FN Thomson Reuters Web of Science™ VR 1.0 PT J AU Turgman-Cohen, S Fischer, DA Kilpatrick, PK Genzer, J AF Turgman-Cohen, Salomon Fischer, Daniel A. Kilpatrick, Peter K. Genzer, Jan TI Asphaltene Adsorption onto Self-Assembled Monolayers of Alkyltrichlorosilanes of Varying Chain Length SO ACS APPLIED MATERIALS & INTERFACES LA English DT Article DE asphaltenes; self-assembled monolayers; alklyltrichlorosilanes; NEXAFS; ellipsometry; wettability ID LANGMUIR-BLODGETT MONOLAYERS; QUARTZ-CRYSTAL MICROBALANCE; REFRACTIVE-INDEX; THIN-FILMS; MOLECULAR-ORIENTATION; ADSORBED MONOLAYERS; OPTICAL-PROPERTIES; GLASS-SURFACE; ELLIPSOMETRY; THICKNESS AB The adsorption of asphaltenes onto flat silica surfaces' modified with self-assembled monolayers (SAMS) of alkyltrichlorosilanes of varying thickness due to a variable number. of carbon atoms (N(C)) has been studied by means of contact angle measurements, spectroscopic ellipsometry and near-edge X-ray absorption. fine structure spectroscopy. The extent of asphaltene adsorption was found to depend primarily on the ability of the SAM. layer to shield the underlying silicon substrate from interacting with the asphaltenes present in solution. Specifically, asphaltene adsorption decreased with an,increase in N(C) and/or an increase in SAM grafting density, O(SAM), (i.e., number of SAM molecules per unit area). The effect of the solvent quality on the extent of asphaltene adsorption was gauged by adsorbing asphaltenes from toluene, 1-methylnaphthalene, tetralin, decalin, and toluene-heptanes mixtures. The extent of asphaltene adsorption was found to increase proportionally with a decrease in the Hildebrand solubility parameter of the solvent. C1 [Turgman-Cohen, Salomon; Kilpatrick, Peter K.; Genzer, Jan] N Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA. [Fischer, Daniel A.] Natl Inst Stand & Technol, Div Ceram, Gaithersburg, MD 20899 USA. RP Genzer, J (reprint author), N Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA. EM Peter.Kilpatrick@nd.edu; jan_Genzer@ncsu.cdu RI Kilpatrick, Peter/G-4264-2011; OI Turgman-Cohen, Salomon/0000-0002-4011-2555 NR 52 TC 13 Z9 13 U1 1 U2 14 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1944-8244 J9 ACS APPL MATER INTER JI ACS Appl. Mater. Interfaces PD JUN PY 2009 VL 1 IS 6 BP 1347 EP 1357 DI 10.1021/am900203u PG 11 WC Nanoscience & Nanotechnology; Materials Science, Multidisciplinary SC Science & Technology - Other Topics; Materials Science GA 464NX UT WOS:000267513100031 PM 20355932 ER PT J AU Chai, H Lee, JJW Kwon, JY Lucas, PW Lawn, BR AF Chai, Herzl Lee, James J. -W. Kwon, Jae-Young Lucas, Peter W. Lawn, Brian R. TI A simple model for enamel fracture from margin cracks SO ACTA BIOMATERIALIA LA English DT Article DE Dental enamel; Fracture modes; Margin cracks; Channel cracks; Occlusal loading ID DENTAL CROWNS; MECHANICAL-PROPERTIES; LAYER STRUCTURES; FAILURE; DAMAGE AB We present results of in situ fracture tests on extracted human molar teeth showing failure by margin cracking. The teeth are mounted into an epoxy base and loaded with a rod indenter capped with a Teflon insert, as representative of food modulus. In situ observations of cracks extending longitudinally upward from the cervical margins are recorded in real time with a video camera. The cracks appear above some threshold and grow steadily within the enamel coat toward the occlusal surface in a configuration reminiscent of channel-like cracks in brittle films. Substantially higher loading is required to delaminate the enamel from the dentin, attesting to the resilience of the tooth structure. A simplistic fracture mechanics analysis is applied to determine the critical load relation for traversal of the margin crack along the full length of the side wall. The capacity of any given tooth to resist failure by margin cracking is predicted to increase with greater enamel thickness and cuspal radius. Implications in relation to dentistry and evolutionary biology are briefly considered. Published by Elsevier Ltd. on behalf of Acta Materialia Inc. C1 [Lee, James J. -W.; Lawn, Brian R.] NIST, Div Ceram, Gaithersburg, MD 20899 USA. [Chai, Herzl] Tel Aviv Univ, Fac Engn, Sch Mech Engn, IL-69978 Tel Aviv, Israel. [Kwon, Jae-Young] Changwon Natl Univ, Sch Nano & Adv Mat Engn, Chang Won, Kyung Nam, South Korea. [Lucas, Peter W.] George Washington Univ, Dept Anthropol, Washington, DC 20052 USA. RP Lawn, BR (reprint author), NIST, Div Ceram, Gaithersburg, MD 20899 USA. EM brian.lawn@nist.gov FU GWU Strategic Plan for Academic Excellence; NIST FX Funds from the GWU Strategic Plan for Academic Excellence and NIST internal funds are gratefully acknowledged. Extracted human teeth were supplied by the American Dental Association at NIST. Approval from the NIST Internal Review Board was obtained to test these teeth. NR 23 TC 37 Z9 37 U1 0 U2 5 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 1742-7061 J9 ACTA BIOMATER JI Acta Biomater. PD JUN PY 2009 VL 5 IS 5 BP 1663 EP 1667 DI 10.1016/j.actbio.2008.11.007 PG 5 WC Engineering, Biomedical; Materials Science, Biomaterials SC Engineering; Materials Science GA 451YM UT WOS:000266506800029 PM 19269906 ER PT J AU Sundman, B Ohnuma, I Dupin, N Kattner, UR Fries, SG AF Sundman, Bo Ohnuma, Ikuo Dupin, Nathalie Kattner, Ursula R. Fries, Suzana G. TI An assessment of the entire Al-Fe system including D0(3) ordering SO ACTA MATERIALIA LA English DT Article DE Calphad; Ordering; Compound energy formalism; Phase diagram; Al-Fe ID IRON-ALUMINUM-ALLOYS; THERMODYNAMIC PROPERTIES; PHASE-DIAGRAM; LIQUID IRON; GAMMA-LOOP; X-RAY; SILICON; TRANSFORMATION; CONSTITUTION; EQUILIBRIA AB The Al-Fe system is important for many alloys and the new interest in iron aluminides makes it necessary to improve the modeling of the different ordered forms on the body-centered cubic lattice in this system. This has now been done using a four-sublattice model based on the compound energy formalism, which can describe disordered A2 and the B2, D0(3) and B32 ordering. The chemical and ferromagnetic ordering transitions can be both first and second-order and they have a strong interaction. Almost all available experimental and theoretical data for all phases in the system have been fitted within estimated uncertainties. (C) 2009 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. C1 [Sundman, Bo] UPSICNRSIENSIACET, CIRIMAT, F-31077 Toulouse, France. [Ohnuma, Ikuo] Tohoku Univ, Dept Mat Sci, Sendai, Miyagi 980, Japan. [Dupin, Nathalie] Calcul Thermodynam, FR-63670 Orcet, France. [Kattner, Ursula R.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. [Fries, Suzana G.] SGF Sci Consultancy, Aachen, Germany. [Fries, Suzana G.] Ruhr Univ Bochum, ICAMS, Bochum, Germany. RP Sundman, B (reprint author), UPSICNRSIENSIACET, CIRIMAT, 116 Route Narbonne, F-31077 Toulouse, France. EM bo.sundman@ensiacet.fr RI Fries, suzana/A-5280-2013 NR 70 TC 64 Z9 67 U1 1 U2 32 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 1359-6454 J9 ACTA MATER JI Acta Mater. PD JUN PY 2009 VL 57 IS 10 BP 2896 EP 2908 DI 10.1016/j.actamat.2009.02.046 PG 13 WC Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Materials Science; Metallurgy & Metallurgical Engineering GA 452CY UT WOS:000266518600004 ER PT J AU Allen, AJ Ilavsky, J Braun, A AF Allen, Andrew J. Ilavsky, Jan Braun, Artur TI Multi-scale Microstructure Characterization of Solid Oxide Fuel Cell Assemblies With Ultra Small-Angle X-Ray Scattering SO ADVANCED ENGINEERING MATERIALS LA English DT Article ID ELECTRICAL-CONDUCTIVITY; ANODE; SOFC; CERMET; SULFUR C1 [Allen, Andrew J.] NIST, US Dept Commerce, Gaithersburg, MD 20899 USA. [Ilavsky, Jan] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, Argonne, IL 60439 USA. [Braun, Artur] Empa Swiss Fed Labs Mat Testing & Res, Lab High Performance Ceram, CH-8600 Dubendorf, Switzerland. RP Allen, AJ (reprint author), NIST, US Dept Commerce, Bldg 223,Room B206,100 Bur Dr,Stop 8520, Gaithersburg, MD 20899 USA. EM andrew.allen@nist.gov; ilavsky@aps.anl.gov; artur.braun@alumni.ethz.ch RI Ilavsky, Jan/D-4521-2013; USAXS, APS/D-4198-2013; BRAUN, Artur/A-1154-2009 OI Ilavsky, Jan/0000-0003-1982-8900; BRAUN, Artur/0000-0002-6992-7774 FU European Union [SES6-CT-2003-502612]; Marie Curie Actions [MIRG-CT-2006-042095]; Swiss Competence Center for Energy Mobility [CCEM-705]; U.S. Department of Energy, Office of Science, Office of Basic Energy Science [DE-AC02-06CH11357] FX We arc grateful to Dr. Josef Sfeir, Hexis Ltd. for discussions and providing the SOFC samples, Dr. Christian Soltmann, Empa, for the ceramographic preparation for USAXS, and to Dipl.-Ing. Peter Ried and Roland Bachtold, both Empa, for the optical and scanning electron micrographs, and Dr. Peter Holtappels for fruitful discussions in this project. A.B. is grateful for financial support by the European Union with the Real-SOFC project # contract # SES6-CT-2003-502612 and Marie Curie Actions # MIRG-CT-2006-042095, and by the Swiss Competence Center for Energy & Mobility, project # CCEM-705. Use of the Advanced Photon Source was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Science under contract no. DE-AC02-06CH11357. NR 15 TC 11 Z9 11 U1 0 U2 7 PU WILEY-V C H VERLAG GMBH PI WEINHEIM PA PO BOX 10 11 61, D-69451 WEINHEIM, GERMANY SN 1438-1656 J9 ADV ENG MATER JI Adv. Eng. Mater. PD JUN PY 2009 VL 11 IS 6 BP 495 EP 501 DI 10.1002/adem.200800357 PG 7 WC Materials Science, Multidisciplinary SC Materials Science GA 468VW UT WOS:000267853400012 ER PT J AU Sherman, K Belkin, IM Friedland, KD O'Reilly, J Hyde, K AF Sherman, Kenneth Belkin, Igor M. Friedland, Kevin D. O'Reilly, John Hyde, Kimberly TI Accelerated Warming and Emergent Trends in Fisheries Biomass Yields of the World's Large Marine Ecosystems SO AMBIO LA English DT Article ID FISH PRODUCTION; CLIMATE-CHANGE; PLANKTON ECOSYSTEMS; BERING-SEA; SHELF; OCEAN; MANAGEMENT; DYNAMICS; ATLANTIC; PACIFIC AB Information on the effects of global climate change on trends in global fisheries biomass yields has been limited in spatial and temporal scale. Results are presented of a global study of the impact of sea surface temperature (SST) changes over the last 25 years on the fisheries yields of 63 large marine ecosystems (LMEs) that annually produce 80% of the world's marine fisheries catches. Warming trends were observed in 61 LMEs around the globe. In 18 of the LMEs, rates of SST warming were two to four times faster during the past 25 years than the globally averaged rates of SST warming reported by the Intergovernmental Panel on Climate Change in 2007. Effects of warming on fisheries biomass yields were greatest in the fast-warming northern Northeast Atlantic LMEs, where increasing trends in fisheries biomass yields were related to zooplankton biomass increases. In contrast, fisheries biomass yields of LMEs in the fast-warming, more southerly reaches of the Northeast Atlantic were declining in response to decreases in zooplankton abundance. The LMEs around the margins of the Indian Ocean, where SSTs were among the world's slowest warming, revealed a consistent pattern of fisheries biomass increases during the past 25 years, driven principally by human need for food security from fisheries resources. As a precautionary approach toward more sustainable fisheries utilization, management measures to limit the total allowable catch through a cap-and-sustain approach are suggested for the developing nations recently fishing heavily on resources of the Agulhas Current, Somali Current, Arabian Sea, and Bay of Bengal LMEs. C1 [Sherman, Kenneth; Friedland, Kevin D.; O'Reilly, John; Hyde, Kimberly] NOAA, USDOC, NMFS, NE Fisheries Sci Ctr,Narragansett Lab, Narragansett, RI 02882 USA. [Belkin, Igor M.] Univ Rhode Isl, Grad Sch Oceanog, Narragansett, RI 02882 USA. RP Sherman, K (reprint author), NOAA, USDOC, NMFS, NE Fisheries Sci Ctr,Narragansett Lab, 28 Tarzwell Dr, Narragansett, RI 02882 USA. EM Kenneth.Sherman@noaa.gov; ibelkin@gso.uri.edu; Kevin.Friedland@noaa.gov; Jay.OReilly@noaa.gov; Kimberly.Hyde@noaa.gov NR 71 TC 41 Z9 42 U1 4 U2 34 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0044-7447 EI 1654-7209 J9 AMBIO JI Ambio PD JUN PY 2009 VL 38 IS 4 BP 215 EP 224 PG 10 WC Engineering, Environmental; Environmental Sciences SC Engineering; Environmental Sciences & Ecology GA 463EB UT WOS:000267410900006 PM 19739556 ER PT J AU Kline, MC Duewer, DL Travis, JC Smith, MV Redman, JW Vallone, PM Decker, AE Butler, JM AF Kline, Margaret C. Duewer, David L. Travis, John C. Smith, Melody V. Redman, Janette W. Vallone, Peter M. Decker, Amy E. Butler, John M. TI Production and certification of NIST Standard Reference Material 2372 Human DNA Quantitation Standard SO ANALYTICAL AND BIOANALYTICAL CHEMISTRY LA English DT Article DE Certified reference material (CRM); Decadic attenuance; Forensic; Human identity; Interlaboratory comparison; Short tandem repeat (STR) multiplex assay; Standard Reference Material (SRM); UV/visible absorbance spectrophotometry ID FORENSIC SAMPLES; PCR ASSAY; QUANTIFICATION METHODS; MIXED STAIN; OLIGONUCLEOTIDES; SPECTROSCOPY; PERFORMANCE; PHOSPHORUS AB Modern highly multiplexed short tandem repeat (STR) assays used by the forensic human-identity community require tight control of the initial amount of sample DNA amplified in the polymerase chain reaction (PCR) process. This, in turn, requires the ability to reproducibly measure the concentration of human DNA, [DNA], in a sample extract. Quantitative PCR (qPCR) techniques can determine the number of intact stretches of DNA of specified nucleotide sequence in an extremely small sample; however, these assays must be calibrated with DNA extracts of well-characterized and stable composition. By 2004, studies coordinated by or reported to the National Institute of Standards and Technology (NIST) indicated that a well-characterized, stable human DNA quantitation certified reference material (CRM) could help the forensic community reduce within-and among-laboratory quantitation variability. To ensure that the stability of such a quantitation standard can be monitored and that, if and when required, equivalent replacement materials can be prepared, a measurement of some stable quantity directly related to [DNA] is required. Using a long-established conventional relationship linking optical density (properly designated as decadic attenuance) at 260 nm with [DNA] in aqueous solution, NIST Standard Reference Material (SRM) 2372 Human DNA Quantitation Standard was issued in October 2007. This SRM consists of three quite different DNA extracts: a single-source male, a multiple-source female, and a mixture of male and female sources. All three SRM components have very similar optical densities, and thus very similar conventional [DNA]. The materials perform very similarly in several widely used gender-neutral assays, demonstrating that the combination of appropriate preparation methods and metrologically sound spectrophotometric measurements enables the preparation and certification of quantitation [DNA] standards that are both maintainable and of practical utility. C1 [Kline, Margaret C.; Travis, John C.; Smith, Melody V.; Redman, Janette W.; Vallone, Peter M.; Decker, Amy E.; Butler, John M.] Natl Inst Stand & Technol, Div Biochem Sci, Gaithersburg, MD 20899 USA. [Duewer, David L.] Natl Inst Stand & Technol, Div Analyt Chem, Gaithersburg, MD 20899 USA. RP Kline, MC (reprint author), Natl Inst Stand & Technol, Div Biochem Sci, 100 Bur Dr,MS 8311, Gaithersburg, MD 20899 USA. EM Margaret.Kline@nist.gov RI Butler, John/C-7812-2011 FU National Institute of Justice FX We thank all of the forensic scientists, supervisors, and forensic DNA testing facilities who contributed their expertise, time, and material resources to the interlaboratory assessment. SRM 2372 would not exist except for their encouragement, advice, and willing cooperation with our sometimes seemingly outre requests. The development of SRM 2372 was funded in part by the National Institute of Justice through an interagency agreement with the NIST Office of Law Enforcement Standards. NR 35 TC 19 Z9 19 U1 1 U2 6 PU SPRINGER HEIDELBERG PI HEIDELBERG PA TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY SN 1618-2642 J9 ANAL BIOANAL CHEM JI Anal. Bioanal. Chem. PD JUN PY 2009 VL 394 IS 4 BP 1183 EP 1192 DI 10.1007/s00216-009-2782-0 PG 10 WC Biochemical Research Methods; Chemistry, Analytical SC Biochemistry & Molecular Biology; Chemistry GA 446ZC UT WOS:000266160400029 PM 19377837 ER PT J AU Bicego, MC Zanardi-Lamardo, E Taniguchi, S Martins, CC Da Silva, DAM Sasaki, ST Albergaria-Barbosa, ACR Paol, FS Weber, RR Montone, RC AF Bicego, Marcia C. Zanardi-Lamardo, Eliete Taniguchi, Satie Martins, Cesar C. Da Silva, Denis A. M. Sasaki, Silvio T. Albergaria-Barbosa, Ana C. R. Paol, Fernando S. Weber, Rolf R. Montone, Rosalinda C. TI Results from a 15-year study on hydrocarbon concentrations in water and sediment from Admiralty Bay, King George Island, Antarctica SO ANTARCTIC SCIENCE LA English DT Article DE PAHs; seawater; sewage; South Shetland Islands ID POLYCYCLIC AROMATIC-HYDROCARBONS; MARINE-ENVIRONMENT; ARTHUR HARBOR; ANTHROPOGENIC HYDROCARBONS; PETROLEUM-HYDROCARBONS; MCMURDO-STATION; DAVIS-STATION; FUEL SPILL; OIL-SPILL; SEA AB Admiralty Bay on the King George Island hosts the Brazilian, Polish and Peruvian research stations as well as the American and Ecuadorian field stations. Human activities in this region require the use of fossil fuels as an energy source, thereby placing the region at risk of hydrocarbon contamination. Hydrocarbon monitoring was conducted on water and sediment samples from the bay over 15 years. Fluorescence spectroscopy was used for the analysis of total polycyclic aromatic hydrocarbons (PAHs) in seawater samples and gas chromatography with flame ionization and/or mass spectrometric detection was used to analyse individual n-alkanes and PAHs in sediment samples. The results revealed that most sites contaminated by these Compounds are around the Brazilian and Polish research stations due to the intense human activities, mainly during the summer. Moreover, the sediments revealed the presence of hydrocarbons from different sources, suggesting a mixture of the direct input of oil or derivatives and derived from hydrocarbon combustion. A decrease in PAH concentrations occurred following improvement of the sewage treatment facilities at the Brazilian research station, indicating that the contribution from human waste may be significant. C1 [Bicego, Marcia C.; Zanardi-Lamardo, Eliete; Taniguchi, Satie; Sasaki, Silvio T.; Albergaria-Barbosa, Ana C. R.; Weber, Rolf R.; Montone, Rosalinda C.] Univ Sao Paulo, Inst Oceanog, Lab Quim Organ Marinha, BR-05508900 Sao Paulo, Brazil. [Martins, Cesar C.] Univ Fed Parana, Ctr Estudos Mar, Pontal Do Parana, Parana, Brazil. [Da Silva, Denis A. M.] NOAA Fisheries, NW Fisheries Sci Ctr, Environm Conservat Div, Seattle, WA 98112 USA. [Paol, Fernando S.] Univ Sao Paulo, Inst Astron Geofis & C Atmosfer, Dept Geofis, BR-05508900 Sao Paulo, Brazil. RP Bicego, MC (reprint author), Univ Sao Paulo, Inst Oceanog, Lab Quim Organ Marinha, BR-05508900 Sao Paulo, Brazil. EM marcia@io.usp.br RI ZANARDI-LAMARDO, ELIETE/A-9084-2011; Martins, Cesar/I-1086-2012; Montone, Rosalinda/J-9110-2012; Bicego, Marcia/D-1996-2013; Taniguchi, Satie/D-2552-2013 OI ZANARDI-LAMARDO, ELIETE/0000-0003-3546-6479; Montone, Rosalinda/0000-0002-9586-1000; Taniguchi, Satie/0000-0002-6825-6390 FU Conselho Nacional de Pesquisa (CNPq) FX The authors would like to thank the Brazilian Antarctic Programme (PROANTAR) for the financial support through a grant from the Conselho Nacional de Pesquisa (CNPq) and logistical support from the Secretaria da Comissao Interministerial para os Recursos do Mar (SECIRM). The authors express their gratitude to the staff at the Brazilian Station for their assistance in the collection of samples and members of the Marine Organic Chemistry Laboratory of the Oceanographic Institute of the Universidade de Sao Paulo for their contribution and suggestions. Additional thanks go to the reviewers for their substantial input. NR 42 TC 22 Z9 23 U1 0 U2 17 PU CAMBRIDGE UNIV PRESS PI NEW YORK PA 32 AVENUE OF THE AMERICAS, NEW YORK, NY 10013-2473 USA SN 0954-1020 J9 ANTARCT SCI JI Antarct. Sci. PD JUN PY 2009 VL 21 IS 3 BP 209 EP 220 DI 10.1017/S0954102009001734 PG 12 WC Environmental Sciences; Geography, Physical; Geosciences, Multidisciplinary SC Environmental Sciences & Ecology; Physical Geography; Geology GA 460OG UT WOS:000267196400005 ER PT J AU Yang, WL Lindquist, HDA Cama, V Schaefer, FW Villegas, E Fayer, R Lewis, EJ Feng, YY Xiao, LH AF Yang, Wenli Lindquist, H. D. Alan Cama, Vitaliano Schaefer, Frank W., III Villegas, Eric Fayer, Ronald Lewis, Earl J. Feng, Yaoyu Xiao, Lihua TI Detection of Toxoplasma gondii Oocysts in Water Sample Concentrates by Real-Time PCR SO APPLIED AND ENVIRONMENTAL MICROBIOLOGY LA English DT Article ID POLYMERASE-CHAIN-REACTION; TRANSFER HYBRIDIZATION PROBES; IMMUNOMAGNETIC SEPARATION; CONGENITAL TOXOPLASMOSIS; OCULAR TOXOPLASMOSIS; QUANTITATIVE PCR; INTERNAL CONTROL; DRINKING-WATER; DIAGNOSIS; ASSAY AB PCR techniques in combination with conventional parasite concentration procedures have potential for the sensitive and specific detection of Toxoplasma gondii oocysts in water. Three real-time PCR assays based on the B1 gene and a 529-bp repetitive element were analyzed for the detection of T. gondii tachyzoites and oocysts. Lower sensitivity and specificity were obtained with the B1 gene-based PCR than with the 529-bp repeat-based PCR. New procedures for the real-time PCR detection of T. gondii oocysts in concentrates of surface water were developed and tested in conjunction with a method for the direct extraction of inhibitor-free DNA from water. This technique detected as few as one oocyst seeded to 0.5 ml of packed pellets from water samples concentrated by Envirocheck filters. Thus, this real-time PCR may provide a detection method alternative to the traditional mouse assay and microscopy. C1 [Xiao, Lihua] Ctr Dis Control & Prevent, Div Parasit Dis, Natl Ctr Zoonot Vector Borne & Enter Dis, Atlanta, GA 30341 USA. [Yang, Wenli] Atlanta Res & Educ Fdn, Decatur, GA 30033 USA. [Lindquist, H. D. Alan; Schaefer, Frank W., III] US EPA, Natl Homeland Secur Res Ctr, Cincinnati, OH 45268 USA. [Villegas, Eric] US EPA, Natl Exposure Res Lab, Cincinnati, OH 45268 USA. [Fayer, Ronald] USDA ARS, Beltsville, MD 20705 USA. [Lewis, Earl J.] Natl Ocean & Atmospher Adm, Ctr Coastal Environm Hlth & Biomol Res, Oxford, MD 21654 USA. [Feng, Yaoyu] E China Univ Sci & Technol, Sch Resource & Environm Engn, Shanghai 200237, Peoples R China. RP Xiao, LH (reprint author), Ctr Dis Control & Prevent, Div Parasit Dis, Natl Ctr Zoonot Vector Borne & Enter Dis, Bldg 22,Mail Stop F-12,4770 Buford Highway, Atlanta, GA 30341 USA. EM lxiao@cdc.gov RI Xiao, Lihua/B-1704-2013; Feng, Yaoyu/B-3076-2014; Villegas, Eric/A-7373-2015 OI Xiao, Lihua/0000-0001-8532-2727; Villegas, Eric/0000-0002-8059-8588 FU EPA; National Oceanic and Atmospheric Administration Oceans and Human Health Initiative FX This study was supported in part by funds from the EPA and the National Oceanic and Atmospheric Administration Oceans and Human Health Initiative. NR 58 TC 15 Z9 17 U1 0 U2 11 PU AMER SOC MICROBIOLOGY PI WASHINGTON PA 1752 N ST NW, WASHINGTON, DC 20036-2904 USA SN 0099-2240 J9 APPL ENVIRON MICROB JI Appl. Environ. Microbiol. PD JUN 1 PY 2009 VL 75 IS 11 BP 3477 EP 3483 DI 10.1128/AEM.00285-09 PG 7 WC Biotechnology & Applied Microbiology; Microbiology SC Biotechnology & Applied Microbiology; Microbiology GA 449QT UT WOS:000266345800012 PM 19363083 ER PT J AU Colburn, NT Zaal, KJM Wang, F Tuan, RS AF Colburn, Nona T. Zaal, Kristien J. M. Wang, Francis Tuan, Rocky S. TI A Role for gamma/delta T Cells in a Mouse Model of Fracture Healing SO ARTHRITIS AND RHEUMATISM LA English DT Article ID COLLAGEN-INDUCED ARTHRITIS; IMMUNE MICROENVIRONMENT; INFLAMMATORY RESPONSE; SYSTEMIC IMMUNITY; TISSUE HEMATOMAS; GROWTH-FACTORS; BONE-FRACTURE; MUTANT MICE; IN-VIVO; GAMMA AB Objective. Fractures can initiate an immune response that disturbs osteoblastic and osteoclastic cellular homeostasis through cytokine production and release. The aim of our study was to investigate gamma/delta T cells, innate lymphocytes known to be involved in tissue repair, as potential cellular components of the osteoimmune system's response to an in vivo model of bone injury. The absence of such cells or their effector cytokines influences the fate of other responder cells in proliferation, differentiation, matrix production, and ultimate callus formation. Methods. Tibia fractures were created in 60 gamma/delta T cell-deficient mice (also called 5 T cell receptor [TCR]-knockout mice) and 60 control C57BL/6 mice. Analysis included radiographs, basic histology, mechanical testing, now cytometry, and immunohistochemical localization of gamma/delta TCR-positive subsets from control animals and of CD44 expression from both groups, as well as enzyme-linked immunosorbent assay for the effector cytokines interleukin-2 (IL-2), interferon-gamma (IFN gamma), and IL-6. Results. Animals deficient in gamma/delta T cells demonstrated more mature histologic elements and quantitative increases in the expression of major bone (bone sialoprotein) and cartilage (type II collagen) matrix proteins and in the expression of bone morphogenetic protein 2 at a critical reparative phase. Moreover, only gamma/delta T cell-deficient animals had a decrease in the osteoprogenitor antiproliferative cytokines IL-6 and IFN gamma at the reparative phase. The result was improved stability at the repair site and an overall superior biomechanical strength in gamma/delta T cell-deficient mice compared with controls. Conclusion. The evidence for a role of gamma/delta T cells in the context of skeletal injury demonstrates the importance of the immune system's effect on bone biology, which is relevant to the field of osteoimmunology, and offers a potential molecular platform from which to develop essential therapeutic strategies. C1 [Colburn, Nona T.; Zaal, Kristien J. M.; Tuan, Rocky S.] NIAMSD, NIH, Bethesda, MD 20892 USA. [Wang, Francis] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Colburn, NT (reprint author), NIAMSD, NIH, 9000 Rockville Pike,Bldg 10,Room 10C-212, Bethesda, MD 20892 USA. EM ColburnN@mail.nih.gov FU National Institute of Arthritis and Musculoskeletal and Skin Diseases [Z01-AR-41131]; National Institute of Standards and Technology FX Supported by the NIH (grant Z01-AR-41131 from the Intramural Research Program of the National Institute of Arthritis and Musculoskeletal and Skin Diseases) and the National Institute of Standards and Technology (official contribution of the National Institute of Standards and Technology; not subject to copyright in the United States). NR 56 TC 33 Z9 33 U1 1 U2 3 PU WILEY-LISS PI HOBOKEN PA DIV JOHN WILEY & SONS INC, 111 RIVER ST, HOBOKEN, NJ 07030 USA SN 0004-3591 J9 ARTHRITIS RHEUM JI Arthritis Rheum. PD JUN PY 2009 VL 60 IS 6 BP 1694 EP 1703 DI 10.1002/art.24520 PG 10 WC Rheumatology SC Rheumatology GA 459PV UT WOS:000267116800019 PM 19479830 ER PT J AU Henkel, C Menten, KM Murphy, MT Jethava, N Flambaum, VV Braatz, JA Muller, S Ott, J Mao, RQ AF Henkel, C. Menten, K. M. Murphy, M. T. Jethava, N. Flambaum, V. V. Braatz, J. A. Muller, S. Ott, J. Mao, R. Q. TI The density, the cosmic microwave background, and the proton-to-electron mass ratio in a cloud at redshift 0.9 SO ASTRONOMY & ASTROPHYSICS LA English DT Article DE galaxies: abundances; galaxies: ISM; galaxies: individual: PKS 1830-211; gravitational lensing; radio lines: galaxies; elementary particles ID FINE-STRUCTURE CONSTANT; GRAVITATIONAL LENS B0218+357; EINSTEIN RING PKS-1830-211; RADIO-SOURCE PKS1830-211; PROBE WMAP OBSERVATIONS; MOLECULAR ABSORPTION; PKS 1830-211; RADIATION TEMPERATURE; FUNDAMENTAL CONSTANTS; PHYSICAL CONSTANTS AB Based on measurements with the Effelsberg 100-m telescope, a multi-line study of molecular species is presented toward the gravitational lens system PKS 1830-211, which is by far the best known target to study dense cool gas in absorption at intermediate redshift. Determining average radial velocities and performing Large Velocity Gradient radiative transfer calculations, the aims of this study are (1) to determine the density of the gas, (2) to constrain the temperature of the cosmic microwave background (CMB), and (3) to evaluate the proton-to-electron mass ratio at redshift z similar to 0.89. Analyzing data from six rotational HC3N transitions (this includes the J = 7 <- 6 line, which is likely detected for the first time in the interstellar medium) we obtain n(H-2) similar to 2600 cm(-3) for the gas density of the south-western absorption component, assuming a background source covering factor, which is independent of frequency. With a possibly more realistic frequency dependence proportional to nu(0.5) (the maximal exponent permitted by observational boundary conditions), n(H-2) similar to 1700 cm(-3). Again toward the south-western source, excitation temperatures of molecular species with optically thin lines and higher rotational constants are, on average, consistent with the expected temperature of the cosmic microwave background, T-CMB = 5.14 K. However, individually, there is a surprisingly large scatter which far surpasses expected uncertainties. A comparison of CS J = 1 <- 0 and 4 <- 3 optical depths toward the weaker north-western absorption component results in T-ex = 11 K and a 1-sigma error of 3 K. For the main component, a comparison of velocities determined from ten optically thin NH3 inversion lines with those from five optically thin rotational transitions of HC3N, observed at similar frequencies, constrains potential variations of the proton-to-electron mass ratio mu to Delta mu/mu < 1.4 x 10(-6) with 3-sigma confidence. Also including optically thin rotational lines from other molecular species, it is emphasized that systematic errors are Delta V < 1 km s(-1), corresponding to Delta mu/mu < 1.0 x 10(-6). C1 [Henkel, C.; Menten, K. M.] Max Planck Inst Radioastron, D-53121 Bonn, Germany. [Murphy, M. T.] Swinburne Univ Technol, Ctr Astrophys & Supercomp, Hawthorn, Vic 3122, Australia. [Jethava, N.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. [Flambaum, V. V.] Univ New S Wales, Sch Phys, Sydney, NSW 2052, Australia. [Braatz, J. A.; Ott, J.] Natl Radio Astron Observ, Charlottesville, VA 22903 USA. [Muller, S.] Acad Sinica, Inst Astron & Astrophys, Taipei 106, Taiwan. [Muller, S.] Onsala Space Observ, S-43992 Onsala, Sweden. [Ott, J.] CALTECH, Pasadena, CA 91125 USA. [Mao, R. Q.] Chinese Acad Sci, Purple Mt Observ, Nanjing 210008, Peoples R China. RP Henkel, C (reprint author), Max Planck Inst Radioastron, Hugel 69, D-53121 Bonn, Germany. EM chenkel@mpifr-bonn.mpg.de RI Murphy, Michael/B-8832-2008; OI Murphy, Michael/0000-0002-7040-5498; /0000-0002-9931-1313 FU Australian Research Council [DP0877998] FX It is a pleasure to thank J.N. Chengalur, S. Thorwirth, and C. M. Walmsley for useful discussions and critical reading of the manuscript. M. T. M. thanks the Australian Research Council for a QEII Fellowship (DP0877998). We used NASA's Astrophysical Data System (ADS), the Cologne Database for Molecular Spectroscopy (CDMS; see Muller et al. 2001, 2005), the JPL Catalog (http://spec.jpl.nasa.gov/ftp/pub/catalog/catform.html), and the line lists of Lovas (1992) and Coudert & Roue. (2006). NR 86 TC 62 Z9 62 U1 0 U2 0 PU EDP SCIENCES S A PI LES ULIS CEDEX A PA 17, AVE DU HOGGAR, PA COURTABOEUF, BP 112, F-91944 LES ULIS CEDEX A, FRANCE SN 0004-6361 EI 1432-0746 J9 ASTRON ASTROPHYS JI Astron. Astrophys. PD JUN PY 2009 VL 500 IS 2 BP 725 EP 734 DI 10.1051/0004-6361/200811475 PG 10 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA 462OC UT WOS:000267363100020 ER PT J AU Saikawa, E Naik, V Horowitz, LW Liu, JF Mauzerall, DL AF Saikawa, Eri Naik, Vaishali Horowitz, Larry W. Liu, Junfeng Mauzerall, Denise L. TI Present and potential future contributions of sulfate, black and organic carbon aerosols from China to global air quality, premature mortality and, radiative forcing SO ATMOSPHERIC ENVIRONMENT LA English DT Article DE Aerosols; China; Air pollution; Premature mortality; Health; Radiative forcing ID LONG-TERM EXPOSURE; POLLUTION; ENVIRONMENT; INVENTORY AB Aerosols are harmful to human health and have both direct and indirect effects on climate. China is a major contributor to global emissions of sulfur dioxide (SO2), a sulfate (SO42-) precursor, organic carbon (OC), and black carbon (BC) aerosols. Although increasingly examined, the effect of present and potential future levels of these emissions on global premature mortality and climate change has not been well quantified. Through both direct radiative effects and indirect effects on clouds, SO42- and OC exert negative radiative forcing (cooling) while BC exerts positive forcing (warming). We analyze the effect of China's emissions Of SO2, 4 OC and BC in 2000 and for three emission scenarios in 2030 on global surface aerosol concentrations, premature mortality, and radiative forcing (RF). Using global models of chemical transport (MOZART-2) and radiative transfer (GFDL RTM), and combining simulation results with gridded population data, mortality rates, and concentration-response relationships from the epidemiological literature, we estimate the contribution of Chinese aerosols to global annual premature mortality and to RF in 2000 and 2030. In 2000, we estimate these aerosols cause approximately 470 000 premature deaths in China and an additional 30000 deaths globally. In 2030, aggressive emission controls lead to a 50% reduction in premature deaths from the 2000 level to 240 000 in China and 10 000 elsewhere, while under a high emissions scenario premature deaths increase 50% from the 2000 level to 720 000 in China and to 40 000 elsewhere. Because the negative RF from SO42- and OC is larger than the positive forcing from BC, Chinese aerosols lead to global net direct RF of -74 mW m(-2) in 2000 and between -15 and -97 mW m(-2) in 2030 depending on the emissions scenario. Our analysis indicates that increased effort to reduce greenhouse gases is essential to address climate change as China's anticipated reduction of aerosols will result in the loss of net negative radiative forcing. (C) 2009 Elsevier Ltd. All rights reserved. C1 [Saikawa, Eri; Naik, Vaishali; Liu, Junfeng; Mauzerall, Denise L.] Princeton Univ, Woodrow Wilson Sch Publ & Int Affairs, Princeton, NJ 08544 USA. [Horowitz, Larry W.] Geophys Fluid Dynam Lab, Princeton, NJ 08540 USA. RP Mauzerall, DL (reprint author), Princeton Univ, Woodrow Wilson Sch Publ & Int Affairs, Princeton, NJ 08544 USA. EM mauzeral@princeton.edu RI Mauzerall, Denise/I-5977-2013; Horowitz, Larry/D-8048-2014; Naik, Vaishali/A-4938-2013; OI Mauzerall, Denise/0000-0003-3479-1798; Horowitz, Larry/0000-0002-5886-3314; Naik, Vaishali/0000-0002-2254-1700; Saikawa, Eri/0000-0003-3166-8620 NR 40 TC 51 Z9 54 U1 1 U2 45 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 1352-2310 EI 1873-2844 J9 ATMOS ENVIRON JI Atmos. Environ. PD JUN PY 2009 VL 43 IS 17 BP 2814 EP 2822 DI 10.1016/j.atmosenv.2009.02.017 PG 9 WC Environmental Sciences; Meteorology & Atmospheric Sciences SC Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences GA 452GX UT WOS:000266529400017 ER PT J AU Myles, L Dobosy, RJ Meyers, TP Pendergrass, WR AF Myles, LaToya Dobosy, Ronald J. Meyers, Tilden P. Pendergrass, William R. TI Spatial variability of sulfur dioxide and sulfate over complex terrain in East Tennessee, USA SO ATMOSPHERIC ENVIRONMENT LA English DT Article DE ETOS; Sulfur dioxide; Sulfate; Pollution roses ID FINE PARTICLES; UNITED-STATES; TRANSPORT; AMMONIA AB In 2004 and 2005, the East Tennessee Ozone Study (ETOS) enhanced its regional measurement program with annular denuder systems to quantify sulfur dioxide (SO(2)) and PM(2.5) sulfate (SO(4)(2-)) at five sampling sites that were representative of the complex terrain and physiographic features of East Tennessee. Intersite spatial variability was more defined for SO(2) than for SO(4)(2-), which showed a fairly uniform structure in both daytime and nighttime measurements. Pollution roses indicated that two sites may have been influenced by the proximity Of SO(2) emission sources. The data suggest that SO(2) is affected by nearby sources in the study area while the sources of SO(4)(2-) are regionally distributed. Published by Elsevier Ltd. C1 [Myles, LaToya; Dobosy, Ronald J.; Meyers, Tilden P.; Pendergrass, William R.] NOAA ARL ATDD, Oak Ridge, TN 37831 USA. RP Myles, L (reprint author), NOAA ARL ATDD, POB 2456, Oak Ridge, TN 37831 USA. EM latoya.myles@noaa.gov RI Myles, LaToya/Q-2470-2015; Dobosy, Ronald/C-3303-2016; Meyers, Tilden/C-6633-2016; Pendergrass, William/C-9073-2016 OI Dobosy, Ronald/0000-0001-8399-8774; FU NOAA Office of Oceanic and Atmospheric Research (OAR) FX The East Tennessee Ozone Study has been funded for multiple years by the NOAA Office of Oceanic and Atmospheric Research (OAR). This work is a contribution to the NOAA Air Quality Program. NR 13 TC 10 Z9 10 U1 0 U2 6 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 1352-2310 J9 ATMOS ENVIRON JI Atmos. Environ. PD JUN PY 2009 VL 43 IS 18 BP 3024 EP 3028 DI 10.1016/j.atmosenv.2009.03.007 PG 5 WC Environmental Sciences; Meteorology & Atmospheric Sciences SC Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences GA 452BZ UT WOS:000266515900021 ER PT J AU Fairlie, TD Szykman, J Gilliland, A Pierce, RB Kittaka, C Weber, S Engel-Cox, J Rogers, RR Tikvart, J Scheffe, R Dimmick, F AF Fairlie, T. Duncan Szykman, James Gilliland, Alice Pierce, R. Bradley Kittaka, Chieko Weber, Stephanie Engel-Cox, Jill Rogers, Raymond R. Tikvart, Joe Scheffe, Rich Dimmick, Fred TI Lagrangian sampling of 3-D air quality model results for regional transport contributions to sulfate aerosol concentrations at Baltimore, MD, in summer 2004 SO ATMOSPHERIC ENVIRONMENT LA English DT Article DE Air quality; Source apportionment modeling; CAIR; CMAQ; Satellite; MODIS; Sulfate; Particulate matter ID FINE PARTICULATE MATTER; UNITED-STATES; OPTICAL DEPTH; TRENDS; VALIDATION; OZONE AB We use ensemble-mean Lagrangian sampling of a 3-D Eulerian air quality model, CMAQ together with ground-based ambient monitors data from several air monitoring networks and satellite (MODIS) observations to provide source apportionment and regional transport vs. local contributions to sulfate aerosol and PM2.5 concentrations at Baltimore, MD, for summer 2004. The Lagrangian method provides estimates of the chemical and physical evolution of air arriving in the daytime boundary layer at Baltimore. Study results indicate a dominant role for regional transport contributions on those days when sulfate air pollution is highest in Baltimore, with a principal transport pathway from the Ohio River Valley (ORV) through southern Pennsylvania and Maryland, consistent with earlier studies. Thus, reductions in sulfur emissions from the ORV under the EPA's Clean Air Interstate Rule may be expected to improve particulate air quality in Baltimore during summer. The Lagrangian sampling of CMAQ offers an inexpensive and complimentary approach to traditional methods of source apportionment based on multivariate observational data analysis, and air quality model emissions separation. This study serves as a prototype for the method applied to Baltimore. EPA is establishing a system to allow air quality planners to readily produce and access equivalent results for locations of their choice. Published by Elsevier Ltd. C1 [Fairlie, T. Duncan] US Natl Aeronaut & Space Adm, Langley Res Ctr, Sci Directorate, Hampton, VA 23681 USA. [Szykman, James; Gilliland, Alice; Dimmick, Fred] US EPA, Off Res & Dev, Natl Exposure Res Lab, Res Triangle Pk, NC 27711 USA. [Pierce, R. Bradley] Natl Environm Satellite Data & Informat Serv, Natl Ocean & Atmospher Adm, Madison, WI 53706 USA. [Kittaka, Chieko; Rogers, Raymond R.] Sci Applicat Int Corp SSAI, Hampton, VA 23666 USA. [Weber, Stephanie] Battelle Mem Inst, Columbus, OH 43201 USA. [Engel-Cox, Jill] Battelle Mem Inst, Arlington, VA 22201 USA. [Tikvart, Joe; Scheffe, Rich] US EPA, Off Air Qual Planning & Stand, Res Triangle Pk, NC 27711 USA. RP Fairlie, TD (reprint author), US Natl Aeronaut & Space Adm, Langley Res Ctr, Sci Directorate, Hampton, VA 23681 USA. EM t.d.fairlie@larc.nasa.gov RI Pierce, Robert Bradley/F-5609-2010; Wang, Linden/M-6617-2014 OI Pierce, Robert Bradley/0000-0002-2767-1643; FU NASA Applied Sciences Program; EPA FX We wish to thank Tanya Otte, Alfreida Torian, and colleagues at Research Triangle Park for providing the CMAQ model and MCIP meteorological fields used in this study. We thank CIMSS, University of Wisconsin, for use of the MODIS data. We thank the AERONET and IMPROVE science teams for use of their data. We thank Ray Hoff (UMBQ for use of the ELF data. Thanks to Matt Seybold (NOAA NESDIS), Mike Woodman (Maryland Department of Environment), and to Susan Wierman (Mid-Atlantic Regional Management Association - MARAMA) for reviews on this work. Thanks to Jeff Stehr (University of Maryland), and Dev Roy (US EPA) for their technical input and discussions, and to the anonymous reviewers of this manuscript for their comments and suggestions. We thank Lawrence Friedl and Doreen Neil for supporting this work through the NASA Applied Sciences Program. Additional support was provided by EPA through the EPA Global Earth Observation (GEO) Advance Monitoring Initiative (AMI). The views expressed and findings contained in this paper are those of the authors and should not be construed as official NASA, EPA, NOAA, or U.S. Government position, policy, or decision. NR 39 TC 12 Z9 13 U1 0 U2 7 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 1352-2310 EI 1873-2844 J9 ATMOS ENVIRON JI Atmos. Environ. PD JUN PY 2009 VL 43 IS 20 BP 3275 EP 3288 DI 10.1016/j.atmosenv.2009.02.026 PG 14 WC Environmental Sciences; Meteorology & Atmospheric Sciences SC Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences GA 459PY UT WOS:000267117100015 ER PT J AU Arifuzzaman, S Ozcam, AE Efimenko, K Fischer, DA Genzer, J AF Arifuzzaman, Shafi Oezcam, Ali E. Efimenko, Kirill Fischer, Daniel A. Genzer, Jan TI Formation of surface-grafted polymeric amphiphilic coatings comprising ethylene glycol and fluorinated groups and their response to protein adsorption SO BIOINTERPHASES LA English DT Article DE adsorption; atomic force microscopy; biomedical materials; contact angle; ellipsometry; hydrophilicity; hydrophobicity; infrared spectra; polymer blends; polymer films; polymerisation; proteins; surface chemistry; X-ray absorption ID SELF-ASSEMBLED MONOLAYERS; INITIATED POLY(HYDROXYETHYL METHACRYLATE); HYPERBRANCHED FLUOROPOLYMER; BLOCK-COPOLYMERS; SIDE-CHAINS; FILMS; ATRP; FIBRINOGEN; BRUSHES; MODEL AB Amphiphilic polymer coatings were prepared by first generating surface-anchored polymer layers of poly(2-hydroxyethyl methacrylate) (PHEMA) on top of flat solid substrates followed by postpolymerization reaction on the hydroxyl terminus of HEMA's pendent group using three classes of fluorinating agents, including organosilanes, acylchlorides, and trifluoroacetic anhydride (TFAA). The distribution of the fluorinated groups inside the polymer brushes was assessed by means of a suite of analytical probes, including contact angle, ellipsometry, infrared spectroscopy, atomic force microscopy, and near-edge x-ray absorption fine structure spectroscopy. While organosilane modifiers were found to reside primarily close to the tip of the brush, acylchlorides penetrated deep inside PHEMA thus forming random copolymers P(HEMA-co-fHEMA). The reaction of TFAA with the PHEMA brush led to the formation of amphiphilic diblocks, PHEMA-b-P(HEMA-co-fHEMA), whose bottom block comprised unmodified PHEMA and the top block was made of P(HEMA-co-fHEMA) rich in the fluorinated segments. This distribution of the fluorinated groups endowed PHEMA-b-P(HEMA-co-fHEMA) with responsive properties; while in hydrophobic environment P(HEMA-co-fHEMA) segregated to the surface, when in contact with a hydrophilic medium, PHEMA partitioned at the brush surface. The surface activity of the amphiphilic coatings was tested by studying the adsorption of fibrinogen (FIB). While some FIB adsorption occurred on most coatings, the ones made by TFAA modification of PHEMA remained relatively free of FIB. C1 [Arifuzzaman, Shafi; Oezcam, Ali E.; Efimenko, Kirill; Genzer, Jan] N Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA. [Fischer, Daniel A.] Natl Inst Stand & Technol, Div Ceram, Gaithersburg, MD 20899 USA. RP Arifuzzaman, S (reprint author), N Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA. EM jan_genzer@ncsu.edu NR 50 TC 23 Z9 23 U1 2 U2 41 PU AVS PI RESEARCH TRIANGLE PARK PA EDITORIAL OFFICE, 100 PARK DR, STE 105, CALLER BOX 13994, RESEARCH TRIANGLE PARK, NC 27709 USA SN 1559-4106 J9 BIOINTERPHASES JI Biointerphases PD JUN PY 2009 VL 4 IS 2 BP FA33 EP FA44 DI 10.1116/1.3114502 PG 12 WC Biophysics; Materials Science, Biomaterials SC Biophysics; Materials Science GA 457ZC UT WOS:000266976300005 PM 20408715 ER PT J AU Dorsey, SM Lin-Gibson, S Simon, CG AF Dorsey, Shauna M. Lin-Gibson, Sheng Simon, Carl G., Jr. TI X-ray microcomputed tomography for the measurement of cell adhesion and proliferation in polymer scaffolds SO BIOMATERIALS LA English DT Article DE 3D imaging; Cell adhesion; Cell proliferation; Polymer scaffold; Salt-leaching; X-ray microcomputed tomography ID TISSUE ENGINEERING SCAFFOLDS; OPTIMIZATION; ASSAY; LINE AB We have explored the use of X-ray microcomputed tomography (mu CT) for assessing cell adhesion and proliferation in polymer scaffolds. Common methods for examining cells in scaffolds include fluorescence microscopy and soluble assays for cell components such as enzymes, protein or DNA. Fluorescence microscopy is generally qualitative and cannot visualize the scaffold interior. Soluble assays quantitatively measure cell number but do not yield information on cell spatial distribution. Herein, the ability of mu CT to detect cells in scaffolds was compared with fluorescence microscopy and a soluble DNA assay. Comparisons were performed using polymer scaffolds that were seeded with cells at different densities and cultured for different times. The results showed that fluorescence microscopy had better resolution than mu CT and that the soluble DNA assay was approximately 5x more sensitive than mu CT under the conditions tested. However, mu CT was able to image through opaque scaffolds to yield quantitative 3D imaging and analysis via a single, non-invasive modality. Quantitative mu CT analysis of cell penetration into scaffolds was demonstrated. Further, quantitative mu CT volume analysis required that the cell density in the scaffolds be greater than 1 million cells per mL indicating that mu CT is best suited for quantifying cells at relatively high density during culture in scaffolds. In sum, the results demonstrate the benefits and limitations of using mu CT for 3D imaging and analysis of cell adhesion and proliferation in polymer scaffolds. Published by Elsevier Ltd. C1 [Dorsey, Shauna M.; Lin-Gibson, Sheng; Simon, Carl G., Jr.] Natl Inst Stand & Technol, Div Polymer, Gaithersburg, MD 20899 USA. RP Simon, CG (reprint author), Natl Inst Stand & Technol, Div Polymer, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM carl.simon@nist.gov FU NIST-NSF; NIST; NIH/NIBIB [R21 EB006497-01] FX We acknowledge valuable contributions from Jirun Sun, Nancy Lin, Diana Zeiger, Yanyin Yang (all from NIST) and Morgan Alexander (University of Nottingham). S.M.D. acknowledges support from the NIST-NSF summer undergraduate research fellowship (SURF). This work was supported by NIST and by NIH/NIBIB R21 EB006497-01. Standard deviation (S.D.) is the same as the combined standard uncertainty for the purposes of this work. The content is solely the responsibility of the authors and does not necessarily represent the official views of the NIH, NIBIB or NIST. This article, a contribution of NIST, is not subject to U.S. copyright. Certain equipment and instruments or materials are identified in the paper to adequately specify the experimental details. Such identification does not imply recommendation by NIST, nor does it imply the materials are necessarily the best available for the purpose. NR 24 TC 26 Z9 26 U1 2 U2 14 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0142-9612 J9 BIOMATERIALS JI Biomaterials PD JUN PY 2009 VL 30 IS 16 BP 2967 EP 2974 DI 10.1016/j.biomaterials.2009.02.032 PG 8 WC Engineering, Biomedical; Materials Science, Biomaterials SC Engineering; Materials Science GA 446UY UT WOS:000266148100001 PM 19286251 ER PT J AU Wang, WG AF Wang, Weiguo TI The Influence of Thermally-Induced Mesoscale Circulations on Turbulence Statistics Over an Idealized Urban Area Under a Zero Background Wind SO BOUNDARY-LAYER METEOROLOGY LA English DT Article DE Isolated urban area; Large-eddy simulation; Mixed layer; Thermally-induced mesoscale circulation; Urban boundary layer ID CONVECTIVE BOUNDARY-LAYER; LARGE-EDDY-SIMULATION; VERTICAL-VELOCITY SKEWNESS; ORGANIZED STRUCTURES; MIXING-HEIGHT; LAND-SURFACE; FLUXES; MODEL; FLOW; ATMOSPHERE AB The influence of mesoscale circulations induced by urban-rural differential surface sensible heat flux and roughness on convective boundary-layer (CBL) flow statistics over an isolated urban area has been examined using large-eddy simulation (LES). Results are analyzed when the circulations influence the entire urban area under a zero background wind. For comparison, the CBL flow over an infinite urban area with identical urban surface characteristics under the same background meteorological conditions is generated as a control case (without circulations). The turbulent flow over the isolated urban area exhibits a mix of streaky structure and cellular pattern, while the cellular pattern dominates in the control case. The mixed-layer height varies significantly over the isolated urban area, and can be lower near the edge of the urban area than over the rural area. The vertical profiles of turbulence statistics over the isolated urban area vary horizontally and are dramatically different from the control case. The turbulent kinetic energy (TKE) sources include wind shear, convergence, and buoyancy productions, compared to only buoyancy production in the control case. The normalized vertical velocity variance is reduced compared to the control case except in the central urban area where it is little affected. The low-level flow convergence is mainly responsible for the enhanced horizontal velocity variance in the central urban area, while wind shear is responsible for the additional local maximum of the horizontal velocity variance near the middle of the CBL outside the central area. Parameterizations in the prognostic equation for TKE used in mesoscale models are evaluated against the LES results over the isolated urban area. We also discuss conditions under which the urban-induced circulations occur and when they may affect the entire urban area. Given that urban-induced circulations can influence the entire urban area within hours for an urban area of a realistic size, it is inappropriate to directly apply empirical relations of turbulence statistics derived under horizontally-homogenous flow conditions to an urban area. C1 NOAA, EMC, IMSG Natl Ctr Environm Predict, Camp Springs, MD 20746 USA. RP Wang, WG (reprint author), NOAA, EMC, IMSG Natl Ctr Environm Predict, Rm 207,5200 Auth Rd, Camp Springs, MD 20746 USA. EM wang_wg@yahoo.com RI Wang, Weiguo/B-4948-2009 NR 41 TC 20 Z9 21 U1 0 U2 9 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0006-8314 J9 BOUND-LAY METEOROL JI Bound.