durack of the University of California, San Francisco (USA), M. V. Durack of educAID (Australia), T. P. Boyer from the National Oceanographic Data Center, Silver Spring (USA), C. M. Domingues from the Antarctic Climate and Ecosystems CRC, Hobart (Australia) and J. A. Church from the Centre for Australian Weather and Climate Research, Hobart (Australia). We acknowledge the sources of observed data used in this study: D. Smith and J. Murphy (Smi07), C. M. Domingues (Dom08), M. Ishii and M. Kimoto (Ish09), S. Levitus and T. Boyer (Lev12) and the International Argo Program and the national programs that contribute to it. We acknowledge the World Climate Research Programmes Working Group on Coupled Modelling, which is responsible for CMIP, and we thank the climate modelling groups (listed in Supplementary Tables 1 and 2) for producing and making available their model output. For CMIP the US Department of Energys Program for Climate Model Diagnosis and Intercomparison provides coordinating support and led development of software infrastructure in partnership with the Global Organization for Earth System Science Portals. The DW10 data presented in this study can be downloaded from the CSIRO Ocean Change website at www.cmar.csiro.au/oceanchange. LLNL Release #: LLNL-JRNL-651841. NR 30 TC 35 Z9 37 U1 2 U2 34 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 1758-678X EI 1758-6798 J9 NAT CLIM CHANGE JI Nat. Clim. Chang. PD NOV PY 2014 VL 4 IS 11 BP 999 EP 1005 DI 10.1038/NCLIMATE2389 PG 7 WC Environmental Sciences; Environmental Studies; Meteorology & Atmospheric Sciences SC Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences GA AT0AD UT WOS:000344598400024 ER PT J AU Kapnick, SB Delworth, TL Ashfaq, M Malyshev, S Milly, PCD AF Kapnick, Sarah B. Delworth, Thomas L. Ashfaq, Moetasim Malyshev, Sergey Milly, P. C. D. TI Snowfall less sensitive to warming in Karakoram than in Himalayas due to a unique seasonal cycle SO NATURE GEOSCIENCE LA English DT Article ID CLIMATE-CHANGE; HYDROLOGICAL CYCLE; WATER-RESOURCES; HINDU-KUSH; PRECIPITATION; GLACIERS; 20TH-CENTURY; SIMULATION; SCENARIOS; MONSOON AB The high mountains of Asia, including the Karakoram, Himalayas and Tibetan Plateau, combine to form a region of perplexing hydroclimate changes. Glaciers have exhibited mass stability or even expansion in the Karakoram region(1-3), contrasting with glacial mass loss across the nearby Himalayas and Tibetan Plateau(1,4), a pattern that has been termed the Karakoram anomaly. However, the remote location, complex terrain and multi-country fabric of high-mountain Asia have made it difficult to maintain longer-term monitoring systems of the meteorological components that may have influenced glacial change. Here we compare a set of high-resolution climate model simulations from 1861 to 2100 with the latest available observations to focus on the distinct seasonal cycles and resulting climate change signatures of Asia's high-mountain ranges. We find that the Karakoram seasonal cycle is dominated by non-monsoonal winter precipitation, which uniquely protects it from reductions in annual snowfall under climate warming over the twenty-first century. The simulations show that climate change signals are detectable only with long and continuous records, and at specific elevations. Our findings suggest a meteorological mechanism for regional differences in the glacier response to climate warming. C1 [Kapnick, Sarah B.] Princeton Univ, Program Atmospher & Ocean Sci, Princeton, NJ 08540 USA. [Kapnick, Sarah B.; Delworth, Thomas L.; Milly, P. C. D.] NOAA, Geophys Fluid Dynam Lab, Princeton, NJ 08540 USA. [Ashfaq, Moetasim] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. [Malyshev, Sergey] Princeton Univ, Dept Ecol & Evolutionary Biol, Princeton, NJ 08540 USA. [Milly, P. C. D.] US Geol Survey, Princeton, NJ 08540 USA. RP Kapnick, SB (reprint author), Princeton Univ, Program Atmospher & Ocean Sci, Princeton, NJ 08540 USA. EM skapnick@princeton.edu RI Kapnick, Sarah/C-5209-2014; Delworth, Thomas/C-5191-2014 OI Kapnick, Sarah/0000-0003-0979-3070; NR 39 TC 27 Z9 27 U1 4 U2 34 PU NATURE PUBLISHING GROUP PI NEW YORK PA 75 VARICK ST, 9TH FLR, NEW YORK, NY 10013-1917 USA SN 1752-0894 EI 1752-0908 J9 NAT GEOSCI JI Nat. Geosci. PD NOV PY 2014 VL 7 IS 11 BP 834 EP 840 DI 10.1038/NGEO2269 PG 7 WC Geosciences, Multidisciplinary SC Geology GA AT3CC UT WOS:000344812100018 ER PT J AU Kim, YM Morozovska, A Eliseev, E Oxley, MP Mishra, R Selbach, SM Grande, T Pantelides, ST Kalinin, SV Borisevich, AY AF Kim, Young-Min Morozovska, Anna Eliseev, Eugene Oxley, Mark P. Mishra, Rohan Selbach, Sverre M. Grande, Tor Pantelides, S. T. Kalinin, Sergei V. Borisevich, Albina Y. TI Direct observation of ferroelectric field effect and vacancy-controlled screening at the BiFeO3/LaxSr1-xMnO3 interface SO NATURE MATERIALS LA English DT Article ID BIFEO3 FILMS; OXIDES; HETEROSTRUCTURES; EELS; POLARIZATION; SPECTROSCOPY; DOMAINS; FUTURE; STATES; SCALE AB The development of interface-based magnetoelectric devices necessitates an understanding of polarization-mediated electronic phenomena and atomistic polarization screening mechanisms. In this work, the LSMO/BFO interface is studied on a single unit-cell level through a combination of direct order parameter mapping by scanning transmission electron microscopy and electron energy-loss spectroscopy. We demonstrate an unexpected similar to 5% lattice expansion for regions with negative polarization charge, with a concurrent anomalous decrease of the Mn valence and change in oxygen K-edge intensity. We interpret this behaviour as direct evidence for screening by oxygen vacancies. The vacancies are predominantly accumulated at the second atomic layer of BFO, reflecting the difference of ionic conductivity between the components. This vacancy exclusion from the interface leads to the formation of a tail-to-tail domain wall. At the same time, purely electronic screening is realized for positive polarization charge, with insignificant changes in lattice and electronic properties. These results underline the non-trivial role of electrochemical phenomena in determining the functional properties of oxide interfaces. Furthermore, these behaviours suggest that vacancy dynamics and exclusion play major roles in determining interface functionality in oxide multilayers, providing clear implications for novel functionalities in potential electronic devices. C1 [Kim, Young-Min; Oxley, Mark P.; Mishra, Rohan; Pantelides, S. T.; Borisevich, Albina Y.] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA. [Kim, Young-Min] Korea Basic Sci Inst, Div Electron Microscop Res, Taejon 305333, South Korea. [Morozovska, Anna] Natl Acad Sci, Inst Phys, UA-03028 Kiev, Ukraine. [Eliseev, Eugene] Natl Acad Sci, Inst Problems Mat Sci, UA-03142 Kiev, Ukraine. [Oxley, Mark P.; Mishra, Rohan; Pantelides, S. T.] Vanderbilt Univ, Dept Phys & Astron, Nashville, TN 37235 USA. [Selbach, Sverre M.; Grande, Tor] Norwegian Univ Sci & Technol, Dept Mat Sci & Engn, NO-7491 Trondheim, Norway. [Kalinin, Sergei V.] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA. RP Kim, YM (reprint author), Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA. EM albinab@ornl.gov RI Borisevich, Albina/B-1624-2009; Mishra, Rohan/J-9127-2013; Grande, Tor/K-4125-2015; Selbach, Sverre/D-5680-2014; Kalinin, Sergei/I-9096-2012; Kim, Young-Min/B-7338-2012 OI Borisevich, Albina/0000-0002-3953-8460; Mishra, Rohan/0000-0003-1261-0087; Kalinin, Sergei/0000-0001-5354-6152; Kim, Young-Min/0000-0003-3220-9004 FU Materials Science and Engineering Division, Office of Basic Energy Sciences of the US DOE; Oak Ridge National Laboratory's Center for Nanophase Materials Sciences - Scientific User Facilities Division, Office of Basic Energy Sciences, US Department of Energy; DOE [DE-FG02-09ER46554]; bilateral SFFR-NSF project, namely US National Science Foundation [NSF-DMR-1210588]; State Fund of Fundamental Research of Ukraine [UU48/002]; Office of Science of the US Department of Energy [DE-AC02-05CH11231] FX The work is supported in part (A.Y.B., Y-M.K., S. V. K., R. M. and S. T. P.) by the Materials Science and Engineering Division, Office of Basic Energy Sciences of the US DOE and through a user project supported by Oak Ridge National Laboratory's Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Scientific User Facilities Division, Office of Basic Energy Sciences, US Department of Energy. M.P.O. acknowledges support from DOE grant DE-FG02-09ER46554. The authors thank P. Yu (Tsinghua University, Beijing, China), Y-H. Chu (National Chiao Tung University, Hsinchu, Taiwan) and R. Ramesh (University of California Berkeley) for providing BiFeO3 films for the study. A. M. and E. E. acknowledge support via a bilateral SFFR-NSF project, namely US National Science Foundation under NSF-DMR-1210588 and State Fund of Fundamental Research of Ukraine, grant UU48/002. This research used resources of the National Energy Research Scientific Computing Center, which is supported by the Office of Science of the US Department of Energy under Contract No. DE-AC02-05CH11231. NR 60 TC 46 Z9 46 U1 19 U2 243 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 1476-1122 EI 1476-4660 J9 NAT MATER JI Nat. Mater. PD NOV PY 2014 VL 13 IS 11 BP 1019 EP 1025 DI 10.1038/NMAT4058 PG 7 WC Chemistry, Physical; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter SC Chemistry; Materials Science; Physics GA AS8AC UT WOS:000344471900008 PM 25129618 ER PT J AU Tochigi, E Zepeda-alarcon, E Wenk, HR Minor, AM AF Tochigi, E. Zepeda-alarcon, E. Wenk, H. -R. Minor, A. M. TI In situ TEM observations of plastic deformation in quartz crystals SO PHYSICS AND CHEMISTRY OF MINERALS LA English DT Article DE Quartz; Dauphine twinning; Dislocations; Amorphization; In situ compression; Transmission electron microscopy ID ROOM-TEMPERATURE; POLYCRYSTALLINE QUARTZ; THERMAL-DIFFUSIVITY; TEXTURE MEMORY; SILICON; TRANSITION; NANOINDENTATION; COMPRESSION; DIFFRACTION; MICROSCOPY AB With in situ nanocompression experiments in a transmission electron microscope, we investigated plastic deformation in natural quartz crystals and observed both dislocation plasticity as well as mechanical twinning. Through this experimental method, we are able to provide direct evidence of Dauphin, twin nucleation and could measure the intrinsic twinning stress. The twinning phenomena appear to include a memory effect, where the same twin can reappear upon successive loading and unloading events. The data provide insight into this twin generation mechanism and can be used as a benchmark for the use of twins in quartz for paleopiezometry. Together, the observation of room-temperature dislocation plasticity and reversible twinning adds new insight into the extensive field of quartz plasticity and demonstrates the usefulness of small-scale testing techniques for mineral physics. C1 [Tochigi, E.; Minor, A. M.] Univ Calif Berkeley, Dept Mat Sci & Engn, Berkeley, CA 94720 USA. [Tochigi, E.; Minor, A. M.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Natl Ctr Electron Microscopy, Berkeley, CA 94720 USA. [Zepeda-alarcon, E.; Wenk, H. -R.] Univ Calif Berkeley, Dept Earth & Planetary Sci, Berkeley, CA 94720 USA. RP Minor, AM (reprint author), Univ Calif Berkeley, Dept Mat Sci & Engn, Berkeley, CA 94720 USA. EM wenk@berkeley.edu; aminor@berkeley.edu RI Foundry, Molecular/G-9968-2014 NR 46 TC 1 Z9 1 U1 3 U2 37 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0342-1791 EI 1432-2021 J9 PHYS CHEM MINER JI Phys. Chem. Miner. PD NOV PY 2014 VL 41 IS 10 BP 757 EP 765 DI 10.1007/s00269-014-0689-6 PG 9 WC Materials Science, Multidisciplinary; Mineralogy SC Materials Science; Mineralogy GA AT0RU UT WOS:000344643500003 ER PT J AU Zavarin, M Zhao, PH Dai, ZR Kersting, AB AF Zavarin, Mavrik Zhao, Pihong Dai, Zurong Kersting, Annie B. TI Plutonium sorption and precipitation in the presence of goethite at 25 and 80 degrees C SO RADIOCHIMICA ACTA LA English DT Article DE Plutonium; Goethite; Sorption; Precipitation ID PU(IV) HYDROUS OXIDE; NEPTUNIUM(V) SORPTION; GROUNDWATER; SOLUBILITY; ADSORPTION; TRANSPORT; SYSTEM; ENVIRONMENT; SPECIATION; REDUCTION AB We have examined the sorption of aqueous Pu(IV) and intrinsic Pu colloids to goethite across a Pu concentration range that spans the solubility of Pu(IV) hydrous oxide, at 25 and 80 degrees C, and after equilibration for over 100 days. The strong affinity of aqueous Pu(IV) for the goethite surface is explained by the epitaxial growth of bcc Pu O-4(7) nano-particles on goethite. The 3-5 nm Pu O-4(7) nano-particles are strictly associated with goethite, widely dispersed across the goethite surface, and stable over the timescale of months at both 25 and 80 degrees C. There is no indication that the sorbed Pu O-4(7) nano-particles alter to PuO2 over time. Intrinsic Pu colloids were identified by TEM as 3-5 nmPuO(2) nano-particles. They exhibit a weaker association with the goethite surface. Aggregation of PuO2 nano-particles was observed. There is no indication that the PuO2 nano-particles, once formed, will alter to Pu O-4(7) on goethite. Based on supernatant Pu concentrations, PuO2 nano-particle aggregation behavior is consistent with Pu(IV) hydrous oxide precipitation. C1 [Zavarin, Mavrik; Zhao, Pihong; Dai, Zurong; Kersting, Annie B.] Inst & Phys & Life Sci Directorate, Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. RP Zavarin, M (reprint author), Inst & Phys & Life Sci Directorate, Lawrence Livermore Natl Lab, 7000 East Ave,L-231, Livermore, CA 94550 USA. EM zavarin1@llnl.gov FU Department of Energy, Nuclear Energy Used Fuel Disposition Program; Subsurface Biogeochemical Research Program of the U.S. Department of Energy's Office of Biological and Environmental Research; U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work was performed with funding from the Department of Energy, Nuclear Energy Used Fuel Disposition Program and the Subsurface Biogeochemical Research Program of the U.S. Department of Energy's Office of Biological and Environmental Research. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. NR 38 TC 5 Z9 5 U1 3 U2 30 PU WALTER DE GRUYTER GMBH PI BERLIN PA GENTHINER STRASSE 13, D-10785 BERLIN, GERMANY SN 0033-8230 J9 RADIOCHIM ACTA JI Radiochim. Acta PD NOV PY 2014 VL 102 IS 11 BP 983 EP 997 DI 10.1515/ract-2013-2188 PG 15 WC Chemistry, Inorganic & Nuclear; Nuclear Science & Technology SC Chemistry; Nuclear Science & Technology GA AT0KM UT WOS:000344625100004 ER PT J AU Lof, M Bolte, A Jacobs, DF Jensen, AM AF Lof, Magnus Bolte, Andreas Jacobs, Douglass F. Jensen, Anna M. TI Nurse Trees as a Forest Restoration Tool for Mixed Plantations: Effects on Competing Vegetation and Performance in Target Tree Species SO RESTORATION ECOLOGY LA English DT Article DE competition; facilitation; plant-plant interactions; two-story plantation; vegetation control ID FRAXINUS-EXCELSIOR; SITE PREPARATION; BETULA-PENDULA; OAK SEEDLINGS; EARLY GROWTH; TEMPERATE; LIGHT; EUROPE; BIRCH; L. AB Multi-species mixed plantations can be designed to meet social, economic, and environmental objectives during forest restoration. This paper reports results from an experiment in southern Sweden concerning the influence of three different fast growing nurse tree species on the cover of herbaceous vegetation and on the performance of several target tree species. After 10 years, the nurse trees had reduced the competing herbaceous vegetation but the effect was weak and it may take more than a decade to achieve effective vegetation control. The nurse tree species Betula pendula and Larix x eurolepis did improve stem form in some target tree species, but had a minor effect on survival and growth. The open conditions before crown closure of nurse trees strongly influence seedling performance and so delayed planting of target tree species may provide a means to avoid those conditions. Survival and growth differed greatly among the tree species. Besides the two nurse tree species mentioned above, high survival was found in Picea abies and Quercus robur and intermediate survival in Fagus sylvatica, Tilia cordata, and in the N-fixing nurse tree Alnus glutinosa. Survival was low in the target tree species Fraxinus excelsior L. and Prunus avium. For restoration practitioners, our results illustrate the potential of using nurse trees for rapidly building a new forest structure and simultaneously increase productivity, which might be a cost-effective strategy for forest restoration. C1 [Lof, Magnus] Swedish Univ Agr Sci, Southern Swedish Forest Res Ctr, SE-23053 Alnarp, Sweden. [Bolte, Andreas] Johann Heinrich von Thunen Inst TI, Fed Res Inst Rural Areas Forestry & Fisheries, Inst Forest Ecosyst, D-16225 Eberswalde, Germany. [Jacobs, Douglass F.] Purdue Univ, Dept Forestry & Nat Resources, Hardwood Tree Improvement & Regenerat Ctr, W Lafayette, IN 47907 USA. [Jensen, Anna M.] Oak Ridge Natl Lab, Climate Change Sci Inst, Oak Ridge, TN 37831 USA. RP Lof, M (reprint author), Swedish Univ Agr Sci, Southern Swedish Forest Res Ctr, POB 49, SE-23053 Alnarp, Sweden. EM Magnus.lof@slu.se RI Bolte, Andreas/A-3521-2009; OI Jensen, Anna Monrad/0000-0001-5113-5624 FU Nordic Energy Research FX The study was supported from the research program Enerwoods (Wood based energy systems from Nordic countries) funded by Nordic Energy Research. NR 27 TC 6 Z9 6 U1 3 U2 62 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1061-2971 EI 1526-100X J9 RESTOR ECOL JI Restor. Ecol. PD NOV PY 2014 VL 22 IS 6 BP 758 EP 765 DI 10.1111/rec.12136 PG 8 WC Ecology SC Environmental Sciences & Ecology GA AS8DL UT WOS:000344480300008 ER PT J AU Morton, EA Arrowsmith, SJ AF Morton, Emily A. Arrowsmith, Stephen J. TI The Development of Global Probabilistic Propagation Look-Up Tables for Infrasound Celerity and Back-Azimuth Deviation SO SEISMOLOGICAL RESEARCH LETTERS LA English DT Article ID ATMOSPHERE; LOCATION; MORPHOLOGY; WAVES C1 [Morton, Emily A.; Arrowsmith, Stephen J.] Los Alamos Natl Lab, Geophys Grp, EES 17, Los Alamos, NM 87545 USA. RP Morton, EA (reprint author), Los Alamos Natl Lab, Geophys Grp, EES 17, POB 1663,Mail Stop F665, Los Alamos, NM 87545 USA. EM emorton@lanl.gov FU National Science Foundation [EAR-0323309, EAR-0323311, EAR-0733069] FX We are grateful for reviews from David Fee and an anonymous reviewer, which helped us to clarify and strengthen this work. We thank Philip Blom for use of his geometric acoustics ray propagation code and input on the project, as well as David Green, Dale Anderson, Rod Whitaker, and Omar Marcillo for helpful feedback. We also thank Alexandra Nippress for providing Utah test and training range event picks and information used in Nippress et al. (2014) for comparisons. Data from the Transportable Array network were made freely available as part of the EarthScope USArray facility, operated by Incorporated Research Institutions for Seismology and supported by the National Science Foundation, under Cooperative Agreements EAR-0323309, EAR-0323311, and EAR-0733069. The GEOS-5 data utilized in conjunction with other data sources in the National Research Laboratory ground-to-space (G2S) atmospheric specification used in modeling was provided by the Global Modeling and Assimilation Office at National Aeronautics and Space Administration (NASA) Goddard Space Flight Center through the online data portal in the NASA Center for Climate Simulation. The National Oceanic and Atmospheric Administration (NOAA) Global Forecast System (GFS), also utilized in the G2S specifications, was obtained from NOAA's National Operational Model Archive and Distribution System, which is maintained at NOAA's National Climatic Data Center. This document is Los Alamos National Laboratory Publication Number LA-UR-14-24264. NR 24 TC 4 Z9 4 U1 2 U2 6 PU SEISMOLOGICAL SOC AMER PI ALBANY PA 400 EVELYN AVE, SUITE 201, ALBANY, CA 94706-1375 USA SN 0895-0695 EI 1938-2057 J9 SEISMOL RES LETT JI Seismol. Res. Lett. PD NOV-DEC PY 2014 VL 85 IS 6 BP 1223 EP 1233 DI 10.1785/0220140124 PG 11 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA AS8QD UT WOS:000344512500009 ER PT J AU Kasem, MA Gonzalez, JJ Russo, RE Harith, MA AF Kasem, M. A. Gonzalez, J. J. Russo, R. E. Harith, M. A. TI Effect of the wavelength on laser induced breakdown spectrometric analysis of archaeological bone SO SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY LA English DT Article; Proceedings Paper CT 7th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy (EMSLIBS) CY SEP 16-20, 2013 CL Bari, ITALY DE LIBS; Wavelength effect; Archaeology; Bone ID TRACE-ELEMENTS; FOSSIL BONES; SPECTROSCOPY; STRONTIUM; AGE AB The analytical exploitation of the laser induced plasma suffers from its transient behavior due to some nonlinear effects. These phenomena are matrix-dependent and limit the use of LIBS to mostly semi-quantitative precision. The plasma parameters have to be kept as constant as possible during LIBS measurements. Studying archaeological bone samples using LIBS technique could be more difficult since these samples are less tough in their texture than many other solid samples. Thus, the ablation process could change the sample morphological features rapidly resulting in poor reproducibility and statistics. Furthermore archaeological bones are subjected to diagenesis effects due to burial environment and postmortem effects. In the present work comparative analytical study of UV (266 nm) and IR (1064 nm) LIBS for archaeological bone samples belonging to four ancient Egyptian dynasties representing the middle kingdom (1980-1630 BC), 2nd intermediate period (1630-1539/23 BC), Roman-Greek period (30 BC-A.D. 395) and the late period (664-332 BC). Measurements have been performed under identical experimental conditions except the laser wavelength to examine its effects. Elemental fluctuations within the same dynasty were studied for reliable information about each dynasty. The analytical results demonstrated that UV-LIBS gives a more realistic picture for bone elemental composition within the same dynasty, and bone ash could be more suitable as a reference material for bone calibration in the case of UV-LIBS. (C) 2014 Elsevier B.V. All rights reserved. C1 [Kasem, M. A.; Harith, M. A.] Cairo Univ, NILES, Giza, Egypt. [Gonzalez, J. J.; Russo, R. E.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. RP Harith, MA (reprint author), Cairo Univ, NILES, Giza, Egypt. EM mharithm@niles.edu.eg NR 18 TC 3 Z9 4 U1 5 U2 31 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0584-8547 J9 SPECTROCHIM ACTA B JI Spectroc. Acta Pt. B-Atom. Spectr. PD NOV 1 PY 2014 VL 101 BP 26 EP 31 DI 10.1016/j.sab.2014.07.010 PG 6 WC Spectroscopy SC Spectroscopy GA AS7MO UT WOS:000344440300005 ER PT J AU Cordes, NL Havrilla, GJ Usov, IO Obrey, KA Patterson, BM AF Cordes, Nikolaus L. Havrilla, George J. Usov, Igor O. Obrey, Kimberly A. Patterson, Brian M. TI Non-destructive elemental quantification of polymer-embedded thin films using laboratory based X-ray techniques SO SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY LA English DT Article DE Confocal micro-X-ray fluorescence; X-ray computed tomography; Embedded thin films ID COMPUTED-TOMOGRAPHY; MICRO-XRF; FLUORESCENCE SPECTROSCOPY; QUANTITATIVE RADIOGRAPHY; CALIBRATION; RECONSTRUCTION; THICKNESS; OBJECTS; COPPER; MODEL AB Thin coatings are important for a variety of industries including energy (e.g., solar cells, batteries), consumer electronics (e.g., LCD displays, computer chips), and medical devices (e.g., implants). These coatings are typically highly uniform layers with thicknesses ranging from a monolayer up to several micrometers. Characterizing these highly uniform coatings for their thickness, elemental composition, and uniformity are all paramount, but obtaining these measurements can be more difficult when the layers are subsurface and must be interrogated non-destructively. The coupling of confocal micro-X-ray fluorescence (confocal MXRF) and nano-scale X-ray computed tomography (nano-CT) together can make these measurements while meeting these sensitivity and resolution specifications necessary for characterizing thin films. Elemental composition, atomic percent, placement, and uniformity can be measured in three dimensions with this integrated approach. Confocal MXRF uses a pair of polycapillary optics to focus and collect X-rays from a material from a 3D spatially restricted confocal volume. Because of the spatial definition, individual layers (of differing composition) can be characterized based upon the elementally characteristic X-ray fluorescence collected for each element. Nano-scale X-ray computed tomography, in comparison, can image the layers at very high resolution (down to 50 nm) to precisely measure the embedded layer thickness. These two techniques must be used together if both the thickness and atomic density of a layer are unknown. This manuscript will demonstrate that it is possible to measure both the atomic percent of an embedded thin film layer and confirm its manufacturing quality. As a proof of principle, a 1.5 atomic percent, 2 pm-thick Ge layer embedded within polymer capsules, used for laser plasma experiments at the Omega Laser Facility and National Ignition Facility, are measured. (C) 2014 Elsevier B.V. All rights reserved. C1 [Cordes, Nikolaus L.; Usov, Igor O.; Obrey, Kimberly A.; Patterson, Brian M.] Los Alamos Natl Lab, Mat Sci & Technol Div, Los Alamos, NM 87545 USA. [Havrilla, George J.] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA. RP Cordes, NL (reprint author), Los Alamos Natl Lab, Mat Sci & Technol Div, POB 1663, Los Alamos, NM 87545 USA. EM ncordes@lanl.gov OI Havrilla, George/0000-0003-2052-7152; Cordes, Nikolaus/0000-0003-3367-5592; Patterson, Brian/0000-0001-9244-7376 FU US Department of Energy [DE-AC52-06NA25396] FX The authors thank General Atomics, Haibo Huang and Abbas Nikroo for the loan of the capsules. Los Alamos National Laboratory is operated by Los Alamos National Security LLC under contract number DE-AC52-06NA25396 for the US Department of Energy. NR 45 TC 7 Z9 7 U1 2 U2 28 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0584-8547 J9 SPECTROCHIM ACTA B JI Spectroc. Acta Pt. B-Atom. Spectr. PD NOV 1 PY 2014 VL 101 BP 320 EP 329 DI 10.1016/j.sab.2014.09.016 PG 10 WC Spectroscopy SC Spectroscopy GA AS7MO UT WOS:000344440300041 ER PT J AU Lin, ZH AF Lin, Zhenhong TI Optimizing and Diversifying Electric Vehicle Driving Range for US Drivers SO TRANSPORTATION SCIENCE LA English DT Article DE electric vehicle; range anxiety; optimal design; transportation energy; alternative fuel infrastructure ID CHARGING INFRASTRUCTURE; ENERGY IMPACT; MANAGEMENT; ECONOMICS AB Properly determining the driving range is critical for accurately predicting the sales and social benefits of battery electric vehicles (BEVs). This study proposes a framework for optimizing the driving range by minimizing the sum of battery price, electricity cost, and range limitation cost-referred to as the "range-related cost"-as a measurement of range anxiety. The objective function is linked to policy-relevant parameters, including battery cost and price markup, battery utilization, charging infrastructure availability, vehicle efficiency, electricity and gasoline prices, household vehicle ownership, daily driving patterns, discount rate, and perceived vehicle lifetime. Qualitative discussion of the framework and its empirical application to a sample (N=D 36,664) representing new car drivers in the United States is included. The quantitative results strongly suggest that ranges of less than 100 miles are likely to be more popular in the BEV market for a long period of time. The average optimal range among U. S. drivers is found to be largely inelastic. Still, battery cost reduction significantly drives BEV demand toward longer ranges, whereas improvement in the charging infrastructure is found to significantly drive BEV demand toward shorter ranges. The bias of a single-range assumption and the effects of range optimization and diversification in reducing such biases are both found to be significant. C1 Oak Ridge Natl Lab, Knoxville, TN 37932 USA. RP Lin, ZH (reprint author), Oak Ridge Natl Lab, Knoxville, TN 37932 USA. EM linz@ornl.gov FU U.S. Department of Energy's Vehicle Technologies Office [DE-AC05-00OR22725] FX This study is sponsored by the U.S. Department of Energy's Vehicle Technologies Office [Contract DE-AC05-00OR22725]. The author thanks project managers Phil Patterson (retired) and Jake Ward for their support and assumes sole responsibility for the content and viewpoints expressed. NR 30 TC 7 Z9 7 U1 1 U2 21 PU INFORMS PI CATONSVILLE PA 5521 RESEARCH PARK DR, SUITE 200, CATONSVILLE, MD 21228 USA SN 0041-1655 J9 TRANSPORT SCI JI Transp. Sci. PD NOV PY 2014 VL 48 IS 4 SI SI BP 635 EP 650 DI 10.1287/trsc.2013.0516 PG 16 WC Operations Research & Management Science; Transportation; Transportation Science & Technology SC Operations Research & Management Science; Transportation GA AT4AT UT WOS:000344880400013 ER PT J AU Petrie, ES Evans, JP Bauer, SJ AF Petrie, E. S. Evans, J. P. Bauer, S. J. TI Failure of cap-rock seals as determined from mechanical stratigraphy, stress history, and tensile-failure analysis of exhumed analogs SO AAPG BULLETIN LA English DT Article ID CENTRAL UTAH; COLORADO PLATEAU; DAMAGE ZONE; FRACTURES; FAULTS; SANDSTONE; USA; DEFORMATION; BASIN; PERMEABILITY AB The sedimentologic and tectonic histories of elastic cap rocks and their inherent mechanical properties control the nature of permeable fractures within them. The migration of fluid through mm- to cm-scale fracture networks can result in focused fluid flow allowing hydrocarbon production from unconventional reservoirs or compromising the seal integrity of fluid traps. To understand the nature and distribution of subsurface fluid-flow pathways through fracture networks in cap-rock seals we examine four exhumed Paleozoic and Mesozoic seal analogs in Utah. We combine these outcrop analyses with subsidence analysis, paleo-loading histories, and rock-strength testing data in modified Mohr-Coulomb-Griffith analyses to evaluate the effects of differential stress and rock type on fracture mode. Relative to the underlying sandstone reservoirs, all four seal types are low-permeability, heterolithic sequences that show mineralized hydraulic-extension fractures, extensional-shear fractures, and shear fractures. Burial-history models suggest that the cap-rock seal analogs reached a maximum burial depth >4 km (2.5 mi) and experienced a lithostatic load of up to 110 MPa (15,954 psi). Median tensile strength from indirect mechanical tests ranges from 2.3 MPa (334 psi) in siltstone to 11.5 MPa (1668 psi) in calcareous shale. Analysis of the pore-fluid factor (lambda(v) = P-f/sigma(v)) through time shows changes in the expected failure mode (extensional shear or hydraulic extension), and that failure mode depends on a combination of mechanical rock properties and differential stress. As expected with increasing lithostatic load, the amount of overpressure that is required to induce failure increases but is also Ethology dependent. C1 [Petrie, E. S.] Western State Colorado Univ, Dept Geol, Gunnison, CO 81230 USA. [Evans, J. P.] Utah State Univ, Dept Geol, Logan, UT 84322 USA. [Bauer, S. J.] Sandia Natl Labs, Geomech Res Ctr Expt Geosci, Albuquerque, NM 87123 USA. RP Petrie, ES (reprint author), Western State Colorado Univ, Dept Geol, Gunnison, CO 81230 USA. EM epetrie@western.edu; james.evans@usu.edu; sjbauer@sandia.gov FU GDL Foundation; DOE [DE-FC26-0xNT4 FE0001786]; U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX This research is supported by grants from GDL Foundation Fellowship to Petrie and DOE DE-FC26-0xNT4 FE0001786 to Evans. Sandia National Laboratories is a multiprogram laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the US. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. The authors thank fellow researchers within the Utah State University Department of Geology structure group for their feedback and discussions. We thank the AAPG editor and reviewers for their detailed comments and suggestions for improvement. NR 69 TC 3 Z9 3 U1 4 U2 18 PU AMER ASSOC PETROLEUM GEOLOGIST PI TULSA PA 1444 S BOULDER AVE, PO BOX 979, TULSA, OK 74119-3604 USA SN 0149-1423 EI 1558-9153 J9 AAPG BULL JI AAPG Bull. PD NOV PY 2014 VL 98 IS 11 BP 2365 EP 2389 DI 10.1306/06171413126 PG 25 WC Geosciences, Multidisciplinary SC Geology GA AS7OO UT WOS:000344445300008 ER PT J AU Hossain, MZ Marian, J AF Hossain, M. Z. Marian, Jaime TI Stress-dependent solute energetics in W-Re alloys from first-principles calculations SO ACTA MATERIALIA LA English DT Article DE Applied stress; Vacancy-formation energy; Solute-migration energy; Dislocation-solute interaction; Solid-solution strengthening ID TUNGSTEN ALLOYS; METALS; TRANSITION; DIFFUSION; ALUMINUM; KINETICS AB We present a systematic study of Re solute transport energetics in W using density functional theory calculations. The study focuses on substitutional solute diffusion in the presence of dislocation strain fields as a first step toward capturing the essential physics of solid solution hardening/softening in W-Re alloys. We calculate the heat of solution, the vacancy formation energy and the solute migration energy as functions of both hydrostatic and shear strains. Our results show that the vacancy formation energy scales with hydrostatic deformation, whereas it decreases with increasing shear strain. The migration energy decreases with hydrostatic deformation, whereas it displays path-length-dependent behavior under shear deformation. In addition, we compute the binding energies of an Re solute atom to the cores of 1/2 < 111 > screw and edge dislocations, and find the binding energy to be highest in the tensile lobe of the edge core. Finally, we obtain the dilatational stress due to a solute atom as a function of distance. Our calculations are then used to parameterize the jump rate of Re atoms in W as a function of the underlying stress state. (C) 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. C1 [Hossain, M. Z.] CALTECH, Div Engn & Appl Sci, Pasadena, CA 91125 USA. [Marian, Jaime] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. RP Hossain, MZ (reprint author), CALTECH, Div Engn & Appl Sci, Pasadena, CA 91125 USA. EM zubaer@caltech.edu FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; DOE/OFES Early Career Program FX This work was carried out under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. M.Z.H. is very grateful to Prof. Kaushik Bhattacharya and the PSAAP-Caltech program. J.M. acknowledges support from DOE/OFES Early Career Program. NR 32 TC 2 Z9 2 U1 6 U2 38 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 1359-6454 EI 1873-2453 J9 ACTA MATER JI Acta Mater. PD NOV PY 2014 VL 80 BP 107 EP 117 DI 10.1016/j.actamat.2014.07.028 PG 11 WC Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Materials Science; Metallurgy & Metallurgical Engineering GA AS3XK UT WOS:000344208300010 ER PT J AU Wells, PB Yamamoto, T Miller, B Milot, T Cole, J Wu, Y Odette, GR AF Wells, Peter B. Yamamoto, Takuya Miller, Brandon Milot, Tim Cole, James Wu, Yuan Odette, G. Robert TI Evolution of manganese-nickel-silicon-dominated phases in highly irradiated reactor pressure vessel steels SO ACTA MATERIALIA LA English DT Article DE Radiation damage; Atom probe tomography; Precipitation; Irradiation embrittlement ID FE-CU-NI; RPV STEELS; ATOM-PROBE; FLOW-STRESS; EMBRITTLEMENT; COPPER; MODEL; SCATTERING; WELDS; IRON AB Formation of a high density of Mn-Ni-Si nanoscale precipitates in irradiated Cu-free and Cu-bearing reactor pressure vessel steels could lead to severe unexpected embrittlement. Models long ago predicted that these precipitates, which are not treated in current embrittlement prediction models, would emerge only at high fluence. However, the mechanisms and variables that control Mn-Ni-Si precipitate formation, and their detailed characteristics, have not been well understood. High flux irradiations of six steels with systematic variations in Cu and Ni contents were carried out at similar to 295 degrees C to high and very high neutron fluences of similar to 1.3 x 10(20) and similar to 1.1 x 10(21) n cm(-2). Atom probe tomography shows that significant mole fractions of Mn-Ni-Si-dominated precipitates form in the Cu-bearing steels at similar to 1.3 x 10(20) n cm(-2), while they are only beginning to develop in Cu-free steels. However, large mole fractions of these precipitates, far in excess of those found in previous studies, are observed at 1.1 x 10(21) n cm(-2) at all Cu contents. At the highest fluence, the precipitate mole fractions primarily depend on the alloy Ni, rather than Cu, content. The Mn-Ni-Si precipitates lead to very large increases in measured hardness, corresponding to yield strength elevations of up to almost 700 MPa. (C) 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. C1 [Wells, Peter B.; Yamamoto, Takuya; Milot, Tim; Wu, Yuan; Odette, G. Robert] Univ Calif Santa Barbara, Santa Barbara, CA 93106 USA. [Miller, Brandon; Cole, James] Idaho Natl Lab, Idaho Falls, ID 83402 USA. RP Wells, PB (reprint author), Univ Calif Santa Barbara, Santa Barbara, CA 93106 USA. EM pwells@umail.ucsb.edu OI Cole, James/0000-0003-1178-5846 FU Advanced Test Reactor National Scientific User Facility through US Department of Energy, Office of Nuclear Energy under DOE Idaho Operations Office [DE-AC07-051D14517]; Jean Claude Van Duysen of Electricite de France; MRSEC Program of NSF [DMR 1121053]; DOE Office of Nuclear Energy's Nuclear Energy University Program, as part of the LRW Sustainability Task FX A portion of this research, both the ATR irradiation and FIB/APT at the Center for Advanced Energy Studies-Microscopy and Characterization Suite (CAES-MaCS), was supported by the Advanced Test Reactor National Scientific User Facility through the US Department of Energy, Office of Nuclear Energy under DOE Idaho Operations Office Contract DE-AC07-051D14517. Special thanks go to Cohn Knight at the Idaho National Laboratory for assisting in the complex steps needed to gain access to the irradiated ATR specimens. The much earlier piggyback BR2 irradiations were sponsored by Jean Claude Van Duysen of Electricite de France and carried out under the supervision of Lorenzo Malerbra at SCK Belgium. We also thank Peter Hosemann at UC Berkeley for access to their FIB to prepare APT samples from the high-fluence (BR2) condition. The MRL Shared Experimental Facilities were used for performing APT on the high-fluence (BR2) samples and are supported by the MRSEC Program of the NSF under Award No. DMR 1121053 as a member of the NSF-funded Materials Research Facilities Network (www.mrfn.org). The bulk of this research was supported by the DOE Office of Nuclear Energy's Nuclear Energy University Program, as part of the LRW Sustainability Task. Finally we thank Huibin Ke, Professor Dane Morgan and our other collaborators at the University of Wisconsin who are leading the modeling effort cited in this paper and who were the source of many helpful discussions and much insight. NR 44 TC 20 Z9 20 U1 9 U2 46 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 1359-6454 EI 1873-2453 J9 ACTA MATER JI Acta Mater. PD NOV PY 2014 VL 80 BP 205 EP 219 DI 10.1016/j.actamat.2014.07.040 PG 15 WC Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Materials Science; Metallurgy & Metallurgical Engineering GA AS3XK UT WOS:000344208300019 ER PT J AU Kiani, S Leung, KWK Radmilovic, V Minor, AM Yang, JM Warner, DH Kodambaka, S AF Kiani, S. Leung, K. W. K. Radmilovic, V. Minor, A. M. Yang, J. -M. Warner, D. H. Kodambaka, S. TI Dislocation glide-controlled room-temperature plasticity in 6H-SiC single crystals SO ACTA MATERIALIA LA English DT Article DE Transmission electron microscopy; Plasticity; Dislocations; Silicon carbide; Molecular dynamics ID SILICON-CARBIDE; ACTIVATION PARAMETERS; PHASE-TRANSFORMATION; BRITTLE REGIME; SIC NANOWIRES; DEFORMATION; INDENTATION; NANOINDENTATION; MICROHARDNESS; SIMULATION AB In situ transmission electron microscopy observations of uniaxial compression of sub-300 nm diameter, cylindrical, single-crystalline 6H-SiC pillars oriented along < 0001 > and at 45 with respect to < 0001 > reveal that plastic slip occurs at room-temperature on the basal {0001} planes at stresses above 7.8 GPa. Using a combination of aberration-corrected electron microscopy, molecular dynamics simulations and density functional theory calculations, we attribute the observed phenomenon to basal slip on the shuffle set along < 1 (1) over bar 00 >. By comparing the experimentally measured yield stresses with the calculated values required for dislocation nucleation, we suggest that room-temperature plastic deformation in 6H-SiC crystals is controlled by glide rather than nucleation of dislocations. (C) 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. C1 [Kiani, S.; Yang, J. -M.; Kodambaka, S.] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA. [Leung, K. W. K.; Warner, D. H.] Cornell Univ, Sch Civil & Environm Engn, Ithaca, NY 14853 USA. [Radmilovic, V.] Univ Belgrade, Fac Technol & Met, Nanotechnol & Funct Mat Ctr, Belgrade 11000, Serbia. [Minor, A. M.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Natl Ctr Electron Microscopy, Berkeley, CA 94720 USA. [Minor, A. M.] Univ Calif Berkeley, Dept Mat Sci & Engn, Berkeley, CA 94720 USA. RP Warner, DH (reprint author), Cornell Univ, Sch Civil & Environm Engn, Ithaca, NY 14853 USA. EM dhw52@cornell.edu; kodambaka@ucla.edu RI Warner, Derek/A-2303-2012; Foundry, Molecular/G-9968-2014 FU AFOSR [FA9550-10-1-0496, FA9550-11-10273]; Office of Science, Office of Basic Energy Sciences, of the US Department of Energy [DE-AC02-05CH11231]; Nanotechnology and Functional Material Center; Ministry of Education and Science of the Republic of Serbia [172054] FX We gratefully acknowledge support from the AFOSR (Dr. Ali Sayir) FA9550-10-1-0496 and FA9550-11-10273. The in situ electron microscopy experiments were conducted as part of a user project at the National Center for Electron Microscopy, Lawrence Berkeley National Laboratory, supported by the Office of Science, Office of Basic Energy Sciences, of the US Department of Energy under Contract No. DE-AC02-05CH11231. We thank Marissa Manusco for her help with the sample preparation. V.R. acknowledges support from Nanotechnology and Functional Material Center, and the Ministry of Education and Science of the Republic of Serbia, project no. 172054. NR 38 TC 7 Z9 7 U1 3 U2 31 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 1359-6454 EI 1873-2453 J9 ACTA MATER JI Acta Mater. PD NOV PY 2014 VL 80 BP 400 EP 406 DI 10.1016/j.actamat.2014.07.066 PG 7 WC Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Materials Science; Metallurgy & Metallurgical Engineering GA AS3XK UT WOS:000344208300036 ER PT J AU Ke, FS Yue, GQ Shen, B Dong, F Wang, SY Zheng, YX Chen, LY Wang, CZ Ho, KM AF Ke, F. S. Yue, G. Q. Shen, B. Dong, F. Wang, S. Y. Zheng, Y. X. Chen, L. Y. Wang, C. Z. Ho, K. M. TI Bergman-type medium-range order in rapidly quenched Ag0.74Ge0.26 eutectic alloy studied by ab initio molecular dynamics simulation SO ACTA MATERIALIA LA English DT Article DE Ab initio molecular dynamics; Local structure; Short-range order; Medium-range order ID METALLIC GLASSES; LIQUID; SYSTEMS; PHASE; GOLD AB The structure of liquid and rapidly quenched amorphous Ag0.74Ge0.26 alloy at the eutectic composition was studied by ab initio molecular dynamics (MD) simulations. The local structural properties were systematically investigated from the liquid at 1123 K to amorphous solid at 300 K. The pair-correlation function at 976 K from the MD simulations agrees well with the experimental data. The local structures were also analyzed using Honeycutt-Andersen (HA) indices, Voronoi tessellation and the atomic cluster alignment (ACA) method. The HA indices analysis reveals that there is a high population of pentagonal bipyramid structure which become more predominant upon solidification. Voronoi tessellation analysis indicates strong icosahedral short-range order (SRO) in the liquid and amorphous samples generated by the MD simulations. Using the ACA method, the development of icosahedral SRO upon cooling is further confirmed and a Bergman medium-range order is also observed. The analysis of structural properties and chemical short-range order suggests that Ag atoms tend to have a Bergman-like packing, while the dispersed Ge atoms prevent the alloy from forming a long-range order upon cooling. The Bergman medium-range order is also confirmed by the constrained reversed Monte Carlo results. (C) 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. C1 [Ke, F. S.; Yue, G. Q.; Shen, B.; Dong, F.; Wang, S. Y.; Zheng, Y. X.; Chen, L. Y.] Fudan Univ, Shanghai Ultra Precis Opt Mfg Engn Ctr, Shanghai 200433, Peoples R China. [Ke, F. S.; Yue, G. Q.; Shen, B.; Dong, F.; Wang, S. Y.; Zheng, Y. X.; Chen, L. Y.] Fudan Univ, Dept Opt Sci & Engn, Shanghai 200433, Peoples R China. [Yue, G. Q.; Wang, S. Y.; Wang, C. Z.; Ho, K. M.] Iowa State Univ, US DOE, Ames Lab, Ames, IA 50011 USA. [Yue, G. Q.; Wang, S. Y.; Wang, C. Z.; Ho, K. M.] Iowa State Univ, Dept Phys & Astron, Ames, IA 50011 USA. [Wang, S. Y.] Key Lab Informat Sci Elect Waves MoE, Shanghai 200433, Peoples R China. RP Wang, SY (reprint author), Fudan Univ, Shanghai Ultra Precis Opt Mfg Engn Ctr, Shanghai 200433, Peoples R China. EM songyouwang@fudan.edu.cn RI Wang, Songyou/H-4529-2011 OI Wang, Songyou/0000-0002-4249-3427 FU NSF of China [11374055, 10974029]; Ministry of Education of China [20100071110025]; National Basic Research Program of China [2010CB933703, 2012CB934303]; Fudan High-end Computing Center; US Department of Energy, Basic Energy Sciences; US Department of Energy, Division of Materials Science and Engineering; National Energy Research Scientific Computing Centre (NERSC) in Berkeley, CA [DE-AC02-07CH11358] FX The work at Fudan university was supported by the NSF of China (Grant Nos. 11374055 and 10974029), Doctoral Fund of Ministry of Education of China (No. 20100071110025), National Basic Research Program of China (No. 2010CB933703 and 2012CB934303), and the Fudan High-end Computing Center. Work at Ames Laboratory was supported by the US Department of Energy, Basic Energy Sciences, and Division of Materials Science and Engineering, including a grant of computer time at the National Energy Research Scientific Computing Centre (NERSC) in Berkeley, CA under Contract No. DE-AC02-07CH11358. NR 33 TC 4 Z9 4 U1 2 U2 51 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 1359-6454 EI 1873-2453 J9 ACTA MATER JI Acta Mater. PD NOV PY 2014 VL 80 BP 498 EP 504 DI 10.1016/j.actamat.2014.06.049 PG 7 WC Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Materials Science; Metallurgy & Metallurgical Engineering GA AS3XK UT WOS:000344208300045 ER PT J AU Gludovatz, B Naleway, SE Ritchie, RO Kruzic, JJ AF Gludovatz, Bernd Naleway, Steven E. Ritchie, Robert O. Kruzic, Jamie J. TI Size-dependent fracture toughness of bulk metallic glasses (vol 70, pg 198, 2014) SO ACTA MATERIALIA LA English DT Correction C1 [Gludovatz, Bernd; Ritchie, Robert O.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA. [Naleway, Steven E.; Kruzic, Jamie J.] Oregon State Univ, Sch Mech Ind & Mfg Engn, Corvallis, OR 97331 USA. [Ritchie, Robert O.] Univ Calif Berkeley, Dept Mat Sci & Engn, Berkeley, CA 94720 USA. RP Kruzic, JJ (reprint author), Oregon State Univ, Sch Mech Ind & Mfg Engn, Corvallis, OR 97331 USA. EM jamie.kruzic@oregonstate.edu RI Kruzic, Jamie/M-3558-2014; OI Kruzic, Jamie/0000-0002-9695-1921; Gludovatz, Bernd/0000-0002-2420-3879 NR 1 TC 0 Z9 0 U1 2 U2 35 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 1359-6454 EI 1873-2453 J9 ACTA MATER JI Acta Mater. PD NOV PY 2014 VL 80 BP 507 EP 507 DI 10.1016/j.actamat.2014.04.001 PG 1 WC Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Materials Science; Metallurgy & Metallurgical Engineering GA AS3XK UT WOS:000344208300047 ER PT J AU Liu, HH Valocchi, AJ Werth, C Kang, QJ Oostrom, M AF Liu, Haihu Valocchi, Albert J. Werth, Charles Kang, Qinjun Oostrom, Mart TI Pore-scale simulation of liquid CO2 displacement of water using a two-phase lattice Boltzmann model SO ADVANCES IN WATER RESOURCES LA English DT Article DE Pore-scale simulation; Lattice Boltzmann model; Porous media; Multiphase flow; Fingering; Heterogeneity ID THROUGH POROUS-MEDIA; MULTIPHASE FLOW; RELATIVE PERMEABILITY; FLUID-FLOWS; THERMOCAPILLARY FLOWS; NUMERICAL SIMULATIONS; CAPILLARY; EQUATION; DYNAMICS; NETWORK AB A lattice Boltzmann color-fluid model, which was recently proposed by Liu et al. (2012) based on a concept of continuum surface force, is improved to simulate immiscible two-phase flows in porous media. The new improvements allow the model to account for different kinematic viscosities of both fluids and to model fluid-solid interactions. The capability and accuracy of this model is first validated by two benchmark tests: a layered two-phase flow with a variable viscosity ratio, and a dynamic capillary intrusion. This model is then used to simulate liquid CO2 (LCO2) displacing water in a dual-permeability pore network. The extent and behavior of LCO2 preferential flow (i.e., fingering) is found to depend on the capillary number (Ca), and three different displacement patterns observed in previous micromodel experiments are reproduced. The predicted variation of LCO2 saturation with Ca, as well as variation of specific interfacial length with LCO2 saturation, are both in reasonable agreement with the experimental observations. To understand the effect of heterogeneity on pore-scale displacement, we also simulate LCO2 displacing water in a randomly heterogeneous pore network, which has the same size and porosity as the simulated dual-permeability pore network. In comparison to the dual-permeability case, the transition from capillary fingering to viscous fingering occurs at a higher Ca, and LCO2 saturation is higher at low Ca but lower at high Ca. In either pore network, the LCO2-water specific interfacial length is found to obey a power-law dependence on LCO2 saturation. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Liu, Haihu; Valocchi, Albert J.; Werth, Charles] Univ Illinois, Dept Civil & Environm Engn, Urbana, IL 61801 USA. [Liu, Haihu] Univ Strathclyde, Dept Mech & Aerosp Engn, Glasgow G1 1XJ, Lanark, Scotland. [Kang, Qinjun] Los Alamos Natl Lab, Earth & Environm Sci Div, Los Alamos, NM 87545 USA. [Oostrom, Mart] Pacific NW Natl Lab, Div Energy & Environm, Hydrol Tech Grp, Richland, WA 99352 USA. RP Liu, HH (reprint author), Univ Illinois, Dept Civil & Environm Engn, Urbana, IL 61801 USA. EM haihliu@gmail.com RI Liu, Haihu/B-2097-2013 OI Liu, Haihu/0000-0002-0295-1251 FU LDRD Program of Los Alamos National Laboratory [20100025DR, 20140002DR]; International Institute for Carbon Neutral Energy Research - Japanese Ministry of Education, Culture, Sports, Science and Technology [WPI-I2CNER]; US Department of Energy [DE-AC05-76RL01830] FX The authors gratefully acknowledge the support from the LDRD Program (20100025DR and 20140002DR) of Los Alamos National Laboratory and from the International Institute for Carbon Neutral Energy Research (WPI-I2CNER), sponsored by the Japanese Ministry of Education, Culture, Sports, Science and Technology. Dr. Mart Oostrom's contribution has been supported by the "Pore-Scale Modeling'' Research Campaign at EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory, operated by Battelle for the US Department of Energy under Contract DE-AC05-76RL01830. We also acknowledge the computing support from LANL Institutional Computing Program. We thank Dr. Changyong Zhang, currently at Exxon-Mobil, for his assistance with analyzing and interpreting the results of the dual-permeability micromodel experiments he performed while at PNNL. NR 104 TC 19 Z9 19 U1 8 U2 75 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0309-1708 EI 1872-9657 J9 ADV WATER RESOUR JI Adv. Water Resour. PD NOV PY 2014 VL 73 BP 144 EP 158 DI 10.1016/j.advwatres.2014.07.010 PG 15 WC Water Resources SC Water Resources GA AS1US UT WOS:000344068000012 ER PT J AU Hyung, SW Piehowski, PD Moore, RJ Orton, DJ Schepmoes, AA Clauss, TR Chu, RK Fillmore, TL Brewer, H Liu, T Zhao, R Smith, RD AF Hyung, Seok-Won Piehowski, Paul D. Moore, Ronald J. Orton, Daniel J. Schepmoes, Athena A. Clauss, Therese R. Chu, Rosalie K. Fillmore, Thomas L. Brewer, Heather Liu, Tao Zhao, Rui Smith, Richard D. TI Microscale depletion of high abundance proteins in human biofluids using IgY14 immunoaffinity resin: analysis of human plasma and cerebrospinal fluid SO ANALYTICAL AND BIOANALYTICAL CHEMISTRY LA English DT Article DE Microscale depletion; IgY-14 immunoaffinity resin; Human plasma; Cerebrospinal fluid; MS ID BIOMARKER DISCOVERY; HUMAN SERUM; PROTEOMIC ANALYSIS; MASS-SPECTROMETRY; SHOTGUN PROTEOMICS; SAMPLE PREPARATION; IDENTIFICATION; SEPARATION; STRATEGIES; CHROMATOGRAPHY AB Removal of highly abundant proteins in plasma is often carried out using immunoaffinity depletion to extend the dynamic range of measurements to lower abundance species. While commercial depletion columns are available for this purpose, they generally are not applicable to limited sample quantities (< 20 mu L) due to low yields stemming from losses caused by nonspecific binding to the column matrix and concentration of large eluent volumes. Additionally, the cost of the depletion media can be prohibitive for larger-scale studies. Modern LC-MS instrumentation provides the sensitivity necessary to scale-down depletion methods with minimal sacrifice to proteome coverage, which makes smaller volume depletion columns desirable for maximizing sample recovery when samples are limited, as well as for reducing the expense of large-scale studies. We characterized the performance of a 346 mu L column volume microscale depletion system, using four different flow rates to determine the most effective depletion conditions for similar to 6-mu L injections of human plasma proteins and then evaluated depletion reproducibility at the optimum flow rate condition. Depletion of plasma using a commercial 10-mL depletion column served as the control. Results showed depletion efficiency of the microscale column increased as flow rate decreased, and that our microdepletion was reproducible. In an initial application, a 600-mu L sample of human cerebrospinal fluid (CSF) pooled from multiple sclerosis patients was depleted and then analyzed using reversed phase liquid chromatography-mass spectrometry to demonstrate the utility of the system for this important biofluid where sample quantities are more commonly limited. C1 [Hyung, Seok-Won; Piehowski, Paul D.; Moore, Ronald J.; Orton, Daniel J.; Schepmoes, Athena A.; Clauss, Therese R.; Chu, Rosalie K.; Fillmore, Thomas L.; Brewer, Heather; Liu, Tao; Zhao, Rui; Smith, Richard D.] Pacific NW Natl Lab, Div Biol Sci, Richland, WA 99352 USA. [Hyung, Seok-Won; Piehowski, Paul D.; Moore, Ronald J.; Orton, Daniel J.; Schepmoes, Athena A.; Clauss, Therese R.; Chu, Rosalie K.; Fillmore, Thomas L.; Brewer, Heather; Liu, Tao; Zhao, Rui; Smith, Richard D.] Pacific NW Natl Lab, Environm Mol Sci Lab, Richland, WA 99352 USA. [Hyung, Seok-Won] Korea Res Inst Stand & Sci, Taejon 305340, South Korea. RP Smith, RD (reprint author), Pacific NW Natl Lab, Div Biol Sci, Richland, WA 99352 USA. EM swhyung@kriss.re.kr; rds@pnnl.gov RI Smith, Richard/J-3664-2012; OI Smith, Richard/0000-0002-2381-2349; Piehowski, Paul/0000-0001-5108-2227 FU National Center for Research Resources [5 P41 RR018522-10]; National Institute of General Medical Sciences from National Institutes of Health [8 P41 GM103493-10]; Department of Energy Office of Biological and Environmental Research Genome Sciences Program; DOE [DE-AC05-76RLO01830] FX This project was supported by grants from the National Center for Research Resources (5 P41 RR018522-10) and the National Institute of General Medical Sciences (8 P41 GM103493-10) from the National Institutes of Health as well as the Department of Energy Office of Biological and Environmental Research Genome Sciences Program under the Pan-omics project. Work was performed in the Environmental Molecular Science Laboratory, a U.S. Department of Energy (DOE) national scientific user facility at Pacific Northwest National Laboratory (PNNL) in Richland, WA. Battelle operates PNNL for the DOE under contract DE-AC05-76RLO01830. We appreciate the favor from Jonas Bergquist at Uppsala University (Department of Chemistry-Biomedical Center, Analytical Chemistry and SciLife Lab, Uppsala, Sweden) for the donation of CSF sample. NR 54 TC 5 Z9 5 U1 2 U2 15 PU SPRINGER HEIDELBERG PI HEIDELBERG PA TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY SN 1618-2642 EI 1618-2650 J9 ANAL BIOANAL CHEM JI Anal. Bioanal. Chem. PD NOV PY 2014 VL 406 IS 28 BP 7117 EP 7125 DI 10.1007/s00216-014-8058-3 PG 9 WC Biochemical Research Methods; Chemistry, Analytical SC Biochemistry & Molecular Biology; Chemistry GA AS5OQ UT WOS:000344320300006 PM 25192788 ER PT J AU Malfatti, MA Lao, V Ramos, CL Ong, VS Turteltaub, KW AF Malfatti, Michael A. Lao, Victoria Ramos, Courtney L. Ong, Voon S. Turteltaub, Kenneth W. TI Use of Microdosing and Accelerator Mass Spectrometry To Evaluate the Pharmacokinetic Linearity of a Novel Tricyclic GyrB/ParE Inhibitor in Rats SO ANTIMICROBIAL AGENTS AND CHEMOTHERAPY LA English DT Article ID DRUG DEVELOPMENT; QUANTIFICATION; EXPERIENCE; BINDING; DNA AB Determining the pharmacokinetics (PKs) of drug candidates is essential for understanding their biological fate. The ability to obtain human PK information early in the drug development process can help determine if future development is warranted. Microdosing was developed to assess human PKs, at ultra-low doses, early in the drug development process. Microdosing has also been used in animals to confirm PK linearity across subpharmacological and pharmacological dose ranges. The current study assessed the PKs of a novel antimicrobial preclinical drug candidate (GP-4) in rats as a step toward human microdosing studies. Dose proportionality was determined at 3 proposed therapeutic doses (3, 10, and 30 mg/kg of body weight), and PK linearity between a microdose and a pharmacological dose was assessed in Sprague-Dawley rats. Plasma PKs over the 3 pharmacological doses were proportional. Over the 10-fold dose range, the maximum concentration in plasma and area under the curve (AUC) increased 9.5- and 15.8-fold, respectively. PKs from rats dosed with a C-14-labeled microdose versus a C-14-labeled pharmacological dose displayed dose linearity. In the animals receiving a microdose and the therapeutically dosed animals, the AUCs from time zero to infinity were 2.6 ng . h/ml and 1,336 ng . h/ml, respectively, and the terminal half-lives were 5.6 h and 1.4 h, respectively. When the AUC values were normalized to a dose of 1.0 mg/kg, the AUC values were 277.5 ng . h/ml for the microdose and 418.2 ng . h/ml for the pharmacological dose. This 1.5-fold difference in AUC following a 300-fold difference in dose is considered linear across the dose range. On the basis of the results, the PKs from the microdosed animals were considered to be predictive of the PKs from the therapeutically dosed animals. C1 [Malfatti, Michael A.; Lao, Victoria; Turteltaub, Kenneth W.] Lawrence Livermore Natl Lab, Biosci & Biotechnol Div, Phys & Life Sci Directorate, Livermore, CA 94550 USA. [Ramos, Courtney L.; Ong, Voon S.] Cubist Pharmaceut, San Diego, CA USA. RP Malfatti, MA (reprint author), Lawrence Livermore Natl Lab, Biosci & Biotechnol Div, Phys & Life Sci Directorate, Livermore, CA 94550 USA. EM malfatti1@llnl.gov FU U.S. DOE [DE-AC52-07NA27344]; National Institute of General Medical Sciences [8 P41 GM103483-14]; NIAID/NIH [HHSN272200800042C]; Cubist Pharmaceuticals FX This work was performed under the auspices of the U.S. DOE by Lawrence Livermore National Laboratory at the Research Resource for Biomedical AMS under contract DE-AC52-07NA27344 and was supported by grants from the National Institute of General Medical Sciences (8 P41 GM103483-14) and NIAID/NIH under contract no. HHSN272200800042C, as well as by Cubist Pharmaceuticals. NR 26 TC 2 Z9 2 U1 0 U2 5 PU AMER SOC MICROBIOLOGY PI WASHINGTON PA 1752 N ST NW, WASHINGTON, DC 20036-2904 USA SN 0066-4804 EI 1098-6596 J9 ANTIMICROB AGENTS CH JI Antimicrob. Agents Chemother. PD NOV PY 2014 VL 58 IS 11 BP 6477 EP 6483 DI 10.1128/AAC.03300-14 PG 7 WC Microbiology; Pharmacology & Pharmacy SC Microbiology; Pharmacology & Pharmacy GA AS3EF UT WOS:000344158600017 PM 25136019 ER PT J AU Kirby, J Nishimoto, M Chow, RWN Pasumarthi, VN Chan, R Chan, LJG Petzold, CJ Keasling, JD AF Kirby, James Nishimoto, Minobu Chow, Ruthie W. N. Pasumarthi, Venkata N. Chan, Rossana Chan, Leanne Jade G. Petzold, Christopher J. Keasling, Jay D. TI Use of Nonionic Surfactants for Improvement of Terpene Production in Saccharomyces cerevisiae SO APPLIED AND ENVIRONMENTAL MICROBIOLOGY LA English DT Article ID ADVANCED BIOFUELS PRODUCTION; DIRECTED EVOLUTION; SESQUITERPENE SYNTHASES; ISOPRENOID PRODUCTION; YEAST; GENES; IDENTIFICATION; EXPRESSION; MUTANTS AB To facilitate enzyme and pathway engineering, a selection was developed for improved sesquiterpene titers in Saccharomyces cerevisiae. alpha-Bisabolene, a candidate advanced biofuel, was found to protect yeast against the disruptive action of nonionic surfactants such as Tween 20 (T20). An experiment employing competition between two strains of yeast, one of which makes twice as much bisabolene as the other, demonstrated that growth in the presence of T20 provided sufficient selective pressure to enrich the high-titer strain to form 97% of the population. Following this, various methods were used to mutagenize the bisabolene synthase (BIS) coding sequence, coupled with selection by subculturing in the presence of T20. Mutagenesis targeting the BIS active site did not yield an improvement in bisabolene titers, although mutants were found which made a mixture of alpha-bisabolene and beta-farnesene, another candidate biofuel. Based on evidence that the 3' end of the BIS mRNA may be unstable in yeast, we randomly recoded the last 20 amino acids of the enzyme and, following selection in T20, found a variant which increased specific production of bisabolene by more than 30%. Since T20 could enrich a mixed population, efficiently removing strains that produced little or no bisabolene, we investigated whether it could also be applied to sustain high product titers in a monoculture for an extended period. Cultures grown in the presence of T20 for 14 days produced bisabolene at titers up to 4-fold higher than cultures grown with an overlay of dodecane, used to sequester the terpene product, and 20-fold higher than cultures grown without dodecane. C1 [Kirby, James; Nishimoto, Minobu; Chow, Ruthie W. N.; Pasumarthi, Venkata N.; Chan, Rossana; Keasling, Jay D.] Univ Calif Berkeley, Calif Inst Quantitat Biosci QB3, Berkeley, CA 94720 USA. [Kirby, James; Nishimoto, Minobu; Chan, Leanne Jade G.; Petzold, Christopher J.; Keasling, Jay D.] Joint BioEnergy Inst, Emeryville, CA USA. [Keasling, Jay D.] Univ Calif Berkeley, Dept Chem Biomol Engn, Berkeley, CA 94720 USA. [Keasling, Jay D.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Phys Biosci Div, Berkeley, CA 94720 USA. RP Keasling, JD (reprint author), Univ Calif Berkeley, Calif Inst Quantitat Biosci QB3, Berkeley, CA 94720 USA. EM keasling@berkeley.edu RI Keasling, Jay/J-9162-2012 OI Keasling, Jay/0000-0003-4170-6088 FU Office of Science, Office of Biological and Environmental Research, of the U.S. Department of Energy [DE-AC02-05CH11231]; U.S. Department of Energy ARPA-E PETRO program [DE-AR0000209] FX The work conducted through the Joint BioEnergy Institute was supported by the Office of Science, Office of Biological and Environmental Research, of the U.S. Department of Energy under contract no. DE-AC02-05CH11231. The work conducted through the University of California, Berkeley, was funded through the U.S. Department of Energy ARPA-E PETRO program, under grant no. DE-AR0000209. NR 30 TC 2 Z9 2 U1 1 U2 13 PU AMER SOC MICROBIOLOGY PI WASHINGTON PA 1752 N ST NW, WASHINGTON, DC 20036-2904 USA SN 0099-2240 EI 1098-5336 J9 APPL ENVIRON MICROB JI Appl. Environ. Microbiol. PD NOV PY 2014 VL 80 IS 21 BP 6685 EP 6693 DI 10.1128/AEM.02155-14 PG 9 WC Biotechnology & Applied Microbiology; Microbiology SC Biotechnology & Applied Microbiology; Microbiology GA AS3FA UT WOS:000344160900013 PM 25149518 ER PT J AU Schwadron, NA Moebius, E Fuselier, SA McComas, DJ Funsten, HO Janzen, P Reisenfeld, D Kucharek, H Lee, MA Fairchild, K Allegrini, F Dayeh, M Livadiotis, G Reno, M Bzowski, M Sokol, JM Kubiak, MA Christian, ER DeMajistre, R Frisch, P Galli, A Wurz, P Gruntman, M AF Schwadron, N. A. Moebius, E. Fuselier, S. A. McComas, D. J. Funsten, H. O. Janzen, P. Reisenfeld, D. Kucharek, H. Lee, M. A. Fairchild, K. Allegrini, F. Dayeh, M. Livadiotis, G. Reno, M. Bzowski, M. Sokol, J. M. Kubiak, M. A. Christian, E. R. DeMajistre, R. Frisch, P. Galli, A. Wurz, P. Gruntman, M. TI SEPARATION OF THE RIBBON FROM GLOBALLY DISTRIBUTED ENERGETIC NEUTRAL ATOM FLUX USING THE FIRST FIVE YEARS OF IBEX OBSERVATIONS SO ASTROPHYSICAL JOURNAL SUPPLEMENT SERIES LA English DT Article DE Sun: heliosphere; ISM: magnetic fields ID INTERSTELLAR-BOUNDARY-EXPLORER; PICK-UP IONS; MAGNETIC-FIELD; SOLAR-WIND; OUTER HELIOSHEATH; VOYAGER 1; ENA FLUX; HELIOPAUSE; HELIOSPHERE; PLASMA AB The Interstellar Boundary Explorer (IBEX) observes the IBEX ribbon, which stretches across much of the sky observed in energetic neutral atoms (ENAs). The ribbon covers a narrow (similar to 20 degrees-50 degrees) region that is believed to be roughly perpendicular to the interstellar magnetic field. Superimposed on the IBEX ribbon is the globally distributed flux that is controlled by the processes and properties of the heliosheath. This is a second study that utilizes a previously developed technique to separate ENA emissions in the ribbon from the globally distributed flux. A transparency mask is applied over the ribbon and regions of high emissions. We then solve for the globally distributed flux using an interpolation scheme. Previously, ribbon separation techniques were applied to the first year of IBEX-Hi data at and above 0.71 keV. Here we extend the separation analysis down to 0.2 keV and to five years of IBEX data enabling first maps of the ribbon and the globally distributed flux across the full sky of ENA emissions. Our analysis shows the broadening of the ribbon peak at energies below 0.71 keV and demonstrates the apparent deformation of the ribbon in the nose and heliotail. We show global asymmetries of the heliosheath, including both deflection of the heliotail and differing widths of the lobes, in context of the direction, draping, and compression of the heliospheric magnetic field. We discuss implications of the ribbon maps for the wide array of concepts that attempt to explain the ribbon's origin. Thus, we present the five-year separation of the IBEX ribbon from the globally distributed flux in preparation for a formal IBEX data release of ribbon and globally distributed flux maps to the heliophysics community. C1 [Schwadron, N. A.; Moebius, E.; Kucharek, H.; Lee, M. A.; Fairchild, K.] Univ New Hampshire, Durham, NH 03824 USA. [Schwadron, N. A.; Fuselier, S. A.; Allegrini, F.; Dayeh, M.; Livadiotis, G.; Reno, M.] SW Res Inst, San Antonio, TX 78228 USA. [McComas, D. J.; Funsten, H. O.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Janzen, P.; Reisenfeld, D.] Univ Montana, Missoula, MT 59812 USA. [Bzowski, M.; Sokol, J. M.; Kubiak, M. A.] Polish Acad Sci, Space Res Ctr, PL-01237 Warsaw, Poland. [Christian, E. R.] NASA, Goddard Space Flight Ctr, Greenbelt, MD 20771 USA. [DeMajistre, R.] Johns Hopkins Univ, Appl Phys Lab, Laurel, MD 20723 USA. [Frisch, P.] Univ Chicago, Chicago, IL 60637 USA. [Galli, A.; Wurz, P.] Univ Bern, Bern, Switzerland. [Gruntman, M.] Univ So Calif, Los Angeles, CA 90089 USA. [Schwadron, N. A.] Univ Texas San Antonio, San Antonio, TX 78228 USA. RP Schwadron, NA (reprint author), Univ New Hampshire, Durham, NH 03824 USA. RI Funsten, Herbert/A-5702-2015; Reisenfeld, Daniel/F-7614-2015; Gruntman, Mike/A-5426-2008; Sokol, Justyna/K-2892-2015; OI Funsten, Herbert/0000-0002-6817-1039; Gruntman, Mike/0000-0002-0830-010X; Moebius, Eberhard/0000-0002-2745-6978 FU NASA's Explorer Program; Polish National Science Centre [2012-06-M-ST9-00455] FX We are deeply indebted to all of the outstanding people who have made the IBEX mission possible. This work was carried out as a part of the IBEX project, with support from NASA's Explorer Program. J.S., M.B., and M.A.K. were supported by the Polish National Science Centre (grant 2012-06-M-ST9-00455). NR 52 TC 22 Z9 22 U1 0 U2 6 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0067-0049 EI 1538-4365 J9 ASTROPHYS J SUPPL S JI Astrophys. J. Suppl. Ser. PD NOV PY 2014 VL 215 IS 1 AR 13 DI 10.1088/0067-0049/215/1/13 PG 18 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA AS2YH UT WOS:000344141800013 ER PT J AU Trabert, E Beiersdorfer, P Brickhouse, NS Golub, L AF Traebert, Elmar Beiersdorfer, Peter Brickhouse, Nancy S. Golub, Leon TI HIGH-RESOLUTION LABORATORY SPECTRA OF THE lambda 193 CHANNEL OF THE ATMOSPHERIC IMAGING ASSEMBLY INSTRUMENT ON BOARD SOLAR DYNAMICS OBSERVATORY SO ASTROPHYSICAL JOURNAL SUPPLEMENT SERIES LA English DT Article DE atomic data; methods: laboratory: atomic; Sun: corona; Sun: UV radiation; techniques: spectroscopic ID EXTREME-ULTRAVIOLET REGION; BEAM ION-TRAP; ATOMIC DATABASE; EMISSION-LINES; GRATING SPECTROMETER; FE-VII; X-RAY; ANGSTROM; CHIANTI; ASTROPHYSICS AB Extreme ultraviolet spectra of C, O, F, Ne, S, Ar, Fe, and Ni have been excited in an electron beam ion trap and studied with much higher resolution than available on the Solar Dynamics Observatory (SDO) in order to ascertain the spectral composition of the SDO/Atmospheric Imaging Assembly (AIA) observations. We present our findings in the wavelength range 182-200 angstrom, which, overall, corroborate the working models of how to interpret the SDO/AIA data. We find, however, that the inclusion of a number of additional lines might improve the data interpretation. C1 [Traebert, Elmar; Beiersdorfer, Peter] Lawrence Livermore Natl Lab, Div Phys, Livermore, CA 94550 USA. [Traebert, Elmar] Ruhr Univ Bochum, Astron Inst, D-44780 Bochum, Germany. [Brickhouse, Nancy S.; Golub, Leon] Harvard Smithsonian Ctr Astrophys, Cambridge, MA 02138 USA. RP Trabert, E (reprint author), Lawrence Livermore Natl Lab, Div Phys, Livermore, CA 94550 USA. FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; Solar and Heliospherical Physics Program of the National Aeronautics and Space Administration [NNH10AN31I]; German Research Association (DFG) [Tr171/18, Tr171/19] FX This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344 and was supported by the Solar and Heliospherical Physics Program of the National Aeronautics and Space Administration under award NNH10AN31I. E.T. acknowledges support from the German Research Association (DFG; grants Tr171/18 and Tr171/19). NR 37 TC 4 Z9 4 U1 1 U2 6 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0067-0049 EI 1538-4365 J9 ASTROPHYS J SUPPL S JI Astrophys. J. Suppl. Ser. PD NOV PY 2014 VL 215 IS 1 AR 6 DI 10.1088/0067-0049/215/1/6 PG 8 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA AS2YH UT WOS:000344141800006 ER PT J AU Titarenko, YE Batyaev, VF Pavlov, KV Titarenko, AY Rogov, VI Zhivun, VM Kulevoy, TV Sobolevsky, NM Voloshchenko, AM Didenko, AN Polozov, SM Koldobsky, AB Alekseev, PN Fomichenko, PA Dudnikov, AA Nevinitsa, VA Sedov, AA Frolov, AA Lubina, AS Balanin, AL Subbotin, SA Subbotin, AS Stankovskiy, AY Van den Eynde, G Mashnik, SG AF Titarenko, Yu. E. Batyaev, V. F. Pavlov, K. V. Titarenko, A. Yu. Rogov, V. I. Zhivun, V. M. Kulevoy, T. V. Sobolevsky, N. M. Voloshchenko, A. M. Didenko, A. N. Polozov, S. M. Koldobsky, A. B. Alekseev, P. N. Fomichenko, P. A. Dudnikov, A. A. Nevinitsa, V. A. Sedov, A. A. Frolov, A. A. Lubina, A. S. Balanin, A. L. Subbotin, S. A. Subbotin, A. S. Stankovskiy, A. Yu. Van den Eynde, G. Mashnik, S. G. TI Analysis of the Parameters of the Target Unit of a Molten-Salt Subcritical Electronuclear Facility SO ATOMIC ENERGY LA English DT Article ID DEPOSITION AB A variant of the target unit based on tungsten rods cooled by molten-salt coolant (alkali-metal fluorides) in a subcritical electronuclear facility is examined. The results of calculations of its main parameters are presented: the neutron yield, neutron spectrum on the lateral surface, top and bottom ends of the target, total energy release, specific energy release and induced activity. The calculations are performed using the three codes MCNPX 2.6B, SHIELD and KATRIN-2.5 and the codes ORIHET3 and DCHAIN-SP for calculating the changes in the radioactivity of the main units. The discrepancies in the parameters of the target unit of a subcritical electronuclear facility were determined by calculating the standard deviation factors. Apparently, the uncertainties in the computational results for the differential and integral parameters are due to the nuclear models and libraries in the programs used. C1 [Titarenko, Yu. E.; Batyaev, V. F.; Pavlov, K. V.; Titarenko, A. Yu.; Rogov, V. I.; Zhivun, V. M.; Kulevoy, T. V.] State Sci Ctr Russian Federat, Alikhanov Inst Theoret & Expt Phys GNTs RF ITEF, Moscow, Russia. [Sobolevsky, N. M.] Russian Acad Sci IYaI RAN, Inst Nucl Res, Moscow, Russia. [Voloshchenko, A. M.] Russian Acad Sci IPM RAN, Inst Appl Math, Moscow, Russia. [Didenko, A. N.; Polozov, S. M.; Koldobsky, A. B.] Natl Nucl Res Univ, Moscow Engn Phys Inst NIYaU MIFI, Moscow, Russia. [Alekseev, P. N.; Fomichenko, P. A.; Dudnikov, A. A.; Nevinitsa, V. A.; Sedov, A. A.; Frolov, A. A.; Lubina, A. S.; Balanin, A. L.; Subbotin, S. A.; Subbotin, A. S.] Natl Res Ctr, Kurchatov Inst, Moscow, Russia. [Stankovskiy, A. Yu.; Van den Eynde, G.] Ctr Nucl Res SCK CEN, Mol, Belgium. [Mashnik, S. G.] LANL, Los Alamos, NM USA. RP Titarenko, YE (reprint author), State Sci Ctr Russian Federat, Alikhanov Inst Theoret & Expt Phys GNTs RF ITEF, Moscow, Russia. RI Balanin, Andrey/I-6896-2015; Didenko, Andrey/M-4671-2016; OI Van den Eynde, Gert/0000-0002-4728-4456 FU Ministry of Education and Science [14.516.11.0082]; National Research Center Kurchatov Institute [14.516.11.0082] FX This work was performed as part of the government contract No. 14.516.11.0082 between the Ministry of Education and Science and National Research Center Kurchatov Institute and the government contract NNSA between the US Department of Energy and the Los Alamos National Laboratory. We thank M. James, the expert in the MCNPX group, for assisting in the analysis of the results obtained. NR 20 TC 1 Z9 2 U1 0 U2 6 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1063-4258 EI 1573-8205 J9 ATOM ENERGY+ JI Atom. Energy PD NOV PY 2014 VL 117 IS 1 BP 19 EP 28 DI 10.1007/s10512-014-9882-4 PG 10 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS1WW UT WOS:000344071100004 ER PT J AU Kang, S Kahan, S McDermott, J Flann, N Shmulevich, I AF Kang, Seunghwa Kahan, Simon McDermott, Jason Flann, Nicholas Shmulevich, Ilya TI Biocellion: accelerating computer simulation of multicellular biological system models SO BIOINFORMATICS LA English DT Article ID INDUCED ANGIOGENESIS; POTTS-MODEL; CELL; MORPHOGENESIS; ENVIRONMENT; NETWORKS AB Motivation: Biological system behaviors are often the outcome of complex interactions among a large number of cells and their biotic and abiotic environment. Computational biologists attempt to understand, predict and manipulate biological system behavior through mathematical modeling and computer simulation. Discrete agent-based modeling (in combination with high-resolution grids to model the extracellular environment) is a popular approach for building biological system models. However, the computational complexity of this approach forces computational biologists to resort to coarser resolution approaches to simulate large biological systems. High-performance parallel computers have the potential to address the computing challenge, but writing efficient software for parallel computers is difficult and time-consuming. Results: We have developed Biocellion, a high-performance software framework, to solve this computing challenge using parallel computers. To support a wide range of multicellular biological system models, Biocellion asks users to provide their model specifics by filling the function body of pre-defined model routines. Using Biocellion, modelers without parallel computing expertise can efficiently exploit parallel computers with less effort than writing sequential programs from scratch. We simulate cell sorting, microbial patterning and a bacterial system in soil aggregate as case studies. C1 [Kang, Seunghwa; McDermott, Jason] Pacific NW Natl Lab, Computat Biol & Bioinformat Grp, Richland, WA 99354 USA. [Kahan, Simon] Pacific NW Natl Lab, High Performance Comp Grp, Richland, WA 99354 USA. [Flann, Nicholas] Utah State Univ, Dept Comp Sci, Logan, UT 84322 USA. [Shmulevich, Ilya] Inst Syst Biol, Seattle, WA 98109 USA. RP Kang, S (reprint author), Pacific NW Natl Lab, Computat Biol & Bioinformat Grp, Richland, WA 99354 USA. FU Extreme Scale Computing Initiative; Fundamental and Computational Sciences Directorate; Technology Investment Program, Laboratory Directed Research and Development Program at Pacific Northwest National Laboratory (PNNL); DOE [DE-ACO5-76RLO 1830] FX Support for this research was provided by the Extreme Scale Computing Initiative, the Fundamental and Computational Sciences Directorate and the Technology Investment Program, as part of the Laboratory Directed Research and Development Program at Pacific Northwest National Laboratory (PNNL). Portions of this work were conducted using PNNL Institutional Computing at PNNL. PNNL is operated by Battelle for DOE under contract DE-ACO5-76RLO 1830. NR 38 TC 6 Z9 6 U1 0 U2 9 PU OXFORD UNIV PRESS PI OXFORD PA GREAT CLARENDON ST, OXFORD OX2 6DP, ENGLAND SN 1367-4803 EI 1460-2059 J9 BIOINFORMATICS JI Bioinformatics PD NOV 1 PY 2014 VL 30 IS 21 BP 3101 EP 3108 DI 10.1093/bioinformatics/btu498 PG 8 WC Biochemical Research Methods; Biotechnology & Applied Microbiology; Computer Science, Interdisciplinary Applications; Mathematical & Computational Biology; Statistics & Probability SC Biochemistry & Molecular Biology; Biotechnology & Applied Microbiology; Computer Science; Mathematical & Computational Biology; Mathematics GA AT0SG UT WOS:000344644600015 PM 25064572 ER PT J AU Yang, Y Zhang, Y Sun, CJ Li, XS Zhang, W Ma, XH Ren, Y Zhang, X AF Yang, Ying Zhang, Ying Sun, Cheng Jun Li, Xinsong Zhang, Wen Ma, Xiaohui Ren, Yang Zhang, Xin TI Heterobimetallic Metal-Organic Framework as a Precursor to Prepare a Nickel/Nanoporous Carbon Composite Catalyst for 4-Nitrophenol Reduction SO CHEMCATCHEM LA English DT Article DE metal-organic frameworks; mesoporous materials; nickel; pyrolysis; reduction ID RAY-ABSORPTION SPECTROSCOPY; ORDERED MESOPOROUS CARBON; FACILE ROUTE FABRICATION; NANOPOROUS CARBONS; DIRECT CARBONIZATION; POROUS CARBON; SURFACE-AREA; NANOPARTICLES; NANOTUBES AB Nickel/nanoporous carbon (Ni/NPC) composites are facilely prepared by direct pyrolysis of nonporous heterobimetallic zinc-nickel-terephthalate frameworks (Zn1-xNixMOF, x approximate to 0-1, MOF= metal-organic framework) at 1223 K in situ. Tailoring the Ni/Zn ratio creates densely populated and small Ni nanocrystals (Ni NCs) while maintaining sufficient porosity and surface area in the final product, which exhibits the largest activity factor (9.2 s(-1)g(-1)) and excellent stability toward 4-nitrophenol reduction. C1 [Yang, Ying; Zhang, Ying; Li, Xinsong; Zhang, Wen; Ma, Xiaohui; Zhang, Xin] China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China. [Sun, Cheng Jun; Ren, Yang] Argonne Natl Lab, Xray Sci Div, Argonne, IL 60439 USA. RP Yang, Y (reprint author), China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China. EM catalyticscience@163.com; zhangxin@cup.edu.cn FU National Natural Science Foundation of China [21303229, 21173269]; Ministry of Science and Technology of China [2011BAK15B05]; Science Foundation of China University of Petroleum, Beijing [2462013YJRC018]; U.S. DOE [DE-AC02-06CH11357]; Shanghai Synchrotron Radiation Facility [13SRBL14B14717] FX Financial support for this research work from the National Natural Science Foundation of China (21303229, 21173269), the Ministry of Science and Technology of China (No. 2011BAK15B05), and the Science Foundation of China University of Petroleum, Beijing (2462013YJRC018) is acknowledged. PNC/XSD facilities at the Advanced Photon Source, and research at these facilities, was supported by the US Department of Energy - Basic Energy Sciences, the Canadian Light Source and its funding partners, the University of Washington, and the Advanced Photon Source. Use of the Advanced Photon Source, an Office of Science User Facility operated for the U.S. Department of Energy (DOE) Office of Science by Argonne National Laboratory, supported by the U.S. DOE under Contract No. DE-AC02-06CH11357, and the use of the Shanghai Synchrotron Radiation Facility with the support of the proposal (13SRBL14B14717) are also acknowledged. NR 39 TC 7 Z9 7 U1 18 U2 96 PU WILEY-V C H VERLAG GMBH PI WEINHEIM PA BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY SN 1867-3880 EI 1867-3899 J9 CHEMCATCHEM JI ChemCatChem PD NOV PY 2014 VL 6 IS 11 BP 3084 EP 3090 DI 10.1002/cctc.201402607 PG 7 WC Chemistry, Physical SC Chemistry GA AS5SW UT WOS:000344330800009 ER PT J AU Kim, JH Kwon, G Chun, H Kim, YT AF Kim, Jun-Hyuk Kwon, Gihan Chun, Hohwan Kim, Yong-Tae TI Enhancement of Activity and Durability through Cr Doping of TiO2 Supports in Pt Electrocatalysts for Oxygen Reduction Reactions SO CHEMCATCHEM LA English DT Article DE chromium; doping; fuel cells; platinum; titanates ID MEMBRANE FUEL-CELLS; RAY-ABSORPTION SPECTROSCOPY; DOPED TIO2; ELECTROCHEMICAL CHARACTERIZATION; PHOTOCATALYTIC ACTIVITY; CATALYST SUPPORT; DISK ELECTRODE; METAL-SURFACES; NANOPARTICLES; CARBON AB A challenging issue in the commercialization of fuel cells is to improve the kinetics of the sluggish oxygen reduction reaction (ORR) and durability of the cathode electrocatalyst under corrosive ORR conditions. In this paper, we report a promising approach to address these two major issues by Cr doping of TiO2 supports in Pt-based electrocatalysts. It was clearly revealed that Cr doping led to a marked enhancement of ORR kinetics, which was attributed to the compressive strain in the Pt lattice as well as the increased electronic conductivity of the Cr-TiO2 supports. Furthermore, Pt/Cr-TiO2 demonstrated a far superior durability to that of conventional Pt/C, which was assessed by accelerated durability tests (ADT) and in situ X-ray absorption near-edge structure studies. The specific activity of Pt/C decreased by 43% after the ADT (141 mu A cm(-2) and 82 mu A cm(-2) before and after ADT, respectively), whereas that of Pt/Cr-TiO2 was merely reduced by 13% (472 mu A cm(-2) and 409 mu A cm(-2)). C1 [Kim, Jun-Hyuk; Kim, Yong-Tae] Pusan Natl Univ, Dept Energy Syst, Pusan 609735, South Korea. [Kwon, Gihan] Argonne Natl Lab, Div Chem Sci, Argonne, IL 60439 USA. [Chun, Hohwan] Pusan Natl Univ, GCRC SOP, Pusan 609735, South Korea. RP Kim, YT (reprint author), Pusan Natl Univ, Dept Energy Syst, Pusan 609735, South Korea. EM yongtae@pusan.ac.kr RI Kim, Jun-Hyuk/G-7245-2011 OI Kim, Jun-Hyuk/0000-0003-4114-6666 FU National Research Foundation of Korea (NRF) - Korean government (MEST) [2012-0008830, NRF-2012K2A1A2032856, 2013M1A8A1040703]; National Research Foundation of Korea (NRF) - Korean government (MEST) (GCRC-SOP) FX This work was supported by a National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (2012-0008830, NRF-2012K2A1A2032856, 2013M1A8A1040703, and GCRC-SOP). NR 67 TC 3 Z9 3 U1 5 U2 48 PU WILEY-V C H VERLAG GMBH PI WEINHEIM PA POSTFACH 101161, 69451 WEINHEIM, GERMANY SN 1867-3880 EI 1867-3899 J9 CHEMCATCHEM JI ChemCatChem PD NOV PY 2014 VL 6 IS 11 BP 3239 EP 3245 DI 10.1002/cctc.201402466 PG 7 WC Chemistry, Physical SC Chemistry GA AS5SW UT WOS:000344330800031 ER PT J AU Balbus, JM Greenblatt, JB Chari, R Millstein, D Ebi, KL AF Balbus, John M. Greenblatt, Jeffery B. Chari, Ramya Millstein, Dev Ebi, Kristie L. TI A wedge-based approach to estimating health co-benefits of climate change mitigation activities in the United States SO CLIMATIC CHANGE LA English DT Article AB While it has been recognized that actions reducing greenhouse gas (GHG) emissions can have significant positive and negative impacts on human health through reductions in ambient fine particulate matter (PM2.5) concentrations, these impacts are rarely taken into account when analyzing specific policies. This study presents a new framework for estimating the change in health outcomes resulting from implementation of specific carbon dioxide (CO2) reduction activities, allowing comparison of different sectors and options for climate mitigation activities. Our estimates suggest that in the year 2020, the reductions in adverse health outcomes from lessened exposure to PM2.5 would yield economic benefits in the range of $6 to $30 billion (in 2008 USD), depending on the specific activity. This equates to between $40 and $198 per metric ton of CO2 in health benefits. Specific climate interventions will vary in the health co-benefits they provide as well as in potential harms that may result from their implementation. Rigorous assessment of these health impacts is essential for guiding policy decisions as efforts to reduce GHG emissions increase in scope and intensity. C1 [Balbus, John M.] NIEHS, Bethesda, MD 20892 USA. [Greenblatt, Jeffery B.; Millstein, Dev] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. [Chari, Ramya] RAND Corp, Santa Monica, CA USA. [Ebi, Kristie L.] Univ Washington, Seattle, WA 98195 USA. RP Balbus, JM (reprint author), NIEHS, 31 Ctr Dr,Room B1C02, Bethesda, MD 20892 USA. EM john.balbus@nih.gov FU U.S. Department of Energy [DE-AC02-05CH11231] FX This research was supported in part by Laboratory Directed Research and Development funding at the Lawrence Berkeley National Laboratory (LBNL), which is operated for U.S. Department of Energy under Contract Grant No. DE-AC02-05CH11231. NR 19 TC 2 Z9 2 U1 3 U2 20 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0165-0009 EI 1573-1480 J9 CLIMATIC CHANGE JI Clim. Change PD NOV PY 2014 VL 127 IS 2 BP 199 EP 210 DI 10.1007/s10584-014-1262-5 PG 12 WC Environmental Sciences; Meteorology & Atmospheric Sciences SC Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences GA AS6QG UT WOS:000344387000004 ER PT J AU Darling, RM Gallagher, KG Kowalski, JA Ha, S Brushett, FR AF Darling, Robert M. Gallagher, Kevin G. Kowalski, Jeffrey A. Ha, Seungbum Brushett, Fikile R. TI Pathways to low-cost electrochemical energy storage: a comparison of aqueous and nonaqueous flow batteries SO ENERGY & ENVIRONMENTAL SCIENCE LA English DT Article ID RESEARCH-AND-DEVELOPMENT; IONIC-CONDUCTIVITY; ELECTRIC VEHICLES; REDOX; ELECTROLYTES; MEMBRANES; PERSPECTIVE; PROGRESS; COUPLES AB Energy storage is increasingly seen as a valuable asset for electricity grids composed of high fractions of intermittent sources, such as wind power or, in developing economies, unreliable generation and transmission services. However, the potential of batteries to meet the stringent cost and durability requirements for grid applications is largely unquantified. We investigate electrochemical systems capable of economically storing energy for hours and present an analysis of the relationships among technological performance characteristics, component cost factors, and system price for established and conceptual aqueous and nonaqueous batteries. We identified potential advantages of nonaqueous flow batteries over those based on aqueous electrolytes; however, new challenging constraints burden the nonaqueous approach, including the solubility of the active material in the electrolyte. Requirements in harmony with economically effective energy storage are derived for aqueous and nonaqueous systems. The attributes of flow batteries are compared to those of aqueous and nonaqueous enclosed and hybrid (semi-flow) batteries. Flow batteries are a promising technology for reaching these challenging energy storage targets owing to their independent power and energy scaling, reliance on facile and reversible reactants, and potentially simpler manufacture as compared to established enclosed batteries such as lead-acid or lithium-ion. C1 [Darling, Robert M.; Gallagher, Kevin G.; Kowalski, Jeffrey A.; Ha, Seungbum; Brushett, Fikile R.] Joint Ctr Energy Storage Res, Argonne, IL 60439 USA. [Darling, Robert M.] United Technol Res Ctr, E Hartford, CT 06108 USA. [Gallagher, Kevin G.; Ha, Seungbum] Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA. [Kowalski, Jeffrey A.; Brushett, Fikile R.] MIT, Dept Chem Engn, Cambridge, MA 02139 USA. RP Darling, RM (reprint author), Joint Ctr Energy Storage Res, Argonne, IL 60439 USA. EM darlinrm@utrc.utc.com; kevin.gallagher@anl.gov FU Joint Center for Energy Storage Research, an Energy Innovation Hub - U.S. Department of Energy, Office of Science, Basic Energy Sciences; U.S. Department of Energy Office of Science laboratory [DE-AC02-06CH11357] FX This work was supported as part of the Joint Center for Energy Storage Research, an Energy Innovation Hub funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences. The submitted manuscript has been created by UChicago Argonne, LLC, Operator of Argonne National Laboratory ("Argonne"). Argonne, a U.S. Department of Energy Office of Science laboratory, is operated under Contract no. DE-AC02-06CH11357. NR 87 TC 81 Z9 81 U1 22 U2 171 PU ROYAL SOC CHEMISTRY PI CAMBRIDGE PA THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND SN 1754-5692 EI 1754-5706 J9 ENERG ENVIRON SCI JI Energy Environ. Sci. PD NOV PY 2014 VL 7 IS 11 BP 3459 EP 3477 DI 10.1039/c4ee02158d PG 19 WC Chemistry, Multidisciplinary; Energy & Fuels; Engineering, Chemical; Environmental Sciences SC Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology GA AS0NR UT WOS:000343974700002 ER PT J AU Eisler, CN Abrams, ZR Sheldon, MT Zhang, X Atwater, HA AF Eisler, Carissa N. Abrams, Ze'ev R. Sheldon, Matthew T. Zhang, Xiang Atwater, Harry A. TI Multijunction solar cell efficiencies: effect of spectral window, optical environment and radiative coupling SO ENERGY & ENVIRONMENTAL SCIENCE LA English DT Article ID DETAILED BALANCE LIMIT; ENERGY-CONVERSION; SYSTEMS; PHOTOVOLTAICS AB Solar cell efficiency is maximized through multijunction architectures that minimize carrier thermalization and increase absorption. Previous proposals suggest that the maximum efficiency for a finite number of subcells is achieved for designs that optimize for light trapping over radiative coupling. We instead show that structures with radiative coupling and back reflectors for light trapping, e.g. spectrum-splitting cells, can achieve higher conversion efficiencies. We model a compatible geometry, the polyhedral specular reflector. We analyze and experimentally verify the effects of spectral window and radiative coupling on voltage and power. Our results indicate that radiative coupling with back reflectors leads to higher efficiencies than previously studied architectures for practical multijunction architectures (i.e., <= 20 subcells). C1 [Eisler, Carissa N.; Sheldon, Matthew T.; Atwater, Harry A.] CALTECH, Thomas J Watson Labs Appl Phys, Pasadena, CA 91125 USA. [Abrams, Ze'ev R.; Zhang, Xiang] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA. [Zhang, Xiang] King Abdulaziz Univ, Dept Phys, Jeddah 21589, Saudi Arabia. [Zhang, Xiang] Univ Calif Berkeley, Kavli Energy NanoSci Inst, Berkeley, CA 94704 USA. [Zhang, Xiang] Lawrence Berkeley Natl Lab, Berkeley, CA 94704 USA. RP Eisler, CN (reprint author), CALTECH, Thomas J Watson Labs Appl Phys, Pasadena, CA 91125 USA. EM haa@caltech.edu RI Zhang, Xiang/F-6905-2011 FU U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001293]; Department of Defense (DoD) through the National Defense Science & Engineering Graduate Fellowship (NDSEG) Program FX This work is part of the 'Light-Material Interactions in Energy Conversion' Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0001293. C. N. Eisler was supported by the Department of Defense (DoD) through the National Defense Science & Engineering Graduate Fellowship (NDSEG) Program. The authors wish to thank E. Kosten and E. Warmann for invaluable discussion as well as B. Kayes and Alta Devices for providing the GaAs cells used in this study. NR 34 TC 9 Z9 9 U1 2 U2 26 PU ROYAL SOC CHEMISTRY PI CAMBRIDGE PA THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND SN 1754-5692 EI 1754-5706 J9 ENERG ENVIRON SCI JI Energy Environ. Sci. PD NOV PY 2014 VL 7 IS 11 BP 3600 EP 3605 DI 10.1039/c4ee01060d PG 6 WC Chemistry, Multidisciplinary; Energy & Fuels; Engineering, Chemical; Environmental Sciences SC Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology GA AS0NR UT WOS:000343974700008 ER PT J AU Liu, TB DuBois, MR DuBois, DL Bullock, RM AF Liu, Tianbiao DuBois, Mary Rakowski DuBois, Daniel L. Bullock, R. Morris TI Electrochemical oxidation of H-2 catalyzed by ruthenium hydride complexes bearing P2N2 ligands with pendant amines as proton relays SO ENERGY & ENVIRONMENTAL SCIENCE LA English DT Article ID 2ND COORDINATION SPHERE; DOT CENTER DOT; DIHYDROGEN COMPLEXES; CRYSTAL-STRUCTURE; MOLECULAR CATALYSTS; ACTIVE-SITE; ELECTROCATALYTIC OXIDATION; HYDROGEN OXIDATION; IRON HYDROGENASE; ORGANOMETALLIC CHEMISTRY AB Two Ru hydride complexes, Cp*Ru((P2N2Bn)-N-Ph)H (1-H) and Cp*Ru((Pt2N2Bn)-N-Bu)H (2-H) supported by cyclic (P2N2R')-N-R ligands (Cp* = eta(5)- C5Me5; (P2N2Bn)-N-R = 1,5-dibenzyl,-3,7-R-1,5-diaza-3,7-diphosphacyclooctane, where R = Ph or Bu-t) have been developed as electrocatalysts for oxidation of H-2 (1.0 atm, 22 degrees C). The turnover frequency of 2-H is 1.2 s(-1) at 22 degrees C (1.0 atm H-2) with an overpotential at E-cat/2 of 0.5 V in the presence of exogenous base, DBU (1,8-diazabicyclo[5.4.0] undec-7-ene), while catalysis by 1-H has a turnover frequency of 0.6 s(-1) and an overpotential of 0.6 V at Ecat/2. Addition of H2O facilitates oxidation of H-2 by 2-H and increases its turnover frequency to 1.9 s(,)(-1) while H2O slows down the catalysis by 1-H. In addition, studies of Cp* Ru(dmpm) H (where dmpm = bis(dimethylphosphino) methane), a control complex lacking pendent amines in its diphosphine ligand, confirms the critical roles of the pendant amines of the P2N2 ligands as proton relays in the oxidation of H-2. C1 [Liu, Tianbiao; DuBois, Mary Rakowski; DuBois, Daniel L.; Bullock, R. Morris] Pacific NW Natl Lab, Ctr Mol Electrocataysis, Div Phys Sci, Richland, WA 99352 USA. RP Liu, TB (reprint author), Pacific NW Natl Lab, Ctr Mol Electrocataysis, Div Phys Sci, POB 999,K2-57, Richland, WA 99352 USA. EM tianbiao.liu@pnnl.gov; morris.bullock@pnnl.gov RI Liu, Tianbiao/A-3390-2011; Bullock, R. Morris/L-6802-2016 OI Bullock, R. Morris/0000-0001-6306-4851 FU U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences; Center for Molecular Electrocatalysis, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences FX We thank the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences, for supporting initial parts of the work. Current work is supported by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy. NR 75 TC 8 Z9 8 U1 6 U2 38 PU ROYAL SOC CHEMISTRY PI CAMBRIDGE PA THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND SN 1754-5692 EI 1754-5706 J9 ENERG ENVIRON SCI JI Energy Environ. Sci. PD NOV PY 2014 VL 7 IS 11 BP 3630 EP 3639 DI 10.1039/c4ee01262c PG 10 WC Chemistry, Multidisciplinary; Energy & Fuels; Engineering, Chemical; Environmental Sciences SC Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology GA AS0NR UT WOS:000343974700012 ER PT J AU Gu, Y Wang, C Liu, F Chen, JH Dyck, OE Duscher, G Russell, TP AF Gu, Yu Wang, Cheng Liu, Feng Chen, Jihua Dyck, Ondrej E. Duscher, Gerd Russell, Thomas P. TI Guided crystallization of P3HT in ternary blend solar cell based on P3HT:PCPDTBT:PCBM SO ENERGY & ENVIRONMENTAL SCIENCE LA English DT Article ID ORGANIC PHOTOVOLTAIC DEVICES; POLYMER CRYSTALLIZATION; SEMICONDUCTING POLYMER; BANDGAP POLYMER; TANDEM POLYMER; SENSITIZATION; OPTIMIZATION; PERFORMANCE; FILMS AB To mimic the performance of the tandem solar cells, ternary blend solar cells with a single active layer of P3HT: PCPDTBT: PC61BM were cast from chlorobenzene and thermally annealed. By varying blending ratio, thermal annealing time and P3HT molecular weight, the device performance was enhanced relative to the binary references. To understand this, the morphology of the active layer was studied using hard and soft X-ray scattering methods in concert with bright field and energy resolved transmission electron microscopies. We found that the phase separation of the amorphous PCPDTBT and P3HT guided the formation of P3HT fibrils, resulting in a unique multi-length-scale morphology. This morphology consisted of bundles of well-defined P3HT fibrils, forming a network, imbedded in an amorphous mixture of the PCBM, PCPDTBT and P3HT. The two polymers acted independently in their specific photoactive ranges, and the sensitization of PCPDTBT benefited the cascade charge transfer. This multi-length-scale morphology was linked to the improved device performance of P3HT: PCPDTBT: PC61BM and the photophysics of the active layer. C1 [Gu, Yu; Liu, Feng; Russell, Thomas P.] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA. [Wang, Cheng] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA. [Chen, Jihua] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA. [Dyck, Ondrej E.; Duscher, Gerd] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA. RP Gu, Y (reprint author), Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA. EM russell@mail.pse.umass.edu RI Chen, Jihua/F-1417-2011; Dyck, Ondrej/A-3294-2016; Duscher, Gerd/G-1730-2014; Wang, Cheng/A-9815-2014; Liu, Feng/J-4361-2014 OI Chen, Jihua/0000-0001-6879-5936; Dyck, Ondrej/0000-0001-8200-9874; Duscher, Gerd/0000-0002-2039-548X; Liu, Feng/0000-0002-5572-8512 FU Department of Energy; Energy Frontier Research Center at the University of Massachusetts [DE-SC0001087]; Advanced Light Source; Lawrence Berkeley National Laboratory; DOE; Office of Science; Office of Basic Energy Sciences; Oak Ridge National Laboratory by the Division of Scientific User Facilities, Office of Basic Energy Sciences, U.S. Department of Energy FX This work was supported by the Department of Energy supported Energy Frontier Research Center at the University of Massachusetts under contract DE-SC0001087. We thank Anthony Young for assisting P-RSoXS measurements at 11.0.1.2, ALS, LBNL. Portions of this research were carried out and supported by the Advanced Light Source, Lawrence Berkeley National Laboratory, which was supported by the DOE, Office of Science, and Office of Basic Energy Sciences. A portion of this research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Division of Scientific User Facilities, Office of Basic Energy Sciences, U.S. Department of Energy. We also thank Kurashiki Research Center in Kuraray Co. Ltd, Japan, for providing P3HT-28k. NR 38 TC 26 Z9 26 U1 7 U2 83 PU ROYAL SOC CHEMISTRY PI CAMBRIDGE PA THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND SN 1754-5692 EI 1754-5706 J9 ENERG ENVIRON SCI JI Energy Environ. Sci. PD NOV PY 2014 VL 7 IS 11 BP 3782 EP 3790 DI 10.1039/c4ee02004a PG 9 WC Chemistry, Multidisciplinary; Energy & Fuels; Engineering, Chemical; Environmental Sciences SC Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology GA AS0NR UT WOS:000343974700028 ER PT J AU Burroughs, NJ Boehm, M Eckert, C Mastroianni, G Spence, EM Yu, JF Nixon, PJ Appel, J Mullineaux, CW Bryan, SJ AF Burroughs, Nigel J. Boehm, Marko Eckert, Carrie Mastroianni, Giulia Spence, Edward M. Yu, Jianfeng Nixon, Peter J. Appel, Jens Mullineaux, Conrad W. Bryan, Samantha J. TI Solar powered biohydrogen production requires specific localization of the hydrogenase SO ENERGY & ENVIRONMENTAL SCIENCE LA English DT Article ID SP PCC 6803; CYANOBACTERIUM SYNECHOCYSTIS PCC6803; BIDIRECTIONAL HYDROGENASE; NDH-1 COMPLEXES; SP PCC-6803; ELECTRON-TRANSPORT; NIFE HYDROGENASES; SUBUNIT; PROTEIN; GENE AB Cyanobacteria contain a bidirectional [NiFe] hydrogenase which transiently produces hydrogen upon exposure of anoxic cells to light, potentially acting as a "valve" releasing excess electrons from the electron transport chain. However, its interaction with the photosynthetic electron transport chain remains unclear. By GFP-tagging the HoxF diaphorase subunit we show that the hydrogenase is thylakoid associated, comprising a population dispersed uniformly through the thylakoids and a subpopulation localized to discrete puncta in the distal thylakoid. Thylakoid localisation of both the HoxH and HoxY hydrogenase subunits is confirmed by immunogold electron microscopy. The diaphorase HoxE subunit is essential for recruitment to the dispersed thylakoid population, potentially anchoring the hydrogenase to the membrane, but aggregation to puncta occurs through a distinct HoxE-independent mechanism. Membrane association does not require NDH-1. Localization is dynamic on a scale of minutes, with anoxia and high light inducing a significant redistribution between these populations in favour of puncta. Since HoxE is essential for access to its electron donor, electron supply to the hydrogenase depends on a physiologically controlled localization, potentially offering a new avenue to enhance photosynthetic hydrogen production by exploiting localization/aggregation signals. C1 [Burroughs, Nigel J.] Univ Warwick, Syst Biol Ctr, Coventry CV4 7AL, W Midlands, England. [Boehm, Marko; Yu, Jianfeng; Nixon, Peter J.] Univ London Imperial Coll Sci Technol & Med, London SW7 2AZ, England. [Eckert, Carrie] Natl Renewable Energy Lab, Biosci Ctr, Golden, CO 80401 USA. [Eckert, Carrie] Univ Colorado, Renewable & Sustainable Energy Inst, Boulder, CO 80309 USA. [Mastroianni, Giulia; Mullineaux, Conrad W.; Bryan, Samantha J.] Queen Mary Univ London, Sch Biol & Chem Sci, London E1 4NS, England. [Spence, Edward M.] Kings Coll London, Div Pharmaceut Sci, London SE1 9NH, England. [Appel, Jens] Univ Kiel, Inst Bot, D-24118 Kiel, Germany. RP Burroughs, NJ (reprint author), Univ Warwick, Syst Biol Ctr, Coventry House, Coventry CV4 7AL, W Midlands, England. EM samantha_bryan@hotmail.co.uk FU BBSRC [BB/G021856/1]; U.S. DoE, Biological and Environmental Research Program; U.S. DoE Fuel Cell Technologies Office [DE-AC36-08-GO28308]; EPSRC [EP/F00270X/1] FX This work was supported by BBSRC Grant (BB/G021856/1) to SJB, PJN and CWM. We acknowledge support from the U.S. DoE, Biological and Environmental Research Program to MB, the U.S. DoE Fuel Cell Technologies Office (contract number DE-AC36-08-GO28308) to CAE and EPSRC (EP/F00270X/1) to MB and PJN. NR 37 TC 3 Z9 3 U1 4 U2 30 PU ROYAL SOC CHEMISTRY PI CAMBRIDGE PA THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND SN 1754-5692 EI 1754-5706 J9 ENERG ENVIRON SCI JI Energy Environ. Sci. PD NOV PY 2014 VL 7 IS 11 BP 3791 EP 3800 DI 10.1039/c4ee02502d PG 10 WC Chemistry, Multidisciplinary; Energy & Fuels; Engineering, Chemical; Environmental Sciences SC Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology GA AS0NR UT WOS:000343974700029 PM 26339289 ER PT J AU Steinzig, M Upshaw, D Rasty, J AF Steinzig, M. Upshaw, D. Rasty, J. TI Influence of Drilling Parameters on the Accuracy of Hole-drilling Residual Stress Measurements SO EXPERIMENTAL MECHANICS LA English DT Article DE Residual stress; Residual stress measurement; Centre hole drilling method; ESPI ID LASER SPECKLE INTERFEROMETRY AB Multiple measurements using the hole drilling method were made in samples with a "known" state of residual stress. Drilling parameters were independently varied (bit rotation speed, bit diameter, and hole depth) to determine the effect on accuracy and repeatability. The study showed that accurate results can be achieved without ultra-high drill rotation speeds and that, in aluminum and stainless steel, speeds over 5 krpm and 10 krpm (respectively) were sufficient. Inaccuracies were evident in the stainless steel at speeds below 10 krpm and were attributed to non-circular holes, which may have been the result of bit vibration. There were no significant trends associated with altering the hole depth and only a slight trend associated with bit diameter variation. C1 [Steinzig, M.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Upshaw, D.; Rasty, J.] Texas Tech Univ, ME Dept, Lubbock, TX 79409 USA. RP Steinzig, M (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. EM dupshaw@slb.com OI Upshaw, David/0000-0003-1440-3380 NR 15 TC 2 Z9 2 U1 0 U2 22 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0014-4851 EI 1741-2765 J9 EXP MECH JI Exp. Mech. PD NOV PY 2014 VL 54 IS 9 BP 1537 EP 1543 DI 10.1007/s11340-014-9923-x PG 7 WC Materials Science, Multidisciplinary; Mechanics; Materials Science, Characterization & Testing SC Materials Science; Mechanics GA AS3BC UT WOS:000344149800004 ER PT J AU Xiong, Y Coradetti, ST Li, X Gritsenko, MA Clauss, T Petyuk, V Camp, D Smith, R Cate, JHD Yang, F Glass, NL AF Xiong, Yi Coradetti, Samuel T. Li, Xin Gritsenko, Marina A. Clauss, Therese Petyuk, Vlad Camp, David Smith, Richard Cate, Jamie H. D. Yang, Feng Glass, N. Louise TI The proteome and phosphoproteome of Neurospora crassa in response to cellulose, sucrose and carbon starvation SO FUNGAL GENETICS AND BIOLOGY LA English DT Article DE Neurospora crassa; Proteome; Phosphoproteome; Cellulase; Carbon starvation; Plant biomass ID JECORINA TRICHODERMA-REESEI; CELL-GROWTH CONTROL; GENE-EXPRESSION; SACCHAROMYCES-CEREVISIAE; HYPOCREA-JECORINA; ASPERGILLUS-NIGER; TRANSCRIPTIONAL REGULATOR; ENDOPLASMIC-RETICULUM; ENCODING GENES; MESSENGER-RNA AB Improving cellulolytic enzyme production by plant biomass degrading fungi holds great potential in reducing costs associated with production of next-generation biofuels generated from lignocellulose. How fungi sense cellulosic materials and respond by secreting enzymes has mainly been examined by assessing function of transcriptional regulators and via transcriptional profiling. Here, we obtained global proteomic and phosphoproteomic profiles of the plant biomass degrading filamentous fungus Neurospora crassa grown on different carbon sources, i.e. sucrose, no carbon, and cellulose, by performing isobaric tags for relative and absolute quantification (iTRAQ)-based LC-MS/MS analyses. A comparison between proteomes and transcriptomes under identical carbon conditions suggests that extensive post-transcriptional regulation occurs in N. crassa in response to exposure to cellulosic material. Several hundred amino acid residues with differential phosphorylation levels on crystalline cellulose (Avicel) or carbon-free medium vs sucrose medium were identified, including phosphorylation sites in a major transcriptional activator for cellulase genes, CLRI, as well as a cellobionic acid transporter, CBTI. Mutation of phosphorylation sites on CLR1 did not have a major effect on transactivation of cellulase production, while mutation of phosphorylation sites in CBT1 increased its transporting capacity. Our data provides rich information at both the protein and phosphorylation levels of the early cellular responses to carbon starvation and cellulosic induction and aids in a greater understanding of the underlying post-transcriptional regulatory mechanisms in filamentous fungi. (C) 2014 Elsevier Inc. All rights reserved. C1 [Xiong, Yi; Coradetti, Samuel T.; Glass, N. Louise] Univ Calif Berkeley, Dept Plant & Microbial Biol, Berkeley, CA 94720 USA. [Gritsenko, Marina A.; Clauss, Therese; Petyuk, Vlad; Camp, David; Smith, Richard; Yang, Feng] Pacific NW Natl Lab, Richland, WA 99352 USA. [Li, Xin] Univ Calif Berkeley, Calif Inst Quantitat Biosci, Berkeley, CA 94720 USA. [Cate, Jamie H. D.] Univ Calif Berkeley, Dept Mol & Cell Biol, Berkeley, CA 94720 USA. [Cate, Jamie H. D.] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA. RP Glass, NL (reprint author), Univ Calif Berkeley, Dept Plant & Microbial Biol, 341 Koshland Hall, Berkeley, CA 94720 USA. EM Lglass@berkeley.edu OI Petyuk, Vladislav/0000-0003-4076-151X FU Energy Biosciences Institute; U.S. Department of Energy (DOE) Office of Biological and Environmental Research (OBER) Pan-omics program at Pacific Northwest National Laboratory (PNNL); DOE [DE-AC05-76RL01830]; [P41GM103493] FX This work was funded by Grants from the Energy Biosciences Institute to N.L.G. and to J.H.D.C. The authors also acknowledge the partial funding support from P41GM103493 (to R.D.S.) for the proteomics and phosphoproteomics analyses. Portions of this project were supported by the U.S. Department of Energy (DOE) Office of Biological and Environmental Research (OBER) Pan-omics program at Pacific Northwest National Laboratory (PNNL) and performed in the Environmental Molecular Sciences Laboratory (EMSL), a U.S. Department of Energy (DOE) OBER national scientific user facility located at PNNL in Richland, Washington. PNNL is a multi-program national laboratory operated by Battelle Memorial Institute for the DOE under Contract DE-AC05-76RL01830. NR 68 TC 18 Z9 20 U1 6 U2 50 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 1087-1845 EI 1096-0937 J9 FUNGAL GENET BIOL JI Fungal Genet. Biol. PD NOV PY 2014 VL 72 SI SI BP 21 EP 33 DI 10.1016/j.fgb.2014.05.005 PG 13 WC Genetics & Heredity; Mycology SC Genetics & Heredity; Mycology GA AS3WU UT WOS:000344206800004 PM 24881580 ER PT J AU Ohm, RA Riley, R Salamov, A Min, B Choi, IG Grigoriev, IV AF Ohm, Robin A. Riley, Robert Salamov, Asaf Min, Byoungnam Choi, In-Geol Grigoriev, Igor V. TI Genomics of wood-degrading fungi SO FUNGAL GENETICS AND BIOLOGY LA English DT Article DE Fungal genomics; Agaricomycetes; Wood decay; Sequencing; Comparative genomics; Lignocellulose degradation ID HYGROMYCIN-B RESISTANCE; SCHIZOPHYLLUM-COMMUNE; PHANEROCHAETE-CARNOSA; COPRINOPSIS-CINEREA; OMPHALOTUS-OLEARIUS; MUSHROOM FORMATION; ARMILLARIA-MELLEA; MASS-SPECTROMETRY; ENZYME-ACTIVITY; DECAY FUNGI AB Woody plants convert the energy of the sun into lignocellulosic biomass, which is an abundant substrate for bioenergy production. Fungi, especially wood decayers from the class Agaricomycetes, have evolved ways to degrade lignocellulose into its monomeric constituents, and understanding this process may facilitate the development of biofuels. Over the past decade genomics has become a powerful tool to study the Agaricomycetes. In 2004 the first sequenced genome of the white rot fungus Phanerochaete chrysosporium revealed a rich catalog of lignocellulolytic enzymes. In the decade that followed the number of genomes of Agaricomycetes grew to more than 75 and revealed a diversity of wood-decaying strategies. New technologies for high-throughput functional genomics are now needed to further study these organisms. (C) 2014 Elsevier Inc. All rights reserved. C1 [Ohm, Robin A.; Riley, Robert; Salamov, Asaf; Min, Byoungnam; Choi, In-Geol; Grigoriev, Igor V.] US DOE, Joint Genome Inst, Walnut Creek, CA 94598 USA. [Min, Byoungnam; Choi, In-Geol] Korea Univ, Computat & Synthet Biol Lab, Coll Life Sci & Biotechnol, Seoul 136713, South Korea. RP Ohm, RA (reprint author), US DOE, Joint Genome Inst, 2800 Mitchell Dr, Walnut Creek, CA 94598 USA. EM raohm@lbl.gov; ivgrigoriev@lbl.gov RI Choi, In-Geol/F-3152-2013; Ohm, Robin/I-6689-2016 FU Office of Science of the U.S. Department of Energy [DE-AC02-05CH11231] FX The work conducted by the U.S. Department of Energy Joint Genome Institute is supported by the Office of Science of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. NR 91 TC 20 Z9 22 U1 5 U2 64 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 1087-1845 EI 1096-0937 J9 FUNGAL GENET BIOL JI Fungal Genet. Biol. PD NOV PY 2014 VL 72 SI SI BP 82 EP 90 DI 10.1016/j.fgb.2014.05.001 PG 9 WC Genetics & Heredity; Mycology SC Genetics & Heredity; Mycology GA AS3WU UT WOS:000344206800009 PM 24853079 ER PT J AU Qu, Y Feng, J Deng, S Cao, L Zhang, QB Zhao, R Zhang, ZR Jiang, YX Zink, EM Baker, SE Lipton, MS Pasa-Tolic, L Hu, JZ Wu, S AF Qu, Yi Feng, Ju Deng, Shuang Cao, Li Zhang, Qibin Zhao, Rui Zhang, Zhaorui Jiang, Yuxuan Zink, Erika M. Baker, Scott E. Lipton, Mary S. Pasa-Tolic, Ljiljana Hu, Jian Zhi Wu, Si TI Structural analysis of N- and O-glycans using ZIC-HILIC/dialysis coupled to NMR detection SO FUNGAL GENETICS AND BIOLOGY LA English DT Article DE ZIC-HILIC; Dialysis; Glycan; NMR; Secretome; A. niger ID ASPERGILLUS-NIGER; PROTEIN GLYCOSYLATION; POSTTRANSLATIONAL MODIFICATIONS; GLYCOPROTEIN STRUCTURE; H-1-NMR SPECTROSCOPY; LINKED GLYCOPEPTIDE; PROTEOMIC ANALYSIS; OLIGOSACCHARIDES; CHROMATOGRAPHY; SEPARATION AB Protein glycosylation, an important and complex post-translational modification (PTM), is involved in various biological processes, including the receptor-ligand and cell-cell interaction, and plays a crucial role in many biological functions. However, little is known about the glycan structures of important biological complex samples, and the conventional glycan enrichment strategy (i.e., size-exclusion column [SEC] separation) prior to nuclear magnetic resonance (NMR) detection is time-consuming and tedious. In this study, we developed a glycan enrichment strategy that couples Zwitterionic hydrophilic interaction liquid chromatography (ZIC-HILIC) with dialysis to enrich the glycans from the pronase E digests of RNase B, followed by NMR analysis of the glycoconjugate. Our results suggest that the ZIC-HILIC enrichment coupled with dialysis is a simple, fast, and efficient sample preparation approach. The approach was thus applied to analysis of a biological complex sample, the pronase E digest of the secreted proteins from the fungus Aspergillus niger. The NMR spectra revealed that the secreted proteins from A. niger contain both N-linked glycans with a high-mannose core similar to the structure of the glycan from RNase B, and O-linked glycans bearing mannose and glucose with 1 -> 3 and 1 -> 6 linkages. In all, our study provides compelling evidence that ZIC-HILIC separation coupled with dialysis is very effective and accessible in preparing glycans for the downstream NMR analysis, which could greatly facilitate the future NMR-based glycoproteomics research. (C) 2014 Elsevier Inc. All rights reserved. C1 [Qu, Yi; Feng, Ju; Cao, Li; Zhang, Qibin; Zink, Erika M.; Lipton, Mary S.; Hu, Jian Zhi] Pacific NW Natl Lab, Fundamental & Computat Sci Directorate, Richland, WA 99352 USA. [Zhao, Rui; Zhang, Zhaorui; Jiang, Yuxuan; Baker, Scott E.; Pasa-Tolic, Ljiljana; Wu, Si] Pacific NW Natl Lab, Environm Mol Sci Lab, Richland, WA 99352 USA. [Deng, Shuang] Pacific NW Natl Lab, Energy & Environm Directorate, Richland, WA 99352 USA. RP Wu, S (reprint author), Pacific NW Natl Lab, Environm Mol Sci Lab, POB 999,MS K8-98, Richland, WA 99352 USA. EM Si.Wu@pnnl.gov RI Hu, Jian Zhi/F-7126-2012; Zhang, Zhaorui/C-3478-2016; Lipton, Mary/H-3913-2012; OI Zhang, Zhaorui/0000-0001-7406-0370; Feng, Ju/0000-0001-5251-2401 FU EMSL intramural research projects; EMSL capability development projects; U.S. Department of Energy Office of Biological and Environmental Research (DOE-BER) Genome Sciences Program under the Pan-omics Project; National Institute of Environmental Health Sciences of the National Institutes of Health (NIH) [R01ES022176]; DOE-BER; DOE [DE-AC05-76RL01830] FX We thank Dr. Ziyu Dai for providing relevant protocols. We also thank anonymous reviewers for their helpful comments to improve the manuscript. Portions of this work were supported by funds from EMSL intramural research projects and EMSL capability development projects, the U.S. Department of Energy Office of Biological and Environmental Research (DOE-BER) Genome Sciences Program under the Pan-omics Project, and the National Institute of Environmental Health Sciences of the National Institutes of Health (NIH) under Award Number R01ES022176. The work was performed at EMSL, a national scientific user facility sponsored by DOE-BER and located at Pacific Northwest National Laboratory (PNNL). PNNL is a multi-program national laboratory operated by Battelle for DOE under Contract DE-AC05-76RL01830. NR 51 TC 3 Z9 3 U1 2 U2 30 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 1087-1845 EI 1096-0937 J9 FUNGAL GENET BIOL JI Fungal Genet. Biol. PD NOV PY 2014 VL 72 SI SI BP 207 EP 215 DI 10.1016/j.fgb.2014.08.001 PG 9 WC Genetics & Heredity; Mycology SC Genetics & Heredity; Mycology GA AS3WU UT WOS:000344206800023 PM 25117693 ER PT J AU Sabau, AS Ohriner, EK Kiggans, J Schaich, CR Ueda, Y Harper, DC Katoh, Y Snead, LL AF Sabau, Adrian S. Ohriner, Evan K. Kiggans, Jim Schaich, Charles R. Ueda, Yoshio Harper, David C. Katoh, Yutai Snead, Lance L. TI HIGH-HEAT-FLUX TESTING OF IRRADIATED TUNGSTEN-BASED MATERIALS FOR FUSION APPLICATIONS USING INFRARED PLASMA ARC LAMPS SO FUSION SCIENCE AND TECHNOLOGY LA English DT Article DE high-heat-flux testing; infrared plasma arc lamp; plasma-facing material ID NEUTRON-IRRADIATION; TEMPERATURE; METALS; TRANSIENT; BEHAVIOR; DIVERTOR; ALLOYS; NICKEL AB Testing of advanced materials and component mockups under prototypical fusion high-heat-flux conditions, while historically a mainstay of fusion research, has proved challenging, especially for irradiated materials. A new high-heat-flux-testing (HHFT) facility based on water-wall plasma arc lamps (PALs) is now introduced for materials and small-component testing. Two PAL systems, utilizing a 12 000 degrees C plasma arc contained in a quartz tube cooled by a spiral water flow over the inside tube surface, provide maximum incident heat fluxes of 4.2 and 27 MW/m(2) over areas of 9 X 12 and 1 x 10 cm(2), respectively. This paper will present the overall design and implementation of a PAL-based irradiated material target station (IMTS). The IMTS is primarily designed for testing the effects of heat flux or thermal cycling on material coupons of interest, such as those for plasma-facing components. Temperature results are shown for thermal cycling under HHFT of tungsten coupon specimens that were neutron irradiated in HFIR. Radiological surveys indicated minimal contamination of the 36- x 36- x 18-cm test section, demonstrating the capability of the new facility to handle irradiated specimens at high temperature. C1 [Sabau, Adrian S.; Ohriner, Evan K.; Kiggans, Jim; Harper, David C.; Katoh, Yutai; Snead, Lance L.] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA. [Schaich, Charles R.] Oak Ridge Natl Lab, Energy & Transportat Sci Div, Oak Ridge, TN 37831 USA. [Ueda, Yoshio] Osaka Univ, Grad Sch Engn, Suita, Osaka 5650871, Japan. RP Sabau, AS (reprint author), Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA. EM sabaua@ornl.gov RI Sabau, Adrian/B-9571-2008; kiggans, james/E-1588-2017 OI Sabau, Adrian/0000-0003-3088-6474; kiggans, james/0000-0001-5056-665X FU Office of Fusion Energy Sciences, U.S. Department of Energy under UT-Battelle, LLC [DE-AC05-00OR22725]; "Technological Assessment of Plasma Facing Components for DEMO Reactors" Japan/United States Fusion Research joint project FX This work was supported by the Office of Fusion Energy Sciences, U.S. Department of Energy under contract DE-AC05-00OR22725 with UT-Battelle, LLC, and the "Technological Assessment of Plasma Facing Components for DEMO Reactors" Japan/United States Fusion Research joint project. The authors would like to thank M. Rieth and J. Reiser of Karlsruhe Institute of Technology, Germany, for providing the tungsten specimens and M. A. Williams of ORNL for safety considerations related to the neutron-irradiated materials and S. Curlin of ORNL for taking the micrographs. NR 32 TC 0 Z9 0 U1 1 U2 10 PU AMER NUCLEAR SOC PI LA GRANGE PK PA 555 N KENSINGTON AVE, LA GRANGE PK, IL 60526 USA SN 1536-1055 EI 1943-7641 J9 FUSION SCI TECHNOL JI Fusion Sci. Technol. PD NOV PY 2014 VL 66 IS 3 BP 394 EP 404 PG 11 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS0FW UT WOS:000343954500003 ER PT J AU Alexander, WG Doering, DT Hittinger, CT AF Alexander, William G. Doering, Drew T. Hittinger, Chris Todd TI High-Efficiency Genome Editing and Allele Replacement in Prototrophic and Wild Strains of Saccharomyces SO GENETICS LA English DT Article ID SITE-DIRECTED MUTAGENESIS; VIRUS THYMIDINE KINASE; DOUBLE-STRAND BREAKS; NEUROSPORA-CRASSA; BUDDING YEAST; IN-VIVO; DEOXYRIBONUCLEIC ACID; GENE DISRUPTION; HOST STRAINS; CEREVISIAE AB Current genome editing techniques available for Saccharomyces yeast species rely on auxotrophic markers, limiting their use in wild and industrial strains and species. Taking advantage of the ancient loss of thymidine kinase in the fungal kingdom, we have developed the herpes simplex virus thymidine kinase gene as a selectable and counterselectable marker that forms the core of novel genome engineering tools called the Haploid Engineering and Replacement Protocol (HERP) cassettes. Here we show that these cassettes allow a researcher to rapidly generate heterogeneous populations of cells with thousands of independent chromosomal allele replacements using mixed PCR products. We further show that the high efficiency of this approach enables the simultaneous replacement of both alleles in diploid cells. Using these new techniques, many of the most powerful yeast genetic manipulation strategies are now available in wild, industrial, and other prototrophic strains from across the diverse Saccharomyces genus. C1 [Alexander, William G.; Doering, Drew T.; Hittinger, Chris Todd] Univ Wisconsin, Wisconsin Energy Inst, Genet Lab, Genome Ctr Wisconsin,JF Crow Inst Study Evolut, Madison, WI 53706 USA. [Alexander, William G.; Hittinger, Chris Todd] Univ Wisconsin, DOE Great Lakes Bioenergy Res Ctr, Madison, WI 53706 USA. [Doering, Drew T.; Hittinger, Chris Todd] Univ Wisconsin, Grad Program Cellular & Mol Biol, Madison, WI 53706 USA. RP Hittinger, CT (reprint author), 2434 Genet Biotechnol Ctr,425-G Henry Mall, Madison, WI 53706 USA. EM cthittinger@wisc.edu OI Doering, Drew/0000-0003-1884-9902 FU National Science Foundation [DEB-1253634]; DOE Great Lakes Bioenergy Research Center (DOE Office of Science) [BER DE-FC02-07ER64494]; National Human Genome Research Institute grant to the Genomic Sciences Training Program [5T32HG002760] FX We thank Audrey P. Gasch, Maria I. Sardi, M. B. O'Neill, EmilyClare Baker, Christina Meihua Kuang, Jin Kang, and David Peris for beta testing; Kayla Sylvester and Amanda Hulfachor for laboratory support; EmilyClare Baker, Christina Meihua Kuang, and David Peris for critical review of this manuscript; and Robert Sclafani for advice. We also thank Jasper Rine and Oliver Zill for JRY9288, Francesca Storici and Michael Resnick for pGSKU, and Robert Sclafani for p306-BrdU-Inc. This material is based upon work supported by the National Science Foundation under grant no. DEB-1253634 and funded in part by the DOE Great Lakes Bioenergy Research Center (DOE Office of Science BER DE-FC02-07ER64494). D.T.D. was supported by a National Human Genome Research Institute training grant to the Genomic Sciences Training Program 5T32HG002760. C.T.H. is a Pew Biomedical Scholar. W.G.A. and C.T.H. have, together with the Wisconsin Alumni Research Foundation, filed a provisional patent application describing the research contained within this article. D.T.D. declares no conflict of interest. NR 60 TC 5 Z9 5 U1 0 U2 6 PU GENETICS SOCIETY AMERICA PI BETHESDA PA 9650 ROCKVILLE AVE, BETHESDA, MD 20814 USA SN 0016-6731 EI 1943-2631 J9 GENETICS JI Genetics PD NOV PY 2014 VL 198 IS 3 BP 859 EP + DI 10.1534/genetics.114.170118 PG 24 WC Genetics & Heredity SC Genetics & Heredity GA AS6KT UT WOS:000344373300005 PM 25209147 ER PT J AU Krishnan, B Thomas, SE Yan, RH Yamada, H Zhulin, IB McKee, BD AF Krishnan, Badri Thomas, Sharon E. Yan, Rihui Yamada, Hirotsugu Zhulin, Igor B. McKee, Bruce D. TI Sisters Unbound Is Required for Meiotic Centromeric Cohesion in Drosophila melanogaster SO GENETICS LA English DT Article ID CHROMOSOME SEGREGATION; CHROMATID COHESION; SYNAPTONEMAL COMPLEX; STRUCTURE PREDICTION; SECONDARY STRUCTURE; MOLECULAR-BIOLOGY; PROTEIN-STRUCTURE; AXIAL ELEMENT; MEIOSIS-I; OOCYTES AB Regular meiotic chromosome segregation requires sister centromeres to mono-orient (orient to the same pole) during the first meiotic division (meiosis I) when homologous chromosomes segregate, and to bi-orient (orient to opposite poles) during the second meiotic division (meiosis II) when sister chromatids segregate. Both orientation patterns require cohesion between sister centromeres, which is established during meiotic DNA replication and persists until anaphase of meiosis II. Meiotic cohesion is mediated by a conserved four-protein complex called cohesin that includes two structural maintenance of chromosomes (SMC) subunits (SMC1 and SMC3) and two non-SMC subunits. In Drosophila melanogaster, however, the meiotic cohesion apparatus has not been fully characterized and the non-SMC subunits have not been identified. We have identified a novel Drosophila gene called sisters unbound (sunn), which is required for stable sister chromatid cohesion throughout meiosis. sunn mutations disrupt centromere cohesion during prophase I and cause high frequencies of non-disjunction (NDJ) at both meiotic divisions in both sexes. SUNN co-localizes at centromeres with the cohesion proteins SMC1 and SOLO in both sexes and is necessary for the recruitment of both proteins to centromeres. Although SUNN lacks sequence homology to cohesins, bioinformatic analysis indicates that SUNN may be a structural homolog of the non-SMC cohesin subunit stromalin (SA), suggesting that SUNN may serve as a meiosis-specific cohesin subunit. In conclusion, our data show that SUNN is an essential meiosis-specific Drosophila cohesion protein. C1 [Krishnan, Badri; Thomas, Sharon E.; Yan, Rihui; Yamada, Hirotsugu; McKee, Bruce D.] Univ Tennessee, Dept Biochem & Cellular & Mol Biol, Knoxville, TN 37996 USA. [Zhulin, Igor B.; McKee, Bruce D.] Univ Tennessee, Genome Sci & Technol Program, Knoxville, TN 37996 USA. [Zhulin, Igor B.] Univ Tennessee, Dept Microbiol, Knoxville, TN 37996 USA. [Zhulin, Igor B.] Oak Ridge Natl Lab, Div Math & Comp Sci, Oak Ridge, TN 37831 USA. RP McKee, BD (reprint author), Univ Tennessee, Dept Biochem & Cellular & Mol Biol, E202 Walters Life Sci Bldg, Knoxville, TN 37996 USA. EM bdmckee@utk.edu FU National Institute of General Medical Sciences [R01 GM040489]; University of Tennessee; Office of Research Administration, College of Arts and Sciences; Department of Biochemistry and Cellular and Molecular Biology FX We thank B. Wakimoto, C. Zuker, Terry Orr-Weaver, Kim McKim, and the Bloomington Stock Center, Indiana University, for providing Drosophila stocks; R. Scott Hawley, Mary Lily, and Sharon Bickel for providing antibodies; Drosophila Genomics Resource Center (DGRC) and Roger Tsien for providing the pPVW (1093) and pPWV (1094) Venus tag containing P-element vector; and Joseph A. May at the Molecular Biology Resource facility, University of Tennessee, Knoxville for performing DNA sequencing. Funding for this work was provided by the National Institute of General Medical Sciences, grant no. R01 GM040489, and by a grant from the University of Tennessee jointly funded by the Office of Research Administration, College of Arts and Sciences and Department of Biochemistry and Cellular and Molecular Biology. NR 65 TC 8 Z9 8 U1 1 U2 5 PU GENETICS SOCIETY AMERICA PI BETHESDA PA 9650 ROCKVILLE AVE, BETHESDA, MD 20814 USA SN 0016-6731 EI 1943-2631 J9 GENETICS JI Genetics PD NOV PY 2014 VL 198 IS 3 BP 947 EP + DI 10.1534/genetics.114.166009 PG 38 WC Genetics & Heredity SC Genetics & Heredity GA AS6KT UT WOS:000344373300012 PM 25194162 ER PT J AU Macpherson, GL Capo, RC Stewart, BW Phan, TT Schroeder, K Hammack, RW AF Macpherson, G. L. Capo, R. C. Stewart, B. W. Phan, T. T. Schroeder, K. Hammack, R. W. TI Temperature-dependent Li isotope ratios in Appalachian Plateau and Gulf Coast Sedimentary Basin saline water SO GEOFLUIDS LA English DT Article DE Appalachian Plateau; diagenesis; fluid transport; formation water; Gulf Coast Sedimentary Basin; lithium; produced water; saline water; stable lithium isotope ratios; water-rock reaction ID FRIO FORMATION OLIGOCENE; KETTLEMAN NORTH-DOME; OIL-FIELD BRINES; LITHIUM ISOTOPE; REGIONAL VARIATIONS; MACKENZIE BASIN; GEOCHEMISTRY; SEAWATER; TEXAS; EVOLUTION AB Lithium (Li) concentrations of produced water from unconventional (horizontally drilled and hydraulically fractured shale) and conventional gas wells in Devonian reservoirs in the Appalachian Plateau region of western Pennsylvania range from 0.6 to 17mmolkg(-1), and Li isotope ratios, expressed as in Li-7, range from +8.2 to +15 parts per thousand. Li concentrations are as high as 40mmolkg(-1) in produced waters from Plio-Pleistocene through Jurassic-aged reservoirs in the Gulf Coast Sedimentary Basin analyzed for this study, and Li-7 values range from about +4.2 to +16.6 parts per thousand. Because of charge-balance constraints and rock buffering, Li concentrations in saline waters from sedimentary basins throughout the world (including this study) are generally positively correlated with chloride (Cl), the dominant anion in these fluids. Li concentrations also vary with depth, although the extent of depth dependence differs among sedimentary basins. In general, Li concentrations are higher than expected from seawater or evaporation of seawater and therefore require water-mineral reactions that remove lithium from the minerals. Li isotope ratios in these produced waters vary inversely with temperature. However, calculations of temperature-dependent fractionation of Li-7 between average shale Li-7 (-0.7 parts per thousand) and water result in Li-7(water) that is more positive than that of most produced waters. This suggests that aqueous Li-7 may reflect transport of water from depth and/or reaction with rocks having Li-7 lighter than average shale. C1 [Macpherson, G. L.] Univ Kansas, Dept Geol, Lawrence, KS 66045 USA. [Capo, R. C.; Stewart, B. W.; Phan, T. T.] Univ Pittsburgh, Dept Geol & Planetary Sci, Pittsburgh, PA 15260 USA. [Capo, R. C.; Stewart, B. W.; Phan, T. T.] Natl Energy Technol Lab Reg Univ Alliance, Pittsburgh, PA USA. [Schroeder, K.; Hammack, R. W.] US DOE, Natl Energy Technol Lab, Pittsburgh, PA USA. RP Macpherson, GL (reprint author), Univ Kansas, Dept Geol, 1475 Jayhawk Blvd,Rm 120 Lindley Hall, Lawrence, KS 66045 USA. EM glmac@ku.edu OI Phan, Thai/0000-0003-2491-749X FU National Energy Technology Laboratory's ongoing research under the RES [DE-FE0004000] FX This work was supported by the National Energy Technology Laboratory's ongoing research under the RES contract DE-FE0004000. We also thank the Geology Foundation of the University of Kansas, and the University of Kansas Department of Geology. This work could not have been completed without laboratory and field support from personnel from DOE-NETL, USGS, and University of Pittsburgh. The authors thank the reviewers, J.S. Hanor and P. Tomascak, for their detailed and insightful comments that greatly improved this manuscript. The authors declare no conflict of interest. NR 73 TC 6 Z9 6 U1 1 U2 24 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1468-8115 EI 1468-8123 J9 GEOFLUIDS JI Geofluids PD NOV PY 2014 VL 14 IS 4 BP 419 EP 429 DI 10.1111/gfl.12084 PG 11 WC Geochemistry & Geophysics; Geology SC Geochemistry & Geophysics; Geology GA AS5UJ UT WOS:000344334600003 ER PT J AU Liu, HH AF Liu, Hui-Hai TI Non-Darcian flow in low-permeability media: key issues related to geological disposal of high-level nuclear waste in shale formations SO HYDROGEOLOGY JOURNAL LA English DT Article DE Diffusion; Groundwater hydraulics; Solute transport; Waste disposal; Conceptual models ID HYDRAULIC CONDUCTIVITY; WATER; EQUATION; LIQUID AB In clay or other low-permeability media, water flow becomes non-Darcian and characterized by the non-linear relationship between water flux and hydraulic gradient. This work is devoted to addressing a number of key issues related to geological disposal of high-level nuclear waste in clay/shale formations. It is demonstrated that water flow velocity in the damaged zone (often considered as a potential preferential advection paths in a repository) surrounding the tunnel is extremely small, as a result of non-Darcian flow behavior, such that solute transport is dominated by diffusion, rather than advection. The finding is also consistent with the often-observed existence of persistent abnormal pressures in shale formations. While relative permeability is the key parameter for modeling the unsaturated flow process, without incorporating non-Darcian flow behavior, significant errors can occur in the determination of relative permeability values from traditional measurement methods. An approach for dealing with temperature impact on non-Darcian flow and a formulation to calculate non-Darcian water flux in an anisotropic medium are presented, taking into consideration that a geological repository is subject to temperature evolution in the near field as a result of heat generated by nuclear waste, and that shale formations are generally anisotropic. C1 Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Earth Sci, Berkeley, CA 94720 USA. RP Liu, HH (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Earth Sci, Berkeley, CA 94720 USA. EM hhliu@lbl.gov FU DOE [DE-AC02-05CH11231] FX The original version of this paper is reviewed by James Houseworth and Dan Hawkes at Lawrence Berkeley National Laboratory. I also appreciate the constructive comments on the work from the associate editor, Mr. Wei Zhang, and an anonymous reviewer. The study documented in section "A demonstration of impact of non-Darcian flow on performance of a clay repository" was largely motivated by a discussion with Dr. Yifeng Wang at Sandia National Laboratory. This work was funded by and conducted for the Used Fuel Disposition Campaign under DOE Contract No. DE-AC02-05CH11231 NR 25 TC 3 Z9 3 U1 2 U2 14 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1431-2174 EI 1435-0157 J9 HYDROGEOL J JI Hydrogeol. J. PD NOV PY 2014 VL 22 IS 7 BP 1525 EP 1534 DI 10.1007/s10040-014-1145-x PG 10 WC Geosciences, Multidisciplinary; Water Resources SC Geology; Water Resources GA AS1RE UT WOS:000344057300004 ER PT J AU Lentine, AL Nielson, GN Okandan, M Cruz-Campa, JL Tauke-Pedretti, A AF Lentine, Anthony L. Nielson, Gregory N. Okandan, Murat Cruz-Campa, Jose-Luis Tauke-Pedretti, Anna TI Voltage Matching and Optimal Cell Compositions for Microsystem-Enabled Photovoltaic Modules SO IEEE JOURNAL OF PHOTOVOLTAICS LA English DT Article DE Microoptics; microsensors; photovoltaic cells; photovoltaic systems; solar energy ID CONCENTRATOR SOLAR-CELLS; OPTICAL-CONSTANTS; PARAMETERS; EFFICIENCY; GAAS AB In this paper, we calculate optimal cell compositions and voltage-matching considerations for independently connected junctions, such as those proposed for microsystem-enabled photovoltaic modules. The calculations show that designs using voltage-matched independent junctions can achieve better yearly efficiency across temperature and spectrum than traditional monolithic cells. Voltage matching is shown to be relatively insensitive to temperature and spectrum but is dependent on open-circuit voltage as a measure of cell efficiency. If the efficiencies and, hence, maximum power point voltages are known a priori, voltage matching can usually yield yearly efficiencies of 98-99% of the efficiency of a system with each cell operating at its own maximum power point. C1 [Lentine, Anthony L.; Nielson, Gregory N.; Okandan, Murat; Cruz-Campa, Jose-Luis; Tauke-Pedretti, Anna] Sandia Natl Labs, Albuquerque, NM 87185 USA. RP Lentine, AL (reprint author), Sandia Natl Labs, POB 5800, Albuquerque, NM 87185 USA. EM alentine@sandia.gov; gnniels@sandia.gov; mokanda@sandia.gov; jlcruzc@sandia.gov; ataukep@sandia.gov FU U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX Sandia National Laboratories is a multiprogram laboratory managed and operated by Sandia Corporation (a wholly owned subsidiary of Lockheed Martin Corporation) for the U.S. Department of Energy's National Nuclear Security Administration under Contract DE-AC04-94AL85000. NR 36 TC 3 Z9 3 U1 1 U2 7 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 2156-3381 J9 IEEE J PHOTOVOLT JI IEEE J. Photovolt. PD NOV PY 2014 VL 4 IS 6 BP 1593 EP 1602 DI 10.1109/JPHOTOV.2014.2345437 PG 10 WC Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied SC Energy & Fuels; Materials Science; Physics GA AS9DH UT WOS:000344542900042 ER PT J AU Hanson, AJ Deline, CA MacAlpine, SM Stauth, JT Sullivan, CR AF Hanson, Alex J. Deline, Christopher A. MacAlpine, Sara M. Stauth, Jason T. Sullivan, Charles R. TI Partial-Shading Assessment of Photovoltaic Installations via Module-Level Monitoring SO IEEE JOURNAL OF PHOTOVOLTAICS LA English DT Article DE DC power optimizer; distributed maximum power point tracking (DMPPT); distributed power electronics; partial shading; PV system performance ID CONNECTED PV SYSTEMS; PERFORMANCE AB Distributed maximum power point tracking (DMPPT) is a topic of much interest in improving photovoltaic (PV) system performance. This study uses measured performance data at the module level for 542 PV systems to estimate lost system performance due to partial shade. Because each of the monitored systems is equipped with module-level dc power optimizers, an estimate is made of the overall system shading loss and the performance improvement that the system has received from this use of DMPPT. The estimate of shade extent and performance improvement predicted by this approach is verified experimentally against a system that has site survey images, and measured production with and without module-level electronics. Summary data for this analysis across 542 systems find an average power loss of 8.3% due to partial shading, which would have increased to 13% were the systems not equipped with panel-level optimizers. It is estimated that on average, 36% of the power lost from partial shading has been recovered through use of module-level dc power electronics. C1 [Hanson, Alex J.; Stauth, Jason T.; Sullivan, Charles R.] Thayer Sch Engn Dartmouth, Hanover, NH 03755 USA. [Deline, Christopher A.; MacAlpine, Sara M.] Natl Renewable Energy Lab, Golden, CO 80401 USA. RP Hanson, AJ (reprint author), MIT, 77 Massachusetts Ave, Cambridge, MA 02139 USA. EM Alex.J.Hanson.14@dartmouth.edu; chris.deline@nrel.gov; sara.macalpine@nrel.gov; jason.t.stauth@dartmouth.edu; charles.r.sullivan@dartmouth.edu FU U.S. Department of Energy [DE-AC36-08-GO28308]; National Renewable Energy Laboratory; U.S. Department of Energy SunShot Incubator 6 Award; SunShot Incubator Award; National Science Foundation [1309905] FX This work was supported in part by the U.S. Department of Energy under Contract DE-AC36-08-GO28308 with the National Renewable Energy Laboratory and with a U.S. Department of Energy SunShot Incubator 6 Award to Tigo Energy. This work was also supported by a SunShot Incubator Award to Tigo Energy and by the National Science Foundation under Grant 1309905. NR 24 TC 7 Z9 7 U1 0 U2 7 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 2156-3381 J9 IEEE J PHOTOVOLT JI IEEE J. Photovolt. PD NOV PY 2014 VL 4 IS 6 BP 1618 EP 1624 DI 10.1109/JPHOTOV.2014.2351623 PG 7 WC Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied SC Energy & Fuels; Materials Science; Physics GA AS9DH UT WOS:000344542900045 ER PT J AU He, XQ Brown, G Demirkan, K Mackie, N Lordi, V Rockett, A AF He, X. Q. Brown, G. Demirkan, K. Mackie, N. Lordi, V. Rockett, A. TI Microstructural and Chemical Investigation of PVD-CdS/PVD-CuIn1-xGaxSe2 Heterojunctions: A Transmission Electron Microscopy Study SO IEEE JOURNAL OF PHOTOVOLTAICS LA English DT Article DE Cu(In, Ga)Se-2 photovoltaics; PVD-CdS structure; transmission electron microscopy; twins ID CU(IN,GA)SE-2 THIN-FILMS; BATH DEPOSITION PROCESS; SOLAR-CELLS; BUFFER LAYERS; CDS; CUINSE2; SURFACE AB We report on a detailed transmission electron microscopy (TEM) study of physical-vapor-deposited (PVD) CdS/CuIn1-xGaxSe2 (CIGS) heterojunctions prepared at the Mia-Sole production line. High-resolution TEM images of the heterointerface reveal the coexistence of CdS domains of cubic and hexagonal phases. Both are shown to grow epitaxially on the CIGS surface. Twin boundaries in the CIGS were observed to propagate into the epitaxial CdS and continue through the whole CdS layer. Scanning TEM in combination with energy dispersive X-ray spectroscopy shows the presence of Cu in the CdS up to similar to 20 nm from the heterojunction. These results provide insights into the PVD-CdS/CIGS heterointerface and suggest that buffer layer crystallinity sufficient to produce photocurrent generation may be obtained with further process optimization. C1 [He, X. Q.; Rockett, A.] Univ Illinois, Urbana, IL 61801 USA. [Brown, G.; Demirkan, K.; Mackie, N.] MiaSole Hitech, Santa Clara, CA 95051 USA. [Lordi, V.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. RP He, XQ (reprint author), Univ Illinois, Urbana, IL 61801 USA. EM hhexiaoqing@gmail.com; gbrown@miasole.com; kdemirkan@miasole.com; nmackie@miasole.com; lordi2@llnl.gov; arockett@illinois.edu FU DOE/EERE SunShot BRIDGE program; U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX This work was supported by the DOE/EERE SunShot BRIDGE program. A portion of this work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. NR 17 TC 5 Z9 5 U1 1 U2 16 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 2156-3381 J9 IEEE J PHOTOVOLT JI IEEE J. Photovolt. PD NOV PY 2014 VL 4 IS 6 BP 1625 EP 1629 DI 10.1109/JPHOTOV.2014.2344752 PG 5 WC Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied SC Energy & Fuels; Materials Science; Physics GA AS9DH UT WOS:000344542900046 ER PT J AU Li, C Poplawsky, J Paudel, N Pennycook, TJ Haigh, SJ Al-Jassim, MM Yan, Y Pennycook, SJ AF Li, C. Poplawsky, J. Paudel, N. Pennycook, T. J. Haigh, S. J. Al-Jassim, M. M. Yan, Y. Pennycook, S. J. TI S-Te Interdiffusion within Grains and Grain Boundaries in CdTe Solar Cells SO IEEE JOURNAL OF PHOTOVOLTAICS LA English DT Article DE CdTe; interface scanning transmission electron microscopy; thin-film photovoltaic ID THIN-FILMS AB At the CdTe/CdS interface, a significant Te-S interdiffusion has been found a few nanometers into the CdTe grain interiors with scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy. This interdiffusion happens on both as-grown and CdCl2 -treated CdTe. S substitution at Te sites has been directly resolved in CdTe with STEM Z-contrast images, which further confirms the S diffusion into CdTe grain interiors. Moreover, when a sufficient amount of S substitutes for Te, a structural transformation from zinc-blende to wurtzite has been observed. In the CdCl2 treated CdTe, Cl segregation has also been found at the interface. STEM electron-beam-induced current shows that the p-n junction occurs a few namometers into the CdTe grains, which is consistent with the S diffusion range we observe. The shift of the p-n junction suggests a buried homojunction which would help reduce nonradiative recombination at the junction. Meanwhile, long-range S diffusion in CdTe grain boundaries (GBs) has been detected, as has Te and Cl diffusion in CdS GBs. C1 [Li, C.] Vanderbilt Univ, Dept Chem, Nashville, TN 37235 USA. [Li, C.; Poplawsky, J.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. [Poplawsky, J.; Pennycook, S. J.] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA. [Paudel, N.; Yan, Y.] Univ Toledo, Dept Phys & Astron, Toledo, OH 43606 USA. [Pennycook, T. J.] Univ Oxford, Dept Mat, Oxford OX13 PH, England. [Pennycook, T. J.] SuperSTEM Lab, Daresbury WA44 AD, England. [Haigh, S. J.] Univ Manchester, Sch Mat, Manchester M139 PL, Lancs, England. [Al-Jassim, M. M.] Natl Renewable Energy Lab, Golden, CO 80401 USA. RP Li, C (reprint author), Vanderbilt Univ, Dept Chem, Box 1583, Nashville, TN 37235 USA. EM lichen0320@gmail.com; poplawskyjd@ornl.gov; naba.paudel@utoledo.edu; pennycook@materials.ox.ac.uk; sarah.haigh@manchester.ac.uk; mowafak.aljassim@nrel.gov; yanfa.yan@utoledo.edu; spennyco@utk.edu RI Pennycook, Timothy/B-4946-2014; Haigh, Sarah/D-1309-2014; Poplawsky, Jonathan/Q-2456-2015 OI Pennycook, Timothy/0000-0002-0008-6516; Haigh, Sarah/0000-0001-5509-6706; Poplawsky, Jonathan/0000-0002-4272-7043 FU U.S. Department of Energy Office of Energy Efficiency and Renewable Energy; Foundational Program to Advance Cell Efficiency (F-PACE); Office of Basic Energy Sciences, Materials Science and Engineering Division; U.K. Engineering and Physical Sciences Research Council through the U.K. National Facility for Aberration-Corrected STEM FX This work was supported by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy, Foundational Program to Advance Cell Efficiency (F-PACE) (C. Li, J. Poplawsky, N. Paudel, Y. Yan, M. M. Al-Jassim, S. J. Pennycook) and the Office of Basic Energy Sciences, Materials Science and Engineering Division (microscope support). STEM-EDX was supported by the U.K. Engineering and Physical Sciences Research Council through the U.K. National Facility for Aberration-Corrected STEM (T. J. Pennycook and S. J. Haigh). NR 24 TC 8 Z9 8 U1 1 U2 47 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 2156-3381 J9 IEEE J PHOTOVOLT JI IEEE J. Photovolt. PD NOV PY 2014 VL 4 IS 6 BP 1636 EP 1643 DI 10.1109/JPHOTOV.2014.2351622 PG 8 WC Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied SC Energy & Fuels; Materials Science; Physics GA AS9DH UT WOS:000344542900048 ER PT J AU Mansfield, LM Noufi, R Muzzillo, CP DeHart, C Bowers, K To, B Pankow, JW Reedy, RC Ramanathan, K AF Mansfield, Lorelle M. Noufi, Rommel Muzzillo, Christopher P. DeHart, Clay Bowers, Karen To, Bobby Pankow, Joel W. Reedy, Robert C. Ramanathan, Kannan TI Enhanced Performance in Cu(In,Ga)Se-2 Solar Cells Fabricated by the Two-Step Selenization Process With a Potassium Fluoride Postdeposition Treatment SO IEEE JOURNAL OF PHOTOVOLTAICS LA English DT Article DE Copper compounds; Cu(In, Ga)Se-2; current-voltage characteristics; photovoltaic cells; potassium fluoride post-deposition treatment; thin films ID EFFICIENCY; FILMS AB Cu(In,Ga)Se-2 (CIGS) solar cells fabricated with two-step selenization processes commonly suffer from low open-circuit voltage (V-oc). We found that the V-oc of solar cells made from selenized Cu/Ga/In stackedmetal precursors can be increased by employing a potassium fluoride (KF) postdeposition treatment (PDT). This study presents a comparison of films and resulting devices with and without the KF PDT. By including the KF PDT, an 18.6%-efficient CIGS device with a V-oc of 0.709 V was fabricated using a two-step selenization process. C1 [Mansfield, Lorelle M.; Noufi, Rommel; Muzzillo, Christopher P.; DeHart, Clay; Bowers, Karen; To, Bobby; Pankow, Joel W.; Reedy, Robert C.; Ramanathan, Kannan] Natl Renewable Energy Lab, Golden, CO 80401 USA. [Muzzillo, Christopher P.] Univ Florida, Gainesville, FL 32601 USA. RP Mansfield, LM (reprint author), Natl Renewable Energy Lab, Golden, CO 80401 USA. EM lorelle.mansfield@nrel.gov; rommel.noufi@gmail.com; christopher.muzzillo@nrel.gov; clay.dehart@nrel.gov; karen.bowers@nrel.gov; bobby.to@nrel.gov; joel.pankow@nrel.gov; bob.reedy@nrel.gov; kannan.ramanathan@nrel.gov FU U.S. Department of Energy [DE-AC36-08-GO28308]; National Renewable Energy Laboratory FX This work was supported by the U.S. Department of Energy under Grant DE-AC36-08-GO28308 with the National Renewable Energy Laboratory. NR 15 TC 5 Z9 5 U1 3 U2 36 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 2156-3381 J9 IEEE J PHOTOVOLT JI IEEE J. Photovolt. PD NOV PY 2014 VL 4 IS 6 BP 1650 EP 1654 DI 10.1109/JPHOTOV.2014.2354259 PG 5 WC Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied SC Energy & Fuels; Materials Science; Physics GA AS9DH UT WOS:000344542900050 ER PT J AU Moseley, J Al-Jassim, MM Kuciauskas, D Moutinho, HR Paudel, N Guthrey, HL Yan, YF Metzger, WK Ahrenkiel, RK AF Moseley, John Al-Jassim, Mowafak M. Kuciauskas, Darius Moutinho, Helio R. Paudel, Naba Guthrey, Harvey L. Yan, Yanfa Metzger, Wyatt K. Ahrenkiel, Richard K. TI Cathodoluminescence Analysis of Grain Boundaries and Grain Interiors in Thin-Film CdTe SO IEEE JOURNAL OF PHOTOVOLTAICS LA English DT Article DE Cathodoluminescence (CL); CdTe solar cells; grain boundaries (GBs); grain interiors (GIs); thin films ID POLYCRYSTALLINE SOLAR-CELLS; BEAM-INDUCED CURRENT; CADMIUM TELLURIDE; CDCL2 TREATMENT; ELECTRON-BEAM; GROWN CDTE; PHOTOLUMINESCENCE; RECRYSTALLIZATION; DISLOCATIONS; LUMINESCENCE AB We used low-temperature cathodoluminescence (CL) spectrum imaging (CLSI) with nanoscale spatial resolution to examine charge-carrier recombination and defects at grain boundaries (GBs) and grain interiors (GIs) in as-deposited and CdCl2-treated CdTe thin films. Supporting time-resolved photoluminescence, T = 4 K photoluminescence, secondary ion mass spectrometry, and electron backscatter diffraction measurements were conducted on the same films. Color-coded maps of the luminescence transition energies (photon energy maps) were used to analyze the qualitative characteristics of the CLSI data. We applied an image analysis algorithm to the pixels in grayscale CL intensity images to compare the luminescence intensities and spectra at the GIs and GBs quantitatively and with statistical relevance. Our results show that GBs in as-deposited films are active recombination centers and are thus harmful to solar cell operation. CL GB defect contrast is quantifiably reduced for the CdCl2-treated film, which is direct evidence of passivation of deep GB core states resulting from the treatment. However, the CdCl2 treatment is not a perfect fix for GB recombination, and GB recombination may still be limiting performance in CdCl2-treated devices. C1 [Moseley, John; Al-Jassim, Mowafak M.; Kuciauskas, Darius; Moutinho, Helio R.; Guthrey, Harvey L.; Metzger, Wyatt K.; Ahrenkiel, Richard K.] Natl Renewable Energy Lab, Golden, CO 80401 USA. [Moseley, John; Ahrenkiel, Richard K.] Colorado Sch Mines, Golden, CO 80401 USA. [Paudel, Naba; Yan, Yanfa] Univ Toledo, Dept Phys & Astron, Toledo, OH 43606 USA. RP Moseley, J (reprint author), Natl Renewable Energy Lab, Golden, CO 80401 USA. EM john.moseley@nrel.gov; mowafak.aljassim@nrel.gov; darius.kuciauskas@nrel.gov; he-lio.moutinho@nrel.gov; naba.paudel@utoledo.edu; harvey.guthrey@nrel.gov; yanfa.yan@utoledo.edu; wyatt.metzger@nrel.gov; richard.ahrenkiel@nrel.gov FU U.S. Department of Energy [DE-AC36-08-GO28308]; National Renewable Energy Laboratory FX This work was supported by the U.S. Department of Energy under Contract DE-AC36-08-GO28308 with the National Renewable Energy Laboratory. NR 56 TC 8 Z9 8 U1 1 U2 37 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 2156-3381 J9 IEEE J PHOTOVOLT JI IEEE J. Photovolt. PD NOV PY 2014 VL 4 IS 6 BP 1671 EP 1679 DI 10.1109/JPHOTOV.2014.2359732 PG 9 WC Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied SC Energy & Fuels; Materials Science; Physics GA AS9DH UT WOS:000344542900053 ER PT J AU Ostrowski, J Wang, JH Liu, C AF Ostrowski, James Wang, Jianhui Liu, Cong TI Transmission Switching With Connectivity-Ensuring Constraints SO IEEE TRANSACTIONS ON POWER SYSTEMS LA English DT Article DE Anti-islanding; integer programming; optimization; reliability; transmission switching ID POWER FLOW; SECURITY; ALGORITHM; SYSTEM; RELIABILITY AB This paper seeks to improve the computational time needed to solve transmission switching problems. Transmission switching provides an effective way to reduce operating costs in power system operations by altering the topology of the transmission network. However, determining the optimal set of lines to switch creates an enormous computational burden. Transmission switching formulations add binary decision variables for many transmission lines in the system to indicate if they are switched. This creates a very weak formulation that is difficult to solve. Altering the transmission topology by switching lines can affect the reliability of the network, for instance, by creating islands. Additional reliability constraints need to be added to the problem formulation. These constraints can potentially make an already difficult problem even harder. This paper takes a different approach to the transmission switching problem. Rather than preventing islanding by using constraints in the problem formulation, we look at how they can be used to improve the solution process. Specifically, we develop a cutting plane algorithm to generate valid inequalities and fix variables based on the fact that optimal solutions to the transmission switching problem that do not contain islands exist. C1 [Ostrowski, James] Univ Tennessee, Ind & Syst Engn Dept, Knoxville, TN 37996 USA. [Wang, Jianhui; Liu, Cong] Argonne Natl Lab, Decis & Informat Sci Div, Argonne, IL 60439 USA. RP Ostrowski, J (reprint author), Univ Tennessee, Ind & Syst Engn Dept, Knoxville, TN 37996 USA. NR 25 TC 2 Z9 3 U1 1 U2 3 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 0885-8950 EI 1558-0679 J9 IEEE T POWER SYST JI IEEE Trans. Power Syst. PD NOV PY 2014 VL 29 IS 6 BP 2621 EP 2627 DI 10.1109/TPWRS.2014.2315434 PG 7 WC Engineering, Electrical & Electronic SC Engineering GA AS6YR UT WOS:000344405600006 ER PT J AU Zhao, CY Wang, QF Wang, JH Guan, YP AF Zhao, Chaoyue Wang, Qianfan Wang, Jianhui Guan, Yongpei TI Expected Value and Chance Constrained Stochastic Unit Commitment Ensuring Wind Power Utilization SO IEEE TRANSACTIONS ON POWER SYSTEMS LA English DT Article DE Chance constraint; expected value constraint; sample average approximation; stochastic optimization; unit commitment; wind power ID SAMPLE AVERAGE APPROXIMATION; OPTIMIZATION; UNCERTAINTY; GENERATION; SYSTEMS; RISK; DEMAND AB This paper proposes an expected value and chance constrained stochastic optimization approach for the unit commitment problem with uncertain wind power output. In the model, the utilization of wind power can be adjusted by changing the utilization rate in the proposed expected value constraint. Meanwhile, the chance constraint is used to restrict the probability of load imbalance. Then a Sample Average Approximation (SAA) method is used to transform the objective function, the expected value constraint, and the chance constraint into sample average reformulations. Furthermore, a combined SAA framework that considers both the expected value and the chance constraints is proposed to construct statistical upper and lower bounds for the optimization problem. Finally, the performance of the proposed algorithm with different utilization rates and different risk levels is tested for a six-bus system. A revised IEEE 118-bus system is also studied to show the scalability of the proposed model and algorithm. C1 [Zhao, Chaoyue] Oklahoma State Univ, Dept Ind Engn & Management, Stillwater, OK 74074 USA. [Wang, Qianfan] Alstom Grid, Redmond, WA 98052 USA. [Wang, Jianhui] Argonne Natl Lab, Decis & Informat Sci Div, Lemont, IL 60439 USA. [Guan, Yongpei] Univ Florida, Dept Ind & Syst Engn, Gainesville, FL 32611 USA. RP Zhao, CY (reprint author), Oklahoma State Univ, Dept Ind Engn & Management, Stillwater, OK 74074 USA. EM cherryzhao09@gmail.com; qfwang@ufl.edu; jianhui.wang@anl.gov; guan@ise.ufl.edu FU University of Chicago Argonne, LLC, Operator of Argonne National Laboratory ("Argonne"). Argonne, a U. S. Department of Energy Office of Science laboratory [DE-AC02-06CH11357] FX This work was supported in part by University of Chicago Argonne, LLC, Operator of Argonne National Laboratory ("Argonne"). Argonne, a U. S. Department of Energy Office of Science laboratory, is operated under Contract No. DE-AC02-06CH11357. Paper no. TPWRS-00686-2013. NR 34 TC 10 Z9 11 U1 3 U2 9 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 0885-8950 EI 1558-0679 J9 IEEE T POWER SYST JI IEEE Trans. Power Syst. PD NOV PY 2014 VL 29 IS 6 BP 2696 EP 2705 DI 10.1109/TPWRS.2014.2319260 PG 10 WC Engineering, Electrical & Electronic SC Engineering GA AS6YR UT WOS:000344405600013 ER PT J AU Li, J Ma, XY Liu, CC Schneider, KP AF Li, Juan Ma, Xi-Yuan Liu, Chen-Ching Schneider, Kevin P. TI Distribution System Restoration With Microgrids Using Spanning Tree Search SO IEEE TRANSACTIONS ON POWER SYSTEMS LA English DT Article DE Distribution automation; Gridlab-D; microgrids; self-healing; service restoration; spanning tree ID SERVICE RESTORATION; EXPERT-SYSTEM; GENERATION; OPERATION AB Distribution system restoration (DSR) is aimed at restoring loads after a fault by altering the topological structure of the distribution network while meeting electrical and operational constraints. The emerging microgrids embedded in distribution systems enhance the self-healing capability and allow distribution systems to recover faster in the event of an outage. This paper presents a graph-theoretic DSR strategy incorporating microgrids that maximizes the restored load and minimizes the number of switching operations. Spanning tree search algorithms are applied to find the candidate restoration strategies by modeling microgrids as virtual feeders and representing the distribution system as a spanning tree. Unbalanced three-phase power flow is performed to ensure that the proposed system topology satisfies all operational constraints. Simulation results based on a modified IEEE 37-node system and a 1069-node distribution system demonstrate the effectiveness of the proposed approach. C1 [Li, Juan] Southern Calif Edison, Rosemead, CA 91770 USA. [Ma, Xi-Yuan] Wuhan Univ, Sch Elect Engn, Wuhan 430072, Peoples R China. [Liu, Chen-Ching] Washington State Univ, Dept Elect Engn & Comp Sci, Pullman, WA 99163 USA. [Liu, Chen-Ching] Univ Coll Dublin, Sch Mech & Mat Engn, Dublin 2, Ireland. [Schneider, Kevin P.] PNNL, Richland, WA 99352 USA. RP Ma, XY (reprint author), Wuhan Univ, Sch Elect Engn, Wuhan 430072, Peoples R China. EM amy.li@sce.com; hushi@whu.edu.cn; liu@eecs.wsu.edu; kevin.schneider@pnl.gov FU U.S. Department of Energy (DOE); Pacific Northwest National Laboratory (PNNL) FX This work was supported in part by the U.S. Department of Energy (DOE) and in part by Pacific Northwest National Laboratory (PNNL). Paper no. TPWRS-01348-2013. NR 23 TC 19 Z9 20 U1 2 U2 9 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 0885-8950 EI 1558-0679 J9 IEEE T POWER SYST JI IEEE Trans. Power Syst. PD NOV PY 2014 VL 29 IS 6 BP 3021 EP 3029 DI 10.1109/TPWRS.2014.2312424 PG 9 WC Engineering, Electrical & Electronic SC Engineering GA AS6YR UT WOS:000344405600046 ER PT J AU Chen, BK Wang, JH Wang, LZ He, YY Wang, ZY AF Chen, Bokan Wang, Jianhui Wang, Lizhi He, Yanyi Wang, Zhaoyu TI Robust Optimization for Transmission Expansion Planning: Minimax Cost vs. Minimax Regret SO IEEE TRANSACTIONS ON POWER SYSTEMS LA English DT Article DE Generation retirement; load growth; minimax cost; minimax regret; robust optimization; transmission expansion planning ID LINEAR-PROGRAMS; UNIT COMMITMENT AB Due to the long planning horizon, transmission expansion planning is typically subjected to a lot of uncertainties including load growth, renewable energy penetration, policy changes, etc. In addition, deregulation of the power industry and pressure from climate change introduced new sources of uncertainties on the generation side of the system. Generation expansion and retirement become highly uncertain as well. Some of the uncertainties do not have probability distributions, making it difficult to use stochastic programming. Techniques like robust optimization that do not require a probability distribution became desirable. To address these challenges, we study two optimization criteria for the transmission expansion planning problem under the robust optimization paradigm, where the maximum cost and maximum regret of the expansion plan over all uncertainties are minimized, respectively. With these models, our objective is to make planning decisions that are robust against all scenarios. We use a two-layer algorithm to solve the resulting tri-level optimization problems. Then, in our case studies, we compare the performance of the minimax cost approach and the minimax regret approach under different characterizations of uncertainties. C1 [Chen, Bokan; Wang, Lizhi; He, Yanyi] Iowa State Univ, Dept Ind & Mfg Syst Engn, Ames, IA 50014 USA. [Wang, Jianhui] Argonne Natl Lab, Lemont, IL 60439 USA. [Wang, Zhaoyu] Georgia Inst Technol, Sch Elect & Comp Engn, Atlanta, GA 30332 USA. RP Chen, BK (reprint author), Iowa State Univ, Dept Ind & Mfg Syst Engn, Ames, IA 50014 USA. EM bokanc@iastate.edu; jianhui.wang@anl.gov; lzwang@iastate.edu; heyanyi@iastate.edu; zhaoyuwang@gatech.edu FU Power Systems Engineering Research Center; Electric Power Research Center at Iowa State University; U.S. Department of Energy Office of Electricity Delivery and Energy Reliability FX B. Chen and L. Wang are supported in part by the Power Systems Engineering Research Center and the Electric Power Research Center at Iowa State University. The work of J. Wang and part of the work by B. Chen was supported by the U.S. Department of Energy Office of Electricity Delivery and Energy Reliability. Without implication, all errors are the authors'. Paper no. TPWRS-01416-2013. NR 28 TC 11 Z9 13 U1 0 U2 10 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 0885-8950 EI 1558-0679 J9 IEEE T POWER SYST JI IEEE Trans. Power Syst. PD NOV PY 2014 VL 29 IS 6 BP 3069 EP 3077 DI 10.1109/TPWRS.2014.2313841 PG 9 WC Engineering, Electrical & Electronic SC Engineering GA AS6YR UT WOS:000344405600051 ER PT J AU Li, ZS Guo, QL Sun, HB Xin, SJ Wang, JH AF Li, Zhengshuo Guo, Qinglai Sun, Hongbin Xin, Shujun Wang, Jianhui TI A New Real-Time Smart-Charging Method Considering Expected Electric Vehicle Fleet Connections SO IEEE TRANSACTIONS ON POWER SYSTEMS LA English DT Article DE Electric vehicle; real-time; valley-filing; vehicle charging; vehicle fleet ID DIVIDED OPTIMIZATION; EV AGGREGATOR; PARTICIPATION AB This letter presents a real-time electric vehicle (EV) smart-charging method (N-RT), that not only considers currently connected EVs, but also uses a prediction of the EVs that are expected to plug in in the future. Numerical tests show that the N-RT method improves valley-filling under various levels of prediction accuracy. C1 [Li, Zhengshuo; Guo, Qinglai; Sun, Hongbin; Xin, Shujun] Tsinghua Univ, State Key Lab Power Syst, Dept Elect Engn, Beijing 100084, Peoples R China. [Wang, Jianhui] Argonne Natl Lab, Decis & Informat Sci Div, Argonne, IL 60439 USA. RP Li, ZS (reprint author), Tsinghua Univ, State Key Lab Power Syst, Dept Elect Engn, Beijing 100084, Peoples R China. EM shb@mail.tsinghua.edu.cn FU National Key Basic Research Program of China (973 Program) [2013CB228202]; National Science Fund for Distinguished Young Scholars [51025725]; National Science Foundation of China [51321005]; Tsinghua University Initiative Scientific Research Program FX This work was supported in part by the National Key Basic Research Program of China (973 Program) (2013CB228202), the National Science Fund for Distinguished Young Scholars (51025725), National Science Foundation of China (51321005), and the Tsinghua University Initiative Scientific Research Program. Paper no. PESL-00093-2013. NR 6 TC 4 Z9 6 U1 1 U2 5 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 0885-8950 EI 1558-0679 J9 IEEE T POWER SYST JI IEEE Trans. Power Syst. PD NOV PY 2014 VL 29 IS 6 BP 3114 EP 3115 DI 10.1109/TPWRS.2014.2311954 PG 2 WC Engineering, Electrical & Electronic SC Engineering GA AS6YR UT WOS:000344405600056 ER PT J AU Mudenda, L Pierle, SA Turse, JE Scoles, GA Purvine, SO Nicora, CD Clauss, TRW Ueti, MW Brown, WC Brayton, KA AF Mudenda, Lwiindi Pierle, Sebastian Aguilar Turse, Joshua E. Scoles, Glen A. Purvine, Samuel O. Nicora, Carrie D. Clauss, Therese R. W. Ueti, Massaro W. Brown, Wendy C. Brayton, Kelly A. TI Proteomics informed by transcriptomics identifies novel secreted proteins in Dermacentor andersoni saliva SO INTERNATIONAL JOURNAL FOR PARASITOLOGY LA English DT Article DE Tick; Gene expression; Transcriptomics; Proteomics; Salivary proteins; Saliva; Mass spectrometry ID RHIPICEPHALUS-APPENDICULATUS TICKS; REAL-TIME PCR; IXODES-SCAPULARIS; ANAPLASMA-MARGINALE; PLATELET-AGGREGATION; AMBLYOMMA-VARIEGATUM; STATISTICAL-ANALYSIS; EXPRESSION PROFILE; REFERENCE GENES; RNA-SEQ AB Dermacentor andersoni, known as the Rocky Mountain wood tick, is found in the western United States and transmits pathogens that cause diseases of veterinary and public health importance including Rocky Mountain spotted fever, tularemia, Colorado tick fever and bovine anaplasmosis. Tick saliva is known to modulate both innate and acquired immune responses, enabling ticks to feed for several days without detection. During feeding ticks subvert host defences such as hemostasis and inflammation, which would otherwise result in coagulation, wound repair and rejection of the tick. Molecular characterization of the proteins and pharmacological molecules secreted in tick saliva offers an opportunity to develop tick vaccines as an alternative to the use of acaricides, as well as new anti-inflammatory drugs. We performed proteomics informed by transcriptomics to identify D. andersoni saliva proteins that are secreted during feeding. The transcript data generated a database of 21,797 consensus sequences, which we used to identify 677 proteins secreted in the saliva of D. andersoni ticks fed for 2 and 5 days, following proteomic investigations of whole saliva using mass spectrometry. Salivary gland transcript levels of unfed ticks were compared with 2 and 5 day fed ticks to identify genes upregulated early during tick feeding. We cross-referenced the proteomic data with the transcriptomic data to identify 157 proteins of interest for immunomodulation and blood feeding. Proteins of unknown function as well as known immunomodulators were identified. (C) 2014 Australian Society for Parasitology Inc. Published by Elsevier Ltd. All rights reserved. C1 [Mudenda, Lwiindi; Pierle, Sebastian Aguilar; Brayton, Kelly A.] Washington State Univ, Paul G Allen Sch Global Anim Hlth, Pullman, WA 99164 USA. [Mudenda, Lwiindi; Pierle, Sebastian Aguilar; Turse, Joshua E.; Brown, Wendy C.; Brayton, Kelly A.] Washington State Univ, Dept Vet Microbiol & Pathol, Pullman, WA 99164 USA. [Scoles, Glen A.; Ueti, Massaro W.] ARS, Anim Dis Res Unit, USDA, Pullman, WA USA. [Purvine, Samuel O.] Pacific NW Natl Lab, Environm Mol Sci Lab, Richland, WA 99352 USA. [Nicora, Carrie D.; Clauss, Therese R. W.] Pacific NW Natl Lab, Div Biol Sci, Richland, WA 99352 USA. RP Brown, WC (reprint author), Washington State Univ, Dept Vet Microbiol & Pathol, Pullman, WA 99164 USA. EM wbrown@vetmed.wsu.edu; kbrayton@vetmed.wsu.edu FU Department of Energy's Office of Biological and Environmental Research; Fulbright Program, USA; Paul G. Allen School for Global Animal Health, Washington State University, USA; Conacyt, Mexico; Poncin, USA; U.S. Department of Agriculture [ARS 5348-32000-033-00D] FX The global proteomic study was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at the Pacific Northwest National Laboratory, Richland, WA, USA. Lwiindi Mudenda was supported by a grant from the Fulbright Program, USA and by the Paul G. Allen School for Global Animal Health, Washington State University, USA, and Sebastian Aguilar Pierle was supported by Conacyt, Mexico and Poncin, USA. This work was supported in part by U.S. Department of Agriculture grant ARS 5348-32000-033-00D. We appreciate the excellent technical support of Xiaoya Cheng, James Allison, Ralph Horn, Sara Davis and Kathy Mason. NR 61 TC 14 Z9 14 U1 2 U2 19 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0020-7519 EI 1879-0135 J9 INT J PARASITOL JI Int. J. Parasit. PD NOV PY 2014 VL 44 IS 13 BP 1029 EP 1037 DI 10.1016/j.ijpara.2014.07.003 PG 9 WC Parasitology SC Parasitology GA AS7GS UT WOS:000344425700007 PM 25110293 ER PT J AU Dingreville, R Eckert-Gallup, A Sallaberry, C AF Dingreville, Remi Eckert-Gallup, Aubrey Sallaberry, Cedric TI Uncertainty analysis for the net-section-collapse failure criterion of circumferentially cracked cylinders for multiple arbitrary-shaped circumferential cracks SO INTERNATIONAL JOURNAL OF PRESSURE VESSELS AND PIPING LA English DT Article DE Surface cracks; Net section collapse; Stability criterion; Corrosion; ASME section XI ID LIMIT LOADS; PIPES; PRESSURE; FRACTURE; FLAWS AB In this manuscript, a generalized net-section-collapse (NSC) failure criterion of circumferentially cracked pipes with multiple arbitrary-shaped cracks is presented. This generalized NSC formulation is capable of predicting the NSC moment of a pipe with multiple arbitrary-shaped cracks distributed around the circumference of the pipe, regardless of whether they are distributed symmetrically or not. The case in which internal cracks straddle the compressive zone is accounted for in the present formulation. Closed form solutions are provided for the maximum moments of pipes containing multiple cracks with idealized shapes, namely constant depth, semi-elliptical and parabolic crack profiles. Through a series of examples, the results show the effectiveness and accuracy of the method. Using this method, quantification of the effect of the crack profile uncertainty on the maximum bending moment sustained by a cracked pipe is evaluated. It is demonstrated that while the uncertainty associated with the surface roughness of the crack profile has little to no effect on the maximum bending moment, irregular shape profiles have, not surprisingly, a large effect on the estimation of the maximum bending moment. In fact, it is mathematically shown that the uncertainty associated with the maximum bending moment is proportional to the magnitude of the crack profile uncertainty and inversely proportional to the square root of the uncertainty sampling size (i.e. surface roughness vs. irregular crack profile). Published by Elsevier Ltd. C1 [Dingreville, Remi; Eckert-Gallup, Aubrey; Sallaberry, Cedric] Sandia Natl Labs, Albuquerque, NM 87185 USA. RP Dingreville, R (reprint author), Sandia Natl Labs, POB 5800, Albuquerque, NM 87185 USA. EM rdingre@sandia.gov OI Dingreville, Remi/0000-0003-1613-695X FU United States Department of Energy [DE-AC04-94AL85000] FX The authors would like to thank Dr. F.W. Brust, Dr. D.L. Rudland and Dr. K. Hasegawa for their valuable comments and suggestions during this work. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy, under Contract No. DE-AC04-94AL85000. NR 22 TC 1 Z9 1 U1 0 U2 9 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0308-0161 EI 1879-3541 J9 INT J PRES VES PIP JI Int. J. Pressure Vessels Pip. PD NOV-DEC PY 2014 VL 123 BP 30 EP 45 DI 10.1016/j.ijpvp.2014.07.005 PG 16 WC Engineering, Multidisciplinary; Engineering, Mechanical SC Engineering GA AS2SM UT WOS:000344129800004 ER PT J AU Beliaev, AS Romine, MF Serres, M Bernstein, HC Linggi, BE Markillie, LM Isern, NG Chrisler, WB Kucek, LA Hill, EA Pinchuk, GE Bryant, DA Wiley, HS Fredrickson, JK Konopka, A AF Beliaev, Alexander S. Romine, Margie F. Serres, Margrethe Bernstein, Hans C. Linggi, Bryan E. Markillie, Lye M. Isern, Nancy G. Chrisler, William B. Kucek, Leo A. Hill, Eric A. Pinchuk, Grigoriy E. Bryant, Donald A. Wiley, H. Steven Fredrickson, Jim K. Konopka, Allan TI Inference of interactions in cyanobacterial-heterotrophic co-cultures via transcriptome sequencing SO ISME JOURNAL LA English DT Article DE cyanobacterium; heterotroph; co-culture; microbial interactions; transcriptome; SOLiD sequencing ID SHEWANELLA-ONEIDENSIS MR-1; STRAIN PCC 7002; GENE-EXPRESSION; AGMENELLUM-QUADRUPLICATUM; GLOBAL TRANSCRIPTOME; COMPARATIVE GENOMICS; ELECTRON-ACCEPTORS; METABOLIC PATHWAYS; MARINE-BACTERIA; GROWTH AB We used deep sequencing technology to identify transcriptional adaptation of the euryhaline unicellular cyanobacterium Synechococcus sp. PCC 7002 and the marine facultative aerobe Shewanella putrefaciens W3-18-1 to growth in a co-culture and infer the effect of carbon flux distributions on photoautotroph-heterotroph interactions. The overall transcriptome response of both organisms to co-cultivation was shaped by their respective physiologies and growth constraints. Carbon limitation resulted in the expansion of metabolic capacities, which was manifested through the transcriptional upregulation of transport and catabolic pathways. Although growth coupling occurred via lactate oxidation or secretion of photosynthetically fixed carbon, there was evidence of specific metabolic interactions between the two organisms. These hypothesized interactions were inferred from the excretion of specific amino acids (for example, alanine and methionine) by the cyanobacterium, which correlated with the downregulation of the corresponding biosynthetic machinery in Shewanella W3-18-1. In addition, the broad and consistent decrease of mRNA levels for many Fe-regulated Synechococcus 7002 genes during co-cultivation may indicate increased Fe availability as well as more facile and energy-efficient mechanisms for Fe acquisition by the cyanobacterium. Furthermore, evidence pointed at potentially novel interactions between oxygenic photoautotrophs and heterotrophs related to the oxidative stress response as transcriptional patterns suggested that Synechococcus 7002 rather than Shewanella W3-18-1 provided scavenging functions for reactive oxygen species under co-culture conditions. This study provides an initial insight into the complexity of photoautotrophic-heterotrophic interactions and brings new perspectives of their role in the robustness and stability of the association. C1 [Beliaev, Alexander S.; Romine, Margie F.; Bernstein, Hans C.; Markillie, Lye M.; Chrisler, William B.; Kucek, Leo A.; Hill, Eric A.; Pinchuk, Grigoriy E.; Fredrickson, Jim K.; Konopka, Allan] Pacific NW Natl Lab, Div Biol Sci, Richland, WA 99352 USA. [Serres, Margrethe] Josephine Bay Paul Ctr, Marine Biol Lab, Woods Hole, MA USA. [Linggi, Bryan E.; Isern, Nancy G.; Wiley, H. Steven] Pacific NW Natl Lab, Environm Mol Sci Lab, Richland, WA 99352 USA. [Bryant, Donald A.] Penn State Univ, Dept Biochem & Mol Biol, University Pk, PA 16802 USA. [Bryant, Donald A.] Montana State Univ, Dept Chem & Biochem, Bozeman, MT 59717 USA. RP Beliaev, AS (reprint author), Pacific NW Natl Lab, Div Biol Sci, POB 999,MS P7-50, Richland, WA 99352 USA. EM alex.beliaev@pnnl.gov RI Beliaev, Alexander/E-8798-2016; OI Beliaev, Alexander/0000-0002-6766-4632; Romine, Margaret/0000-0002-0968-7641; Bernstein, Hans/0000-0003-2913-7708 FU Genomic Science Program (GSP); Office of Biological and Environmental Research (BER), US Department of Energy (DOE); DOE by Battelle Memorial Institute [DE-AC05-76RLO 1830] FX The research was supported by the Genomic Science Program (GSP), Office of Biological and Environmental Research (BER), US Department of Energy (DOE) and is a contribution of the PNNL Foundational Scientific Focus Area (FSFA). A significant portion of the research was performed using the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by DOE BER and located at PNNL. We acknowledge PNNL staff who helped to support this work, specifically Oleg Geydebrekht and Thomas Wietsma for assistance with the analytical measurements. We are also grateful to Dr William Nelson for help with the functional genome annotation and Dr Sergey Stolyar for valuable advice and critical discussions. PNNL is operated for the DOE by Battelle Memorial Institute under Contract DE-AC05-76RLO 1830. NR 62 TC 17 Z9 18 U1 11 U2 53 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 1751-7362 EI 1751-7370 J9 ISME J JI ISME J. PD NOV PY 2014 VL 8 IS 11 BP 2243 EP 2255 DI 10.1038/ismej.2014.69 PG 13 WC Ecology; Microbiology SC Environmental Sciences & Ecology; Microbiology GA AS7SB UT WOS:000344454000008 PM 24781900 ER PT J AU Pasquier, R Goulet, JA Acevedo, C Smith, IFC AF Pasquier, Romain Goulet, James-A. Acevedo, Claire Smith, Ian F. C. TI Improving Fatigue Evaluations of Structures Using In-Service Behavior Measurement Data SO JOURNAL OF BRIDGE ENGINEERING LA English DT Article DE Remaining fatigue life; Model-based data interpretation; Population of models; Uncertainty; Conservatism ID HEALTH MONITORING DATA; LIFE PREDICTION; STEEL BRIDGES; IDENTIFICATION; ERRORS AB Conservative models and code practices are usually employed for fatigue-damage predictions of existing structures. Direct in-service behavior measurements are able to provide more accurate estimations of remaining-fatigue-life predictions. However, these estimations are often accurate only for measured locations and measured load conditions. Behavior models are necessary for exploiting information given by measurements and predicting the fatigue damage at all critical locations and for other load cases. Model-prediction accuracy can be improved using system identification techniques where the properties of structures are inferred using behavior measurements. Building upon recent developments in system identification where both model and measurement uncertainties are considered, this paper presents a new data-interpretation framework for reducing uncertainties related to prediction of fatigue life. An initial experimental investigation confirms that, compared with traditional engineering approaches, the methodology provides a safe and more realistic estimation of the fatigue reserve capacity. A second application on a full-scale bridge also confirms that using load-test data reduces the uncertainty related to remaining-fatigue-life predictions. (C) 2014 American Society of Civil Engineers. C1 [Pasquier, Romain; Smith, Ian F. C.] Ecole Polytech Fed Lausanne, Sch Architecture Civil & Environm Engn ENAC, Appl Comp & Mech Lab IMAC, CH-1015 Lausanne, Switzerland. [Goulet, James-A.] Univ Calif Berkeley, Dept Civil & Environm Engn, Berkeley, CA 94720 USA. [Acevedo, Claire] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Ritchie Grp, Mat Sci Div, Berkeley, CA 94720 USA. RP Pasquier, R (reprint author), Ecole Polytech Fed Lausanne, Sch Architecture Civil & Environm Engn ENAC, Appl Comp & Mech Lab IMAC, CH-1015 Lausanne, Switzerland. EM romain.pasquier@epfl.ch RI Acevedo, Claire/R-6711-2016; OI Acevedo, Claire/0000-0001-5425-3052; Smith, Ian/0000-0002-5033-2113 FU Swiss national Science Foundation [200020-144304] FX The authors acknowledge ICOM (Steel Structures Laboratory), EPFL for providing test results, bridge drawings, and monitoring data, and Yves Reuland for work on the truss-beam example. This work was partially funded by the Swiss national Science Foundation under contract no. 200020-144304. NR 35 TC 3 Z9 3 U1 4 U2 16 PU ASCE-AMER SOC CIVIL ENGINEERS PI RESTON PA 1801 ALEXANDER BELL DR, RESTON, VA 20191-4400 USA SN 1084-0702 EI 1943-5592 J9 J BRIDGE ENG JI J. Bridge Eng. PD NOV PY 2014 VL 19 IS 11 AR 04014045 DI 10.1061/(ASCE)BE.1943-5592.0000619 PG 10 WC Engineering, Civil SC Engineering GA AS0XG UT WOS:000343998500003 ER PT J AU Bai, XL Shrestha, SL Casey, FXM Hakk, H Fan, ZS AF Bai, Xuelian Shrestha, Suman L. Casey, Francis X. M. Hakk, Heldur Fan, Zhaosheng TI Modeling coupled sorption and transformation of 17 beta-estradiol-17-sulfate in soil-water systems SO JOURNAL OF CONTAMINANT HYDROLOGY LA English DT Article DE Hormone transport; Estrogen; Estrogen conjugates; 17 beta-Estradiol-17-sulfate ID AGRICULTURAL SOILS; STOCHASTIC RANKING; STEROID-HORMONES; ESTROGENS; TRANSPORT; FATE; TESTOSTERONE; ESTRADIOL; ESTRONE; MANURE AB Animal manure is the primary source of exogenous free estrogens in the environment, which are known endocrine-disrupting chemicals to disorder the reproduction system of organisms. Conjugated estrogens can act as precursors to free estrogens, which may increase the total estrogenicity in the environment. In this study, a comprehensive model was used to simultaneously simulate the coupled sorption and transformation of a sulfate estrogen conjugate, 17 beta-estradiol-17-sulfate (E2-17S), in various soil-water systems (non-sterile/sterile; topsoil/subsoil). The simulated processes included multiple transformation pathways (i.e. hydroxylation, hydrolysis, and oxidation) and mass transfer between the aqueous, reversibly sorbed, and irreversibly sorbed phases of all soils for E2-17S and its metabolites. The conceptual model was conceived based on a series of linear sorption and first-order transformation expressions. The model was inversely solved Using finite difference to estimate process parameters. A global optimization method was applied for the inverse analysis along with variable model restrictions to estimate 36 parameters. The model provided a satisfactory simultaneous fit (R-adj(2) = 0.93 and d = 0.87) of all the experimental data and reliable parameter estimates. This modeling study improved the understanding on fate and transport of estrogen conjugates under various soil-water conditions. (C) 2014 Elsevier B.V. All rights reserved. C1 [Bai, Xuelian; Casey, Francis X. M.] N Dakota State Univ, Dept Soil Sci, Fargo, ND 58108 USA. [Shrestha, Suman L.] Bayer CropSci, Res Triangle Pk, NC 27709 USA. [Hakk, Heldur] USDA ARS, Biosci Res Lab, Forgo, ND 58102 USA. [Fan, Zhaosheng] Argonne Natl Lab, Biosci Div, Argonne, IL 60439 USA. RP Casey, FXM (reprint author), N Dakota State Univ, Dept Soil Sci, POB 6050, Fargo, ND 58108 USA. EM Francis.Casey@ndsu.edu RI Casey, Francis/A-2135-2010 OI Casey, Francis/0000-0002-6035-7234 FU Agriculture and Food Research Initiative Competitive Grant from the USDA National Institute of Food and Agriculture [2010-65102-20400] FX The authors sincerely thank Mrs. Colleen Pfaff (Biosciences Research Laboratory, USDA-ARS, Fargo, ND) and Mr. Nathan Derby (Department of Soil Science, North Dakota State University, Fargo, ND) for their assistance on the research. We would like to acknowledge Dr. Jane Schuh (Department of Veterinary and Microbiological Sciences, North Dakota State University, Fargo, ND) for her support on the sterilization procedure. This project is supported by Agriculture and Food Research Initiative Competitive Grant No. 2010-65102-20400 from the USDA National Institute of Food and Agriculture. Mention of trade names or commercial products in this publication is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the USDA. USDA is an equal opportunity provider and employer. NR 38 TC 0 Z9 0 U1 3 U2 38 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0169-7722 EI 1873-6009 J9 J CONTAM HYDROL JI J. Contam. Hydrol. PD NOV 1 PY 2014 VL 168 BP 17 EP 24 DI 10.1016/j.jconhyd.2014.09.001 PG 8 WC Environmental Sciences; Geosciences, Multidisciplinary; Water Resources SC Environmental Sciences & Ecology; Geology; Water Resources GA AS7KT UT WOS:000344435800002 PM 25247675 ER PT J AU Winger, AM Heazlewood, JL Chan, LJG Petzold, CJ Permaul, K Singh, S AF Winger, A. M. Heazlewood, J. L. Chan, L. J. G. Petzold, C. J. Permaul, K. Singh, S. TI Secretome analysis of the thermophilic xylanase hyper-producer Thermomyces lanuginosus SSBP cultivated on corn cobs SO JOURNAL OF INDUSTRIAL MICROBIOLOGY & BIOTECHNOLOGY LA English DT Article DE Thermomyces lanuginosus; Fungal secretome; Hemicellulase; Lignocellulose; Industrial enzymes ID BIOCHEMICAL CHARACTERISTICS; EXTRACELLULAR PROTEOME; STATISTICAL-MODEL; FUNGUS; ENZYMES; PURIFICATION; DATABASE; HEMICELLULASES; INHIBITION; SUBSTRATE AB Thermomyces lanuginosus is a thermophilic fungus known for its ability to produce industrially important enzymes including large amounts of xylanase, the key enzyme in hemicellulose hydrolysis. The secretome of T. lanuginosus SSBP was profiled by shotgun proteomics to elucidate important enzymes involved in hemicellulose saccharification and to characterise the presence of other industrially interesting enzymes. This study reproducibly identified a total of 74 proteins in the supernatant following growth on corn cobs. An analysis of proteins revealed nine glycoside hydrolase (GH) enzymes including xylanase GH11, beta-xylosidase GH43, beta-glucosidase GH3, a-galactosidase GH36 and trehalose hydrolase GH65. Two commercially produced Thermomyces enzymes, lipase and amylase, were also identified. In addition, other industrially relevant enzymes not currently explored in Thermomyces were identified including glutaminase, fructose-bisphosphate aldolase and cyanate hydratase. Overall, these data provide insight into the novel ability of a cellulase-free fungus to utilise lignocellulosic material, ultimately producing a number of enzymes important to various industrial processes. C1 [Winger, A. M.; Permaul, K.; Singh, S.] Durban Univ Technol, Dept Biotechnol & Food Technol, ZA-4001 Durban, South Africa. [Heazlewood, J. L.; Chan, L. J. G.; Petzold, C. J.] Lawrence Berkeley Natl Lab, Joint BioEnergy Inst, Phys Biosciences Div, Berkeley, CA USA. RP Singh, S (reprint author), Durban Univ Technol, Dept Biotechnol & Food Technol, ZA-4001 Durban, South Africa. EM singhs@dut.ac.za RI Heazlewood, Joshua/A-2554-2008; OI Heazlewood, Joshua/0000-0002-2080-3826; Permaul, Kugen/0000-0001-5032-3092 FU DUT; National Research Foundation, Republic of South Africa; Office of Science, Office of Biological and Environmental Research, of the US Department of Energy [DE-AC02-05CH11231] FX The work conducted at the Durban University of Technology (DUT) was supported by grants from DUT and the National Research Foundation, Republic of South Africa. The work conducted by the Joint BioEnergy Institute was supported by the Office of Science, Office of Biological and Environmental Research, of the US Department of Energy under Contract No. DE-AC02-05CH11231. NR 41 TC 6 Z9 6 U1 4 U2 35 PU SPRINGER HEIDELBERG PI HEIDELBERG PA TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY SN 1367-5435 EI 1476-5535 J9 J IND MICROBIOL BIOT JI J. Ind. Microbiol. Biotechnol. PD NOV PY 2014 VL 41 IS 11 BP 1687 EP 1696 DI 10.1007/s10295-014-1509-1 PG 10 WC Biotechnology & Applied Microbiology SC Biotechnology & Applied Microbiology GA AS1TQ UT WOS:000344064800011 PM 25223615 ER PT J AU Ounzain, S Pezzuto, I Micheletti, R Burdet, F Sheta, R Nemir, M Gonzales, C Sarre, A Alexanian, M Blow, MJ May, D Johnson, R Dauvillier, J Pennacchio, LA Pedrazzini, T AF Ounzain, Samir Pezzuto, Iole Micheletti, Rudi Burdet, Frederic Sheta, Razan Nemir, Mohamed Gonzales, Christine Sarre, Alexandre Alexanian, Michael Blow, Matthew J. May, Dalit Johnson, Rory Dauvillier, Jerome Pennacchio, Len A. Pedrazzini, Thierry TI Functional importance of cardiac enhancer-associated noncoding RNAs in heart development and disease SO JOURNAL OF MOLECULAR AND CELLULAR CARDIOLOGY LA English DT Article DE Cardiac development; Heart failure; Gene regulation; Gene regulatory networks; Enhancers; Long noncoding RNA (lncRNAs) ID GENE-EXPRESSION; TRANSCRIPTION; CHROMATIN; MOUSE; CELLS; DIFFERENTIATION; LINEAGE; GENOME; HYPERTROPHY; PROMOTERS AB The key information processing units within gene regulatory networks are enhancers. Enhancer activity is associated with the production of tissue-specific noncoding RNAs, yet the existence of such transcripts during cardiac development has not been established. Using an integrated genomic approach, we demonstrate that fetal cardiac enhancers generate long noncoding RNAs (lncRNAs) during cardiac differentiation and morphogenesis. Enhancer expression correlates with the emergence of active enhancer chromatin states, the initiation of RNA polymerase II at enhancer loci and expression of target genes. Orthologous human sequences are also transcribed in fetal human hearts and cardiac progenitor cells. Through a systematic bioinformatic analysis, we identified and characterized, for the first time, a catalog of lncRNAs that are expressed during embryonic stem cell differentiation into cardiomyocytes and associated with active cardiac enhancer sequences. RNA-sequencing demonstrates that many of these transcripts are polyadenylated, multi-exonic long noncoding RNAs. Moreover, knockdown of two enhancer-associated lncRNAs resulted in the specific downregulation of their predicted target genes. Interestingly, the reactivation of the fetal gene program, a hallmark of the stress response in the adult heart, is accompanied by increased expression of fetal cardiac enhancer transcripts. Altogether, these findings demonstrate that the activity of cardiac enhancers and expression of their target genes are associated with the production of enhancer-derived lncRNAs. (c) 2014 The Authors. Published by Elsevier Ltd. C1 [Ounzain, Samir; Pezzuto, Iole; Micheletti, Rudi; Sheta, Razan; Nemir, Mohamed; Gonzales, Christine; Alexanian, Michael; Pedrazzini, Thierry] Univ Lausanne, Dept Med, Expt Cardiol Unit, Sch Med, Lausanne, Switzerland. [Burdet, Frederic; Dauvillier, Jerome] Univ Lausanne, Swiss Inst Bioinformat, VitalIT, Lausanne, Switzerland. [Sarre, Alexandre] Univ Lausanne, Cardiovasc Assessment Facil, Lausanne, Switzerland. [Blow, Matthew J.; May, Dalit; Pennacchio, Len A.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Genom Div, Berkeley, CA 94720 USA. [Blow, Matthew J.; May, Dalit; Pennacchio, Len A.] US DOE, Joint Genome Inst, Walnut Creek, CA USA. [Johnson, Rory] Ctr Genom Regulat, Bioinformat & Genom Grp, Barcelona, Spain. RP Ounzain, S (reprint author), Univ Lausanne, Dept Med, Expt Cardiol Unit, Sch Med, Lausanne, Switzerland. EM samir.ounzain@chuv.ch; thierry.pedrazzini@chuv.ch RI Blow, Matthew/G-6369-2012; OI Blow, Matthew/0000-0002-8844-9149; Johnson, Rory/0000-0003-4607-2782 FU Swiss National Science Foundation [406340-128129]; NHGRI [R01HG003988]; United States Department of Energy Joint Genome Institute, Department of Energy [DE-AC02-05CH11231] FX This Work was supported by grants from the Swiss National Science Foundation (T.P., grant no 406340-128129) within the frame of the National Research Program 63 on "Stem Cells and Regenerative Medicine". L.A.P. was supported by NHGRI grant R01HG003988. L.A.P., D.M. and M.J.B. performed work at Lawrence Berkeley National Laboratory and at the United States Department of Energy Joint Genome Institute, Department of Energy Contract DE-AC02-05CH11231, University of California. NR 57 TC 38 Z9 42 U1 2 U2 7 PU ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD PI LONDON PA 24-28 OVAL RD, LONDON NW1 7DX, ENGLAND SN 0022-2828 EI 1095-8584 J9 J MOL CELL CARDIOL JI J. Mol. Cell. Cardiol. PD NOV PY 2014 VL 76 BP 55 EP 70 DI 10.1016/j.yjmcc.2014.08.009 PG 16 WC Cardiac & Cardiovascular Systems; Cell Biology SC Cardiovascular System & Cardiology; Cell Biology GA AS3UF UT WOS:000344202800007 PM 25149110 ER PT J AU Lee, KS Kang, JW Cha, JH Kim, KS AF Lee, Ki Sun Kang, Jeong Won Cha, Jong-Ho Kim, Ki-Sub TI Evolution of CdTe Nanoparticles Into Nanowires via Self-Assembly SO JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY LA English DT Article DE CdTe; Self-Assembly; Self-Organization; Nanowire; Nanoparticle ID NANOCRYSTALS; NANORODS; SHEETS; GROWTH AB Cadmium telluride (CdTe) nanowires were successfully synthesized from individual nanoparticles via self-assembly, and the evolutionary process was investigated. The oxidation of tellurium ions in CdTe nanoparticles under dark conditions led to the assembly of straight nanowires made of several layers of individual nanoparticles. Transmission electron microscopy and scanning electron microscopy were performed to characterize the synthesized nanostructures. The length of the NWs assembled from CdTe NPs ranged from 0.5 to 30 mu m. Unlike generally prepared NWs, these NWs were made from individual NPs layered on top of each other. Remarkably, the assembly of individual NPs formed bundles during the intermediate steps before they unraveled into individual NWs. Both control of the amount of stabilizer and oxidation of Te ions acted as driving forces to form NWs. Thus, small modifications in synthesis yielded a major difference in the final nanomaterial structure. The suggested synthetic procedure provides a viable pathway for the fabrication of nanomaterials. C1 [Lee, Ki Sun; Kim, Ki-Sub] Korea Natl Univ Transportat, Dept Chem & Biol Engn, Chungju 380702, South Korea. [Kang, Jeong Won] Korea Natl Univ Transportat, Grad Sch Transportat, Dept Transportat Syst Engn, Uiwang Si 437763, Gyeonggi Do, South Korea. [Kang, Jeong Won] Korea Natl Univ Transportat, Grad Sch, Dept IT Convergence, Chungju 380702, South Korea. [Cha, Jong-Ho] US DOE, Natl Energy Technol Lab, Morgantown, WV 26507 USA. RP Kang, JW (reprint author), Korea Natl Univ Transportat, Grad Sch Transportat, Dept Transportat Syst Engn, Uiwang Si 437763, Gyeonggi Do, South Korea. FU Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology [2012R1A1A2041510]; MSIP (Ministry of Science, ICT and Future Planning), Korea, under the CITRC (Convergence Information Technology Research Center) support program [NIPA-2013-H0401-13-2011] FX This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2012R1A1A2041510) and partly supported by the MSIP (Ministry of Science, ICT and Future Planning), Korea, under the CITRC (Convergence Information Technology Research Center) support program (NIPA-2013-H0401-13-2011) supervised by the NIPA (National IT Industry Promotion Agency). NR 17 TC 1 Z9 1 U1 1 U2 10 PU AMER SCIENTIFIC PUBLISHERS PI VALENCIA PA 26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USA SN 1533-4880 EI 1533-4899 J9 J NANOSCI NANOTECHNO JI J. Nanosci. Nanotechnol. PD NOV PY 2014 VL 14 IS 11 BP 8863 EP 8866 DI 10.1166/jnn.2014.10005 PG 4 WC Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter SC Chemistry; Science & Technology - Other Topics; Materials Science; Physics GA AS2RE UT WOS:000344126500134 PM 25958618 ER PT J AU Koschny, R Boehm, C Sprick, MR Haas, TL Holland, H Xu, LX Krupp, W Mueller, WC Bauer, M Koschny, T Keller, M Sinn, P Meixensberger, J Walczak, H Ganten, TM AF Koschny, Ronald Boehm, Christina Sprick, Martin R. Haas, Tobias L. Holland, Heidrun Xu, Li-Xin Krupp, Wolfgang Mueller, Wolf C. Bauer, Manfred Koschny, Thomas Keller, Marius Sinn, Peter Meixensberger, Juergen Walczak, Henning Ganten, Tom M. TI Bortezomib Sensitizes Primary Meningioma Cells to TRAIL-Induced Apoptosis by Enhancing Formation of the Death-Inducing Signaling Complex SO JOURNAL OF NEUROPATHOLOGY AND EXPERIMENTAL NEUROLOGY LA English DT Article DE Apoptosis; Bortezomib; Chemotherapy; Meningioma; Primary meningioma cells; TRAIL ID HEPATOCELLULAR-CARCINOMA CELLS; MULTIPLE-MYELOMA; CHEMOTHERAPEUTIC DRUGS; ANTICANCER THERAPY; MEDIATED APOPTOSIS; CANCER-CELLS; TUMOR-CELLS; ACTIVATION; RESISTANCE; INHIBITION AB A meningioma is the most common primary intracranial tumor in adults. Here, we investigated the therapeutic potential of the tumor necrosis factor-related apoptosis-inducing ligand (TRAIL) in 37 meningiomas. Freshly isolated primary meningioma cells were treated with TRAIL with or without different sensitizing protocols, and apoptotic cell death was then quantified. Mechanisms of TRAIL sensitization were determined by a combination of Western blotting, flow cytometry, receptor complex immunoprecipitation, and siRNA-mediated knockdown experiments. Tumor necrosis factor-related apoptosis-inducing ligand receptor expression was analyzed using immunohistochemistry and quantified by an automated software-based algorithm. Primary tumor cells from 11 (29.7%) tumor samples were sensitive to TRAIL-induced apoptosis, 12 (32.4%) were intermediate TRAIL resistant, and 14 (37.8%) were completely TRAIL resistant. We tested synergistic apoptosis-inducing cotreatment strategies and determined that only the proteasome inhibitor bortezomib potently enhanced expression of the TRAIL receptors TRAIL-R1 and/or TRAIL-R2, the formation of the TRAIL death-inducing signaling complex, and activation of caspases; this treatment resulted in sensitization of all TRAIL-resistant meningioma samples to TRAIL-induced apoptosis. Bortezomib pretreatment induced NOXA expression and downregulated c-FLIP, neither of which caused the TRAIL-sensitizing effect. Native TRAIL receptor expression could not predict primary TRAIL sensitivity. This first report on TRAIL sensitivity of primary meningioma cells demonstrates that TRAIL/bortezomib cotreatment may represent a novel therapeutic option for meningiomas. C1 [Koschny, Ronald; Ganten, Tom M.] Univ Heidelberg Hosp, Dept Gastroenterol, Heidelberg, Germany. [Boehm, Christina] German Canc Res Ctr, Div Signaling & Funct Genom, Heidelberg, Germany. [Boehm, Christina] Heidelberg Univ, Dept Cell & Mol Biol, Fac Med Mannheim, D-69115 Heidelberg, Germany. [Sprick, Martin R.] German Canc Res Ctr Heidelberg, HI STEM GGmbH, Heidelberg, Germany. [Haas, Tobias L.] Natl Canc Inst Regina Elena, Rome, Italy. [Holland, Heidrun; Xu, Li-Xin] Univ Leipzig, Translat Ctr Regenerat Med Leipzig, D-04109 Leipzig, Germany. [Holland, Heidrun; Xu, Li-Xin] Univ Leipzig, Fac Med, D-04109 Leipzig, Germany. [Xu, Li-Xin; Krupp, Wolfgang; Meixensberger, Juergen] Univ Leipzig, Dept Neurosurg, D-04109 Leipzig, Germany. [Mueller, Wolf C.; Bauer, Manfred] Univ Leipzig, Dept Neuropathol, D-04109 Leipzig, Germany. [Koschny, Thomas] US DOE, Ames Lab, Ames, IA 50011 USA. [Koschny, Thomas] Iowa State Univ, Dept Phys & Astron, Ames, IA USA. [Keller, Marius] Univ Heidelberg Hosp, Dept Cardiol, Heidelberg, Germany. [Sinn, Peter] Univ Heidelberg Hosp, Dept Pathol, Heidelberg, Germany. [Walczak, Henning] UCL Canc Inst, Ctr Cell Death Canc & Inflammat, London, England. RP Koschny, R (reprint author), Dept Internal Med, Neuenheimer Feld 410, D-69120 Heidelberg, Germany. EM ronald.koschny@med.uni-heidelberg.de RI Sprick, Martin/A-8611-2008 OI Sprick, Martin/0000-0001-9691-7574 FU Cancer Research UK FX Henning Walczak is supported by a Cancer Research UK program grant. NR 43 TC 6 Z9 7 U1 0 U2 6 PU LIPPINCOTT WILLIAMS & WILKINS PI PHILADELPHIA PA 530 WALNUT ST, PHILADELPHIA, PA 19106-3621 USA SN 0022-3069 EI 1554-6578 J9 J NEUROPATH EXP NEUR JI J. Neuropathol. Exp. Neurol. PD NOV PY 2014 VL 73 IS 11 BP 1034 EP 1046 DI 10.1097/NEN.0000000000000129 PG 13 WC Clinical Neurology; Neurosciences; Pathology SC Neurosciences & Neurology; Pathology GA AS5YP UT WOS:000344342700005 PM 25289891 ER PT J AU Amoroso, J Marra, JC Tang, M Lin, Y Chen, FL Su, D Brinkman, KS AF Amoroso, Jake Marra, James C. Tang, Ming Lin, Ye Chen, Fanglin Su, Dong Brinkman, Kyle S. TI Melt processed multiphase ceramic waste forms for nuclear waste immobilization SO JOURNAL OF NUCLEAR MATERIALS LA English DT Article ID SYNROC; HOLLANDITE; CESIUM AB Ceramic waste forms are promising hosts for nuclear waste immobilization as they have the potential for increased durability and waste loading compared with conventional borosilicate glass waste forms. Ceramics are generally processed using hot pressing, spark plasma sintering, and conventional solid-state reaction, however such methods can be prohibitively expensive or impractical at production scales. Recently, melt processing has been investigated as an alternative to solid-state sintering methods. Given that melter technology is currently in use for High Level Waste (HLW) vitrification in several countries, the technology readiness of melt processing appears to be advantageous over sintering methods. This work reports the development of candidate multi-phase ceramic compositions processed from a melt. Cr additions, developed to promote the formation and stability of a Cs containing hollandite phase were successfully incorporated into melt processed multi-phase ceramics. Control of the reduction-oxidation (Redox) conditions suppressed undesirable Cs-Mo containing phases, and additions of Al and Fe reduced the melting temperature. (C) 2014 Elsevier B.V. All rights reserved. C1 [Amoroso, Jake; Marra, James C.] Savannah River Natl Lab, Aiken, SC 29808 USA. [Tang, Ming] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Lin, Ye; Chen, Fanglin] Univ S Carolina, Columbia, SC 29208 USA. [Su, Dong] Brookhaven Natl Lab, Upton, NY 11973 USA. [Brinkman, Kyle S.] Clemson Univ, Clemson, SC 29634 USA. RP Amoroso, J (reprint author), Savannah River Natl Lab, Aiken, SC 29808 USA. EM jake.amoroso@srs.gov RI Chen, Fanglin/K-1039-2012; OI Chen, Fanglin/0000-0001-9942-8872; Brinkman, Kyle/0000-0002-2219-1253 FU U.S. Department of Energy [DE-AC09-08SR22470]; U.S. Department of Energy, Office of Basic Energy Sciences [DE-AC02-98CH10886]; DOE-NE Materials Recovery and Waste Form Development program FX This document was prepared in conjunction with work accomplished under Contract No. DE-AC09-08SR22470 with the U.S. Department of Energy. TEM was carried out at the Center for Functional Nanomaterials, Brookhaven National Laboratory, which is supported by the U.S. Department of Energy, Office of Basic Energy Sciences, under contract no. DE-AC02-98CH10886. The authors acknowledge gratefully the financial support of the DOE-NE Materials Recovery and Waste Form Development program including program support from James Bresee, Kimberly Gray, Terry Todd and John Vienna. David Missimer is acknowledged gratefully for processing and characterization work. NR 19 TC 7 Z9 7 U1 9 U2 38 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-3115 EI 1873-4820 J9 J NUCL MATER JI J. Nucl. Mater. PD NOV PY 2014 VL 454 IS 1-3 BP 12 EP 21 DI 10.1016/j.jnucmat.2014.07.035 PG 10 WC Materials Science, Multidisciplinary; Nuclear Science & Technology SC Materials Science; Nuclear Science & Technology GA AS7IA UT WOS:000344428900003 ER PT J AU Angle, JP Nelson, AT Men, D Mecartney, ML AF Angle, Jesse P. Nelson, Andrew T. Men, Danju Mecartney, Martha L. TI Thermal measurements and computational simulations of three-phase (CeO2-MgAl2O4-CeMgAl11O19) and four-phase (3Y-TZP-Al2O3-MgAl2O4-LaPO4) composites as surrogate inert matrix nuclear fuel SO JOURNAL OF NUCLEAR MATERIALS LA English DT Article ID OXIDE FUELS; CONDUCTIVITY; RESISTANCE; MICROSTRUCTURES; CERAMICS; BEHAVIOR; ALUMINA; PHASE AB This study investigates the temperature dependent thermal conductivity of multiphase ceramic composites for simulated inert matrix nuclear fuel. Fine grained composites were made of CeO2-MgAl2O4-CeMgAl11O19 or 3Y-TZP-Al2O3-MgAl2O4-LaPO4. CeO2 and 3Y-TZP are used as UO2 surrogates due to their similar structures and low thermal conductivities. Laser flash analysis from room temperature to 1273K (1000 degrees C) was used to determine the temperature dependent thermal conductivity. A computational approach using Object Oriented Finite Element Analysis Version 2 (OOF2) was employed to simulate the composite thermal conductivity based on the microstructure. Observed discrepancies between experimental and simulated thermal conductivities at low temperature may be due to Kapitza resistance; however, there is less than 3% deviation between models and experiments above 673 K (400 degrees C) for both compositions. When the surrogate phase was replaced with UO2 in the computational model for the four-phase composite, a 12-16% increase in thermal conductivity resulted compared to single phase UO2, in the range of 673-1273 K (400-1000 degrees C). This computational approach may be potentially viable for the high-throughput evaluation of composite systems and the strategic selection of inert phases without extensive sample fabrication during the initial development stages of composite nuclear fuel design. (C) 2014 Elsevier B.V. All rights reserved. C1 [Angle, Jesse P.; Men, Danju; Mecartney, Martha L.] Univ Calif Irvine, Dept Chem Engn & Mat Sci, Irvine, CA 92697 USA. [Nelson, Andrew T.] Los Alamos Natl Lab, Mat Sci & Technol Div, Los Alamos, NM 87545 USA. RP Mecartney, ML (reprint author), Univ Calif Irvine, Dept Chem Engn & Mat Sci, Irvine, CA 92697 USA. EM martham@uci.edu FU U.S. Department of Energy [DE-NE0000711]; NSF [DMR-0606063]; agency of the United States Government; U.S. Department of Education Graduate Assistance in Areas of National Need (GAANN) Fellowship FX This research is supported by the U.S. Department of Energy funding under grant DE-NE0000711. Some of the materials were developed under an NSF DMR-0606063 grant. This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. The authors acknowledge the use of the UC Irvine Laboratory for Electron and X-Ray instrumentation (LEXI). A U.S. Department of Education Graduate Assistance in Areas of National Need (GAANN) Fellowship provided additional graduate student support for JPA. NR 33 TC 1 Z9 1 U1 4 U2 34 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-3115 EI 1873-4820 J9 J NUCL MATER JI J. Nucl. Mater. PD NOV PY 2014 VL 454 IS 1-3 BP 69 EP 76 DI 10.1016/j.jnucmat.2014.07.039 PG 8 WC Materials Science, Multidisciplinary; Nuclear Science & Technology SC Materials Science; Nuclear Science & Technology GA AS7IA UT WOS:000344428900010 ER PT J AU Perron, A Turchi, PEA Landa, A Soderlind, P Ravat, B Oudot, B Delaunay, F Kurata, M AF Perron, A. Turchi, P. E. A. Landa, A. Soederlind, P. Ravat, B. Oudot, B. Delaunay, F. Kurata, M. TI Thermodynamic re-assessment of the Pu-U system and its application to the ternary Pu-U-Ga system SO JOURNAL OF NUCLEAR MATERIALS LA English DT Article ID PHASE-TRANSFORMATIONS; PLUTONIUM-URANIUM; MATERIALS SCIENCE; ACTINIDE ALLOYS; THERMO-CALC; ZR SYSTEM; EQUILIBRIA; DIAGRAM; CHALLENGES AB Phase diagram and thermodynamic properties of the Plutonium-Uranium (Pu-U) system have been successfully re-assessed using the CALPHAD method with input from ab initio electronic-structure calculations for the bcc phase (gamma-U, is an element of-Pu). Results and methodology are discussed and compared with previous assessments. In addition, the already assessed Pu-Ga (Gallium) and U-Ga data are combined to build the Pu-U-Ga thermodynamic database. The predictions made using this database indicate that a small amount of U impacts the (delta-Pu) Pu-Ga phase stability by precipitating the complicated eta and zeta phases that exist in the Pu-U system. Finally, the present investigation provides guidelines for further experimental studies. Published by Elsevier B.V. C1 [Perron, A.; Turchi, P. E. A.; Landa, A.; Soederlind, P.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Ravat, B.; Oudot, B.; Delaunay, F.] CEA Ctr Valduc, F-21120 Is Sur Tille, France. [Kurata, M.] JAEA, Nucl Sci & Engn Directorate, Tokai, Ibaraki 3191195, Japan. RP Perron, A (reprint author), Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. EM perron1@llni.gov OI Perron, Aurelien/0000-0002-5280-003X FU U.S Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; Laboratory Directed Research and Development Program [12-SI-008]; CEA-Centre de Valduc (France); Post-doctoral program at LLNL; DOE-NNSA; CEA-DAM FX This work was performed under the auspices of the U.S Department of Energy by Lawrence Livermore National Laboratory under contract DE-AC52-07NA27344. Work at LLNL was funded by the Laboratory Directed Research and Development Program under project tracking code 12-SI-008. This work was done as part of the international agreement on cooperation between DOE-NNSA and CEA-DAM in fundamental science supporting stockpile stewardship. A.P. gratefully acknowledges the financial support from the CEA-Centre de Valduc (France), the Post-doctoral program at LLNL, and M. Fluss for a thorough reading of the manuscript. NR 48 TC 3 Z9 3 U1 2 U2 23 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-3115 EI 1873-4820 J9 J NUCL MATER JI J. Nucl. Mater. PD NOV PY 2014 VL 454 IS 1-3 BP 81 EP 95 DI 10.1016/j.jnucmat.2014.07.051 PG 15 WC Materials Science, Multidisciplinary; Nuclear Science & Technology SC Materials Science; Nuclear Science & Technology GA AS7IA UT WOS:000344428900012 ER PT J AU Yang, Y Lo, WY Dickerson, C Allen, TR AF Yang, Yong Lo, Wei-Yang Dickerson, Clayton Allen, Todd R. TI Stoichiometry effect on the irradiation response in the microstructure of zirconium carbides SO JOURNAL OF NUCLEAR MATERIALS LA English DT Article ID COATED FUEL-PARTICLES; ZRC; VOIDS AB Zone-refined ultra high pure ZrC with five C/Zr ratios ranging from 0.84 to 1.17 was irradiated using a 2 MeV proton beam at 1125 degrees C. The stoichiometry effect on the irradiation response of ZrC microstructure was examined using transmission electron microscopy following the irradiation. The irradiated microstructures generally feature a high density of perfect dislocation loops particularly at away from the graphite precipitates, and the C/Zr ratio shows a notable effect on the size and density of dislocation loops. The dislocation loops are identified as interstitial type perfect loops, and it was indirectly proved that the dislocation loop core likely consists of carbon atoms. Graphite precipitates that form with excess carbon in the super-stoichiometric ZrC are detrimental, and the dramatic increases in the size of and density of dislocation loops in the vicinity of graphite precipitates in ZrC phase were observed. Irradiation-induced faceted voids were only observed in ZrC0.95, which is attributed to the pre-existing dislocation lines as biased sinks for vacancies. (C) 2014 Elsevier B.V. All rights reserved. C1 [Yang, Yong; Lo, Wei-Yang] Univ Florida, Nucl Engn Program, Gainesville, FL 32611 USA. [Dickerson, Clayton] Argonne Natl Lab, Lemont, IL 60439 USA. [Allen, Todd R.] Univ Wisconsin, Dept Engn Phys, Madison, WI 53706 USA. [Allen, Todd R.] Idaho Natl Lab, Idaho Falls, ID 83415 USA. RP Yang, Y (reprint author), Univ Florida, Nucl Engn Program, Gainesville, FL 32611 USA. EM yongyang@ufl.edu OI Allen, Todd/0000-0002-2372-7259 FU U.S. Department of Energy FX The present study is the result of "Deep Burn: Development of Transuranic Fuel and Fuel Cycles for High Temperature Gas-Cooled Reactor," supported by the U.S. Department of Energy. The authors would like to thank Y. Katoh, J.D. Hunn of the Oak Ridge National Laboratory for providing the zone-refined ZrC materials. NR 18 TC 5 Z9 5 U1 4 U2 18 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-3115 EI 1873-4820 J9 J NUCL MATER JI J. Nucl. Mater. PD NOV PY 2014 VL 454 IS 1-3 BP 130 EP 135 DI 10.1016/j.jnucmat.2014.07.071 PG 6 WC Materials Science, Multidisciplinary; Nuclear Science & Technology SC Materials Science; Nuclear Science & Technology GA AS7IA UT WOS:000344428900018 ER PT J AU Mohamed, W Yun, D Mo, K Pellin, MJ Billone, MC Almer, J Yacout, AM AF Mohamed, Walid Yun, Di Mo, Kun Pellin, Michael J. Billone, Michael C. Almer, Jonathan Yacout, Abdellatif M. TI Depth profile of oxide volume fractions of Zircaloy-2 in. high-temperature steam: An in-situ synchrotron radiation study SO JOURNAL OF NUCLEAR MATERIALS LA English DT Article ID X-RAY-DIFFRACTION; OXIDATION-KINETICS; ZIRCONIUM ALLOYS; QUANTITATIVE MEASUREMENT; INDUCED MARTENSITE; PHASE-DIAGRAM; CORROSION; PRESSURE; STRAIN; STEEL AB To study the steam oxidation behavior of Zircaloy-2, a high-energy synchrotron X-ray diffraction technique was applied to perform an in-situ oxidation measurement. The depth profiles of oxide volume fractions were obtained at both 600 and 800 degrees C. Multiple layers, including ZrO2 scale, (beta + beta) Zr matrix with ZrO2 incursions, and (alpha + beta) Zr matrix, were mapped according to the volume fraction of each phase. The volume fractions of these phases were observed to change gradually with different distances to the surface, without a sharp edge distinguishing each of the layers. The ZrO2 consisted of tetragonal and monoclinic crystal structures, which were observed to coexist with different ratios of volume fractions in depth. The higher amount of tetragonal ZrO2 observed in the very inner region of the oxidizing Zircaloy sample indicates that the tetragonal crystal structure is the ab initio phase type, in which new oxide molecules form at the metal-oxide interface. (C) 2014 Elsevier B.V. All rights reserved. C1 [Mohamed, Walid; Yun, Di; Mo, Kun; Billone, Michael C.; Yacout, Abdellatif M.] Argonne Natl Lab, Nucl Engn Div, Argonne, IL 60439 USA. [Pellin, Michael J.] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA. [Almer, Jonathan] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA. RP Mo, K (reprint author), Argonne Natl Lab, Nucl Engn Div, Argonne, IL 60439 USA. EM kunmo@anl.gov RI Pellin, Michael/B-5897-2008 OI Pellin, Michael/0000-0002-8149-9768 FU U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357] FX This work was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. NR 35 TC 2 Z9 2 U1 1 U2 21 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-3115 EI 1873-4820 J9 J NUCL MATER JI J. Nucl. Mater. PD NOV PY 2014 VL 454 IS 1-3 BP 192 EP 199 DI 10.1016/j.jnucmat.2014.07.018 PG 8 WC Materials Science, Multidisciplinary; Nuclear Science & Technology SC Materials Science; Nuclear Science & Technology GA AS7IA UT WOS:000344428900028 ER PT J AU Kim, YS Park, JM Lee, KH Yoo, BO Ryu, HJ Ye, B AF Kim, Yeon Soo Park, J. M. Lee, K. H. Yoo, B. O. Ryu, H. J. Ye, B. TI In-pile test results of U-silicide or U-nitride coated U-7Mo particle dispersion fuel in Al SO JOURNAL OF NUCLEAR MATERIALS LA English DT Article ID INTERACTION LAYER GROWTH; MO DISPERSION; DEGREES-C; ALLOY; SI; INTERDIFFUSION; URANIUM; IRRADIATION; ALUMINUM; MATRIX AB U-silicide or U-nitride coated U-Mo particle dispersion fuel in Al (U-Mo/Al) was in-pile tested to examine the effectiveness of the coating as a diffusion barrier between the U-7Mo fuel kernels and Al matrix. This paper reports the PIE data and analyses focusing on the effectiveness of the coating in terms of interaction layer (IL) growth and general fuel performance. The U-silicide coating showed considerable success, but it also provided evidence for additional improvement for coating process. The U-nitride coated specimen showed largely inefficient results in reducing IL growth. From the test, important observations were also made that can be utilized to improve U-Mo/Al fuel performance. The heating process for coating turned out to be beneficial to suppress fuel swelling. The use of larger fuel particles confirmed favorable effects on fuel performance. (C)2014 Elsevier B.V. All rights reserved. C1 [Kim, Yeon Soo; Ye, B.] Argonne Natl Lab, Argonne, IL 60439 USA. [Park, J. M.; Lee, K. H.; Yoo, B. O.] Korea Atom Energy Res Inst, Taejon 305353, South Korea. [Ryu, H. J.] Korea Adv Inst Sci & Technol, Dept Nucl & Quantum Engn, Taejon 305701, South Korea. RP Kim, YS (reprint author), Argonne Natl Lab, 9700 S Cass Ave, Argonne, IL 60439 USA. EM yskim@anl.gov RI RYU, HO JIN/J-2764-2013 OI RYU, HO JIN/0000-0002-3387-7381 FU National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future Planning (MSIP) of Republic of Korea [NRF-2013M2A8A1041241]; UChicago Argonne, LCC as Operator of Argonne National Laboratory [DE-AC-02-06CH11357] FX This study was supported by the National Research Foundation of Korea (NRF) grant funded by the Ministry of Science, ICT and Future Planning (MSIP) of Republic of Korea (NRF-2013M2A8A1041241) and the ANL contribution was supported by the UChicago Argonne, LCC as Operator of Argonne National Laboratory under Contract No. DE-AC-02-06CH11357 between UChicago Argonne, LLC and the US Department of Energy. NR 52 TC 4 Z9 4 U1 2 U2 11 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-3115 EI 1873-4820 J9 J NUCL MATER JI J. Nucl. Mater. PD NOV PY 2014 VL 454 IS 1-3 BP 238 EP 246 DI 10.1016/j.jnucmat.2014.08.005 PG 9 WC Materials Science, Multidisciplinary; Nuclear Science & Technology SC Materials Science; Nuclear Science & Technology GA AS7IA UT WOS:000344428900034 ER PT J AU Pakarinen, J Khafizov, M He, LF Wetteland, C Gan, J Nelson, AT Hurley, DH El-Azab, A Allen, TR AF Pakarinen, Janne Khafizov, Marat He, Lingfeng Wetteland, Chris Gan, Jian Nelson, Andrew T. Hurley, David H. El-Azab, Anter Allen, Todd R. TI Microstructure changes and thermal conductivity reduction in UO2 following 3.9 MeV He2+ ion irradiation SO JOURNAL OF NUCLEAR MATERIALS LA English DT Article ID URANIUM-DIOXIDE; SINGLE-CRYSTALS; SOLID-SOLUTIONS; NUCLEAR-FUELS; BURN-UP; LATTICE; CERAMICS; EVOLUTION; BEHAVIOR; DEFECTS AB The microstructural changes and associated effects on thermal conductivity were examined in UO2 after irradiation using 3.9 MeV He2+ ions. Lattice expansion of UO2 was observed in X-ray diffraction after ion irradiation up to 5 x 1016 He2+/cm(2) at low-temperature (<200 degrees C). Transmission electron microscopy (TEM) showed homogenous irradiation damage across an 8 mu m thick plateau region, which consisted of small dislocation loops accompanied by dislocation segments. Dome-shaped blisters were observed at the peak damage region (depth around 8.5 mu m) in the sample subjected to 5 x 10(16) He2+/cm(2), the highest fluence reached, while similar features were not detected at 9 x 10(15) He2+/cm(2). Laser-based thermoreflectance measurements showed that the thermal conductivity for the irradiated layer decreased about 55% for the high fluence sample and 35% for the low fluence sample as compared to an un-irradiated reference sample. Detailed analysis for the thermal conductivity indicated that the conductivity reduction was caused by the irradiation induced point defects. (C) 2014 Elsevier B.V. All rights reserved. C1 [Pakarinen, Janne; He, Lingfeng; Allen, Todd R.] Univ Wisconsin, Dept Engn Phys, Madison, WI 53706 USA. [Khafizov, Marat; Gan, Jian; Hurley, David H.; Allen, Todd R.] Idaho Natl Lab, Idaho Falls, ID 83415 USA. [Wetteland, Chris] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA. [Nelson, Andrew T.] Los Alamos Natl Lab, Div Mat Sci & Technol, Los Alamos, NM 87545 USA. [El-Azab, Anter] Purdue Univ, Sch Nucl Engn, W Lafayette, IN 47907 USA. RP Pakarinen, J (reprint author), SCK CEN, Belgian Nucl Res Ctr, Boeretang 200, B-2400 Mol, Belgium. EM jmpaka@gmail.com RI Khafizov, Marat/B-3744-2012; OI Khafizov, Marat/0000-0001-8171-3528; Allen, Todd/0000-0002-2372-7259; He, Lingfeng/0000-0003-2763-1462 FU Center for Materials Science of Nuclear Fuel, Energy Frontier Research Center; U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences; U.S. Department of Energy, Office of Nuclear Energy under DOE Idaho Operations Office, ATR National Scientific [DE-AC07-051D14517] FX This work was supported as a part of the Center for Materials Science of Nuclear Fuel, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. The FIB and TEM work was supported by the U.S. Department of Energy, Office of Nuclear Energy under DOE Idaho Operations Office Contract DE-AC07-051D14517, as part of an ATR National Scientific User Facility experiment. NR 42 TC 6 Z9 6 U1 5 U2 36 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-3115 EI 1873-4820 J9 J NUCL MATER JI J. Nucl. Mater. PD NOV PY 2014 VL 454 IS 1-3 BP 283 EP 289 DI 10.1016/j.jnucmat.2014:07.053 PG 7 WC Materials Science, Multidisciplinary; Nuclear Science & Technology SC Materials Science; Nuclear Science & Technology GA AS7IA UT WOS:000344428900039 ER PT J AU Turchi, PEA Ivashchenko, VI AF Turchi, P. E. A. Ivashchenko, V. I. TI First-principles study of the Pd-Si system and Pd(001)/SiC(001) hetero-structure SO JOURNAL OF NUCLEAR MATERIALS LA English DT Article ID CRYSTAL-STRUCTURE; C SYSTEM AB First-principles molecular dynamics simulations of the Pd(001)/3C-SiC(001) nano-layered structure were carried out at different temperatures ranging from 300 to 2100 K. Various PdSi (Pnma, Fm3m, p6m2, pm3m), Pd2Si (P62m, P6(3)/mmc, p3m1, P31m) and Pd3Si (Pnma, P6(3)22, pm3m, I4/mmm) structures under pressure were studied to identify the structure of the Pd/Si and Pd/C interfaces in the Pd/SiC systems at high temperatures. It was found that a large atomic mixing at the Pd/Si interface occurred at 1500-1800K, whereas the Pd/C interface remained sharp even at the highest temperature of 2100 K. At the Pd/C interface, voids and a graphite-like clustering were detected. Palladium and silicon atoms interact at the Pd/Si interface to mostly form C22-Pd2Si and D0(11)-Pd3Si fragments, in agreement with experiment. (C) 2014 Elsevier B.V. All rights reserved. C1 [Turchi, P. E. A.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. [Ivashchenko, V. I.] NAS Ukraine, Inst Problems Mat Sci, UA-03142 Kiev, Ukraine. RP Turchi, PEA (reprint author), Lawrence Livermore Natl Lab, L-352,7000 East Ave, Livermore, CA 94551 USA. FU Laboratory Directed Research and Development Program at LLNL [12-SI-008]; STCU [5539]; U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX The work of P.T. was performed under the auspices of the U.S. Department of Energy by the Lawrence Livermore National Laboratory under contract No. DE-AC52-07NA27344, and supported by the Laboratory Directed Research and Development Program at LLNL under project tracking code 12-SI-008. The work of V.I. was supported by the STCU contract No. 5539. NR 17 TC 2 Z9 2 U1 2 U2 16 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-3115 EI 1873-4820 J9 J NUCL MATER JI J. Nucl. Mater. PD NOV PY 2014 VL 454 IS 1-3 BP 308 EP 314 DI 10.1016/j.jnucmat.2014.08.025 PG 7 WC Materials Science, Multidisciplinary; Nuclear Science & Technology SC Materials Science; Nuclear Science & Technology GA AS7IA UT WOS:000344428900042 ER PT J AU Field, KG Gussev, MN Yamamoto, Y Snead, LL AF Field, Kevin G. Gussev, Maxim N. Yamamoto, Yukinori Snead, Lance L. TI Deformation behavior of laser welds in high temperature oxidation resistant Fe-Cr-Al alloys for fuel cladding applications SO JOURNAL OF NUCLEAR MATERIALS LA English DT Article ID STAINLESS-STEEL; CREEP; STEAM AB Ferritic-structured Fe-Cr-Al alloys are being developed and show promise as oxidation resistant accident tolerant light water reactor fuel cladding. This study focuses on investigating the weldability and postweld mechanical behavior of three model alloys in a range of Fe-(13-17.5)Cr-(3-4.4)Al (wt.%) with a minor addition of yttrium using modern laser-welding techniques. A detailed study on the mechanical performance of bead-on-plate welds using sub-sized, flat dog-bone tensile specimens and digital image correlation (DIC) has been carried out to determine the performance of welds as a function of alloy composition. Results indicated a reduction in the yield strength within the fusion zone compared to the base metal. Yield strength reduction was found to be primarily constrained to the fusion zone due to grain coarsening with a less severe reduction in the heat affected zone. For all proposed alloys, laser welding resulted in a defect free weld devoid of cracking or inclusions. (C) 2014 Elsevier B.V. All rights reserved. C1 [Field, Kevin G.; Gussev, Maxim N.; Yamamoto, Yukinori; Snead, Lance L.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. RP Field, KG (reprint author), Div Mat Sci & Technol, POB 2008, Oak Ridge, TN 37831 USA. EM fieldkg@ornl.gov; gussevmn@ornl.gov; yamamotoy@ornl.gov; sneadll@ornl.gov RI Chen, Ru/A-5105-2015 FU U.S. Department of Energy's Office of Nuclear Energy, Advanced Fuel Campaign of the Fuel Cycle RD program; UT-Battelle LLC [DE-AC05-00OR22725]; US Department of Energy [DE-AC05-00OR22725] FX This research was funded by the U.S. Department of Energy's Office of Nuclear Energy, Advanced Fuel Campaign of the Fuel Cycle R&D program. Authors would like to thank D.A. Fredrick and R.G. Miller from Oak Ridge National Laboratory for their fruitful discussions and assistance with conducting the welding trials.; This manuscript has been authored by the Oak Ridge National Laboratory, managed by UT-Battelle LLC under Contract No. DE-AC05-00OR22725 with the US Department of Energy. The US Government retains and the publisher, by accepting the article for publication, acknowledges that the US Government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this manuscript, or allow others to do so, for US Government purposes. NR 32 TC 4 Z9 4 U1 4 U2 46 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-3115 EI 1873-4820 J9 J NUCL MATER JI J. Nucl. Mater. PD NOV PY 2014 VL 454 IS 1-3 BP 352 EP 358 DI 10.1016/j.jnucmat.2014.08.013 PG 7 WC Materials Science, Multidisciplinary; Nuclear Science & Technology SC Materials Science; Nuclear Science & Technology GA AS7IA UT WOS:000344428900047 ER PT J AU Silva, CM Lindemer, TB Voit, SR Hunt, RD Besmann, TM Terrani, KA Snead, LL AF Silva, Chinthaka M. Lindemer, Terrence B. Voit, Stewart R. Hunt, Rodney D. Besmann, Theodore M. Terrani, Kurt A. Snead, Lance L. TI Characteristics of uranium carbonitride microparticles synthesized using different reaction conditions SO JOURNAL OF NUCLEAR MATERIALS LA English DT Article ID NITRIDE; MICROSPHERES; MONONITRIDE; KERNELS AB Three sets of experimental conditions were tested to synthesize uranium carbonitride (UC1-xNx) kernels from gel-derived urania-carbon microspheres. Primarily, three sequences of gases were used, N-2 to N-2-4%H-2 to Ar, Ar to N-2 to Ar, and Ar-4%H-2 to N-2-4%H-2 to Ar-4%H-2. Physical and chemical characteristics such as geometrical density, phase purity, and chemical compositions of the synthesized UC1-xNx were measured. Single-phase kernels were commonly obtained with densities generally ranging from 85% to 93% TD and values of x as high as 0.99. In-depth analysis of the microstrutures of UC1-xNx has been carried out and is discussed with the objective of large batch fabrication of high density UC1-xNx kernels. Published by Elsevier B.V. C1 [Silva, Chinthaka M.; Voit, Stewart R.; Hunt, Rodney D.; Besmann, Theodore M.; Terrani, Kurt A.; Snead, Lance L.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. [Silva, Chinthaka M.] Univ Tennessee, Knoxville, TN 37996 USA. [Lindemer, Terrence B.] MPi Business Solut Inc, Knoxville, TN 37915 USA. RP Silva, CM (reprint author), Univ Tennessee, Knoxville, TN 37996 USA. EM silvagw@ornl.gov FU U.S. Department of Energy [DE-ACO5-00OR22725]; UT-Battelle, LLC FX This effort was sponsored by the U.S. Department of Energy through the Office of Nuclear Energy, Science and Technology's Fuel Cycle Research and Development Program under contract DE-ACO5-00OR22725 with UT-Battelle, LLC. NR 17 TC 2 Z9 2 U1 1 U2 11 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-3115 EI 1873-4820 J9 J NUCL MATER JI J. Nucl. Mater. PD NOV PY 2014 VL 454 IS 1-3 BP 405 EP 412 DI 10.1016/j.jnucmat.2014.08.038 PG 8 WC Materials Science, Multidisciplinary; Nuclear Science & Technology SC Materials Science; Nuclear Science & Technology GA AS7IA UT WOS:000344428900053 ER PT J AU Barashev, AV Xu, H Stoller, RE AF Barashev, A. V. Xu, H. Stoller, R. E. TI The behavior of small helium clusters near free surfaces in tungsten SO JOURNAL OF NUCLEAR MATERIALS LA English DT Article ID MONTE-CARLO-SIMULATION; POINT-DEFECTS; DYNAMICS; IRON; HE AB The results of a computational study of helium vacancy clusters in tungsten are reported. A recently developed atomistic kinetic Monte Carlo method employing empirical interatomic potentials was used to investigate the behavior of clusters composed of three interstitial-helium atoms near {1 1 1}, {1 1 0} and {1 0 0} free surfaces. Multiple configurations were examined and the local energy landscape was characterized to determine cluster mobility and the potential for interactions with the surface. The clusters were found to be highly mobile if far from the surface, but were attracted and bound to the surface when within a distance of a few lattice parameters. When near the surface, the clusters were transformed into an immobile configuration due to the creation of a Frenkel pair; the vacancy was incorporated into what became a He-3-vacancy complex. The corresponding interstitial migrated to and became an adatom on the free surface. This process can contribute to He retention, and may be responsible for the observed deterioration of the plasma-exposed tungsten surfaces. (C) 2014 Elsevier B.V. All rights reserved. C1 [Barashev, A. V.; Xu, H.; Stoller, R. E.] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA. [Barashev, A. V.; Xu, H.] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA. RP Xu, H (reprint author), Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA. EM xhx@utk.edu RI Xu, Haixuan/C-9841-2009 FU U.S. Department of Energy, Office of Science [DE-SC0008875]; U.S. Department of Energy, Office of Fusion Energy Sciences [DE-SC0008875]; U.S. Department of Energy, Office of Advanced Scientific Computing Research [DE-SC0008875] FX This material is based upon work supported by the U.S. Department of Energy, Office of Science, Office of Fusion Energy Sciences and Office of Advanced Scientific Computing Research through the Scientific Discovery through Advanced Computing (SciDAC) project on Plasma-Surface Interactions, under Award No. DE-SC0008875. NR 22 TC 14 Z9 14 U1 0 U2 16 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-3115 EI 1873-4820 J9 J NUCL MATER JI J. Nucl. Mater. PD NOV PY 2014 VL 454 IS 1-3 BP 421 EP 426 DI 10.1016/j.jnucmat.2014.08.033 PG 6 WC Materials Science, Multidisciplinary; Nuclear Science & Technology SC Materials Science; Nuclear Science & Technology GA AS7IA UT WOS:000344428900055 ER PT J AU Gan, J Miller, BD Keiser, DD Robinson, AB Madden, JW Medvedev, PG Wachs, DM AF Gan, J. Miller, B. D. Keiser, D. D., Jr. Robinson, A. B. Madden, J. W. Medvedev, P. G. Wachs, D. M. TI Microstructural characterization of irradiated U-7Mo/Al-5Si dispersion fuel to high fission density SO JOURNAL OF NUCLEAR MATERIALS LA English DT Article AB The fuel development program for research and test reactors calls for improved knowledge on the effect of microstructure on fuel performance in reactors. This paper summarizes the recent TEM microstructural characterization of an irradiated U-7Mo/Al-5Si dispersion fuel plate (R3R050) in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) to 5.2 x 10(21) fissions/cm(3). While a large fraction of the fuel grains is decorated with large bubbles, there is no evidence showing interlinking of these bubbles at the specified fission density. The attachment of solid fission product precipitates to the bubbles is likely the result of fission product diffusion into these bubbles. The process of fission gas bubble superlattice collapse appears through bubble coalescence. The results are compared with the previous TEM work on the dispersion fuels irradiated to lower fission density from the same fuel plate. (C) 2014 Elsevier B.V. All rights reserved. C1 [Gan, J.; Miller, B. D.; Keiser, D. D., Jr.; Robinson, A. B.; Madden, J. W.; Medvedev, P. G.; Wachs, D. M.] Idaho Natl Lab, Nucl Fuels & Mat Div, Idaho Falls, ID 83415 USA. RP Gan, J (reprint author), Idaho Natl Lab, Nucl Fuels & Mat Div, POB 1625, Idaho Falls, ID 83415 USA. EM jian.Gan@in1.gov FU U.S. Department of Energy, Office of Nuclear Materials Threat Reduction [NA-212]; National Nuclear Security Administration, under DOE-NE Idaho Operations Office [DE-AC07-05ID14517] FX Acknowledgment is given to the INL Hot Fuel Examination Facility staff for producing the sample from fuel plate R3R050. This work was supported by the U.S. Department of Energy, Office of Nuclear Materials Threat Reduction (NA-212), National Nuclear Security Administration, under DOE-NE Idaho Operations Office Contract DE-AC07-05ID14517. Accordingly, the U.S. Government retains a nonexclusive, royalty-free license to publish or reproduce the published form of this contribution, or allow others to do so, for U.S. Government purposes. NR 17 TC 4 Z9 4 U1 1 U2 5 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-3115 EI 1873-4820 J9 J NUCL MATER JI J. Nucl. Mater. PD NOV PY 2014 VL 454 IS 1-3 BP 434 EP 445 DI 10.1016/j.jnucmat.2014.08.052 PG 12 WC Materials Science, Multidisciplinary; Nuclear Science & Technology SC Materials Science; Nuclear Science & Technology GA AS7IA UT WOS:000344428900057 ER PT J AU Baessler, S Bowman, JD Penttila, S Pocanic, D AF Baessler, S. Bowman, J. D. Penttilae, S. Pocanic, D. TI New precision measurements of free neutron beta decay with cold neutrons SO JOURNAL OF PHYSICS G-NUCLEAR AND PARTICLE PHYSICS LA English DT Article DE beta decay; precision measurements; cold neutrons ID INELASTICALLY SCATTERED NEUTRONS; ANGULAR-CORRELATION COEFFICIENT; STORING ULTRACOLD NEUTRONS; LIFETIME MEASUREMENT; POLARIZED NEUTRONS; GA-GV; ASYMMETRY; TRAP; SPECTROMETER; PARAMETERS AB Precision measurements in free neutron beta decay serve to determine the coupling constants of beta decay, and offer several stringent tests of the standard model. This paper describes the free neutron beta decay program planned for the Fundamental Physics Beamline at the Spallation Neutron Source at Oak Ridge National Laboratory, and puts it into the context of other recent and planned measurements of neutron beta decay observables. C1 [Baessler, S.; Pocanic, D.] Univ Virginia, Charlottesville, VA 22904 USA. [Baessler, S.; Bowman, J. D.; Penttilae, S.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. RP Baessler, S (reprint author), Univ Virginia, Charlottesville, VA 22904 USA. EM baessler@virginia.edu FU Office of Nuclear Physics in the Office of Science of the Department of Energy; National Science Foundation [PHY-0653356, PHY-0855610, PHY-0970013, PHY-1205833, PHY-1307328] FX We thank the members of the Nab collaboration, and H Abele, B Markisch, J Nico, T Soldner and F Wietfeldt, for help in the preparation of the manuscript. We gratefully acknowledge support from the Office of Nuclear Physics in the Office of Science of the Department of Energy, and the National Science Foundation, through NSF grants PHY-0653356, -0855610, -0970013, -1205833 and -1307328. NR 89 TC 7 Z9 7 U1 2 U2 11 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0954-3899 EI 1361-6471 J9 J PHYS G NUCL PARTIC JI J. Phys. G-Nucl. Part. Phys. PD NOV PY 2014 VL 41 IS 11 AR 114003 DI 10.1088/0954-3899/41/11/114003 PG 32 WC Physics, Nuclear; Physics, Particles & Fields SC Physics GA AS2DT UT WOS:000344090500005 ER PT J AU Rajabali, MM Grzywacz, R Liddick, SN Mazzocchi, C Batchelder, JC Baumann, T Bingham, CR Darby, IG Ginter, TN Ilyushkin, SV Karny, M Krolas, W Mantica, PF Miernik, K Pfutzner, M Rykaczewski, KP Weisshaar, D Winger, JA AF Rajabali, M. M. Grzywacz, R. Liddick, S. N. Mazzocchi, C. Batchelder, J. C. Baumann, T. Bingham, C. R. Darby, I. G. Ginter, T. N. Ilyushkin, S. V. Karny, M. Krolas, W. Mantica, P. F. Miernik, K. Pfuetzner, M. Rykaczewski, K. P. Weisshaar, D. Winger, J. A. TI beta decay of Co-72 and microsecond isomers in even-mass neutron-rich nickel isotopes SO JOURNAL OF PHYSICS G-NUCLEAR AND PARTICLE PHYSICS LA English DT Article DE beta decay; gamma spectroscopy; isomer; nickel; cobalt ID NUCLEI AB A new excited state at 2164 keV has been identified in Ni-72 with tentative spin and parity of 4(+) based on comparison to shell model calculations. This level is suggested to be populated via the beta-decay of an isomeric state in Co-72, and is postulated to be one of the key states that play a role in the disappearance of isomers in Ni-72,Ni-74. The known low-energy levels in Ni-72 are compared with results of shell model calculations using the NR78 interaction to follow the seniority of the observed states. In addition, the half-life of the 8(+) isomer in Ni-76 has been measured as 630(90) ns and the full cascade of transitions from this isomer has been verified experimentally in this work. C1 [Rajabali, M. M.; Grzywacz, R.; Liddick, S. N.; Mazzocchi, C.; Bingham, C. R.; Darby, I. G.] Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA. [Rajabali, M. M.] TRIUMF, Div Sci, Vancouver, BC V6T 2A3, Canada. [Rajabali, M. M.] Tennessee Technol Univ, Dept Phys, Cookeville, TN 38505 USA. [Grzywacz, R.; Rykaczewski, K. P.] Oak Ridge Natl Lab, Div Phys, Oak Ridge, TN 37831 USA. [Liddick, S. N.; Mantica, P. F.] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA. [Liddick, S. N.; Baumann, T.; Ginter, T. N.; Mantica, P. F.; Weisshaar, D.] Michigan State Univ, Natl Superconducting Cyclotron Lab, E Lansing, MI 48824 USA. [Mazzocchi, C.; Karny, M.; Miernik, K.; Pfuetzner, M.] Univ Warsaw, Fac Phys, PL-00681 Warsaw, Poland. [Batchelder, J. C.] Oak Ridge Associated Univ, UNIRIB, Oak Ridge, TN 37831 USA. [Darby, I. G.] Univ Liverpool, Dept Phys, Oliver Lodge Lab, Liverpool L69 7ZE, Merseyside, England. [Ilyushkin, S. V.; Winger, J. A.] Mississippi State Univ, Dept Phys & Astron, Mississippi State, MS 39762 USA. [Krolas, W.] Polish Acad Sci, Inst Nucl Phys, PL-31342 Krakow, Poland. [Krolas, W.] Joint Inst Heavy Ion Res, Oak Ridge, TN 37831 USA. RP Rajabali, MM (reprint author), Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA. EM mrajabali@tntech.edu FU US DOE [DE-AC05-00OR22725, DE-FG02-96ER40983, DE-FG02-96ER41006]; NNSA through DOE [DE-FC03-03NA00143]; Polish Ministry of Science [N N202 103333]; Natural Sciences and Engineering Research Council of Canada; NSF [PHY06-06007] FX This work was supported under US DOE grants DE-AC05-00OR22725, DE-FG02-96ER40983, DE-FG02-96ER41006 and in part by the NNSA through DOE Cooperative Agreement DE-FC03-03NA00143. W Krolas was also supported by the Polish Ministry of Science contract No. N N202 103333. MM Rajabali was partially supported by the Natural Sciences and Engineering Research Council of Canada. NSCL operation is supported in part by NSF grant PHY06-06007. NR 14 TC 4 Z9 4 U1 0 U2 6 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0954-3899 EI 1361-6471 J9 J PHYS G NUCL PARTIC JI J. Phys. G-Nucl. Part. Phys. PD NOV PY 2014 VL 41 IS 11 AR 115104 DI 10.1088/0954-3899/41/11/115104 PG 9 WC Physics, Nuclear; Physics, Particles & Fields SC Physics GA AS2DT UT WOS:000344090500017 ER PT J AU Young, AR Clayton, S Filippone, BW Geltenbort, P Ito, TM Liu, CY Makela, M Morris, CL Plaster, B Saunders, A Seestrom, SJ Vogelaar, RB AF Young, A. R. Clayton, S. Filippone, B. W. Geltenbort, P. Ito, T. M. Liu, C-Y Makela, M. Morris, C. L. Plaster, B. Saunders, A. Seestrom, S. J. Vogelaar, R. B. TI Beta decay measurements with ultracold neutrons: a review of recent measurements and the research program at Los Alamos National Laboratory SO JOURNAL OF PHYSICS G-NUCLEAR AND PARTICLE PHYSICS LA English DT Article DE fundamental symmetries; neutron decay; ultracold neutrons ID SOLID-DEUTERIUM SOURCE; BIG-BANG NUCLEOSYNTHESIS; INELASTICALLY SCATTERED NEUTRONS; MONTE-CARLO-SIMULATION; COLD NEUTRONS; POLARIZED NEUTRONS; STANDARD-MODEL; RADIATIVE-CORRECTIONS; SUPERFLUID HE-4; SEMILEPTONIC DECAYS AB We present a review of the motivation and results of recent experiments which utilize ultracold neutrons for measurements of neutron beta decay. Because these experiments hinge critically on the available ultracold neutron source technology, we also review the status of ultracold neutron source development, emphasizing the Los Alamos ultracold neutron facility and the ongoing beta decay research program sited there. C1 [Young, A. R.] N Carolina State Univ, Dept Phys, Raleigh, NC 27695 USA. [Young, A. R.] Triangle Univ Nucl Lab, Durham, NC 27708 USA. [Clayton, S.; Ito, T. M.; Makela, M.; Morris, C. L.; Saunders, A.; Seestrom, S. J.