-Layer Meteor. PD JUN PY 2009 VL 131 IS 3 BP 403 EP 423 DI 10.1007/s10546-009-9378-2 PG 21 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 442HD UT WOS:000265831400005 ER PT J AU Demargne, J Mullusky, M Werner, K Adams, T Lindsey, S Schwein, N Marosi, W Welles, E AF Demargne, Julie Mullusky, Mary Werner, Kevin Adams, Thomas Lindsey, Scott Schwein, Noreen Marosi, William Welles, Edwin TI Application of Forecast Verification Science to Operational River Forecasting in the US National Weather Service SO BULLETIN OF THE AMERICAN METEOROLOGICAL SOCIETY LA English DT Article AB Forecast verification in operational hydrology has been very limited to date, mainly due to the complexity of verifying both forcing input forecasts and hydrologic forecasts on multiple space-time scales. However, forecast verification needs to be the driver in both hydrologic research and operations to help advance the understanding of predictability and help the diverse users better utilize the river forecasts. Therefore, in NOAA's National Weather Service, the Hydrologic Services Program is developing a comprehensive river forecast verification service to routinely and systematically verify all hydrometeorological and hydrologic forecasts. This verification service will include capabilities for archiving forecast and observed data, evaluating logistical properties of the forecast services, computing a variety of verification metrics to evaluate the different aspects of forecast quality, displaying and disseminating verification data and metrics, and analyzing the sources of forecast skill and uncertainty through the use of multiple forecast and hindcast scenarios. This paper describes ongoing and planned verification activities for enhancing the collaboration between the meteorological and hydrologic research and operational communities to quantify forecast improvements based on rigorous forecast verification. C1 [Demargne, Julie] NOAA, Off Hydrol Dev, Natl Weather Serv, Silver Spring, MD 20910 USA. [Demargne, Julie] Univ Corp Atmospher Res, Boulder, CO USA. [Mullusky, Mary] NOAA, Off Climate Water & Weather Serv, Natl Weather Serv, Silver Spring, MD 20910 USA. [Werner, Kevin] NOAA, Colorado Basin River Forecast Ctr, Natl Weather Serv, Salt Lake City, UT USA. [Adams, Thomas] NOAA, Ohio River Forecast Ctr, Natl Weather Serv, Wilmington, OH USA. [Lindsey, Scott] NOAA, Alaska Pacific River Forecast Ctr, Natl Weather Serv, Anchorage, AK USA. [Schwein, Noreen] NOAA, Cent Reg Headquarters, Natl Weather Serv, Kansas City, MO USA. [Marosi, William] NOAA, Middle Atlantic River Forecast Ctr, Natl Weather Serv, State Coll, PA USA. [Welles, Edwin] NOAA, Off Sci & Technol, Natl Weather Serv, Silver Spring, MD 20910 USA. RP Demargne, J (reprint author), NOAA, Off Hydrol Dev, Natl Weather Serv, 1325 EW Highway,Bldg SSMC 2, Silver Spring, MD 20910 USA. EM Julie.Demargne@noaa.gov NR 10 TC 19 Z9 19 U1 1 U2 7 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0003-0007 EI 1520-0477 J9 B AM METEOROL SOC JI Bull. Amer. Meteorol. Soc. PD JUN PY 2009 VL 90 IS 6 BP 779 EP 784 DI 10.1175/2008BAMS2619.1 PG 6 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 476VE UT WOS:000268473500002 ER PT J AU Pandya, RE Smith, DR Charlevoix, DJ Hart, W Hayes, MJ Murillo, ST Murphy, KA Stanitski, DM Whittaker, TM AF Pandya, Rajul E. Smith, David R. Charlevoix, Donna J. Hart, Wayne Hayes, Marianne J. Murillo, Shirley T. Murphy, Kathleen A. Stanitski, Diane M. Whittaker, Thomas M. TI A SUMMARY OF THE 16TH SYMPOSIUM ON EDUCATION SO BULLETIN OF THE AMERICAN METEOROLOGICAL SOCIETY LA English DT Editorial Material C1 [Pandya, Rajul E.] UCAR SOARS Program, Boulder, CO 80307 USA. [Smith, David R.] USN Acad, Annapolis, MD 21402 USA. [Charlevoix, Donna J.] Univ Illinois, Urbana, IL 61801 USA. [Hart, Wayne] WHT TV, Evansville, IN USA. [Hayes, Marianne J.] Fairfax Cty Publ Sch, Springfield, VA USA. [Murillo, Shirley T.] NOAA, Atlantic Oceanog & Meteorol Lab, Hurricane Res Div, Miami, FL 33149 USA. [Murphy, Kathleen A.] Ladue Sch Dist, St Louis, MO USA. [Stanitski, Diane M.] Geocation LLC, Boulder, CO USA. [Whittaker, Thomas M.] Univ Wisconsin, Space Sci & Engn Ctr, Cooperat Inst Meteorol Satellite Studies, Madison, WI USA. RP Pandya, RE (reprint author), UCAR SOARS Program, POB 3000, Boulder, CO 80307 USA. EM pandya@ucar.edu RI Murillo, Shirley/C-3259-2014 OI Murillo, Shirley/0000-0002-2075-8682 NR 0 TC 0 Z9 0 U1 0 U2 0 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0003-0007 J9 B AM METEOROL SOC JI Bull. Amer. Meteorol. Soc. PD JUN PY 2009 VL 90 IS 6 BP 861 EP 865 DI 10.1175/2009BAMS2510.1 PG 5 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 476VE UT WOS:000268473500009 ER PT J AU Kotwicki, S Robertis, A von Szalay, P Towler, R AF Kotwicki, Stan De Robertis, Alex von Szalay, Paul Towler, Rick TI The effect of light intensity on the availability of walleye pollock (Theragra chalcogramma) to bottom trawl and acoustic surveys SO CANADIAN JOURNAL OF FISHERIES AND AQUATIC SCIENCES LA English DT Article ID DIEL VERTICAL MIGRATION; EASTERN BERING-SEA; FISH DISTRIBUTION; DEMERSAL FISH; CATCH RATES; BARENTS SEA; NORTH-SEA; ATLANTIC; BEHAVIOR; TEMPERATURE AB Quantitative assessment of semidemersal fish such as walleye pollock (Theragra chalcogramma) is difficult because the proportion of walleye pollock available to standardized surveys varies temporally and spatially. The US National Marine Fisheries Service's Alaska Fisheries Science Center conducts bottom trawl (BT) surveys to estimate the demersal portion of the walleye pollock population and acoustic trawl (AT) surveys to estimate the pelagic portion. Both surveys are conducted during daylight hours to minimize variability due to diel changes in vertical distribution. To test if daytime near-bottom light intensity affects the proportion of walleye pollock available to the BT survey, we concurrently measured light and walleye pollock abundance on the Bering Sea shelf. Logistic regression models demonstrated that both light and depth affected walleye pollock abundance estimates by either BT or AT surveys, with more walleye pollock available to the BT survey under high illumination and at shallow depths and less walleye pollock available to the AT survey under these conditions. This finding suggests that daytime survey catchability for walleye pollock depends on depth and light intensity and that incorporation of light measurements could improve the precision of abundance estimates of semidemersal species such as walleye pollock. C1 [Kotwicki, Stan; De Robertis, Alex; von Szalay, Paul; Towler, Rick] NOAA, Natl Marine Fisheries Serv, Alaska Fisheries Sci Ctr, Seattle, WA 98115 USA. RP Kotwicki, S (reprint author), NOAA, Natl Marine Fisheries Serv, Alaska Fisheries Sci Ctr, 7600 Sand Point Way NE, Seattle, WA 98115 USA. EM stan.kotwicki@noaa.gov RI Kotwicki, Stan/C-3599-2009 FU NOAA's; AFSC; Advanced Sampling Technology Working Group FX Foremost, we thank all people from the AFSC who helped in our data collection. We thank Lyle Britt and Ellis R. Loew for assessing the usefulness of the MK-9 sensors and for building a calibrator, which we used for monitoring the accuracy of our sensors. We also thank Rich Titgen and Cliff Ryer for calibrating the MK-9s and for technical support and discussions, Dave Somerton for continuous support and advice, Craig Rose for lending us two light meters in the first year of this study, Kazimierz Dymowski for help in manufacturing device housings, Paul Walline and Steve Syrjala for statistical discussions, Dionne Andersen for help in data processing, and all the reviewers of the previous versions of this manuscript. We also thank NOAA's AFSC and Advanced Sampling Technology Working Group for financing our project. Reference to trade names does not imply endorsement by the National Marine Fishery Service, NOAA. NR 55 TC 17 Z9 17 U1 0 U2 5 PU NATL RESEARCH COUNCIL CANADA-N R C RESEARCH PRESS PI OTTAWA PA BUILDING M 55, OTTAWA, ON K1A 0R6, CANADA SN 0706-652X J9 CAN J FISH AQUAT SCI JI Can. J. Fish. Aquat. Sci. PD JUN PY 2009 VL 66 IS 6 BP 983 EP 994 DI 10.1139/F09-055 PG 12 WC Fisheries; Marine & Freshwater Biology SC Fisheries; Marine & Freshwater Biology GA 469CU UT WOS:000267873800010 ER PT J AU Larese, JP Chivers, SJ AF Larese, Jason P. Chivers, Susan J. TI Growth and reproduction of female eastern and whitebelly spinner dolphins incidentally killed in the eastern tropical Pacific tuna purse-seine fishery SO CANADIAN JOURNAL OF ZOOLOGY-REVUE CANADIENNE DE ZOOLOGIE LA English DT Article ID STENELLA-LONGIROSTRIS; AERIAL PHOTOGRAMMETRY; DELPHINUS-DELPHIS; GEOGRAPHIC-VARIATION; OFFSHORE WATERS; POPULATION-SIZE; COMMON DOLPHIN; OCEAN; ATTENUATA; PORPOISE AB Life-history parameters are estimated for two forms of the spinner dolphin (Stenella longirostris (Gray, 1828)): the eastern subspecies (Stenella longirostris orientalis Perrin, 1990) and the whitebelly hybrid. The data analyzed (n = 3138 eastern and 3099 whitebelly spinner dolphins) were collected between 1968 and 1994 from female dolphins incidentally killed in the yellowfin tuna (Thunnus albacares (Bonnaterre, 1788)) purse-seine fishery that operates in the eastern tropical Pacific Ocean. Eastern spinner dolphins averaged 79.7 cm at birth, 121.5 cm at 1 year, and 171.5 cm at asymptotic length, and had a mean annual pregnancy rate of 0.351 and a calving interval of 2.84 years. Whitebelly spinner dolphins averaged 80.2 cm at birth, 122.5 cm at 1 year, and 177.1 cm at asymptotic length, and had a mean annual pregnancy rate of 0.329 and calving interval of 3.04 years. The mean age at attainment of sexual maturity was estimated to be 8.7 and 8.4 years for eastern and whitebelly spinner dolphins, respectively, which are 3.2 and 1.7 years older than those previously published. This difference indicates that the mean reproductive output during a female's life is lower than previously expected and likely translates into lower population growth rates. C1 [Larese, Jason P.; Chivers, Susan J.] NOAA, NMFS, SW Fisheries Sci Ctr, La Jolla, CA 92037 USA. RP Chivers, SJ (reprint author), NOAA, NMFS, SW Fisheries Sci Ctr, 8604 La Jolla Shores Dr, La Jolla, CA 92037 USA. EM susan.chivers@noaa.gov NR 63 TC 3 Z9 3 U1 2 U2 14 PU NATL RESEARCH COUNCIL CANADA-N R C RESEARCH PRESS PI OTTAWA PA BUILDING M 55, OTTAWA, ON K1A 0R6, CANADA SN 0008-4301 J9 CAN J ZOOL JI Can. J. Zool.-Rev. Can. Zool. PD JUN PY 2009 VL 87 IS 6 BP 537 EP 552 DI 10.1139/Z09-038 PG 16 WC Zoology SC Zoology GA 459BS UT WOS:000267075500009 ER PT J AU Moss, S Keller, JM Richards, S Wilson, TP AF Moss, Stefan Keller, Jennifer M. Richards, Sean Wilson, Thomas P. TI Concentrations of persistent organic pollutants in plasma from two species of turtle from the Tennessee River Gorge SO CHEMOSPHERE LA English DT Article DE Reptile; Organochlorine; Brominated flame retardant; Chelonians; American rivers ID POLYBROMINATED DIPHENYL ETHERS; GREAT-LAKES BASIN; ORGANOCHLORINE PESTICIDES; SNAPPING TURTLES; POLYCHLORINATED-BIPHENYLS; CHELYDRA-SERPENTINA; SEX DETERMINATION; FLAME RETARDANTS; MARINE TURTLES; COMMON CARP AB Persistent organic Pollutants (POPs) are characterized by their resistance to degradation, biomagnification, global transport. and adverse toxicological effects. The goal of this study was to determine baseline concentrations of several classes of POPs, including polychlorinated biphenyls (PCBs), organochlorine pesticides, and polybrominated diphenyl ethers (PBDEs) in two turtle species, the Cumberland slider (Trachemys scripta troosti) and the common musk turtle (Sternotherus odoratus) from the Tennessee River Gorge. Plasma samples from five male and five female adults of each species were analyzed for concentrations of 83 PCB congeners, six DDT compounds, four toxaphene congeners, 18 additional pesticides, pentachlorobenzene, octachlorostyrene, and 28 PBDE congeners using gas chromatography/mass spectrometry. In both species, total PCBs were the predominant contaminant class, at approximately 10-fold higher concentration than p,p'-DDE, total PBDEs, and total chlordanes. Mirex, dieldrin and one toxaphene congener (Parlar 50) were also detected at even lower concentrations. The female turtles had lower concentrations of some contaminants (PCB 153 + 132. oxychlordane, mirex. PBDE 153, PBDE 154, Sigma PBDEs) than males, suggesting maternal transfer to eggs. Cumberland sliders had lower concentrations of PCB 138, p,p'-DDE, Sigma DDTs, oxychlordane, PBDE 47, and PBDE 99 than musk turtles. The turtles had a unique PBDE pattern with PBDE 100 predominating. The POP concentrations were lower than those measured previously in other reptiles from contaminated sites where endocrine disruption has been observed. One exception was a female musk turtle with 29.9 ng g(-1) p,p'-DDE (wet mass basis), which is greater than the concentrations measured in reptiles with evidence of endocrine disruption. Additional monitoring and research is necessary to determine if other species or age classes in this turtle assemblage might be at higher risk of POP accumulation, as well as to assess the potential risk of these concentrations on their health and reproduction. (C) 2009 Elsevier Ltd. All rights reserved. C1 [Moss, Stefan; Richards, Sean; Wilson, Thomas P.] Univ Tennessee, Dept Biol & Environm Sci, Chattanooga, TN 37403 USA. [Keller, Jennifer M.] Natl Inst Stand & Technol, Div Analyt Chem, Hollings Marine Lab, Charleston, SC 29412 USA. [Wilson, Thomas P.] Tennessee Aquarium Res Inst, Chattanooga, TN 37401 USA. RP Wilson, TP (reprint author), Univ Tennessee, Dept Biol & Environm Sci, Chattanooga, TN 37403 USA. EM Thomas-wilson@utc.edu FU Lupton Renaissance Gift Fund [UCFRF-R040152003]; NIST; Institutional Review Board [UTC IRB 05-267]; IACUC [1205TPW-01, 0506TPW-02]; Tennessee Wildlife Resource Agency [TWRA 1534, 3082] FX We would like to thank the following individuals for reviewing this manuscript Drs. Karen Adsit, John Tucker, Mark Schorr, and John Kucklick. Additionally, we would like to thank those involved with the collection of field data, especially Dr. Wilson's Turtle crew, Chris Manis, Robert Minton, Dave Collins, Tim Schmeidhausen, Dr. Chris Keller, Dr. Mark Schorr, Jack Pickett, Kim Brown, and Steve Price. We thank Dr. Mark Schorr for statistical advice and support. Research was funded by the Lupton Renaissance Gift Fund (UCFRF-R040152003) under direction of Dr. Thomas P. Wilson and assistance in-kind was provided by NIST for contaminant analysis. All work was conducted under the following permits/approvals: Institutional Review Board (UTC IRB# 05-267), IACUC (1205TPW-01, 0506TPW-02) and Tennessee Wildlife Resource Agency (TWRA # 1534 and 3082 issued to Dr. Thomas P. Wilson). Lastly, we thank Dave Collins of the Tennessee Aquarium, George Benz and Paul Johnson of the Tennessee Aquarium Research Institute (TNARI), Charles Nelson and John Sharer of the University of Tennessee at Chattanooga, Department of Biological and Environmental Sciences, and Jim Brown of the Tennessee River Gorge Trust for support. NR 52 TC 21 Z9 22 U1 2 U2 23 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0045-6535 J9 CHEMOSPHERE JI Chemosphere PD JUN PY 2009 VL 76 IS 2 BP 194 EP 204 DI 10.1016/j.chemosphere.2009.03.054 PG 11 WC Environmental Sciences SC Environmental Sciences & Ecology GA 460AJ UT WOS:000267155600007 PM 19406450 ER PT J AU Liang, JY Yang, S Hu, ZZ Huang, BH Kumar, A Zhang, ZQ AF Liang, Jianyin Yang, Song Hu, Zeng-Zhen Huang, Bohua Kumar, Arun Zhang, Zuqiang TI Predictable patterns of the Asian and Indo-Pacific summer precipitation in the NCEP CFS SO CLIMATE DYNAMICS LA English DT Article DE Asian monsoon; Predictable patterns; NCEP climate forecast system ID SEA-SURFACE TEMPERATURE; TROPICAL ATLANTIC; INDIAN-OCEAN; MONSOON; ENSO; CLIMATE; VARIABILITY; MODEL; INITIALIZATION; TELECONNECTION AB The predictable patterns of the Asian and Indo-Pacific summer precipitation in the NCEP climate forecast system (CFS) are depicted by applying a maximized signal-to-noise empirical orthogonal function analysis. The CFS captures the two most dominant modes of observed climate patterns. The first most dominant mode is characterized by the climate features of the onset years of El NiA +/- o-Southern Oscillation (ENSO), with strong precipitation signals over the tropical eastern Indian and western Pacific oceans, Southeast Asia, and tropical Asian monsoon regions including the Bay of Bengal and the South China Sea. The second most dominant mode is characterized by the climate features of the decay years of ENSO, with weakening signals over the western-central Pacific and strengthening signals over the Indian Ocean. The CFS is capable of predicting the most dominant modes several months in advance. It is also highly skillful in capturing the air-sea interaction processes associated with the precipitation features, as demonstrated in sea surface temperature and wind patterns. C1 [Yang, Song; Kumar, Arun] NOAA, NWS, NCEP Climate Predict Ctr, Camp Springs, MD 20746 USA. [Liang, Jianyin] CMA Inst Trop & Marine Meteorol, Guangzhou, Guangdong, Peoples R China. [Hu, Zeng-Zhen] Ctr Ocean Land Atmosphere Studies, Calverton, MD USA. [Huang, Bohua] George Mason Univ, Dept Climate Dynam, Fairfax, VA 22030 USA. [Zhang, Zuqiang] CMA Natl Climate Ctr, Beijing, Peoples R China. RP Yang, S (reprint author), NOAA, NWS, NCEP Climate Predict Ctr, 5200 Auth Rd,Room 605, Camp Springs, MD 20746 USA. EM song.yang@noaa.gov RI Yang, Song/B-4952-2009; Hu, Zeng-Zhen/B-4373-2011 OI Hu, Zeng-Zhen/0000-0002-8485-3400 FU U. S. National Oceanic and Atmospheric Administration; China Meteorological Administration; NOAA [NA04OAR4310115] FX Jianyin Liang and Zuqiang Zhang, partially supported by the U. S. National Oceanic and Atmospheric Administration and the China Meteorological Administration bilateral program on climate and monsoons, thanks to NOAA's Climate Prediction Center (CPC) for hosting their visits while this study was conducted. Drs. Wanqiu Wang and Qin Zhang of CPC provided constructive comments on an earlier version of the manuscript. Zeng-Zhen Hu and Bohua Huang were supported by NOAA grant NA04OAR4310115. NR 38 TC 39 Z9 39 U1 1 U2 5 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0930-7575 J9 CLIM DYNAM JI Clim. Dyn. PD JUN PY 2009 VL 32 IS 7-8 BP 989 EP 1001 DI 10.1007/s00382-008-0420-8 PG 13 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 435ZN UT WOS:000265382500005 ER PT J AU Camara, JE Phinney, KW AF Camara, J. E. Phinney, K. W. TI Development of a Reference Method for B6 Vitamer Pyridoxal 5 '-Phosphate in Serum Using Isotope-Dilution Liquid Chromatography-Tandem Mass Spectrometry SO CLINICAL CHEMISTRY LA English DT Meeting Abstract CT Annual Meeting of the American-Association-for-Clinical-Chemistry CY JUL 19-23, 2009 CL Chicago, IL SP Amer Assoc Clin Chem C1 [Camara, J. E.; Phinney, K. W.] NIST, Gaithersburg, MD 20899 USA. NR 0 TC 0 Z9 0 U1 0 U2 2 PU AMER ASSOC CLINICAL CHEMISTRY PI WASHINGTON PA 2101 L STREET NW, SUITE 202, WASHINGTON, DC 20037-1526 USA SN 0009-9147 J9 CLIN CHEM JI Clin. Chem. PD JUN PY 2009 VL 55 IS 6 BP A230 EP A231 PG 2 WC Medical Laboratory Technology SC Medical Laboratory Technology GA 456ZZ UT WOS:000266895401295 ER PT J AU Kilpatrick, EL Liao, W Turko, IV Camara, JE Dodder, NG Bunk, DM AF Kilpatrick, E. L. Liao, W. Turko, I. V. Camara, J. E. Dodder, N. G. Bunk, D. M. TI Quantification of C-reactive protein in human serum with affinity purification and isotope-dilution tandem mass spectrometry SO CLINICAL CHEMISTRY LA English DT Meeting Abstract CT Annual Meeting of the American-Association-for-Clinical-Chemistry CY JUL 19-23, 2009 CL Chicago, IL SP Amer Assoc Clin Chem C1 [Kilpatrick, E. L.] Natl Inst Stand & Technol, Charleston, SC USA. [Liao, W.; Turko, I. V.; Camara, J. E.; Dodder, N. G.; Bunk, D. M.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RI Dodder, Nathan/C-7971-2015 OI Dodder, Nathan/0000-0001-5913-1767 NR 0 TC 4 Z9 4 U1 0 U2 6 PU AMER ASSOC CLINICAL CHEMISTRY PI WASHINGTON PA 2101 L STREET NW, SUITE 202, WASHINGTON, DC 20037-1526 USA SN 0009-9147 J9 CLIN CHEM JI Clin. Chem. PD JUN PY 2009 VL 55 IS 6 BP A205 EP A206 PG 2 WC Medical Laboratory Technology SC Medical Laboratory Technology GA 456ZZ UT WOS:000266895401224 ER PT J AU Kessel, ST Gruber, SH Gedamke, T Perkins, RG AF Kessel, Steven T. Gruber, Samuel H. Gedamke, Todd Perkins, Rupert G. TI Seasonal residency and migration of mature lemon sharks (Negaprion brevirostris) off the southeast Florida Coast SO COMPARATIVE BIOCHEMISTRY AND PHYSIOLOGY A-MOLECULAR & INTEGRATIVE PHYSIOLOGY LA English DT Meeting Abstract CT Annual Meeting of the Society-for-Experimental-Biology CY JUN 28-JUL 01, 2009 CL Glasgow, SCOTLAND SP Soc Expt Biol C1 [Kessel, Steven T.] Cardiff Univ, Bimini Biol Field Stn, Cardiff, S Glam, Wales. [Gedamke, Todd] NOAA, Washington, DC USA. EM steven_kessel@hotmail.com NR 0 TC 0 Z9 0 U1 1 U2 9 PU ELSEVIER SCIENCE INC PI NEW YORK PA 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA SN 1095-6433 J9 COMP BIOCHEM PHYS A JI Comp. Biochem. Physiol. A-Mol. Integr. Physiol. PD JUN PY 2009 VL 153A IS 2 BP S66 EP S66 DI 10.1016/j.cbpa.2009.04.010 PG 1 WC Biochemistry & Molecular Biology; Physiology; Zoology SC Biochemistry & Molecular Biology; Physiology; Zoology GA 464QM UT WOS:000267520700063 ER PT J AU Fischer, CF Zatsarinny, O AF Fischer, Charlotte Froese Zatsarinny, Oleg TI A B-spline Galerkin method for the Dirac equation SO COMPUTER PHYSICS COMMUNICATIONS LA English DT Article DE B-splines; Coulomb wavefunctions; Dirac equation; R-matrix ID CROSS-SECTION; PHOTODETACHMENT; PHYSICS; SETS AB The B-spline Galerkin method is first investigated for the simple eigenvalue problem, y '' = -lambda(2)y, that can also be written as a pair of first-order equations y' = lambda z, z' = -lambda y. Expanding both y(r) and z(r) in the B(k) basis results in many spurious solutions such as those observed for the Dirac equation. However, when y(r) is expanded in the B(k) basis and z(r) in the dB(k)/dr basis, solutions of the well-behaved second-order differential equation are obtained. From this analysis, we propose a stable method (B(k), B(k +/- 1)) basis for the Dirac equation and evaluate its accuracy by comparing the computed and exact R-matrix for a wide range of nuclear charges Z and angular quantum numbers K. When splines of the same order are used, many Spurious solutions are found whereas none are found for splines of different order. Excellent agreement is obtained for the R-matrix and energies for bound states for low values of Z. For high Z, accuracy requires the use of a grid with many points near the nucleus. We demonstrate the accuracy of the bound-state wavefunctions by comparing integrals arising in hyperfine interaction matrix elements with exact analytic expressions. We also show that the Thomas-Reiche-Ktlhn sure rule is not a good measure of the quality of the solutions obtained by the B-spline Galerkin method whereas the R-matrix is very sensitive to the appearance of pseudo-states. (C) 2009 Elsevier B.V. All rights reserved. C1 [Fischer, Charlotte Froese] Natl Inst Stand & Technol, Atom Phys Div, Gaithersburg, MD 20899 USA. [Zatsarinny, Oleg] Drake Univ, Dept Phys & Astron, Des Moines, IA 50311 USA. RP Fischer, CF (reprint author), Natl Inst Stand & Technol, Atom Phys Div, Gaithersburg, MD 20899 USA. EM Charlotte.Fischer@nist.gov FU National Science Foundation [PHY-555226] FX The authors are most grateful to P. Mohr for providing the reference to exact analytic expressions for integrals related to hyperfine interaction matrix elements for Dirac Coulomb wavefunctions. The work of O.Z. was supported by the National Science Foundation under Grant No. PHY-555226. NR 23 TC 16 Z9 16 U1 1 U2 4 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0010-4655 J9 COMPUT PHYS COMMUN JI Comput. Phys. Commun. PD JUN PY 2009 VL 180 IS 6 BP 879 EP 886 DI 10.1016/j.cpc.2008.12.010 PG 8 WC Computer Science, Interdisciplinary Applications; Physics, Mathematical SC Computer Science; Physics GA 454CX UT WOS:000266660400010 ER PT J AU Beveridge, JR Givens, GH Phillips, PJ Draper, BA AF Beveridge, J. Ross Givens, Geof H. Phillips, P. Jonathon Draper, Bruce A. TI Factors that influence algorithm performance in the Face Recognition Grand Challenge SO COMPUTER VISION AND IMAGE UNDERSTANDING LA English DT Article DE Face recognition; Subject covariates; Performance analysis; Statistical modeling ID MODELS AB A statistical study is presented quantifying the effects of covariates such as gender, age, expression, image resolution and focus on three face recognition algorithms. Specifically, a Generalized Linear Mixed Effect model is used to relate probability of verification to subject and image covariates. The data and algorithms are selected from the Face Recognition Grand Challenge and the results show that the effects of covariates are strong and algorithm specific. The paper presents in detail all of the significant effects including interactions among covariates. One significant conclusion is that covariates matter. The variation in verification Fates as a function of covariates is greater than the difference in average performance between the two best algorithms. Another is that few OF no universal effects emerge; almost no covariates effect all algorithms in the same way and to the same degree. To highlight one specific effect, there is evidence that verification systems should enroll subjects with smiling rather than neutral expressions for best performance. (C) 2009 Elsevier Inc. All rights reserved. C1 [Beveridge, J. Ross; Draper, Bruce A.] Colorado State Univ, Dept Comp Sci, Ft Collins, CO 80523 USA. [Givens, Geof H.] Colorado State Univ, Dept Stat, Ft Collins, CO 80523 USA. [Phillips, P. Jonathon] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Beveridge, JR (reprint author), Colorado State Univ, Dept Comp Sci, Ft Collins, CO 80523 USA. EM ross@cs.colostate.edu NR 31 TC 25 Z9 26 U1 0 U2 4 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 1077-3142 EI 1090-235X J9 COMPUT VIS IMAGE UND JI Comput. Vis. Image Underst. PD JUN PY 2009 VL 113 IS 6 BP 750 EP 762 DI 10.1016/j.cviu.2008.12.007 PG 13 WC Computer Science, Artificial Intelligence; Engineering, Electrical & Electronic SC Computer Science; Engineering GA 436OX UT WOS:000265424800007 ER PT J AU Shamblin, BM Faircloth, BC Dodd, MG Bagley, DA Ehrhart, LM Dutton, PH Frey, A Nairn, CJ AF Shamblin, Brian M. Faircloth, Brant C. Dodd, Mark G. Bagley, Dean A. Ehrhart, Llewellyn M. Dutton, Peter H. Frey, Amy Nairn, Campbell J. TI Tetranucleotide markers from the loggerhead sea turtle (Caretta caretta) and their cross-amplification in other marine turtle species SO CONSERVATION GENETICS LA English DT Article DE Caretta caretta; Loggerhead turtle; Microsatellites; Cross-amplification ID LOCI; DNA AB The loggerhead sea turtle (Caretta caretta) is a federally threatened species and listed as endangered by the World Conservation Union (IUCN). We describe primers and polymerase chain reaction (PCR) conditions to amplify 11 novel tetranucleotide microsatellite loci from the loggerhead sea turtle. We tested primers using samples from 22 females that nested at Melbourne Beach, Florida (USA). Primer pairs yielded an average of 11.2 alleles per locus (range of 4-24), an average observed heterozygosity of 0.83 (range 0.59-0.96), and an average polymorphic information content of 0.80 (range 0.62-0.94). We also demonstrate the utility of these primers, in addition to primers for 15 loci previously described, for amplifying microsatellite loci in four additional species representing the two extant marine turtle families: olive ridley (Lepidochelys olivacea), hawksbill (Eretmochelys imbricata), green turtle (Chelonia mydas), and leatherback (Dermochelys coriacea). C1 [Shamblin, Brian M.; Faircloth, Brant C.; Nairn, Campbell J.] Univ Georgia, DB Warnell Sch Forestry & Nat Resources, Athens, GA 30602 USA. [Dodd, Mark G.] Georgia Dept Nat Resources, Wildlife Resources Div, Brunswick, GA 31520 USA. [Bagley, Dean A.; Ehrhart, Llewellyn M.] Univ Cent Florida, Dept Biol, Orlando, FL 32816 USA. [Ehrhart, Llewellyn M.] Hubbs SeaWorld Res Inst, Orlando, FL 32821 USA. [Dutton, Peter H.; Frey, Amy] NOAA Fisheries, SW Fisheries Sci Ctr, La Jolla, CA 92037 USA. RP Nairn, CJ (reprint author), Univ Georgia, DB Warnell Sch Forestry & Nat Resources, Athens, GA 30602 USA. EM jnairn@warnell.uga.edu OI Faircloth, Brant/0000-0002-1943-0217 FU Georgia Department of Natural Resources; Daniel B. Warnell School of Forestry and Natural Resources; Florida Fish and Wildlife Conservation Commission [135]; UGA Institutional Animal Care and Use Committee [A2006-10002-0] FX This research was supported by the Georgia Department of Natural Resources and the Daniel B. Warnell School of Forestry and Natural Resources. Handling of turtles was approved by the Florida Fish and Wildlife Conservation Commission (FWC, MTP # 135) and the UGA Institutional Animal Care and Use Committee (approval number: A2006-10002-0). We thank Paul Tritaik of the ACNWR and Meghan Koperski of FWC for facilitating beach access and permit assistance. We thank the University of Central Florida Marine Turtle Research crew for providing ACNWR samples. We thank the NOAA-Fisheries' Southwest Fisheries Science Center (SWFSC) for collecting and providing the Olive Ridley samples. We thank Zandy Hillis-Starr, from the Buck Island Reef National Park, as well as Ana Bass for the Hawksbill samples provided through the SWFSC Genetics tissue sample archive. NR 11 TC 15 Z9 16 U1 2 U2 17 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 1566-0621 J9 CONSERV GENET JI Conserv. Genet. PD JUN PY 2009 VL 10 IS 3 BP 577 EP 580 DI 10.1007/s10592-008-9573-6 PG 4 WC Biodiversity Conservation; Genetics & Heredity SC Biodiversity & Conservation; Genetics & Heredity GA 442HJ UT WOS:000265832000019 ER PT J AU Miller, MW Kramer, KL Williams, SM Johnston, L Szmant, AM AF Miller, M. W. Kramer, K. L. Williams, S. M. Johnston, L. Szmant, A. M. TI Assessment of current rates of Diadema antillarum larval settlement SO CORAL REEFS LA English DT Article DE Florida Keys; Recovery; Puerto Rico; Settlement; Larval supply ID MASS MORTALITY; SEA-URCHIN; CORAL-REEF; POPULATIONS; RECOVERY; DYNAMICS; ECHINODERMATA; ECHINOIDEA; HABITATS; DENSITY AB The generally slow and incomplete recovery of the long-spined sea urchin, Diadema antillarum, from the 1983-84 Caribbean-wide die-off, particularly in the Florida Keys, USA, raises the question of factors limiting population recovery. This study sought to quantify larval settlement rates as an indicator of larval supply at two sites in the Florida Keys, utilizing methods comparable to an historic study. Settlement at two sites in southwest Puerto Rico was also examined as a comparison of present-day settlement rates at a site where D. antillarum recovery has been moderate. Monthly settlement rates were low (max < 2 m(-2)) and did not differ between the two sites examined in the Florida Keys. Settlement was significantly higher at only one of the Puerto Rico sites (max 16 m(-2)), but still an order of magnitude lower than that reported for historic populations in Cura double dagger ao (1982-83). Results are consistent with the hypothesis of low larval supply limiting D. antillarum recovery in the Florida Keys. C1 [Miller, M. W.] Southeast Fisheries Sci Ctr, NOAA Fisheries Serv, Miami, FL 33149 USA. [Kramer, K. L.] Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, Cooperat Inst Marine & Atmospher Sci, Miami, FL 33149 USA. [Williams, S. M.] Univ Puerto Rico, Dept Marine Sci, Mayaguez, PR 00681 USA. [Johnston, L.] Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, Div Marine Biol & Fisheries, Miami, FL 33149 USA. [Szmant, A. M.] Univ N Carolina, Ctr Marine Sci, Wilmington, NC 28409 USA. RP Miller, MW (reprint author), Southeast Fisheries Sci Ctr, NOAA Fisheries Serv, 75 Virginia Beach Dr, Miami, FL 33149 USA. EM margaret.w.miller@noaa.gov FU NOAA-National Marine Sanctuaries Program [FKNMS-2004-057, FKNMS-2006-026] FX This project was made possible by funding from the NOAA-National Marine Sanctuaries Program and conduced under permits FKNMS-2004-057 and FKNMS-2006-026. Field assistance was provided by B. Mason, D. Williams, K. Flynn, and L. Harman. NR 19 TC 12 Z9 15 U1 3 U2 11 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0722-4028 J9 CORAL REEFS JI Coral Reefs PD JUN PY 2009 VL 28 IS 2 BP 511 EP 515 DI 10.1007/s00338-008-0458-4 PG 5 WC Marine & Freshwater Biology SC Marine & Freshwater Biology GA 442HK UT WOS:000265832100023 ER PT J AU Bruno, JF Sweatman, H Precht, WF Selig, ER Schutte, VGW AF Bruno, John F. Sweatman, Hugh Precht, William F. Selig, Elizabeth R. Schutte, Virginia G. W. TI Assessing evidence of phase shifts from coral to macroalgal dominance on coral reefs SO ECOLOGY LA English DT Article DE Caribbean; coral reefs; Florida Keys; Great Barrier Reef; Indo-Pacific; macroalgae; phase shifts; reef management ID CLIMATE-CHANGE; HERBIVOROUS FISHES; COMMUNITY DYNAMICS; BLEACHING EVENT; MARINE RESERVE; STABLE STATES; DISCOVERY BAY; JAMAICA; COVER; DECLINE AB Many marine scientists have concluded that coral reefs are moving toward or are locked into a seaweed-dominated state. However, because there have been no regional- or global-scale analyses of such coral reef "phase shifts,'' the magnitude of this phenomenon was unknown. We analyzed 3581 quantitative surveys of 1851 reefs performed between 1996 and 2006 to determine the frequency, geographical extent, and degree of macroalgal dominance of coral reefs and of coral to macroalgal phase shifts around the world. Our results indicate that the replacement of corals by macroalgae as the dominant benthic functional group is less common and less geographically extensive than assumed. Although we found evidence of moderate local increases in macroalgal cover, particularly in the Caribbean, only 4% of reefs were dominated by macroalgae (i.e., >50% cover). Across the Indo-Pacific, where regional averages of macroalgal cover were 9-12%, macroalgae only dominated 1% of the surveyed reefs. Between 1996 and 2006, phase shift severity decreased in the Caribbean, did not change in the Florida Keys and Indo-Pacific, and increased slightly on the Great Barrier Reef due to moderate coral loss. Coral reef ecosystems appear to be more resistant to macroalgal blooms than assumed, which has important implications for reef management. C1 [Bruno, John F.; Schutte, Virginia G. W.] Univ N Carolina, Dept Marine Sci, Chapel Hill, NC 27599 USA. [Sweatman, Hugh] Australian Inst Marine Sci, Townsville, Qld 4810, Australia. [Precht, William F.] Florida Keys Natl Marine Sanctuary, Natl Ocean & Atmospher Adm, Key Largo, FL 33037 USA. [Selig, Elizabeth R.] Univ N Carolina, Curriculum Ecol, Chapel Hill, NC 27599 USA. [Selig, Elizabeth R.] Univ N Carolina, Dept Marine Sci, Chapel Hill, NC 27599 USA. RP Bruno, JF (reprint author), Univ N Carolina, Dept Marine Sci, Chapel Hill, NC 27599 USA. EM jbruno@unc.edu RI kohki, sowa/D-2955-2011 FU U.S. EPA; NOAA's Florida Keys National Marine Sanctuary; National Science Foundation [OCE-0326705]; Australian Institute of Marine Science; University of North Carolina at Chapel Hill FX We are grateful to the many organizations that shared their published and unpublished data with us, particularly the Florida Keys Coral Reef Monitoring Program (funded by the U.S. EPA and NOAA's Florida Keys National Marine Sanctuary) and Reef Check which provided the data for nearly half the surveys used in this analysis. This research was funded in part the National Science Foundation (OCE-0326705 to J.F. Bruno), the Australian Institute of Marine Science, the Marine and Tropical Research facility, and the University of North Carolina at Chapel Hill. NR 56 TC 162 Z9 166 U1 12 U2 106 PU ECOLOGICAL SOC AMER PI WASHINGTON PA 1990 M STREET NW, STE 700, WASHINGTON, DC 20036 USA SN 0012-9658 J9 ECOLOGY JI Ecology PD JUN PY 2009 VL 90 IS 6 BP 1478 EP 1484 DI 10.1890/08-1781.1 PG 7 WC Ecology SC Environmental Sciences & Ecology GA 454DR UT WOS:000266662500008 PM 19569362 ER PT J AU Bottom, DL Jones, KK Simenstad, CA Smith, CL AF Bottom, Daniel L. Jones, Kim K. Simenstad, Charles A. Smith, Courtland L. TI Reconnecting Social and Ecological Resilience in Salmon Ecosystems SO ECOLOGY AND SOCIETY LA English DT Editorial Material DE fishery management; Pacific Northwest; Pacific salmon; resilience; salmon ecosystem ID MULTIPLE STABLE STATES; PACIFIC SALMON; NORTHEAST PACIFIC; ONCORHYNCHUS-KISUTCH; CATASTROPHIC SHIFTS; RESOURCE-MANAGEMENT; FISHERY MANAGEMENT; MARINE ECOSYSTEMS; CLIMATIC-CHANGE; REGIME SHIFTS AB Fishery management programs designed to control Pacific salmon (Oncorhynchus spp.) for optimum production have failed to prevent widespread fish population decline and have caused greater uncertainty for salmon, their ecosystems, and the people who depend upon them. In this special feature introduction, we explore several key attributes of ecosystem resilience that have been overlooked by traditional salmon management approaches. The dynamics of salmon ecosystems involve social-ecological interactions across multiple scales that create difficult mismatches with the many jurisdictions that manage fisheries and other natural resources. Of particular importance to ecosystem resilience are large-scale shifts in oceanic and climatic regimes or in global economic conditions that unpredictably alter social and ecological systems. Past management actions that did not account for such changes have undermined salmon population resilience and increased the risk of irreversible regime shifts in salmon ecosystems. Because salmon convey important provisioning, cultural, and supporting services to their local watersheds, widespread population decline has undermined both human well-being and ecosystem resilience. Strengthening resilience will require expanding habitat opportunities for salmon populations to express their maximum life-history variation. Such actions also may benefit the "response diversity" of local communities by expanding the opportunities for people to express diverse social and economic values. Reestablishing social-ecological connections in salmon ecosystems will provide important ecosystem services, including those that depend on clean water, ample stream flows, functional wetlands and floodplains, intact riparian systems, and abundant fish populations. C1 [Bottom, Daniel L.] NOAA Fisheries, NW Fisheries Sci Ctr, Washington, DC USA. [Simenstad, Charles A.] Univ Washington, Seattle, WA 98195 USA. [Smith, Courtland L.] Oregon State Univ, Dept Anthropol, Corvallis, OR 97331 USA. RP Bottom, DL (reprint author), NOAA Fisheries, NW Fisheries Sci Ctr, Washington, DC USA. NR 124 TC 33 Z9 32 U1 7 U2 29 PU RESILIENCE ALLIANCE PI WOLFVILLE PA ACADIA UNIV, BIOLOGY DEPT, WOLFVILLE, NS B0P 1X0, CANADA SN 1708-3087 J9 ECOL SOC JI Ecol. Soc. PD JUN PY 2009 VL 14 IS 1 AR 5 PG 18 WC Ecology; Environmental Studies SC Environmental Sciences & Ecology GA 468TY UT WOS:000267846300002 ER PT J AU Waples, RS Beechie, T Pess, GR AF Waples, Robin S. Beechie, Tim Pess, George R. TI Evolutionary History, Habitat Disturbance Regimes, and Anthropogenic Changes: What Do These Mean for Resilience of Pacific Salmon Populations? SO ECOLOGY AND SOCIETY LA English DT Article DE climate change; duration; frequency; historical template; magnitude; Pacific Northwest; Oncorhynchus; Pacific salmon; predictability ID COLUMBIA RIVER-BASIN; LIFE-HISTORY; SOCKEYE-SALMON; CHINOOK SALMON; NORTHWEST WATERSHEDS; BIOLOGICAL DIVERSITY; ANADROMOUS SALMONIDS; GEOMORPHIC PROCESSES; SIGNIFICANT UNITS; BRITISH-COLUMBIA AB Because resilience of a biological system is a product of its evolutionary history, the historical template that describes the relationships between species and their dynamic habitats is an important point of reference. Habitats used by Pacific salmon have been quite variable throughout their evolutionary history, and these habitats can be characterized by four key attributes of disturbance regimes: frequency, magnitude, duration, and predictability. Over the past two centuries, major anthropogenic changes to salmon ecosystems have dramatically altered disturbance regimes that the species experience. To the extent that these disturbance regimes assume characteristics outside the range of the historical template, resilience of salmon populations might be compromised. We discuss anthropogenic changes that are particularly likely to compromise resilience of Pacific salmon and management actions that could help bring the current patterns of disturbance regimes more in line with the historical template. C1 [Waples, Robin S.; Beechie, Tim; Pess, George R.] NOAA Fisheries, NW Fisheries Ctr, Environm Conservat Div, Washington, DC USA. RP Waples, RS (reprint author), NOAA Fisheries, NW Fisheries Ctr, Environm Conservat Div, Washington, DC USA. RI Waples, Robin/K-1126-2016 NR 78 TC 41 Z9 41 U1 0 U2 31 PU RESILIENCE ALLIANCE PI WOLFVILLE PA ACADIA UNIV, BIOLOGY DEPT, WOLFVILLE, NS B0P 1X0, CANADA SN 1708-3087 J9 ECOL SOC JI Ecol. Soc. PD JUN PY 2009 VL 14 IS 1 AR 3 PG 18 WC Ecology; Environmental Studies SC Environmental Sciences & Ecology GA 468TY UT WOS:000267846300044 ER PT J AU Kemp, PS Williams, JG AF Kemp, P. S. Williams, J. G. TI Illumination influences the ability of migrating juvenile salmonids to pass a submerged experimental weir SO ECOLOGY OF FRESHWATER FISH LA English DT Article DE smolts; rheotaxis; swimming-ability; barriers; vision; nocturnal ID ATLANTIC SALMON; SALAR L; LATERAL-LINE; SMOLT MIGRATION; LIGHT-INTENSITY; DOWNSTREAM MIGRATION; SWIMMING PERFORMANCE; BEHAVIOR; FISH; RESPONSES AB The downstream migration of juvenile salmonids has previously been considered predominantly passive. It has been argued that passive displacement during periods of darkness is, partially at least, a result of an inability to maintain a fixed position in the absence of visual cues. In this study, behaviour of juvenile Pacific salmonids was assessed under conditions of light and dark as they passed through an artificial channel and encountered a submerged weir. Results indicated that when light, fish formed schools and actively explored the channel. Conversely, when dark (infrared illumination only) they did not form schools, but maintained randomly distributed positions holding station against the flow. As a consequence, more fish approached and either passed, or rejected, the weir when light. The majority of fish that passed the weir did so within the first minute of each trial. Fish predominantly passed through the channel facing downstream and changed orientation prior to passing tail first over the weir crest in the presence and absence of visual cues. The orientation switch was less common when dark. This study shows, at a fine-resolution scale, that downstream movement of juvenile salmonids can be inhibited as fish exhibit alternative behaviours in the absence of visual cues. Downstream movement was not predominantly passive. Fish passage design should not be based on the assumption that downstream migration is passive. C1 [Kemp, P. S.] Univ Southampton, Int Ctr Ecohydraul Res, Sch Civil Engn & Environm, Southampton SO17 1BJ, Hants, England. [Kemp, P. S.; Williams, J. G.] NOAA, Natl Marine Fisheries Serv, NW Fisheries Ctr, Fish Ecol Div, Seattle, WA 98112 USA. RP Kemp, PS (reprint author), Univ Southampton, Int Ctr Ecohydraul Res, Sch Civil Engn & Environm, Southampton SO17 1BJ, Hants, England. EM p.kemp@soton.ac.uk FU National Research Council FX We acknowledge the practical support provided by Michael Gessel (NOAA National Marine Fisheries Service). We thank Professor Neil Metcalfe (University of Glasgow) and two anonymous referees for useful comments on earlier versions of this manuscript. This work was performed while the author held a National Research Council Research Associateship Award. NR 41 TC 12 Z9 14 U1 1 U2 10 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 0906-6691 J9 ECOL FRESHW FISH JI Ecol. Freshw. Fish PD JUN PY 2009 VL 18 IS 2 BP 297 EP 304 DI 10.1111/j.1600-0633.2008.00347.x PG 8 WC Fisheries; Marine & Freshwater Biology SC Fisheries; Marine & Freshwater Biology GA 446GV UT WOS:000266111000012 ER PT J AU Donovan, GH Butry, DT AF Donovan, Geoffrey H. Butry, David T. TI The value of shade: Estimating the effect of urban trees on summertime electricity use SO ENERGY AND BUILDINGS LA English DT Article DE Urban trees; Energy conservation; Economics; Shade; Carbon ID ENERGY USE; SURFACES AB We estimated the effect of shade trees on the summertime electricity use of 460 single-family homes in Sacramento, California. Results show that trees on the west and south sides of a house reduce summertime electricity use, whereas trees on the north side of a house increase summertime electricity use. The current level of tree cover on the west and south sides of houses in our sample reduced summertime electricity use by 185 kWh (5.2%), whereas north-side trees increased electricity use by 55 kWh (1.5%). Results also show that a London plane tree, planted on the west side of a house, can reduce carbon emissions from summertime electricity use by an average of 31% over 100 years. Published by Elsevier B.V. C1 [Donovan, Geoffrey H.] US Forest Serv, USDA, PNW Res Stn, Portland, OR 97205 USA. [Butry, David T.] NIST, Gaithersburg, MD 20899 USA. RP Donovan, GH (reprint author), US Forest Serv, USDA, PNW Res Stn, 620 SW Main,Suite 400, Portland, OR 97205 USA. EM gdonovan@fs.fed.us; david.butry@nist.gov NR 10 TC 49 Z9 59 U1 1 U2 30 PU ELSEVIER SCIENCE SA PI LAUSANNE PA PO BOX 564, 1001 LAUSANNE, SWITZERLAND SN 0378-7788 J9 ENERG BUILDINGS JI Energy Build. PD JUN PY 2009 VL 41 IS 6 BP 662 EP 668 DI 10.1016/j.enbuild.2009.01.002 PG 7 WC Construction & Building Technology; Energy & Fuels; Engineering, Civil SC Construction & Building Technology; Energy & Fuels; Engineering GA 445OL UT WOS:000266060000009 ER PT J AU Butry, DT AF Butry, David T. TI Fighting fire with fire: estimating the efficacy of wildfire mitigation programs using propensity scores SO ENVIRONMENTAL AND ECOLOGICAL STATISTICS LA English DT Article CT Workshop on Forest Fires and Point Processes CY MAY, 2005 CL Fields Inst, Toronto, CANADA HO Fields Inst DE Endogeneity; Prescribed fire; Propensity score; Treatment effects; Wildfire production functions ID SEMI-LOGARITHMIC EQUATIONS; TRAINING-PROGRAMS; DUMMY VARIABLES; CAUSAL; MANAGEMENT; INFERENCE; BIAS AB This paper examines the effect wildfire mitigation has on broad-scale wildfire behavior. Each year, hundreds of million of dollars are spent on fire suppression and fuels management applications, yet little is known, quantitatively, of the returns to these programs in terms of their impact on wildfire extent and intensity. This is especially true when considering that wildfire management influences and reacts to several, often times confounding factors, including socioeconomic characteristics, values at risk, heterogeneous landscapes, and climate. Due to the endogenous nature of suppression effort and fuels management intensity and placement with wildfire behavior, traditional regression models may prove inadequate. Instead, I examine the applicability of propensity score matching (PSM) techniques in modeling wildfire. This research makes several significant contributions including: (1) applying techniques developed in labor economics and in epidemiology to evaluate the effects of natural resource policies on landscapes, rather than on individuals; (2) providing a better understanding of the relationship between wildfire mitigation strategies and their influence on broad-scale wildfire patterns; (3) quantifying the returns to suppression and fuels management on wildfire behavior. C1 Natl Inst Stand & Technol, Off Appl Econ, Bldg & Fire Res Lab, Gaithersburg, MD 20899 USA. RP Butry, DT (reprint author), Natl Inst Stand & Technol, Off Appl Econ, Bldg & Fire Res Lab, 100 Bur Dr,Mailstop 8603, Gaithersburg, MD 20899 USA. EM david.butry@nist.gov NR 47 TC 9 Z9 9 U1 2 U2 10 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 1352-8505 J9 ENVIRON ECOL STAT JI Environ. Ecol. Stat. PD JUN PY 2009 VL 16 IS 2 BP 291 EP 319 DI 10.1007/s10651-007-0083-3 PG 29 WC Environmental Sciences; Mathematics, Interdisciplinary Applications; Statistics & Probability SC Environmental Sciences & Ecology; Mathematics GA 437TH UT WOS:000265509300010 ER PT J AU Petersen, EJ Pinto, RA Landrum, PF Weber, WJ AF Petersen, Elijah J. Pinto, Roger A. Landrum, Peter F. Weber, Walter J., Jr. TI Influence of Carbon Nanotubes on Pyrene Bioaccumulation from Contaminated Soils by Earthworms SO ENVIRONMENTAL SCIENCE & TECHNOLOGY LA English DT Article ID POLYCYCLIC AROMATIC-HYDROCARBONS; DISTRIBUTED REACTIVITY MODEL; NATURAL ORGANIC SORBENTS; ENVIRONMENTAL APPLICATIONS; ENGINEERED NANOPARTICLES; BENTHIC INVERTEBRATES; EISENIA-FOETIDA; BIOAVAILABILITY; SEDIMENT; NANOMATERIALS AB Increasing production of and application potentials for carbon nanotubes (CNTs) suggest these materials will enter soil and sediment ecosystems in significant masses in upcoming years. This may result in ecological risks, either from the presence of the CNTs themselves or, given their exceptional sorption capacities, from their effects on the fate and accumulation of concurrently present hydrophobic organic chemicals (HOCs). Here we test the influence of additions of single-walled CNTs (SWNTs) and multi-walled CNTs (MWNTs) to two different pyrene-contaminated soils on uptake of this HOC by earthworms (Eisenia foetida). The effects of nanotube additions to the soils were observed to be CNT concentration dependent, with 0.3 mg nanotubes per gram of soil having no impact, while 3.0 mg/g of SWNTs or MWNTs substantially decreased pyrene bioaccumulation from both contaminated soils. The presence of CNTs also affected pyrene elimination rates. After a 14-day exposure to pyrene-spiked soils, earthworms showed enhanced elimination rates in soils amended with 3.0 mg CNT/g but not 0.3 mg CNT/g. These results suggest that the presence of SWNTs or MWNTs in terrestrial ecosystems will have concentration-dependent effects on decreasing HOC accumulation by earthworms in a manner similar to that expected of most "hard" carbons. C1 [Petersen, Elijah J.; Pinto, Roger A.; Weber, Walter J., Jr.] Univ Michigan, Dept Chem Engn, Ann Arbor, MI 48109 USA. [Landrum, Peter F.] NOAA, Great Lakes Environm Res Lab, Ann Arbor, MI 48108 USA. RP Petersen, EJ (reprint author), Univ Michigan, Dept Chem Engn, Ann Arbor, MI 48109 USA. EM epeterse@umich.edu; wjwjr@umich.edu RI Petersen, Elijah/E-3034-2013 FU University of Michigan Graham Environmental Sustainability Institute; U.S. EPA [RD833321] FX We thank Kyle Roebuck, Hayley Smithkort, and Jesse Tzeng for their experimental assistance. We thank Marja Noponen and Dr. Jussi Kukkonen for making the hard carbon measurements and Drs. Xiaoyin Chen and Johannes Schwank for assistance with surface area measurements. This work was supported by awards from the University of Michigan Graham Environmental Sustainability Institute and from U.S. EPA grant RD833321. This is Great Lakes Environmental Research Laboratory contribution 1513. NR 37 TC 83 Z9 88 U1 8 U2 86 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0013-936X J9 ENVIRON SCI TECHNOL JI Environ. Sci. Technol. PD JUN 1 PY 2009 VL 43 IS 11 BP 4181 EP 4187 DI 10.1021/es803023a PG 7 WC Engineering, Environmental; Environmental Sciences SC Engineering; Environmental Sciences & Ecology GA 452NJ UT WOS:000266546700035 PM 19569349 ER PT J AU Lin, GD Zhu, SL Islam, R Kim, K Chang, MS Korenblit, S Monroe, C Duan, LM AF Lin, G. -D. Zhu, S. -L. Islam, R. Kim, K. Chang, M. -S. Korenblit, S. Monroe, C. Duan, L. -M. TI Large-scale quantum computation in an anharmonic linear ion trap SO EPL LA English DT Article ID PHASE-TRANSITIONS; ATOMIC IONS; ENTANGLEMENT; ARCHITECTURE; THRESHOLD; COMPUTER; CRYSTALS; STATE; GATES AB We propose a large-scale quantum computer architecture by more easily stabilizing a single large linear ion chain in a very simple trap geometry. By confining ions in an anharmonic linear trap with nearly uniform spacing between ions, we show that high-fidelity quantum gates can be realized in large linear ion crystals under the Doppler temperature based on coupling to a near-continuum of transverse motional modes with simple shaped laser pulses. Copyright (C) EPLA, 2009 C1 [Lin, G. -D.; Zhu, S. -L.; Duan, L. -M.] Univ Michigan, FOCUS Ctr, Ann Arbor, MI 48109 USA. [Lin, G. -D.; Zhu, S. -L.; Duan, L. -M.] Univ Michigan, MCTP, Dept Phys, Ann Arbor, MI 48109 USA. [Zhu, S. -L.] S China Normal Univ, LQIT, Guangzhou, Guangdong, Peoples R China. [Zhu, S. -L.] S China Normal Univ, ICMP, Dept Phys, Guangzhou, Guangdong, Peoples R China. [Islam, R.; Kim, K.; Chang, M. -S.; Korenblit, S.; Monroe, C.] Univ Maryland, Joint Quantum Inst, College Pk, MD 20742 USA. [Islam, R.; Kim, K.; Chang, M. -S.; Korenblit, S.; Monroe, C.] Natl Inst Stand & Technol, College Pk, MD 20742 USA. RP Lin, GD (reprint author), Univ Michigan, FOCUS Ctr, Ann Arbor, MI 48109 USA. EM guindarl@umich.edu RI Monroe, Christopher/G-8105-2011; Zhu, Shi-Liang/F-2334-2011; Chang, Ming-Shien/F-7922-2012 NR 29 TC 73 Z9 73 U1 0 U2 3 PU EPL ASSOCIATION, EUROPEAN PHYSICAL SOCIETY PI MULHOUSE PA 6 RUE DES FRERES LUMIERE, MULHOUSE, 68200, FRANCE SN 0295-5075 J9 EPL-EUROPHYS LETT JI EPL PD JUN PY 2009 VL 86 IS 6 AR 60004 DI 10.1209/0295-5075/86/60004 PG 5 WC Physics, Multidisciplinary SC Physics GA 488NX UT WOS:000269357700005 ER PT J AU Jeanneret, B Benz, SP AF Jeanneret, B. Benz, S. P. TI Application of the Josephson effect in electrical metrology SO EUROPEAN PHYSICAL JOURNAL-SPECIAL TOPICS LA English DT Review ID PROGRAMMABLE VOLTAGE STANDARDS; QUANTIZED HALL RESISTANCE; WAVE-FORM SYNTHESIZER; JOHNSON NOISE THERMOMETRY; JUNCTION SERIES ARRAYS; STACKED MOSI2-BARRIER JUNCTIONS; TO-ANALOG CONVERTERS; DC TRANSFER-STANDARD; OPERATING MARGINS; SUPERCONDUCTOR JUNCTIONS AB Over the last 30 years, metrology laboratories have used the quantum behavior of the Josephson effect to greatly improve voltage metrology. The following article reviews the history and present status of the research and development for Josephson voltage standards. Specifically, the technology and performance of voltage standards that have quantum accuracy is explained in detail, as is their impact on a wide range of electrical metrology applications, primarily those for dc and ac voltage measurements. The physics of the Josephson effect will be presented and the importance of quantum-based electrical standards will be discussed. A detailed explanation of the operation of the conventional Josephson voltage standard and its use for dc applications will be presented, including a description of the most important results. The latter sections of this paper describe recent efforts to apply the Josephson effect to ac voltage and other electrical metrology applications. Advanced voltage standard systems have been developed that provide new features such as stable, programmable dc voltages and quantum-accurate ac waveform synthesis. The superconducting technology and integrated circuit designs for these systems will be described. Two different systems have dramatically improved precision measurements for audio-frequency voltages and for electric power metrology. C1 [Jeanneret, B.] Fed Off Metrol METAS, CH-3003 Bern, Switzerland. [Benz, S. P.] NIST, Boulder, CO 80305 USA. RP Jeanneret, B (reprint author), Fed Off Metrol METAS, Lindenweg 50, CH-3003 Bern, Switzerland. EM blaise.jeanneret@metas.ch; benz@boulder.nist.gov NR 127 TC 47 Z9 47 U1 1 U2 19 PU EDP SCIENCES S A PI LES ULIS CEDEX A PA 17, AVE DU HOGGAR, PA COURTABOEUF, BP 112, F-91944 LES ULIS CEDEX A, FRANCE SN 1951-6355 J9 EUR PHYS J-SPEC TOP JI Eur. Phys. J.-Spec. Top. PD JUN PY 2009 VL 172 BP 181 EP 206 DI 10.1140/epjst/e2009-01050-6 PG 26 WC Physics, Multidisciplinary SC Physics GA 461GM UT WOS:000267252700014 ER PT J AU Keller, MW AF Keller, M. W. TI Practical aspects of counting electrons with a single-electron tunneling pump SO EUROPEAN PHYSICAL JOURNAL-SPECIAL TOPICS LA English DT Review ID CAPACITANCE STANDARD; METROLOGY TRIANGLE; COULOMB-BLOCKADE; ACCURACY; DEVICES; ERRORS; FILTERS; LEAKAGE; NOISE AB This review covers various aspects of the single-electron tunneling pumps based on Al junctions studied at NIST over the past 15 years. The operation of a pump is described, and some important error mechanisms are summarized, which allows for a sketch of the basic pump parameters required for metrological accuracy. Fabrication of pumps, filtering of leads in the cryostat, and the electronics used to drive the pump are described next. The shuttle error technique that allows measurement of very rare errors is then described, and some outstanding questions about limitations of pumps based on Al junctions are mentioned. A detailed algorithm for cancelling the cross capacitance in a pump is described in an appendix. C1 NIST, Boulder, CO 80305 USA. RP Keller, MW (reprint author), NIST, 325 Broadway, Boulder, CO 80305 USA. EM mark.keller@boulder.nist.gov NR 35 TC 7 Z9 8 U1 0 U2 0 PU SPRINGER HEIDELBERG PI HEIDELBERG PA TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY SN 1951-6355 J9 EUR PHYS J-SPEC TOP JI Eur. Phys. J.-Spec. Top. PD JUN PY 2009 VL 172 BP 297 EP 309 DI 10.1140/epjst/e2009-01055-1 PG 13 WC Physics, Multidisciplinary SC Physics GA 461GM UT WOS:000267252700019 ER PT J AU Serafy, JE Kerstetter, DW Rice, PH AF Serafy, Joseph E. Kerstetter, David W. Rice, Patrick H. TI Can circle hook use benefit billfishes? SO FISH AND FISHERIES LA English DT Review DE Billfish; circle hooks; hook performance; marlin; sailfish; review ID PELAGIC LONGLINE FISHERY; WESTERN NORTH-ATLANTIC; WHITE MARLIN; MORTALITY; CATCH; SURVIVAL; CAUGHT; REDUCE; SIZE AB We performed a quantitative review to evaluate circle hook use in recreational and commercial hook-and-line fisheries that interact with billfishes (Family: Istiophoridae). Specifically, we scrutinized the findings of 11 recent empirical studies that reported, on a species-specific basis, side-by-side measures of circle vs. J-hook fishing performance: catch, mortality, deep-hooking and bleeding rates. Of the 30 total comparisons extracted from the literature that satisfied our inclusion criteria, 13 indicated significant differences between hook types for the specific metric compared. No study reported significant billfish catch rate differences between hook types. However, when significant differences between hook types were found, higher mortality rates and higher rates of deep-hooking and bleeding were associated with J-hooks relative to circle hooks. We conclude that empirical evidence is sufficient to promote circle hook use in almost all hook-and-line fishery sectors that typically interact with istiophorids. However, billfish conservation benefits will only be realized if fishers use unmodified circle hooks, commit to releasing live fish and take other appropriate measures which maximize post-release survival. While there may be fishing modes where circle hook effects are negative, for billfish conservation, we recommend managers grant exceptions to circle hook use only when experimental results support such a practice. C1 [Serafy, Joseph E.] Natl Marine Fisheries Serv, SE Fisheries Sci Ctr, Miami, FL 33149 USA. [Serafy, Joseph E.; Rice, Patrick H.] Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, Miami, FL 33149 USA. [Kerstetter, David W.] Nova SE Univ, Oceanog Ctr, Dania, FL 33004 USA. RP Serafy, JE (reprint author), SEFSC, 75 Virginia Beach Dr, Miami, FL 33133 USA. EM joe.serafy@noaa.gov RI Kerstetter, David/I-5396-2012 NR 39 TC 32 Z9 32 U1 2 U2 10 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 1467-2960 J9 FISH FISH JI Fish. Fish. PD JUN PY 2009 VL 10 IS 2 BP 132 EP 142 DI 10.1111/j.1467-2979.2008.00298.x PG 11 WC Fisheries SC Fisheries GA 445BM UT WOS:000266024600002 ER PT J AU Thorson, JT Simpfendorfer, CA AF Thorson, James T. Simpfendorfer, Colin A. TI Gear selectivity and sample size effects on growth curve selection in shark age and growth studies SO FISHERIES RESEARCH LA English DT Article DE Individual growth model; Model selection; Length-selective sampling; Akaike information criterion; Multi-model estimation ID MODELING FISH GROWTH; CARCHARHINUS-OBSCURUS; MULTIMODEL INFERENCE; AUSTRALIAN WATERS; MESH SELECTIVITY; GUMMY SHARK; PARAMETERS; BIAS AB The effects of gear selectivity and sample size on growth model selection for shark length-at-age data was investigated using simulated data sets for dusky (Carcharhinus obscurus) and Atlantic sharpnose (Rhizoprionodon terroenovae) sharks. Simulated data sets were generated using four different individual growth functions (von Bertalanffy, Gompertz, logistic and Schnute) with five different sample sizes and seven different sampling gear selectivity functions. Five growth models were fit to each data set and the Akaike information criterion (AIC) and AIC weights used to evaluate which fit best to the data. The accuracy of each of the fitting models was also determined and compared with estimates derived from AIC multi-model inference (MMI). The results demonstrated that no one growth model outperformed all other models in all situations, with the two-parameter von Bertalanffy model being selected most often by AIC. There were clear differences between the fitting models that were ranked the highest based on AIC selection or AIC weights and those based on models accuracy of length and growth parameter estimates. In most situations, the two-parameter von Bertalanffy model provided the least accuracy in parameter recovery, while the Schnute model was the most accurate individual model in most situations. The AIC MMI approach improved estimation accuracy over most individual models, except at very low sample sizes. These simulation results suggest that sample sizes of 200 are required to consistently achieve good accuracy for growth parameters, and that sampling gear selectivity has clear effects on which growth models fit best to the data. The use of the AIC MMI approach is recommended, as it provides the most robust estimates of growth parameters. (C) 2009 Elsevier B.V. All rights reserved. C1 [Thorson, James T.; Simpfendorfer, Colin A.] Mote Marine Lab, Ctr Shark Res, Sarasota, FL 34236 USA. RP Thorson, JT (reprint author), Virginia Tech, NMFS RTR Unit, 101 Cheatham Hall, Blacksburg, VA 24061 USA. EM thorson@vt.edu; colin.simpfendorfer@jcu.edu.au RI Simpfendorfer, Colin/G-9681-2011; Thorson, James/O-7937-2014 OI Simpfendorfer, Colin/0000-0002-0295-2238; Thorson, James/0000-0001-7415-1010 FU Gilbert S. Louis Shark Conservation Fellowship FX The authors would like to thank John Carlson for providing Atlantic sharpnose shark length-at-age data, the Gilbert S. Louis Shark Conservation Fellowship. James Cook University, the NFS-RTR Unit at Virginia Tech, staff at Mote Marine labs, two anonymous reviewers and the editor-in-chief of Fisheries Research, as well as Jim Berkson and Robert Leaf. NR 26 TC 34 Z9 34 U1 2 U2 18 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0165-7836 EI 1872-6763 J9 FISH RES JI Fish Res. PD JUN PY 2009 VL 98 IS 1-3 BP 75 EP 84 DI 10.1016/j.fishres.2009.03.016 PG 10 WC Fisheries SC Fisheries GA 465RQ UT WOS:000267604900010 ER PT J AU de Gouw, JA Warneke, C Montzka, SA Brioude, J Holloway, JS Parrish, DD Fehsenfeld, FC Atlas, EL Weber, RJ Flocke, FM AF de Gouw, J. A. Warneke, C. Montzka, S. A. Brioude, J. Holloway, J. S. Parrish, D. D. Fehsenfeld, F. C. Atlas, E. L. Weber, R. J. Flocke, F. M. TI How much biogenic SOA is present in the Northeastern US? SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [de Gouw, J. A.; Warneke, C.; Montzka, S. A.; Brioude, J.; Holloway, J. S.; Parrish, D. D.; Fehsenfeld, F. C.] NOAA, Earth Syst Res Lab, Boulder, CO USA. [de Gouw, J. A.; Warneke, C.; Brioude, J.; Holloway, J. S.; Fehsenfeld, F. C.] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. [Atlas, E. L.] Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, Miami, FL 33149 USA. [Weber, R. J.] Georgia Inst Technol, Sch Earth & Atmospher Sci, Atlanta, GA 30332 USA. [Flocke, F. M.] Natl Ctr Atmospher Res, Boulder, CO 80307 USA. EM Joost.deGouw@noaa.gov RI Warneke, Carsten/E-7174-2010; Parrish, David/E-8957-2010; Brioude, Jerome/E-4629-2011; Fehsenfeld, Frederick/I-4876-2013; Atlas, Elliot/J-8171-2015 OI Parrish, David/0000-0001-6312-2724; NR 0 TC 1 Z9 1 U1 0 U2 3 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A273 EP A273 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229900559 ER PT J AU de Ronde, C Baker, E Embley, R Lupton, J Butterfield, D Faure, K Leybourne, M Chadwick, W Ishibashi, J Resing, J Walker, S Merle, S Greene, R AF de Ronde, C. Baker, E. Embley, R. Lupton, J. Butterfield, D. Faure, K. Leybourne, M. Chadwick, W. Ishibashi, J. Resing, J. Walker, S. Merle, S. Greene, R. TI Hydrothermal systems of intraoceanic arcs SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [de Ronde, C.; Faure, K.; Leybourne, M.] GNS Sci, Lower Hutt 5010, New Zealand. [Baker, E.; Butterfield, D.; Resing, J.; Walker, S.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98195 USA. [Embley, R.; Lupton, J.; Chadwick, W.; Merle, S.; Greene, R.] NOAA, Pacific Marine Environm Lab, Newport, OR 97365 USA. [Ishibashi, J.] Kyushu Univ, Dept Earth & Planetary Sci, Fukuoka 812, Japan. EM cornel.deronde@gns.cri.nz RI Butterfield, David/H-3815-2016 OI Butterfield, David/0000-0002-1595-9279 NR 0 TC 0 Z9 0 U1 0 U2 2 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A282 EP A282 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229900577 ER PT J AU Feingold, G Wang, HL AF Feingold, Graham Wang, Hailong TI Aerosol, clouds, precipitation and self-organization of stratocumulus SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Feingold, Graham; Wang, Hailong] NOAA, Earth Syst Res Lab, Boulder, CO USA. [Wang, Hailong] CIRES, Boulder, CO USA. EM graham.feingold@noaa.gov; hailong.wang@noaa.gov RI Feingold, Graham/B-6152-2009 NR 5 TC 0 Z9 0 U1 0 U2 1 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A362 EP A362 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229900736 ER PT J AU Folberth, GA Abraham, NL Collins, WJ Johnson, CE Morgenstern, O O'Connor, FM Young, PJ AF Folberth, G. A. Abraham, N. L. Collins, W. J. Johnson, C. E. Morgenstern, O. O'Connor, F. M. Young, P. J. TI Evolution of SOA formation and budget over the 21(st) century with implications for air quality SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Folberth, G. A.; Collins, W. J.; Johnson, C. E.; O'Connor, F. M.] Hadley Ctr, UK Met Off, Exeter, Devon, England. [Abraham, N. L.] Univ Cambridge, Dept Chem, Ctr Atmospher Sci, Cambridge CB2 1EW, England. [Morgenstern, O.] Natl Inst Water & Atmospher Res, Lauder, New Zealand. [Young, P. J.] NOAA Earth Syst Res Lab, Boulder, CO 80305 USA. EM gerd.folberth@metoffice.gov.uk; luke.abraham@atm.ch.cam.ac.uk; o.morgenstern@niwa.co.nz; paul.j.young@noaa.gov RI Young, Paul/E-8739-2010 OI Young, Paul/0000-0002-5608-8887 NR 2 TC 0 Z9 0 U1 0 U2 1 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 SU S BP A387 EP A387 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229901006 ER PT J AU Granier, C Mieville, A Liousse, C Guillaume, B Mouillot, F Gregoire, JM AF Granier, C. Mieville, A. Liousse, C. Guillaume, B. Mouillot, F. Gregoire, J. M. TI Historial emissions of atmospheric compounds resulting from biomass burning SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Granier, C.; Mieville, A.] Univ Paris 06, UPMC, F-75005 Paris, France. [Granier, C.; Mieville, A.] CNRS, UMR 7620, Serv Aeron, F-75005 Paris, France. [Granier, C.] NOAA, Earth Syst Sci Lab, Boulder, CO 80305 USA. [Granier, C.] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80305 USA. [Liousse, C.; Guillaume, B.] UPS, CNRS, UMR 5560, Lab Aerol, F-31000 Toulouse, France. [Mouillot, F.] CNRS, CEFE, IRD, Montpellier, France. [Gregoire, J. M.] JRC, Ispra, Italy. EM claire.granier@aero.jussieu.fr RI Granier, Claire/D-5360-2013; MOUILLOT, florent/C-2204-2015 OI Granier, Claire/0000-0001-7344-7995; MOUILLOT, florent/0000-0002-6548-4830 NR 0 TC 0 Z9 0 U1 0 U2 3 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A461 EP A461 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229901153 ER PT J AU Gruber, N Stendardo, I Frohlicher, T Johnson, GC AF Gruber, Nicolas Stendardo, Ilaria Froehlicher, Thomas Johnson, Gregory C. TI The recent deoxygenation of the North Atlantic thermocline: A harbinger of the future? SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Gruber, Nicolas; Stendardo, Ilaria] ETH, Inst Biogeochem & Pollutant Dynam, CH-8092 Zurich, Switzerland. [Froehlicher, Thomas] Univ Bern, Bern, Switzerland. [Johnson, Gregory C.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. EM nicolas.gruber@env.ethz.ch RI Froelicher, Thomas/A-9926-2011; Gruber, Nicolas/B-7013-2009 OI Gruber, Nicolas/0000-0002-2085-2310 NR 0 TC 1 Z9 1 U1 3 U2 5 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A471 EP A471 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229901173 ER PT J AU Gupta, P Noone, D Galewsky, J Sweeney, C Vaughn, BH AF Gupta, P. Noone, D. Galewsky, J. Sweeney, C. Vaughn, B. H. TI A new laser-based, field-deployable analyzer for laboratory-class stable isotope measurements in water SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Gupta, P.] Picarro Inc, Sunnyvale, CA 94085 USA. [Noone, D.] Univ Colorado, Dept Atmospher & Ocean Sci, Boulder, CO 80309 USA. [Noone, D.] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. [Galewsky, J.] Univ New Mexico, Dept Earth & Planetary Sci, Albuquerque, NM 87131 USA. [Sweeney, C.] Natl Oceanog & Atmospher Adm, Earth Syst Res Lab, Boulder, CO 80304 USA. [Vaughn, B. H.] Univ Colorado, Inst Arctic & Alpine Res, Boulder, CO 80309 USA. EM pgupta@picarro.com NR 0 TC 4 Z9 4 U1 0 U2 0 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A480 EP A480 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229901191 ER PT J AU Koren, I Feingold, G Remer, LA Martins, JV AF Koren, Ilan Feingold, Graham Remer, Lorraine A. Martins, J. Vanderlei TI How interactions between clouds and aerosols depend on scale SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Koren, Ilan] Weizmann Inst Sci, IL-76100 Rehovot, Israel. [Feingold, Graham] NOAA, ESRL, Boulder, CO 80305 USA. [Remer, Lorraine A.] NASA, Goddard Space Flight Ctr, Atmospheres Lab, Greenbelt, MD 20771 USA. [Martins, J. Vanderlei] Univ Maryland Baltimore Cty, Dept Phys, Baltimore, MD 21228 USA. [Martins, J. Vanderlei] Univ Maryland Baltimore Cty, Joint Ctr Earth Syst Technol, Baltimore, MD 21228 USA. EM Ilan.koren@weizmann.ac.il; Graham.Feingold@noaa.gov; lorraine.a.remer@nasa.gov; martins@umbc.edu RI Feingold, Graham/B-6152-2009; Koren, Ilan/K-1417-2012 OI Koren, Ilan/0000-0001-6759-6265 NR 0 TC 0 Z9 0 U1 0 U2 1 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A682 EP A682 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229901596 ER PT J AU Krishna, MS Anderson, DM Sarma, NS Pasha, SG AF Krishna, Moturi S. Anderson, David M. Sarma, Nittala S. Pasha, Sk. G. TI Tropical Indian Ocean temperature and salinity variations during the last 280,000 yrs SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Krishna, Moturi S.; Sarma, Nittala S.; Pasha, Sk. G.] Andhra Univ, Sch Chem, Visakhapatnam 530003, Andhra Pradesh, India. [Anderson, David M.] Univ Colorado, NOAA, Boulder, CO 80309 USA. RI anderson, david/E-6416-2011 NR 0 TC 0 Z9 0 U1 0 U2 0 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A696 EP A696 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229901624 ER PT J AU Lee, YN Springston, S Jayne, J Wang, J Hubbe, J Senum, G Brioude, J Alexander, L Kleinman, L Daum, P AF Lee, Y. -N. Springston, S. Jayne, J. Wang, J. Hubbe, J. Senum, G. Brioude, J. Alexander, L. Kleinman, L. Daum, P. TI Aerosol chemical composition and source characterization during 2008 VOCALS REX SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Lee, Y. -N.; Springston, S.; Wang, J.; Senum, G.; Kleinman, L.; Daum, P.] Brookhaven Natl Lab, Div Atmospher Sci, Upton, NY 11973 USA. [Jayne, J.] Aerodyne Res Inc, Billerica, MA 01821 USA. [Hubbe, J.; Alexander, L.] Pacific NW Natl Lab, Richland, WA 99352 USA. [Brioude, J.] NOAA, Earth Syst Res Lab, Boulder, CO 80305 USA. EM ynlee@bnl.gov RI Brioude, Jerome/E-4629-2011 NR 0 TC 0 Z9 0 U1 0 U2 3 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 SU S BP A738 EP A738 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229901708 ER PT J AU Lilley, MD Pedersen, RB Thorseth, IH Lupton, JE Olson, EJ Fruh-Green, GL Baumberger, T AF Lilley, M. D. Pedersen, R. B. Thorseth, I. H. Lupton, J. E. Olson, E. J. Frueh-Green, G. L. Baumberger, T. TI Volatiles in the Loki's Castle and Jan Mayen vent fields of the ultra-slow spreading Knipovich and Mohns Ridges SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Lilley, M. D.; Olson, E. J.] Univ Washington, Sch Oceanog, Seattle, WA 98195 USA. [Pedersen, R. B.; Thorseth, I. H.] Univ Bergen, Ctr Geobiol, N-5007 Bergen, Norway. [Lupton, J. E.] NOAA, Pacifc Marine Environm Lab, Newport, OR 97365 USA. [Frueh-Green, G. L.; Baumberger, T.] ETH, Dept Earth Sci, CH-8092 Zurich, Switzerland. EM lilley@u.washington.edu; rolf.pedersen@geo.uib.no; john.e.lupton@noaa.gov; frueh-green@erdw.ethz.ch NR 0 TC 0 Z9 0 U1 1 U2 9 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A763 EP A763 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229901758 ER PT J AU Lupton, J Resing, J Arculus, R Lilley, M Embley, R Baker, E Butterfield, D Nakamura, K Crowhurst, P Greene, R AF Lupton, J. Resing, J. Arculus, R. Lilley, M. Embley, R. Baker, E. Butterfield, D. Nakamura, K. Crowhurst, P. Greene, R. TI Hydrothermal systems and recent eruptive activity in the northern Lau Basin, South Pacific Ocean SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Lupton, J.; Embley, R.; Greene, R.] NOAA, Pacific Marine Environm Lab, Newport, OR 97365 USA. [Resing, J.; Baker, E.; Butterfield, D.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98195 USA. [Arculus, R.] Australian Natl Univ, Canberra, ACT 0200, Australia. [Lilley, M.] Univ Washington, Seattle, WA 98115 USA. [Nakamura, K.] Nautilus Minerals, Milton, Qld 4064, Australia. [Crowhurst, P.] AIST, Tsukuba, Ibaraki 3058567, Japan. EM john.e.lupton@noaa.gov RI Butterfield, David/H-3815-2016 OI Butterfield, David/0000-0002-1595-9279 NR 0 TC 0 Z9 0 U1 1 U2 2 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A804 EP A804 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229902067 ER PT J AU Lupton, JE AF Lupton, John E. TI Helium isotopes: From mantle degassing to ocean circulation SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Lupton, John E.] NOAA, Pacific Marine Environm Lab, Newport, OR 97365 USA. EM John.e.lupton@noaa.gov NR 0 TC 0 Z9 0 U1 0 U2 0 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A803 EP A803 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229902066 ER PT J AU Murphy, DM Solomon, S Portmann, RW Rosenlof, KH Forster, PM Wong, T AF Murphy, D. M. Solomon, S. Portmann, R. W. Rosenlof, K. H. Forster, P. M. Wong, T. TI The Earth's energy budget and aerosol radiative forcing SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Murphy, D. M.; Solomon, S.; Portmann, R. W.; Rosenlof, K. H.] NOAA Earth Syst Res Lab, Div Chem Sci, Washington, DC 20230 USA. [Forster, P. M.] Univ Leeds, Sch Earth & Environm, Leeds LS2 9JT, W Yorkshire, England. EM daniel.m.murphy@noaa.gov; susan.solomon@noaa.gov; robert.w..portmann@noaa.gov; karen.h.rosenlof@noaa.gov; piers@env.leeds.ac.uk; takmeng.wong@nasa.gov RI Portmann, Robert/C-4903-2009; Murphy, Daniel/J-4357-2012; Rosenlof, Karen/B-5652-2008 OI Portmann, Robert/0000-0002-0279-6087; Murphy, Daniel/0000-0002-8091-7235; Rosenlof, Karen/0000-0002-0903-8270 NR 0 TC 0 Z9 0 U1 0 U2 2 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A921 EP A921 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229902301 ER PT J AU Sorooshian, A Feingold, G AF Sorooshian, Armin Feingold, Graham TI Precipitation in warm clouds and its susceptibility to aerosol perturbations SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Sorooshian, Armin; Feingold, Graham] NOAA, Earth Syst Res Lab, Boulder, CO USA. [Sorooshian, Armin] CIRA, Boulder, CO USA. EM graham.feingold@noaa.gov RI Feingold, Graham/B-6152-2009 NR 2 TC 0 Z9 0 U1 0 U2 1 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A1255 EP A1255 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229903197 ER PT J AU Toggweiler, JR AF Toggweiler, J. R. TI Temperature differences between the hemispheres drive ice-age climate variability SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Toggweiler, J. R.] NOAA, Geophys Fluid Dynam Lab, Princeton, NJ USA. NR 0 TC 0 Z9 0 U1 0 U2 0 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A1334 EP A1334 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229903356 ER PT J AU Topalov, K Schimmelmann, A Polly, PD Sauer, PE Lowry, M AF Topalov, K. Schimmelmann, A. Polly, P. D. Sauer, P. E. Lowry, M. TI D/H of bone collagen as environmental and trophic indicator SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Topalov, K.; Schimmelmann, A.; Polly, P. D.; Sauer, P. E.] Indiana Univ, Dept Geol Sci, Bloomington, IN 47405 USA. [Lowry, M.] SW Fisheries Sci Ctr, NOAA Fisheries Serv, La Jolla, CA 92037 USA. EM aschimme@indiana.edu NR 2 TC 0 Z9 0 U1 0 U2 2 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A1340 EP A1340 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229903368 ER PT J AU Trainor, TP Iceman, CS Tanwar, KS Petitto, SC Eng, PJ Mason, S Chaka, AM AF Trainor, T. P. Iceman, C. S. Tanwar, K. S. Petitto, S. C. Eng, P. J. Mason, S. Chaka, A. M. TI Structure and modification of iron-oxide surfaces during reaction with dissolved iron SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Meeting Abstract CT 19th Annual VM Goldschmidt Conference CY JUN 21, 2009 CL Davos, SWITZERLAND C1 [Trainor, T. P.; Tanwar, K. S.; Petitto, S. C.] Univ Alaska Fairbanks, Dept Chem & Biochem, Fairbanks, AK 99775 USA. [Eng, P. J.] Univ Chicago, Consortium Adv Radiat Sources, Chicago, IL 60637 USA. [Mason, S.; Chaka, A. M.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. EM fftpt@uaf.edu; fncri@uaf.edu; ftkjt@uaf.edu; fnscp@uaf.edu; eng@cars.uchicago.edu; sara.mason@nist.gov; anne.chaka@nist.gov NR 0 TC 0 Z9 0 U1 1 U2 1 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP A1344 EP A1344 PG 1 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229903375 ER PT J AU Sunda, WG AF Sunda, William G. TI Acceptance of the 2008 Clair C. Patterson Award SO GEOCHIMICA ET COSMOCHIMICA ACTA LA English DT Editorial Material C1 [Sunda, William G.] NOAA, Beaufort Lab CCFHR, Natl Ocean Serv, Beaufort, NC 28516 USA. EM Bill.Sunda@noaa.gov NR 0 TC 0 Z9 0 U1 1 U2 2 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0016-7037 J9 GEOCHIM COSMOCHIM AC JI Geochim. Cosmochim. Acta PD JUN PY 2009 VL 73 IS 13 BP S11 EP S12 DI 10.1016/j.gca.2009.05.038 PG 2 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 460YS UT WOS:000267229900008 ER PT J AU Morton, SL Vershinin, A Smith, LL Leighfield, TA Pankov, S Quilliam, MA AF Morton, Steve L. Vershinin, Alexander Smith, Laurinda L. Leighfield, Tod A. Pankov, Sergey Quilliam, Michael A. TI Seasonality of Dinophysis spp. and Prorocentrum lima in Black Sea phytoplankton and associated shellfish toxicity SO HARMFUL ALGAE LA English DT Article DE Black Sea; Dinophyceae; Dinophysis; Dinophysistoxin; DSP; Mussel; Okadaic acid; Pectenotoxin; Phycotoxins; Phytoplankton; Prorocentrum; Shellfish aquaculture AB Plankton surveys, between 2001 and 2005 along the Russian Caucasian Black Sea Coast, revealed Dinophysis rotundata, D. caudata and Prorocentrum lima as the most ubiquitous of the known dinoflagellates associated with diarrhetic shellfish poisoning (DSP). Dinophysis spp. were first observed during the spring phytoplankton succession and persist throughout the late summer phytoplankton peak. The highest total concentration, 3000 cells/L, of D. rotundata and D, caudata was observed in April 2001. Unlike Dinophysis, P. lima was rarely observed in plankton samples but closely followed storm events with maximum cell counts of P. lima occurred in July 2002. The presence of Dinophysis in mussel (Mytilus galloprovincialis) hepatopancreas correlated with concentration with Dinophysis observed in the plankton samples. Conversely, P. lima could be found in most hepatopancreas samples collected during the May to October period. Therefore, planktonic concentration of P. lima does not reflect its availability for and consumption by shellfish. Samples of mussel hepatopancreas, from August 2002, with a corresponding Dinophysis concentration of 250 cells/L and no observable P. lima, were found to contain 0.03 ng OAE/g. This sample analyses by LC-MS/MS displayed okadaic acid (OA) and related congeners (DTX1) along with the pectinotoxins (PTX2 and PTX2sa). Highest observed levels of P. lima-induced DSP-toxicity in hepatopancreas was 0.41 g OA-equivalents/g corresponded to the highest observed planktonic cell counts of P. lima, 300 cell/L in August 2001. Cultures isolated from this sample were found to produce OA, DTX1 and their related diol esters. These data reveal a threat, represented by DSP-toxic species, at Black Sea coasts, and provide grounds for the introduction of phycotoxin control measures in the region. Published by Elsevier B.V. C1 [Morton, Steve L.; Smith, Laurinda L.; Leighfield, Tod A.] NOAA, Natl Ocean Serv, Marine Biotoxins Program, Charleston, SC 29412 USA. [Vershinin, Alexander] RAS, PP Shirshov Oceanol Inst, Moscow 127220, Russia. [Pankov, Sergey] Marine Biotechnol Ctr Bolshoy Utrish, Anapa 353410, Russia. [Quilliam, Michael A.] Natl Res Council Canada, Inst Marine Biosci, Halifax, NS B3H 3Z1, Canada. RP Morton, SL (reprint author), NOAA, Natl Ocean Serv, Marine Biotoxins Program, 219 Ft Johnson Rd, Charleston, SC 29412 USA. EM Steve.morton@noaa.gov NR 27 TC 17 Z9 23 U1 0 U2 7 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 1568-9883 J9 HARMFUL ALGAE JI Harmful Algae PD JUN PY 2009 VL 8 IS 5 BP 629 EP 636 DI 10.1016/j.hal.2008.10.011 PG 8 WC Marine & Freshwater Biology SC Marine & Freshwater Biology GA 459ZW UT WOS:000267153900001 ER PT J AU Fire, SE Wang, ZH Leighfield, TA Morton, SL Mcfee, WE McLellan, WA Litaker, RW Tester, PA Hohn, AA Lovewell, G Harms, C Rotstein, DS Barco, SG Costidis, A Sheppard, B Bossart, GD Stolen, M Durden, WN Van Dolah, FM AF Fire, Spencer E. Wang, Zhihong Leighfield, Tod A. Morton, Steve L. McFee, Wayne E. McLellan, William A. Litaker, R. Wayne Tester, Patricia A. Hohn, Aleta A. Lovewell, Gretchen Harms, Craig Rotstein, David S. Barco, Susan G. Costidis, Alex Sheppard, Barbara Bossart, Gregory D. Stolen, Megan Durden, Wendy Noke Van Dolah, Frances M. TI Domoic acid exposure in pygmy and dwarf sperm whales (Kogia spp.) from southeastern and mid-Atlantic US waters SO HARMFUL ALGAE LA English DT Article DE Domoic acid; Dwarf sperm whale; Harmful algal bloom; Kogia; Phycotoxin; Pygmy sperm whale ID LIONS ZALOPHUS-CALIFORNIANUS; PSEUDO-NITZSCHIA-AUSTRALIS; SEA LIONS; MULTISERIES; MORTALITY; TOXICITY; CHANNEL; BLOOMS AB The neurotoxin domoic acid (DA) was detected in urine and fecal samples recovered from pygmy sperm whales (Kogia breviceps) and dwarf sperm whales (Kogia sima) stranding along the U.S. Atlantic coast from 1997 to 2008. Of the 41 animals analyzed from Virginia, North Carolina, South Carolina and Florida, 24 (59%) tested positive for DA at concentrations of 0.4-1.8 ng/mL in urine and 12-13,566 ng/g in feces as determined by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Feces appeared to be the best indicator of DA exposure in Kogia spp., with 87% of all fecal samples analyzed testing positive for this toxin. Additional stranded animals (n = 40) representing 11 other cetacean species were recovered from the same region between 2006 and 2008 and analyzed by LC-MS/MS, however DA was not detected in any of these individuals. DA is produced naturally by diatoms in the genus Pseudo-nitzschia. Although blooms of DA-producing Pseudo-nitzschia have been associated with repeated large-scale marine mammal mortalities on the west coast of the U.S., there is no documented history of similar blooms on the southeast U.S. coast, and there were no observed Pseudo-nitzschia blooms in the region associated with any of these strandings. The feeding habits of Kogia spp. are poorly documented; thus, the vector(s) for DA exposure to these deep-diving species remains to be identified. Toxin accumulation in these pelagic whale species may be an indication of cryptic harmful algal bloom activity in offshore areas not currently being monitored. This study highlights the need for a better understanding of the role of toxigenic algae in marine mammal morbidity and mortality globally. Published by Elsevier B.V. C1 [Fire, Spencer E.; Wang, Zhihong; Leighfield, Tod A.; Morton, Steve L.; McFee, Wayne E.; Van Dolah, Frances M.] NOAA, Ctr Coastal Environm Hlth & Biomol Res, Charleston, SC 29412 USA. [McLellan, William A.] Univ N Carolina, Wilmington, NC 28403 USA. [Litaker, R. Wayne; Tester, Patricia A.; Hohn, Aleta A.; Lovewell, Gretchen] NOAA, Ctr Coastal Fisheries & Habitat Res, Beaufort, NC 28516 USA. [Harms, Craig] N Carolina State Univ, Ctr Marine Sci & Technol, Morehead City, NC 28557 USA. [Rotstein, David S.] Univ Tennessee, Coll Vet Med, Cooperat Ctr Marine Anim Hlth, NOAA, Knoxville, TN 37996 USA. [Barco, Susan G.] Virginia Aquarium & Marine Sci Ctr, Virginia Beach, VA 23451 USA. [Costidis, Alex; Sheppard, Barbara] Univ Florida, Coll Vet Med, Gainesville, FL 32611 USA. [Bossart, Gregory D.] Harbor Branch Oceanog Inst Inc, Marine Mammal Res & Conservat Program, Ft Pierce, FL 34946 USA. [Stolen, Megan; Durden, Wendy Noke] Hubbs SeaWorld Res Inst, Orlando, FL 32821 USA. RP Fire, SE (reprint author), NOAA, Ctr Coastal Environm Hlth & Biomol Res, 219 Ft Johnson Rd, Charleston, SC 29412 USA. EM spencer.fire@noaa.gov RI Fire, Spencer/P-6040-2014; Hohn, Aleta/G-2888-2011 OI Fire, Spencer/0000-0002-1657-790X; Hohn, Aleta/0000-0002-9992-7062 NR 45 TC 29 Z9 31 U1 5 U2 26 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 1568-9883 EI 1878-1470 J9 HARMFUL ALGAE JI Harmful Algae PD JUN PY 2009 VL 8 IS 5 BP 658 EP 664 DI 10.1016/j.hal.2008.12.002 PG 7 WC Marine & Freshwater Biology SC Marine & Freshwater Biology GA 459ZW UT WOS:000267153900005 ER PT J AU Fontes, CJ Abdallah, J Bowen, C Lee, RW Ralchenko, Y AF Fontes, C. J. Abdallah, J., Jr. Bowen, C. Lee, R. W. Ralchenko, Yu. TI Review of the NLTE-5 kinetics workshop SO HIGH ENERGY DENSITY PHYSICS LA English DT Review DE Non-LTE population kinetics; Code comparisons; Collisional-radiative modeling; Radiative power losses ID NON-LTE PLASMAS; MODEL; SPECTROSCOPY AB We review the 5th non-LTE kinetics code comparison workshop, held in November 2007. Both steady-state and time-dependent cases for elements ranging from carbon to gold were examined in detail. Calculations of radiative power losses and specific spectra were requested in addition to typical plasma quantities such as the ionization balance. Non-Maxwellian electrons, external Planckian radiation and opacity effects in spectra were also included in the comparisons. We discuss the organization of the workshop and present a set of representative results. The particular case of a tungsten plasma at tokamak operating densities was considered for the first time. Due to its importance to the ITER project, more detailed results of these comparisons will be published elsewhere. (C) 2009 Elsevier B.V. All rights reserved. C1 [Bowen, C.] CEA, DAM, DIF, F-91297 Arpajon, France. [Fontes, C. J.] Los Alamos Natl Lab, Div Appl Phys, Los Alamos, NM 87545 USA. [Abdallah, J., Jr.] Los Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USA. [Lee, R. W.] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA. [Ralchenko, Yu.] NIST, Gaithersburg, MD 20899 USA. RP Bowen, C (reprint author), CEA, DAM, DIF, F-91297 Arpajon, France. EM christopher.bowen@cea.fr RI Ralchenko, Yuri/B-7687-2011; Ralchenko, Yuri/E-9297-2016 OI Ralchenko, Yuri/0000-0003-0083-9554 FU CEA; IMDEC (Berkeley); LANL; NIST; U.S. Department of Energy through Los Alamos National Laboratory FX The organizers wish to thank H.-K. Chung, J. Colgan and S. Hansen for their contribution to the workshop and their input for this paper, and J. Bailey for agreeing to present a current experimental viewpoint in NLTE physics. Financial and organizational support from CEA, IMDEC (Berkeley), LANL and NIST are gratefully acknowledged. The work of J. Abdallah and C. Fontes was performed under the auspices of the U.S. Department of Energy through the Los Alamos National Laboratory. NR 36 TC 51 Z9 51 U1 1 U2 6 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 1574-1818 J9 HIGH ENERG DENS PHYS JI High Energy Density Phys. PD JUN PY 2009 VL 5 IS 1-2 BP 15 EP 22 DI 10.1016/j.hedp.2009.02.004 PG 8 WC Physics, Fluids & Plasmas SC Physics GA 686FF UT WOS:000284681500002 ER PT J AU Hong, K Lee, S Golmie, N AF Hong, Kunho Lee, SuKyoung Golmie, Nada TI Throughput Study for Admission Control in IEEE 802.11 DCF with ARF SO IEEE COMMUNICATIONS LETTERS LA English DT Article DE Throughput; ARF; DCF; admission control ID DISTRIBUTED COORDINATION FUNCTION AB We propose an analytical approach to determining the admission of new stations to a WLAN operating in IEEE 802.11 Distributed Coordination Function (DCF) with Auto Rate Fallback (ARF). The proposed approach is based on a cross layer analytical model of how the throughput of existing stations in the WLAN is affected by admitting the new station in non-saturated as well as saturated traffic conditions. The effectiveness of the proposed approach is verified by simulations. C1 [Hong, Kunho; Lee, SuKyoung] Yonsei Univ, Dept Comp Sci, Seoul 120749, South Korea. [Golmie, Nada] NIST, ANTD, Emerging & Mobile Network Technol Grp, Gaithersburg, MD 20899 USA. RP Hong, K (reprint author), Yonsei Univ, Dept Comp Sci, Seoul 120749, South Korea. EM sklee@cs.yonsei.ac.kr FU Development of user-centric terminal-control led seamless mobility technology [2009-F-043-01]; ITRC (Information Technology Research Center) [IITA-2008C 1090-0902-0005] FX This work was supported in part by the IT R&D program of MKE/IITA [2009-F-043-01, Development of user-centric terminal-control led seamless mobility technology] and in part by ITRC (Information Technology Research Center) support program supervised by the MKE/IITA, Korea (IITA-2008C 1090-0902-0005). NR 8 TC 4 Z9 5 U1 0 U2 1 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 1089-7798 J9 IEEE COMMUN LETT JI IEEE Commun. Lett. PD JUN PY 2009 VL 13 IS 6 BP 432 EP 434 DI 10.1109/LCOMM.2009.090108 PG 3 WC Telecommunications SC Telecommunications GA 458YE UT WOS:000267064800022 ER PT J AU Lu, KJ Fu, SL Qian, Y Chen, HH AF Lu, Kejie Fu, Shengli Qian, Yi Chen, Hsiao-Hwa TI On Capacity of Random Wireless Networks with Physical-Layer Network Coding SO IEEE JOURNAL ON SELECTED AREAS IN COMMUNICATIONS LA English DT Article DE Network coding; physical-layer network coding; throughput; random wireless network AB Throughput capacity of a random wireless network has been studied extensively in the literature. Most existing studies were based on the assumption that each transmission involves only one transmitter in order to avoid interference. However, recent studies on physical-layer network coding (PLNC) have shown that such an assumption can be relaxed to improve throughput performance of a wireless network. In PLNC, signals from different senders can be transmitted to the same receiver in the same channel simultaneously. In this paper, we investigate the impact of PLNC on throughput capacity of a random wireless network. Our study reveals that, although PLNC scheme does not change the scaling law, it can improve throughput capacity by a fixed factor. Specifically, for a one-dimensional network, we observe that PLNC can eliminate the effect of interference in some scenarios. A tighter capacity bound is derived for a two-dimensional network. In addition, we also show achievable lower bounds for random wireless networks with network coding and PLNC. C1 [Lu, Kejie] Univ Puerto Rico, Dept Elect & Comp Engn, Mayaguez, PR 00681 USA. [Fu, Shengli] Univ N Texas, Dept Elect Engn, Denton, TX 76207 USA. [Qian, Yi] NIST, Gaithersburg, MD 20899 USA. [Chen, Hsiao-Hwa] Natl Cheng Kung Univ, Dept Engn Sci, Tainan 70101, Taiwan. RP Lu, KJ (reprint author), Univ Puerto Rico, Dept Elect & Comp Engn, Mayaguez, PR 00681 USA. EM lukejie@ece.uprm.edu; fu@unt.edu; yqian@nist.gov; hshwchen@ieee.org NR 18 TC 39 Z9 43 U1 0 U2 5 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 0733-8716 J9 IEEE J SEL AREA COMM JI IEEE J. Sel. Areas Commun. PD JUN PY 2009 VL 27 IS 5 BP 763 EP 772 DI 10.1109/JSAC.2009.090616 PG 10 WC Engineering, Electrical & Electronic; Telecommunications SC Engineering; Telecommunications GA 456UT UT WOS:000266877600016 ER PT J AU Olaya, D Dresselhaus, PD Benz, SP Bjarnason, J Grossman, EN AF Olaya, David Dresselhaus, Paul D. Benz, Samuel P. Bjarnason, Jon Grossman, Erich N. TI Amorphous Nb-Si Barrier Junctions for Voltage Standard and Digital Applications SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE Josephson junctions; Josephson voltage standard; SNS junction ID JOSEPHSON TUNNEL-JUNCTIONS; CIRCUITS; FREQUENCY; GHZ AB Amorphous Nb-Si has been previously demonstrated as a Josephson junction barrier material for Nb-based superconducting voltage standard circuits, including both dc programmable and ac Josephson voltage standards operating at frequencies up to 20 GHz. This material was chosen so that the junctions could be fabricated in vertical stacks, increasing the number of junctions in an array, which in turn increases the output voltage of the circuits. This barrier material may also be used to create higher-speed junctions, because the same factors that lead to improved stacks also lead to more reproducible junctions with thin, insulating barriers. Recently, a collaboration between the Physikalisch-Technische Bundesanstalt (PTB) and the National Institute of Standards and Technology (NIST) produced 1 V and 10 V programmable Josephson voltage standard chips operating at 75 GHz that use these junctions. In this paper, we demonstrate junctions with characteristic frequencies approaching 500 GHz and observed Josephson phase locking at frequencies of 400 GHz and 800 GHz. These junctions are promising for applications in high-speed superconducting digital electronics. C1 [Olaya, David; Dresselhaus, Paul D.; Benz, Samuel P.; Bjarnason, Jon; Grossman, Erich N.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Olaya, D (reprint author), Natl Inst Stand & Technol, Boulder, CO 80305 USA. EM samuel.benz@nist.gov NR 22 TC 6 Z9 7 U1 0 U2 3 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 144 EP 148 DI 10.1109/TASC.2009.2018254 PG 5 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000006 ER PT J AU Estey, BV Beall, JA Hilton, GC Irwin, KD Schmidt, DR Ullom, JN Schwall, RE AF Estey, Brian V. Beall, James A. Hilton, Gene C. Irwin, Kent D. Schmidt, Dan R. Ullom, Joel N. Schwall, Robert E. TI Time-of-Flight Mass Spectrometry With Latching Nb Meander Detectors SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE Mass spectrometry; niobium meander ID CRYOGENIC DETECTORS AB Mass Spectrometry is widely used for protein characterization, structural virology, drug discovery, and clinical chemistry. However, the detection efficiency of existing detectors for mass spectrometry degrades rapidly as mass is increased, and is only similar to 10(-5) at 10(6) Da. Superconducting detectors provide detection efficiency that is essentially independent of mass, and previous efforts have explored the use of superconducting tunnel junctions (STJs) and normal-insulator-superconductor (NIS) microcalorimeters as detectors. Both STJ and NIS detectors, however have active areas limited to similar to 1 mm(2), well below the similar to 1 cm(2) required for a viable system. Microwave-interrogated microstripline meander detectors have the potential to provide the necessary area and speed. We describe such a design and present initial spectra of representative ionized biological molecules obtained from simple prototype detectors mounted on a cryocooler and interfaced to a commercial mass spectrometer. C1 [Estey, Brian V.; Beall, James A.; Hilton, Gene C.; Irwin, Kent D.; Schmidt, Dan R.; Ullom, Joel N.; Schwall, Robert E.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Estey, BV (reprint author), Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA. EM estey@berkeley.edu; schwall@boulder.nist.gov NR 11 TC 9 Z9 9 U1 0 U2 3 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 382 EP 385 DI 10.1109/TASC.2009.2018507 PN 1 PG 4 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000060 ER PT J AU Cecil, TW Cyberey, ME Matthews, RE Zhang, JZ Lichtenberger, AW AF Cecil, Thomas W. Cyberey, Michael E. Matthews, Roy E. Zhang, Jian Z. Lichtenberger, Arthur W. TI Development of Nb/Al-AlN/NbTiN SIS Junctions With ICP Nitridation SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE Aluminum nitride; inductively couple plasma; niobium titanium nitride; SIS ID TUNNEL-JUNCTIONS; CURRENT-DENSITY; FABRICATION; BARRIER AB Increasing the operating frequency of SIS receivers requires a shift from Nb/Al - AlO(X)/Nb junctions to new material systems. Two major limiting factors of higher frequency operation are the increase in subgap leakage that occurs in AlO(X) barriers as current densities approach and exceed 10 kA/cm(2) and the increased loss in Nb electrodes above similar to 700 GHz. A promising alternative structure is the hybrid Nb/Al-AlN/NbTiN junction. Realization of these devices has been difficult due to the challenge of fabricating devices with repeatable current densities and electrical characteristics. We present on the fabrication and dc testing of Nb/AlN/NbTiN junctions. The AlN barrier is formed using our inductively coupled plasma (ICP) technique which allows for independent control of both ion energy and current density. This improved control enables the repeatable synthesis of high quality and high Jc barriers. Nb and NbTiN electrodes are deposited by unbalanced dc magnetron. A new fabrication process was developed to enable fabrication of junctions with area as small as 0.28 mu m(2). The relationship between barrier thickness and plasma conditions is determined by in-situ discrete ellipsometry. Ellipsometry results were verified by comparison with measured current-voltage characteristics. I(V) curves for a range of junction sizes are presented. Plans for in-situ Faraday monitoring of the energy and current density of the ICP nitridation plasma will also be discussed. C1 [Cyberey, Michael E.; Matthews, Roy E.; Zhang, Jian Z.; Lichtenberger, Arthur W.] Univ Virginia, Dept Elect & Comp Engn, Charlottesville, VA 22904 USA. RP Cecil, TW (reprint author), Natl Inst Stand & Technol, Boulder, CO 80305 USA. EM twc7c@virginia.edu; mc8qr@virginia.edu; roy.matthews.iv@gmail.com; jz4n@Virginia.EDU; arthurW@virginia.edu NR 15 TC 0 Z9 0 U1 2 U2 5 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 409 EP 412 DI 10.1109/TASC.2009.2017950 PG 4 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000066 ER PT J AU Lueker, M Benson, BA Chang, CL Cho, HM Dobbs, M Holzapfel, WL Lanting, T Lee, AT Mehl, J Plagge, T Shirokoff, E Spieler, HG Vieira, JD AF Lueker, Martin Benson, Bradford A. Chang, Clarence L. Cho, Hsiao-Mei Dobbs, Matt Holzapfel, William L. Lanting, Trevor Lee, Adrian T. Mehl, Jared Plagge, Thomas Shirokoff, Erik Spieler, Helmuth G. Vieira, Joaquin D. TI Thermal Design and Characterization of Transition-Edge Sensor (TES) Bolometers for Frequency-Domain Multiplexing SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE Bolometer; multiplexer; transition-edge ID IMPEDANCE; ARRAYS AB In contemporary Cosmic Microwave Background experiments, bolometric detectors are often background limited, and in this case the sensitivity of instruments can only be improved by increasing the number of background-limited detectors, and so contemporary TES receivers contain as many pixels as possible. Frequency-Domain Multiplexing (fMUX) is one strategy for reading out many detectors with one SQUID. For any readout system, it is important to carefully evaluate the thermal design of detector, in conjunction with the readout bandwidth, in order to ensure stable electro-thermal feedback (ETF). We demonstrate a novel technique for characterizing the thermal circuit of our detectors, using am AC-bias and the fMUX electronics. This technique is used to study the internal thermal coupling of a TES bolometer. We illustrate how the insights gathered by this technique have been instrumental in improving the stability of our multiplexed detectors for the South Pole Telescope (SPT). C1 [Lueker, Martin; Benson, Bradford A.; Holzapfel, William L.; Lee, Adrian T.; Mehl, Jared; Plagge, Thomas; Shirokoff, Erik] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA. [Chang, Clarence L.; Vieira, Joaquin D.] Univ Chicago, Kavli Inst Cosmol Phys, Chicago, IL 60637 USA. [Cho, Hsiao-Mei] Natl Inst Stand & Technol, Boulder, CO 80305 USA. [Dobbs, Matt; Lanting, Trevor] McGill Univ, Montreal, PQ H3A 2T5, Canada. [Lee, Adrian T.; Spieler, Helmuth G.] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA. RP Lueker, M (reprint author), Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA. EM lueker@socrates.berkeley.edu; bbenson@bolo.berkeley.edu; clchang@kicp.uchicago.edu; hsiao-mei.cho@boulder.nist.gov; matt.dobbs@mcgill.ca; swlh@physics7.berkeley.edu; trevor.lanting@mcgill.ca; atl@cosmology.berkeley.edu; mehl@socrates.berkeley.edu; tplagge@bolo.berkeley.edu; shiro@berkeley.edu; hgspieler@lbl.gov; vieira@kicp.uchicago.edu RI Holzapfel, William/I-4836-2015 NR 16 TC 15 Z9 15 U1 0 U2 5 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 496 EP 500 DI 10.1109/TASC.2009.2018036 PG 5 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000086 ER PT J AU Shirokoff, E Benson, BA Bleem, LE Chang, CL Cho, HM Crites, AT Dobbs, MA Holzapfel, WL Lanting, T Lee, AT Lueker, M Mehl, J Plagge, T Spieler, HG Vieira, JD AF Shirokoff, Erik Benson, Bradford A. Bleem, Lindsey E. Chang, Clarence L. Cho, Hsiao-Mei Crites, Abigail T. Dobbs, Matt A. Holzapfel, William L. Lanting, Trevor Lee, Adrian T. Lueker, Martin Mehl, Jared Plagge, Thomas Spieler, Helmuth G. Vieira, Joaquin D. TI The South Pole Telescope SZ-Receiver Detectors SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE Bolometers; superconducting devices; transition edge sensors AB We will discuss the design, fabrication, and testing of a 960-element TES array installed on the new 10 meter South Pole Telescope (SPT). This array is designed to survey for galaxy clusters using the Sunyaev-Zel'dovich (SZ) effect, which is the inverse-Compton scattering of Cosmic Microwave Background photons by plasma bound to clusters of galaxies. The SPT bolometer array consists of fully lithographed spider-web absorbers fabricated on adhesive-bonded silicon wafers with an embedded metal back plane. The absorbers are connected to aluminum-titanium bilayer TESs with a transition temperature of approximately 550 mK. Additional normal-metal features adjust the devices' thermal properties to suit our readout system and observational strategy. The focal plane is cooled using a commercial, closed cycle, pulse-tube refrigerator and a three-stage helium sorption refrigerator with a 250 mK base temperature. C1 [Shirokoff, Erik; Spieler, Helmuth G.] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA. [Bleem, Lindsey E.; Chang, Clarence L.; Crites, Abigail T.; Vieira, Joaquin D.] Kavli Inst Cosmol Phys, Chicago, IL USA. [Cho, Hsiao-Mei] Natl Inst Stand & Technol, Bulder, CO 80305 USA. [Dobbs, Matt A.; Lanting, Trevor] McGill Univ, Montreal, PQ H3A 2T5, Canada. RP Shirokoff, E (reprint author), Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA. EM shiro@berkeley.edu RI Holzapfel, William/I-4836-2015 NR 8 TC 17 Z9 17 U1 0 U2 2 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 517 EP 519 DI 10.1109/TASC.2009.2018229 PG 3 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000091 ER PT J AU Jethava, N Ullom, JN Bennett, DA Doriese, WB Beall, JA Hilton, GC Horansky, RD Irwin, KD Sassi, E Vale, LR Bacrania, MK Hoover, AS Karpius, PJ Rabin, MW Rudy, CR Vo, DT AF Jethava, N. Ullom, J. N. Bennett, D. A. Doriese, W. B. Beall, J. A. Hilton, G. C. Horansky, R. D. Irwin, K. D. Sassi, E. Vale, L. R. Bacrania, M. K. Hoover, A. S. Karpius, P. J. Rabin, M. W. Rudy, C. R. Vo, D. T. TI Improved Isotopic Analysis With a Large Array of Gamma-Ray Microcalorimeters SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE Gamma-ray microcalorimeter; plutonium isotopics; SQUID multiplexing; transition edge sensor ID TRANSITION-EDGE SENSORS; SQUID MULTIPLEXER; RESOLUTION AB We present results from the largest array of gamma-ray microcalorimeters operated to date. The microcalorimeters consist of Mo/Cu transition-edge sensors with attached Sn absorbers. The detector array contains 66 pixels each with an active area 2.25 mm(2). Out of 66 pixels, 55 are active, and 31 were used to acquire a high statistics Pu gamma-ray spectrum. The energy resolution of the best 21 pixels was found to be 120 eV FWHM. The array is read out using time domain SQUID multiplexing. Here, we describe the multiplexing and present a high statistics Pu spectra. Because of the large collecting area of our array, the statistical error in the (240)Pu line intensity is approximately 0.7%, which is comparable to the systematic error in a measurement with a 500 eV germanium sensor. Hence, we have reached an important threshold for demonstrating improved isotopic measurements with microcalorimeter sensors. With straightforward changes, we plan to achieve a resolution of about 50 eV FWHM with 256 multiplexed detectors. Finally, we present early estimates of on-chip heating within our sensor array. C1 [Jethava, N.; Ullom, J. N.; Bennett, D. A.; Doriese, W. B.; Beall, J. A.; Hilton, G. C.; Horansky, R. D.; Irwin, K. D.; Sassi, E.; Vale, L. R.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. [Bacrania, M. K.; Hoover, A. S.; Karpius, P. J.; Rabin, M. W.; Rudy, C. R.; Vo, D. T.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. RP Jethava, N (reprint author), Natl Inst Stand & Technol, Boulder, CO 80305 USA. EM jethava@boulder.nist.gov RI Bennett, Douglas/B-8001-2012 OI Bennett, Douglas/0000-0003-3011-3690 NR 12 TC 1 Z9 1 U1 0 U2 3 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 536 EP 539 DI 10.1109/TASC.2009.2017945 PG 4 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000096 ER PT J AU Wikus, P Rutherford, JM Adams, JS Bagdasarova, Y Bandler, SR Bautz, M Boyce, K Brown, G Deiker, S Doriese, WB Figueroa-Feliciano, E Flanagan, K Galeazzi, M Hilton, GC Hwang, U Irwin, KD Kelley, RL Kallman, T Kilbourne, CA Kissel, S Leman, SW Levine, A Loewenstein, M Martinez-Galarce, D Mushotzky, R McCammon, D Najjar, D Petre, R Porter, FS Reintsema, CD Saab, T Schulz, N Serlemitsos, P Smith, R Ullom, JN Yoha, K AF Wikus, Patrick Rutherford, J. M. Adams, J. S. Bagdasarova, Y. Bandler, S. R. Bautz, M. Boyce, K. Brown, G. Deiker, S. Doriese, W. B. Figueroa-Feliciano, E. Flanagan, K. Galeazzi, M. Hilton, G. C. Hwang, U. Irwin, K. D. Kelley, R. L. Kallman, T. Kilbourne, C. A. Kissel, S. Leman, S. W. Levine, A. Loewenstein, M. Martinez-Galarce, D. Mushotzky, R. McCammon, D. Najjar, D. Petre, R. Porter, F. S. Reintsema, C. D. Saab, T. Schulz, N. Serlemitsos, P. Smith, R. Ullom, J. N. Yoha, K. TI Micro-X, the TES X-ray Imaging Rocket: First Year Progress SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE Cryogenics; rockets; SQUIDs; transition edge sensors; X-ray astronomy AB Micro-X is a sounding-rocket experiment that will combine a transition edge sensor (TES) microcalorimeter array with an imaging mirror to obtain high-spectral-resolution images of astronomical X-ray sources. The instrument's resolution across the 0.3-2.5 keV band will be 2 eV. The first flight will target the region of the Bright Eastern Knot of the Puppis A supernova remnant and is slated for January 2011. The obtained high-resolution X-ray spectra will be used to ascertain the temperature and ionization state of the X-ray-emitting gas and to determine its velocity structure. The TES array is read out by a time-division superconducting quantum interference device (SQUID) multiplexing system. The detector front end assembly and the SQUID multiplexing circuit are cooled to the operating temperature of 50 mK with an adiabatic demagnetization refrigerator (ADR). The design of this refrigerator is tailored to the requirements of rocket flight. Stable operation of the TES array close to the ADR magnet will be achieved with a magnetic shielding system, which will be based on a combination of a bucking coil and high-permeability and superconducting shield materials to cancel out residual fields. We describe our progress in developing the Micro-X instrument. C1 [Wikus, Patrick; Rutherford, J. M.; Bagdasarova, Y.; Bautz, M.; Figueroa-Feliciano, E.; Flanagan, K.; Kissel, S.; Leman, S. W.; Levine, A.; Najjar, D.; Schulz, N.] MIT, Cambridge, MA 02139 USA. [Adams, J. S.; Bandler, S. R.; Boyce, K.; Hwang, U.; Kelley, R. L.; Kallman, T.; Kilbourne, C. A.; Loewenstein, M.; Mushotzky, R.; Petre, R.; Porter, F. S.; Serlemitsos, P.; Smith, R.] NASA, Goddard Space Flight Ctr, Greenbelt, MD 20771 USA. [Brown, G.] Lawrence Livermore Natl Lab, High Energy Dens Phys & Astrophys Div, Livermore, CA 94550 USA. [Deiker, S.; Martinez-Galarce, D.] Lockheed Martin Solar & Astrophys Lab, Palo Alto, CA 94304 USA. [Doriese, W. B.; Hilton, G. C.; Irwin, K. D.; Reintsema, C. D.; Ullom, J. N.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. [Galeazzi, M.] Univ Miami, Dept Phys, Coral Gables, FL 33146 USA. [McCammon, D.] Univ Wisconsin, Dept Phys, Madison, WI 53706 USA. [Saab, T.; Yoha, K.] Univ Florida, Dept Phys, Gainesville, FL 32611 USA. RP Wikus, P (reprint author), MIT, 77 Massachusetts Ave, Cambridge, MA 02139 USA. EM wikus@mit.edu RI Bandler, Simon/A-6258-2010; Kelley, Richard/K-4474-2012; Porter, Frederick/D-3501-2012 OI Bandler, Simon/0000-0002-5112-8106; Porter, Frederick/0000-0002-6374-1119 NR 7 TC 1 Z9 1 U1 0 U2 4 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 553 EP 556 DI 10.1109/TASC.2009.2019129 PG 4 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000100 ER PT J AU Toonen, RC Benz, SP AF Toonen, Ryan C. Benz, Samuel P. TI Nonlinear Behavior of Electronic Components Characterized With Precision Multitones From a Josephson Arbitrary Waveform Synthesizer SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE Harmonic distortion; intermodulation distortion; Josephson arrays; signal generators ID DISTORTION; RADIOS AB We have extended the application of quantum-based electrical standards from single frequency calibrations to multi-tone tests that can be used to characterize the nonlinear behavior of electronic components and circuits. Specifically, we have used a Josephson arbitrary waveform synthesizer to generate highly accurate, two-tone waveforms having center frequencies ranging from 10 kHz to 1 MHz. These waveforms have unprecedented spectral purity because they are constructed from perfectly quantized voltage pulses. Using this measurement system, we have characterized the intermodulation distortion properties of a highly linear amplifier used in metrological applications. Additionally, we have shown that these test signals can be upconverted to microwave frequencies, so that they may be used to characterize the nonlinearities of RF and microwave components. C1 [Toonen, Ryan C.; Benz, Samuel P.] Natl Inst Stand & Technol, Quantum Voltage Project, Elect & Elect Engn Lab, Boulder, CO 80305 USA. RP Toonen, RC (reprint author), USA, Res Lab, Act Thin Films Team, Weap & Mat Res Directorate, Aberdeen Proving Ground, MD 21005 USA. EM ryan.toonen@arl.army.mil; benz@boulder.nist.gov NR 15 TC 12 Z9 13 U1 0 U2 3 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 715 EP 718 DI 10.1109/TASC.2009.2019051 PN 1 PG 4 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000136 ER PT J AU Booth, JC Orloff, ND Mateu, J AF Booth, James C. Orloff, Nathan D. Mateu, Jordi TI Measurement of the Microwave Nonlinear Response of Combined Ferroelectric-Superconductor Transmission Lines SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE Coplanar waveguide; ferroelectric; nonlinear response; transmission line ID THIN-FILMS AB We fabricated nonlinear transmission lines and resonators that incorporate both distributed nonlinear capacitance and distributed nonlinear inductance in order to explore how such nonlinear elements interact in a combined nonlinear device. This work is motivated by the desire to reduce the nonlinearity associated with high temperature superconductor (HTS) microwave circuits by active cancellation through the use of nonlinear dielectrics. We characterized the nonlinear response of composite HTS-ferroelectric devices by combining intermodulation distortion (IMD) measurements vs. incident power with detailed linear measurements to extract the nonlinear circuit impedance. By directly comparing a resonator whose nonlinear response is dominated by the HTS nonlinear response with the nonlinear response of the composite HTS-ferroelectric device at different temperatures, we were able to differentiate between HTS and ferroelectric contributions to the overall nonlinear response. Although we observe no direct evidence for the cancellation or compensation of inductive HTS nonlinear effects due to the capacitive nonlinearity of integrated ferroelectric materials, we do observe a cross-over as a function of temperature from capacitive-dominated nonlinearity to inductive-dominated nonlinearity. C1 [Booth, James C.; Orloff, Nathan D.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. [Mateu, Jordi] Univ Politecn Cataluna, Barcelona, Spain. RP Booth, JC (reprint author), Natl Inst Stand & Technol, Boulder, CO 80305 USA. EM booth@boulder.nist.gov RI mateu, jordi/H-7285-2015 OI mateu, jordi/0000-0001-9833-9966 NR 11 TC 0 Z9 0 U1 0 U2 7 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 940 EP 943 DI 10.1109/TASC.2009.2018087 PG 4 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000190 ER PT J AU Castellanos-Beltran, MA Irwin, KD Vale, LR Hilton, GC Lehnert, KW AF Castellanos-Beltran, Manuel A. Irwin, Kent D. Vale, Leila R. Hilton, Gene C. Lehnert, Konrad W. TI Bandwidth and Dynamic Range of a Widely Tunable Josephson Parametric Amplifier SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE Gain measurement; Josephson amplifiers; Josephson arrays; parametric amplifiers; SQUIDs ID NOISE; CIRCUIT AB We characterize the signal bandwidth and dynamic range of a recently developed type of Josephson parametric amplifier. These amplifiers consist of a series array of SQUIDs embedded in a microwave cavity. They are narrow band, only amplifying signals close to the cavity's resonance frequency, but the cavity's resonance frequency, and hence the amplified band, can be widely tuned. For a particular realization of these amplifiers we measure how the signal bandwidth depends on amplifier's gain. We find that the amplitude gain times signal bandwidth is approximately the linewidth of the cavity. In addition we measure the amplifier's dynamic range and saturation power. C1 [Castellanos-Beltran, Manuel A.; Lehnert, Konrad W.] Univ Colorado, JILA, Boulder, CO 80309 USA. [Castellanos-Beltran, Manuel A.; Lehnert, Konrad W.] Univ Colorado, Dept Phys, Boulder, CO 80309 USA. [Irwin, Kent D.; Vale, Leila R.; Hilton, Gene C.; Lehnert, Konrad W.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Castellanos-Beltran, MA (reprint author), Univ Colorado, JILA, Boulder, CO 80309 USA. EM castellm@colorado.edu; irwin@nist.gov; leila.vale@nist.gov; gene.hilton@nist.gov; konrad.lehnert@jila.colorado.edu RI Lehnert, Konrad/B-7577-2009 OI Lehnert, Konrad/0000-0002-0750-9649 NR 14 TC 9 Z9 9 U1 0 U2 6 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 1051-8223 EI 1558-2515 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 944 EP 947 DI 10.1109/TASC.2009.2018119 PN 1 PG 4 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000191 ER PT J AU Cicak, K Allman, MS Strong, JA Osborn, KD Simmonds, RW AF Cicak, Katarina Allman, Michael S. Strong, Joshua A. Osborn, Kevin D. Simmonds, Raymond W. TI Vacuum-Gap Capacitors for Low-Loss Superconducting Resonant Circuits SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE High-Q resonator; loss tangent; low-loss superconducting capacitor; superconducting qubit; vacuum-gap capacitor; vacuum microelectronics AB Low-loss microwave components are used in many superconducting resonant circuits from multiplexed readouts of low-temperature detector arrays to quantum bits. Two-level system defects in amorphous dielectric materials cause excess energy loss. In an effort to improve capacitor components, we have used optical lithography and micromachining techniques to develop superconducting parallel-plate capacitors in which lossy dielectrics are replaced by vacuum gaps. Resonance measurements at 50 mK on lumped LC circuits that incorporate these vacuum-gap capacitors (VGCs) reveal loss tangents at low powers as low as 4 x 10(-5) significantly lower than with capacitors using amorphous dielectrics. VGCs are structurally robust, small, and easily scaled to capacitance values above 100 pF. C1 [Cicak, Katarina; Allman, Michael S.; Strong, Joshua A.; Osborn, Kevin D.; Simmonds, Raymond W.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Cicak, K (reprint author), Natl Inst Stand & Technol, Boulder, CO 80305 USA. EM cicak@boulder.nist.gov; mallman@boulder.nist.gov; strong@boulder.nist.gov; osborn@lps.umd.edu; simmonds@boulder.nist.gov RI Allman, Michael/E-5922-2011 NR 12 TC 5 Z9 5 U1 1 U2 5 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 948 EP 952 DI 10.1109/TASC.2009.2019665 PN 1 PG 5 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000192 ER PT J AU Mueller, F Behr, R Weimann, T Palafox, L Olaya, D Dresselhaus, PD Benz, SP AF Mueller, F. Behr, R. Weimann, T. Palafox, L. Olaya, D. Dresselhaus, P. D. Benz, S. P. TI 1 V and 10 V SNS Programmable Voltage Standards for 70 GHz SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE AC Josephson voltage standard; Josephson arrays; programmable Josephson voltage standard; SINIS junction; SNS junction ID JOSEPHSON TUNNEL-JUNCTIONS; SUPERCONDUCTOR JUNCTIONS; CIRCUITS; BARRIERS AB Programmable Josephson voltage standards (PJVSs) in combination with fast switchable DC current sources have opened up new applications in the field of low-frequency AC metrology. The growing interest in output voltages of up to +/- 10 V initiated efforts by several National Metrological Institutes to realize 10 V PJVSs. Presently, only 10 V PJVSs from PTB based on SINIS junctions have been successfully incorporated into existing setups for AC metrology. However, the fabrication of 10 V SINIS arrays that are driven at 70 GHz suffers from very low yield. The recent technological progress made at NIST enabled the drop-in replacement of the low-yield SINIS arrays by more robust SNS arrays. The N-material is an amorphous Nb(x)Si(1-x) alloy near the metal-insulator transition and is deposited by co-sputtering. For the first time, fully operational 1 V and 10 V PJVSs with SNS junctions that are suitable for a 70 GHz drive have been fabricated and tested. This work was done in close cooperation between NIST and PTB. C1 [Mueller, F.; Behr, R.; Weimann, T.; Palafox, L.] PTB, D-38116 Braunschweig, Germany. [Olaya, D.; Dresselhaus, P. D.; Benz, S. P.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Mueller, F (reprint author), PTB, D-38116 Braunschweig, Germany. EM franz.mueller@ptb.de; samuel.benz@nist.gov OI Palafox, Luis/0000-0001-7663-856X NR 24 TC 43 Z9 43 U1 0 U2 5 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 981 EP 986 DI 10.1109/TASC.2009.2017911 PG 6 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000199 ER PT J AU Dresselhaus, PD Elsbury, MM Benz, SP AF Dresselhaus, Paul D. Elsbury, Michael M. Benz, Samuel P. TI Tapered Transmission Lines With Dissipative Junctions SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE Josephson arrays; nonlinear circuits; superconducting transmission lines; superconductor-normal-superconductor devices ID SUPERCONDUCTING STRIPLINES; JOSEPHSON; CIRCUITS AB NIST is optimizing the design of a 10 V programmable Josephson voltage standard so that it uses less microwave power by employing fewer parallel-biased arrays with higher voltage per array. Increasing the voltage per array by adding more junctions is challenging because the dissipation of the over-damped Josephson junctions limits the total number that may be located in each array. If there is too much dissipation in the array, the junctions at the end receive too little microwave power compared with the junctions at the beginning of the array. To compensate for the junction attenuation, tapered impedance transmission lines were used to maintain a nearly constant microwave current along the lossy transmission line. Simulation and testing have improved the microwave uniformity of our designs for tapered impedances from 85 Ohms to 5 Ohms. Low-leakage bias tees for various characteristic impedances were designed so that sub-arrays could be measured within long arrays. These tapered arrays have improved the bias current margins, junction number, and bandwidth of NIST junction arrays. By measuring the microwave power from the output of these long arrays, harmonic generation and the nonlinear properties of dissipative junction arrays are studied. C1 [Dresselhaus, Paul D.; Benz, Samuel P.] NIST, Boulder, CO 80305 USA. [Elsbury, Michael M.] Univ Colorado, Dept Elect & Comp Engn, Boulder, CO 80309 USA. RP Dresselhaus, PD (reprint author), NIST, Boulder, CO 80305 USA. EM paul.dressel-haus@nist.gov; mike.elsbury@nist.gov; benz@boulder.nist.gov NR 16 TC 15 Z9 15 U1 1 U2 4 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 993 EP 998 DI 10.1109/TASC.2009.2019245 PG 6 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000201 ER PT J AU Elsbury, MM Burroughs, CJ Dresselhaus, PD Popovic, ZB Benz, SP AF Elsbury, Michael M. Burroughs, Charles J. Dresselhaus, Paul D. Popovic, Zoya B. Benz, Samuel P. TI Microwave Packaging for Voltage Standard Applications SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article; Proceedings Paper CT Applied Superconductivity Conference CY AUG 17-22, 2008 CL Chicago, IL SP ATI Wah Chang, Coalit Commercial Applicat Superconductors, CryoZone, GE Global Res Ctr, IEEE Council Superconductiv, IEEE Magnet Soc, PHPK Technologies, SuperPower Inc, Teax Ctr Superconductiv, Univ Houston DE Cryogenic electronics; integrated circuit packaging; Josephson arrays; Josephson device packaging; superconducting device packaging; superconducting integrated circuits; superconducting microwave devices AB Improved packages for Josephson Voltage Standard (JVS) circuits have increased operating margins, reliability, and longevity of JVS systems. By using the "flip-chip-on-flex" technique, reliable chip and cryoprobe mounting have been demonstrated. The microwave structures on these packages have been improved such that more power can be delivered to the JVS chip over a wider frequency range: DC to over 30 GHz. Detailed finite-element simulations were performed to optimize the chip-to-flex launches as well as the on-flex transmission lines. It was found that coplanar waveguide transmission line designs had improved insertion and return losses compared to those of the microstrip transmission line designs, in large part due to the large discontinuities associated with through-substrate vias for microstrip ground connections. The improved coplanar-waveguide package/probe yielded insertion loss dominated by the similar to 0.25 dB/GHz cable loss and VSWR better than 2:1 for the entire 0-30 GHz band. Substantially larger JVS system operating margins were measured using the coplanar-waveguide package; for a 5120 junction array a quantized voltage step greater than 1 mA bias current range is shown for a 10-30 GHz band. C1 [Elsbury, Michael M.; Popovic, Zoya B.] Univ Colorado, Dept Elect & Comp Engn, Boulder, CO 80309 USA. [Burroughs, Charles J.; Dresselhaus, Paul D.; Benz, Samuel P.] NIST, Boulder, CO 80305 USA. RP Elsbury, MM (reprint author), Univ Colorado, Dept Elect & Comp Engn, Boulder, CO 80309 USA. EM michael.elsbury@colorado.edu; paul.dresselhaus@nist.gov; zoya.popovic@col-orado.edu NR 8 TC 0 Z9 0 U1 0 U2 1 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 1012 EP 1015 DI 10.1109/TASC.2009.2018766 PG 4 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KK UT WOS:000268282000205 ER PT J AU Parrell, JA Zhang, YZ Field, MB Meinesz, M Huang, YB Miao, HP Hong, S Cheggour, N Goodrich, L AF Parrell, Jeff A. Zhang, Youzhu Field, Mike B. Meinesz, Maarten Huang, Yibing Miao, Hanping Hong, Seung Cheggour, Najib Goodrich, Loren TI Internal Tin Nb3Sn Conductors Engineered for Fusion and Particle Accelerator Applications SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article DE Internal tin; Nb3Sn; superconducting materials ID PERFORMANCE; STRAND; SUPERCONDUCTORS; TEMPERATURE; MAGNETS; SAMPLES AB The critical current density (J(c)) of Nb3Sn strand has been significantly improved over the last several years. For most magnet applications, high J(c) internal tin has displaced bronze process strand. The highest J(c) values are obtained from distributed barrier strands. We have continued development of strands made with Nb-47wt% Ti rods to supply the dopant, and have achieved J(c) values of 3000 A/mm(2) (12 T, 4.2 K). Such wires have very good higher field performance as well, reaching 1700 A/mm(2) at 15 T. To reduce the effective filament diameter in these high J(c) strands, the number of subelement rods incorporated into the final restack billet has been increased to 127 in routine production, and results are presented on experimental 217 stacks. A new re-extrusion technique for improving the monofilament shape is also described. For fusion applications such as ITER, we have developed single-barrier internal tin strands having non-Cu J(c) values over 1100 A/mm(2) (12 T, 4.2 K) with hysteresis losses less than 700 mJ/cm(3) over non-Cu volume. The J(c)-strain behavior of such composites is also presented. C1 [Parrell, Jeff A.; Zhang, Youzhu; Field, Mike B.; Meinesz, Maarten; Huang, Yibing; Miao, Hanping; Hong, Seung; Cheggour, Najib; Goodrich, Loren] Oxford Instruments, Superconducting Technol, Carteret, NJ 07008 USA. [Cheggour, Najib; Goodrich, Loren] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Parrell, JA (reprint author), Oxford Instruments, Superconducting Technol, Carteret, NJ 07008 USA. EM jeff.parrell@oxinst.com; youzhu.zhang@oxinst.com; mike.field@oxinst.com; maarten.meinesz@oxinst.com; yibing.huang@oxinst.com; hanping.miao@oxinst.com; seung.hong@oxinst.com; cheg-gour@boulder.nist.gov; goodrich@boulder.nist.gov RI Cheggour, Najib/K-2769-2012 OI Cheggour, Najib/0000-0002-0741-3065 FU High Energy Physics Division of DOE through Lawrence Berkeley National Laboratory [DE-AC03-76SF00098] FX This work was supported in part by the High Energy Physics Division of DOE through Lawrence Berkeley National Laboratory (Contract DE-AC03-76SF00098). NR 31 TC 22 Z9 22 U1 1 U2 9 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 2573 EP 2579 DI 10.1109/TASC.2009.2018074 PN 3 PG 7 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KM UT WOS:000268282200010 ER PT J AU Motowidlo, LR Barzi, E Turrioni, D Cheggour, N Goodrich, LF AF Motowidlo, Leszek R. Barzi, Emanuela Turrioni, Daniele Cheggour, Najib Goodrich, Loren F. TI An Octagonal Architecture for High Strength PIT Nb3Sn Conductors SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article DE Hexagonal architecture; irreversible strain; Nb3Sn wire; octagonal architecture; powder-in-tube AB Powder-in-Tube (PIT) Nb3Sn conductors have been fabricated with a low-cost intermetallic Cu5Sn4 powder as the tin source. A novel octagonal PIT design that incorporates dispersion strengthened copper as well as a hexagonal PIT design were fabricated. In this paper, we compare the critical current and strain properties of the octagonal PIT conductor designs with standard hexagonal PIT conductor designs. C1 [Motowidlo, Leszek R.] SupraMagnetics Inc, Plantsville, CT 06479 USA. [Barzi, Emanuela; Turrioni, Daniele] Fermilab Natl Accelerator Lab, Batavia, IL 60510 USA. [Cheggour, Najib; Goodrich, Loren F.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Motowidlo, LR (reprint author), SupraMagnetics Inc, Plantsville, CT 06479 USA. EM LMOTO@cox.net; barzi@fnal.gov; cheggour@boulder.nist.gov RI Cheggour, Najib/K-2769-2012 OI Cheggour, Najib/0000-0002-0741-3065 FU U.S. Department of Energy [DE-FG02-05ER84381] FX This work was supported in part by the U.S. Department of Energy Grant DE-FG02-05ER84381 (High Energy Physics). NR 19 TC 6 Z9 6 U1 0 U2 3 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 2598 EP 2601 DI 10.1109/TASC.2009.2018155 PN 3 PG 4 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KM UT WOS:000268282200015 ER PT J AU Godeke, A Turrioni, D Boutboul, T Cheggour, N Ghosh, AK Goodrich, LF Meinesz, M den Ouden, A AF Godeke, Arno Turrioni, Daniele Boutboul, Thierry Cheggour, Najib Ghosh, Arup K. Goodrich, Loren F. Meinesz, Maarten den Ouden, Andries TI Interlaboratory Comparisons of NbTi Critical Current Measurements SO IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY LA English DT Article DE Critical current; NbTi; round robin; standardization ID HARD SUPERCONDUCTORS AB We report on a multi-institute comparison of critical current data measured on a modern NbTi wire for the Large Hadron Collider (LHC), which has shown a standard deviation below 1% in critical current density spread in more than 1500 measurements. Interlaboratory comparisons on Nb(3)Sn wires have shown ambiguities that could be attributable to strain related differences in critical current density, originating from differences in sample handling, reaction, and mounting techniques, or also to differences in the magnetic field and current calibrations between the institutes. A round robin test of a well characterized NbTi wire provides a baseline variance in critical current results that is presumed to be attributable only to differences in the characterization systems. Systematic differences on the order of 3.5% are found in the comparison. The most likely cause for the observed differences is a small diameter holder that brings the wire into a strain regime in which strain effects can no longer be ignored. A NbTi round robin test, when performed properly, will separate system differences from sample specific differences and provide laboratories with an opportunity to calibrate equipment against a standard measurement. C1 [Godeke, Arno] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA. [Turrioni, Daniele] Fermilab Natl Accelerator Lab, Batavia, IL 60510 USA. [Boutboul, Thierry] CERN, AT MCS, CH-1211 Geneva, Switzerland. [Cheggour, Najib; Goodrich, Loren F.