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Filippone, B. W.] CALTECH, Kellogg Radiat Lab, Pasadena, CA 91125 USA. [Geltenbort, P.] Inst Max Von Laue Paul Langevin, F-38042 Grenoble 9, France. [Liu, C-Y] Indiana Univ, Dept Phys, Bloomington, IN 47408 USA. [Plaster, B.] Univ Kentucky, Dept Phys & Astron, Lexington, KY 40506 USA. [Vogelaar, R. B.] Virginia Polytech & State Univ, Dept Phys, Blacksburg, VA 24061 USA. RP Young, AR (reprint author), N Carolina State Univ, Dept Phys, Raleigh, NC 27695 USA. OI Makela, Mark/0000-0003-0592-3683; Morris, Christopher/0000-0003-2141-0255; Ito, Takeyasu/0000-0003-3494-6796; Clayton, Steven/0000-0002-1401-2761 FU LANL LDRD program, LANL DOE [2015LANL-LE9BU]; Indiana University NSF [PHY-0969490/PHY-1068712]; NCSU NSF [1005233]; VT NSF grant [1005233]; Caltech NSF [1205977]; UK DOE [DE-FG02-08ER41557]; DOE [DE-FG02-97ER41042] FX This work was supported by the LANL LDRD program, LANL DOE grant 2015LANL-LE9BU, the Indiana University NSF grants PHY-0969490/PHY-1068712, NCSU NSF grant 1005233/DOE grant DE-FG02-97ER41042, VT NSF grant 1005233, Caltech NSF grant 1205977, and UK DOE grant DE-FG02-08ER41557. The authors wish to gratefully acknowledge the encouragement of B Holstein to write this article and also the assistance of A Coc in preparing section 2.2, and also acknowledge helpful discussion with V Cirigliano, A Garcia, G Greene, R Golub, V Gudkov, R Gupta, W Marciano, V Nesvizhevsky, W M Snow, E Korobkina, A Steyerl, F Wauters and O Zimmer. NR 202 TC 10 Z9 10 U1 5 U2 17 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0954-3899 EI 1361-6471 J9 J PHYS G NUCL PARTIC JI J. Phys. G-Nucl. Part. Phys. PD NOV PY 2014 VL 41 IS 11 AR 114007 DI 10.1088/0954-3899/41/11/114007 PG 72 WC Physics, Nuclear; Physics, Particles & Fields SC Physics GA AS2DT UT WOS:000344090500009 ER PT J AU Iverson, BD Bauer, SJ Flueckiger, SM AF Iverson, Brian D. Bauer, Stephen J. Flueckiger, Scott M. TI Thermocline Bed Properties for Deformation Analysis SO JOURNAL OF SOLAR ENERGY ENGINEERING-TRANSACTIONS OF THE ASME LA English DT Article DE thermocline; thermal energy storage; concentrating solar power; solar energy ID MOLTEN-SALT THERMOCLINE; THERMAL-ENERGY STORAGE; GRANULAR-MATERIALS; DILATANCY; SYSTEM AB Thermocline tanks have been considered as an alternative to traditional two-tank molten salt thermal storage in concentrating solar power systems due to their potential for cost reduction. One concern for thermocline usage is thermal ratcheting caused by the internal rock bed deformation during cyclic operation and significant temperature fluctuations. Thermal ratcheting studies have been performed in the literature to identify the possibility of tank rupture. However, these studies numerically modeled the ratcheting behavior utilizing bed properties that have never been measured for the materials used in thermocline storage systems. This work presents triaxial test data quartzite and silica thermocline filler materials to better inform future investigations of thermal ratcheting. Molten salt is replaced with water as the interstitial fluid due to similarity in dimensionless numbers and to accommodate room temperature measurement. Material property data for cohesion, dilatancy angle, internal angle of friction, Young's modulus, Poisson's ratio, and bulk modulus are presented for 0.138-0.414MPa confining pressure. The material properties are then compared to those assumed in the literature to comment on the potential impact of this property data relative to thermal ratcheting. C1 [Iverson, Brian D.] Brigham Young Univ, Dept Mech Engn, Provo, UT 84602 USA. [Iverson, Brian D.; Bauer, Stephen J.] Sandia Natl Labs, Albuquerque, NM 87185 USA. [Flueckiger, Scott M.] Purdue Univ, Sch Mech Engn, W Lafayette, IN 47907 USA. RP Iverson, BD (reprint author), Brigham Young Univ, Dept Mech Engn, Provo, UT 84602 USA. EM bdiverson@byu.edu FU U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX This manuscript has been authored by Sandia National Laboratories, a multiprogram laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under Contract No. DE-AC04-94AL85000. NR 25 TC 0 Z9 0 U1 2 U2 3 PU ASME PI NEW YORK PA TWO PARK AVE, NEW YORK, NY 10016-5990 USA SN 0199-6231 EI 1528-8986 J9 J SOL ENERG-T ASME JI J. Sol. Energy Eng. Trans.-ASME PD NOV PY 2014 VL 136 IS 4 AR 041002 DI 10.1115/1.4027287 PG 9 WC Energy & Fuels; Engineering, Mechanical SC Energy & Fuels; Engineering GA AS6AE UT WOS:000344346600002 ER PT J AU Ning, SA Damiani, R Moriarty, PJ AF Ning, S. Andrew Damiani, Rick Moriarty, Patrick J. TI Objectives and Constraints for Wind Turbine Optimization SO JOURNAL OF SOLAR ENERGY ENGINEERING-TRANSACTIONS OF THE ASME LA English DT Article ID DESIGN AB Efficient extraction of wind energy is a complex, multidisciplinary process. This paper examines common objectives used in wind turbine optimization problems. The focus is not on the specific optimized designs, but rather on understanding when certain objectives and constraints are necessary, and what their limitations are. Maximizing annual energy production, or even using sequential aero/structural optimization, is shown to be significantly suboptimal compared to using integrated aero/structural metrics. Minimizing the ratio of turbine mass to annual energy production can be effective for fixed rotor diameter designs, as long as the tower mass is estimated carefully. For variable-diameter designs, the predicted optimal diameter may be misleading. This is because the mass of the tower is a large fraction of the total turbine mass, but the cost of the tower is a much smaller fraction of overall turbine costs. Minimizing the cost of energy is a much better metric, though high fidelity in the cost modeling is as important as high fidelity in the physics modeling. Furthermore, deterministic cost of energy minimization can be inadequate, given the stochastic nature of the wind and various uncertainties associated with physical processes and model choices. Optimization in the presence of uncertainty is necessary to create robust turbine designs. C1 [Ning, S. Andrew; Damiani, Rick; Moriarty, Patrick J.] Natl Wind Technol Ctr, Golden, CO 80401 USA. RP Ning, SA (reprint author), Natl Wind Technol Ctr, 15013 Denver West Pkwy, Golden, CO 80401 USA. EM andrew.ning@nrel.gov OI Ning, Andrew/0000-0003-2190-823X FU U.S. Department of Energy under National Renewable Energy Laboratory [DE-AC36-08GO28308]; DOE Office of Energy Efficiency and Renewable Energy, Wind, and Water Power Technologies Office FX The authors gratefully acknowledge George Scott of NREL for providing a Python version of NREL's cost and scaling model and Katherine Dykes of NREL for providing the blade cost scaling relationship and suggesting the inclusion of drivetrain efficiency losses. This work was supported by the U.S. Department of Energy under Contract No. DE-AC36-08GO28308 with the National Renewable Energy Laboratory. Funding for the work was provided by the DOE Office of Energy Efficiency and Renewable Energy, Wind, and Water Power Technologies Office. NR 32 TC 2 Z9 2 U1 1 U2 11 PU ASME PI NEW YORK PA TWO PARK AVE, NEW YORK, NY 10016-5990 USA SN 0199-6231 EI 1528-8986 J9 J SOL ENERG-T ASME JI J. Sol. Energy Eng. Trans.-ASME PD NOV PY 2014 VL 136 IS 4 AR 041010 DI 10.1115/1.4027693 PG 12 WC Energy & Fuels; Engineering, Mechanical SC Energy & Fuels; Engineering GA AS6AE UT WOS:000344346600010 ER PT J AU De Carlo, F Gursoy, D Marone, F Rivers, M Parkinson, DY Khan, F Schwarz, N Vine, DJ Vogt, S Gleber, SC Narayanan, S Newville, M Lanzirotti, T Sun, Y Hong, YP Jacobsen, C AF De Carlo, Francesco Guersoy, Doga Marone, Federica Rivers, Mark Parkinson, Dilworth Y. Khan, Faisal Schwarz, Nicholas Vine, David J. Vogt, Stefan Gleber, Sophie-Charlotte Narayanan, Suresh Newville, Matt Lanzirotti, Tony Sun, Yue Hong, Young Pyo Jacobsen, Chris TI Scientific data exchange: a schema for HDF5-based storage of raw and analyzed data SO JOURNAL OF SYNCHROTRON RADIATION LA English DT Article DE data storage; provenance; HDF5 ID SOFTWARE TOOLS; MICROSCOPY; FORMAT AB Data Exchange is a simple data model designed to interface, or 'exchange', data among different instruments, and to enable sharing of data analysis tools. Data Exchange focuses on technique rather than instrument descriptions, and on provenance tracking of analysis steps and results. In this paper the successful application of the Data Exchange model to a variety of X-ray techniques, including tomography, fluorescence spectroscopy, fluorescence tomography and photon correlation spectroscopy, is described. C1 [De Carlo, Francesco; Guersoy, Doga; Khan, Faisal; Schwarz, Nicholas; Vine, David J.; Vogt, Stefan; Gleber, Sophie-Charlotte; Narayanan, Suresh; Jacobsen, Chris] Argonne Natl Lab, Argonne, IL 60439 USA. [Marone, Federica] Paul Scherrer Inst, Villigen, Switzerland. [Rivers, Mark; Newville, Matt; Lanzirotti, Tony] Univ Chicago, Ctr Adv Radiat Sources, Argonne Natl Lab, Argonne, IL 60439 USA. [Parkinson, Dilworth Y.] Adv Light Source, Berkeley, CA 94720 USA. [Sun, Yue; Hong, Young Pyo; Jacobsen, Chris] Northwestern Univ, Dept Phys & Astron, Evanston, IL 60208 USA. [Jacobsen, Chris] Northwestern Univ, Chem Life Proc Inst, Evanston, IL 60208 USA. RP De Carlo, F (reprint author), Argonne Natl Lab, 9700 S Cass Ave, Argonne, IL 60439 USA. EM decarlo@aps.anl.gov RI Marone, Federica/J-4420-2013; Parkinson, Dilworth/A-2974-2015; Jacobsen, Chris/E-2827-2015 OI Parkinson, Dilworth/0000-0002-1817-0716; Jacobsen, Chris/0000-0001-8562-0353 FU NIGMS NIH HHS [R01 GM104530] NR 21 TC 14 Z9 14 U1 5 U2 22 PU INT UNION CRYSTALLOGRAPHY PI CHESTER PA 2 ABBEY SQ, CHESTER, CH1 2HU, ENGLAND SN 1600-5775 J9 J SYNCHROTRON RADIAT JI J. Synchrot. Radiat. PD NOV PY 2014 VL 21 BP 1224 EP 1230 DI 10.1107/S160057751401604X PN 6 PG 7 WC Instruments & Instrumentation; Optics; Physics, Applied SC Instruments & Instrumentation; Optics; Physics GA AS6JR UT WOS:000344370400002 PM 25343788 ER PT J AU Soares, AS Mullen, JD Parekh, RM McCarthy, GS Roessler, CG Jackimowicz, R Skinner, JM Orville, AM Allaire, M Sweet, RM AF Soares, Alexei S. Mullen, Jeffrey D. Parekh, Ruchi M. McCarthy, Grace S. Roessler, Christian G. Jackimowicz, Rick Skinner, John M. Orville, Allen M. Allaire, Marc Sweet, Robert M. TI Solvent minimization induces preferential orientation and crystal clustering in serial micro-crystallography on micro-meshes, in situ plates and on a movable crystal conveyor belt SO JOURNAL OF SYNCHROTRON RADIATION LA English DT Article DE in situ X-ray data collection; crystallography; acoustic droplet ejection; serial crystallography ID MACROMOLECULAR CRYSTALLOGRAPHY; PROTEIN CRYSTALS; RADIATION-DAMAGE; DIFFRACTION; REFINEMENT; BEAMLINES; ELECTRON AB X-ray diffraction data were obtained at the National Synchrotron Light Source from insulin and lysozyme crystals that were densely deposited on three types of surfaces suitable for serial micro-crystallography: MiTeGen MicroMeshes (TM), Greiner Bio-One Ltd in situ micro-plates, and a moving kapton crystal conveyor belt that is used to deliver crystals directly into the X-ray beam. 6 degrees wedges of data were taken from similar to 100 crystals mounted on each material, and these individual data sets were merged to form nine complete data sets (six from insulin crystals and three from lysozyme crystals). Insulin crystals have a parallelepiped habit with an extended flat face that preferentially aligned with the mounting surfaces, impacting the data collection strategy and the design of the serial crystallography apparatus. Lysozyme crystals had a cuboidal habit and showed no preferential orientation. Preferential orientation occluded regions of reciprocal space when the X-ray beam was incident normal to the data-collection medium surface, requiring a second pass of data collection with the apparatus inclined away from the orthogonal. In addition, crystals measuring less than 20 mu m were observed to clump together into clusters of crystals. Clustering required that the X-ray beam be adjusted to match the crystal size to prevent overlapping diffraction patterns. No additional problems were encountered with the serial crystallography strategy of combining small randomly oriented wedges of data from a large number of specimens. High-quality data able to support a realistic molecular replacement solution were readily obtained from both crystal types using all three serial crystallography strategies. C1 [Soares, Alexei S.; McCarthy, Grace S.; Roessler, Christian G.; Jackimowicz, Rick; Skinner, John M.; Orville, Allen M.; Allaire, Marc; Sweet, Robert M.] Brookhaven Natl Lab, Photon Sci Directorate, Upton, NY 11973 USA. [Mullen, Jeffrey D.; Parekh, Ruchi M.] Brookhaven Natl Lab, Off Educ Programs, Upton, NY 11973 USA. [Mullen, Jeffrey D.] Univ Oregon, Dept Phys, Eugene, OR 97403 USA. [Parekh, Ruchi M.] Suffolk Cty Community Coll, Selden, NY 11784 USA. [Orville, Allen M.; Sweet, Robert M.] Brookhaven Natl Lab, Dept Biosci, Upton, NY 11973 USA. RP Soares, AS (reprint author), Brookhaven Natl Lab, Photon Sci Directorate, Upton, NY 11973 USA. EM soares@bnl.gov FU NCI NIH HHS [Y1-CO-1020]; NCRR NIH HHS [P41 RR012408, P41RR012408]; NIGMS NIH HHS [P41GM103473, P41 GM103473, P41 GM111244, Y1-GM-1104] NR 30 TC 3 Z9 3 U1 1 U2 10 PU INT UNION CRYSTALLOGRAPHY PI CHESTER PA 2 ABBEY SQ, CHESTER, CH1 2HU, ENGLAND SN 1600-5775 J9 J SYNCHROTRON RADIAT JI J. Synchrot. Radiat. PD NOV PY 2014 VL 21 BP 1231 EP 1239 DI 10.1107/S1600577514017731 PN 6 PG 9 WC Instruments & Instrumentation; Optics; Physics, Applied SC Instruments & Instrumentation; Optics; Physics GA AS6JR UT WOS:000344370400003 PM 25343789 ER PT J AU Laanait, N Zhang, Z Schleputz, CM Vila-Comamala, J Highland, MJ Fenter, P AF Laanait, Nouamane Zhang, Zhan Schlepuetz, Christian M. Vila-Comamala, Joan Highland, Matthew J. Fenter, Paul TI Full-field X-ray reflection microscopy of epitaxial thin-films SO JOURNAL OF SYNCHROTRON RADIATION LA English DT Article DE X-ray surface diffraction; X-ray microscopy; interfaces and thin films; materials science ID IMAGE-ANALYSIS; DIFFRACTION; NANOSCALE; SYNCHROTRON; INTERFACES; DYNAMICS; CONTRAST; SCIENCE; PBTIO3 AB Novel X-ray imaging of structural domains in a ferroelectric epitaxial thin film using diffraction contrast is presented. The full-field hard X-ray microscope uses the surface scattering signal, in a reflectivity or diffraction experiment, to spatially resolve the local structure with 70 nm lateral spatial resolution and sub-nanometer height sensitivity. Sub-second X-ray exposures can be used to acquire a 14 mu m x 14 mu m image with an effective pixel size of 20 nm on the sample. The optical configuration and various engineering considerations that are necessary to achieve optimal imaging resolution and contrast in this type of microscopy are discussed. C1 [Laanait, Nouamane; Fenter, Paul] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA. [Zhang, Zhan; Schlepuetz, Christian M.; Vila-Comamala, Joan] Argonne Natl Lab, Xray Sci Div, Argonne, IL 60439 USA. [Highland, Matthew J.] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA. RP Laanait, N (reprint author), Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA. EM nlaanait@anl.gov; fenter@anl.gov RI Schleputz, Christian/C-4696-2008; Laanait, Nouamane/A-2498-2016; Zhang, Zhan/A-9830-2008; Vila-Comamala, Joan/E-2106-2017 OI Schleputz, Christian/0000-0002-0485-2708; Laanait, Nouamane/0000-0001-7100-4250; Zhang, Zhan/0000-0002-7618-6134; FU Geosciences Research Program of the Office of Basic Energy Sciences, US Department of Energy (DOE) [DE-AC02-06CH11357]; US DOE, Office of Basic Energy Sciences, Materials Sciences and Engineering Division; US Department of Energy Office of Science laboratory [DE-AC02-06CH11357]; US Government FX We would like to acknowledge Jonathan Tischler (X-ray Science Division, Argonne National Laboratory) for his invaluable advice and suggestions during the design of the microscope. We also would like to thank Peter Eng (CARS, University of Chicago) for installing and configuring the Kirkpatrick-Baez mirror system. We have benefited from many discussions with Steve Wang (Washington State University) and Dillon Fong (Argonne National Laboratory). We thank Zunping Liu (X-ray Science Division, Argonne National Laboratory) for assistance with the hutch vibration measurements. This work was supported by the Geosciences Research Program of the Office of Basic Energy Sciences, US Department of Energy (DOE), through Contract number DE-AC02-06CH11357 at Argonne National Laboratory, and through a collaborative 'Partner User Proposal' awarded for the development of this instrument. The X-ray data were collected at the X-ray Operations and Research beamline 33-ID-D at the Advanced Photon Source, Argonne National Laboratory. MJH was supported by US DOE, Office of Basic Energy Sciences, Materials Sciences and Engineering Division. The submitted manuscript has been created by UChicago Argonne, LLC, Operator of Argonne National Laboratory ('Argonne'). Argonne, a US Department of Energy Office of Science laboratory, is operated under Contract number DE-AC02-06CH11357. The US Government retains for itself, and others acting on its behalf, a paid-up non-exclusive irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly and display publicly, by or on behalf of the Government. NR 49 TC 3 Z9 3 U1 3 U2 25 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0909-0495 EI 1600-5775 J9 J SYNCHROTRON RADIAT JI J. Synchrot. Radiat. PD NOV PY 2014 VL 21 BP 1252 EP 1261 DI 10.1107/S1600577514016555 PN 6 PG 10 WC Instruments & Instrumentation; Optics; Physics, Applied SC Instruments & Instrumentation; Optics; Physics GA AS6JR UT WOS:000344370400006 PM 25343792 ER PT J AU Li, LX Kwasniewski, P Orsi, D Wiegart, L Cristofolini, L Caronna, C Fluerasu, A AF Li, Luxi Kwasniewski, Pawel Orsi, Davide Wiegart, Lutz Cristofolini, Luigi Caronna, Chiara Fluerasu, Andrei TI Photon statistics and speckle visibility spectroscopy with partially coherent X-rays SO JOURNAL OF SYNCHROTRON RADIATION LA English DT Article DE photon statistics; speckle visibility spectroscopy; partially coherent X-rays ID FLUCTUATIONS; BEAMS AB A new approach is proposed for measuring structural dynamics in materials from multi-speckle scattering patterns obtained with partially coherent X-rays. Coherent X-ray scattering is already widely used at high-brightness synchrotron lightsources to measure dynamics using X-ray photon correlation spectroscopy, but in many situations this experimental approach based on recording long series of images (i.e. movies) is either not adequate or not practical. Following the development of visible-light speckle visibility spectroscopy, the dynamic information is obtained instead by analyzing the photon statistics and calculating the speckle contrast in single scattering patterns. This quantity, also referred to as the speckle visibility, is determined by the properties of the partially coherent beam and other experimental parameters, as well as the internal motions in the sample (dynamics). As a case study, Brownian dynamics in a low-density colloidal suspension is measured and an excellent agreement is found between correlation functions measured by X-ray photon correlation spectroscopy and the decay in speckle visibility with integration time obtained from the analysis presented here. C1 [Li, Luxi; Wiegart, Lutz; Fluerasu, Andrei] Brookhaven Natl Lab, Photon Sci Directorate, Upton, NY 11973 USA. [Kwasniewski, Pawel] European Synchrotron Radiat Facil, F-38043 Grenoble, France. [Orsi, Davide; Cristofolini, Luigi] Univ Parma, Dept Phys & Earth Sci, I-43100 Parma, Italy. [Caronna, Chiara] Stanford Linear Accelerator Lab, Menlo Pk, CA 94025 USA. RP Li, LX (reprint author), Brookhaven Natl Lab, Photon Sci Directorate, Upton, NY 11973 USA. EM luxi.li2012@gmail.com RI Orsi, Davide/P-5748-2016 OI Orsi, Davide/0000-0003-3223-8622 FU NSLS-II with the US Department of Energy [DE-AC02-98CH10886]; Brookhaven National Laboratory Directed Research Development (LDRD) [11-025] FX The authors would like to thank the ESRF ID10 beamline for the beam time, and Y. Chushkin and F. Zontone for the support during the experiments. The research is financially supported by NSLS-II under contract No. DE-AC02-98CH10886 with the US Department of Energy, and Brookhaven National Laboratory Directed Research Development (LDRD) No. 11-025. NR 20 TC 2 Z9 2 U1 3 U2 15 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0909-0495 EI 1600-5775 J9 J SYNCHROTRON RADIAT JI J. Synchrot. Radiat. PD NOV PY 2014 VL 21 BP 1288 EP 1295 DI 10.1107/S1600577514015847 PN 6 PG 8 WC Instruments & Instrumentation; Optics; Physics, Applied SC Instruments & Instrumentation; Optics; Physics GA AS6JR UT WOS:000344370400011 PM 25343797 ER PT J AU Xu, WH Lauer, K Chu, Y Nazaretski, E AF Xu, Weihe Lauer, Kenneth Chu, Yong Nazaretski, Evgeny TI A high-precision instrument for mapping of rotational errors in rotary stages SO JOURNAL OF SYNCHROTRON RADIATION LA English DT Article DE high-precision instrument; rotational errors; rotary stages ID RAY; RESOLUTION AB A rotational stage is a key component of every X-ray instrument capable of providing tomographic or diffraction measurements. To perform accurate three-dimensional reconstructions, runout errors due to imperfect rotation (e.g. circle of confusion) must be quantified and corrected. A dedicated instrument capable of full characterization and circle of confusion mapping in rotary stages down to the sub-10 nm level has been developed. A high-stability design, with an array of five capacitive sensors, allows simultaneous measurements of wobble, radial and axial displacements. The developed instrument has been used for characterization of two mechanical stages which are part of an X-ray microscope. C1 [Xu, Weihe; Lauer, Kenneth; Chu, Yong; Nazaretski, Evgeny] Brookhaven Natl Lab, Upton, NY 11973 USA. RP Nazaretski, E (reprint author), Brookhaven Natl Lab, Upton, NY 11973 USA. EM enazaretski@bnl.gov FU US Department of Energy [DE-AC02-98CH10886] FX We acknowledge B. Mullany (BNL) for help with three-dimensional modeling of the microscope and D. Kuhne (BNL) for machining and assembling of mechanical parts. Work at BNL was supported by the US Department of Energy under contract No. DE-AC02-98CH10886. NR 13 TC 4 Z9 4 U1 0 U2 1 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0909-0495 EI 1600-5775 J9 J SYNCHROTRON RADIAT JI J. Synchrot. Radiat. PD NOV PY 2014 VL 21 BP 1367 EP 1369 DI 10.1107/S160057751401618X PN 6 PG 3 WC Instruments & Instrumentation; Optics; Physics, Applied SC Instruments & Instrumentation; Optics; Physics GA AS6JR UT WOS:000344370400021 PM 25343807 ER PT J AU Le Gros, MA McDermott, G Cinquin, BP Smith, EA Do, M Chao, WLL Naulleau, PP Larabell, CA AF Le Gros, Mark A. McDermott, Gerry Cinquin, Bertrand P. Smith, Elizabeth A. Do, Myan Chao, Weilun L. Naulleau, Patrick P. Larabell, Carolyn A. TI Biological soft X-ray tomography on beamline 2.1 at the Advanced Light Source SO JOURNAL OF SYNCHROTRON RADIATION LA English DT Article DE cell biology; cellular imaging; cryo-preservation; cryogenic fluorescence tomography; cryostage; three-dimensional reconstruction ID MICROSCOPY; RESOLUTION; FLUORESCENCE; SPECIMENS; IMAGES; CELLS AB Beamline 2.1 (XM-2) is a transmission soft X-ray microscope in sector 2 of the Advanced Light Source at Lawrence Berkeley National Laboratory. XM-2 was designed, built and is now operated by the National Center for X-ray Tomography as a National Institutes of Health Biomedical Technology Research Resource. XM-2 is equipped with a cryogenic rotation stage to enable tomographic data collection from cryo-preserved cells, including large mammalian cells. During data collection the specimen is illuminated with 'water window' X-rays (284-543 eV). Illuminating photons are attenuated an order of magnitude more strongly by biomolecules than by water. Consequently, differences in molecular composition generate quantitative contrast in images of the specimen. Soft X-ray tomography is an information-rich three-dimensional imaging method that can be applied either as a standalone technique or as a component modality in correlative imaging studies. C1 [Le Gros, Mark A.; McDermott, Gerry; Cinquin, Bertrand P.; Smith, Elizabeth A.; Do, Myan; Larabell, Carolyn A.] Univ Calif San Francisco, Sch Med, Dept Anat, San Francisco, CA 94143 USA. [Le Gros, Mark A.; McDermott, Gerry; Cinquin, Bertrand P.; Smith, Elizabeth A.; Do, Myan; Larabell, Carolyn A.] Natl Ctr Xray Tomog, Adv Light Source, Berkeley, CA 94720 USA. [Le Gros, Mark A.; Larabell, Carolyn A.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Phys Biosci Div, Berkeley, CA 94720 USA. [Chao, Weilun L.; Naulleau, Patrick P.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Ctr Xray Opt, Berkeley, CA 94720 USA. RP Le Gros, MA (reprint author), Univ Calif San Francisco, Sch Med, Dept Anat, San Francisco, CA 94143 USA. EM mark.legros@ucsf.edu; carolyn.larabell@ucsf.edu FU US Department of Energy, Office of Basic Energy Science [DE-AC02-05CH11231]; US Department of Energy, Office of Biological and Environmental Research [DE-AC02-05CH11231]; National Center for Research Resources of the National Institutes of Health [P41RR019664]; National Institute of General Medicine of the National Institutes of Health [P41GM103445]; Gordon and Betty Moore Foundation [3497] FX We thank Drs Dula Parkinson and Christian Knoechel for their assistance in the preparation of Fig. 4 and Dr David Kilcoyne for his expert help on ALS beamline 5.3.2. The Advanced Light Source is supported by the US Department of Energy, Office of Basic Energy Science (DE-AC02-05CH11231). The National Center for X-ray Tomography is supported by: the US Department of Energy, Office of Biological and Environmental Research (DE-AC02-05CH11231); the National Center for Research Resources of the National Institutes of Health (P41RR019664); the National Institute of General Medicine of the National Institutes of Health (P41GM103445). The Gordon and Betty Moore Foundation (3497) support our development of 'super resolution' cryo-fluorescence tomography for correlated imaging studies. NR 28 TC 7 Z9 7 U1 4 U2 23 PU INT UNION CRYSTALLOGRAPHY PI CHESTER PA 2 ABBEY SQ, CHESTER, CH1 2HU, ENGLAND SN 1600-5775 J9 J SYNCHROTRON RADIAT JI J. Synchrot. Radiat. PD NOV PY 2014 VL 21 BP 1370 EP 1377 DI 10.1107/S1600577514015033 PN 6 PG 8 WC Instruments & Instrumentation; Optics; Physics, Applied SC Instruments & Instrumentation; Optics; Physics GA AS6JR UT WOS:000344370400022 PM 25343808 ER PT J AU Xue, ZY Charonko, JJ Vlachos, PP AF Xue, Zhenyu Charonko, John J. Vlachos, Pavlos P. TI Particle image velocimetry correlation signal-to-noise ratio metrics and measurement uncertainty quantification SO MEASUREMENT SCIENCE AND TECHNOLOGY LA English DT Article; Proceedings Paper CT 4th Conference on Asia Pacific Optical Sensors (APOS) CY OCT 15-18, 2013 CL Wuhan, PEOPLES R CHINA SP Wuhan Univ Technol, Univ Elect Sci & Technol China, Hong Kong Polytechn Univ, Harbin Engn Univ, Huazhong Univ Sci & Technol, Nat Sci Fdn China, Chinese Opt Soc DE particle image velocimetry; PIV; uncertainty; signal-to-noise ratio ID INTERNATIONAL PIV CHALLENGE; PULSED SYSTEMS; OPTIMIZATION; FLOWS AB In particle image velocimetry (PIV) the measurement signal is contained in the recorded intensity of the particle image pattern superimposed on a variety of noise sources. The signal-to-noise-ratio (SNR) strength governs the resulting PIV cross correlation and ultimately the accuracy and uncertainty of the resulting PIV measurement. Hence we posit that correlation SNR metrics calculated from the correlation plane can be used to quantify the quality of the correlation and the resulting uncertainty of an individual measurement. In this paper we extend the original work by Charonko and Vlachos and present a framework for evaluating the correlation SNR using a set of different metrics, which in turn are used to develop models for uncertainty estimation. Several corrections have been applied in this work. The SNR metrics and corresponding models presented herein are expanded to be applicable to both standard and filtered correlations by applying a subtraction of the minimum correlation value to remove the effect of the background image noise. In addition, the notion of a 'valid' measurement is redefined with respect to the correlation peak width in order to be consistent with uncertainty quantification principles and distinct from an 'outlier' measurement. Finally the type and significance of the error distribution function is investigated. These advancements lead to more robust and reliable uncertainty estimation models compared with the original work by Charonko and Vlachos. The models are tested against both synthetic benchmark data as well as experimental measurements. In this work, U-68.5 uncertainties are estimated at the 68.5% confidence level while U-95 uncertainties are estimated at 95% confidence level. For all cases the resulting calculated coverage factors approximate the expected theoretical confidence intervals, thus demonstrating the applicability of these new models for estimation of uncertainty for individual PIV measurements. C1 [Xue, Zhenyu] Virginia Tech, Dept Mech Engn, Blacksburg, VA 24061 USA. [Charonko, John J.] Los Alamos Natl Lab, Los Alamos, NM USA. [Vlachos, Pavlos P.] Purdue Univ, Sch Mech Engn, W Lafayette, IN 47907 USA. RP Xue, ZY (reprint author), Virginia Tech, Dept Mech Engn, Blacksburg, VA 24061 USA. EM pvlachos@purdue.edu RI Charonko, John/D-6701-2013 OI Charonko, John/0000-0002-0396-9672 FU NSF-IDBR award [1152304]; NSF/FDA SIR award [1239265] FX The authors wish to acknowledge the support of NSF-IDBR award 1152304 and the NSF/FDA SIR award 1239265. Also PPV would like to thank Barton L Smith, Bernd Wieneke, Andrea Sciacchitano and Doug Neal for the numerous discussions over the past year on the various issues related to the PIV uncertainty quantification. NR 32 TC 10 Z9 10 U1 1 U2 9 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0957-0233 EI 1361-6501 J9 MEAS SCI TECHNOL JI Meas. Sci. Technol. PD NOV PY 2014 VL 25 IS 11 AR 115301 DI 10.1088/0957-0233/25/11/115301 PG 15 WC Engineering, Multidisciplinary; Instruments & Instrumentation SC Engineering; Instruments & Instrumentation GA AS0AM UT WOS:000343940800021 ER PT J AU Rauscher, SA Ringler, TD AF Rauscher, Sara A. Ringler, Todd D. TI Impact of Variable-Resolution Meshes on Midlatitude Baroclinic Eddies Using CAM-MPAS-A SO MONTHLY WEATHER REVIEW LA English DT Article ID MULTIRESOLUTION MODELING APPROACH; HORIZONTAL RESOLUTION; STORM-TRACKS; AQUAPLANET SIMULATIONS; CLIMATE SIMULATION; DYNAMICAL CORE; SENSITIVITY; ATMOSPHERE; GCM; PRECIPITATION AB The effects of a variable-resolution mesh on simulated midlatitude baroclinic eddies in idealized settings are examined. Both aquaplanet and Held-Suarez experiments are performed using the Model for Prediction Across Scales-Atmosphere (MPAS-A) hydrostatic dynamical core implemented within the National Science Foundation Department of Energy (NSF-DOE) Community Atmosphere Model (CAM-MPAS-A). In the real world, midlatitude eddy activity is organized by orography, land sea contrasts, and sea surface temperature anomalies. In these zonally symmetric idealized settings, transients should have an equal probability of occurring at any longitude. However, the use of a variable-resolution mesh with a circular high-resolution region centered at 30 degrees N results in a maximum in eddy kinetic energy on the eastern side and downstream of this high-resolution region in both aquaplanet and Held Suarez CAM-MPAS-A simulations. The presence of a geographically confined maximum in both simulations suggests this response is mainly attributable to CAM-MPAS-A's ability to resolve eddies via the model dynamics as resolution increases. However, in the aquaplanet simulation, a secondary maximum in eddy kinetic energy is present, which is probably linked to the resolution dependencies of the CAM physics. These mesh responses must be considered when interpreting real-world variable-resolution CAM-MPAS-A simulations, particularly in climate change experiments. C1 [Rauscher, Sara A.; Ringler, Todd D.] Los Alamos Natl Lab, Fluid Dynam & Solid Mech Grp, Div Theoret, Los Alamos, NM USA. RP Rauscher, SA (reprint author), Univ Delaware, Dept Geog, 219 Pearson Hall, Newark, DE 19716 USA. EM rauscher@udel.edu FU DOE [07SCPF152] FX We thank three anonymous reviewers for their comments that greatly helped to improve the quality of this manuscript. This work is supported by the DOE 07SCPF152 for the "Development of Frameworks for Robust Regional Climate Modeling." The efforts of Art Mirin, Dan Bergman, and Jeff Painter in helping to couple MPAS-A with CAM are very much appreciated. NR 49 TC 4 Z9 4 U1 0 U2 2 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0027-0644 EI 1520-0493 J9 MON WEATHER REV JI Mon. Weather Rev. PD NOV PY 2014 VL 142 IS 11 BP 4256 EP 4268 DI 10.1175/MWR-D-13-00366.1 PG 13 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA AS4BW UT WOS:000344219400017 ER PT J AU Duarte, M Almgren, AS Balakrishnan, K Bell, JB Romps, DM AF Duarte, Max Almgren, Ann S. Balakrishnan, Kaushik Bell, John B. Romps, David M. TI A Numerical Study of Methods for Moist Atmospheric Flows: Compressible Equations SO MONTHLY WEATHER REVIEW LA English DT Article ID THERMODYNAMIC FOUNDATION; CONSERVATIVE SCHEME; CUMULUS CONVECTION; MODEL; SIMULATION; MICROPHYSICS; EXPLICIT; ENTROPY AB Two common numerical techniques for integrating reversible moist processes in atmospheric flows are investigated in the context of solving the fully compressible Euler equations. The first is a one-step, coupled technique based on using appropriate invariant variables such that terms resulting from phase change are eliminated in the governing equations. In the second approach, which is a two-step scheme, separate transport equations for liquid water and water vapor are used, and no conversion between water vapor and liquid water is allowed in the first step, while in the second step a saturation adjustment procedure is performed that correctly allocates the water into its two phases based on the Clausius-Clapeyron formula. The numerical techniques described are first validated by comparing to a well-established benchmark problem. Particular attention is then paid to the effect of changing the time scale at which the moist variables are adjusted to the saturation requirements in two different variations of the two-step scheme. This study is motivated by the fact that when acoustic modes are integrated separately in time (neglecting phase change related phenomena), or when soundproof equations are integrated, the time scale for imposing saturation adjustment is typically much larger than the numerical one related to the acoustics. C1 [Duarte, Max; Almgren, Ann S.; Balakrishnan, Kaushik; Bell, John B.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Ctr Computat Sci & Engn, Berkeley, CA 94720 USA. [Romps, David M.] Univ Calif Berkeley, Dept Earth & Planetary Sci, Berkeley, CA 94720 USA. [Romps, David M.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Earth Sci, Berkeley, CA 94720 USA. RP Duarte, M (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Ctr Computat Sci & Engn, 1 Cyclotron Rd,MS 50A-1148, Berkeley, CA 94720 USA. EM mdgonzalez@lbl.gov RI Romps, David/F-8285-2011 FU Applied Mathematics Program of the DOE Office of Advance Scientific Computing Research under U.S. Department of Energy [DE-AC02-05CH11231]; Scientific Discovery through Advanced Computing (SciDAC) program - U.S. Department of Energy Office of Advanced Scientific Computing Research; Office of Biological and Environmental Research FX The work in the Center for Computational Sciences and Engineering at LBNL was supported by the Applied Mathematics Program of the DOE Office of Advance Scientific Computing Research under U.S. Department of Energy under Contract DE-AC02-05CH11231. DR was supported by the Scientific Discovery through Advanced Computing (SciDAC) program funded by the U.S. Department of Energy Office of Advanced Scientific Computing Research and Office of Biological and Environmental Research. NR 23 TC 5 Z9 5 U1 0 U2 7 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0027-0644 EI 1520-0493 J9 MON WEATHER REV JI Mon. Weather Rev. PD NOV PY 2014 VL 142 IS 11 BP 4269 EP 4283 DI 10.1175/MWR-D-13-00368.1 PG 15 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA AS4BW UT WOS:000344219400018 ER PT J AU Deyle, DR Hansen, RS Cornea, AM Li, LB Burt, AA Alexander, IE Sandstrom, RS Stamatoyannopoulos, JA Wei, CL Russell, DW AF Deyle, David R. Hansen, R. Scott Cornea, Anda M. Li, Li B. Burt, Amber A. Alexander, Ian E. Sandstrom, Richard S. Stamatoyannopoulos, John A. Wei, Chia-Lin Russell, David W. TI A genome-wide map of adeno-associated virus-mediated human gene targeting SO NATURE STRUCTURAL & MOLECULAR BIOLOGY LA English DT Article ID TRANSCRIPTION-ASSOCIATED RECOMBINATION; STALLED REPLICATION FORKS; DOUBLE-STRAND BREAKS; HOMOLOGOUS RECOMBINATION; HUMAN-CELLS; MINUTE VIRUS; CONVERGENT TRANSCRIPTION; DNA; VECTORS; REPEATS AB To determine which genomic features promote homologous recombination, we created a genome-wide map of gene targeting sites. We used an adeno-associated virus vector to target identical loci introduced as transcriptionally active retroviral vectors. A comparison of 2,000 targeted and untargeted sites showed that targeting occurred throughout the human genome and was not influenced by the presence of nearby CpG islands, sequence repeats or DNase l hypersensitive sites. Targeted sites were preferentially located within transcription units, especially when the target loci were transcribed in the opposite orientation to their surrounding chromosomal genes. We determined the impact of DNA replication by mapping replication forks, which revealed a preference for recombination at target loci transcribed toward an incoming fork. Our results constitute the first genome-wide screen of gene targeting in mammalian cells and demonstrate a strong recombinogenic effect of colliding polymerases. C1 [Deyle, David R.; Hansen, R. Scott; Li, Li B.; Burt, Amber A.; Russell, David W.] Univ Washington, Dept Med, Seattle, WA 98195 USA. [Cornea, Anda M.] Univ Washington, Dept Mol & Cell Biol, Seattle, WA 98195 USA. [Alexander, Ian E.] Childrens Med Res Inst, Gene Therapy Res Unit, Westmead, NSW, Australia. [Sandstrom, Richard S.; Stamatoyannopoulos, John A.] Univ Washington, Dept Genome Sci, Seattle, WA 98195 USA. [Wei, Chia-Lin] Joint Genome Inst, Genom Technol Dept, Walnut Creek, CA USA. [Russell, David W.] Univ Washington, Dept Biochem, Seattle, WA 98195 USA. RP Russell, DW (reprint author), Univ Washington, Dept Med, Seattle, WA 98195 USA. EM drussell@u.washington.edu RI LI, LI/G-6197-2015 FU US National Institutes of Health [R01DK55759, P01HL53750, R01AR48328, K08AR053917, U54HG007010]; Australian Department of Innovation, Industry, Science and Research [CG130052]; Genome Institute of Singapore (GIS) - Agency for Science, Technology and Research (A*STAR), Singapore FX We thank). Delrow, A. Dawson and R. Basom for microarray analysis, P. Hendrie for MVM data, T. Canfield for Repli-Seq processing and R. Hirata and R. Stolitenko for technical assistance. This work was supported by grants from the US National Institutes of Health (R01DK55759, P01HL53750 and R01AR48328) to D.W.R., (K08AR053917) to D.R.D. and (U54HG007010 and P01HL53750) to R.S.H. and J.A.S. This work was also supported by grants from the Australian Department of Innovation, Industry, Science and Research (CG130052) to D.W.R., I.E.A. and C.-L.W., and the Genome Institute of Singapore (GIS) funded by the Agency for Science, Technology and Research (A*STAR), Singapore, to C.-L.W. NR 57 TC 2 Z9 2 U1 1 U2 3 PU NATURE PUBLISHING GROUP PI NEW YORK PA 75 VARICK ST, 9TH FLR, NEW YORK, NY 10013-1917 USA SN 1545-9993 EI 1545-9985 J9 NAT STRUCT MOL BIOL JI Nat. Struct. Mol. Biol. PD NOV PY 2014 VL 21 IS 11 BP 969 EP 975 DI 10.1038/nsmb.2895 PG 7 WC Biochemistry & Molecular Biology; Biophysics; Cell Biology SC Biochemistry & Molecular Biology; Biophysics; Cell Biology GA AS8QM UT WOS:000344513400006 PM 25282150 ER PT J AU Briggs, JB Gulliford, J AF Briggs, J. Blair Gulliford, Jim TI An Overview of the International Reactor Physics Experiment Evaluation Project SO NUCLEAR SCIENCE AND ENGINEERING LA English DT Article ID BENCHMARK EVALUATION PROJECT AB Interest in high-quality integral benchmark data is increasing as efforts to quantify and reduce cakulational uncertainties associated with advanced modeling and simulation accelerate to meet the demands of next-generation reactor and advanced fuel cycle concepts. Two Organisation for Economic Co-operation and Development (OECD)/Nuclear Energy Agency (NEA) activities, the International Criticality Safety Benchmark Evaluation Project (ICSBEP), initiated in 1992, and the International Reactor Physics Experiment Evaluation Project (IRPhEP), initiated in 2003, have been identifying existing integral experiment data, evaluating those data, and providing integral benchmark specifications for methods and data validation for nearly two decades. Data provided by those two projects will be of use to the international reactor physics, criticality safety, and nuclear data communities for future decades. An overview of the IRPhEP and a brief update of the ICSBEP are provided in this paper. C1 [Briggs, J. Blair] Idaho Natl Lab, Idaho Falls, ID 83415 USA. [Gulliford, Jim] Org Econ Cooperat & Dev, Nucl Energy Agcy, F-92130 Paris, France. RP Briggs, JB (reprint author), Idaho Natl Lab, POB 1625,MS 3860, Idaho Falls, ID 83415 USA. EM j.briggs@inl.gov NR 9 TC 2 Z9 2 U1 0 U2 0 PU AMER NUCLEAR SOC PI LA GRANGE PK PA 555 N KENSINGTON AVE, LA GRANGE PK, IL 60526 USA SN 0029-5639 EI 1943-748X J9 NUCL SCI ENG JI Nucl. Sci. Eng. PD NOV PY 2014 VL 178 IS 3 BP 269 EP 279 PG 11 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS0FX UT WOS:000343954600002 ER PT J AU Palmiotti, G Briggs, JB Kugo, T Trumble, E Kahler, AC Lancaster, D AF Palmiotti, Giuseppe Briggs, J. Blair Kugo, Teruhiko Trumble, Edward (Fitz) Kahler, Albert C. (Skip) Lancaster, Dale TI Applications of Integral Benchmark Data SO NUCLEAR SCIENCE AND ENGINEERING LA English DT Article ID CORE PERFORMANCE PARAMETERS; BIAS FACTOR METHODS; PREDICTION ACCURACY; NEUTRONIC CHARACTERISTICS; REACTOR CORE; ENDF/B-VII.1; IMPROVEMENT; ADJUSTMENT; JENDL-4.0; ERROR AB The International Reactor Physics Experiment Evaluation Project (IRPhEP) and the International Criticality Safety Benchmark Evaluation Project (ICSBEP) provide evaluated integral benchmark data that may be used for validation of reactor physics/nuclear criticality safety analytical methods and data, nuclear data testing, advanced modeling and simulation, and safety analysis licensing activities. The handbooks produced by these programs are used in over 30 countries. Five example applications are presented in this paper: (a) use of IRPhEP data in uncertainty analyses and cross-section adjustment, (b) uncertainty evaluation methods for reactor core design at Japan Atomic Energy Agency using reactor physics experimental data, (c) application of benchmarking data to a broad range of criticality safety problems, (d) cross-section data testing with ICSBEP benchmarks, and (e) use of the International Handbook of Evaluated Reactor Physics Benchmark Experiments to support the power industry. C1 [Palmiotti, Giuseppe; Briggs, J. Blair] Idaho Natl Lab, Nucl Syst Design & Anal Div, Idaho Falls, ID 83415 USA. [Kugo, Teruhiko] Japan Atom Energy Agcy, Nucl Sci & Engn Directorate, Tokai, Ibaraki 3191195, Japan. [Trumble, Edward (Fitz)] URS Profess Solut, Aiken, SC 29803 USA. [Kahler, Albert C. (Skip)] Los Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USA. [Lancaster, Dale] NuclearConsultants Com, State Coll, PA 16801 USA. RP Palmiotti, G (reprint author), Idaho Natl Lab, Nucl Syst Design & Anal Div, POB 1625,MS 3860, Idaho Falls, ID 83415 USA. EM giuseppe.palmiotti@inl.gov NR 33 TC 1 Z9 1 U1 0 U2 1 PU AMER NUCLEAR SOC PI LA GRANGE PK PA 555 N KENSINGTON AVE, LA GRANGE PK, IL 60526 USA SN 0029-5639 EI 1943-748X J9 NUCL SCI ENG JI Nucl. Sci. Eng. PD NOV PY 2014 VL 178 IS 3 BP 295 EP 310 PG 16 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS0FX UT WOS:000343954600004 ER PT J AU Lell, RM AF Lell, Richard M. TI ZPPR-LMFR-EXP-010: Criticality and Sodium Void Worth Measurements in ZPPR-12 SO NUCLEAR SCIENCE AND ENGINEERING LA English DT Article AB The ZPPR-12 experiments conducted by Argonne National Laboratory were designed to study sodium void worth, cell heterogeneity, and neutron streaming. The small core made it possible to conduct sodium void and neutron streaming experiments over the entire core. The simple, clean, single-zone core had no internal structures such as internal blankets or control rods to affect measurements or complicate interpretation of experimental results. Criticality and selected sodium void worth measurements were evaluated for ZPPR-12, and a detailed uncertainty analysis was performed for the measurements chosen for the benchmark. Highly detailed as-built models were developed for all configurations selected for the benchmark. A simplified RZ model was also created for the criticality benchmark. MCNP5 calculations with ENDF/B-VII.0 data for the benchmark models show generally good agreement between calculated and benchmark values for k(eff) and sodium void worth. C1 Argonne Natl Lab, Nucl Engn Div, Argonne, IL 60439 USA. RP Lell, RM (reprint author), Argonne Natl Lab, Nucl Engn Div, 9700 South Cass Ave,Bldg 208, Argonne, IL 60439 USA. EM rmlell@anl.gov NR 7 TC 0 Z9 0 U1 1 U2 1 PU AMER NUCLEAR SOC PI LA GRANGE PK PA 555 N KENSINGTON AVE, LA GRANGE PK, IL 60526 USA SN 0029-5639 EI 1943-748X J9 NUCL SCI ENG JI Nucl. Sci. Eng. PD NOV PY 2014 VL 178 IS 3 BP 326 EP 334 PG 9 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS0FX UT WOS:000343954600006 ER PT J AU Bess, JD Montierth, LM Koberl, O Snoj, L AF Bess, John D. Montierth, Leland M. Koeberl, Oliver Snoj, Luka TI Benchmark Evaluation of HTR-PROTEUS Pebble Bed Experimental Program SO NUCLEAR SCIENCE AND ENGINEERING LA English DT Article ID CORE PHYSICS TESTS; MONTE-CARLO; 1ST CRITICALITY; NUCLEAR-SCIENCE; REACTOR; TECHNOLOGY; NEUTRON; LIBRARY AB Benchmark models were developed to evaluate II critical core configurations of the HTR-PROTEUS pebble bed experimental program. Various additional reactor physics measurements were carried out as part of this program; currently, only a total of 37 absorber rod worth measurements have been evaluated as acceptable benchmark experiments for cores 4, 9, and 10. Dominant uncertainties in the experimental k(eff) for all core configurations come from uncertainties in the U-235 enrichment of the fuel, impurities in the moderator pebbles, and the density and impurity content of the radial reflector. Calculations of keff with MCNP5 and ENDF/B-VII.0 neutron nuclear data are greater than the benchmark values but are within 1% and also within the 3 sigma uncertainty, except for core 4, which is the only randomly packed pebble configuration. Repeated calculations of k(eff) with MCNP6.1 and ENDF/B-VII.1 are lower than the benchmark values but are within 1% (similar to 3 sigma), except for cores 5 and 9, which calculate lower than the benchmark eigenvalues by <4 sigma. The primary difference between the two nuclear data libraries is the adjustment of the absorption cross section of graphite. Simulations of the absorber rod worth measurements are within 3 sigma of the benchmark experiment values. The complete benchmark evaluation details are available in the 2014 edition of the International Handbook of Evaluated Reactor Physics Benchmark Experiments. C1 [Bess, John D.; Montierth, Leland M.] Idaho Natl Lab, Idaho Falls, ID 83415 USA. [Koeberl, Oliver] Axpo Power AG Kernenergie, CH-5312 Dottingen, Switzerland. [Snoj, Luka] Jozef Stefan Inst, SI-1000 Ljubljana, Slovenia. RP Bess, JD (reprint author), Idaho Natl Lab, POB 1625,MS 3855, Idaho Falls, ID 83415 USA. EM john.bess@inl.gov OI Bess, John/0000-0002-4936-9103; Snoj, Luka/0000-0003-3097-5928 FU U.S. Department of Energy [DE-AC07-05ID14517] FX The authors would like to thank B. H. Dolphin, W. K. Terry, and C. A. Wemple, all formerly from Idaho National Laboratory, for their initial efforts in compiling data for the benchmark evaluation. The authors would like to express gratitude for the comprehensive review and support provided by J. W. Sterbentz, J. B. Briggs, and H. D. Gougar from Idaho National Laboratory; I. Lengar from Jozef Stefan Institute; and J. Kelly from University of Florida (formerly from PSI). Appreciation is provided for D. Hanlon from AMEC and B. Chukbar from Kurchatov Institute for their additional analyses of the core 4 critical configuration. Further indebtedness is expressed to all the international participants in the International Reactor Physics Experiment Evaluation Project for all their well-spent time and effort. This paper was prepared at Idaho National Laboratory for the U.S. Department of Energy under contract DE-AC07-05ID14517. NR 37 TC 0 Z9 0 U1 0 U2 1 PU AMER NUCLEAR SOC PI LA GRANGE PK PA 555 N KENSINGTON AVE, LA GRANGE PK, IL 60526 USA SN 0029-5639 EI 1943-748X J9 NUCL SCI ENG JI Nucl. Sci. Eng. PD NOV PY 2014 VL 178 IS 3 BP 387 EP 400 PG 14 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS0FX UT WOS:000343954600011 ER PT J AU Bess, JD Fujimoto, N AF Bess, John D. Fujimoto, Nozomu TI Benchmark Evaluation of Start-Up and Zero-Power Measurements at the High-Temperature Engineering Test Reactor SO NUCLEAR SCIENCE AND ENGINEERING LA English DT Article ID CORE PHYSICS TESTS; NUCLEAR-DATA; HTTR; SCIENCE; CRITICALITY; TECHNOLOGY; LIBRARY AB Benchmark models were developed to evaluate six cold-critical and two warm-critical, zero-power measurements of the high-temperature engineering test reactor (HTTR). Additional measurements of the subcritical configuration of the fully loaded core, core excess reactivity, shutdown margins, six isothermal temperature coefficients, and axial reaction-rate distributions were also evaluated as acceptable benchmark experiments. Insufficient information is publicly available to develop finely detailed models of the HTTR as much of the design information is still proprietary. The uncertainties in the benchmark models are judged to be of sufficient magnitude to encompass any biases and bias uncertainties incurred through the simplification process used to develop the benchmark models. However, use of the benchmark critical configurations of the HTTR for nuclear data adjustment is not recommended as the impact of these biases has not been addressed with rigorous detail. The impact of any simplification biases, if any, is not expected to significantly impact evaluation of the other reactor physics measurement calculations. Dominant uncertainties in the experimental k(eff) for all core configurations come from uncertainties in the impurity content of the various graphite blocks that compose the HTTR. Monte Carlo calculations of k(eff) are between 0.9% and 2.7% greater than the benchmark values. Reevaluation of the HTTR models as additional information becomes available could improve the quality of this benchmark and possibly reduce the computational biases. High-quality characterization of graphite impurities would significantly improve the quality of the HTTR benchmark assessment. Simulations of the other reactor physics measurements are in good agreement with the benchmark experiment values. The complete benchmark evaluation details are available in the 2014 edition of the International Handbook of Evaluated Reactor Physics Benchmark Experiments. C1 [Bess, John D.] Idaho Natl Lab, Idaho Falls, ID 83415 USA. [Fujimoto, Nozomu] Japan Atom Energy Agcy, Oarai Res & Dev Ctr, Dept HTTR, Oarai, Ibaraki 3111393, Japan. RP Bess, JD (reprint author), Idaho Natl Lab, POB 1625,MS 3855, Idaho Falls, ID 83415 USA. EM john.bess@inl.gov OI Bess, John/0000-0002-4936-9103 FU U.S. Department of Energy [DE-AC07-05ID14517] FX The authors would like to thank J. W. Sterbentz and B. H. Dolphin from Idaho National Laboratory and L. Snoj from Jozef Stefan Institute for their review and support in developing a comprehensive benchmark evaluation. Extra gratitude is expressed for A. Zukeran, retired from JAEA, for his collaboration in obtaining and reviewing HTTR data, including translation from Japanese into English. Further appreciation is expressed to all the international participants in the International Reactor Physics Experiment Evaluation Project for all their well-spent time and effort. This paper was prepared at Idaho National Laboratory for the U.S. Department of Energy under contract DE-AC07-05ID14517. NR 26 TC 1 Z9 1 U1 0 U2 1 PU AMER NUCLEAR SOC PI LA GRANGE PK PA 555 N KENSINGTON AVE, LA GRANGE PK, IL 60526 USA SN 0029-5639 EI 1943-748X J9 NUCL SCI ENG JI Nucl. Sci. Eng. PD NOV PY 2014 VL 178 IS 3 BP 414 EP 427 PG 14 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS0FX UT WOS:000343954600013 ER PT J AU Newhouse, AE Polin-McGuigan, LD Baier, KA Valletta, KER Rottmann, WH Tschaplinski, TJ Maynard, CA Powell, WA AF Newhouse, Andrew E. Polin-McGuigan, Linda D. Baier, Kathleen A. Valletta, Kristia E. R. Rottmann, William H. Tschaplinski, Timothy J. Maynard, Charles A. Powell, William A. TI Transgenic American chestnuts show enhanced blight resistance and transmit the trait to T1 progeny SO PLANT SCIENCE LA English DT Article DE Restoration; Heritage tree; Genetic engineering; Invasive; Co-transformation; Fungus ID AGROBACTERIUM-MEDIATED TRANSFORMATION; DENTATA MARSH. BORKH.; OXALATE OXIDASE; ANTIMICROBIAL PEPTIDES; PARTICLE BOMBARDMENT; SOMATIC EMBRYOS; SEPTORIA-MUSIVA; EXPRESSION; CASTANEA; GENE AB American chestnut (Castanea dentata) is a classic example of a native keystone species that was nearly eradicated by an introduced fungal pathogen. This report describes progress made toward producing a fully American chestnut tree with enhanced resistance to the blight fungus (Cryphonectria parasitica). The transgenic American chestnut 'Darling4,' produced through an Agrobacterium co-transformation procedure to express a wheat oxalate oxidase gene driven by the VspB vascular promoter, shows enhanced blight resistance at a level intermediate between susceptible American chestnut and resistant Chinese chestnut (Castanea mollissima). Enhanced resistance was identified first with a leaf-inoculation assay using young chestnuts grown indoors, and confirmed with traditional stem inoculations on 3- and 4-year-old field-grown trees. Pollen from 'Darling4' and other events was used to produce transgenic T1 seedlings, which also expressed the enhanced resistance trait in leaf assays. Outcrossed transgenic seedlings have several advantages over tissue-cultured plantlets, including increased genetic diversity and faster initial growth. This represents a major step toward the restoration of the majestic American chestnut. (C) 2014 Elsevier Ireland Ltd. All rights reserved. C1 [Newhouse, Andrew E.; Polin-McGuigan, Linda D.; Baier, Kathleen A.; Valletta, Kristia E. R.; Maynard, Charles A.; Powell, William A.] SUNY Coll Environm Sci & Forestry, Syracuse, NY 13210 USA. [Rottmann, William H.] Arborgen Inc, Ridgeville, SC 29472 USA. [Tschaplinski, Timothy J.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. RP Powell, WA (reprint author), SUNY Coll Environm Sci & Forestry, 1 Forestry Dr, Syracuse, NY 13210 USA. EM wapowell@esf.edu OI Tschaplinski, Timothy/0000-0002-9540-6622 FU American Chestnut Foundation - New York Chapter; Forest Health Initiative; BRAG -Biotechnology Risk Assessment Program from the USDA National Institute of Food and Agriculture [2008-39211-19564]; ArborGen Inc.; Unger Vetlesen Foundation; Department of Energy, Office of Science, Biological and Environmental Research, Plant-microbe Interfaces Science Focus Area (at Oak Ridge National Laboratory, Oak Ridge, TN, U.S.A.); US Government [DE-AC05-00OR22725]; SUNY-ESF Physical Plant FX Funding sources included: The American Chestnut Foundation - New York Chapter, the Forest Health Initiative, BRAG -Biotechnology Risk Assessment Program Competitive Grant no. 2008-39211-19564 from the USDA National Institute of Food and Agriculture, ArborGen Inc., and the Unger Vetlesen Foundation. This research was supported, in part, by the Department of Energy, Office of Science, Biological and Environmental Research, as part of the Plant-microbe Interfaces Science Focus Area (based at Oak Ridge National Laboratory, Oak Ridge, TN, U.S.A.). This manuscript has been co-authored by a contractor of the US Government under contract DE-AC05-00OR22725. None of these funding sources were involved in study design, data collection, data analysis, interpretation of results, writing of this report, or the decision to submit this report for publication.; Help and support were graciously provided by: Maud Hinchee, Herb & Jane Darling and Richard Wells of TACF-NY, the SUNY-ESF Physical Plant, Aaron Barrigar, Collin Bartholomew, Clara Miller, Megan Newhouse, Drew Teller, and Allison Oakes. NR 44 TC 9 Z9 9 U1 14 U2 59 PU ELSEVIER IRELAND LTD PI CLARE PA ELSEVIER HOUSE, BROOKVALE PLAZA, EAST PARK SHANNON, CO, CLARE, 00000, IRELAND SN 0168-9452 J9 PLANT SCI JI Plant Sci. PD NOV PY 2014 VL 228 SI SI BP 88 EP 97 DI 10.1016/j.plantsci.2014.04.004 PG 10 WC Biochemistry & Molecular Biology; Plant Sciences SC Biochemistry & Molecular Biology; Plant Sciences GA AS7NI UT WOS:000344442200010 PM 25438789 ER PT J AU White, JC Godsey, ME Bhatia, SR AF White, Joseph C. Godsey, Megan E. Bhatia, Surita R. TI Perfluorocarbons enhance oxygen transport in alginate-based hydrogels SO POLYMERS FOR ADVANCED TECHNOLOGIES LA English DT Article; Proceedings Paper CT 12th Conference on Polymers for Advanced Technologies (PAT) CY 2013 CL Belin, GERMANY DE oxygen; hydrogels; perfluorocarbon; biomaterials; tissue engineering ID CELL ENCAPSULATION; EMULSIONS; DELIVERY; CULTURE; TISSUE; DIFFERENTIATION; DIFFUSION; MATRICES; CARRIERS AB A major limitation of current soft biomaterials for tissue engineering and cell encapsulation is inadequate transport of oxygen to cells and tissues. Oxygen transport is a challenge in nearly all aqueous hydrogel biomaterials. Here, we report the effective diffusivity of oxygen in alginate-based hydrogels containing stable perfluorocarbon (PFC) emulsions. Incorporation of 7% perfluorooctyl bromide into the alginate gels was found to increase oxygen permeability by a factor of three. Our work also demonstrates that the increase in oxygen transport is largely due to improved oxygen solubility in PFC-containing gels. Although promising, this improved oxygen transport comes with a trade-off in terms of mechanical robustness. This must be carefully considered in future development of PFC-containing hydrogels for biomedical devices. Copyright (c) 2014 John Wiley & Sons, Ltd. C1 [White, Joseph C.; Godsey, Megan E.; Bhatia, Surita R.] Univ Massachusetts, Dept Chem Engn, Amherst, MA 01003 USA. [Bhatia, Surita R.] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA. [Bhatia, Surita R.] Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11793 USA. RP Bhatia, SR (reprint author), SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA. EM surita.bhatia@stonybrook.edu RI Bhatia, Surita/B-4536-2008; White, Joe/I-8148-2015 NR 26 TC 2 Z9 2 U1 7 U2 28 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1042-7147 EI 1099-1581 J9 POLYM ADVAN TECHNOL JI Polym. Adv. Technol. PD NOV PY 2014 VL 25 IS 11 SI SI BP 1242 EP 1246 DI 10.1002/pat.3296 PG 5 WC Polymer Science SC Polymer Science GA AS0UU UT WOS:000343994800008 ER PT J AU Yu, YQ Cheng, X AF Yu, Y. Q. Cheng, X. TI Experimental study of water film flow on large vertical and inclined flat plate SO PROGRESS IN NUCLEAR ENERGY LA English DT Article DE PCCS; Water film; Flat plate; Solitary wave; Inclined plate ID LIQUID-FILM; FALLING FILMS; WAVES; GAS; LAYER; WALL; THIN AB Free falling water film flow is widely applied in many industrial fields, including the PCCS (Passive Containment Cooling System) of the Generation III nuclear power plant. This paper describes an experimental study of free falling water film flow on a vertical and an inclined flat plate (2 x 5 m and 0.4 x 5 m). A capacitance probe and high-speed camera were used to capture the characteristics of film flow with different Reynolds (50 similar to 3600). Many statistical variables of the film flow are presented, such as film thickness, wave length, wave frequency, and wave velocity etc. The test data are also compared with Nusselt theory and some empirical correlations from other researches. The effect of Reynolds number and inclination of the plate on film flow are studied. Three transition points which indicate different flow mechanism changes are found by analyzing different statistical film flow variables. With the increase of Reynolds number, the solitary waves of film flow develop from low speed waves of high frequency and short wave length to high speed waves of low frequency and long wave length. Empirical correlations of (delta) over bar, delta(min), delta(max), delta(sub), delta(p), U-wave of film flow on large flat plate are obtained. It could be applied to the safety analysis program for PCCS. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Yu, Y. Q.; Cheng, X.] Shanghai Jiao Tong Univ, Sch Nucl Sci & Engn, Shanghai 200240, Peoples R China. [Cheng, X.] Inst Nucl & Energy Technol, Res Ctr Karlsruhe, D-76021 Karlsruhe, Germany. [Yu, Y. Q.] Argonne Natl Lab, Nucl Engn Div, Argonne, IL 60439 USA. RP Yu, YQ (reprint author), Argonne Natl Lab, Nucl Engn Div, 9700 S Cass Ave, Argonne, IL 60439 USA. EM yyu@anl.gov FU China National Key Projects [2010ZX06002-005]; U.S. Department of Energy, Basic Energy Sciences, Office of Science [DE-AC02-06CH11357] FX The support from China National Key Projects 2010ZX06002-005 is gratefully acknowledged. This work is also supported by the U.S. Department of Energy, Basic Energy Sciences, Office of Science, under contract # DE-AC02-06CH11357. NR 30 TC 3 Z9 3 U1 3 U2 17 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0149-1970 J9 PROG NUCL ENERG JI Prog. Nucl. Energy PD NOV PY 2014 VL 77 BP 176 EP 186 DI 10.1016/j.pnucene.2014.07.001 PG 11 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS3WT UT WOS:000344206700017 ER PT J AU McFarlane, H AF McFarlane, Harold TI Special Section on Status of Generation IV Reactor Development Preface SO PROGRESS IN NUCLEAR ENERGY LA English DT Editorial Material C1 Idaho Natl Lab, Idaho Falls, ID 83415 USA. RP McFarlane, H (reprint author), Idaho Natl Lab, 2525 N Fremont, Idaho Falls, ID 83415 USA. EM harold.mcfarlane@inl.gov NR 0 TC 1 Z9 1 U1 1 U2 1 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0149-1970 J9 PROG NUCL ENERG JI Prog. Nucl. Energy PD NOV PY 2014 VL 77 BP 239 EP 239 DI 10.1016/j.pnucene.2014.03.008 PG 1 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS3WT UT WOS:000344206700023 ER PT J AU Kelly, JE AF Kelly, John E. TI Generation IV International Forum: A decade of progress through international cooperation SO PROGRESS IN NUCLEAR ENERGY LA English DT Article DE Generation IV; Reactor systems; Forum; Methodology working groups; Nuclear fuel; Reactor coolant AB The Generation IV International Forum has marked significant progress in developing a next generation of reactor technologies that break out of the limitations of currently deployed nuclear energy systems. In slightly more than 10 years, the Forum down selected to the six most promising systems, forged a powerful framework for multilateral cooperation, organized itself into the necessary functional groups, created four overarching research objectives, established a dozen international projects, and completed hundreds of milestones. The Forum has focused research on viability and performance issues. A revised technology development roadmap completed in 2013 lays out the research agenda for the next decade. This paper summarizes the overall accomplishments of the Forum and the development status of the six advanced reactor systems. Accompanying papers describe the related research and development activities for each system. Published by Elsevier Ltd. C1 US DOE, Generat Int Forum 4, Nucl Reactor Technol, Washington, DC 20585 USA. RP Kelly, JE (reprint author), US DOE, Generat Int Forum 4, Nucl Reactor Technol, 1000 Independence Ave SW, Washington, DC 20585 USA. EM johnE.kelly@nuclear.energy.gov NR 17 TC 8 Z9 8 U1 0 U2 11 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0149-1970 J9 PROG NUCL ENERG JI Prog. Nucl. Energy PD NOV PY 2014 VL 77 BP 240 EP 246 DI 10.1016/j.pnucene.2014.02.010 PG 7 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS3WT UT WOS:000344206700024 ER PT J AU Aoto, K Dufour, P Yang, HY Glatz, JP Kim, Y Ashurko, Y Hill, R Uto, N AF Aoto, Kazumi Dufour, Philippe Yang Hongyi Glatz, Jean Paul Kim, Yeong-il Ashurko, Yury Hill, Robert Uto, Nariaki TI A summary of sodium-cooled fast reactor development SO PROGRESS IN NUCLEAR ENERGY LA English DT Article DE Sodium-Cooled Fast Reactor; Closed fuel cycle; Minor actinide management; Improved safety performance; Long term development experience; Generation IV International Forum AB Much of the basic technology for the Sodium-cooled fast Reactor (SFR) has been established through long term development experience with former fast reactor programs, and is being confirmed by the Phenix end-of-life tests in France, the restart of Monju in Japan, the lifetime extension of BN-600 in Russia, and the startup of the China Experimental Fast Reactor in China. Planned startup in 2014 for new SFRs: BN-800 in Russia and PFBR in India, will further enhance the confirmation of the SFR basic technology. Nowadays, the SFR development has advanced to aiming at establishment of the Generation-IV system which is dedicated to sustainable energy generation and actinide management, and several advanced SFR concepts are under development such as PRISM, JSFR, ASTRID, PGSFR, BN-1200, and CFR-600. Generation-IV International Forum is an international collaboration framework where various R&D activities are progressing on design of system and component, safety and operation, advanced fuel, and actinide cycle for the Generation-IV SFR development, and will play a beneficial role of promoting them thorough providing an opportunity to share the past experience and the latest data of design and R&D among countries developing SFR. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Aoto, Kazumi] Japan Atom Energy Agcy, Chiyoda Ku, Tokyo 1008577, Japan. [Dufour, Philippe] French Alternat Energies & Atom Energy Commiss CE, Cadarache, France. [Yang Hongyi] CIAE, Beijing, Peoples R China. [Glatz, Jean Paul] European Commiss, Joint Res Ctr, Karlsruhe, Germany. [Kim, Yeong-il] Korea Atom Energy Res Inst, Taejon, South Korea. [Ashurko, Yury] Inst Phys & Power Engn, Obninsk, Russia. [Hill, Robert] Argonne Natl Lab, Argonne, IL 60439 USA. [Uto, Nariaki] Japan Atom Energy Agcy, Oarai, Ibaraki, Japan. RP Aoto, K (reprint author), Japan Atom Energy Agcy, Chiyoda Ku, 2-2-2 Uchisaiwai, Tokyo 1008577, Japan. EM aoto.kazumi@jaea.go.jp NR 15 TC 4 Z9 5 U1 7 U2 29 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0149-1970 J9 PROG NUCL ENERG JI Prog. Nucl. Energy PD NOV PY 2014 VL 77 BP 247 EP 265 DI 10.1016/j.pnucene.2014.05.008 PG 19 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS3WT UT WOS:000344206700025 ER PT J AU Futterer, MA Fu, L Sink, C de Groot, S Pouchon, M Kim, YW Carre, F Tachibana, Y AF Futterer, Michael A. Fu, Li Sink, Carl de Groot, Sander Pouchon, Manuel Kim, Yong Wan Carre, Frank Tachibana, Yukio TI Status of the very high temperature reactor system SO PROGRESS IN NUCLEAR ENERGY LA English DT Article DE Generation IV international forum; Very high temperature reactor; Materials; Fuel; Hydrogen production; International cooperation ID HTR-PM; EXPERIENCE; PROJECT AB The purpose of this paper is to provide an update on the international effort in the development of the Very High Temperature Reactor system pursued through international collaboration in the Generation IV International Forum (GIF) and an outlook for further activities. The initial motivations to develop this reactor type are recalled, a historical overview is given about technology developments and test reactors since 1945 and several of the targeted non-electric applications of VHTR power are addressed. Cooperation in the frame of GIF is clearly beneficial for all project partners. Initially, a wealth of historical experience was collected and shared in the form of documents, dedicated workshops or fuel and material samples. This exchange included properties data, fabrication, irradiation and post-irradiation testing methods, quality assurance, design and analysis tools and methods, as well as the experience in building and operating related equipment. In the further course of the project execution, time, effort and scarce facilities (such as irradiation space or hot cell equipment) are shared, they accelerate progress and create synergies. Recent highlights from currently active GIF VHTR R&D projects (Materials, Fuel and Fuel Cycle, Hydrogen Production) are then provided and placed into the context of the GIF VHTR signatories' national programs. The majority of these currently focus on licensing requirements for demonstrators of near term process steam production scenarios while more aggressive, longer term and higher temperature applications are mainly pursued to enable thermochemical production of bulk hydrogen. Based on the VHTR's high technology readiness level, orientations for future R&D are outlined which would contribute to enhancing the system's market readiness level. These include work on System Integration and Assessment, Safety Analysis and Demonstration, Waste Minimization and Cost Reductions. The inherent safety characteristics of the VHTR are a precious asset for it to become a strong response to today's concerns of nuclear safety, energy security and climate change. (C) 2014 Published by Elsevier Ltd. C1 [Futterer, Michael A.] Inst Energy & Transport, Joint Res Ctr, Commiss European Communities, NL-1755 ZG Petten, Netherlands. [Fu, Li] Tsinghua Univ, INEI, Beijing 100084, Peoples R China. [Sink, Carl] US DOE, Washington, DC 20585 USA. [de Groot, Sander] NRG, NL-1755 ZG Petten, Netherlands. [Pouchon, Manuel] Paul Scherrer Inst, CH-5232 Villigen, Switzerland. [Kim, Yong Wan] Korea Atom Energy Res Inst, Taejon 305353, South Korea. [Carre, Frank] CEA, F-91191 Gif Sur Yvette, France. [Tachibana, Yukio] JAEA, Oarai, Ibaraki 3111393, Japan. RP Futterer, MA (reprint author), Inst Energy & Transport, Joint Res Ctr, Commiss European Communities, NL-1755 ZG Petten, Netherlands. EM michael.fuetterer@ec.europa.eu; lifu@mail.tsinghua.edu.cn; carl.sink@nuclear.energy.gov; s.degroot@nrg.eu; manuel.pouchon@psi.ch; ywkim@kaeri.re.kr; franck.carre@cea.fr; tachibana.yukio@jaea.gojp RI Pouchon, Manuel Alexandre/J-7213-2015 NR 30 TC 4 Z9 4 U1 2 U2 30 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0149-1970 J9 PROG NUCL ENERG JI Prog. Nucl. Energy PD NOV PY 2014 VL 77 BP 266 EP 281 DI 10.1016/j.pnucene.2014.01.013 PG 16 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS3WT UT WOS:000344206700026 ER PT J AU Serp, J Allibert, M Benes, O Delpech, S Feynberg, O Ghetta, V Heuer, D Holcomb, D Ignatiev, V Kloosterman, JL Luzzi, L Merle-Lucotte, E Uhlir, J Yoshioka, R Dai, ZM AF Serp, Jerome Allibert, Michel Benes, Ondrej Delpech, Sylvie Feynberg, Olga Ghetta, Veronique Heuer, Daniel Holcomb, David Ignatiev, Victor Kloosterman, Jan Leen Luzzi, Lelio Merle-Lucotte, Elsa Uhlir, Jan Yoshioka, Ritsuo Dai Zhimin TI The molten salt reactor (MSR) in generation IV: Overview and perspectives SO PROGRESS IN NUCLEAR ENERGY LA English DT Article DE Molten salt reactor; Gen IV; Nuclear systems; Neutronic performance; Fuel cycle ID HIGH-TEMPERATURE REACTOR; FUEL-CYCLE; CORE PHYSICS; THORIUM; DESIGN; SYSTEM AB Molten Salt Reactors (MSR) with the fuel dissolved in the liquid salt and fluoride-salt-cooled High-temperature Reactors (FHR) have many research themes in common. This paper gives an overview of the international R&D efforts on these reactor types carried out in the framework of Generation-IV. Many countries worldwide contribute to this reactor technology, among which the European Union, France, Japan, Russia and the USA, and for the past few years China and India have also contributed. In general, the international R&D focuses on three main lines of research. The USA focuses on the FHR, which will be a nearer-term application of liquid salt as a reactor coolant, while China also focuses on solid fuel reactors as a precursor to molten salt reactors with liquid fuel and a thermal neutron spectrum. The EU, France and Russia are focusing on the development of a fast spectrum molten salt reactor capable of either breeding or transmutation of actinides from spent nuclear fuel. Future research topics focus on liquid salt technology and materials behavior, the fuel and fuel cycle chemistry and modeling, and the numerical simulation and safety design aspects of the reactor. MSR development attracts more and more attention every year, because it is generally considered as most sustainable of the six Generation-IV designs with intrinsic safety features. Continuing joint efforts are needed to advance common molten salt reactor technologies. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Serp, Jerome] CEA Marcoule, Radiochem & Proc Dept, Nucl Energy Div, SCPS LEPS, F-30207 Bagnols Sur Ceze, France. [Benes, Ondrej] Commiss European Communities, Joint Res Ctr, Inst Transuranium Elements, D-76125 Karlsruhe, Germany. [Delpech, Sylvie] Univ Paris, IPNO, Grp Radiochim, F-91406 Orsay, France. [Allibert, Michel; Ghetta, Veronique; Heuer, Daniel; Merle-Lucotte, Elsa] UJF Grenoble, INP, IN2P3 CNRS, LPSC, F-38026 Grenoble, France. [Holcomb, David] Oak Ridge Natl Lab, Oak Ridge, TN USA. [Ignatiev, Victor] Kurchatov Inst, Natl Res Ctr, Moscow, Russia. [Kloosterman, Jan Leen] Delft Univ Technol, Dept Radiat Sci & Technol, NL-2629 JB Delft, Netherlands. [Luzzi, Lelio] Politecn Milan, Dept Energy, Nucl Engn Div, I-20133 Milan, Italy. [Uhlir, Jan] Res Ctr Rez, CZ-25068 Rez, Czech Republic. [Yoshioka, Ritsuo] Int Thorium Molten Salt Forum, Tokyo, Japan. [Dai Zhimin] Chinese Acad Sci, Shanghai 201800, Peoples R China. RP Serp, J (reprint author), CEA Marcoule, Radiochem & Proc Dept, Nucl Energy Div, SCPS LEPS, F-30207 Bagnols Sur Ceze, France. EM jerome.serp@cea.fr; mallibert@orange.fr; ondrej.benes@ec.europa.eu; delpech@ipno.in2p3.fr; olga.fein@yandex.ru; Veronique.Ghetta@lpsc.in2p3.fr; Daniel.Heuer@lpsc.in2p3.fr; HolcombDE@oml.gov; ignatiev@vver.kiae.ru; J.L.Kloosterman@tudelft.nl; lelio.luzzi@polimi.it; elsa.merle@lpsc.in2p3.fr; jan.Uhlir@cvrez.cz; yoshioka@nifty.ne.jp; daizm@sinap.ac.cn RI Serp, Jerome/C-2935-2016; OI Serp, Jerome/0000-0001-6677-6352; Holcomb, David/0000-0001-8263-4661; Luzzi, Lelio/0000-0002-9754-4535 NR 54 TC 43 Z9 50 U1 20 U2 126 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0149-1970 J9 PROG NUCL ENERG JI Prog. Nucl. Energy PD NOV PY 2014 VL 77 BP 308 EP 319 DI 10.1016/j.pnucene.2014.02.014 PG 12 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS3WT UT WOS:000344206700029 ER PT J AU Cisneros-Dozal, LM Huang, YS Heikoop, JM Fawcett, PJ Fessenden, J Anderson, RS Meyers, PA Larson, T Perkins, G Toney, J Werne, JP Goff, F WoldeGabriel, G Allen, CD Berke, MA AF Cisneros-Dozal, Luz M. Huang, Yongsong Heikoop, Jeffrey M. Fawcett, Peter J. Fessenden, Julianna Anderson, R. Scott Meyers, Philip A. Larson, Toti Perkins, George Toney, Jaime Werne, Josef P. Goff, Fraser WoldeGabriel, Giday Allen, Craig D. Berke, Melissa A. TI Assessing the strength of the monsoon during the late Pleistocene in southwestern United States SO QUATERNARY SCIENCE REVIEWS LA English DT Article DE Monsoonal precipitation; Hydrogen isotope; Leaf plant waxes; Southwestern US; Drought ID NORTH-AMERICAN MONSOON; CLIMATE VARIABILITY; N-ALKANES; MILLENNIAL-SCALE; DEVILS-HOLE; LEAF WATER; RECORD; PRECIPITATION; PLANTS; MODEL AB Improved predictions of drought require an understanding of natural and human-induced climate variability. Long-term records across glacial-interglacial cycles provide the natural component of variability, however few such records exist for the southwestern United States (US) and quantitative or semiquantitative records of precipitation are absent. Here we use the hydrogen isotope (delta D) value of C-28 n-alkanoic acid in lacustrine sediments of Pleistocene age to reconstruct delta D values of precipitation in northern New Mexico over two glacial-interglacial cycles (similar to 550,000-360,000 years before present) and obtain a record of monsoon strength. Overall, reconstructed delta D values range from -53.8 parts per thousand to -94.4 parts per thousand, with a mean value of -77.5 +/- 8 parts per thousand. Remarkably, this variation falls within the measured present-day summer monsoonal and winter weighted means (-50.3 +/- 3 parts per thousand and 106.4 +/- 20 parts per thousand respectively), suggesting that processes similar to those of present time also controlled precipitation during Marine Isotope Stage (MIS) 13 to 10. Using the delta D summer monsoonal and winter mean values as end-members, we interpret our reconstructed delta D record of precipitation as a direct, and semi-quantitative, indicator of monsoon strength during MIS 13 to 10. Interglacial periods were characterized by greater monsoon strength but also greater variability compared to glacial periods. Pronounced cycles in the strength of the monsoon occurred during interglacial periods and in general were positively correlated with maximum mean annual temperatures. Our estimates of monsoon strength are supported by independent proxies of ecosystem productivity, namely, TOC, delta C-13 of TOC and Si/Ti ratio and warm pollen taxa Juniperus and Quercus. Interglacial variability in the strength of the monsoon resembles a response to the land-sea surface temperature contrast (LSTC) except for the early part of MIS 11. During this period, LSTC would have remained relatively strong while monsoonal strength decreased to a minimum. This minimum occurred following the warmest interval of MIS 11, suggesting a more complex driving of monsoon strength during warm periods. In addition, this period of monsoon minimum coincided with a core section of mud-cracked sediments that suggest low monsoonal precipitation was an important factor in the onset of drought. Our estimates of monsoon strength represent a record of natural variability in the region that is relevant to present time, in particular the variability during interglacial MIS 11, which is considered an analog for the current interglacial. Our results suggest that natural variability can cause significant reductions in monsoonal precipitation with the implication of a potentially adverse effect from sustained warming. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Cisneros-Dozal, Luz M.; Heikoop, Jeffrey M.; Fessenden, Julianna; Larson, Toti; Perkins, George; WoldeGabriel, Giday] Los Alamos Natl Lab, Div Earth & Environm Sci, Los Alamos, NM 87545 USA. [Huang, Yongsong; Toney, Jaime] Brown Univ, Dept Geol Sci, Providence, RI 02912 USA. [Fawcett, Peter J.; Goff, Fraser] Univ New Mexico, Dept Earth & Planetary Sci, Albuquerque, NM 87131 USA. [Werne, Josef P.; Berke, Melissa A.] Univ Minnesota, Large Lakes Observ, Duluth, MN 55812 USA. [Anderson, R. Scott] No Arizona Univ, Sch Earth Sci & Environm Sustainabil, Flagstaff, AZ 86011 USA. [Anderson, R. Scott] No Arizona Univ, Lab Paleoecol, Bilby Res Ctr, Flagstaff, AZ 86011 USA. [Meyers, Philip A.] Univ Michigan, Dept Earth & Environm Sci, Ann Arbor, MI 48109 USA. [Allen, Craig D.] USGS Ft Collins Sci Ctr, Jemez Mt Field Stn, Los Alamos, NM 87544 USA. RP Cisneros-Dozal, LM (reprint author), Scottish Univ Environm Res Ctr, Nat Environm Res Council, Radiocarbon Facil East Kilbride, E Kilbride G75 0QF, Lanark, Scotland. EM Malu.Cisneros@glasgow.ac.uk RI Heikoop, Jeffrey/C-1163-2011; Toney, Jaime/I-5083-2012; OI Toney, Jaime/0000-0003-3182-6887; Heikoop, Jeffrey/0000-0001-7648-3385 FU NSF [P2C2]; IGPP LANL; USGS Western Mountain Initiative FX We thank LRC/LacCore for assistance with core sampling. We thank two anonymous reviewers for their helpful comments on this manuscript. This work was supported by the NSF P2C2, IGPP LANL and the USGS Western Mountain Initiative. NR 46 TC 1 Z9 1 U1 1 U2 21 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0277-3791 J9 QUATERNARY SCI REV JI Quat. Sci. Rev. PD NOV 1 PY 2014 VL 103 BP 81 EP 90 DI 10.1016/j.quascirev.2014.08.022 PG 10 WC Geography, Physical; Geosciences, Multidisciplinary SC Physical Geography; Geology GA AS3YM UT WOS:000344211000007 ER PT J AU Romanyukha, A Trompier, F Reyes, RA Christensen, DM Iddins, CJ Sugarman, SL AF Romanyukha, Alexander Trompier, Francois Reyes, Ricardo A. Christensen, Doran M. Iddins, Carol J. Sugarman, Stephen L. TI Electron paramagnetic resonance radiation dose assessment in fingernails of the victim exposed to high dose as result of an accident SO RADIATION AND ENVIRONMENTAL BIOPHYSICS LA English DT Article DE EPR; ESR; Radiation accident; Fingernail dosimetry ID EPR DOSIMETRY; RADICALS; ESR AB In this paper, we report results of radiation dose measurements in fingernails of a worker who sustained a radiation injury to his right thumb while using 130 kVp X-ray for nondestructive testing. Clinically estimated absorbed dose was about 20-25 Gy. Electron paramagnetic resonance (EPR) dose assessment was independently carried out by two laboratories, the Naval Dosimetry Center (NDC) and French Institut de Radioprotection et de SA >> ret, Nucl,aire (IRSN). The laboratories used different equipments and protocols to estimate doses in the same fingernail samples. NDC used an X-band transportable EPR spectrometer, e-scan produced by Bruker BioSpin, and a universal dose calibration curve. In contrast, IRSN used a more sensitive Q-band stationary spectrometer (EMXplus) with a new approach for the dose assessment (dose saturation method), derived by additional dose irradiation to known doses. The protocol used by NDC is significantly faster than that used by IRSN, nondestructive, and could be done in field conditions, but it is probably less accurate and requires more sample for the measurements. The IRSN protocol, on the other hand, potentially is more accurate and requires very small amount of sample but requires more time and labor. In both EPR laboratories, the intense radiation-induced signal was measured in the accidentally irradiated fingernails and the resulting dose assessments were different. The dose on the fingernails from the right thumb was estimated as 14 +/- A 3 Gy at NDC and as 19 +/- A 6 Gy at IRSN. Both EPR dose assessments are given in terms of tissue kerma. This paper discusses the experience gained by using EPR for dose assessment in fingernails with a stationary spectrometer versus a portable one, the reasons for the observed discrepancies in dose, and potential advantages and disadvantages of each approach for EPR measurements in fingernails. C1 [Romanyukha, Alexander] Naval Dosimetry Ctr, Bethesda, MD 20889 USA. [Trompier, Francois] Inst Radioprotect Surete Nucl, Fontenay Aux Roses, France. [Reyes, Ricardo A.] Uniformed Serv Univ Hlth Sci, Bethesda, MD 20814 USA. [Christensen, Doran M.; Iddins, Carol J.; Sugarman, Stephen L.] ORISE, REAC TS, Oak Ridge, TN USA. RP Romanyukha, A (reprint author), Naval Dosimetry Ctr, Bethesda, MD 20889 USA. EM alexander.romanyukha@med.navy.mil OI TROMPIER, Francois/0000-0002-8776-6572 FU Dartmouth Physically Based Center for Medical Countermeasures Against Radiation; NIH from the National Institute of Allergy and Infectious Diseases [U19-AI091173] FX The authors would like to thank Dr. Art Heiss (BrukerBiospin USA) for excellent technical support of this work. The authors would like to acknowledge funding from the Pilot Project Program of the Dartmouth Physically Based Center for Medical Countermeasures Against Radiation, with NIH funding from the National Institute of Allergy and Infectious Diseases (U19-AI091173). NR 20 TC 13 Z9 13 U1 0 U2 6 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0301-634X EI 1432-2099 J9 RADIAT ENVIRON BIOPH JI Radiat. Environ. Biophys. PD NOV PY 2014 VL 53 IS 4 BP 755 EP 762 DI 10.1007/s00411-014-0553-6 PG 8 WC Biology; Biophysics; Environmental Sciences; Radiology, Nuclear Medicine & Medical Imaging SC Life Sciences & Biomedicine - Other Topics; Biophysics; Environmental Sciences & Ecology; Radiology, Nuclear Medicine & Medical Imaging GA AS3KZ UT WOS:000344177800014 PM 24957016 ER PT J AU Hayes, DB Bellgraph, BJ Roth, BM Dauble, DD Mueller, RP AF Hayes, D. B. Bellgraph, B. J. Roth, B. M. Dauble, D. D. Mueller, R. P. TI TIMING OF REDD CONSTRUCTION BY FALL CHINOOK SALMON IN THE HANFORD REACH OF THE COLUMBIA RIVER SO RIVER RESEARCH AND APPLICATIONS LA English DT Article DE redd construction; Chinook salmon; modelling; water temperature; logistic regression ID UPSTREAM MIGRATION; TEMPERATURE; HABITATS; FLOW AB Spawning habits of fall Chinook salmon in the Hanford Reach of the Columbia River have been documented with annual aerial surveys since 1948. We developed a series of models analysing these data, exploring the influence of environmental factors on the timing of redd construction. These models included a logistic regression and a dynamic modelling approach, with combinations of day of year (as a surrogate for environmental cues such as day length), water temperature and discharge as potential explanatory factors. Results of these analyses indicate that day of year was the strongest predictor of the timing of redd construction, but with significant modifying effects of water temperature and discharge. The dynamic modelling approach provides substantial advantages over a traditional logistic regression, including (1) the ability to treat data collected at non-synchronous time intervals in a consistent fashion and (2) the ability to easily implement complex functions (e.g., threshold responses) relating behaviour to environmental cues. Evaluation of the series as a whole indicates that the median date of redd construction has increased over time, from approximately day 299 in 1950 to day 307 in 2010, as has the temperature on Oct 1 (16.3 degrees C-18.1 degrees C). The degree to which these changes are caused by climate change or dam operations is uncertain, however. Copyright (c) 2013 John Wiley & Sons, Ltd. C1 [Hayes, D. B.; Roth, B. M.] Michigan State Univ, Dept Fisheries & Wildlife, E Lansing, MI 48824 USA. [Bellgraph, B. J.; Dauble, D. D.; Mueller, R. P.] Pacific NW Natl Lab, Ecol Grp, Richland, WA 99352 USA. RP Hayes, DB (reprint author), Michigan State Univ, Dept Fisheries & Wildlife, E Lansing, MI 48824 USA. EM hayesdan@msu.edu FU Grant County Public Utility District (GCPUD) FX We thank Grant County Public Utility District (GCPUD) for funding the development of the HAnford Reach fall CHinook productivitY (HierARCHY) simulation model, which ultimately led to the analysis and formation of this manuscript, and for funding a separate project from which environmental data were obtained. We specifically thank Russell Langshaw and Todd Pearsons of GCPUD for providing insight and guidance on spawn timing and other life history data related to Priest Rapids Dam operating conditions; Geoff McMichael at the Pacific Northwest National Laboratory (PNNL) for sharing his knowledge of the Hanford Reach population of fall Chinook salmon that formed some of the original study impetus and for reviewing the draft manuscript; and William Perkins, Marshall Richmond, and Sara Niehus of PNNL for producing the Hanford Reach environmental data using the MASS2 hydrologic model. NR 20 TC 1 Z9 1 U1 1 U2 8 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1535-1459 EI 1535-1467 J9 RIVER RES APPL JI River Res. Appl. PD NOV PY 2014 VL 30 IS 9 BP 1110 EP 1119 DI 10.1002/rra.2719 PG 10 WC Environmental Sciences; Water Resources SC Environmental Sciences & Ecology; Water Resources GA AS0SO UT WOS:000343989000004 ER PT J AU Pan, PZ Rutqvist, J Feng, XT Yan, F Jiang, Q AF Pan, Peng-Zhi Rutqvist, Jonny Feng, Xia-Ting Yan, Fei Jiang, Quan TI A Discontinuous Cellular Automaton Method for Modeling Rock Fracture Propagation and Coalescence Under Fluid Pressurization Without Remeshing SO ROCK MECHANICS AND ROCK ENGINEERING LA English DT Article DE Crack propagation; Fluid pressure; Rock discontinuous cellular automaton; Level set method; Partition of unity; Stress intensity factor ID FINITE-ELEMENT-METHOD; DRIVEN FRACTURES; CRACK-GROWTH; BRITTLE MATERIALS AB We present a formulation of a discontinuous cellular automaton method for modeling of rock fluid pressure induced fracture propagation and coalescence without the need for remeshing. Using this method, modelers discretize a discontinuous rock-mass domain into a system composed of cell elements in which the numerical grid and crack geometry are independent of each other. The level set method, which defines the relationship between cracks and the numerical grid, is used for tracking the crack location and its propagation path. As a result, no explicit meshing for crack surfaces and no remeshing for crack growth are needed. Discontinuous displacement functions, i.e., the Heaviside functions for crack surfaces and asymptotic crack-tip displacement fields, are introduced to represent complex discontinuities. When two cracks intersect, the tip enrichment of the approaching crack is annihilated and is replaced by a Heaviside enrichment. We use the "partition of unity" concept to improve the integral precision for elements, including crack surfaces and crack tips. From this, we develop a cellular automaton updating rule to calculate the stress field induced by fluid pressure. Then, the stress is substituted into a mixed-mode fracture criterion. The cracking direction is determined from the stress analysis around the crack tips, where fracture fluid is assumed to penetrate into the newly developed crack, leading to a continuous crack propagation. Finally, we performed verification against independent numerical models and analytic solutions and conducted a number of simulations with different crack geometries and crack arrangements to show the robustness and applicability of this method. C1 [Pan, Peng-Zhi; Feng, Xia-Ting; Yan, Fei; Jiang, Quan] Chinese Acad Sci, Inst Rock & Soil Mech, State Key Lab Geomech & Geotech Engn, Wuhan 430071, Peoples R China. [Pan, Peng-Zhi; Rutqvist, Jonny] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. RP Pan, PZ (reprint author), Chinese Acad Sci, Inst Rock & Soil Mech, State Key Lab Geomech & Geotech Engn, Wuhan 430071, Peoples R China. EM pzpan@whrsm.ac.cn RI Rutqvist, Jonny/F-4957-2015 OI Rutqvist, Jonny/0000-0002-7949-9785 FU National Natural Science Foundation of China [51322906, 41272349]; National Basic Research Program of China [2010CB732006]; US Dept. of Energy [DE-AC02-05CH11231] FX This work was finically supported by the National Natural Science Foundation of China under Grant Nos. 51322906, 41272349 and the National Basic Research Program of China under Grant No. 2010CB732006, and in part, supported by the US Dept. of Energy under contract No. DE-AC02-05CH11231. We thank Daisuke Asahina and Daniel Hawkes at LBNL for reviewing the initial version of the paper. NR 44 TC 1 Z9 2 U1 1 U2 14 PU SPRINGER WIEN PI WIEN PA SACHSENPLATZ 4-6, PO BOX 89, A-1201 WIEN, AUSTRIA SN 0723-2632 EI 1434-453X J9 ROCK MECH ROCK ENG JI Rock Mech. Rock Eng. PD NOV PY 2014 VL 47 IS 6 BP 2183 EP 2198 DI 10.1007/s00603-013-0522-4 PG 16 WC Engineering, Geological; Geosciences, Multidisciplinary SC Engineering; Geology GA AS6UK UT WOS:000344397400016 ER PT J AU Ryals, R Kaiser, M Torn, MS Berhe, AA Silver, WL AF Ryals, R. Kaiser, M. Torn, M. S. Berhe, A. Asefaw Silver, W. L. TI Impacts of organic matter amendments on carbon and nitrogen dynamics in grassland soils (vol 68, pg 52, 2014) SO SOIL BIOLOGY & BIOCHEMISTRY LA English DT Correction C1 [Ryals, R.; Silver, W. L.] Univ Calif Berkeley, Dept Environm Sci Policy & Management, Berkeley, CA 94720 USA. [Kaiser, M.; Berhe, A. Asefaw] Univ Calif Merced, Sch Nat Sci, Atwater, CA 95301 USA. [Torn, M. S.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Earth Sci, Berkeley, CA 94720 USA. RP Ryals, R (reprint author), Brown Univ, MacMillan Hall Box 1951, Providence, RI 02906 USA. EM rebecca_ryals@brown.edu RI Torn, Margaret/D-2305-2015 NR 1 TC 0 Z9 0 U1 5 U2 37 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0038-0717 J9 SOIL BIOL BIOCHEM JI Soil Biol. Biochem. PD NOV PY 2014 VL 78 BP 340 EP 340 DI 10.1016/j.soilbio.2014.07.001 PG 1 WC Soil Science SC Agriculture GA AS0EH UT WOS:000343950600039 ER PT J AU White, JF Holladay, JE Zacher, AA Frye, JG Werpy, TA AF White, James F. Holladay, Johnathan E. Zacher, Allan A. Frye, John G., Jr. Werpy, Todd A. TI Challenges in Catalytic Manufacture of Renewable Pyrrolidinones from Fermentation Derived Succinate SO TOPICS IN CATALYSIS LA English DT Article; Proceedings Paper CT 25th Biennial Conference of the Organic-Reactions-Catalysis-Society (ORCS) CY MAR 02-06, 2014 CL Tucson, AZ SP Organ React Catalysis Soc, Eastman Chem Co, Heraeus, Amegen, Pfizer, Takasago, Mettler Toledo, Biotage, ACS Catalysis, ACS Sustainable Chem & Engn, Pacific NW Natl Lab, W R Grace, Parr, BASF, Evonik DE Succinic acid; Hydrogenation; N-Methyl succimide; N-Methyl-2-pyrrolidinone; 2-pyrrolidinone; Renewable resources ID ACID AB Fermentation derived succinic acid ammonium salt is an ideal precursor for manufacture of renewable N-methyl pyrrolidinone (NMP) or 2-pyrrolidinone (2P) via heterogeneous catalysis. However, there are many challenges to making this a practical reality. Chief among the challenges is avoiding catalyst poisoning by fermentation by- and co-products. Battelle/Pacific Northwest National Laboratory have developed an effective technology strategy for this purpose. The technology is a combination of purely thermal processing, followed by simple catalytic hydrogenation that together avoids catalyst poisoning from fermentation impurities and provides high selectivity and yields of NMP or 2P. C1 [White, James F.] 3RiversCatalysis LLC, Richland, WA 99352 USA. [Holladay, Johnathan E.; Zacher, Allan A.; Frye, John G., Jr.] Pacific NW Natl Lab, Richland, WA 99352 USA. [Werpy, Todd A.] JRR Res Ctr, Decatur, IL 62521 USA. RP White, JF (reprint author), 3RiversCatalysis LLC, 409 Adair Dr, Richland, WA 99352 USA. EM 3riverscatalysis@charter.net NR 35 TC 1 Z9 1 U1 3 U2 14 PU SPRINGER/PLENUM PUBLISHERS PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1022-5528 EI 1572-9028 J9 TOP CATAL JI Top. Catal. PD NOV PY 2014 VL 57 IS 17-20 BP 1325 EP 1334 DI 10.1007/s11244-014-0299-z PG 10 WC Chemistry, Applied; Chemistry, Physical SC Chemistry GA AS3EC UT WOS:000344158300004 ER PT J AU Allgeier, AM Andersen, D Bartberger, MD Bunel, EE Larsen, RD Liu, PL Storz, T Tedrow, JS AF Allgeier, Alan M. Andersen, Denise Bartberger, Michael D. Bunel, Emilio E. Larsen, Robert D. Liu, Pingli Storz, Thomas Tedrow, Jason S. TI Reductive Amination Without the Aldehyde: Use of a Ketolactol as an Aldehyde Surrogate SO TOPICS IN CATALYSIS LA English DT Article; Proceedings Paper CT 25th Biennial Conference of the Organic-Reactions-Catalysis-Society (ORCS) CY MAR 02-06, 2014 CL Tucson, AZ SP Organ React Catalysis Soc, Eastman Chem Co, Heraeus, Amegen, Pfizer, Takasago, Mettler Toledo, Biotage, ACS Catalysis, ACS Sustainable Chem & Engn, Pacific NW Natl Lab, W R Grace, Parr, BASF, Evonik DE Reductive amination; Ketolactol; gamma-aminoacid; Process chemistry; Mass transfer; Density functional theory ID MASS-TRANSFER; BISULFITE ADDUCTS; ACIDS; HYDROGENATION; REACTORS AB To overcome stability issues associated with the use of an aldehyde in a catalytic reductive amination reaction, a cyclic ketolactol (omega-hydroxylactone) was employed as an aldehyde surrogate to form a gamma-aminoacid. The reaction proceeded most favorably over a Pt/C catalyst. The thermodynamics of each step were evaluated using density functional theory calculations, which correctly predicted the dominance of the ring-closed lactol reactant, yet suggested a preference for a ring-opened iminium intermediate upon the initial, slightly endoergic addition of amine substrate. Exoergic hydrogenation of this intermediate provided the thermodynamic driving force for the overall transformation. During development, the reaction was observed to depend significantly on the volumetric gas to liquid mass transfer coefficient (k(L)a) and this parameter was optimized to ensure successful scale up in a 400 L stirred tank reactor. C1 [Allgeier, Alan M.] EI duPont Nemours & Co, Cent Res & Dev, Wilmington, DE 19880 USA. [Andersen, Denise] Threshold Pharmaceut, San Francisco, CA 94080 USA. [Bartberger, Michael D.; Tedrow, Jason S.] Amgen Inc, Thousand Oaks, CA 91320 USA. [Bunel, Emilio E.] Argonne Natl Lab, Lemont, IL 60439 USA. [Larsen, Robert D.] Alcon, Ft Worth, TX 76134 USA. [Liu, Pingli] Incyte Corp, Wilmington, DE 19880 USA. [Storz, Thomas] Ironwood Pharmaceut, Cambridge, MA 02142 USA. RP Allgeier, AM (reprint author), EI duPont Nemours & Co, Cent Res & Dev, Wilmington, DE 19880 USA. EM alan.m.allgeier@dupont.com; michael.bartberger@amgen.com OI Allgeier, Alan/0000-0001-9122-2108 NR 26 TC 0 Z9 0 U1 1 U2 6 PU SPRINGER/PLENUM PUBLISHERS PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1022-5528 EI 1572-9028 J9 TOP CATAL JI Top. Catal. PD NOV PY 2014 VL 57 IS 17-20 BP 1335 EP 1341 DI 10.1007/s11244-014-0300-x PG 7 WC Chemistry, Applied; Chemistry, Physical SC Chemistry GA AS3EC UT WOS:000344158300005 ER PT J AU Diaz-San Segundo, F Dias, CC Moraes, MP Weiss, M Perez-Martin, E Salazar, AM Grubman, MJ de los Santos, T AF Diaz-San Segundo, Fayna Dias, Camila C. Moraes, Mauro P. Weiss, Marcelo Perez-Martin, Eva Salazar, Andres M. Grubman, Marvin J. de los Santos, Teresa TI Poly ICLC increases the potency of a replication-defective human adenovirus vectored foot-and-mouth disease vaccine SO VIROLOGY LA English DT Article DE Foot-and-mouth disease; Foot-and-mouth disease virus; Replication-defective adenovirus; Vaccines; Adjuvants; Neutralizing antibodies; Cell-mediated immunity; Poly ICLC ID POLYRIBOINOSINIC-POLYRIBOCYTIDYLIC ACID; EQUINE ENCEPHALOMYELITIS VIRUS; PORCINE INTERFERON-ALPHA; NONSTRUCTURAL PROTEIN 2B; IMMUNE-RESPONSES; ENDOPLASMIC-RETICULUM; THERAPEUTIC EFFICACY; POLYCYTIDYLIC ACID; NONHUMAN-PRIMATES; SUBUNIT VACCINE AB Foot-and-mouth disease virus (FMDV) causes a highly contagious disease of cloven-hoofed animals. We have previously demonstrated that a replication-defective human adenovirus 5 vector carrying the FMDV capsid coding region of serotype A24 Cruzeiro (Ad5-CI-A24-2B) protects swine and cattle against FMDV challenge by 7 days post-vaccination. However, since relatively large amounts of Ad5-CI-A24-2B are required to induce protection this strategy could be costly for livestock production. Poly ICLC is a synthetic double stranded RNA that activates multiple innate and adaptive immune pathways. In this study, we have tested for the first time, the adjuvant effect of poly ICLC in combination with Ad5-CI-A24-2B in swine. We found that the combination resulted in a reduction of the vaccine protective dose by 80-fold. Interestingly, the lowest dose of Ad5-CI-A24-2B plus I mg of poly ICLC protected animals against challenge even in the absence of detectable FMDV-specific neutralizing antibodies at the time of challenge. Published by Elsevier Inc. C1 [Diaz-San Segundo, Fayna; Dias, Camila C.; Moraes, Mauro P.; Weiss, Marcelo; Perez-Martin, Eva; Grubman, Marvin J.; de los Santos, Teresa] ARS, Plum Isl Anim Dis Ctr, USDA, Greenport, NY 11944 USA. [Dias, Camila C.; Weiss, Marcelo; Perez-Martin, Eva] Oak Ridge Inst Sci & Educ, PIADC Res Participat Program, Oak Ridge, TN 37831 USA. [Moraes, Mauro P.] Univ Connecticut, Dept Pathobiol & Vet Sci, Storrs, CT 06269 USA. [Salazar, Andres M.] Oncovir Inc, Washington, DC 20008 USA. RP Grubman, MJ (reprint author), ARS, Plum Isl Anim Dis Ctr, USDA, POB 848, Greenport, NY 11944 USA. EM marvin.grubman@ars.usda.gov; teresa.delossantos@ars.usda.gov RI Weiss, Marcelo/I-1274-2012 OI Weiss, Marcelo/0000-0001-7902-3210 FU Plum Island Animal Disease Research Participation Program; USDA CRIS [1940-32000-057-00D]; Agricultural Research Service, USDA; Science and Technology Directorate of the U.S. Department of Homeland Security [HSHQPD-07-X-00003, HSHQDC-09-X-00373] FX This research was supported in part by the Plum Island Animal Disease Research Participation Program administered by the Oak Ridge Institute for Science and Education through an interagency agreement between the U.S. Department of Energy and the U.S. Department of Agriculture (USDA) (appointments of Camila C.A. Dias, Marcelo Weiss, and Eva Perez-Martin), by USDA CRIS project 1940-32000-057-00D, (M.J. Grubman and T. de los Santos), and by an interagency agreement between Agricultural Research Service, USDA and the Science and Technology Directorate of the U.S. Department of Homeland Security under awards HSHQPD-07-X-00003 and HSHQDC-09-X-00373 (M.J. Grubman and T. de los Santos). The authors thank Fawzi Mohamed, FADDL, for performing a histopathological analysis on the animals that died in the various trials; and the animal care staff at PIADC for their professional support and assistance. NR 61 TC 3 Z9 3 U1 3 U2 6 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0042-6822 J9 VIROLOGY JI Virology PD NOV PY 2014 VL 468 BP 283 EP 292 DI 10.1016/j.virol.2014.08.012 PG 10 WC Virology SC Virology GA AS7KF UT WOS:000344434400033 PM 25216089 ER PT J AU McIntosh, KG Neal, JA Nath, P Havrilla, GJ AF McIntosh, Kathryn G. Neal, J. Avery Nath, Pulak Havrilla, George J. TI Microfluidic sample preparation for elemental analysis in liquid samples using micro X-ray fluorescence spectrometry SO X-RAY SPECTROMETRY LA English DT Article ID SCATTERING AB The integration of microfluidic devices with micro X-ray fluorescence (micro-XRF) spectrometry offers a new approach for the direct characterization of liquid materials. A sample presentation method based on use of small volumes (<5 mu l) of liquid contained in an XRF-compatible device has been developed. In this feasibility study, a prototype chip was constructed, and its suitability for XRF analysis of liquids was evaluated, along with that of a commercially produced microfluidic device. Each of the chips had an analytical chamber which contained approximately 1 mu l of sample when the device was filled using a pipette. The performance of the chips was assessed using micro-XRF and high resolution monochromatic wavelength dispersive X-ray fluorescence, a method that provides highly selective and sensitive detection of actinides. The intended application of the device developed in this study is for measurement of Pu in spent nuclear fuel. Aqueous solutions and a synthetic spent fuel matrix were used to evaluate the devices. Sr, which has its K line energy close to the Pu L line at 14.2keV, was utilized as a surrogate for Pu because of reduced handling risks. Between and within chip repeatability were studied, along with linearity of response and accuracy. The limit of detection for Sr determination in the chip is estimated at 5ng/mu l (ppm). This work demonstrates the applicability of microfluidic sample preparation to liquid characterization by XRF, and provides a basis for further development of this approach for elemental analysis within a range of sample types. Copyright (c) 2014 John Wiley & Sons, Ltd. C1 [McIntosh, Kathryn G.; Neal, J. Avery; Nath, Pulak; Havrilla, George J.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. RP McIntosh, KG (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. EM kmcintosh@lanl.gov OI Havrilla, George/0000-0003-2052-7152; McIntosh, Kathryn/0000-0002-8623-403X FU U.S. Department of Energy through the LANL/LDRD Program under the Seaborg Institute Postdoctoral Fellowship program; Next Generation Safeguards Initiative (NGSI), Office of Nonproliferation and International Security (NIS); National Nuclear Security Administration (NNSA); National Nuclear Security Administration of the U.S. Department of Energy [DE-AC52-06NA25396] FX The authors thank Velma M. Lopez and Eli J. Berg of C-CDE at LANL for their contributions in sample preparation and microscope imaging. The authors also acknowledge the support of the U.S. Department of Energy through the LANL/LDRD Program under the auspices of the Seaborg Institute Postdoctoral Fellowship program, and Next Generation Safeguards Initiative (NGSI), Office of Nonproliferation and International Security (NIS), and National Nuclear Security Administration (NNSA). Los Alamos National Laboratory is operated by the Los Alamos National Security, LLC for the National Nuclear Security Administration of the U.S. Department of Energy under contract DE-AC52-06NA25396. NR 18 TC 3 Z9 3 U1 1 U2 11 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0049-8246 EI 1097-4539 J9 X-RAY SPECTROM JI X-Ray Spectrom. PD NOV-DEC PY 2014 VL 43 IS 6 BP 332 EP 337 DI 10.1002/xrs.2559 PG 6 WC Spectroscopy SC Spectroscopy GA AS3LG UT WOS:000344178700005 ER PT J AU Howley, K Wasem, J AF Howley, Kirsten Wasem, Joseph TI A simplified approach to uncertainty quantification for orbits in impulsive deflection scenarios SO ACTA ASTRONAUTICA LA English DT Article DE Asteroids: dynamics, individual (2011 AG5); Comets: dynamics; Orbit: determination uncertainty; Satellites: dynamics; Mission planning ID NEAR-EARTH ASTEROIDS; IMPACTS; CRATER AB For the majority of near-Earth Asteroid (NEA) impact scenarios, optimal deflection strategies use a massive impactor or a nuclear explosive, either of which produce an impulsive change to the orbit of the object However, uncertainties regarding the object composition and the efficiency of the deflection event lead to a non-negligible uncertainty in the deflection delta-velocity. Propagating this uncertainty through the resulting orbit will create a positional uncertainty envelope at the original impact epoch. We calculate a simplified analytic evolution for impulsively deflected NEAs and perform a full propagation of uncertainties that is nonlinear in the deflection delta-velocity vector. This provides an understanding of both the optimal deflection velocities needed for a given scenario, as well as the resulting positional uncertainty and corresponding residual impact probability. Confidence of a successful deflection attempt as a function of launch opportunities is also discussed for a specific case. (C) 2014 IAA. Published by Elsevier Ltd. All rights reserved. C1 [Howley, Kirsten; Wasem, Joseph] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. RP Howley, K (reprint author), Lawrence Livermore Natl Lab, POB 808, Livermore, CA 94551 USA. EM howley1@llnl.gov; wasem2@llnl.gov FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; Laboratory Directed Research and Development Program at LLNL [12-ERD-005] FX LLNL-JRNL-643133. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344, and partially funded by the Laboratory Directed Research and Development Program at LLNL under tracking code 12-ERD-005. NR 30 TC 0 Z9 0 U1 0 U2 1 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0094-5765 EI 1879-2030 J9 ACTA ASTRONAUT JI Acta Astronaut. PD NOV PY 2014 VL 104 IS 1 SI SI BP 206 EP 219 DI 10.1016/j.actaastro.2014.06.041 PG 14 WC Engineering, Aerospace SC Engineering GA AR8RH UT WOS:000343841700021 ER PT J AU Wagnild, R Candler, GV AF Wagnild, Ross Candler, Graham V. TI Computational Verification of Acoustic Damping in High-Enthalpy Environments SO AIAA JOURNAL LA English DT Article ID BOUNDARY-LAYER-TRANSITION; SOUND C1 [Wagnild, Ross] Sandia Natl Labs, Aerosci Dept, Albuquerque, NM 87123 USA. [Candler, Graham V.] Univ Minnesota, Dept Aerosp Engn & Mech, Minneapolis, MN 55455 USA. RP Wagnild, R (reprint author), Sandia Natl Labs, Aerosci Dept, Albuquerque, NM 87123 USA. FU U.S. Air Force Office of Scientific Research (AFOSR) [FA9550-10-1-0563, FA955010-1-0352]; Department of Defense National Security Science and Engineering Faculty Fellowship; U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX This work was sponsored by the U.S. Air Force Office of Scientific Research (AFOSR) under grants FA9550-10-1-0563 and FA955010-1-0352 and by the Department of Defense National Security Science and Engineering Faculty Fellowship. Sandia National Laboratories is a multiprogram laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. The views and conclusions contained herein are those of the author and should not be interpreted as necessarily representing the official policies or endorsements, either expressed or implied, of the AFOSR, Sandia, or the U.S. Government. NR 20 TC 0 Z9 0 U1 2 U2 5 PU AMER INST AERONAUTICS ASTRONAUTICS PI RESTON PA 1801 ALEXANDER BELL DRIVE, STE 500, RESTON, VA 22091-4344 USA SN 0001-1452 EI 1533-385X J9 AIAA J JI AIAA J. PD NOV PY 2014 VL 52 IS 11 BP 2615 EP 2618 DI 10.2514/1.J052802 PG 4 WC Engineering, Aerospace SC Engineering GA AR8AX UT WOS:000343799000021 ER PT J AU Alford, ER Lindblom, SD Pittarello, M Freeman, JL Fakra, SC Marcus, MA Broeckling, C Pilon-Smits, EAH Paschke, MW AF Alford, Elan R. Lindblom, Stormy D. Pittarello, Marco Freeman, John L. Fakra, Sirine C. Marcus, Matthew A. Broeckling, Corey Pilon-Smits, Elizabeth A. H. Paschke, Mark W. TI ROLES OF RHIZOBIAL SYMBIONTS IN SELENIUM HYPERACCUMULATION IN ASTRAGALUS (FABACEAE) SO AMERICAN JOURNAL OF BOTANY LA English DT Article DE Astragalus; Fabaceae; gamma-glutamyl-methylselenocysteine; hyperaccumulation; legume; nodulation; selenium; symbiosis; x-ray absorption spectroscopy ID NITROGEN-FIXATION; PLANTS; RHIZOSPHERE; ACCUMULATION; GROWTH; SOIL; SELENOCYSTEINE; SULFUR; HEALTH; METAL AB Premise of the study: Are there dimensions of symbiotic root interactions that are overlooked because plant mineral nutrition is the foundation and, perhaps too often, the sole explanation through which we view these relationships? In this paper we investigate how the root nodule symbiosis in selenium (Se) hyperaccumulator and nonaccumulator Astragalus species influences plant selenium (Se) accumulation. Methods: In greenhouse studies, Se was added to nodulated and nonnodulated hyperaccumulator and nonaccumulator Astragalus plants, followed by investigation of nitrogen (N)-Se relationships. Selenium speciation was also investigated, using x-ray microprobe analysis and liquid chromatography-mass spectrometry (LC-MS). Key results: Nodulation enhanced biomass production and Se to S ratio in both hyperaccumulator and nonaccumulator plants. The hyperaccumulator contained more Se when nodulated, while the nonaccumulator contained less S when nodulated. Shoot [ Se] was positively correlated with shoot N in Se-hyperaccumulator species, but not in nonhyperaccumulator species. The x-ray microprobe analysis showed that hyperaccumulators contain significantly higher amounts of organic Se than nonhyperaccumulators. LC-MS of A. bisulcatus leaves revealed that nodulated plants contained more gamma-glutamyl-methylselenocysteine (gamma-Glu-MeSeCys) than nonnodulated plants, while MeSeCys levels were similar. Conclusions: Root nodule mutualism positively affects Se hyperaccumulation in Astragalus. The microbial N supply particularly appears to contribute glutamate for the formation of gamma-Glu-MeSeCys. Our results provide insight into the significance of symbiotic interactions in plant adaptation to edaphic conditions. Specifically, our findings illustrate that the importance of these relationships are not limited to alleviating macronutrient deficiencies. C1 [Alford, Elan R.; Pilon-Smits, Elizabeth A. H.; Paschke, Mark W.] Colorado State Univ, Grad Degree Program Ecol, Ft Collins, CO 80523 USA. [Alford, Elan R.; Paschke, Mark W.] Colorado State Univ, Dept Forest & Rangeland Stewardship, Ft Collins, CO 80523 USA. [Lindblom, Stormy D.; Pittarello, Marco; Freeman, John L.; Pilon-Smits, Elizabeth A. H.] Colorado State Univ, Dept Biol, Ft Collins, CO 80523 USA. [Fakra, Sirine C.; Marcus, Matthew A.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA. [Broeckling, Corey] Colorado State Univ, Prote & Metabol Facil, Ft Collins, CO 80523 USA. RP Pilon-Smits, EAH (reprint author), Colorado State Univ, Grad Degree Program Ecol, Ft Collins, CO 80523 USA. EM elizabeth.pilon-smits@colostate.edu OI Alford, Elan/0000-0001-9602-0177 FU National Science Foundation [IOS-0817748]; Office of Science, Office of Basic Energy Sciences, U.S. Department of Energy [DE-AC02-05CH11231] FX The authors thank J. Cappa for help preparing plants for selenoamino acid analysis and L. Bodistow for field assistance. They also thank the student crew at the Restoration Ecology laboratory at Colorado State University for root washing assistance. National Science Foundation grant # IOS-0817748 provided funding to E.A.H.P.-S. The operations of the Advanced Light Source at Lawrence Berkeley National Laboratory are supported by the Director, Office of Science, Office of Basic Energy Sciences, U.S. Department of Energy under contract number DE-AC02-05CH11231. NR 65 TC 3 Z9 3 U1 3 U2 29 PU BOTANICAL SOC AMER INC PI ST LOUIS PA PO BOX 299, ST LOUIS, MO 63166-0299 USA SN 0002-9122 EI 1537-2197 J9 AM J BOT JI Am. J. Bot. PD NOV PY 2014 VL 101 IS 11 BP 1895 EP 1905 DI 10.3732/ajb.1400223 PG 11 WC Plant Sciences SC Plant Sciences GA AS1CC UT WOS:000344013400007 PM 25366855 ER PT J AU Pumera, M Polsky, R Banks, C AF Pumera, Martin Polsky, Ronen Banks, Craig TI Graphene in analytical science SO ANALYTICAL AND BIOANALYTICAL CHEMISTRY LA English DT Editorial Material C1 [Pumera, Martin] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore. [Polsky, Ronen] Sandia Natl Labs, Albuquerque, NM 87123 USA. [Banks, Craig] Manchester Metropolitan Univ, Sch Sci & Environm, Div Chem & Environm Sci, Manchester M1 5GD, Lancs, England. RP Pumera, M (reprint author), Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, SPMS CBC-04-07,21 Nanyang Link, Singapore 637371, Singapore. EM pumera@ntu.edu.sg RI Pumera, Martin/F-2724-2010; OI Pumera, Martin/0000-0001-5846-2951; banks, craig/0000-0002-0756-9764 NR 0 TC 3 Z9 3 U1 2 U2 21 PU SPRINGER HEIDELBERG PI HEIDELBERG PA TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY SN 1618-2642 EI 1618-2650 J9 ANAL BIOANAL CHEM JI Anal. Bioanal. Chem. PD NOV PY 2014 VL 406 IS 27 BP 6883 EP 6884 DI 10.1007/s00216-014-8153-5 PG 2 WC Biochemical Research Methods; Chemistry, Analytical SC Biochemistry & Molecular Biology; Chemistry GA AR8DG UT WOS:000343805100013 PM 25240933 ER PT J AU Zhang, P Goodwin, PM Werner, JH AF Zhang, P. Goodwin, P. M. Werner, J. H. TI Interferometric three-dimensional single molecule localization microscopy using a single high-numerical-aperture objective SO APPLIED OPTICS LA English DT Article ID OPTICAL RECONSTRUCTION MICROSCOPY; FLUORESCENCE MICROSCOPY; DIFFRACTION-LIMIT; LIVE CELLS; RESOLUTION; TRACKING AB Interferometric detection of the fluorescence emission from a single molecule [interferometric photoactivated localization microscopy (iPALM)] enables a localization accuracy of nanometers in axial localization for 3D superresolution imaging. However, iPALM uses two high-numerical-aperture (NA) objectives in juxtaposition for fluorescence collection (a 4Pi microscope geometry), increasing expense and limiting samples that can be studied. Here, we propose an interferometric single molecule localization microscopy method using a single high-NA objective. The axial position of single molecules can be unambiguously determined from the phase-shifted interference signals with nanometer precision and over a range of 2 lambda. The use of only one objective simplifies the system configuration and sample mounting. In addition, due to the use of wavefront-splitting interference in our approach, the two parts of the wave-front that eventually merge and interfere with each other travel along nearly equivalent optical paths, which should minimize the effect of drift for long-term 3D superresolution imaging. (C) 2014 Optical Society of America C1 [Zhang, P.; Goodwin, P. M.; Werner, J. H.] Los Alamos Natl Lab, Ctr Integrated Nanotechnol, Los Alamos, NM 87545 USA. RP Werner, JH (reprint author), Los Alamos Natl Lab, Ctr Integrated Nanotechnol, POB 1663, Los Alamos, NM 87545 USA. EM jwerner@lanl.gov FU Los Alamos National Laboratory Directed Research and Development (LDRD) program; U.S. Department of Energy, Office of Basic Energy Sciences user facility at Los Alamos National Laboratory [DE-AC52-06NA25396] FX This work was supported through Los Alamos National Laboratory Directed Research and Development (LDRD) program and was performed at the Center for Integrated Nanotechnologies, a U.S. Department of Energy, Office of Basic Energy Sciences user facility at Los Alamos National Laboratory (Contract DE-AC52-06NA25396). NR 23 TC 0 Z9 0 U1 1 U2 17 PU OPTICAL SOC AMER PI WASHINGTON PA 2010 MASSACHUSETTS AVE NW, WASHINGTON, DC 20036 USA SN 1559-128X EI 2155-3165 J9 APPL OPTICS JI Appl. Optics PD NOV 1 PY 2014 VL 53 IS 31 BP 7415 EP 7421 DI 10.1364/AO.53.007415 PG 7 WC Optics SC Optics GA AR9TL UT WOS:000343919400045 PM 25402907 ER PT J AU Rakhman, A Wang, Y Garcia, F Long, C Huang, CN Takeda, Y Liu, Y AF Rakhman, Abdurahim Wang, Yang Garcia, Frances Long, Cary Huang, Chunning Takeda, Yasuhiro Liu, Yun TI Multifunctional optical correlator for picosecond ultraviolet laser pulse measurement SO APPLIED OPTICS LA English DT Article ID 2-PHOTON ABSORPTION; ULTRASHORT PULSES; PHASE; UV AB A compact multifunctional optical correlator system for pulse width measurement of ultrashort ultraviolet (UV) pulses has been designed and experimentally demonstrated. Both autocorrelation and crosscorrelation functions are measured using a single nonlinear crystal, and the switching between two measurements requires no adjustment of phase matching and detector. The system can measure UV pulse widths from sub-picoseconds to 100 ps, and it involves no auxiliary pulse in the measurement. The measurement results on a burst-mode picosecond UV laser show a high-quality performance on speed, accuracy, resolution, and dynamic range. The proposed correlator can be applied to measure any ultrashort UV pulses produced through sum-frequency generation or second-harmonic generation. (C) 2014 Optical Society of America C1 [Rakhman, Abdurahim; Garcia, Frances] Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA. [Rakhman, Abdurahim; Long, Cary; Huang, Chunning; Takeda, Yasuhiro; Liu, Yun] Oak Ridge Natl Lab, Spallat Neutron Source, Res Accelerator Div, Oak Ridge, TN 37831 USA. [Wang, Yang] Univ Alabama, Dept Mech & Aerosp Engn, Huntsville, AL 35899 USA. RP Liu, Y (reprint author), Oak Ridge Natl Lab, Spallat Neutron Source, Res Accelerator Div, 1 Bethel Valley Rd, Oak Ridge, TN 37831 USA. EM liuy2@ornl.gov RI Rakhman, Adurahim/K-8146-2012 OI Rakhman, Adurahim/0000-0002-9880-6074 FU DOE Higher Education Research Experiences (HERE) program; U.S. DOE [DE-FG02-13ER41967]; Oak Ridge National Laboratory for the U.S. Department of Energy [DE-AC05-00OR22725] FX We thank A. Aleksandrov and S. Cousineau for their support. Technical help from J. Diamond, S. Murray III, and A. Webster is acknowledged. Y. Wang acknowledges support from the DOE Higher Education Research Experiences (HERE) program. This work has been partially supported by U.S. DOE grant DE-FG02-13ER41967. Oak Ridge National Laboratory is managed by UT-Battelle, LLC, under contract DE-AC05-00OR22725 for the U.S. Department of Energy. NR 16 TC 4 Z9 4 U1 0 U2 4 PU OPTICAL SOC AMER PI WASHINGTON PA 2010 MASSACHUSETTS AVE NW, WASHINGTON, DC 20036 USA SN 1559-128X EI 2155-3165 J9 APPL OPTICS JI Appl. Optics PD NOV 1 PY 2014 VL 53 IS 31 BP 7603 EP 7609 DI 10.1364/AO.53.007603 PG 7 WC Optics SC Optics GA AR9TL UT WOS:000343919400066 PM 25402928 ER PT J AU Arnache, O Campillo, G Hoffmann, A AF Arnache, O. Campillo, G. Hoffmann, A. TI Study of critical exponents in doped La2/3Ca1/3Mn1-yFeyO3 (y=0, 0.03) manganite films SO APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING LA English DT Article ID FERROMAGNETIC PHASE-TRANSITION; CRITICAL-BEHAVIOR; LA0.67CA0.33MNO3 FILMS; MAGNETIC-PROPERTIES; THIN-FILMS; TEMPERATURE; DEPENDENCE; SUBSTRATE; NICKEL; OXIDE AB In this work, we investigated close to the Curie temperature T-C the critical exponents of the magnetization of doped manganite La(2/3)Ca(1/3)Mn(0.97)Fe(0.0)3O(3) (LCMFO) thin films, as well as undoped La2/3Ca1/3MnO3 (LCMO). Using a T-C distribution given by the intrinsic magnetic inhomogeneities in these ferromagnets enables the determination of beta and delta critical exponents [corresponding to M(T) and M(H) respectively], average Curie temperature < T-C >, and the T-C distribution width, Delta T-C. Additionally, we extracted the critical exponent eta = beta delta from the fits of Delta T-C as a function of the external applied magnetic field. We found a value of 1.74 +/- 0.09 for this exponent, close to that reported in undoped La2/3Ca1/3MnO3 thin films. Even though the substitution effects of the Mn ions by Fe affect the magnetotransport and structural properties of LCMO system, these results suggest that around T-C, the magnetic phase transition, governed by the critical exponents, is similar in both magnetic systems, and belongs to the same universality class. C1 [Arnache, O.] Univ Antioquia, Fac Ciencias Exactas & Nat, Inst Fis, Grp Estado Solido, Medellin, Colombia. [Campillo, G.] Univ Medellin, Dept Ciencias Basicas, Medellin 1983, Colombia. [Hoffmann, A.] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA. RP Campillo, G (reprint author), Univ Medellin, Dept Ciencias Basicas, Carrera 87 30-65, Medellin 1983, Colombia. EM gecampillo@udem.edu.co RI Hoffmann, Axel/A-8152-2009 OI Hoffmann, Axel/0000-0002-1808-2767 FU Universidad de Antioquia-Colombia [231, SIU-24-1-434]; U.S. Department of Energy, Office of Science, Materials Science and Engineering Division FX This work was supported by the Universidad de Antioquia-Colombia, under Act No. 231 CODI project-2012 (SIU-24-1-434). Work at Argonne was supported by the U.S. Department of Energy, Office of Science, Materials Science and Engineering Division. NR 35 TC 2 Z9 2 U1 1 U2 15 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0947-8396 EI 1432-0630 J9 APPL PHYS A-MATER JI Appl. Phys. A-Mater. Sci. Process. PD NOV PY 2014 VL 117 IS 2 BP 937 EP 943 DI 10.1007/s00339-014-8477-1 PG 7 WC Materials Science, Multidisciplinary; Physics, Applied SC Materials Science; Physics GA AR5TX UT WOS:000343647600077 ER PT J AU Singaravelu, S Mayo, DC Park, HK Schriver, KE Klopf, JM Kelley, MJ Haglund, RF AF Singaravelu, S. Mayo, D. C. Park, H. K. Schriver, K. E. Klopf, J. M. Kelley, M. J. Haglund, R. F., Jr. TI Fabrication and performance of polymer-nanocomposite anti-reflective thin films deposited by RIR-MAPLE SO APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING LA English DT Article ID HIGH REFRACTIVE-INDEX; PULSED-LASER EVAPORATION; POLY(METHYL METHACRYLATE); TIO2 AB Design of polymer anti-reflective (AR) optical coatings for plastic substrates is challenging because polymers exhibit a relatively narrow range of refractive indices. Here, we report synthesis of a four-layer AR stack using hybrid polymer: nanoparticle materials deposited by resonant infrared matrix-assisted pulsed laser evaporation. An Er: YAG laser ablated frozen solutions of a high-index composite containing TiO2 nanoparticles and poly(methylmethacrylate) (PMMA), alternating with a layer of PMMA. The optimized AR coatings, with thicknesses calculated using commercial software, yielded a coating for polycarbonate with transmission over 97 %, scattering <3 %, and a reflection coefficient below 0.5 % across the visible range, with a much smaller number of layers than would be predicted by a standard thin film calculation. The TiO2 nanoparticles contribute more to the enhanced refractive index of the high-index layers than can be accounted for by an effective medium model of the nanocomposite. C1 [Singaravelu, S.; Park, H. K.; Schriver, K. E.] AppliFlex LLC, Nashville, TN 37211 USA. [Mayo, D. C.; Haglund, R. F., Jr.] Vanderbilt Univ, Interdisciplinary Mat Sci Program, Nashville, TN 37235 USA. [Klopf, J. M.] Thomas Jefferson Natl Accelerator Facil, Newport News, VA 23606 USA. [Kelley, M. J.] Coll William & Mary, Dept Appl Sci, Williamsburg, VA 23187 USA. [Haglund, R. F., Jr.] Vanderbilt Univ, Dept Phys & Astron, Nashville, TN 37235 USA. RP Singaravelu, S (reprint author), AppliFlex LLC, 110 Space Pk South, Nashville, TN 37211 USA. EM rajaodu@gmail.com; richard.haglund@vanderbilt.edu FU Air Force Research Laboratory under STTR [FA9550-12-C-0006]; National Science Foundation [IIP-0740683]; Office of Naval Research; Army Night Vision Laboratory; Air Force Research Laboratory; Joint Technology Office; Commonwealth of Virginia; U.S. Department of Energy [DE-AC05-060R23177] FX The authors thank Professor Costas Grigoropoulos for providing the ZnO nanoparticle solution. This work was sponsored by the Air Force Research Laboratory under STTR Award FA9550-12-C-0006. D. C. Mayo was supported by the National Science Foundation (IIP-0740683). The Jefferson NationLab FEL is supported by the Office of Naval Research, the Army Night Vision Laboratory, the Air Force Research Laboratory, the Joint Technology Office, the Commonwealth of Virginia, and the U.S. Department of Energy, under contract No. DE-AC05-060R23177. We thank Professor Richard Mu, Fisk University, for helpful discussions and access to spectroscopy equipment. NR 37 TC 2 Z9 2 U1 4 U2 22 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0947-8396 EI 1432-0630 J9 APPL PHYS A-MATER JI Appl. Phys. A-Mater. Sci. Process. PD NOV PY 2014 VL 117 IS 3 BP 1415 EP 1423 DI 10.1007/s00339-014-8566-1 PG 9 WC Materials Science, Multidisciplinary; Physics, Applied SC Materials Science; Physics GA AR9RC UT WOS:000343911600058 ER PT J AU Johnson, TJ Bernacki, BE Redding, RL Su, YF Brauer, CS Myers, TL Stephan, EG AF Johnson, Timothy J. Bernacki, Bruce E. Redding, Rebecca L. Su, Yin-Fong Brauer, Carolyn S. Myers, Tanya L. Stephan, Eric G. TI Intensity-Value Corrections for Integrating Sphere Measurements of Solid Samples Measured Behind Glass SO APPLIED SPECTROSCOPY LA English DT Article DE Visible near-infrared spectroscopy; Vis-NIR; Integrating sphere; Diffuse reflectance; Calibration; Glass reflectance; Reflectance standards ID DIFFUSE-REFLECTANCE; AVIRIS DATA; STANDARDS; SURFACES; VEGETATION; LIBRARIES; SPECTRUM AB Accurate and calibrated directional-hemispherical reflectance spectra of solids are important for both in situ and remote sensing. Many solids are in the form of powders or granules and to measure their diffuse reflectance spectra in the laboratory, it is often necessary to place the samples behind a transparent medium such as glass for the ultraviolet (UV), visible, or near-infrared spectral regions. Using both experimental methods and a simple optical model, we demonstrate that glass (fused quartz in our case) leads to artifacts in the reflectance values. We report our observations that the measured reflectance values, for both hemispherical and diffuse reflectance, are distorted by the additional reflections arising at the air-quartz and sample-quartz interfaces. The values are dependent on the sample reflectance and are offset in intensity in the hemispherical case, leading to measured values up to similar to 6% too high for a 2% reflectance surface, similar to 3.8% too high for 10% reflecting surfaces, approximately correct for 40-60% diffuse-reflecting surfaces, and similar to 1.5% too low for 99% reflecting Spectralon (R) surfaces. For the case of diffuse-only reflectance, the measured values are uniformly too low due to the polished glass, with differences of nearly 6% for a 99% reflecting matte surface. The deviations arise from the added reflections from the quartz surfaces, as verified by both theory and experiment, and depend on sphere design. Empirical correction factors were implemented into post-processing software to redress the artifact for hemispherical and diffuse reflectance data across the 300-2300 nm range. C1 [Johnson, Timothy J.; Bernacki, Bruce E.; Redding, Rebecca L.; Su, Yin-Fong; Brauer, Carolyn S.; Myers, Tanya L.; Stephan, Eric G.] Pacific NW Natl Lab, Richland, WA 99352 USA. RP Johnson, TJ (reprint author), Pacific NW Natl Lab, POB 999, Richland, WA 99352 USA. EM timothy.johnson@pnnl.gov OI Stephan, Eric/0000-0002-8155-6806 FU U.S. Department of Energy (DOE) Office of Nonproliferation and Verification Research and Development [NA-22]; U.S. DOE [DE-AC05-76RLO1830] FX We thank R. James Ewing for the design of the custom sample holder and Dr. Jim Steensrud of Agilent Technologies for fruitful discussions. We thank Labsphere for the courtesy to reproduce the sphere diagram. The research described in this article was supported in part by the U.S. Department of Energy (DOE) Office of Nonproliferation and Verification Research and Development (NA-22), as well as other sponsors. PNNL is operated by Battelle for the U.S. DOE under Contract DE-AC05-76RLO1830. We gratefully thank our sponsors for their support. NR 48 TC 7 Z9 8 U1 0 U2 10 PU SOC APPLIED SPECTROSCOPY PI FREDERICK PA 5320 SPECTRUM DRIVE SUITE C, FREDERICK, MD 21703 USA SN 0003-7028 EI 1943-3530 J9 APPL SPECTROSC JI Appl. Spectrosc. PD NOV PY 2014 VL 68 IS 11 BP 1224 EP 1234 DI 10.1366/13-07322 PG 11 WC Instruments & Instrumentation; Spectroscopy SC Instruments & Instrumentation; Spectroscopy GA AR7YT UT WOS:000343793600003 PM 25280186 ER PT J AU McGrane, SD Moore, DS Goodwin, PM Dattelbaum, DM AF McGrane, Shawn D. Moore, David S. Goodwin, Peter M. Dattelbaum, Dana M. TI Quantitative Tradeoffs Between Spatial, Temporal, and Thermometric Resolution of Nonresonant Raman Thermometry for Dynamic Experiments SO APPLIED SPECTROSCOPY LA English DT Article DE Raman; Thermometry; Dynamic; Single shot; Stokes to anti-Stokes ratio ID NANOSECOND TEMPERATURE-JUMP; VIBRATIONAL SPECTROSCOPY; SCATTERING; STOKES; CALIBRATION; THRESHOLD; PYROMETRY; SILICON; QUARTZ; DAMAGE AB The ratio of Stokes to anti-Stokes nonresonant spontaneous Raman can provide an in situ thermometer that is noncontact, independent of any material specific parameters or calibrations, can be multiplexed spatially with line imaging, and can be time resolved for dynamic measurements. However, spontaneous Raman cross sections are very small, and thermometric measurements are often limited by the amount of laser energy that can be applied without damaging the sample or changing its temperature appreciably. In this paper, we quantitatively detail the tradeoff space between spatial, temporal, and thermometric accuracy measurable with spontaneous Raman. Theoretical estimates are pinned to experimental measurements to form realistic expectations of the resolution tradeoffs appropriate to various experiments. We consider the effects of signal to noise, collection efficiency, laser heating, pulsed laser ablation, and blackbody emission as limiting factors, provide formulae to help choose optimal conditions and provide estimates relevant to planning experiments along with concrete examples for single-shot measurements. C1 [McGrane, Shawn D.; Moore, David S.; Dattelbaum, Dana M.] Los Alamos Natl Lab, Shock & Detonat Phys Grp, Los Alamos, NM 87545 USA. [Goodwin, Peter M.] Los Alamos Natl Lab, Ctr Integrated Nanotechnol, Los Alamos, NM 87545 USA. RP McGrane, SD (reprint author), Los Alamos Natl Lab, Shock & Detonat Phys Grp, MS P952, Los Alamos, NM 87545 USA. EM mcgrane@lanl.gov OI Mcgrane, Shawn/0000-0002-2978-3980 FU US DOE through the LANL LDRD program; Campaign 2 High Explosive Science program FX The authors gratefully acknowledge funding from the US DOE through the LANL LDRD program and the Campaign 2 High Explosive Science program. NR 43 TC 2 Z9 2 U1 5 U2 20 PU SOC APPLIED SPECTROSCOPY PI FREDERICK PA 5320 SPECTRUM DRIVE SUITE C, FREDERICK, MD 21703 USA SN 0003-7028 EI 1943-3530 J9 APPL SPECTROSC JI Appl. Spectrosc. PD NOV PY 2014 VL 68 IS 11 BP 1279 EP 1288 DI 10.1366/14-07503 PG 10 WC Instruments & Instrumentation; Spectroscopy SC Instruments & Instrumentation; Spectroscopy GA AR7YT UT WOS:000343793600011 PM 25279842 ER PT J AU Gnedin, NY Draine, BT AF Gnedin, Nickolay Y. Draine, Bruce T. TI LINE OVERLAP AND SELF-SHIELDING OF MOLECULAR HYDROGEN IN GALAXIES SO ASTROPHYSICAL JOURNAL LA English DT Article DE cosmology: theory; galaxies: evolution; galaxies: formation; methods: numerical; stars: formation ID REGULATED STAR-FORMATION; SMALL-MAGELLANIC-CLOUD; NEARBY DISK GALAXIES; H I; STELLAR FEEDBACK; COLUMN DENSITIES; DWARF GALAXIES; GAS CONTENT; KPC SCALES; SIMULATIONS AB The effect of line overlap in the Lyman and Werner bands, often ignored in galactic studies of the atomic-to-molecular transition, greatly enhances molecular hydrogen self-shielding in low metallicity environments and dominates over dust shielding for metallicities below about 10% solar. We implement that effect in cosmological hydrodynamics simulations with an empirical model, calibrated against the observational data, and provide fitting formulae for the molecular hydrogen fraction as a function of gas density on various spatial scales and in environments with varied dust abundance and interstellar radiation field. We find that line overlap, while important for detailed radiative transfer in the Lyman and Werner bands, has only a minor effect on star formation on galactic scales, which, to a much larger degree, is regulated by stellar feedback. C1 [Gnedin, Nickolay Y.] Fermilab Natl Accelerator Lab, Ctr Particle Astrophys, Batavia, IL 60510 USA. [Gnedin, Nickolay Y.] Univ Chicago, Kavli Inst Cosmol Phys, Chicago, IL 60637 USA. [Gnedin, Nickolay Y.] Univ Chicago, Dept Astron & Astrophys, Chicago, IL 60637 USA. [Draine, Bruce T.] Princeton Univ Observ, Princeton, NJ 08544 USA. RP Gnedin, NY (reprint author), Fermilab Natl Accelerator Lab, Ctr Particle Astrophys, POB 500, Batavia, IL 60510 USA. EM gnedin@fnal.gov; draine@astro.princeton.edu FU United States Department of Energy [DE-AC02-07CH11359]; NSF [AST-1211190, AST-1008570] FX Fermilab is operated by the Fermi Research Alliance, LLC, under contract No. DE-AC02-07CH11359 with the United States Department of Energy. N.Y.G.'s work was also supported in part by the NSF grant AST-1211190. B.T.D. was supported in part by NSF grant AST-1008570. NR 50 TC 11 Z9 11 U1 0 U2 3 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0004-637X EI 1538-4357 J9 ASTROPHYS J JI Astrophys. J. PD NOV 1 PY 2014 VL 795 IS 1 AR 37 DI 10.1088/0004-637X/795/1/37 PG 6 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA AR8YN UT WOS:000343857300037 ER PT J AU Pei, LY Barth, AJ Aldering, GS Briley, MM Carroll, CJ Carson, DJ Cenko, SB Clubb, KI Cohen, DP Cucchiara, A Desjardins, TD Edelson, R Fang, JJ Fedrow, JM Filippenko, AV Fox, OD Furniss, A Gates, EL Gregg, M Gustafson, S Horst, JC Joner, MD Kelly, PL Lacy, M Laney, CD Leonard, DC Li, WD Malkan, MA Margon, B Neeleman, M Nguyen, ML Prochaska, JX Ross, NR Sand, DJ Searcy, KJ Shivvers, IS Silverman, JM Smith, GH Suzuki, N Smith, KL Tytler, D Werk, JK Worseck, G AF Pei, Liuyi Barth, Aaron J. Aldering, Greg S. Briley, Michael M. Carroll, Carla J. Carson, Daniel J. Cenko, S. Bradley Clubb, Kelsey I. Cohen, Daniel P. Cucchiara, Antonino Desjardins, Tyler D. Edelson, Rick Fang, Jerome J. Fedrow, Joseph M. Filippenko, Alexei V. Fox, Ori D. Furniss, Amy Gates, Elinor L. Gregg, Michael Gustafson, Scott Horst, J. Chuck Joner, Michael D. Kelly, Patrick L. Lacy, Mark Laney, C. David Leonard, Douglas C. Li, Weidong Malkan, Matthew A. Margon, Bruce Neeleman, Marcel Nguyen, My L. Prochaska, J. Xavier Ross, Nathaniel R. Sand, David J. Searcy, Kinchen J. Shivvers, Isaac S. Silverman, Jeffrey M. Smith, Graeme H. Suzuki, Nao Smith, Krista Lynne Tytler, David Werk, Jessica K. Worseck, Gabor TI REVERBERATION MAPPING OF THE KEPLER FIELD AGN KA1858+4850 SO ASTROPHYSICAL JOURNAL LA English DT Article DE galaxies: active; galaxies: individual (1RXSJ185800.9+485020); galaxies: nuclei ID ACTIVE GALACTIC NUCLEI; BROAD-LINE REGION; BLACK-HOLE MASS; RAPID OPTICAL VARIABILITY; MONITORING PROJECT; LUMINOSITY RELATIONSHIP; RECOMBINATION LINES; QUASARS; GALAXIES; CALIBRATION AB KA1858+4850 is a narrow-line Seyfert 1 galaxy at redshift 0.078 and is among the brightest active galaxies monitored by the Kepler mission. We have carried out a reverberation mapping campaign designed to measure the broad-line region size and estimate the mass of the black hole in this galaxy. We obtained 74 epochs of spectroscopic data using the Kast Spectrograph at the Lick 3 m telescope from 2012 February to November, and obtained complementary V-band images from five other ground-based telescopes. We measured the H beta light curve lag with respect to the V-band continuum light curve using both cross-correlation techniques (CCF) and continuum light curve variability modeling with the JAVELIN method and found rest-frame lags of tau(CCF) = 13.53(+2.03)(-2.32) days and tau(JAVELIN) = 13.15(+1.08)(-1.00) days. The H beta rms line profile has a width of sigma line = 770 +/- 49 km s(-1). Combining these two results and assuming a virial scale factor of f = 5.13, we obtained a virial estimate of M-BH = 8.06(+1.59)(-1.72) x 10(6) M circle dot for the mass of the central black hole and an Eddington ratio of L/L-Edd approximate to 0.2. We also obtained consistent but slightly shorter emission-line lags with respect to the Kepler light curve. Thanks to the Kepler mission, the light curve of KA1858+4850 has among the highest cadences and signal-to-noise ratios ever measured for an active galactic nucleus; thus, our black hole mass measurement will serve as a reference point for relations between black hole mass and continuum variability characteristics in active galactic nuclei. C1 [Pei, Liuyi; Barth, Aaron J.; Carson, Daniel J.] Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA. [Aldering, Greg S.; Cucchiara, Antonino] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. [Briley, Michael M.] Appalachian State Univ, Dept Phys & Astron, Boone, NC 28608 USA. [Carroll, Carla J.; Joner, Michael D.; Laney, C. David] Brigham Young Univ, Dept Phys & Astron, Provo, UT 84602 USA. [Cenko, S. Bradley; Edelson, Rick; Smith, Krista Lynne] Univ Maryland, Dept Astron, College Pk, MD 20742 USA. [Cenko, S. Bradley] NASA, Astrophys Sci Div, Goddard Space Flight Ctr, Greenbelt, MD 20771 USA. [Cenko, S. Bradley] Univ Maryland, Joint Space Sci Inst, College Pk, MD 20742 USA. [Clubb, Kelsey I.; Cohen, Daniel P.; Cucchiara, Antonino; Filippenko, Alexei V.; Fox, Ori D.; Kelly, Patrick L.; Li, Weidong; Shivvers, Isaac S.] Univ Calif Berkeley, Dept Astron, Berkeley, CA 94720 USA. [Desjardins, Tyler D.] Univ Western Ontario, Dept Phys & Astron, London, ON N6A 3K7, Canada. [Fang, Jerome J.; Margon, Bruce; Prochaska, J. Xavier; Werk, Jessica K.] Univ Calif Santa Cruz, Dept Astron & Astrophys, Santa Cruz, CA 95064 USA. [Fedrow, Joseph M.; Horst, J. Chuck; Leonard, Douglas C.] San Diego State Univ, Dept Astron, San Diego, CA 92182 USA. [Fedrow, Joseph M.] Univ Calif San Diego, Ctr Astrophys & Space Sci, La Jolla, CA 92093 USA. [Furniss, Amy] Stanford Univ, Dept Phys, Stanford, CA 94305 USA. [Gates, Elinor L.] Univ Calif Santa Cruz, Lick Observ, Mt Hamilton, CA 95140 USA. [Gregg, Michael] Univ Calif Davis, Dept Phys, Davis, CA 95616 USA. [Gustafson, Scott; Neeleman, Marcel; Tytler, David] Univ Calif San Diego, Dept Phys, La Jolla, CA 92093 USA. [Lacy, Mark] Natl Radio Astron Observ, Charlottesville, VA 22903 USA. [Malkan, Matthew A.; Ross, Nathaniel R.] Univ Calif Los Angeles, Dept Phys & Astron, Los Angeles, CA 90095 USA. [Nguyen, My L.] Univ Wyoming, Dept Phys & Astron, Laramie, WY 82071 USA. [Prochaska, J. Xavier; Smith, Graeme H.; Werk, Jessica K.; Worseck, Gabor] Univ Calif Santa Cruz, Dept Astron & Astrophys, UCO Lick Observ, Santa Cruz, CA 95064 USA. [Sand, David J.] Las Cumbres Observ Global Telescope Network, Goleta, CA 93117 USA. [Sand, David J.] Texas Tech Univ, Dept Phys, Lubbock, TX 79409 USA. [Searcy, Kinchen J.] San Diego Astron Assoc, San Diego, CA 92193 USA. [Silverman, Jeffrey M.] Univ Texas Austin, Dept Astron, Austin, TX 78712 USA. [Suzuki, Nao] Stanford Univ, Kavli Inst Particle Astrophys & Cosmol, Stanford, CA 94305 USA. RP Pei, LY (reprint author), Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA. OI Worseck, Gabor/0000-0003-0960-3580; Shivvers, Isaac/0000-0003-3373-8047; Barth, Aaron/0000-0002-3026-0562 FU NSF [AST-1108835, AST-1107812, AST-1108665, AST-1211916, AST-1302771, AST-1009571, AST-1210311, AST-0618209]; TABASGO Foundation; Christopher R. Redlich Fund; NASA [NAS5-26555]; NASA Office of Space Science [NNX13AC07G]; NASA Science Mission directorate FX Research by L. P. and A.J.B. at UC Irvine has been supported by NSF grant AST-1108835. Research by M. A. M. at UCLA was supported by NSF grant AST-1107812. A.V.F.'s group at UC Berkeley was supported through NSF grants AST-1108665 and AST-1211916, the TABASGO Foundation, and the Christopher R. Redlich Fund. KAIT and its ongoing operation were made possible by donations from Sun Microsystems, Inc., the Hewlett-Packard Company, AutoScope Corporation, Lick Observatory, the NSF, the University of California, the Sylvia & Jim Katzman Foundation, and the TABASGO Foundation. We are very grateful to our late colleague Weidong Li, who was instrumental in making KAIT successful and taught us much about photometry.; J.M.S. is supported by an NSF Astronomy and Astrophysics Postdoctoral Fellowship under award AST-1302771. Research by D.C.L., J.C.H., and J.M.F. at San Diego State University is supported by NSF grants AST-1009571 and AST-1210311. The WMO 0.9 m telescope was funded by NSF grant AST-0618209.; This work makes use of observations from the LCOGT network. Some of the data presented in this paper were obtained from the Mikulski Archive for Space Telescopes (MAST). STScI is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS5-26555. Support for MAST for non-HST data is provided by the NASA Office of Space Science via grant NNX13AC07G and by other grants and contracts. This paper includes data collected by the Kepler mission. Funding for the Kepler mission is provided by the NASA Science Mission directorate. NR 58 TC 9 Z9 9 U1 1 U2 7 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0004-637X EI 1538-4357 J9 ASTROPHYS J JI Astrophys. J. PD NOV 1 PY 2014 VL 795 IS 1 AR 38 DI 10.1088/0004-637X/795/1/38 PG 15 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA AR8YN UT WOS:000343857300038 ER PT J AU Takami, M Hasegawa, Y Muto, T Gu, PG Dong, RB Karr, JL Hashimoto, J Kusakabe, N Chapillon, E Tang, YW Itoh, Y Carson, J Follette, KB Mayama, S Sitko, M Janson, M Grady, CA Kudo, T Akiyama, E Kwon, J Takahashi, Y Suenaga, T Abe, L Brandner, W Brandt, TD Currie, T Egner, SE Feldt, M Guyon, O Hayano, Y Hayashi, M Hayashi, S Henning, T Hodapp, KW Honda, M Ishii, M Iye, M Kandori, R Knapp, GR Kuzuhara, M McElwain, MW Matsuo, T Miyama, S Morino, JI Moro-Martin, A Nishimura, T Pyo, TS Serabyn, E Suto, H Suzuki, R Takato, N Terada, H Thalmann, C Tomono, D Turner, EL Wisniewski, JP Watanabe, M Yamada, T Takami, H Usuda, T Tamura, M AF Takami, Michihiro Hasegawa, Yasuhiro Muto, Takayuki Gu, Pin-Gao Dong, Ruobing Karr, Jennifer L. Hashimoto, Jun Kusakabe, Nobuyuki Chapillon, Edwige Tang, Ya-Wen Itoh, Youchi Carson, Joseph Follette, Katherine B. Mayama, Satoshi Sitko, Michael Janson, Markus Grady, Carol A. Kudo, Tomoyuki Akiyama, Eiji Kwon, Jungmi Takahashi, Yasuhiro Suenaga, Takuya Abe, Lyu Brandner, Wolfgang Brandt, Timothy D. Currie, Thayne Egner, Sebastian E. Feldt, Markus Guyon, Olivier Hayano, Yutaka Hayashi, Masahiko Hayashi, Saeko Henning, Thomas Hodapp, Klaus W. Honda, Mitsuhiko Ishii, Miki Iye, Masanori Kandori, Ryo Knapp, Gillian R. Kuzuhara, Masayuki McElwain, Michael W. Matsuo, Taro Miyama, Shoken Morino, Jun-Ichi Moro-Martin, Amaya Nishimura, Tetsuo Pyo, Tae-Soo Serabyn, Eugene Suto, Hiroshi Suzuki, Ryuji Takato, Naruhisa Terada, Hiroshi Thalmann, Christian Tomono, Daigo Turner, Edwin L. Wisniewski, John P. Watanabe, Makoto Yamada, Toru Takami, Hideki Usuda, Tomonori Tamura, Motohide TI SURFACE GEOMETRY OF PROTOPLANETARY DISKS INFERRED FROM NEAR-INFRARED IMAGING POLARIMETRY SO ASTROPHYSICAL JOURNAL LA English DT Article DE polarization; protoplanetary disks; stars: individual (SAO 206462, MWC 758, 2MASS J16042165-2130284, PDS 70, MWC 480); stars: pre-main sequence ID SPECTRAL ENERGY-DISTRIBUTIONS; YOUNG STELLAR OBJECTS; T-TAURI STARS; POLARIZED SCATTERED-LIGHT; CIRCUMSTELLAR DISK; TRANSITIONAL DISK; HIGH-RESOLUTION; UPPER SCORPIUS; PDS 70; PROTOSTELLAR ENVELOPES AB We present a new method of analysis for determining the surface geometry of five protoplanetary disks observed with near-infrared imaging polarimetry using Subaru-HiCIAO. Using as inputs the observed distribution of polarized intensity (PI), disk inclination, assumed properties for dust scattering, and other reasonable approximations, we calculate a differential equation to derive the surface geometry. This equation is numerically integrated along the distance from the star at a given position angle. We show that, using these approximations, the local maxima in the PI distribution of spiral arms (SAO 206462, MWC 758) and rings (2MASS J16042165-2130284, PDS 70) are associated with local concave-up structures on the disk surface. We also show that the observed presence of an inner gap in scattered light still allows the possibility of a disk surface that is parallel to the light path from the star, or a disk that is shadowed by structures in the inner radii. Our analysis for rings does not show the presence of a vertical inner wall as often assumed in studies of disks with an inner gap. Finally, we summarize the implications of spiral and ring structures as potential signatures of ongoing planet formation. C1 [Takami, Michihiro; Hasegawa, Yasuhiro; Gu, Pin-Gao; Karr, Jennifer L.; Chapillon, Edwige; Tang, Ya-Wen] Acad Sinica, Inst Astron & Astrophys, Taipei 10617, Taiwan. [Muto, Takayuki] Kogakuin Univ, Div Liberal Arts, Shinjuku Ku, Tokyo 1638677, Japan. [Dong, Ruobing] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Nucl Sci, Berkeley, CA 94720 USA. [Dong, Ruobing] Univ Calif Berkeley, Dept Astron, Berkeley, CA 94720 USA. [Hashimoto, Jun; Wisniewski, John P.] Univ Oklahoma, HL Dodge Dept Phys & Astron, Norman, OK 73019 USA. [Kusakabe, Nobuyuki; Akiyama, Eiji; Kwon, Jungmi; Takahashi, Yasuhiro; Hayashi, Masahiko; Ishii, Miki; Iye, Masanori; Kandori, Ryo; Kuzuhara, Masayuki; Miyama, Shoken; Morino, Jun-Ichi; Suto, Hiroshi; Suzuki, Ryuji; Takami, Hideki; Usuda, Tomonori; Tamura, Motohide] Natl Astron Observ Japan, Mitaka, Tokyo 1818588, Japan. [Itoh, Youchi] Univ Hyogo, Nishi Harima Astron Observ, Ctr Astron, Sayo, Hyogo 6795313, Japan. [Carson, Joseph] Coll Charleston, Dept Phys & Astron, Charleston, SC 29424 USA. [Follette, Katherine B.] Univ Arizona, Steward Observ, Tucson, AZ 85721 USA. [Mayama, Satoshi] Grad Univ Adv Studies SOKENDAI, Ctr Promot Integrated Sci, Hayama, Kanagawa 2400193, Japan. [Sitko, Michael] Univ Cincinnati, Dept Phys, Cincinnati, OH 45221 USA. [Janson, Markus] Queens Univ Belfast, Astrophys Res Ctr, Belfast BT7 1NN, Antrim, North Ireland. [Grady, Carol A.] Eureka Sci, Oakland, CA 96402 USA. [Grady, Carol A.; McElwain, Michael W.] NASA, Goddard Space Flight Ctr, ExoPlanets & Stellar Astrophys Lab, Greenbelt, MD 20771 USA. [Kudo, Tomoyuki; Egner, Sebastian E.; Guyon, Olivier; Hayano, Yutaka; Hayashi, Saeko; Nishimura, Tetsuo; Pyo, Tae-Soo; Takato, Naruhisa; Terada, Hiroshi; Tomono, Daigo] Subaru Telescope, Hilo, HI 96720 USA. [Takahashi, Yasuhiro; Tamura, Motohide] Univ Tokyo, Dept Astron, Bunkyo Ku, Tokyo 1130033, Japan. [Suenaga, Takuya; Tamura, Motohide] Grad Univ Adv Studies SOKENDAI, Dept Astron Sci, Mitaka, Tokyo 1818588, Japan. [Abe, Lyu] Univ Nice Sophia Antipolis, CNRS, Observ Cote Azur, Lab Lagrange,UMR 7293, F-06108 Nice 2, France. [Brandner, Wolfgang; Feldt, Markus; Henning, Thomas] Max Planck Inst Astron, D-69117 Heidelberg, Germany. [Brandt, Timothy D.; Knapp, Gillian R.; Turner, Edwin L.] Princeton Univ, Dept Astrophys Sci, Princeton, NJ 08544 USA. [Currie, Thayne] Univ Toronto, Dept Astron & Astrophys, Toronto, ON, Canada. [Hodapp, Klaus W.] Univ Hawaii, Inst Astron, Hilo, HI 96720 USA. [Honda, Mitsuhiko] Kanagawa Univ, Fac Sci, Dept Math & Phys, Hiratsuka, Kanagawa 2591293, Japan. [Kuzuhara, Masayuki] Univ Tokyo, Dept Earth & Planetary Sci, Bunkyo Ku, Tokyo 1130033, Japan. [Kuzuhara, Masayuki] Tokyo Inst Technol, Dept Earth & Planetary Sci, Meguro Ku, Tokyo 1528551, Japan. [Matsuo, Taro] Kyoto Univ, Dept Astron, Sakyo Ku, Kyoto 6068502, Japan. [Moro-Martin, Amaya] CAB CSIC INTA, Dept Astrophys, E-28850 Madrid, Spain. [Serabyn, Eugene] CALTECH, Jet Prop Lab, Pasadena, CA 91109 USA. [Thalmann, Christian] ETH, Inst Astron, CH-8093 Zurich, Switzerland. [Turner, Edwin L.] Univ Tokyo, Kavli Inst Phys & Math Universe, Kashiwa, Chiba 2778568, Japan. [Watanabe, Makoto] Hokkaido Univ, Dept Cosmosci, Kita Ku, Sapporo, Hokkaido 0600810, Japan. [Yamada, Toru] Tohoku Univ, Astron Inst, Aoba Ku, Sendai, Miyagi 9808578, Japan. RP Takami, M (reprint author), Acad Sinica, Inst Astron & Astrophys, POB 23-141, Taipei 10617, Taiwan. EM hiro@asiaa.sinica.edu.tw RI MIYAMA, Shoken/A-3598-2015; Watanabe, Makoto/E-3667-2016 OI Watanabe, Makoto/0000-0002-3656-4081 FU Ministry of Science and Technology (MoST) of Taiwan [100-2112-M-001-007-MY3, 103-2112-M-001-029]; EACOA by East Asia Core Observatories Association; National Astronomical Observatory of Japan; National Astronomical Observatory of China; Korea Astronomy and Space Science Institute; JSPS KAKENHI [26800106, 23103004, 26400224]; NASA through Hubble Fellowship by Space Telescope Science Institute [HST-HF-51320.01-A]; NASA [NAS 5-26555]; JSPS [PD: 24.110]; NSF-AST [1009203, 1009314]; NSF [AST 1008440] FX We are grateful for anonymous referees who provided thorough reviews and valuable comments. We thank the Subaru Telescope staff for their support, especially from Michael Lemmen for making our observations successful. We thank Dr. Hyosun Kim for useful discussion. M. T. is supported by the Ministry of Science and Technology (MoST) of Taiwan (Grant Nos. 100-2112-M-001-007-MY3 and 103-2112-M-001-029). Y.H. is supported by the EACOA Fellowship that is supported by the East Asia Core Observatories Association which consists of the Academia Sinica Institute of Astronomy and Astrophysics, the National Astronomical Observatory of Japan, the National Astronomical Observatory of China, and the Korea Astronomy and Space Science Institute. T. M. is supported by JSPS KAKENHI grant Nos. 26800106, 23103004, 26400224. R. D. acknowledges the support for this work by NASA through Hubble Fellowship grant HST-HF-51320.01-A awarded by the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., for NASA, under contract NAS 5-26555. Jungmi Kwon is supported by the JSPS Research Fellowships for Young Scientists (PD: 24.110). J.C. was supported by NSF-AST 1009203. C. A. G. acknowledges support under NSF AST 1008440. J.P.W. is supported by NSF-AST 1009314. This research made use of the Simbad data base operated at CDS, Strasbourg, France, and the NASA's Astrophysics Data System Abstract Service. NR 77 TC 16 Z9 16 U1 1 U2 5 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0004-637X EI 1538-4357 J9 ASTROPHYS J JI Astrophys. J. PD NOV 1 PY 2014 VL 795 IS 1 AR 71 DI 10.1088/0004-637X/795/1/71 PG 21 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA AR8YN UT WOS:000343857300071 ER PT J AU Chen, H Lei, Z Zang, MY AF Chen, Hu Lei, Zhou Zang, Mengyan TI LC-Grid: a linear global contact search algorithm for finite element analysis SO COMPUTATIONAL MECHANICS LA English DT Article DE Contact; Global search algorithm; Space decomposition; Finite element analysis ID SHOT PEENING PROCESSES; IMPACT PROBLEMS; CONSERVING ALGORITHMS; INTERACTION LAWS; SURFACE-CONTACT; SIMULATION; FRICTION; FORMULATION AB The contact searching is computationally intensive and its memory requirement is highly demanding; therefore, it is significant to develop an efficient contact search algorithm with less memory required. In this paper, we propose an efficient global contact search algorithm with linear complexity in terms of computational cost and memory requirement for the finite element analysis of contact problems. This algorithm is named LC-Grid (Lei devised the algorithm and Chen implemented it). The contact space is decomposed; thereafter, all contact nodes and segments are firstly mapped onto layers, then onto rows and lastly onto cells. In each mapping level, the linked-list technique is used for the efficient storing and retrieval of contact nodes and segments. The contact detection is performed in each non-empty cell along non-empty rows in each non-empty layer, and moves to the next non-empty layer once a layer is completed. The use of migration strategy makes the algorithm insensitive to mesh size. The properties of this algorithm are investigated and numerically verified to be linearly proportional to the number of contact segments. Besides, the ideal ranges of two significant scale factors of cell size and buffer zone which strongly affect computational efficiency are determined via an illustrative example. C1 [Chen, Hu] Univ New S Wales, Sch Engn & Informat Technol, ADFA, Canberra, ACT 2600, Australia. [Lei, Zhou] Los Alamos Natl Lab, Geophys Grp, Los Alamos, NM 87545 USA. [Zang, Mengyan] S China Univ Technol, Sch Mech & Automot Engn, Guangzhou 510640, Guangdong, Peoples R China. RP Zang, MY (reprint author), S China Univ Technol, Sch Mech & Automot Engn, Guangzhou 510640, Guangdong, Peoples R China. EM hu.chen@student.adfa.edu.au; alei.hnu@gmail.com; myzang@scut.edu.cn OI Chen, Hu/0000-0002-5645-9449; Lei, Zhou/0000-0002-4965-5556 FU International Cooperation Project of the Ministry of Science and Technology of China [2008DFA51740]; National Natural Science Foundation of China [10972079, 11172104]; China Scholarship Council; UNSW Canberra FX This work was supported by the International Cooperation Project of the Ministry of Science and Technology of China (No. 2008DFA51740), the National Natural Science Foundation of China (No. 10972079 and 11172104). The valuable comments and suggestions from anonymous reviewers are gratefully acknowledged. Also the first author would want to express his gratitude to the China Scholarship Council and UNSW Canberra for their financial support. NR 39 TC 6 Z9 6 U1 0 U2 5 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0178-7675 EI 1432-0924 J9 COMPUT MECH JI Comput. Mech. PD NOV PY 2014 VL 54 IS 5 BP 1285 EP 1301 DI 10.1007/s00466-014-1058-5 PG 17 WC Mathematics, Interdisciplinary Applications; Mechanics SC Mathematics; Mechanics GA AR9EJ UT WOS:000343874700014 ER PT J AU Aktulga, HM Yang, C Ng, EG Maris, P Vary, JP AF Aktulga, Hasan Metin Yang, Chao Ng, Esmond G. Maris, Pieter Vary, James P. TI Improving the scalability of a symmetric iterative eigensolver for multi-core platforms SO CONCURRENCY AND COMPUTATION-PRACTICE & EXPERIENCE LA English DT Article DE symmetric iterative eigensolvers; topology-aware mapping; hybrid MPI; OpenMP parallelism AB We describe an efficient and scalable symmetric iterative eigensolver developed for distributed memory multi-core platforms. We achieve over 80% parallel efficiency by major reductions in communication overheads for the sparse matrix-vector multiplication and basis orthogonalization tasks. We show that the scalability of the solver is significantly improved compared to an earlier version, after we carefully reorganize the computational tasks and map them to processing units in a way that exploits the network topology. We discuss the advantage of using a hybrid OpenMP/MPI programming model to implement such a solver. We also present strategies for hiding communication on a multi-core platform. We demonstrate the effectiveness of these techniques by reporting the performance improvements achieved when we apply our solver to large-scale eigenvalue problems arising in nuclear structure calculations. Because sparse matrix-vector multiplication and inner product computation constitute the main kernels in most iterative methods, our ideas are applicable in general to the solution of problems involving large-scale symmetric sparse matrices with irregular sparsity patterns. Copyright (c) 2013 John Wiley & Sons, Ltd. C1 [Aktulga, Hasan Metin; Yang, Chao; Ng, Esmond G.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Computat Res Div, Berkeley, CA 94720 USA. [Maris, Pieter; Vary, James P.] Iowa State Univ, Dept Phys & Astron, Ames, IA 50011 USA. RP Aktulga, HM (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Computat Res Div, Berkeley, CA 94720 USA. EM hmaktulga@lbl.gov FU Scientific Discovery through Advanced Computing Program in the Offices of Advanced Scientific Computing Research and Nuclear Physics in the Office of Science, US Department of Energy [DE-AC02-05CH11231, DE-FG-02-87ER40371, DE-FC02-09ER41582, DE-SC0008485]; US NSF [0904782]; US DOE Office of Science FX This work was supported in part by the Scientific Discovery through Advanced Computing Program in the Offices of Advanced Scientific Computing Research and Nuclear Physics in the Office of Science, US Department of Energy under contract no. DE-AC02-05CH11231 at LBNL and grants no. DE-FG-02-87ER40371, DE-FC02-09ER41582, and DE-SC0008485 at the Iowa State University. It was also funded in part by the US NSF grant no. 0904782 at the Iowa State University. Computational resources were provided by NERSC, which is supported by the US DOE Office of Science. NR 20 TC 14 Z9 14 U1 0 U2 5 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1532-0626 EI 1532-0634 J9 CONCURR COMP-PRACT E JI Concurr. Comput.-Pract. Exp. PD NOV PY 2014 VL 26 IS 16 BP 2631 EP 2651 DI 10.1002/cpe.3129 PG 21 WC Computer Science, Software Engineering; Computer Science, Theory & Methods SC Computer Science GA AR8GT UT WOS:000343814500001 ER PT J AU Paul, TC Morshed, AKMM Fox, EB Visser, AE Bridges, NJ Khan, JA AF Paul, Titan C. Morshed, A. K. M. M. Fox, Elise B. Visser, Ann E. Bridges, Nicholas J. Khan, Jamil A. TI Thermal performance of ionic liquids for solar thermal applications SO EXPERIMENTAL THERMAL AND FLUID SCIENCE LA English DT Article DE Ionic liquid; Heat capacity; Thermal conductivity; Convective heat transfer coefficient; Nusselt number; Reynolds number ID HEAT-TRANSFER BEHAVIOR; SURFACE-TENSION; IMIDAZOLIUM; FLUIDS; STABILITY; CORROSION; PRESSURE; SOLVENTS; DENSITY AB Experimental investigations were carried out to evaluate thermophysical properties, i.e. density, viscosity, heat capacity, and thermal conductivity and high temperature forced convection behavior of N-butyl-N,N,N-trimetylammoniumbis(trifluormethylsulfonyl)imide ([N-4111][NTf2]) ionic liquid (IL) for its potential application in concentrated solar power (CSP). Results from the experiments will be useful in assessing the potential of using ILs for solar thermal collectors. Experimental results show that thethermal conductivity was slightly decrease with the increase of temperature; vary from 0.124 to 0.121 W/m K for a change in temperature of 283-343 K, strong temperature effect on the viscosity of IL was observed and maintain an exponential relationship with the temperature; heat capacity increases linearly with temperature measured from 298 to 618 K. Forced convection performance of the IL was studied in a circular tube under both in laminar and turbulent conditions. Although the heat transfer coefficient of the IL was found to be lower compared to the De-Ionized (DI) water, its thermal stability and other attractive properties may make it a viable candidate for solar collector use. Our experimental results also established that Shah's equation and Gnielinski's equation can predict forced convection performance of IL for both the laminar region and turbulent region respectively. (C) 2014 Elsevier Inc. All rights reserved. C1 [Paul, Titan C.; Morshed, A. K. M. M.; Khan, Jamil A.] Univ S Carolina, Dept Mech Engn, Columbia, SC 29208 USA. [Fox, Elise B.; Visser, Ann E.; Bridges, Nicholas J.] Savannah River Natl Lab, Aiken, SC USA. RP Khan, JA (reprint author), Univ S Carolina, Dept Mech Engn, Columbia, SC 29208 USA. EM khan@cec.sc.edu FU Department of Energy (DOE) Solar Energy Technology Program; U.S. Department of Energy [DEAC09-08SR22470] FX The financial support for this research is from Department of Energy (DOE) Solar Energy Technology Program. Savannah River National Laboratory is operated by Savannah River Nuclear Solutions. This document was prepared in conjunction with work accomplished under Contract No. DEAC09-08SR22470 with the U.S. Department of Energy. NR 39 TC 4 Z9 5 U1 3 U2 21 PU ELSEVIER SCIENCE INC PI NEW YORK PA 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA SN 0894-1777 EI 1879-2286 J9 EXP THERM FLUID SCI JI Exp. Therm. Fluid Sci. PD NOV PY 2014 VL 59 BP 88 EP 95 DI 10.1016/j.expthermflusci.2014.08.002 PG 8 WC Thermodynamics; Engineering, Mechanical; Physics, Fluids & Plasmas SC Thermodynamics; Engineering; Physics GA AR8RZ UT WOS:000343843400010 ER PT J AU Johnston, R Bacon, D Teodoro, LFA Nichol, RC Warren, MS Cress, C AF Johnston, R. Bacon, D. Teodoro, L. F. A. Nichol, R. C. Warren, M. S. Cress, C. TI Reconstructing the velocity field beyond the local universe SO GENERAL RELATIVITY AND GRAVITATION LA English DT Article DE Methods: data analysis, numerical, statistical; Galaxies: distances and redshifts; Cosmology: large-scale structure of universe ID LARGE-SCALE STRUCTURE; DIGITAL SKY SURVEY; EARLY-TYPE GALAXIES; PECULIAR VELOCITY; TULLY-FISHER; FUNDAMENTAL PLANE; REDSHIFT DATA; WIENER RECONSTRUCTION; ELLIPTIC GALAXIES; DENSITY AB We present a maximum probability approach to reconstructing spatial maps of the peculiar velocity field at redshifts z similar to 0.1, where the velocities have been measured from distance indicators (DI) such as D-n - sigma relations or Tully-Fisher. With the large statistical uncertainties associated with DIs, our reconstruction method aims to recover the underlying true peculiar velocity field by reducing these errors with the use of two physically motivated filtering prior terms. The first constructs an estimate of the velocity field derived from the galaxy over-density delta(g) and the second makes use of the matter linear density power spectrum P-k. Using N-body simulations we find, with an SDSS-like sample (N-gal similar to 33 per deg(2)), an average correlation coefficient value of r = 0.55 +/- 0.02 between our reconstructed velocity field and that of the true velocity field from the simulation. However, with a suitably high number density of galaxies from the next generation surveys (e. g. N-gal similar or equal to 140 per deg(2)) we can achieve an average r = 0.70 +/- 0.02 out to moderate redshifts z similar to 0.1. This will prove useful for future tests of gravity, as these relatively deep maps are complementary to weak lensing maps at the same redshift. LA-UR 12-24505. C1 [Johnston, R.] Univ Western Cape, Dept Phys, Cape Town, South Africa. [Bacon, D.; Nichol, R. C.] Univ Portsmouth, Inst Cosmol & Gravitat, Portsmouth PO1 3FX, Hants, England. [Teodoro, L. F. A.] NASA, BAER Inst, Space Sci & Astrobiol Div, Ames Res Ctr, Moffett Field, CA 94035 USA. [Warren, M. S.] Los Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USA. [Cress, C.] Ctr High Performance Comp, ZA-7700 Cape Town, South Africa. RP Johnston, R (reprint author), Univ Western Cape, Dept Phys, Cape Town, South Africa. EM rwi.johnston@gmail.com FU SKA-South Africa; National Research Foundation (NRF); UK Science and Technology Facilities Council [ST/H002774/1, ST/K0090X/1]; ICG, at the University of Portsmouth FX We would like to extend special thanks to Enzo Branchini and Adi Nusser for stimulating discussions, their comments and reading several drafts of this paper. We also would like to thank Martin Hendry, Mat Smith, Andreas Faltenbacher, Roy Maartens, Daniele Bertacca, Rafal Szepietowski, Yong-Seon Song, Kazuya Koyama, Prina Patel, Emma Beynon, Robert Crittenden and Philip Marshall for useful discussions. RJ acknowledges the support of the SKA-South Africa and the National Research Foundation (NRF), as well as the hospitality of the Institute of Cosmology and Gravitation (ICG) at the University of Portsmouth where some of this work was carried out. DB and RN are supported by the UK Science and Technology Facilities Council (Grant Nos. ST/H002774/1 and ST/K0090X/1). The analysis was performed with the SCIAMA High Performance Computing cluster supported by the ICG, at the University of Portsmouth. We would like to thank the SCIAMA cluster administrator, Gary Burton, for all his help. Please contact the authors to request access to research materials discussed in this paper. NR 58 TC 1 Z9 1 U1 0 U2 2 PU SPRINGER/PLENUM PUBLISHERS PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0001-7701 EI 1572-9532 J9 GEN RELAT GRAVIT JI Gen. Relativ. Gravit. PD NOV PY 2014 VL 46 IS 11 AR 1812 DI 10.1007/s10714-014-1812-1 PG 18 WC Astronomy & Astrophysics; Physics, Multidisciplinary; Physics, Particles & Fields SC Astronomy & Astrophysics; Physics GA AR9FT UT WOS:000343879000005 ER PT J AU Pitrou, C Stebbins, A AF Pitrou, Cyril Stebbins, Albert TI Parameterization of temperature and spectral distortions in future CMB experiments SO GENERAL RELATIVITY AND GRAVITATION LA English DT Article ID RADIATION; UNIVERSE AB CMB spectral distortions are induced by Compton collisions with electrons. We review the various schemes to characterize the anisotropic CMB with a non-Planckian spectrum. We advocate using logarithmically averaged temperature moments as the preferred language to describe these spectral distortions, both for theoretical modeling and observations. Numerical modeling is simpler, the moments are frame-independent, and in terms of scattering the mode truncation is exact. C1 [Pitrou, Cyril] Univ Paris 06, CNRS UMR, Inst Astrophys Paris, F-75014 Paris, France. [Pitrou, Cyril] Univ Paris 04, Inst Lagrange Paris, F-75014 Paris, France. [Stebbins, Albert] Fermilab Natl Accelerator Lab, Theoret Astrophys Grp, Batavia, IL 60510 USA. RP Pitrou, C (reprint author), Univ Paris 06, CNRS UMR, Inst Astrophys Paris, 98 Bis Bd Arago, F-75014 Paris, France. EM pitrou@iap.fr FU French state funds [ANR-11-IDEX-0004-02]; DOE at Fermilab [DE-AC02-07CH11359] FX C.P. thanks J. Chluba, C. Fidler, Z. Huang, S. Renaux-Petel, G. Pettinari, J.-P. Uzan, and F. Vernizzi for fruitful discussions. This work was supported by French state funds managed by the ANR within the Investissements d'Avenir programme under reference ANR-11-IDEX-0004-02. AS was supported by the DOE at Fermilab under Contract No. DE-AC02-07CH11359. NR 28 TC 1 Z9 1 U1 0 U2 0 PU SPRINGER/PLENUM PUBLISHERS PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0001-7701 EI 1572-9532 J9 GEN RELAT GRAVIT JI Gen. Relativ. Gravit. PD NOV PY 2014 VL 46 IS 11 AR 1806 DI 10.1007/s10714-014-1806-z PG 10 WC Astronomy & Astrophysics; Physics, Multidisciplinary; Physics, Particles & Fields SC Astronomy & Astrophysics; Physics GA AR9FT UT WOS:000343879000003 ER PT J AU Li, XW Wang, Z Mao, XL Russo, RE AF Li, Xiongwei Wang, Zhe Mao, Xianglei Russo, Richard E. TI Spatially and temporally resolved spectral emission of laser-induced plasmas confined by cylindrical cavities SO JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY LA English DT Article ID INDUCED BREAKDOWN SPECTROSCOPY; ABLATION; SIGNAL; IMPROVEMENT; GAS AB Laser-induced plasmas generated on pure copper samples in air with and without the presence of cylindrical cavities were investigated using spatially and temporally resolved spectroscopic measurements. The cylindrical cavities with variable diameters (3, 4 and 5 mm) and variable heights (1, 2, and 3 mm) were fabricated in quartz glass and placed on the sample surface and around the focused laser beam. Compared with plasmas generated without the cavity, the spectral emission intensities of plasmas generated with cylindrical cavities were enhanced after several microseconds, and the enhanced emission regions moved to higher locations above the sample with time. Plasma spatial and temporal emission was influenced by cavity diameter. As the diameter increased from 3 to 5 mm, the spectral emission was enhanced later in time and the enhancement became weaker. Plasma spatial and temporal emission was not significantly influenced by cavity height if the cavity was higher than the vapor plume. Shock wave theory was utilized to explain the observed phenomena. C1 [Li, Xiongwei; Wang, Zhe] Tsinghua Univ, Dept Thermal Engn, State Key Lab Power Syst, Tsinghua BP Clean Energy Ctr, Beijing 100084, Peoples R China. [Mao, Xianglei; Russo, Richard E.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. RP Russo, RE (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. EM rerusso@lbl.gov RI Wang, Zhe/E-1705-2011 OI Wang, Zhe/0000-0001-6857-7672 FU U.S. Department of Energy, Office of Basic Energy Sciences, Chemical Science Division at Lawrence Berkeley National Laboratory [2013CB228501]; National Natural Science Foundation of China [51276100]; National Basic Research Program [2013CB228501] FX The research at LBNL was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Chemical Science Division at Lawrence Berkeley National Laboratory under contract number 2013CB228501. Xiongwei Li and Zhe Wang also acknowledge the financial support from the National Natural Science Foundation of China (Grant no. 51276100) and National Basic Research Program (Grant no. 2013CB228501). NR 29 TC 11 Z9 11 U1 3 U2 21 PU ROYAL SOC CHEMISTRY PI CAMBRIDGE PA THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND SN 0267-9477 EI 1364-5544 J9 J ANAL ATOM SPECTROM JI J. Anal. At. Spectrom. PD NOV 1 PY 2014 VL 29 IS 11 BP 2127 EP 2135 DI 10.1039/c4ja00178h PG 9 WC Chemistry, Analytical; Spectroscopy SC Chemistry; Spectroscopy GA AR7IJ UT WOS:000343752600015 ER PT J AU Jacobs, JM Rhodes, M Brown, CW Hood, RR Leight, A Long, W Wood, R AF Jacobs, J. M. Rhodes, M. Brown, C. W. Hood, R. R. Leight, A. Long, W. Wood, R. TI Modeling and forecasting the distribution of Vibrio vulnificus in Chesapeake Bay SO JOURNAL OF APPLIED MICROBIOLOGY LA English DT Article DE Chesapeake Bay; forecasting; modeling; pathogen; Vibrio ID REAL-TIME PCR; NEUSE RIVER ESTUARY; OYSTERS CRASSOSTREA-VIRGINICA; GULF-OF-MEXICO; UNITED-STATES; NORTH-CAROLINA; CHRYSAORA-QUINQUECIRRHA; ENVIRONMENTAL-FACTORS; PROPIDIUM MONOAZIDE; INFECTIOUS-DISEASE AB AimTo construct statistical models to predict the presence, abundance and potential virulence of Vibrio vulnificus in surface waters of Chesapeake Bay for implementation in ecological forecasting systems. Methods and ResultsWe evaluated and applied previously published qPCR assays to water samples (n=1636) collected from Chesapeake Bay from 2007-2010 in conjunction with State water quality monitoring programmes. A variety of statistical techniques were used in concert to identify water quality parameters associated with V.vulnificus presence, abundance and virulence markers in the interest of developing strong predictive models for use in regional oceanographic modeling systems. A suite of models are provided to represent the best model fit and alternatives using environmental variables that allow them to be put to immediate use in current ecological forecasting efforts. ConclusionsEnvironmental parameters such as temperature, salinity and turbidity are capable of accurately predicting abundance and distribution of V.vulnificus in Chesapeake Bay. Forcing these empirical models with output from ocean modeling systems allows for spatially explicit forecasts for up to 48h in the future. Significance and Impact of the StudyThis study uses one of the largest data sets compiled to model Vibrio in an estuary, enhances our understanding of environmental correlates with abundance, distribution and presence of potentially virulent strains and offers a method to forecast these pathogens that may be replicated in other regions. C1 [Jacobs, J. M.; Leight, A.; Wood, R.] NOAA, Natl Ctr Coastal Ocean Sci, Cooperat Oxford Lab, Oxford, MD 21654 USA. [Rhodes, M.] JHT Inc, NOAA, Natl Ctr Coastal Ocean Sci, Cooperat Oxford Lab, Oxford, MD USA. [Brown, C. W.] NOAA, Ctr Satellite Applicat & Res, College Pk, MD USA. [Hood, R. R.; Long, W.] Univ Maryland, Ctr Environm Sci, Horn Point Lab, Cambridge, MD USA. [Long, W.] Pacific NW Natl Lab, Marine Sci Lab, Sequim, WA USA. RP Jacobs, JM (reprint author), NOAA, NOS Cooperat Oxford Lab, 904 South Morris St, Oxford, MD 21654 USA. EM John.Jacobs@NOAA.gov RI Brown, Christopher/B-8213-2008 OI Brown, Christopher/0000-0002-9905-6391 NR 84 TC 1 Z9 1 U1 3 U2 22 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1364-5072 EI 1365-2672 J9 J APPL MICROBIOL JI J. Appl. Microbiol. PD NOV PY 2014 VL 117 IS 5 BP 1312 EP 1327 DI 10.1111/jam.12624 PG 16 WC Biotechnology & Applied Microbiology; Microbiology SC Biotechnology & Applied Microbiology; Microbiology GA AR9DB UT WOS:000343870700010 PM 25139334 ER PT J AU Breen, MS Schultz, BD Sohn, MD Long, T Langstaff, J Williams, R Isaacs, K Meng, QY Stallings, C Smith, L AF Breen, Michael S. Schultz, Bradley D. Sohn, Michael D. Long, Thomas Langstaff, John Williams, Ronald Isaacs, Kristin Meng, Qing Yu Stallings, Casson Smith, Luther TI A review of air exchange rate models for air pollution exposure assessments SO JOURNAL OF EXPOSURE SCIENCE AND ENVIRONMENTAL EPIDEMIOLOGY LA English DT Review DE Air exchange rate models; air pollution; exposure assessment; leakage; natural ventilation; mechanical ventilation ID PARTICULATE MATTER; UNITED-STATES; INFILTRATION; OUTDOOR; WIND; TEMPERATURE; BUILDINGS; INDOOR; VENTILATION; POLLUTANTS AB A critical aspect of air pollution exposure assessments is estimation of the air exchange rate (AER) for various buildings where people spend their time. The AER, which is the rate of exchange of indoor air with outdoor air, is an important determinant for entry of outdoor air pollutants and for removal of indoor-emitted air pollutants. This paper presents an overview and critical analysis of the scientific literature on empirical and physically based AER models for residential and commercial buildings; the models highlighted here are feasible for exposure assessments as extensive inputs are not required. Models are included for the three types of airflows that can occur across building envelopes: leakage, natural ventilation, and mechanical ventilation. Guidance is provided to select the preferable AER model based on available data, desired temporal resolution, types of airflows, and types of buildings included in the exposure assessment. For exposure assessments with some limited building leakage or AER measurements, strategies are described to reduce AER model uncertainty. This review will facilitate the selection of AER models in support of air pollution exposure assessments. C1 [Breen, Michael S.; Schultz, Bradley D.; Williams, Ronald; Isaacs, Kristin] US EPA, Natl Exposure Res Lab, Human Exposure & Atmospher Sci Div, Off Res & Dev, Res Triangle Pk, NC 27711 USA. [Sohn, Michael D.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Dept Energy Anal & Environm Impacts, Berkeley, CA 94720 USA. [Long, Thomas] US EPA, Natl Ctr Environm Assessments, Res Triangle Pk, NC 27711 USA. [Langstaff, John] US EPA, Off Air Qual & Planning Stand, Res Triangle Pk, NC 27711 USA. [Meng, Qing Yu] UMDNJ Sch Publ Hlth, Dept Environm & Occupat Hlth, Piscataway, NJ USA. [Stallings, Casson; Smith, Luther] Alion Sci & Technol Inc, Res Triangle Pk, NC USA. RP Breen, MS (reprint author), US EPA, Natl Exposure Res Lab, Human Exposure & Atmospher Sci Div, Exposure Modeling Res Branch,Off Res & Dev, 109 TW Alexander Dr,Mail E205-02, Res Triangle Pk, NC 27711 USA. EM breen.michael@epa.gov FU U.S. Department of Energy [DE-AC02-05CH11231] FX We thank Jennifer Richmond-Bryant and Vito Ilacqua for review comments and helpful suggestions. Although the manuscript was reviewed by the US Environmental Protection Agency and approved for publication, it may not necessarily reflect official Agency policy. Mention of trade names or commercial products does not constitute endorsement or recommendation for use. Michael Sohn performed this work under Contract No. DE-AC02-05CH11231 with the U.S. Department of Energy. NR 61 TC 9 Z9 9 U1 3 U2 33 PU NATURE PUBLISHING GROUP PI NEW YORK PA 75 VARICK ST, 9TH FLR, NEW YORK, NY 10013-1917 USA SN 1559-0631 EI 1559-064X J9 J EXPO SCI ENV EPID JI J. Expo. Sci. Environ. Epidemiol. PD NOV-DEC PY 2014 VL 24 IS 6 BP 555 EP 563 DI 10.1038/jes.2013.30 PG 9 WC Environmental Sciences; Public, Environmental & Occupational Health; Toxicology SC Environmental Sciences & Ecology; Public, Environmental & Occupational Health; Toxicology GA AS0IJ UT WOS:000343960800002 PM 23715084 ER PT J AU Kohler, S Schoeneberg, U Czeschik, JC Doelken, SC Hehir-Kwa, JY Ibn-Salem, J Mungall, CJ Smedley, D Haendel, MA Robinson, PN AF Koehler, Sebastian Schoeneberg, Uwe Czeschik, Johanna Christina Doelken, Sandra C. Hehir-Kwa, Jayne Y. Ibn-Salem, Jonas Mungall, Christopher J. Smedley, Damian Haendel, Melissa A. Robinson, Peter N. TI Clinical interpretation of CNVs with cross-species phenotype data SO JOURNAL OF MEDICAL GENETICS LA English DT Article ID COPY NUMBER; CONGENITAL-ANOMALIES; HUMAN GENOME; ZEBRAFISH; CYTOSCAPE; STANDARDS; VARIANTS; DISEASE; ACCESS; HEALTH AB Background Clinical evaluation of CNVs identified via techniques such as array comparative genome hybridisation (aCGH) involves the inspection of lists of known and unknown duplications and deletions with the goal of distinguishing pathogenic from benign CNVs. A key step in this process is the comparison of the individual's phenotypic abnormalities with those associated with Mendelian disorders of the genes affected by the CNV. However, because often there is not much known about these human genes, an additional source of data that could be used is model organism phenotype data. Currently, almost 6000 genes in mouse and zebrafish are, when knocked out, associated with a phenotype in the model organism, but no disease is known to be caused by mutations in the human ortholog. Yet, searching model organism databases and comparing model organism phenotypes with patient phenotypes for identifying novel disease genes and medical evaluation of CNVs is hindered by the difficulty in integrating phenotype information across species and the lack of appropriate software tools. Methods Here, we present an integrated ranking scheme based on phenotypic matching, degree of overlap with known benign or pathogenic CNVs and the haploinsufficiency score for the prioritisation of CNVs responsible for a patient's clinical findings. Results We show that this scheme leads to significant improvements compared with rankings that do not exploit phenotypic information. We provide a software tool called PhenogramViz, which supports phenotype-driven interpretation of aCGH findings based on multiple data sources, including the integrated cross-species phenotype ontology Uberpheno, in order to visualise gene-to-phenotype relations. Conclusions Integrating and visualising cross-species phenotype information on the affected genes may help in routine diagnostics of CNVs. C1 [Koehler, Sebastian; Doelken, Sandra C.; Robinson, Peter N.] Charite, Inst Med Genet & Human Genet, D-13353 Berlin, Germany. [Koehler, Sebastian; Robinson, Peter N.] Berlin Brandenburg Ctr Regenerat Therapies BCRT, Berlin, Germany. [Schoeneberg, Uwe] Free Univ Berlin, Fdn Inst Mol Biol & Bioinformat, Berlin, Germany. [Czeschik, Johanna Christina] Univ Duisburg Essen, Univ Klinikum Essen, Inst Humangenet, Essen, Germany. [Hehir-Kwa, Jayne Y.] Radboud Univ Nijmegen, Med Ctr, Dept Human Genet, Nijmegen, Netherlands. [Mungall, Christopher J.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. [Smedley, Damian] Wellcome Trust Genome Campus, Wellcome Trust Sanger Inst, Hinxton, Cambs, England. [Haendel, Melissa A.] Oregon Hlth & Sci Univ, Dept Med Informat & Epidemiol, Portland, OR 97201 USA. [Haendel, Melissa A.] Oregon Hlth & Sci Univ, OHSU Lib, Portland, OR 97201 USA. [Robinson, Peter N.] Max Planck Inst Mol Genet, D-14195 Berlin, Germany. [Robinson, Peter N.] Free Univ Berlin, Inst Bioinformat, Dept Math & Comp Sci, Berlin, Germany. RP Kohler, S (reprint author), Charite, Inst Med Genet & Human Genet, Augustenburger Pl 1, D-13353 Berlin, Germany. EM sebastian.koehler@charite.de RI Hehir, g. J.Y./L-4358-2015; OI Ibn-Salem, Jonas/0000-0001-9886-113X; Kohler, Sebastian/0000-0002-5316-1399 FU Bundesministerium fuer Bildung und Forschung (BMBF) [0313911]; European Community [602300]; National Institutes of Health (NIH Office of the Director Grant) [5R24OD011883] FX The project was funded by grants of the Bundesministerium fuer Bildung und Forschung (BMBF project number 0313911) and the European Community's Seventh Framework Programme (Grant Agreement 602300; SYBIL). Further support was provided by the National Institutes of Health (NIH Office of the Director Grant #5R24OD011883). NR 33 TC 7 Z9 7 U1 0 U2 5 PU BMJ PUBLISHING GROUP PI LONDON PA BRITISH MED ASSOC HOUSE, TAVISTOCK SQUARE, LONDON WC1H 9JR, ENGLAND SN 0022-2593 EI 1468-6244 J9 J MED GENET JI J. Med. Genet. PD NOV PY 2014 VL 51 IS 11 BP 766 EP 772 DI 10.1136/jmedgenet-2014-102633 PG 7 WC Genetics & Heredity SC Genetics & Heredity GA AR9ET UT WOS:000343875900007 PM 25280750 ER PT J AU Gardeux, V Achour, I Li, JR Maienschein-Cline, M Li, HQ Pesce, L Parinandi, G Bahroos, N Winn, R Foster, I Garcia, JGN Lussier, YA AF Gardeux, Vincent Achour, Ikbel Li, Jianrong Maienschein-Cline, Mark Li, Haiquan Pesce, Lorenzo Parinandi, Gurunadh Bahroos, Neil Winn, Robert Foster, Ian Garcia, Joe G. N. Lussier, Yves A. TI 'N-of-1-pathways' unveils personal deregulated mechanisms from a single pair of RNA-Seq samples: towards precision medicine SO JOURNAL OF THE AMERICAN MEDICAL INFORMATICS ASSOCIATION LA English DT Article ID GENOME-WIDE ASSOCIATION; LUNG ADENOCARCINOMA; CLINICAL-TRIALS; CANCER; CLASSIFICATION; DISEASE; BREAST; MICROARRAYS; EXPRESSION; PREDICTION AB Background The emergence of precision medicine allowed the incorporation of individual molecular data into patient care. Indeed, DNA sequencing predicts somatic mutations in individual patients. However, these genetic features overlook dynamic epigenetic and phenotypic response to therapy. Meanwhile, accurate personal transcriptome interpretation remains an unmet challenge. Further, N-of-1 (single-subject) efficacy trials are increasingly pursued, but are underpowered for molecular marker discovery. Method 'N-of-1-pathways' is a global framework relying on three principles: (i) the statistical universe is a single patient; (ii) significance is derived from geneset/biomodules powered by paired samples from the same patient; and (iii) similarity between genesets/biomodules assesses commonality and differences, within-study and cross-studies. Thus, patient gene-level profiles are transformed into deregulated pathways. From RNA-Seq of 55 lung adenocarcinoma patients, N-of-1-pathways predicts the deregulated pathways of each patient. Results Cross-patient N-of-1-pathways obtains comparable results with conventional genesets enrichment analysis (GSEA) and differentially expressed gene (DEG) enrichment, validated in three external evaluations. Moreover, heatmap and star plots highlight both individual and shared mechanisms ranging from molecular to organ-systems levels (eg, DNA repair, signaling, immune response). Patients were ranked based on the similarity of their deregulated mechanisms to those of an independent gold standard, generating unsupervised clusters of diametric extreme survival phenotypes (p= 0.03). Conclusions The N-of-1-pathways framework provides a robust statistical and relevant biological interpretation of individual disease-free survival that is often overlooked in conventional cross-patient studies. It enables mechanism-level classifiers with smaller cohorts as well as N-of-1 studies. C1 [Gardeux, Vincent; Achour, Ikbel; Li, Jianrong; Li, Haiquan; Garcia, Joe G. N.; Lussier, Yves A.] Univ Arizona, Dept Med, Inst Bio5, UA Canc Ctr, Tucson, AZ 85721 USA. [Gardeux, Vincent; Achour, Ikbel; Li, Jianrong; Li, Haiquan; Parinandi, Gurunadh; Winn, Robert; Lussier, Yves A.] Univ Illinois, Dept Med, Chicago, IL USA. [Gardeux, Vincent] EISTI, Dept Med, Sch Engn, Cergy Pontoise, France. [Gardeux, Vincent; Achour, Ikbel; Li, Jianrong; Maienschein-Cline, Mark; Li, Haiquan; Parinandi, Gurunadh; Bahroos, Neil; Lussier, Yves A.] Univ Illinois, Inst Translat Hlth Informat, Chicago, IL USA. [Pesce, Lorenzo; Foster, Ian; Lussier, Yves A.] Argonne Natl Lab, Computat Inst, Chicago, IL USA. [Pesce, Lorenzo; Foster, Ian] Univ Chicago, Chicago, IL 60637 USA. [Winn, Robert; Lussier, Yves A.] Univ Chicago, Ctr Canc, Chicago, IL 60637 USA. [Foster, Ian] Univ Chicago, Dept Comp Sci, Chicago, IL 60637 USA. [Foster, Ian] Argonne Natl Lab, Math & Comp Sci Div, Chicago, IL USA. [Lussier, Yves A.] Univ Illinois, Dept Bioengn, Chicago, IL USA. [Lussier, Yves A.] Univ Illinois, Coll Pharm, Dept Biopharmaceut Sci, Chicago, IL USA. [Lussier, Yves A.] Univ Chicago, Inst Genom & Syst Biol, Chicago, IL 60637 USA. [Lussier, Yves A.] Univ Illinois, Dept Pharmacol, Chicago, IL USA. RP Lussier, YA (reprint author), Univ Arizona, 1657 E Helen St,251 POB 210240, Tucson, AZ 85721 USA. EM yves@email.arizona.edu RI Gardeux, Vincent/O-9653-2016; OI Gardeux, Vincent/0000-0001-8954-2161; Li, Haiquan/0000-0002-8049-0278; Lussier, Yves/0000-0001-9854-1005 FU NIH [UL1TR000050, 1S10RR029030- 01, K22LM008308]; University of Illinois Cancer Center FX The study was supported in part by NIH grants UL1TR000050 (University of Illinois CTSA), 1S10RR029030- 01 (BEAGLE Cray Supercomputer), and K22LM008308, and the University of Illinois Cancer Center. NR 38 TC 5 Z9 5 U1 0 U2 7 PU BMJ PUBLISHING GROUP PI LONDON PA BRITISH MED ASSOC HOUSE, TAVISTOCK SQUARE, LONDON WC1H 9JR, ENGLAND SN 1067-5027 EI 1527-974X J9 J AM MED INFORM ASSN JI J. Am. Med. Inf. Assoc. PD NOV PY 2014 VL 21 IS 6 BP 1015 EP 1025 DI 10.1136/amiajnl-2013-002519 PG 11 WC Computer Science, Information Systems; Computer Science, Interdisciplinary Applications; Health Care Sciences & Services; Information Science & Library Science; Medical Informatics SC Computer Science; Health Care Sciences & Services; Information Science & Library Science; Medical Informatics GA AR7RJ UT WOS:000343776700012 PM 25301808 ER PT J AU Garimella, SVB Ibrahim, YM Webb, IK Tolmachev, AV Zhang, XY Prost, SA Anderson, GA Smith, RD AF Garimella, Sandilya V. B. Ibrahim, Yehia M. Webb, Ian K. Tolmachev, Aleksey V. Zhang, Xinyu Prost, Spencer A. Anderson, Gordon A. Smith, Richard D. TI Simulation of Electric Potentials and Ion Motion in Planar Electrode Structures for Lossless Ion Manipulations (SLIM) SO JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY LA English DT Article DE Gas phase ions; Lossless manipulations; Ion trajectory simulations; Ion mobility; Resolving power ID DC COLLISIONAL ACTIVATION; MASS-SPECTROMETRY; MOBILITY SPECTROMETRY; FUNNEL TRAP; ION/ION REACTIONS; RF-CARPET; INTERFACE; ION/MOLECULE; INSTRUMENT; THROUGHPUT AB We report a conceptual study and computational evaluation of novel planar electrode structures for lossless ion manipulations (SLIM). Planar electrode SLIM components were designed that allow for flexible ion confinement, transport, and storage using a combination of radio frequency (rf) and DC fields. Effective potentials can be generated that provide near ideal regions for confining and manipulating ions in the presence of a gas. Ion trajectory simulations using SIMION 8.1 demonstrated the capability for lossless ion motion in these devices over a wide m/z range and a range of electric fields at low pressures (e.g., a few Torr). More complex ion manipulations (e.g., turning ions by 90(o) and dynamically switching selected ion species into orthogonal channels) are also shown feasible. The performance of SLIM devices at similar to 4 Torr pressure for performing ion mobility-based separations (IMS) is computationally evaluated and compared with initial experimental results, and both are also shown to agree closely with experimental and theoretical IMS performance for a conventional drift tube design. C1 [Garimella, Sandilya V. B.; Ibrahim, Yehia M.; Webb, Ian K.; Tolmachev, Aleksey V.; Zhang, Xinyu; Prost, Spencer A.; Anderson, Gordon A.; Smith, Richard D.] Pacific NW Natl Lab, Div Biol Sci, Richland, WA 99352 USA. RP Smith, RD (reprint author), Pacific NW Natl Lab, Div Biol Sci, POB 999, Richland, WA 99352 USA. EM rds@pnnl.gov RI Smith, Richard/J-3664-2012; OI Smith, Richard/0000-0002-2381-2349; Garimella, Sandilya Venkata Bhaskara/0000-0001-6649-9842 FU National Institutes of Health (NIH) NIGMS [P41GM103493, R21 GM103497]; Department of Energy Office of Biological and Environmental Research Genome Sciences Program through the 'Pan-omics' project at the Pacific Northwest National Laboratory (PNNL); Laboratory Directed Research and Development program at the PNNL FX Portions of this research were supported by the National Institutes of Health (NIH) NIGMS grants P41GM103493 (R.D.S.), R21 GM103497 (Y.M.I.), by the Department of Energy Office of Biological and Environmental Research Genome Sciences Program through the 'Pan-omics' project at the Pacific Northwest National Laboratory (PNNL), and the Laboratory Directed Research and Development program at the PNNL. Work was performed in the Environmental Molecular Sciences Laboratory (EMSL), a DOE national scientific user facility at PNNL. NR 38 TC 17 Z9 17 U1 1 U2 23 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1044-0305 EI 1879-1123 J9 J AM SOC MASS SPECTR JI J. Am. Soc. Mass Spectrom. PD NOV PY 2014 VL 25 IS 11 BP 1890 EP 1896 DI 10.1007/s13361-014-0976-y PG 7 WC Biochemical Research Methods; Chemistry, Analytical; Chemistry, Physical; Spectroscopy SC Biochemistry & Molecular Biology; Chemistry; Spectroscopy GA AR9NO UT WOS:000343902100008 PM 25257188 ER PT J AU Shvartsburg, AA Ibrahim, YM Smith, RD AF Shvartsburg, Alexandre A. Ibrahim, Yehia M. Smith, Richard D. TI Differential Ion Mobility Separations in up to 100% Helium Using Microchips (vol 25, pg 480, 2014) SO JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY LA English DT Correction C1 [Shvartsburg, Alexandre A.; Ibrahim, Yehia M.; Smith, Richard D.] Pacific NW Natl Lab, Div Biol Sci, Richland, WA 99352 USA. RP Shvartsburg, AA (reprint author), Pacific NW Natl Lab, Div Biol Sci, POB 999, Richland, WA 99352 USA. EM alexandre.shvartsburg@pnnl.gov RI Smith, Richard/J-3664-2012 OI Smith, Richard/0000-0002-2381-2349 NR 1 TC 0 Z9 0 U1 2 U2 6 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1044-0305 EI 1879-1123 J9 J AM SOC MASS SPECTR JI J. Am. Soc. Mass Spectrom. PD NOV PY 2014 VL 25 IS 11 BP 1995 EP 1995 DI 10.1007/s13361-014-0984-y PG 1 WC Biochemical Research Methods; Chemistry, Analytical; Chemistry, Physical; Spectroscopy SC Biochemistry & Molecular Biology; Chemistry; Spectroscopy GA AR9NO UT WOS:000343902100020 ER PT J AU Webb, IK Chen, TC Danielson, WF Ibrahim, YM Tang, K Anderson, GA Smith, RD AF Webb, Ian K. Chen, Tsung-Chi Danielson, William F., III Ibrahim, Yehia M. Tang, Keqi Anderson, Gordon A. Smith, Richard D. TI Implementation of Dipolar Resonant Excitation for Collision Induced Dissociation with Ion Mobility/Time-of-Flight MS (vol 25, pg 563, 2014) SO JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY LA English DT Correction C1 [Smith, Richard D.] Pacific NW Natl Lab, Div Biol Sci, Richland, WA 99352 USA. Pacific NW Natl Lab, Environm Mol Sci Lab, Richland, WA 99352 USA. RP Smith, RD (reprint author), Pacific NW Natl Lab, Div Biol Sci, Richland, WA 99352 USA. EM rds@pnnl.gov RI Smith, Richard/J-3664-2012 OI Smith, Richard/0000-0002-2381-2349 NR 1 TC 0 Z9 0 U1 0 U2 2 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1044-0305 EI 1879-1123 J9 J AM SOC MASS SPECTR JI J. Am. Soc. Mass Spectrom. PD NOV PY 2014 VL 25 IS 11 BP 1996 EP 1996 DI 10.1007/s13361-014-0985-x PG 1 WC Biochemical Research Methods; Chemistry, Analytical; Chemistry, Physical; Spectroscopy SC Biochemistry & Molecular Biology; Chemistry; Spectroscopy GA AR9NO UT WOS:000343902100021 ER PT J AU Youinou, GJ Sen, RS AF Youinou, Gilles J. Sen, R. Sonat TI IMPACT OF ACCIDENT-TOLERANT FUELS AND CLADDINGS ON THE OVERALL FUEL CYCLE: A PRELIMINARY SYSTEMS ANALYSIS SO NUCLEAR TECHNOLOGY LA English DT Article DE accident-tolerant fuel; accident-tolerant cladding; light water reactor AB This paper presents a preliminary systems analysis related to most of the currently proposed enhanced accident-tolerant fuel and cladding concepts: fully ceramic microencapsulated fuels, uranium-molybdenum fuels, uranium-nitride fuels, uranium silicide fuels, silicon carbide cladding, advanced steel cladding, and molybdenum cladding. The benefits drawn from the implementation of demonstrated accident-tolerant fuels on the future development of nuclear energy generation as well as public acceptance are difficult to quantify but would probably be very significant. The potential impacts of these innovative light water reactor fuels on the front end of the fuel cycle, on the reactor operation, and on the back end of the fuel cycle are succinctly described. C1 [Youinou, Gilles J.; Sen, R. Sonat] Idaho Natl Lab, Nucl Syst Design & Anal Div, Idaho Falls, ID 83415 USA. RP Youinou, GJ (reprint author), Idaho Natl Lab, Nucl Syst Design & Anal Div, POB 1625,MS 3860, Idaho Falls, ID 83415 USA. EM gilles.youinou@inl.gov FU Idaho National Laboratory for the U.S. Department of Energy (DOE) [DE-AC07-05ID14517] FX This paper was prepared at the Idaho National Laboratory for the U.S. Department of Energy (DOE) under contract DE-AC07-05ID14517. This work was prepared for the DOE Fuel Cycle Options Campaign. NR 19 TC 3 Z9 3 U1 3 U2 29 PU AMER NUCLEAR SOC PI LA GRANGE PK PA 555 N KENSINGTON AVE, LA GRANGE PK, IL 60526 USA SN 0029-5450 EI 1943-7471 J9 NUCL TECHNOL JI Nucl. Technol. PD NOV PY 2014 VL 188 IS 2 BP 123 EP 138 PG 16 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS0GT UT WOS:000343956800002 ER PT J AU Radulescu, G Gauld, IC Ilas, G Wagner, JC AF Radulescu, Georgeta Gauld, Ian C. Ilas, Germina Wagner, John C. TI APPROACH FOR VALIDATING ACTINIDE AND FISSION PRODUCT COMPOSITIONS FOR BURNUP CREDIT CRITICALITY SAFETY ANALYSES SO NUCLEAR TECHNOLOGY LA English DT Article DE depletion; criticality; validation ID ANALYSIS CAPABILITIES; SCALE 6 AB This paper describes a depletion code validation approach for criticality safety analysis using burnup credit for actinide and fission product nuclides in spent nuclear fuel (SNF) compositions. The technical basis for determining the uncertainties in the calculated nuclide concentrations is comparison of calculations to available measurements obtained from destructive radiochemical assay of SNF samples. Probability distributions developed for the uncertainties in the calculated nuclide concentrations were applied to the SNF compositions of criticality safety analysis models by the use of a Monte Carlo uncertainty sampling method to determine bias and bias uncertainty in the effective neutron multiplication factor. Application of the Monte Carlo uncertainty sampling approach is demonstrated for representative criticality safety analysis models of pressurized water reactor spent fuel pool storage racks and transportation packages using burnup-dependent nuclide concentrations calculated with Standardized Computer Analyses for Licensing Evaluation (SCALE) 6.1 and the Evaluated Nuclear Data File/B (ENDF/B) Version VII nuclear data. The validation approach and results support a recent revision of the U.S. Nuclear Regulatory Commission Interim Staff Guidance (ISG)-8. C1 [Radulescu, Georgeta; Gauld, Ian C.; Ilas, Germina; Wagner, John C.] Oak Ridge Natl Lab, Reactor & Nucl Syst Div, Oak Ridge, TN 37831 USA. RP Radulescu, G (reprint author), Oak Ridge Natl Lab, Reactor & Nucl Syst Div, POB 2008,Bldg 5700, Oak Ridge, TN 37831 USA. EM radulescug@ornl.gov RI Wagner, John/K-3644-2015; OI Wagner, John/0000-0003-0257-4502; Radulescu, Georgeta/0000-0001-7664-1718; Gauld, Ian/0000-0002-3893-7515 FU U.S. Department of Energy [DE-AC05-00OR22725] FX This manuscript has been authored by Oak Ridge National Laboratory, managed by UT-Battelle, LLC, under contract DE-AC05-00OR22725 with the U.S. Department of Energy. The work presented in this paper was performed under contract with the Office of Nuclear Regulatory Research, NRC. This paper was prepared with support provided by the NRC Office of Nuclear Material Safety and Safeguards (NMSS). The authors gratefully acknowledge useful review comments and suggestions provided by D. Algama, the NRC Project Manager; K. A. Wood of the Office of Nuclear Reactor Regulation; M. Aissa and R. Y. Lee of the Office of Nuclear Research; M. Rahimi, A. B. Barto, and Z. Li of NMSS; and C. N. Van Wert and A. Patel of the Office of New Reactors. NR 41 TC 1 Z9 1 U1 0 U2 5 PU AMER NUCLEAR SOC PI LA GRANGE PK PA 555 N KENSINGTON AVE, LA GRANGE PK, IL 60526 USA SN 0029-5450 EI 1943-7471 J9 NUCL TECHNOL JI Nucl. Technol. PD NOV PY 2014 VL 188 IS 2 BP 154 EP 171 PG 18 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS0GT UT WOS:000343956800004 ER PT J AU Hunier, SR Lavrik, NV Datskos, PG Clayton, D AF Hunier, Scott R. Lavrik, Nickolay V. Datskos, Panos G. Clayton, Dwight TI PYROELECTRIC ENERGY SCAVENGING TECHNIQUES FOR SELF-POWERED NUCLEAR REACTOR WIRELESS SENSOR NETWORKS SO NUCLEAR TECHNOLOGY LA English DT Article DE energy harvesting; pyroelectric; wireless ID HARVESTING WASTE HEAT; ELECTRICAL ENERGY; CONVERSION; CONVERTER; COPOLYMER; OPTIMIZATION; SIMULATIONS; P(VDF-TRFE); HYSTERESIS; EFFICIENCY AB Recent advances in technologies for harvesting waste thermal energy from ambient environments present an opportunity to implement truly wireless sensor nodes in nuclear power plants. These sensors could continue to operate during extended station blackouts and during periods when operation of the plant's internal power distribution system has been disrupted. The energy required to power the wireless sensors must be generated using energy harvesting techniques from locally available energy sources, and the energy consumption within the sensor circuitry must therefore be low to minimize power and hence the size requirements of the energy harvester. Harvesting electrical energy from thermal energy sources can be achieved using pyroelectric or thermoelectric conversion techniques. Recent modeling and experimental studies have shown that pyroelectric in techniques can be cost-competitive with thermoelectrics in self-powered wireless sensor applications and, using new temperature cycling techniques, have the potential to be several times as efficient as thermoelectrics under comparable operating conditions. The development of a new thermal energy harvester concept, based on temperature cycled pyroelectric thermal-to-electrical energy conversion, is outlined. This paper outlines the modeling of cantilever and pyroelectric structures and single-element devices that demonstrate the potential of this technology for the development of high-efficiency thermal-to-electrical energy conversion devices. C1 [Hunier, Scott R.; Lavrik, Nickolay V.; Datskos, Panos G.; Clayton, Dwight] Oak Ridge Natl Lab, Measurement Sci & Syst Engn Div, Oak Ridge, TN 37831 USA. [Lavrik, Nickolay V.] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci Div, Oak Ridge, TN 37831 USA. RP Hunier, SR (reprint author), Oak Ridge Natl Lab, Measurement Sci & Syst Engn Div, POB 2008, Oak Ridge, TN 37831 USA. EM huntersr@ornl.gov RI Lavrik, Nickolay/B-5268-2011 OI Lavrik, Nickolay/0000-0002-9543-5634 FU Laboratory Directed Research and Development program at Oak Ridge National Laboratory (ORNL) [DE-AC05-00OR22725]; Scientific User Facilities Division, Office of Basic Energy Sciences, DOE FX This research was sponsored by the Laboratory Directed Research and Development program at Oak Ridge National Laboratory (ORNL), managed and operated by UT-Battelle, LLC, for the U.S. Department of Energy (DOE) under contract DE-AC05-00OR22725. A portion of this research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at ORNL by the Scientific User Facilities Division, Office of Basic Energy Sciences, DOE. NR 40 TC 2 Z9 2 U1 0 U2 12 PU AMER NUCLEAR SOC PI LA GRANGE PK PA 555 N KENSINGTON AVE, LA GRANGE PK, IL 60526 USA SN 0029-5450 EI 1943-7471 J9 NUCL TECHNOL JI Nucl. Technol. PD NOV PY 2014 VL 188 IS 2 BP 172 EP 184 PG 13 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS0GT UT WOS:000343956800005 ER PT J AU Conlin, JL Parsons, DK Gardiner, SJ Gray, M Kahler, AC Lee, MB While, MC AF Conlin, Jeremy Lloyd Parsons, D. Kent Gardiner, Steven J. Gray, Mark Kahler, A. C. Lee, M. Beth While, Morgan C. TI VERIFICATION AND VALIDATION OF THE ENDF/B-VII.1-BASED CONTINUOUS-ENERGY DATA TABLES FOR MCNP6 SO NUCLEAR TECHNOLOGY LA English DT Article DE Monte Carlo; ENDF/B-VII.1; nuclear data ID NUCLEAR-SCIENCE; TECHNOLOGY; LIBRARY AB In December 2011, the National Nuclear Data Center released ENDF/B-VII.1, the "latest recommended evaluated nuclear data file for use in nuclear science and technology applications." The data were released in the standard Evaluated Nuclear Data Format (ENDF). This release represents the advances made in nuclear data during the 5 years since the release of ENDF/B-VII.0. The Nuclear Data Team at Los Alamos National Laboratory has processed the ENDF/B-VII.1 library and made available a library of ACE data tables at several temperatures for each of the ENDF/B files. The ACE data library is called ENDF71x and is available through the Radiation Safety Information Computational Center with MCNP6. The files can also be used with MCNP5 or other Monte Carlo codes. C1 [Conlin, Jeremy Lloyd; Parsons, D. Kent; Gardiner, Steven J.; Gray, Mark; Kahler, A. C.; Lee, M. Beth; While, Morgan C.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. RP Conlin, JL (reprint author), Los Alamos Natl Lab, POB 1663,MS F663, Los Alamos, NM 87545 USA. EM jlconlin@lanl.gov NR 11 TC 0 Z9 0 U1 0 U2 0 PU AMER NUCLEAR SOC PI LA GRANGE PK PA 555 N KENSINGTON AVE, LA GRANGE PK, IL 60526 USA SN 0029-5450 EI 1943-7471 J9 NUCL TECHNOL JI Nucl. Technol. PD NOV PY 2014 VL 188 IS 2 BP 218 EP 227 PG 10 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AS0GT UT WOS:000343956800009 ER PT J AU Casillas-Trujillo, L Andersson, DA Dorado, B Nikl, M Sickafus, KE McClellan, KJ Stanek, CR AF Casillas-Trujillo, L. Andersson, D. A. Dorado, B. Nikl, M. Sickafus, K. E. McClellan, K. J. Stanek, C. R. TI Intrinsic defects, nonstoichiometry, and aliovalent doping of A(2+)B(4)+O-3 perovskite scintillators SO PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS LA English DT Article DE atomistic simulation; defects; nonstoichiometry; perovskites; scintillators ID TEMPERATURE PHASE-TRANSITIONS; NEUTRON POWDER DIFFRACTION; DOPED BARIUM ZIRCONATE; CRYSTAL-STRUCTURES; LATTICE-DYNAMICS; SRHFO3; HAFNATE; SRZRO3; OXIDES; LUMINESCENCE AB We have employed a range of atomistic simulation methods to explore aspects defect chemistry in ABO; (where A(2+) =Ba2+ or Sr2+, and B4+ = zr(4+) or Hf4+) perovskites. placing emphasis Oil processes relevant for application of these materials iis high performance scintillittors. Specifically. vie examined intrinsic defect. reactions. A :Ind k excess nonstoichiometry :Ind the solution of Nile rare earth cations. As has predicted in previous studies. we MkI that Schottl:y disorder is the lowest energy intrinsic process. kg nonstoichitimetry. we predict that Ao-excess is compensated by- oxygen x-aciincies aid 2excess is charge compensated by A (SCC Zibslracl figure). Finally. for Me" solution. WC considered seyeral reactions for Me' cations ranging in size from to lu and the preferred reaction depends on the specific Me' cation;Ind xvhether or not phase seperation occurs C1 [Casillas-Trujillo, L.; Sickafus, K. E.] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA. [Andersson, D. A.; Dorado, B.; McClellan, K. J.; Stanek, C. R.] Los Alamos Natl Lab, Div Mat Sci & Technol, Los Alamos, NM 87545 USA. [Dorado, B.] CEA, DAM, DIF, F-91297 Arpajon, France. [Nikl, M.] Acad Sci Czech Republic, Inst Phys, Prague 16253, Czech Republic. RP Stanek, CR (reprint author), Los Alamos Natl Lab, Div Mat Sci & Technol, Los Alamos, NM 87545 USA. EM stanek@lanl.gov NR 71 TC 4 Z9 4 U1 1 U2 31 PU WILEY-V C H VERLAG GMBH PI WEINHEIM PA POSTFACH 101161, 69451 WEINHEIM, GERMANY SN 0370-1972 EI 1521-3951 J9 PHYS STATUS SOLIDI B JI Phys. Status Solidi B-Basic Solid State Phys. PD NOV PY 2014 VL 251 IS 11 BP 2279 EP 2286 DI 10.1002/pssb.201451064 PG 8 WC Physics, Condensed Matter SC Physics GA AS6GP UT WOS:000344362700021 ER PT J AU Kanevce, A Levi, DH Kuciauskas, D AF Kanevce, A. Levi, D. H. Kuciauskas, D. TI The role of drift, diffusion, and recombination in time-resolved photoluminescence of CdTe solar cells determined through numerical simulation SO PROGRESS IN PHOTOVOLTAICS LA English DT Article DE CdTe; photoluminescence; numerical simulations AB Time-resolved photoluminescence (TRPL) measurements are one of the key metrics available to determine the minority-carrier lifetime in the absorber layer of direct band gap photovoltaic devices. Direct measurement of the minority-carrier lifetime is essential to understanding the impact of changes in deposition and processing on material quality. Unfortunately, the TRPL signal is determined by a complex convolution of multiple physical factors including bulk carrier lifetime, interface recombination velocity, electric field, doping density, photo-excited carrier density, and carrier mobility. To gain clarity, we have used numerical simulations to analyze the carrier dynamics after a CdTe device is illuminated with a short light pulse. After the light pulse, the photo-generated carriers undergo complex dynamics including drift, diffusion, interface, and bulk recombination. In this work, we develop a new formalism that enables much greater insight into which factors dominate the TRPL decay dynamics. By breaking down the carrier dynamics into drift, diffusion, and recombination terms, we have developed six-factor, four-factor, and two-factor analyses that provide clear understanding of which physical factors dominate the decay dynamics under various conditions and at different times during the decay. We show that in a typical CdTe device under the typical experimental conditions used in our laboratories, the faster part of the decay is dominated by charge separation, whereas the slower part is dominated by carrier recombination. Therefore, under the conditions investigated in this study, the slower part of the decay is a better parameter to explain the defect density in the CdTe layer. Copyright (c) 2013 John Wiley & Sons, Ltd. C1 [Kanevce, A.; Levi, D. H.; Kuciauskas, D.] Natl Renewable Energy Lab, Golden, CO 80401 USA. RP Kanevce, A (reprint author), Natl Renewable Energy Lab, Golden, CO 80401 USA. EM Ana.Kanevce@nrel.gov FU US Department of Energy [DE-AC36-08-GO28308]; National Renewable Energy Laboratory FX The authors wish to acknowledge valuable discussions regarding the nature of TRPL decays in CdTe devices with Timothy A. Gessert and David S. Albin of the NREL. This work was supported by the US Department of Energy under Contract No. DE-AC36-08-GO28308 with the National Renewable Energy Laboratory. This paper is subject to government rights. NR 18 TC 23 Z9 23 U1 4 U2 46 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1062-7995 EI 1099-159X J9 PROG PHOTOVOLTAICS JI Prog. Photovoltaics PD NOV PY 2014 VL 22 IS 11 BP 1138 EP 1146 DI 10.1002/pip.2369 PG 9 WC Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied SC Energy & Fuels; Materials Science; Physics GA AR7JH UT WOS:000343755000004 ER PT J AU Kempe, MD Dameron, AA Reese, MO AF Kempe, Michael D. Dameron, Arrelaine A. Reese, Matthew O. TI Evaluation of moisture ingress from the perimeter of photovoltaic modules SO PROGRESS IN PHOTOVOLTAICS LA English DT Article DE photovoltaic; edge-seal; moisture; humidity; polyisobutylene; desiccant; encapsulant ID DIFFUSION TIME LAG; WATER-VAPOR; SOLAR-CELLS; POLYISOBUTYLENE; TEMPERATURE; STABILITY; SORPTION; SYSTEMS; TESTS; FILM AB Many thin film photovoltaic (PV) technologies can be sensitive to corrosion induced by the presence of water vapor in the packaging materials. Typically impermeable front and backsheets are used in conjunction with an edge-seal around the perimeter to prevent water vapor ingress. These edge-seal materials are often made of a polyisobutylene resin filled with desiccant, which dramatically increases the time for moisture to reach sensitive module components. While edge-seals can prevent moisture ingress, even the lowest diffusivity transparent encapsulant materials are insufficient for the lifetime of a module. To evaluate the performance of edge-seal and encapsulant materials in a manner that simulates their function in a PV module, an optical method was devised where ingress is detected by reaction of a Ca film with water. Using this method, we have exposed test samples to heat and humidity allowing quantitative comparison of different edge-seal and encapsulant materials. Next, we use measurements of polymer diffusivity and solubility to evaluate the ability to model this moisture ingress. Here, we find good agreement between these two methods highlighting the much greater ability of polyisobutylene materials to keep moisture out as compared with typical encapsulant materials used in the PV industry. Copyright (c) 2013 John Wiley & Sons, Ltd. C1 [Kempe, Michael D.; Dameron, Arrelaine A.; Reese, Matthew O.] NREL, Golden, CO 80401 USA. RP Kempe, MD (reprint author), NREL, Golden, CO 80401 USA. EM michael.kempe@nrel.gov FU US Department of Energy [DOE-AC36-08GO28308]; National Renewable Energy Laboratory FX The Authors would like to acknowledge the help of Sarah Kurtz, David Miller, Calvin Curtis, Kent Terwilliger, Thomas Moricone, Joshua Martin, and Tom Gennett. This work was supported by the US Department of Energy under Contract No. DOE-AC36-08GO28308 with the National Renewable Energy Laboratory. NR 32 TC 14 Z9 14 U1 2 U2 29 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1062-7995 EI 1099-159X J9 PROG PHOTOVOLTAICS JI Prog. Photovoltaics PD NOV PY 2014 VL 22 IS 11 BP 1159 EP 1171 DI 10.1002/pip.2374 PG 13 WC Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied SC Energy & Fuels; Materials Science; Physics GA AR7JH UT WOS:000343755000006 ER PT J AU Liang, R Shterengas, L Hosoda, T Stein, A Lu, M Kipshidze, G Belenky, G AF Liang, Rui Shterengas, Leon Hosoda, Takashi Stein, Aaron Lu, Ming Kipshidze, Gela Belenky, Gregory TI Diffraction limited 3.15 mu m cascade diode lasers SO SEMICONDUCTOR SCIENCE AND TECHNOLOGY LA English DT Article DE diffraction limited; cascade; diode lasers; type-I; quantum well; GaSb ID GASB; GAIN AB Cascade GaSb-based type-I quantum well diode lasers emitting near 3.15 mu m were designed and fabricated. The efficient carrier recycling between stages was confirmed by twofold increase of the efficiency of two-stage cascade laser as compared to reference single-stage devices. Narrow ridge cascade lasers generated more than 40 mW of continuous-wave output power in diffraction limited beam at room temperature. C1 [Liang, Rui; Shterengas, Leon; Hosoda, Takashi; Kipshidze, Gela; Belenky, Gregory] SUNY Stony Brook, Dept ECE, Stony Brook, NY 11794 USA. [Stein, Aaron; Lu, Ming] Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11973 USA. RP Liang, R (reprint author), SUNY Stony Brook, Dept ECE, Stony Brook, NY 11794 USA. EM leon.shterengas@stonybrook.edu RI Liang, Rui/A-7968-2012 OI Liang, Rui/0000-0001-5833-2292 FU US Army Research Office [W911NF1110109]; Air Force Office of Scientific Research [FA95501110136]; US Department of Energy, Office of Basic Energy Sciences [DE-AC02-98CH10886] FX This work was supported by US Army Research Office, Grant W911NF1110109 and Air Force Office of Scientific Research, Grant FA95501110136. Research carried out in part at the Center for Functional Nanomaterials, Brookhaven National Laboratory, which is supported by the US Department of Energy, Office of Basic Energy Sciences, under Contract No. DE-AC02-98CH10886. NR 13 TC 4 Z9 4 U1 0 U2 10 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0268-1242 EI 1361-6641 J9 SEMICOND SCI TECH JI Semicond. Sci. Technol. PD NOV PY 2014 VL 29 IS 11 AR 115016 DI 10.1088/0268-1242129/11/115016 PG 6 WC Engineering, Electrical & Electronic; Materials Science, Multidisciplinary; Physics, Condensed Matter SC Engineering; Materials Science; Physics GA AS0YS UT WOS:000344003300019 ER PT J AU Rumyantsev, SL Levinshtein, ME Saxena, T Shur, MS Cheng, L Palmour, JW Agarwal, A AF Rumyantsev, S. L. Levinshtein, M. E. Saxena, T. Shur, M. S. Cheng, L. Palmour, J. W. Agarwal, A. TI Optical triggering of 4H-SiC thyristors (18kV class) to high currents in purely inductive load circuit SO SEMICONDUCTOR SCIENCE AND TECHNOLOGY LA English DT Article DE silicon carbide; power devices; thyristors; optical triggering ID SILICON-CARBIDE THYRISTOR; POWER APPLICATIONS; SWITCH-ON AB Optical switch-on of a very high voltage (18 kV class) 4H-SiC thyristor with an amplification step (pilot thyristor) to the current I-max= 1225 A is demonstrated using a purely inductive load and a calibrated air transformer. Increasing the inductance of the transformer primary winding slows down the turn on process. However, the inductance has little effect during the initial stage of the switch-on process when the voltage drop on the thyristor and its internal resistance is high. The results show that a further switch-on current increase can be only achieved by introducing additional amplification steps in the pilot thyristor. C1 [Rumyantsev, S. L.; Levinshtein, M. E.] Ioffe Inst, St Petersburg 194021, Russia. [Rumyantsev, S. L.; Saxena, T.; Shur, M. S.] Rensselaer Polytech Inst, CII 6017, Dept Elect Comp & Syst Engn & Phys Appl Phys & As, Troy, NY 12180 USA. [Cheng, L.; Palmour, J. W.] Cree Inc, Durham, NC 27703 USA. [Agarwal, A.] US DOE, EERE, Washington, DC USA. RP Rumyantsev, SL (reprint author), Ioffe Inst, 26 Politekhnicheskaya, St Petersburg 194021, Russia. EM roumis2@rpi.edu RI Levinshtein, Michael/A-4325-2014; Shur, Michael/A-4374-2016 OI Shur, Michael/0000-0003-0976-6232 FU Russian Foundation for Basic Research; Army Research Laboratory under ARL MSME Alliance FX At Cree Inc., this work was supported by Mr Charles Scozzie of Army Research Laboratory, Adelphi, Maryland. At the Ioffe Institute this work was partly supported by the Russian Foundation for Basic Research. The work at Rensselaer Polytechnic Institute was supported by the Army Research Laboratory under ARL MSME Alliance (Project Monitor Dr Meredith Read). NR 22 TC 0 Z9 0 U1 0 U2 3 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0268-1242 EI 1361-6641 J9 SEMICOND SCI TECH JI Semicond. Sci. Technol. PD NOV PY 2014 VL 29 IS 11 AR 115003 DI 10.1088/0268-1242/29/11/115003 PG 5 WC Engineering, Electrical & Electronic; Materials Science, Multidisciplinary; Physics, Condensed Matter SC Engineering; Materials Science; Physics GA AS0YS UT WOS:000344003300006 ER PT J AU Maxwell, JL Webb, N Bradshaw, D Black, MR Maskaly, K Chavez, CA Espinoza, M Vessard, S Art, B Johnson, S Boman, M Gananavelu, S AF Maxwell, James L. Webb, Nicholas Bradshaw, Douglas Black, Marcie R. Maskaly, Karlene Chavez, Craig A. Espinoza, Miguel Vessard, Stuart Art, Blair Johnson, Scot Boman, Mats Gananavelu, S. TI On "how to start a fire'', or transverse forced-convection, hyperbaric laser chemical vapor deposition of fibers and textiles SO TEXTILE RESEARCH JOURNAL LA English DT Article DE laser deposition; fiber; coil; microstructure; hyperbaric pressure; pyrolysis; natural convection; forced convection; mass transfer; flow rate; fire ID CARBON-FIBERS; SINGLE-CRYSTALS; GROWTH; LCVD; TITANIUM; SILICON; PHASE; FILMS; BORON AB This work explores the transverse forced flow of precursor gases during hyperbaric pressure laser chemical vapor deposition (HP-LCVD). Axial and mass growth rates of carbon fibers are measured experimentally, and a numerical model is developed that provides fiber growth rates in both the mass-transport-limited (MTL) and kinetically limited (KL) regimes. It is found that the fiber's transport-limited rate increases as the square root of the flow velocity, while simultaneously, the temperature drops with the inverse square root of the flow velocity. Growth is enhanced by forced flow so long as the reaction zone remains within the MTL regime; upon reaching a critical temperature and flow rate, however, fibers enter the KL regime, and the growth rate declines with rising flow rate. Molecular properties of the precursors employed and gas concentrations ultimately determine the range of the MTL and the locations of the critical temperature and flow rate. The growth rates of fibers can indeed be enhanced by transverse forced convection-to at least three times the zero-flow steady-state rate, provided an MTL regime exists. Complex three-dimensional structures may be grown from these fibers in a freeform manner, and the more rapidly such microstructures can be fabricated, the more practical HP-LCVD becomes for industrial use, including the fabrication of novel textiles. C1 [Maxwell, James L.; Webb, Nicholas; Bradshaw, Douglas; Espinoza, Miguel] Dynetics Inc, Adv Mat & Nanosyst Grp, Huntsville, AL USA. [Black, Marcie R.; Gananavelu, S.] Bandgap Engn Inc, Salem, NH USA. [Maskaly, Karlene; Chavez, Craig A.; Vessard, Stuart; Art, Blair] Los Alamos Natl Lab, NEMISIS Team, Intelligence Anal & Technol IAT Div, Los Alamos, NM 87545 USA. [Johnson, Scot] Los Alamos Natl Lab, ENV EDA Div, Los Alamos, NM 87545 USA. [Boman, Mats] Uppsala Univ, Dept Inorgan Chem, Uppsala, Sweden. [Gananavelu, S.] Louisiana Tech Univ, IFM, Ruston, LA USA. RP Maxwell, JL (reprint author), Dynetics Inc, Huntsville, AL 35805 USA. EM james.maxwell@dynetics.com NR 55 TC 0 Z9 0 U1 1 U2 8 PU SAGE PUBLICATIONS LTD PI LONDON PA 1 OLIVERS YARD, 55 CITY ROAD, LONDON EC1Y 1SP, ENGLAND SN 0040-5175 EI 1746-7748 J9 TEXT RES J JI Text. Res. J. PD NOV PY 2014 VL 84 IS 18 BP 1976 EP 1986 DI 10.1177/0040517514527373 PG 11 WC Materials Science, Textiles SC Materials Science GA AR7NX UT WOS:000343767600007 ER PT J AU Burton, AL Johnson, JM Foerster, JM Hirsch, CN Buell, CR Hanlon, MT Kaeppler, SM Brown, KM Lynch, JP AF Burton, Amy L. Johnson, James M. Foerster, Jillian M. Hirsch, Candice N. Buell, C. R. Hanlon, Meredith T. Kaeppler, Shawn M. Brown, Kathleen M. Lynch, Jonathan P. TI QTL mapping and phenotypic variation for root architectural traits in maize (Zea mays L.) SO THEORETICAL AND APPLIED GENETICS LA English DT Article ID SYSTEM ARCHITECTURE; PHOSPHORUS ACQUISITION; GENETIC-IMPROVEMENT; PHASEOLUS-VULGARIS; DROUGHT-RESISTANCE; FIELD CONDITIONS; SEEDLING STAGE; WATER REGIMES; SHOOT TRAITS; UPLAND RICE AB QTL were identified for root architectural traits in maize. Root architectural traits, including the number, length, orientation, and branching of the principal root classes, influence plant function by determining the spatial and temporal domains of soil exploration. To characterize phenotypic patterns and their genetic control, three recombinant inbred populations of maize were grown for 28 days in solid media in a greenhouse and evaluated for 21 root architectural traits, including length, number, diameter, and branching of seminal, primary and nodal roots, dry weight of embryonic and nodal systems, and diameter of the nodal root system. Significant phenotypic variation was observed for all traits. Strong correlations were observed among traits in the same root class, particularly for the length of the main root axis and the length of lateral roots. In a principal component analysis, relationships among traits differed slightly for the three families, though vectors grouped together for traits within a given root class, indicating opportunities for more efficient phenotyping. Allometric analysis showed that trajectories of growth for specific traits differ in the three populations. In total, 15 quantitative trait loci (QTL) were identified. QTL are reported for length in multiple root classes, diameter and number of seminal roots, and dry weight of the embryonic and nodal root systems. Phenotypic variation explained by individual QTL ranged from 0.44 % (number of seminal roots, NyH population) to 13.5 % (shoot dry weight, OhW population). Identification of QTL for root architectural traits may be useful for developing genotypes that are better suited to specific soil environments. C1 [Burton, Amy L.; Hanlon, Meredith T.; Brown, Kathleen M.; Lynch, Jonathan P.] Penn State Univ, Dept Plant Sci, University Pk, PA 16801 USA. [Johnson, James M.; Foerster, Jillian M.; Kaeppler, Shawn M.] Univ Wisconsin, Dept Agron, Madison, WI 53706 USA. [Hirsch, Candice N.; Buell, C. R.] Michigan State Univ, Dept Plant Biol, E Lansing, MI 48824 USA. [Hirsch, Candice N.; Buell, C. R.] Michigan State Univ, DOE Great Lakes Bioenergy Res Ctr, E Lansing, MI 48824 USA. RP Lynch, JP (reprint author), Penn State Univ, Dept Plant Sci, 102 Tyson Bldg, University Pk, PA 16801 USA. EM jpl4@psu.edu OI Kaeppler, Shawn/0000-0002-5964-1668 FU United States Department of Agriculture National Research Initiative [207-35100-18365] FX We thank Lauren Gelesh, Johanna Mirenda, and Robert Snyder for technical assistance with plant cultivation and harvesting, and Anushree Sanyal for assistance with the QTL analysis. We thank Harini Rangarajan for creation of the image used in Fig. 1. This work was supported by United States Department of Agriculture National Research Initiative [grant # 207-35100-18365 to JPL and KMB]. NR 70 TC 16 Z9 17 U1 7 U2 59 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0040-5752 EI 1432-2242 J9 THEOR APPL GENET JI Theor. Appl. Genet. PD NOV PY 2014 VL 127 IS 11 BP 2293 EP 2311 DI 10.1007/s00122-014-2353-4 PG 19 WC Agronomy; Plant Sciences; Genetics & Heredity; Horticulture SC Agriculture; Plant Sciences; Genetics & Heredity GA AS5YY UT WOS:000344343500002 PM 25230896 ER PT J AU Ma, DY Wang, ZD Guo, M Zhang, M Liu, JB AF Ma, Dongyang Wang, Zhendong Guo, Min Zhang, Mei Liu, Jingbo TI Feasible conversion of solid waste bauxite tailings into highly crystalline 4A zeolite with valuable application SO WASTE MANAGEMENT LA English DT Article DE Bauxite tailings; 4A zeolite; Alkali fusion; Crystallization; Calcium ion exchange capacity ID RED MUD; DIASPORIC-BAUXITE; FLY-ASH; WATER; FLOTATION; MICROSTRUCTURE; METAKAOLIN; SEPARATION; COLLECTOR; EXCHANGE AB Bauxite tailings are a major type of solid wastes generated in the flotation process. The waste by-products caused significant environmental impact. To lessen this hazardous effect from poisonous mine tailings, a feasible and cost-effective solution was conceived and implemented. Our approach focused on reutilization of the bauxite tailings by converting it to 4A zeolite for reuse in diverse applications. Three steps were involved in the bauxite conversion: wet-chemistry, alkali fusion, and crystallization to remove impurities and to prepare porous 4A zeolite. It was found that the cubic 4A zeolite was single phase, in high purity, with high crystallinity and well-defined structure. Importantly, the 4A zeolite displayed maximum calcium ion exchange capacity averaged at 296 mg CaCO3/g, comparable to commercially-available zeolite (310 mg CaCO3/g) exchange capacity. Base on the optimal synthesis condition, the reaction yield of zeolite 4A from bauxite tailings achieved to about 38.43%, hence, this study will provide a new paradigm for remediation of bauxite tailings, further mitigating the environmental and health care concerns, particularly in the mainland of PR China. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Ma, Dongyang; Wang, Zhendong; Guo, Min; Zhang, Mei] Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China. [Liu, Jingbo] Texas A&M Univ Kingsville, Dept Chem, Kingsville, TX 78363 USA. [Liu, Jingbo] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA. RP Zhang, M (reprint author), Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China. EM zhangmei@ustb.edu.cn FU National Science Foundation of China [51272025, 51072022, 50874013]; National Science and Technology Supporting Program [2011BAB03B02] FX The National Science Foundation of China (Nos. 51272025, 51072022, 50874013) and National Science and Technology Supporting Program (No. 2011BAB03B02) are duly acknowledged for their financial support. Dr. S. Bashir (Department of Chemistry, TAMUK) was also acknowledged for proof-reading and copyediting the manuscript. NR 27 TC 4 Z9 4 U1 4 U2 37 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0956-053X J9 WASTE MANAGE JI Waste Manage. PD NOV PY 2014 VL 34 IS 11 BP 2365 EP 2372 DI 10.1016/j.wasman.2014.07.012 PG 8 WC Engineering, Environmental; Environmental Sciences SC Engineering; Environmental Sciences & Ecology GA AR8QY UT WOS:000343840800053 PM 25153822 ER PT J AU Kilpelainen, A Robertson, RA Leitner, T Sandstrom, E Maeurer, M Wahren, B AF Kilpelainen, Athina Robertson, Rebecca Axelsson Leitner, Thomas Sandstrom, Eric Maeurer, Markus Wahren, Britta TI Short Communication: HIV-1 Nef Protein Carries Multiple Epitopes Suitable for Induction of Cellular Immunity for an HIV Vaccine in Africa SO AIDS RESEARCH AND HUMAN RETROVIRUSES LA English DT Article ID CLASS-I; DOWN-REGULATION; HLA-A; SEQUENCE; PREDICTIONS; RESPONSES; GAG; NETMHCPAN; DATABASE; BINDING AB Using the early protein HIV Nef, new HLA class I binding epitopes of importance for immune responses to HIV were predicted for common African alleles. In total we identified 45 epitopes previously not described for the HLA alleles A*30:01, A*30:02, B*58:01, and C*07:01 and compared them to reported epitopes, primarily from HLA-A*02:01, from the Los Alamos database and our own vaccine studies. Related to its small size, the Nef gene/protein appears to be able to contribute effectively to confer both stronger and broader cellular immunogenicity to an HIV-1 vaccine. We also propose feasible mutations of such an additional vaccine antigen to preserve its immunogenicity, modified not to confer HLA or CD4(+) down-regulating activities. This article includes data on a valuable HIV immunogenic component for a vaccine in Africa. C1 [Kilpelainen, Athina; Wahren, Britta] Karolinska Inst, Dept Microbiol Tumor & Cell Biol, SE-17177 Stockholm, Sweden. [Robertson, Rebecca Axelsson; Maeurer, Markus] Karolinska Inst, Therapeut Immunol TIM, Dept Lab Med, SE-17177 Stockholm, Sweden. [Robertson, Rebecca Axelsson; Maeurer, Markus] Karolinska Inst, CAST, SE-17177 Stockholm, Sweden. [Leitner, Thomas] Los Alamos Natl Lab, Los Alamos, NM USA. [Sandstrom, Eric] Karolinska Inst, Dept Sodersjukhuset, SE-17177 Stockholm, Sweden. RP Wahren, B (reprint author), Karolinska Inst, Dept Microbiol Tumor & Cell Biol, SE-17177 Stockholm, Sweden. EM britta.wahren@ki.se FU Swedish Research Council; European Commission [037611] FX Funding was received from the Swedish Research Council and the European Commission FP6 grant 037611 (Europrise). NR 37 TC 0 Z9 0 U1 0 U2 5 PU MARY ANN LIEBERT, INC PI NEW ROCHELLE PA 140 HUGUENOT STREET, 3RD FL, NEW ROCHELLE, NY 10801 USA SN 0889-2229 EI 1931-8405 J9 AIDS RES HUM RETROV JI Aids Res. Hum. Retrovir. PD NOV 1 PY 2014 VL 30 IS 11 BP 1065 EP 1071 DI 10.1089/aid.2013.0299 PG 7 WC Immunology; Infectious Diseases; Virology SC Immunology; Infectious Diseases; Virology GA AR7OY UT WOS:000343770300008 PM 24866397 ER PT J AU Kressel, L Faries, KM Wander, MJ Zogzas, CE Mejdrich, RJ Hanson, DK Holten, D Laible, PD Kirmaier, C AF Kressel, Lucas Faries, Kaitlyn M. Wander, Marc J. Zogzas, Charles E. Mejdrich, Rachel J. Hanson, Deborah K. Holten, Dewey Laible, Philip D. Kirmaier, Christine TI High yield of secondary B-side electron transfer in mutant Rhodobacter capsulatus reaction centers SO BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS LA English DT Article DE Photosynthetic reaction center; Charge recombination; High-throughput screening; Ultrafast spectroscopy; Directed evolution; Transmembrane electron transfer ID PHOTOSYNTHETIC REACTION CENTERS; BACTERIAL REACTION CENTERS; SPHAEROIDES REACTION CENTERS; PRIMARY CHARGE SEPARATION; PHOTOACTIVE BACTERIOPHEOPHYTIN; RHODOPSEUDOMONAS-SPHAEROIDES; FREE-ENERGY; BACTERIOCHLOROPHYLL REPLACES; TEMPERATURE-DEPENDENCE; QUINONE REDUCTION AB From the crystal structures of reaction centers (RCs) from purple photosynthetic bacteria, two pathways for electron transfer (ET) are apparent but only one pathway (the A side) operates in the native protein-cofactor complex. Partial activation of the B-side pathway has unveiled the true inefficiencies of ET processes on that side in comparison to analogous reactions on the A side. Of significance are the relative rate constants for forward ET and the competing charge recombination reactions. On the B side, these rate constants are nearly equal for the secondary charge-separation step (ET from bacteriopheophytin to quinone), relegating the yield of this process to <50%. Herein we report efforts to optimize this step. In surveying all possible residues at position 131 in the M subunit, we discovered that when glutamic acid replaces the native valine the efficiency of the secondary ET is nearly two-fold higher than in the wild-type RC. The positive effect of M131 Glu is likely due to formation of a hydrogen bond with the ring V keto group of the B-side bacteriopheophytin leading to stabilization of the charge-separated state involving this cofactor. This change slows charge recombination by roughly a factor of two and affords the improved yield of the desired forward ET to the B-side quinone terminal acceptor. (C) 2014 Elsevier B.V. All rights reserved. C1 [Kressel, Lucas; Wander, Marc J.; Zogzas, Charles E.; Mejdrich, Rachel J.; Hanson, Deborah K.; Laible, Philip D.] Argonne Natl Lab, Biosci Div, Argonne, IL 60439 USA. [Faries, Kaitlyn M.; Holten, Dewey; Kirmaier, Christine] Washington Univ, Dept Chem, St Louis, MO 63130 USA. RP Kirmaier, C (reprint author), Washington Univ, Dept Chem, St Louis, MO 63130 USA. EM kirmaier@wustl.edu OI zogzas, charles/0000-0003-0092-6316 FU DOE Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences [DE-FG-02-09ER16116]; Argonne, a U.S. Department of Energy Office of Science [DE-AC02-06CH11357]; National Science Foundation Graduate Research Fellowship [DGE-1143954] FX This work was supported by grant DE-FG-02-09ER16116 (to CK, DH and PDL) from DOE Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. Argonne, a U.S. Department of Energy Office of Science laboratory, is operated under Contract No. DE-AC02-06CH11357. KMF was supported by the National Science Foundation Graduate Research Fellowship under Grant No. DGE-1143954. CEZ and RJM were participants in DOE-sponsored summer internship programs for undergraduate students. NR 67 TC 3 Z9 3 U1 0 U2 23 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0005-2728 EI 0006-3002 J9 BBA-BIOENERGETICS JI Biochim. Biophys. Acta-Bioenerg. PD NOV PY 2014 VL 1837 IS 11 BP 1892 EP 1903 DI 10.1016/j.bbabio.2014.07.015 PG 12 WC Biochemistry & Molecular Biology; Biophysics SC Biochemistry & Molecular Biology; Biophysics GA AR5JM UT WOS:000343621200005 PM 25091280 ER PT J AU Rankin, BA Magnotti, G Barlow, RS Gore, JP AF Rankin, Brent A. Magnotti, Gaetano Barlow, Robert S. Gore, Jay P. TI Radiation intensity imaging measurements of methane and dimethyl ether turbulent nonpremixed and partially premixed jet flames SO COMBUSTION AND FLAME LA English DT Article DE Flame radiation; Turbulent nonpremixed flame; Turbulent partially premixed flame; Dimethyl ether flame; Non-intrusive measurement; Infrared imaging ID LAMINAR DIFFUSION FLAMES; TIME-SERIES MEASUREMENTS; SPECTRAL RADIATION; SCALAR DISSIPATION; PDF CALCULATIONS; LENGTH SCALES; SIMULATION; EXTINCTION; DYNAMICS; NOISE AB Quantitative time-dependent images of the infrared radiation intensity from methane and dimethyl ether (DME) turbulent nonpremixed and partially premixed jet flames are measured and discussed in this work. The fuel compositions (CH4/H-2/N-2, C2H6O/H-2/N-2, CH4/air, and C2H6O/air) and Reynolds numbers (15,200-46,250) for the flames were selected following the guidelines of the International Workshop on Measurement and Computation of Turbulent Nonpremixed Flames (TNF Workshop). The images of the radiation intensity are acquired using a calibrated high speed infrared camera and three band-pass filters. The band-pass filters enable measurements of radiation from water vapor and carbon dioxide over the entire flame length and beyond. The images reveal localized regions of high and low intensity characteristic of turbulent flames. The peak mean radiation intensity is approximately 15% larger for the DME nonpremixed flames and 30% larger for the DME partially premixed flames in comparison to the corresponding methane flames. The trends are explained by a combination of higher temperatures and longer stoichiometric flame lengths for the DME flames. The longer flame lengths are attributed to the higher density of the DME fuel mixtures based on existing flame length scaling relationships. The longer flame lengths result in larger volumes of high temperature gas and correspondingly higher path-integrated radiation intensities near and downstream of the stoichiometric flame length. The radiation intensity measurements acquired with the infrared camera agree with existing spectroscopy measurements demonstrating the quantitative nature of the present imaging technique. The images provide new benchmark data of turbulent nonpremixed and partially premixed jet flames. The images can be compared with results of large eddy simulations rendered in the form of quantitative images of the infrared radiation intensity. Such comparisons are expected to support the evaluation of models used in turbulent combustion and radiation simulations. (C) 2014 The Combustion Institute. Published by Elsevier Inc. All rights reserved. C1 [Rankin, Brent A.; Gore, Jay P.] Purdue Univ, Sch Mech Engn, W Lafayette, IN 47907 USA. [Rankin, Brent A.] Innovat Sci Solut Inc, Dayton, OH 45459 USA. [Magnotti, Gaetano; Barlow, Robert S.] Sandia Natl Labs, Livermore, CA 94551 USA. RP Rankin, BA (reprint author), 7610 McEwen Rd, Dayton, OH 45459 USA. EM brent.rankin.ctr@us.af.mil RI Rankin, Brent/A-1598-2017 OI Rankin, Brent/0000-0002-5967-9527 NR 49 TC 2 Z9 2 U1 6 U2 15 PU ELSEVIER SCIENCE INC PI NEW YORK PA 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA SN 0010-2180 EI 1556-2921 J9 COMBUST FLAME JI Combust. Flame PD NOV PY 2014 VL 161 IS 11 BP 2849 EP 2859 DI 10.1016/j.combustflame.2014.04.019 PG 11 WC Thermodynamics; Energy & Fuels; Engineering, Multidisciplinary; Engineering, Chemical; Engineering, Mechanical SC Thermodynamics; Energy & Fuels; Engineering GA AR1YH UT WOS:000343380000009 ER PT J AU Lin, G Bao, J Xu, ZJ AF Lin, Guang Bao, Jie Xu, Zhijie TI A three-dimensional phase field model coupled with a lattice kinetics solver for modeling crystal growth in furnaces with accelerated crucible rotation and traveling magnetic field SO COMPUTERS & FLUIDS LA English DT Article DE Phase field; Crystal growth; Accelerated crucible rotation technique; (ACRT); Traveling magnetic field (TMF); Lattice Kinetics; Modeling ID VERTICAL BRIDGMAN GROWTH; CADMIUM ZINC TELLURIDE; SIGE SINGLE-CRYSTALS; BOLTZMANN-EQUATION; THERMAL-CONDUCTIVITY; FLUID-FLOWS; SIMULATIONS; CDXHG1-XTE; ACRT; SEGREGATION AB In this study, we present a new three-dimensional numerical model for crystal growth in a vertical solidification system. This model accounts for buoyancy, accelerated crucible rotation technique (ACRT), and traveling magnetic field (TMF) induced convective flow and their effect on crystal growth and the chemical component's transport process. The evolution of the crystal growth interface is simulated using the phase-field method. A semi-implicit lattice kinetics solver based on the Boltzmann equation is employed to model the unsteady incompressible flow. A one-way coupled concentration transport model is used to simulate the component fraction variation in both the liquid and solid phases, which can be used to check the quality of the crystal growth. Numerical results indicate that ACRT can slightly increase the quality of grown crystal, but the effect of TMF on quality of grown crystal depends on the temperature profile of the ampoule wall. Finally, excellent scalability of our developed parallel methods is demonstrated on the three-dimensional cases. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Lin, Guang] Purdue Univ, Dept Math, Sch Mech Engn, W Lafayette, IN 47907 USA. [Bao, Jie; Xu, Zhijie] Pacific NW Natl Lab, Richland, WA 99352 USA. RP Lin, G (reprint author), Purdue Univ, Dept Math, Sch Mech Engn, W Lafayette, IN 47907 USA. EM guanglin@purdue.edu RI Xu, Zhijie/A-1627-2009 OI Xu, Zhijie/0000-0003-0459-4531 FU Applied Mathematics Program within the Department of Energy Office of Advanced Scientific Computing Research, Collaboratory on Mathematics for Mesoscopic Modeling of Materials; U.S. Department of Energy [DE-AC05-76RL01830] FX This work was supported by the Applied Mathematics Program within the Department of Energy Office of Advanced Scientific Computing Research as part of the Collaboratory on Mathematics for Mesoscopic Modeling of Materials. PNNL is operated by Battelle for the U.S. Department of Energy under Contract DE-AC05-76RL01830. We would like to thank Dr. Kenneth Jarman for carefully proofreading the manuscript. The research was performed using PNNL Institutional Computing, as well as the National Energy Research Scientific Computing Center at Lawrence Berkeley National Laboratory. NR 54 TC 2 Z9 2 U1 0 U2 20 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0045-7930 EI 1879-0747 J9 COMPUT FLUIDS JI Comput. Fluids PD NOV 1 PY 2014 VL 103 BP 204 EP 214 DI 10.1016/j.compfluid.2014.07.027 PG 11 WC Computer Science, Interdisciplinary Applications; Mechanics SC Computer Science; Mechanics GA AR1PT UT WOS:000343357800017 ER PT J AU Marks, NE Borg, LE Hutcheon, ID Jacobsen, B Clayton, RN AF Marks, N. E. Borg, L. E. Hutcheon, I. D. Jacobsen, B. Clayton, R. N. TI Samarium-neodymium chronology and rubidium-strontium systematics of an Allende calcium-aluminum-rich inclusion with implications for Sm-146 half-life SO EARTH AND PLANETARY SCIENCE LETTERS LA English DT Article DE CAIs; Sm-Nd; Rb-Sr; initial Solar System Sm-146/Sm-144; Sm-146 half-life ID ANGRA-DOS-REIS; ND ISOTOPIC EVOLUTION; SOLAR-SYSTEM; CARBONACEOUS CHONDRITES; PROTOPLANETARY DISK; INITIAL SR-87/SR-86; EARLY HISTORY; SM; AGES; SR AB Calcium-aluminum-rich inclusions (CAIs) are primitive objects that formed within the protoplanetary disk surrounding the young Sun. Recent Pb-Pb chronologic studies have demonstrated that CAIs are the oldest solar system solids, crystallizing 4567 Ma ago (Amelin et al., 2002; Connelly et al., 2012). The isotope systematics of CAIs therefore provide critical insight into the earliest history of the Solar System. Although Sm-Nd and Rb-Sr geochronometers are highly effective tools for investigating cosmochemical evolution in the early Solar System, previous studies of CAIs have revealed evidence for isotopically disturbed systems. Here we report new age data for Allende CAI Al3S4 derived from both the long-lived (Sm-147-Nd-143) and short-lived (Sm-146-Nd-142) isotopic systems. The Sm-147-Nd-143 chronometer yields an age of 4560 +/- 34 Ma that is concordant with Pb-207-Pb-206 ages for CAIs and indicates that the Sm-Nd system was not significantly disturbed by secondary alteration or nucleosynthetic processes. The slope of the Sm-146-Nd-142 isochron defines the Solar System initial Sm-146/Sm-144 of 0.00828 +/- 0.00044. This value is significantly different from the value of 0.0094 determined by Kinoshita et al. (2012). Ages recalculated from all published Sm-146-Nd-142 isochron data using the traditional 103 Ma half-life and the initial Sm-146/Sm-144 value determined here closely match Pb-Pb and Sm-147-Nd-143 ages determined on the same samples. In contrast, ages recalculated using the 68 Ma half-life determined by Kinoshita et al. (2012) and either of the initial Sm-146/Sm-144 values are often anomalously old. This is particularly true for the youngest samples with Sm-146-Nd-142 isochron ages that are most sensitive to the choice of Sm-146 half-life used in the age calculation. In contrast to the Sm-Nd isotope system, the Rb-Sr system is affected by alteration but yields an apparent isochron with a slope corresponding to a much younger age of 4247 +/- 110 Ma. Although the Rb-Sr system in CAIs appears to be disturbed, the initial Sr-87/Sr-86 value determined from the isochron is 0.698942 +/- 0.000008, and closely approximates estimates of the initial Solar System value. Although this isochron may be a mixing line, it might also record alteration on the Allende parent body in which Rb was added to the Al3S4 CAI that was initially largely devoid of Rb. (C) 2014 Elsevier B.V. All rights reserved. C1 [Marks, N. E.; Borg, L. E.; Hutcheon, I. D.; Jacobsen, B.] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA. [Clayton, R. N.] Univ Chicago, Chicago, IL 60637 USA. RP Marks, NE (reprint author), Lawrence Livermore Natl Lab, 7000 East Ave L-231, Livermore, CA 94551 USA. EM marks23@llnl.gov OI Marks, Naomi/0000-0002-4737-9877 FU US Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; NASA Origins of Solar Systems [NNH10AO05I]; NASA Cosmochemistry [NNH12AT841, NNH10AO48I] FX This contribution is dedicated to Toshiko K. Mayeda. Without her invaluable contributions this project would not have been possible. We thank T. Kleine and two anonymous reviewers for valuable comments. This work was performed under the auspices of the US Department of Energy by Lawrence Livermore National Laboratory under contract number DE-AC52-07NA27344. The portion of the work performed at Lawrence Livermore National Laboratory was supported by NASA Origins of Solar Systems grant NNH10AO05I (P.I. Hutcheon) and NASA Cosmochemistry grants NNH12AT841 (P.I. Borg) and NNH10AO48I (P.I. Hutcheon). NR 66 TC 20 Z9 20 U1 5 U2 26 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0012-821X EI 1385-013X J9 EARTH PLANET SC LETT JI Earth Planet. Sci. Lett. PD NOV 1 PY 2014 VL 405 BP 15 EP 24 DI 10.1016/j.epsl.2014.08.017 PG 10 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA AR5LF UT WOS:000343625500002 ER PT J AU Kelley, SE Kaplan, MR Schaefer, JM Andersen, BG Barrell, DJA Putnam, AE Denton, GH Schwartz, R Finkel, RC Doughty, AM AF Kelley, Samuel E. Kaplan, Michael R. Schaefer, Joerg M. Andersen, Bjorn G. Barrell, David J. A. Putnam, Aaron E. Denton, George H. Schwartz, Roseanne Finkel, Robert C. Doughty, Alice M. TI High-precision Be-10 chronology of moraines in the Southern Alps indicates synchronous cooling in Antarctica and New Zealand 42,000 years ago SO EARTH AND PLANETARY SCIENCE LETTERS LA English DT Article DE Be-10 surface-exposure dating; LGM; MIS 3; Southern Hemisphere; westerly wind field; New Zealand ID LAST GLACIAL MAXIMUM; PRODUCTION-RATE CALIBRATION; CLIMATE VARIABILITY; ATMOSPHERIC CO2; RAKAIA VALLEY; DEGLACIATION; TERMINATION; GREENLAND; HOLOCENE; ISLAND AB Millennial-scale temperature variations in Antarctica during the period 80,000 to 18,000 years ago are known to anti-correlate broadly with winter-centric cold-warm episodes revealed in Greenland ice cores. However, the extent to which climate fluctuations in the Southern Hemisphere beat in time with Antarctica, rather than with the Northern Hemisphere, has proved a controversial question. In this study we determine the ages of a prominent sequence of glacial moraines in New Zealand and use the results to assess the phasing of millennial climate change. Forty-four Be-10 cosmogenic surface-exposure ages of boulders deposited by the Pukaki glacier in the Southern Alps document four moraine-building events from Marine Isotope Stage 3 (MIS 3) through to the end of the Last Glacial Maximum (similar to 18,000 years ago; LGM). The earliest moraine-building event is defined by the ages of nine boulders on a belt of moraine that documents the culmination of a glacier advance 42,000 years ago. At the Pukaki locality this advance was of comparable scale to subsequent advances that, from the remaining exposure ages, occurred between 28,000 and 25,000, at 21,000, and at 18,000 years ago. Collectively, all four moraine-building events represent the LGM. The glacier advance 42,000 years ago in the Southern Alps coincides in Antarctica with a cold episode, shown by the isotopic record from the EPICA Dome C ice core, between the prominent A1 and A2 warming events. Therefore, the implication of the Pukaki glacier record is that as early as 42,000 years ago an episode of glacial cold similar to that of the LGM extended in the atmosphere from high on the East Antarctic plateau to at least as far north as the Southern Alps (similar to 44 degrees S). Such a cold episode is thought to reflect the translation through the atmosphere and/or the ocean of the anti-phased effects of Northern Hemisphere interstadial conditions to the southern half of the Southern Hemisphere. Regardless of the mechanism, any explanation for the cold episode at 42,000 years ago must account for its widespread atmospheric footprint not only in Antarctica but also within the westerly wind belt in southern mid-latitudes. (C) 2014 Elsevier B.V. All rights reserved. C1 [Kelley, Samuel E.; Denton, George H.] Univ Maine, Dept Earth Sci, Orono, ME 04469 USA. [Kelley, Samuel E.; Denton, George H.] Univ Maine, Climate Change Inst, Orono, ME 04469 USA. [Kaplan, Michael R.; Schaefer, Joerg M.; Putnam, Aaron E.; Schwartz, Roseanne] Lamont Doherty Earth Observ, Palisades, NY 10964 USA. [Andersen, Bjorn G.] Univ Oslo, Dept Geosci, Oslo, Norway. [Barrell, David J. A.] GNS Sci, Dunedin, New Zealand. [Finkel, Robert C.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Doughty, Alice M.] Dartmouth Coll, Dept Earth Sci, Hanover, NH 03750 USA. RP Kelley, SE (reprint author), SUNY Buffalo, Dept Geol, 411 Cooke Hall, Buffalo, NY 14260 USA. EM Samuelke@buffalo.edu RI Kaplan, Michael/D-4720-2011; OI Putnam, Aaron/0000-0002-5358-1473 FU Corner Science and Education Foundation (CSEF); National Oceanic and Atmospheric Administration (NOAA); National Science Foundation [EAR-110278, EAR-0745781]; New Zealand Government through the GNS Science 'Global Change through Time' research programme; University of Maine, Climate Change Institute Fellowship [7821] FX This work was supported by funding from the Corner Science and Education Foundation (CSEF), the National Oceanic and Atmospheric Administration (NOAA), and by National Science Foundation grants EAR-110278 and EAR-0745781. D. Barrell was supported by funding from the New Zealand Government through the GNS Science 'Global Change through Time' research programme. We are grateful to J. Frisch and D. Sprecher for assistance with laboratory work and to T. and K. Ritchie of Lake Ruataniwha Holiday Park for a home away from home during long field seasons. We thank the owners and caretakers of Braemar Station, Mt. Cook Station, Irishman Creek Station, Balmoral Station, Tasman Downs Station, and the New Zealand Defence Force for granting access to their land. S.E.K. was supported by a University of Maine, Climate Change Institute Fellowship. This paper is LDEO contribution no. 7821. NR 66 TC 9 Z9 9 U1 5 U2 32 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0012-821X EI 1385-013X J9 EARTH PLANET SC LETT JI Earth Planet. Sci. Lett. PD NOV 1 PY 2014 VL 405 BP 194 EP 206 DI 10.1016/j.epsl.2014.07.031 PG 13 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA AR5LF UT WOS:000343625500017 ER PT J AU Griffiths, NA Hill, WR AF Griffiths, Natalie A. Hill, Walter R. TI Temporal Variation in the Importance of a Dominant Consumer to Stream Nutrient Cycling SO ECOSYSTEMS LA English DT Article DE consumer; snails; excretion; nutrient spiraling; nitrogen; phosphorus; ammonium; uptake rate; stream; temporal variation ID AGRICULTURAL LAND-USE; WOODLAND STREAM; BENTHIC INVERTEBRATES; ECOSYSTEM RESPONSES; PRIMARY PRODUCERS; PHOSPHORUS; NITROGEN; EXCRETION; STOICHIOMETRY; FISH AB Animal excretion can be a significant nutrient flux within ecosystems, where it supports primary production and facilitates microbial decomposition of organic matter. The effects of excretory products on nutrient cycling have been documented for various species and ecosystems, but temporal variation in these processes is poorly understood. We examined variation in excretion rates of a dominant grazing snail, Elimia clavaeformis, and its contribution to nutrient cycling, over the course of 14 months in a well-studied, low-nutrient stream (Walker Branch, east Tennessee, USA). Biomass-specific excretion rates of ammonium varied over twofold during the study, coinciding with seasonal changes in food availability (measured as gross primary production) and water temperature (multiple linear regression, R-2 = 0.57, P = 0.053). The contribution of ammonium excretion to nutrient cycling varied with seasonal changes in both biological (that is, nutrient uptake rate) and physical (that is, stream flow) variables. On average, ammonium excretion accounted for 58% of stream water ammonium concentrations, 26% of whole-stream nitrogen demand, and 66% of autotrophic nitrogen uptake. Phosphorus excretion by Elimia was contrastingly low throughout the year, supplying only 1% of total dissolved phosphorus concentrations. The high average N: P ratio (89: 1) of snail excretion likely exacerbated phosphorus limitation in Walker Branch. To fully characterize animal excretion rates and effects on ecosystem processes, multiple measurements through time are necessary, especially in ecosystems that experience strong seasonality. C1 [Griffiths, Natalie A.] Oak Ridge Natl Lab, Climate Change Sci Inst, Oak Ridge, TN 37831 USA. [Griffiths, Natalie A.] Oak Ridge Natl Lab, Div Environm Sci, Oak Ridge, TN 37831 USA. [Hill, Walter R.] Univ Illinois, Illinois Nat Hist Survey, Champaign, IL 61821 USA. [Hill, Walter R.] Univ Illinois, Prairie Res Inst, Champaign, IL 61821 USA. RP Griffiths, NA (reprint author), Oak Ridge Natl Lab, Climate Change Sci Inst, Oak Ridge, TN 37831 USA. EM griffithsna@ornl.gov OI Griffiths, Natalie/0000-0003-0068-7714 FU U.S. Department of Energy's Office of Science, Biological and Environmental Research; U.S. Department of Energy [DE-AC05-00OR22725]; ORNL Postdoctoral Research Associates Program FX We are grateful to the late Pat Mulholland for his advice, mentoring, and friendship. We thank D. Brice, J. Childs, A. Fortner, and K. McCracken for technical assistance. Comments by R. McManamay, A. Stewart, and two anonymous reviewers greatly improved an earlier version of this manuscript. This research was part of the Long-term Walker Branch Watershed project and supported by the U.S. Department of Energy's Office of Science, Biological and Environmental Research. Oak Ridge National Laboratory is managed by UT-Battelle, LLC, for the U.S. Department of Energy under contract DE-AC05-00OR22725. N. Griffiths was partially supported by a postdoctoral fellowship through the ORNL Postdoctoral Research Associates Program administered by Oak Ridge Associated Universities. NR 64 TC 1 Z9 1 U1 8 U2 44 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1432-9840 EI 1435-0629 J9 ECOSYSTEMS JI Ecosystems PD NOV PY 2014 VL 17 IS 7 BP 1169 EP 1185 DI 10.1007/s10021-014-9785-1 PG 17 WC Ecology SC Environmental Sciences & Ecology GA AR6UF UT WOS:000343717900004 ER PT J AU Shao, JJ Zhou, XH He, HL Yu, GR Wang, HM Luo, YQ Chen, JK Gu, LH Li, B AF Shao, Junjiong Zhou, Xuhui He, Honglin Yu, Guirui Wang, Huimin Luo, Yiqi Chen, Jiakuan Gu, Lianhong Li, Bo TI Partitioning Climatic and Biotic Effects on Interannual Variability of Ecosystem Carbon Exchange in Three Ecosystems SO ECOSYSTEMS LA English DT Article DE biotic effects; climatic effects; eddy covariance; interannual variability; net ecosystem exchange; relative contribution ID EVERGREEN CONIFEROUS PLANTATION; ATMOSPHERE CO2 EXCHANGE; DECIDUOUS FOREST; ENVIRONMENTAL CONTROLS; TERRESTRIAL BIOSPHERE; DIOXIDE EXCHANGE; GRASS PRAIRIE; EDDY FLUX; RESPIRATION; CHINA AB Understanding the climatic and biotic controls of interannual variability (IAV) in net ecosystem exchange (NEE) is important for projecting future uptake of CO2 in terrestrial ecosystems. In this study, a statistical modeling approach was used to partition climatic and biotic effects on the IAV in NEE, gross primary productivity (GPP) and ecosystem respiration (RE) at a subtropical evergreen plantation in China (QYZ), a deciduous forest (MOZ), and a grassland (DK1) in the USA. The climatic effects in the study are defined as the interannual anomalies in carbon (C) fluxes directly caused by climatic variations, whereas the biotic effects are those caused by the IAV in photosynthetic and respiratory traits. The results showed that the contribution of biotic effects to the IAV in NEE increased significantly as the temporal scale got longer from daily to annual scales. At the annual scale, the contribution of biotic effects to the IAV in NEE was 47, 69, and 77% at QYZ, MOZ, and DK1, respectively. However, the IAV in NEE was mainly controlled by GPP at QYZ, and by RE at DK1, whereas the contributions of GPP and RE to the IAV in NEE were similar at MOZ, indicating different mechanisms regulating the IAV in NEE among ecosystems. Interestingly, there was a strong negative correlation between the climatic and biotic effects at the annual scale from 2003 to 2009 at QYZ (r(2) = 0.80, P < 0.01), suggesting these two effects counteracted each other and resulted in a relatively stable C sink, whereas no correlations were found at the other two sites. Overall, our study revealed the relative importance of climatic and biotic effects on the IAV in NEE and contributed to our understanding of their underlying mechanisms. C1 [Shao, Junjiong; Zhou, Xuhui; Luo, Yiqi; Chen, Jiakuan; Li, Bo] Fudan Univ, Inst Biodivers Sci, Coastal Ecosyst Res Stn Yangtze River Estuary, Minist Educ,Key Lab Biodivers Sci & Ecol Engn, Shanghai 200433, Peoples R China. [Shao, Junjiong; He, Honglin; Yu, Guirui; Wang, Huimin] Chinese Acad Sci, Inst Geog Sci & Nat Resource Res, Beijing 100101, Peoples R China. [Luo, Yiqi] Univ Oklahoma, Dept Microbiol & Plant Biol, Norman, OK 73019 USA. [Gu, Lianhong] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. RP Zhou, XH (reprint author), Fudan Univ, Inst Biodivers Sci, Coastal Ecosyst Res Stn Yangtze River Estuary, Minist Educ,Key Lab Biodivers Sci & Ecol Engn, 220 Handan Rd, Shanghai 200433, Peoples R China. EM zxuhui14@fudan.edu.cn; yugr@igsnrr.ac.cn RI 于, 贵瑞/C-1768-2014; Li, Bo/B-8016-2010; Zhou, Xuhui/H-4332-2011; Shao, Junjiong/G-1010-2016; Gu, Lianhong/H-8241-2014 OI Li, Bo/0000-0002-0439-5666; Gu, Lianhong/0000-0001-5756-8738 FU National Basic Research Program of China [2010CB833504]; National Natural Science Foundation of China [31070407, 31370489]; Shanghai Pujiang Program [12PJ1401400]; "Thousand Young Talents" Program in China; Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning FX The authors thank the two anonymous reviewers for their insightful comments and suggestions. This research was financially supported by the National Basic Research Program of China (2010CB833504), the National Natural Science Foundation of China (31070407, 31370489), 2012 Shanghai Pujiang Program (12PJ1401400), "Thousand Young Talents" Program in China, and The Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning. NR 67 TC 6 Z9 6 U1 4 U2 64 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1432-9840 EI 1435-0629 J9 ECOSYSTEMS JI Ecosystems PD NOV PY 2014 VL 17 IS 7 BP 1186 EP 1201 DI 10.1007/s10021-014-9786-0 PG 16 WC Ecology SC Environmental Sciences & Ecology GA AR6UF UT WOS:000343717900005 ER PT J AU Qu, M Abdelaziz, O Yin, HX AF Qu, Ming Abdelaziz, Omar Yin, Hongxi TI New configurations of a heat recovery absorption heat pump integrated with a natural gas boiler for boiler efficiency improvement SO ENERGY CONVERSION AND MANAGEMENT LA English DT Article DE Natural gas boiler; Absorption heat pump; Heat recovery; Dew point; Flue gas; System configuration ID PERFORMANCE; SYSTEM; STATE; LIBR AB Conventional natural gas-fired boilers exhaust flue gas direct to the atmosphere at 150-200 degrees C, which, at such temperatures, contains large amount of energy and results in relatively low thermal efficiency ranging from 70% to 80%. Although condensing boilers for recovering the heat in the flue gas have been developed over the past 40 years, their present market share is still less than 25%. The major reason for this relatively slow acceptance is the limited improvement in the thermal efficiency of condensing boilers. In the condensing boiler, the temperature of the hot water return at the range of 50-60 degrees C, which is used to cool the flue gas, is very close to the dew point of the water vapor in the flue gas. Therefore, the latent heat, the majority of the waste heat in the flue gas, which is contained in the water vapor, cannot be recovered. This paper presents a new approach to improve boiler thermal efficiency by integrating absorption heat pumps with natural gas boilers for waste heat recovery (HRAHP). Three configurations of HRAHPs are introduced and discussed. The three configurations are modeled in detail to illustrate the significant thermal efficiency improvement they attain. Further, for conceptual proof and validation, an existing hot water-driven absorption chiller is operated as a heat pump at operating conditions similar to one of the devised configurations. An overall system performance and economic analysis are provided for decision-making and as evidence of the potential benefits. These three configurations of HRAHP provide a pathway to achieving realistic high-efficiency natural gas boilers for applications with process fluid return temperatures higher than or close to the dew point of the water vapor in the flue gas. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Qu, Ming] Purdue Univ, Sch Civil Engn, W Lafayette, IN 47906 USA. [Abdelaziz, Omar] Oak Ridge Natl Lab, Energy & Transportat Sci Div, Oak Ridge, TN 37831 USA. [Yin, Hongxi] Southeast Univ, Sch Architecture, Nanjing 210096, Jiangsu, Peoples R China. RP Qu, M (reprint author), Purdue Univ, Sch Civil Engn, 550 Stadium Mall Dr, W Lafayette, IN 47907 USA. EM mqu@purdue.edu RI Abdelaziz, Omar/O-9542-2015 OI Abdelaziz, Omar/0000-0002-4418-0125 FU U.S. DOE Visiting Faculty Program FX This research was funded by the U.S. DOE Visiting Faculty Program. We thank Patricia W. Garland, Nasr E. Alkadi, Sachin U. Nimbalkar, and James R. Keiser from the Oak Ridge National Laboratory for enlightening discussions and for leveraging the authors' technical expertise during this research project. NR 27 TC 18 Z9 20 U1 5 U2 33 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0196-8904 EI 1879-2227 J9 ENERG CONVERS MANAGE JI Energy Conv. Manag. PD NOV PY 2014 VL 87 BP 175 EP 184 DI 10.1016/j.enconman.2014.06.083 PG 10 WC Thermodynamics; Energy & Fuels; Mechanics SC Thermodynamics; Energy & Fuels; Mechanics GA AR1HV UT WOS:000343337200018 ER PT J AU Zhang, J Chowdhury, S Messac, A Hodge, BM AF Zhang, Jie Chowdhury, Souma Messac, Achille Hodge, Bri-Mathias TI A hybrid measure-correlate-predict method for long-term wind condition assessment SO ENERGY CONVERSION AND MANAGEMENT LA English DT Article DE Measure-correlate-predict (MCP); Power generation; Wind resource assessment; Wind distribution; Wind energy ID SUPPORT VECTOR MACHINES; SPEED PREDICTION; ENERGY; MODEL; SITE AB This paper develops a hybrid measure-correlate-predict (MCP) strategy to assess long-term wind resource variations at a farm site. The hybrid MCP method uses recorded data from multiple reference stations to estimate long-term wind conditions at a target wind plant site with greater accuracy than is possible with data from a single reference station. The weight of each reference station in the hybrid strategy is determined by the (i) distance and (ii) elevation differences between the target farm site and each reference station. In this case, the wind data is divided into sectors according to the wind direction, and the MCP strategy is implemented for each wind direction sector separately. The applicability of the proposed hybrid strategy is investigated using five MCP methods: (i) the linear regression; (ii) the variance ratio; (iii) the Weibull scale; (iv) the artificial neural networks; and (v) the support vector regression. To implement the hybrid MCP methodology, we use hourly averaged wind data recorded at five stations in the state of Minnesota between 07-01-1996 and 06-30-2004. Three sets of performance metrics are used to evaluate the hybrid MCP method. The first set of metrics analyze the statistical performance, including the mean wind speed, wind speed variance, root mean square error, and mean absolute error. The second set of metrics evaluate the distribution of long-term wind speed; to this end, the Weibull distribution and the Multivariate and Multimodal Wind Distribution models are adopted. The third set of metrics analyze the energy production of a wind farm. The best hybrid MCP strategy from 256 different combinations of MCP algorithms and reference stations is investigated and selected. The results illustrate that the many-to-one correlation in such a hybrid approach can provide a more reliable prediction of long-term on-site wind variations than that provided by the one-to-one correlations. The accuracy of the hybrid MCP method is found to be highly sensitive to the combination of individual MCP algorithms and reference stations used. It is also observed that the best combination of MCP algorithms is influenced by the length of the concurrent short-term correlation period. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Zhang, Jie; Hodge, Bri-Mathias] Natl Renewable Energy Lab, Golden, CO 80401 USA. [Chowdhury, Souma; Messac, Achille] Mississippi State Univ, Mississippi State, MS 39762 USA. RP Zhang, J (reprint author), Natl Renewable Energy Lab, Golden, CO 80401 USA. EM jie.zhang@nrel.gov FU National Science Foundation [CMMI-1100948, CMMI-1437746]; U.S. Department of Energy [DE-AC36-08-GO28308]; National Renewable Energy Laboratory FX Support from the National Science Foundation Awards CMMI-1100948 and CMMI-1437746 is gratefully acknowledged. Any opinions, findings, conclusions, or recommendations expressed in this paper are those of the authors and do not necessarily reflect the views of the NSF. This work was also supported by the U.S. Department of Energy under Contract No. DE-AC36-08-GO28308 with the National Renewable Energy Laboratory. NR 41 TC 3 Z9 4 U1 1 U2 10 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0196-8904 EI 1879-2227 J9 ENERG CONVERS MANAGE JI Energy Conv. Manag. PD NOV PY 2014 VL 87 BP 697 EP 710 DI 10.1016/j.enconman.2014.07.057 PG 14 WC Thermodynamics; Energy & Fuels; Mechanics SC Thermodynamics; Energy & Fuels; Mechanics GA AR1HV UT WOS:000343337200072 ER PT J AU Kozarac, D Vuilleumier, D Saxena, S Dibble, RW AF Kozarac, Darko Vuilleumier, David Saxena, Samveg Dibble, Robert W. TI Analysis of benefits of using internal exhaust gas recirculation in biogas-fueled HCCI engines SO ENERGY CONVERSION AND MANAGEMENT LA English DT Article DE Biogas; HCCI; Internal EGR; Simulation ID POWER-GENERATION; PERFORMANCE; STRATEGIES; COMBUSTION; OPERATION AB This paper describes a numerical study that analyzed the influence of combustion products (CP) concentration on the combustion characteristics (combustion timing and combustion duration) of a biogas fueled homogeneous charge compression ignition (HCCI) engine and the possibility of reducing the high intake temperature requirement necessary for igniting biogas in a HCCI engine by using internal exhaust gas recirculation (EGR) enabled by negative valve overlap (NVO). An engine model created in AVL Boost, and validated against experimental engine data, was used in this study. The results show, somewhat counter-intuitively, that when CP concentrations are increased the required intake temperature for maintaining the same combustion timing must be increased. When greater NVO is used to increase the in-cylinder CP concentration, the in-cylinder temperature does increase, but the chemical dilution influence of CP almost entirely counteracts this thermal effect. Additionally, it has been observed that with larger fractions of CP some instability of combustion in the calculation was obtained which indicates that the increase of internal EGR might produce some combustion instability. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Kozarac, Darko; Vuilleumier, David; Dibble, Robert W.] Univ Calif Berkeley, Dept Mech Engn, Berkeley, CA 94720 USA. [Saxena, Samveg] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Environm Energy Technol Div, Berkeley, CA 94720 USA. RP Kozarac, D (reprint author), Univ Zagreb, Fac Mech Engn & Naval Architecture, Ivana Lucica 5, Zagreb 10000, Croatia. EM darko.kozarac@fsb.hr; david.vuilleumier@berkeley.edu; samveg@berkeley.edu; dokdibble@gmail.com NR 22 TC 15 Z9 15 U1 3 U2 9 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0196-8904 EI 1879-2227 J9 ENERG CONVERS MANAGE JI Energy Conv. Manag. PD NOV PY 2014 VL 87 BP 1186 EP 1194 DI 10.1016/j.enconman.2014.04.085 PG 9 WC Thermodynamics; Energy & Fuels; Mechanics SC Thermodynamics; Energy & Fuels; Mechanics GA AR1HV UT WOS:000343337200123 ER PT J AU Zheng, GY Xu, XQ Ryutov, DD Pan, YD Xia, TY AF Zheng, G. Y. Xu, X. Q. Ryutov, D. D. Pan, Y. D. Xia, T. Y. TI Magnetic configuration flexibility of snowflake divertor for HL-2M SO FUSION ENGINEERING AND DESIGN LA English DT Article DE Snowflake divertor; Poloidal field; Magnetic field shear; Tripod divertor ID PHYSICS; ITER AB HL-2M (Li, 2013 [1]) is a tokamak device that is under construction. Based on the magnetic coils design of HL-2M, four kinds of divertor configurations are calculated by CORSICA code (PearIstein et al., 2001 [2]) with the same main plasma parameters, which are standard divertor, exact snowflake divertor, snowflake-plus divertor and snowflake-minus divertor configurations. The potential properties of these divertors are analyzed and presented in this paper: low poloidal field area around X-point, connection length from outside mid-plane to the primary X-point, target plate design and magnetic field shear. The results show that the snowflake configurations not only can reduce the heat load at divertor target plates, but also may improve the magneto-hydrodynamic stability by stronger magnetic shear at the edge. A new divertor configuration, named "tripod divertor", is designed by adjusting the positions of the two X-points according to plasma parameters and magnetic coils current of HL-2M. (C) 2014 Elsevier B.V. All rights reserved. C1 [Zheng, G. Y.; Pan, Y. D.] Southwestern Inst Phys, Chengdu, Peoples R China. [Zheng, G. Y.; Xu, X. Q.; Ryutov, D. D.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Xia, T. Y.] Chinese Acad Sci, Inst Plasma Phys, Hefei, Peoples R China. RP Zheng, GY (reprint author), Southwestern Inst Phys, Chengdu, Peoples R China. EM zgy@swip.ac.cn FU Chinese ITER Plan Project Foundation [2013GB113001]; National Natural Science Foundation of China [11275061, 11175058]; LLNL for USDOE [DE-AC52-07NA27344 (LLNL-JRNL-651522)] FX The authors wish to acknowledge Drs. R.H. Bulmer, M.V. Umansky, and G.Q Li for their valuable suggestions, advice and timely help for using CORSICA code during this research. Many thanks in particular to Drs. Y. Liu and X.R. Duan for their support and encouragement for US-China International Collaboration project. This work was supported by Chinese ITER Plan Project Foundation (grant no. 2013GB113001), National Natural Science Foundation of China (grant nos. 11275061 and 11175058), and by LLNL for USDOE under DE-AC52-07NA27344 (LLNL-JRNL-651522). NR 20 TC 6 Z9 6 U1 0 U2 8 PU ELSEVIER SCIENCE SA PI LAUSANNE PA PO BOX 564, 1001 LAUSANNE, SWITZERLAND SN 0920-3796 EI 1873-7196 J9 FUSION ENG DES JI Fusion Eng. Des. PD NOV PY 2014 VL 89 IS 11 BP 2621 EP 2627 DI 10.1016/j.fusengdes.2014.06.014 PG 7 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AR5KD UT WOS:000343622800016 ER PT J AU Clark, AW Doumet, M Hammond, KC Kornbluth, Y Spong, DA Sweeney, R Volpe, FA AF Clark, A. W. Doumet, M. Hammond, K. C. Kornbluth, Y. Spong, D. A. Sweeney, R. Volpe, F. A. TI Proto-CIRCUS tilted-coil tokamak-torsatron hybrid: Design and construction SO FUSION ENGINEERING AND DESIGN LA English DT Article DE Stellarator; Electron cyclotron resonance; Interlinked coils; Rotational transform; Tilted coils ID STELLARATORS AB We present the field-line modeling, design, and construction of a prototype circular-coil tokamak-torsatron hybrid called Proto-CIRCUS. The device has a major radius R = 16 cm and minor radius a < 5 cm. The six "toroidal field" coils are planar as in a tokamak, but they are tilted. This, combined with induced or driven plasma current, is expected to generate rotational transform, as seen in field-line tracing and equilibrium calculations. The device is expected to operate at lower plasma current than a tokamak of comparable size and magnetic field, which might have interesting implications for disruptions and steady-state operation. Additionally, the toroidal magnetic ripple is less pronounced than in an equivalent tokamak in which the coils are not tilted. The tilted coils are interlocked, resulting in a relatively low aspect ratio, and can be moved, both radially and in tilt angle, between discharges. This capability will be exploited for detailed comparisons between calculations and field-line mapping measurements. Such comparisons will reveal whether this relatively simple concept can generate the expected rotational transform. (C) 2014 Elsevier B.V. All rights reserved. C1 [Clark, A. W.; Doumet, M.; Hammond, K. C.; Sweeney, R.; Volpe, F. A.] Columbia Univ, Dept Appl Phys & Appl Math, New York, NY 10027 USA. [Kornbluth, Y.] Yeshiva Univ, New York, NY 10033 USA. [Spong, D. A.] Oak Ridge Natl Lab, Oak Ridge, TN 37830 USA. RP Volpe, FA (reprint author), Columbia Univ, Dept Appl Phys & Appl Math, New York, NY 10027 USA. EM fvolpe@columbia.edu RI Volpe, Francesco/D-2994-2009; OI Volpe, Francesco/0000-0002-7193-7090; Hammond, Kenneth/0000-0002-1104-4434 NR 12 TC 1 Z9 1 U1 0 U2 2 PU ELSEVIER SCIENCE SA PI LAUSANNE PA PO BOX 564, 1001 LAUSANNE, SWITZERLAND SN 0920-3796 EI 1873-7196 J9 FUSION ENG DES JI Fusion Eng. Des. PD NOV PY 2014 VL 89 IS 11 BP 2732 EP 2737 DI 10.1016/j.fusengdes.2014.07.012 PG 6 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AR5KD UT WOS:000343622800030 ER PT J AU Mumgaard, RT Vieira, R Parkin, W Scott, SD AF Mumgaard, R. T. Vieira, R. Parkin, W. Scott, S. D. TI A small, novel, remote in-vessel inspection system for the Alcator C-Mod tokamak SO FUSION ENGINEERING AND DESIGN LA English DT Article DE Inspection; Tomakak; Remote handling; Cameras; Alcator C-Mod ID VACUUM AB A small robust system has been constructed for in-situ visual inspection of the Alcator C-Mod tokamak. The system consists of a small, light, wide-angle high definition camera and LED package housed in a nacelle on the end of thin, rigid, 3.5 m long support pole. The nacelle has two actuated degrees of freedom allowing the camera to observe nearly 4 pi steradians. The support pole has a specific slight curve that allows it to pass to either side of the center column of the tokamak to observe the entirety of the vessel interior, while still fitting through the small aspect ratio Alcator C-Mod vacuum port structure. The support pole and camera can enter the vessel through any horizontal vacuum port with an inner diameter greater than 4cm, thus a dedicated port is not required. The inspection is typically undertaken during maintenance periods when the vessel is filled with a noble gas near atmospheric pressure thus minimizing the influx of water vapor and the concomitant loss of wall conditioning. The system is operated manually, producing photos and video which are reviewed in near real-time. Nearly the entire vessel, including the plasma facing components, can be carefully inspected in 3-5 h. The system provides improved characterization of the interior components and surfaces of the tokamak with a modest engineering and operational effort. Information gathered from the system has identified damage to plasma facing components that were interfering with tokamak operation, as well as damage to mechanical components which were redesigned during the remainder of the campaign, thereby enhancing program planning. (C) 2014 Elsevier B.V. All rights reserved. C1 [Mumgaard, R. T.; Vieira, R.; Parkin, W.] MIT, Plasma Sci & Fus Ctr, Cambridge, MA 02139 USA. [Scott, S. D.] Princeton Plasma Phys Lab, Princeton, NJ USA. RP Mumgaard, RT (reprint author), MIT, Plasma Sci & Fus Ctr, Cambridge, MA 02139 USA. FU US DOE [DE-FC02-99ER54512] FX This work was supported by US DOE award DE-FC02-99ER54512. NR 11 TC 1 Z9 1 U1 2 U2 4 PU ELSEVIER SCIENCE SA PI LAUSANNE PA PO BOX 564, 1001 LAUSANNE, SWITZERLAND SN 0920-3796 EI 1873-7196 J9 FUSION ENG DES JI Fusion Eng. Des. PD NOV PY 2014 VL 89 IS 11 BP 2784 EP 2788 DI 10.1016/j.fusengdes.2014.08.003 PG 5 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AR5KD UT WOS:000343622800038 ER PT J AU Liese, E AF Liese, Eric TI Modeling of a Steam Turbine Including Partial Arc Admission for Use in a Process Simulation Software Environment SO JOURNAL OF ENGINEERING FOR GAS TURBINES AND POWER-TRANSACTIONS OF THE ASME LA English DT Article AB A dynamic process model of a steam turbine, including partial arc admission operation, is presented. Models were made for the first stage and last stage, with the middle stages assumed to have a constant pressure ratio and efficiency. A condenser model is also presented. The paper discusses the function and importance of the steam turbine's entrance design and the first stage. The results for steam turbines with a partial arc entrance are shown and compare well with experimental data available in the literature; in particular, the "valve loop" behavior as the steam flow rate is reduced. This is important to model correctly since it significantly influences the downstream state variables of the steam, and thus the characteristic of the entire steam turbine, e. g., state conditions at extractions, overall turbine flow, and condenser behavior. The importance of the last stage (the stage just upstream of the condenser) in determining the overall flow rate and exhaust conditions to the condenser is described and shown via results. C1 Natl Energy Technol Lab, Dept Energy, Morgantown, WV 26507 USA. RP Liese, E (reprint author), Natl Energy Technol Lab, Dept Energy, 3610 Collins Ferry Rd, Morgantown, WV 26507 USA. EM eric.liese@netl.doe.gov NR 10 TC 0 Z9 0 U1 2 U2 7 PU ASME PI NEW YORK PA TWO PARK AVE, NEW YORK, NY 10016-5990 USA SN 0742-4795 EI 1528-8919 J9 J ENG GAS TURB POWER JI J. Eng. Gas. Turbines Power-Trans. ASME PD NOV PY 2014 VL 136 IS 11 AR 112605 DI 10.1115/1.4027255 PG 7 WC Engineering, Mechanical SC Engineering GA AR5ZI UT WOS:000343661200020 ER PT J AU Senecal, PK Pomraning, E Anders, JW Weber, MR Gehrke, CR Polonowski, CJ Mueller, CJ AF Senecal, P. K. Pomraning, E. Anders, J. W. Weber, M. R. Gehrke, C. R. Polonowski, C. J. Mueller, C. J. TI Predictions of Transient Flame Lift-off Length With Comparison to Single-Cylinder Optical Engine Experiments SO JOURNAL OF ENGINEERING FOR GAS TURBINES AND POWER-TRANSACTIONS OF THE ASME LA English DT Article AB A state-of-the-art, grid-convergent simulation methodology was applied to three-dimensional calculations of a single-cylinder optical engine. A mesh resolution study on a sector-based version of the engine geometry further verified the RANS-based cell size recommendations previously presented by Senecal et al. ("Grid Convergent Spray Models for Internal Combustion Engine CFD Simulations," ASME Paper No. ICEF2012-92043). Convergence of cylinder pressure, flame lift-off length, and emissions was achieved for an adaptive mesh refinement cell size of 0.35 mm. Full geometry simulations, using mesh settings derived from the grid convergence study, resulted in excellent agreement with measurements of cylinder pressure, heat release rate, and NOx emissions. On the other hand, the full geometry simulations indicated that the flame lift-off length is not converged at 0.35 mm for jets not aligned with the computational mesh. Further simulations suggested that the flame lift-off lengths for both the nonaligned and aligned jets appear to be converged at 0.175 mm. With this increased mesh resolution, both the trends and magnitudes in flame lift-off length were well predicted with the current simulation methodology. Good agreement between the overall predicted flame behavior and the available chemiluminescence measurements was also achieved. The present study indicates that cell size requirements for accurate prediction of full geometry flame lift-off lengths may be stricter than those for global combustion behavior. This may be important when accurate soot predictions are required. C1 [Senecal, P. K.; Pomraning, E.] Convergent Sci Inc, Middleton, WI 53562 USA. [Anders, J. W.; Weber, M. R.; Gehrke, C. R.] Caterpillar Inc, Peoria, IL 61629 USA. [Polonowski, C. J.; Mueller, C. J.] Sandia Natl Labs, Livermore, CA 94551 USA. RP Senecal, PK (reprint author), Convergent Sci Inc, Middleton, WI 53562 USA. EM senecal@convergecfd.com; pomraning@convergecfd.com; anders_jon@cat.com; weber_marcus_r@cat.com; gehrke_christopher_r@cat.com; cpolonow@ford.com; cjmuell@sandia.gov FU U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX The experimental research described herein was conducted at the Combustion Research Facility, Sandia National Laboratories, Livermore, CA. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the U.S. Department of Energy's National Nuclear Security Administration, under Contract No. DE-AC04-94AL85000. The authors would like to thank the support team at CEI, Inc., for their help in automating the flame lift-off length calculations. NR 28 TC 0 Z9 0 U1 2 U2 14 PU ASME PI NEW YORK PA TWO PARK AVE, NEW YORK, NY 10016-5990 USA SN 0742-4795 EI 1528-8919 J9 J ENG GAS TURB POWER JI J. Eng. Gas. Turbines Power-Trans. ASME PD NOV PY 2014 VL 136 IS 11 AR 111505 DI 10.1115/1.4027653 PG 19 WC Engineering, Mechanical SC Engineering GA AR5ZI UT WOS:000343661200006 ER PT J AU Senecal, PK Pomraning, E Xue, Q Som, S Banerjee, S Hu, B Liu, K Deur, JM AF Senecal, P. K. Pomraning, E. Xue, Q. Som, S. Banerjee, S. Hu, B. Liu, K. Deur, J. M. TI Large Eddy Simulation of Vaporizing Sprays Considering Multi-Injection Averaging and Grid-Convergent Mesh Resolution SO JOURNAL OF ENGINEERING FOR GAS TURBINES AND POWER-TRANSACTIONS OF THE ASME LA English DT Article AB A state-of-the-art spray modeling methodology, recently presented by Senecal et al. (2012, "Grid Convergent Spray Models for Internal Combustion Engine CFD Simulations," Proceedings of the ASME 2012 Internal Combustion Engine Division Fall Technical Conference, Vancouver, Canada, Paper No. ICEF2012-92043; 2013 "An Investigation of Grid Convergence for Spray Simulations using an LES Turbulence Model," Paper No. SAE 2013-01-1083) is applied to large eddy simulations (LES) of vaporizing sprays. Simulations of noncombusting Spray A (n-dodecane fuel) from the engine combustion network are performed. An adaptive mesh refinement (AMR) cell size of 0.0625mm is utilized based on the accuracy/runtime tradeoff demonstrated by Senecal et al. (2013, "An Investigation of Grid Convergence for Spray Simulations using an LES Turbulence Model," Paper No. SAE 2013-01-1083). In that work, it was shown that grid convergence of key parameters for nonevaporating and evaporating sprays was achieved for cell sizes between 0.0625 and 0.125mm using the dynamic structure LES model. The current work presents an extended and more thorough investigation of Spray A using multidimensional spray modeling and the dynamic structure LES model. Twenty different realizations are simulated by changing the random number seed used in the spray submodels. Multirealization (ensemble) averaging is shown to be necessary when comparing to local spray measurements of quantities such as mixture fraction and gas-phase velocity. Through a detailed analysis, recommendations are made regarding the minimum number of LES realizations required for accurate prediction of diesel sprays. Finally, the effect of a spray primary breakup model constant on the results is assessed. C1 [Senecal, P. K.; Pomraning, E.] Convergent Sci Inc, Middleton, WI 53562 USA. [Xue, Q.; Som, S.] Argonne Natl Lab, Argonne, IL 60439 USA. [Banerjee, S.; Hu, B.; Liu, K.; Deur, J. M.] Cummins Inc, Columbus, IN 47201 USA. RP Senecal, PK (reprint author), Convergent Sci Inc, Middleton, WI 53562 USA. EM senecal@convergecfd.com; pomraning@convergecfd.com; qxue@anl.gov; ssom@anl.gov; siddhartha.banerjee@cummins.com; bing.hu@cummins.com; kai.liu@cummins.com; john.deur@cummins.com FU U.S. Department of Energy Office of Science laboratory [DE-AC02-06CH11357] FX The submitted manuscript has been created in collaboration with UChicago Argonne, LLC, operator of Argonne National Laboratory (Argonne). Argonne, a U.S. Department of Energy Office of Science laboratory, is operated under Contract No. DE-AC02-06CH11357. The U.S. Government retains for itself, and others acting on its behalf, a paid-up, nonexclusive, irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly and display publicly, by or on behalf of the Government. The authors would like to thank Shawn Givler for help in processing the multiple realization data. The authors would also like to thank Lyle Pickett of Sandia National Laboratories for many helpful discussions. We gratefully acknowledge the computing resources provided on "Fusion," a 320-node computing cluster operated by the Laboratory Computing Resource Center at Argonne National Laboratory. NR 22 TC 3 Z9 3 U1 2 U2 13 PU ASME PI NEW YORK PA TWO PARK AVE, NEW YORK, NY 10016-5990 USA SN 0742-4795 EI 1528-8919 J9 J ENG GAS TURB POWER JI J. Eng. Gas. Turbines Power-Trans. ASME PD NOV PY 2014 VL 136 IS 11 AR 111504 DI 10.1115/1.4027449 PG 13 WC Engineering, Mechanical SC Engineering GA AR5ZI UT WOS:000343661200005 ER PT J AU Kurikami, H Kitamura, A Yokuda, ST Onishi, Y AF Kurikami, Hiroshi Kitamura, Akihiro Yokuda, Satoru Thomas Onishi, Yasuo TI Sediment and Cs-137 behaviors in the Ogaki Dam Reservoir during a heavy rainfall event SO JOURNAL OF ENVIRONMENTAL RADIOACTIVITY LA English DT Article DE Fukushima Daiichi NPP; Ogaki Dam Reservoir; Numerical modeling; Cesium; Sediment; Heavy rainfall events ID RADIONUCLIDES; MODELS AB We performed a simulation of sediment and Cs-137 behaviors in the Ogaki Dam Reservoir, one of the main irrigation reservoirs in the Fukushima prefecture, japan, during a heavy rainfall event occurred in 2013. The one-dimensional river and reservoir simulation scheme TODAM, Time-dependent One-dimensional Degradation and Migration, was applied for calculating the time dependent migration of sediment and Cs-137 in dissolved and sediment-sorbed forms in the reservoir. Continuous observational data achieved in the upper rivers were used as the input boundary conditions for the simulation. The simulation results were compared with the continuous data achieved in the lower river and we confirmed the predicted values of sediment and Cs-137 in sediment-sorbed form at the exit of reservoir satisfactorily reproduced the observational data. We also performed sediment and Cs-137 behavioral simulation by changing the water level of the reservoir, because such a dam operation could control the quantities of sediment and Cs-137 discharge from and/or deposition in the reservoir. The simulation clarified that the reservoir played an important role to delay and buffer the movement of radioactive cesium in heavy rainfall events and the buffer effect of the reservoir depended on particle sizes of suspended sediment and the water level. It was also understood that silt deposition was the main source of the bed contamination (except for the initial fallout impact), while clay was the main carrier of Cs-137 to the lower river at a later stage of rainfall events. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Kurikami, Hiroshi; Kitamura, Akihiro] Japan Atom Energy Agcy, Sect Fukushima Res & Dev, Tokai, Ibaraki 3191194, Japan. [Yokuda, Satoru Thomas; Onishi, Yasuo] Pacific NW Natl Lab, Richland, WA 99352 USA. RP Kurikami, H (reprint author), Japan Atom Energy Agcy, Sect Fukushima Res & Dev, 4-33 Muramatsu, Tokai, Ibaraki 3191194, Japan. EM kurikami.hiroshi@jaea.go.jp; kitamura.akihiro@jaea.go.jp; satoru.yokuda@pnnl.gov; yasuo.onishi@pnnl.gov NR 16 TC 5 Z9 5 U1 0 U2 28 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0265-931X EI 1879-1700 J9 J ENVIRON RADIOACTIV JI J. Environ. Radioact. PD NOV PY 2014 VL 137 BP 10 EP 17 DI 10.1016/j.jenvrad.2014.06.013 PG 8 WC Environmental Sciences SC Environmental Sciences & Ecology GA AR5MG UT WOS:000343628100002 PM 24980512 ER PT J AU Cassata, WS Prussin, SG Knight, KB Hutcheon, ID Isselhardt, BH Renne, PR AF Cassata, W. S. Prussin, S. G. Knight, K. B. Hutcheon, I. D. Isselhardt, B. H. Renne, P. R. TI When the dust settles: stable xenon isotope constraints on the formation of nuclear fallout SO JOURNAL OF ENVIRONMENTAL RADIOACTIVITY LA English DT Article DE Nuclear fallout; Xenon; Fission product; Chemical fractionation; Nuclear fireball ID GAMMA-RAY SPECTROSCOPY; VAPORIZATION BEHAVIOR; OUT PARTICLES; DEBRIS; DEVICE; RADIONUCLIDES; TRINITITE; YIELD; FRACTIONATION; SYSTEMS AB Nuclear weapons represent one of the most immediate threats of mass destruction. In the event that a procured or developed nuclear weapon is detonated in a populated metropolitan area, timely and accurate nuclear forensic analysis and fallout modeling would be needed to support attribution efforts and hazard assessments. Here we demonstrate that fissiogenic xenon isotopes retained in radioactive fallout generated by a nuclear explosion provide unique constraints on (1) the timescale of fallout formation, (2) chemical fractionation that occurs when fission products and nuclear fuel are incorporated into fallout, and (3) the speciation of fission products in the fireball. Our data suggest that, in near surface nuclear tests, the presence of a significant quantity of metal in a device assembly, combined with a short time allowed for mixing with the ambient atmosphere (seconds), may prevent complete oxidation of fission products prior to their incorporation into fallout. Xenon isotopes thus provide a window into the chemical composition of the fireball in the seconds that follow a nuclear explosion, thereby improving our understanding of the physical and thermo-chemical conditions under which fallout forms. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Cassata, W. S.; Knight, K. B.; Hutcheon, I. D.; Isselhardt, B. H.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Prussin, S. G.] Univ Calif Berkeley, Dept Nucl Engn, Berkeley, CA 94720 USA. [Renne, P. R.] Berkeley Geochronol Ctr, Berkeley, CA 94709 USA. [Renne, P. R.] Univ Calif Berkeley, Dept Earth & Planetary Sci, Berkeley, CA 94720 USA. RP Cassata, WS (reprint author), Lawrence Livermore Natl Lab, 7000 East Ave, Livermore, CA 94550 USA. EM cassata2@llnl.gov FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; U.S. Department of Energy's National Nuclear Security Administration, Office of Defense Nuclear Nonproliferation Research and Development FX This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. We thank the U.S. Department of Energy's National Nuclear Security Administration, Office of Defense Nuclear Nonproliferation Research and Development, for financial support. Jim Delmore and two anonymous reviewers are thanked for their thoughtful and constructive reviews of the manuscript. NR 34 TC 8 Z9 8 U1 4 U2 24 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0265-931X EI 1879-1700 J9 J ENVIRON RADIOACTIV JI J. Environ. Radioact. PD NOV PY 2014 VL 137 BP 88 EP 95 DI 10.1016/j.jenvrad.2014.06.011 PG 8 WC Environmental Sciences SC Environmental Sciences & Ecology GA AR5MG UT WOS:000343628100012 PM 25014883 ER PT J AU Livesay, RJ Blessinger, CS Guzzardo, TF Hausladen, PA AF Livesay, R. J. Blessinger, C. S. Guzzardo, T. F. Hausladen, P. A. TI Rain-induced increase in background radiation detected by Radiation Portal Monitors SO JOURNAL OF ENVIRONMENTAL RADIOACTIVITY LA English DT Article DE Environmental radiation; Portal monitors; Background radiation; Radioisotopes; Radon ID RAINWATER AB A complete understanding of both the steady state and transient background measured by Radiation Portal Monitors (RPMs) is essential to predictable system performance, as well as maximization of detection sensitivity. To facilitate this understanding, a test bed for the study of natural background in RPMs has been established at the Oak Ridge National Laboratory. This work was performed in support of the Second Line of Defense Program's mission to enhance partner country capability to deter, detect, and interdict the illicit movement of special nuclear material. In the present work, transient increases in gamma-ray counting rates in RPMs due to rain are investigated. The increase in background activity associated with rain, which has been well documented in the field of environmental radioactivity, originates primarily from the wet-deposition of two radioactive daughters of Rn-222, namely, Pb-214 and Bi-214. In this study, rainfall rates recorded by a co-located weather station are compared with RPM count rates and high-purity germanium spectra. The data verify that these radionuclides are responsible for the largest environmental background fluctuations in RPMs. Analytical expressions for the detector response function in Poly-Vinyl Toluene have been derived. Effects on system performance and potential mitigation strategies are discussed. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Livesay, R. J.] Mason Livesay Sci LLC, Knoxville, TN 37917 USA. [Blessinger, C. S.; Guzzardo, T. F.; Hausladen, P. A.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. RP Livesay, RJ (reprint author), Mason Livesay Sci LLC, 1519 Fremont Pl, Knoxville, TN 37917 USA. EM jake@masonlivesay.com FU UT-Battelle, LLC [DE-AC05-000R22725]; U.S. Department of Energy FX This manuscript has been authored by UT-Battelle, LLC, under Contract No. DE-AC05-000R22725 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. NR 8 TC 4 Z9 4 U1 3 U2 13 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0265-931X EI 1879-1700 J9 J ENVIRON RADIOACTIV JI J. Environ. Radioact. PD NOV PY 2014 VL 137 BP 137 EP 141 DI 10.1016/j.jenvrad.2014.07.010 PG 5 WC Environmental Sciences SC Environmental Sciences & Ecology GA AR5MG UT WOS:000343628100019 PM 25062116 ER PT J AU Zhao, P Tinnacher, RM Zavarin, M Kersting, AB AF Zhao, P. Tinnacher, R. M. Zavarin, M. Kersting, A. B. TI Analysis of trace neptunium in the vicinity of underground nuclear tests at the Nevada National Security Site SO JOURNAL OF ENVIRONMENTAL RADIOACTIVITY LA English DT Article DE Ultra-low level; Neptunium analysis; Environment; Nevada National Security Site; Retardation ID PLASMA-MASS SPECTROMETRY; ENVIRONMENTAL-SAMPLES; IRISH SEA; INTERTIDAL COASTAL; MARINE-ENVIRONMENT; GLOBAL FALLOUT; NP-237; PLUTONIUM; PU; BEHAVIOR AB A high sensitivity analytical method for Np-237 analysis was developed and applied to groundwater samples from the Nevada National Security Site (NNSS) using short-lived Np-239 as a yield tracer and HR magnetic sector ICP-MS. The Np-237 concentrations in the vicinity of the Almendro, Cambric, Dalhart, Cheshire, and Chancellor underground nuclear test locations range from <4 x 10(-4) to 2.6 mBq/L (6 x 10(-17)-4.2 x 10(-13) mol/L). All measured Np-237 concentrations are well below the drinking water maximum contaminant level for alpha emitters identified by the U.S. EPA (560 mBq/L). Nevertheless, Np-237 remains an important indicator for radionuclide transport rates at the NNSS. Retardation factor ratios were used to compare the mobility of Np-237 to that of other radionuclides. The results suggest that Np-237 is less mobile than tritium and other non-sorbing radionuclides (C-14, (CI)-C-36, Tc-99 and I-129) as expected. Surprisingly, Np-237 and plutonium (Pu-239,Pu-249) retardation factors are very similar. It is possible that Np(IV) exists under mildly reducing groundwater conditions and exhibits a retardation behavior that is comparable to Pu(IV). Independent of the underlying process, Np-237 is migrating downgradient from NNSS underground nuclear tests at very low but measureable concentrations. (C) 2014 The Authors. Published by Elsevier Ltd. C1 [Zhao, P.; Zavarin, M.; Kersting, A. B.] Lawrence Livermore Natl Lab, GT Seaborg Inst, Livermore, CA 94550 USA. [Zhao, P.; Zavarin, M.; Kersting, A. B.] Lawrence Livermore Natl Lab, Div Chem Sci, Livermore, CA 94550 USA. [Tinnacher, R. M.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Earth Sci, Berkeley, CA 94720 USA. RP Zhao, P (reprint author), Lawrence Livermore Natl Lab, GT Seaborg Inst, 7000 East Ave, Livermore, CA 94550 USA. EM zhao1@llnl.gov RI Tinnacher, Ruth/I-4845-2015 FU Underground Test Area Project, National Nuclear Security Administration Nevada Site Office - Subsurface Biogeochemical Research Program of the U.S. Department of Energy's Office of Biological and Environmental Research; U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344] FX Authors thank Dr. Ross Williams for ICP-MS analysis; Dr. Yunwei Sun for fruitful discussions and calculations of radiologic chain decay. This work was funded by the Underground Test Area Project, National Nuclear Security Administration Nevada Site Office; supported by the Subsurface Biogeochemical Research Program of the U.S. Department of Energy's Office of Biological and Environmental Research; and performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. NR 48 TC 6 Z9 6 U1 1 U2 28 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0265-931X EI 1879-1700 J9 J ENVIRON RADIOACTIV JI J. Environ. Radioact. PD NOV PY 2014 VL 137 BP 163 EP 172 DI 10.1016/j.jenvrad.2014.07.011 PG 10 WC Environmental Sciences SC Environmental Sciences & Ecology GA AR5MG UT WOS:000343628100022 PM 25078472 ER PT J AU Chiu, S Williams, PT Dawson, T Bergman, RN Stefanovski, D Watkins, SM Krauss, RM AF Chiu, Sally Williams, Paul T. Dawson, Taylor Bergman, Richard N. Stefanovski, Darko Watkins, Steven M. Krauss, Ronald M. TI Diets High in Protein or Saturated Fat Do Not Affect Insulin Sensitivity or Plasma Concentrations of Lipids and Lipoproteins in Overweight and Obese Adults SO JOURNAL OF NUTRITION LA English DT Article ID TYPE-2 DIABETES-MELLITUS; METABOLIC RISK-FACTORS; APOLIPOPROTEIN-A-I; BODY-MASS INDEX; BRANCHED-CHAIN; WEIGHT-LOSS; MONOUNSATURATED FAT; MEAT CONSUMPTION; AMINO-ACIDS; CARDIOVASCULAR RISK AB Background: Previous human studies reported inconsistent effects of dietary protein and branched-chain amino acids (BCAAs) on insulin action and glucose metabolism. Similarly, it is unclear whether saturated fat (SF) intake influences these metabolic variables. Objective: The objective of this study was to test the effects of high [30% of energy (%E)] vs. moderate (20%E) intakes of protein (primarily whey) on insulin action and lipid and lipoprotein concentrations in the context of both high (15%E) and low (7%E) SF diets. Methods: The study was conducted as a randomized controlled trial in 158 overweight and obese men and women. After a 4-wk baseline diet [55%E carbohydrate, 15%E protein, 30%E fat (7%E SF)), participants were randomly assigned to 4 wk of either the baseline diet or 1 of 4 test diets containing 35%E carbohydrate and either 20%E or 30%E protein and either 7%E or 15%E SF. Frequently sampled iv. glucose tolerance tests were administered after each dietary period. Results: Other than significantly higher fasting glucose concentrations for high vs. moderate protein intakes with a low-fat diet (difference +/- SE: 0.47 +/- 0.14 mmol/L; P = 0.001), there were no significant effects of dietary protein or SF on glucose metabolism, plasma insulin, or concentrations of lipids and lipoproteins. Changes in plasma BCAAs across all diets were negatively correlated with changes in the metabolic clearance rate of insulin (rho = -0.18, P = 0.03) and positively correlated with changes in the acute insulin response to glucose (rho = 0.15, P = 0.05). Conclusions: These findings suggest that short-term intake Of BCAAs can influence insulin dynamics. However, in this group of overweight and obese individuals, neither high protein nor SF intake affected insulin sensitivity or plasma concentrations of lipids and lipoproteins. This trial was registered at clinicaltrials.gov as NCT00508937. C1 [Chiu, Sally; Dawson, Taylor; Krauss, Ronald M.] Childrens Hosp Oakland Res Inst, Oakland, CA 94609 USA. [Williams, Paul T.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. [Bergman, Richard N.; Stefanovski, Darko] Cedars Sinai Med Ctr, Diabet & Obes Res Inst, Los Angeles, CA 90048 USA. [Watkins, Steven M.] Lipomics, West Sacramento, CA USA. RP Krauss, RM (reprint author), Childrens Hosp Oakland Res Inst, Oakland, CA 94609 USA. EM rkrauss@chori.org FU Dairy Management, Inc; National Center for Research Resources; National Center for Advancing Translational Sciences, NIH through UCSF-CTSI [UL1 RR024131] FX This research was funded by Dairy Management, Inc, and was also supported by the National Center for Research Resources and the National Center for Advancing Translational Sciences, NIH, through UCSF-CTSI grant UL1 RR024131. The contents of this article are solely the responsibility of the authors and do not necessarily represent the official views of the NIH. NR 67 TC 12 Z9 12 U1 0 U2 20 PU AMER SOC NUTRITION-ASN PI BETHESDA PA 9650 ROCKVILLE PIKE, BETHESDA, MD 20814 USA SN 0022-3166 EI 1541-6100 J9 J NUTR JI J. Nutr. PD NOV PY 2014 VL 144 IS 11 BP 1753 EP 1759 DI 10.3945/jn.114.197624 PG 7 WC Nutrition & Dietetics SC Nutrition & Dietetics GA AR6GN UT WOS:000343681400012 PM 25332473 ER PT J AU Hraber, P Korber, BT Lapedes, AS Bailer, RT Seaman, MS Gao, H Greene, KM McCutchan, F Williamson, C Kim, JH Tovanabutra, S Hahn, BH Swanstrom, R Thomson, MM Gao, F Harris, L Giorgi, E Hengartner, N Bhattacharya, T Mascola, JR Montefiori, DC AF Hraber, Peter Korber, Bette T. Lapedes, Alan S. Bailer, Robert T. Seaman, Michael S. Gao, Hongmei Greene, Kelli M. McCutchan, Francine Williamson, Carolyn Kim, Jerome H. Tovanabutra, Sodsai Hahn, Beatrice H. Swanstrom, Ronald Thomson, Michael M. Gao, Feng Harris, Linda Giorgi, Elena Hengartner, Nicholas Bhattacharya, Tanmoy Mascola, John R. Montefiori, David C. TI Impact of Clade, Geography, and Age of the Epidemic on HIV-1 Neutralization by Antibodies SO JOURNAL OF VIROLOGY LA English DT Article ID IMMUNODEFICIENCY-VIRUS TYPE-1; INJECTION-DRUG USERS; B-CELL RECEPTORS; EFFICACY TRIAL; ENVELOPE GLYCOPROTEINS; VACCINE DEVELOPMENT; IMMUNOGEN DESIGN; STRUCTURAL BASIS; FOUNDER VIRUS; ENV CLONES AB Neutralizing antibodies (nAbs) are a high priority for vaccines that aim to prevent the acquisition of HIV-1 infection. Vaccine effectiveness will depend on the extent to which induced antibodies neutralize the global diversity of circulating HIV-1 variants. Using large panels of genetically and geographically diverse HIV-1 Env-pseudotyped viruses and chronic infection plasma samples, we unambiguously show that cross-clade nAb responses are commonly induced in response to infection by any virus clade. Nonetheless, neutralization was significantly greater when the plasma clade matched the clade of the virus being tested. This within-clade advantage was diminished in older, more-diverse epidemics in southern Africa, the United States, and Europe compared to more recent epidemics in Asia. It was most pronounced for circulating recombinant form (CRF) 07_BC, which is common in China and is the least-divergent lineage studied; this was followed by the slightly more diverse Asian CRF01_AE. We found no evidence that transmitted/founder viruses are generally more susceptible to neutralization and are therefore easier targets for vaccination than chronic viruses. Features of the gp120 V1V2 loop, in particular, length, net charge, and number of N-linked glycans, were associated with Env susceptibility and plasma neutralization potency in a manner consistent with neutralization escape being a force that drives viral diversification and plasma neutralization breadth. The overall susceptibility of Envs and potencies of plasma samples were highly predictive of the neutralization outcome of any single virus-plasma combination. These findings highlight important considerations for the design and testing of candidate HIV-1 vaccines that aim to elicit effective nAbs. IMPORTANCE An effective HIV-1 vaccine will need to overcome the extraordinary variability of the virus, which is most pronounced in the envelope glycoproteins (Env), which are the sole targets for neutralizing antibodies (nAbs). Distinct genetic lineages, or clades, of HIV-1 occur in different locales that may require special consideration when designing and testing vaccines candidates. We show that nAb responses to HIV-1 infection are generally active across clades but are most potent within clades. Because effective vaccine-induced nAbs are likely to share these properties, optimal coverage of a particular clade or combination of clades may require clade-matched immunogens. Optimal within-clade coverage might be easier to achieve in regions such as China and Thailand, where the epidemic is more recent and the virus less diverse than in southern Africa, the United States, and Europe. Finally, features of the first and second hypervariable regions of gp120 (V1V2) may be critical for optimal vaccine design. C1 [Hraber, Peter; Korber, Bette T.; Lapedes, Alan S.; Giorgi, Elena; Hengartner, Nicholas; Bhattacharya, Tanmoy] Los Alamos Natl Lab, Los Alamos, NM 87544 USA. [Korber, Bette T.] New Mexico Consortium, Los Alamos, NM USA. [Bailer, Robert T.; Mascola, John R.] NIH, Vaccine Res Ctr, Bethesda, MD 20892 USA. [Seaman, Michael S.] Beth Israel Deaconess Med Ctr, Boston, MA 02215 USA. [Gao, Hongmei; Greene, Kelli M.; Gao, Feng; Montefiori, David C.] Duke Univ, Med Ctr, Durham, NC USA. [McCutchan, Francine; Kim, Jerome H.; Tovanabutra, Sodsai] Walter Reed Army Inst Res, US Mil HIV Res Program, Silver Spring, MD USA. [Williamson, Carolyn] Univ Cape Town, Inst Infect Dis & Mol Med, ZA-7925 Cape Town, South Africa. [Hahn, Beatrice H.] Univ Penn, Perelman Sch Med, Philadelphia, PA 19104 USA. [Swanstrom, Ronald] Univ N Carolina, Dept Microbiol & Immunol, Chapel Hill, NC USA. [Thomson, Michael M.] Inst Salud Carlos III, Ctr Nacl Microbiol, Madrid, Spain. [Harris, Linda] Fred Hutchinson Canc Res Ctr, Seattle, WA 98104 USA. [Bhattacharya, Tanmoy] Santa Fe Inst, Santa Fe, NM 87501 USA. RP Montefiori, DC (reprint author), Los Alamos Natl Lab, Los Alamos, NM 87544 USA. EM david.montefiori@duke.edu RI Bhattacharya, Tanmoy/J-8956-2013; OI Bhattacharya, Tanmoy/0000-0002-1060-652X; , Carolyn/0000-0003-0125-1226; Korber, Bette/0000-0002-2026-5757; Hraber, Peter/0000-0002-2920-4897 FU Bill & Melinda Gates Foundation [38619, 1032144] FX This work was funded by grants from the Bill & Melinda Gates Foundation, which established the Comprehensive Antibody Vaccine Immune Monitoring Consortium as part of the Collaboration for AIDS Vaccine Discovery (grants 38619 and 1032144). NR 111 TC 18 Z9 18 U1 1 U2 7 PU AMER SOC MICROBIOLOGY PI WASHINGTON PA 1752 N ST NW, WASHINGTON, DC 20036-2904 USA SN 0022-538X EI 1098-5514 J9 J VIROL JI J. Virol. PD NOV PY 2014 VL 88 IS 21 BP 12623 EP 12643 DI 10.1128/JVI.01705-14 PG 21 WC Virology SC Virology GA AR1BN UT WOS:000343314900038 PM 25142591 ER PT J AU Nicholl, M Smartt, SJ Jerkstrand, A Inserra, C Anderson, JP Baltay, C Benetti, S Chen, TW Elias-Rosa, N Feindt, U Fraser, M Gal-Yam, A Hadjiyska, E Howell, DA Kotak, R Lawrence, A Leloudas, G Margheim, S Mattila, S McCrum, M McKinnon, R Mead, A Nugent, P Rabinowitz, D Rest, A Smith, KW Sollerman, J Sullivan, M Taddia, F Valenti, S Walker, ES Young, DR AF Nicholl, M. Smartt, S. J. Jerkstrand, A. Inserra, C. Anderson, J. P. Baltay, C. Benetti, S. Chen, T. -W. Elias-Rosa, N. Feindt, U. Fraser, M. Gal-Yam, A. Hadjiyska, E. Howell, D. A. Kotak, R. Lawrence, A. Leloudas, G. Margheim, S. Mattila, S. McCrum, M. McKinnon, R. Mead, A. Nugent, P. Rabinowitz, D. Rest, A. Smith, K. W. Sollerman, J. Sullivan, M. Taddia, F. Valenti, S. Walker, E. S. Young, D. R. TI Superluminous supernovae from PESSTO SO MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY LA English DT Article DE supernovae: general; supernovae: individual: LSQ12dlf; supernovae: individual: SN 2013dg; supernovae: individual: SSS120810:231802-560926 ID X-RAY-EMISSION; LIGHT CURVES; LUMINOUS SUPERNOVAE; PAIR-INSTABILITY; CIRCUMSTELLAR MEDIUM; ANALYTIC SOLUTIONS; IC SUPERNOVAE; MASSIVE STARS; IA SUPERNOVA; EXPLOSION AB We present optical spectra and light curves for three hydrogen-poor superluminous supernovae followed by the Public ESO Spectroscopic Survey of Transient Objects (PESSTO). Time series spectroscopy from a fewdays aftermaximum light to 100 d later shows them to be fairly typical of this class, with spectra dominated by Ca II, MgII, FeII, and Si II, which evolve slowly over most of the post-peak photospheric phase. We determine bolometric light curves and apply simple fitting tools, based on the diffusion of energy input by magnetar spin-down, Ni-56 decay, and collision of the ejecta with an opaque circumstellar shell. We investigate how the heterogeneous light curves of our sample (combined with others from the literature) can help to constrain the possible mechanisms behind these events. We have followed these events to beyond 100-200 d after peak, to disentangle host galaxy light from fading supernova flux and to differentiate between the models, which predict diverse behaviour at this phase. Models powered by radioactivity require unrealistic parameters to reproduce the observed light curves, as found by previous studies. Both magnetar heating and circumstellar interaction still appear to be viable candidates. A large diversity is emerging in observed tail-phase luminosities, with magnetar models failing in some cases to predict the rapid drop in flux. This would suggest either that magnetars are not responsible, or that the X-ray flux from the magnetar wind is not fully trapped. The light curve of one object shows a distinct rebrightening at around 100 d after maximum light. We argue that this could result either from multiple shells of circumstellar material, or from a magnetar ionization front breaking out of the ejecta. C1 [Nicholl, M.; Smartt, S. J.; Jerkstrand, A.; Inserra, C.; Chen, T. -W.; Kotak, R.; McCrum, M.; Smith, K. W.; Young, D. R.] Queens Univ Belfast, Sch Math & Phys, Astrophys Res Ctr, Belfast BT7 1NN, Antrim, North Ireland. [Anderson, J. P.] European So Observ, Santiago 19, Chile. [Baltay, C.; Hadjiyska, E.; McKinnon, R.; Rabinowitz, D.; Walker, E. S.] Yale Univ, Dept Phys, New Haven, CT 06520 USA. [Benetti, S.; Elias-Rosa, N.] INAF Osservatorio Astron Padova, I-35122 Padua, Italy. [Feindt, U.] Univ Bonn, Inst Phys, D-53115 Bonn, Germany. [Fraser, M.] Univ Cambridge, Inst Astron, Cambridge CB3 0HA, England. [Gal-Yam, A.] Weizmann Inst Sci, Benoziyo Ctr Astrophys, IL-76100 Rehovot, Israel. [Howell, D. A.; Valenti, S.] Univ Calif Santa Barbara, Dept Phys, Santa Barbara, CA 93106 USA. [Howell, D. A.; Valenti, S.] Global Telescope Network, Las Cumbres Observ, Goleta, CA 93117 USA. [Lawrence, A.; Mead, A.] Univ Edinburgh, Royal Observ, Inst Astron, Edinburgh EH9 3HJ, Midlothian, Scotland. [Leloudas, G.] Stockholm Univ, Dept Phys, Oskar Klein Ctr, SE-10691 Stockholm, Sweden. [Leloudas, G.] Univ Copenhagen, Niels Bohr Inst, Dark Cosmol Ctr, DK-2100 Copenhagen, Denmark. [Margheim, S.] Southern Operat Ctr, Gemini Observ, La Serena, Chile. [Mattila, S.] Univ Turku, Finnish Ctr Astron ESO FINCA, FI-21500 Piikkio, Finland. [Nugent, P.] Univ Calif Berkeley, Dept Astron, Berkeley, CA 94720 USA. [Nugent, P.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Computat Res Div, Computat Cosmol Ctr, Berkeley, CA 94720 USA. [Rest, A.] Space Telescope Sci Inst, Baltimore, MD 21218 USA. [Sollerman, J.; Taddia, F.] Stockholm Univ, Dept Astron, Oskar Klein Ctr, SE-10691 Stockholm, Sweden. [Sullivan, M.] Univ Southampton, Sch Phys & Astron, Southampton SO17 1BJ, Hants, England. RP Nicholl, M (reprint author), Queens Univ Belfast, Sch Math & Phys, Astrophys Res Ctr, Belfast BT7 1NN, Antrim, North Ireland. EM mnicholl03@qub.ac.uk RI Jerkstrand, Anders/K-9648-2015; Elias-Rosa, Nancy/D-3759-2014; OI Mead, Alexander/0000-0003-3794-581X; Benetti, Stefano/0000-0002-3256-0016; Jerkstrand, Anders/0000-0001-8005-4030; Elias-Rosa, Nancy/0000-0002-1381-9125; Sollerman, Jesper/0000-0003-1546-6615; Chen, Ting-Wan/0000-0002-1066-6098; Kotak, Rubina/0000-0001-5455-3653; Inserra, Cosimo/0000-0002-3968-4409; Fraser, Morgan/0000-0003-2191-1674; Sullivan, Mark/0000-0001-9053-4820 FU PESSTO, ESO programme [188.D-3003]; ESO programmes [089.D-0270, 091.D-0749]; UK Science and Technology Facilities Council; Las Cumbres Observatory Global Telescope Network (LCOGTN); Gemini Observatory; European Research Council under the European Union [291222]; STFC; DEL NI; PRIN-INAF; project 'Transient Universe: from ESO Large to PESSTO'; European Union [320360, 267251]; 'The Quantum Universe' I-Core program by the Israeli Committee for planning and funding; ISF; GIF grant; Kimmel award FX This work is based on observations collected at the European Organisation for Astronomical Research in the Southern hemisphere, Chile, as part of PESSTO, ESO programme ID 188.D-3003. VLT+X-shooter spectra were obtained under ESO programmes 089.D-0270 and 091.D-0749. Other observations have been collected using: the 4.3 m WHT, operated on the island of La Palma by the Isaac Newton Group of Telescope; the Liverpool Telescope, which is operated by Liverpool John Moores University in the Spanish Observatorio del Roque de los Muchachos of the Instituto de Astrofisica de Canarias with financial support from the UK Science and Technology Facilities Council; the Las Cumbres Observatory Global Telescope Network (LCOGTN); the Gemini Observatory, which is operated by the Association of Universities for Research in Astronomy, Inc., under a cooperative agreement with the NSF on behalf of the Gemini partnership: the National Science Foundation (United States), the National Research Council (Canada), CONICYT (Chile), the Australian Research Council (Australia), Ministerio da Ciencia, Tecnologia e Inovacao (Brazil), and Ministerio de Ciencia, Tecnologia e Innovacion Productiva (Argentina). Research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP7/2007-2013)/ERC Grant agreement no. [291222] (PI SJS). We acknowledge funding from STFC and DEL NI. SB is partially supported by the PRIN-INAF 2011 with the project 'Transient Universe: from ESO Large to PESSTO'. MF was partly supported by the European Union FP7 programme through ERC grant number 320360. NER acknowledges the support from the European Union Seventh Framework Programme (FP7/2007-2013) under grant agreement no. 267251 'Astronomy Fellowships in Italy' (AstroFIt). AG-Y is supported by 'The Quantum Universe' I-Core program by the Israeli Committee for planning and funding and the ISF, a GIF grant, and the Kimmel award. NR 69 TC 47 Z9 48 U1 0 U2 1 PU OXFORD UNIV PRESS PI OXFORD PA GREAT CLARENDON ST, OXFORD OX2 6DP, ENGLAND SN 0035-8711 EI 1365-2966 J9 MON NOT R ASTRON SOC JI Mon. Not. Roy. Astron. Soc. PD NOV 1 PY 2014 VL 444 IS 3 BP 2096 EP 2113 DI 10.1093/mnras/stu1579 PG 18 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA AR2FS UT WOS:000343399600010 ER PT J AU Mehta, SL Dharap, A Vemuganti, R AF Mehta, Suresh L. Dharap, Ashutosh Vemuganti, Raghu TI Expression of transcribed ultraconserved regions of genome in rat cerebral cortex SO NEUROCHEMISTRY INTERNATIONAL LA English DT Article DE Brain; Non-coding RNA; lncRNA; Transcription; Gene expression ID LONG NONCODING RNAS; FOCAL ISCHEMIA; GENE DESERTS; CANCER; ELEMENTS; ENHANCER; CLASSIFICATION; EVOLUTION; SYSTEM; DNA AB Emerging evidence indicates that 481 regions of the genome (>200 bp) that actively transcribe noncoding RNAs shows 100% homology between humans, rats and mice. These transcribed ultraconserved regions (T-UCRs) are thought to control the essential regulatory functions basic for life in rodents and mammals. Using microarray analysis, we presently show that 107 T-UCRs are actively expressed in adult rat cerebral cortex. They are grouped into intragenic (61) and intergenic (46) based on their genic location. Interestingly, 10 T-UCRs are expressed at unusually high levels in cerebral cortex. Additionally, many T-UCRs also showed cogenic expression. We further analyzed the correlation of intragenic T-UCRs with their host protein coding genes. Surprisingly, most of the expressed intragenic T-UCRs (54 out of 61) displayed a negative correlation with their host gene expression. T-UCRs are thought to control the splicing and transcription of the protein-coding genes that host them and flank them. Bioinformatics analysis indicated that the protein products of majority of these genes are nuclear in localization, share protein domains and are involved in the regulation of diverse biological and molecular functions including metabolism, development, cell cycle, binding and transcription factor regulation. In conclusion, this is the first study to shows that many T-UCRs are expressed in rodent brain and they might play a role in physiological brain functions. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Mehta, Suresh L.; Dharap, Ashutosh; Vemuganti, Raghu] Univ Wisconsin, Dept Neurol Surg, Madison, WI USA. [Dharap, Ashutosh] Los Alamos Natl Lab, Los Alamos, NM USA. RP Vemuganti, R (reprint author), Dept Neurol Surg, Mail Code CSC-8660,600 Highland Ave, Madison, WI 53792 USA. EM Vemuganti@neurosurgery.wisc.edu FU NIH [NS061071, NS074444] FX The study was supported by NIH Grants NS061071 and NS074444. NR 39 TC 0 Z9 0 U1 0 U2 3 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0197-0186 EI 1872-9754 J9 NEUROCHEM INT JI Neurochem. Int. PD NOV PY 2014 VL 77 SI SI BP 86 EP 93 DI 10.1016/j.neuint.2014.06.006 PG 8 WC Biochemistry & Molecular Biology; Neurosciences SC Biochemistry & Molecular Biology; Neurosciences & Neurology GA AR5MH UT WOS:000343628200012 PM 24953281 ER PT J AU Khumalo, ZM Topic, M Comrie, CM Blumenthal, M Pineda-Vargas, CA Bucher, R Kisslinger, K AF Khumalo, Z. M. Topic, M. Comrie, C. M. Blumenthal, M. Pineda-Vargas, C. A. Bucher, R. Kisslinger, K. TI Effect of annealing on phase sequence and their composition in the Pt-coated Mo system SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS LA English DT Article DE Phase transformation; Rutherford backscattering spectrometry (RBS); X-ray diffraction (XRD); Transmission electron microscopy (TEM); Energy dispersive spectroscopy (EDS) ID MOLYBDENUM-PLATINUM SYSTEM; FORMATION MODEL; EFFECTIVE HEAT AB The phase formation sequence and the composition of phases induced by thermal annealing in a platinum (Pt) coated molybdenum (Mo) system were investigated by X-ray diffraction (XRD), Rutherford backscattering spectrometry (RBS) and transmission electron microscopy (TEM). The X-ray diffraction study of a 0.2 mu m thick platinum layer deposited on a Mo substrate and annealed at temperatures between 800 degrees C and 900 degrees C for different periods of time shows the formation of MoPt2 and MoPt phases. It was also found that these phases nucleate sequentially and the MoPt2 phase becomes unstable at 900 degrees C after a longer annealing time of 8 h. Rutherford backscattering spectroscopy and transmission electron microscopy showed that the coating thickness approximately doubled after thermal annealing, from 0.22 mu m to 0.46 mu m, due to the formation of the Pt Mo phases. (C) 2014 Elsevier B.V. All rights reserved. C1 [Khumalo, Z. M.; Comrie, C. M.; Blumenthal, M.] Univ Cape Town, Dept Phys, ZA-7701 Rondebosch, South Africa. [Khumalo, Z. M.; Topic, M.; Comrie, C. M.; Pineda-Vargas, C. A.; Bucher, R.] Natl Res Fdn, Mat Res Dept, iThemba LABS, Somerset West, South Africa. [Kisslinger, K.] Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11973 USA. RP Khumalo, ZM (reprint author), Univ Cape Town, Dept Phys, Private Bag X3, ZA-7701 Rondebosch, South Africa. EM zakhele@tlabs.ac.za RI Kisslinger, Kim/F-4485-2014 FU Mintek, Department of Science and Technology (DST); South African National Research Foundation (NRF) FX Mintek, Department of Science and Technology (DST) and South African National Research Foundation (NRF) for financial support, Center for Functional Nanomaterials (Brookhaven National Laboratory, USA), Electron Microscope Unit (University of Cape Town) and Electron Microscope Unit (University of the Western Cape) for the use of their facilities. NR 12 TC 0 Z9 0 U1 1 U2 9 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-583X EI 1872-9584 J9 NUCL INSTRUM METH B JI Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms PD NOV 1 PY 2014 VL 338 BP 8 EP 12 DI 10.1016/j.nimb.2014.07.029 PG 5 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Atomic, Molecular & Chemical; Physics, Nuclear SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AR2CE UT WOS:000343390400002 ER PT J AU Zhang, Y Crespillo, ML Xue, H Jin, K Chen, CH Fontana, CL Graham, JT Weber, WJ AF Zhang, Y. Crespillo, M. L. Xue, H. Jin, K. Chen, C. H. Fontana, C. L. Graham, J. T. Weber, W. J. TI New ion beam materials laboratory for materials modification and irradiation effects research SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS LA English DT Article DE Tandem accelerator; Ion beam analysis; Ion-solid interaction; Irradiation effects ID TIME-OF-FLIGHT; RECOIL DETECTION ANALYSIS; SURFACE-LAYERS; LIGHT-ELEMENTS; ALPHA-QUARTZ; ENERGY LOSS; HEAVY-IONS; TOF-ERDA; RESOLUTION; DETECTOR AB A new multifunctional ion beam materials laboratory (IBML) has been established at the University of Tennessee, in partnership with Oak Ridge National Laboratory. The IBML is currently equipped with two ion sources, a 3 MV tandem accelerator, three beamlines and three endstations. The IBML is primarily dedicated to fundamental research on ion solid interaction, ion beam analysis, ion beam modification, and other basic and applied research on irradiation effects in a wide range of materials. An overview of the IBML facility is provided, and experimental results are reported to demonstrate the specific capabilities. (C) 2014 Elsevier B.V. All rights reserved. C1 [Zhang, Y.; Fontana, C. L.; Weber, W. J.] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA. [Zhang, Y.; Crespillo, M. L.; Xue, H.; Jin, K.; Chen, C. H.; Graham, J. T.; Weber, W. J.] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA. RP Zhang, Y (reprint author), Oak Ridge Natl Lab, MS 6138, Oak Ridge, TN 37831 USA. EM Zhangy1@ornl.gov; wjweber@utk.edu RI Weber, William/A-4177-2008 OI Weber, William/0000-0002-9017-7365 FU UT-ORNL Governor's Chair program; U.S. Department of Energy (DOE), Nuclear Energy University Programs; U.S. DOE Office of Basic Energy Sciences (BES), Materials Sciences & Engineering Division (MSED); U.S. DOE, BES, MSED; U.S. Department of Defense (DOD), Defense Threat Reduction Agency (DTRA), Research and Development (R&D) Enterprise, Basic and Applied Sciences Directorate; ORNL LDRD for the TOF ERDA development FX The UT-ORNL Ion Beam Materials Laboratory (IBML) was established with support from the UT-ORNL Governor's Chair program. The development of the high temperature endstation (L3) was supported by an infrastructure grant from the U.S. Department of Energy (DOE), Nuclear Energy University Programs. Y. Zhang is grateful to the Presidential Early Career Award for Scientists and Engineers (PECASE) support through the U.S. DOE Office of Basic Energy Sciences (BES), Materials Sciences & Engineering Division (MSED). Y. Zhang, C.L. Fontana and W.J. Weber were partially supported by the U.S. DOE, BES, MSED in the development and demonstration of unique capabilities for damage accumulation studies. K. Jin and Y. Zhang acknowledge the support on energy loss determination from the U.S. Department of Defense (DOD), Defense Threat Reduction Agency (DTRA), Research and Development (R&D) Enterprise, Basic and Applied Sciences Directorate. C.L. Fontana was partially supported by ORNL LDRD for the TOF ERDA development. Y. Zhang is also grateful to the assistance and support from Gregory A. Norton, Jeremy Kasmarek, and Dan Bernhardt at National Electrostatics Corp. NR 55 TC 20 Z9 20 U1 0 U2 13 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-583X EI 1872-9584 J9 NUCL INSTRUM METH B JI Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms PD NOV 1 PY 2014 VL 338 BP 19 EP 30 DI 10.1016/j.nimb.2014.07.028 PG 12 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Atomic, Molecular & Chemical; Physics, Nuclear SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AR2CE UT WOS:000343390400004 ER PT J AU Hattar, K Bufford, DC Buller, DL AF Hattar, K. Bufford, D. C. Buller, D. L. TI Concurrent in situ ion irradiation transmission electron microscope SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS LA English DT Article DE In situ transmission electron microscopy (TEM); Single ion strike; Radiation effects; Ion irradiation; Extreme environments ID DISLOCATION LOOPS; ISOTOPE SEPARATOR; TEM OBSERVATIONS; EVOLUTION; ALLOYS; DAMAGE; IMPLANTATION; CASCADES; HYDROGEN; DEFECTS AB An in situ ion irradiation transmission electron microscope has been developed and is operational at Sandia National Laboratories. This facility permits high spatial resolution, real time observation of electron transparent samples under ion irradiation, implantation, mechanical loading, corrosive environments, and combinations thereof. This includes the simultaneous implantation of low-energy gas ions (0.8-30 key) during high-energy heavy ion irradiation (0.8-48 MeV). Initial results in polycrystalline gold foils are provided to demonstrate the range of capabilities. (C) 2014 The Authors. Published by Elsevier B.V. C1 [Hattar, K.; Bufford, D. C.; Buller, D. L.] Sandia Natl Labs, Dept Radiat Solid Interact, Livermore, CA 94550 USA. RP Hattar, K (reprint author), Sandia Natl Labs, Dept Radiat Solid Interact, Livermore, CA 94550 USA. EM khattar@sandia.gov FU US Department of Energy, Office of Basic Energy Sciences; U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX The authors would like to thank J.P. Allain, C.M. Barr, B.L. Boyce, T.J. Boyle, C. Chisholm, B.G. Clark, J.S. Custer, B.L. Doyle, O. El-Atwani, B.A. Hernandez-Sanchez, J.A. Hinks, P. Hosemann, A. Kinghom, M. Kirk, N. Li, T. Lagrange, A. Lupinacci, M. Marshall, D. Masiel, M. Mecklenbrug, A. Minor, A. Misra, S.H. Pratt, J.A. Scott, D.K. Serkland, J.A. Sharon, M. Steckbeck, M.L. Taheri, G.A. Vetterick, J. Vilone, G. Vizkelethy, W. Wampler, and B. Yates for their advice and assistance in the development of this facility. This work was partially supported by the US Department of Energy, Office of Basic Energy Sciences. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. NR 54 TC 19 Z9 19 U1 2 U2 42 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-583X EI 1872-9584 J9 NUCL INSTRUM METH B JI Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms PD NOV 1 PY 2014 VL 338 BP 56 EP 65 DI 10.1016/j.nimb.2014.08.002 PG 10 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Atomic, Molecular & Chemical; Physics, Nuclear SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AR2CE UT WOS:000343390400009 ER PT J AU Scandale, W Arduini, G Butcher, M Cerutti, F Gilardoni, S Lari, L Lechner, A Losito, R Masi, A Mereghetti, A Metral, E Mirarchi, D Montesano, S Redaelli, S Schoofs, P Smirnov, G Bagli, E Bandiera, L Baricordi, S Dalpiaz, P Guidi, V Mazzolari, A Vincenzi, D Claps, G Dabagov, S Hampai, D Murtas, F Cavoto, G Garattini, M Iacoangeli, F Ludovici, L Santacesaria, R Valente, P Galluccio, F Afonin, AG Chesnokov, YA Maisheev, VA Sandomirskiy, YE Yanovich, AA Yazynin, LA Kovalenko, A Taratin, AM Gavrikov, YA Ivanov, YM Lapina, LP Ferguson, W Fulcheri, J Hall, G Pesaresi, M Raymond, M Previtali, V AF Scandale, W. Arduini, G. Butcher, M. Cerutti, F. Gilardoni, S. Lari, L. Lechner, A. Losito, R. Masi, A. Mereghetti, A. Metral, E. Mirarchi, D. Montesano, S. Redaelli, S. Schoofs, P. Smirnov, G. Bagli, E. Bandiera, L. Baricordi, S. Dalpiaz, P. Guidi, V. Mazzolari, A. Vincenzi, D. Claps, G. Dabagov, S. Hampai, D. Murtas, F. Cavoto, G. Garattini, M. Iacoangeli, F. Ludovici, L. Santacesaria, R. Valente, P. Galluccio, F. Afonin, A. G. Chesnokov, Yu. A. Maisheev, V. A. Sandomirskiy, Yu. E. Yanovich, A. A. Yazynin, L. A. Kovalenko, Ad. Taratin, A. M. Gavrikov, Yu. A. Ivanov, Yu. M. Lapina, L. P. Ferguson, W. Fulcheri, J. Hall, G. Pesaresi, M. Raymond, M. Previtali, V. TI Deflection of high energy protons by multiple volume reflections in a modified multi-strip silicon deflector SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS LA English DT Article DE Accelerator; Beam collimation; Crystal; Channeling; Volume reflection ID BENT CRYSTALS; CHARGED-PARTICLES; SEQUENCE; BEAMS AB The effect of multiple volume reflections in one crystal was observed in each of several bent silicon strips for 400 GeV/c protons. This considerably increased the particle deflections. Some particles were also deflected due to channeling in one of the subsequent strips. As a result, the incident beam was strongly spread because of opposite directions of the deflections. A modified multi-strip deflector produced by periodic grooves on the surface of a thick silicon plate was used for these measurements. This technique provides perfect mutual alignment between crystal strips. Such multi-strip deflector may be effective for collider beam halo collimation and a study is planned at the CERN SPS circulating beam. (C) 2014 Elsevier B.V. All rights reserved. C1 [Scandale, W.; Arduini, G.; Butcher, M.; Cerutti, F.; Gilardoni, S.; Lari, L.; Lechner, A.; Losito, R.; Masi, A.; Mereghetti, A.; Metral, E.; Mirarchi, D.; Montesano, S.; Redaelli, S.; Schoofs, P.; Smirnov, G.] CERN, European Org Nucl Res, CH-1211 Geneva 23, Switzerland. [Scandale, W.] Univ Paris Sud Orsay, LAL, Orsay, France. [Bagli, E.; Bandiera, L.; Baricordi, S.; Dalpiaz, P.; Guidi, V.; Mazzolari, A.; Vincenzi, D.] Univ Ferrara, Ist Nazl Fis Nucl, Dipartimento Fis, Sez Ferrara, I-44100 Ferrara, Italy. [Claps, G.; Dabagov, S.; Hampai, D.; Murtas, F.] Ist Nazl Fis Nucl, Lab Nazl Frascati, I-00044 Frascati, Roma, Italy. [Scandale, W.; Cavoto, G.; Garattini, M.; Iacoangeli, F.; Ludovici, L.; Santacesaria, R.; Valente, P.] Ist Nazl Fis Nucl, Sez Roma, I-00185 Rome, Italy. [Galluccio, F.] Ist Nazl Fis Nucl, Sez Napoli, Naples, Italy. [Afonin, A. G.; Chesnokov, Yu. A.; Maisheev, V. A.; Sandomirskiy, Yu. E.; Yanovich, A. A.; Yazynin, L. A.] Inst High Energy Phys, RU-142284 Protvino, Russia. [Kovalenko, Ad.; Taratin, A. M.] Joint Inst Nucl Res, Dubna 141980, Moscow Region, Russia. [Gavrikov, Yu. A.; Ivanov, Yu. M.; Lapina, L. P.] Petersburg Nucl Phys Inst, Gatchina 188300, Leningrad Regio, Russia. [Mirarchi, D.; Ferguson, W.; Fulcheri, J.; Hall, G.; Pesaresi, M.; Raymond, M.] Univ London Imperial Coll Sci Technol & Med, London, England. [Previtali, V.] Fermilab Natl Accelerator Lab, Batavia, IL 60510 USA. [Lari, L.] Inst Fis Corpuscular, CSIC, IFIC, Valencia, Spain. [Dabagov, S.] PN Lebedev Phys Inst, Moscow 117924, Russia. [Dabagov, S.] NRNU MEPhl, Moscow, Russia. RP Taratin, AM (reprint author), Joint Inst Nucl Res, Joliot Curie 6, Dubna 141980, Moscow Region, Russia. RI valente, paolo/A-6640-2010; Bagli, Enrico/E-5906-2012; Ludovici, Lucio/F-5917-2011; Murtas, Fabrizio/B-5729-2012; Dabagov, Sultan/M-6425-2015; Mazzolari, Andrea/A-1100-2017; OI valente, paolo/0000-0002-5413-0068; Bagli, Enrico/0000-0003-3913-7701; Ludovici, Lucio/0000-0003-1970-9960; Dabagov, Sultan/0000-0003-3087-1205; Mazzolari, Andrea/0000-0003-0804-6778; guidi, vincenzo/0000-0001-9726-8481; Murtas, Fabrizio/0000-0002-7041-6541; Cavoto, Gianluca/0000-0003-2161-918X FU Russian Foundation for Basic Research [05-02-17622, 06-02-16912]; RF President Foundation [SS-3383.2010.2]; LHC Program of Presidium of Russian Academy of Sciences; Grant RFBR-CERN [12-02-91532]; MIUR [FIRB RBFR085MOL_001/I11J10000090001]; Ministry of Education and Science of RF [02.A03.21.0005]; EuCARD program within the "Collimators and Materials for high power beams" work package (Colmat-WP) [GA 227579]; UK Science and Technology Facilities Council FX We wish to acknowledge the strong support of the CERN EN-STI and BE-AOP groups. We also acknowledge the partial support by the Russian Foundation for Basic Research Grants 05-02-17622 and 06-02-16912, the RF President Foundation Grant SS-3383.2010.2, the "LHC Program of Presidium of Russian Academy of Sciences" and the Grant RFBR-CERN 12-02-91532. G. Cavoto, F. Iacoangeli and R. Santacesaria acknowledge the support from MIUR (Grant FIRB RBFR085MOL_001/I11J10000090001). S. Dabagov acknowledges the support by the Ministry of Education and Science of RF in the frames of Competitiveness Growth Program of NRNU MEPhI, Agreement 02.A03.21.0005. Work supported by the EuCARD program GA 227579, within the "Collimators and Materials for high power beams" work package (Colmat-WP). The Imperial College group gratefully acknowledges support from the UK Science and Technology Facilities Council. NR 22 TC 1 Z9 1 U1 0 U2 7 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-583X EI 1872-9584 J9 NUCL INSTRUM METH B JI Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms PD NOV 1 PY 2014 VL 338 BP 108 EP 111 DI 10.1016/j.nimb.2014.08.013 PG 4 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Atomic, Molecular & Chemical; Physics, Nuclear SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AR2CE UT WOS:000343390400016 ER PT J AU Schwehr, KA Otosaka, S Merchel, S Kaplan, DI Zhang, S Xu, C Li, HP Ho, YF Yeager, CM Santschi, PH AF Schwehr, Kathleen A. Otosaka, Shigeyoshi Merchel, Silke Kaplan, Daniel I. Zhang, Saijin Xu, Chen Li, Hsiu-Ping Ho, Yi-Fang Yeager, Chris M. Santschi, Peter H. CA ASTER Team TI Speciation of iodine isotopes inside and outside of a contaminant plume at the Savannah River Site SO SCIENCE OF THE TOTAL ENVIRONMENT LA English DT Article DE Radioiodine (I-129); Iodide; Iodate; Organo-iodine; Accelerator mass spectrometer (AMS) Iodine speciation ID ENVIRONMENTAL TRACER; MASS-SPECTROMETRY; RADIOIODINE I-129; ORGANIC-MATTER; GROUNDWATER; I-129/I-127; FACILITIES; MOBILITY; WATERS; AMS AB A primary obstacle in understanding the fate and transport of the toxic radionuclide I-129 (a thyroid seeker) is an accurate method to distinguish it from the stable isotope, I-127, and to quantify the various species at environmentally relevant concentrations (similar to 10(-8) M). A pH-dependent solvent extraction and combustion method was paired with accelerator mass spectrometry (AMS) to measure ambient levels of I-129/I-127 isotope ratios and iodine speciation (iodide (I-), iodate (IO3-), and organo-I (OI)) in aquatic systems. The method exhibited an overall uncertainty of 10% or less for I- and IO3- and less than 30% for OI species concentrations and enabled I-129 measurements as low as 0.001 Bq/L (I Bq/L = 10(-13) M). The method was used to analyze groundwater from the Savannah River Site (SRS), South Carolina, USA, along a pH, redox potential (Eh), and organic carbon gradient (8-60 mu M DOC). The data confirmed that the I-129/I-127 ratios and species distribution were strongly pH dependent and varied in a systematic manner from the strongly acidic source. While I-129 speciation in plume samples containing total I concentrations >1.7 Bq/L was similar whether measured by AMS or GC-MS ([I-] >> [IO3-] = [OI]), AMS enabled I-129 speciation measurements at much lower concentrations than what was possible with GC-MS. AMS analyses demonstrated that groundwater samples minimally impacted by the plume were still orders of magnitude higher than ambient I-129 concentrations typically found elsewhere in the USA groundwaters and rivers. This is likely due to past atmospheric releases of volatile I-129 species by SRS nuclear reprocessing facilities near the study site. Furthermore, the results confirmed the existence of I-129 not only as I-, but also as OI and IO3- species. (C) 2014 Elsevier B.V. All rights reserved. C1 [Schwehr, Kathleen A.; Otosaka, Shigeyoshi; Zhang, Saijin; Xu, Chen; Li, Hsiu-Ping; Ho, Yi-Fang; Santschi, Peter H.] Texas A&M Univ, Dept Marine Sci, Lab Oceanog & Environm Res, Galveston, TX 77553 USA. [Otosaka, Shigeyoshi] Japan Atom Energy Agcy, Res Grp Environm Sci, Tokai, Ibaraki 3191195, Japan. [Merchel, Silke] Helmholtz Zentrum Dresden Rossendorf, D-01328 Dresden, Germany. [Kaplan, Daniel I.] Savannah River Natl Lab, Aiken, SC 29808 USA. [Yeager, Chris M.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [ASTER Team] Aix Marseille Univ, ASTER Team, CEREGE, CNRS IRD UM 34, F-13545 Aix En Provence, France. RP Schwehr, KA (reprint author), Texas A&M Univ, Dept Marine Sci, Lab Oceanog & Environm Res, OCSB 3029,200 Seawolf Pkwy, Galveston, TX 77553 USA. OI Santschi, Peter/0000-0001-8188-7691 FU INSU/CNRS; French Ministry of Research and Higher Education; IRD; CEA; German-French exchange program (DAAD) [500 888 61, 22077QC]; German-French exchange program (EGIDE) [500 888 61, 22077QC]; US Department of Energy's (DOE) Subsurface Biogeochemical Research (SBR) Program within the Office of Science [ER65222-1038426-0017532] FX We would like to thank E. Nottoli for her valuable assistance during the AMS measurements that were performed at the French AMS national facility ASTER (CEREGE, Aix-en-Provence) which is supported by the INSU/CNRS, the French Ministry of Research and Higher Education, the IRD and the CEA. This work was partially funded by a German-French exchange program (DAAD and EGIDE) (500 888 61 and 22077QC), and the US Department of Energy's (DOE) Subsurface Biogeochemical Research (SBR) Program within the Office of Science (ER65222-1038426-0017532). NR 33 TC 1 Z9 1 U1 1 U2 27 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0048-9697 EI 1879-1026 J9 SCI TOTAL ENVIRON JI Sci. Total Environ. PD NOV 1 PY 2014 VL 497 BP 671 EP 678 DI 10.1016/j.scitotenv.2014.07.006 PG 8 WC Environmental Sciences SC Environmental Sciences & Ecology GA AR5GM UT WOS:000343613100072 PM 25173764 ER PT J AU Budiman, AS Illya, G Handara, V Caldwell, WA Bonelli, C Kunz, M Tamura, N Verstraeten, D AF Budiman, A. S. Illya, G. Handara, V. Caldwell, W. A. Bonelli, C. Kunz, M. Tamura, N. Verstraeten, D. TI Enabling thin silicon technologies for next generation c-Si solar PV renewable energy systems using synchrotron X-ray microdiffraction as stress and crack mechanism probe SO SOLAR ENERGY MATERIALS AND SOLAR CELLS LA English DT Article DE Thin silicon; Solar cell; Synchrotron X-ray microdiffraction; Stress; Fracture ID RELIABILITY AB Recently, there has been a strong commercial push toward thinner silicon in the solar photovoltaic (PV) technologies due to the significant cost reduction associated with it. Tensile stress (normal, in-plane) and fracture of the silicon cells are increasingly observed and reported for products of crystalline solar cell technologies. In an effort to shed light on these topics, stress measurements and mapping of the solar cells in the vicinity of the most typically observed crack initiation locations using synchrotron X-ray microdiffraction technique was conducted and are reported in this paper. The technique is unique as it has the capabilities to quantitatively determine stresses in silicon and to map these stresses with a micron resolution, all while the silicon cells are already encapsulated. With this technique, we aim to gain fundamental understanding of the stress magnitudes as well as characteristics that could lead to crack initiation and propagation. We have thus far found evidences of both extrinsic (device related) as well as intrinsic (crystallographic) nature of silicon cracking, which further confirm that the control of mechanical stress is the key to enable thin silicon solar cell technologies in the coming years. This study represents an ongoing high impact technology research that addresses real and important fundamental materials issue facing the crystalline silicon solar PV industry and contributes directly to the industry drive to reduce cost of PV systems to grid parity. (C) 2014 Elsevier B.V. All rights reserved. C1 [Budiman, A. S.] SUTD, EPD Pillar, Singapore 138682, Singapore. [Illya, G.; Handara, V.] Surya Univ, Ctr Solar Photovolta Mat & Technol CPV, Summarecon Serpong 15810, Tangerang, Indonesia. [Budiman, A. S.; Caldwell, W. A.] SunPower Corp, R&D, San Jose, CA 95134 USA. [Bonelli, C.; Verstraeten, D.] TOTAL Gas & Power, R&D Div, F-92400 Courbevoie, France. [Kunz, M.; Tamura, N.] Lawrence Berkeley Natl Lab, ALS, Berkeley, CA 94720 USA. RP Budiman, AS (reprint author), SUTD, EPD Pillar, 20 Dover Dr, Singapore 138682, Singapore. EM suriadi@alumni.stanford.edu FU Sun Power Corporation; Surya University through the Center for Solar Photovoltaics Materials and Technology (CPV); Office of Science, Office of Basic Energy Sciences, Materials Sciences Division of the U.S.Department of Energy at Lawrence Berkeley National Laboratory [DE-AC02-05CH11231]; University of California, Berkeley, California; NSF [0416243] FX ASB gratefully acknowledges research support and samples provided by Sun Power Corporation. He also gratefully acknowledges critical support and infrastructure provided by Singapore University of Technology and Design (SUTD) during the writing of this manuscript. GI and VH gratefully acknowledge research support and infrastructure provided by Surya University through the Center for Solar Photovoltaics Materials and Technology (CPV; www.cpv-surya.corn).; The Advanced Light Source is supported by the Director, Office of Science, Office of Basic Energy Sciences, Materials Sciences Division of the U.S.Department of Energy under Contract no. DE-AC02-05CH11231 at Lawrence Berkeley National Laboratory and University of California, Berkeley, California.; The move of the micro-diffraction program from ALS beamline 7.3.3 onto to the ALS superbend source 12.3.2 was enabled through the NSF Grant no. 0416243. NR 17 TC 20 Z9 20 U1 2 U2 15 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0927-0248 EI 1879-3398 J9 SOL ENERG MAT SOL C JI Sol. Energy Mater. Sol. Cells PD NOV PY 2014 VL 130 SI SI BP 303 EP 308 DI 10.1016/j.solmat.2014.07.029 PG 6 WC Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied SC Energy & Fuels; Materials Science; Physics GA AR5GH UT WOS:000343612600038 ER PT J AU Choi, SG Kim, TJ Hwang, SY Li, J Persson, C Kim, YD Wei, SH Repins, IL AF Choi, S. G. Kim, T. J. Hwang, S. Y. Li, J. Persson, C. Kim, Y. D. Wei, S. -H. Repins, I. L. TI Temperature dependent band-gap energy for Cu2ZnSnSe4: A spectroscopic ellipsometric study SO SOLAR ENERGY MATERIALS AND SOLAR CELLS LA English DT Article DE Cu2ZnSnSe4 solar cell; Spectroscopic ellipsometry; Band-gap energy ID DIELECTRIC FUNCTION; SOLAR-CELLS; FILMS; SEMICONDUCTORS; EFFICIENCY; MODEL; IV; VI AB Spectroscopic ellipsometry (SE) is used to study the dependence of the band-gap energy for Cu2ZnSnSe4 (CZTSe) on temperature ranging from 50 to 350 K. A CZTSe thin film prepared by the pseudo-bulk approach allows direct observation of the fundamental band-gap E-0(A,B) in the SE data without need for multi-layer modeling. We obtain accurate energy values for E-0(A,B) and its spin-orbit splitting component E-0(C) from standard lineshape analysis of the second-energy-derivative spectra. The E-0(A,B) and E-0(C) energies for CZTSe decrease with increasing temperature, as for many semiconductors, but their temperature dependencies are relatively weak. Our experimental observation can be explained in terms of relatively small change in bond-length and strong p-d states coupling at the valence band maximum. (C) 2014 Elsevier B.V. All rights reserved. C1 [Choi, S. G.; Kim, T. J.; Wei, S. -H.; Repins, I. L.] Natl Renewable Energy Lab, Golden, CO 80401 USA. [Kim, T. J.; Hwang, S. Y.; Kim, Y. D.] Kyung Hee Univ, Dept Phys, Seoul 130701, South Korea. [Li, J.] Univ Toledo, Dept Phys & Astron, Toledo, OH 43606 USA. [Persson, C.] Univ Oslo, Dept Phys, N-0316 Oslo, Norway. RP Choi, SG (reprint author), Natl Renewable Energy Lab, Golden, CO 80401 USA. EM sukgeun.choi@nrel.gov FU U.S. Department of Energy [DE-AC36-08-GO28308]; National Renewable Energy Laboratory; National Research Foundation of Korea (NRF) grant - Korea government (MSIP) [2013-016297] FX This work was supported by the U.S. Department of Energy under Contract no. DE-AC36-08-GO28308 with the National Renewable Energy Laboratory. The work done at Kyung Hee University was supported by the National Research Foundation of Korea (NRF) grant funded through the Korea government (MSIP) (Grant no. 2013-016297). The work at the University of Oslo was done with HPC resources at USIT through NOTUR. NR 29 TC 15 Z9 15 U1 4 U2 33 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0927-0248 EI 1879-3398 J9 SOL ENERG MAT SOL C JI Sol. Energy Mater. Sol. Cells PD NOV PY 2014 VL 130 SI SI BP 375 EP 379 DI 10.1016/j.solmat.2014.07.039 PG 5 WC Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied SC Energy & Fuels; Materials Science; Physics GA AR5GH UT WOS:000343612600047 ER PT J AU Sinsabaugh, RL Belnap, J Findlay, SG Shah, JJF Hill, BH Kuehn, KA Kuske, CR Litvak, ME Martinez, NG Moorhead, DL Warnock, DD AF Sinsabaugh, Robert L. Belnap, Jayne Findlay, Stuart G. Shah, Jennifer J. Follstad Hill, Brian H. Kuehn, Kevin A. Kuske, Cheryl R. Litvak, Marcy E. Martinez, Noelle G. Moorhead, Daryl L. Warnock, Daniel D. TI Extracellular enzyme kinetics scale with resource availability SO BIOGEOCHEMISTRY LA English DT Article DE Ecological stoichiometry; Extracellular enzymes; Enzyme kinetics; Microbial community; Microbial metabolism ID SOIL ORGANIC-MATTER; CARBON-MONOXIDE CONSUMPTION; METHANE-OXIDIZING BACTERIA; ECOENZYMATIC STOICHIOMETRY; RIVERINE BACTERIOPLANKTON; TEMPERATURE SENSITIVITY; EXOPROTEOLYTIC ACTIVITY; THEORETICAL-MODEL; TROPHIC GRADIENT; SIZE FRACTIONS AB Microbial community metabolism relies on external digestion, mediated by extracellular enzymes that break down complex organic matter into molecules small enough for cells to assimilate. We analyzed the kinetics of 40 extracellular enzymes that mediate the degradation and assimilation of carbon, nitrogen and phosphorus by diverse aquatic and terrestrial microbial communities (1160 cases). Regression analyses were conducted by habitat (aquatic and terrestrial), enzyme class (hydrolases and oxidoreductases) and assay methodology (low affinity and high affinity substrates) to relate potential reaction rates to substrate availability. Across enzyme classes and habitats, the scaling relationships between apparent V-max and apparent K-m followed similar power laws with exponents of 0.44 to 0.67. These exponents, called elasticities, were not statistically distinct from a central value of 0.50, which occurs when the K-m of an enzyme equals substrate concentration, a condition optimal for maintenance of steady state. We also conducted an ecosystem scale analysis of ten extracellular hydrolase activities in relation to soil and sediment organic carbon (2,000-5,000 cases/enzyme) that yielded elasticities near 1.0 (0.9 +/- A 0.2, n = 36). At the metabolomic scale, the elasticity of extracellular enzymatic reactions is the proportionality constant that connects the C:N:P stoichiometries of organic matter and ecoenzymatic activities. At the ecosystem scale, the elasticity of extracellular enzymatic reactions shows that organic matter ultimately limits effective enzyme binding sites. Our findings suggest that one mechanism by which microbial communities maintain homeostasis is regulating extracellular enzyme expression to optimize the short-term responsiveness of substrate acquisition. The analyses also show that, like elemental stoichiometry, the fundamental attributes of enzymatic reactions can be extrapolated from biochemical to community and ecosystem scales. C1 [Sinsabaugh, Robert L.; Litvak, Marcy E.; Martinez, Noelle G.; Warnock, Daniel D.] Univ New Mexico, Dept Biol, Albuquerque, NM 87131 USA. [Belnap, Jayne] US Geol Survey, Southwest Biol Sci Ctr, Moab, UT 84532 USA. [Findlay, Stuart G.] Cary Inst Ecosyst Studies, Millbrook, NY 12545 USA. [Shah, Jennifer J. Follstad] Utah State Univ, Watershed Sci Dept, Logan, UT 84322 USA. [Hill, Brian H.] US EPA, Natl Hlth & Environm Effects Lab, Midcontinent Ecol Div, Off Res & Dev, Duluth, MN 55804 USA. [Kuehn, Kevin A.] Univ So Mississippi, Dept Biol Sci, Hattiesburg, MS 39406 USA. [Kuske, Cheryl R.] Los Alamos Natl Lab, Biosci Div, Los Alamos, NM USA. [Moorhead, Daryl L.] Univ Toledo, Dept Environm Sci, Toledo, OH 43606 USA. RP Sinsabaugh, RL (reprint author), Univ New Mexico, Dept Biol, Albuquerque, NM 87131 USA. EM rlsinsab@unm.edu FU NSF Ecosystem Sciences program [DEB-0918718]; Sevilleta LTER Program; NSF [DEB-0315686, DBI-0420965, DBI-0521018]; Michigan Sea Grant College Program under NOAA [NA76RG0133]; DOE BER Science Focus Area grant; DOE BER [DE-SC0008088] FX RLS acknowledges support from the NSF Ecosystem Sciences program (DEB-0918718) and the Sevilleta LTER Program. KAK acknowledges support from NSF (DEB-0315686, DBI-0420965, DBI-0521018) and the Michigan Sea Grant College Program (NA76RG0133) under NOAA. CRK acknowledges support from a DOE BER Science Focus Area grant. MEL and RLS acknowledge support from DOE BER Grant number DE-SC0008088. Mention of trade names or commercial products does not constitute endorsement or recommendation for use. NR 94 TC 15 Z9 15 U1 22 U2 123 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0168-2563 EI 1573-515X J9 BIOGEOCHEMISTRY JI Biogeochemistry PD NOV PY 2014 VL 121 IS 2 BP 287 EP 304 DI 10.1007/s10533-014-0030-y PG 18 WC Environmental Sciences; Geosciences, Multidisciplinary SC Environmental Sciences & Ecology; Geology GA AQ9BL UT WOS:000343135800001 ER PT J AU Acerbo, AS Kwaczala, AT Yang, L Judex, S Miller, LM AF Acerbo, Alvin S. Kwaczala, Andrea T. Yang, Lin Judex, Stefan Miller, Lisa M. TI Alterations in Collagen and Mineral Nanostructure Observed in Osteoporosis and Pharmaceutical Treatments Using Simultaneous Small- and Wide-Angle X-ray Scattering SO CALCIFIED TISSUE INTERNATIONAL LA English DT Article DE Bone nanostructure; Osteoporosis; X-ray scattering; Synchrotron; Microbeam mapping ID BONE MINERALIZATION; FLUORIDE TREATMENT; CANCELLOUS BONE; CORTICAL BONE; SODIUM-FLUORIDE; RATS; ALENDRONATE; CRYSTALS; STRENGTH; POROSITY AB The influence of the macroscale material properties of bone on its mechanical competence has been extensively investigated, but less is known about possible contributions from bone's nanoscale material properties. These nanoscale properties, particularly the collagen network and the size and shape of hydroxyapatite mineral crystals, may be affected by aging, mechanical loading, and diseases including osteoporosis. Here, changes to the collagen and mineral properties of cortical bone induced by osteoporosis and subsequent pharmaceutical treatments were investigated by simultaneous small- and wide-angle X-ray scattering (SAXS/WAXS) microbeam mapping. Adult rats (6 months old) were ovariectomized and treated with alendronate, parathyroid hormone, or sodium fluoride, and compared to untreated ovariectomized and age-matched controls. Scattering data from tibial cortical bone showed that osteoporosis increased collagen alignment in existing intracortical bone, while this effect was mitigated in the alendronate and sodium fluoride groups though by different mechanisms. Further, mineral crystal lengths in newly formed cortical bone were smaller in animals with osteoporosis, but existing cortical bone was not altered. Subsequent treatment with alendronate mitigated changes in crystal lengths. Together, these results suggest that osteoporosis may alter the collagen alignment and mineral geometry in bone formed before and after the onset of this disease, and that osteoporosis treatments may differentially rescue these changes. C1 [Acerbo, Alvin S.; Kwaczala, Andrea T.; Judex, Stefan; Miller, Lisa M.] SUNY Stony Brook, Dept Biomed Engn, Stony Brook, NY 11794 USA. [Acerbo, Alvin S.; Yang, Lin; Miller, Lisa M.] Brookhaven Natl Lab, Photon Sci Directorate, Upton, NY 11973 USA. RP Miller, LM (reprint author), Brookhaven Natl Lab, Photon Sci Directorate, Upton, NY 11973 USA. EM lmiller@bnl.gov FU National Institutes of Health [AR052778]; U.S. Department of Energy [DE-AC02-98CH10886] FX This work was funded by the National Institutes of Health Grant AR052778. The National Synchrotron Light Source is supported by the U.S. Department of Energy under Contract No. DE-AC02-98CH10886. NR 46 TC 3 Z9 3 U1 2 U2 13 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0171-967X EI 1432-0827 J9 CALCIFIED TISSUE INT JI Calcif. Tissue Int. PD NOV PY 2014 VL 95 IS 5 BP 446 EP 456 DI 10.1007/s00223-014-9913-0 PG 11 WC Endocrinology & Metabolism SC Endocrinology & Metabolism GA AQ8OW UT WOS:000343088500008 PM 25190190 ER PT J AU Dixon, DA Katz, A Arslan, I Gates, BC AF Dixon, David A. Katz, Alexander Arslan, Ilke Gates, Bruce C. TI Beyond Relationships Between Homogeneous and Heterogeneous Catalysis SO CATALYSIS LETTERS LA English DT Editorial Material DE Catalysis; Enzymatic catalysis; Heterogeneous catalysis; Homogeneous catalysis; Singlesite catalysts ID METATHESIS CATALYSTS; BOND-ENERGIES; NOBEL LECTURE; CLUSTERS; ZEOLITE; LIGANDS; COMPLEX; SITE; SPECTROSCOPY; IR-6 C1 [Dixon, David A.] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA. [Katz, Alexander] Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA. [Arslan, Ilke] Pacific NW Natl Lab, Fundamental & Computat Sci Directorate, Richland, WA 99352 USA. [Gates, Bruce C.] Univ Calif Davis, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA. RP Gates, BC (reprint author), Univ Calif Davis, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA. EM bcgates@ucdavis.edu NR 30 TC 1 Z9 1 U1 2 U2 53 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1011-372X EI 1572-879X J9 CATAL LETT JI Catal. Lett. PD NOV PY 2014 VL 144 IS 11 BP 1785 EP 1789 DI 10.1007/s10562-014-1332-3 PG 5 WC Chemistry, Physical SC Chemistry GA AQ9BN UT WOS:000343136100001 ER PT J AU Wang, HL An, K Sapi, A Liu, FD Somorjai, GA AF Wang, Hailiang An, Kwangjin Sapi, Andras Liu, Fudong Somorjai, Gabor A. TI Effects of Nanoparticle Size and Metal/Support Interactions in Pt-Catalyzed Methanol Oxidation Reactions in Gas and Liquid Phases SO CATALYSIS LETTERS LA English DT Article DE Heterogeneous catalysis; Nanoparticles; Alcohol oxidation ID OXYGEN REDUCTION REACTION; PLATINUM NANOPARTICLES; PARTICLE-SIZE; MESOPOROUS SILICA; HYDROGENATION; SELECTIVITY; MECHANISM; SURFACES; KINETICS; CARBON AB We compare catalytic methanol oxidation reactions in the gas and liquid phases by focusing on the kinetic effects of platinum nanoparticle size and metal/support interactions. Under the reaction conditions at 60 A degrees C, methanol can be oxidized to multiple products including carbon dioxide (full-oxidation product), formaldehyde (partial-oxidation product) and methyl formate (partial-oxidation and coupling product). We use 2, 4, 6 and 8 nm platinum nanoparticles supported on mesoporous silica as catalysts to study the size effect, and 2.5 nm platinum nanoparticles supported on mesoporous SiO2, Co3O4, MnO2, Fe2O3, NiO and CeO2 to study the metal/oxide interface effect. We find that all three products are formed with comparable selectivities in the gas phase, but in the liquid phase formaldehyde is the dominant product. While the influence of size on activity is not substantial in the gas phase, the liquid-phase reaction rates monotonically increase by a factor of 6 in the size range of 2-8 nm. The reaction rates in the gas phase are dramatically affected by the strong interactions between the platinum nanoparticles and transition metal oxide supports. While the Pt/MnO2 is 135 times less active, the Pt/CeO2 is 12 times more active, both compared to the Pt/SiO2. However in the liquid phase, the support effect is less significant, with the most active catalyst Pt/MnO2 exhibiting an enhancement factor of 2.5 compared to the Pt/SiO2. Our results suggest that the kinetic effects of platinum nanoparticle size and metal/support interactions can be totally different between the solid/gas and solid/liquid interfaces even for the same chemical reaction. C1 [Wang, Hailiang; An, Kwangjin; Sapi, Andras; Liu, Fudong; Somorjai, Gabor A.] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA. [Wang, Hailiang; An, Kwangjin; Sapi, Andras; Liu, Fudong; Somorjai, Gabor A.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA. [Wang, Hailiang; An, Kwangjin; Sapi, Andras; Liu, Fudong; Somorjai, Gabor A.