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. [Ghosh, Arup K.] Brookhaven Natl Lab, Upton, NY 11973 USA. [Meinesz, Maarten] Oxford Instruments, Superconducting Technol, Carteret, NJ 07008 USA. [den Ouden, Andries] Univ Twente, Fac Sci & Technol, Low Temp Div, NL-7500 AE Enschede, Netherlands. RP Godeke, A (reprint author), Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA. EM agodeke@lbl.gov; turrioni@fnal.gov; thierry.boutboul@cern.ch; cheggour@boulder.nist.gov; aghosh@bnl.gov; goodrich@boulder.nist.gov; maarten.meinesz@oxinst.com; a.denouden@utwente.nl RI Cheggour, Najib/K-2769-2012 OI Cheggour, Najib/0000-0002-0741-3065 FU Director Office of Science High Energy Physics U.S. Department of Energy [DE-AC02-05CH11231] FX This work was supported by the Director Office of Science High Energy Physics U.S. Department of Energy under Contract DE-AC02-05CH11231. NR 12 TC 8 Z9 8 U1 0 U2 5 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 1051-8223 J9 IEEE T APPL SUPERCON JI IEEE Trans. Appl. Supercond. PD JUN PY 2009 VL 19 IS 3 BP 2633 EP 2636 DI 10.1109/TASC.2009.2019096 PG 4 WC Engineering, Electrical & Electronic; Physics, Applied SC Engineering; Physics GA 474KM UT WOS:000268282200023 ER PT J AU Hu, CM Muller-Karger, F Murch, B Myhre, D Taylor, J Luerssen, R Moses, C Zhang, CY Gramer, L Hendee, J AF Hu, Chuanmin Muller-Karger, Frank Murch, Brock Myhre, Douglas Taylor, Judd Luerssen, Remy Moses, Christopher Zhang, Caiyun Gramer, Lew Hendee, James TI Building an Automated Integrated Observing System to Detect Sea Surface Temperature Anomaly Events in the Florida Keys SO IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING LA English DT Article DE Advanced Very High Resolution Radiometer (AVHRR); cloud detection; coastal ocean observing system (COOS); Florida Keys; MODerate-resolution Imaging Spectroradiometer (MODIS); remote sensing; sea surface temperature (SST); water quality ID MISSISSIPPI-RIVER FLOOD; CORAL-REEF; CLOUD DETECTION; AVHRR DATA; FRONTAL EDDIES; SST IMAGES; SATELLITE; OCEAN; VARIABILITY; GULF AB Satellite-derived sea surface temperature (SST) images have had limited applications in near-shore and coastal environments due to inadequate spatial resolution, incorrect geocorrection, or cloud contamination. We have developed a practical approach to remove these errors using Advanced Very High Resolution Radiometer (AVHRR) and MODerate-resolution Imaging Spectro radiometer (MODIS) I-km resolution data. The objective was to improve the accuracy of SST anomaly estimates in the Florida Keys and to provide the best quality (in particular, high temporal and spatial resolutions) SST data products for this region. After manual navigation of over 47 000 AVHRR images (1993-2005), we implemented a cloud-filtering technique that differs from previously published image processing methods. The filter used a 12-year climatology and +/-3-day running SST statistics to flag cloud-contaminated pixels. Comparison with concurrent (+/-0.5 h) data from the SEAKEYS in situ stations in the Florida Keys showed near-zero bias errors (< 0.05 degrees C) in the weekly anomaly for SST anomalies between -3 degrees C and 3 degrees C, with standard deviations < 0.5 degrees C. The cloud filter was implemented using Interactive Data Language for near-real-time processing of AVHRR and MODIS data. The improved SST products were used to detect SST anomalies and to estimate degree-heating weeks (DHWs) to assess the potential for coral reef stress. The mean and anomaly products are updated weekly, with periodic updates of the DHW products, on a Web site. The SST data at specific geographical locations were also automatically ingested in near real time into National Oceanic and Atmospheric Administration's (NOAA) Integrated Coral Observing Network Web-based application to assist in management and decision making through a novel expert system tool (G2) implemented at NOAA. C1 [Hu, Chuanmin; Murch, Brock; Myhre, Douglas] Univ S Florida, Coll Marine Sci, Inst Marine Remote Sensing, St Petersburg, FL 33701 USA. [Muller-Karger, Frank] Univ Massachusetts Dartmouth, Sch Marine Sci & Technol, Dartmouth, MA 02744 USA. [Taylor, Judd] Orbital Syst Ltd, Dallas, TX 75063 USA. [Luerssen, Remy] James Madison Univ, Virginia Coastal Energy Res Consortium, Harrisonburg, VA 22807 USA. [Moses, Christopher] Jacobs Technol, St Petersburg, FL 33701 USA. [Zhang, Caiyun] Xiamen Univ, Coll Oceanog & Environm Sci, Xiamen 361005, Peoples R China. [Gramer, Lew] Univ Miami, Cooperat Inst Marine & Atmospher Studies, Miami, FL 33149 USA. [Hendee, James] NOAA, Atlantic Oceanog & Meteorol Lab, Miami, FL 33149 USA. RP Hu, CM (reprint author), Univ S Florida, Coll Marine Sci, Inst Marine Remote Sensing, St Petersburg, FL 33701 USA. RI Hendee, James/E-6358-2010; hu, chuanmin/J-5021-2012; Gramer, Lewis/A-5620-2010 OI Hendee, James/0000-0002-4799-5354; Gramer, Lewis/0000-0003-4772-1991 FU National Aeronautics and Atmospheric Administration; National Oceanic and Atmospheric Administration (NOAA); The Nature Conservancy FX This work was supported in part by the National Aeronautics and Atmospheric Administration (NASA Ocean Biology and Biogeochemistry Program and Interdisciplinary EOS Program) and in part by the National Oceanic and Atmospheric Administration (NOAA) Coral Reef Conservation Program and The Nature Conservancy. NR 56 TC 16 Z9 16 U1 2 U2 7 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855-4141 USA SN 0196-2892 J9 IEEE T GEOSCI REMOTE JI IEEE Trans. Geosci. Remote Sensing PD JUN PY 2009 VL 47 IS 6 BP 1607 EP 1620 DI 10.1109/TGRS.2008.2007425 PG 14 WC Geochemistry & Geophysics; Engineering, Electrical & Electronic; Remote Sensing; Imaging Science & Photographic Technology SC Geochemistry & Geophysics; Engineering; Remote Sensing; Imaging Science & Photographic Technology GA 450NW UT WOS:000266409100004 ER PT J AU Gaderer, G Lee, K AF Gaderer, Georg Lee, Kang TI Foreword to the Special Section on the 2007 IEEE International Symposium on Precision Clock Synchronization for Measurement, Control, and Communication SO IEEE TRANSACTIONS ON INSTRUMENTATION AND MEASUREMENT LA English DT Editorial Material C1 [Gaderer, Georg] Austrian Acad Sci, Clock Synchronizat Res Grp, A-1010 Vienna, Austria. [Lee, Kang] Natl Inst Stand & Technol, Sensor Dev & Applicat Grp, Mfg Engn Lab, Gaithersburg, MD 20899 USA. RP Gaderer, G (reprint author), Austrian Acad Sci, Clock Synchronizat Res Grp, A-1010 Vienna, Austria. NR 0 TC 0 Z9 0 U1 0 U2 4 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 0018-9456 J9 IEEE T INSTRUM MEAS JI IEEE Trans. Instrum. Meas. PD JUN PY 2009 VL 58 IS 6 BP 1831 EP 1832 DI 10.1109/TIM.2009.2013651 PG 2 WC Engineering, Electrical & Electronic; Instruments & Instrumentation SC Engineering; Instruments & Instrumentation GA 447EH UT WOS:000266173900004 ER PT J AU Yoo, SJ Golmie, N AF Yoo, Sang-Jo Golmie, Nada TI QoS Supported Dynamic Channel Scanning for Seamless Handovers in Wireless Networks SO IEICE TRANSACTIONS ON COMMUNICATIONS LA English DT Article DE scanning; QoS support; seamless handover AB Channel scanning is an important aspect of seamless handovers since it is required in order to find a target point of attachment (PoA). However, channel scanning in single radio devices may cause severe service disruptions with the current PoA so that the provided QoS will be further degraded during a handover. In this letter, we propose a dynamic channel scanning algorithm that supports QoS. Simulation results show that the proposed mechanism reduces the service disruptions and provides the desired QoS to users during the scanning period. C1 [Yoo, Sang-Jo] Inha Univ, Inchon, South Korea. NIST, Gaithersburg, MD 20899 USA. RP Yoo, SJ (reprint author), Inha Univ, Inchon, South Korea. EM sjyoo@inha.ac.kr; nada.golmie@nist.gov FU Inha University Research Grant FX This work was supported by Inha University Research Grant. NR 7 TC 0 Z9 0 U1 0 U2 0 PU IEICE-INST ELECTRONICS INFORMATION COMMUNICATIONS ENG PI TOKYO PA KIKAI-SHINKO-KAIKAN BLDG, 3-5-8, SHIBA-KOEN, MINATO-KU, TOKYO, 105-0011, JAPAN SN 0916-8516 EI 1745-1345 J9 IEICE T COMMUN JI IEICE Trans. Commun. PD JUN PY 2009 VL E92B IS 6 BP 2267 EP 2270 DI 10.1587/transcom.E92.B.2267 PG 4 WC Engineering, Electrical & Electronic; Telecommunications SC Engineering; Telecommunications GA 466CN UT WOS:000267638400048 ER PT J AU Xue, M Liu, Y Schaffino, RM Xiang, SC Zhao, XJ Zhu, GS Qiu, SL Chen, BL AF Xue, Ming Liu, Yun Schaffino, Roxanna M. Xiang, Shengchang Zhao, Xiaojun Zhu, Guang-Shan Qiu, Shi-Lun Chen, Banglin TI New Prototype Isoreticular Metal-Organic Framework Zn4O(FMA)(3) for Gas Storage SO INORGANIC CHEMISTRY LA English DT Article ID MICROPOROUS METAL; HYDROGEN STORAGE; SELECTIVE SORPTION; CARBON-DIOXIDE; HIGH-CAPACITY; PORE-SIZE; ADSORPTION; METHANE; DESIGN; SITES AB A new isoreticular metal-organic framework Zn4O(FMA)(3)center dot xG (1; FMA = fumarate; G = guest molecules) of a primitive cubic net was synthesized and structurally characterized. With intersecting pores of about 6.8 x 6.8 angstrom, the activated 1 a exhibits high gas adsorption with respect to H-2, CH4, and CO2. C1 [Xue, Ming; Schaffino, Roxanna M.; Xiang, Shengchang; Chen, Banglin] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78539 USA. [Xue, Ming; Zhao, Xiaojun; Zhu, Guang-Shan; Qiu, Shi-Lun] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China. [Liu, Yun] NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Liu, Yun] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. RP Chen, BL (reprint author), Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78539 USA. EM banglin@utpa.edu RI Chen, Banglin/F-5461-2010; Zhu, Guangshan/E-2024-2013; Liu, Yun/A-2478-2010; Xiang, Shengchang/F-9210-2010; Liu, Yun/F-6516-2012 OI Chen, Banglin/0000-0001-8707-8115; Liu, Yun/0000-0002-0944-3153; Xiang, Shengchang/0000-0001-6016-2587; Liu, Yun/0000-0002-0944-3153 FU NSF [CHE 0718281]; State Basic Research Project [2006CB806100]; Outstanding Young Scientist Foundation of NSFC [20625102] FX This work was supported by Award CHE 0718281 from the NSF (B.C.), the State Basic Research Project (2006CB806100), and the Outstanding Young Scientist Foundation of NSFC (Grant 20625102). NR 38 TC 49 Z9 49 U1 2 U2 27 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0020-1669 J9 INORG CHEM JI Inorg. Chem. PD JUN 1 PY 2009 VL 48 IS 11 BP 4649 EP 4651 DI 10.1021/ic900486r PG 3 WC Chemistry, Inorganic & Nuclear SC Chemistry GA 450VB UT WOS:000266428100020 PM 19405500 ER PT J AU Hu, RQY Hu, WW Jin, MZ Qian, Y AF Hu, Rose Qingyang Hu, Weiwei Jin, Mingzhou Qian, Yi TI Wavelength retuning without service interruption in an all-optical survivable network SO INTERNATIONAL JOURNAL OF COMMUNICATION SYSTEMS LA English DT Article DE backup path wavelength retuning (BPWR); one-path model; two-path model; switch-to-available-wavelength (STAW); exchange-wavelength (ECW); wavelength continuity ID REROUTING ALGORITHM; WDM NETWORKS AB This paper proposes a new wavelength retuning (WRT) scheme in an all-optical WDM network. Compared with the existing WRT schemes developed for all-optical networks, which can alleviate the wavelength-continuity constraint but cannot avoid service interruption or data loss, the proposed scheme is able to alleviate the wavelength-continuity constraint and reduce the connection blocking probability with no service interruption to the on-going traffic. This is achieved by allocating two routes, one for active path and one for backup path, to each incoming connection request and conducting WRT only on the backup path. The backup path provides an alternate path in case of a failure, while the active path carries traffic under normal conditions. Thus, WRT on the backup path will not cause any impact on data transmission. An optimal backup path WRT scheme and a heuristic algorithm are developed and the performance evaluation on the proposed schemes is presented. The simulation results show that the proposed optimal scheme reduces the connection blocking probability by 46.8% on average, while the proposed heuristic scheme reduces the blocking probability by 28.3% on average, all compared with the scheme without WRT. Copyright (C) 2009 John Wiley & Sons, Ltd. C1 [Qian, Yi] NIST, Gaithersburg, MD 20899 USA. [Hu, Rose Qingyang] Nortel Networks, Richardson, TX 75082 USA. [Hu, Weiwei] Mississippi State Univ, Dept Elect & Comp Engn, Mississippi State, MS 39762 USA. [Jin, Mingzhou] Mississippi State Univ, Dept Ind Engn, Mississippi State, MS 39762 USA. RP Qian, Y (reprint author), NIST, 100 Bur Dr,Stop 8920, Gaithersburg, MD 20899 USA. EM yqian@nist.gov NR 15 TC 2 Z9 2 U1 0 U2 2 PU JOHN WILEY & SONS LTD PI CHICHESTER PA THE ATRIUM, SOUTHERN GATE, CHICHESTER PO19 8SQ, W SUSSEX, ENGLAND SN 1074-5351 J9 INT J COMMUN SYST JI Int. J. Commun. Syst. PD JUN PY 2009 VL 22 IS 6 BP 719 EP 738 DI 10.1002/dac.995 PG 20 WC Engineering, Electrical & Electronic; Telecommunications SC Engineering; Telecommunications GA 459OD UT WOS:000267111700004 ER PT J AU Polikhronidi, NG Abdulagatov, IM Batyrova, RG Stepanov, GV AF Polikhronidi, N. G. Abdulagatov, I. M. Batyrova, R. G. Stepanov, G. V. TI Experimental Study of the Critical Behavior of the Isochoric Heat Capacity of Aqueous Ammonia Mixture SO INTERNATIONAL JOURNAL OF THERMOPHYSICS LA English DT Review DE Ammonia; Binary mixture; Coexistence curve; Critical parameters; Critical point; Equation of state; Isochoric heat capacity; Krichevskii parameter; Maxcondetherm; Quasi-static thermograms; Retrograde phenomena; Water ID EQUATION-OF-STATE; VAPOR-LIQUID-EQUILIBRIA; PARTIAL MOLAR VOLUMES; THERMODYNAMIC PROPERTIES; CRITICAL-POINT; CRITICAL REGION; INFINITE DILUTION; WATER-SYSTEM; CORRESPONDING STATES; PHASE-TRANSITIONS AB The isochoric heat capacity of a NH(3) + H(2)O (0.2607 mole fraction of ammonia) mixture has been measured in the near- and supercritical regions. Measurements were made in the single- and two-phase regions including the coexistence curve using a high-temperature, high-pressure, nearly constant-volume adiabatic calorimeter. Measurements were made along 38 liquid and vapor isochores in the range from 120.03 kg center dot m(-3) to 671.23 kg center dot m(-3) and at temperatures from 478 K to 634 K and at pressures up to 28 MPa. Temperatures at the liquid-gas phase transition curve, T (S)(rho), for each measured density (isochore) and the critical parameters (T (C) and rho (C)) for the 0.2607 NH(3) + 0.7393 H(2)O mixture were obtained using the quasi-static thermograms technique. The expanded uncertainty of the heat-capacity measurements at the 95 % confidence level with a coverage factor of k = 2 is estimated to be 2 % to 3 % in the near-critical and supercritical regions, 1.0 % to 1.5 % in the liquid phase, and 3 % to 4 % in the vapor phase. Uncertainties of the density, temperature, and concentration measurements are estimated to be 0.06 %, 15mK, and 5x10(-5) mole fraction, respectively. An unusual behavior of the isochoric heat capacity of the mixture was found near the maxcondetherm point (in the retrograde region). The value of the Krichevskii parameter was calculated using the critical properties data for the mixture and vapor-pressure data for the pure solvent (H(2)O). The derived value of the Krichevskii parameter was used to analyze the critical behavior of the strong (C (P) , K (T) ) and weakly (C (V) ) singular properties in terms of the principle of isomorphism of critical phenomena in binary mixtures. The values of the characteristic parameters (K (1), K (2)), temperatures (tau (1), tau (2)), and the characteristic density differences (Delta rho (1), Delta rho (2)) were calculated for the NH(3) + H(2)O mixture by using the critical-curve data. C1 [Polikhronidi, N. G.; Abdulagatov, I. M.; Batyrova, R. G.; Stepanov, G. V.] Russian Acad Sci, Inst Phys, Dagestan Sci Ctr, Makhachkala, Dagestan, Russia. [Abdulagatov, I. M.] Russian Acad Sci, Geothermal Res Inst, Dagestan Sci Ctr, Makhachkala, Dagestan, Russia. RP Abdulagatov, IM (reprint author), NIST, Thermophys Properties Div, 325 Broadway, Boulder, CO 80305 USA. EM ilmutdin@boulder.nist.gov FU Russian Foundation of Basic Research [RFBR 08-08-12258] FX I. M. Abdulagatov thanks the Thermophysical Properties Division at the National Institute of Standards and Technology for the opportunity to work as a Guest Researcher at NIST during the course of this research. This study was also supported by the Grant from the Russian Foundation of Basic Research RFBR 08-08-12258. The authors also thank Dr. J. W. Magee for his help in promoting this study and for useful discussions. NR 113 TC 15 Z9 15 U1 1 U2 7 PU SPRINGER/PLENUM PUBLISHERS PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0195-928X J9 INT J THERMOPHYS JI Int. J. Thermophys. PD JUN PY 2009 VL 30 IS 3 BP 737 EP 781 DI 10.1007/s10765-009-0602-6 PG 45 WC Thermodynamics; Chemistry, Physical; Mechanics; Physics, Applied SC Thermodynamics; Chemistry; Mechanics; Physics GA 470VF UT WOS:000268008700001 ER PT J AU King-Smith, PE Fink, BA Nichols, JJ Nichols, KK Braun, RJ McFadden, GB AF King-Smith, P. Ewen Fink, Barbara A. Nichols, Jason J. Nichols, Kelly K. Braun, Richard J. McFadden, Geoffrey B. TI The Contribution of Lipid Layer Movement to Tear Film Thinning and Breakup SO INVESTIGATIVE OPHTHALMOLOGY & VISUAL SCIENCE LA English DT Article ID SINGLE-EQUATION MODELS; PRECORNEAL FILM; CORNEAL EPITHELIUM; BLINK CYCLE; DRY EYE; THICKNESS; RUPTURE; SURFACE; TIME; DESICCATION AB PURPOSE. To investigate whether the tear film thinning between blinks is caused by evaporation or by tangential flow of the tear film along the surface of the cornea. Tangential flow was studied by measuring the movement of the lipid layer. METHODS. Four video recordings of the lipid layer of the tear film were made from 16 normal subjects, with the subjects keeping their eyes open for up to 30 seconds after a blink. To assess vertical and horizontal stretching of the lipid layer and underlying aqueous layer, lipid movement was analyzed at five positions, a middle position 1 mm below the corneal center, and four positions respectively 1 mm above, below, nasal, and temporal to this middle position. In addition, in 13 subjects, the thinning of the tear film after a blink was measured. RESULTS. The total upward movement could be fitted by the sum of an exponential decay plus a slow steady drift; this drift was upward in 14 of 16 subjects (P = 0.002). Areas of thick lipid were seen to expand causing upward or downward drift or horizontal movement. The velocity of the initial rapid upward movement and the time constant of upward movement were found to correlate significantly with tear film thickness but not with tear-thinning rate. CONCLUSIONS. Analysis indicated that the observed movement of the lipid layer was too slow to explain the observed thinning rate of the tear film. In the Appendix, it is shown that flow under a stationary lipid layer cannot explain the observed thinning rate. It is concluded that most of the observed tear thinning between blinks is due to evaporation. (Invest Ophthalmol Vis Sci. 2009; 50: 2747-2756) DOI: 10.1167/iovs.08-2459 C1 [King-Smith, P. Ewen; Fink, Barbara A.; Nichols, Jason J.; Nichols, Kelly K.] Ohio State Univ, Coll Optometry, Columbus, OH 43210 USA. [Braun, Richard J.] Univ Delaware, Dept Math Sci, Newark, DE 19716 USA. [McFadden, Geoffrey B.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP King-Smith, PE (reprint author), Ohio State Univ, Coll Optometry, 338 W 10th Ave, Columbus, OH 43210 USA. EM king-smith.1@osu.edu RI McFadden, Geoffrey/A-7920-2008; OI McFadden, Geoffrey/0000-0001-6723-2103; Nichols, Jason/0000-0003-1519-7734 FU Ohio Lions Eye Research Foundation FX Supported by the Ohio Lions Eye Research Foundation. NR 45 TC 58 Z9 58 U1 0 U2 11 PU ASSOC RESEARCH VISION OPHTHALMOLOGY INC PI ROCKVILLE PA 12300 TWINBROOK PARKWAY, ROCKVILLE, MD 20852-1606 USA SN 0146-0404 J9 INVEST OPHTH VIS SCI JI Invest. Ophthalmol. Vis. Sci. PD JUN PY 2009 VL 50 IS 6 BP 2747 EP 2756 DI 10.1167/iovs.08-2459 PG 10 WC Ophthalmology SC Ophthalmology GA 450ME UT WOS:000266403800032 PM 19218611 ER PT J AU Borsa, T Williams, DF Hale, PD Van Zeghbroeck, B AF Borsa, Tomoko Williams, Dylan F. Hale, Paul D. Van Zeghbroeck, Bart TI Novel Nano-structured Metal-Semiconductor-Metal Photodetector with High Peak Voltage SO JAPANESE JOURNAL OF APPLIED PHYSICS LA English DT Article; Proceedings Paper CT 21st International Microprocesses and Nanotechnology Conference CY OCT 27-30, 2008 CL Fukuoka, JAPAN SP Japan Soc Appl Phys & Tech, IEEE Elect Device Soc, Assoc Super Adv Elect Technol, Inst Elect Engineers Japan, Inst Elect, Informat & Commun Engineers, Japan Soc Precis Engn, Japanese Soc Synchrotron Radiat Res, Japanese Soc Microscopy, Surface Sci Soc Japan, Vacuum Soc Japan ID TRANSITION AB A novel nano-structured metal-semiconductor-metal photodetector consisting of interdigitated metal fingers and nanodots is successfully fabricated on a semi-insulating GaAs substrate by electron beam lithography, and integrated with an on-chip ground-signal-ground coplanar transmission line for pulse response measurements. The fabricated nano-structured metal-semiconcluctor-metal photodetector can be operated at 5 V, more than three times higher than the operating voltage of the regular metal-semiconductor-metal photodetector composed of narrowly spaced interdigitated electrodes only. Its dark current is lower than 0.5 nA until the bias voltage approaches the breakdown voltage. More importantly, it demonstrates a more than three times higher peak voltage output than that of the regular metal-semiconductor-metal photodetector while maintaining approximately a 10ps pulse width that is limited by the bandwidth of the measurement setup, not by the speed of the photodetector. The transit model simulation indicates that the amplitude of the pulse response is strongly influenced by the voltage collapse across the photodetector. (C) 2009 The Japan Society of Applied Physics C1 [Borsa, Tomoko; Van Zeghbroeck, Bart] Univ Colorado, Dept Elect Comp & Energy Engn, Boulder, CO 80309 USA. [Williams, Dylan F.; Hale, Paul D.] NIST, Boulder, CO 80305 USA. RP Borsa, T (reprint author), Univ Colorado, Dept Elect Comp & Energy Engn, 425 UCB, Boulder, CO 80309 USA. RI Hale, Paul/B-1737-2013 NR 10 TC 1 Z9 1 U1 0 U2 3 PU JAPAN SOCIETY APPLIED PHYSICS PI TOKYO PA KUDAN-KITA BUILDING 5TH FLOOR, 1-12-3 KUDAN-KITA, CHIYODA-KU, TOKYO, 102-0073, JAPAN SN 0021-4922 J9 JPN J APPL PHYS JI Jpn. J. Appl. Phys. PD JUN PY 2009 VL 48 IS 6 AR 06FD03 DI 10.1143/JJAP.48.06FD03 PG 5 WC Physics, Applied SC Physics GA 466PM UT WOS:000267674600027 ER PT J AU Ilavsky, J Jemian, PR Allen, AJ Zhang, F Levine, LE Long, GG AF Ilavsky, Jan Jemian, Pete R. Allen, Andrew J. Zhang, Fan Levine, Lyle E. Long, Gabrielle G. TI Ultra-small-angle X-ray scattering at the Advanced Photon Source SO JOURNAL OF APPLIED CRYSTALLOGRAPHY LA English DT Article DE ultra-small-angle X-ray scattering (USAXS); Advanced Photon Source (APS) ID DOUBLE-CRYSTAL DIFFRACTOMETER; THERMAL BARRIER COATINGS; NEUTRON-SCATTERING; PARASITIC SCATTERING; INSTRUMENT; RESOLUTION; USANS; SYNCHROTRON; MECHANISM; REACTOR AB The design and operation of a versatile ultra-small-angle X-ray scattering (USAXS) instrument at the Advanced Photon Source (APS) at Argonne National Laboratory are presented. The instrument is optimized for the high brilliance and low emittance of an APS undulator source. It has angular and energy resolutions of the order of 10(-4), accurate and repeatable X-ray energy tunability over its operational energy range from 8 to 18 keV, and a dynamic intensity range of 10(8) to 10(9), depending on the configuration. It further offers quantitative primary calibration of X-ray scattering cross sections, a scattering vector range from 0.0001 to 1 angstrom(-1), and stability and reliability over extended running periods. Its operational configurations include one-dimensional collimated (slit-smeared) USAXS, two-dimensional collimated USAXS and USAXS imaging. A robust data reduction and data analysis package, which was developed in parallel with the instrument, is available and supported at the APS. C1 [Ilavsky, Jan; Jemian, Pete R.; Zhang, Fan; Long, Gabrielle G.] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA. [Allen, Andrew J.; Levine, Lyle E.] NIST, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA. RP Ilavsky, J (reprint author), Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA. EM ilavsky@aps.anl.gov RI Zhang, Fan/A-6133-2010; USAXS, APS/D-4198-2013; OI Ilavsky, Jan/0000-0003-1982-8900 FU National Institute of Standards and Technology for the University-National Laboratory-Industry Collaborative Access Team (UNICAT); US Department of Energy; Office of Science; Office of Basic Energy Sciences [DE-AC02-06CH11357] FX The APS USAXS instrument was originally constructed by the National Institute of Standards and Technology for the University-National Laboratory-Industry Collaborative Access Team (UNICAT) for operation on Sector 33 of the APS. Research at the APS is supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences under contract No. DE-AC02-06CH11357. The authors thank John Barker (NIST) and Paul Zschack (APS) for helpful discussions. NR 51 TC 97 Z9 97 U1 3 U2 30 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 0021-8898 J9 J APPL CRYSTALLOGR JI J. Appl. Crystallogr. PD JUN PY 2009 VL 42 BP 469 EP 479 DI 10.1107/S0021889809008802 PG 11 WC Chemistry, Multidisciplinary; Crystallography SC Chemistry; Crystallography GA 448NC UT WOS:000266268300014 ER PT J AU Ward, EJ Holmes, EE Balcomb, KC AF Ward, Eric J. Holmes, Elizabeth E. Balcomb, Ken C. TI Quantifying the effects of prey abundance on killer whale reproduction SO JOURNAL OF APPLIED ECOLOGY LA English DT Article DE bayesian model selection; killer whale; management of endangered species; predator-prey interactions; resource limitation; salmon ID ANTARCTIC FUR SEALS; ORCINUS-ORCA; SENESCENCE; PACIFIC; POPULATION; DEMOGRAPHY; AGE; OSCILLATION; PERFORMANCE; SELECTION AB Management decisions for threatened and endangered species require risks to be identified and prioritized, based on the degree to which they influence population dynamics. The potential for recovery of small populations at risk may be determined by multiple factors, including intrinsic population characteristics (inbreeding, sex ratios) and extrinsic variables (prey availability, disease, human disturbance). Using Bayesian statistical methods, the impact of each of these risk factors on demographic rates can be quantified and assigned probabilities to express uncertainty. We assessed the impact of a wide range of factors on the fecundity of two threatened populations of killer whales Orcinus orca, specifically whether killer whale production is limited by availability of Chinook salmon Oncorhynchus tshawytscha. Additional variables included anthropogenic factors, climate variables, temporal effects, and population variables (population size, number of males, female age). Our results indicate that killer whale fecundity is highly correlated with the abundance of Chinook salmon. For example, the probability of a female calving differed by 50% between years of low salmon abundance and high salmon abundance. Weak evidence exists for linking fecundity to other variables, such as sea surface temperature. There was strong data support for reproductive senescence in female killer whales. This pattern of rapid maturity and gradual decline of fecundity with age commonly seen in terrestrial mammals has been documented in few marine mammal species. Maximum production for this species occurs between ages 20-22, and reproductive performance declines gradually to menopause over a period of 25 years. Synthesis and applications. Our results provide strong evidence for reproductive senescence in killer whales, and more importantly, that killer whale fecundity is strongly tied to the abundance of Chinook salmon, a species that is susceptible to environmental variation and has high commercial value to fisheries. This strong predator-prey relationship highlights the importance of understanding which salmon populations overlap with killer whales seasonally and spatially, so that those salmon populations important as prey for killer whales can be identified and targeted for conservation efforts. C1 [Ward, Eric J.; Holmes, Elizabeth E.] NOAA, Natl Marine Fisheries Serv, NW Fisheries Sci Ctr, Seattle, WA 98112 USA. [Balcomb, Ken C.] Ctr Whale Res, Friday Harbor, WA 98250 USA. RP Ward, EJ (reprint author), NOAA, Natl Marine Fisheries Serv, NW Fisheries Sci Ctr, 2725 Montlake Blvd E, Seattle, WA 98112 USA. EM Eric.Ward@noaa.gov FU National Research Council FX Post-doctoral funding supporting E. Ward was provided by the National Research Council. We would also like to thank M. Ford, C. Emmons, B. Hanson, and D. Noren for helpful discussions and comments, and M. Scheuerell for providing data for climate indices. NR 48 TC 45 Z9 47 U1 13 U2 72 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 0021-8901 EI 1365-2664 J9 J APPL ECOL JI J. Appl. Ecol. PD JUN PY 2009 VL 46 IS 3 BP 632 EP 640 DI 10.1111/j.1365-2664.2009.01647.x PG 9 WC Biodiversity Conservation; Ecology SC Biodiversity & Conservation; Environmental Sciences & Ecology GA 439GE UT WOS:000265614800017 ER PT J AU Heidinger, AK Pavolonis, MJ AF Heidinger, Andrew K. Pavolonis, Michael J. TI Gazing at Cirrus Clouds for 25 Years through a Split Window. Part I: Methodology SO JOURNAL OF APPLIED METEOROLOGY AND CLIMATOLOGY LA English DT Article ID PATMOS CLIMATE DATASET; ALGORITHM DESCRIPTION; ICE CLOUDS; RETRIEVAL; AVHRR; TEMPERATURE; ATMOSPHERE; INFORMATION; CONTRAILS; PRODUCTS AB This paper demonstrates that the split-window approach for estimating cloud properties can improve upon the methods commonly used for generating cloud temperature and emissivity climatologies from satellite imagers. Because the split-window method provides cloud properties that are consistent for day and night, it is ideally suited for the generation of a cloud climatology from the Advanced Very High Resolution Radiometer (AVHRR), which provides sampling roughly four times per day. While the split-window approach is applicable to all clouds, this paper focuses on its application to cirrus (high semitransparent ice clouds), where this approach is most powerful. An optimal estimation framework is used to extract estimates of cloud temperature, cloud emissivity, and cloud microphysics from the AVHRR split-window observations. The performance of the split-window approach is illustrated through the diagnostic quantities generated by the optimal estimation approach. An objective assessment of the performance of the algorithm cloud products from the recently launched space lidar [Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation/Cloud-Aerosol Lidar with Orthogonal Polarization (CALIPSO/CALIOP)] is used to characterize the performance of the AVHRR results and also to provide the constraints needed for the optimal estimation approach. C1 [Heidinger, Andrew K.; Pavolonis, Michael J.] NOAA, NESDIS Ctr Satellite Applicat & Res, Madison, WI 53705 USA. RP Heidinger, AK (reprint author), NOAA, NESDIS Ctr Satellite Applicat & Res, 1225 W Dayton St, Madison, WI 53705 USA. EM andrew.heidinger@noaa.gov RI Pavolonis, Mike/F-5618-2010; Heidinger, Andrew/F-5591-2010 OI Pavolonis, Mike/0000-0001-5822-219X; Heidinger, Andrew/0000-0001-7631-109X NR 26 TC 62 Z9 62 U1 0 U2 6 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 1558-8424 EI 1558-8432 J9 J APPL METEOROL CLIM JI J. Appl. Meteorol. Climatol. PD JUN PY 2009 VL 48 IS 6 BP 1100 EP 1116 DI 10.1175/2008JAMC1882.1 PG 17 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 472JF UT WOS:000268125900002 ER PT J AU Lu, HJ Xu, Q AF Lu, Huijuan Xu, Qin TI Trade-Offs between Measurement Accuracy and Resolutions in Configuring Phased-Array Radar Velocity Scans for Ensemble-Based Storm-Scale Data Assimilation SO JOURNAL OF APPLIED METEOROLOGY AND CLIMATOLOGY LA English DT Article ID ROOT KALMAN FILTER; MIGRATING BIRDS; PART II; MODEL; RETRIEVAL; IMPACT; ERROR; TESTS; WIND AB Assimilation experiments are carried out with simulated radar radial-velocity observations to examine the impacts of observation accuracy and resolutions on storm-scale wind assimilation with an ensemble square root filter (EnSRF) on a storm-resolving grid (Delta x = 2 km). In this EnSRF, the background covariance is estimated from an ensemble of 40 imperfect-model predictions. The observation error includes both measurement error and representativeness error, and the error variance is estimated from the simulated observations against the simulated "truth.'' The results show that the analysis is not significantly improved when the measurement error is overly reduced (from 4 to 1 m s(-1)) and becomes smaller than the representativeness error. The analysis can be improved by properly coarsening the observation resolution (to 2 km in the radial direction) with an increase in measurement accuracy and further improved by properly enhancing the temporal resolution of radar volume scans (from every 5 to 2 or 1 min) with a decrease in measurement accuracy. There can be an optimal balance or trade-off between measurement accuracy and resolutions (in space and time) for configuring radar scans, especially phased-array radar scans, to improve storm-scale radar wind analysis and assimilation. C1 [Xu, Qin] NOAA, Natl Severe Storms Lab, Norman, OK 73072 USA. [Lu, Huijuan] Chinese Acad Meteorol Sci, State Key Lab Severe Weather, Res Ctr Numer Predict, Beijing, Peoples R China. [Lu, Huijuan] Univ Oklahoma, Cooperat Inst Mesoscale Meteorol Studies, Norman, OK 73019 USA. RP Xu, Q (reprint author), NOAA, Natl Severe Storms Lab, 120 David L Boren Blvd, Norman, OK 73072 USA. EM qin.xu@noaa.gov FU FAA [IA DTFA03-01-X-9007]; ONR [N000140410312]; University of Oklahoma; NOAA/Office of Oceanic and Atmospheric Research under NOAA/University of Oklahoma Cooperative Agreement [NA17RJ1227]; U. S. Department of Commerce; Key Project of the National Natural Science Foundation of China [2004GB418306] FX We are thankful to the anonymous reviewers for their insightful comments and suggestions that called our attention to the representativeness error (not considered in the original submission) and improved the quality and presentation of the work. We are also thankful to Mingjing Tong and Xue Ming for their help in providing the original ARPS EnKF code, and to Mingming Yao for her help in performing numerical experiments for the revision. The computational resource was provided by the OU Supercomputing Center for Education & Research at the University of Oklahoma. The research work was supported by the FAA Contract IA DTFA03-01-X-9007 to NSSL and by ONR Grant N000140410312 to CIMMS, the University of Oklahoma. Funding was also provided to CIMMS by NOAA/Office of Oceanic and Atmospheric Research under NOAA/University of Oklahoma Cooperative Agreement NA17RJ1227, U. S. Department of Commerce. Part of this work was also funded by the Key Project of the National Natural Science Foundation of China Grant 2004GB418306. NR 29 TC 8 Z9 8 U1 0 U2 1 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 1558-8424 J9 J APPL METEOROL CLIM JI J. Appl. Meteorol. Climatol. PD JUN PY 2009 VL 48 IS 6 BP 1230 EP 1244 DI 10.1175/2008JAMC2009.1 PG 15 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 472JF UT WOS:000268125900009 ER PT J AU Knupp, KR Ware, R Cimini, D Vandenberghe, F Vivekanandan, J Westwater, E Coleman, T Phillips, D AF Knupp, K. R. Ware, R. Cimini, D. Vandenberghe, F. Vivekanandan, J. Westwater, E. Coleman, T. Phillips, D. TI Ground-Based Passive Microwave Profiling during Dynamic Weather Conditions SO JOURNAL OF ATMOSPHERIC AND OCEANIC TECHNOLOGY LA English DT Article ID CLOUD LIQUID WATER; RADIANCE INTERFEROMETER AERI; BOUNDARY-LAYER; WIND PROFILER; HUMIDITY; TEMPERATURE; VAPOR; RADIOMETER; BORE; PRECIPITATION AB Short-period (1-5 min) temperature and humidity soundings up to 10-km height are retrieved from ground-based 12-channel microwave radiometer profiler (MWRP) observations. In contrast to radiosondes, the radiometric retrievals provide very high temporal resolution (1 min or less) of thermodynamic profiles, but the vertical resolution, which declines in proportion to the height above ground level, is lower. The high temporal resolution is able to resolve detailed meso-gamma-scale thermodynamic and limited microphysical features of various rapidly changing mesoscale and/or hazardous weather phenomena. To illustrate the MWRP capabilities and potential benefits to research and operational activities, the authors present example radiometric retrievals from a variety of dynamic weather phenomena including upslope supercooled fog, snowfall, a complex cold front, a nocturnal bore, and a squall line accompanied by a wake low and other rapid variations in low-level water vapor and temperature. C1 [Knupp, K. R.] Univ Alabama, Dept Atmospher Sci, Huntsville, AL 35805 USA. [Ware, R.] Radiometrics Corp, Boulder, CO USA. [Ware, R.; Vandenberghe, F.; Vivekanandan, J.] Natl Ctr Atmospher Res, Boulder, CO 80307 USA. [Cimini, D.] Univ Aquila, Ctr Excellence CETEMPS, I-67100 Laquila, Italy. [Westwater, E.] Univ Colorado, Dept Elect & Comp Engn, NOAA CU Ctr Environm Technol, Boulder, CO 80309 USA. RP Knupp, KR (reprint author), Univ Alabama, Dept Atmospher Sci, Huntsville, AL 35805 USA. EM kevin.knupp@nsstc.uah.edu RI Cimini, Domenico/M-8707-2013 OI Cimini, Domenico/0000-0002-5962-223X FU National Science Foundation [ATM-0079829, ATM-0533596]; U.S. Army Research Laboratory [DAAD1701-C-0045] FX Three of the authors (KRK, TC, and DP) acknowledge support from the National Science Foundation under Grants ATM-0079829 (used to procure the UAH MWRP in 2001) and ATM-0533596. One of the authors (RW) acknowledges support from U.S. Army Research Laboratory Contract DAAD1701-C-0045 (E. Measure, Program Manager). NR 49 TC 35 Z9 43 U1 1 U2 4 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0739-0572 J9 J ATMOS OCEAN TECH JI J. Atmos. Ocean. Technol. PD JUN PY 2009 VL 26 IS 6 BP 1057 EP 1073 DI 10.1175/2008JTECHA1150.1 PG 17 WC Engineering, Ocean; Meteorology & Atmospheric Sciences SC Engineering; Meteorology & Atmospheric Sciences GA 462RB UT WOS:000267372200003 ER PT J AU Vidot, J Bennartz, R O'Dell, CW Preusker, R Lindstrot, R Heidinger, AK AF Vidot, Jerome Bennartz, Ralf O'Dell, Christopher W. Preusker, Rene Lindstrot, Rasmus Heidinger, Andrew K. TI CO2 Retrieval over Clouds from the OCO Mission: Model Simulations and Error Analysis SO JOURNAL OF ATMOSPHERIC AND OCEANIC TECHNOLOGY LA English DT Article ID BULK SCATTERING PROPERTIES; RADIATIVE-TRANSFER MODEL; ATMOSPHERIC CO2; PART I; INFORMATION-CONTENT; LIGHT-SCATTERING; ICE CLOUDS; BAND AB Spectral characteristics of the future Orbiting Carbon Observatory (OCO) sensor, which will be launched in January 2009, were used to infer the carbon dioxide column-averaged mixing ratio over liquid water clouds over ocean by means of radiative transfer simulations and an inversion process based on optimal estimation theory. Before retrieving the carbon dioxide column-averaged mixing ratio over clouds, cloud properties such as cloud optical depth, cloud effective radius, and cloud-top pressure must be known. Cloud properties were not included in the prior in the inversion but are retrieved within the algorithm. The high spectral resolution of the OCO bands in the oxygen absorption spectral region around 0.76 mu m, the weak CO2 absorption band around 1.61 mu m, and the strong CO2 absorption band around 2.06 mu m were used. The retrieval of all parameters relied on an optimal estimation technique that allows an objective selection of the channels needed to reach OCO's requirement accuracy. The errors due to the radiometric noise, uncertainties in temperature profile, surface pressure, spectral shift, and presence of cirrus above the liquid water clouds were quantified. Cirrus clouds and spectral shifts are the major sources of errors in the retrieval. An accurate spectral characterization of the OCO bands and an effective mask for pixels contaminated by cirrus would mostly eliminate these errors. C1 [Vidot, Jerome; Bennartz, Ralf; O'Dell, Christopher W.] Univ Wisconsin, Atmospher & Ocean Sci Dept, Madison, WI USA. [Preusker, Rene; Lindstrot, Rasmus] Free Univ Berlin, Inst Space Sci, Berlin, Germany. [Heidinger, Andrew K.] NOAA NESDIS, Ctr Satellite Applicat & Res, Madison, WI USA. RP Vidot, J (reprint author), Univ Clermont Ferrand, Lab Meteorol Phys, 24 Ave Landais, F-63000 Clermont Ferrand, France. EM j.vidot@opgc.univ-bpclermont.fr RI Bennartz, Ralf/F-3760-2010; Heidinger, Andrew/F-5591-2010; OI Heidinger, Andrew/0000-0001-7631-109X; Lindstrot, Rasmus/0000-0001-9352-3684 FU National Aeronautics and Space Administration (NASA) [NNG05GE57G] FX The authors thank anonymous reviewers for their constructive comments. We would like to thank Rasmus Lindstrot from FUB for preliminary development of the algorithm. The research described in this paper was performed for the Orbiting Carbon Observatory Project, under Contract NNG05GE57G with the National Aeronautics and Space Administration (NASA). NR 38 TC 3 Z9 3 U1 2 U2 5 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0739-0572 J9 J ATMOS OCEAN TECH JI J. Atmos. Ocean. Technol. PD JUN PY 2009 VL 26 IS 6 BP 1090 EP 1104 DI 10.1175/2009JTECHA1200.1 PG 15 WC Engineering, Ocean; Meteorology & Atmospheric Sciences SC Engineering; Meteorology & Atmospheric Sciences GA 462RB UT WOS:000267372200005 ER PT J AU Tokay, A Hartmann, P Battaglia, A Gage, KS Clark, WL Williams, CR AF Tokay, Ali Hartmann, Peter Battaglia, Alessandro Gage, Kenneth S. Clark, Wallace L. Williams, Christopher R. TI A Field Study of Reflectivity and Z-R Relations Using Vertically Pointing Radars and Disdrometers SO JOURNAL OF ATMOSPHERIC AND OCEANIC TECHNOLOGY LA English DT Article ID RAIN-GAUGE MEASUREMENTS; DROP SIZE DISTRIBUTION; INSTRUMENTAL UNCERTAINTIES; CONVECTIVE CLOUDS; SPECTRA; DISTRIBUTIONS; CALIBRATION; ERRORS AB Observations from a 16-month field study using two vertically pointing radars and a disdrometer at Wallops Island are analyzed to examine the consistency of the multi-instrument observations with respect to reflectivity and Z-R relations. The vertically pointing radars were operated at S and K bands and had a very good agreement in reflectivity at a gate centered on 175 and 177 m above ground level over a variety of storms. This agreement occurred even though the sampling volumes were of different size and even though the S band measured the reflectivity factor directly, whereas the K-band radar deduced it from attenuated K-band measurements. Indeed, the radar agreement in reflectivity at the collocated range gates was superior to that between the disdrometer and either radar. This is attributed in large part to the spatial separation of the disdrometer and radar sample volumes, although the lesser agreement observed in a prior collocated disdrometer-disdrometer comparison suggests the larger size of the radar sample volumes as well as the better overlap also play a role. Vertical variations in the observations were examined with the aid of the two radar profilers. As expected, the agreement between the disdrometer reflectivity and the reflectivity seen in the vertically pointing radars decreased with height. The effect of these vertical variations on determinations of Z-R relation coefficients was then examined, using a number of different methods for finding the best fitting coefficients. The coefficient of the Z-R relation derived from paired disdrometer rain rate and radar reflectivity decreased with height, while the exponent of the Z-R relation increased with height. The coefficient and exponent of the Z-R relations also showed sensitivity to the choice of derivation method [linear and nonlinear least squares, fixed exponent, minimizing the root-mean-square difference (RMSD), and probability matching]. The influence of the time lag between the radar and disdrometer measurements was explored by examining the RMSD in reflectivity for paired measurements between 0- and 4-min lag. The no-lag conditions had the lowest RMSD up to 400 m, while 1-min lag gave the lowest RMSD at higher heights. The coefficient and exponent of the Z-R relations, on the other hand, did not have a significant change between no-lag-and 1-min-lag-based pairs. C1 [Tokay, Ali] NASA, Goddard Space Flight Ctr, Greenbelt, MD 20771 USA. [Tokay, Ali] Univ Maryland Baltimore Cty, Joint Ctr Earth Syst Technol, Baltimore, MD 21228 USA. [Hartmann, Peter; Battaglia, Alessandro] Univ Bonn, Inst Meteorol, D-5300 Bonn, Germany. [Gage, Kenneth S.; Clark, Wallace L.; Williams, Christopher R.] NOAA, Earth Syst Res Lab, Boulder, CO USA. [Gage, Kenneth S.; Clark, Wallace L.; Williams, Christopher R.] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. RP Tokay, A (reprint author), NASA, Goddard Space Flight Ctr, Code 613-1, Greenbelt, MD 20771 USA. EM ali.tokay-1@nasa.gov RI Williams, Christopher/A-2723-2015 OI Williams, Christopher/0000-0001-9394-8850 NR 29 TC 24 Z9 26 U1 0 U2 4 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0739-0572 J9 J ATMOS OCEAN TECH JI J. Atmos. Ocean. Technol. PD JUN PY 2009 VL 26 IS 6 BP 1120 EP 1134 DI 10.1175/2008JTECHA1163.1 PG 15 WC Engineering, Ocean; Meteorology & Atmospheric Sciences SC Engineering; Meteorology & Atmospheric Sciences GA 462RB UT WOS:000267372200007 ER PT J AU Lofaj, F Wiederhorn, SN AF Lofaj, Frantisek Wiederhorn, Sheldon N. TI Creep processes in silicon nitride ceramics SO JOURNAL OF CERAMIC PROCESSING RESEARCH LA English DT Article DE Silicon nitride; Tensile creep; Dilatational stresses; Cavitation; Solution-precipitation; Crystalline secondary phases; Residual glass ID O-N GLASSES; TENSILE CREEP; OXYNITRIDE GLASSES; COMPRESSIVE CREEP; CAVITATION; BEHAVIOR; LU; LA; GD; RE AB Recent advances in our understanding of creep deformation in silicon nitride ceramics are reviewed and compared to two different models of creep. The classical models adopted from the metals literature are based on the assumption that creep occurs primarily by diffusion of atoms either through the grains, or along grain boundaries. The cavitation model of creep is-as developed specifically to explain creep in materials that consist of rigid grains with a mobile secondary phase at the grain boundaries, materials having structures similar to that of silicon nitride. Well-known effects such as creep asymmetry and a very wide range of stress exponents in the early commercial grades of silicon nitride can be fully understood within the framework of the cavitation models. The work discussed includes an identification of critical types of creep cavities in silicon nitride, the evolution of cavities with tensile strain, and an analysis of possible mechanisms involved in cavity formation. The p occurs via a combination of analysis amplifies the cavitation creep model of Luecke and Wiederhorn and assumes that creep grain boundary sliding, viscous flow and solution-precipitation of the crystalline secondary phase, resulting in a redistribution of this phase among the multigrain junctions of the solid. The increase in creel) resistance in the latest generation of silicon nitride materials was found to be related to the suppression of cavitation and a shift toward non-cavitation creep mechanisms. Differences between volume conservative mechanisms in tension and compression depend on the existence of different driving forces for creep: local tensile/compressive stresses and/or dilatational stresses. Increasing the viscosity of residual glassy films at the grain boundaries is believed to be an effective way to suppress cavitation and increase creep resistance. The addition of Lu(+3) and N(-3) to the bulk oxynitride glasses, similar to those at the grain boundary films, increases their viscosity. Thus, the suppression of cavitation and the higher creep resistance of the Lu-containing silicon nitride can be explained by the combined effect of Lu(+3) and N(-3) in the residual glass. C1 [Lofaj, Frantisek] Slovak Acad Sci, Inst Mat Res, Kosice 04353, Slovakia. [Wiederhorn, Sheldon N.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Lofaj, F (reprint author), Slovak Acad Sci, Inst Mat Res, Watsonova 47, Kosice 04353, Slovakia. EM flofaj@imr.saske.sk NR 44 TC 4 Z9 4 U1 2 U2 7 PU KOREAN ASSOC CRYSTAL GROWTH, INC PI SEOUL PA SUNGDONG POST OFFICE, P O BOX 27, SEOUL 133-600, SOUTH KOREA SN 1229-9162 J9 J CERAM PROCESS RES JI J. Ceram. Process. Res. PD JUN PY 2009 VL 10 IS 3 BP 269 EP 277 PG 9 WC Materials Science, Ceramics SC Materials Science GA 471QL UT WOS:000268073200006 ER PT J AU Caullield, JA Bruno, TJ Miller, KE AF Caullield, Jeffrey A. Bruno, Thomas J. Miller, Keith E. TI Enthalpy of Solution and Kovats Retention Indices for Nitroaromatic Compounds on Stationary Phases Using Gas Chromatography SO JOURNAL OF CHEMICAL AND ENGINEERING DATA LA English DT Article ID SOLID CHROMATOGRAPHY; EXPLOSIVES; ADSORPTION; HEATS; CLAY AB Worldwide terrorism has recently resulted in increased efforts to detect and identify explosive residues. Availability of experimentally determined thermochemical data for explosive compounds and their degradation products is limited, however. Gas chromatography was used to determine the enthalpy of solution, Delta(sol)H, for a series of nitroaromatic explosives and explosive degradation products including nitrobenzene, 2-nitrotoluene, 3-nitrotoluene, 4-nitrotoluene, 1,2-dinitrobenzene, 1,3-dinitrobenzene, 1,4-dinitrobenzene, 2,4-dinitrotoluene, 2,6-dinitrotoluene, 3,4-dinitrotoluene, 3,5-dinitrotoluene, 1,3,5-trinitrobenzene, and 2,4,6-trinitrotoluene. Four polar stationary phases (by mass composition), namely, 80 % dimethyl + 20 % diphenyl polysiloxane, 14 % cyanopropylphenyl + 86 % dimethyl polysiloxane, 50 % phenyl + 50 % methyl polysiloxane, and 100 % polyethylene glycol, were evaluated with the 13 nitroaromatic compounds. Isothermal Kovats retention indices are also reported for the nitroaromatics as well as the Delta(sol)H of several n-alkanes. Enthalpies reported herein were computed over a wide temperature range, thus net retention volumes are also tabulated to facilitate the specific needs of interested readers. C1 [Caullield, Jeffrey A.; Miller, Keith E.] Univ Denver, Dept Chem & Biochem, Denver, CO 80208 USA. [Bruno, Thomas J.] Natl Inst Stand & Technol, Thermophys Properties Div, Chem Sci & Technol Lab, Boulder, CO 80305 USA. RP Miller, KE (reprint author), Univ Denver, Dept Chem & Biochem, 2190 E Iliff Ave, Denver, CO 80208 USA. EM keith.miller@du.edu FU University of Denver, Department of Chemistry and Biochemistry; National Institute of Standards and Technology [36119] FX The authors gratefully thank the University of Denver, Department of Chemistry and Biochemistry, for financial support as well as the National Institute of Standards and Technology for the financial support provided through NIST contract 36119. NR 17 TC 12 Z9 12 U1 1 U2 8 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0021-9568 J9 J CHEM ENG DATA JI J. Chem. Eng. Data PD JUN PY 2009 VL 54 IS 6 BP 1814 EP 1822 DI 10.1021/je800851j PG 9 WC Thermodynamics; Chemistry, Multidisciplinary; Engineering, Chemical SC Thermodynamics; Chemistry; Engineering GA 458LC UT WOS:000267021200027 ER PT J AU Free, M Lanzante, J AF Free, Melissa Lanzante, John TI Effect of Volcanic Eruptions on the Vertical Temperature Profile in Radiosonde Data and Climate Models SO JOURNAL OF CLIMATE LA English DT Article ID QUASI-BIENNIAL OSCILLATION; DATA HOMOGENIZATION; TREND PROFILES; MOUNT-PINATUBO; TOTAL OZONE; EL CHICHON; SIMULATIONS; IMPACT; VARIABILITY; AEROSOL AB Both observed and modeled upper-air temperature profiles show the tropospheric cooling and tropical stratospheric warming effects from the three major volcanic eruptions since 1960. Detailed comparisons of vertical profiles of Radiosonde Atmospheric Temperature Products for Assessing Climate (RATPAC) and Hadley Centre Atmospheric Temperatures, version 2 (HadAT2), radiosonde temperatures with output from six coupled GCMs show good overall agreement on the responses to the 1991 Mount Pinatubo and 1982 El Chichon eruptions in the troposphere and stratosphere, with a tendency of the models to underestimate the upper-tropospheric cooling and overestimate the stratospheric warming relative to observations. The cooling effect at the surface in the tropics is amplified with altitude in the troposphere in both observations and models, but this amplification is greater for the observations than for the models. Models and observations show a large disagreement around 100 mb for Mount Pinatubo in the tropics, where observations show essentially no change, while models show significant warming of similar to 0.7 to similar to 2.6 K. This difference occurs even in models that accurately simulate stratospheric warming at 50 mb. Overall, the Parallel Climate Model is an outlier in that it simulates more volcanic-induced stratospheric warming than both the other models and the observations in most cases. From 1979 to 1999 in the tropics, RATPAC shows a trend of less than 0.1 K decade(-1) at and above 300 mb before volcanic effects are removed, while the mean of the models used here has a trend of more than 0.3 K decade(-1), giving a difference of similar to 0.2 K decade(-1). At 300 mb, from 0.02 to 0.10 K decade(-1) of this difference may be due to the influence of volcanic eruptions, with the smaller estimate appearing more likely than the larger. No more than similar to 0.03 K of the similar to 0.1-K difference in trends between the surface and troposphere at 700 mb or below in the radiosonde data appears to be due to volcanic effects. C1 [Free, Melissa] NOAA, Air Resources Lab, Silver Spring, MD 20910 USA. [Lanzante, John] NOAA, Geophys Fluid Dynam Lab, Princeton, NJ USA. RP Free, M (reprint author), NOAA, Air Resources Lab, 1315 EW Highway, Silver Spring, MD 20910 USA. EM melissa.free@noaa.gov NR 33 TC 14 Z9 15 U1 0 U2 8 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0894-8755 EI 1520-0442 J9 J CLIMATE JI J. Clim. PD JUN PY 2009 VL 22 IS 11 BP 2925 EP 2939 DI 10.1175/2008JCLI2562.1 PG 15 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 467SR UT WOS:000267763200008 ER PT J AU Newman, M Sardeshmukh, PD Penland, C AF Newman, Matthew Sardeshmukh, Prashant D. Penland, Cecile TI How Important Is Air-Sea Coupling in ENSO and MJO Evolution? SO JOURNAL OF CLIMATE LA English DT Article ID MADDEN-JULIAN OSCILLATION; GENERAL-CIRCULATION MODEL; SURFACE TEMPERATURE ANOMALIES; TROPICAL INTRASEASONAL VARIABILITY; NINO-SOUTHERN OSCILLATION; 1997-98 EL-NINO; PART I; EQUATORIAL PACIFIC; PATTERN-ANALYSIS; FORECAST SKILL AB The effect of air-sea coupling on tropical climate variability is investigated in a coupled linear inverse model (LIM) derived from the simultaneous and 6-day lag covariances of observed 7-day running mean departures from the annual cycle. The model predicts the covariances at all other lags. The predicted and observed lag covariances, as well as the associated power spectra, are generally found to agree within sampling uncertainty. This validates the LIM's basic premise that beyond daily time scales, the evolution of tropical atmospheric and oceanic anomalies is effectively linear and stochastically driven. It also justifies a linear diagnosis of air-sea coupling in the system. The results show that air-sea coupling has a very small effect on subseasonal atmospheric variability. It has much larger effects on longer-term variability, in both the atmosphere and the ocean, including greatly increasing the amplitude of ENSO and lengthening its dominant period from 2 to 4 years. Consistent with these results, the eigenvectors of the system's dynamical evolution operator also separate into two distinct, but nonorthogonal, subspaces: one governing the nearly uncoupled subseasonal dynamics and the other governing the strongly coupled longer-term dynamics. These subspaces arise naturally from the LIM analysis; no bandpass frequency filtering need be applied. One implication of this remarkably clean separation of the uncoupled and coupled dynamics is that GCM errors in anomalous tropical air-sea coupling may cause substantial errors on interannual and longer time scales but probably not on the subseasonal scales associated with the MJO. C1 [Newman, Matthew; Sardeshmukh, Prashant D.] Univ Colorado, CIRES Climate Diagnost Ctr, Boulder, CO 80309 USA. [Newman, Matthew; Sardeshmukh, Prashant D.; Penland, Cecile] NOAA Earth Syst Res Lab, Div Phys Sci, Boulder, CO USA. RP Newman, M (reprint author), NOAA ESRL PSD R PSD1, 325 Broadway, Boulder, CO 80305 USA. EM matt.newman@noaa.gov RI Newman, Matthew /F-8336-2010 OI Newman, Matthew /0000-0001-5348-2312 FU Office of Science, U.S. Department of Energy; NOAA CLIVAR-Pacific FX The authors thank George Kiladis and Klaus Weickmann for useful conversations. Ludmila Matrosova kindly supplied code to interpolate weekly SST to daily time scales. Paul Roundy and an anonymous reviewer made useful comments on an earlier version of the manuscript. We acknowledge the international modeling groups for providing their data for analysis and the Program for Climate Model Diagnosis and Intercomparison (PCMDI) for collecting and archiving the model data. The IPCC Data Archive at the Lawrence Livermore National Laboratory is supported by the Office of Science, U.S. Department of Energy. This work was partially supported by a grant from NOAA CLIVAR-Pacific. NR 70 TC 34 Z9 35 U1 1 U2 16 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0894-8755 J9 J CLIMATE JI J. Clim. PD JUN PY 2009 VL 22 IS 11 BP 2958 EP 2977 DI 10.1175/2008JCLI2659.1 PG 20 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 467SR UT WOS:000267763200010 ER PT J AU Waliser, D Sperber, K Hendon, H Kim, D Wheeler, M Weickmann, K Zhang, C Donner, L Gottschalck, J Higgins, W Kang, IS Legler, D Moncrieff, M Vitart, F Wang, B Wang, W Woolnough, S Maloney, E Schubert, S Stern, W AF Waliser, D. Sperber, K. Hendon, H. Kim, D. Wheeler, M. Weickmann, K. Zhang, C. Donner, L. Gottschalck, J. Higgins, W. Kang, I. -S. Legler, D. Moncrieff, M. Vitart, F. Wang, B. Wang, W. Woolnough, S. Maloney, E. Schubert, S. Stern, W. CA Clivar Madden-Julian Oscillation TI MJO Simulation Diagnostics SO JOURNAL OF CLIMATE LA English DT Review ID MADDEN-JULIAN OSCILLATION; TROPICAL INTRASEASONAL OSCILLATION; SEA-SURFACE TEMPERATURE; GENERAL-CIRCULATION MODEL; ASIAN SUMMER MONSOON; EXTREME PRECIPITATION EVENTS; NINO SOUTHERN-OSCILLATION; COUPLED EQUATORIAL WAVES; EASTERN NORTH PACIFIC; 30-50 DAY VARIABILITY AB The Madden-Julian oscillation (MJO) interacts with and influences a wide range of weather and climate phenomena (e. g., monsoons, ENSO, tropical storms, midlatitude weather), and represents an important, and as yet unexploited, source of predictability at the subseasonal time scale. Despite the important role of the MJO in climate and weather systems, current global circulation models (GCMs) exhibit considerable shortcomings in representing this phenomenon. These shortcomings have been documented in a number of multimodel comparison studies over the last decade. However, diagnosis of model performance has been challenging, and model progress has been difficult to track, because of the lack of a coherent and standardized set of MJO diagnostics. One of the chief objectives of the U. S. Climate Variability and Predictability (CLIVAR) MJO Working Group is the development of observation-based diagnostics for objectively evaluating global model simulations of the MJO in a consistent framework. Motivation for this activity is reviewed, and the intent and justification for a set of diagnostics is provided, along with specification for their calculation, and illustrations of their application. The diagnostics range from relatively simple analyses of variance and correlation to more sophisticated space-time spectral and empirical orthogonal function analyses. These diagnostic techniques are used to detect MJO signals, to construct composite life cycles, to identify associations of MJO activity with the mean state, and to describe interannual variability of the MJO. C1 [Waliser, D.] CALTECH, Jet Prop Lab, Pasadena, CA 91109 USA. [Sperber, K.] Lawrence Livermore Natl Lab, PCMDI, Livermore, CA USA. [Hendon, H.; Wheeler, M.] Ctr Australian Weather & Climate Res, Melbourne, Vic, Australia. [Kim, D.] Seoul Natl Univ, Seoul, South Korea. [Maloney, E.] Colorado State Univ, Ft Collins, CO 80523 USA. [Weickmann, K.] NOAA Earth Syst Res Lab, Boulder, CO USA. [Zhang, C.] Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, Miami, FL 33149 USA. [Donner, L.; Stern, W.] NOAA GFDL, Princeton, NJ USA. [Gottschalck, J.; Higgins, W.; Wang, W.] NOAA NCEP, Camp Springs, MD USA. [Kang, I. -S.] Seoul Natl Univ, Seoul, South Korea. [Legler, D.] US CLIVAR Off, Washington, DC USA. [Moncrieff, M.] NCAR, Boulder, CO USA. [Schubert, S.] NASA, Goddard Space Flight Ctr, Greenbelt, MD 20771 USA. [Vitart, F.] European Ctr Medium Range Weather Forecasts, Reading RG2 9AX, Berks, England. [Wang, B.] Univ Hawaii Manoa, IPRC, Honolulu, HI 96822 USA. [Woolnough, S.] Univ Reading, Reading, Berks, England. RP Waliser, D (reprint author), CALTECH, Jet Prop Lab, MS 183-505,4800 Oak Grove Dr, Pasadena, CA 91109 USA. EM duane.waliser@jpl.nasa.gov RI Wheeler, Matthew/C-9038-2011; Maloney, Eric/A-9327-2008; Sperber, Kenneth/H-2333-2012; 안, 민섭/D-9972-2015 OI Wheeler, Matthew/0000-0002-9769-1973; Maloney, Eric/0000-0002-2660-2611; FU U.S. CLIVAR and International CLIVAR; U.S. Department of Energy Office of Science; Lawrence Livermore National Laboratory [DE-AC52-07NA27344]; NSF Climate and Large-Scale Dynamics Program [ATM-063234]; NOAA CPPA Award [NA05OAR4310006]; NSF [ATM0739402]; NOAA Office of Global Programs through the Cooperative Institute for Marine and Atmospheric Studies (CIMAS); Korea Meteorological Administration Research and Development Program [CATER_ 2006-4206]; BK21 program FX The MJOWG wishes to acknowledge and thank U.S. CLIVAR and International CLIVAR for supporting this working group and its activities. We would like to specifically acknowledge the administrative support on behalf of the MJOWG by Cathy Stevens of the U.S. CLIVAR Office. KRS was supported under the auspices of the U.S. Department of Energy Office of Science, Climate Change Prediction Program by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. DEW's contributions to this study were carried out on behalf of the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration (NASA). EDM was supported by the NSF Climate and Large-Scale Dynamics Program under Grant ATM-063234, and by NOAA CPPA Award NA05OAR4310006. CZ was support by NSF Grant ATM0739402 and by the NOAA Office of Global Programs through the Cooperative Institute for Marine and Atmospheric Studies (CIMAS). D. Kim and I. Kang were supported by the Korea Meteorological Administration Research and Development Program under Grant CATER_ 2006-4206 and BK21 program. NR 138 TC 110 Z9 111 U1 1 U2 25 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0894-8755 EI 1520-0442 J9 J CLIMATE JI J. Clim. PD JUN PY 2009 VL 22 IS 11 BP 3006 EP 3030 DI 10.1175/2008JCLI2731.1 PG 25 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 467SR UT WOS:000267763200013 ER PT J AU Yang, S Jiang, YD Zheng, DW Higgins, RW Zhang, Q Kousky, VE Wen, M AF Yang, Song Jiang, Yundi Zheng, Dawei Higgins, R. Wayne Zhang, Qin Kousky, Vernon E. Wen, Min TI Variations of US Regional Precipitation and Simulations by the NCEP CFS: Focus on the Southwest SO JOURNAL OF CLIMATE LA English DT Article ID CLIMATE FORECAST SYSTEM; SEA-SURFACE TEMPERATURE; ASIAN SUMMER MONSOON; UNITED-STATES; INTERANNUAL VARIABILITY; SOUTHERN OSCILLATION; PREDICTION; RAINFALL; MEXICO; MODEL AB Variations of U. S. regional precipitation in both observations and free-run experiments with the NCEP Climate Forecast System (CFS) are investigated. The seasonality of precipitation over the continental United States and the time-frequency characteristics of precipitation over the Southwest (SW) are the focus. The differences in precipitation variation among different model resolutions are also analyzed. The spatial distribution of U. S. precipitation is characterized by high values over the East and the West Coasts, especially over the Gulf Coast and southeast states, and low values elsewhere except over the SW in summer. A large annual cycle of precipitation occurs over the SW, northern plains, and the West Coast. Overall, the CFS captures the above features reasonably well, except for the SW. However, it overestimates the precipitation over the western United States, except the SW in summer, and underestimates the precipitation over the central South, except in springtime. It also overestimates (underestimates) the precipitation seasonality over the intermountain area and Gulf Coast states (SW, West Coast, and northern Midwest). The model using T126 resolution captures the observed features more realistically than at the lower T62 resolution over a large part of the United States. The variability of observed SW precipitation is characterized by a large annual cycle, followed by a semiannual cycle, and the oscillating signals on annual, semiannual, and interannual time scales account for 41% of the total precipitation variability. However, the CFS, at both T62 and T126 resolution, fails in capturing the above feature. The variability of SW precipitation in the CFS is much less periodic. The annual oscillation of model precipitation is much weaker than that observed and it is even much weaker than the simulated semiannual oscillation. The weakly simulated annual cycle is attributed by the unrealistic precipitation simulations of all seasons, especially spring and summer. On the annual time scale, the CFS fails in simulating the relationship between the SW precipitation and the basinwide sea surface temperature (SST) and the overlying atmospheric circulation. On the semiannual time scale, the model exaggerates the response of the regional precipitation to the variations of SST and atmospheric circulation over the tropics and western Atlantic, including the Gulf of Mexico. This study also demonstrates a challenge for the next-generation CFS, at T126 resolution, to predict the variability of North American monsoon climate. C1 [Jiang, Yundi] China Meteorol Adm, Natl Climate Ctr, Beijing 100081, Peoples R China. [Yang, Song; Higgins, R. Wayne; Zhang, Qin; Kousky, Vernon E.] NOAA, Climate Predict Ctr, Camp Springs, MD USA. [Zheng, Dawei] Chinese Acad Sci, Shanghai Astron Observ, Shanghai, Peoples R China. [Wen, Min] Chinese Acad Meteorol Sci, Beijing, Peoples R China. RP Jiang, YD (reprint author), China Meteorol Adm, Natl Climate Ctr, 46 Zhongguancun Nandajie, Beijing 100081, Peoples R China. EM jiangyd@cma.gov.cn RI Yang, Song/B-4952-2009 FU U. S. National Oceanic and Atmospheric Administration; China Meteorological Administration bilateral program on climate and monsoons FX We are thankful to Viviane Silva, Huug van den Dool, and Hui Wang of the NOAA Climate Prediction Center and three anonymous reviewers, who provided helpful comments for improving the overall quality of the manuscript. Bhaskar Jha provided the AMIP output for computing the Southwest U. S. precipitation used in Fig. 7d. Yundi Jiang and Min Wen were partially supported by the U. S. National Oceanic and Atmospheric Administration and the China Meteorological Administration bilateral program on climate and monsoons. NR 55 TC 15 Z9 15 U1 1 U2 8 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0894-8755 J9 J CLIMATE JI J. Clim. PD JUN PY 2009 VL 22 IS 12 BP 3211 EP 3231 DI 10.1175/2009JCLI2532.1 PG 21 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 472JI UT WOS:000268126300003 ER PT J AU Findell, KL Pitman, AJ England, MH Pegion, PJ AF Findell, Kirsten L. Pitman, Andrew J. England, Matthew H. Pegion, Philip J. TI Regional and Global Impacts of Land Cover Change and Sea Surface Temperature Anomalies SO JOURNAL OF CLIMATE LA English DT Article ID TROPICAL DEFORESTATION; PART I; CARBON-DIOXIDE; CLIMATE MODEL; ATMOSPHERE; PRECIPITATION; CIRCULATION; VEGETATION; PARAMETERIZATION; SENSITIVITY AB The atmospheric and land components of the Geophysical Fluid Dynamics Laboratory's (GFDL's) Climate Model version 2.1 (CM2.1) is used with climatological sea surface temperatures (SSTs) to investigate the relative climatic impacts of historical anthropogenic land cover change (LCC) and realistic SST anomalies. The SST forcing anomalies used are analogous to signals induced by El Nino-Southern Oscillation (ENSO), the North Atlantic Oscillation (NAO), and the background global warming trend. Coherent areas of LCC are represented throughout much of central and eastern Europe, northern India, southeastern China, and on either side of the ridge of the Appalachian Mountains in North America. Smaller areas of change are present in various tropical regions. The land cover changes in the model are almost exclusively a conversion of forests to grasslands. Model results show that, at the global scale, the physical impacts of LCC on temperature and rainfall are less important than large-scale SST anomalies, particularly those due to ENSO. However, in the regions where the land surface has been altered, the impact of LCC can be equally or more important than the SST forcing patterns in determining the seasonal cycle of the surface water and energy balance. Thus, this work provides a context for the impacts of LCC on climate: namely, strong regional-scale impacts that can significantly change globally averaged fields but that rarely propagate beyond the disturbed regions. This suggests that proper representation of land cover conditions is essential in the design of climate model experiments, particularly if results are to be used for regional-scale assessments of climate change impacts. C1 [Findell, Kirsten L.] NOAA, Geophys Fluid Dynam Lab, Princeton, NJ 08540 USA. [Findell, Kirsten L.; Pitman, Andrew J.; England, Matthew H.] Univ New S Wales, Climate Change Res Ctr, Sydney, NSW, Australia. [Pegion, Philip J.] NASA, Goddard Space Flight Ctr, Global Modeling & Assimilat Off, Greenbelt, MD 20771 USA. [Pegion, Philip J.] Sci Applicat Int Corp, Beltsville, MD USA. RP Findell, KL (reprint author), NOAA, Geophys Fluid Dynam Lab, 201 Forrestal Rd, Princeton, NJ 08540 USA. EM kirsten.findell@noaa.gov RI Pitman, Andrew/A-7353-2011; Pegion, Philip/E-5247-2012; England, Matthew/A-7539-2011; Findell, Kirsten/D-4430-2014 OI Pitman, Andrew/0000-0003-0604-3274; England, Matthew/0000-0001-9696-2930; NR 61 TC 34 Z9 37 U1 5 U2 34 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0894-8755 EI 1520-0442 J9 J CLIMATE JI J. Clim. PD JUN PY 2009 VL 22 IS 12 BP 3248 EP 3269 DI 10.1175/2008JCLI2580.1 PG 22 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 472JI UT WOS:000268126300005 ER PT J AU Jiang, CL Thompson, L Kelly, KA Cronin, MF AF Jiang, Chuanli Thompson, Luanne Kelly, Kathryn A. Cronin, Meghan F. TI The Roles of Intraseasonal Kelvin Waves and Tropical Instability Waves in SST Variability along the Equatorial Pacific in an Isopycnal Ocean Model SO JOURNAL OF CLIMATE LA English DT Article ID MADDEN-JULIAN OSCILLATION; SEA-SURFACE TEMPERATURE; 1997-98 EL-NINO; NORTH PACIFIC; HEAT-BUDGET; ANOMALIES; CYCLE; ADVECTION; EVOLUTION; BALANCE AB The roles of intraseasonal Kelvin waves and tropical instability waves (TIWs) in the intraseasonal and low-frequency mixed-layer temperature budget were examined in an isopycnal ocean model forced by QuikSCAT winds from 2000 to 2004. Correlations between temperature tendency and other terms of the intraseasonal budget compare well with previous results using Tropical Atmosphere Ocean (TAO) observations: the net heat flux has the largest correlation in the western Pacific and zonal advection has the largest correlation in the central Pacific. In the central Pacific, the intraseasonal variations in zonal advection were due to both the zonal background velocity acting on the Kelvin wave temperature anomaly and the Kelvin wave's anomalous velocity acting on the background temperature. In the eastern Pacific, three of the four temperature budget terms have comparable correlations. In particular, the vertical processes acting on the shallow thermocline cause large SST anomalies in phase with the intraseasonal thermocline anomalies. On intraseasonal time scales, the influence of individual composite upwelling and downwelling Kelvin waves cancel each other. However, because the intraseasonal SST anomalies increase to the east, a zonal gradient of SST is generated that is in phase with intraseasonal zonal velocity. Consequently, heat advection by the Kelvin waves rectifies into lower frequencies in the eastern Pacific. Rectification resulting from TIWs was also seen. The prevalence of intraseasonal Kelvin waves and the zonal structure of intraseasonal SST from 2002 to early 2004 suggested that they might be important in setting the eastern Pacific SST on inter-annual time scales. C1 [Jiang, Chuanli; Thompson, Luanne] Univ Washington, Sch Oceanog, Seattle, WA 98195 USA. [Kelly, Kathryn A.] Univ Washington, Appl Phys Lab, Seattle, WA 98195 USA. [Cronin, Meghan F.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. RP Jiang, CL (reprint author), Univ Calif San Diego, Scripps Inst Oceanog, 9500 Gilman Dr,Mail Code 0230, La Jolla, CA 92093 USA. EM chjiang@ucsd.edu FU NOAA Office of Global Programs Pan American Climate Studies [GC99-370]; NASA Ocean Vector Winds Science Team [1285662] FX The authors thank Suzanne Dickinson for preparing the QuikSCAT gridded winds and NCEP-2 fields. We would also like to thank Jordan T. Dawe and David Darr for their help with the HIM model. NCEP-2 reanalysis data were obtained online from ftp://ftp.cdc.noaa.gov/Datasets/-ncep.reanalysis2.dailyavgs/.ERA-40 data were obtained online from http://data.ecmwf.int/data/d/era40_daily/. The TAO buoy data are from the NOAA Pacific Marine Environmental Laboratory (PMEL; available online at http://www.pmel.noaa.gov/tao/data_deliv/). We also acknowledge the TAO Project Office, Dr. Michael J. McPhaden, Director. This work was supported by Grant GC99-370 from the NOAA Office of Global Programs Pan American Climate Studies, and the NASA Ocean Vector Winds Science Team through Contract 1285662 with the Jet Propulsion Laboratory. NR 37 TC 5 Z9 5 U1 1 U2 7 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0894-8755 J9 J CLIMATE JI J. Clim. PD JUN PY 2009 VL 22 IS 12 BP 3470 EP 3487 DI 10.1175/2009JCLI2767.1 PG 18 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 472JI UT WOS:000268126300017 ER PT J AU Bryant, GW AF Bryant, Garnett W. TI Surface States on Semiconductor Nanocrystals: The Effects of Unpassivated Dangling Bonds SO JOURNAL OF COMPUTATIONAL AND THEORETICAL NANOSCIENCE LA English DT Article DE Nanocrystals; Quantum Dots; Surface States; Semiconductor; Electronic Structure ID LIGHT-EMITTING-DIODES; CDSE QUANTUM DOTS; ELECTRONIC-STRUCTURE; TIGHT-BINDING; CORE/SHELL NANOCRYSTALS; OPTICAL-PROPERTIES; LEVEL STRUCTURE; ENERGY-TRANSFER; EXCITON-STATES; IN-VIVO AB Surface effects significantly influence the functionality of semiconductor nanocrystals (NC). A theoretical understanding of these effects requires an atomic-scale description of the NC surface. We present an atomistic tight-binding theory of the electronic and optical properties of partially passivated cadmium sulfide NCs. Fully passivated quantum dots, with all dangling bonds saturated, have no surface states in the fundamental band gap. When all surface anion dangling bonds are unpassivated, two anion-derived, surface state bands lie above the valence band edge. By investigating NCs with a single unpassivated surface anion, we are able to assign the surface state bands to states derived from surface anions with one or two unpassivated dangling bonds. The surface state energies for a NC with a single unpassivated surface S atom depend of the number of unpassivated dangling bonds, but are not otherwise strongly sensitive to the local atomic environment. Unpassivated surface dangling bonds can also shift the internally confined states, split their level degeneracies, break their symmetry and change their oscillator strengths. For NCs with multiple unpassivated surface S atoms, coupling between unpassivated dangling bonds can occur across the entire NC, leading to substantial mixing of dangling bond states and significant broadening of the density of states. Ordered rings of unpassivated dangling bonds show level coupling analogous to coupling in molecular rings. The surface states of clusters of unpassivated anions depend on the cluster size. The optical response due to internally confined states becomes indistinguishable in the broadened optical response as the cluster size increases. Incomplete surface passivation is modeled by considering NCs with randomly passivated surface atoms. For a low density of unpassivated surface anions, the density of surface states broadens substantially as the density of unpassivated surface anions increases. The fundamental NC optical response due to confined states disappears if 30 percent of the S surface atoms are unpassivated. However, at a high density of unpassivated surface anions, the density of surface states narrows as the density of unpassivated surface anions increases and NC evolves to a more ordered structure with all surface atoms unpassivated. Comparable effects are found for NCs with unpassivated surface cations. The coupling between anion-derived and cation-derived surface states is weak because these states occur at very different energies. C1 [Bryant, Garnett W.] Natl Inst Stand & Technol, Atom Phys Div, Gaithersburg, MD 20899 USA. [Bryant, Garnett W.] Natl Inst Stand & Technol, Joint Quantum Inst, Gaithersburg, MD 20899 USA. RP Bryant, GW (reprint author), Natl Inst Stand & Technol, Atom Phys Div, Gaithersburg, MD 20899 USA. FU National Institute of Standards and Technology FX This work was supported in part front the Advanced Technology Program at the National Institute of Standards and Technology. The assistance of Howard Hung with visualization programs is gratefully acknowledged. NR 63 TC 7 Z9 7 U1 0 U2 14 PU AMER SCIENTIFIC PUBLISHERS PI VALENCIA PA 26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USA SN 1546-1955 J9 J COMPUT THEOR NANOS JI J. Comput. Theor. Nanosci. PD JUN PY 2009 VL 6 IS 6 SI SI BP 1262 EP 1271 DI 10.1166/jctn.2009.1174 PG 10 WC Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter SC Chemistry; Science & Technology - Other Topics; Materials Science; Physics GA 441BU UT WOS:000265745100005 ER PT J AU Banerjee, AG Balijepalli, A Gupta, SK LeBrun, TW AF Banerjee, Ashis Gopal Balijepalli, Arvind Gupta, Satyandra K. LeBrun, Thomas W. TI Generating Simplified Trapping Probability Models From Simulation of Optical Tweezers System SO JOURNAL OF COMPUTING AND INFORMATION SCIENCE IN ENGINEERING LA English DT Article ID FORCES; MANIPULATION; MICROSPHERES AB This paper presents a radial basis function based approach to generate simplified models to estimate the trapping probability in optical trapping experiments using offline simulations. The difference form of Langevin's equation is used to perform physically accurate simulations of a particle under the influence of a trapping potential and is used to estimate trapping probabilities at discrete points in the parameter space. Gaussian radial basis functions combined with kd-tree based partitioning of the parameter space are then used to generate simplified models of trapping probability. We show that the proposed approach is computationally efficient in estimating the trapping probability and that the estimated probability using the simplified models is sufficiently close to the probability estimates from offline simulation data. [DOI: 10.1115/1.3130784] C1 [Banerjee, Ashis Gopal; Balijepalli, Arvind; Gupta, Satyandra K.] Univ Maryland, Dept Mech Engn, College Pk, MD 20742 USA. [Banerjee, Ashis Gopal; Balijepalli, Arvind; Gupta, Satyandra K.] Univ Maryland, Syst Res Inst, College Pk, MD 20742 USA. [Balijepalli, Arvind; LeBrun, Thomas W.] Natl Inst Stand & Technol, Div Precis Engn, Mfg Engn Lab, Gaithersburg, MD 20899 USA. RP Gupta, SK (reprint author), Univ Maryland, Dept Mech Engn, College Pk, MD 20742 USA. EM skgupta@umd.edu FU Center for Nano Manufacturing and Metrology; University of Maryland; National Institute of Standards and Technology FX This work was supported in part by the Center for Nano Manufacturing and Metrology, a joint venture between the University of Maryland and the National Institute of Standards and Technology. NR 16 TC 12 Z9 12 U1 0 U2 3 PU ASME-AMER SOC MECHANICAL ENG PI NEW YORK PA THREE PARK AVE, NEW YORK, NY 10016-5990 USA SN 1530-9827 J9 J COMPUT INF SCI ENG JI J. Comput. Inf. Sci. Eng. PD JUN PY 2009 VL 9 IS 2 AR 021003 DI 10.1115/1.3130784 PG 9 WC Computer Science, Interdisciplinary Applications; Engineering, Manufacturing SC Computer Science; Engineering GA 454FF UT WOS:000266667100003 ER PT J AU Hertz, JL Rothschild, A Tuller, HL AF Hertz, Joshua L. Rothschild, Avner Tuller, Harry L. TI Highly enhanced electrochemical performance of silicon-free platinum-yttria stabilized zirconia interfaces SO JOURNAL OF ELECTROCERAMICS LA English DT Article DE Yttria-stabilized zirconia (YSZ); Platinum; Polarization resistance; Impedance spectroscopy; Solid oxide fuel cells (SOFC) ID OXIDE FUEL-CELL; TRIPLE-PHASE BOUNDARY; REACTION-MECHANISM; MODEL ELECTRODES; SINGLE-CRYSTAL; SURFACE; SEGREGATION; CATHODES; SYSTEM; OXYGEN AB In the drive to achieve economically viable solid oxide fuel cells, efforts have been directed towards substantially decreasing their operating temperature. Unfortunately, these efforts have been hindered by extremely sluggish electrode kinetics at reduced temperatures. In this report, we show that silicon impurities on the surface of the electrolyte play a critical role in influencing electrode kinetics. More specifically, improvements by as much as three orders of magnitude are reported for the performance of platinum electrodes on yttria-stabilized zirconia electrolytes prepared as high purity thin films with a largely Si-free surface. These improvements in performance are estimated to enable operation of a solid oxide fuel cell down to approximately 400 A degrees C. C1 [Hertz, Joshua L.; Rothschild, Avner; Tuller, Harry L.] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA. RP Hertz, JL (reprint author), Natl Inst Stand & Technol, 100 Bur Dr,MS8362, Gaithersburg, MD 20899 USA. EM joshua.hertz@nist.gov RI Rothschild, Avner/B-7896-2009; Hertz, Joshua/B-7239-2012 OI Rothschild, Avner/0000-0002-2512-0370; Hertz, Joshua/0000-0003-0650-5141 FU Army Research Office [DAAD19-01-1-0566]; National Science Foundation [DMR 02-13282] FX This work was supported by the DoD Multidisciplinary University Research Initiative Program administered by the Army Research Office under Grant No. DAAD19-01-1-0566. This work made use of the Shared Experimental Facilities supported by the MRSEC Program of the National Science Foundation under award number DMR 02-13282. The authors thank Joseph Bullard and Elisabeth Shaw for assistance in obtaining the XPS data. NR 41 TC 39 Z9 39 U1 1 U2 20 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 1385-3449 J9 J ELECTROCERAM JI J. Electroceram. PD JUN PY 2009 VL 22 IS 4 BP 428 EP 435 DI 10.1007/s10832-008-9475-5 PG 8 WC Materials Science, Ceramics SC Materials Science GA 448CU UT WOS:000266241200011 ER PT J AU Pothoven, SA Vanderploeg, HA Ludsin, SA Hook, TO Brandt, SB AF Pothoven, Steven A. Vanderploeg, Henry A. Ludsin, Stuart A. Hoeoek, Tomas O. Brandt, Stephen B. TI Feeding ecology of emerald shiners and rainbow smelt in central Lake Erie SO JOURNAL OF GREAT LAKES RESEARCH LA English DT Article DE Emerald shiner; Rainbow smelt; Ration; Hypoxia; Feeding ecology; Lake Erie ID FISH DAILY RATION; BYTHOTREPHES-CEDERSTROEMI; PLANKTIVOROUS FISHES; HYPOLIMNETIC OXYGENATION; COREGONUS-ARTEDI; OSMERUS-MORDAX; YELLOW PERCH; AMISK LAKE; FOOD; ZOOPLANKTON AB To better understand the feeding ecology of two important Laurentian Great Lakes prey species, rainbow smelt Osmerus mordax and emerald shiners Notropis atherinoides, we quantified the diet composition, selectivity, daily ration, and diet overlap of both species in offshore central Lake Erie during May through October 2005, which spanned a period of severe hypolimnetic hypoxia (<2 mg O-2/L). Rainbow smelt fed upon a variety of prey taxa, including zooplankton, chironomid pupae and larvae, and fish, whereas emerald shiners primarily consumed cladocerans, if available, In turn, diet overlap between rainbow smelt and emerald shiners was low except during September when hypolimnetic hypoxia reduced rainbow smelt access to benthic prey. Rainbow smelt most frequently selected chironomid pupae, while emerald shiners generally selected pupae or large predatory cladocerans (Leptodora or Bythotrephes). Daily ration and individual consumption by rainbow smelt were 54-68% less during hypoxia than at the same site during stratified pre-hypoxic or mixed post-hypoxic conditions. Although emerald shiner daily ration and individual consumption decreased between pre-hypoxic and hypoxic periods, it continued to decrease during the post-hypoxic period, suggesting that reduced consumption may not have been linked to hypoxic conditions. Ultimately, our findings suggest that emerald shiners are as important regulator of zooplankton abundance in the Great Lakes as rainbow smelt, given their potentially high mass-specific consumption rates, selectivity and diet patterns, and current high abundance. Published by Elsevier Inc. C1 [Pothoven, Steven A.] NOAA, Great Lakes Environm Res Lab, Muskegon, MI 49441 USA. [Vanderploeg, Henry A.] NOAA, Great Lakes Environm Res Lab, Ann Arbor, MI 48108 USA. [Ludsin, Stuart A.] Ohio State Univ, Dept Ecol Evolut & Organismal Biol, Aquat Ecol Lab, Columbus, OH 43212 USA. [Hoeoek, Tomas O.] Purdue Univ, Dept Forestry & Nat Resources, W Lafayette, IN 47907 USA. [Brandt, Stephen B.] Oregon State Univ, Corvallis, OR 97331 USA. RP Pothoven, SA (reprint author), NOAA, Great Lakes Environm Res Lab, 1431 Beach St, Muskegon, MI 49441 USA. EM steve.pothoven@noaa.gov; henry.vanderploeg@noaa.gov; ludsin.1@osu.edu; thook@purdue.edu; Stephen.Brandt@oregonstate.edu RI Ludsin, Stuart/F-2925-2010; OI Ludsin, Stuart/0000-0002-3866-2216; Pothoven, Steven/0000-0002-7992-5422 FU NOAA-GLERL; U.S. E.P.A. Great Lakes National Program Office [1515] FX We thank all those who provided lab, field, or data management support, including K. Bailey, A. Bajcz, A. Belyaeva, S. Bickel, J. Cavaletto, A. Clites, S. Constant, M. Costantim, C. Darnell, D. Fanslow, H. Gunder, A. Harrison, N. Hawley, D. Hondorp, G. Lang, M. Lansing, J. Liebig, S. Lozano, G. Maria, K. Molton, T. Naiepa, S. Peacor, C. Rae, J. Roberts, S. Sisler, and the crews of both the R/V Laurentian and R/V Lake Guardian. This work was conducted as part of the International Field Years on Lake Erie (IFYLE) program, supported primarily by NOAA-GLERL and secondarily by the U.S. E.P.A. Great Lakes National Program Office. This is GLERL contribution # 1515. NR 51 TC 26 Z9 27 U1 1 U2 34 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0380-1330 J9 J GREAT LAKES RES JI J. Gt. Lakes Res. PD JUN PY 2009 VL 35 IS 2 BP 190 EP 198 DI 10.1016/j.jglr.2008.11.011 PG 9 WC Environmental Sciences; Limnology; Marine & Freshwater Biology SC Environmental Sciences & Ecology; Marine & Freshwater Biology GA 460DH UT WOS:000267167400004 ER PT J AU Chapra, SC Dove, A Rockwell, DC AF Chapra, Steven C. Dove, Alice Rockwell, David C. TI Great Lakes chloride trends: Long-term mass balance and loading analysis SO JOURNAL OF GREAT LAKES RESEARCH LA English DT Article DE Chloride; Lakes; Water quality; Model; Loadings; Salt ID TOTAL PHOSPHORUS MODEL; ONONDAGA-LAKE; NEW-YORK; WATER; DEPOSITION; POLLUTION; MACKINAC; STRAITS; BUDGET; FLOW AB Surveillance data collected over the past 150 years are compiled and analyzed to identify chloride trends in the Laurentian Great Lakes. These data indicate that chloride levels started rising in the mid-19th century and began accelerating in the early twentieth century. Lake Superior's and Lake Michigan's concentrations have continued to increase steadily and currently stand at their maximum recorded levels. In contrast, lakes Huron, Erie and Ontario reached peak levels between 1965 and 1975, but then began to decline. However, recent data indicate that the chloride concentrations in these lakes are now increasing again. Because loading data are not readily available, a mass-balance model is employed to estimate the chloride inputs required to account for the concentration trends. This inverse analysis yields computed load reductions that are consistent with reported industrial load reductions during the last three decades of the 20th century. Hence, it appears that the improvements were for the most part attributable to industrial controls. The model is also used to predict that if loads are held fixed at 2006 levels, concentrations in all lakes will continue to increase with the Most dramatic rise occurring in Lake Michigan which will ultimately approach the level of Lake Erie. (C) 2009 Published by Elsevier Inc. C1 [Chapra, Steven C.] Tufts Univ, Dept Civil & Environm Engn, Medford, MA 02155 USA. [Dove, Alice] Environm Canada, Water Qual Monitoring & Surveillance Ontario, Burlington, ON L7R 4A6, Canada. [Rockwell, David C.] NOAA, Ctr Excellence Great Lakes & Human Hlth, Ann Arbor, MI 48108 USA. RP Chapra, SC (reprint author), Tufts Univ, Dept Civil & Environm Engn, Medford, MA 02155 USA. EM steven.chapra@tufts.edu; alice.dove@ec.gc.ca; dcrockwe@umich.edu RI Chapra, Steven/A-5752-2008 OI Chapra, Steven/0000-0003-0238-6376 FU University of Washington; New Zealand's National Institute of Water and Atmospheric Research FX Thanks to Tom Croley and Tim Hunter of GLERL/NOAA for assistance related to Great Lakes hydrology. The paper benefited from suggestions made by anonymous reviewers. Part of this work was supported by the University of Washington (Visiting Endowed Professorship) and New Zealand's National Institute of Water and Atmospheric Research (Visiting Scientist Award) for SCC. NR 70 TC 32 Z9 32 U1 3 U2 34 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0380-1330 J9 J GREAT LAKES RES JI J. Gt. Lakes Res. PD JUN PY 2009 VL 35 IS 2 BP 272 EP 284 DI 10.1016/j.jglr.2008.11.013 PG 13 WC Environmental Sciences; Limnology; Marine & Freshwater Biology SC Environmental Sciences & Ecology; Marine & Freshwater Biology GA 460DH UT WOS:000267167400013 ER PT J AU Behrangi, A Hsu, KL Imam, B Sorooshian, S Kuligowski, RJ AF Behrangi, Ali Hsu, Kuo-Lin Imam, Bisher Sorooshian, Soroosh Kuligowski, Robert J. TI Evaluating the Utility of Multispectral Information in Delineating the Areal Extent of Precipitation SO JOURNAL OF HYDROMETEOROLOGY LA English DT Article ID SATELLITE RAINFALL ESTIMATION; SOLAR-RADIATION MEASUREMENTS; ARTIFICIAL NEURAL-NETWORKS; EFFECTIVE PARTICLE RADIUS; MICROWAVE SOUNDING UNIT; PASSIVE MICROWAVE; GLOBAL PRECIPITATION; INFRARED DATA; OPTICAL-THICKNESS; VISIBLE DATA AB Data from geosynchronous Earth-orbiting (GEO) satellites equipped with visible (VIS) and infrared (IR) scanners are commonly used in rain retrieval algorithms. These algorithms benefit from the high spatial and temporal resolution of GEO observations, either in stand-alone mode or in combination with higher-quality but less frequent microwave observations from low Earth-orbiting (LEO) satellites. In this paper, a neural network-based framework is presented to evaluate the utility of multispectral information in improving rain/no-rain (R/NR) detection. The algorithm uses the powerful classification features of the self-organizing feature map (SOFM), along with probability matching techniques to map single-or multispectral input space into R/NR maps. The framework was tested and validated using the 31 possible combinations of the five Geostationary Operational Environmental Satellite 12 (GOES-12) channels. An algorithm training and validation study was conducted over the conterminous United States during June-August 2006. The results indicate that during daytime, the visible channel (0.65 mu m) can yield significant improvements in R/NR detection capabilities, especially when combined with any of the other four GOES-12 channels. Similarly, for nighttime detection the combination of two IR channels-particularly channels 3 (6.5 mu m) and 4 (10.7 mu m)-resulted in significant performance gain over any single IR channel. In both cases, however, using more than two channels resulted only in marginal improvements over two-channel combinations. Detailed examination of event-based images indicate that the proposed algorithm is capable of extracting information useful to screen no-rain pixels associated with cold, thin clouds and identifying rain areas under warm but rainy clouds. Both cases have been problematic areas for IR-only algorithms. C1 [Behrangi, Ali; Hsu, Kuo-Lin; Imam, Bisher; Sorooshian, Soroosh] Univ Calif Irvine, Dept Civil & Environm Engn, Henry Samueli Sch Engn, CHRS, Irvine, CA 92697 USA. [Kuligowski, Robert J.] NOAA, NESDIS, Ctr Satellite Res & Applicat STAR, Camp Springs, MD USA. RP Behrangi, A (reprint author), Univ Calif Irvine, Dept Civil & Environm Engn, Henry Samueli Sch Engn, CHRS, E-4130 Engn Gateway, Irvine, CA 92697 USA. EM abehrang@uci.edu RI Kuligowski, Robert/C-6981-2009; sorooshian, soroosh/B-3753-2008 OI Kuligowski, Robert/0000-0002-6909-2252; sorooshian, soroosh/0000-0001-7774-5113 FU NASA [NNX08AU78H, NNX06AF934]; NASA-PMM [NNG04GC74G]; NOAA/NESDIS GOES-R Program Office; NSF [EAR-9876800] FX Partial financial support is made available from NASA Earth and Space Science Fellowship (NESSF award NNX08AU78H), NASA-PMM (Grant NNG04GC74G), NOAA/NESDIS GOES-R Program Office (GPO) via the GOES-R Algorithm Working Group (AWG), NSF STC for Sustainability of Semi-Arid Hydrology and Riparian Areas (SAHRA; Grant EAR-9876800), and NASA NEWS (Grant NNX06AF934) programs. The authors thank Mr. Dan Braithwaite for his technical assistance on processing the satellite/radar data for this experiment. The contents of this paper are solely the opinion of the authors and do not constitute a statement of policy, decision, or position on behalf of the GOES-R Program Office, NOAA, or the U. S. government. NR 60 TC 21 Z9 21 U1 1 U2 4 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 1525-755X J9 J HYDROMETEOROL JI J. Hydrometeorol. PD JUN PY 2009 VL 10 IS 3 BP 684 EP 700 DI 10.1175/2009JHM1077.1 PG 17 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 463HB UT WOS:000267420900006 ER PT J AU Hou, DC Mitchell, K Toth, Z Lohmann, D Wei, HL AF Hou, Dingchen Mitchell, Kenneth Toth, Zoltan Lohmann, Dag Wei, Helin TI The Effect of Large-Scale Atmospheric Uncertainty on Streamflow Predictability SO JOURNAL OF HYDROMETEOROLOGY LA English DT Article ID ENSEMBLE PREDICTION SYSTEM; MACROSCALE WATER FLUXES; MODEL; PRECIPITATION; ACCURACY; BASIN AB Hydrological processes are strongly coupled with atmospheric processes related, for example, to precipitation and temperature, and a coupled atmosphere-land surface system is required for a meaningful hydrological forecast. Since the atmosphere is a chaotic system with limited predictability, ensemble forecasts offer a practical tool to predict the future state of the coupled system in a probabilistic fashion, potentially leading to a more complete and informative hydrologic prediction. As ensemble forecasts with coupled meteorological-hydrological models are operationally running at major numerical weather prediction centers, it is currently possible to produce a gridded streamflow prognosis in the form of a probabilistic forecast based on ensembles. Evaluation and improvement of such products require a comprehensive assessment of both components of the coupled system. In this article, the atmospheric component of a coupled ensemble forecasting system is evaluated in terms of its ability to provide reasonable forcing to the hydrological component and the effect of the uncertainty represented in the atmospheric ensemble system on the predictability of streamflow as a hydrological variable. The Global Ensemble Forecast System (GEFS) of NCEP is evaluated following a "perfect hydrology'' approach, in which its hydrological component, including the Noah land surface model and attached river routing model, is considered free of errors and the initial conditions in the hydrological variables are assumed accurate. The evaluation is performed over the continental United States (CONUS) domain for various sizes of river basins. The results from the experiment suggest that the coupled system is capable of generating useful gridded streamflow forecast when the land surface model and the river routing model can successfully simulate the hydrological processes, and the ensemble strategy significantly improves the forecast. The expected forecast skill increases with increasing size of the river basin. With the current GEFS system, positive skill in short-range (one to three days) predictions can be expected for all significant river basins; for the major rivers with mean streamflow more than 500 m(3) s(-1), significant skill can be expected from extended-range (the second week) predictions. Possible causes for the loss of skills, including the existence of systematic error and insufficient ensemble spread, are discussed and possible approaches for the improvement of the atmospheric ensemble forecast system are also proposed. C1 [Hou, Dingchen; Wei, Helin] NOAA, NWS, NCEP, EMC,SAIC, Camp Springs, MD 20746 USA. [Lohmann, Dag] Risk Management Solut Ltd, London, England. RP Hou, DC (reprint author), NOAA, NWS, NCEP, EMC,SAIC, W-NP2 NOAA WWB 207,5200 Auth Rd, Camp Springs, MD 20746 USA. EM dingchen.hou@noaa.gov RI Toth, Zoltan/I-6624-2015 OI Toth, Zoltan/0000-0002-9635-9194 FU NCEP/EMC; NOAA FX The work on this research by NCEP/EMC was supported by the NOAA Climate Program Office, funding for the NOAA Core Project for CPPA/GAPP (PI K. E. Mitchell), and the NOAA THORPEX program. We appreciate the discussions with D.- J. Seo, P. Restrepo, J. C. Schaake, A. Wood, D. Lettenmaier, and Y. Xia, whose comments and suggestions helped us to understand and interpret the results. Suggestions for improving the manuscript by Y. Xia and three anonymous peer reviewers are acknowledged. The authors thank Yuejian Zhu for help with data archives and George Gayno for assistance with the runoff interpolation. NR 23 TC 3 Z9 5 U1 2 U2 4 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 1525-755X J9 J HYDROMETEOROL JI J. Hydrometeorol. PD JUN PY 2009 VL 10 IS 3 BP 717 EP 733 DI 10.1175/2008JHM1064.1 PG 17 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 463HB UT WOS:000267420900008 ER PT J AU Ryu, D Crow, WT Zhan, XW Jackson, TJ AF Ryu, Dongryeol Crow, Wade T. Zhan, Xiwu Jackson, Thomas J. TI Correcting Unintended Perturbation Biases in Hydrologic Data Assimilation SO JOURNAL OF HYDROMETEOROLOGY LA English DT Article ID LAND DATA ASSIMILATION; SOIL-MOISTURE; MODEL; WATER; EVAPORATION; SYSTEM; FIELD AB Hydrologic data assimilation has become an important tool for improving hydrologic model predictions by using observations from ground, aircraft, and satellite sensors. Among existing data assimilation methods, the ensemble Kalman filter (EnKF) provides a robust framework for optimally updating nonlinear model predictions using observations. In the EnKF, background prediction uncertainty is obtained using a Monte Carlo approach where state variables, parameters, and forcing data for the model are synthetically perturbed to explicitly simulate the error-prone representation of hydrologic processes in the model. However, it is shown here that, owing to the nonlinear nature of these processes, an ensemble of model forecasts perturbed by mean-zero Gaussian noise can produce biased background predictions. This ensemble perturbation bias in soil moisture states can lead to significant mass balance errors and degrade the performance of the EnKF analysis in deeper soil layers. Here, a simple method of bias correction is introduced in which such perturbation bias is corrected using an unperturbed model simulation run in parallel with the EnKF analysis. The proposed bias-correction scheme effectively removes biases in soil moisture and reduces soil water mass balance errors. The performance of the EnKF is improved in deeper layers when the filter is applied with the bias-correction scheme. The interplay of nonlinear hydrologic processes is discussed in the context of perturbation biases, and implications of the bias correction for real-data assimilation cases are presented. C1 [Ryu, Dongryeol] Univ Melbourne, Dept Civil & Environm Engn, Parkville, Vic 3010, Australia. [Crow, Wade T.; Jackson, Thomas J.] ARS, Hydrol & Remote Sensing Lab, USDA, Beltsville, MD USA. [Zhan, Xiwu] NOAA, NESDIS, Camp Springs, MD USA. RP Ryu, D (reprint author), Univ Melbourne, Dept Civil & Environm Engn, Parkville, Vic 3010, Australia. EM dryu@unimelb.edu.au RI Zhan, Xiwu/F-5487-2010; Ryu, Dongryeol/C-5903-2008 OI Ryu, Dongryeol/0000-0002-5335-6209 FU NASA [NNH04AC301] FX This work was partially supported by the NASA EOS Aqua Project Science and the NASA Terrestrial Hydrology programs through Grant NNH04AC301. NR 27 TC 29 Z9 30 U1 3 U2 8 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 1525-755X EI 1525-7541 J9 J HYDROMETEOROL JI J. Hydrometeorol. PD JUN PY 2009 VL 10 IS 3 BP 734 EP 750 DI 10.1175/2008JHM1038.1 PG 17 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 463HB UT WOS:000267420900009 ER PT J AU Pickart, RS Moore, GWK Macdonald, AM Renfrew, IA Walsh, JE Kessler, WS AF Pickart, Robert S. Moore, G. W. K. Macdonald, Alison M. Renfrew, Ian A. Walsh, John E. Kessler, William S. TI Seasonal Evolution of Aleutian Low Pressure Systems: Implications for the North Pacific Subpolar Circulation SO JOURNAL OF PHYSICAL OCEANOGRAPHY LA English DT Article ID DEPTH-INTEGRATED FLOW; BERING-SEA BASIN; CYCLONE ACTIVITY; BAROCLINIC TRANSPORT; IRMINGER SEAS; WATER-VAPOR; CLIMATOLOGY; OCEAN; VARIABILITY; TEMPERATURE AB The seasonal change in the development of Aleutian low pressure systems from early fall to early winter is analyzed using a combination of meteorological reanalysis fields, satellite sea surface temperature (SST) data, and satellite wind data. The time period of the study is September-December 2002, although results are shown to be representative of the long-term climatology. Characteristics of the storms were documented as they progressed across the North Pacific, including their path, central pressure, deepening rate, and speed of translation. Clear patterns emerged. Storms tended to deepen in two distinct geographical locations-the Gulf of Alaska in early fall and the western North Pacific in late fall. In the Gulf of Alaska, a quasi-permanent "notch'' in the SST distribution is argued to be of significance. The signature of the notch is imprinted in the atmosphere, resulting in a region of enhanced cyclonic potential vorticity in the lower troposphere that is conducive for storm development. Later in the season, as winter approaches and the Sea of Okhotsk becomes partially ice covered and cold, the air emanating from the Asian continent leads to enhanced baroclinicity in the region south of Kamchatka. This corresponds to enhanced storm cyclogenesis in that region. Consequently, there is a seasonal westward migration of the dominant lobe of the Aleutian low. The impact of the wind stress curl pattern resulting from these two regions of storm development on the oceanic circulation is investigated using historical hydrography. It is argued that the seasonal bimodal input of cyclonic vorticity from the wind may be partly responsible for the two distinct North Pacific subarctic gyres. C1 [Pickart, Robert S.; Macdonald, Alison M.] Woods Hole Oceanog Inst, Woods Hole, MA 02543 USA. [Moore, G. W. K.] Univ Toronto, Toronto, ON, Canada. [Renfrew, Ian A.] Univ E Anglia, Norwich NR4 7TJ, Norfolk, England. [Walsh, John E.] Int Arctic Res Ctr, Fairbanks, AK USA. [Kessler, William S.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. RP Pickart, RS (reprint author), Woods Hole Oceanog Inst, Clark 3 MS 21, Woods Hole, MA 02543 USA. EM rpickart@whoi.edu RI Renfrew, Ian/E-4057-2010; Moore, Kent/D-8518-2011 OI Renfrew, Ian/0000-0001-9379-8215; Moore, Kent/0000-0002-3986-5605 FU Office of Naval Research [N00014-02-1-0317]; Natural Sciences and Engineering Research Council of Canada; National Science Foundation [OCE-0623261]; Natural Environmental Research Council [NE/C003365/1] FX This work was carried out while RP was on sabbatical at the University of Alaska, Fairbanks (UAF) and the International Arctic Research Center (IARC). RP acknowledges the generous support provided by D. Wiesenburg (UAF) and S. Akasofu (IARC). RP is indebted to Tom Weingartner for making the visit possible and for many stimulating discussions. K. Vage helped with the QuikSCAT and NCEP data analysis, S. Danielson provided various technical assistance, T. McKee aided in figure preparation, and R. Goldsmith provided programming support. The following funding sources are acknowledged: Office of Naval Research Grant N00014-02-1-0317 (RP); Natural Sciences and Engineering Research Council of Canada (GWKM); National Science Foundation Grant OCE-0623261 (AM); Natural Environmental Research Council Grant NE/C003365/1 (IR). NR 57 TC 31 Z9 31 U1 1 U2 17 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0022-3670 EI 1520-0485 J9 J PHYS OCEANOGR JI J. Phys. Oceanogr. PD JUN PY 2009 VL 39 IS 6 BP 1317 EP 1339 DI 10.1175/2008JPO3891.1 PG 23 WC Oceanography SC Oceanography GA 470EV UT WOS:000267958800003 ER PT J AU Rothman, LS Gordon, IE Barbe, A Benner, DC Bernath, PE Birk, M Boudon, V Brown, LR Campargue, A Champion, JP Chance, K Coudert, LH Dana, V Devi, VM Fally, S Flaud, JM Gamache, RR Goldman, A Jacquemart, D Kleiner, I Lacome, N Lafferty, WJ Mandin, JY Massie, ST Mikhailenko, SN Miller, CE Moazzen-Ahmadi, N Naumenko, OV Nikitin, AV Orphal, J Perevalov, VI Perrin, A Predoi-Cross, A Rinsland, CP Rotger, M Simeckova, M Smith, MAH Sung, K Tashkun, SA Tennyson, J Toth, RA Vandaele, AC Vander Auwera, J AF Rothman, L. S. Gordon, I. E. Barbe, A. Benner, D. Chris Bernath, P. E. Birk, M. Boudon, V. Brown, L. R. Campargue, A. Champion, J. -P. Chance, K. Coudert, L. H. Dana, V. Devi, V. M. Fally, S. Flaud, J. -M. Gamache, R. R. Goldman, A. Jacquemart, D. Kleiner, I. Lacome, N. Lafferty, W. J. Mandin, J. -Y. Massie, S. T. Mikhailenko, S. N. Miller, C. E. Moazzen-Ahmadi, N. Naumenko, O. V. Nikitin, A. V. Orphal, J. Perevalov, V. I. Perrin, A. Predoi-Cross, A. Rinsland, C. P. Rotger, M. Simeckova, M. Smith, M. A. H. Sung, K. Tashkun, S. A. Tennyson, J. Toth, R. A. Vandaele, A. C. Vander Auwera, J. TI The HITRAN 2008 molecular spectroscopic database SO JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER LA English DT Review DE HITRAN; Spectroscopic database; Molecular spectroscopy; Molecular absorption; Spectroscopic line parameters; Absorption cross-sections; Aerosols ID ABSORPTION CROSS-SECTIONS; ABSOLUTE LINE-INTENSITIES; FOURIER-TRANSFORM SPECTROSCOPY; SELF-BROADENING COEFFICIENTS; DIODE-LASER MEASUREMENTS; HIGH-RESOLUTION ANALYSIS; WATER-VAPOR TRANSITIONS; OXYGEN A-BAND; MU-M REGION; CONSTRAINED MULTISPECTRUM ANALYSIS AB This paper describes the status of the 2008 edition of the HITRAN molecular spectroscopic database. The new edition is the first official public release since the 2004 edition, although a number of crucial updates had been made available online since 2004. The HITRAN compilation consists of several components that serve as input for radiative-transfer calculation codes: individual line parameters for the microwave through visible spectra of molecules in the gas phase; absorption cross-sections for molecules having dense spectral features, i.e. spectra in which the individual lines are not resolved; individual line parameters and absorption cross-sections for bands in the ultraviolet; refractive indices of aerosols, tables and files of general properties associated with the database; and database management software. The line-by-line portion of the database contains spectroscopic parameters for 42 molecules including many of their isotopologues. (c) 2009 Elsevier Ltd. All rights reserved. C1 [Rothman, L. S.; Gordon, I. E.; Chance, K.; Simeckova, M.] Harvard Smithsonian Ctr Astrophys, Atom & Mol Phys Div, Cambridge, MA 02138 USA. [Barbe, A.; Rotger, M.] Univ Reims, Grp Spectrometrie Mol & Atmospher, F-51062 Reims, France. [Benner, D. Chris; Devi, V. M.] Coll William & Mary, Dept Phys, Williamsburg, VA 23187 USA. [Bernath, P. E.] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England. [Birk, M.] DLR Remote Sensing Technol Inst, Wessling, Germany. [Boudon, V.; Champion, J. -P.; Rotger, M.] Univ Bourgogne, CNRS, Inst Carnot Bourgogne, F-21078 Dijon, France. [Brown, L. R.; Miller, C. E.; Sung, K.; Toth, R. A.] CALTECH, Jet Prop Lab, Pasadena, CA 91109 USA. [Campargue, A.] Univ Grenoble 1, CNRS, Spectrometrie Phys Lab, F-38402 St Martin Dheres, France. [Dana, V.; Mandin, J. -Y.] Univ Paris 06, UPMC, UMR 7092, Lab Phys Mol & Applicat, F-75252 Paris, France. [Fally, S.] Univ Libre Bruxelles, Serv Chim Quant & Photophys, B-1050 Brussels, Belgium. [Gamache, R. R.] Univ Mass Lowell, Dept Environm Earth & Atmospher Sci, Lowell, MA 01854 USA. [Goldman, A.] Univ Denver, Dept Phys, Denver, CO 80208 USA. [Jacquemart, D.] Univ Paris 06, UPMC, UMR 7075, Lab Dynam Interact & React, F-75252 Paris, France. [Lafferty, W. J.] NIST, Gaithersburg, MD 20899 USA. [Massie, S. T.] Natl Ctr Atmospher Res, Boulder, CO 80307 USA. [Mikhailenko, S. N.; Naumenko, O. V.; Nikitin, A. V.; Perevalov, V. I.; Tashkun, S. A.] Inst Atmospher Opt, Tomsk 634055, Russia. [Moazzen-Ahmadi, N.] Univ Calgary, Dept Phys & Astron, Calgary, AB T2N 1N4, Canada. [Predoi-Cross, A.] Univ Lethbridge, Dept Phys & Astron, Lethbridge, AB T1K 3M4, Canada. [Rinsland, C. P.; Smith, M. A. H.] NASA, Langley Res Ctr, Sci Directorate, Hampton, VA 23681 USA. [Tennyson, J.] UCL, Dept Phys & Astron, London WC1E 6BT, England. [Vandaele, A. C.] Inst Aeron Spatiale Belgique, B-1180 Brussels, Belgium. RP Rothman, LS (reprint author), Harvard Smithsonian Ctr Astrophys, Atom & Mol Phys Div, 60 Garden St, Cambridge, MA 02138 USA. EM lrothman@cfa.harvard.edu RI BOUDON, Vincent/A-4504-2010; Champion, Jean-Paul/C-3963-2009; Lacome, Nelly/A-7043-2008; Bernath, Peter/B-6567-2012; Tennyson, Jonathan/I-2222-2012; Orphal, Johannes/A-8667-2012; Nikitin, Andrei/K-2624-2013; Tashkun, Sergey/E-8682-2014; Sung, Keeyoon/I-6533-2015 OI Rothman, Laurence/0000-0002-3837-4847; Chance, Kelly/0000-0002-7339-7577; Gordon, Iouli/0000-0003-4763-2841; Bernath, Peter/0000-0002-1255-396X; Tennyson, Jonathan/0000-0002-4994-5238; Orphal, Johannes/0000-0002-1943-4496; Nikitin, Andrei/0000-0002-4280-4096; NR 368 TC 2138 Z9 2222 U1 31 U2 260 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0022-4073 EI 1879-1352 J9 J QUANT SPECTROSC RA JI J. Quant. Spectrosc. Radiat. Transf. PD JUN-JUL PY 2009 VL 110 IS 9-10 SI SI BP 533 EP 572 DI 10.1016/j.jqsrt.2009.02.013 PG 40 WC Optics; Spectroscopy SC Optics; Spectroscopy GA 447HD UT WOS:000266181300002 ER PT J AU Tennyson, J Bernath, PF Brown, LR Campargue, A Carleere, MR Csaszar, AG Gamache, RR Hodges, JT Jenouvrier, A Naumenko, OV Polyansky, OL Rothman, LS Toth, RA Vandaele, AC Zobov, NF Daumont, L Fazliev, AZ Furtenbacher, T Gordon, IE Mikhailenko, SN Shirin, SV AF Tennyson, Jonathan Bernath, Peter F. Brown, Linda R. Campargue, Alain Carleere, Michel R. Csaszar, Attila G. Gamache, Robert R. Hodges, Joseph T. Jenouvrier, Alain Naumenko, Olga V. Polyansky, Oleg L. Rothman, Laurence S. Toth, Robert A. Vandaele, Ann Carine Zobov, Nikolai F. Daumont, Ludovic Fazliev, Alexander Z. Furtenbacher, Tibor Gordon, Iouli E. Mikhailenko, Semen N. Shirin, Sergei V. TI IUPAC critical evaluation of the rotational-vibrational spectra of water vapor. Part I-Energy levels and transition wavenumbers for (H2O)-O-17 and (H2O)-O-18 SO JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER LA English DT Review DE Water vapor; Transition wavenumbers; Atmospheric physics; Energy levels; MARVEL; Information system; Database; Infrared spectra; Microwave spectra ID SUBMILLIMETER MICROWAVE-SPECTRUM; LORENTZ-BROADENING COEFFICIENTS; CENTRIFUGAL-DISTORTION ANALYSIS; FOURIER-TRANSFORM SPECTROSCOPY; RESOLUTION INFRARED SPECTRA; LINE-SHIFT COEFFICIENTS; RING-DOWN SPECTROSCOPY; 1.39 MU-M; INTERACTING STATES; ABSORPTION-SPECTRA AB This is the first part of a series of articles reporting critically evaluated rotational-vibrational line positions, transition intensities, pressure dependence and energy levels, with associated critically reviewed assignments and uncertainties, for all the main isotopologues of water. The present article contains energy levels and data for line positions of the singly substituted isotopologues (H2O)-O-17 and (H2O)-O-18. The procedure and code MARVEL, standing for measured active rotational-vibrational energy levels, is used extensively in all stages of determining the validated levels and lines and their self-consistent uncertainties. The spectral regions covered for both isotopologues (H2O)-O-17 and (H2O)-O-18 are 0-17 125 cm(-1). The energy levels are checked against ones determined from accurate variational calculations. The number of critically evaluated and recommended levels and lines are, respectively, 2687 and 8614 for (H2O)-O-17, and 4839 and 29364 for (H2O)-O-18. The extensive lists of MARVEL lines and levels obtained are deposited in the Supplementary Material, as well as in a distributed information system applied to water, W@DIS, where they can easily be retrieved. A distinguishing feature of the present evaluation of water spectroscopic data is the systematic use of all available experimental data and validation by first-principles theoretical calculations. (c) 2009 Elsevier Ltd. All rights reserved. C1 [Tennyson, Jonathan; Polyansky, Oleg L.] UCL, Dept Phys & Astron, London WC1E 6BT, England. [Bernath, Peter F.] Univ York, York YO10 5DD, N Yorkshire, England. [Brown, Linda R.; Toth, Robert A.] CALTECH, Jet Prop Lab, Pasadena, CA USA. [Campargue, Alain] Univ Grenoble 1, Grenoble, France. [Carleere, Michel R.] Univ Libre Brussels, Brussels, Belgium. [Csaszar, Attila G.; Furtenbacher, Tibor] Eotvos Lorand Univ, Budapest, Hungary. [Gamache, Robert R.] Univ Massachusetts, Lowell, MA USA. [Hodges, Joseph T.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. [Jenouvrier, Alain; Daumont, Ludovic] Univ Reims, Reims, France. [Naumenko, Olga V.; Fazliev, Alexander Z.; Mikhailenko, Semen N.] Russian Acad Sci, Inst Atmospher Opt, Tomsk, Russia. [Rothman, Laurence S.; Gordon, Iouli E.] Harvard Smithsonian Ctr Astrophys, Cambridge, MA 02138 USA. [Vandaele, Ann Carine] Inst Aeron Spatiale Belgique, B-1180 Brussels, Belgium. [Zobov, Nikolai F.; Shirin, Sergei V.] Russian Acad Sci, Inst Appl Phys, Nizhnii Novgorod 603600, Russia. RP Tennyson, J (reprint author), UCL, Dept Phys & Astron, Mortimer St, London WC1E 6BT, England. EM j.tennyson@ucl.ac.uk RI Csaszar, Attila/A-5241-2009; Bernath, Peter/B-6567-2012; Hodges, Joseph/B-4578-2009; Tennyson, Jonathan/I-2222-2012; OI Bernath, Peter/0000-0002-1255-396X; Tennyson, Jonathan/0000-0002-4994-5238; Gordon, Iouli/0000-0003-4763-2841; Rothman, Laurence/0000-0002-3837-4847 FU Union of Pure and Applied Chemistry [2004-035-1-100]; UK Engineering and Physical Science Research Council; UK Natural Environment Research Council; Royal Society; British Council; INTAS foundation [WWLC-008535-MCA FP6 EC]; Scientific Research Fund of Hungary [OTKA T47185, K72885]; NKTH; European Union QUASAAR Marie Curie research training network; NATO; Russian Foundation for Basic Research; Belgian Federal Science Policy Office [EV/35/3A, SD/AT/01A, PRODEX 151490INLSFe(IC)]; Belgian National Fund for Scientific Research (FRFC contracts); Communaut de Belgique (Action de Recherche Concertees); NASA Earth Observing System (EOS) [NAG5-13534]; NASA laboratory astrophysics program; Programme National LEFE (CHAT) of CNRS (INSU); The National Aeronaudcs and Space Administratio FX We all thank the international Union of Pure and Applied Chemistry for funding under Project 2004-035-1-100 (A database of water transitions from experiment and theory). In addition, this work has received partial support from the UK Engineering and Physical Science Research Council, the UK Natural Environment Research Council, the Royal Society, the British Council, the INTAS foundation, Grant WWLC-008535-(reintegration) MCA FP6 EC, the Scientific Research Fund of Hungary (Grants OTKA T47185 and K72885), the NKTH, the European Union QUASAAR Marie Curie research training network, NATO, the Russian Foundation for Basic Research, the Belgian Federal Science Policy Office (Contracts EV/35/3A, SD/AT/01A, PRODEX 151490INLSFe(IC)), the Belgian National Fund for Scientific Research (FRFC contracts), the Communaut de Belgique (Action de Recherche Concertees), NASA Earth Observing System (EOS), under the Grant NAG5-13534, the NASA laboratory astrophysics program. Alain Campargue and Ludovic Daumont are grateful for the financial support provided by the Programme National LEFE (CHAT) of CNRS (INSU). Part of the research described in this paper was performed at the jet Propulsion Laboratory, California Institute of Technology, under contract with The National Aeronaudcs and Space Administration. NR 127 TC 90 Z9 95 U1 4 U2 28 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0022-4073 J9 J QUANT SPECTROSC RA JI J. Quant. Spectrosc. Radiat. Transf. PD JUN-JUL PY 2009 VL 110 IS 9-10 SI SI BP 573 EP 596 DI 10.1016/j.jqsrt.2009.02.014 PG 24 WC Optics; Spectroscopy SC Optics; Spectroscopy GA 447HD UT WOS:000266181300003 ER PT J AU Flaud, JM Lafferty, WJ Sams, RL AF Flaud, J. -M. Lafferty, W. J. Sams, R. L. TI Line intensities for the nu(1), nu(3) and nu(1)+nu(3) bands of (SO2)-S-34 SO JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER LA English DT Article DE (SO2)-S-34 infrared spectrum; Band intensities; nu(1), nu(3) and nu(1)+nu(3) bands ID EQUILIBRIUM ROTATIONAL-CONSTANTS; HIGH-RESOLUTION ANALYSIS; VIBRATIONAL-STATES; COMBINATION BAND; SULFUR-DIOXIDE; SO2; POSITIONS; SPECTROSCOPY; SPECTRA AB Using both high resolution (0.0018 cm(-1)) and medium resolution (0.112 cm(-1)) Fourier transform spectra of an enriched S-34 (95.3%) sample of sulfur dioxide, it has been possible to accurately measure a large number of individual line intensities for some of the strongest of the SO2 bands, i.e. nu(1), nu(3) and nu(1)+nu(3). These intensities were least-squares fitted using a theoretical model which takes into account the vibration-rotation interactions linking the upper energy levels where needed, and, in this way, expansions of the various transition moment operators were determined. The Hamiltonian parameters determined in previous analyses together with these moments were then used to generate synthetic spectra for the bands studied and their corresponding hot bands providing one with an extensive picture of the absorption spectrum of (SO2)-S-34 in the spectral domains, 8.7, 7.4, and 4 mu m. Published by Elsevier Ltd. C1 [Lafferty, W. J.] NIST, Opt Phys Div, Gaithersburg, MD 20899 USA. [Flaud, J. -M.] Univ Paris Est, CNRS, Lab Inter Univ Syst Atmospher, F-94010 Creteil, France. [Flaud, J. -M.] Univ Paris 07, CNRS, Lab Inter Univ Syst Atmospher, F-94010 Creteil, France. [Sams, R. L.] Pacific NW Natl Lab, Richland, WA 99352 USA. RP Lafferty, WJ (reprint author), NIST, Opt Phys Div, Gaithersburg, MD 20899 USA. EM Walter.Lafferty@nist.gov FU NASA Upper Atmosphere Research Program; United States Department of Energy; Office of Basic Energy Sciences; Pacific Northwest National Laboratory is operated for the United States Department of Energy by Battelle [DE-AC05-76RLO 1830] FX The portion of this work performed at NIST was supported in part by the NASA Upper Atmosphere Research Program. This research was also supported, in part, by the United States Department of Energy, Office of Basic Energy Sciences, Chemical Sciences Division, and the experimental part was performed at the W. R. Wiley Environmental Molecular Science Laboratory, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research located at the Pacific Northwest National Laboratory. Pacific Northwest National Laboratory is operated for the United States Department of Energy by Battelle under contract DE-AC05-76RLO 1830. JMF thanks the Optical Technology Division of NIST for its support during his visit. NR 23 TC 18 Z9 18 U1 0 U2 2 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0022-4073 J9 J QUANT SPECTROSC RA JI J. Quant. Spectrosc. Radiat. Transf. PD JUN-JUL PY 2009 VL 110 IS 9-10 SI SI BP 669 EP 674 DI 10.1016/j.jqsrt.2008.12.003 PG 6 WC Optics; Spectroscopy SC Optics; Spectroscopy GA 447HD UT WOS:000266181300010 ER PT J AU West, DV McQueen, TM Posen, ID Ke, X Huang, Q Zandbergen, HW Williams, AJ Schiffer, P Cava, RJ AF West, D. V. McQueen, T. M. Posen, I. D. Ke, X. Huang, Q. Zandbergen, H. W. Williams, A. J. Schiffer, P. Cava, R. J. TI The A(2+)Mn(5)(SO4)(6) family of triangular lattice, ferrimagnetic sulfates SO JOURNAL OF SOLID STATE CHEMISTRY LA English DT Article DE Triangular lattice; Geometric frustration; Magnetism; Sulfate; Regular polygon tiling; Crystallography; New crystal structure AB A new family of anhydrous sulfates, A(2+)Mn(5)(SO4)(6) (A = Pb, Ba, Sr) is reported. The crystal structures of PbMn5(SO4)(6) and SrMn5(SO4)(6) are solved by powder X-ray and neutron diffraction. BaMn5(SO4)(6) is isostructural. PbMn5(SO4)(6) Crystallizes with P (3) over bar symmetry and unit cell parameters of a = 14.551 (1) angstrom and c = 7.535(1) angstrom. The structure has rich features, including dimers of face-sharing MnO6 octahedra, and two complementary triangular layers of Mn atoms. All compounds undergo a magnetic ordering transition at 10 K, below which, the magnetic susceptibility of the compounds varies systematically with the radius of the non-magnetic cation. Low temperature neutron diffraction shows that the complementary triangular layers result in a ferrimagnet with a net moment corresponding to one high spin Mn2+ per unit cell, correlating well with the magnetization data. The non-magnetic variant PbMg5(SO4)(6) is also reported. (C) 2009 Elsevier Inc. All rights reserved. C1 [West, D. V.; McQueen, T. M.; Posen, I. D.; Williams, A. J.; Cava, R. J.] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA. [Ke, X.; Schiffer, P.] Penn State Univ, Dept Phys, University Pk, PA 16802 USA. [Ke, X.; Schiffer, P.] Penn State Univ, Mat Res Inst, University Pk, PA 16802 USA. [Huang, Q.] NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Zandbergen, H. W.] Delft Univ Technol, Kavli Inst Nanosci, Delft, Netherlands. RP West, DV (reprint author), Princeton Univ, Dept Chem, Princeton, NJ 08544 USA. EM barelytone@gmail.com RI Schiffer, Peter/F-3227-2011; OI Schiffer, Peter/0000-0002-6430-6549; Posen, I. Daniel/0000-0001-5093-140X FU NSF [DMR-0701582, DMR-0703095] FX This research was supported by the NSF grant number DMR-0701582, and by the NSF program in Solid State Chemistry, grant number NSF DMR-0703095. Certain commercial materials and equipment are identified in this report to describe the subject adequately. Such identification does not imply recommendation or endorsement by the NIST, nor does it imply that the materials and equipment identified are necessarily the best available for the purpose. TM. McQueen gratefully acknowledges support of the National Science Foundation Graduate Research Fellowship Program. NR 18 TC 3 Z9 3 U1 0 U2 10 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0022-4596 EI 1095-726X J9 J SOLID STATE CHEM JI J. Solid State Chem. PD JUN PY 2009 VL 182 IS 6 BP 1343 EP 1350 DI 10.1016/j.jssc.2009.03.001 PG 8 WC Chemistry, Inorganic & Nuclear; Chemistry, Physical SC Chemistry GA 454KI UT WOS:000266680400010 ER PT J AU Hildebrand, M Kim, S Shi, D Scott, K Subramaniam, S AF Hildebrand, Mark Kim, Sang Shi, Dan Scott, Keana Subramaniam, Sriram TI 3D imaging of diatoms with ion-abrasion scanning electron microscopy SO JOURNAL OF STRUCTURAL BIOLOGY LA English DT Article DE Diatom; Ion-abrasion SEM; Biomineral structure formation; Biosilicification; 3D tomography ID SILICA SHELL FORMATION; THALASSIOSIRA-PSEUDONANA; VALVE MORPHOGENESIS; CENTRIC DIATOM; CELL-WALL; CYLINDROTHECA-FUSIFORMIS; CYCLOTELLA-CRYPTICA; MICROTUBULE CENTER; FINE-STRUCTURE; BIOSILICA AB Ion-abrasion scanning electron microscopy (IASEM) takes advantage of focused ion beams to abrade thin sections from the surface of bulk specimens, coupled with SEM to image the surface of each section, enabling 3D reconstructions of subcellular architecture at similar to 30 nm resolution. Here, we report the first application of IASEM for imaging a biomineralizing organism, the marine diatom Thalassiosira pseudonana. Diatoms have highly patterned silica-based cell wall structures that are unique models for the study and application of directed nanomaterials synthesis by biological systems. Our study provides new insights into the architecture and assembly principles of both the "hard" (siliceous) and "soft" (organic) components of the cell. From 3D reconstructions of developmentally synchronized diatoms captured at different stages, we show that both micro- and nanoscale siliceous structures can be visualized at specific stages in their formation. We show that not only are structures visualized in a whole-cell context, but demonstrate that fragile, early-stage structures are visible, and that this can be combined with elemental mapping in the exposed slice. We demonstrate that the 3D architectures of silica structures, and the cellular components that mediate their creation and positioning can be visualized simultaneously, providing new opportunities to study and manipulate mineral nanostructures in a genetically tractable system. (C) 2009 Elsevier Inc. All rights reserved. C1 [Hildebrand, Mark] Univ Calif San Diego, Scripps Inst Oceanog, La Jolla, CA 92093 USA. [Kim, Sang; Shi, Dan; Subramaniam, Sriram] NCI, Cell Biol Lab, NIH, Bethesda, MD 20817 USA. [Scott, Keana] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Hildebrand, M (reprint author), Univ Calif San Diego, Scripps Inst Oceanog, 9500 Gilman Dr, La Jolla, CA 92093 USA. EM mhildebrand@ucsd.edu RI Scott, Keana/J-5717-2015 FU Air Force Office of Scientific Research Multidisciplinary University Research Initiative [RF00965521]; National Cancer Institute FX This work was supported by the Air Force Office of Scientific Research Multidisciplinary University Research Initiative Grant RF00965521 (to M.H.) and by the intramural program of the National Cancer Institute (to S.S.). NR 52 TC 41 Z9 42 U1 2 U2 30 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 1047-8477 J9 J STRUCT BIOL JI J. Struct. Biol. PD JUN PY 2009 VL 166 IS 3 BP 316 EP 328 DI 10.1016/j.jsb.2009.02.014 PG 13 WC Biochemistry & Molecular Biology; Biophysics; Cell Biology SC Biochemistry & Molecular Biology; Biophysics; Cell Biology GA 445QL UT WOS:000266066500008 PM 19269330 ER PT J AU Campbell, S Shipp, S Mulcahy, T Allen, TW AF Campbell, Stephen Shipp, Stephanie Mulcahy, Tim Allen, Ted W. TI Informing public policy on science and innovation: the Advanced Technology Program's experience SO JOURNAL OF TECHNOLOGY TRANSFER LA English DT Article DE Innovation measurement; Data Enclave; Advanced Technology Program AB The Advanced Technology Program (ATP) collected a unique source of data from highly innovative firms beginning in 1993. These data follow the OECD's guidelines for collecting innovation data and provide important insights for understanding the innovation process within firms. Although the data are not representative of the population of firms, there is sufficient number of firms in the dataset to test hypotheses and to provide a starting point for calls for innovation metrics. Because of the confidential nature of the data, ATP worked with the National Opinion Research Center (NORC) to create a Data Enclave so that researchers could remotely access the ATP data in a secure environment. To initiate the use of ATP data in the Data Enclave, the ATP program funded researchers to undertake research projects that use ATP data. Other organizations have joined the Data Enclave, including the Department of Agriculture and the Kauffman Foundation. C1 [Shipp, Stephanie] Inst Sci & Technol Policy, Alexandria, VA 22314 USA. [Campbell, Stephen] NIST, Gaithersburg, MD 20899 USA. [Mulcahy, Tim] Univ Chicago, NORC, Bethesda, MD 20814 USA. [Allen, Ted W.] 5X5 Mkt Syst, Silver Spring, MD 20901 USA. RP Shipp, S (reprint author), Inst Sci & Technol Policy, Alexandria, VA 22314 USA. EM stephen.campbell@nist.gov; sshipp@ida.org; mulcahy-tim@norc.org; twa5X5@verizon.net NR 25 TC 2 Z9 2 U1 0 U2 8 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0892-9912 J9 J TECHNOL TRANSFER JI J. Technol. Transf. PD JUN PY 2009 VL 34 IS 3 BP 304 EP 319 DI 10.1007/s10961-008-9098-7 PG 16 WC Engineering, Industrial; Management SC Engineering; Business & Economics GA 404VP UT WOS:000263181400004 ER PT J AU Sarvazyan, A Ostrovsky, L AF Sarvazyan, Armen Ostrovsky, Lev TI Stirring and mixing of liquids using acoustic radiation force SO JOURNAL OF THE ACOUSTICAL SOCIETY OF AMERICA LA English DT Article ID STANDING-WAVE; BUBBLE; ULTRASOUND; MANIPULATION; CELLS; FIELD; ENHANCEMENT; PARTICLES; MOTION; SOUND AB The possibility of using acoustic radiation force in standing waves for stirring and mixing small volumes of liquids is theoretically analyzed. The principle of stirring considered in this paper is based on moving the microparticles suspended in a standing acoustic wave by changing the frequency so that one standing wave mode is replaced by the other, with differently positioned minima of potential energy. The period-average transient dynamics of solid microparticles and gas microbubbles is considered, and simple analytical solutions are obtained for the case of standing waves of variable amplitude. It is shown that bubbles can be moved from one equilibrium position to another two to three orders of magnitude faster than solid particles. For example, radiation force in a standing acoustic wave field may induce movement of microbubbles with a speed of the order of a few m/s at a frequency of 1 MHz and ultrasound pressure amplitude of 100 kPa, whereas the speed of rigid particles does not exceed 1 cm/s under the same conditions. The stirring effect can be additionally enhanced due to the fact that the bubbles that are larger and smaller than the resonant bubbles move in opposite directions. Possible applications of the analyzed stirring mechanism, such as in microarrays, are discussed. (C) 2009 Acoustical Society of America. [DOI: 10.1121/1.3124769] C1 [Sarvazyan, Armen] ARTANN Labs Inc, Trenton, NJ 08618 USA. [Ostrovsky, Lev] Univ Colorado, Zel Technol NOAA Earth Sci Res Lab, Boulder, CO 80305 USA. RP Sarvazyan, A (reprint author), ARTANN Labs Inc, 1459 Lower Ferry Rd, Trenton, NJ 08618 USA. OI Ostrovsky, Lev/0000-0003-2233-1305 NR 28 TC 5 Z9 5 U1 1 U2 11 PU ACOUSTICAL SOC AMER AMER INST PHYSICS PI MELVILLE PA STE 1 NO 1, 2 HUNTINGTON QUADRANGLE, MELVILLE, NY 11747-4502 USA SN 0001-4966 J9 J ACOUST SOC AM JI J. Acoust. Soc. Am. PD JUN PY 2009 VL 125 IS 6 BP 3548 EP 3554 DI 10.1121/1.3124769 PG 7 WC Acoustics; Audiology & Speech-Language Pathology SC Acoustics; Audiology & Speech-Language Pathology GA 454FI UT WOS:000266667400012 PM 19507936 ER PT J AU Kidd, C Levizzani, V Turk, J Ferraro, R AF Kidd, Chris Levizzani, Vincenzo Turk, Joe Ferraro, Ralph TI Satellite Precipitation Measurements for Water Resource Monitoring SO JOURNAL OF THE AMERICAN WATER RESOURCES ASSOCIATION LA English DT Article DE precipitation; remote sensing; hydrologic cycle; meteorology ID PASSIVE MICROWAVE; RAINFALL ESTIMATION; INTERCOMPARISON PROJECT; CLIMATOLOGY PROJECT; ALGORITHMS; VALIDATION; CLOUD; TRMM AB Satellites offer an unrivaled vantage point to observe and measure Earth system processes and parameters. Observations of meteorological phenomena permit a more holistic view of the weather and climate that is not possible through conventional surface observations. Precipitation (rain and snow) in particular, benefit from such observations since precipitation is spatially and temporally highly variable: conventional gauge and radar measurements tend to be land-based with variable coverage. This paper provides an overview of the satellite systems that provide the observations, the techniques used to derive precipitation from the observations, and examples of the precipitation products available for users to access. C1 [Ferraro, Ralph] CNR, Ist Sci Atmosfera & Clima, I-40126 Bologna, Italy. [Ferraro, Ralph] NRL, Monterey, CA USA. [Ferraro, Ralph] NOAA, Satellite Climate Studies Branch, College Pk, MD USA. [Ferraro, Ralph] Univ Birmingham, Sch Geog Earth & Environm Sci, Birmingham B15 2TT, W Midlands, England. EM C.Kidd@bham.ac.uk RI Ferraro, Ralph/F-5587-2010; Levizzani, Vincenzo/A-9070-2013; Kidd, Christopher/H-9910-2014 OI Ferraro, Ralph/0000-0002-8393-7135; Levizzani, Vincenzo/0000-0002-7620-5235; FU The Ivanhoe Foundation grants Fellowships FX The authors would like to acknowledge the various members of the satellite precipitation community that contribute material for the furtherance of precipitation research. We would also like to thank data providers, particularly EUMETSAT and NASA/TSDIS for the provision of image data. NR 29 TC 23 Z9 24 U1 0 U2 8 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 1093-474X J9 J AM WATER RESOUR AS JI J. Am. Water Resour. Assoc. PD JUN PY 2009 VL 45 IS 3 BP 567 EP 579 DI 10.1111/j.1752-1688.2009.00326.x PG 13 WC Engineering, Environmental; Geosciences, Multidisciplinary; Water Resources SC Engineering; Geology; Water Resources GA 449NA UT WOS:000266336100003 ER PT J AU Schramm, Y Mesnick, SL de la Rosa, J Palacios, DM Lowry, MS Aurioles-Gamboa, D Snell, HM Escorza-Trevino, S AF Schramm, Yolanda Mesnick, S. L. de la Rosa, J. Palacios, D. M. Lowry, M. S. Aurioles-Gamboa, D. Snell, H. M. Escorza-Trevino, S. TI Phylogeography of California and Galapagos sea lions and population structure within the California sea lion SO MARINE BIOLOGY LA English DT Review ID GULF-OF-CALIFORNIA; CONTROL-REGION SEQUENCES; ZALOPHUS-CALIFORNIANUS; BAJA-CALIFORNIA; GENETIC DIVERSITY; DNA-SEQUENCE; MEXICO; BIOGEOGRAPHY; PACIFIC; DIVERGENCE AB We investigate the phylogeography of California (Zalophus californianus) and Galapagos (Z. wollebaeki) sea lions and describe within-population structure for the California sea lion based on mitochondrial DNA. Fifty control-region haplotypes were found, 41 from Z. californianus and 9 from Z. wollebaeki, with three fixed differences between the two species. Ranked population boundaries along the range of Z. californianus were defined based on the Monmonier Maximum Difference Algorithm, resulting in five genetically distinct populations, two in the Pacific Ocean and three inside the Gulf of California. A Minimum Spanning Network showed a strong phylogeographic signal with two well-defined clusters, Z. californianus and Z. wollebaeki, separated by six base-pair differences, supporting the existence of two genetically distinct species with an estimated divergence time of similar to 0.8 Ma. Results are discussed in the context of the historical geologic and paleoceanographic events of the last 1 Ma in the eastern Pacific. C1 [Schramm, Yolanda; de la Rosa, J.] Univ Autonoma Baja California, Fac Ciencias Marinas, Ensenada 22830, Baja California, Mexico. [Mesnick, S. L.; Lowry, M. S.] NOAA Fisheries, SW Fisheries Sci Ctr, Protected Resources Div, La Jolla, CA 92037 USA. [Palacios, D. M.] Univ Hawaii, Joint Inst Marine & Atmospher Res, Honolulu, HI 96822 USA. [Palacios, D. M.] NOAA Fisheries, SW Fisheries Sci Ctr, Div Environm Res, Pacific Grove, CA 93950 USA. [Aurioles-Gamboa, D.] Inst Politecn Nacl, Ctr Interdisciplinario Ciencias Marinas, La Paz 23000, Baja California, Mexico. [Snell, H. M.] Charles Darwin Fdn, Charles Darwin Res Stn, Isla Santa Cruz, Galapagos, Ecuador. [Escorza-Trevino, S.] Calif State Univ Los Angeles, Dept Biol Sci, Los Angeles, CA 90032 USA. RP Schramm, Y (reprint author), Univ Autonoma Baja California, Fac Ciencias Marinas, Km 103 Carretera Tijuana Ensenada S-N, Ensenada 22830, Baja California, Mexico. EM yschramm@uabc.mx RI Munguia-Vega, Adrian/G-8417-2012; OI Palacios, Daniel/0000-0001-7069-7913 FU Mexican National Science Foundation (CONACyT); Alstom Power (Rosarito, Mexico); Universidad Autonoma de Baja California; US Office of Naval Research [N00014-05-1-0045]; National