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA. RP Somorjai, GA (reprint author), Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA. EM somorjai@berkeley.edu RI Liu, Fudong/H-2050-2012; Sapi, Andras/G-3527-2015 OI Sapi, Andras/0000-0001-6557-0731 FU Division of Chemical Sciences, Geological and Biosciences of the U.S. Department of Energy [DE-AC02-05CH11231]; Philomathia Postdoctoral Fellowship FX This work is supported by the Director, Office of Basic Energy Sciences, Materials Science and Engineering Division and the Division of Chemical Sciences, Geological and Biosciences of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. H. W. acknowledges support from the Philomathia Postdoctoral Fellowship. NR 30 TC 6 Z9 7 U1 10 U2 139 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1011-372X EI 1572-879X J9 CATAL LETT JI Catal. Lett. PD NOV PY 2014 VL 144 IS 11 BP 1930 EP 1938 DI 10.1007/s10562-014-1347-9 PG 9 WC Chemistry, Physical SC Chemistry GA AQ9BN UT WOS:000343136100018 ER PT J AU O'Connor, BL Hamada, Y Bowen, EE Grippo, MA Hartmann, HM Patton, TL Van Lonkhuyzen, RA Carr, AE AF O'Connor, Ben L. Hamada, Yuki Bowen, Esther E. Grippo, Mark A. Hartmann, Heidi M. Patton, Terri L. Van Lonkhuyzen, Robert A. Carr, Adrianne E. TI Quantifying the sensitivity of ephemeral streams to land disturbance activities in arid ecosystems at the watershed scale SO ENVIRONMENTAL MONITORING AND ASSESSMENT LA English DT Article DE Ephemeral streams; Land disturbance; Arid ecosystems; Watershed characteristics; Environmental assessment ID UNITED-STATES; RIPARIAN VEGETATION; MANAGEMENT; RECHARGE; FLOOD; ADJUSTMENT; LINKAGES; CHANNELS; ARIZONA; IMPACTS AB Large areas of public lands administered by the Bureau of Land Management and located in arid regions of the southwestern United States are being considered for the development of utility-scale solar energy facilities. Land-disturbing activities in these desert, alluvium-filled valleys have the potential to adversely affect the hydrologic and ecologic functions of ephemeral streams. Regulation and management of ephemeral streams typically falls under a spectrum of federal, state, and local programs, but scientifically based guidelines for protecting ephemeral streams with respect to land-development activities are largely nonexistent. This study developed an assessment approach for quantifying the sensitivity to land disturbance of ephemeral stream reaches located in proposed solar energy zones (SEZs). The ephemeral stream assessment approach used publicly-available geospatial data on hydrology, topography, surficial geology, and soil characteristics, as well as high-resolution aerial imagery. These datasets were used to inform a professional judgment-based score index of potential land disturbance impacts on selected critical functions of ephemeral streams, including flow and sediment conveyance, ecological habitat value, and groundwater recharge. The total sensitivity scores (sum of scores for the critical stream functions of flow and sediment conveyance, ecological habitats, and groundwater recharge) were used to identify highly sensitive stream reaches to inform decisions on developable areas in SEZs. Total sensitivity scores typically reflected the scores of the individual stream functions; some exceptions pertain to groundwater recharge and ecological habitats. The primary limitations of this assessment approach were the lack of high-resolution identification of ephemeral stream channels in the existing National Hydrography Dataset, and the lack of mechanistic processes describing potential impacts on ephemeral stream functions at the watershed scale. The primary strength of this assessment approach is that it allows watershed-scale planning for low-impact development in arid ecosystems; the qualitative scoring of potential impacts can also be adjusted to accommodate new geospatial data, and to allow for expert and stakeholder input into decisions regarding the identification and potential avoidance of highly sensitive stream reaches. C1 [O'Connor, Ben L.; Hamada, Yuki; Bowen, Esther E.; Grippo, Mark A.; Hartmann, Heidi M.; Patton, Terri L.; Van Lonkhuyzen, Robert A.; Carr, Adrianne E.] Argonne Natl Lab, Div Environm Sci, Argonne, IL 60439 USA. RP O'Connor, BL (reprint author), Univ Illinois, Dept Civil & Mat Engn, Chicago, IL 60607 USA. EM oconnorb@uic.edu FU US Department of the Interior, Bureau of Land Management through US Department of Energy [DE-AC02-06CH11357] FX Funding for this project was supported by the US Department of the Interior, Bureau of Land Management, under interagency agreement, through US Department of Energy contract DE-AC02-06CH11357. We would also like to thank two anonymous reviewers for comments that improved the quality of this manuscript. NR 52 TC 2 Z9 2 U1 4 U2 23 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0167-6369 EI 1573-2959 J9 ENVIRON MONIT ASSESS JI Environ. Monit. Assess. PD NOV PY 2014 VL 186 IS 11 BP 7075 EP 7095 DI 10.1007/s10661-014-3912-5 PG 21 WC Environmental Sciences SC Environmental Sciences & Ecology GA AQ8CU UT WOS:000343051400008 PM 25129382 ER PT J AU Kratochwil, C Giesel, FL Bruchertseifer, F Mier, W Apostolidis, C Boll, R Murphy, K Haberkorn, U Morgenstern, A AF Kratochwil, C. Giesel, F. L. Bruchertseifer, F. Mier, W. Apostolidis, C. Boll, R. Murphy, K. Haberkorn, U. Morgenstern, A. TI Bi-213-DOTATOC receptor-targeted alpha-radionuclide therapy induces remission in neuroendocrine tumours refractory to beta radiation: a first-in-human experience SO EUROPEAN JOURNAL OF NUCLEAR MEDICINE AND MOLECULAR IMAGING LA English DT Article DE Targeted alpha therapy (TAT); Bi-213; Ac-225; DOTATOC ID SOMATOSTATIN-ANALOG; MYELOID-LEUKEMIA; AC-225; GA-68-DOTATOC; Y-90-DOTATOC; COMBINATION; METASTASES; DOSIMETRY; TOXICITY; ARTERIAL AB Purpose Radiopeptide therapy using a somatostatin analogue labelled with a beta emitter such as Y-90/Lu-177-DOTATOC is a new therapeutic option in neuroendocrine cancer. Alternative treatments for patients with refractory disease are rare. Here we report the first-in-human experience with Bi-213-DOTATOC targeted alpha therapy (TAT) in patients pretreated with beta emitters. Methods Seven patients with progressive advanced neuroendocrine liver metastases refractory to treatment with Y-90/Lu-177-DOTATOC were treated with an intraarterial infusion of Bi-213-DOTATOC, and one patient with bone marrow carcinosis was treated with a systemic infusion of Bi-213-DOTATOC. Haematological, kidney and endocrine toxicities were assessed according to CTCAE criteria. Radiological response was assessed with contrast-enhanced MRI and Ga-68-DOTATOC-PET/CT. More than 2 years of follow-up were available in seven patients. Results The biodistribution of Bi-213-DOTATOC was evaluable with 440 keV gamma emission scans, and demonstrated specific tumour binding. Enduring responses were observed in all treated patients. Chronic kidney toxicity was moderate. Acute haematotoxicity was even less pronounced than with the preceding beta therapies. Conclusion TAT can induce remission of tumours refractory to beta radiation with favourable acute and mid-term toxicity at therapeutic effective doses. C1 [Kratochwil, C.; Giesel, F. L.; Mier, W.; Haberkorn, U.] Univ Heidelberg Hosp, Dept Nucl Med, D-69120 Heidelberg, Germany. [Bruchertseifer, F.; Apostolidis, C.; Morgenstern, A.] Commiss European Communities, Inst Transuranium Elements, Karlsruhe, Germany. [Boll, R.; Murphy, K.] Oak Ridge Natl Lab, Oak Ridge, TN USA. RP Kratochwil, C (reprint author), Univ Heidelberg Hosp, Dept Nucl Med, INF 400, D-69120 Heidelberg, Germany. EM clemens.kratochwil@t-online.de RI Boll, Rose/C-4138-2016 OI Boll, Rose/0000-0003-2507-4834 NR 41 TC 33 Z9 33 U1 2 U2 20 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1619-7070 EI 1619-7089 J9 EUR J NUCL MED MOL I JI Eur. J. Nucl. Med. Mol. Imaging PD NOV PY 2014 VL 41 IS 11 BP 2106 EP 2119 DI 10.1007/s00259-014-2857-9 PG 14 WC Radiology, Nuclear Medicine & Medical Imaging SC Radiology, Nuclear Medicine & Medical Imaging GA AQ8CX UT WOS:000343051700014 PM 25070685 ER PT J AU Kapuscinski, KL Farrell, JM Stehman, SV Boyer, GL Fernando, DD Teece, MA Tschaplinski, TJ AF Kapuscinski, Kevin L. Farrell, John M. Stehman, Stephen V. Boyer, Gregory L. Fernando, Danilo D. Teece, Mark A. Tschaplinski, Timothy J. TI Selective herbivory by an invasive cyprinid, the rudd Scardinius erythrophthalmus SO FRESHWATER BIOLOGY LA English DT Article DE macrophytes; phenolic compounds; rudd; selective herbivory ID FRESH-WATER MACROPHYTES; P-COUMARIC ACID; GRASS CARP; AQUATIC MACROPHYTES; FEEDING PREFERENCES; SUBMERGED MACROPHYTES; SPECIES COMPOSITION; EXOTIC HERBIVORES; ROSMARINIC ACID; CAFFEIC ACID AB 1. Herbivory by non-native animals is a problem of growing concern globally, especially for ecosystems where there were few native herbivores or where they have been replaced by non-natives. The rudd (Scardinius erythrophthalmus) is an omnivorous cyprinid (native to Europe) now very widespread due to human introductions, yet it is unknown whether the invasive rudd feeds selectively among aquatic macrophyte species common in North America. 2. We tested feeding selectivity by rudd using five species of aquatic macrophytes: Ceratophyllum demersum, Elodea canadensis, Najas flexilis, Stuckenia pectinata and Vallisneria americana. Fish were presented with known quantities of each macrophyte species in a randomized complete block design, and we measured the mean per cent mass remaining in each case. We also quantified differences in the chemical attributes of the five macrophyte species and determined whether feeding by rudd was related to dry matter content (DMC), per cent C by dry mass (% C), per cent N by dry mass (% N), and the concentrations of total soluble proteins, two organic acids (aconitic and oxalic acid), total soluble phenolic compounds (< 1000 Da), nine soluble phenolic metabolites and total phenolic compounds. 3. Rudd fed selectively, with consumption declining in the order N. flexilis > E. canadensis > S. pectinata > V. americana > C. demersum. Selection was positively related to % C and atomic C : N, but not DMC, % N or concentration of total soluble proteins, contrary to the expectation that rudd would select the most nutritious plants available. The concentration of aconitic acid was greatest in N. flexilis, a preferred macrophyte, contrary to the expectation that this compound provides resistance to herbivory. The concentration of oxalic acid, which negatively affects palatability, was highest in C. demersum, the least preferred macrophyte. 4. Selection was also positively related to the concentration of total (and some specific) soluble phenolic compounds. The concentrations of caffeic acid, trans-caftaric acid and quercetin were positively related to macrophyte preference by rudd, whereas concentrations of cis-4-O- and trans-4-O-ferulic acid glucoside were negatively related. 5. Selective feeding by rudd (which can be very numerous in North American fresh waters) could evidently alter macrophyte assemblages and hinder attempts to restore plant communities. C1 [Kapuscinski, Kevin L.; Farrell, John M.; Fernando, Danilo D.] SUNY Coll Environm Sci & Forestry, Dept Environm & Forest Biol, Syracuse, NY 13210 USA. [Stehman, Stephen V.] SUNY Coll Environm Sci & Forestry, Dept Forest & Nat Resources Management, Syracuse, NY 13210 USA. [Boyer, Gregory L.; Teece, Mark A.] SUNY Coll Environm Sci & Forestry, Dept Chem, Syracuse, NY 13210 USA. [Tschaplinski, Timothy J.] Oak Ridge Natl Lab, Biosci Div, Oak Ridge, TN USA. RP Kapuscinski, KL (reprint author), Lake Super State Univ, Sch Biol Sci, CRW225,650 W Easterday Ave, Sault Sainte Marie, MI 49783 USA. EM kkapuscinski@lssu.edu OI Tschaplinski, Timothy/0000-0002-9540-6622 FU Niagara River Ecological Standing Committee, Fish and Wildlife Habitat Enhancement and Restoration Fund FX Alexander Karatayev provided access to the indoor laboratory at the State University of New York-Buffalo State Great Lakes Center and Mark Clapsadl provided expertise in setting up the laboratory, which made this study possible. We thank Michael Wilkinson (New York State Department of Environmental Conservation) for his assistance collecting rudd, Andrew Panczykowski (State University of New York College of Environmental Science and Forestry) for his assistance collecting rudd, macrophytes, and data during the selection experiment and Robert Johnson (Racine-Johnson Aquatic Ecologists) for verifying the species of macrophytes used in this research. Kathleen Baier, Thomas Horton and William Powell (State University of New York College of Environmental Science and Forestry) provided essential access to laboratory equipment and their expertise. We are grateful to Jessica Bouchard (State University of New York College of Environmental Science and Forestry), Jesse Crandall (State University of New York College of Environmental Science and Forestry) and Nancy Engle (Oak Ridge National Laboratory) for conducting analyses on the chemical attributes of macrophytes. Comments from three anonymous referees greatly improved the final version of this paper. A grant from the Niagara River Ecological Standing Committee, Fish and Wildlife Habitat Enhancement and Restoration Fund supported this research. NR 63 TC 9 Z9 9 U1 3 U2 29 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0046-5070 EI 1365-2427 J9 FRESHWATER BIOL JI Freshw. Biol. PD NOV PY 2014 VL 59 IS 11 BP 2315 EP 2327 DI 10.1111/fwb.12433 PG 13 WC Marine & Freshwater Biology SC Marine & Freshwater Biology GA AQ8BP UT WOS:000343047000009 ER PT J AU Rieger, CG Scheidt, DH Smart, WD AF Rieger, Craig G. Scheidt, David H. Smart, William D. TI Guest Editorial: Introduction to the Special Issue on Resilient Control Architectures and Systems SO IEEE TRANSACTIONS ON CYBERNETICS LA English DT Editorial Material C1 [Rieger, Craig G.] Idaho Natl Lab, Idaho Falls, ID 83415 USA. [Scheidt, David H.] Johns Hopkins Univ, Appl Phys Lab, Laurel, MD 20723 USA. [Smart, William D.] Oregon State Univ, Corvallis, OR 97331 USA. RP Rieger, CG (reprint author), Idaho Natl Lab, Idaho Falls, ID 83415 USA. NR 2 TC 1 Z9 1 U1 0 U2 1 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 2168-2267 EI 2168-2275 J9 IEEE T CYBERNETICS JI IEEE T. Cybern. PD NOV PY 2014 VL 44 IS 11 SI SI BP 1994 EP 1996 DI 10.1109/TCYB.2014.2339951 PG 3 WC Computer Science, Artificial Intelligence; Computer Science, Cybernetics SC Computer Science GA AR1CT UT WOS:000343319700001 ER PT J AU Garcia, HE Lin, WC Meerkov, SM Ravichandran, MT AF Garcia, Humberto E. Lin, Wen-Chiao Meerkov, Semyon M. Ravichandran, Maruthi T. TI Resilient Monitoring Systems: Architecture, Design, and Application to Boiler/Turbine Plant SO IEEE TRANSACTIONS ON CYBERNETICS LA English DT Article DE Cyber attacks; data quality assessment; measure of resiliency; resilient monitoring systems; sensor networks AB Resilient monitoring systems, considered in this paper, are sensor networks that degrade gracefully under malicious attacks on their sensors, causing them to project misleading information. The goal of this paper is to design, analyze, and evaluate the performance of a resilient monitoring system intended to monitor plant conditions (normal or anomalous). The architecture developed consists of four layers: data quality assessment, process variable assessment, plant condition assessment, and sensor network adaptation. Each of these layers is analyzed by either analytical or numerical tools. The performance of the overall system is evaluated using a simplified boiler/turbine plant. The measure of resiliency is quantified based on the Kullback-Leibler divergence and shown to be sufficiently high in all scenarios considered. C1 [Garcia, Humberto E.; Lin, Wen-Chiao] Idaho Natl Lab, Idaho Falls, ID 83415 USA. [Meerkov, Semyon M.; Ravichandran, Maruthi T.] Univ Michigan, Dept Elect Engn & Comp Sci, Ann Arbor, MI 48109 USA. RP Garcia, HE (reprint author), Idaho Natl Lab, Idaho Falls, ID 83415 USA. EM humberto.garcia@inl.gov; wen-chiao.lin@inl.gov; smm@umich.edu; marutrav@umich.edu FU U.S. Department of Energy under DOE [DE-AC07-05ID14517] FX This work was supported by the U.S. Department of Energy under DOE Contract DE-AC07-05ID14517 and performed as a part of the Instrumentation, Control, and Intelligent Systems (ICIS) initiative at the Idaho National Laboratory. This paper was recommended by Associate Editor W. Smart. NR 25 TC 2 Z9 2 U1 0 U2 6 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 2168-2267 EI 2168-2275 J9 IEEE T CYBERNETICS JI IEEE T. Cybern. PD NOV PY 2014 VL 44 IS 11 SI SI BP 2010 EP 2023 DI 10.1109/TCYB.2014.2316003 PG 14 WC Computer Science, Artificial Intelligence; Computer Science, Cybernetics SC Computer Science GA AR1CT UT WOS:000343319700003 PM 24816628 ER PT J AU Wijayasekara, D Linda, O Manic, M Rieger, C AF Wijayasekara, Dumidu Linda, Ondrej Manic, Milos Rieger, Craig TI FN-DFE: Fuzzy-Neural Data Fusion Engine for Enhanced Resilient State-Awareness of Hybrid Energy Systems SO IEEE TRANSACTIONS ON CYBERNETICS LA English DT Article DE Artificial neural networks; data fusion; fuzzy logic systems; resilient control systems; state-awareness ID NUCLEAR-POWER-PLANT; MULTISENSOR DATA FUSION; DECISION-SUPPORT; FAULT-DIAGNOSIS; EXPERT-SYSTEM; NETWORKS; IDENTIFICATION; PREDICTION; ALGORITHM AB Resiliency and improved state-awareness of modern critical infrastructures, such as energy production and industrial systems, is becoming increasingly important. As control systems become increasingly complex, the number of inputs and outputs increase. Therefore, in order to maintain sufficient levels of state-awareness, a robust system state monitoring must be implemented that correctly identifies system behavior even when one or more sensors are faulty. Furthermore, as intelligent cyber adversaries become more capable, incorrect values may be fed to the operators. To address these needs, this paper proposes a fuzzy-neural data fusion engine (FN-DFE) for resilient state-awareness of control systems. The designed FN-DFE is composed of a three-layered system consisting of: 1) traditional threshold based alarms; 2) anomalous behavior detector using self-organizing fuzzy logic system; and 3) artificial neural network-based system modeling and prediction. The improved control system state-awareness is achieved via fusing input data from multiple sources and combining them into robust anomaly indicators. In addition, the neural network-based signal predictions are used to augment the resiliency of the system and provide coherent state-awareness despite temporary unavailability of sensory data. The proposed system was integrated and tested with a model of the Idaho National Laboratory's hybrid energy system facility known as HYTEST. Experiment results demonstrate that the proposed FN-DFE provides timely plant performance monitoring and anomaly detection capabilities. It was shown that the system is capable of identifying intrusive behavior significantly earlier than conventional threshold-based alarm systems. C1 [Wijayasekara, Dumidu; Manic, Milos] Univ Idaho, Dept Comp Sci, Idaho Falls, ID 83402 USA. [Linda, Ondrej] Expedia Inc, Bellevue, WA 98004 USA. [Rieger, Craig] Idaho Natl Lab, Idaho Falls, ID 83402 USA. RP Wijayasekara, D (reprint author), Univ Idaho, Dept Comp Sci, Idaho Falls, ID 83402 USA. EM dumidu.wijayasekara@gmail.com; olindaczech@gmail.com; misko@ieee.org; craig.rieger@inl.gov RI Wijayasekara, Dumidu/E-6346-2017 FU U.S. Department of Energy under DOE Idaho Operations Office [DE-AC07-05ID14517] FX This work was supported by the U.S. Department of Energy under DOE Idaho Operations Office Contract DE-AC07-05ID14517. This paper was recommended by Associate Editor W. Smart. NR 41 TC 8 Z9 8 U1 2 U2 13 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 2168-2267 EI 2168-2275 J9 IEEE T CYBERNETICS JI IEEE T. Cybern. PD NOV PY 2014 VL 44 IS 11 SI SI BP 2065 EP 2075 DI 10.1109/TCYB.2014.2323891 PG 11 WC Computer Science, Artificial Intelligence; Computer Science, Cybernetics SC Computer Science GA AR1CT UT WOS:000343319700007 PM 24893372 ER PT J AU Bhatia, H Pascucci, V Bremer, PT AF Bhatia, Harsh Pascucci, Valerio Bremer, Peer-Timo TI The Natural Helmholtz-Hodge Decomposition for Open-Boundary Flow Analysis SO IEEE TRANSACTIONS ON VISUALIZATION AND COMPUTER GRAPHICS LA English DT Article DE The Helmholtz-Hodge decomposition; vector fields; boundary conditions; uniqueness; harmonic flows ID DIRECT NUMERICAL-SIMULATION; VECTOR FIELD DECOMPOSITION; NAVIER-STOKES EQUATIONS; PROJECTION METHOD; HEATED COFLOW; JET FLAME; STABILIZATION; MOTION; IMAGE AB The Helmholtz-Hodge decomposition (HHD), which describes a flow as the sum of an incompressible, an irrotational, and a harmonic flow, is a fundamental tool for simulation and analysis. Unfortunately, for bounded domains, the HHD is not uniquely defined, traditionally, boundary conditions are imposed to obtain a unique solution. However, in general, the boundary conditions used during the simulation may not be known known, or the simulation may use open boundary conditions. In these cases, the flow imposed by traditional boundary conditions may not be compatible with the given data, which leads to sometimes drastic artifacts and distortions in all three components, hence producing unphysical results. This paper proposes the natural HHD, which is defined by separating the flow into internal and external components. Using a completely data-driven approach, the proposed technique obtains uniqueness without assuming boundary conditions a priori. As a result, it enables a reliable and artifact-free analysis for flows with open boundaries or unknown boundary conditions. Furthermore, our approach computes the HHD on a point-wise basis in contrast to the existing global techniques, and thus supports computing inexpensive local approximations for any subset of the domain. Finally, the technique is easy to implement for a variety of spatial discretizations and interpolated fields in both two and three dimensions. C1 [Bhatia, Harsh; Pascucci, Valerio; Bremer, Peer-Timo] Univ Utah, Sci Comp & Imaging Inst, Salt Lake City, UT 84112 USA. [Bhatia, Harsh; Bremer, Peer-Timo] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. RP Bhatia, H (reprint author), Univ Utah, Sci Comp & Imaging Inst, Salt Lake City, UT 84112 USA. EM hbhatia@sci.utah.edu; pascucci@sci.utah.edu; ptbremer@sci.utah.edu FU US Department of Energy (DOE) by Lawrence Livermore National Laboratory (LLNL) [DE-AC52-07NA27344. LLNL-JRNL-644755] FX The authors are grateful to Jacqueline Chen from the Sandia National Laboratory for the data used for Figs. 8 and 11. The data used in Fig. 7 has been simulated by Mahsa Mirzargar using Nektar++ [44], and the data in Fig. 10 by Alexander Wiebel using NaSt3DGP. The authors also thank Mathew Maltude from the Climate, Ocean and Sea Ice Modelling program at Los Alamos National Laboratory and the BER Office of Science UV-CDAT team for providing us access to the ocean data from Fig. 12. This work was performed under the auspices of the US Department of Energy (DOE) by Lawrence Livermore National Laboratory (LLNL) under contract DE-AC52-07NA27344. LLNL-JRNL-644755. NR 42 TC 3 Z9 3 U1 1 U2 4 PU IEEE COMPUTER SOC PI LOS ALAMITOS PA 10662 LOS VAQUEROS CIRCLE, PO BOX 3014, LOS ALAMITOS, CA 90720-1314 USA SN 1077-2626 EI 1941-0506 J9 IEEE T VIS COMPUT GR JI IEEE Trans. Vis. Comput. Graph. PD NOV PY 2014 VL 20 IS 11 BP 1566 EP 1578 DI 10.1109/TVCG.2014.2312012 PG 13 WC Computer Science, Software Engineering SC Computer Science GA AQ7OX UT WOS:000343009400008 PM 26355335 ER PT J AU Carriero, A Zimmermann, EA Shefelbine, SJ Ritchie, RO AF Carriero, Alessandra Zimmermann, Elizabeth A. Shefelbine, Sandra J. Ritchie, Robert O. TI A methodology for the investigation of toughness and crack propagation in mouse bone SO JOURNAL OF THE MECHANICAL BEHAVIOR OF BIOMEDICAL MATERIALS LA English DT Article DE Bone fracture; Mouse bone; Fracture mechanics; Crack path; Crack initiation; Brittle bone; Crack growth ID HUMAN CORTICAL BONE; FRACTURE-TOUGHNESS; OSTEOGENESIS IMPERFECTA; MICROCRACKING; MICRODAMAGE; MORPHOLOGY; POROSITY; FAILURE; BRITTLE; GROWTH AB Bone fracture is a health concern for those with aged bone and brittle bone diseases. Mouse bone is widely used as a model of human bone, especially to investigate preclinical treatment strategies. However, little is known about the mechanisms of mouse bone fracture and its similarities and differences from fracture in human bone. In this work we present a methodology to investigate the fracture toughness during crack initiation and crack propagation for mouse bone. Mouse femora were dissected, polished on their periosteal surface, notched on the posterior surface at their mid-diaphysis, and tested in three-point bending under displacement control at a rate of 0.1 mm/min using an in situ loading stage within an environmental scanning electron microscope. We obtained high-resolution real-time imaging of the crack initiation and propagation in mouse bone. From the images we can measure the crack extension at each step of the crack growth and calculate the toughness of the bone (in terms of stress intensity factor (K) and work to fracture (W-f)) as a function of stable crack length (Delta a), thus generating a resistance curve for the mouse bone. The technique presented here provides insight into the evolution of microdamage and the toughening mechanisms that resist crack propagation, which are essential for preclinical development of treatments to enhance bone quality and combat fracture risk. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Carriero, Alessandra; Shefelbine, Sandra J.] Univ London Imperial Coll Sci Technol & Med, Dept Bioengn, London SW7 2AZ, England. [Carriero, Alessandra; Zimmermann, Elizabeth A.; Ritchie, Robert O.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA. [Carriero, Alessandra; Zimmermann, Elizabeth A.; Ritchie, Robert O.] Univ Calif Berkeley, Dept Mat Sci & Engn, Berkeley, CA 94720 USA. RP Carriero, A (reprint author), Univ London Imperial Coll Sci Technol & Med, Royal Sch Mines, Dept Bioengn, South Kensington Campus, London SW7 2AZ, England. EM a.carriero@imperial.ac.uk RI Ritchie, Robert/A-8066-2008; Zimmermann, Elizabeth/A-4010-2015; OI Ritchie, Robert/0000-0002-0501-6998; Zimmermann, Elizabeth/0000-0001-9927-3372; Carriero, Alessandra/0000-0001-8103-4795 FU Royal Academy of Engineering; Elsie Widdowson Foundation, UK; National Institute of Health (NIH/NIDCR) [5R01 DE015633] FX This work was performed primarily at the Lawrence Berkeley National Laboratory. It was funded by The Royal Academy of Engineering (Global Research Award for A.C.), by the Elsie Widdowson Foundation, UK (for S.J.S), and by the National Institute of Health (NIH/NIDCR) under Grant no. 5R01 DE015633 (for E.A.Z. and R.O.R.). NR 40 TC 6 Z9 6 U1 4 U2 25 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 1751-6161 EI 1878-0180 J9 J MECH BEHAV BIOMED JI J. Mech. Behav. Biomed. Mater. PD NOV PY 2014 VL 39 BP 38 EP 47 DI 10.1016/j.jmbbm.2014.06.017 PG 10 WC Engineering, Biomedical; Materials Science, Biomaterials SC Engineering; Materials Science GA AR1IL UT WOS:000343338800004 PM 25084121 ER PT J AU Beck, MW Tomcko, CM Valley, RD Staples, DF AF Beck, Marcus W. Tomcko, Cynthia M. Valley, Ray D. Staples, David F. TI Analysis of macrophyte indicator variation as a function of sampling, temporal, and stressor effects SO ECOLOGICAL INDICATORS LA English DT Article DE Climate; Development; Lake monitoring; Macrophytes; Power; Variation ID BIOTIC INTEGRITY; SUBMERGED MACROPHYTES; MINNESOTA LAKES; EUROPEAN LAKES; INDEX; PERFORMANCE AB Biological indicators that signal changes in lake condition are essential tools for guiding resource management decisions. Macrophyte-based indicators have traditionally been selected and evaluated in the context of nutrient-based stressors, although the need to evaluate indicators that are sensitive to climate stressors has been increasingly relevant. Moreover, indicators should ideally exhibit minimal sampling variation and have low natural temporal variation so there is high power to detect changes in the mean value over time. Eight macrophyte indicators were estimated in 23 Minnesota (USA) lakes using four years of repeated surveys to estimate sampling and temporal variation, response to development (phosphorus concentration) and climate stress (annual growing degree days), and power to detect significant change at various annual sampling intervals. Indicators included a macrophyte index of biotic integrity, floristic quality index, maximum depth of growth, total species richness, common species richness, mean richness, and frequency occurrence of rooted species and Chara sp. Overall, regression and smoothed additive models indicated significant relationships of indicators to total lake phosphorus and mean annual growing degree days. The macrophyte index of biotic integrity, floristic quality index, and the frequency rooted species had minimal sampling variation in this study, were responsive to development or climate stress, and had low annual variation (coefficients of variation 0.08, 0.10, and 0.19, respectively) resulting in high to moderate power (>50%) for detecting significant change over a 20 year period. Results from these analyses will facilitate the use of precise and powerful indicators that respond to stressors that are of concern for the management of freshwater glacial lakes. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Beck, Marcus W.] Univ Minnesota, Conservat Biol Grad Program, St Paul, MN 55108 USA. [Tomcko, Cynthia M.] Minnesota Dept Nat Resources, Div Fisheries & Wildlife, Grand Rapids, MN 55744 USA. [Valley, Ray D.] Minnesota Dept Nat Resources, Div Fisheries & Wildlife, St Paul, MN 55744 USA. [Staples, David F.] Minnesota Dept Nat Resources, Div Fisheries & Wildlife, Forest Lake, MN 55025 USA. RP Beck, MW (reprint author), US EPA, ORISE Res Participat Program, Natl Hlth & Environm Effects Res Lab, Gulf Ecol Div, 1 Sabine Isl Dr, Gulf Breeze, FL 32561 USA. EM beck.marcus@epa.gov; cindy.tomcko@state.mn.us; ray.valley@navico.com; david.staples@state.mn.us NR 33 TC 3 Z9 3 U1 3 U2 25 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 1470-160X EI 1872-7034 J9 ECOL INDIC JI Ecol. Indic. PD NOV PY 2014 VL 46 BP 323 EP 335 DI 10.1016/j.ecolind.2014.07.002 PG 13 WC Biodiversity Conservation; Environmental Sciences SC Biodiversity & Conservation; Environmental Sciences & Ecology GA AQ2YO UT WOS:000342656100034 ER PT J AU Saeed, LM Mahmood, M Pyrek, SJ Fahmi, T Xu, Y Mustafa, T Nima, ZA Bratton, SM Casciano, D Dervishi, E Radominska-Pandya, A Biris, AS AF Saeed, Lamya M. Mahmood, Meena Pyrek, Sebastian J. Fahmi, Tariq Xu, Yang Mustafa, Thikra Nima, Zeid A. Bratton, Stacie M. Casciano, Dan Dervishi, Enkeleda Radominska-Pandya, Anna Biris, Alexandru S. TI Single-walled carbon nanotube and graphene nanodelivery of gambogic acid increases its cytotoxicity in breast and pancreatic cancer cells SO JOURNAL OF APPLIED TOXICOLOGY LA English DT Article DE Cancer nanotechnology; Gambogic Acid; Graphene; Single-Walled Carbon Nanotubes; Nanodelivery; Breast cancer; Pancreatic cancer ID MAGNETIC FE3O4 NANOPARTICLES; GARCINIA XANTHONES; LIPID DROPLETS; LEUKEMIA-CELLS; NILE RED; APOPTOSIS; DELIVERY; DRUG; PROLIFERATION; COMBINATION AB Graphene and single-walled carbon nanotubes were used to deliver the natural low-toxicity drug gambogic acid (GA) to breast and pancreatic cancer cells in vitro, and the effectiveness of this complex in suppressing cellular integrity was assessed. Cytotoxicity was assessed by measuring lactate dehydrogenase release, mitochondria dehydrogenase activity, mitochondrial membrane depolarization, DNA fragmentation, intracellular lipid content, and membrane permeability/caspase activity. The nanomaterials showed no toxicity at the concentrations used, and the antiproliferative effects of GA were significantly enhanced by nanodelivery. The results suggest that these complexes inhibit human breast and pancreatic cancer cells grown in vitro. This analysis represents a first step toward assessing their effectiveness in more complex, targeted, nanodelivery systems. Copyright (c) 2014 John Wiley & Sons, Ltd. C1 [Saeed, Lamya M.; Mahmood, Meena; Xu, Yang; Mustafa, Thikra; Nima, Zeid A.; Casciano, Dan; Dervishi, Enkeleda; Biris, Alexandru S.] Univ Arkansas, Ctr Integrat Nanotechnol Sci, Little Rock, AR 72204 USA. [Pyrek, Sebastian J.; Fahmi, Tariq; Bratton, Stacie M.; Radominska-Pandya, Anna] Univ Arkansas Med Sci, Coll Med, Dept Biochem & Mol Biol, Little Rock, AR 72205 USA. [Dervishi, Enkeleda] Los Alamos Natl Lab, Ctr Integrated Nanotechnol, Mat Phys & Applicat Div, Los Alamos, NM 87544 USA. [Mustafa, Thikra] Univ Baghdad, Coll Sci Women, Dept Biol, Baghdad, Iraq. RP Radominska-Pandya, A (reprint author), Univ Arkansas, Ctr Integrat Nanotechnol Sci, Little Rock, AR 72204 USA. EM radominskaanna@uams.edu; asbiris@ualr.edu FU Department of Defense [X81XWH-11-1-0795]; Arkansas Breast Cancer Research Program/University of Arkansas for Medical Sciences Translational Research Institute Clinical Translational Science Award [UL1TR000039] FX This work was funded by grants from the Department of Defense (X81XWH-11-1-0795) to A.S.B. and A.R.-P., and from the Arkansas Breast Cancer Research Program/University of Arkansas for Medical Sciences Translational Research Institute Clinical Translational Science Award (UL1TR000039) to A.R.-P. NR 56 TC 13 Z9 13 U1 7 U2 61 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0260-437X EI 1099-1263 J9 J APPL TOXICOL JI J. Appl. Toxicol. PD NOV PY 2014 VL 34 IS 11 BP 1188 EP 1199 DI 10.1002/jat.3018 PG 12 WC Toxicology SC Toxicology GA AQ4GF UT WOS:000342750800008 PM 25220893 ER PT J AU Panyala, NR Sturzbecher-Hoehne, M Abergel, RJ AF Panyala, Nagender R. Sturzbecher-Hoehne, Manuel Abergel, Rebecca J. TI Identification of process related trace level impurities in the actinide decorporation agent 3,4,3-LI(1,2-HOPO): Nozzle-skimmer fragmentation via ESI LC-QTOFMS SO JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS LA English DT Article DE 3,4,3-LI(1,2-HOPO) ligand; LC-MS/MS; Structural elucidation; Method development; Fragmentation ID MASS-SPECTROMETRY; ELECTROSPRAY-IONIZATION; SEQUESTERING AGENTS; DISSOCIATION; CHELATION; EFFICACY; LIGANDS; COMPLEX; IONS; HPLC AB 3,4,3-LI(1,2-HOPO) is a chelating ligand and decorporation agent that can remove radioactive lanthanides and actinides from the body. Identification of trace impurities in drug samples is gaining much interest due to their significant influence on drug activity. In this study, trace impurities were detected in manufactured lots of 3,4,3-LI(1,2-HOPO) by a developed method of liquid chromatography coupled with photo-diode array UV detection and electrospray ionization-quadrupole time of flight mass spectrometry (LC-QTOFMS), via induced-in-source or collision-induced mass fragmentation (nozzle-skimmer fragmentation). Molecular ions were fragmented within the nozzle-skimmer region of electrospray ionization (ESI) mass spectrometer equipped with a Time of Flight detector. Eight major (detected at levels higher than a 0.1% threshold) and seven minor trace impurities were identified. The respective structures of these impurities were elucidated via analysis of the generated fragment ions using mass fragmentation and elemental composition software. Proposed structures of impurities were further confirmed via isotopic modeling. (C) 2014 Elsevier B.V. All rights reserved. C1 [Panyala, Nagender R.; Sturzbecher-Hoehne, Manuel; Abergel, Rebecca J.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA. RP Abergel, RJ (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Chem Sci, Berkeley, CA 94720 USA. EM rjabergel@lbl.gov FU National Institutes of Health/National Institute of Allergy and Infectious Diseases Medical Countermeasures Against Radiological Threats (MCART) Consortium through the U.S. Department of Energy [HHSN272201000046C, DE-AC02-05CH11231] FX This work was supported by the National Institutes of Health/National Institute of Allergy and Infectious Diseases Medical Countermeasures Against Radiological Threats (MCART) Consortium (Contract #HHSN272201000046C to the University of Maryland School of Medicine), through the U.S. Department of Energy under Contract #DE-AC02-05CH11231. NR 35 TC 1 Z9 1 U1 2 U2 14 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0731-7085 EI 1873-264X J9 J PHARMACEUT BIOMED JI J. Pharm. Biomed. Anal. PD NOV PY 2014 VL 100 BP 157 EP 166 DI 10.1016/j.jpba.2014.08.004 PG 10 WC Chemistry, Analytical; Pharmacology & Pharmacy SC Chemistry; Pharmacology & Pharmacy GA AQ7TC UT WOS:000343021100021 PM 25165012 ER PT J AU Hapeman, P Latch, EK Rhodes, OE Kilpatrick, CW AF Hapeman, Paul Latch, Emily K. Rhodes, Olin E. Kilpatrick, Charles W. TI When recent and evolutionary histories meet: deciphering temporal events from contemporary patterns of mtDNA from fishers (Martes pennanti) in north-eastern North America SO JOURNAL OF ZOOLOGICAL SYSTEMATICS AND EVOLUTIONARY RESEARCH LA English DT Article DE Fragmentation; Martes pennanti; nucleotide diversity; spatial analysis of molecular variance ID DNA POLYMORPHISM DATA; POPULATION-STRUCTURE; MITOCHONDRIAL-DNA; POSTGLACIAL COLONIZATION; CONSERVATION GENETICS; PLEISTOCENE REFUGIA; STATISTICAL TESTS; PHYLOGEOGRAPHY; NEUTRALITY; DISPERSAL AB The current spatial distribution of genetic lineages across a region should reflect the complex interplay of both historical and contemporary processes. Postglacial expansion and recolonization in the distant past, in combination with more recent events with anthropogenic effects such as habitat fragmentation and overexploitation, can help shape the pattern of genetic structure observed in contemporary populations. In this study, we characterize the spatial distribution of mtDNA lineages for fisher (Martes pennanti) in north-eastern North America. The history of fishers in this region is well understood and thus provides an opportunity to interpret patterns of genetic structure in the light of known historical (e. g. recolonization from glacial refugia) and contemporary events (e. g. reintroductions, fragmentation and natural recolonization). Our results indicate that fishers likely recolonized north-eastern North America from a single Pleistocene refugium. Three genetically distinct remnant populations persisted through the population declines of the 1800s and served as sources for multiple reintroductions and natural recolonizations that have restored the fisher throughout north-eastern North America. However, the spatial genetic structure of genetic lineages across the region still reflects the three remnant populations. C1 [Hapeman, Paul] Cent Connecticut State Univ, Dept Biol, New Britain, CT 06050 USA. [Latch, Emily K.] Univ Wisconsin, Dept Biol Sci, Milwaukee, WI 53201 USA. [Rhodes, Olin E.] Univ Georgia, Savannah River Ecol Lab, Aiken, SC 29802 USA. [Kilpatrick, Charles W.] Univ Vermont, Dept Biol, Burlington, VT USA. RP Hapeman, P (reprint author), Cent Connecticut State Univ, Dept Biol, New Britain, CT 06050 USA. EM hapeman@ccsu.edu; latch@uwm.edu; rhodes@srel.uga.edu; wkilpatr@uvm.edu FU Norcross Wildlife Foundation; University of Vermont FX This research was funded by the A.V. Stout Fund c/o Norcross Wildlife Foundation and the University of Vermont. Many people deserve thanks for contributing time, effort, samples and resources to this project including Mark Brown, Scott Smith and New York Department of Environmental Conservation, Charlie Brown and Rhode Island Division of Fish and Wildlife, Eric Orff, Will Staats and the New Hampshire Fish and Game Department, Kim Royar and Vermont Fish and Wildlife, Paul Rego and employees at Connecticut Department of Environmental Protection, Chrissy Henner, Tony Gola and Massachusetts Division of Fish and Wildlife, Wally Jakubas and Maine Department of Inland Fisheries and Wildlife. The following trappers in Maine provided tissue samples: Greg Gallant, Rick Crowe, Tom Stevens, Eugene Worster and Harry Seekins. Rod Williams at Purdue University provided DNA samples and information regarding his research on fishers. Jenny Fike assisted with some of the laboratory work at Purdue University. Sequence data from New Brunswick were provided by Rob Drew and Jim Hallet at Washington State University. NR 63 TC 1 Z9 1 U1 4 U2 28 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0947-5745 EI 1439-0469 J9 J ZOOL SYST EVOL RES JI J. Zool. Syst. Evol. Res. PD NOV PY 2014 VL 52 IS 4 BP 331 EP 337 DI 10.1111/jzs.12060 PG 7 WC Evolutionary Biology; Zoology SC Evolutionary Biology; Zoology GA AQ5IQ UT WOS:000342841700008 ER PT J AU Murshed, MM Mendive, CB Curti, M Nenert, G Kalita, PE Lipinska, K Cornelius, AL Huq, A Gesing, TM AF Murshed, M. Mangir Mendive, Cecilia B. Curti, Mariano Nenert, Gwilherm Kalita, Patricia E. Lipinska, Kris Cornelius, Andrew L. Huq, Ashfia Gesing, Thorsten M. TI Anisotropic lattice thermal expansion of PbFeBO4: A study by X-ray and neutron diffraction, Raman spectroscopy and DFT calculations SO MATERIALS RESEARCH BULLETIN LA English DT Article DE Inorganic compounds; Raman spectroscopy; X-ray diffraction; Thermal expansion; Equations-of-state ID PBMBO4 M; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; OPTICAL PHONONS; MN; FE; CR AB The lattice thermal expansion of mullite-type PbFeBO4 is presented in this study. The thermal expansion coefficients of the metric parameters were obtained from composite data collected from temperature-dependent neutron and X-ray powder diffraction between 10 K and 700 K. The volume thermal expansion was modeled using extended Gruneisen first-order approximation to the zero-pressure equation of state. The additive frame of the model includes harmonic, quasi-harmonic and intrinsic anharmonic potentials to describe the change of the internal energy as a function of temperature. The unit-cell volume at zero-pressure and OK was optimized during the OFT simulations. Harmonic frequencies of the optical Raman modes at the Gamma-point of the Brillouin zone at OK were also calculated by DFT, which help to assign and crosscheck the experimental frequencies. The low-temperature Raman spectra showed significant anomaly in the antiferromagnetic regions, leading to softening or hardening of some phonons. Selected modes were analyzed using a modified Klemens model. The shift of the frequencies and the broadening of the line-widths helped to understand the anharmonic vibrational behaviors of the PbO4, FeO6 and BO3 polyhedra as a function of temperature. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Murshed, M. Mangir; Gesing, Thorsten M.] Univ Bremen, Inst Anorgan Chem, D-28359 Bremen, Germany. [Mendive, Cecilia B.; Curti, Mariano] Univ Nacl Mar del Plata, Fac Ciencias Exactas & Nat, Dept Quim, Mar Del Plata, Buenos Aires, Argentina. [Nenert, Gwilherm] Inst Laue Langevin, F-38042 Grenoble, France. [Kalita, Patricia E.; Cornelius, Andrew L.] Univ Nevada, Dept Phys & Astron, Las Vegas, NV 89154 USA. [Kalita, Patricia E.; Cornelius, Andrew L.] Univ Nevada, High Pressure Sci & Engn Ctr, Las Vegas, NV 89154 USA. [Lipinska, Kris] Univ Nevada, Dept Mech Engn, Las Vegas, NV 89154 USA. [Huq, Ashfia] Oak Ridge Natl Lab, Chem & Engn Mat Div, Oak Ridge, TN 37831 USA. RP Murshed, MM (reprint author), Univ Bremen, Inst Anorgan Chem, Leobener Str, D-28359 Bremen, Germany. EM murshed@uni-bremen.de RI Cornelius, Andrew/A-9837-2008; Huq, Ashfia/J-8772-2013; OI Huq, Ashfia/0000-0002-8445-9649; Curti, Mariano/0000-0002-3721-4358 FU Deutsche Forschungsgemeinschaft (DFG) [GE1981/4-1, GE1981/3-1]; Scientific User Facilities Division, Office of Basic Energy Sciences, US Department of Energy; DOE-EERE [DE-FG 3606GO8636, EE-0000269]; DOE [DEFG36-05GO08502]; US Department of Energy, National Nuclear Security Administration [DE-FC08-01 NV14049]; ANPCyT (Arg.) [PICT-2683]; CONICET FX We gratefully acknowledge the Deutsche Forschungsgemeinschaft (DFG) for the financial support through the mullite-LEP project GE1981/4-1. TMG especially acknowledges the DFG for a support in the Heisenberg program (GE1981/3-1). Part of the research conducted at ORNL's Spallation Neutron Source was sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, US Department of Energy. High-pressure Raman spectroscopy in diamond anvil cell was carried out using experimental facilities of FAME-Tech Labs (University of Nevada Las Vegas, Dept. of Mechanical Engineering) which are supported by DOE-EERE under Award No. DE-FG 3606GO8636 and Award No. EE-0000269. Work at UNLV is supported by DOE award No. DEFG36-05GO08502. The UNLV, HiPSEC is supported by the US Department of Energy, National Nuclear Security Administration, under Cooperative Agreement DE-FC08-01 NV14049. CBM is a member of the research staff of CONICET and thanks ANPCyT (Arg.) for the financial support PICT-2683. MC is grateful to CONICET for the doctoral scholarship. NR 26 TC 6 Z9 6 U1 1 U2 24 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0025-5408 EI 1873-4227 J9 MATER RES BULL JI Mater. Res. Bull. PD NOV PY 2014 VL 59 BP 170 EP 178 DI 10.1016/j.materresbull.2014.07.005 PG 9 WC Materials Science, Multidisciplinary SC Materials Science GA AQ6XA UT WOS:000342956000028 ER PT J AU Jess, S Kildea, S Moody, A Rennick, G Murchie, AK Cooke, LR AF Jess, Stephen Kildea, Steven Moody, Aidan Rennick, Gordon Murchie, Archie K. Cooke, Louise R. TI European Union policy on pesticides: implications for agriculture in Ireland SO PEST MANAGEMENT SCIENCE LA English DT Review DE pesticides; EU policy; agriculture; integrated pest management; sustainability ID MYCOSPHAERELLA-GRAMINICOLA; WINTER-WHEAT; RESISTANCE; BLOTCH AB European Community (EC) legislation has limited the availability of pesticide active substances used in effective plant protection products. The Pesticide Authorisation Directive 91/414/EEC introduced the principle of risk assessment for approval of pesticide active substances. This principle was modified by the introduction of Regulation (EC) 1107/2009, which applies hazard, the intrinsic toxicity of the active substance, rather than risk, the potential for hazard to occur, as the approval criterion. Potential impacts of EC pesticide legislation on agriculture in Ireland are summarised. While these will significantly impact on pesticide availability in the medium to long term, regulations associated with water quality (Water Framework Directive 2000/60/EC and Drinking Water Directive 1998/83/EC) have the potential to restrict pesticide use more immediately, as concerns regarding public health and economic costs associated with removing pesticides from water increase. This rationale will further reduce the availability of effective pesticide active substances, directly affecting crop protection and increasing pesticide resistance within pest and disease populations. In addition, water quality requirements may also impact on important active substances used in plant protection in Ireland. The future challenge for agriculture in Ireland is to sustain production and profitability using reduced pesticide inputs within a framework of integrated pest management. (C) 2014 Society of Chemical Industry C1 [Jess, Stephen; Murchie, Archie K.; Cooke, Louise R.] Agrifood & Biosci Inst, Sustainable Agrifood Sci Div, Belfast BT9 5PX, Antrim, North Ireland. [Kildea, Steven] TEAGASC, Oak Pk Crops Res Ctr, Dept Crop Sci, Carlow, Ireland. [Moody, Aidan; Rennick, Gordon] Dept Agr Food & theMarine, Pesticide Registrat Div, Celbridge, Kildare, Ireland. [Moody, Aidan; Rennick, Gordon] Dept Agr Food & theMarine, Control Div, Celbridge, Kildare, Ireland. RP Jess, S (reprint author), Agrifood & Biosci Inst, Sustainable Agrifood Sci Div, 18a Newforge Lane, Belfast BT9 5PX, Antrim, North Ireland. EM stephen.jess@afbini.gov.uk FU Department of Agriculture and Rural Development (Northern Ireland) FX The authors are grateful to the Department of Agriculture and Rural Development (Northern Ireland) for funding this review. They also acknowledge the staff of the Agri-Food and Biosciences Institute, Pesticide Usage Monitoring Group, for access to their datasets. NR 33 TC 16 Z9 16 U1 3 U2 69 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1526-498X EI 1526-4998 J9 PEST MANAG SCI JI Pest Manag. Sci. PD NOV PY 2014 VL 70 IS 11 BP 1646 EP 1654 DI 10.1002/ps.3801 PG 9 WC Agronomy; Entomology SC Agriculture; Entomology GA AQ5LN UT WOS:000342850800002 PM 24753219 ER PT J AU Keck, RE de Mare, M Churchfield, MJ Lee, S Larsen, G Aagaard Madsen, H AF Keck, Rolf-Erik de Mare, Martin Churchfield, Matthew J. Lee, Sang Larsen, Gunner Aagaard Madsen, Helge TI On atmospheric stability in the dynamic wake meandering model SO WIND ENERGY LA English DT Article DE atmospheric stability; wake modelling; wake meandering; dynamic wake meandering model; wake-added turbulence; wake dynamics; wind power ID WIND TURBINE WAKES; POWER-LAW EXPONENT; SURFACE-ROUGHNESS; LAYER TURBULENCE; BOUNDARY-LAYER; PROFILE; SIMULATION AB The present study investigates a new approach for capturing the effects of atmospheric stability on wind turbine wake evolution and wake meandering by using the dynamic wake meandering model. The most notable impact of atmospheric stability on the wind is the changes in length and velocity scales of the atmospheric turbulence. The length and velocity scales in the turbulence are largely responsible for the way in which wind turbine wakes meander as they convect downstream. The hypothesis of the present work is that appropriate turbulence scales can be extracted from the oncoming atmospheric turbulence spectra and applied to the dynamic wake meandering model to capture the correct wake meandering behaviour. The ambient turbulence in all stability classes is generated using the Mann turbulence model, where the effects of non-neutral atmospheric stability are approximated by the selection of input parameters. In order to isolate the effect of atmospheric stability, simulations of neutral and unstable atmospheric boundary layers using large-eddy simulation are performed at the same streamwise turbulence intensity level. The turbulence intensity is kept constant by calibrating the surface roughness in the computational domain. The changes in the turbulent length scales due to the various atmospheric stability states impact the wake meandering characteristics and thus the power generation by the individual turbines. The proposed method is compared with results from both large-eddy simulation coupled with an actuator line model and field measurements, where generally good agreement is found with respect to the velocity, turbulence intensity and power predictions. Copyright (c) 2013 John Wiley & Sons, Ltd. C1 [Keck, Rolf-Erik; de Mare, Martin] Vestas Wind Syst AS, Rotor Syst, DK-4000 Roskilde, Denmark. [Keck, Rolf-Erik; de Mare, Martin; Larsen, Gunner; Aagaard Madsen, Helge] Riso DTU Natl Lab Sustainable Energy, Wind Energy Dept, DK-4000 Roskilde, Denmark. [Churchfield, Matthew J.; Lee, Sang] Natl Renewable Energy Lab, Golden, CO 80401 USA. RP Keck, RE (reprint author), Riso DTU Natl Lab Sustainable Energy, Wind Energy Dept, DK-4000 Roskilde, Denmark. EM rolf.keck@gmail.com OI Aagaard Madsen , Helge/0000-0002-4647-3706 NR 38 TC 15 Z9 15 U1 1 U2 6 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1095-4244 EI 1099-1824 J9 WIND ENERGY JI Wind Energy PD NOV PY 2014 VL 17 IS 11 BP 1689 EP 1710 DI 10.1002/we.1662 PG 22 WC Energy & Fuels; Engineering, Mechanical SC Energy & Fuels; Engineering GA AQ6IT UT WOS:000342915100005 ER PT J AU Mills, AD Wiser, RH AF Mills, A. D. Wiser, R. H. TI Changes in the economic value of wind energy and flexible resources at increasing penetration levels in the Rocky Mountain Power Area SO WIND ENERGY LA English DT Article DE economic valuation; flexibility; real-time pricing; storage; wind integration ID MARKET PRICES; GENERATION; GERMANY; IMPACTS AB We use a consistent economic framework to estimate the long-run economic value of wind while including operational constraints for conventional generation and hourly variation in wind and load. Day-ahead forecast errors in wind are corrected in the real-time, after commitment decisions for many thermal generators have already been made. The framework is used to estimate the change in the marginal economic value of wind with increasing penetration in the Rocky Mountain Power Area of the USA. We also evaluate the marginal economic benefit to wind energy of implementing several strategies to manage wind energy variability and uncertainty: more flexible conventional generation, real-time pricing, low cost bulk energy storage, and increased geographic diversity of wind plant siting. Without mitigation, the marginal economic value of wind is found to decrease by $21 MWh (37% of the marginal value of wind at 0% penetration) as wind penetration increases from 0% to 30%. The decline is largely because of the hourly profile of wind output and day-ahead wind energy forecast errors; factors whose impact is reduced by the mitigation strategies. With mitigation, the marginal value of wind at the 30% penetration level is $6-$11 MWh greater than the value without the measures (17-31% increase in value). Although the marginal value of wind energy decreases with increasing penetration in this region, several different types of mitigation strategies are available and should be investigated in more detail. Copyright (c) 2013 John Wiley & Sons, Ltd. C1 [Mills, A. D.; Wiser, R. H.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. RP Mills, AD (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, 1 Cyclotron Rd,MS90R4000, Berkeley, CA 94720 USA. EM ADMills@lbl.gov RI Mills, Andrew/B-3469-2016 OI Mills, Andrew/0000-0002-9065-0458 FU US Department of Energy (National Electricity Delivery Division) [DE-AC02-05CH11231]; US Department of Energy (Office of Energy Efficiency and Renewable Energy, Wind & Water Power Program) [DE-AC02-05CH11231]; US Department of Energy (Office of Electricity Delivery and Energy Reliability, Research & Development Division) [DE-AC02-05CH11231] FX The work described in this paper was funded by the US Department of Energy (Office of Energy Efficiency and Renewable Energy, Wind & Water Power Program; and Office of Electricity Delivery and Energy Reliability, Research & Development Division and National Electricity Delivery Division) under Contract No. DE-AC02-05CH11231. We would particularly like to thank Larry Mansueti, Gilbert Bindewald and Patrick Gilman (US Department of Energy) for their support of this work. Debbie Lew, Michael Milligan, George Scott and Ray George of the National Renewable Energy Laboratory provided helpful guidance and data for this project. Marco Nicolosi provided helpful discussions and feedback on this project while a visitor at Berkeley Lab. An anonymous reviewer also provides several helpful suggestions. NR 39 TC 5 Z9 5 U1 1 U2 10 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1095-4244 EI 1099-1824 J9 WIND ENERGY JI Wind Energy PD NOV PY 2014 VL 17 IS 11 BP 1711 EP 1726 DI 10.1002/we.1663 PG 16 WC Energy & Fuels; Engineering, Mechanical SC Energy & Fuels; Engineering GA AQ6IT UT WOS:000342915100006 ER PT J AU Griffith, DT Yoder, NC Resor, B White, J Paquette, J AF Griffith, D. Todd Yoder, Nathanael C. Resor, Brian White, Jonathan Paquette, Joshua TI Structural health and prognostics management for the enhancement of offshore wind turbine operations and maintenance strategies SO WIND ENERGY LA English DT Article DE structural health monitoring; prognostics management; condition-based maintenance; offshore wind turbines; operations and maintenance; prognostic control ID POWER; BENEFIT AB Offshore wind turbines are an attractive source for clean and renewable energy for reasons including their proximity to population centers and higher capacity factors. One obstacle to the more widespread installation of offshore wind turbines in the USA, however, is that recent projections of offshore operations and maintenance costs vary from two to five times the land-based costs. One way in which these costs could be reduced is through use of a structural health and prognostics management (SHPM) system as part of a condition-based maintenance paradigm with smart loads management. This paper contributes to the development of such strategies by developing an initial roadmap for SHPM, with application to the blades. One of the key elements of the approach is a multiscale simulation approach developed to identify how the underlying physics of the system are affected by the presence of damage and how these changes manifest themselves in the operational response of a full turbine. A case study of a trailing edge disbond is analysed to demonstrate the multiscale sensitivity of damage approach and to show the potential life extension and increased energy capture that can be achieved using simple changes in the overall turbine control and loads management strategy. The integration of health monitoring information, economic considerations such as repair costs versus state of health, and a smart loads management methodology provides an initial roadmap for reducing operations and maintenance costs for offshore wind farms while increasing turbine availability and overall profit. Copyright (c) 2013 John Wiley & Sons, Ltd. C1 [Griffith, D. Todd; Resor, Brian; White, Jonathan; Paquette, Joshua] Sandia Natl Labs, Wind & Water Technol, Albuquerque, NM 87185 USA. [Yoder, Nathanael C.] ATA Engn, San Diego, CA USA. RP Griffith, DT (reprint author), Sandia Natl Labs, POB 5800, Albuquerque, NM 87185 USA. EM dgriffi@sandia.gov FU US Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX Sandia National Laboratories is a multi-program laboratory operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the US Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. NR 35 TC 6 Z9 6 U1 7 U2 36 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1095-4244 EI 1099-1824 J9 WIND ENERGY JI Wind Energy PD NOV PY 2014 VL 17 IS 11 BP 1737 EP 1751 DI 10.1002/we.1665 PG 15 WC Energy & Fuels; Engineering, Mechanical SC Energy & Fuels; Engineering GA AQ6IT UT WOS:000342915100008 ER PT J AU Ade, PAR Aghanim, N Armitage-Caplan, C Arnaud, M Ashdown, M Atrio-Barandela, F Aumont, J Baccigalupi, C Banday, AJ Barreiro, RB Bartlett, JG Battaner, E Benabed, K Benoit, A Benoit-Levy, A Bernard, JP Bersanelli, M Bielewicz, P Bobin, J Bock, JJ Bonaldi, A Bond, JR Borrill, J Bouchet, FR Bridges, M Bucher, M Burigana, C Butler, RC Calabrese, E Cappellini, B Cardoso, JF Catalano, A Challinor, A Chamballu, A Chary, RR Chen, X Chiang, HC Chiang, LY Christensen, PR Church, S Clements, DL Colombi, S Colombo, LPL Couchot, F Coulais, A Crill, BP Curto, A Cuttaia, F Danese, L Davies, RD Davis, RJ de Bernardis, P de Rosa, A de Zotti, G Delabrouille, J Delouis, JM Desert, FX Dickinson, C Diego, JM Dolag, K Dole, H Donzelli, S Dore, O Douspis, M Dunkley, J Dupac, X Efstathiou, G Elsner, F Ensslin, TA Eriksen, HK Finelli, F Forni, O Frailis, M Fraisse, AA Franceschi, E Gaier, TC Galeotta, S Galli, S Ganga, K Giard, M Giardino, G Giraud-Heraud, Y Gjerlow, E Gonzalez-Nuevo, J Gorski, KM Gratton, S Gregorio, A Gruppuso, A Gudmundsson, JE Haissinski, J Hamann, J Hansen, FK Hanson, D Harrison, D Henrot-Versille, S Hernandez-Monteagudo, C Herranz, D Hildebrandt, SR Hivon, E Hobson, M Holmes, WA Hornstrup, A Hou, Z Hovest, W Huffenberger, KM Jaffe, AH Jaffe, TR Jewell, J Jones, WC Juvela, M Keihanen, E Keskitalo, R Kisner, TS Kneissl, R Knoche, J Knox, L Kunz, M Kurki-Suonio, H Lagache, G Lahteenmaki, A Lamarre, JM Lasenby, A Lattanzi, M Laureijs, RJ Lawrence, CR Leach, S Leahy, JP Leonardi, R Leon-Tavares, J Lesgourgues, J Lewis, A Liguori, M Lilje, PB Linden-Vornle, M Lopez-Caniego, M Lubin, PM Macias-Perez, JF Maffei, B Maino, D Mandolesi, N Maris, M Marshall, DJ Martin, PG Martinez-Gonzalez, E Masi, S Massardi, M Matarrese, S Matthai, F Mazzotta, P Meinhold, PR Melchiorri, A Melin, JB Mendes, L Menegoni, E Mennella, A Migliaccio, M Millea, M Mitra, S Miville-Deschenes, MA Moneti, A Montier, L Morgante, G Mortlock, D Moss, A Munshi, D Murphy, JA Naselsky, P Nati, F Natoli, P Netterfield, CB Norgaard-Nielsen, HU Noviello, F Novikov, D Novikov, I O'Dwyer, IJ Osborne, S Oxborrow, CA Paci, F Pagano, L Pajot, F Paladini, R Paoletti, D Partridge, B Pasian, F Patanchon, G Pearson, D Pearson, TJ Peiris, HV Perdereau, O Perotto, L Perrotta, F Pettorino, V Piacentini, F Piat, M Pierpaoli, E Pietrobon, D Plaszczynski, S Platania, P Pointecouteau, E Polenta, G Ponthieu, N Popa, L Poutanen, T Pratt, GW Prezeau, G Prunet, S Puget, JL Rachen, JP Reach, WT Rebolo, R Reinecke, M Remazeilles, M Renault, C Ricciardi, S Riller, T Ristorcelli, I Rocha, G Rosset, C Roudier, G Rowan-Robinson, M Rubino-Martin, JA Rusholme, B Sandri, M Santos, D Savelainen, M Savini, G Scott, D Seiffert, MD Shellard, EPS Spencer, LD Starck, JL Stolyarov, V Stompor, R Sudiwala, R Sunyaev, R Sureau, F Sutton, D Suur-Uski, AS Sygnet, JF Tauber, JA Tavagnacco, D Terenzi, L Toffolatti, L Tomasi, M Tristram, M Tucci, M Tuovinen, J Turler, M Umana, G Valenziano, L Valiviita, J Van Tent, B Vielva, P Villa, F Vittorio, N Wade, A Wandelt, BD Wehus, IK White, M White, SDM Wilkinson, A Yvon, D Zacchei, A Zonca, A AF Ade, P. A. R. Aghanim, N. Armitage-Caplan, C. Arnaud, M. Ashdown, M. Atrio-Barandela, F. Aumont, J. Baccigalupi, C. Banday, A. J. Barreiro, R. B. Bartlett, J. G. Battaner, E. Benabed, K. Benoit, A. Benoit-Levy, A. Bernard, J. -P. Bersanelli, M. Bielewicz, P. Bobin, J. Bock, J. J. Bonaldi, A. Bond, J. R. Borrill, J. Bouchet, F. R. Bridges, M. Bucher, M. Burigana, C. Butler, R. C. Calabrese, E. Cappellini, B. Cardoso, J. -F. Catalano, A. Challinor, A. Chamballu, A. Chary, R. -R. Chen, X. Chiang, H. C. Chiang, L. -Y Christensen, P. R. Church, S. Clements, D. L. Colombi, S. Colombo, L. P. L. Couchot, F. Coulais, A. Crill, B. P. Curto, A. Cuttaia, F. Danese, L. Davies, R. D. Davis, R. J. de Bernardis, P. de Rosa, A. de Zotti, G. Delabrouille, J. Delouis, J. -M. Desert, F. -X. Dickinson, C. Diego, J. M. Dolag, K. Dole, H. Donzelli, S. Dore, O. Douspis, M. Dunkley, J. Dupac, X. Efstathiou, G. Elsner, F. Ensslin, T. A. Eriksen, H. K. Finelli, F. Forni, O. Frailis, M. Fraisse, A. A. Franceschi, E. Gaier, T. C. Galeotta, S. Galli, S. Ganga, K. Giard, M. Giardino, G. Giraud-Heraud, Y. Gjerlow, E. Gonzalez-Nuevo, J. Gorski, K. M. Gratton, S. Gregorio, A. Gruppuso, A. Gudmundsson, J. E. Haissinski, J. Hamann, J. Hansen, F. K. Hanson, D. Harrison, D. Henrot-Versille, S. Hernandez-Monteagudo, C. Herranz, D. Hildebrandt, S. R. Hivon, E. Hobson, M. Holmes, W. A. Hornstrup, A. Hou, Z. Hovest, W. Huffenberger, K. M. Jaffe, A. H. Jaffe, T. R. Jewell, J. Jones, W. C. Juvela, M. Keihanen, E. Keskitalo, R. Kisner, T. S. Kneissl, R. Knoche, J. Knox, L. Kunz, M. Kurki-Suonio, H. Lagache, G. Lahteenmaki, A. Lamarre, J. -M. Lasenby, A. Lattanzi, M. Laureijs, R. J. Lawrence, C. R. Leach, S. Leahy, J. P. Leonardi, R. Leon-Tavares, J. Lesgourgues, J. Lewis, A. Liguori, M. Lilje, P. B. Linden-Vornle, M. Lopez-Caniego, M. Lubin, P. M. Macias-Perez, J. F. Maffei, B. Maino, D. Mandolesi, N. Maris, M. Marshall, D. J. Martin, P. G. Martinez-Gonzalez, E. Masi, S. Massardi, M. Matarrese, S. Matthai, F. Mazzotta, P. Meinhold, P. R. Melchiorri, A. Melin, J. -B. Mendes, L. Menegoni, E. Mennella, A. Migliaccio, M. Millea, M. Mitra, S. Miville-Deschenes, M. -A. Moneti, A. Montier, L. Morgante, G. Mortlock, D. Moss, A. Munshi, D. Murphy, J. A. Naselsky, P. Nati, F. Natoli, P. Netterfield, C. B. Norgaard-Nielsen, H. U. Noviello, F. Novikov, D. Novikov, I. O'Dwyer, I. J. Osborne, S. Oxborrow, C. A. Paci, F. Pagano, L. Pajot, F. Paladini, R. Paoletti, D. Partridge, B. Pasian, F. Patanchon, G. Pearson, D. Pearson, T. J. Peiris, H. V. Perdereau, O. Perotto, L. Perrotta, F. Pettorino, V. Piacentini, F. Piat, M. Pierpaoli, E. Pietrobon, D. Plaszczynski, S. Platania, P. Pointecouteau, E. Polenta, G. Ponthieu, N. Popa, L. Poutanen, T. Pratt, G. W. Prezeau, G. Prunet, S. Puget, J. -L. Rachen, J. P. Reach, W. T. Rebolo, R. Reinecke, M. Remazeilles, M. Renault, C. Ricciardi, S. Riller, T. Ristorcelli, I. Rocha, G. Rosset, C. Roudier, G. Rowan-Robinson, M. Rubino-Martin, J. A. Rusholme, B. Sandri, M. Santos, D. Savelainen, M. Savini, G. Scott, D. Seiffert, M. D. Shellard, E. P. S. Spencer, L. D. Starck, J. -L. Stolyarov, V. Stompor, R. Sudiwala, R. Sunyaev, R. Sureau, F. Sutton, D. Suur-Uski, A. -S. Sygnet, J. -F. Tauber, J. A. Tavagnacco, D. Terenzi, L. Toffolatti, L. Tomasi, M. Tristram, M. Tucci, M. Tuovinen, J. Tuerler, M. Umana, G. Valenziano, L. Valiviita, J. Van Tent, B. Vielva, P. Villa, F. Vittorio, N. Wade, A. Wandelt, B. D. Wehus, I. K. White, M. White, S. D. M. Wilkinson, A. Yvon, D. Zacchei, A. Zonca, A. TI Planck 2013 results. XVI. Cosmological parameters SO ASTRONOMY & ASTROPHYSICS LA English DT Article DE cosmic background radiation; cosmological parameters; early Universe; inflation; primordial nucleosynthesis ID MICROWAVE-ANISOTROPY-PROBE; BARYON ACOUSTIC-OSCILLATIONS; SOUTH-POLE TELESCOPE; HUBBLE-SPACE-TELESCOPE; DIGITAL SKY SURVEY; BACKGROUND POWER SPECTRUM; SUPERNOVA LEGACY SURVEY; INFLATIONARY UNIVERSE SCENARIO; PRIMORDIAL MAGNETIC-FIELDS; FINE-STRUCTURE CONSTANT AB This paper presents the first cosmological results based on Planck measurements of the cosmic microwave background (CMB) temperature and lensing-potential power spectra. We find that the Planck spectra at high multipoles (l greater than or similar to 40) are extremely well described by the standard spatially-flat six-parameter ACDM cosmology with a power-law spectrum of adiabatic scalar perturbations. Within the context of this cosmology, the Planck data determine the cosmological parameters to high precision: the angular size of the sound horizon at recombination, the physical densities of baryons and cold dark matter, and the scalar spectral index are estimated to be theta* = (1.04147 +/- 0.00062) x 10(-2), Omega(b)h(2) = 0.02205 +/- 0.00028, Omega(c)h(2) = 0.1199 +/- 0.0027, and n(s) = 0.9603 +/- 0.0073, respectively (note that in this abstract we quote 68% errors on measured parameters and 95% upper limits on other parameters). For this cosmology, we find a low value of the Hubble constant, H-0 = (67.3 +/- 1.2) km s(-1) Mpc(-1), and a high value of the matter density parameter, Omega(m) = 0.315 +/- 0.017. These values are in tension with recent direct measurements of H-0 and the magnitude-redshift relation for Type Ia supernovae, but are in excellent agreement with geometrical constraints from baryon acoustic oscillation (BAO) surveys. Including curvature, we find that the Universe is consistent with spatial flatness to percent level precision using Planck CMB data alone. We use high-resolution CMB data together with Planck to provide greater control on extragalactic foreground components in an investigation of extensions to the six-parameter ACDM model. We present selected results from a large grid of cosmological models, using a range of additional astrophysical data sets in addition to Planck and high-resolution CMB data. None of these models are favoured over the standard six-parameter ACDM cosmology. The deviation of the scalar spectral index from unity is insensitive to the addition of tensor modes and to changes in the matter content of the Universe. We find an upper limit of r(0.002) < 0.11 on the tensor-to-scalar ratio. There is no evidence for additional neutrino-like relativistic particles beyond the three families of neutrinos in the standard model. Using BAO and CMB data, we find N-eff = 3.30 +/- 0.27 for the effective number of relativistic degrees of freedom, and an upper limit of 0.23 eV for the sum of neutrino masses. Our results are in excellent agreement with big bang nucleosynthesis and the standard value of N-eff = 3.046. We find no evidence for dynamical dark energy; using BAO and CMB data, the dark energy equation of state parameter is constrained to be w = -1.13(-0.10)(+0.13). We also use the Planck data to set limits on a possible variation of the fine-structure constant, dark matter annihilation and primordial magnetic fields. Despite the success of the six-parameter ACDM model in describing the Planck data at high multipoles, we note that this cosmology does not provide a good fit to the temperature power spectrum at low multipoles. The unusual shape of the spectrum in the multipole range 20 less than or similar to l less than or similar to 40 was seen previously in the WMAP data and is a real feature of the primordial CMB anisotropies. The poor fit to the spectrum at low multipoles is not of decisive significance, but is an "anomaly" in an otherwise self-consistent analysis of the Planck temperature data. C1 [Bartlett, J. G.; Bucher, M.; Cardoso, J. -F.; Delabrouille, J.; Ganga, K.; Giraud-Heraud, Y.; Patanchon, G.; Piat, M.; Remazeilles, M.; Rosset, C.; Roudier, G.; Stompor, R.] Univ Paris Diderot, Sorbonne Paris Cite, APC, CNRS IN2P3,CEA Lrfu,Observ Paris, F-75205 Paris 13, France. [Lahteenmaki, A.; Leon-Tavares, J.; Poutanen, T.] Aalto Univ Metsahovi Radio Observ, Kylmala 02540, Finland. [Kunz, M.] African Inst Math Sci, ZA-7950 Cape Town, South Africa. [Natoli, P.; Polenta, G.] Agenzia Spaziale Italiana Sci Data Ctr, I-00133 Rome, Italy. [Mandolesi, N.] Agenzia Spaziale Italiana, I-00198 Rome, Italy. 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EM gpe@ast.cam.ac.uk RI Martinez-Gonzalez, Enrique/E-9534-2015; Gonzalez-Nuevo, Joaquin/I-3562-2014; Yvon, Dominique/D-2280-2015; Mazzotta, Pasquale/B-1225-2016; Colombo, Loris/J-2415-2016; Novikov, Igor/N-5098-2015; Nati, Federico/I-4469-2016; Novikov, Dmitry/P-1807-2015; Herranz, Diego/K-9143-2014; Vielva, Patricio/F-6745-2014; Toffolatti, Luigi/K-5070-2014; Tomasi, Maurizio/I-1234-2016; White, Martin/I-3880-2015; Valiviita, Jussi/A-9058-2016; Kurki-Suonio, Hannu/B-8502-2016; Pearson, Timothy/N-2376-2015; Stolyarov, Vladislav/C-5656-2017; Piacentini, Francesco/E-7234-2010; Atrio-Barandela, Fernando/A-7379-2017; Lahteenmaki, Anne/L-5987-2013; Lattanzi, Massimiliano/D-8120-2011; popa, lucia/B-4718-2012; Gruppuso, Alessandro/N-5592-2015; OI TERENZI, LUCA/0000-0001-9915-6379; Starck, Jean-Luc/0000-0003-2177-7794; Reach, William/0000-0001-8362-4094; Franceschi, Enrico/0000-0002-0585-6591; Mitra, Sanjit/0000-0002-0800-4626; Martinez-Gonzalez, Enrique/0000-0002-0179-8590; Gonzalez-Nuevo, Joaquin/0000-0003-1354-6822; Mazzotta, Pasquale/0000-0002-5411-1748; Colombo, Loris/0000-0003-4572-7732; Nati, Federico/0000-0002-8307-5088; Herranz, Diego/0000-0003-4540-1417; Vielva, Patricio/0000-0003-0051-272X; Toffolatti, Luigi/0000-0003-2645-7386; Tomasi, Maurizio/0000-0002-1448-6131; White, Martin/0000-0001-9912-5070; Valiviita, Jussi/0000-0001-6225-3693; Kurki-Suonio, Hannu/0000-0002-4618-3063; Pearson, Timothy/0000-0001-5213-6231; Stolyarov, Vladislav/0000-0001-8151-828X; Piacentini, Francesco/0000-0002-5444-9327; Atrio-Barandela, Fernando/0000-0002-2130-2513; Lattanzi, Massimiliano/0000-0003-1059-2532; Gruppuso, Alessandro/0000-0001-9272-5292; De Zotti, Gianfranco/0000-0003-2868-2595; Juvela, Mika/0000-0002-5809-4834; Lilje, Per/0000-0003-4324-7794; Paoletti, Daniela/0000-0003-4761-6147; Savini, Giorgio/0000-0003-4449-9416; Pierpaoli, Elena/0000-0002-7957-8993; Huffenberger, Kevin/0000-0001-7109-0099; Galeotta, Samuele/0000-0002-3748-5115; Ricciardi, Sara/0000-0002-3807-4043; Zacchei, Andrea/0000-0003-0396-1192; Scott, Douglas/0000-0002-6878-9840; Villa, Fabrizio/0000-0003-1798-861X; Hivon, Eric/0000-0003-1880-2733 FU ESA; CNES; CNRS/INSU-IN2P3-INP (France) FX The development of Planck has been supported by: ESA; CNES and CNRS/INSU-IN2P3-INP (France); ASI, CNR, and INAF (Italy); NASA and DoE (USA); STFC and UKSA (UK); CSIC, MICINN and JA (Spain); Tekes, AoF and CSC (Finland); DLR and MPG (Germany); CSA (Canada); DTU Space (Denmark); SER/SSO (Switzerland); RCN (Norway); SFI (Ireland); FCT/MCTES (Portugal); and PRACE (EU). A description of the Planck Collaboration and a list of its members, including the technical or scientific activities in which they have been involved, can be found at http://www.sciops.esa.int/index.php? project=planck&page=Planck_Collaboration. We thank the referee for a comprehensive and helpful report. We also thank Jean-Philippe Uzan for his contributions to Sect. 6.8. We additionally acknowledge useful comments on the first version of this paper from a large number of scientists who have helped improve the clarity of the revised version. We mention specifically Jim Braatz, John Carlstrom, Alex Conley, Raphael Flauger, Liz Humphreys, Adam Riess, Beth Reid, Uros Seljak, David Spergel, Mark Sullivan, and Reynald Pain. NR 359 TC 631 Z9 632 U1 3 U2 3 PU EDP SCIENCES S A PI LES ULIS CEDEX A PA 17, AVE DU HOGGAR, PA COURTABOEUF, BP 112, F-91944 LES ULIS CEDEX A, FRANCE SN 1432-0746 J9 ASTRON ASTROPHYS JI Astron. Astrophys. PD NOV PY 2014 VL 571 AR A16 DI 10.1051/0004-6361/201321591 PG 66 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA AT9ZK UT WOS:000345282600027 ER PT J AU Ade, PAR Aghanim, N Armitage-Caplan, C Arnaud, M Ashdown, M Atrio-Barandela, F Aumont, J Baccigalupi, C Banday, AJ Barreiro, RB Bartlett, JG Bartolo, N Battaner, E Benabed, K Benoit, A Benoit-Levy, A Bernard, JP Bersanelli, M Bielewicz, P Bobin, J Bock, JJ Bonaldi, A Bonavera, L Bond, JR Borrill, J Bouchet, FR Bridges, M Bucher, M Burigana, C Butler, RC Cardoso, JF Catalano, A Challinor, A Chamballu, A Chiang, HC Chiang, LY Christensen, PR Church, S Clements, DL Colombi, S Colombo, LPL Couchot, F Coulais, A Crill, BP Curto, A Cuttaia, F Danese, L Davies, RD Davis, RJ de Bernardis, P de Rosa, A de Zotti, G Delabrouille, J Delouis, JM Desert, FX Diego, JM Dole, H Donzelli, S Dore, O Douspis, M Ducout, A Dunkley, J Dupac, X Efstathiou, G Elsner, F Ensslin, TA Eriksen, HK Fergusson, J Finelli, F Forni, O Frailis, M Franceschi, E Galeotta, S Ganga, K Giard, M Giraud-Heraud, Y Gonzalez-Nuevo, J Gorski, KM Gratton, S Gregorio, A Gruppuso, A Hansen, FK Hanson, D Harrison, D Heavens, A Henrot-Versille, S Hernandez-Monteagudo, C Herranz, D Hildebrandt, SR Hivon, E Hobson, M Holmes, WA Hornstrup, A Hovest, W Huffenberger, KM Jaffe, AH Jaffe, TR Jones, WC Juvela, M Keihanen, E Keskitalo, R Kisner, TS Knoche, J Knox, L Kunz, M Kurki-Suonio, H Lacasa, F Lagache, G Lahteenmaki, A Lamarre, JM Lasenby, A Laureijs, RJ Lawrence, CR Leahy, JP Leonardi, R Lesgourgues, J Lewis, A Liguori, M Lilje, PB Linden-Vornle, M Lopez-Caniego, M Lubin, PM Macias-Perez, JF Maffei, B Maino, D Mandolesi, N Mangilli, A Marinucci, D Maris, M Marshall, DJ Martin, PG Martinez-Gonzalez, E Masi, S Massardi, M Matarrese, S Matthai, F Mazzotta, P Meinhold, PR Melchiorri, A Mendes, L Mennella, A Migliaccio, M Mitra, S Miville-Deschenes, MA Moneti, A Montier, L Morgante, G Mortlock, D Moss, A Munshi, D Murphy, JA Naselsky, P Natoli, P Netterfield, CB Norgaard-Nielsen, HU Noviello, F Novikov, D Novikov, I Osborne, S Oxborrowl, CA Paci, F Pagano, L Pajot, F Paoletti, D Pasian, F Patanchon, G Peiris, HV Perdereau, O Perotto, L Perrotta, F Piacentini, F Piat, M Pierpaoli, E Pietrobon, D Plaszczynski, S Pointecouteau, E Polenta, G Ponthieu, N Popa, L Poutanen, T Pratt, GW Prezeau, G Prunet, S Puget, JL Rachen, JP Racine, B Rebolo, R Reinecke, M Remazeilles, M Renault, C Renzi, A Ricciardi, S Riller, T Ristorcelli, I Rocha, G Rosset, C Roudier, G Rubino-Martin, JA Rusholme, B Sandri, M Santos, D Savini, G Scott, D Seiffert, MD Shellard, EPS Smith, K Spencer, LD Starck, JL Stolyarov, V Stompor, R Sudiwala, R Sunyaev, R Sureau, F Sutter, P Sutton, D Suur-Uski, AS Sygnet, JF Tauber, JA Tavagnacco, D Terenzi, L Toffolatti, L Tomasi, M Tristram, M Tucci, M Tuovinen, J Valenziano, L Valiviita, J Van Tent, B Varis, J Vielva, P Villa, F Vittorio, N Wade, LA Wandelt, BD White, M White, SDM Yvon, D Zacchei, A Zonca, A AF Ade, P. A. R. Aghanim, N. Armitage-Caplan, C. Arnaud, M. Ashdown, M. Atrio-Barandela, F. Aumont, J. Baccigalupi, C. Banday, A. J. Barreiro, R. B. Bartlett, J. G. Bartolo, N. Battaner, E. Benabed, K. Benoit, A. Benoit-Levy, A. Bernard, J. -P. Bersanelli, M. Bielewicz, P. Bobin, J. Bock, J. J. Bonaldi, A. Bonavera, L. Bond, J. R. Borrill, J. Bouchet, F. R. Bridges, M. Bucher, M. Burigana, C. Butler, R. C. Cardoso, J. -F. Catalano, A. Challinor, A. Chamballu, A. Chiang, H. C. Chiang, L. -Y Christensen, P. R. Church, S. Clements, D. L. Colombi, S. Colombo, L. P. L. Couchot, F. Coulais, A. Crill, B. P. Curto, A. Cuttaia, F. Danese, L. Davies, R. D. Davis, R. J. de Bernardis, P. de Rosa, A. de Zotti, G. Delabrouille, J. Delouis, J. -M. Desert, F. -X. Diego, J. M. Dole, H. Donzelli, S. Dore, O. Douspis, M. Ducout, A. Dunkley, J. Dupac, X. Efstathiou, G. Elsner, F. Ensslin, T. A. Eriksen, H. K. Fergusson, J. Finelli, F. Forni, O. Frailis, M. Franceschi, E. Galeotta, S. Ganga, K. Giard, M. Giraud-Heraud, Y. Gonzalez-Nuevo, J. Gorski, K. M. Gratton, S. Gregorio, A. Gruppuso, A. Hansen, F. K. Hanson, D. Harrison, D. Heavens, A. Henrot-Versille, S. Hernandez-Monteagudo, C. Herranz, D. Hildebrandt, S. R. Hivon, E. Hobson, M. Holmes, W. A. Hornstrup, A. Hovest, W. Huffenberger, K. M. Jaffe, A. H. Jaffe, T. R. Jones, W. C. Juvela, M. Keihanen, E. Keskitalo, R. Kisner, T. S. Knoche, J. Knox, L. Kunz, M. Kurki-Suonio, H. Lacasa, F. Lagache, G. Lahteenmaki, A. Lamarre, J. -M. Lasenby, A. Laureijs, R. J. Lawrence, C. R. Leahy, J. P. Leonardi, R. Lesgourgues, J. Lewis, A. Liguori, M. Lilje, P. B. Linden-Vornle, M. Lopez-Caniego, M. Lubin, P. M. Macias-Perez, J. F. Maffei, B. Maino, D. Mandolesi, N. Mangilli, A. Marinucci, D. Maris, M. Marshall, D. J. Martin, P. G. Martinez-Gonzalez, E. Masi, S. Massardi, M. Matarrese, S. Matthai, F. Mazzotta, P. Meinhold, P. R. Melchiorri, A. Mendes, L. Mennella, A. Migliaccio, M. Mitra, S. Miville-Deschenes, M. -A. Moneti, A. Montier, L. Morgante, G. Mortlock, D. Moss, A. Munshi, D. Murphy, J. A. Naselsky, P. Natoli, P. Netterfield, C. B. Norgaard-Nielsen, H. U. Noviello, F. Novikov, D. Novikov, I. Osborne, S. Oxborrowl, C. A. Paci, F. Pagano, L. Pajot, F. Paoletti, D. Pasian, F. Patanchon, G. Peiris, H. V. Perdereau, O. Perotto, L. Perrotta, F. Piacentini, F. Piat, M. Pierpaoli, E. Pietrobon, D. Plaszczynski, S. Pointecouteau, E. Polenta, G. Ponthieu, N. Popa, L. Poutanen, T. Pratt, G. W. Prezeau, G. Prunet, S. Puget, J. -L. Rachen, J. P. Racine, B. Rebolo, R. Reinecke, M. Remazeilles, M. Renault, C. Renzi, A. Ricciardi, S. Riller, T. Ristorcelli, I. Rocha, G. Rosset, C. Roudier, G. Rubino-Martin, J. A. Rusholme, B. Sandri, M. Santos, D. Savini, G. Scott, D. Seiffert, M. D. Shellard, E. P. S. Smith, K. Spencer, L. D. Starck, J. -L. Stolyarov, V. Stompor, R. Sudiwala, R. Sunyaev, R. Sureau, F. Sutter, P. Sutton, D. Suur-Uski, A. -S. Sygnet, J. -F. Tauber, J. A. Tavagnacco, D. Terenzi, L. Toffolatti, L. Tomasi, M. Tristram, M. Tucci, M. Tuovinen, J. Valenziano, L. Valiviita, J. Van Tent, B. Varis, J. Vielva, P. Villa, F. Vittorio, N. Wade, L. A. Wandelt, B. D. White, M. White, S. D. M. Yvon, D. Zacchei, A. Zonca, A. CA Planck Collaboration TI Planck 2013 results. XXIV. Constraints on primordial non-Gaussianity SO ASTRONOMY & ASTROPHYSICS LA English DT Article DE cosmic background radiation; cosmology: observations; cosmology: theory; early Universe; inflation; methods: data analysis ID PROBE WMAP OBSERVATIONS; OBSERVATIONS COSMOLOGICAL INTERPRETATION; MICROWAVE BACKGROUND BISPECTRUM; NONLINEAR COUPLING PARAMETER; 3-POINT CORRELATION-FUNCTION; LARGE-SCALE STRUCTURE; MINKOWSKI FUNCTIONALS; COMPONENT SEPARATION; POINT SOURCES; POLARIZATION ANISOTROPIES AB The Planck nominal mission cosmic microwave background (CMB) maps yield unprecedented constraints on primordial non-Gaussianity (NG). Using three optimal bispectrum estimators, separable template-fitting (KSW), binned, and modal, we obtain consistent values for the primordial local, equilateral, and orthogonal bispectrum amplitudes, quoting as our final result f(NL)(local) = 2.7 +/- 5.8, f(NL)(equil) = -42 +/- 75, and f(NL)(ortho) = 25 +/- 39 (68% CL statistical). Non-Gaussianity is detected in the data; using skew-C 'statistics we find a nonzero bispectrum from residual point sources, and the integrated-Sachs-Wolfe-lensing bispectrum at a level expected in the CDM scenario. The results are based on comprehensive crossvalidation of these estimators on Gaussian and non-Gaussian simulations, are stable across component separation techniques, pass an extensive suite of tests, and are confirmed by skew-C `, wavelet bispectrum and Minkowski functional estimators. Beyond estimates of individual shape amplitudes, we present model-independent, three-dimensional reconstructions of the Planck CMB bispectrum and thus derive constraints on early-Universe scenarios that generate primordial NG, including general single-field models of inflation, excited initial states (non-Bunch-Davies vacua), and directionally-dependent vector models. We provide an initial survey of scale-dependent feature and resonance models. These results bound both general single-field and multi-field model parameter ranges, such as the speed of sound, cs 0 : 02 (95% CL), in an e ff ective field theory parametrization, and the curvaton decay fraction rD 0 : 15 (95% CL). The Planck data significantly limit the viable parameter space of the ekpyrotic / cyclic scenarios. The amplitude of the four-point function in the local model NL < 2800 (95% CL). 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R.; Cardoso, J. -F.; Colombi, S.; Delouis, J. -M.; Ducout, A.; Elsner, F.; Hivon, E.; Mangilli, A.; Moneti, A.; Prunet, S.; Sutter, P.; Sygnet, J. -F.; Wandelt, B. D.] CNRS, Inst Astrophys Paris, UMR 7095, F-75014 Paris, France. [Popa, L.] Inst Space Sci, Bucharest 077125, Romania. [Chiang, L. -Y] Acad Sinica, Inst Astron & Astrophys, Taipei 106, Taiwan. [Bridges, M.; Challinor, A.; Efstathiou, G.; Gratton, S.; Harrison, D.; Migliaccio, M.; Sutton, D.] Univ Cambridge, Inst Astron, Cambridge CB3 0HA, England. [Eriksen, H. K.; Hansen, F. K.; Lilje, P. B.; Valiviita, J.] Univ Oslo, Inst Theoret Astrophys, N-0315 Oslo, Norway. [Rebolo, R.; Rubino-Martin, J. A.] Inst Astrofis Canarias, Tenerife 38200, Spain. [Barreiro, R. B.; Bonavera, L.; Curto, A.; Diego, J. M.; Gonzalez-Nuevo, J.; Herranz, D.; Lopez-Caniego, M.; Martinez-Gonzalez, E.; Toffolatti, L.; Vielva, P.] Univ Cantabria, CSIC, Inst Fis Cantabria, E-39005 Santander, Spain. [Bartlett, J. G.; Bock, J. J.; Colombo, L. P. L.; Dore, O.; Gorski, K. M.; Hanson, D.; Holmes, W. A.; Lawrence, C. R.; Mitra, S.; Pietrobon, D.; Prezeau, G.; Rocha, G.; Roudier, G.; Seiffert, M. D.; Wade, L. A.] CALTECH, Jet Prop Lab, Pasadena, CA USA. [Bonaldi, A.; Davies, R. D.; Davis, R. J.; Leahy, J. P.; Maffei, B.; Noviello, F.; Remazeilles, M.] Univ Manchester, Jodrell Bank, Ctr Astrophys, Sch Phys & Astron, Manchester M13 9PL, Lancs, England. [Ashdown, M.; Bridges, M.; Challinor, A.; Gratton, S.; Harrison, D.; Migliaccio, M.; Stolyarov, V.; Sutton, D.] Kavli Inst Cosmol Cambridge, Cambridge CB3 0HA, England. [Couchot, F.; Henrot-Versille, S.; Perdereau, O.; Plaszczynski, S.; Tristram, M.; Tucci, M.] Univ Paris 11, CNRS, IN2P3, LAL, F-91383 Orsay, France. [Catalano, A.; Coulais, A.; Lamarre, J. -M.; Roudier, G.] CNRS, Observ Paris, LERMA, F-75014 Paris, France. [Arnaud, M.; Bobin, J.; Chamballu, A.; Marshall, D. J.; Pratt, G. W.; Starck, J. -L.; Sureau, F.] Univ Paris Diderot, CNRS, CEA DSM, Lab AIM,IRFU Serv Astrophys, F-91191 Gif Sur Yvette, France. [Cardoso, J. -F.] CNRS, Lab Traitement & Commun Informat, UMR 5141, F-75634 Paris 13, France. [Cardoso, J. -F.] Telecom ParisTech, F-75634 Paris 13, France. [Catalano, A.; Macias-Perez, J. F.; Perotto, L.; Renault, C.; Santos, D.] Univ Grenoble 1, Inst Natl Polytech Grenoble, CNRS IN2P3, Lab Phys Subatom & Cosmol, F-38026 St Martin Dheres, France. [Van Tent, B.] Univ Paris 11, Phys Theor Lab, F-91405 Orsay, France. [Kisner, T. S.] CNRS, F-91405 Orsay, France. [Ensslin, T. A.; Hernandez-Monteagudo, C.; Hovest, W.; Knoche, J.; Matthai, F.; Rachen, J. P.; Reinecke, M.; Riller, T.; Sunyaev, R.; White, S. D. M.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. [Hanson, D.] Max Planck Inst Astrophys, D-85741 Garching, Germany. [Tuovinen, J.; Varis, J.] McGill Univ, McGill Phys, Montreal, PQ H3A 2T8, Canada. [Murphy, J. A.] VTT Tech Res Ctr, MilliLab, Espoo 02044, Finland. [Christensen, P. R.; Naselsky, P.; Novikov, I.] Natl Univ Ireland, Dept Expt Phys, Maynooth, Kildare, Ireland. [Crill, B. P.] Niels Bohr Inst, DK-2100 Copenhagen, Denmark. [Savini, G.] CALTECH, Observat Cosmol, Pasadena, CA 91125 USA. [Lesgourgues, J.] UCL, Opt Sci Lab, London, England. [Baccigalupi, C.; Bielewicz, P.; Danese, L.; Gonzalez-Nuevo, J.; Paci, F.; Perrotta, F.; Renzi, A.] Ecole Polytech Fed Lausanne, SB ITP LPPC, CH-1015 Lausanne, Switzerland. [Ade, P. A. R.; Munshi, D.; Spencer, L. D.; Sudiwala, R.] SISSA, Astrophys Sect, I-34136 Trieste, Italy. [Moss, A.] Cardiff Univ, Sch Phys & Astron, Cardiff CF24 3AA, S Glam, Wales. [Sunyaev, R.] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England. [Borrill, J.] Russian Acad Sci, Space Res Inst IKI, Moscow 117997, Russia. [Stolyarov, V.] Univ Calif Berkeley, Space Sci Lab, Berkeley, CA 94720 USA. [Church, S.; Osborne, S.] Russian Acad Sci, Special Astrophys Observ, Karachai Cherkessian 369167, Russia. [Armitage-Caplan, C.; Dunkley, J.] Stanford Univ, Dept Phys, Stanford, CA 94305 USA. [Lesgourgues, J.] Univ Oxford, Sub Dept Astrophys, Oxford OX1 3RH, England. [Benabed, K.; Benoit-Levy, A.; Bouchet, F. R.; Colombi, S.; Delouis, J. -M.; Elsner, F.; Hivon, E.; Prunet, S.; Wandelt, B. D.] CERN, Div Theory, PH TH, CH-1211 Geneva 23, Switzerland. [Banday, A. J.; Bernard, J. -P.; Bielewicz, P.; Forni, O.; Giard, M.; Jaffe, T. R.; Montier, L.; Pointecouteau, E.; Ristorcelli, I.] Univ Paris 06, UMR7095, F-75014 Paris, France. [Battaner, E.] Univ Toulouse, UPS OMP, IRAP, F-31028 Toulouse 4, France. [Gorski, K. M.] Univ Granada, Dept Fis Teor & Cosmos, Fac Ciencias, E-18071 Granada, Spain. Univ Warsaw Observ, PL-00478 Warsaw, Poland. RP Bartolo, N (reprint author), Univ Padua, Dipartimento Fis & Astron G Galilei, Via Marzolo 8, I-35131 Padua, Italy. EM nicola.bartolo@pd.infn.it RI Tomasi, Maurizio/I-1234-2016; Novikov, Igor/N-5098-2015; Colombo, Loris/J-2415-2016; Nati, Federico/I-4469-2016; popa, lucia/B-4718-2012; Piacentini, Francesco/E-7234-2010; Atrio-Barandela, Fernando/A-7379-2017; Stolyarov, Vladislav/C-5656-2017; White, Martin/I-3880-2015; Valiviita, Jussi/A-9058-2016; Kurki-Suonio, Hannu/B-8502-2016; Lahteenmaki, Anne/L-5987-2013; Toffolatti, Luigi/K-5070-2014; Martinez-Gonzalez, Enrique/E-9534-2015; Herranz, Diego/K-9143-2014; Gonzalez-Nuevo, Joaquin/I-3562-2014; Gruppuso, Alessandro/N-5592-2015; Novikov, Dmitry/P-1807-2015; Mazzotta, Pasquale/B-1225-2016; Butler, Reginald/N-4647-2015; Barreiro, Rita Belen/N-5442-2014; Vielva, Patricio/F-6745-2014; bonavera, laura/E-9368-2017; Remazeilles, Mathieu/N-1793-2015; Yvon, Dominique/D-2280-2015; OI Tomasi, Maurizio/0000-0002-1448-6131; Colombo, Loris/0000-0003-4572-7732; Nati, Federico/0000-0002-8307-5088; Piacentini, Francesco/0000-0002-5444-9327; Atrio-Barandela, Fernando/0000-0002-2130-2513; Stolyarov, Vladislav/0000-0001-8151-828X; White, Martin/0000-0001-9912-5070; Valiviita, Jussi/0000-0001-6225-3693; Kurki-Suonio, Hannu/0000-0002-4618-3063; Toffolatti, Luigi/0000-0003-2645-7386; Martinez-Gonzalez, Enrique/0000-0002-0179-8590; Herranz, Diego/0000-0003-4540-1417; Gonzalez-Nuevo, Joaquin/0000-0003-1354-6822; Gruppuso, Alessandro/0000-0001-9272-5292; Mazzotta, Pasquale/0000-0002-5411-1748; Hivon, Eric/0000-0003-1880-2733; Lilje, Per/0000-0003-4324-7794; Paoletti, Daniela/0000-0003-4761-6147; Galeotta, Samuele/0000-0002-3748-5115; Ricciardi, Sara/0000-0002-3807-4043; Zacchei, Andrea/0000-0003-0396-1192; Scott, Douglas/0000-0002-6878-9840; Villa, Fabrizio/0000-0003-1798-861X; Franceschi, Enrico/0000-0002-0585-6591; Mitra, Sanjit/0000-0002-0800-4626; TERENZI, LUCA/0000-0001-9915-6379; Starck, Jean-Luc/0000-0003-2177-7794; Lopez-Caniego, Marcos/0000-0003-1016-9283; Gregorio, Anna/0000-0003-4028-8785; Polenta, Gianluca/0000-0003-4067-9196; Butler, Reginald/0000-0003-4366-5996; Sandri, Maura/0000-0003-4806-5375; Cuttaia, Francesco/0000-0001-6608-5017; Huffenberger, Kevin/0000-0001-7109-0099; Burigana, Carlo/0000-0002-3005-5796; Bouchet, Francois/0000-0002-8051-2924; Maris, Michele/0000-0001-9442-2754; Valenziano, Luca/0000-0002-1170-0104; Matarrese, Sabino/0000-0002-2573-1243; Pasian, Fabio/0000-0002-4869-3227; WANDELT, Benjamin/0000-0002-5854-8269; Barreiro, Rita Belen/0000-0002-6139-4272; Finelli, Fabio/0000-0002-6694-3269; Frailis, Marco/0000-0002-7400-2135; Vielva, Patricio/0000-0003-0051-272X; bonavera, laura/0000-0001-8039-3876; Rubino-Martin, Jose Alberto/0000-0001-5289-3021; De Zotti, Gianfranco/0000-0003-2868-2595; Masi, Silvia/0000-0001-5105-1439; de Bernardis, Paolo/0000-0001-6547-6446; Morgante, Gianluca/0000-0001-9234-7412; Remazeilles, Mathieu/0000-0001-9126-6266; Savini, Giorgio/0000-0003-4449-9416; Pierpaoli, Elena/0000-0002-7957-8993; Juvela, Mika/0000-0002-5809-4834 NR 282 TC 1126 Z9 1126 U1 21 U2 89 PU EDP SCIENCES S A PI LES ULIS CEDEX A PA 17, AVE DU HOGGAR, PA COURTABOEUF, BP 112, F-91944 LES ULIS CEDEX A, FRANCE SN 1432-0746 J9 ASTRON ASTROPHYS JI Astron. Astrophys. PD NOV PY 2014 VL 571 AR A24 DI 10.1051/0004-6361/201321554 PG 58 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA AT9ZK UT WOS:000345282600018 ER PT J AU Aylward, FO Suen, G Biedermann, PHW Adams, AS Scott, JJ Malfatti, SA del Rio, TG Tringe, SG Poulsen, M Raffa, KF Klepzig, KD Currie, CR AF Aylward, Frank O. Suen, Garret Biedermann, Peter H. W. Adams, Aaron S. Scott, Jarrod J. Malfatti, Stephanie A. del Rio, Tijana Glavina Tringe, Susannah G. Poulsen, Michael Raffa, Kenneth F. Klepzig, Kier D. Currie, Cameron R. TI Convergent Bacterial Microbiotas in the Fungal Agricultural Systems of Insects SO MBIO LA English DT Article ID LEAF-CUTTER ANTS; GUT MICROBIOTA; PHYLOGENETIC CLASSIFICATION; BARK BEETLES; GROWING ANTS; COMMUNITIES; DIVERSITY; HOST; DATABASE; GENES AB The ability to cultivate food is an innovation that has produced some of the most successful ecological strategies on the planet. Although most well recognized in humans, where agriculture represents a defining feature of civilization, species of ants, beetles, and termites have also independently evolved symbioses with fungi that they cultivate for food. Despite occurring across divergent insect and fungal lineages, the fungivorous niches of these insects are remarkably similar, indicating convergent evolution toward this successful ecological strategy. Here, we characterize the microbiota of ants, beetles, and termites engaged in nutritional symbioses with fungi to define the bacterial groups associated with these prominent herbivores and forest pests. Using culture-independent techniques and the in silico reconstruction of 37 composite genomes of dominant community members, we demonstrate that different insect-fungal symbioses that collectively shape ecosystems worldwide have highly similar bacterial microbiotas comprised primarily of the genera Enterobacter, Rahnella, and Pseudomonas. Although these symbioses span three orders of insects and two phyla of fungi, we show that they are associated with bacteria sharing high whole-genome nucleotide identity. Due to the fine-scale correspondence of the bacterial microbiotas of insects engaged in fungal symbioses, our findings indicate that this represents an example of convergence of entire host-microbe complexes. IMPORTANCE The cultivation of fungi for food is a behavior that has evolved independently in ants, beetles, and termites and has enabled many species of these insects to become ecologically important and widely distributed herbivores and forest pests. Although the primary fungal cultivars of these insects have been studied for decades, comparatively little is known of their bacterial microbiota. In this study, we show that diverse fungus-growing insects are associated with a common bacterial community composed of the same dominant members. Furthermore, by demonstrating that many of these bacteria have high whole-genome similarity across distantly related insect hosts that reside thousands of miles apart, we show that these bacteria are an important and underappreciated feature of diverse fungus-growing insects. Because of the similarities in the agricultural lifestyles of these insects, this is an example of convergence between both the life histories of the host insects and their symbiotic microbiota. C1 [Aylward, Frank O.; Suen, Garret; Scott, Jarrod J.; Currie, Cameron R.] Univ Wisconsin, Dept Bacteriol, Madison, WI 53706 USA. [Aylward, Frank O.; Scott, Jarrod J.; Currie, Cameron R.] Univ Wisconsin, Dept Energy, Great Lakes Bioenergy Res Ctr, Madison, WI USA. [Biedermann, Peter H. W.] Max Planck Inst Chem Ecol, Insect Symbiosis Res Grp, Jena, Germany. [Adams, Aaron S.; Raffa, Kenneth F.] Univ Wisconsin, Dept Entomol, Madison, WI 53706 USA. [Scott, Jarrod J.] Smithsonian Trop Res Inst, Balboa, Ancon, Panama. [Malfatti, Stephanie A.; del Rio, Tijana Glavina; Tringe, Susannah G.] Genome Inst, Dept Energy Joint, Walnut Creek, CA USA. [Poulsen, Michael] Univ Copenhagen, Sect Ecol & Evolut, Dept Biol, Copenhagen, Denmark. [Klepzig, Kier D.] US Forest Serv, USDA, Sourth Res Stn, Asheville, NC USA. RP Aylward, FO (reprint author), Univ Wisconsin, Dept Bacteriol, Madison, WI 53706 USA. EM faylward@hawaii.edu; currie@bact.wisc.edu RI Biedermann, Peter/E-3641-2013; OI Biedermann, Peter/0000-0003-4234-5659; Tringe, Susannah/0000-0001-6479-8427; Suen, Garret/0000-0002-6170-711X; Poulsen, Michael/0000-0002-2839-1715 FU Office of Science of the U.S. Department of Energy [DE-AC02-05CH11231]; USDA NRI [2008-02438]; National Science Foundation [DEB-0747002, MCB-0702025, MCB-0731822]; DOE Great Lakes Bioenergy Research Center (DOE Office of Science BER) [DE-FC02-07ER64494]; SNSF [PB-BEP3_141472]; STENO grant from The Danish Council for Independent Research-Natural Sciences FX This work was supported by the Office of Science of the U.S. Department of Energy under contract no. DE-AC02-05CH11231, the USDA NRI (2008-02438), National Science Foundation grants DEB-0747002, MCB-0702025, and MCB-0731822 to C.R.C., and the DOE Great Lakes Bioenergy Research Center (DOE Office of Science BER DE-FC02-07ER64494). P.H.W.B. was funded by an SNSF postdoctoral research grant (PB-BEP3_141472), and M.P. was supported by a STENO grant from The Danish Council for Independent Research-Natural Sciences. NR 78 TC 13 Z9 13 U1 5 U2 13 PU AMER SOC MICROBIOLOGY PI WASHINGTON PA 1752 N ST NW, WASHINGTON, DC 20036-2904 USA SN 2150-7511 J9 MBIO JI mBio PD NOV-DEC PY 2014 VL 5 IS 6 AR e02077-14 DI 10.1128/mBio.02077-14 PG 10 WC Microbiology SC Microbiology GA AX7CE UT WOS:000347073600038 PM 25406380 ER PT J AU Foo, JL Jensen, HM Dahl, RH George, K Keasling, JD Lee, TS Leong, S Mukhopadhyay, A AF Foo, Jee Loon Jensen, Heather M. Dahl, Robert H. George, Kevin Keasling, Jay D. Lee, Taek Soon Leong, Susanna Mukhopadhyay, Aindrila TI Improving Microbial Biogasoline Production in Escherichia coli Using Tolerance Engineering SO MBIO LA English DT Article ID ISOPRENOID PRODUCTION; ALDEHYDE REDUCTASE; HEAT-SHOCK; ONE-POT; RESISTANCE; GENES; EXPRESSION; PROTEINS; PATHWAY; METHYLTRANSFERASE AB Engineering microbial hosts for the production of fungible fuels requires mitigation of limitations posed on the production capacity. One such limitation arises from the inherent toxicity of solvent-like biofuel compounds to production strains, such as Escherichia coli. Here we show the importance of host engineering for the production of short-chain alcohols by studying the overexpression of genes upregulated in response to exogenous isopentenol. Using systems biology data, we selected 40 genes that were upregulated following isopentenol exposure and subsequently overexpressed them in E. coli. Overexpression of several of these candidates improved tolerance to exogenously added isopentenol. Genes conferring isopentenol tolerance phenotypes belonged to diverse functional groups, such as oxidative stress response (soxS, fpr, and nrdH), general stress response (metR, yqhD, and gidB), heat shock-related response (ibpA), and transport (mdlB). To determine if these genes could also improve isopentenol production, we coexpressed the tolerance-enhancing genes individually with an isopentenol production pathway. Our data show that expression of 6 of the 8 candidates improved the production of isopentenol in E. coli, with the methionine biosynthesis regulator MetR improving the titer for isopentenol production by 55%. Additionally, expression of MdlB, an ABC transporter, facilitated a 12% improvement in isopentenol production. To our knowledge, MdlB is the first example of a transporter that can be used to improve production of a short-chain alcohol and provides a valuable new avenue for host engineering in biogasoline production. IMPORTANCE The use of microbial host platforms for the production of bulk commodities, such as chemicals and fuels, is now a focus of many biotechnology efforts. Many of these compounds are inherently toxic to the host microbe, which in turn places a limit on production despite efforts to optimize the bioconversion pathways. In order to achieve economically viable production levels, it is also necessary to engineer production strains with improved tolerance to these compounds. We demonstrate that microbial tolerance engineering using transcriptomics data can also identify targets that improve production. Our results include an exporter and a methionine biosynthesis regulator that improve isopentenol production, providing a starting point to further engineer the host for biogasoline production. C1 [Foo, Jee Loon] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 639798, Singapore. [Foo, Jee Loon; Jensen, Heather M.; George, Kevin; Keasling, Jay D.; Lee, Taek Soon; Mukhopadhyay, Aindrila] Joint BioEnergy Inst, Emeryville, CA 94608 USA. [Foo, Jee Loon; Leong, Susanna] Natl Univ Singapore, Yong Loo Lin Sch Med, Dept Biochem, Singapore 117595, Singapore. [Jensen, Heather M.; George, Kevin; Keasling, Jay D.; Lee, Taek Soon; Mukhopadhyay, Aindrila] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Phys Biosci Div, Berkeley, CA 94720 USA. [Dahl, Robert H.; Keasling, Jay D.] Univ Calif Berkeley, Dept Biomol & Chem Engn, Berkeley, CA 94720 USA. [Dahl, Robert H.; Keasling, Jay D.] Univ Calif Berkeley, Dept Bioengn, Berkeley, CA 94720 USA. [Leong, Susanna] Singapore Inst Technol, Singapore, Singapore. RP Mukhopadhyay, A (reprint author), Joint BioEnergy Inst, Emeryville, CA 94608 USA. EM amukhopadhyay@lbl.gov FU U.S. Department of Energy, Office of Science [DE-AC02-05CH11231]; National Research Foundation of Singapore [NRF-CRP5-2009-03]; U.S. Department of Energy, Office of Biological and Environmental Research [DE-AC02-05CH11231] FX This work was part of the DOE Joint BioEnergy Institute partnership (http://www.jbei.org) supported by the U.S. Department of Energy, Office of Science, Office of Biological and Environmental Research, through contract DE-AC02-05CH11231 between Lawrence Berkeley National Laboratory and the U.S. Department of Energy. Jee Loon Foo was supported by the Competitive Research Program of the National Research Foundation of Singapore (NRF-CRP5-2009-03). NR 46 TC 14 Z9 16 U1 2 U2 6 PU AMER SOC MICROBIOLOGY PI WASHINGTON PA 1752 N ST NW, WASHINGTON, DC 20036-2904 USA SN 2150-7511 J9 MBIO JI mBio PD NOV-DEC PY 2014 VL 5 IS 6 AR e01932-14 DI 10.1128/mBio.01932-14 PG 9 WC Microbiology SC Microbiology GA AX7CE UT WOS:000347073600020 PM 25370492 ER PT J AU Belleri, A Lollini, R Dutton, SM AF Belleri, Annamaria Lollini, Roberto Dutton, Spencer M. TI Natural ventilation design: An analysis of predicted and measured performance SO BUILDING AND ENVIRONMENT LA English DT Article DE Natural ventilation; Early-design-stage; Uncertainty analysis; Air change rates; Occupant behavior; Airflow network AB We present a study of natural ventilation design during the early (conceptual) stage of a building's design, based on a field study in a naturally ventilated office in California where we collected data on occupants' window use, local weather conditions, indoor environmental conditions, and air change rates based on tracer-gas decay. We performed uncertainty and sensitivity analyses to determine which design parameters have most impact on the uncertainty associated with ventilation performance predictions. Using the results of the field study along with wind-tunnel measurements and other detailed analysis, we incrementally improved our early-design-stage model. The improved model's natural ventilation performance predictions were significantly more accurate than those of the first draft early-stage-design model that employed model assumptions typical during initial design. This process highlighted significant limitations in the EnergyPlus software's models of occupant-driven window control. We conclude with recommendations on key design parameters including window control, wind pressure coefficients and weather data resolution to help improve early-design-stage predictions of natural ventilation performance using EnergyPlus. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Belleri, Annamaria; Lollini, Roberto] Inst Renewable Energy, EURAC Res, Bolzano, Italy. [Belleri, Annamaria] Univ Bergamo, Bergamo, Italy. [Dutton, Spencer M.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. RP Belleri, A (reprint author), Viale Druso 1, I-39100 Bolzano, Italy. EM annamaria.belleri@eurac.edu OI Lollini, Roberto/0000-0003-0480-1166 FU Cariplo Foundation [(2011)AP-02]; California Energy Commission; Public Interest Energy Research Program; Buildings End Use Energy Efficiency Program [500-10-025]; U.S. Department of Energy [DE-AC03-76SF00098] FX This work was supported by Cariplo Foundation, (2011)AP-02 "Promoting the training of human capital for excellence" (2011) and by the California Energy Commission, Public Interest Energy Research Program, Buildings End Use Energy Efficiency Program, Contract number 500-10-025, through the U.S. Department of Energy under contract DE-AC03-76SF00098. The authors would like to thank our partners Edward Arens and Hui Zhang, from the University of California (UC) Berkeley Center for the Built Environment; David Banks from CPP Engineering; William Fisk and Priya Gandhi for their valuable input and Nan Wishner for editing. NR 29 TC 14 Z9 14 U1 2 U2 18 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0360-1323 EI 1873-684X J9 BUILD ENVIRON JI Build. Environ. PD NOV PY 2014 VL 81 BP 123 EP 138 DI 10.1016/j.buildenv.2014.06.009 PG 16 WC Construction & Building Technology; Engineering, Environmental; Engineering, Civil SC Construction & Building Technology; Engineering GA AQ1HJ UT WOS:000342532200014 ER PT J AU Puretzky, AA Merkulov, IA Rouleau, CM Eres, G Geohegan, DB AF Puretzky, A. A. Merkulov, I. A. Rouleau, C. M. Eres, G. Geohegan, D. B. TI Revealing the surface and bulk regimes of isothermal graphene nucleation and growth on Ni with in situ kinetic measurements and modeling SO CARBON LA English DT Article ID CHEMICAL-VAPOR-DEPOSITION; FEW-LAYER GRAPHENE; HIGH-QUALITY GRAPHENE; LARGE-AREA; MONOLAYER GRAPHENE; POLYCRYSTALLINE NI; BILAYER GRAPHENE; CARBON; NICKEL; MECHANISM AB In situ optical diagnostics are used to reveal the isothermal nucleation and growth kinetics of graphene on Ni across a wide temperature range (560 degrees C < T < 840 degrees C) by chemical vapor deposition from single, sub-second pulses of acetylene. An abrupt, two-orders of magnitude change in growth times (similar to 100-1 s) is revealed at T = 680 degrees C. Above this temperature, sigmoidal kinetics are measured and attributed to autocatalytic nucleation and growth from carbon dissolved in the bulk of the Ni film. However, for T < 680 degrees C fast surface nucleation and growth occurring during the gas pulse appears responsible for the drastic alteration of the kinetics of subsequent dissolution-mediated growth. A simple and general kinetic model for isothermal graphene growth is developed that includes the nucleation phase and the effects of carbon solubility in metals, describes delayed nucleation, and allows the interpretation of the competition between surface- and bulk-nucleation and growth. The easily-implemented optical reflectivity diagnostics and the simple kinetic model described here allow a pathway to optimize the growth of graphene on metals with arbitrary carbon solubility. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Puretzky, A. A.; Merkulov, I. A.; Rouleau, C. M.; Eres, G.; Geohegan, D. B.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. RP Puretzky, AA (reprint author), Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. EM puretzkya@ornl.gov RI Rouleau, Christopher/Q-2737-2015; Puretzky, Alexander/B-5567-2016; Geohegan, David/D-3599-2013; Eres, Gyula/C-4656-2017 OI Rouleau, Christopher/0000-0002-5488-3537; Puretzky, Alexander/0000-0002-9996-4429; Geohegan, David/0000-0003-0273-3139; Eres, Gyula/0000-0003-2690-5214 FU Materials Sciences and Engineering Division, Office of Basic Energy Sciences, U.S. Department of Energy; Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy FX Synthesis science was sponsored by the Materials Sciences and Engineering Division, Office of Basic Energy Sciences, U.S. Department of Energy. Characterization science including Raman spectroscopy was developed at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy. NR 48 TC 4 Z9 4 U1 3 U2 51 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0008-6223 EI 1873-3891 J9 CARBON JI Carbon PD NOV PY 2014 VL 79 BP 256 EP 264 DI 10.1016/j.carbon.2014.07.066 PG 9 WC Chemistry, Physical; Materials Science, Multidisciplinary SC Chemistry; Materials Science GA AQ2YY UT WOS:000342657100026 ER PT J AU Vial, S Nykypanchuk, D Deepak, FL Prado, M Gang, O AF Vial, Stephanie Nykypanchuk, Dmytro Deepak, Francis Leonard Prado, Marta Gang, Oleg TI Plasmonic response of DNA-assembled gold nanorods: Effect of DNA linker length, temperature and linker/nanoparticles ratio SO JOURNAL OF COLLOID AND INTERFACE SCIENCE LA English DT Article DE Plasmon coupling; Gold nanorod; DNA; Self-assembly ID NANOPARTICLE ASSEMBLIES; OPTICAL-PROPERTIES; CRYSTALLIZATION; AGGREGATION; GROWTH AB Optical properties of gold nanorod (AuNR) particles self-assembled with DNA are systematically investigated. The particles assembly is driven by specific base-pair recognition between single strand (ss) DNA linker and DNA anchored to AuNRs, and it results in the distance- and morphology-dependent plasmonic coupling of AuNRs. The longitudinal plasmon band is distinctly affected by tuning the length of DNA linker, the temperature and linker/AuNRs ratio. We observed that the increase of temperature enhances the interparticle interactions and leads to clear distinguishable plasmonic signals between linker lengths up to 100 bases. Both absorbance decrease and shift of the longitudinal plasmon allow for use of AuNR for the DNA sensing applications. (C) 2014 Elsevier Inc. All rights reserved. C1 [Vial, Stephanie; Deepak, Francis Leonard; Prado, Marta] Int Iberian Nanotechnol, P-4715330 Braga, Portugal. [Nykypanchuk, Dmytro; Gang, Oleg] Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11973 USA. RP Vial, S (reprint author), Univ Minho, Headquarters European Inst Excellence Tissue Engn, Res Grp Biomat Biodegradables & Biomimet 3Bs, P-4806909 Taipas, Guimaraes, Portugal. EM stephanie.vial@dep.uminho.pt; dnykypan@bnl.gov; leonard.francis@inl.int; marta.prado@inl.int; ogang@bnl.gov RI Prado, Marta/K-7365-2012; INL, Citations/K-3436-2015 OI Vial, Stephanie/0000-0002-8714-0713; Francis, Leonard/0000-0002-3833-1775; Prado, Marta/0000-0002-0529-5771; INL, Citations/0000-0002-3745-5100 FU Self assembled nanostructures and functionalization protocols for biomedical, food quality, and environment control [SAESCTN-PLICDT/1/2011]; U.S. Department of Energy, Office of Basic Energy Sciences [DE-AC02-98CH10886]; Norte Regional Operational programme (ON.2 - O Novo Norte), under the National Strategic Referenced Framework Programme (QREN); European Regional Devevelopment Fund (FEDER) FX The authors thank Dr. Jhon Gonzalez for the discussion, his technical help and his support during the manuscript process. SV acknowledges financial support from "Self assembled nanostructures and functionalization protocols for biomedical, food quality, and environment control" "integrated programme (SAESCTN-PLIC&DT/1/2011), financed by the Norte Regional Operational programme (ON.2 - O Novo Norte), under the National Strategic Referenced Framework Programme (QREN), through the European Regional Devevelopment Fund (FEDER)". Research carried out at the Center for Functional Nanomaterials, Brookhaven National Laboratory, was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, under Contract No. DE-AC02-98CH10886. NR 35 TC 2 Z9 2 U1 6 U2 100 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0021-9797 EI 1095-7103 J9 J COLLOID INTERF SCI JI J. Colloid Interface Sci. PD NOV 1 PY 2014 VL 433 BP 34 EP 42 DI 10.1016/j.jcis.2014.07.020 PG 9 WC Chemistry, Physical SC Chemistry GA AQ1IR UT WOS:000342535600005 PM 25112910 ER PT J AU Beriguete, W Cao, J Ding, YY Hans, S Heeger, KM Hu, LM Huang, AZ Luk, KB Nemchenok, I Qi, M Rosero, R Sun, HS Wang, RG Wang, YF Wen, LJ Yang, Y Yeh, MF Zhang, ZY Zhou, L AF Beriguete, Wanda Cao, Jun Ding, Yayun Hans, Sunej Heeger, Karsten M. Hu, Liangming Huang, Aizhong Luk, Kam-Biu Nemchenok, Igor Qi, Ming Rosero, Richard Sun, Hansheng Wang, Ruiguang Wang, Yifang Wen, Liangjian Yang, Yi Yeh, Minfang Zhang, Zhiyong Zhou, Li TI Production of a gadolinium-loaded liquid scintillator for the Daya Bay reactor neutrino experiment SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE Daya Bay; Reactor; Antineutrino; Gadolinium; Metal-loaded liquid scintillator; Linear alkyl benzene AB We report on the production and characterization of liquid scintillators for the detection of electron antineutrinos by the Daya Bay reactor neutrino experiment. A 185 tons of gadolinium-loaded (0.1% by mass) liquid scintillator (Gd-LS) and a 200 tons of unloaded liquid scintillator (LS) were successfully produced from a linear-alkylbenzene (LAB) solvent in 6 months. The scintillator properties, the production and purification systems, and the quality assurance and control (QA/QC) procedures are described. (C) 2014 Elsevier By. All rights reserved. C1 [Beriguete, Wanda; Hans, Sunej; Hu, Liangming; Rosero, Richard; Yeh, Minfang] Brookhaven Natl Lab, Upton, NY 11973 USA. [Cao, Jun; Ding, Yayun; Sun, Hansheng; Wang, Ruiguang; Wang, Yifang; Wen, Liangjian; Yang, Yi; Zhang, Zhiyong; Zhou, Li] Inst High Energy Phys, Beijing 100039, Peoples R China. [Heeger, Karsten M.] Univ Wisconsin, Madison, WI USA. [Heeger, Karsten M.] Yale Univ, New Haven, CT USA. [Huang, Aizhong] Jinling Petrochem Corp, Nanjing, Jiangsu, Peoples R China. [Luk, Kam-Biu] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. [Luk, Kam-Biu] Univ Calif Berkeley, Berkeley, CA 94720 USA. [Nemchenok, Igor] Joint Inst Nucl Res, Moscow 101000, Russia. [Qi, Ming] Nanjing Univ, Nanjing 210008, Jiangsu, Peoples R China. RP Ding, YY (reprint author), Inst High Energy Phys, Beijing 100039, Peoples R China. EM dingyy@ihep.ac.cn; yeh@bnl.gov RI Nemchenok, Igor/F-9715-2014; Cao, Jun/G-8701-2012 OI Cao, Jun/0000-0002-3586-2319 FU Ministry of Science and Technology of China [2013CB834300]; National Natural Science Foundation of China [11005117]; U.S. Department of Energy, Office of High Energy Physics and Office of Nuclear Physics [DE-AC02-98CH10886, DE-AC02-05CH11231] FX We would like to express our gratitude to the technical staffs of 1HEP for excellent support in production, to Raymond Kwok and his colleagues at CUHK for sample arrangement and shipment for long-term stability monitoring, and to Jinchang Liu, Chengju Lin, WeiliZhong, and J. Pedro Ochoa from IHEP and LBNL for interesting discussions and for help in the attenuation length assessments. This work was partially supported by the Ministry of Science and Technology of China (Grant no. 2013CB834300), National Natural Science Foundation of China (Grant no. 11005117), the U.S. Department of Energy, Office of High Energy Physics and Office of Nuclear Physics (under Contract nos. DE-AC02-98CH10886 and DE-AC02-05CH11231). NR 18 TC 7 Z9 7 U1 1 U2 18 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 82 EP 88 DI 10.1016/j.nirna.2014.05.110 PG 7 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200011 ER PT J AU Lakshmanan, MN Harrawood, BP Rusev, G Agasthya, GA Kapadia, AJ AF Lakshmanan, Manu N. Harrawood, Brian P. Rusev, Gencho Agasthya, Greeshma A. Kapadia, Anuj J. TI Simulations of nuclear resonance fluorescence in GEANT4 SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE Nuclear resonance fluorescence; GEANT4; Simulation benchmarking ID GAMMA-RAYS; EXCITED STATE; IRON STORES; SCATTERING; QUANTIFICATION; SPECTROSCOPY; TEMPERATURE; LIFETIME; WIDTHS; B-11 AB The nuclear resonance fluorescence (NRF) technique has been used effectively to identify isotopes based on their nuclear energy levels. Specific examples of its modern-day applications include detecting spent nuclear waste and cargo scanning for homeland security. The experimental designs for these NRF applications can be more efficiently optimized using Monte Carlo simulations before the experiment is implemented. One of the most widely used Monte Carlo physics simulations is the open-source toolkit GEANT4. However, NRF physics has not been incorporated into the GEANT4 simulation toolkit in publicly available software. Here we describe the development and testing of an NRF simulation in GEANT4. We describe in depth the development and architecture of this software for the simulation of NRF in any isotope in GEANT4; as well as verification and validation testing of the simulation for NRF in boron. In the verification testing, the simulation showed agreement with the analytical model to be within 0.6% difference for boron and iron. In the validation testing, the simulation showed agreement to be within 20.5% difference with the experimental measurements for boron, with the percent difference likely due to small uncertainties in beam polarization, energy distribution, and detector composition. (C) 2014 Elsevier B.V. All rights reserved. C1 [Lakshmanan, Manu N.; Harrawood, Brian P.; Agasthya, Greeshma A.; Kapadia, Anuj J.] Duke Univ, Med Ctr, Dept Radiol, Ravin Adv Imaging Labs, Durham, NC 27710 USA. [Rusev, Gencho] Los Alamos Natl Lab, Div Chem, Los Alamos, NM USA. RP Lakshmanan, MN (reprint author), Duke Univ, Med Ctr, Dept Radiol, Ravin Adv Imaging Labs, Durham, NC 27710 USA. EM mnL7@duke.edu RI Kapadia, Anuj/C-6538-2016; OI Kapadia, Anuj/0000-0003-2755-4495; Rusev, Gencho/0000-0001-7563-1518 NR 48 TC 3 Z9 3 U1 0 U2 7 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 89 EP 96 DI 10.1016/j.nima.2014.06.030 PG 8 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200012 ER PT J AU Novokhatski, A Mosnier, A AF Novokhatski, Alexander Mosnier, Alban TI Short bunch wake potentials for a chain of TESLA cavities SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE Wake field potentials; Accelerating structure; Loss factor ID LONGITUDINAL IMPEDANCE; HIGH-FREQUENCY AB The modification of wake fields from a single cavity to a quasi periodic structure of cavities is of great concern, especially for applications using very short bunches. We extend our former study (Novokhatski, 1997 [1]). A strong modification of wake fields along a train of cavities was clearly found for bunch lengths lower than 1 mm. In particular, the wakes induced by the bunch, as it proceeds down the successive cavities, decrease in amplitude and become more linear around the bunch center, with a profile very close to the integral of the charge density. The loss factor, decreasing also with the number of cells, becomes independent of bunch length for very short bunches and tends asymptotically to a finite value. This nice behavior of wake fields for short bunches presents good opportunity for application of very short bunches in Linear Colliders and X-ray Free Electron Lasers. (C) 2014 Elsevier B.V. All rights reserved. C1 [Novokhatski, Alexander] SLAC, Natl Accelerator Lab, Menlo Pk, CA 94025 USA. [Mosnier, Alban] CEA Saclay, IRFU, Inst Res Fundamental Laws Univ, F-91191 Gif Sur Yvette, France. RP Novokhatski, A (reprint author), SLAC, Natl Accelerator Lab, Menlo Pk, CA 94025 USA. EM novo@slac.stanford.oclu FU Department of Energy [DOE-AC03-76SF00515] FX The authors would like to thank Mike Sullivan and Olivier Napoly for fruitful discussions. Work supported by Department of Energy Contract no. DOE-AC03-76SF00515. NR 12 TC 1 Z9 1 U1 0 U2 1 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 202 EP 209 DI 10.1016/j.nima.2014.06.049 PG 8 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200029 ER PT J AU Mitchell, AJ Bertone, PF DiGiovine, B Lister, CJ Carpenter, MP Chowdhury, P Clark, JA D'Olympia, N Deo, AY Kondev, FG McCutchan, EA Rohrer, J Savard, G Seweryniak, D Zhu, S AF Mitchell, A. J. Bertone, P. F. DiGiovine, B. Lister, C. J. Carpenter, M. P. Chowdhury, P. Clark, J. A. D'Olympia, N. Deo, A. Y. Kondev, F. G. McCutchan, E. A. Rohrer, J. Savard, G. Seweryniak, D. Zhu, S. TI The X-Array and SATURN: A new decay-spectroscopy station for CARIBU SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE Neutron-rich exotic nuclei; beta decay; HPGe detectors; Plastic Scintillator detectors; Tape-Transport system ID SYSTEM AB A new decay-spectroscopy station has been commissioned for experiments with low-energy, fission-fragment radioactive beams from the CARIBU ion source. The new set-up consists of the 'X-Array, a highly-efficient array of HPGe clover detectors, and 'SATURN' (Scintillator And Tape Using Radioactive Nuclei), a plastic scintillator detector combined with a tape-transport system for detection of beta particles and removal of long-lived isobaric decay products. (C) 2014 Elsevier B.V. All rights reserved. C1 [Mitchell, A. J.; Lister, C. J.; Chowdhury, P.; D'Olympia, N.; Deo, A. Y.] Univ Massachusetts Lowell, Dept Phys & Appl Phys, Lowell, MA 01854 USA. [Bertone, P. F.; DiGiovine, B.; Carpenter, M. P.; Clark, J. A.; Kondev, F. G.; McCutchan, E. A.; Rohrer, J.; Savard, G.; Seweryniak, D.; Zhu, S.] Argonne Natl Lab, Div Phys, Argonne, IL 60439 USA. [Kondev, F. G.] Argonne Natl Lab, Nucl Engn Div, Argonne, IL 60439 USA. [Savard, G.] Univ Chicago, Dept Phys, Chicago, IL 60637 USA. RP Mitchell, AJ (reprint author), Univ Massachusetts Lowell, Dept Phys & Appl Phys, Lowell, MA 01854 USA. EM alan_mitchell@uml.edu RI Carpenter, Michael/E-4287-2015; Mitchell, Alan John/M-4486-2015 OI Carpenter, Michael/0000-0002-3237-5734; Mitchell, Alan John/0000-0002-6742-695X FU US Department of Energy, Office of Nuclear Physics [DE-AC02-06CH11357, DE-FG02-94ER40848] FX The authors wish to express their thanks to E. Zganjar of Louisiana State University for education on the design of tape-transport systems, the Engineering Department at Argonne National Laboratory and the Submillimeter-Wave Technology Laboratory, University of Massachusetts Lowell. This work was supported by the US Department of Energy, Office of Nuclear Physics, under Contract nos. DE-AC02-06CH11357 and DE-FG02-94ER40848. NR 11 TC 2 Z9 2 U1 1 U2 6 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 232 EP 239 DI 10.1016/j.nima.2014.06.024 PG 8 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200032 ER PT J AU Francis, K Repond, J Schlereth, J Smith, J Xia, L Baldolemar, E Li, J Park, ST Sosebee, M White, AP Yu, J Eigen, G Mikami, Y Watson, NK Thomson, MA Ward, DR Benchekroun, D Hoummada, A Khoulaki, Y Apostolakis, J Dotti, A Folger, G Ivantchenko, V Ribon, A Uzhinskiy, V Carloganu, C Gay, P Manen, S Royer, L Tytgat, M Zaganidis, N Blazey, GC Dyshkant, A Lima, JGR Zutshi, V Hostachy, JY Morin, L Cornett, U David, D Ebrahimi, A Falley, G Gadow, K Gottlicher, P Gunter, C Hartbrich, O Hermberg, B Karstensen, S Krivan, F Kruger, K Lutz, B Morozov, S Morgunov, V Neubuser, C Reinecke, M Sefkow, F Smirnov, P Terwort, M Garutti, E Laurien, S Lu, S Marchesini, I Matysek, M Ramilli, M Briggl, K Eckert, P Harion, T Schultz-Coulon, HC Shen, W Stamen, R Bilki, B Norbeck, E Northacker, D Onel, Y Wilson, GW Kawagoe, K Sudo, Y Yoshioka, T Dauncey, PD Wing, M Salvatore, F Gil, EC Mannai, S Baulieu, G Calabria, P Caponetto, L Combaret, C Della Negra, R Grenier, G Han, R Ianigro, JC Kieffer, R Laktineh, I Lumb, N Mathez, H Mirabito, L Petrukhin, A Steen, A Tromeur, W Vander Donckt, M Zoccarato, Y Alamillo, EC Fouz, MC Puerta-Pelayo, J Corriveau, F Bobchenko, B Chadeeva, M Danilov, M Epifantsev, A Markin, O Mizuk, R Novikov, E Popov, V Rusinov, V Tarkovsky, E Besson, D Buzhan, P Ilyin, A Kantserov, V Kaplin, V Karakash, A Popova, E Tikhomirov, V Kiesling, C Seidel, K Simon, F Soldner, C Weuste, L Amjad, MS Bonis, J Callier, S di Lorenzo, SC Cornebise, P Doublet, P Dulucq, F Fleury, J Frisson, T van der Kolk, N Li, H Martin-Chassard, G Richard, F de la Taille, C Poschl, R Raux, L Rouene, J Seguin-Moreau, N Anduze, M Balagura, V Boudry, V Brient, JC Cornat, R Frotin, M Gastaldi, F Guliyev, E Haddad, Y Magniette, F Musat, G Ruan, M Tran, TH Videau, H Bulanek, B Zacek, J Cvach, J Gallus, P Havranek, M Janata, M Kvasnicka, J Lednicky, D Marcisovsky, M Polak, I Popule, J Tomasek, L Tomasek, M Ruzicka, P Sicho, P Smolik, J Vrba, V Zalesak, J Belhorma, B Ghazlane, H Kotera, K Ono, H Takeshita, T Uozumi, S Jeans, D Chang, S Khan, A Kim, DH Kong, DJ Oh, YD Gotze, M Sauer, J Weber, S Zeitnitz, C AF Francis, K. Repond, J. Schlereth, J. Smith, J. Xia, L. Baldolemar, E. Li, J. Park, S. T. Sosebee, M. White, A. P. Yu, J. Eigen, G. Mikami, Y. Watson, N. K. Thomson, M. A. Ward, D. R. Benchekroun, D. Hoummada, A. Khoulaki, Y. Apostolakis, J. Dotti, A. Folger, G. Ivantchenko, V. Ribon, A. Uzhinskiy, V. Carloganu, C. Gay, P. Manen, S. Royer, L. Tytgat, M. Zaganidis, N. Blazey, G. C. Dyshkant, A. Lima, J. G. R. Zutshi, V. Hostachy, J. -Y. Morin, L. Cornett, U. David, D. Ebrahimi, A. Falley, G. Gadow, K. Goettlicher, P. Guenter, C. Hartbrich, O. Hermberg, B. Karstensen, S. Krivan, F. Krueger, K. Lutz, B. Morozov, S. Morgunov, V. Neubueser, C. Reinecke, M. Sefkow, F. Smirnov, P. Terwort, M. Garutti, E. Laurien, S. Lu, S. Marchesini, I. Matysek, M. Ramilli, M. Briggl, K. Eckert, P. Harion, T. Schultz-Coulon, H. -Ch. Shen, W. Stamen, R. Bilki, B. Norbeck, E. Northacker, D. Onel, Y. Wilson, G. W. Kawagoe, K. Sudo, Y. Yoshioka, T. Dauncey, P. D. Wing, M. Salvatore, F. Gil, E. Cortina Mannai, S. Baulieu, G. Calabria, P. Caponetto, L. Combaret, C. Della Negra, R. Grenier, G. Han, R. Ianigro, J. -C. Kieffer, R. Laktineh, I. Lumb, N. Mathez, H. Mirabito, L. Petrukhin, A. Steen, A. Tromeur, W. Vander Donckt, M. Zoccarato, Y. Calvo Alamillo, E. Fouz, M. -C. Puerta-Pelayo, J. Corriveau, F. Bobchenko, B. Chadeeva, M. Danilov, M. Epifantsev, A. Markin, O. Mizuk, R. Novikov, E. Popov, V. Rusinov, V. Tarkovsky, E. Besson, D. Buzhan, P. Ilyin, A. Kantserov, V. Kaplin, V. Karakash, A. Popova, E. Tikhomirov, V. Kiesling, C. Seidel, K. Simon, F. Soldner, C. Weuste, L. Amjad, M. S. Bonis, J. Callier, S. di Lorenzo, S. Conforti Cornebise, P. Doublet, Ph. Dulucq, F. Fleury, J. Frisson, T. van der Kolk, N. Li, H. Martin-Chassard, G. Richard, F. de la Taille, Ch. Poeschl, R. Raux, L. Rouene, J. Seguin-Moreau, N. Anduze, M. Balagura, V. Boudry, V. Brient, J. -C. Cornat, R. Frotin, M. Gastaldi, F. Guliyev, E. Haddad, Y. Magniette, F. Musat, G. Ruan, M. Tran, T. H. Videau, H. Bulanek, B. Zacek, J. Cvach, J. Gallus, P. Havranek, M. Janata, M. Kvasnicka, J. Lednicky, D. Marcisovsky, M. Polak, I. Popule, J. Tomasek, L. Tomasek, M. Ruzicka, P. Sicho, P. Smolik, J. Vrba, V. Zalesak, J. Belhorma, B. Ghazlane, H. Kotera, K. Ono, H. Takeshita, T. Uozumi, S. Jeans, D. Chang, S. Khan, A. Kim, D. H. Kong, D. J. Oh, Y. D. Goetze, M. Sauer, J. Weber, S. Zeitnitz, C. TI Performance of the first prototype of the CALICE scintillator strip electromagnetic calorimeter SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE Particle Flow; Electromagnetic calorimeter; Scintillator; MPPC AB A first prototype of a scintillator strip-based electromagnetic calorimeter was built, consisting of 26 layers of tungsten absorber plates interleaved with planes of 45 x 10 x 3 mm plastic scintillator strips. Data were collected using a positron test beam at DESY with momenta between 1 and 6 GeV/c. The prototype's performance is presented in terms of the linearity and resolution of the energy measurement. These results represent an important milestone in the development of highly granular calorimeters using scintillator strip technology. A number of possible design improvements were identified, which should be implemented in a future detector of this type. This technology is being developed for a future linear collider experiment, aiming at the precise measurement of jet energies using particle flow techniques. (C) 2014 Elsevier B.V. All rights reserved. C1 [Francis, K.; Repond, J.; Schlereth, J.; Smith, J.; Xia, L.; Bilki, B.] Argonne Natl Lab, Argonne, IL 60439 USA. [Baldolemar, E.; Li, J.; Park, S. T.; Sosebee, M.; White, A. P.; Yu, J.] Univ Texas Arlington, Dept Phys, Arlington, TX 76019 USA. [Eigen, G.] Univ Bergen, Inst Phys, N-5007 Bergen, Norway. [Mikami, Y.; Watson, N. K.] Univ Birmingham, Sch Phys & Astron, Birmingham B15 2TT, W Midlands, England. [Thomson, M. A.; Ward, D. R.] Univ Cambridge, Cavendish Lab, Cambridge CB3 OHE, England. [Benchekroun, D.; Hoummada, A.; Khoulaki, Y.] Univ Hassan II Ain Chock, Fac Sci, Casablanca, Morocco. [Apostolakis, J.; Dotti, A.; Folger, G.; Ivantchenko, V.; Ribon, A.; Uzhinskiy, V.] CERN, CH-1211 Geneva 23, Switzerland. [Carloganu, C.; Gay, P.; Manen, S.; Royer, L.] Univ Clermont Ferrand, Clermont Univ, CNRS, Phys Corpusculaire Lab,IN2P3, F-63000 Clermont Ferrand, France. [Tytgat, M.; Zaganidis, N.] Univ Ghent, Dept Phys & Astron, B-9000 Ghent, Belgium. [Blazey, G. C.; Dyshkant, A.; Lima, J. G. R.; Zutshi, V.] No Illinois Univ, NICADD, Dept Phys, De Kalb, IL 60115 USA. [Hostachy, J. -Y.; Morin, L.] Univ Grenoble 1, CNRS, Inst Polytech Grenoble, Lab Phys Subatom & Cosmol,IN2P3, F-38026 Grenoble, France. [Cornett, U.; David, D.; Ebrahimi, A.; Falley, G.; Gadow, K.; Goettlicher, P.; Guenter, C.; Hartbrich, O.; Hermberg, B.; Karstensen, S.; Krivan, F.; Krueger, K.; Lutz, B.; Morozov, S.; Morgunov, V.; Neubueser, C.; Reinecke, M.; Sefkow, F.; Smirnov, P.; Terwort, M.; Marchesini, I.] DESY, D-22603 Hamburg, Germany. [Garutti, E.; Laurien, S.; Lu, S.; Marchesini, I.; Matysek, M.; Ramilli, M.] Univ Hamburg, Inst Expt Phys, Dept Phys, D-22761 Hamburg, Germany. [Briggl, K.; Eckert, P.; Harion, T.; Schultz-Coulon, H. -Ch.; Shen, W.; Stamen, R.] Heidelberg Univ, Fac Phys & Astron, D-69120 Heidelberg, Germany. [Bilki, B.; Norbeck, E.; Northacker, D.; Onel, Y.] Univ Iowa, Dept Phys & Astron, Iowa City, IA 52242 USA. [Wilson, G. W.] Univ Kansas, Dept Phys & Astron, Lawrence, KS 66045 USA. [Kawagoe, K.; Sudo, Y.; Yoshioka, T.] Kyushu Univ, Dept Phys, Fukuoka 8128581, Japan. [Dauncey, P. D.] Univ London Imperial Coll Sci Technol & Med, Dept Phys, Blackett Lab, London SW7 2AZ, England. [Wing, M.] UCL, Dept Phys & Astron, London WC1E 6BT, England. [Salvatore, F.] Royal Holloway Univ London, Dept Phys, Egham TW20 0EX, Surrey, England. [Gil, E. Cortina; Mannai, S.] Catholic Univ Louvain, Ctr Cosmol Particle Phys & Cosmol CP3, B-1320 Louvain la Neuve, Belgium. Univ Lyon 1, CNRS, IPNL, IN2P3, F-69622 Villeurbanne, France. [Calvo Alamillo, E.; Fouz, M. -C.; Puerta-Pelayo, J.] CIEMAT, E-28040 Madrid, Spain. [Corriveau, F.] Inst Particle Phys Canada, Montreal, PQ H3A 2T8, Canada. [Corriveau, F.] Dept Phys, Montreal, PQ H3A 2T8, Canada. [Bobchenko, B.; Chadeeva, M.; Danilov, M.; Epifantsev, A.; Markin, O.; Mizuk, R.; Novikov, E.; Popov, V.; Rusinov, V.; Tarkovsky, E.] Inst Theoret & Expt Phys, RU-117218 Moscow, Russia. [Danilov, M.; Mizuk, R.; Besson, D.; Buzhan, P.; Ilyin, A.; Kantserov, V.; Kaplin, V.; Karakash, A.; Popova, E.; Tikhomirov, V.] Moscow Phys Engn Inst, MEPhI, Dept Phys, Moscow 115409, Russia. [Kiesling, C.; Seidel, K.; Simon, F.; Soldner, C.; Weuste, L.] Max Planck Inst Phys & Astrophys, D-80805 Munich, Germany. [Amjad, M. S.; Bonis, J.; Callier, S.; di Lorenzo, S. Conforti; Cornebise, P.; Doublet, Ph.; Dulucq, F.; Fleury, J.; Frisson, T.; van der Kolk, N.; Li, H.; Martin-Chassard, G.; Richard, F.; de la Taille, Ch.; Poeschl, R.; Raux, L.; Rouene, J.; Seguin-Moreau, N.] Univ Paris 11, Ctr Sci Orsay, Lab Accelerateur Lineaire, CNRS IN2P3, F-91898 Orsay, France. [Anduze, M.; Balagura, V.; Boudry, V.; Brient, J. -C.; Cornat, R.; Frotin, M.; Gastaldi, F.; Guliyev, E.; Haddad, Y.; Magniette, F.; Musat, G.; Ruan, M.; Tran, T. H.; Videau, H.] Ecole Polytech, CNRS, LLR, IN2P3, F-91128 Palaiseau, France. [Bulanek, B.; Zacek, J.] Charles Univ Prague, Inst Nucl & Particle Phys, CZ-18000 Prague 8, Czech Republic. [Cvach, J.; Gallus, P.; Havranek, M.; Janata, M.; Kvasnicka, J.; Lednicky, D.; Marcisovsky, M.; Polak, I.; Popule, J.; Tomasek, L.; Tomasek, M.; Ruzicka, P.; Sicho, P.; Smolik, J.; Vrba, V.; Zalesak, J.] Acad Sci Czech Republic, Inst Phys, CZ-18221 Prague 8, Czech Republic. [Belhorma, B.; Ghazlane, H.] Ctr Natl Energie Sci & Tech Nucl, Rabat, Morocco. [Kotera, K.; Ono, H.; Takeshita, T.; Uozumi, S.] Shinshu Univ, Dept Phys, Nagano 3908621, Japan. [Jeans, D.] Univ Tokyo, Grad Sch Sci, Dept Phys, Bunkyo Ku, Tokyo 1130033, Japan. [Chang, S.; Khan, A.; Kim, D. H.; Kong, D. J.; Oh, Y. D.] Kyungpook Natl Univ, Dept Phys, Taegu 702701, South Korea. [Goetze, M.; Sauer, J.; Weber, S.; Zeitnitz, C.] Berg Univ Wuppertal, Fachbereich C Phys, D-42097 Wuppertal, Germany. [Danilov, M.; Mizuk, R.] Moscow Inst Phys & Technol, Moscow, Russia. RP Uozumi, S (reprint author), KNU, Taegu, South Korea. EM satoru@knu.ac.kr; jeans@icepp.s.u-tokyo.ac.jp RI Smirnov, Petr/N-9652-2015; U-ID, Kyushu/C-5291-2016; Danilov, Mikhail/C-5380-2014; Mizuk, Roman/B-3751-2014; Calvo Alamillo, Enrique/L-1203-2014; Cvach, Jaroslav/G-6269-2014; Chadeeva, Marina/C-8789-2016; van der Kolk, Naomi/M-9423-2016; Tikhomirov, Vladimir/M-6194-2015 OI Watson, Nigel/0000-0002-8142-4678; Blazey, Gerald/0000-0002-7435-5758; Bilki, Burak/0000-0001-9515-3306; Jeans, Daniel/0000-0002-5208-7617; Danilov, Mikhail/0000-0001-9227-5164; Calvo Alamillo, Enrique/0000-0002-1100-2963; Chadeeva, Marina/0000-0003-1814-1218; van der Kolk, Naomi/0000-0002-8670-0408; Tikhomirov, Vladimir/0000-0002-9634-0581 FU Bundesministerium fur Bildung und Forschung, Germany; DEG cluster of excellence 'Origin and Structure of the Universe' of Germany; Helmholtz-Nachwuchsgruppen grant [VH-NG-206]; BMBF [05HS6VH1]; JSPS KAKENHI [17340071, 18GS0202]; Russian Ministry of Education and Science [8174, 8411, 1366.2012.2, 14.A12.31.0006]; MICINN, Spain; CPAN, Spain; CRI(MST) of MOST/KOSEF in Korea; World Class University (WCU) project through the National Research Foundation (NRF) of Korea - Ministry of Education, Science Technology [R32-2008-000-20001-0]; US Department of Energy and the US National Science Foundation; Ministry of Education, Youth and Sports of the Czech Republic [AV0 Z3407391, AV0 Z10100502, LC527, LA09042]; Grant Agency of the Czech Republic [202/05/0653]; National Sciences and Engineering Research Council of Canada; Science and Technology Facilities Council, UK FX We gratefully acknowledge the DESY management for its support and hospitality, and the DESY accelerator staff for the reliable and efficient beam operation. We would like to thank the HEP group of the University of Tsukuba for the loan of drift chambers. This work was supported by the Bundesministerium fur Bildung und Forschung, Germany; by the DEG cluster of excellence 'Origin and Structure of the Universe' of Germany; by the Helmholtz-Nachwuchsgruppen grant VH-NG-206; by the BMBF, grant no, 05HS6VH1; by JSPS KAKENHI Grant-in-Aid for Scientific Research numbers 17340071 and 18GS0202; by the Russian Ministry of Education and Science contracts 8174, 8411, 1366.2012.2, and 14.A12.31.0006; by MICINN and CPAN, Spain; by CRI(MST) of MOST/KOSEF in Korea; by the World Class University (WCU) project through the National Research Foundation (NRF) of Korea funded by the Ministry of Education, Science & Technology (Grant no. R32-2008-000-20001-0); by the US Department of Energy and the US National Science Foundation; by the Ministry of Education, Youth and Sports of the Czech Republic under the projects AV0 Z3407391, AV0 Z10100502, LC527 and LA09042 and by the Grant Agency of the Czech Republic under the project 202/05/0653; by the National Sciences and Engineering Research Council of Canada; and by the Science and Technology Facilities Council, UK. NR 14 TC 7 Z9 7 U1 1 U2 18 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 278 EP 289 DI 10.1016/j.nima.2014.06.039 PG 12 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200039 ER PT J AU Abazov, VM Abbott, B Acharya, BS Adams, M Adams, T Agnew, JP Alexeev, GD Alkhazov, G Alton, A Askew, A Atkins, S Augsten, K Avila, C Badaud, F Bagby, L Baldin, B Bandurin, DV Banerjee, S Barberis, E Baringer, P Bartlett, JF Sassler, U Bazterra, V Bean, A Begalli, M Bellantoni, L Beri, SB Bernardi, G Bernhard, R Bertram, I Besancon, M Beuselinck, R Bhat, PC Bhatia, S Bhatnagar, V Blazey, G Blessing, S Bloom, K Boehnlein, A Boline, D Boos, EE Borissov, G Borysova, M Brandt, A Brandt, O Brock, R Bross, A Brown, D Bu, XB Buehler, M Buescher, V Bunichev, V Burdin, S Buszello, CP Camacho-Perez, E Casey, BCK Castilla-Valdez, H Caughron, S Chakrabarti, S Chan, KM Chandra, A Chapon, E Chen, G Cho, SW Choi, S Choudhary, B Cihangir, S Claes, D Clutter, J Cooke, M Cooper, WE Corcoran, M Couderc, F Cousinou, MC Cutts, D Das, A Davies, G de Jong, SJ De La Cruz-Burelo, E de Lima, RT Deliot, F Demina, R Denisov, D Denisov, SP Desai, S Deterre, C DeVaughan, K Diehl, HT Diesburg, M Ding, PF Dominguez, A Dubey, A Dudko, LV Duperrin, A Dutt, S Eads, M Edmunds, D Ellison, J Elvira, VD Enari, Y Evans, H Evdokimov, VN Feng, L Ferbel, T Fiedler, F Filthaut, F Fisher, W Fisk, HE Fortner, M Fox, H Fuess, S Garbincius, PH Garcia-Bellido, A Garcia-Gonzalez, JA Gavrilov, V Geng, W Gerber, CE Gershtein, Y Ginther, G Golovanov, G Grannis, PD Greder, S Greenlee, H Grenier, G Gris, P Grivaz, JF Grohsjean, A Grunendahl, S Grunewald, MW Guillemin, T Gutierrez, G Gutierrez, P Haley, J Han, L Harder, K Harel, A Hauptman, JM Hays, J Head, T Hebbeker, T Hedin, D Hegab, H Heinson, AP Heintz, U Hensel, C Heredia-De La Cruz, I Herner, K Hesketh, G Hildreth, MD Hirosky, R Hoang, T Hobbs, JD Hoeneisen, B Hogan, J Hohlfeld, M Holzbauer, JL Howley, I Hubacek, Z Hynek, V Iashvili, I Ilchenko, Y Illingworth, R Ito, AS Jabeen, S Jaffre, M Jayasinghe, A Jeong, MS Jesik, R Jiang, P Johns, K Johnson, E Johnson, M Jonckheere, A Jonsson, P Joshi, J Jung, AW Juste, A Kajfasz, E Karmanov, D Katsanos, I Kehoe, R Kermiche, S Khalatyan, N Khanov, A Kharchilava, A Kharzheev, YN Kiselevich, I Kohli, JM Kozelov, AV Kraus, J Kumar, A Kupco, A Kurca, T Kuzmin, VA Lammers, S Lebrun, P Lee, HS Lee, SW Lee, WM Lei, X Lellouch, J Li, D Li, H Li, L Li, QZ Lim, JK Lincoln, D Linnemann, J Lipaev, VV Lipton, R Liu, H Liu, Y Lobodenko, A Lokajicek, M de Sa, RL Luna-Garcia, R Lyon, AL Maciel, AKA Madar, R Magana-Villalba, R Malik, S Malyshev, VL Mansour, J Martinez-Ortega, J McCarthy, R McGivern, CL Meijer, MM Melnitchouk, A Menezes, D Mercadante, PG Merkin, M Meyer, A Meyer, J Miconi, F Mondal, NK Mulhearn, M Nagy, E Narain, M Nayyar, R Neal, HA Negret, JP Neustroev, P Nguyen, HT Nunnemann, T Orduna, J Osman, N Osta, J Pal, A Parashar, N Parihar, V Park, SK Partridge, R Parua, N Patwa, A Penning, B Perfilov, M Peters, Y Petridis, K Petrillo, G Petroff, P Pleier, MA Podstavkov, VM Popov, AV Prewitt, M Price, D Prokopenko, N Qian, J Quadt, A Quinn, B Ratoff, PN Razumov, I Ripp-Baudot, I Rizatdinova, F Rominsky, M Ross, A Royon, C Rubinov, P Ruchti, R Sajot, G Sanchez-Hernandez, A Sanders, MP Santos, AS Savage, G Sawyer, L Scanlon, T Schamberger, RD Scheglov, Y Schellman, H Schwanenberger, C Schwienhorst, R Sekaric, J Severini, H Shabalina, E Shary, V Shaw, S Shchukin, AA Simak, V Skubic, P Slattery, P Smirnov, D Snow, GR Snow, J Snyder, S Soldner-Rembold, S Sonnenschein, L Soustruznik, K Stark, J Stoyanova, DA Strauss, M Suter, L Svoisky, P Titov, M Tokmenin, VV Tsai, YT Tsybychev, D Tuchming, B Tully, C Uvarov, L Uvarov, S Uzunyan, S Kooten, R van Leeuwen, WM Varelas, N Varnes, EW Vasilyev, IA Verkheev, AY Vertogradov, LS Verzocchi, M Vesterinen, M Vilanova, D Vokac, P Wahl, HD Wang, MHLS Warchol, J Watts, G Wayne, M Weichert, J Welty-Rieger, L Williams, MRJ Wilson, GW Wobisch, M Wood, DR Wyatt, TR Xie, Y Yamada, R Yang, S Yasuda, T Yatsunenko, YA Ye, W Ye, Z Yin, H Yip, K Youn, SW Yu, JM Zennamo, J Zhao, TG Zhou, B Zhu, J Zielinski, M Zieminska, D Zivkovic, L AF Abazov, V. M. Abbott, B. Acharya, B. S. Adams, M. Adams, T. Agnew, J. P. Alexeev, G. D. Alkhazov, G. Alton, A. Askew, A. Atkins, S. Augsten, K. Avila, C. Badaud, F. Bagby, L. Baldin, B. Bandurin, D. V. Banerjee, S. Barberis, E. Baringer, P. Bartlett, J. F. Sassler, U. Bazterra, V. Bean, A. Begalli, M. Bellantoni, L. Beri, S. B. Bernardi, G. Bernhard, R. Bertram, I. Besancon, M. Beuselinck, R. Bhat, P. C. Bhatia, S. Bhatnagar, V. Blazey, G. Blessing, S. Bloom, K. Boehnlein, A. Boline, D. Boos, E. E. Borissov, G. Borysova, M. Brandt, A. Brandt, O. Brock, R. Bross, A. Brown, D. Bu, X. B. Buehler, M. Buescher, V. Bunichev, V. Burdin, S. Buszello, C. P. Camacho-Perez, E. Casey, B. C. K. Castilla-Valdez, H. Caughron, S. Chakrabarti, S. Chan, K. M. Chandra, A. Chapon, E. Chen, G. Cho, S. W. Choi, S. Choudhary, B. Cihangir, S. Claes, D. Clutter, J. Cooke, M. Cooper, W. E. Corcoran, M. Couderc, F. Cousinou, M. -C. Cutts, D. Das, A. Davies, G. de Jong, S. J. De La Cruz-Burelo, E. de Lima, R. T. Deliot, F. Demina, R. Denisov, D. Denisov, S. P. Desai, S. Deterre, C. DeVaughan, K. Diehl, H. T. Diesburg, M. Ding, P. F. Dominguez, A. Dubey, A. Dudko, L. V. Duperrin, A. Dutt, S. Eads, M. Edmunds, D. Ellison, J. Elvira, V. D. Enari, Y. Evans, H. Evdokimov, V. N. Feng, L. Ferbel, T. Fiedler, F. Filthaut, F. Fisher, W. Fisk, H. E. Fortner, M. Fox, H. Fuess, S. Garbincius, P. H. Garcia-Bellido, A. Garcia-Gonzalez, J. A. Gavrilov, V. Geng, W. Gerber, C. E. Gershtein, Y. Ginther, G. Golovanov, G. Grannis, P. D. Greder, S. Greenlee, H. Grenier, G. Gris, Ph. Grivaz, J. -F. Grohsjean, A. Gruenendahl, S. Gruenewald, M. W. Guillemin, T. Gutierrez, G. Gutierrez, P. Haley, J. Han, L. Harder, K. Harel, A. Hauptman, J. M. Hays, J. Head, T. Hebbeker, T. Hedin, D. Hegab, H. Heinson, A. P. Heintz, U. Hensel, C. Heredia-De La Cruz, I. Herner, K. Hesketh, G. Hildreth, M. D. Hirosky, R. Hoang, T. Hobbs, J. D. Hoeneisen, B. Hogan, J. Hohlfeld, M. Holzbauer, J. L. Howley, I. Hubacek, Z. Hynek, V. Iashvili, I. Ilchenko, Y. Illingworth, R. Ito, A. S. Jabeen, S. Jaffre, M. Jayasinghe, A. Jeong, M. S. Jesik, R. Jiang, P. Johns, K. Johnson, E. Johnson, M. Jonckheere, A. Jonsson, P. Joshi, J. Jung, A. W. Juste, A. Kajfasz, E. Karmanov, D. Katsanos, I. Kehoe, R. Kermiche, S. Khalatyan, N. Khanov, A. Kharchilava, A. Kharzheev, Y. N. Kiselevich, I. Kohli, J. M. Kozelov, A. V. Kraus, J. Kumar, A. Kupco, A. Kurca, T. Kuzmin, V. A. Lammers, S. Lebrun, P. Lee, H. S. Lee, S. W. Lee, W. M. Lei, X. Lellouch, J. Li, D. Li, H. Li, L. Li, Q. Z. Lim, J. K. Lincoln, D. Linnemann, J. Lipaev, V. V. Lipton, R. Liu, H. Liu, Y. Lobodenko, A. Lokajicek, M. de Sa, R. Lopes Luna-Garcia, R. Lyon, A. L. Maciel, A. K. A. Madar, R. Magana-Villalba, R. Malik, S. Malyshev, V. L. Mansour, J. Martinez-Ortega, J. McCarthy, R. McGivern, C. L. Meijer, M. M. Melnitchouk, A. Menezes, D. Mercadante, P. G. Merkin, M. Meyer, A. Meyer, J. Miconi, F. Mondal, N. K. Mulhearn, M. Nagy, E. Narain, M. Nayyar, R. Neal, H. A. Negret, J. P. Neustroev, P. Nguyen, H. T. Nunnemann, T. Orduna, J. Osman, N. Osta, J. Pal, A. Parashar, N. Parihar, V. Park, S. K. Partridge, R. Parua, N. Patwa, A. Penning, B. Perfilov, M. Peters, Y. Petridis, K. Petrillo, G. Petroff, P. Pleier, M. -A. Podstavkov, V. M. Popov, A. V. Prewitt, M. Price, D. Prokopenko, N. Qian, J. Quadt, A. Quinn, B. Ratoff, P. N. Razumov, I. Ripp-Baudot, I. Rizatdinova, F. Rominsky, M. Ross, A. Royon, C. Rubinov, P. Ruchti, R. Sajot, G. Sanchez-Hernandez, A. Sanders, M. P. Santos, A. S. Savage, G. Sawyer, L. Scanlon, T. Schamberger, R. D. Scheglov, Y. Schellman, H. Schwanenberger, C. Schwienhorst, R. Sekaric, J. Severini, H. Shabalina, E. Shary, V. Shaw, S. Shchukin, A. A. Simak, V. Skubic, P. Slattery, P. Smirnov, D. Snow, G. R. Snow, J. Snyder, S. Soeldner-Rembold, S. Sonnenschein, L. Soustruznik, K. Stark, J. Stoyanova, D. A. Strauss, M. Suter, L. Svoisky, P. Titov, M. Tokmenin, V. V. Tsai, Y. -T. Tsybychev, D. Tuchming, B. Tully, C. Uvarov, L. Uvarov, S. Uzunyan, S. Van Kooten, R. van Leeuwen, W. M. Varelas, N. Varnes, E. W. Vasilyev, I. A. Verkheev, A. Y. Vertogradov, L. S. Verzocchi, M. Vesterinen, M. Vilanova, D. Vokac, P. Wahl, H. D. Wang, M. H. L. S. Warchol, J. Watts, G. Wayne, M. Weichert, J. Welty-Rieger, L. Williams, M. R. J. Wilson, G. W. Wobisch, M. Wood, D. R. Wyatt, T. R. Xie, Y. Yamada, R. Yang, S. Yasuda, T. Yatsunenko, Y. A. Ye, W. Ye, Z. Yin, H. Yip, K. Youn, S. W. Yu, J. M. Zennamo, J. Zhao, T. G. Zhou, B. Zhu, J. Zielinski, M. Zieminska, D. Zivkovic, L. TI Improved b quark jet identification at the D0 experiment SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE b-Jet identification; D0; Tevatron; Collider AB The ability to identify jets which originated from b quarks is an important tool of the physics program of the D0 experiment at the Fermilab Tevatron p (p) over bar collider. This paper describes a new algorithm designed to select jets originating from b quarks while suppressing the contamination caused by jets from other quark flavors and gluons. Additionally, a new technique, the SystemN method, for determining the misidentification rate directly from data is presented. (C) 2014 Elsevier B.V. All rights reserved. C1 [de Lima, R. T.; Hensel, C.; Maciel, A. K. A.; Santos, A. S.] LAFEX, Ctr Brasileiro Pesquisas Fis, Rio De Janeiro, Brazil. [Begalli, M.] Univ Estado Rio de Janeiro, BR-20550011 Rio De Janeiro, Brazil. [Mercadante, P. G.] Univ Fed ABC, Santo Andre, Brazil. [Han, L.; Liu, Y.; Yang, S.] Univ Sci & Technol China, Hefei 230026, Peoples R China. [Avila, C.; Negret, J. P.] Univ Los Andes, Bogota, Colombia. [Soustruznik, K.] Charles Univ Prague, Fac Math & Phys, Ctr Particle Phys, Prague, Czech Republic. [Augsten, K.; Hynek, V.; Simak, V.; Vokac, P.] Czech Tech Univ, Prague, Czech Republic. 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[Beuselinck, R.; Davies, G.; Hays, J.; Jesik, R.; Jonsson, P.; Scanlon, T.] Univ London Imperial Coll Sci Technol & Med, London SW7 2AZ, England. [Agnew, J. P.; Ding, P. F.; Harder, K.; Head, T.; Hesketh, G.; McGivern, C. L.; Peters, Y.; Petridis, K.; Price, D.; Schwanenberger, C.; Soeldner-Rembold, S.; Suter, L.; Vesterinen, M.; Wyatt, T. R.; Zhao, T. G.] Univ Manchester, Manchester M13 9PL, Lancs, England. [Das, A.; Johns, K.; Lei, X.; Nayyar, R.; Varnes, E. W.] Univ Arizona, Tucson, AZ 85721 USA. [Ellison, J.; Heinson, A. P.; Joshi, J.; Li, L.] Univ Calif Riverside, Riverside, CA 92521 USA. [Adams, T.; Askew, A.; Blessing, S.; Hoang, T.; Wahl, H. D.] Florida State Univ, Tallahassee, FL 32306 USA. [Bagby, L.; Baldin, B.; Bartlett, J. F.; Bellantoni, L.; Bhat, P. C.; Boehnlein, A.; Bross, A.; Bu, X. B.; Buehler, M.; Casey, B. C. K.; Cihangir, S.; Cooke, M.; Cooper, W. E.; Denisov, D.; Desai, S.; Diehl, H. T.; Diesburg, M.; Elvira, V. D.; Fisk, H. E.; Fuess, S.; Garbincius, P. H.; Ginther, G.; Greenlee, H.; Gruenendahl, S.; Gutierrez, G.; Herner, K.; Illingworth, R.; Ito, A. S.; Johnson, M.; Jonckheere, A.; Jung, A. W.; Khalatyan, N.; Lee, W. M.; Li, Q. Z.; Lincoln, D.; Lipton, R.; Lyon, A. L.; Melnitchouk, A.; Penning, B.; Podstavkov, V. M.; Quadt, A.; Rominsky, M.; Rubinov, P.; Savage, G.; Verzocchi, M.; Wang, M. H. L. S.; Xie, Y.; Yamada, R.; Yasuda, T.; Ye, Z.; Yin, H.; Youn, S. W.] Fermilab Natl Accelerator Lab, Batavia, IL 60510 USA. [Adams, M.; Bazterra, V.; Gerber, C. E.; Varelas, N.] Univ Illinois, Chicago, IL 60607 USA. [Blazey, G.; Eads, M.; Feng, L.; Fortner, M.; Hedin, D.; Menezes, D.; Uzunyan, S.] No Illinois Univ, De Kalb, IL 60115 USA. [Schellman, H.; Welty-Rieger, L.] Northwestern Univ, Evanston, IL 60208 USA. [Evans, H.; Lammers, S.; Parua, N.; Van Kooten, R.; Williams, M. R. J.; Zieminska, D.] Indiana Univ, Bloomington, IN 47405 USA. [Parashar, N.] Purdue Univ Calumet, Hammond, IN 46323 USA. [Chan, K. M.; Hildreth, M. D.; Osta, J.; Ruchti, R.; Smirnov, D.; Warchol, J.; Wayne, M.] Univ Notre Dame, Notre Dame, IN 46556 USA. [Hauptman, J. M.; Lee, S. W.] Iowa State Univ, Ames, IA 50011 USA. [Baringer, P.; Bean, A.; Chen, G.; Clutter, J.; Sekaric, J.; Wilson, G. W.] Univ Kansas, Lawrence, KS 66045 USA. [Atkins, S.; Sawyer, L.; Wobisch, M.] Louisiana Tech Univ, Ruston, LA 71272 USA. [Barberis, E.; Wood, D. R.] Northeastern Univ, Boston, MA 02115 USA. [Alton, A.; Neal, H. A.; Qian, J.; Yu, J. M.; Zhou, B.; Zhu, J.] Univ Michigan, Ann Arbor, MI 48109 USA. [Brock, R.; Caughron, S.; Edmunds, D.; Fisher, W.; Johnson, E.; Linnemann, J.; Schwienhorst, R.; Shaw, S.] Michigan State Univ, E Lansing, MI 48824 USA. [Bhatia, S.; Holzbauer, J. L.; Kraus, J.; Quinn, B.] Univ Mississippi, University, MS 38677 USA. [Bloom, K.; Claes, D.; DeVaughan, K.; Dominguez, A.; Katsanos, I.; Malik, S.; Snow, G. R.] Univ Nebraska, Lincoln, NE 68588 USA. [Gershtein, Y.] Rutgers State Univ, Piscataway, NJ 08855 USA. [Tully, C.] Princeton Univ, Princeton, NJ 08544 USA. [Iashvili, I.; Kharchilava, A.; Kumar, A.; Zennamo, J.] SUNY Buffalo, Buffalo, NY 14260 USA. [Demina, R.; Ferbel, T.; Garcia-Bellido, A.; Ginther, G.; Harel, A.; Petrillo, G.; Slattery, P.; Tsai, Y. -T.; Zielinski, M.] Univ Rochester, Rochester, NY 14627 USA. [Boline, D.; Chakrabarti, S.; Grannis, P. D.; Hobbs, J. D.; de Sa, R. Lopes; McCarthy, R.; Schamberger, R. D.; Tsybychev, D.; Ye, W.] SUNY Stony Brook, Stony Brook, NY 11794 USA. [Patwa, A.; Pleier, M. -A.; Snyder, S.; Yip, K.] Brookhaven Natl Lab, Upton, NY 11973 USA. [Snow, J.] Langston Univ, Langston, OK 73050 USA. [Abbott, B.; Gutierrez, P.; Jayasinghe, A.; Severini, H.; Skubic, P.; Strauss, M.; Svoisky, P.] Univ Oklahoma, Norman, OK 73019 USA. [Haley, J.; Hegab, H.; Khanov, A.; Parihar, V.; Rizatdinova, F.] Oklahoma State Univ, Stillwater, OK 74078 USA. [Cutts, D.; Heintz, U.; Jabeen, S.; Narain, M.; Partridge, R.] Brown Univ, Providence, RI 02912 USA. [Brandt, A.; Howley, I.; Pal, A.] Univ Texas Arlington, Arlington, TX 76019 USA. [Ilchenko, Y.; Kehoe, R.; Liu, H.] So Methodist Univ, Dallas, TX 75275 USA. [Chandra, A.; Corcoran, M.; Hogan, J.; Orduna, J.; Prewitt, M.] Rice Univ, Houston, TX 77005 USA. [Bandurin, D. V.; Hirosky, R.; Li, H.; Mulhearn, M.; Nguyen, H. T.] Univ Virginia, Charlottesville, VA 22904 USA. [Watts, G.] Univ Washington, Seattle, WA 98195 USA. RP Abazov, VM (reprint author), LAFEX, Ctr Brasileiro Pesquisas Fis, Rio De Janeiro, Brazil. RI Lei, Xiaowen/O-4348-2014; Yip, Kin/D-6860-2013; Gutierrez, Phillip/C-1161-2011; Sharyy, Viatcheslav/F-9057-2014; Dudko, Lev/D-7127-2012; Merkin, Mikhail/D-6809-2012; Li, Liang/O-1107-2015; Juste, Aurelio/I-2531-2015; OI Lei, Xiaowen/0000-0002-2564-8351; Hedin, David/0000-0001-9984-215X; de Jong, Sijbrand/0000-0002-3120-3367; Blessing, Susan/0000-0002-4455-7279; Duperrin, Arnaud/0000-0002-5789-9825; Hoeneisen, Bruce/0000-0002-6059-4256; Yip, Kin/0000-0002-8576-4311; Sharyy, Viatcheslav/0000-0002-7161-2616; Dudko, Lev/0000-0002-4462-3192; Li, Liang/0000-0001-6411-6107; Beuselinck, Raymond/0000-0003-2613-7446; Heinson, Ann/0000-0003-4209-6146; grannis, paul/0000-0003-4692-2142; Blazey, Gerald/0000-0002-7435-5758; Wahl, Horst/0000-0002-1345-0401; Bean, Alice/0000-0001-5967-8674; Sawyer, Lee/0000-0001-8295-0605; Juste, Aurelio/0000-0002-1558-3291; Gershtein, Yuri/0000-0002-4871-5449; Malik, Sudhir/0000-0002-6356-2655; Qian, Jianming/0000-0003-4813-8167; Williams, Mark/0000-0001-5448-4213; Grohsjean, Alexander/0000-0003-0748-8494; Chapon, Emilien/0000-0001-6968-9828; Melnychuk, Oleksandr/0000-0002-2089-8685; Ding, Pengfei/0000-0002-4050-1753; Bassler, Ursula/0000-0002-9041-3057; Price, Darren/0000-0003-2750-9977; Filthaut, Frank/0000-0003-3338-2247; Bertram, Iain/0000-0003-4073-4941 FU DOE (USA); NSF (USA); CEA (France); CNRS/IN2P3 (France); MON (Russia); NRC KI (Russia); RFBR (Russia); CNPq (Brazil); FAPERJ (Brazil); FAPESP (Brazil); FUNDUNESP (Brazil); DAE (India); DST (India); Colciencias (Colombia); CONACyT (Mexico); NRF (Korea); FOM (The Netherlands); STFC (United Kingdom); Royal Society (United Kingdom); MSMT (Czech Republic); GACR (Czech Republic); BMBF (Germany); DFG (Germany); SFI (Ireland); Swedish Research Council (Sweden); CAS (China); CNSF (China) FX We thank the staffs at Fermilab and collaborating institutions, and acknowledge support from the DOE and NSF (USA); CEA and CNRS/IN2P3 (France); MON, NRC KI and RFBR (Russia); CNPq, FAPERJ, FAPESP and FUNDUNESP (Brazil); DAE and DST (India); Colciencias (Colombia); CONACyT (Mexico); NRF (Korea); FOM (The Netherlands); STFC and the Royal Society (United Kingdom); MSMT and GACR (Czech Republic); BMBF and DFG (Germany); SFI (Ireland); The Swedish Research Council (Sweden); and CAS and CNSF (China). NR 14 TC 15 Z9 15 U1 0 U2 10 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 290 EP 303 DI 10.1016/j.nima.2014.04.087 PG 14 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200040 ER PT J AU Krzywda, A Alagoz, E Bubna, M Obertino, M Solano, A Arndt, K Uplegger, L Betta, GFD Boscardin, M Ngadiuba, J Rivera, R Menasce, D Moroni, L Terzo, S Bortoletto, D Prosser, A Adreson, J Kwan, S Osipenkov, I Bolla, G Lei, CM Shipsey, I Tan, P Tran, N Chramowicz, J Cumalat, J Perera, L Povoli, M Mendicino, R Pereira, AV Brosius, R Kumar, A Wagner, S Jensen, F Bose, S Tentindo, S AF Krzywda, A. Alagoz, E. Bubna, M. Obertino, M. Solano, A. Arndt, K. Uplegger, L. Betta, G. F. Dalla Boscardin, M. Ngadiuba, J. Rivera, R. Menasce, D. Moroni, L. Terzo, S. Bortoletto, D. Prosser, A. Adreson, J. Kwan, S. Osipenkov, I. Bolla, G. Lei, C. M. Shipsey, I. Tan, P. Tran, N. Chramowicz, J. Cumalat, J. Perera, L. Povoli, M. Mendicino, R. Pereira, A. Vilela Brosius, R. Kumar, A. Wagner, S. Jensen, F. Bose, S. Tentindo, S. TI Pre- and post-irradiation performance of FBK 3D silicon pixel detectors for CMS SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE 3D; CMS; Pixel detector; HL-LHC; Radiation-hard ID FABRICATION; UPGRADE; DESIGN; LHC AB In preparation for the tenfold luminosity upgrade of the Large Hadron Collider (the HL-LHC) around 2020, three-dimensional (3D) silicon pixel sensors are being developed as a radiation-hard candidate to replace the planar ones currently being used in the CMS pixel detector. This study examines an early batch of FBK sensors (named ATLAS08) of three 3D pixel geometries: 1E, 2E, and 4E, which respectively contain one, two, and four readout electrodes for each pixel, passing completely through the bulk. We present electrical characteristics and beam test performance results for each detector before and after irradiation. The maximum fluence applied is 3.5 x 10(15) n (eq)/cm(2). (C) 2014 Elsevier B.V. All rights reserved. C1 [Krzywda, A.; Alagoz, E.; Bubna, M.; Arndt, K.; Bortoletto, D.; Bolla, G.; Shipsey, I.; Brosius, R.] Purdue Univ, Dept Phys & Astron, W Lafayette, IN 47907 USA. [Obertino, M.] Univ Piemonte Orientate, Novara, Italy. [Solano, A.] Univ Turin, Turin, Italy. [Obertino, M.] INFN, Sez Torino, Turin, Italy. [Uplegger, L.; Rivera, R.; Prosser, A.; Adreson, J.; Kwan, S.; Lei, C. M.; Tan, P.; Tran, N.; Chramowicz, J.; Kumar, A.] Fermilab Natl Accelerator Lab, Batavia, IL 60510 USA. [Boscardin, M.] Ctr Mat, I-38123 Povo, TN, Italy. [Boscardin, M.] I Microsist Fdn Bruno Kessler FBK, I-38123 Povo, TN, Italy. [Betta, G. F. Dalla; Povoli, M.; Mendicino, R.] Trent Univ, TIFPA INEN, I-38123 Povo, TN, Italy. [Betta, G. F. Dalla; Povoli, M.; Mendicino, R.] Trent Univ, Dipartimento Ingn Ind, I-38123 Povo, TN, Italy. [Ngadiuba, J.; Menasce, D.; Moroni, L.; Terzo, S.] Univ Milano Bicocca, Milan, Italy. [Cumalat, J.; Wagner, S.; Jensen, F.] Univ Colorado, Dept Phys, Boulder, CO 80309 USA. [Osipenkov, I.] Texas A&M Univ, Dept Phys, College Stn, TX 77843 USA. [Pereira, A. Vilela] Univ Estado Rio de Janeiro, Inst Fis, BR-20550013 Rio De Janeiro, Brazil. [Perera, L.] Univ Mississippi, Dept Phys & Astron, University, MS 38677 USA. [Bose, S.] Univ Nebraska, Lincoln, NE 68508 USA. [Tentindo, S.] Florida State Univ, Tallahassee, FL 32306 USA. RP Krzywda, A (reprint author), Purdue Univ, Dept Phys & Astron, W Lafayette, IN 47907 USA. EM akrzywda@purdue.edu RI Dalla Betta, Gian-Franco/I-1783-2012; Menasce, Dario Livio/A-2168-2016; OI Terzo, Stefano/0000-0003-3388-3906; Dalla Betta, Gian-Franco/0000-0001-5516-9282; Menasce, Dario Livio/0000-0002-9918-1686; Arndt, Kirk/0000-0002-6826-8340 FU U.S. Department of Energy [DE-FG02-91ER40681]; National Science foundation [PHY 0612805 UCLA Subaward 1000 G HD 870]; Provincia Autonoma di Trento through the Project MEMS2; Italian National Institute for Nuclear Physics (INFN) through the CSN5 Project TREDI FX This work was funded by the U.S. Department of Energy under Grant DE-FG02-91ER40681, the National Science foundation under Cooperative Agreement PHY 0612805 UCLA Subaward 1000 G HD 870, the Provincia Autonoma di Trento through the Project MEMS2, and also by the Italian National Institute for Nuclear Physics (INFN) through the CSN5 Project TREDI, The PSI46v2 ROCs were developed by R. Horisberger's research group (W. Erdmann, R. Horisberger, H.C. Kastli, and B. Meier) at the Paul Scherrer Institute in Switzerland. NR 25 TC 1 Z9 1 U1 0 U2 3 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 404 EP 411 DI 10.1016/j.nima.2014.06.029 PG 8 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200055 ER PT J AU Abazov, VM Abbott, B Acharya, BS Adams, M Adams, T Agnew, JP Alexeev, GD Alkhazov, G Alton, A Askew, A Atkins, S Augsten, K Avila, C Badaud, F Bagby, L Baldin, B Bandurin, DV Banerjee, S Baringer, P Bartlett, JF Bassler, U Bazterra, V Bean, A Begalli, M Bellantoni, L Beri, SB Bernardi, G Bernhard, R Bertram, I Besancon, M Beuselinck, R Bhat, PC Bhatia, S Bhatnagar, V Blazey, G Blessing, S Bloom, K Boehnlein, A Boline, D Boos, EE Borissov, G Borysova, M Brandt, A Brandt, . Brock, R Bross, A Brown, D Bu, XB Buehler, M Buescher, V Bunichev, V Burdin, S Buszello, CP Camacho-Perez, E Casey, BCK Castilla-Valdez, H Caughron, S Chakrabarti, S Chan, KM Chandra, A Chapon, E Chen, G Cho, SW Choi, S Choudhary, B Cihangir, S Claes, D Clutter, J Cooke, M Cooper, WE Corcoran, M Couderc, F Cousinou, MC Cutts, D Das, A Davies, G de Jong, SJ De la Cruz-Burelo, E Deliot, F Demina, R Denisov, D Denisov, SP Desai, S Deterre, C DeVaughan, K Diehl, HT Diesburg, M Dine, PF Dominguez, A Dubey, A Dudko, LV Duperrin, A Dutt, S Eads, M Edmunds, D Ellison, J Elvira, VD Enari, Y Evans, H Evdokimov, VN Feng, L Ferbel, T Fiedler, F Filthaut, F Fisher, W Fisk, HE Fortner, M Fox, H Fuess, S Garbincius, PH Garcia-Bellido, A Garcia-Gonzalez, JA Gavrilov, V Geng, W Gerber, CE Gershtein, Y Ginther, G Golovanov, G Grannis, PD Greder, S Greenlee, H Grenier, G Gris, P Grivaz, JF Grohsjean, A Grunendahl, S Grunewald, MW Guillemin, T Gutierrez, G Gutierrez, P Haley, J Han, L Harder, K Harel, A Hauptman, JM Hays, J Head, T Hebbeker, T Hedin, D Hegab, H Heinson, AP Heintz, U Hensel, C Heredia-De La Cruz, I Herner, K Hesketh, G Hildreth, MD Hirosky, R Hoang, T Hobbs, JD Hoeneisen, B Hogan, J Hohlfeld, M Holzbauer, JL Howley, I Hubacek, Z Hynek, V Lashvili, I Ilchenko, Y Illingworth, R Ito, AS Jabeen, S Jaffre, M Jayasinghe, A Jeong, MS Jesik, R Jiang, P Johns, K Johnson, E Johnson, M Jonckheere, A Jonsson, P Joshi, J Jung, AW Juste, A Kajfasz, E Karmanov, D Katsanos, I Kehoe, R Kermiche, S Khalatyan, N Khanov, A Kharchilava, A Kharzheev, YN Kiselevich, I Kohli, JM Kozelov, AV Kraus, J Kumar, A Kupco, A Kucra, T Kuzmin, VA Lammers, S Lebrun, P Lee, HS Lee, SW Lee, WM Lei, X Lellouch, J Li, D Li, H Li, L Li, QZ Lim, JK Lincoln, D Linnemann, J Lipaev, VV Lipton, R Liu, H Liu, Y Lobodenko, A Lokajicek, M de Sa, RL Luna-Garcia, R Lyon, AL Maciel, AKA Madar, R Magana-Villalba, R Makovec, N Malik, S Malyshev, VL Mansour, J Martinez-Ortega, J McCarthy, R McGivern, CL Meijer, MM Melnitchouk, A Menezes, D Mercadante, G Merkin, M Meyers, A Meyer, J Miconi, F Mondal, NK Mulhearn, M Nagy, E Narain, M Nayyar, R Neal, HA Negret, JP Neustroev, P Nguyen, HT Nunnemann, T Orduna, J Osman, N Osta, J Pal, A Parashar, N Parihar, V Park, SK Partridge, R Parua, N Patwa, A Penning, B Perfilov, N Peters, Y Petridis, K Petrillo, G Petroff, P Pleier, MA Podstavkov, VM Popov, V Prewitt, N Price, D Prokopenko, N Ochando, C Qian, J Quadt, A Quinn, B Raja, R Ratoff, PN Razumov, I Ripp-Baudot, I Rizatdinova, F Rominsky, N Ross, A Royon, C Rubinov, P Ruchti, R Sajot, G Sanchez-Hernandez, A Sanders, MP Santos, AS Savage, G Sawyer, L Scanlon, T Schamberger, RD Scheglov, Y Schellman, H Schwanenberger, C Schwienhorst, R Sekaric, J Severini, H Shabalina, E Shary, V Shaw, S Shchukin, AA Simak, V Skubic, P Slattery, P Smirnov, D Snow, GR Snow, J Snyder, S Soldner-Rembold, S Sonnenschein, L Soustruznik, K Stark, J Stoyanova, DA Strauss, M Suter, L Svoisky, P Titov, M Tokmenin, VV Tsai, YT Tsybychev, D Tuchming, B Tully, C Uvarov, L Uvarov, S Uzunyan, S Van Kooten, R van Leeuwen, WM Varelas, N Varnes, EW Vasilyev, IA Verkheev, AY Vertogradov, LS Verzocchi, M Vesterinen, M Vilanova, D Vokac, P Wahl, HD Wang, MHLS Warchol, J Watts, G Wayne, M Weichert, J Welty-Rieger, L Williams, MRJ Wilson, W Wobisch, N Wood, DR Wyatt, TR Xie, Y Yamada, R Yang, S Yasuda, T Yatsunenko, YA Ye, W Ye, Z Yin, H Yip, K Youn, SW Yu, JM Zennamo, J Zhao, TG Zhou, B Zhu, J Zielinski, M Zieminska, D Zivkovic, L AF Abazov, V. M. Abbott, B. Acharya, B. S. Adams, M. Adams, T. Agnew, J. P. Alexeev, G. D. Alkhazov, G. Alton, A. Askew, A. Atkins, S. Augsten, K. Avila, C. Badaud, F. Bagby, L. Baldin, B. Bandurin, D. V. Barberis, E. Baringer, P. Bartlett, J. F. Bassler, U. Bazterra, V. Bean, A. Begalli, M. Bellantoni, L. Beri, S. B. Bernardi, G. Bernhard, R. Bertram, I. Besancon, M. Beuselinck, R. Bhat, P. C. Bhatia, S. Bhatnagar, V. Blazey, G. Blessing, S. Bloom, K. Boehnlein, A. Boline, D. Boos, E. E. Borissov, G. Borysova, M. Brandt, A. Brandt, O. Brock, R. Bross, A. Brown, D. Bu, X. B. Buehler, M. Buescher, V. Bunichev, V. Burdin, S. Buszello, C. P. Camacho-Perez, E. Casey, B. C. K. Castilla-Valdez, H. Caughron, S. Chakrabarti, S. Chan, K. M. Chandra, A. Chapon, E. Chen, G. Cho, S. W. Choi, S. Choudhary, B. Cihangir, S. Claes, D. Clutter, J. Cooke, M. Cooper, W. E. Corcoran, M. Couderc, F. Cousinou, M. -C. Cutts, D. Das, A. Davies, G. de Jong, S. J. De la Cruz-Burelo, E. Deliot, F. Demina, R. Denisov, D. 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Ito, A. S. Jabeen, S. Jaffre, M. Jayasinghe, A. Jeong, M. S. Jesik, R. Jiang, P. Johns, K. Johnson, E. Johnson, M. Jonckheere, A. Jonsson, P. Joshi, J. Jung, A. W. Juste, A. Kajfasz, E. Karmanov, D. Katsanos, I. Kehoe, R. Kermiche, S. Khalatyan, N. Khanov, A. Kharchilava, A. Kharzheev, Y. N. Kiselevich, I. Kohli, J. M. Kozelov, A. V. Kraus, J. Kumar, A. Kupco, A. Kucra, T. Kuzmin, V. A. Lammers, S. Lebrun, P. Lee, H. S. Lee, S. W. Lee, W. M. Lei, X. Lellouch, J. Li, D. Li, H. Li, L. Li, Q. Z. Lim, J. K. Lincoln, D. Linnemann, J. Lipaev, V. V. Lipton, R. Liu, H. Liu, Y. Lobodenko, A. Lokajicek, M. de Sa, R. Lopes Luna-Garcia, R. Lyon, A. L. Maciel, A. K. A. Madar, R. Magana-Villalba, R. Makovec, N. Malik, S. Malyshev, V. L. Mansour, J. Martinez-Ortega, J. McCarthy, R. McGivern, C. L. Meijer, M. M. Melnitchouk, A. Menezes, D. Mercadante, G. Merkin, M. Meyers, A. Meyer, J. Miconi, F. Mondal, N. K. Mulhearn, M. Nagy, E. Narain, M. Nayyar, R. Neal, H. A. Negret, J. P. Neustroev, P. Nguyen, H. T. Nunnemann, T. Orduna, J. Osman, N. Osta, J. Pal, A. Parashar, N. Parihar, V. Park, S. K. Partridge, R. Parua, N. Patwa, A. Penning, B. Perfilov, Ni. Peters, Y. Petridis, K. Petrillo, G. Petroff, P. Pleier, M. -A. Podstavkov, V. M. Popov, V. Prewitt, Ni. Price, D. Prokopenko, N. Ochando, C. Qian, J. Quadt, A. Quinn, B. Raja, R. Ratoff, P. N. Razumov, I. Ripp-Baudot, I. Rizatdinova, F. Rominsky, Ni. Ross, A. Royon, C. Rubinov, P. Ruchti, R. Sajot, G. Sanchez-Hernandez, A. Sanders, M. P. Santos, A. S. Savage, G. Sawyer, L. Scanlon, T. Schamberger, R. D. Scheglov, Y. Schellman, H. Schwanenberger, C. Schwienhorst, R. Sekaric, J. Severini, H. Shabalina, E. Shary, V. Shaw, S. Shchukin, A. A. Simak, V. Skubic, P. Slattery, P. Smirnov, D. Snow, G. R. Snow, J. Snyder, S. Soeldner-Rembold, S. Sonnenschein, L. Soustruznik, K. Stark, J. Stoyanova, D. A. Strauss, M. Suter, L. Svoisky, P. Titov, M. Tokmenin, V. V. Tsai, Y. -T. Tsybychev, D. Tuchming, B. Tully, C. Uvarov, L. Uvarov, S. Uzunyan, S. Van Kooten, R. van Leeuwen, W. M. Varelas, N. Varnes, E. W. Vasilyev, I. A. Verkheev, A. Y. Vertogradov, L. S. Verzocchi, M. Vesterinen, M. Vilanova, D. Vokac, P. Wahl, H. D. Wang, M. H. L. S. Warchol, J. Watts, G. Wayne, M. Weichert, J. Welty-Rieger, L. Williams, M. R. J. Wilson, W. Wobisch, Ni. Wood, D. R. Wyatt, T. R. Xie, Y. Yamada, R. Yang, S. Yasuda, T. Yatsunenko, Y. A. Ye, W. Ye, Z. Yin, H. Yip, K. Youn, S. W. Yu, J. M. Zennamo, J. Zhao, T. G. Zhou, B. Zhu, J. Zielinski, M. Zieminska, D. Zivkovic, L. TI Jet energy scale determination in the DO experiment SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE Fermilab; DZero; DO; Tevatron Run II; Jet energy scale; Jet energy calibration ID P(P)OVER-BAR COLLISIONS; D0 DETECTOR; IDENTIFICATION; TEV AB The calibration of jet energy measured in the DO detector is presented, based on p (p) over bar collisions at a center-of-mass energy of 1.96 TeV at the Fermilab Tevatron collider, jet energies are measured using a sampling calorimeter composed of uranium and liquid argon as the passive and active media, respectively. This paper describes the energy calibration of jets performed with gamma+jet, Z+jet and dilet events, with jet transverse momentum p(T) > 6 GeV and pseudorapidity range vertical bar eta vertical bar < 3.6, The corrections are measured separately for data and simulation, achieving a precision of 1.4-1.8% for jets in the central part of the calorimeter ancl up to 3.5% for the jets with pseudorapidity vertical bar eta vertical bar = 3.0. Specific corrections are extracted to enhance the description of jet energy in simulation and in particular of the effects due to the flavor of the parton originating the jet, correcting biases up to 3-4% in jets with low PT originating from gluons and up to 6-8% in jets from b quarks. Published by Elsevier B.V. C1 [Hensel, C.; Maciel, A. K. A.; Santos, A. S.] Ctr Brasileiro Pesquisas Fis, LAFEX, Rio De Janeiro, Brazil. [Begalli, M.] Univ Estado Rio de Janeiro, BR-20550011 Rio De Janeiro, Brazil. [Mercadante, G.] Univ Fed ABC, Santo Andra, Brazil. 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[Chandra, A.; Corcoran, M.; Hogan, J.; Orduna, J.; Prewitt, Ni.] Rice Univ, Houston, TX 77005 USA. [Bandurin, D. V.; Hirosky, R.; Li, H.; Mulhearn, M.; Nguyen, H. T.] Univ Virginia, Charlottesville, VA 22904 USA. [Watts, G.] Univ Washington, Seattle, WA 98195 USA. RP Bandurin, DV (reprint author), Univ Virginia, Charlottesville, VA 22904 USA. EM bandurn@fnal.gov RI Lei, Xiaowen/O-4348-2014; Gutierrez, Phillip/C-1161-2011; Sharyy, Viatcheslav/F-9057-2014; Dudko, Lev/D-7127-2012; Merkin, Mikhail/D-6809-2012; Li, Liang/O-1107-2015; OI Lei, Xiaowen/0000-0002-2564-8351; Sharyy, Viatcheslav/0000-0002-7161-2616; Dudko, Lev/0000-0002-4462-3192; Li, Liang/0000-0001-6411-6107; Williams, Mark/0000-0001-5448-4213; Bassler, Ursula/0000-0002-9041-3057; Grohsjean, Alexander/0000-0003-0748-8494; Chapon, Emilien/0000-0001-6968-9828; Melnychuk, Oleksandr/0000-0002-2089-8685; Ding, Pengfei/0000-0002-4050-1753; Price, Darren/0000-0003-2750-9977; Filthaut, Frank/0000-0003-3338-2247; Bertram, Iain/0000-0003-4073-4941 FU DOE (USA); NSF (USA); CEA (France); CNRS/IN2P3 (France); MON (Russia); NRC KI (Russia); RFBR (Russia); CNPq (Brazil); FAPERJ (Brazil); FAPESP (Brazil); FUNDUNESP (Brazil); DAE (India); DST (India); Colciencias (Colombia); CONACyT (Mexico); NRF (Korea); FOM (The Netherlands); STFC (United Kingdom); Royal Society (United Kingdom); MSMT (Czech Republic); GACR (Czech Republic); BMBF (Germany); DFG (Germany); SFI (Ireland); Swedish Research Council (Sweden); CAS (China); CNSF (China) FX We thank the staffs at Fermilab and collaborating institutions, and acknowledge support from the DOE and NSF (USA); CEA and CNRS/IN2P3 (France); MON, NRC KI and RFBR (Russia); CNPq, FAPERJ, FAPESP and FUNDUNESP (Brazil); DAE and DST (India); Colciencias (Colombia); CONACyT (Mexico); NRF (Korea); FOM (The Netherlands); STFC and the Royal Society (United Kingdom); MSMT and GACR (Czech Republic); BMBF and DFG (Germany); SFI (Ireland); The Swedish Research Council (Sweden); and CAS and CNSF (China). NR 43 TC 14 Z9 14 U1 3 U2 20 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 442 EP 475 DI 10.1016/j.nima.2014.05.044 PG 34 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200060 ER PT J AU Laubach, MA Hayward, JP Zhang, X Cates, JW AF Laubach, M. A. Hayward, J. P. Zhang, X. Cates, J. W. TI Timing and position response of a block detector for fast neutron time-of-flight imaging SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE Neutron detectors; Time resolution; Scintillators; Neutron imaging ID PARTICLE DETECTOR; IDENTIFICATION; SIMULATION; SYSTEM AB Our research effort seeks to improve the spatial and timing performance of a block detector made of a pixilated plastic scintillator (EJ-200), first demonstrated as part of Oak Ridge National Laboratory's Advanced Portable Neutron Imaging System. Improvement of the position and time response is necessary to achieve better resolution and contrast in the images of shielded special nuclear material. Time-of-flight is used to differentiate between gamma and different sources of neutrons (e.g., transmission and fission neutrons). Factors limiting the timing and position performance of the neutron detector have been revealed through simulations and measurements. Simulations have suggested that the degradation in the ability to resolve pixels in the neutron detector is due to those interactions occurring near the light guide. The energy deposition within the neutron detector is shown to affect position performance and imaging efficiency. This examination details how energy cuts improve the position performance and degrade the imaging efficiency. Measurements have shown the neutron detector to have a timing resolution of sigma=238 ps. The majority of this timing uncertainty is from the depth-of-interaction (DOI) of the neutron which is confirmed by simulations and analytical calculations. (C) 2014 Elsevier B.V. All rights reserved. C1 [Laubach, M. A.; Hayward, J. P.; Zhang, X.; Cates, J. W.] Univ Tennessee, Dept Nucl Engn, Knoxville, TN 37996 USA. [Hayward, J. P.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. RP Laubach, MA (reprint author), Univ Tennessee, Dept Nucl Engn, 207 Pasqua Engn Bldg, Knoxville, TN 37996 USA. EM mlaubach@utk.edu; jhayward@utk.edu; xzhang39@utk.edu; jcates7@vols.utk.edu NR 22 TC 1 Z9 1 U1 0 U2 11 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 495 EP 501 DI 10.1016/j.nima.2014.06.052 PG 7 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200063 ER PT J AU Cooper, K Sumithrarachchi, CS Morrissey, DJ Levand, A Rodriguez, JA Savard, G Schwarz, S Zabransky, B AF Cooper, K. C Sumithrarachchi, C. S. Morrissey, D. J. Levand, A. Rodriguez, J. A. Savard, G. Schwarz, S. Zabransky, B. TI Extraction of thermalized projectile fragments from a large volume gas cell SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE Projectile fragments; Thermalization; Gas cell; Radioactive ions ID ION GUIDE; BEAMS; CATCHER; MEV/U AB Experiments to determine the stopping and extraction efficiency of energetic (90 MeV/u)C-76,a fragments in a 1.2 m long gas cell filled with helium at 123 mbar are reported. The thermalized ions were transported by DC and RF fields as well as gas flow, then jetted through a supersonic nozzle into a RF quadrupole ion guide and accelerated into an electrostatic beam line. The ions were collected in either a Faraday cup or a silicon beta detector immediately after acceleration or after magnetic analysis. The range distributions of the ions and extraction efficiency of the system were measured for different implantation rates and compared with the theoretically calculated values. The singly charged 7GGa ions were observed as [Ga-76(H2O)(n)](+) molecular ions with n=0, 1, and 2. The stopping efficiency and the extraction efficiency were obtained from the measured distributions and compared to previous results from other devices. Ks. (C) 2014 Elsevier By. All rights reserved, C1 [Cooper, K. C; Sumithrarachchi, C. S.; Morrissey, D. J.; Rodriguez, J. A.; Schwarz, S.] Michigan State Univ, Natl Superconducting Cyclotron Lab, E Lansing, MI 48824 USA. [Cooper, K. C; Morrissey, D. J.] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA. [Levand, A.; Savard, G.; Zabransky, B.] Argonne Natl Lab, Div Phys, Lemont, IL 60439 USA. RP Cooper, K (reprint author), Michigan State Univ, Natl Superconducting Cyclotron Lab, E Lansing, MI 48824 USA. EM cooperk@nscl.msu.edu FU Michigan State University; National Science Foundation [PHY-11-02511]; U.S. Department of Energy [DE-AC02-06CH11357] FX We thank Scott Williams for his contributions to the data acquisition system. We also wish to acknowledge the support of Michigan State University, the National Science Foundation under Cooperative agreement no. PHY-11-02511, and the U.S. Department of Energy under Contract DE-AC02-06CH11357. NR 20 TC 11 Z9 11 U1 1 U2 7 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 543 EP 546 DI 10.1016/j.nima.2014.06.075 PG 4 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200070 ER PT J AU Chipps, KA Greife, U Bardayan, DW Blackmon, JC Kontos, A Linhardt, LE Matos, M Pain, SD Pittman, ST Sachs, A Schatz, H Schmitt, KT Smith, MS Thompson, P AF Chipps, K. A. Greife, U. Bardayan, D. W. Blackmon, J. C. Kontos, A. Linhardt, L. E. Matos, M. Pain, S. D. Pittman, S. T. Sachs, A. Schatz, H. Schmitt, K. T. Smith, M. S. Thompson, P. TI The Jet Experiments in Nuclear Structure and Astrophysics (JENSA) gas jet target SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE Gas jet target; Transfer reactions; Capture reactions; Radioactive ion beams ID DENSITY AB New radioactive ion beam (RIB) facilities will push further away from stability and enable the next generation of nuclear physics experiments. Of great importance to the future of RIB physics are scattering, transfer, and capture reaction measurements of rare, exotic, and unstable nuclei on light targets such as hydrogen and helium. These measurements require targets that are dense, highly localized, and pure. Targets must also accommodate the use of large area silicon detector arrays, high-efficiency gamma arrays, and heavy ion detector systems to efficiently measure the reaction products. To address these issues, the Jet Experiments in Nuclear Structure and Astrophysics (JENSA) Collaboration has designed, built, and characterized a supersonic gas jet target, capable of providing gas areal densities on par with commonly used solid targets within a region of a few millimeters diameter. Densities of over 5 x 10(18) atoms/cm(2) of helium have been achieved, making the JENSA gas jet target the most dense helium jet achieved so far. (C) 2014 Elsevier B.V. All rights reserved, C1 [Chipps, K. A.; Greife, U.] Colorado Sch Mines, Dept Phys, Golden, CO 80401 USA. [Chipps, K. A.; Matos, M.; Pittman, S. T.; Sachs, A.; Schmitt, K. T.; Thompson, P.] Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA. [Chipps, K. A.; Bardayan, D. W.; Matos, M.; Pain, S. D.; Smith, M. S.] Oak Ridge Natl Lab, Div Phys, Oak Ridge, TN 37831 USA. [Bardayan, D. W.] Univ Notre Dame, Dept Phys, Notre Dame, IN 46556 USA. [Blackmon, J. C.; Linhardt, L. E.] Louisiana State Univ, Dept Phys & Astron, Baton Rouge, LA 70803 USA. [Kontos, A.; Schatz, H.] Michigan State Univ, Dept Phys & Astron, E Lansing, MI 48824 USA. [Kontos, A.] Univ Notre Dame, Joint Inst Nucl Astrophys, Notre Dame, IN 46556 USA. RP Chipps, KA (reprint author), Oak Ridge Natl Lab, Div Phys, Oak Ridge, TN 37831 USA. EM kchipps@nuclearemail.org RI Pain, Steven/E-1188-2011; OI Pain, Steven/0000-0003-3081-688X; Chipps, Kelly/0000-0003-3050-1298 FU US DOE Office of Nuclear Physics (Colorado School of Mines grant) [DE-FG02-10ER41704, DE-FG02-93ER40789]; NSF FX The authors wish to thank Devin Connolly at the Colorado School of Mines for producing the camera-ready CAD images for Figs, 1-3, This work is supported by the US DOE Office of Nuclear Physics (Colorado School of Mines grants DE-FG02-10ER41704 and DE-FG02-93ER40789) and the NSF. NR 25 TC 14 Z9 14 U1 0 U2 5 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 553 EP 564 DI 10.1016/j.nima.2014.00.042 PG 12 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200072 ER PT J AU Dolan, JL Flaska, M Poitrasson-Riviere, A Enqvist, A Peerani, P Chichester, DL Pozzi, SA AF Dolan, Jennifer L. Flaska, Marek Poitrasson-Riviere, Alexis Enqvist, Andreas Peerani, Paolo Chichester, David L. Pozzi, Sara A. TI Plutonium measurements with a fast-neutron multiplicity counter for nuclear safeguards applications SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE Nuclear safeguards; He-3 alternatives; Liquid scintillation detectors; MCNPX-PoliMi ID PULSE-SHAPE DISCRIMINATION; GAMMA-RAY AB Measurements were performed at the joint Research Centre in Ispra, Italy to field test a fast-neutron multiplicity counter developed at the University of Michigan. The measurements allowed the assessment of the system's photon discrimination abilities, efficiency when measuring neutron multiplicity, ability to characterize Pu-240(eff) mass, and performance relative to a currently deployed neutron coincidence counter. This work is motivated by the need to replace and improve upon He-3 neutron detection systems for nuclear safeguards applications. (C) 2014 Elsevier B.V. All rights reserved. C1 [Dolan, Jennifer L.; Flaska, Marek; Poitrasson-Riviere, Alexis; Pozzi, Sara A.] Univ Michigan, Nucl Engn & Radiol Sci Dept, Ann Arbor, MI 48109 USA. [Enqvist, Andreas] Univ Florida, Gainesville, FL 32611 USA. [Peerani, Paolo] European Commiss, Joint Res Ctr, Inst Transuranium Elements, Ispra, Italy. [Chichester, David L.] Idaho Natl Lab, Idaho Falls, ID 83415 USA. RP Dolan, JL (reprint author), Univ Michigan, Nucl Engn & Radiol Sci Dept, Ann Arbor, MI 48109 USA. EM jldolan@umich.edu FU U.S. Department of Energy's Fuel Cycle Technologies Program, in the Material Protection, Accounting, and Control Technologies (MPACT) Campaign; U.S. Department of Energy by Battelle Energy [AC07-05-ID14517]; National Science Foundation; Domestic Nuclear Detection Office of the U.S. Department of Homeland Security through the Academic Research Initiative Award [CMMI 0938909]; U.S. Department of Homeland Security's Domestic Nuclear Detection Office; U.S. Department of Defense's Defense Threat Reduction Agency FX This work was supported by the U.S. Department of Energy's Fuel Cycle Technologies Program, in the Material Protection, Accounting, and Control Technologies (MPACT) Campaign. Idaho National Laboratory is operated for the U.S. Department of Energy by Battelle Energy Alliance under DOE contract DE-AC07-05-ID14517. This work was also supported by the National Science Foundation and the Domestic Nuclear Detection Office of the U.S. Department of Homeland Security through the Academic Research Initiative Award # CMMI 0938909. This research was performed under the Nuclear Forensics Graduate Fellowship Program which is sponsored by the U.S. Department of Homeland Security's Domestic Nuclear Detection Office and the U.S. Department of Defense's Defense Threat Reduction Agency. NR 18 TC 9 Z9 9 U1 0 U2 4 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 565 EP 574 DI 10.1016/j.nima.2014.06.028 PG 10 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200073 ER PT J AU Li, YJ Wang, LF Lin, FL AF Li, Yingjie Wang, Lanfa Lin, Fanglei TI Landau damping effects and evolutions of energy spread in small isochronous ring SO NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT LA English DT Article DE Isochronous ring; Microwave instability; Space charge field; Landau damping; 2D dispersion relation; Energy spread AB This paper presents the Landau damping effects on the microwave instability of a coasting long bunch in an isochronous ring due to Unite energy spread and emittance. Our two-dimensional (2D) dispersion relation gives more accurate predictions of the microwave instability growth rates of short-wavelength perturbations than the conventional ID formula. The long-term evolution of energy spread is also studied by measurements and simulations. (C) 2014 Elsevier B.V. All rights reserved. C1 [Li, Yingjie] Michigan State Univ, Dept Phys, E Lansing, MI 48824 USA. [Wang, Lanfa] SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA. [Lin, Fanglei] Thomas Jefferson Natl Accelerator Facil, Newport News, VA 23606 USA. RP Li, YJ (reprint author), Michigan State Univ, Dept Phys, E Lansing, MI 48824 USA. EM liyingji@msu.edu FU NSF Grant [PHY 0606007] FX We would like to thank Prof. F. Marti and T. P. Wangler for their guidance. We are also grateful to Y.C. Wang, S. Y. Lee, K. Y. Ng, G. Stupakov, E. Pozdeyev, A. W. Chao, R. York, M. Syphers, V. Zelevinsky, J. Baldwin, and J. A. Rodriguez for their fruitful discussions and suggestions. This work was supported by NSF Grant # PHY 0606007. NR 18 TC 1 Z9 1 U1 0 U2 0 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0168-9002 EI 1872-9576 J9 NUCL INSTRUM METH A JI Nucl. Instrum. Methods Phys. Res. Sect. A-Accel. Spectrom. Dect. Assoc. Equip. PD NOV 1 PY 2014 VL 763 BP 674 EP 687 DI 10.1016/j.nima.2014.06.070 PG 14 WC Instruments & Instrumentation; Nuclear Science & Technology; Physics, Nuclear; Physics, Particles & Fields SC Instruments & Instrumentation; Nuclear Science & Technology; Physics GA AP3ON UT WOS:000341986200079 ER PT J AU Tak, T Lee, D Kim, TK Hong, SG AF Tak, Taewoo Lee, Deokjung Kim, T. K. Hong, Ser Gi TI Optimization study of Ultra-long Cycle Fast Reactor core concept SO ANNALS OF NUCLEAR ENERGY LA English DT Article DE Ultra-long Cycle Fast Reactor; Optimization; Breed-and-burn; Safety ID SUBCHANNEL ANALYSIS; CODE; DESIGN AB An optimization of an Ultra-long Cycle Fast Reactor (UCFR) design with a power rating of 1000 MW (electric), UCFR-1000, has been performed. Firstly, geometric optimization has been performed in the aspects of core size and core shape in terms of thermal-hydraulic (TH) feedback. Secondly, fuel composition optimization has been performed by adopting pressurized water reactor (PWR) spent fuel (SF) as a blanket material as well as natural uranium (NU). Thirdly, thorium has been loaded in the inner core for the optimization of radial power distribution. Lastly, a small-size UCFR with a power rate of 100 MWe has been developed with optimization of maximum neutron flux and fast neutron fluence limit for a short term deployable nuclear reactor. The equivalent diameter and the height of the optimized UCFR-1000 core are 5.9 and 2.4 m, respectively, while the equivalent diameter and the height of the optimized UCFR-100 core are 4.3 and 1.0 m, respectively. The size of the optimized UCFR-1000 has been enlarged in the radial direction and shortened in the axial direction from those of the initial UCFR design (Tak et al., 2013a) and this modification makes the burning speed of active core movement slower. It has been confirmed for both designs that a full-power operation of 60 years without refueling is feasible with respect to isotopics and criticality by a breed-and-burn strategy. The core performance characteristics of both designs have been evaluated in terms of axial/radial power shapes, neutron flux and nuclide distributions, breeding ratio, reactivity feedback coefficients, control rod worth, etc. By the design optimization study in this paper, the reductions of maximum neutron flux, fast neutron fluence, and axial/radial power peaking have been achieved, which are favorable for the safety of the UCFR. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Tak, Taewoo; Lee, Deokjung] Ulsan Natl Inst Sci & Technol, Ulsan 689798, South Korea. [Kim, T. K.] Argonne Natl Lab, Argonne, IL 60564 USA. [Hong, Ser Gi] Kyung Hee Univ, Yongin 446701, Gyeonggi Do, South Korea. RP Lee, D (reprint author), Ulsan Natl Inst Sci & Technol, UNIST Gil 50, Ulsan 689798, South Korea. EM deokjung@unist.ac.kr; tkkim@anl.gov; sergihong@khu.ac.kr OI Lee, Deokjung/0000-0002-3935-5058 FU National Research Foundation of Korea (NRF) - Korean government (MSIP) FX This work was supported by a National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP). NR 36 TC 5 Z9 5 U1 1 U2 12 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0306-4549 J9 ANN NUCL ENERGY JI Ann. Nucl. Energy PD NOV PY 2014 VL 73 BP 145 EP 161 DI 10.1016/j.anucene.2014.06.030 PG 17 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AP7HM UT WOS:000342248400015 ER PT J AU Carney, S Brown, F Kiedrowski, B Martin, W AF Carney, Sean Brown, Forrest Kiedrowski, Brian Martin, William TI Theory and applications of the fission matrix method for continuous-energy Monte Carlo SO ANNALS OF NUCLEAR ENERGY LA English DT Article DE Monte Carlo; Criticality; k-Effective; Eigenmodes ID CRITICALITY AB The fission matrix method can be used to provide estimates of the fundamental mode fission distribution, the dominance ratio, the eigenvalue spectrum, and higher mode forward and adjoint eigenfunctions of the fission distribution. It can also be used to accelerate the convergence of power method iterations and to provide basis functions for higher-order perturbation theory. The higher-mode fission sources can be used to determine higher-mode forward fluxes and tallies, and work is underway to provide higher-mode adjoint-weighted fluxes and tallies. These aspects of the method are here both theoretically justified and demonstrated, and then used to investigate fundamental properties of the transport equation for a continuous-energy physics treatment. Implementation into the MCNP6 Monte Carlo code is also discussed, including a sparse representation of the fission matrix, which permits much larger and more accurate representations. Properties of the calculated eigenvalue spectrum of a 2D PWR problem are discussed: for a fine enough mesh and a sufficient degree of sampling, the spectrum both converges and has a negligible imaginary component. Calculation of the fundamental mode of the fission matrix for a fuel storage vault problem shows how convergence can be accelerated by over a factor of ten given a flat initial distribution. Forward fluxes and the relative uncertainties for a 2D PWR are shown, both of which qualitatively agree with expectation. Lastly, eigenmode expansions are performed during source convergence of the 2D PWR problem for two initial distributions; observed decay rates of coefficients agree closely with expectation. Published by Elsevier Ltd. C1 [Carney, Sean; Martin, William] Univ Michigan, Ann Arbor, MI 48109 USA. [Brown, Forrest; Kiedrowski, Brian] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. RP Carney, S (reprint author), Univ Michigan, 2355 Bonisteel Blvd, Ann Arbor, MI 48109 USA. EM seanec@umich.edu FU Department of Energy Nuclear Energy University Programs Graduate Fellowship; U.S. Department of Energy FX This material is based upon work supported under a Department of Energy Nuclear Energy University Programs Graduate Fellowship. This work was also supported by the U.S. Department of Energy NNSA Advanced Simulation and Computing Program and Nuclear Criticality Safety Program. NR 24 TC 7 Z9 7 U1 0 U2 7 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0306-4549 J9 ANN NUCL ENERGY JI Ann. Nucl. Energy PD NOV PY 2014 VL 73 BP 423 EP 431 DI 10.1016/j.anucene.2014.07.020 PG 9 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AP7HM UT WOS:000342248400043 ER PT J AU Martin, WJ de Oliveira, CRE Hecht, AA AF Martin, W. J. de Oliveira, C. R. E. Hecht, A. A. TI Reactor fuel depletion benchmark of TINDER SO ANNALS OF NUCLEAR ENERGY LA English DT Article DE Burnup; Depletion; Nuclear reactor; CINDER2008; TINDER AB Accurate burnup calculations are key to proper nuclear reactor design, fuel cycle modeling, and disposal estimations. The TINDER code, originally designed for activation analyses, has been modified to handle full burnup calculations, including the widely used predictor-corrector feature: In order to properly characterize the performance of TINDER for this application, a benchmark calculation was performed. Although the results followed the trends of past benchmarked codes for a UO2 PWR fuel sample from the Takahama-3 reactor, there were obvious deficiencies in the final result, likely in the nuclear data library that was used. Isotopic comparisons versus experiment and past code benchmarks are given, as well as hypothesized areas of deficiency and future work. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Martin, W. J.] Sandia Natl Labs, Albuquerque, NM 87185 USA. [de Oliveira, C. R. E.; Hecht, A. A.] Univ New Mexico, Albuquerque, NM 87131 USA. RP Martin, WJ (reprint author), Sandia Natl Labs, POB 5800, Albuquerque, NM 87185 USA. EM wjmarti@sandia.gov FU U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. NR 13 TC 0 Z9 0 U1 3 U2 8 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0306-4549 J9 ANN NUCL ENERGY JI Ann. Nucl. Energy PD NOV PY 2014 VL 73 BP 547 EP 551 DI 10.1016/j.anucene.2014.04.036 PG 5 WC Nuclear Science & Technology SC Nuclear Science & Technology GA AP7HM UT WOS:000342248400056 ER PT J AU Stadler, M Groissbock, M Cardoso, G Marnay, C AF Stadler, M. Groissboeck, M. Cardoso, G. Marnay, C. TI Optimizing Distributed Energy Resources and building retrofits with the strategic DER-CAModel SO APPLIED ENERGY LA English DT Article DE Building retrofits; Distributed energy resources; Microgrid; Mixed integer linear programming; Strategic decision; Zero net energy buildings ID EFFICIENCY AB The pressuring need to reduce the import of fossil fuels as well as the need to dramatically reduce CO2 emissions in Europe motivated the European Commission (EC) to implement several regulations directed to building owners. Most of these regulations focus on increasing the number of energy efficient buildings, both new and retrofitted, since retrofits play an important role in energy efficiency. Overall, this initiative results from the realization that buildings will have a significant impact in fulfilling the 20/20/20-goals of reducing the greenhouse gas emissions by 20%, increasing energy efficiency by 20%, and increasing the share of renewables to 20%, all by 2020. The Distributed Energy Resources Customer Adoption Model (DER-CAM) is an optimization tool used to support DER investment decisions, typically by minimizing total annual costs or CO2 emissions while providing energy services to a given building or microgrid site. This paper shows enhancements made to DER-CAM to consider building retrofit measures along with DER investment options. Specifically, building shell improvement options have been added to DER-CAM as alternative or complementary options to investments in other DER such as PV, solar thermal, combined heat and power, or energy storage. The extension of the mathematical formulation required by the new features introduced in DER-CAM is presented and the resulting model is demonstrated at an Austrian Campus building by comparing DERCAM results with and without building shell improvement options. Strategic investment results are presented and compared to the observed investment decision at the test site. Results obtained considering building shell improvement options suggest an optimal weighted average U value of about 0.53 W/(m(2) K) for the test site. This result is approximately 25% higher than what is currently observed in the building, suggesting that the retrofits made in 2002 were not optimal. Furthermore, the results obtained with DER-CAM illustrate the complexity of interactions between DER and passive measure options, showcasing the need for a holistic optimization approach to effectively optimize energy costs and CO2 emissions. The simultaneous optimization of building shell improvements and DER investments enables building owners to take one step further towards nearly zero energy buildings (nZEB) or nearly zero carbon emission buildings (nZCEB), and therefore support the 20/20/20 goals. Published by Elsevier Ltd. C1 [Stadler, M.; Groissboeck, M.; Cardoso, G.; Marnay, C.] Ernest Orlando Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. [Stadler, M.; Groissboeck, M.] Ctr Energy & Innovat Technol CET, A-3681 Hofamt Priel, Austria. [Cardoso, G.] Univ Tecn Lisboa, Inst Super Tecn, P-1100 Lisbon, Portugal. RP Stadler, M (reprint author), Ernest Orlando Lawrence Berkeley Natl Lab, One Cyclotron Rd,MS 90-1121, Berkeley, CA 94720 USA. EM mstadler@lbl.gov FU Office of Electricity Delivery and Energy Reliability, Distributed Energy Program of the U.S. Department of Energy [DE-AC02-05CH11231] FX The Distributed Energy Resources Customer Adoption Model (DER-CAM) has been designed at Lawrence Berkeley National Laboratory (LBNL). DER-CAM has been funded partly by the Office of Electricity Delivery and Energy Reliability, Distributed Energy Program of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. NR 24 TC 21 Z9 21 U1 3 U2 39 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0306-2619 EI 1872-9118 J9 APPL ENERG JI Appl. Energy PD NOV 1 PY 2014 VL 132 BP 557 EP 567 DI 10.1016/j.apenergy.2014.07.041 PG 11 WC Energy & Fuels; Engineering, Chemical SC Energy & Fuels; Engineering GA AP7HC UT WOS:000342247400053 ER PT J AU Pan, JJ Marquardt, D Heberle, FA Kucerka, N Katsaras, J AF Pan, Jianjun Marquardt, Drew Heberle, Frederick A. Kucerka, Norbert Katsaras, John TI Revisiting the bilayer structures of fluid phase phosphatidylglycerol lipids: Accounting for exchangeable hydrogens SO BIOCHIMICA ET BIOPHYSICA ACTA-BIOMEMBRANES LA English DT Article DE Lipid bilayer structure; SANS; SAXS; MD simulations; PG lipid; Hydrogen exchange ID X-RAY-SCATTERING; SMALL-ANGLE NEUTRON; MEMBRANES; SIMULATIONS; NMR; DISTRIBUTIONS; SPECTROSCOPY; MIXTURES; STEROLS; LENGTH AB We recently published two papers detailing the structures of fluid phase phosphatidylglycerol (PG) lipid bilayers (Kucerka et al., 20121 Phys. Chem. B 116: 232-239; Pan et al., 2012 Biochim. Biophys. Acta Biomembr. 1818: 2135-2148), which were determined using the scattering density profile model. This hybrid experimental/computational technique utilizes molecular dynamics simulations to parse a lipid bilayer into components whose volume probabilities follow simple analytical functional forms. Given the appropriate scattering densities, these volume probabilities are then translated into neutron scattering length density (NSLD) and electron density (ED) profiles, which are used to jointly refine experimentally obtained small angle neutron and X-ray scattering data. However, accurate NSLD and ED profiles can only be obtained if the bilayer's chemical composition is known. Specifically, in the case of neutron scattering, the lipid's exchangeable hydrogens with aqueous D2O must be accounted for, as they can have a measureable effect on the resultant lipid bilayer structures. This was not done in our above-mentioned papers. Here we report on the molecular structures of PG lipid bilayers by appropriately taking into account the exchangeable hydrogens. Analysis indicates that the temperature-averaged PG lipid areas decrease by 15 to 3.8 angstrom(2), depending on the lipid's acyl chain length and unsaturation, compared to PG areas when hydrogen exchange was not taken into account. (C) 2014 Elsevier B.V. All rights reserved. C1 [Pan, Jianjun] Univ S Florida, Dept Phys, Tampa, FL 33620 USA. [Marquardt, Drew; Katsaras, John] Brock Univ, Dept Phys, St Catharines, ON L2S 3A1, Canada. [Heberle, Frederick A.; Katsaras, John] Oak Ridge Natl Lab, Neutron Sci Directorate, Oak Ridge, TN 37831 USA. [Kucerka, Norbert] Comenius Univ, Dept Phys Chem Drugs, Bratislava 83232, Slovakia. [Kucerka, Norbert] Joint Inst Nucl Res, Frank Lab Neutron Phys, Dubna 141980, Russia. [Katsaras, John] Oak Ridge Natl Lab, Joint Inst Neutron Scattering, Oak Ridge, TN 37831 USA. [Katsaras, John] Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA. RP Pan, JJ (reprint author), Univ S Florida, Dept Phys, Tampa, FL 33620 USA. EM panj@usf.edu; katsarasj@ornl.gov OI Katsaras, John/0000-0002-8937-4177; Marquardt, Drew/0000-0001-6848-2497 FU Scientific User Facilities Division of the DOE Office of Basic Energy Sciences (BES); Laboratory Directed Research and Development Program of Oak Ridge National Laboratory (ORNL) [DE-AC05-00OR2275]; University of South Florida FX J.K. is supported through the Scientific User Facilities Division of the DOE Office of Basic Energy Sciences (BES), and by the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory (ORNL), managed by UT-Battelle, LLC, for the U.S. Department of Energy (DOE) under contract no. DE-AC05-00OR2275. J.J.P. is partially supported by a startup fund from the University of South Florida. NR 26 TC 12 Z9 12 U1 1 U2 18 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0005-2736 EI 0006-3002 J9 BBA-BIOMEMBRANES JI Biochim. Biophys. Acta-Biomembr. PD NOV PY 2014 VL 1838 IS 11 BP 2966 EP 2969 DI 10.1016/j.bbamem.2014.08.009 PG 4 WC Biochemistry & Molecular Biology; Biophysics SC Biochemistry & Molecular Biology; Biophysics GA AQ0MM UT WOS:000342477400022 PM 25135659 ER PT J AU Huang, YP Zheng, QP Wang, JH AF Huang, Yuping Zheng, Qipeng P. Wang, Jianhui TI Two-stage stochastic unit commitment model including non-generation resources with conditional value-at-risk constraints SO ELECTRIC POWER SYSTEMS RESEARCH LA English DT Article DE Stochastic unit commitment; Demand response; Energy storage; Conditional value-at-risk; Benders decomposition; Sensitivity analysis ID TRANSMISSION NETWORK EXPANSION; WIND POWER-GENERATION; ENERGY-STORAGE; DEMAND RESPONSE; SYSTEM; UNCERTAINTIES; OPTIMIZATION; MANAGEMENT; ALGORITHM; RESERVE AB This paper presents a two-stage stochastic unit commitment (UC) model, which integrates non-generation resources such as demand response (DR) and energy storage (ES) while including risk constraints to balance between cost and system reliability due to the fluctuation of variable generation such as wind and solar power. This paper uses conditional value-at-risk (CVaR) measures to model risks associated with the decisions in a stochastic environment. In contrast to chance-constrained models requiring extra binary variables, risk constraints based on CVaR only involve linear constraints and continuous variables, making it more computationally attractive. The proposed models with risk constraints are able to avoid over-conservative solutions but still ensure system reliability represented by loss of loads. Then numerical experiments are conducted to study the effects of non-generation resources on generator schedules and the difference of total expected generation costs with risk consideration. Sensitivity analysis based on reliability parameters is also performed to test the decision preferences of confidence levels and load-shedding loss allowances on generation cost reduction. (c) 2014 Elsevier B.V. All rights reserved. C1 [Huang, Yuping; Zheng, Qipeng P.] Univ Cent Florida, Dept Ind Engn & Management Syst, Orlando, FL 32816 USA. [Wang, Jianhui] Argonne Natl Lab, Argonne, IL 60439 USA. RP Huang, YP (reprint author), Univ Cent Florida, Dept Ind Engn & Management Syst, Orlando, FL 32816 USA. EM yuping.huang@knights.ucf.edu OI Zheng, Qipeng/0000-0002-4597-3426 FU National Science Foundation [CMMI-1355939, ECCS-1232168]; U.S. Department of Energy (DOE) Office of Electricity Delivery and Energy Reliability FX The works of the first and the second author are in part supported by the National Science Foundation under grants CMMI-1355939 and ECCS-1232168. The third author is supported by the U.S. Department of Energy (DOE) Office of Electricity Delivery and Energy Reliability. The authors also would like to thank the reviewers for their suggestions on improving the quality of this paper. NR 41 TC 14 Z9 14 U1 4 U2 26 PU ELSEVIER SCIENCE SA PI LAUSANNE PA PO BOX 564, 1001 LAUSANNE, SWITZERLAND SN 0378-7796 EI 1873-2046 J9 ELECTR POW SYST RES JI Electr. Power Syst. Res. PD NOV PY 2014 VL 116 BP 427 EP 438 DI 10.1016/j.epsr.2014.07.010 PG 12 WC Engineering, Electrical & Electronic SC Engineering GA AP7OX UT WOS:000342267700046 ER PT J AU Xie, ZL Blair, RG Orlovskaya, N Cullen, DA Payzant, EA AF Xie, Zhilin Blair, Richard G. Orlovskaya, Nina Cullen, David A. Payzant, E. Andrew TI Thermal stability of hexagonal OsB2 SO JOURNAL OF SOLID STATE CHEMISTRY LA English DT Article DE Osmium; Boron; Stability; Coefficient of thermochemical expansion ID OSMIUM DIBORIDE; HARD MATERIAL; TRANSITION; BORIDES AB The synthesis of novel hexagonal ReB2-type OsB2 ceramic powder was performed by high energy ball milling of elemental Os and B powders. Two different sources of B powder have been used for this mechanochemical synthesis. One B powder consisted of a mixture of amorphous and crystalline phases and a mixture of B-10 and B-11 isotopes with a fine particle size, while another B powder was a purely crystalline (rhombohedral) material consisting of enriched B-11 isotope with coarse particle size. The same Os powder was used for the synthesis in both cases. It was established that, in the first case, the hexagonal OsB2 phase was the main product of synthesis with a small quantity of Os2B3 phase present after synthesis as an intermediate product. In the second case, where coarse crystalline 11B powder was used as a raw material, only Os2B3 boride was synthesized mechanochemically. The thermal stability of hexagonal OsB2 powder was studied by heating under argon up to 876 degrees C and cooling in vacuo down to -225 degrees C. During the heating, the sacrificial reaction 2OsB(2) + 3O(2) -> 2Os + 2B(2)O(3) took place due to presence of O-2/water vapor molecules in the heating chamber, resulting in the oxidation of B atoms and formation of B2O3 and precipitation of Os metal out of the OsB2 lattice. As a result of such phase changes during heating, the lattice parameters of hexagonal OsB2 changed significantly. The shrinkage of the a lattice parameter was recorded in 276-426 degrees C temperature range upon heating, which was attributed to the removal of B atoms from the OsB2 lattice due to oxidation followed by the precipitation of Os atoms and formation of Os metal. While significant structural changes occurred upon heating due to presence of O-2, the hexagonal OsB2 ceramic demonstrated good phase stability upon cooling in vacuo with linear shrinkage of the lattice parameters and no phase changes detected during cooling. (C) 2014 Elsevier Inc. All rights reserved. C1 [Xie, Zhilin; Blair, Richard G.; Orlovskaya, Nina] Univ Cent Florida, Dept Mech & Aerosp Engn, Orlando, FL 32816 USA. [Blair, Richard G.] Univ Cent Florida, Dept Phys, Orlando, FL 32816 USA. [Cullen, David A.] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA. [Payzant, E. Andrew] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA. RP Orlovskaya, N (reprint author), Univ Cent Florida, Dept Mech & Aerosp Engn, Orlando, FL 32816 USA. EM Nina.Orlovskaya@ucf.edu RI Payzant, Edward/B-5449-2009; Cullen, David/A-2918-2015 OI Payzant, Edward/0000-0002-3447-2060; Cullen, David/0000-0002-2593-7866 FU NSF [DMR - 0748364]; Center for Nanophase Material Sciences; Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy at Oak Ridge National Laboratory FX This work was supported by NSF projects DMR - 0748364. High and low temperature X-ray diffraction studies and electron microscopy were supported by Center for Nanophase Material Sciences, which is sponsored at Oak Ridge National Laboratory by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy. The authors also wish to thank Ceradyne, Inc. for the donation the crystalline 11B powder. NR 12 TC 6 Z9 6 U1 1 U2 17 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0022-4596 EI 1095-726X J9 J SOLID STATE CHEM JI J. Solid State Chem. PD NOV PY 2014 VL 219 BP 210 EP 219 DI 10.1016/j.jssc.2014.07.035 PG 10 WC Chemistry, Inorganic & Nuclear; Chemistry, Physical SC Chemistry GA AP8NQ UT WOS:000342336100029 ER PT J AU Petersen, LB Lipton, AS Zorin, V Nielsen, UG AF Petersen, Line Boisen Lipton, Andrew S. Zorin, Vadim Nielsen, Ulla Gro TI Local environment and composition of magnesium gallium layered double hydroxides determined from solid-state H-1 and Ga-71 NMR spectroscopy SO JOURNAL OF SOLID STATE CHEMISTRY LA English DT Article DE Layered double hydroxides; Cation ordering; Solid state NMR ID HYDROTALCITE-LIKE COMPOUNDS; MAGNETIC-RESONANCE-SPECTROSCOPY; QUADRUPOLAR NUCLEI; MAS NMR; MG-AL; DYNAMICS; GA; IDENTIFICATION; HYDROLYSIS; OXYANIONS AB Ordering of gallium(III) in a series of magnesium gallium (MgGa) layered double hydroxides (LDHs), [Mg1-xGax(OH)(2)(NO3)(x).yH(2)O] was investigated using solid-state H-1 and Ga-71 NMR spectroscopy as well as powder X-ray diffraction. Three different proton environments from Mg-3-OH, Mg2Ga-OH and intergallery water molecules were assigned and quantified using {H-1,Ga-71} HETCOR and H-1 MAS NMR. A single Ga-71 site originating from the unique Go site in the MgGa LDH's was observed in Ga-71 MAS and 3QMAS NMR spectra. Both H-1 MAS NMR spectra recorded at 21.1 T (900 MHz) and elemental analysis show that the synthesized MgGa LDH's had a lower Mg:Go ratio than that of the starting reactant solution. The origin of this is the formation of soluble [Ga(OH)(4)](-) complexes formed during synthesis, and not due to formation of insoluble gallium (oxy)hydroxides. No sign of Ga-O-Ga connectivities or defects were detected for the MgGa LDH's. (C) 2014 Elsevier Inc. All rights reserved. C1 [Petersen, Line Boisen; Nielsen, Ulla Gro] Univ Southern Denmark, Dept Phys Chem & Pharm, DK-5230 Odense M, Denmark. [Lipton, Andrew S.] Pacific NW Natl Lab, Div Biol Sci, Richland, WA 99354 USA. [Zorin, Vadim] Agilent Technol UK Ltd, Yarnton OX5 1QU, Oxon, England. RP Nielsen, UG (reprint author), Univ Southern Denmark, Dept Phys Chem & Pharm, DK-5230 Odense M, Denmark. EM ugn@sdu.dk OI Zorin, Vadim/0000-0002-5572-0166; Nielsen, Ulla Gro/0000-0002-2336-3061 FU Villum Young Investigator Programme [VKR022364]; Office of Biological and Environmental Research at Pacific Northwest National Laboratory FX This work was financially supported by the "Villum Young Investigator Programme" (UGN and LBP) (grant no. VKR022364). A portion of the research was performed using EMSL, a DOE Office of Science User Facility sponsored by the Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory. Ms. Carina Lohmann, Department of Biology, University of Southern Denmark is thanked for performing the ICP analysis. NR 34 TC 4 Z9 5 U1 4 U2 47 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0022-4596 EI 1095-726X J9 J SOLID STATE CHEM JI J. Solid State Chem. PD NOV PY 2014 VL 219 BP 242 EP 246 DI 10.1016/j.jssc.2014.07.023 PG 5 WC Chemistry, Inorganic & Nuclear; Chemistry, Physical SC Chemistry GA AP8NQ UT WOS:000342336100033 ER PT J AU Sombrio, CIL Franzen, PL dos Reis, R Boudinov, HI Baptista, DL AF Sombrio, C. I. L. Franzen, P. L. dos Reis, R. Boudinov, H. I. Baptista, D. L. TI Passivation of defects in ZnO nanowires by SiO2 sputtering deposition SO MATERIALS LETTERS LA English DT Article DE Zinc oxide nanowires; SiO2 matrix; Photoluminescence; Native point defects passivation ID GROWTH; SIZE AB Passivation of native point defects in ZnO nanowires was successfully achieved by SiO2 deposition. The ZnO nanowires were grown on sapphire by the vapor-liquid-solid method and coated with SiO2 through reactive sputtering deposition. The samples were post-annealed at different temperatures in Argon atmosphere. Photoluminescence measurements at room temperature and electron transmission microscopy were performed. The coated nanowires present a core-shell structure. A strong oxygen vacancies passivation were observed resulting in a drastic suppression on visible light emissions in favor of UV ones. On the other hand, annealing at increasingly higher temperatures favored the oxygen desorption and the increase of deep-level states. (C) 2014 Elsevier B.V. All rights reserved. C1 [Sombrio, C. I. L.; Franzen, P. L.; Boudinov, H. I.; Baptista, D. L.] Univ Fed Rio Grande do Sul, Inst Fis, BR-91509900 Porto Alegre, RS, Brazil. [dos Reis, R.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Natl Ctr Electron Microscopy, Berkeley, CA 94720 USA. RP Sombrio, CIL (reprint author), Univ Fed Rio Grande do Sul, Inst Fis, BR-91509900 Porto Alegre, RS, Brazil. EM caroline.lisevski@gmail.com RI Boudinov, Henri/D-2274-2009; Baptista, Daniel/I-2605-2012; dos Reis, Roberto/E-9486-2012 OI Baptista, Daniel/0000-0002-2658-6412; dos Reis, Roberto/0000-0002-6011-6078 FU CNPq; CAPES; National Center for Electron Microscopy, Lawrence Berkeley Lab; U.S. Department of Energy [DE-AC02-05CH11231] FX This project is supported by CNPq and CAPES. The authors appreciate the use of the CME and CNANO facilities at UFRGS. D. L. Baptista thanks DIMAT/NULAM for the use of Electron Microscopy facilities at INMETRO. R. dos Reis acknowledge the support of the National Center for Electron Microscopy, Lawrence Berkeley Lab, which is supported by the U.S. Department of Energy under Contract # DE-AC02-05CH11231. NR 14 TC 0 Z9 0 U1 0 U2 33 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0167-577X EI 1873-4979 J9 MATER LETT JI Mater. Lett. PD NOV 1 PY 2014 VL 134 BP 126 EP 129 DI 10.1016/j.matlet.2014.07.066 PG 4 WC Materials Science, Multidisciplinary; Physics, Applied SC Materials Science; Physics GA AP7GE UT WOS:000342245000033 ER PT J AU Didomizio, R Huang, SY Dial, L Ilavsky, J Larsen, M AF Didomizio, Richard Huang, Shenyan Dial, Laura Ilavsky, Jan Larsen, Mike TI An Assessment of Milling Time on the Structure and Properties of a Nanostructured Ferritic Alloy (NFA) SO METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE LA English DT Article ID PARTICLE-SIZE DISTRIBUTIONS; STRENGTHENING MECHANISMS; TEMPERATURE-DEPENDENCE; STEELS; OXIDE; DISLOCATIONS; DEFORMATION; SCATTERING; HELIUM; CREEP AB The tensile properties of a 14 wt pct chromium nanostructured ferritic alloy (NFA) are assessed as a function of attrition time. Small angle X-ray scattering results show quantitatively that the number density of precipitated oxides increases as a function of milling time. This difference in oxide density alone is not enough to describe the tensile behavior of the NFA as a function of temperature. As a result, a previously proposed root mean square strengthening model is applied to the current study where direct dispersion strengthening, grain boundary strengthening, dislocation forest hardening, and matrix hardening are all considered. When an optimization routine is conducted, the fitting results suggest that the precipitated oxides are soft obstacles to dislocation motion. C1 [Didomizio, Richard; Huang, Shenyan; Dial, Laura; Larsen, Mike] GE Global Res, Niskayuna, NY 12309 USA. [Ilavsky, Jan] Argonne Natl Lab, Argonne, IL 60439 USA. RP Didomizio, R (reprint author), GE Global Res, Niskayuna, NY 12309 USA. EM didomizr@crd.ge.com RI Ilavsky, Jan/D-4521-2013 OI Ilavsky, Jan/0000-0003-1982-8900 FU Department of Energy [EE0003487]; agency of the United States Government; National Science Foundation/Department of Energy [NSF/CHE-0822838]; U.S. DoE [DE-AC02-06CH11357] FX This material is based upon work supported by the Department of Energy under Award Number EE0003487. This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes and legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. ChemMatCARS Sector 15 is principally supported by the National Science Foundation/Department of Energy under grant number NSF/CHE-0822838. Use of the Advanced Photon Source, an Office of Science User Facility operated for the U.S. Department of Energy (DoE) Office of Science by Argonne National Laboratory, was supported by the U.S. DoE under Contract No. DE-AC02-06CH11357. The authors greatly acknowledge Dr. Matthew Alinger, Dr. Ernie Hall, Dr. Yan Gao, Mr. Orrie Riccobono, Mr. Ian Spinelli, Mr. Tony Barbuto, Ms. Rebecca Casey, Mr. Mitchell Hammond, and Dr. Ning Zhou for their efforts and discussions. NR 29 TC 2 Z9 2 U1 0 U2 8 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1073-5623 EI 1543-1940 J9 METALL MATER TRANS A JI Metall. Mater. Trans. A-Phys. Metall. Mater. Sci. PD NOV PY 2014 VL 45A IS 12 BP 5409 EP 5418 DI 10.1007/s11661-014-2521-9 PG 10 WC Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Materials Science; Metallurgy & Metallurgical Engineering GA AQ0AI UT WOS:000342443200018 ER PT J AU Lentz, M Klaus, M Coelho, RS Schaefer, N Schmack, F Reimers, W Clausen, B AF Lentz, Martin Klaus, Manuela Coelho, Rodrigo S. Schaefer, Nobert Schmack, Florian Reimers, Walter Clausen, Bjorn TI Analysis of the Deformation Behavior of Magnesium-Rare Earth Alloys Mg-2 pct Mn-1 pct Rare Earth and Mg-5 pct Y-4 pct Rare Earth by In Situ Energy-Dispersive X-ray Synchrotron Diffraction and Elasto-Plastic Self-Consistent Modeling SO METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE LA English DT Article ID NEUTRON-DIFFRACTION; TENSILE DUCTILITY; TEXTURE; MECHANISMS; PLASTICITY; ELEMENTS; SLIP AB The deformation behavior of the Mg-RE alloys ME21 and WE54 was investigated. Although both alloys contain rare earth elements, which alter and weaken the texture, the flow curves of the alloys deviate significantly, especially in uniaxial compression test. Apart from the higher strength of the WE54 alloy, the compression flow curve does not exhibit the typical sigmoidal shape, which is associated with tension twinning. However, optical microscopy, X-ray texture measurements, and EBSD analysis reveal the activity of tension twinning. The combination of in situ energy-dispersive X-ray synchrotron diffraction and EPSC modeling was used to analyze these differences. The investigation reveals that twin propagation is decelerated in the WE54 alloy, which requires a change of the twinning scheme from the 'finite initial fraction' to the 'continuity' assumption. Furthermore, an enhanced activity of the aOE (c) c+a > pyramidal slip system was observed in case of the WE54 alloy. C1 [Lentz, Martin; Schmack, Florian; Reimers, Walter] Tech Univ Berlin, D-10587 Berlin, Germany. [Klaus, Manuela; Coelho, Rodrigo S.] Helmholtz Zentrum Berlin Mat & Energien, D-12489 Berlin, Germany. [Schaefer, Nobert] Helmholtz Zentrum Berlin Mat & Energien, D-14109 Berlin, Germany. [Clausen, Bjorn] Los Alamos Natl Lab, LANSCE LC, Los Alamos, NM 87545 USA. RP Lentz, M (reprint author), Tech Univ Berlin, Ernst Reuter Pl 1, D-10587 Berlin, Germany. EM martin.lentz@tu-berlin.de RI Clausen, Bjorn/B-3618-2015; OI Clausen, Bjorn/0000-0003-3906-846X; Lentz, Martin/0000-0001-8310-0063 FU Deutsche Forschungsgemeinschaft (DFG) [RE 688/67-1]; US Department of Energy Office of Basic Energy Science [FWP 06SCPE401] FX The authors M. Lentz and W. Reimers are grateful for the financial support of the Deutsche Forschungsgemeinschaft (DFG) under the Contract Number RE 688/67-1. B. Clausen acknowledges support from US Department of Energy Office of Basic Energy Science through Project FWP 06SCPE401. The authors would like to thank Dr. T. Link (TU Berlin, Metallische Werkstoffe) for his support of the TEM analysis. The authors thank Dipl.-Ing. Iryna Driehorst and Dipl.-Ing. Jorg Nissen (TU Berlin, ZELMI) for the realization of the SEM and EBSD analysis. The authors would like to thank Dr. C. N. Tome (Los Alamos National Laboratory, MST-8, NM, USA) for providing the EPSC 4 code and for helpful discussions. NR 28 TC 9 Z9 9 U1 3 U2 21 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1073-5623 EI 1543-1940 J9 METALL MATER TRANS A JI Metall. Mater. Trans. A-Phys. Metall. Mater. Sci. PD NOV PY 2014 VL 45A IS 12 BP 5721 EP 5735 DI 10.1007/s11661-014-2533-5 PG 15 WC Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Materials Science; Metallurgy & Metallurgical Engineering GA AQ0AI UT WOS:000342443200044 ER PT J AU Dias, FT Pinheiro, LBLG de Souz, GB Serbena, FC da Silva, SA Jurelo, AR Bud'ko, SL Thaler, A Canfield, PC AF Dias, Fabio T. Pinheiro, Lincoln B. L. G. de Souz, Gelson B. Serbena, Francisco C. da Silva, Simone A. Jurelo, Alcione R. Bud'ko, Sergey L. Thaler, Alex Canfield, Paul C. TI Nanoscratch and indentation fracture toughness in superconductor Ba-Fe-As single crystals with lamellar structure SO TRIBOLOGY INTERNATIONAL LA English DT Article DE Iron-based superconductor; Lamellar; Nanoscratch; Nanoindentation ID ORIENTED FESE0.5TE0.5 SUPERCONDUCTOR; INSTRUMENTED INDENTATION; LAYERED SUPERCONDUCTOR; MECHANICAL-PROPERTIES; FESEX SUPERCONDUCTOR; ELASTIC-MODULUS; HARDNESS AB Tribological aspects of Ba(Fe0.974Mn0.026)(2)As-2 single crystals were analyzed through nanoscratch tests and correlated with fracture toughness data. The similar to 100 mu m thick samples present oh-planes stacked by following the c-axis (lamellar structure). Scratch hardness (0.31 GPa for oh-plane and 2.10 GPa for a(b)c-plane) and wear rate are in accordance with previous results for indentation hardness. Microcracking rules the scratching behavior of both planes, the ab-one presenting a marked critical load for cracking that is loading-rate dependent. Fracture toughness, estimated by the minimum load for crack nucleation in indentation tests, was statistically similar, 1.8 +/- 0.9 MPa m(1/2) for the oh-plane and 1.5 +/- 0.5 MPa m(1/2) for the a(b)c-plane. Results lead to the conclusion that the lamellar structure determines the material tribo-mechanical behavior. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Dias, Fabio T.] Univ Fed Pelotas UFPEL, Dept Phys, BR-96010900 Pelotas, RS, Brazil. [Pinheiro, Lincoln B. L. G.; de Souz, Gelson B.; Serbena, Francisco C.; da Silva, Simone A.; Jurelo, Alcione R.] Univ Estadual Ponta Grossa, Dept Phys, BR-84030000 Ponta Grossa, PR, Brazil. [Bud'ko, Sergey L.; Thaler, Alex; Canfield, Paul C.] Iowa State Univ, Ames Lab, US DOE, Ames, IA 50011 USA. [Bud'ko, Sergey L.; Thaler, Alex; Canfield, Paul C.] Iowa State Univ, Dept Phys & Astron, Ames, IA 50011 USA. RP de Souz, GB (reprint author), Univ Estadual Ponta Grossa, Dept Phys, Av Gen Carlos Cavalcanti 4748, BR-84030000 Ponta Grossa, PR, Brazil. EM gelsonbs@uepg.br RI de Souza, Gelson/F-6002-2015; OI Thaler, Alexander/0000-0001-5066-8904 FU CNPq [474.077/2007-1, 472.746/2013-8] FX This work was partially financed by CNPq under Contracts nos. 474.077/2007-1 and 472.746/2013-8. The authors thank Prof. Dr. Carlos M. Lepienski for the use of the instrumented indentation facilities, the CME/UFPR and C-LABMU/UEPG for the use of research laboratory facilities. NR 24 TC 3 Z9 3 U1 3 U2 25 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0301-679X EI 1879-2464 J9 TRIBOL INT JI Tribol. Int. PD NOV PY 2014 VL 79 BP 84 EP 91 DI 10.1016/j.triboint.2014.05.026 PG 8 WC Engineering, Mechanical SC Engineering GA AP7PG UT WOS:000342268600010 ER PT J AU Cai, M Nonaka, A Bell, JB Griffith, BE Donev, A AF Cai, Mingchao Nonaka, Andy Bell, John B. Griffith, Boyce E. Donev, Aleksandar TI Efficient Variable-Coefficient Finite-Volume Stokes Solvers SO COMMUNICATIONS IN COMPUTATIONAL PHYSICS LA English DT Article DE Stokes flow; variable density; variable viscosity; saddle point problems; projection method; preconditioning; GMRES ID SADDLE-POINT PROBLEMS; ADAPTIVE PROJECTION METHOD; LINEAR-SYSTEMS; FLUCTUATING HYDRODYNAMICS; UNIFORM PRECONDITIONERS; INCOMPRESSIBLE-FLOW; EQUATIONS; VISCOSITY; ALGORITHM; ACCURATE AB We investigate several robust preconditioners for solving the saddle-point linear systems that arise from spatial discretization of unsteady and steady variable-coefficient Stokes equations on a uniform staggered grid. Building on the success of using the classical projection method as a preconditioner for the coupled velocity-pressure system [B. E. Griffith, J. Comp. Phys., 228 (2009), pp. 7565-7595], as well as established techniques for steady and unsteady Stokes flow in the finite-element literature, we construct preconditioners that employ independent generalized Helmholtz and Poisson solvers for the velocity and pressure subproblems. We demonstrate that only a single cycle of a standard geometric multigrid algorithm serves as an effective inexact solver for each of these subproblems. Contrary to traditional wisdom, we find that the Stokes problem can be solved nearly as efficiently as the independent pressure and velocity subproblems, making the overall cost of solving the Stokes system comparable to the cost of classical projection or fractional step methods for incompressible flow, even for steady flow and in the presence of large density and viscosity contrasts. Two of the five preconditioners considered here are found to be robust to GMRES restarts and to increasing problem size, making them suitable for large-scale problems. Our work opens many possibilities for constructing novel unsplit temporal integrators for finite-volume spatial discretizations of the equations of low Mach and incompressible flow dynamics. C1 [Cai, Mingchao; Griffith, Boyce E.; Donev, Aleksandar] NYU, Courant Inst Math Sci, New York, NY 10012 USA. [Nonaka, Andy; Bell, John B.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Ctr Computat Sci & Engn, Berkeley, CA 94720 USA. [Griffith, Boyce E.] NYU, Sch Med, Dept Med, Leon H Charney Div Cardiol, New York, NY 10003 USA. [Griffith, Boyce E.] Univ N Carolina, Dept Math, Chapel Hill, NC 27599 USA. RP Donev, A (reprint author), NYU, Courant Inst Math Sci, 251 Mercer St, New York, NY 10012 USA. EM cmchao2005@gmail.com; ajnonaka@lbl.gov; jbbel@lbl.gov; boyceg@mail.unc.edu; donev@courant.nyu.edu FU NSF [DMS-1115341]; DOE Office of Science [DE-SC0008271]; National Science Foundation [OCT 1047734, DMS 1016554]; DOE Applied Mathematics Program of the DOE Office of Advanced Scientific Computing Research under the U.S. Department of Energy [DE-AC02-05CH11231] FX We thank Howard Elman for informative discussions. A. Donev and M. Cai were supported in part by the NSF under grant DMS-1115341. Additional support for A. Donev was provided by the DOE Office of Science through Early Career award DE-SC0008271. B. E. Griffith acknowledges research support from the National Science Foundation under awards OCT 1047734 and DMS 1016554. J. Bell and A. Nonaka were supported by the DOE Applied Mathematics Program of the DOE Office of Advanced Scientific Computing Research under the U.S. Department of Energy under contract No. DE-AC02-05CH11231. NR 51 TC 8 Z9 8 U1 0 U2 3 PU GLOBAL SCIENCE PRESS PI WANCHAI PA ROOM 3208, CENTRAL PLAZA, 18 HARBOUR RD, WANCHAI, HONG KONG 00000, PEOPLES R CHINA SN 1815-2406 EI 1991-7120 J9 COMMUN COMPUT PHYS JI Commun. Comput. Phys. PD NOV PY 2014 VL 16 IS 5 BP 1263 EP 1297 DI 10.4208/cicp.070114.170614a PG 35 WC Physics, Mathematical SC Physics GA AP4XZ UT WOS:000342085000005 ER PT J AU Meng, D Zheng, B Lin, G Sushko, ML AF Meng, Da Zheng, Bin Lin, Guang Sushko, Maria L. TI Numerical Solution of 3D Poisson-Nernst-Planck Equations Coupled with Classical Density Functional Theory for Modeling Ion and Electron Transport in a Confined Environment SO COMMUNICATIONS IN COMPUTATIONAL PHYSICS LA English DT Article DE Poisson-Nernst-Planck equations; classical density functional theory; algebraic multigrid method; fast Fourier transform; Li-ion battery ID FUNDAMENTAL-MEASURE-THEORY; CHARGED HARD-SPHERES; FREE-ENERGY MODEL; I-V RELATIONS; RYANODINE RECEPTOR; LI+/ELECTRON CONDUCTIVITY; ASYMPTOTIC ANALYSIS; TIO2 NANOPARTICLES; DOUBLE-LAYERS; CHANNELS AB We have developed efficient numerical algorithms for solving 3D steady-state Poisson-Nernst-Planck (PNP) equations with excess chemical potentials described by the classical density functional theory (cDFT). The coupled PNP equations are discretized by a finite difference scheme and solved iteratively using the Gummel method with relaxation. The Nernst-Planck equations are transformed into Laplace equations through the Slotboom transformation. Then, the algebraic multigrid method is applied to efficiently solve the Poisson equation and the transformed Nernst-Planck equations. A novel strategy for calculating excess chemical potentials through fast Fourier transforms is proposed, which reduces computational complexity from O(N-2) to O(N log N), where N is the number of grid points. Integrals involving the Dirac delta function are evaluated directly by coordinate transformation, which yields more accurate results compared to applying numerical quadrature to an approximated delta function. Numerical results for ion and electron transport in solid electrolyte for lithium-ion (Li-ion) batteries are shown to be in good agreement with the experimental data and the results from previous studies. C1 [Meng, Da; Zheng, Bin; Lin, Guang; Sushko, Maria L.] Pacific NW Natl Lab, Richland, WA 99352 USA. [Lin, Guang] Purdue Univ, Sch Mech Engn, Dept Math, W Lafayette, IN 47907 USA. RP Sushko, ML (reprint author), Pacific NW Natl Lab, Richland, WA 99352 USA. EM da.meng@pnnl.gov; bin.zheng@pnnl.gov; Guanglin@purdue.edu; Maria.Sushko@pnnl.gov RI Sushko, Maria/C-8285-2014 OI Sushko, Maria/0000-0002-7229-7072 FU Materials Synthesis and Simulation across Scales (MS3) Initiative (Laboratory Directed Research and Development (LDRD) Program) at Pacific Northwest National Laboratory (PNNL); U.S. Department of Energy (DOE) Office of Science's Advanced Scientific Computing Research Applied Mathematics program; Early Career Award Initiative (LDRD Program) at PNNL; DOE [DE-AC05-76RL01830] FX Work by MLS and DM was supported by the Materials Synthesis and Simulation across Scales (MS3) Initiative (Laboratory Directed Research and Development (LDRD) Program) at Pacific Northwest National Laboratory (PNNL). Work by GL was supported by the U.S. Department of Energy (DOE) Office of Science's Advanced Scientific Computing Research Applied Mathematics program and work by BZ by Early Career Award Initiative (LDRD Program) at PNNL. PNNL is operated by Battelle for the DOE under Contract DE-AC05-76RL01830. The research was performed using PNNL Institutional Computing, as well as the National Energy Research Scientific Computing Center at Lawrence Berkeley National Laboratory. NR 75 TC 8 Z9 8 U1 0 U2 25 PU GLOBAL SCIENCE PRESS PI WANCHAI PA ROOM 3208, CENTRAL PLAZA, 18 HARBOUR RD, WANCHAI, HONG KONG 00000, PEOPLES R CHINA SN 1815-2406 EI 1991-7120 J9 COMMUN COMPUT PHYS JI Commun. Comput. Phys. PD NOV PY 2014 VL 16 IS 5 BP 1298 EP 1322 DI 10.4208/cicp.040913.120514a PG 25 WC Physics, Mathematical SC Physics GA AP4XZ UT WOS:000342085000006 ER PT J AU Xu, W Sun, X Koeppel, BJ Zbib, HM AF Xu, Wei Sun, Xin Koeppel, Brian J. Zbib, Hussein M. TI A continuum thermo-inelastic model for damage and healing in self-healing glass materials SO INTERNATIONAL JOURNAL OF PLASTICITY LA English DT Article DE Thermomechanical processes; Constitutive behavior; Glass material; Viscoelastic material; Self-healing ID OXIDE FUEL-CELLS; CRACK-GROWTH; FABRIC TENSORS; DUCTILE DAMAGE; THERMOMECHANICAL BEHAVIOR; AMORPHOUS MATERIALS; BOROSILICATE GLASS; BRITTLE MATERIALS; ASPHALT CONCRETE; FINITE-ELEMENTS AB Self-healing glass, a recent advancement in the class of smart sealing materials, has attracted great attention from both research and industrial communities because of its unique capability of repairing itself at elevated temperatures. However, further development and optimization of this material rely on a more fundamental and thorough understanding of its essential thermo-mechanical response characteristics, which is also pivotal in predicting the coupling and interactions between the nonlinear stress and temperature dependent damage and healing behaviors. In the current study, a continuum three-dimensional thermo-inelastic damage-healing constitutive framework has been developed for the compliant self-healing glass material with different damage mechanisms, i.e. micro-cracks and micro-pores, taken into account. The important feature of the present model is that different physically-driven evolution kinetics have been unified to represent the distinct inelastic, damage, and healing behaviors associated with the mechanical degradation processes. Coupled with the micro-crack and micro-void models reported in the literature, a continuum description of the healing behavior has been established based on the lower-length scale kinetic Monte Carlo simulations to characterize the local thermal-diffusional bond re-formation process across the fracture interface. The proposed formulations are implemented into finite element analyses and the effects of various loading conditions and material properties on the material's mechanical resistance are investigated. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Xu, Wei; Sun, Xin; Koeppel, Brian J.] Pacific NW Natl Lab, Richland, WA 99354 USA. [Zbib, Hussein M.] Washington State Univ, Sch Mech & Mat Engn, Pullman, WA 99164 USA. RP Xu, W (reprint author), Pacific NW Natl Lab, Richland, WA 99354 USA. EM wei.xu@pnnl.gov FU Solid-State-Energy Conversion Alliance Core Technology Program by the U.S. Department of Energy's (DOE) National Energy Technology Laboratory; DOE [DE-ACO5-76RL01830] FX The work presented in the paper was funded as part of the Solid-State-Energy Conversion Alliance Core Technology Program by the U.S. Department of Energy's (DOE) National Energy Technology Laboratory. Pacific Northwest National Laboratory is operated by Battelle for DOE under Contract DE-ACO5-76RL01830. NR 84 TC 2 Z9 2 U1 7 U2 77 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0749-6419 EI 1879-2154 J9 INT J PLASTICITY JI Int. J. Plast. PD NOV PY 2014 VL 62 BP 1 EP 16 DI 10.1016/j.ijplas.2014.06.011 PG 16 WC Engineering, Mechanical; Materials Science, Multidisciplinary; Mechanics SC Engineering; Materials Science; Mechanics GA AP7JO UT WOS:000342253800001 ER PT J AU Bertin, N Tome, CN Beyerlein, IJ Barnett, MR Capolungo, L AF Bertin, N. Tome, C. N. Beyerlein, I. J. Barnett, M. R. Capolungo, L. TI On the strength of dislocation interactions and their effect on latent hardening in pure Magnesium SO INTERNATIONAL JOURNAL OF PLASTICITY LA English DT Article DE Dislocations; Constitutive behaviour ID SLIP SYSTEMS INTERACTIONS; CLOSE-PACKED METALS; CRYSTAL PLASTICITY; DYNAMICS SIMULATIONS; CONSTITUTIVE MODEL; SINGLE-CRYSTALS; DEFORMATION; MECHANISMS; TEMPERATURE; EVOLUTION AB This study is dedicated to the quantification of latent hardening and its effect on the plasticity of pure hexagonal magnesium. To this end, discrete dislocation dynamics simulations are used to (1) extract latent hardening parameters coupling different slip systems, and to (2) assess the validity of two existing constitutive models linking slip system strength to dislocation densities on all slip systems. As hexagonal materials deform via activation of different slip modes, each with different mobilities and lattice friction stress, the effects of the latter on latent hardening evolution are also investigated. It is found that the multi-slip formulation proposed by Franciosi and Zaoui gives accurate predictions when multiple interactions are involved while the formulation suggested by Lavrentev and Pokhil systematically overestimates the flow stress. Similar to FCC materials, it is also found that collinear interactions potentially contribute the most to latent hardening. Basal/pyramidal < c + a > interactions are found to be very strong, while interactions involving second-order pyramidal < c + a > primary dislocations appear to be the weakest ones. Finally, the latent hardening parameters, extracted from the discrete dislocation dynamics simulations, are used in polycrystal simulations and the impact of finely accounting for latent hardening on predictions of the macroscopic anisotropic response is shown to be of significant importance. (C) 2014 Published by Elsevier Ltd. C1 [Bertin, N.; Capolungo, L.] Georgia Inst Technol, George W Woodruff Sch Mech Engn, UMI Georgia Tech CNRS 2958, F-57070 Metz, France. [Tome, C. N.] Los Alamos Natl Lab, MST Div, Los Alamos, NM 87545 USA. [Beyerlein, I. J.] Los Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USA. [Barnett, M. R.] Deakin Univ, Inst Frontier Mat, Geelong, Vic 3217, Australia. RP Capolungo, L (reprint author), Georgia Inst Technol, George W Woodruff Sch Mech Engn, UMI Georgia Tech CNRS 2958, F-57070 Metz, France. EM laurent.capolungo@me.gatech.edu RI Tome, Carlos/D-5058-2013; Beyerlein, Irene/A-4676-2011 FU Office of Basic Energy Sciences [FWP 06SCPE401]; French National Research Agency (ANR) [MAGTWIN ANR-12-BS09-0010-02] FX IJB and CNT acknowledge full support by Office of Basic Energy Sciences (Project FWP 06SCPE401). NB and LC acknowledge partial support, and also wish to thank the French National Research Agency (ANR) (Project MAGTWIN ANR-12-BS09-0010-02). MB would like to acknowledge the Deakin University Academic Studies Program, the ARC Future Fellowship scheme and the "Chercheur d'Excellence" scheme of the Lorraine-Champagne Region. NR 54 TC 31 Z9 31 U1 4 U2 54 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0749-6419 EI 1879-2154 J9 INT J PLASTICITY JI Int. J. Plast. PD NOV PY 2014 VL 62 BP 72 EP 92 DI 10.1016/j.ijplas.2014.06.010 PG 21 WC Engineering, Mechanical; Materials Science, Multidisciplinary; Mechanics SC Engineering; Materials Science; Mechanics GA AP7JO UT WOS:000342253800005 ER PT J AU Knezevic, M Beyerlein, IJ Lovato, ML Tome, CN Richards, AW McCabe, RJ AF Knezevic, Marko Beyerlein, Irene J. Lovato, Manuel L. Tome, Carlos N. Richards, Andrew W. McCabe, Rodney J. TI A strain-rate and temperature dependent constitutive model for BCC metals incorporating non-Schmid effects: Application to tantalum-tungsten alloys SO INTERNATIONAL JOURNAL OF PLASTICITY LA English DT Article DE Microstructures; Non-Schmid effects; Constitutive behaviour; Polycrystalline material; Electron microscopy ID CRYSTAL PLASTICITY MODELS; HIGH-PURITY TANTALUM; SINGLE-CRYSTALS; TEXTURE EVOLUTION; POLYCRYSTAL PLASTICITY; MECHANICAL RESPONSE; SCREW DISLOCATIONS; PATH CHANGES; ANNEALED TANTALUM; RATE DEFORMATION AB In this work, we present a multiscale physically based constitutive law for predicting the mechanical response and texture evolution of body-centered cubic (BCC) metals as a function of strain-rate and temperature. In the model, deformation of individual single crystals results not only from the resolved shear stress along the direction of slip (Schmid law) but also from shear stresses resolved along directions orthogonal to the slip direction as well as the three normal stress components (non-Schmid effects). We account for coupled Schmid and non-Schmid effects through the modification of the resolved shear stress for both 1/2 < 1(1) over bar 1 >{110} and 1/2 < 11(1) over bar >{112} slip systems and the modification of the slip resistance for 1/2 < 11(1) over bar >{112} slip systems. The single crystal model is implemented into a self-consistent homogenization scheme containing a hardening law for crystallographic slip. The hardening law is based on the evolution of dislocation densities that incorporates strain-rate and temperature effects through the Peierls stress, thermally activated recovery, dislocation substructure formation and dislocation interactions. The polycrystal model is calibrated and validated using a set of mechanical and texture data collected on a tantalum-tungsten alloy, Ta-10W, at temperatures ranging from 298 K to 673 K and strain-rates from 10(-3) s(-1) to 2400 s(-1). We show the model effectively captures the anisotropic hardening rate and texture evolution for all data using a single set of single-crystal hardening parameters. Comparisons between predictions and measured data allow us to discuss the role of slip on {110} and {112} in determining plasticity and texture evolution in Ta-10W. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Knezevic, Marko] Univ New Hampshire, Dept Mech Engn, Durham, NH 03824 USA. [Beyerlein, Irene J.] Los Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USA. [Lovato, Manuel L.; Tome, Carlos N.; Richards, Andrew W.; McCabe, Rodney J.] Los Alamos Natl Lab, Mat Sci & Technol Div, Los Alamos, NM 87545 USA. RP Knezevic, M (reprint author), Univ New Hampshire, Dept Mech Engn, 33 Acad Way,Kingsbury Hall,W119, Durham, NH 03824 USA. EM marko.knezevic@unh.edu RI Tome, Carlos/D-5058-2013; Beyerlein, Irene/A-4676-2011; OI McCabe, Rodney /0000-0002-6684-7410 FU U.S. Department of Energy [DE-AC52-06NA25396]; Los Alamos National Laboratory [236698-1] FX The work was supported by the U.S. Department of Energy under Contract No. DE-AC52-06NA25396. MK acknowledges subcontract, NO. 236698-1, granted by Los Alamos National Laboratory to the University of New Hampshire. NR 76 TC 33 Z9 33 U1 9 U2 55 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0749-6419 EI 1879-2154 J9 INT J PLASTICITY JI Int. J. Plast. PD NOV PY 2014 VL 62 BP 93 EP 104 DI 10.1016/j.ijplas.2014.07.007 PG 12 WC Engineering, Mechanical; Materials Science, Multidisciplinary; Mechanics SC Engineering; Materials Science; Mechanics GA AP7JO UT WOS:000342253800006 ER PT J AU Wu, W Qiao, H An, K Guo, XQ Wu, PD Liaw, PK AF Wu, Wei Qiao, Hua An, Ke Guo, Xiaoqian Wu, Peidong Liaw, Peter K. TI Investigation of deformation dynamics in a wrought magnesium alloy SO INTERNATIONAL JOURNAL OF PLASTICITY LA English DT Article DE Dynamics; Twinning; Crystal plasticity; Metallic material; Neutron diffraction ID SITU NEUTRON-DIFFRACTION; STRAIN-PATH CHANGES; TWINNING-DETWINNING BEHAVIOR; TEXTURE EVOLUTION; INTERNAL STRAIN; MECHANICAL-PROPERTIES; PLASTIC-DEFORMATION; INELASTIC BEHAVIOR; STRESS-RELAXATION; FATIGUE BEHAVIOR AB In the present research, the real-time in-situ neutron diffraction measurements under a continuous-loading condition and elastic-viscoplastic self-consistent (EVPSC) polycrystal modeling were employed to study the deformation dynamics and the effect of the deformation history on plastic deformation in a wrought magnesium alloy. The experimental results reveal that pre-deformation delays the activation of the tensile twinning during the subsequent compression, mainly resulting from the residual strains. Detwinning does not occur until the applied stress exceeds the tensile yield strength during the reverse loading. It is believed that the grain rotation plays an important role in the elastic region during the reverse loading. The EVPSC model, which has been recently updated by implementing the twinning and detwinning model, was employed to characterize the deformation mechanism during the strain-path changes. The simulation result predicts well the experimental observation from the real-time in-situ neutron diffraction measurements. The present study provides a new insight of the nature of deformation mechanisms in a hexagonal close-packed (HCP) structured polycrystalline wrought magnesium alloy, which has significant implications for future work on studying the deformation mechanisms of HCP-structured materials. Published by Elsevier Ltd. C1 [Wu, Wei; Liaw, Peter K.] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA. [Wu, Wei; An, Ke] Oak Ridge Natl Lab, Chem & Engn Mat Div, Oak Ridge, TN 37831 USA. [Qiao, Hua; Guo, Xiaoqian; Wu, Peidong] McMaster Univ, Dept Mech Engn, Hamilton, ON L8S 4L7, Canada. [Guo, Xiaoqian] China Univ Min & Technol, State Key Lab Geomech & Deep Underground Engn, Xuzhou 221116, Jiangsu, Peoples R China. RP An, K (reprint author), Oak Ridge Natl Lab, Chem & Engn Mat Div, 1 Bethel Valley Rd, Oak Ridge, TN 37831 USA. EM kean@ornl.gov; pliaw@utk.edu RI An, Ke/G-5226-2011; Wu, Wei/G-3204-2014; Wu, Peidong/A-7009-2008 OI An, Ke/0000-0002-6093-429X; Wu, Wei/0000-0002-8596-9253; FU Scientific User Facilities Division, Office of Basic Energy Sciences, Department of Energy (DOE); Columbus McKinnon Corporation; Laboratory Directed Research and Development (LDRD) project of ORNL; Natural Sciences and Engineering Research Council of Canada (NSERC); China Scholarship Council [201206420031]; State Key Development Program for Basic Research of China [2013CB227900]; US National Science Foundation [DMR-0909037, CMMI-0900271, CMMI-1100080]; DOE, Office of Fossil Energy, National Energy Technology Laboratory [DE-FE-0008855, DE-FE-001194] FX The research conducted at SNS, ORNL was sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, Department of Energy (DOE). The authors appreciate beamline scientists and staff at the VULCAN Engineering Diffractometer, SNS, ORNL for their kind help. WW is grateful for the financial support from Columbus McKinnon Corporation and a Laboratory Directed Research and Development (LDRD) project of ORNL. HQ and PDW thank the support provided by the Natural Sciences and Engineering Research Council of Canada (NSERC). XQG was supported by the China Scholarship Council (No. 201206420031) and the State Key Development Program for Basic Research of China (Grant No. 2013CB227900). PKL very much appreciates the financial support from the US National Science Foundation (DMR-0909037, CMMI-0900271, and CMMI-1100080) with C. Huber, C.V. Cooper, D. Finotello, A. Ardell, and E. Taleff as contract monitors, and DOE, Office of Fossil Energy, National Energy Technology Laboratory (DE-FE-0008855 and DE-FE-001194), with Mr. V. Cedro and S. Markovich as program managers. NR 79 TC 23 Z9 23 U1 9 U2 56 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0749-6419 EI 1879-2154 J9 INT J PLASTICITY JI Int. J. Plast. PD NOV PY 2014 VL 62 BP 105 EP 120 DI 10.1016/j.ijplas.2014.07.005 PG 16 WC Engineering, Mechanical; Materials Science, Multidisciplinary; Mechanics SC Engineering; Materials Science; Mechanics GA AP7JO UT WOS:000342253800007 ER PT J AU Olson, GL AF Olson, Gordon L. TI Gray radiation transport models for two-dimensional binary stochastic media with material temperature coupling using spherical harmonics SO JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER LA English DT Article DE Stochastic media; Radiation transport; Gray transport; Spherical harmonics ID GREY; EQUATIONS AB Due to the high computational cost of time-dependent radiation transport calculations, most multi-dimensional simulations of stochastic media have used the lowest angle order approximation, the Pi approximation. Here spherical harmonics of order n=5 are used to solve the transport equation in two-dimensional binary stochastic media. The results are consistent with earlier Pi simulations. Transport solutions using constant and temperature-dependent opacities and heat capacities are shown and analyzed. The standard closure poorly approximates the mean radiation field in these test problems. For one physical case, a less common closure is better. To best fit the most general cases, a new procedure is presented. In all cases, the approximate transport solutions work best in dilute systems where one material comprises less than about 10% of the total. The conclusions reached here should be independent of the transport solution method whether one uses spherical harmonics or discrete ordinates. Published by Elsevier Ltd. C1 Los Alamos Natl Lab, Comp & Computat Sci Div CCS 2, Madison, WI 53717 USA. RP Olson, GL (reprint author), Los Alamos Natl Lab, Comp & Computat Sci Div CCS 2, 5 Foxglove Circle, Madison, WI 53717 USA. EM olson99gl@gmail.com NR 14 TC 2 Z9 2 U1 2 U2 2 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0022-4073 EI 1879-1352 J9 J QUANT SPECTROSC RA JI J. Quant. Spectrosc. Radiat. Transf. PD NOV PY 2014 VL 148 BP 127 EP 133 DI 10.1016/j.jqsrt.2014.07.002 PG 7 WC Optics; Spectroscopy SC Optics; Spectroscopy GA AP7JR UT WOS:000342254100015 ER PT J AU Jin, HE Farr, R Lee, SW AF Jin, Hyo-Eon Farr, Rebecca Lee, Seung-Wuk TI Collagen mimetic peptide engineered M13 bacteriophage for collagen targeting and imaging in cancer SO BIOMATERIALS LA English DT Article DE Collagen; Bacteriophage; Cancer; Targeting; Imaging ID I COLLAGEN; MATRIX METALLOPROTEINASES; MAMMOGRAPHIC DENSITIES; FILAMENTOUS PHAGE; BREAST-CANCER; TRIPLE-HELIX; PROGRESSION; BINDING; VIVO; STREPTAVIDIN AB Collagens are over-expressed in various human cancers and subsequently degraded and denatured by proteolytic enzymes, thus making them a target for diagnostics and therapeutics. Genetically engineered bacteriophage (phage) is a promising candidate for the development of imaging or therapeutic materials for cancer collagen targeting due to its promising structural features. We genetically engineered M13 phages with two functional peptides, collagen mimetic peptide and streptavidin binding peptide, on their minor and major coat proteins, respectively. The resulting engineered phage functions as a therapeutic or imaging material to target degraded and denatured collagens in cancerous tissues. We demonstrated that the engineered phages are able to target and label abnormal collagens expressed on A549 human lung adenocarcinoma cells after the conjugation with streptavidin-linked fluorescent agents. Our engineered collagen binding phage could be a useful platform for abnormal collagen imaging and drug delivery in various collagen-related diseases. Published by Elsevier Ltd. C1 [Jin, Hyo-Eon; Farr, Rebecca; Lee, Seung-Wuk] Univ Calif Berkeley, Dept Bioengn, Berkeley, CA 94720 USA. [Jin, Hyo-Eon; Farr, Rebecca; Lee, Seung-Wuk] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Phys Biosci Div, Berkeley, CA 94720 USA. RP Lee, SW (reprint author), Univ Calif Berkeley, Dept Bioengn, Berkeley, CA 94720 USA. EM leesw@berkeley.edu FU Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology [NRF-2011-357-E00083] FX H.E.J. was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (NRF-2011-357-E00083). NR 64 TC 11 Z9 12 U1 7 U2 54 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0142-9612 EI 1878-5905 J9 BIOMATERIALS JI Biomaterials PD NOV PY 2014 VL 35 IS 33 BP 9236 EP 9245 DI 10.1016/j.biomaterials.2014.07.044 PG 10 WC Engineering, Biomedical; Materials Science, Biomaterials SC Engineering; Materials Science GA AO9KK UT WOS:000341674400020 PM 25115789 ER PT J AU Jahed, Z Molladavoodi, S Seo, BB Gorbet, M Tsui, TY Mofrad, MRK AF Jahed, Zeinab Molladavoodi, Sara Seo, Brandon B. Gorbet, Maud Tsui, Ting Y. Mofrad, Mohammad R. K. TI Cell responses to metallic nanostructure arrays with complex geometries SO BIOMATERIALS LA English DT Article DE Nanopillar; Nanotopography sensing; Cell adhesion; Mechanotransduction ID SILICON NANOWIRES; LIVING CELLS; FORCE; FILOPODIA; CIRCUITS; PLATFORM AB Metallic nanopillar/nanowires are emerging as promising platforms for biological applications, as they allow for the direct characterization and regulation of cell function. Herein we study the response of cells to a versatile nanopillar platform. Nanopillar arrays of various shape, size, and spacing and different nanopillar-substrate interfacial strengths were fabricated and interfaced with fibroblasts and several unique cell-nanopillar interactions were observed using high resolution scanning electron microscopy. Nanopillar penetration, engulfment, tilting, lift off and membrane thinning, were observed by manipulating nanopillar material, size, shape and spacing. These unique cell responses to various nanostructures can be employed for a wide range of applications including the design of highly sensitive nano-electrodes for single-cell probing. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Jahed, Zeinab; Mofrad, Mohammad R. K.] Univ Calif Berkeley, Dept Bioengn & Mech Engn, Mol Cell Biomech Lab, Berkeley, CA 94720 USA. [Molladavoodi, Sara; Seo, Brandon B.; Tsui, Ting Y.] Univ Waterloo, Dept Mech & Mech Engn, Waterloo, ON N2L 3G1, Canada. [Gorbet, Maud] Univ Waterloo, Dept Syst Design Engn, Waterloo, ON N2L 3G1, Canada. [Tsui, Ting Y.] Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada. [Mofrad, Mohammad R. K.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Phys Biosci Div, Berkeley, CA 94720 USA. RP Mofrad, MRK (reprint author), Univ Calif Berkeley, Dept Bioengn & Mech Engn, 208A Stanley Hall, Berkeley, CA 94720 USA. EM tttsui@uwaterloo.ca; mofrad@berkeley.edu FU Natural Sciences and Engineering Council of Canada, NSERC [RGPIN-355552]; National Science Foundation via the CAREER award [CBET-0955291] FX The authors would like to thank the Natural Sciences and Engineering Council of Canada, NSERC for their support of this research project through Discovery and RTI grants (RGPIN-355552) as well as Graduate Fellowships to ZJ. In addition, financial support through National Science Foundation via the CAREER award (CBET-0955291) is gratefully acknowledged. The authors gratefully acknowledge critical support and infrastructure provided for this work by the Emerging Communications Technology Institute at the University of Toronto. Fruitful discussions with Kiavash Garakani and other members of the Molecular Cell Biomechanics Lab at the University of California Berkeley are gratefully acknowledged. NR 26 TC 9 Z9 9 U1 3 U2 53 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0142-9612 EI 1878-5905 J9 BIOMATERIALS JI Biomaterials PD NOV PY 2014 VL 35 IS 34 BP 9363 EP 9371 DI 10.1016/j.biomaterials.2014.07.022 PG 9 WC Engineering, Biomedical; Materials Science, Biomaterials SC Engineering; Materials Science GA AP2KO UT WOS:000341901300012 PM 25123921 ER PT J AU Sun, ZY Li, L Fernandez, M Wang, JH AF Sun, Zeyi Li, Lin Fernandez, Mayela Wang, Jianhui TI Inventory control for peak electricity demand reduction of manufacturing systems considering the tradeoff between production loss and energy savings SO JOURNAL OF CLEANER PRODUCTION LA English DT Article DE Inventory control; Peak electricity demand; Electricity load management; Tradeoff between production loss and energy savings AB The effective reduction of the electricity consumption during peak periods plays a critical role in reducing the cost and improving the reliability of the operation of power grid. The unbalanced situation between the supply and the demand of the electricity during peak periods can be relieved. The need for installing and running some peaking power plants and associated power delivery infrastructure can be partially avoided. This paper proposes an analytical model focusing on the electricity load management aiming at reducing the electricity consumption during peak periods by buffer inventory control for the typical manufacturing systems with multiple machines and buffers. Compared with the previous research that is strictly under the constraint of the throughput of manufacturing systems, this research is advanced by considering the tradeoff between the penalty due to production loss and the benefit resulted from energy savings, and thus more load management options are available. The optimal load management actions and corresponding buffer inventory control policies for the whole system are identified by minimizing the summation of the buffer inventory holding cost, electricity consumption cost, and potential production loss penalty throughout the production horizon. A numerical case study based on an automotive assembly line is used to illustrate the effectiveness of the proposed method. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Sun, Zeyi; Li, Lin; Fernandez, Mayela] Univ Illinois, Dept Mech & Ind Engn, Chicago, IL 60607 USA. [Wang, Jianhui] Argonne Natl Lab, Decis & Informat Sci Div, Ctr Energy Environm & Econ Syst Anal, Argonne, IL 60439 USA. RP Li, L (reprint author), Univ Illinois, Dept Mech & Ind Engn, 842 W Taylor St,ERF 3057, Chicago, IL 60607 USA. EM linli@uic.edu OI sun, zeyi/0000-0003-0704-2708 NR 31 TC 8 Z9 8 U1 0 U2 17 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0959-6526 EI 1879-1786 J9 J CLEAN PROD JI J. Clean Prod. PD NOV 1 PY 2014 VL 82 BP 84 EP 93 DI 10.1016/j.jclepro.2014.06.071 PG 10 WC GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY; Engineering, Environmental; Environmental Sciences SC Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology GA AO6OK UT WOS:000341471200008 ER PT J AU Yue, YF Guo, BK Qiao, ZA Fulvio, PF Chen, JH Binder, AJ Tian, CC Dai, S AF Yue, Yanfeng Guo, Bingkun Qiao, Zhen-An Fulvio, Pasquale F. Chen, Jihua Binder, Andrew J. Tian, Chengcheng Dai, Sheng TI Multi-wall carbon nanotube@zeolite imidazolate framework composite from a nanoscale zinc oxide precursor SO MICROPOROUS AND MESOPOROUS MATERIALS LA English DT Article DE Zeolitic imidazolate frameworks; Carbon nanotubes; ZnO nanoparticles; Lithium-sulfur (Li-S) batteries ID LITHIUM-SULFUR BATTERIES; METAL-ORGANIC FRAMEWORKS; CATHODE MATERIALS; SHELL; ADSORPTION; SOLVENT; AMMONIA; ENERGY; FILMS AB Nanocomposite of multi-walled carbon nanotube@zeolite imidazolate frameworks (MWNT@ZIF) was prepared through a nanotube-facilitated growth based on a nanosized ZnO precursor. The electrically conductive nanocomposite displays a capacity of 380 mAh/g at 0.1 degrees C in Li-sulfur battery, transforming electrically inactive ZIF into the active one for battery applications. (C) 2014 Elsevier Inc. All rights reserved. C1 [Yue, Yanfeng; Guo, Bingkun; Qiao, Zhen-An; Fulvio, Pasquale F.; Dai, Sheng] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA. [Chen, Jihua] Oak Ridge Natl Lab, Div Mat Sci, Ctr Nanophase, Oak Ridge, TN 37831 USA. [Binder, Andrew J.; Tian, Chengcheng; Dai, Sheng] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA. [Fulvio, Pasquale F.] Univ Puerto Rico, Dept Chem, San Juan, PR 00931 USA. RP Fulvio, PF (reprint author), Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA. EM fulviopf@ornl.gov; dais@ornl.gov RI Chen, Jihua/F-1417-2011; Guo, Bingkun/J-5774-2014; Dai, Sheng/K-8411-2015; OI Chen, Jihua/0000-0001-6879-5936; Dai, Sheng/0000-0002-8046-3931; Qiao, Zhen-An/0000-0001-6064-9360 FU U.S. Department of Energy's Office of Basic Energy Science, Division of Materials Sciences and Engineering; Oak Ridge National Laboratory by the Division of Scientific User Facilities, Office of Basic Energy Sciences, U.S. Department of Energy FX This research was supported by the U.S. Department of Energy's Office of Basic Energy Science, Division of Materials Sciences and Engineering. A portion of this research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Division of Scientific User Facilities, Office of Basic Energy Sciences, U.S. Department of Energy. NR 47 TC 9 Z9 9 U1 11 U2 184 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 1387-1811 EI 1873-3093 J9 MICROPOR MESOPOR MAT JI Microporous Mesoporous Mat. PD NOV 1 PY 2014 VL 198 BP 139 EP 143 DI 10.1016/j.micromeso.2014.07.026 PG 5 WC Chemistry, Applied; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary SC Chemistry; Science & Technology - Other Topics; Materials Science GA AP2JW UT WOS:000341899500018 ER PT J AU Mullen, MR Spirig, JV Hoy, J Routbort, JL Singh, D Dutta, PK AF Mullen, Max R. Spirig, John V. Hoy, Julia Routbort, Jules L. Singh, Dileep Dutta, Prabir K. TI Development of nanosized lanthanum strontium aluminum manganite as electrodes for potentiometric oxygen sensor SO SENSORS AND ACTUATORS B-CHEMICAL LA English DT Article DE Electrochemical sensor; Oxygen; Potentiometric; YSZ; LSM; High temperature ID YTTRIA-STABILIZED ZIRCONIA; ELECTRICAL-CONDUCTIVITY; INTERNAL REFERENCE; TETRAGONAL ZIRCONIA; CATHODE MATERIALS; PLASTIC-FLOW; CERAMICS; OXIDE; DEFORMATION; TZP AB Nanocrystalline La0.8Sr0.2Al0.9Mn0.1O3 (LSAM) was synthesized by a microwave-assisted citrate method, and characterized by electron microscopy and X-ray diffraction. Electrical behavior of LSAM was investigated by impedance spectroscopy and activation energy of conduction was obtained. Joining of sintered bodies of LSAM and yttria-stabilized tetragonal zirconia polycrystals (YTZP), an extensively studied oxygen ion conducting electrolyte, was examined by isostatic hot pressing methods. Characteristics of the joining region were evaluated with microprobe Raman spectroscopy, and products formed at the interface, primarily strontium zirconate, was confirmed by examination of high temperature chemical reaction between LSAM and YTZP powders. The electrical properties of the LSAM were exploited for development of a high temperature oxygen sensor in which LSAM functioned as the electrode and YTZP as electrolyte. (C) 2014 Elsevier B.V. All rights reserved. C1 [Mullen, Max R.; Spirig, John V.; Hoy, Julia; Dutta, Prabir K.] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA. [Routbort, Jules L.; Singh, Dileep] Argonne Natl Lab, Argonne, IL 60439 USA. RP Dutta, PK (reprint author), Ohio State Univ, Dept Chem, 100 West 18th Ave, Columbus, OH 43210 USA. EM dutta@chemistry.ohio-state.edu FU National Science Foundation [NSF-PFI 1318136] FX The authors would like to express their gratitude to the National Science Foundation (NSF-PFI 1318136) for support of this research. NR 31 TC 1 Z9 1 U1 4 U2 28 PU ELSEVIER SCIENCE SA PI LAUSANNE PA PO BOX 564, 1001 LAUSANNE, SWITZERLAND SN 0925-4005 J9 SENSOR ACTUAT B-CHEM JI Sens. Actuator B-Chem. PD NOV PY 2014 VL 203 BP 670 EP 676 DI 10.1016/j.snb.2014.07.027 PG 7 WC Chemistry, Analytical; Electrochemistry; Instruments & Instrumentation SC Chemistry; Electrochemistry; Instruments & Instrumentation GA AO6JB UT WOS:000341455400088 ER PT J AU Aab, A Abreu, P Aglietta, M Ahlers, M Ahn, EJ Albuquerque, IFM Allekotte, I Allen, J Allison, P Almela, A Castillo, JA Alvarez-Muniz, J Batista, RA Ambrosio, M Aminaei, A Anchordoqui, L Andringa, S Antictic, T Aramo, C Arqueros, F Asorey, H Assis, P Aublin, J Ave, M Avenier, M Avila, G Badescu, AM Barber, KB Bardenet, R Bauml, J Baus, C Beatty, JJ Becker, KH Bellido, JA BenZvi, S Berat, C Bertou, X Biermann, PL Billoir, P Blanco, F Blanco, M Bleve, C Blumer, H Bohacova, M Boncioli, D Bonifazi, C Bonino, R Borodai, N Brack, J Brancus, I Brogueira, P Brown, WC Buchholz, P Bueno, A Buscemi, M Caballero-Mora, KS Caccianiga, B Caccianiga, L Candusso, M Caramete, L Caruso, R Castellina, A Cataldi, G Cazon, L Cester, R Cheng, SH Chiavassa, A Chinellato, JA Chudoba, J Cilmo, M Clay, RW Cocciolo, G Colalillo, R Collica, L Coluccia, MR Conceicao, R Contreras, F Cooper, MJ Coutu, S Covault, CE Criss, A Cronin, J Curutiu, A Dallier, R Daniel, B Dasso, S Daumiller, K Dawson, BR De Almeida, RM De Domenico, M de Jong, SJ De La Vega, G de Mello, WJM Neto, JRTD De Mitri, I de Souza, V de Vries, KD del Peral, L Deligny, O Dembinski, H Dhital, N Di Giulio, C Di Matteo, A Diaz, JC Castro, MLD Diep, PN Diogo, F Dobrigkeit, C Docters, W D'Olivo, JC Dong, PN Dorofeev, A dos Anjos, JC Dova, MT Ebr, J Engel, R Erdmann, M Escobar, CO Espadanal, J Etchegoyen, A Luis, PFS Falcke, H Fang, K Farrar, G Fauth, AC Fazzini, N Ferguson, AP Fick, B Figueira, JM Filevich, A Filipcic, A Foerster, N Fox, BD Fracchiolla, CE Fraenkel, ED Fratu, O Frohlich, U Fuchs, B Gaior, R Gamarra, RF Gambetta, S Garcia, B Roca, STG Garcia-Gamez, D Garcia-Pinto, D Garilli, G Bravo, AG Gemmeke, H Ghia, PL Giammarchi, M Giller, M Gitto, J Glaser, C Glass, H Albarracin, FG Berisso, MG Vitale, PFG Goncalves, P Gonzalez, JG Gookin, B Gorgi, A Gorham, P Gouffon, P Grebe, S Griffith, N Grillo, AF Grubb, TD Guardincerri, Y Guarino, F Guedes, GP Hansen, P Harari, D Harrison, TA Harton, JL Haungs, A Hebbeker, T Heck, D Herve, AE Hill, GC Hojvat, C Hollon, N Holt, E Homola, P Horandel, JR Horvath, P Hrabovsky, M Huber, D Huege, T Insolia, A Isar, PG Jansen, S Jarne, C Josebachuili, M Kadija, K Kambeitz, O Kampert, KH Karhan, P Kasper, P Katkov, I Kegl, B Keilhauer, B Keivani, A Kemp, E Kieckhafer, RM Klages, HO Kleifges, M Kleinfeller, J Knapp, J Krause, R Krohm, N Kromer, O Kruppke-Hansen, D Kuempel, D Kunka, N La Rosa, G LaHurd, D Latronico, L Lauer, R Lauscher, M Lautridou, P Le Coz, S Leao, MSAB Lebrun, D Lebrun, P de Oliveira, MAL Letessier-Selvon, A Lhenry-Yvon, I Link, K Lopez, R Aguera, AL Louedec, K Bahilo, JL Lu, L Lucero, A Ludwig, M Lyberis, H Maccarone, MC Malacari, M Maldera, S Mailer, J Mandat, D Mantsch, P Mariazzi, AG Marin, V Maris, IC Falcon, HRM Marsella, G Martello, D Martin, L Martinez, H Bravo, OM Martraire, D Meza, JJM Mathes, HJ Matthews, J Matthews, JIG Matthiae, G Maurel, D Maurizio, D Mayotte, E Mazur, PO Medina, C Medina-Tanco, G Melissas, M Melo, D Menichetti, E Menshikov, A Messina, S Meyhandan, R Micanovic, S Micheletti, MI Middendorf, L Minaya, IA Miramonti, L Mitrica, B Molina-Bueno, L Mollerach, S Monasor, M Ragaigne, DM Montanet, F Morales, B Morello, C Moreno, JC Mostafa, M Moura, CA Muller, MA Muller, G Munchmeyer, M Mussa, R Navarra, G Navarro, JL Navas, S Necesal, P Nellen, L Nelles, A Neuser, J Nhung, PT Niechciol, M Niemietz, L Niggemann, T Nitz, D Nosek, D Nozka, L Oehlschlager, J Olinto, A Oliveira, M Ortiz, M Pacheco, N Selmi-Dei, DP Palatka, M Pallotta, J Palmieri, N Parente, G Parra, A Pastor, S Paul, T Pech, M Kala, JP Pelayo, R Pepe, IM Perrone, L Pesce, R Petermann, E Petrera, S Petrolini, A Petrov, Y Piegaia, R Pierog, T Pieroni, P Pimenta, M Pirronello, V Platino, M Plum, M Pontz, M Porcelli, A Preda, T Privitera, P Prouza, M Quel, EJ Querchfeld, S Quinn, S Rautenberg, J Ravel, O Ravignani, D Revenu, B Ridky, J Riggi, S Risse, M Ristori, P Rivera, H Rizi, V Roberts, J de Carvalho, WR Cabo, IR Fernandez, GR Martino, JR Rojo, JR Rodriguez-Frias, MD Ros, G Rosado, J Rossler, T Roth, M Rouille-d'Orfeuil, B Roulet, E Rovero, AC Ruhle, C Saffi, SJ Saftoiu, A Salamida, F Salazar, H Greus, FS Salina, G Sanchez, F Sanchez-Lucas, P Santo, CE Santos, E Santos, EM Sarazin, F Sarkar, B Sarmento, R Sato, R Scharf, N Scherini, V Schieler, H Schiffer, P Schmidt, A Scholten, O Schoorlemmer, H Schovanek, P Schroder, FG Schulz, A Schulz, J Sciutto, SJ Scuderi, M Segreto, A Settimo, M Shadkam, A Shellard, RC Sidelnik, I Sigl, G Sima, O Smialkowski, A Smida, R Snow, GR Sommers, P Sorokin, J Spinka, H Squartini, R Srivastava, YN Stanic, S Stapleton, J Stasielak, J Stephan, M Straub, M Stutz, A Suarez, F Suomijarvi, T Supanitsky, AD Susa, T Sutherland, MS Swain, J Szadkowski, Z Szuba, M Tapia, A Tartare, M Tascau, O Thao, NT Tiffenberg, J Timmermans, C Tkaczyk, W Peixoto, CJT Toma, G Tomankova, L Tome, B Tonachini, A Elipe, GT Machado, DT Travnicek, P Tridapalli, DB Trovato, E Tueros, M Ulrich, R Unger, M Galicia, JFV Valino, I Valore, L van Aar, G van den Berg, AM van Velzen, S van Vliet, A Varela, E Cardenas, BV Varner, G Vazquez, JR Vazquez, RA Veberic, D Verzi, V Vicha, J Videla, M Villasenor, L Wahlberg, H Wahrlich, P Wainberem, O Walz, D Watson, AA Weber, M Weidenhaupt, K Weindl, A Werner, F Westerhoff, S Whelan, BJ Widom, A Wieczorek, G Wiencke, L Wilczynska, B Wilczynski, H Will, M Williams, C Winchen, T Wundheiler, B Wykes, S Yamamoto, T Yapici, T Younk, P Yuan, G Yushkov, A Zamorano, B Zas, E Zavrtanik, D Zavrtanik, M Zaw, I Zepeda, A Zhou, J Zhu, Y Silva, MZ Ziolkowski, M Curci, G AF Aab, A. Abreu, P. Aglietta, M. Ahlers, M. Ahn, E. J. Albuquerque, I. F. M. Allekotte, I. Allen, J. Allison, P. Almela, A. Castillo, J. Alvarez Alvarez-Muniz, J. Batista, R. Alves Ambrosio, M. Aminaei, A. Anchordoqui, L. Andringa, S. Antictic, T. Aramo, C. Arqueros, F. Asorey, H. Assis, P. Aublin, J. Ave, M. Avenier, M. Avila, G. Badescu, A. M. Barber, K. B. Bardenet, R. Baeuml, J. Baus, C. Beatty, J. J. Becker, K. H. Bellido, J. A. BenZvi, S. Berat, C. Bertou, X. Biermann, P. L. Billoir, P. Blanco, F. Blanco, M. Bleve, C. Bluemer, H. Bohacova, M. Boncioli, D. Bonifazi, C. Bonino, R. Borodai, N. Brack, J. Brancus, I. Brogueira, P. Brown, W. C. Buchholz, P. Bueno, A. Buscemi, M. Caballero-Mora, K. S. Caccianiga, B. Caccianiga, L. Candusso, M. Caramete, L. Caruso, R. Castellina, A. Cataldi, G. Cazon, L. Cester, R. Cheng, S. H. Chiavassa, A. Chinellato, J. A. Chudoba, J. Cilmo, M. Clay, R. W. Cocciolo, G. Colalillo, R. Collica, L. Coluccia, M. R. Conceicao, R. Contreras, F. Cooper, M. J. Coutu, S. Covault, C. E. Criss, A. Cronin, J. Curutiu, A. Dallier, R. Daniel, B. Dasso, S. Daumiller, K. Dawson, B. R. De Almeida, R. M. De Domenico, M. de Jong, S. J. De La Vega, G. de Mello, W. J. M., Jr. de Mello Neto, J. R. T. De Mitri, I. de Souza, V. de Vries, K. D. del Peral, L. Deligny, O. Dembinski, H. Dhital, N. Di Giulio, C. Di Matteo, A. Diaz, J. C. Castro, M. L. Diaz Diep, P. N. Diogo, F. Dobrigkeit, C. Docters, W. D'Olivo, J. C. Dong, P. N. Dorofeev, A. dos Anjos, J. C. Dova, M. T. Ebr, J. Engel, R. Erdmann, M. Escobar, C. O. Espadanal, J. Etchegoyen, A. Luis, P. Facal San Falcke, H. Fang, K. Farrar, G. Fauth, A. C. Fazzini, N. Ferguson, A. P. Fick, B. Figueira, J. M. Filevich, A. Filipcic, A. Foerster, N. Fox, B. D. Fracchiolla, C. E. Fraenkel, E. D. Fratu, O. Froehlich, U. Fuchs, B. Gaior, R. Gamarra, R. F. Gambetta, S. Garcia, B. Roca, S. T. Garcia Garcia-Gamez, D. Garcia-Pinto, D. Garilli, G. Bravo, A. Gascon Gemmeke, H. Ghia, P. L. Giammarchi, M. Giller, M. Gitto, J. Glaser, C. Glass, H. Albarracin, F. Gomez Berisso, M. Gomez Vitale, P. F. Gomez Goncalves, P. Gonzalez, J. G. Gookin, B. Gorgi, A. Gorham, P. Gouffon, P. Grebe, S. Griffith, N. Grillo, A. F. Grubb, T. D. Guardincerri, Y. Guarino, F. Guedes, G. P. Hansen, P. Harari, D. Harrison, T. A. Harton, J. L. Haungs, A. Hebbeker, T. Heck, D. Herve, A. E. Hill, G. C. Hojvat, C. Hollon, N. Holt, E. Homola, P. Horandel, J. R. Horvath, P. Hrabovsky, M. Huber, D. Huege, T. Insolia, A. Isar, P. G. Jansen, S. Jarne, C. Josebachuili, M. Kadija, K. Kambeitz, O. Kampert, K. H. Karhan, P. Kasper, P. Katkov, I. Kegl, B. Keilhauer, B. Keivani, A. Kemp, E. Kieckhafer, R. M. Klages, H. O. Kleifges, M. Kleinfeller, J. Knapp, J. Krause, R. Krohm, N. Kroemer, O. Kruppke-Hansen, D. Kuempel, D. Kunka, N. La Rosa, G. LaHurd, D. Latronico, L. Lauer, R. Lauscher, M. Lautridou, P. Le Coz, S. Leao, M. S. A. B. Lebrun, D. Lebrun, P. de Oliveira, M. A. Leigui Letessier-Selvon, A. Lhenry-Yvon, I. Link, K. Lopez, R. Aguera, A. Lopez Louedec, K. Bahilo, J. Lozano Lu, L. Lucero, A. Ludwig, M. Lyberis, H. Maccarone, M. C. Malacari, M. Maldera, S. Mailer, J. Mandat, D. Mantsch, P. Mariazzi, A. G. Marin, V. Maris, I. C. Falcon, H. R. Marquez Marsella, G. Martello, D. Martin, L. Martinez, H. Bravo, O. Martinez Martraire, D. Meza, J. J. Masias Mathes, H. J. Matthews, J. Matthews, J. I. G. Matthiae, G. Maurel, D. Maurizio, D. Mayotte, E. Mazur, P. O. Medina, C. Medina-Tanco, G. Melissas, M. Melo, D. Menichetti, E. Menshikov, A. Messina, S. Meyhandan, R. Micanovic, S. Micheletti, M. I. Middendorf, L. Minaya, I. A. Miramonti, L. Mitrica, B. Molina-Bueno, L. Mollerach, S. Monasor, M. Ragaigne, D. Monnier Montanet, F. Morales, B. Morello, C. Moreno, J. C. Mostafa, M. Moura, C. A. Muller, M. A. Mueller, G. Munchmeyer, M. Mussa, R. Navarra, G. Navarro, J. L. Navas, S. Necesal, P. Nellen, L. Nelles, A. Neuser, J. Nhung, P. T. Niechciol, M. Niemietz, L. Niggemann, T. Nitz, D. Nosek, D. Nozka, L. Oehlschlaeger, J. Olinto, A. Oliveira, M. Ortiz, M. Pacheco, N. Selmi-Dei, D. Pakk Palatka, M. Pallotta, J. Palmieri, N. Parente, G. Parra, A. Pastor, S. Paul, T. Pech, M. Kala, J. P. Pelayo, R. Pepe, I. M. Perrone, L. Pesce, R. Petermann, E. Petrera, S. Petrolini, A. Petrov, Y. Piegaia, R. Pierog, T. Pieroni, P. Pimenta, M. Pirronello, V. Platino, M. Plum, M. Pontz, M. Porcelli, A. Preda, T. Privitera, P. Prouza, M. Quel, E. J. Querchfeld, S. Quinn, S. Rautenberg, J. Ravel, O. Ravignani, D. Revenu, B. Ridky, J. Riggi, S. Risse, M. Ristori, P. Rivera, H. Rizi, V. Roberts, J. de Carvalho, W. Rodrigues Cabo, I. Rodriguez Fernandez, G. Rodriguez Martino, J. Rodriguez Rojo, J. Rodriguez Rodriguez-Frias, M. D. Ros, G. Rosado, J. Rossler, T. Roth, M. Rouille-d'Orfeuil, B. Roulet, E. Rovero, A. C. Ruehle, C. Saffi, S. J. Saftoiu, A. Salamida, F. Salazar, H. Greus, F. Salesa Salina, G. Sanchez, F. Sanchez-Lucas, P. Santo, C. E. Santos, E. Santos, E. M. Sarazin, F. Sarkar, B. Sarmento, R. Sato, R. Scharf, N. Scherini, V. Schieler, H. Schiffer, P. Schmidt, A. Scholten, O. Schoorlemmer, H. Schovanek, P. Schroeder, F. G. Schulz, A. Schulz, J. Sciutto, S. J. Scuderi, M. Segreto, A. Settimo, M. Shadkam, A. Shellard, R. C. Sidelnik, I. Sigl, G. Sima, O. Smialkowski, A. Smida, R. Snow, G. R. Sommers, P. Sorokin, J. Spinka, H. Squartini, R. Srivastava, Y. N. Stanic, S. Stapleton, J. Stasielak, J. Stephan, M. Straub, M. Stutz, A. Suarez, F. Suomijarvi, T. Supanitsky, A. D. Susa, T. Sutherland, M. S. Swain, J. Szadkowski, Z. Szuba, M. Tapia, A. Tartare, M. Tascau, O. Thao, N. T. Tiffenberg, J. Timmermans, C. Tkaczyk, W. Peixoto, C. J. Todero Toma, G. Tomankova, L. Tome, B. Tonachini, A. Elipe, G. Torralba Machado, D. Torres Travnicek, P. Tridapalli, D. B. Trovato, E. Tueros, M. Ulrich, R. Unger, M. Galicia, J. F. Valdes Valino, I. Valore, L. van Aar, G. van den Berg, A. M. van Velzen, S. van Vliet, A. Varela, E. Cardenas, B. Vargas Varner, G. Vazquez, J. R. Vazquez, R. A. Veberic, D. Verzi, V. Vicha, J. Videla, M. Villasenor, L. Wahlberg, H. Wahrlich, P. Wainberem, O. Walz, D. Watson, A. A. Weber, M. Weidenhaupt, K. Weindl, A. Werner, F. Westerhoff, S. Whelan, B. J. Widom, A. Wieczorek, G. Wiencke, L. Wilczynska, B. Wilczynski, H. Will, M. Williams, C. Winchen, T. Wundheiler, B. Wykes, S. Yamamoto, T. Yapici, T. Younk, P. Yuan, G. Yushkov, A. Zamorano, B. Zas, E. Zavrtanik, D. Zavrtanik, M. Zaw, I. Zepeda, A. Zhou, J. Zhu, Y. Silva, M. Zimbres Ziolkowski, M. Curci, G. CA Pierre Auger Collaborat TI Origin of atmospheric aerosols at the Pierre Auger Observatory using studies of air mass trajectories in South America SO ATMOSPHERIC RESEARCH LA English DT Article DE Cosmic ray; Aerosol; Air masses; Atmospheric effect; HYSPLIT; GDAS ID CONCENTRATION DISTRIBUTIONS; OPTICAL DEPTH; TRANSPORT; SYSTEM; CHILE AB The Pierre Auger Observatory is making significant contributions towards understanding the nature and origin of ultra-high energy cosmic rays. One of its main challenges is the monitoring of the atmosphere, both in terms of its state variables and its optical properties. The aim of this work is to analyse aerosol optical depth tau(a)(z) values measured from 2004 to 2012 at the observatory, which is located in a remote and relatively unstudied area of Pampa Amarilla, Argentina. The aerosol optical depth is in average quite low - annual mean tau(a)(3.5 km) similar to 0.04 - and shows a seasonal trend with a winter minimum - tau(a)(3.5 km) - 0.03 -, and a summer maximum - tau(a)(3.5 km) similar to 0.06 -, and an unexpected increase from August to September tau(a)(35 km) similar to 0.055. We computed backward trajectories for the years 2005 to 2012 to interpret the air mass origin. Winter nights with low aerosol concentrations show air masses originating from the Pacific Ocean. 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RI Pastor, Sergio/J-6902-2014; Badescu, Alina/B-6087-2012; Torralba Elipe, Guillermo/A-9524-2015; Chinellato, Jose Augusto/I-7972-2012; Pech, Miroslav/G-5760-2014; Albuquerque, Ivone/H-4645-2012; Parente, Gonzalo/G-8264-2015; Caramete, Laurentiu/C-2328-2011; Alves Batista, Rafael/K-6642-2012; Horvath, Pavel/G-6334-2014; Sima, Octavian/C-3565-2011; dos Santos, Eva/N-6351-2013; Alvarez-Muniz, Jaime/H-1857-2015; de souza, Vitor/D-1381-2012; Rosado, Jaime/K-9109-2014; Valino, Ines/J-8324-2012; Garcia Pinto, Diego/J-6724-2014; Navas, Sergio/N-4649-2014; Espadanal, Joao/I-6618-2015; Di Giulio, Claudio/B-3319-2015; Vazquez, Jose Ramon/K-2272-2015; Insolia, Antonio/M-3447-2015; Ros, German/L-4764-2014; Petrolini, Alessandro/H-3782-2011; de Mello Neto, Joao/C-5822-2013; Brogueira, Pedro/K-3868-2012; scuderi, mario/O-7019-2014; zas, enrique/I-5556-2015; Chinellato, Carola Dobrigkeit /F-2540-2011; Curci, Gabriele/A-2020-2011; Arqueros, Fernando/K-9460-2014; Moura Santos, Edivaldo/K-5313-2016; Gouffon, Philippe/I-4549-2012; de Almeida, Rogerio/L-4584-2016; Fauth, Anderson/F-9570-2012; De Domenico, Manlio/B-5826-2014; Todero Peixoto, Carlos Jose/G-3873-2012; Abreu, Pedro/L-2220-2014; Sao Carlos Institute of Physics, IFSC/USP/M-2664-2016; Assis, Pedro/D-9062-2013; Blanco, Francisco/F-1131-2015; Cazon, Lorenzo/G-6921-2014; Conceicao, Ruben/L-2971-2014; Bueno, Antonio/F-3875-2015; Beatty, James/D-9310-2011; Guarino, Fausto/I-3166-2012; Colalillo, Roberta/R-5088-2016; Buscemi, Mario/R-5071-2016; Bonino, Raffaella/S-2367-2016; Rodriguez Frias, Maria /A-7608-2015; Inst. of Physics, Gleb Wataghin/A-9780-2017; De Mitri, Ivan/C-1728-2017; Mitrica, Bogdan/D-5201-2009; Rodriguez Fernandez, Gonzalo/C-1432-2014; Nosek, Dalibor/F-1129-2017; Lozano Bahilo, Julio/F-4881-2016; Pimenta, Mario/M-1741-2013; Ridky, Jan/H-6184-2014; Martello, Daniele/J-3131-2012; OI Torralba Elipe, Guillermo/0000-0001-8738-194X; Chinellato, Jose Augusto/0000-0002-3240-6270; Albuquerque, Ivone/0000-0001-7328-0136; Parente, Gonzalo/0000-0003-2847-0461; Alves Batista, Rafael/0000-0003-2656-064X; Horvath, Pavel/0000-0002-6710-5339; dos Santos, Eva/0000-0002-0474-8863; Alvarez-Muniz, Jaime/0000-0002-2367-0803; Rosado, Jaime/0000-0001-8208-9480; Valino, Ines/0000-0001-7823-0154; Garcia Pinto, Diego/0000-0003-1348-6735; Navas, Sergio/0000-0003-1688-5758; Espadanal, Joao/0000-0002-1301-8061; Di Giulio, Claudio/0000-0002-0597-4547; Vazquez, Jose Ramon/0000-0001-9217-5219; Insolia, Antonio/0000-0002-9040-1566; Ros, German/0000-0001-6623-1483; Petrolini, Alessandro/0000-0003-0222-7594; de Mello Neto, Joao/0000-0002-3234-6634; Brogueira, Pedro/0000-0001-6069-4073; scuderi, mario/0000-0001-9026-5317; zas, enrique/0000-0002-4430-8117; Chinellato, Carola Dobrigkeit /0000-0002-1236-0789; Curci, Gabriele/0000-0001-9871-5570; Arqueros, Fernando/0000-0002-4930-9282; Moura Santos, Edivaldo/0000-0002-2818-8813; Gouffon, Philippe/0000-0001-7511-4115; de Almeida, Rogerio/0000-0003-3104-2724; Fauth, Anderson/0000-0001-7239-0288; De Domenico, Manlio/0000-0001-5158-8594; Todero Peixoto, Carlos Jose/0000-0003-3669-8212; Abreu, Pedro/0000-0002-9973-7314; Assis, Pedro/0000-0001-7765-3606; Blanco, Francisco/0000-0003-4332-434X; Cazon, Lorenzo/0000-0001-6748-8395; Conceicao, Ruben/0000-0003-4945-5340; Bueno, Antonio/0000-0002-7439-4247; Beatty, James/0000-0003-0481-4952; Guarino, Fausto/0000-0003-1427-9885; Colalillo, Roberta/0000-0002-4179-9352; Buscemi, Mario/0000-0003-2123-5434; Rodriguez Frias, Maria /0000-0002-2550-4462; De Mitri, Ivan/0000-0002-8665-1730; Rodriguez Fernandez, Gonzalo/0000-0002-4683-230X; Nosek, Dalibor/0000-0001-6219-200X; Asorey, Hernan/0000-0002-4559-8785; de Jong, Sijbrand/0000-0002-3120-3367; Sigl, Guenter/0000-0002-4396-645X; Cataldi, Gabriella/0000-0001-8066-7718; La Rosa, Giovanni/0000-0002-3931-2269; Navarro Quirante, Jose Luis/0000-0002-9915-1735; Lozano Bahilo, Julio/0000-0003-0613-140X; Pimenta, Mario/0000-0002-2590-0908; Mantsch, Paul/0000-0002-8382-7745; Salamida, Francesco/0000-0002-9306-8447; Ridky, Jan/0000-0001-6697-1393; Segreto, Alberto/0000-0001-7341-6603; Aglietta, Marco/0000-0001-8354-5388; Maccarone, Maria Concetta/0000-0001-8722-0361; Kothandan, Divay/0000-0001-9048-7518; Castellina, Antonella/0000-0002-0045-2467; maldera, simone/0000-0002-0698-4421; Yuan, Guofeng/0000-0002-1907-8815; Sarmento, Raul/0000-0002-5018-5467; Aramo, Carla/0000-0002-8412-3846; Knapp, Johannes/0000-0003-1519-1383; Martello, Daniele/0000-0003-2046-3910; Petrera, Sergio/0000-0002-6029-1255; Mussa, Roberto/0000-0002-0294-9071; Ulrich, Ralf/0000-0002-2535-402X; Garcia, Beatriz/0000-0003-0919-2734; Dembinski, Hans/0000-0003-3337-3850; Del Peral, Luis/0000-0003-2580-5668; Coutu, Stephane/0000-0003-2923-2246; Rizi, Vincenzo/0000-0002-5277-6527; Ravignani, Diego/0000-0001-7410-8522; Matthews, James/0000-0002-1832-4420; Marsella, Giovanni/0000-0002-3152-8874; Bonino, Raffaella/0000-0002-4264-1215 FU Italian Space Agency (ASI); Comision Nacional de Energia Atomica; Gobierno de Argentina, Fundacion Antorchas; Gobierno De La Provincia de Mendoza; Municipalidad de Malargile; NDM Holdings and Valle Las Lenas; Australian Research Council; Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq); Financiadora de Estudos e Projetos (FINEP); Fundacao de Amparo a Pesquisa do Estado de Rio de Janeiro (FAPERJ); Sao Paulo Research Foundation (FAPFSP) [2010/07359-6, 1999/05404-3]; Ministerio de Ciencia e Tecnologia (MCT), Brazil; AVCR, Czech Republic; MSMT-CR, Czech Republic [LG13007, 7AMB12AR013, MSM0021620859]; TACR, Czech Republic [TA01010517]; Centre de Calcul [IN2P3/CNRS]; Centre National de la Recherche Scientifique (CNRS); Conseil Regional Ile-de-France; Departement Physique Nucleaire et Corpusculaire [PNC-IN2P3/CNRS]; Departement Sciences de l'Univers (SDU-INSU/CNRS), France; Bundesministerium fur Bildung und Forschung (BMBF); Deutsche Forschungsgemeinschaft (DFG); Finanzministerium Baden-Wurttemberg; Helmholtz-Gemeinschaft Deutscher Forschungszentren (HGF); Ministerium fur Wissenschaft und Forschung; Nordrhein-Westfalen; Ministerium fur Wissenschaft, Forschung und Kunst, Baden-Wurttemberg, Germany; Istituto Nazionale di Fisica Nucleare (INFN); Ministero dell'Istruzione, dell'Universita e della Ricerca (MIUR); Gran Sasso Center for Astroparticle Physics (CFA); CETEMPS Center of Excellence, Italy; Consejo Nacional de Ciencia y Tecnologia (CONACYT), Mexico; Ministerie van Onderwijs, Cultuur en Wetenschap; Nederlandse Organisatie voor Wetenschappelijk Onderzoek (NWO); Stichting voor Fundamenteel Onderzoek der Materie (FOM), Netherlands; Ministry of Science and Higher Education [N N202 200239, N N202 207238]; National Centre for Research and Development, Poland [ERA-NET-ASPERA/02/11]; Portuguese national funds; FEDER funds within COMPETE Programa Operacional Factores de Competitividade through Fundacao para a Ciencia e a Tecnologia, Portugal; Romanian Authority for Scientific Research ANCS; CNDI-UEFISCDI partnership projects, Romania [20/2012, 194/2012, 1/ASPERA2/2012 ERA-NET, PN-II-RU-PD-2011-3-0145-17, PN-II-RU-PD-2011-3-0062]; Ministry for Higher Education, Science, and Technology; Slovenian Research Agency, Slovenia; Comunidad de Madrid; FEDER funds; Ministerio de Ciencia e Innovacion and Consolider-Ingenio; Xunta de Galicia, Spain;; Leverhulme Foundation, Science and Technology Facilities Council, United Kingdom; Department of Energy [DE-AC02-07CH11359, DE-FR02-04ER41300, DE-FG02-99ER41107]; National Science Foundation [0450696, 0855680, 1207605]; Grainger Foundation USA; NAFOSTED, Vietnam; Marie Curie-IRSES/EPLANET; European Particle Physics Latin American Network; European Union [PIRSES-2009-GA-246806]; UNESCO FX The successful installation, commissioning, and operation of the Pierre Auger Observatory would not have been possible without the strong commitment and effort from the technical and administrative staff in Malargile. G. Curci was supported by the Italian Space Agency (ASI) in the frame of PRIMES project.; We are very grateful to the following agencies and organizations for financial support: Comision Nacional de Energia Atomica, Gobierno de Argentina, Fundacion Antorchas, Gobierno De La Provincia de Mendoza, Municipalidad de Malargile, NDM Holdings and Valle Las Lenas, in gratitude for their continuing cooperation over land access, Argentina; the Australian Research Council; Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq), Financiadora de Estudos e Projetos (FINEP), Fundacao de Amparo a Pesquisa do Estado de Rio de Janeiro (FAPERJ), Sao Paulo Research Foundation (FAPFSP) Grants #2010/07359-6, #1999/05404-3, Ministerio de Ciencia e Tecnologia (MCT), Brazil; AVCR, MSMT-CR LG13007, 7AMB12AR013, MSM0021620859, and TACR TA01010517, Czech Republic; Centre de Calcul IN2P3/CNRS, Centre National de la Recherche Scientifique (CNRS), Conseil Regional Ile-de-France, Departement Physique Nucleaire et Corpusculaire (PNC-IN2P3/CNRS), Departement Sciences de l'Univers (SDU-INSU/CNRS), France; Bundesministerium fur Bildung und Forschung (BMBF), Deutsche Forschungsgemeinschaft (DFG), Finanzministerium Baden-Wurttemberg, Helmholtz-Gemeinschaft Deutscher Forschungszentren (HGF), Ministerium fur Wissenschaft und Forschung, Nordrhein-Westfalen, Ministerium fur Wissenschaft, Forschung und Kunst, Baden-Wurttemberg, Germany; Istituto Nazionale di Fisica Nucleare (INFN), Ministero dell'Istruzione, dell'Universita e della Ricerca (MIUR), Gran Sasso Center for Astroparticle Physics (CFA), CETEMPS Center of Excellence, Italy; Consejo Nacional de Ciencia y Tecnologia (CONACYT), Mexico; Ministerie van Onderwijs, Cultuur en Wetenschap, Nederlandse Organisatie voor Wetenschappelijk Onderzoek (NWO), Stichting voor Fundamenteel Onderzoek der Materie (FOM), Netherlands; Ministry of Science and Higher Education, Grant Nos. N N202 200239 and N N202 207238, The National Centre for Research and Development Grant No ERA-NET-ASPERA/02/11, Poland; Portuguese national funds and FEDER funds within COMPETE Programa Operacional Factores de Competitividade through Fundacao para a Ciencia e a Tecnologia, Portugal; Romanian Authority for Scientific Research ANCS, CNDI-UEFISCDI partnership projects nr.20/2012 and nr.194/2012, project nr.1/ASPERA2/2012 ERA-NET, PN-II-RU-PD-2011-3-0145-17, and PN-II-RU-PD-2011-3-0062, Romania; Ministry for Higher Education, Science, and Technology, Slovenian Research Agency, Slovenia; Comunidad de Madrid, FEDER funds, Ministerio de Ciencia e Innovacion and Consolider-Ingenio 2010 (CPAN), Xunta de Galicia, Spain; The Leverhulme Foundation, Science and Technology Facilities Council, United Kingdom; Department of Energy, Contract Nos. DE-AC02-07CH11359, DE-FR02-04ER41300, DE-FG02-99ER41107, National Science Foundation, Grant No. 0450696, 0855680, 1207605, The Grainger Foundation USA; NAFOSTED, Vietnam; Marie Curie-IRSES/EPLANET, European Particle Physics Latin American Network, European Union 7th Framework Program, Grant No. PIRSES-2009-GA-246806; and UNESCO. NR 34 TC 1 Z9 1 U1 2 U2 73 PU ELSEVIER SCIENCE INC PI NEW YORK PA 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA SN 0169-8095 EI 1873-2895 J9 ATMOS RES JI Atmos. Res. PD NOV PY 2014 VL 149 BP 120 EP 135 DI 10.1016/j.atmosres.2014.05.021 PG 16 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA AO6NF UT WOS:000341468100011 ER PT J AU Banuelos, JL Feng, G Fulvio, PF Li, S Rother, G Arend, N Faraone, A Dai, S Cummings, PT Wesolowski, DJ AF Banuelos, Jose Leobardo Feng, Guang Fulvio, Pasquale F. Li, Song Rother, Gernot Arend, Nikolas Faraone, Antonio Dai, Sheng Cummings, Peter T. Wesolowski, David J. TI The influence of a hierarchical porous carbon network on the coherent dynamics of a nanoconfined room temperature ionic liquid: A neutron spin echo and atomistic simulation investigation SO CARBON LA English DT Article ID ALKYL CHAIN-LENGTH; X-RAY-SCATTERING; MOLECULAR-DYNAMICS; STRUCTURAL-PROPERTIES; ELECTROCHEMICAL CAPACITORS; NITROGEN ADSORPTION; MESOPOROUS CARBONS; DOUBLE-LAYER; IMIDAZOLIUM; HETEROGENEITY AB The molecular-scale dynamic properties of the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, or [C(4)mim(+)][Tf2N-], confined in hierarchical microporous-mesoporous carbon, were investigated using neutron spin echo (NSE) and molecular dynamics (MD) simulations. Both NSE and MD reveal pronounced slowing of the overall collective dynamics, including the presence of an immobilized fraction of RTIL at the pore wall, on the time scales of these approaches. A fraction of the dynamics, corresponding to RTIL inside 0.75 nm micropores located along the mesopore surfaces, are faster than those of RTIL in direct contact with the walls of 5.8 nm and 7.8 nm cylindrical mesopores. This behavior is ascribed to the near-surface confined-ion density fluctuations resulting from the ion-ion and ion-wall interactions between the micropores and mesopores as well as their confinement geometries. Strong micropore-RTIL interactions result in less-coordinated RTIL within the micropores than in the bulk fluid. Increasing temperature from 296 K to 353 K reduces the immobilized RTIL fraction and results in nearly an order of magnitude increase in the RTIL dynamics. The observed interfacial phenomena underscore the importance of tailoring the surface properties of porous carbons to achieve desirable electrolyte dynamic behavior, since this impacts the performance in applications such as electrical energy storage devices. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Banuelos, Jose Leobardo; Fulvio, Pasquale F.; Rother, Gernot; Dai, Sheng; Wesolowski, David J.] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA. [Feng, Guang; Li, Song; Cummings, Peter T.] Vanderbilt Univ, Dept Chem & Biomol Engn, Nashville, TN 37235 USA. [Arend, Nikolas] Julich Ctr Neutron Sci JCNS, Outstn Spallat Neutron Source SNS, Oak Ridge, TN 37831 USA. [Faraone, Antonio] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Faraone, Antonio] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. RP Feng, G (reprint author), Vanderbilt Univ, Dept Chem & Biomol Engn, Nashville, TN 37235 USA. EM banuelosjl@ornl.gov; gfeng@hust.edu.cn RI Rother, Gernot/B-7281-2008; Dai, Sheng/K-8411-2015; Feng, Guang/D-8989-2011; Banuelos, Jose/L-1561-2013; OI Rother, Gernot/0000-0003-4921-6294; Dai, Sheng/0000-0002-8046-3931; Banuelos, Jose/0000-0003-4644-526X; Feng, Guang/0000-0001-6659-9181 FU Fluid Interface Reactions, Structures and Transport (FIRST) Center, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences; Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy; National Science Foundation [DMR-0944772] FX This work was supported as part of the Fluid Interface Reactions, Structures and Transport (FIRST) Center, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. The SNS NSE portion and bulk liquid diffraction portion of this research conducted at Oak Ridge National Laboratory's Spallation Neutron Source was sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, U.S. Department of Energy. The NIST NSE portion of this work utilized facilities supported in part by the National Science Foundation under Agreement No. DMR-0944772. G.F. thanks the Palmetto Cluster at Clemson University for providing computational resources. The authors thank the reviewers for their insightful comments that helped improve the clarity and strengthen certain points in this work. The authors would like to acknowledge M. Monkenbusch of the Julich Centre for Neutron Science JCNS for his helpful discussions during the SNS NSE experiment, review of the manuscript, and helpful comments. The authors acknowledge C. Liao, formerly of Oak Ridge National Laboratory (ORNL) for performing the anion exchange in the deuterated RTIL, as well as X. Wang, formerly of ORNL, for the synthesis of the 5.8 nm-confined RTIL compound. The authors also acknowledge T. Kozielewski and M. Ohl of JCNS Outstation at SNS for their assistance in setting up the NSE experiments on BL-15 at the SNS, as well as C. Do of ORNL for assistance during beam time on BL-6B at the SNS. NR 64 TC 6 Z9 6 U1 5 U2 93 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0008-6223 EI 1873-3891 J9 CARBON JI Carbon PD NOV PY 2014 VL 78 BP 415 EP 427 DI 10.1016/j.carbon.2014.07.020 PG 13 WC Chemistry, Physical; Materials Science, Multidisciplinary SC Chemistry; Materials Science GA AO6LP UT WOS:000341463900044 ER PT J AU Hruby, P Singh, SS Williams, JJ Xiao, XH De Carlo, F Chawla, N AF Hruby, Peter Singh, Sudhanshu S. Williams, Jason J. Xiao, Xianghui De Carlo, Francesco Chawla, Nikhilesh TI Fatigue crack growth in SiC particle reinforced Al alloy matrix composites at high and low R-ratios by in situ X-ray synchrotron tomography SO INTERNATIONAL JOURNAL OF FATIGUE LA English DT Article DE Metal-matrix composites (MMCs); SiC particles; Fatigue; R-ratio; X-ray tomography ID ADVANCED PHOTON SOURCE; 3-DIMENSIONAL CHARACTERIZATION; MICROSTRUCTURE VISUALIZATION; MATERIALS SCIENCE; DAMAGE EVOLUTION; ALUMINUM-ALLOY; METAL; MICROTOMOGRAPHY; BEHAVIOR; POROSITY AB Metal matrix composites (MMCs) offer high strength, high stiffness, low density, and good fatigue resistance, while maintaining cost an acceptable level. Fatigue resistance of MMCs depends on many aspects of composite microstructure. Fatigue crack growth behavior is particularly dependent on the reinforcement characteristics and matrix microstructure. The goal of this work is to obtain a fundamental understanding of fatigue crack growth behavior in SiC particle-reinforced 2080 Al alloy composites. 'In situ X-ray synchrotron tomography was performed on two samples at low (R = 0.1) and at high (R = 0.6) R-ratios. The resulting reconstructed images were used to obtain three-dimensional (3D) rendering of the particles and fatigue crack. Behaviors of the particles and crack, as well as their interaction, were analyzed and quantified. Four-dimensional (4D) visual representations were constructed to aid in the overall understanding of damage evolution. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Hruby, Peter; Singh, Sudhanshu S.; Williams, Jason J.; Chawla, Nikhilesh] Arizona State Univ, Sch Engn Matter Transport & Energy, Ira A Fulton Sch Engn, Tempe, AZ 85287 USA. [Xiao, Xianghui; De Carlo, Francesco] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA. RP Chawla, N (reprint author), Arizona State Univ, Sch Engn Matter Transport & Energy, Ira A Fulton Sch Engn, Tempe, AZ 85287 USA. EM nchawla@asu.edu OI Singh, Sudhanshu Shekhar/0000-0002-8681-6558 FU U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357] FX Use of the Advanced Photon Source was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. NR 50 TC 5 Z9 5 U1 3 U2 60 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0142-1123 EI 1879-3452 J9 INT J FATIGUE JI Int. J. Fatigue PD NOV PY 2014 VL 68 BP 136 EP 143 DI 10.1016/j.ijfatigue.2014.05.010 PG 8 WC Engineering, Mechanical; Materials Science, Multidisciplinary SC Engineering; Materials Science GA AO6LN UT WOS:000341463700013 ER PT J AU Goguet, A Partridge, WP Aiouche, F Hardacre, C Morgan, K Stere, C Sa, J AF Goguet, Alexandre Partridge, William P. Aiouche, Farid Hardacre, Christopher Morgan, Kevin Stere, Cristina Sa, Jacinto TI Comment on "The Critical evaluation of in situ probe techniques for catalytic honeycomb monoliths" by Hettel et al. SO CATALYSIS TODAY LA English DT Editorial Material ID GAS-PHASE REACTIONS; TEMPERATURE; OXIDATION; STORAGE; BED C1 [Goguet, Alexandre; Hardacre, Christopher; Morgan, Kevin; Stere, Cristina] Queens Univ Belfast, Sch Chem & Chem Engn, CenTACat, Belfast BT9 5AG, Antrim, North Ireland. [Partridge, William P.] Oak Ridge Natl Lab, Fuels Engines & Emiss Res Ctr, Oak Ridge, TN 37831 USA. [Aiouche, Farid] Univ Lancaster, Dept Engn, Lancaster LA1 4YR, England. [Sa, Jacinto] Paul Scherrer Inst, CH-5232 Villigen, Switzerland. RP Goguet, A (reprint author), Queens Univ Belfast, Sch Chem & Chem Engn, CenTACat, Stranmillis Rd, Belfast BT9 5AG, Antrim, North Ireland. EM a.goguet@qub.ac.uk; partridgewp@ornl.gov RI Morgan, Kevin/B-6056-2012 OI Morgan, Kevin/0000-0002-6648-2546 NR 11 TC 5 Z9 5 U1 1 U2 13 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0920-5861 EI 1873-4308 J9 CATAL TODAY JI Catal. Today PD NOV 1 PY 2014 VL 236 BP 206 EP 208 DI 10.1016/j.cattod.2014.02.034 PN B PG 3 WC Chemistry, Applied; Chemistry, Physical; Engineering, Chemical SC Chemistry; Engineering GA AN9RS UT WOS:000340946500004 ER PT J AU Phuoc, TX Wang, P McIntyre, D Shadle, L AF Phuoc, Tran X. Wang, Ping McIntyre, Dustin Shadle, Lawrence TI Synthesis and characterization of a thixotropic coal-water slurry for use as a liquid fuel SO FUEL PROCESSING TECHNOLOGY LA English DT Article DE Coal-water slurry; Thixotropy; Co-intercalated laponite ID LASER-ABLATION; SUSPENSIONS; PARTICLES AB We reported here a novel approach to synthesize a low-viscosity and stable coal water slurry for use in many practical applications. The slurry was prepared by mixing coal particles with a gelling solution containing water and 1 wt.% of cobalt-intercalated laponite. The coal particle sizes were less than 75 pm and the coal loading was 50% by weight. The slurry prepared this way was able to transform to a high-viscous and unflowable gel holding coal particles uniformly throughout its volume when it was stored at rest. When it was sheared, its gelling network structure was immediately broken down becoming a low-viscous flowable liquid. The transport and thixotropic properties of the prepared slurry were measured and they were described very well by the Bingham model and the thixotropic model proposed by Usui, respectively. Published by Elsevier B.V. C1 [Phuoc, Tran X.; Wang, Ping; McIntyre, Dustin; Shadle, Lawrence] Dept Energy, Natl Energy Technol Lab, Pittsburgh, PA 15236 USA. RP Phuoc, TX (reprint author), Dept Energy, Natl Energy Technol Lab, POB 10940,MS 841-340, Pittsburgh, PA 15236 USA. EM tran@netl.doe.gov OI McIntyre, Dustin/0000-0003-4907-9576; Shadle, Lawrence/0000-0002-6283-3628 NR 18 TC 8 Z9 9 U1 0 U2 20 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0378-3820 EI 1873-7188 J9 FUEL PROCESS TECHNOL JI Fuel Process. Technol. PD NOV PY 2014 VL 127 BP 105 EP 110 DI 10.1016/j.fuproc.2014.06.019 PG 6 WC Chemistry, Applied; Energy & Fuels; Engineering, Chemical SC Chemistry; Energy & Fuels; Engineering GA AO0CK UT WOS:000340976500015 ER PT J AU Otto, F Hanold, NL George, EP AF Otto, F. Hanold, N. L. George, E. P. TI Microstructural evolution after thermomechanical processing in an equiatomic, single-phase CoCrFeMnNi high-entropy alloy with special focus on twin boundaries SO INTERMETALLICS LA English DT Article DE High-entropy alloys; Twinning; Recrystallization and recovery; Thermomechanical processing; Microstructure; Electron backscatter diffraction ID CU-AL ALLOYS; ANNEALING TWINS; GRAIN-GROWTH; ENERGY; ORIGIN; ALPHA AB The FCC-structured equiatomic CoCrFeMnNi high-entropy alloy was produced by arc melting and drop casting. After homogenization, the drop-cast ingots were cold rolled to sheets with six different final thicknesses (thickness reductions of 21, 41, 61, 84, 92 and 96%). Samples were cut from the rolled sheets and annealed for 1 h at temperatures between 400 and 1000 degrees C. The recrystallization temperature was then determined as a function of cold work by means of scanning electron microscopy and electron backscatter diffraction measurements. Additionally, Vickers indentation was performed on these samples. It was found that the microhardness first tends to increase slightly upon annealing below the recrystallization temperature but then drops steeply for higher annealing temperatures due to the onset of recrystallization. To study grain growth kinetics, samples that underwent 96% cold rolling were first recrystallized for 1 h at 800 degrees C, which is the lowest temperature at which complete recrystallization occurs, and then annealed at temperatures between 800 and 1150 degrees C for various times. The grain growth exponent was determined to be approximately n = 3, and the activation energy Q = 325 kJ/mol, both of which agree well with published values for this alloy. EBSD measurements were made in the as-recrystallized and grain growth samples to analyze the annealing twins. The density of annealing twins in the grain growth samples was found to depend only on grain size, i.e., it was independent of annealing temperature and time. No such correlation could be found for the as-recrystallized samples. These observations are discussed in the framework of existing theories for the formation of annealing twins. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Otto, F.; George, E. P.] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA. [Otto, F.; Hanold, N. L.; George, E. P.] Univ Tennessee, Mat Sci & Engn Dept, Knoxville, TN 37996 USA. RP Otto, F (reprint author), Ruhr Univ Bochum, Inst Werkstoffe, D-44780 Bochum, Germany. EM frederik.otto@rub.de RI George, Easo/L-5434-2014; OI Hanold, Nikki/0000-0003-0196-0356 FU U.S. Department of Energy, Basic Energy Sciences, Materials Sciences and Engineering Division; Alexander von Humboldt Foundation through a Feodor Lynen Research Fellowship FX This research was sponsored by the U.S. Department of Energy, Basic Energy Sciences, Materials Sciences and Engineering Division. F.O. also received funding from the Alexander von Humboldt Foundation through a Feodor Lynen Research Fellowship. NR 21 TC 37 Z9 37 U1 18 U2 133 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0966-9795 EI 1879-0216 J9 INTERMETALLICS JI Intermetallics PD NOV PY 2014 VL 54 BP 39 EP 48 DI 10.1016/j.intermet.2014.05.014 PG 10 WC Chemistry, Physical; Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Chemistry; Materials Science; Metallurgy & Metallurgical Engineering GA AO0FF UT WOS:000340983800006 ER PT J AU Hasemann, G Schneibel, JH Kruger, M George, EP AF Hasemann, G. Schneibel, J. H. Krueger, M. George, E. P. TI Vacancy strengthening in Fe3Al iron aluminides SO INTERMETALLICS LA English DT Article DE Iron aluminides; Yield stress; Heat treatment; Mechanical testing ID PLASTIC DEFORMATION BEHAVIOUR; FE-AL ALLOYS; MECHANICAL-PROPERTIES; FRACTURE-BEHAVIOR; YIELD-STRESS; TEMPERATURES; TRANSFORMATION; DIFFUSION; HARDNESS; FE-40AL AB The room temperature strength of FeAl alloys can be increased significantly by freezing in the high thermal vacancy concentrations present at elevated temperatures. In contrast, because of their lower thermal vacancy concentrations, vacancy strengthening in quenched Fe3Al alloys is believed to be much smaller and has not received much attention to date. In the present work, the influence of annealing time and quench temperature on the room temperature strength of extruded and recrystallized Fe3Al alloys is evaluated. For aluminum concentrations between 28 and 32 at% and quench temperatures between 400 and 900 degrees C both the magnitude and the kinetics of strengthening are found to be consistent with reported values for the thermal vacancy concentrations and vacancy migration rates. To assess the potential contributions of other strengthening mechanisms, appropriate heat treatments will need to be designed in follow-on studies that alter microstructural features relevant to those mechanisms while maintaining a constant vacancy concentration. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Hasemann, G.; Krueger, M.] Univ Magdeburg, Inst Mat & Joining Technol, D-39106 Magdeburg, Germany. [George, E. P.] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA. [George, E. P.] Univ Tennessee, Mat Sci & Engn Dept, Knoxville, TN 37996 USA. RP Hasemann, G (reprint author), Univ Magdeburg, Inst Mat & Joining Technol, Univ Pl 2, D-39106 Magdeburg, Germany. EM georg.hasemann@ovgu.de RI George, Easo/L-5434-2014 FU U.S. Department of Energy, Basic Energy Sciences, Materials Sciences and Engineering Division; Methodisch-Diagnostisches Zentrum Werkstoffprufung (MDZWP) e.V., Magdeburg, Germany FX This research was sponsored by the U.S. Department of Energy, Basic Energy Sciences, Materials Sciences and Engineering Division. GH and MK also acknowledge financial support of the Methodisch-Diagnostisches Zentrum Werkstoffprufung (MDZWP) e.V., Magdeburg, Germany. NR 46 TC 3 Z9 3 U1 1 U2 27 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0966-9795 EI 1879-0216 J9 INTERMETALLICS JI Intermetallics PD NOV PY 2014 VL 54 BP 95 EP 103 DI 10.1016/j.intermet.2014.05.013 PG 9 WC Chemistry, Physical; Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Chemistry; Materials Science; Metallurgy & Metallurgical Engineering GA AO0FF UT WOS:000340983800013 ER PT J AU Ma, SG Zhang, SF Qiao, JW Wang, ZH Gao, MC Jiao, ZM Yang, HJ Zhang, Y AF Ma, S. G. Zhang, S. F. Qiao, J. W. Wang, Z. H. Gao, M. C. Jiao, Z. M. Yang, H. J. Zhang, Y. TI Superior high tensile elongation of a single-crystal CoCrFeNiAl0.3 high-entropy alloy by Bridgman solidification SO INTERMETALLICS LA English DT Article DE Fracture mode; Casting; Microstructure; Mechanical properties ID MULTICOMPONENT ALLOYS; MICROSTRUCTURE; SUPERALLOYS; SPECIMEN; BEHAVIOR; HARDNESS AB The crystallographic orientation, tensile behavior, fracture mechanism, hardness, and elastic modulus of a single-crystal CoCrFeNiAl0.3 high-entropy alloy (HEA) successfully synthesized by Bridgman solidification are investigated in detail. The growth direction of the single-crystal product mainly focuses on the < 001 > orientation. An ultimate tensile elongation of about 80% is achieved in the single-crystal alloy, accompanied by a large work-hardening exponent and a shear-fracture mode. A quantitative Hall Petch relationship for the current HEA can be obtained as sigma(y) = 171.65 + 0.73/root d. The single-crystal sample displays a relatively-lower elastic modulus than the as-cast counterpart, indicating the anisotropy of elastic modulus. The outstanding tensile ductility for the single-crystal product is attributed to (1) low-angle grain boundaries and thus less distance to dislocation motion; and (2) single < 001 > crystallographic orientation and therefore less plastic-strain incompatibility. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Ma, S. G.; Wang, Z. H.; Jiao, Z. M.] Taiyuan Univ Technol, Inst Appl Mech & Biomed Engn, Taiyuan 030024, Peoples R China. [Zhang, S. F.; Zhang, Y.] Univ Sci & Technol Beijing, State Key Lab Adv Met & Mat, Beijing 100083, Peoples R China. [Qiao, J. W.; Yang, H. J.] Taiyuan Univ Technol, Coll Mat Sci & Technol, Lab Appl Phys & Mech Adv Mat, Taiyuan 030024, Peoples R China. [Gao, M. C.] Natl Energy Technol Lab, Albany, OR 97321 USA. [Yang, H. J.] Taiyuan Univ Technol, Res Inst Surface Engn, Taiyuan 030024, Peoples R China. RP Ma, SG (reprint author), Taiyuan Univ Technol, Inst Appl Mech & Biomed Engn, Taiyuan 030024, Peoples R China. EM mashengguo@tyut.edu.cn; drzhangy@ustb.edu.cn RI ZHANG, Yong/B-7928-2009 OI ZHANG, Yong/0000-0002-6355-9923 FU National Natural Science Foundation of China [51101110, 51371122, 11390362, 51341006]; Shanxi Scholarship Council of China [2012-032]; Program for the outstanding Innovative Teams of Higher Learning Institutions of Shanxi; Top Young Academic Leaders of Shanxi and the Outstanding Innovative Teams of Higher Learning Institutions of Shanxi; State Key Lab of Advanced Metals and Materials [2013-Z03] FX J.W. Qiao would like to acknowledge the financial support of the National Natural Science Foundation of China (Nos. 51101110 and 51371122), the Research Project supported by Shanxi Scholarship Council of China (No. 2012-032), and the Program for the outstanding Innovative Teams of Higher Learning Institutions of Shanxi (2013). Z.H. Wang would like to acknowledge the financial support of the National Natural Science Foundation of China (No.11390362), the Top Young Academic Leaders of Shanxi and the Outstanding Innovative Teams of Higher Learning Institutions of Shanxi. H.J. Yang would like to acknowledge the financial support of the National Natural Science Foundation of China (No. 51341006), and the State Key Lab of Advanced Metals and Materials (No.2013-Z03). NR 38 TC 14 Z9 18 U1 8 U2 88 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0966-9795 EI 1879-0216 J9 INTERMETALLICS JI Intermetallics PD NOV PY 2014 VL 54 BP 104 EP 109 DI 10.1016/j.intermet.2014.05.018 PG 6 WC Chemistry, Physical; Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Chemistry; Materials Science; Metallurgy & Metallurgical Engineering GA AO0FF UT WOS:000340983800014 ER PT J AU Barlow, A Hill, R Shashkov, M AF Barlow, Andrew Hill, Ryan Shashkov, Mikhail TI Constrained optimization framework for interface-aware sub-scale dynamics closure model for multimaterial cells in Lagrangian and arbitrary Lagrangian-Eulerian hydrodynamics SO JOURNAL OF COMPUTATIONAL PHYSICS LA English DT Article DE Lagrangian hydrodynamics; Multimaterial cells; Interface-aware sub-scale closure models ID COMPRESSIBLE MULTIFLUIDS; MIXTURE THEORY; 2-PHASE FLOW; RECONSTRUCTION; PRESSURE; COMPUTATIONS AB A systematic description of the new interface-aware sub-scale-dynamics (IA-SSD) closure model for the Lagrangian stage of multimaterial arbitrary Lagrangian-Eulerian methods is presented. The IA-SSD closure model consists of two stages. During the first, bulk, stage, the well known equal compressibility model is used. During the second stage, sub-scale interactions of the materials inside the multimaterial cell are taken into account. At this stage, information about the topology of the materials inside the multimaterial cell is utilized, allowing the orientations of internal interfaces to be included in the model. Each material interacts in a pair-wise fashion with the materials with which it has a common boundary. The interactions are based on the solution of the acoustic Riemann problem between each pair of materials and is limited using physically justified constraints: positivity of volume, positivity of internal energy and controlled rate of pressure relaxation. To determine the values of the limiter coefficients, a constrained-optimization framework is employed using a quadratic objective function with linear constraints. The algorithm guarantees the positivity of the material volume and internal energy as well as the smooth relaxation of the pressure - this allows a significant increase in the robustness of the overall algorithm. The results of comprehensive testing of the new model have been presented for one- and two-dimensional multimaterial Lagrangian hydrodynamics along with representative results for 2D multimaterial arbitrary Lagrangian-Eulerian (ALE) calculations. The numerical tests have shown that in most cases the new IA-SSD closure model produces better results compared to the well known Tipton's closure model. (C) 2014 Elsevier Inc. All rights reserved. C1 [Barlow, Andrew; Hill, Ryan] AWE Aldermaston, Computat Phys Grp, Reading RG7 4PR, Berks, England. [Hill, Ryan; Shashkov, Mikhail] Los Alamos Natl Lab, XCP 4, X Computat Phys, Los Alamos, NM 87545 USA. RP Shashkov, M (reprint author), Los Alamos Natl Lab, XCP 4, X Computat Phys, Los Alamos, NM 87545 USA. EM shashkov@lanl.gov FU National Nuclear Security Administration of the US Department of Energy [DE-AC52-06NA25396]; US Department of Energy Office of Science Advanced Scientific Computing Research (ASCR) Program in Applied Mathematics Research (Project "Mimetic Methods for Partial Differential Equations"); US Department of Energy National Nuclear Security Administration Advanced Simulation and Computing (ASC) Program FX This work was performed under the auspices of the National Nuclear Security Administration of the US Department of Energy at Los Alamos National Laboratory under Contract No. DE-AC52-06NA25396. The authors gratefully acknowledge the partial support of the US Department of Energy Office of Science Advanced Scientific Computing Research (ASCR) Program in Applied Mathematics Research (Project "Mimetic Methods for Partial Differential Equations") and the partial support of the US Department of Energy National Nuclear Security Administration Advanced Simulation and Computing (ASC) Program. NR 51 TC 3 Z9 3 U1 2 U2 14 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0021-9991 EI 1090-2716 J9 J COMPUT PHYS JI J. Comput. Phys. PD NOV 1 PY 2014 VL 276 BP 92 EP 135 DI 10.1016/j.jcp.2014.07.031 PG 44 WC Computer Science, Interdisciplinary Applications; Physics, Mathematical SC Computer Science; Physics GA AO4LP UT WOS:000341310100006 ER PT J AU Willert, J Park, H AF Willert, Jeffrey Park, H. TI Residual Monte Carlo high-order solver for Moment-Based Accelerated Thermal Radiative Transfer equations SO JOURNAL OF COMPUTATIONAL PHYSICS LA English DT Article DE Thermal Radiative Transfer; Moment-Based Acceleration; Monte Carlo; Residual Monte Carlo ID DIFFERENCE FORMULATION; TRANSPORT; DISCRETIZATION AB In this article we explore the possibility of replacing Standard Monte Carlo (SMC) transport sweeps within a Moment-Based Accelerated Thermal Radiative Transfer (TRT) algorithm with a Residual Monte Carlo (RMC) formulation. Previous Moment-Based Accelerated TRT implementations have encountered trouble when stochastic noise from SMC transport sweeps accumulates over several iterations and pollutes the low-order system. With RMC we hope to significantly lower the build-up of statistical error at a much lower cost. First, we display encouraging results for a zero-dimensional test problem. Then, we demonstrate that we can achieve a lower degree of error in two one-dimensional test problems by employing an RMC transport sweep with multiple orders of magnitude fewer particles per sweep. We find that by reformulating the high-order problem, we can compute more accurate solutions at a fraction of the cost. (C) 2014 Elsevier Inc. All rights reserved. C1 [Willert, Jeffrey; Park, H.] Los Alamos Natl Lab, Div Theoret, MS B216, Los Alamos, NM 87545 USA. RP Willert, J (reprint author), Los Alamos Natl Lab, Div Theoret, MS B216, Los Alamos, NM 87545 USA. EM jaw@lanl.gov FU U.S. Department of Energy [DE-AC52-06NA25396] FX This work was performed under U.S. government contract DE-AC52-06NA25396 for Los Alamos National Laboratory, which is operated by Los Alamos National Security, LLC, for the U.S. Department of Energy. NR 13 TC 4 Z9 4 U1 0 U2 2 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0021-9991 EI 1090-2716 J9 J COMPUT PHYS JI J. Comput. Phys. PD NOV 1 PY 2014 VL 276 BP 405 EP 421 DI 10.1016/j.jcp.2014.07.039 PG 17 WC Computer Science, Interdisciplinary Applications; Physics, Mathematical SC Computer Science; Physics GA AO4LP UT WOS:000341310100017 ER PT J AU Lin, G Liu, JG Mu, L Ye, X AF Lin, Guang Liu, Jiangguo Mu, Lin Ye, Xiu TI Weak Galerkin finite element methods for Darcy flow: Anisotropy and heterogeneity SO JOURNAL OF COMPUTATIONAL PHYSICS LA English DT Article DE Anisotropy; Darcy flow; Heterogeneity; Porous media; Weak Galerkin ID 2ND-ORDER ELLIPTIC PROBLEMS; DISCONTINUOUS GALERKIN; SUPPORT; MESHES AB This paper presents a family of weak Galerkin finite element methods (WGFEMs) for Darcy flow computation. The WGFEMs are new numerical methods that rely on the novel concept of discrete weak gradients. The WGFEMs solve for pressure unknowns both in element interiors and on the mesh skeleton. The numerical velocity is then obtained from the discrete weak gradient of the numerical pressure. The new methods are quite different than many existing numerical methods in that they are locally conservative by design, the resulting discrete linear systems are symmetric and positive-definite, and there is no need for tuning problem-dependent penalty factors. We test the WGFEMs on benchmark problems to demonstrate the strong potential of these new methods in handling strong anisotropy and heterogeneity in Darcy flow. Published by Elsevier Inc. C1 [Lin, Guang] Purdue Univ, Dept Math, W Lafayette, IN 47907 USA. [Lin, Guang] Purdue Univ, Sch Mech Engn, W Lafayette, IN 47907 USA. [Lin, Guang] Pacific NW Natl Lab, Richland, WA 99352 USA. [Liu, Jiangguo] Colorado State Univ, Dept Math, Ft Collins, CO 80523 USA. [Mu, Lin] Michigan State Univ, Dept Math, E Lansing, MI 48824 USA. [Ye, Xiu] Univ Arkansas, Dept Math, Little Rock, AR 72204 USA. RP Lin, G (reprint author), Purdue Univ, Dept Math, W Lafayette, IN 47907 USA. EM guanglin@purdue.edu FU US DOE Office of Advanced Scientific Computing Research; Pacific Northwest National Laboratory's Carbon Sequestration Initiative; National Science Foundation [DMS-1419077, DMS-1115097]; U.S. Department of Energy [DE-AC05-76RL01830] FX G. Lin would like to acknowledge support by the Applied Mathematics program of the US DOE Office of Advanced Scientific Computing Research and Pacific Northwest National Laboratory's Carbon Sequestration Initiative, which is part of the Laboratory Directed Research and Development Program. J. Liu was partially supported by the National Science Foundation under Grant No. DMS-1419077. X. Ye was supported in part by the National Science Foundation under Grant No. DMS-1115097. Computations were performed using the computational resources of Pacific Northwest National Laboratory (PNNL) Institutional Computing cluster systems and the National Energy Research Scientific Computing Center at Lawrence Berkeley National Laboratory. The PNNL is operated by Battelle for the U.S. Department of Energy under Contract DE-AC05-76RL01830. NR 33 TC 3 Z9 3 U1 0 U2 7 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0021-9991 EI 1090-2716 J9 J COMPUT PHYS JI J. Comput. Phys. PD NOV 1 PY 2014 VL 276 BP 422 EP 437 DI 10.1016/j.jcp.2014.07.001 PG 16 WC Computer Science, Interdisciplinary Applications; Physics, Mathematical SC Computer Science; Physics GA AO4LP UT WOS:000341310100018 ER PT J AU Kramer, RMJ Bochev, PB Siefert, CM Voth, TE AF Kramer, Richard M. J. Bochev, Pavel B. Siefert, Christopher M. Voth, Thomas E. TI Algebraically constrained extended edge element method (eXFEM-AC) for resolution of multi-material cells SO JOURNAL OF COMPUTATIONAL PHYSICS LA English DT Article DE Eddy current equations; Transverse electric mode; Material interface; Algebraic constraints ID MIXED FINITE-ELEMENTS; EULERIAN HYDROCODES; INTERFACE PROBLEMS; MIXTURES; HOMOGENIZATION; MODELS AB Surface effects are critical to the predictive simulation of electromagnetics as current tends to concentrate near material interfaces. There are two principal difficulties in the accurate representation of these effects in discrete models. First, many applications of interest operate at large deformations, where body-fitted meshes are impractical. Second, physics-compatible discretizations of the governing equations require curl-conforming edge elements, for which no practical alternatives to body-fitted meshes exist. The main purpose of this paper is to develop such an alternative that avoids remeshing the problem. Our approach uses the existing edge element basis to dynamically construct an interface-conforming basis. We show that in the case of triangular grids in two dimensions, our approach generates a basis that spans the same space as edge elements on an interface-fitted mesh. We also demonstrate the efficacy of the approach computationally. (C) 2014 Elsevier Inc. All rights reserved. C1 [Kramer, Richard M. J.; Bochev, Pavel B.; Siefert, Christopher M.; Voth, Thomas E.] Sandia Natl Labs, Albuquerque, NM 87185 USA. RP Siefert, CM (reprint author), Sandia Natl Labs, POB 5800, Albuquerque, NM 87185 USA. EM csiefer@sandia.gov FU U. S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX Sandia National Laboratories area multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U. S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. NR 27 TC 0 Z9 0 U1 1 U2 6 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0021-9991 EI 1090-2716 J9 J COMPUT PHYS JI J. Comput. Phys. PD NOV 1 PY 2014 VL 276 BP 596 EP 612 DI 10.1016/j.jcp.2014.07.021 PG 17 WC Computer Science, Interdisciplinary Applications; Physics, Mathematical SC Computer Science; Physics GA AO4LP UT WOS:000341310100026 ER PT J AU Tan, S Huang, LJ AF Tan, Sirui Huang, Lianjie TI A staggered-grid finite-difference scheme optimized in the time-space domain for modeling scalar-wave propagation in geophysical problems SO JOURNAL OF COMPUTATIONAL PHYSICS LA English DT Article DE Dispersion error; Finite-difference scheme; Finite-difference stencil; Numerical modeling; Optimized scheme; Scalar wave; Wave propagation ID ABSORBING BOUNDARY-CONDITIONS; PERFECTLY MATCHED LAYER; HIGH-ORDER; COMPUTATIONAL ACOUSTICS; HETEROGENEOUS MEDIA; EQUATION; ACCURACY; VELOCITY; SIMULATION; 4TH-ORDER AB For modeling scalar-wave propagation in geophysical problems using finite-difference schemes, optimizing the coefficients of the finite-difference operators can reduce numerical dispersion. Most optimized finite-difference schemes for modeling seismic-wave propagation suppress only spatial but not temporal dispersion errors. We develop a novel optimized finite-difference scheme for numerical scalar-wave modeling to control dispersion errors not only in space but also in time. Our optimized scheme is based on a new stencil that contains a few more grid points than the standard stencil. We design an objective function for minimizing relative errors of phase velocities of waves propagating in all directions within a given range of wavenumbers. Dispersion analysis and numerical examples demonstrate that our optimized finite-difference scheme is computationally up to 2.5 times faster than the optimized schemes using the standard stencil to achieve the similar modeling accuracy for a given 2D or 3D problem. Compared with the high-order finite-difference scheme using the same new stencil, our optimized scheme reduces 50 percent of the computational cost to achieve the similar modeling accuracy. This new optimized finite-difference scheme is particularly useful for large-scale 3D scalar-wave modeling and inversion. Published by Elsevier Inc. C1 [Tan, Sirui] Formerly Alamos Natl Lab, Geophys Grp, Los Alamos, NM 87545 USA. [Huang, Lianjie] Los Alamos Natl Lab, Geophys Grp, Los Alamos, NM 87545 USA. RP Huang, LJ (reprint author), Los Alamos Natl Lab, Geophys Grp, Los Alamos, NM 87545 USA. EM siruitan@hotmail.com; ljh@lanl.gov RI Tan, Sirui/H-9565-2015 OI Tan, Sirui/0000-0002-8150-3261 FU U.S. Department of Energy [DE-AC52-06NA25396] FX This work was supported by U.S. Department of Energy through contract DE-AC52-06NA25396 to Los Alamos National Laboratory (LANL). The computation was performed using super-computers of LANL's Institutional Computing Program. We thank three anonymous reviewers for their valuable comments. NR 43 TC 11 Z9 12 U1 0 U2 11 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0021-9991 EI 1090-2716 J9 J COMPUT PHYS JI J. Comput. Phys. PD NOV 1 PY 2014 VL 276 BP 613 EP 634 DI 10.1016/j.jcp.2014.07.044 PG 22 WC Computer Science, Interdisciplinary Applications; Physics, Mathematical SC Computer Science; Physics GA AO4LP UT WOS:000341310100027 ER PT J AU Levin, EM Kramer, MJ Schmidt-Rohr, K AF Levin, E. M. Kramer, M. J. Schmidt-Rohr, K. TI Local composition and carrier concentration in Pb0.7Ge0.3Te and Pb0.5Ge0.5Te alloys from Te-125 NMR and microscopy SO JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS LA English DT Article DE Chalcogenides; Electron microscopy; X-ray diffraction; Microstructure; Nuclear magnetic resonance (NMR) ID GERMANIUM TELLURIDE; THERMOELECTRIC-MATERIALS; BAND STRUCTURE; PBTE; GETE; SEMICONDUCTORS; CHALCOGENIDES; DESIGN AB Pb0.7Ge0.3Te and Pb0.5Ge0.5Te alloys, (i) quenched from 923 K or (ii) quenched and annealed at 573 K for 2 h, have been studied by Te-125 NMR, X-ray diffraction, electron and optical microscopy, as well as energy dispersive spectroscopy. Depending on the composition and thermal treatment history, Te-125 NMR spectra exhibit different resonance frequencies and spin-lattice relaxation times, which can be assigned to different phases in the alloy. Quenched and annealed Pb0.7Ge0.3Te alloys can be considered as solid solutions but are shown by NMR to have components with various carrier concentrations. Quenched and annealed Pb0.5Ge0.5Te alloys contain GeTe- and PbTe-based phases with different compositions and charge carrier concentrations. Based on the analysis of non-exponential Te-125 NMR spin-lattice relaxation, the fractions and carrier concentrations of the various phases have been estimated. Our data show that alloying of PbTe with Ge results in the formation of chemically and electronically inhomogeneous systems. Te-125 NMR can be used as an efficient probe to detect the local composition in equilibrium as well as non-equilibrium states, and to determine the local carrier concentrations in complex multiphase tellurides. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Levin, E. M.; Kramer, M. J.; Schmidt-Rohr, K.] Iowa State Univ, Div Mat Sci & Engn, US DOE, Ames Lab, Ames, IA 50011 USA. [Levin, E. M.] Iowa State Univ, Dept Phys & Astron, Ames, IA 50011 USA. [Kramer, M. J.] Iowa State Univ, Dept Mat Sci & Engn, Ames, IA 50011 USA. [Schmidt-Rohr, K.] Iowa State Univ, Dept Chem, Ames, IA 50011 USA. RP Levin, EM (reprint author), Iowa State Univ, Div Mat Sci & Engn, US DOE, Ames Lab, Ames, IA 50011 USA. EM levin@iastate.edu FU U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences, Materials Science and Engineering Division; U.S. DOE by Iowa State University [DE-AC02-07CH11358] FX The authors thank L.P. Lincoln and H. Sailsbury at the Materials Preparation Center at Ames Laboratory for sample synthesis, and J.L. Harringa and B.A. Cook (Ames Laboratory) for helpful discussions. E.M.L. thanks J.P. Heremans (Ohio State University) for providing the p-type PbTe sample. This work was supported by the U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences, Materials Science and Engineering Division. The research was performed at the Ames Laboratory, which is operated for the U.S. DOE by Iowa State University under contract no. DE-AC02-07CH11358. NR 35 TC 0 Z9 0 U1 3 U2 37 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0022-3697 EI 1879-2553 J9 J PHYS CHEM SOLIDS JI J. Phys. Chem. Solids PD NOV PY 2014 VL 75 IS 11 BP 1269 EP 1276 DI 10.1016/j.jpcs.2014.06.004 PG 8 WC Chemistry, Multidisciplinary; Physics, Condensed Matter SC Chemistry; Physics GA AO0FO UT WOS:000340984700014 ER PT J AU Zhang, JS Liu, YN Huan, Y Hao, SJ Jiang, DQ Ren, Y Shao, Y Ru, YD Wang, ZQ Cui, LS AF Zhang, Junsong Liu, Yinong Huan, Yong Hao, Shijie Jiang, Daqiang Ren, Yang Shao, Yang Ru, Yadong Wang, Zhongqiang Cui, Lishan TI High damping NiTi/Ti3Sn in situ composite with transformation-mediated plasticity SO MATERIALS & DESIGN LA English DT Article DE Composite; Synchrotron; Damping; Ti3Sn; NiTi ID SHAPE-MEMORY ALLOYS; METAL-MATRIX COMPOSITES; HIGH-STRENGTH; BEHAVIOR; TI3SN; TRIP; CAPACITY; ALUMINUM; TWIN AB The concept of transformation-induced plasticity effect is introduced in this work to improve the plasticity of brittle intermetallic compound Ti3Sn, which is a potent high damping material. This concept is achieved in an in situ NiTi/Ti3Sn composite. The composite is composed of primary Ti3Sn phase and (NiTi + Ti3Sn) eutectic structure formed via hypereutectic solidification. The composite exhibits a high damping capacity of 0.075 (indexed by tan delta), a high ultimate compressive strength of 1350 MPa, and a large plasticity of 27.5%. In situ synchrotron high-energy X-ray diffraction measurements revealed clear evidence of the stress-induced martensitic transformation (B2 -> B19') of the NiTi component during deformation. The strength of the composite mainly stems from the Ti3Sn, whereas the NiTi component is responsible for the excellent plasticity of the composite. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Zhang, Junsong; Hao, Shijie; Jiang, Daqiang; Shao, Yang; Ru, Yadong; Wang, Zhongqiang; Cui, Lishan] China Univ Petr, Dept Mat Sci & Engn, Beijing 102249, Peoples R China. [Liu, Yinong] Univ Western Australia, Sch Mech & Chem Engn, Crawley, WA 6009, Australia. [Huan, Yong] Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech LNM, Beijing 100190, Peoples R China. [Ren, Yang] Argonne Natl Lab, Xray Sci Div, Argonne, IL 60439 USA. RP Cui, LS (reprint author), China Univ Petr, Dept Mat Sci & Engn, Beijing 102249, Peoples R China. EM lscui@cup.edu.cn RI Liu, Yinong/G-6637-2011; Jiang, Daqiang /G-5511-2014 OI Liu, Yinong/0000-0002-8784-8543; FU National Natural Science Foundation of China (NSFC) [51231008]; National 973 programs of China [2012CB619403]; Australian Research Council [DP140103805]; Key Project of Chinese Ministry of Education [313055]; US Department of Energy, Office of Science, and Office of Basic Energy Science, Office of Basic Energy Sciences [DE-AC02-06CH11357] FX This work was supported by the key program project of National Natural Science Foundation of China (NSFC) (Grant No. 51231008), the National 973 programs of China (Grant No. 2012CB619403), the Australian Research Council (Grant No. DP140103805), and the Key Project of Chinese Ministry of Education (Grant No. 313055). The use of the Advanced Photon Source was supported by the US Department of Energy, Office of Science, and Office of Basic Energy Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. NR 23 TC 6 Z9 6 U1 5 U2 39 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0261-3069 EI 1873-4197 J9 MATER DESIGN JI Mater. Des. PD NOV PY 2014 VL 63 BP 460 EP 463 DI 10.1016/j.matdes.2014.05.062 PG 4 WC Materials Science, Multidisciplinary SC Materials Science GA AN9SQ UT WOS:000340949300056 ER PT J AU Takizawa, K Bazilevs, Y Tezduyar, TE Long, CC Marsden, AL Schjodt, K AF Takizawa, Kenji Bazilevs, Yuri Tezduyar, Tayfun E. Long, Christopher C. Marsden, Alison L. Schjodt, Kathleen TI ST and ALE-VMS methods for patient-specific cardiovascular fluid mechanics modeling SO MATHEMATICAL MODELS & METHODS IN APPLIED SCIENCES LA English DT Article DE Cardiovascular fluid mechanics; fluid-structure interaction; cerebral aneurysms; pulsatile ventricular assist devices; stents; ALE methods; ST methods; special techniques ID FINITE-ELEMENT COMPUTATION; INCOMPRESSIBLE-FLOW COMPUTATIONS; VARIATIONAL MULTISCALE METHOD; GENERALIZED-ALPHA METHOD; NAVIER-STOKES EQUATIONS; LARGE-EDDY SIMULATION; SPACE-TIME PROCEDURE; MOVING BOUNDARIES; CEREBRAL ANEURYSMS; BLOOD-FLOW AB This paper provides a review of the space-time (ST) and Arbitrary Lagrangian-Eulerian (ALE) techniques developed by the first three authors' research teams for patient-specific cardiovascular fluid mechanics modeling, including fluid-structure interaction (FSI). The core methods are the ALE-based variational multiscale (ALE-VMS) method, the Deforming-Spatial-Domain/Stabilized ST formulation, and the stabilized ST FSI technique. A good number of special techniques targeting cardiovascular fluid mechanics have been developed to be used with the core methods. These include: (i) arterial-surface extraction and boundary condition techniques, (ii) techniques for using variable arterial wall thickness, (iii) methods for calculating an estimated zero-pressure arterial geometry, (iv) techniques for prestressing of the blood vessel wall, (v) mesh generation techniques for building layers of refined fluid mechanics mesh near the arterial walls, (vi) a special mapping technique for specifying the velocity profile at an inflow boundary with non-circular shape, (vii) a scaling technique for specifying a more realistic volumetric flow rate, (viii) techniques for the projection of fluid-structure interface stresses, (ix) a recipe for pre-FSI computations that improve the convergence of the FSI computations, (x) the Sequentially-Coupled Arterial FSI technique and its multiscale versions, (xi) techniques for calculation of the wall shear stress (WSS) and oscillatory shear index (OSI), (xii) methods for stent modeling and mesh generation, (xiii) methods for calculation of the particle residence time, and (xiv) methods for an estimated element-based zero-stress state for the artery. Here we provide an overview of the special techniques for WSS and OSI calculations, stent modeling and mesh generation, and calculation of the residence time with application to pulsatile ventricular assist device (PVAD). We provide references for some of the other special techniques. With results from earlier computations, we show how these core and special techniques work. C1 [Takizawa, Kenji] Waseda Univ, Dept Modern Mech Engn, Shinjuku Ku, Tokyo 1698050, Japan. [Takizawa, Kenji] Waseda Univ, Waseda Inst Adv Study, Shinjuku Ku, Tokyo 1698050, Japan. [Bazilevs, Yuri; Marsden, Alison L.] Univ Calif San Diego, La Jolla, CA 92093 USA. [Tezduyar, Tayfun E.; Schjodt, Kathleen] Rice Univ, Houston, TX 77005 USA. [Long, Christopher C.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. RP Takizawa, K (reprint author), Waseda Univ, Dept Modern Mech Engn, Shinjuku Ku, 1-6-1 Nishi Waseda, Tokyo 1698050, Japan. EM Kenji.Takizawa@tafsm.org RI Takizawa, Kenji/E-2245-2013; Tezduyar, Tayfun/F-6134-2012 OI Takizawa, Kenji/0000-0003-1172-113X; Tezduyar, Tayfun/0000-0001-8707-3162 NR 130 TC 26 Z9 26 U1 1 U2 28 PU WORLD SCIENTIFIC PUBL CO PTE LTD PI SINGAPORE PA 5 TOH TUCK LINK, SINGAPORE 596224, SINGAPORE SN 0218-2025 EI 1793-6314 J9 MATH MOD METH APPL S JI Math. Models Meth. Appl. Sci. PD NOV PY 2014 VL 24 IS 12 DI 10.1142/S0218202514500250 PG 50 WC Mathematics, Applied SC Mathematics GA AO0OC UT WOS:000341008600003 ER PT J AU Romero-Gomez, P Richmond, MC AF Romero-Gomez, Pedro Richmond, Marshall C. TI Simulating blade-strike on fish passing through marine hydrokinetic turbines SO RENEWABLE ENERGY LA English DT Article DE Hydrokinetic; CFD; DES; Lagrangian particles; Tidal; Turbine ID JUVENILE FISH; PASSAGE; SALMON; FLOW AB The occurrence, frequency, and intensity of blade-strike of fish on an axial-flow marine hydrokinetic turbine was simulated using two modeling approaches: a novel scheme combining computational fluid dynamics (CFD) with Lagrangian particle tracking, and a conventional kinematic model. The kinematic model included simplifying assumptions of fish trajectories such as distribution and velocity. The proposed CFD and Lagrangian particle tracking methods provided a more realistic representation of blade-strike mechanisms by integrating the following components: (i) advanced unsteady turbulence simulation using detached eddy simulation (DES), (ii) generation of inflow turbulence based on field data, (iii) moving turbine blades in highly transient flows, and (iv) Lagrangian particles to mimic the potential fish pathways. The test conditions to evaluate the blade-strike probability and fish survival rate were: (i) the turbulence environment, (ii) the fish size, and (iii) the approaching flow velocity. The proposed Lagrangian method simulates potential fish trajectories and their interaction with the rotating turbine with the limitation that it does not include any volitional fish avoidance behavior. Depending upon the scenario, the percentage of particles that registered a collision event ranged from 6% to 19% of the released sample size. Next, by using a set of experimental correlations of the exposure-response for live fish colliding with moving blades, the simulated collision data were used as input variables to estimate the survival rate of fish passing through the operating turbine. The resulting survival rates were greater than 96% in all scenarios, which is comparable to or better than known survival rates for conventional hydropower turbines. The kinematic model predicted higher blade-strike probabilities and mortality rates than the Lagrangian particle-based method did. The Lagrangian method also offers the advantage of expanding the evaluation framework to include additional mechanisms of stress and injury on fish, or other aquatic biota, caused by hydrokinetic turbines and related devices. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Romero-Gomez, Pedro; Richmond, Marshall C.] Pacific NW Natl Lab, Hydrol Grp, Earth Syst Sci Div, Richland, WA 99352 USA. RP Richmond, MC (reprint author), Pacific NW Natl Lab, Hydrol Grp, Earth Syst Sci Div, POB 999, Richland, WA 99352 USA. EM marshall.richmond@pnnl.gov RI Richmond, Marshall/D-3915-2013 OI Richmond, Marshall/0000-0003-0111-1485 FU U.S. Department of Energy, Energy Efficiency and Renewable Energy, Wind and Water Power Program [DE-AC06-76RLO 1830]; U.S. Department of Energy [DE-AC06-76RLO 1830] FX This research was supported by the U.S. Department of Energy, Energy Efficiency and Renewable Energy, Wind and Water Power Program (Contract No. DE-AC06-76RLO 1830).; Pacific Northwest National Laboratory (PNNL) is operated for the U.S. Department of Energy by Battelle Memorial Institute under Contract No. DE-AC06-76RLO 1830. NR 40 TC 4 Z9 4 U1 4 U2 37 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0960-1481 J9 RENEW ENERG JI Renew. Energy PD NOV PY 2014 VL 71 BP 401 EP 413 DI 10.1016/j.renene.2014.05.051 PG 13 WC GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY; Energy & Fuels SC Science & Technology - Other Topics; Energy & Fuels GA AO0CL UT WOS:000340976600045 ER PT J AU Gunawan, B Neary, VS Colby, J AF Gunawan, Budi Neary, Vincent S. Colby, Jonathan TI Tidal energy site resource assessment in the East River tidal strait, near Roosevelt Island, New York, New York SO RENEWABLE ENERGY LA English DT Article DE Acoustic Doppler velocimeter; Hub-height velocity measurements; Hydrokinetic power density; Roosevelt Island tidal energy site; Tidal energy converter; Turbulence ID PUGET-SOUND; FLOW; TURBULENCE; VESSEL; USA; WA AB This study demonstrates a site resource assessment to examine the temporal variation of the current speeds, current directions, turbulence intensities, and power densities for a tidal energy site in the East River tidal strait. These variables were derived from two months of acoustic Doppler velocimeter (ADV) measurements at the design hub height of the Verdant Power Gen5 hydrokinetic turbine. The study site is a tidal strait that exhibits semi-diurnal tidal current characteristics, with a mean horizontal current speed of 1.4 m s(-1), and a turbulence intensity of 15% at a reference mean current of 2 m s(-1). Flood and ebb flow directions are nearly bi-directional, with a higher current speed during flood tide, which skews the power production towards the flood tide period. The tidal hydrodynamics at the site are highly regular, as indicated by the tidal current time series that resembles a sinusoidal function. This study also shows that the theoretical force and the power densities derived from the current measurements can be significantly influenced by the length of the time window used for averaging the current speed data. Furthermore, the theoretical power density at the site, derived from the current speed measurements, is one order of magnitude greater than that reported in the U.S. national resource assessment. This discrepancy highlights the importance of conducting site resource assessments based on measurements at the tidal energy converter device scale. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Gunawan, Budi; Neary, Vincent S.] Sandia Natl Labs, Albuquerque, NM 87185 USA. [Colby, Jonathan] Verdant Power Inc, New York, NY 10044 USA. RP Gunawan, B (reprint author), Sandia Natl Labs, PO 5800,1515 Eubank Ave, Albuquerque, NM 87185 USA. EM budi.gunawan@sandia.gov FU U.S. Department of Energy's (DOE) Office of Energy Efficiency and Renewable Energy, Wind and Water Power Technologies Program under the DOE Advanced Water Power Project [DE-FG36-08GO18168/M001]; DOE Advanced Water Power Project [DE -FG36-08GO18168.005]; U.S. Department of Energy's National Nuclear Security Administration [DE-AC04-94AL85000] FX This research was supported by the U.S. Department of Energy's (DOE) Office of Energy Efficiency and Renewable Energy, Wind and Water Power Technologies Program under the DOE Advanced Water Power Project Grant No. DE-FG36-08GO18168/M001, the DOE Advanced Water Power Project Contract No. DE -FG36-08GO18168.005, titled: "Improved Structure and Fabrication of Large, High-Power IMPS Rotors." Sandia National Laboratories is a multiprogram laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. The authors thank Dean Corren and Mary Ann Adonizio of Verdant Power, as well as the reviewers of this paper, for their helpful comments and suggestions. NR 40 TC 8 Z9 8 U1 1 U2 30 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0960-1481 J9 RENEW ENERG JI Renew. Energy PD NOV PY 2014 VL 71 BP 509 EP 517 DI 10.1016/j.renene.2014.06.002 PG 9 WC GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY; Energy & Fuels SC Science & Technology - Other Topics; Energy & Fuels GA AO0CL UT WOS:000340976600057 ER PT J AU Khairallah, SA Anderson, A AF Khairallah, Saad A. Anderson, Andy TI Mesoscopic simulation model of selective laser melting of stainless steel powder SO JOURNAL OF MATERIALS PROCESSING TECHNOLOGY LA English DT Article DE Additive manufacturing; Selective laser melting; Fluid dynamics; Heat transfer; First-principles simulation ID METALLIC POWDERS; RADIATION; BED AB A 3D mesoscopic model is developed to simulate selective laser melting processes using the ALE3D multiphysics code. We study the laser-induced melting of a random bed of stainless steel 316 particles on a solid substrate (1000 mu m x 300 mu m x 50 mu m) and its solidification into either a continuous track or a discontinuous track as a result of Plateau Rayleigh instability. Our approach couples thermal diffusion to hydrodynamics and accounts for temperature dependent material properties and surface tension, as well as the random particle distribution. The simulations give new physical insight that should prove useful for development of continuum models, where the powder is homogenized. We validate our approach against the experiment and find that we match the main laser track characteristics. Published by Elsevier B.V. C1 [Khairallah, Saad A.; Anderson, Andy] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. RP Khairallah, SA (reprint author), Lawrence Livermore Natl Lab, 7000 East Ave, Livermore, CA 94550 USA. EM khairallah1@llnl.gov FU U.S. Department of Energy by Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; Laboratory Directed Research and Development Program at LLNL [13-SI-002] FX We would like to thank Al Nichols III for his help with the thermal package in ALE3D. Also, we acknowledge fruitful discussions with Sasha Rubenshick, Wayne King and Bob Ferencz. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. This work was funded by the Laboratory Directed Research and Development Program at LLNL under project tracking code 13-SI-002. The LLNL document review and release number is LLNL-JRNL-649602. NR 19 TC 31 Z9 31 U1 24 U2 129 PU ELSEVIER SCIENCE SA PI LAUSANNE PA PO BOX 564, 1001 LAUSANNE, SWITZERLAND SN 0924-0136 J9 J MATER PROCESS TECH JI J. Mater. Process. Technol. PD NOV PY 2014 VL 214 IS 11 BP 2627 EP 2636 DI 10.1016/j.jmatprotec.2014.06.001 PG 10 WC Engineering, Industrial; Engineering, Manufacturing; Materials Science, Multidisciplinary SC Engineering; Materials Science GA AN0UV UT WOS:000340300400046 ER PT J AU O'Brien, TA Collins, WD Rauscher, SA Ringler, TD AF O'Brien, Travis A. Collins, William D. Rauscher, Sara A. Ringler, Todd D. TI Reducing the computational cost of the ECF using a nuFFT: A fast and objective probability density estimation method SO COMPUTATIONAL STATISTICS & DATA ANALYSIS LA English DT Article DE Empirical characteristic function; ECF; Kernel density estimation; Histogram; Nonuniform FFT; nuFFT ID EMPIRICAL CHARACTERISTIC FUNCTION; AQUAPLANET SIMULATIONS; PRECIPITATION; SPECTRA; MODELS; CLOUDS; SERIES AB A nonuniform, fast Fourier transform can be used to reduce the computational cost of the empirical characteristic function (ECF) by a factor of 100. This fast ECF calculation method is applied to a new, objective, and robust method for estimating the probability distribution of univariate data, which effectively modulates and filters the ECF of a dataset in a way that yields an optimal estimate of the (Fourier transformed) underlying distribution. This improvement in computational efficiency is leveraged to estimate probability densities from a large ensemble of atmospheric velocity increments (gradients), with the purpose of characterizing the statistical and fractal properties of the velocity field. It is shown that the distribution of velocity increments depends on location in an atmospheric model and that the increments are clearly not normally distributed. The estimated increment distributions exhibit self-similar and distinctly multifractal behavior, as shown by structure functions that exhibit power-law scaling with a non-linear dependence of the power-law exponent on the structure function order. Published by Elsevier B.V. C1 [O'Brien, Travis A.; Collins, William D.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. [Collins, William D.] Univ Calif Berkeley, Berkeley, CA 94720 USA. [Rauscher, Sara A.] Univ Delaware, Newark, DE USA. [Ringler, Todd D.] Los Alamos Natl Lab, Los Alamos, NM USA. RP O'Brien, TA (reprint author), 1 Cyclotron Rd,MS84R-0171, Berkeley, CA 94720 USA. EM TAOBrien@lbl.gov RI O'Brien, Travis/M-5250-2013; Collins, William/J-3147-2014 OI O'Brien, Travis/0000-0002-6643-1175; Collins, William/0000-0002-4463-9848 FU Office of Science, Office of Biological and Environmental Research of the US Department of Energy Regional and Global Climate Modeling Program (RGCM); Office of Science of the US Department of Energy [DE-AC02-05CH11231] FX This research was supported by the Director, Office of Science, Office of Biological and Environmental Research of the US Department of Energy Regional and Global Climate Modeling Program (RGCM) and used resources of the National Energy Research Scientific Computing Center (NERSC), also supported by the Office of Science of the US Department of Energy under Contract No. DE-AC02-05CH11231. NR 36 TC 1 Z9 1 U1 1 U2 18 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0167-9473 EI 1872-7352 J9 COMPUT STAT DATA AN JI Comput. Stat. Data Anal. PD NOV PY 2014 VL 79 BP 222 EP 234 DI 10.1016/j.csda.2014.06.002 PG 13 WC Computer Science, Interdisciplinary Applications; Statistics & Probability SC Computer Science; Mathematics GA AM8PQ UT WOS:000340139900016 ER PT J AU Kesler, M Ozdemir, E Kisacikoglu, MC Tolbert, LM AF Kesler, Metin Ozdemir, Engin Kisacikoglu, Mithat C. Tolbert, Leon M. TI Power Converter-Based Three-Phase Nonlinear Load Emulator for a Hardware Testbed System SO IEEE TRANSACTIONS ON POWER ELECTRONICS LA English DT Article DE Three-phase diode bridge rectifier; emulator; hardware testbed (HTB); nonlinear load; power converter ID THE-LOOP SIMULATION; DESIGN; ELECTRONICS; PLATFORM; DRIVES AB A three-phase nonlinear load emulator using a power electronic converter is presented in this study. The proposed nonlinear load emulator is intended to be used in an ultrawide-area grid transmission network emulator, also called hardware testbed (HTB). The emulator converter is controlled in rectifier mode to act as the real nonlinear three-phase diode rectifier load. This paper presents an accurate controller for the nonlinear load emulator based on a three-phase diode rectifier system to be used in the HTB. This study also demonstrates simulation and experimental results for verification of the proposed controller. C1 [Kesler, Metin] Bilecik Seyh Edebali Univ, Dept Comp Engn, TR-11210 Bilecik, Turkey. [Ozdemir, Engin] Kocaeli Univ, TR-41300 Izmit, Turkey. [Kisacikoglu, Mithat C.] Sci & Technol Res Council Turkey TUBITAK, TR-06100 Ankara, Turkey. [Tolbert, Leon M.] Univ Tennessee, Oak Ridge, TN 37831 USA. [Tolbert, Leon M.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. RP Kesler, M (reprint author), Bilecik Seyh Edebali Univ, Dept Comp Engn, TR-11210 Bilecik, Turkey. EM metin.kesler@bilecik.edu.tr; eozdemir@kocaeli.edu.tr; mithat.kisacikoglu@tubitak.gov.tr; tolbert@utk.edu OI Ozdemir, Engin/0000-0003-0882-332X; Tolbert, Leon/0000-0002-7285-609X FU Engineering Research Center Program of the National Science Foundation; Department of Energy under NSF [EEC-1041877]; CURENT Industry Partnership Program; TUBITAK(The Scientific and Technological Research Council of Turkey) via its BIDEB-2219 program; YOK (Turkish Higher Education Council) FX This work was supported by the Engineering Research Center Program of the National Science Foundation, the Department of Energy under NSF Award EEC-1041877, the CURENT Industry Partnership Program and TUBITAK(The Scientific and Technological Research Council of Turkey) via its BIDEB-2219 program. This study is also supported by YOK (Turkish Higher Education Council). Recommended for publication by Associate Editor P. Chi-Kwong Luk. NR 22 TC 2 Z9 2 U1 0 U2 12 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 0885-8993 EI 1941-0107 J9 IEEE T POWER ELECTR JI IEEE Trans. Power Electron. PD NOV PY 2014 VL 29 IS 11 BP 5806 EP 5812 DI 10.1109/TPEL.2014.2301815 PG 7 WC Engineering, Electrical & Electronic SC Engineering GA AM1PJ UT WOS:000339619400017 ER PT J AU Johnson, BB Dhople, SV Hamadeh, AO Krein, PT AF Johnson, Brian B. Dhople, Sairaj V. Hamadeh, Abdullah O. Krein, Philip T. TI Synchronization of Parallel Single-Phase Inverters With Virtual Oscillator Control SO IEEE TRANSACTIONS ON POWER ELECTRONICS LA English DT Article DE Distributed ac power systems; inverters; microgrids; nonlinear control; oscillators; synchronization; uninterruptible power supplies; voltage source inverters ID DISTRIBUTED GENERATION SYSTEMS; DROOP CONTROL METHOD; AUTONOMOUS OPERATION; LCL-FILTER; MICROGRIDS; VOLTAGE; DESIGN; AC; PERFORMANCE; CONVERTERS AB A method to synchronize and control a system of parallel single-phase inverters without communication is presented. Inspired by the phenomenon of synchronization in networks of coupled oscillators, we propose that each inverter be controlled to emulate the dynamics of a nonlinear dead-zone oscillator. As a consequence of the electrical coupling between inverters, they synchronize and share the load in proportion to their ratings. We outline a sufficient condition for global asymptotic synchronization and formulate a methodology for controller design such that the inverter terminal voltages oscillate at the desired frequency, and the load voltage is maintained within prescribed bounds. We also introduce a technique to facilitate the seamless addition of inverters controlled with the proposed approach into an energized system. Experimental results for a system of three inverters demonstrate power sharing in proportion to power ratings for both linear and nonlinear C1 [Johnson, Brian B.] Natl Renewable Energy Lab, Power Syst Engn Ctr, Golden, CO 80401 USA. [Dhople, Sairaj V.] Univ Minnesota, Dept Elect & Comp Engn, Minneapolis, MN 55455 USA. [Hamadeh, Abdullah O.] MIT, Dept Mech Engn, Cambridge, MA 02139 USA. [Krein, Philip T.] Univ Illinois, Dept Elect & Comp Engn, Urbana, IL 61801 USA. RP Johnson, BB (reprint author), Natl Renewable Energy Lab, Power Syst Engn Ctr, Golden, CO 80401 USA. EM brian.johnson@NREL.GOV; sdhople@UMN.EDU; ahamadeh@MIT.EDU; krein@ILLINOIS.EDU FU National Science Foundation Graduate Research Fellowship; Grainger Center for Electric Machinery and Electromechanics at the University of Illinois; Global Climate and Energy Project at Stanford University FX The work of B. B. Johnson was supported in part by the National Science Foundation Graduate Research Fellowship and the Grainger Center for Electric Machinery and Electromechanics at the University of Illinois. The work of P. T. Krein was supported in part by the Global Climate and Energy Project at Stanford University. Recommended for publication by Associate Editor P. C. Loh. NR 57 TC 18 Z9 20 U1 1 U2 19 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 0885-8993 EI 1941-0107 J9 IEEE T POWER ELECTR JI IEEE Trans. Power Electron. PD NOV PY 2014 VL 29 IS 11 BP 6124 EP 6138 DI 10.1109/TPEL.2013.2296292 PG 15 WC Engineering, Electrical & Electronic SC Engineering GA AM1PJ UT WOS:000339619400044 ER PT J AU Onen, A Woyak, J Arghandeh, R Jung, J Scirbona, C Broadwater, RP AF Onen, Ahmet Woyak, Jeremy Arghandeh, Reza Jung, Jaesung Scirbona, Charlie Broadwater, Robert P. TI Time-varying cost of loss evaluation in distribution networks using market marginal price SO INTERNATIONAL JOURNAL OF ELECTRICAL POWER & ENERGY SYSTEMS LA English DT Article DE Locational marginal price; Distribution network; Phase balancing; Hourly load AB In the electric power system planning process, engineers seek to identify the most cost-effective means of serving the load within reliability and power quality criteria. In order to accurately assess the cost of a given project, the feeder losses must be calculated. In the past, it was necessary to estimate the feeder losses based upon the peak load and a calculated load factor for the year. The cost of these losses would then be calculated based upon an expected, fixed per-kW h generation cost. This paper presents a more accurate means of calculating the cost of losses, using hourly feeder load information and time-varying electric energy cost data. This paper attempts to quantify the improvement in accuracy and presents an example where the economic evaluation of a planning project requires the more accurate loss calculation. (C) 2014 Elsevier Ltd. All rights reserved. C1 [Onen, Ahmet] Minist Natl Educ, Ankara, Turkey. [Broadwater, Robert P.] Virginia Polytech Inst & State Univ, Dept Elect & Comp Engn, Blacksburg, VA 24061 USA. [Jung, Jaesung] Brookhaven Natl Lab, Sustainable Energy Technol Dept, Upton, NY 11973 USA. [Arghandeh, Reza] Univ Calif Berkeley, Calif Inst Energy & Environm, Berkeley, CA 94720 USA. [Woyak, Jeremy; Broadwater, Robert P.] Elect Distribut Design Inc, Blacksburg, VA USA. [Scirbona, Charlie] Orange & Rockland Util, New York, NY USA. RP Onen, A (reprint author), Virginia Tech, 302 Whittemore Hall, Blacksburg, VA 24061 USA. EM aonen@vt.edu RI Onen, Ahmet/N-6632-2014; OI Onen, Ahmet/0000-0001-7086-5112 FU Electrical Distribution Design, Inc, Orange Rockland FX The authors would like to thank Electrical Distribution Design, Inc, Orange & Rockland for providing data, funding, and technical assistance. NR 18 TC 3 Z9 3 U1 0 U2 17 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0142-0615 EI 1879-3517 J9 INT J ELEC POWER JI Int. J. Electr. Power Energy Syst. PD NOV PY 2014 VL 62 BP 712 EP 717 DI 10.1016/j.ijepes.2014.05.028 PG 6 WC Engineering, Electrical & Electronic SC Engineering GA AM1JF UT WOS:000339601500074 ER PT J AU Xia, YZ Li, TL Ren, F Gao, YF Wang, H AF Xia, Yuzhi Li, Tianlei Ren, Fei Gao, Yanfei Wang, Hsin TI Failure analysis of pinch torsion tests as a thermal runaway risk evaluation method of Li-ion cells SO JOURNAL OF POWER SOURCES LA English DT Article DE Li-ion battery; Finite element analysis; Pinch torsion test; Fracture; Internal short circuit ID SIMULATION; BATTERIES; SAFETY AB Recently a pinch torsion test is developed for safety testing of Li-ion batteries. It has been demonstrated that this test can generate small internal short-circuit spots in the separator in a controllable and repeatable manner. In the current research, the failure mechanism is examined by numerical simulations and comparisons to experimental observations. Finite element models are developed to evaluate the deformation of the separators under both pure pinch and pinch torsion loading conditions. It is discovered that the addition of the torsion component significantly increased the maximum first principal strain, which is believed to induce the internal short circuit. In addition, the applied load in the pinch torsion test is significantly less than in the pure pinch test, thus dramatically improving the applicability of this method to ultra-thick batteries which otherwise require heavy load in excess of machine capability. It is further found that the separator failure is achieved in the early stage of torsion (within a few degree of rotation). Effect of coefficient of friction on the maximum first principal strain is also examined. (C) 2014 Elsevier B.V. All rights reserved. C1 [Xia, Yuzhi; Gao, Yanfei] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA. [Li, Tianlei] Florida State Univ, Natl High Magnet Field Lab, Tallahassee, FL 32310 USA. [Ren, Fei] Temple Univ, Dept Mech Engn, Philadelphia, PA 19122 USA. [Gao, Yanfei; Wang, Hsin] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA. RP Wang, H (reprint author), Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA. EM wangh2@ornl.gov RI Gao, Yanfei/F-9034-2010; Wang, Hsin/A-1942-2013 OI Gao, Yanfei/0000-0003-2082-857X; Wang, Hsin/0000-0003-2426-9867 FU Office of Vehicle Technologies of the Department of Energy-Oak Ridge National Laboratory [DE-AC05-000R22725]; UT-Battelle, LLC; NSF [CMMI 0900027]; U.S. Department of Energy, Basic Energy Sciences, Materials Sciences and Engineering Division (YFG); College of Engineering at Temple University; State of Florida; National Science Foundation through NSF Cooperative Grant [DMR 0654118] FX This work was sponsored by the Office of Vehicle Technologies of the Department of Energy and was carried out at Oak Ridge National Laboratory under contract DE-AC05-000R22725 with UT-Battelle, LLC. The authors acknowledge the support from NSF CMMI 0900027 (YZX), and the U.S. Department of Energy, Basic Energy Sciences, Materials Sciences and Engineering Division (YFG). FR would like to thank the College of Engineering at Temple University for its financial support during manuscript preparation. TLT would like to acknowledge the support in part by the State of Florida and the National Science Foundation through NSF Cooperative Grant DMR 0654118. NR 18 TC 5 Z9 6 U1 1 U2 30 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0378-7753 EI 1873-2755 J9 J POWER SOURCES JI J. Power Sources PD NOV 1 PY 2014 VL 265 BP 356 EP 362 DI 10.1016/j.jpowsour.2014.04.040 PG 7 WC Chemistry, Physical; Electrochemistry; Energy & Fuels; Materials Science, Multidisciplinary SC Chemistry; Electrochemistry; Energy & Fuels; Materials Science GA AJ7LY UT WOS:000337879400046 ER PT J AU Kus, P Solin, P Andrs, D AF Kus, Pavel Solin, Pavel Andrs, David TI Arbitrary-level hanging nodes for adaptive hp-FEM approximations in 3D SO JOURNAL OF COMPUTATIONAL AND APPLIED MATHEMATICS LA English DT Article; Proceedings Paper CT 4th international conference on finite element methods in engineering and sciences (FEMTEC) CY MAY 19-24, 2013 CL Las Vegas, NV DE Finite element method; Higher-order elements; Constrained approximation; Irregular meshes; Arbitrary-level hanging nodes; Automatic adaptivity AB In this paper we discuss constrained approximation with arbitrary-level hanging nodes in adaptive higher-order finite element methods (hp-FEM) for three-dimensional problems. This technique enables using highly irregular meshes, and it greatly simplifies the design of adaptive algorithms as it prevents refinements from propagating recursively through the finite element mesh. The technique makes it possible to design efficient adaptive algorithms for purely hexahedral meshes. We present a detailed mathematical description of the method and illustrate it with numerical examples. (C) 2014 Elsevier B.V. All rights reserved. C1 [Kus, Pavel; Solin, Pavel] Univ W Bohemia, RICE, Plzen, Czech Republic. [Kus, Pavel] Univ W Bohemia, KTE, Plzen, Czech Republic. [Solin, Pavel] Univ Nevada, Reno, NV 89557 USA. [Andrs, David] INL, Dept Fuels Modeling & Simulat, Idaho Falls, ID USA. RP Kus, P (reprint author), Univ 8, Plzen 30614, Czech Republic. EM pkus@rice.zcu.cz; solin@unr.edu; david.andrs@inl.gov RI Kus, Pavel/H-4757-2013 FU European Regional Development Fund; Ministry of Education, Youth and Sports of the Czech Republic (Regional Innovation Centre for Electrical Engineering RICE) [CZ.1.05/2.1.00/03.0094]; GACR [P102/11/0498] FX This work was supported by the European Regional Development Fund and Ministry of Education, Youth and Sports of the Czech Republic (Project No. CZ.1.05/2.1.00/03.0094: Regional Innovation Centre for Electrical Engineering RICE) and Grant project GACR P102/11/0498. NR 11 TC 5 Z9 5 U1 1 U2 10 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0377-0427 EI 1879-1778 J9 J COMPUT APPL MATH JI J. Comput. Appl. Math. PD NOV PY 2014 VL 270 BP 121 EP 133 DI 10.1016/j.cam.2014.02.010 PG 13 WC Mathematics, Applied SC Mathematics GA AJ4QE UT WOS:000337660100013 ER PT J AU Yang, D Moridis, GJ Blasingame, TA AF Yang, Daegil Moridis, George J. Blasingame, Thomas A. TI A fully coupled multiphase flow and geomechanics solver for highly heterogeneous porous media SO JOURNAL OF COMPUTATIONAL AND APPLIED MATHEMATICS LA English DT Article; Proceedings Paper CT 4th international conference on finite element methods in engineering and sciences (FEMTEC) CY MAY 19-24, 2013 CL Las Vegas, NV DE Coupled multiphase flow and geomechanics; Heterogeneous media; FEM ID MULTIPOINT FLUX APPROXIMATIONS; FINITE-ELEMENT-METHOD; QUADRILATERAL GRIDS; DISCONTINUOUS GALERKIN; EFFECTIVE ELASTICITY; MIXED METHODS; RESERVOIR; SIMULATION; PRESSURE; ROCKS AB This paper introduces a fully coupled multiphase flow and geomechanics solver that can be applied to modeling highly heterogeneous porous media. Multiphase flow in deformable porous media is a multiphysics problem that considers the flow physics and rock physics simultaneously. To model this problem, the multiphase flow equations and geomechanical equilibrium equation must be tightly coupled. Conventional finite element modeling of coupled flow and geomechanics does not conserve mass locally since it uses continuous basis functions. Mixed finite element discretization that satisfies local mass conservation of the flow equation can be a good solution for this problem. In addition, the stabilized finite element method for discretizing the saturation equation minimizes numerical diffusion and provides better resolution of saturation solution. In this work, we developed a coupled multiphase flow and geomechanics solver that solves fully coupled governing equations, namely pressure, velocity, saturation, and geomechanical equilibrium equations. The solver can deal with full tensor permeability and elastic stiffness for modeling a highly heterogeneous reservoir system. The results of the numerical experiments are very encouraging. We used the solver to simulate a reservoir system that has very heterogeneous permeability and elastic stiffness fields and found that the numerical solution captures the complex multiphysics of the system. In addition, we obtained higher resolution of saturation solution than with the conventional finite volume discretization. This would help us make a better estimate of the numerical solution of complex multiphysics problems. (C) 2013 Elsevier B.V. All rights reserved. C1 [Yang, Daegil] Chevron Energy Technol Co, Houston, TX 77002 USA. [Moridis, George J.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Earth Sci, Berkeley, CA 94720 USA. [Moridis, George J.; Blasingame, Thomas A.] Texas A&M Univ, Harold Vance Dept Petr Engn, College Stn, TX 77843 USA. RP Yang, D (reprint author), Chevron Energy Technol Co, Houston, TX 77002 USA. EM daegil.yang@gmail.com FU RPSEA [08122-45] FX This work was supported by RPSEA (Contract No. 08122-45) through the Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum Resources Research and Development Program as authorized by the United States Energy Policy Act of 2005. NR 53 TC 2 Z9 2 U1 1 U2 26 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0377-0427 EI 1879-1778 J9 J COMPUT APPL MATH JI J. Comput. Appl. Math. PD NOV PY 2014 VL 270 BP 417 EP 432 DI 10.1016/j.cam.2013.12.029 PG 16 WC Mathematics, Applied SC Mathematics GA AJ4QE UT WOS:000337660100037 ER PT J AU Price, MN Ray, J Wetmore, KM Kuehl, JV Bauer, S Deutschbauer, AM Arkin, AP AF Price, Morgan N. Ray, Jayashree Wetmore, Kelly M. Kuehl, Jennifer V. Bauer, Stefan Deutschbauer, Adam M. Arkin, Adam P. TI The genetic basis of energy conservation in the sulfate-reducing bacterium Desulfovibrio alaskensis G20 SO FRONTIERS IN MICROBIOLOGY LA English DT Article DE energy metabolism; sulfate reducing bacteria; membrane complexes; Desulfovibrio; electron bifurcation ID VULGARIS HILDENBOROUGH; GENOME SEQUENCE; REDUCTION; HYDROGEN; DESULFURICANS; METABOLISM; MECHANISM; DELETION; COMPLEX; GROWTH AB Sulfate-reducing bacteria play major roles in the global carbon and sulfur cycles, but it remains unclear how reducing sulfate yields energy. To determine the genetic basis of energy conservation, we measured the fitness of thousands of pooled mutants of Desulfovibrio alaskensis G20 during growth in 12 different combinations of electron donors and acceptors. We show that ion pumping by the ferredoxin:NADH oxidoreductase Rnf is required whenever substrate-level phosphorylation is not possible. The uncharacterized complex Hdr/flox-1 (Dde_1207:13) is sometimes important alongside Rnf and may perform an electron bifurcation to generate more reduced ferredoxin from NADH to allow further ion pumping. Similarly, during the oxidation of malate or fumarate, the electron-bifurcating transhydrogenase NfnAB-2 (Dde_1250:1) is important and may generate reduced ferredoxin to allow additional ion pumping by Rnf. During formate oxidation, the periplasmic [NiFeSe] hydrogenase HysAB is required, which suggests that hydrogen forms in the periplasm, diffuses to the cytoplasm, and is used to reduce ferredoxin, thus providing a substrate for Rnf. During hydrogen utilization, the transmembrane electron transport complex Tmc is important and may move electrons from the periplasm into the cytoplasmic sulfite reduction pathway. Finally, mutants of many other putative electron carriers have no clear phenotype, which suggests that they are not important under our growth conditions, although we cannot rule out genetic redundancy. C1 [Price, Morgan N.; Ray, Jayashree; Wetmore, Kelly M.; Kuehl, Jennifer V.; Deutschbauer, Adam M.; Arkin, Adam P.] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Phys Biosci Div, Berkeley, CA 94720 USA. [Bauer, Stefan; Arkin, Adam P.] Univ Calif Berkeley, Energy Biosci Inst, Berkeley, CA 94720 USA. [Arkin, Adam P.] Univ Calif Berkeley, Dept Bioengn, Berkeley, CA 94720 USA. RP Price, MN (reprint author), Univ Calif Berkeley, Lawrence Berkeley Natl Lab, 1 Cyclotron Rd Mail Stop 955-512L, Berkeley, CA 94720 USA. EM morgannprice@yahoo.com; aparkin@lbl.gov RI Ray, Jayashree/F-9162-2016; Arkin, Adam/A-6751-2008; OI Arkin, Adam/0000-0002-4999-2931; Kuehl, Jennifer/0000-0003-2813-2518 FU Office of Science, Office of Biological and Environmental Research, of the U. S. Department of Energy [DE-AC02-05CH11231] FX This work conducted by ENIGMA was supported by the Office of Science, Office of Biological and Environmental Research, of the U. S. Department of Energy under Contract No. DE-AC02-05CH11231. The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript. NR 31 TC 13 Z9 13 U1 5 U2 17 PU FRONTIERS MEDIA SA PI LAUSANNE PA PO BOX 110, EPFL INNOVATION PARK, BUILDING I, LAUSANNE, 1015, SWITZERLAND SN 1664-302X J9 FRONT MICROBIOL JI Front. Microbiol. PD OCT 31 PY 2014 VL 5 AR 577 DI 10.3389/fmicb.2014.00577 PG 20 WC Microbiology SC Microbiology GA CO5GF UT WOS:000359186900001 PM 25400629 ER EF