Oceanographic Partnership Program FX Tissue samples were collected in Mexico under permit No. DOO750.8106-97 from the Instituto Nacional de Ecologia; in California under permit No. 1026 from the US Department of Commerce; and in Galapagos, Ecuador, under permit No. PC-009-99 from the Galapagos National Park (and permit No. 017-00 for sample export). Additional sea lion samples from San Miguel Island were kindly provided by S. Melin (US National Marine Fisheries Service) and from Galapagos by S. K. Salazar (Charles Darwin Research Station). Work in Mexico was facilitated by A. Zavala and O. Maravilla and carried out on Mexican Navy ships. G. Heckel, L. Inclan and M. L. Anoge participated during the cruise. We acknowledge the invaluable logistical support provided by the Charles Darwin Research Station in Galapagos (through P. Robayo). Thanks to the welcome provided by A. Dizon and staff at the SWFSC Marine Mammal Genetics Laboratory and to C. Le Duc, K. Robertson and J. Hyde for their assistance in the lab. Y. S. had grants from the Mexican National Science Foundation (CONACyT), Alstom Power (Rosarito, Mexico), and the Universidad Autonoma de Baja California. D. M. P. was supported by award No. N00014-05-1-0045 from the US Office of Naval Research, National Oceanographic Partnership Program. Supplemental funding for Galapagos sample export was provided by the Protected Resources Division of the SWFSC (through R. L. Brownell Jr.). Earlier drafts of the manuscript benefited from comments by G. Heckel. We thank to two anonymous reviewers for their valuable suggestions and comments. The experiments comply with the current laws of the USA, Mexico and Ecuador. NR 103 TC 14 Z9 14 U1 3 U2 13 PU SPRINGER HEIDELBERG PI HEIDELBERG PA TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY SN 0025-3162 EI 1432-1793 J9 MAR BIOL JI Mar. Biol. PD JUN PY 2009 VL 156 IS 7 BP 1375 EP 1387 DI 10.1007/s00227-009-1178-1 PG 13 WC Marine & Freshwater Biology SC Marine & Freshwater Biology GA 444WE UT WOS:000266010300002 ER PT J AU Cui, XP Li, XF AF Cui, Xiaopeng Li, Xiaofan TI Diurnal responses of tropical convective and stratiform rainfall to diurnally varying sea surface temperature SO METEOROLOGY AND ATMOSPHERIC PHYSICS LA English DT Article ID CLOUD MICROPHYSICAL PROCESSES; RADIATION INTERACTION; MICROSCALE STRUCTURE; OCEANIC CONVECTION; CUMULUS CONVECTION; EQUILIBRIUM STATES; FRONTAL RAINBANDS; RESOLVING MODEL; TOGA COARE; PRECIPITATION AB Two experiments were carried out using a two-dimensional cloud-resolving model to study the effects of diurnally varying sea surface temperature (SST) on diurnal variations of tropical convective and stratiform rainfall. Experiment SST29 is imposed by a constant SST of 29A degrees C, whereas experiment SST29D is imposed by a diurnally varying SST with a time-mean of 29A degrees C and a diurnal difference of 1A degrees C. Both experiments are also zonally uniformly imposed by a zero vertical velocity and a constant zonal wind, and are integrated for 40 days to reach quasi-equilibrium states. The model domain mean surface rain rate is larger in SST29D than in SST29 in the late afternoon, when the ocean surface is warmer in SST29D. Convective-stratiform rainfall partitioning analysis reveals that the late-afternoon convective rainfall is larger in SST29D than in SST29, whereas the stratiform rainfalls are similar in both experiments. Further analysis of surface rainfall and cloud microphysical budgets over convective regions shows that, in the late afternoon, the larger amount of water vapor is pumped into the non-raining region through the larger surface evaporation associated with the warmer SST. This water vapor is then transported into convective regions to produce more vapor condensation and greater collection of cloud water by raindrops and larger convective rainfall in SST29D than in SST29. C1 [Cui, Xiaopeng] Chinese Acad Sci, Inst Atmospher Phys, Lab Cloud Precipitat Phys & Severe Storms, Beijing 100029, Peoples R China. [Li, Xiaofan] Joint Ctr Satellite Data Assimilat, Camp Springs, MD USA. [Li, Xiaofan] NOAA NESDIS Off Res & Applicat, Camp Springs, MD USA. RP Cui, XP (reprint author), Chinese Acad Sci, Inst Atmospher Phys, Lab Cloud Precipitat Phys & Severe Storms, Beijing 100029, Peoples R China. EM xpcui@mail.iap.ac.cn RI Li, Xiaofan/F-5605-2010; Li, Xiaofan/G-2094-2014 FU National Natural Science Foundation of China [40775036]; Outstanding Oversea Scholars [2005-2-17]; Chinese Academy of Sciences [IAP07214] FX The authors thank the two anonymous reviewers for their helpful comments. Dr. X. Cui is supported by the National Natural Science Foundation of China under Grant No. 40775036, "Outstanding Oversea Scholars'' project under Grant No. 2005-2-17, and the Knowledge Innovation Program of the Chinese Academy of Sciences (IAP07214). NR 46 TC 10 Z9 11 U1 0 U2 4 PU SPRINGER WIEN PI WIEN PA SACHSENPLATZ 4-6, PO BOX 89, A-1201 WIEN, AUSTRIA SN 0177-7971 J9 METEOROL ATMOS PHYS JI Meteorol. Atmos. Phys. PD JUN PY 2009 VL 104 IS 1-2 BP 53 EP 61 DI 10.1007/s00703-008-0016-1 PG 9 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 443OK UT WOS:000265919400005 ER PT J AU Holt, DR AF Holt, Donald R. TI Periodic electromagnetic fields for finding the propagation constant of coaxial air lines with surface roughness and ohmic wall loss SO METROLOGIA LA English DT Article ID WAVE-GUIDES; WAVEGUIDE; REFLECTION AB Maxwell's equations in the context of Floquet's theorem for construction of a sequence of periodic precision air lines with surface roughness and ohmic resistance in the conductor walls offer a solution for finding the propagation constants in correspondence to the principal transverse magnetic mode. Boundary conditions to define surface roughness and ohmic wall loss through a tangent surface vector expression to incorporate composite axial and radial electromagnetic field components enable the construction of a system determinant to extract the propagation constant. C1 [Holt, Donald R.] Natl Inst Stand & Technol, Microwave Measurements Grp, Boulder, CO 80305 USA. EM sigzit@cox.net NR 24 TC 1 Z9 1 U1 0 U2 0 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0026-1394 J9 METROLOGIA JI Metrologia PD JUN PY 2009 VL 46 IS 3 BP 167 EP 177 DI 10.1088/0026-1394/46/3/003 PG 11 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 451FY UT WOS:000266457300006 ER PT J AU Harvey, AH Span, R Fujii, K Tanaka, M Davis, RS AF Harvey, A. H. Span, R. Fujii, K. Tanaka, M. Davis, R. S. TI Density of water: roles of the CIPM and IAPWS standards SO METROLOGIA LA English DT Article ID THERMODYNAMIC PROPERTIES; DISSOLVED AIR; 40-DEGREES-C; 0-DEGREES-C AB This contribution discusses the relative roles of the standard formulation for the density of liquid water recommended for metrology by the International Committee for Weights and Measures (CIPM) in 2001 and the thermodynamic property formulation adopted by the International Association for the Properties of Water and Steam (IAPWS) in 1995. The two formulations give consistent results for densities in the region of validity of the CIPM standard. Guidelines are presented for the appropriate use of the two formulations. C1 [Harvey, A. H.] Natl Inst Stand & Technol, Thermophys Properties Div, Boulder, CO 80305 USA. [Span, R.] Ruhr Univ Bochum, Lehrstuhl Thermodynam, Fak Maschinenbau, D-44780 Bochum, Germany. [Fujii, K.; Tanaka, M.] AIST Cent 3, Natl Metrol Inst Japan, Tsukuba, Ibaraki 3058563, Japan. [Davis, R. S.] Bur Int Poids & Mesures, F-92312 Sevres, France. RP Harvey, AH (reprint author), Natl Inst Stand & Technol, Thermophys Properties Div, 325 Broadway, Boulder, CO 80305 USA. EM aharvey@boulder.nist.gov; fujii.kenichi@aist.go.jp OI Span, Roland/0000-0002-8350-8285 NR 17 TC 10 Z9 10 U1 0 U2 1 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0026-1394 J9 METROLOGIA JI Metrologia PD JUN PY 2009 VL 46 IS 3 BP 196 EP 198 DI 10.1088/0026-1394/46/3/006 PG 3 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 451FY UT WOS:000266457300009 ER PT J AU Mariassy, M Pratt, KW Spitzer, P AF Mariassy, Michal Pratt, Kenneth W. Spitzer, Petra TI Major applications of electrochemical techniques at national metrology institutes SO METROLOGIA LA English DT Review ID PRECISE COULOMETRIC TITRATION; CONSTANT-CURRENT COULOMETRY; CONTROLLED-POTENTIAL COULOMETRY; REFERENCE VALUE STANDARDS; ORGANIC-SOLVENT MIXTURES; COMPRESSED GAS-MIXTURES; PH MEASUREMENTS; ELECTROLYTIC CONDUCTIVITY; ABSOLUTE DETERMINATION; ATOMIC WEIGHT AB A review of the state of the art of electrochemical methods at the highest metrology level in national metrology institutes (NMIs) is given, with emphasis on standardization work (primary methods) in the fields of pH and electrolytic conductivity, as well as use of coulometry. Attention is also given to certain technical issues in the implementation of these methods. C1 [Mariassy, Michal] Slovensky Metrol Ustav, SK-84255 Bratislava 4, Slovakia. [Pratt, Kenneth W.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. [Spitzer, Petra] Phys Tech Bundesanstalt, D-38116 Braunschweig, Germany. RP Mariassy, M (reprint author), Slovensky Metrol Ustav, Karloveska 63, SK-84255 Bratislava 4, Slovakia. EM mariassy@smu.gov.sk NR 151 TC 26 Z9 26 U1 0 U2 15 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0026-1394 EI 1681-7575 J9 METROLOGIA JI Metrologia PD JUN PY 2009 VL 46 IS 3 BP 199 EP 213 DI 10.1088/0026-1394/46/3/007 PG 15 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 451FY UT WOS:000266457300010 ER PT J AU Kacker, RN Lawrence, JF AF Kacker, Raghu N. Lawrence, James F. TI Rectangular distribution whose width is not exactly known: isocurvilinear trapezoidal distribution SO METROLOGIA LA English DT Article AB After the Gaussian distribution, the probability distribution most commonly used in evaluation of uncertainty in measurement is the rectangular distribution. If the half-width of a rectangular distribution is specified, the mid-point is uncertain, and the probability distribution of the mid-point may be represented by another (narrower) rectangular distribution then the resulting distribution is an isosceles trapezoidal distribution. However, in metrological applications, it is more common that the mid-point is specified but the half-width is uncertain. If the probability distribution of the half-width may be represented by another (narrower) rectangular distribution, then the resulting distribution looks like an isosceles trapezoid whose sloping sides are curved. We can refer to such a probability distribution as an isocurvilinear trapezoidal distribution. We describe the main characteristics of an isocurvilinear trapezoidal distribution which arises when the half-width is uncertain. When the uncertainty in specification of the half-width is not excessive, the isocurvilinear trapezoidal distribution can be approximated by an isosceles trapezoidal distribution. C1 [Kacker, Raghu N.; Lawrence, James F.] Natl Inst Stand & Technol, Math & Computat Sci Div, Gaithersburg, MD 20899 USA. [Lawrence, James F.] George Mason Univ, Dept Math, Fairfax, VA 22030 USA. RP Kacker, RN (reprint author), Natl Inst Stand & Technol, Math & Computat Sci Div, Gaithersburg, MD 20899 USA. EM raghu.kacker@nist.gov; james.lawrence@nist.gov NR 4 TC 5 Z9 5 U1 2 U2 2 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0026-1394 J9 METROLOGIA JI Metrologia PD JUN PY 2009 VL 46 IS 3 BP 254 EP 260 DI 10.1088/0026-1394/46/3/012 PG 7 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 451FY UT WOS:000266457300015 ER PT J AU Elster, C Toman, B AF Elster, Clemens Toman, Blaza TI Bayesian uncertainty analysis under prior ignorance of the measurand versus analysis using the Supplement 1 to the Guide: a comparison SO METROLOGIA LA English DT Article ID GUM AB A recent supplement to the GUM (GUM S1) is compared with a Bayesian analysis in terms of a particular task of data analysis, one where no prior knowledge of the measurand is presumed. For the Bayesian analysis, an improper prior density on the measurand is employed. It is shown that both approaches yield the same results when the measurand depends linearly on the input quantities, but generally different results otherwise. This difference is shown to be not a conceptual one, but due to the fact that the two methods correspond to Bayesian analysis under different parametrizations, with ignorance of the measurand expressed by a non-informative prior on a different parameter. The use of the improper prior for the measurand itself may result in an improper posterior probability density function (PDF) when the measurand depends non-linearly on the input quantities. On the other hand, the PDF of the measurand derived by the GUM supplement method is always proper but may sometimes have undesirable properties such as non-existence of moments. It is concluded that for a linear model both analyses can safely be applied. For a non-linear model, the GUM supplement approach may be preferred over a Bayesian analysis using a constant prior on the measurand. But since in this case the GUM S1 PDF may also have undesirable properties, and as often some prior knowledge about the measurand may be established, metrologists are strongly encouraged to express this prior knowledge in terms of a proper PDF which can then be included in a Bayesian analysis. The results of this paper are illustrated by an example of a simple non-linear model. C1 [Elster, Clemens] Phys Tech Bundesanstalt, D-10587 Berlin, Germany. [Toman, Blaza] Natl Inst Stand & Technol, Stat Engn Div, Informat Technol Lab, US Dept Commerce, Gaithersburg, MD 20899 USA. RP Elster, C (reprint author), Phys Tech Bundesanstalt, Abbestr 2-12, D-10587 Berlin, Germany. NR 11 TC 25 Z9 25 U1 0 U2 1 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0026-1394 J9 METROLOGIA JI Metrologia PD JUN PY 2009 VL 46 IS 3 BP 261 EP 266 DI 10.1088/0026-1394/46/3/013 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 451FY UT WOS:000266457300016 ER PT J AU Rukhin, AL AF Rukhin, Andrew L. TI Weighted means statistics in interlaboratory studies SO METROLOGIA LA English DT Article ID RANDOM EFFECTS MODEL; KEY COMPARISON DATA; ESTIMATORS; VARIANCES; VALUES AB The usefulness of weighted means statistics as a consensus mean estimator in collaborative studies is discussed. A random effects model designed to combine information from several sources is employed to justify their appeal to metrologists. Some methods of estimating the uncertainties and of constructing confidence intervals are reviewed. C1 Natl Inst Stand & Technol, Stat Engn Div, Gaithersburg, MD 20899 USA. RP Rukhin, AL (reprint author), Natl Inst Stand & Technol, Stat Engn Div, Gaithersburg, MD 20899 USA. NR 37 TC 34 Z9 34 U1 0 U2 6 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0026-1394 J9 METROLOGIA JI Metrologia PD JUN PY 2009 VL 46 IS 3 BP 323 EP 331 DI 10.1088/0026-1394/46/3/021 PG 9 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 451FY UT WOS:000266457300024 ER PT J AU Jabbour, ZJ Abbott, P Williams, E Liu, R Lee, V AF Jabbour, Zeina J. Abbott, Patrick Williams, Edwin Liu, Ruimin Lee, Vincent TI Linking air and vacuum mass measurement by magnetic levitation SO METROLOGIA LA English DT Article ID SUSPENSION BALANCE; KILOGRAM; REDEFINITION; STANDARDS; CONSTANT; DENSITY AB This paper describes a new approach to link air and vacuum mass measurements using magnetic levitation techniques. This procedure provides direct traceability to national standards, presently defined in ambient air. We describe the basic principles, challenges, initial modelling calculations and performance expectations(1). C1 [Jabbour, Zeina J.; Abbott, Patrick; Williams, Edwin; Liu, Ruimin; Lee, Vincent] NIST, Gaithersburg, MD 20899 USA. RP Jabbour, ZJ (reprint author), NIST, Gaithersburg, MD 20899 USA. NR 27 TC 6 Z9 6 U1 0 U2 1 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0026-1394 J9 METROLOGIA JI Metrologia PD JUN PY 2009 VL 46 IS 3 BP 339 EP 344 DI 10.1088/0026-1394/46/3/023 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 451FY UT WOS:000266457300026 ER PT J AU Zhang, WP Zhang, NF Liu, HK AF Zhang, Weiping Zhang, Nien Fan Liu, Hung-kung TI A generalized method for the multiple artefacts problem in interlaboratory comparisons with linear trends SO METROLOGIA LA English DT Article ID KEY COMPARISONS; STANDARDS AB A generalized statistical approach for interlaboratory comparisons with linear trends is proposed. This new approach can be applied to the general case when the artefacts are measured and reported multiple times in each participating laboratory. The advantages of this approach are that it is consistent with the previous approaches when only the pilot lababoratory makes multiple measurements and it applies whether or not there exists a trend. The uncertainties for the comparison reference value and the degree of equivalence are also provided. As an illustration, the method is applied to the SIM.EM-K2 comparison for resistance at the level of 1 G Omega. C1 [Zhang, Weiping; Zhang, Nien Fan; Liu, Hung-kung] NIST, Stat Engn Div, Gaithersburg, MD 20899 USA. [Zhang, Weiping] Univ Sci & Technol China, Dept Stat & Finance, Hefei 230026, Peoples R China. RP Zhang, WP (reprint author), NIST, Stat Engn Div, Gaithersburg, MD 20899 USA. RI Zhang, Weiping/C-6158-2014 NR 11 TC 7 Z9 7 U1 0 U2 0 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0026-1394 J9 METROLOGIA JI Metrologia PD JUN PY 2009 VL 46 IS 3 BP 345 EP 350 DI 10.1088/0026-1394/46/3/024 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 451FY UT WOS:000266457300027 ER PT J AU Taylor, BN AF Taylor, Barry N. TI Molar mass and related quantities in the New SI SO METROLOGIA LA English DT Letter ID FUNDAMENTAL PHYSICAL CONSTANTS; CODATA RECOMMENDED VALUES AB This letter addresses the calculation of molar mass and related quantities in the updated version of the SI (most often called the 'New SI' but sometimes the 'Quantum SI') currently under discussion by the International Committee for Weights and Measures and its Consultative Committee for Units and which could be adopted by the next General Conference on Weights and Measures in 2011. C1 Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Taylor, BN (reprint author), Natl Inst Stand & Technol, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM barry.taylor@nist.gov NR 5 TC 17 Z9 17 U1 0 U2 0 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0026-1394 J9 METROLOGIA JI Metrologia PD JUN PY 2009 VL 46 IS 3 BP L16 EP L19 DI 10.1088/0026-1394/46/3/L01 PG 4 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 451FY UT WOS:000266457300002 ER PT J AU Gu, DZ Rodriguez-Morales, F Yngvesson, SK AF Gu, Dazhen Rodriguez-Morales, Fernando Yngvesson, Sigfrid K. TI AIR-BRIDGE-INTEGRATED STUB FILTER FOR SUBMILLIMETER WAVE APPLICATIONS SO MICROWAVE AND OPTICAL TECHNOLOGY LETTERS LA English DT Article DE air-bridge; band-stop filter; electroplating; microfabrication; submillimeter wave systems ID MODE; CPW AB We report a coplanar waveguide notch filter with all integrated air-bridge, designed for operation at submillimeter wave frequencies and cryogenic temperatures. The filter is built with a planar slot-ring antenna, which is in turn loaded with a superconducting mixer detector. The filter is designed to have a narrow-band response with 40 dB of attenuation at 1.56 THz The fabrication of the micrometer-scale structure was accomplished by means of UV photolithography and electroplating. The optimized microelectronic fabrication process produced high Yields and good reliability. Preliminary measurements of a submillimeter wave receiver based on this design showed satisfactory performance of the filter. (c) 2009 Wiley Periodicals, Inc. Microwave Opt Technol Lett 51: 1436-1439, 2009. *This article is a US Government work and. as such, is in the public domain in the United States of America. Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/mop.24375 C1 [Gu, Dazhen] Natl Inst Stand & Technol, Electromagnet Div, Boulder, CO 80305 USA. [Rodriguez-Morales, Fernando] Ctr Remote Sensing Ice Sheets, Lawrence, KS 66045 USA. [Yngvesson, Sigfrid K.] Univ Massachusetts, Dept Elect & Comp Engn, Amherst, MA 01003 USA. RP Gu, DZ (reprint author), Natl Inst Stand & Technol, Electromagnet Div, 325 Broadway, Boulder, CO 80305 USA. EM dazhen.gu@boulder.nist.gov RI Gu, Dazhen/B-4854-2012 NR 9 TC 0 Z9 0 U1 0 U2 2 PU JOHN WILEY & SONS INC PI HOBOKEN PA 111 RIVER ST, HOBOKEN, NJ 07030 USA SN 0895-2477 J9 MICROW OPT TECHN LET JI Microw. Opt. Technol. Lett. PD JUN PY 2009 VL 51 IS 6 BP 1436 EP 1439 DI 10.1002/mop.24375 PG 4 WC Engineering, Electrical & Electronic; Optics SC Engineering; Optics GA 433WP UT WOS:000265236800014 ER PT J AU Eytan, RI Hayes, M Arbour-Reily, P Miller, M Hellberg, ME AF Eytan, Ron I. Hayes, Marshall Arbour-Reily, Patricia Miller, Margaret Hellberg, Michael E. TI Nuclear sequences reveal mid-range isolation of an imperilled deep-water coral population SO MOLECULAR ECOLOGY LA English DT Review DE multilocus genotyping; Oculina Banks; Oculina; population isolation ID MULTILOCUS GENOTYPE DATA; MONTASTRAEA-ANNULARIS; GENE FLOW; PHENOTYPIC PLASTICITY; SCLERACTINIAN CORAL; DNA-SEQUENCES; MORPHOLOGICAL PLASTICITY; HAPLOTYPE RECONSTRUCTION; BALANOPHYLLIA ELEGANS; EVOLUTIONARY HISTORY AB The mitochondrial DNA of corals and their anthozoan kin evolves slowly, with substitution rates about two orders of magnitude lower than in typical bilateral animals. This has impeded the delineation of closely related species and isolated populations in corals, compounding problems caused by high morphological plasticity. Here we characterize rates of divergence and levels of variation for three nuclear gene regions, then use these nuclear sequences as markers to test for population structure in Oculina, a taxonomically confused genus of corals. Rates of sequence divergence (obtained by comparison to Solenastrea hyades) were at least five (and sometimes over 10) times faster for the three nuclear markers than for a mitochondrial reference sequence. Nuclear sequence variation was also high within populations, although it tended to decline north of Cape Canaveral. Significant subdivision was evident among samples from 10 locations from between North Carolina and the Florida Panhandle, but neither nominal species designation nor population depth explained much of this variation. Instead, a single population from the unique deep (> 70 m) water reefs at the Oculina Banks off central Florida was a strong genetic outlier: all pairwise measures of subdivision involving this population were greater than those involving all other populations, and multilocus clustering recognized the Oculina Banks as distinct from other populations, despite its close proximity (<= 36 km) to populations from shallower waters nearby and its location at the centre of the sampled range. Genetic isolation of the Oculina Banks population suggests that focused efforts will be needed to conserve the foundation species of these monotypic reefs and that depth may play a role in isolating marine populations and perhaps facilitating initial steps towards speciation. C1 [Eytan, Ron I.; Arbour-Reily, Patricia; Hellberg, Michael E.] Louisiana State Univ, Dept Biol Sci, Baton Rouge, LA 70803 USA. [Hayes, Marshall] Cornell Univ, Dept Plant Pathol & Plant Microbe Biol, Ithaca, NY 14853 USA. [Miller, Margaret] SE Sci Ctr, NOAA Fisheries, Miami, FL 33149 USA. RP Hellberg, ME (reprint author), Louisiana State Univ, Dept Biol Sci, Baton Rouge, LA 70803 USA. EM mhellbe@lsu.edu FU NOAA Office of Ocean Exploration [NA05OAR4601040]; National Science Foundation [OCE-0550270] FX We thank the many who assisted with collections, including Todd Barber, John Brusher, Alice Dennis, Stacey Harter, Niels Lindquist, Greg McFall, Grant Gilmore, Sean Cimilluca, Jon Mackenzie, Karen Neely, Tracy Ziegler, the Volusia County Reef Research Team, the Jacksonville Reef Research Team, and especially Sandra Brooke. Special thanks to Greg Piniak (NOAA Center for Coastal Fisheries & Habitat Research, Beaufort, NC) and the crew of the NOAA Ship Nancy Foster. Sandra Brooke and Carlos Prada provided useful comments on the manuscript. Partial funding was provided by the NOAA-Fisheries Species of Concern program and the NOAA Coral Reef Conservation Program. Additional support came from the NOAA Office of Ocean Exploration (NA05OAR4601040 to WW Kirby-Smith) and from the National Science Foundation (OCE-0550270 to MEH and Iliana Baums). NR 112 TC 39 Z9 39 U1 0 U2 12 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 0962-1083 J9 MOL ECOL JI Mol. Ecol. PD JUN PY 2009 VL 18 IS 11 BP 2375 EP 2389 DI 10.1111/j.1365-294X.2009.04202.x PG 15 WC Biochemistry & Molecular Biology; Ecology; Evolutionary Biology SC Biochemistry & Molecular Biology; Environmental Sciences & Ecology; Evolutionary Biology GA 448NH UT WOS:000266268800008 PM 19457199 ER PT J AU Whitaker, JS Compo, GP Thepaut, JN AF Whitaker, Jeffrey S. Compo, Gilbert P. Thepaut, Jean-Noel TI A Comparison of Variational and Ensemble-Based Data Assimilation Systems for Reanalysis of Sparse Observations SO MONTHLY WEATHER REVIEW LA English DT Article ID IMPLEMENTATION AB An observing system experiment, simulating a surface-only observing network representative of the 1930s, is carried out with three-and four-dimensional variational data assimilation systems (3D-VAR and 4D-VAR) and an ensemble-based data assimilation system (EnsDA). It is found that 4D-VAR and EnsDA systems produce analyses of comparable quality and that both are much more accurate than the analyses produced by the 3D-VAR system. The EnsDA system also produces useful estimates of analysis error, which are not directly available from the variational systems. C1 [Whitaker, Jeffrey S.; Compo, Gilbert P.] NOAA Earth Syst Res Lab, Div Phys Sci, Boulder, CO 80305 USA. [Compo, Gilbert P.] Univ Colorado, Cooperat Inst Res Environm Sci, Climate Diagnost Ctr, Boulder, CO 80309 USA. [Thepaut, Jean-Noel] European Ctr Medium Range Weather Forecasts, Reading RG2 9AX, Berks, England. RP Whitaker, JS (reprint author), NOAA Earth Syst Res Lab, Div Phys Sci, 325 Broadway R PSD1, Boulder, CO 80305 USA. EM jeffrey.s.whitaker@noaa.gov OI COMPO, GILBERT/0000-0001-5199-9633 FU NOAA Climate Program Office through the Climate Dynamics and Experimental Predictions (CDEP) program FX Fruitful discussions with P. Sardeshmukh, A. Simmons, N. Matsui, andT. Hamill aregratefully acknowledged, as are the comments of two anonymous reviewers. This project would not have been possible without a U.S. Department of Energy Innovative and Novel Computational Impact on Theory and Experiment (INCITE) computing award at the National Energy Research Scientific Computer Center. Funding was provided by the NOAA Climate Program Office through the Climate Dynamics and Experimental Predictions (CDEP) program and through the Explaining Climate to Improve Predictions (ECIP) project. NR 12 TC 33 Z9 33 U1 0 U2 4 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0027-0644 J9 MON WEATHER REV JI Mon. Weather Rev. PD JUN PY 2009 VL 137 IS 6 BP 1991 EP 1999 DI 10.1175/2008MWR2781.1 PG 9 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 468VA UT WOS:000267850700017 ER PT J AU Green, MA AF Green, Mark A. TI When small is better SO NATURE MATERIALS LA English DT News Item C1 [Green, Mark A.] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. [Green, Mark A.] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. RP Green, MA (reprint author), Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. EM mark.green@nist.gov NR 4 TC 1 Z9 1 U1 1 U2 12 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 1476-1122 J9 NAT MATER JI Nat. Mater. PD JUN PY 2009 VL 8 IS 6 BP 450 EP 451 DI 10.1038/nmat2457 PG 2 WC Chemistry, Physical; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter SC Chemistry; Materials Science; Physics GA 447RE UT WOS:000266208700013 PM 19458643 ER PT J AU Coddington, I Swann, WC Nenadovic, L Newbury, NR AF Coddington, I. Swann, W. C. Nenadovic, L. Newbury, N. R. TI Rapid and precise absolute distance measurements at long range SO NATURE PHOTONICS LA English DT Article ID FEMTOSECOND PULSE LASER; MODE-LOCKED LASERS; FREQUENCY-COMB; FIBER-LASER; NOBEL LECTURE; INTERFEROMETRY; METROLOGY; TECHNOLOGY; MISSION; NOISE AB The ability to determine absolute distance to an object is one of the most basic measurements of remote sensing. High-precision ranging has important applications in both large-scale manufacturing and in future tight formation-flying satellite missions, where rapid and precise measurements of absolute distance are critical for maintaining the relative pointing and position of the individual satellites. Using two coherent broadband fibre-laser frequency comb sources, we demonstrate a coherent laser ranging system that combines the advantages of time-of-flight and interferometric approaches to provide absolute distance measurements, simultaneously from multiple reflectors, and at low power. The pulse time-of-flight yields a precision of 3 mm with an ambiguity range of 1.5 m in 200 mu s. Through the optical carrier phase, the precision is improved to better than 5 nm at 60 ms, and through the radio-frequency phase the ambiguity range is extended to 30 km, potentially providing 2 parts in 10(13) ranging at long distances. C1 [Coddington, I.; Swann, W. C.; Nenadovic, L.; Newbury, N. R.] NIST, Boulder, CO 80305 USA. RP Coddington, I (reprint author), NIST, 325 Broadway MS 815, Boulder, CO 80305 USA. EM ian@nist.gov; nnewbury@boulder.nist.gov NR 50 TC 247 Z9 261 U1 17 U2 111 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 1749-4885 EI 1749-4893 J9 NAT PHOTONICS JI Nat. Photonics PD JUN PY 2009 VL 3 IS 6 BP 351 EP 356 DI 10.1038/NPHOTON.2009.94 PG 6 WC Optics; Physics, Applied SC Optics; Physics GA 452MK UT WOS:000266544000016 ER PT J AU Watkins, JD Schaff, TR Spinrad, RW AF Watkins, James D. Schaff, Terrence R. Spinrad, Richard W. TI How the Oceanographic Community Created a National Oceanographic Partnership Program SO OCEANOGRAPHY LA English DT Editorial Material C1 [Schaff, Terrence R.] Woods Hole Oceanog Inst, Woods Hole, MA 02543 USA. [Spinrad, Richard W.] Natl Ocean & Atmospher Adm, Silver Spring, MD USA. EM Richard.Spinrad@noaa.gov NR 6 TC 0 Z9 0 U1 0 U2 2 PU OCEANOGRAPHY SOC PI ROCKVILLE PA P.O. BOX 1931, ROCKVILLE, MD USA SN 1042-8275 J9 OCEANOGRAPHY JI Oceanography PD JUN PY 2009 VL 22 IS 2 BP 20 EP 24 PG 5 WC Oceanography SC Oceanography GA 457WC UT WOS:000266964200007 ER PT J AU Roemmich, D Johnson, GC Riser, S Davis, R Gilson, J Owens, WB Garzoli, SL Schmid, C Ignaszewski, M AF Roemmich, Dean Johnson, Gregory C. Riser, Stephen Davis, Russ Gilson, John Owens, W. Brechner Garzoli, Silvia L. Schmid, Claudia Ignaszewski, Mark TI The Argo Program Observing the Global Ocean with Profiling Floats SO OCEANOGRAPHY LA English DT Article ID PACIFIC AB The Argo Program has created the first global array for observing the subsurface ocean. Argo arose from a compelling scientific need for climate-relevant ocean data; it was made possible by technology development and implemented through international collaboration. The float program and its data management system began with regional arrays in 1999, scaled up to global deployments by 2004, and achieved its target of 3000 active instruments in 2007. US Argo, supported by the National Oceanic and Atmospheric Administration and the Navy through the National Oceanographic Partnership Program, provides half of the floats in the international array, plus leadership in float technology, data management, data quality control, international coordination, and outreach. All Argo data are freely available without restriction, in real time and in research-quality forms. Uses of Argo data range from oceanographic research, climate research, and education, to operational applications in ocean data assimilation and seasonal-to-decadal prediction. Argo's value grows as its data accumulate and their applications are better understood. Continuing advances in profiling float and sensor technologies open many exciting possibilities for Argo's future, including expanding sampling into high latitudes and the deep ocean, improving near-surface sampling, and adding biogeochemical parameters. C1 [Roemmich, Dean; Davis, Russ] Univ Calif San Diego, Scripps Inst Oceanog, Instrument Dev Grp, La Jolla, CA 92093 USA. [Johnson, Gregory C.] NOAA, Pacific Marine Environm Lab, Ocean Climate Res Div, Seattle, WA 98115 USA. [Riser, Stephen] Univ Washington, Sch Oceanog, Seattle, WA 98195 USA. [Owens, W. Brechner] Woods Hole Oceanog Inst, Woods Hole, MA 02543 USA. [Garzoli, Silvia L.; Schmid, Claudia] NOAA, Atlantic Oceanog & Meteorol Lab, Phys Oceanog Div, Miami, FL 33149 USA. [Ignaszewski, Mark] USN, Fleet Numer Meteorol & Oceanog Ctr, Monterey, CA USA. RP Roemmich, D (reprint author), Univ Calif San Diego, Scripps Inst Oceanog, Instrument Dev Grp, La Jolla, CA 92093 USA. EM droemmich@ucsd.edu RI Garzoli, Silvia/A-3556-2010; Johnson, Gregory/I-6559-2012; Schmid, Claudia/D-5875-2013 OI Davis, Russ/0000-0003-1903-6313; Garzoli, Silvia/0000-0003-3553-2253; Johnson, Gregory/0000-0002-8023-4020; Schmid, Claudia/0000-0003-2132-4736 FU US Argo via the National Ocean Partnership Program [NA17RJ1231, NA17RJ1232, NA17RJ1223] FX Argo data are collected and made freely available by the international Argo Program and by the national programs that contribute to it (http://www.argo. net). The authors and their part of the Argo Program were supported by US Argo via the National Ocean Partnership Program, including NOAA Grants NA17RJ1231 (SIO-JIMO), NA17RJ1232 (UW-JISAO), and NA17RJ1223 (WHOI-CICOR). The statements, findings, conclusions, and recommendations herein are those of the authors and do not necessarily reflect the views of the National Oceanic and Atmospheric Administration or the Department of Commerce, and the mention of commercial products herein does not constitute endorsement by these entities. Graphics in the Global Marine Atlas are produced using Ferret software, a product of NOAA's Pacific Marine Environmental Laboratory. PMEL contribution Number 3244. NR 20 TC 132 Z9 135 U1 1 U2 29 PU OCEANOGRAPHY SOC PI ROCKVILLE PA P.O. BOX 1931, ROCKVILLE, MD USA SN 1042-8275 J9 OCEANOGRAPHY JI Oceanography PD JUN PY 2009 VL 22 IS 2 SI SI BP 34 EP 43 DI 10.5670/oceanog.2009.36 PG 10 WC Oceanography SC Oceanography GA 457WC UT WOS:000266964200010 ER PT J AU Chassignet, EP Hurlburt, HE Metzger, EJ Smedstad, OM Cummings, JA Halliwell, GR Bleck, R Baraille, R Wallcraft, AJ Lozano, C Tolman, HL Srinivasan, A Hankin, S Cornillon, P Weisberg, R Barth, A He, R Werner, F Wilkin, J AF Chassignet, Eric P. Hurlburt, Harley E. Metzger, E. Joseph Smedstad, Ole Martin Cummings, James A. Halliwell, George R. Bleck, Rainer Baraille, Remy Wallcraft, Alan J. Lozano, Carlos Tolman, Hendrik L. Srinivasan, Ashwanth Hankin, Steve Cornillon, Peter Weisberg, Robert Barth, Alexander He, Ruoying Werner, Francisco Wilkin, John TI US GODAE Global Ocean Prediction with the HYbrid Coordinate Ocean Model (HYCOM) SO OCEANOGRAPHY LA English DT Article ID NORTH-ATLANTIC; VERTICAL COORDINATE; DATA ASSIMILATION; SYSTEM; 1/10-DEGREES; SIMULATION; SURFACE; IMPACT AB During the past five to ten years, a broad partnership of institutions under NOPP sponsorship has collaborated in developing and demonstrating the performance and application of eddy-resolving, real-time global- and basin-scale ocean prediction systems using the HYbrid Coordinate Ocean Model (HYCOM). The partnership represents a broad spectrum of the oceanographic community, bringing together academia, federal agencies, and industry/commercial entities, and spanning modeling, data assimilation, data management and serving, observational capabilities, and application of HYCOM prediction system outputs. In addition to providing real-time, eddy-resolving global- and basin-scale ocean prediction systems for the US Navy and NOAA, this project also offered an outstanding opportunity for NOAA-Navy collaboration and cooperation, ranging from research to the operational level. This paper provides an overview of the global HYCOM ocean prediction system and highlights some of its achievements. An important outcome of this effort is the capability of the global system to provide boundary conditions to even higher-resolution regional and coastal models. C1 [Chassignet, Eric P.] Florida State Univ, Ctr Ocean Atmospher Predict Studies, Tallahassee, FL 32306 USA. [Smedstad, Ole Martin] QinetiQ N Amer Technol Solut Grp, Stennis Space Ctr, MS USA. [Metzger, E. Joseph; Cummings, James A.; Wallcraft, Alan J.] USN, Res Lab, Ocean Dynam & Predict Branch, Stennis Space Ctr, MS USA. [Halliwell, George R.] NOAA, Atlantic Oceanog & Meteorol Lab, Miami, FL 33149 USA. [Bleck, Rainer] NASA, Goddard Inst Space Studies, New York, NY 10025 USA. [Bleck, Rainer] NOAA, Earth Syst Res Lab, Boulder, CO USA. [Baraille, Remy] Serv Hydrog & Oceanog Marine, Toulouse, France. [Tolman, Hendrik L.] NOAA, Natl Ctr Environm Predict, Environm Modeling Ctr, Marine Modeling & Anal Branch, Camp Springs, MD USA. [Srinivasan, Ashwanth] Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, Div Meteorol & Oceanog, Miami, FL 33149 USA. [Hankin, Steve] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. [Cornillon, Peter] Univ Rhode Isl, Grad Sch Oceanog, Narragansett, RI 02882 USA. [Weisberg, Robert] Univ S Florida, Coll Marine Sci, St Petersburg, FL 33701 USA. [Barth, Alexander] Univ Liege, Liege, Belgium. [He, Ruoying] N Carolina State Univ, Dept Marine Earth & Atmospher Sci, Raleigh, NC 27695 USA. [Werner, Francisco; Wilkin, John] Rutgers State Univ, Inst Marine & Coastal Sci, New Brunswick, NJ 08903 USA. RP Chassignet, EP (reprint author), Florida State Univ, Ctr Ocean Atmospher Predict Studies, Tallahassee, FL 32306 USA. EM echassignet@coaps.fsu.edu RI Wilkin, John/E-5343-2011; Halliwell, George/B-3046-2011 OI Wilkin, John/0000-0002-5444-9466; Halliwell, George/0000-0003-4216-070X NR 24 TC 119 Z9 125 U1 2 U2 16 PU OCEANOGRAPHY SOC PI ROCKVILLE PA P.O. BOX 1931, ROCKVILLE, MD USA SN 1042-8275 J9 OCEANOGRAPHY JI Oceanography PD JUN PY 2009 VL 22 IS 2 SI SI BP 64 EP 75 DI 10.5670/oceanog.2009 PG 12 WC Oceanography SC Oceanography GA 457WC UT WOS:000266964200013 ER PT J AU Gentemann, CL Minnett, PJ Sienkiewicz, J DeMaria, M Cummings, J Jin, Y Doyle, JD Gramer, L Barron, CN Casey, KS Donlon, CJ AF Gentemann, Chelle L. Minnett, Peter J. Sienkiewicz, Joseph DeMaria, Mark Cummings, James Jin, Yi Doyle, James D. Gramer, Lew Barron, Charlie N. Casey, Kenneth S. Donlon, Craig J. TI MISST THE MULTI-SENSOR IMPROVED SEA SURFACE TEMPERATURE PROJECT SO OCEANOGRAPHY LA English DT Article ID COOL-SKIN AB Sea surface temperature (SST) measurements are vital to global weather prediction, climate change studies, fisheries management, and a wide range of other applications. Measurements are taken by several satellites carrying infrared and microwave radiometers, moored buoys, drifting buoys, and ships. Collecting all these measurements together and producing global maps of SST has been a difficult endeavor due in part to different data formats, data location and accessibility, and lack of measurement error estimates. The need for a uniform approach to SST measurements and estimation of measurement errors resulted in the formation of the international Global Ocean Data Assimilation Experiment (GODAE) High Resolution SST Pilot Project (GHRSST-PP). Projects were developed in Japan, Europe, and Australia. Simultaneously, in the United States, the Multi-sensor Improved SST (MISST) project was initiated. Five years later, the MISST project has produced satellite SST data from nine satellites in an identical format with ancillary information and estimates of measurement error. Use of these data in global SST analyses has been improved through research into modeling of the ocean surface skin layer and upper ocean diurnal heaing. These data and research results have been used by several groups within MISST to produce high-resolution global maps of SSTs, which have been shown to improve tropical cyclone prediction. Additionally, the new SSTs are now used operationally for marine weather warnings and forecasts. C1 [Gentemann, Chelle L.] Remote Sensing Syst, Santa Rosa, CA USA. [Minnett, Peter J.] Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, Miami, FL 33149 USA. [Sienkiewicz, Joseph] NOAA, Ocean Predict Ctr, Ocean Applicat Branch, Camp Springs, MD USA. [DeMaria, Mark] NOAA Natl Environm Satellite, Ctr Satellite Applicat & Res, Ft Collins, CO USA. [Cummings, James] USN, Res Lab, Div Oceanog, Monterey, CA USA. [Jin, Yi; Doyle, James D.] USN, Res Lab, Marine Meteorol Div, Monterey, CA USA. [Gramer, Lew] Univ Miami, Cooperat Inst Marine & Atmospher Studies, Miami, FL USA. [Barron, Charlie N.] USN, Div Oceanog, Stennis Space Ctr, MS USA. [Casey, Kenneth S.] NOAA, Natl Oceanog Data Ctr, Silver Spring, MD USA. [Donlon, Craig J.] Int Global High Resolut Sea Surface Temp Project, Exeter, Devon, England. RP Gentemann, CL (reprint author), Remote Sensing Syst, Santa Rosa, CA USA. EM gentemann@remss.com RI Gramer, Lewis/A-5620-2010; DeMaria, Mark/F-5583-2010; Casey, Kenneth/D-4065-2013; Barron, Charlie/C-1451-2008 OI Gramer, Lewis/0000-0003-4772-1991; Casey, Kenneth/0000-0002-6052-7117; NR 29 TC 14 Z9 15 U1 0 U2 4 PU OCEANOGRAPHY SOC PI ROCKVILLE PA P.O. BOX 1931, ROCKVILLE, MD USA SN 1042-8275 J9 OCEANOGRAPHY JI Oceanography PD JUN PY 2009 VL 22 IS 2 BP 76 EP 87 PG 12 WC Oceanography SC Oceanography GA 457WC UT WOS:000266964200014 ER PT J AU Cornillon, P Adams, J Blumenthal, MB Chassignet, E Davis, E Hankin, S Kinter, J Mendelssohn, R Potemra, JT Srinivasan, A Sirott, J AF Cornillon, Peter Adams, Jennifer Blumenthal, M. Benno Chassignet, Eric Davis, Ethan Hankin, Steve Kinter, James Mendelssohn, Roy Potemra, James T. Srinivasan, Ashwanth Sirott, Joseph TI NVODS AND THE DEVELOPMENT OF OPeNDAP SO OCEANOGRAPHY LA English DT Article AB The National Oceanographic Partnership Program (NOPP) funded a project to develop the foundation for a National Virtual Ocean Data System (NVODS) that has resulted in a robust data access framework for the exchange of oceanographic data (the Open source Project for a Network Data Access Protocol, or OPeNDAP) and a broad community of ocean data providers that remains vigorous and growing five years after NOPP funding ended. The project produced a number of "lessons learned" related to the design and implementation of distributed data systems that can inform other related efforts. These lessons are presented along with a brief overview of OPeNDAP and summaries of a number of projects that depend on OPeNDAP for data distribution. C1 [Cornillon, Peter] Univ Rhode Isl, Grad Sch Oceanog, Narragansett, RI 02882 USA. [Adams, Jennifer; Kinter, James] IGES, Ctr Ocean Land Atmosphere Studies, Calverton, MD USA. [Blumenthal, M. Benno] Columbia Univ, Int Res Inst Climate & Soc, Palisades, NY USA. [Chassignet, Eric] Florida State Univ, Ctr Ocean Atmospher Predict Studies, Tallahassee, FL 32306 USA. [Davis, Ethan] Univ Corporat Atmospheric Res, Boulder, CO USA. [Hankin, Steve; Sirott, Joseph] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. [Mendelssohn, Roy] NOAA, Natl Marine Fisheries Serv, SW Fisheries Sci Ctr, Div Environm Res, Pacific Grove, CA USA. [Kinter, James] Univ Hawaii, Sch Ocean & Earth Sci & Technol, Honolulu, HI 96822 USA. [Srinivasan, Ashwanth] Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, Miami, FL 33149 USA. RP Cornillon, P (reprint author), Univ Rhode Isl, Grad Sch Oceanog, Narragansett, RI 02882 USA. EM pcornillon@gso.uri.edu RI Kinter, James/A-8610-2015 OI Kinter, James/0000-0002-6277-0559 NR 3 TC 6 Z9 6 U1 1 U2 3 PU OCEANOGRAPHY SOC PI ROCKVILLE PA P.O. BOX 1931, ROCKVILLE, MD USA SN 1042-8275 J9 OCEANOGRAPHY JI Oceanography PD JUN PY 2009 VL 22 IS 2 SI SI BP 116 EP 127 DI 10.5670/oceanog.2009.43 PG 12 WC Oceanography SC Oceanography GA 457WC UT WOS:000266964200017 ER PT J AU Scholin, C Doucette, G Jensen, S Roman, B Pargett, D Marin, R Preston, C Jones, W Feldman, J Everlove, C Harris, A Alvarado, N Massion, E Birch, J Greenfield, D Vrijenhoek, R Mikulski, C Jones, K AF Scholin, Christopher Doucette, Gregory Jensen, Scott Roman, Brent Pargett, Douglas Marin, Roman, III Preston, Christina Jones, William Feldman, Jason Everlove, Cheri Harris, Adeline Alvarado, Nilo Massion, Eugene Birch, James Greenfield, Dianne Vrijenhoek, Robert Mikulski, Christina Jones, Kelly TI REMOTE DETECTION OF MARINE MICROBES, SMALL INVERTEBRATES, HARMFUL ALGAE, AND BIOTOXINS USING THE ENVIRONMENTAL SAMPLE PROCESSOR (ESP) SO OCEANOGRAPHY LA English DT Article ID DOMOIC ACID; MONTEREY BAY; CALIFORNIA; PROBES; LARVAE AB The advent of ocean observatories is creating unique opportunities for deploying novel sensor systems. We are exploring that potential through the development and application-of the Environmental Sample Processor (ESP). ESP is an electromechanical/fluidic system designed to collect discrete water samples, concentrate microorganisms, and automate application of molecular probe technologies. Development and application of ESP grew from extensive partnerships galvanized by the National Oceanographic Partnership Program. Near-real-time observations are currently achieved using low-density DNA probe and protein arrays. Filter-based sandwich hybridization methodology enables direct detection of ribosomal RNA sequences diagnostic for groups of bacteria and archaea, as well as a variety of invertebrates and harmful algal species. An antibody-based technique is used for detecting domoic acid, an algal biotoxin. To date, ESP has been deployed in ocean waters from the near surface to 1000 m. Shallow-water deployments demonstrated application of all four types of assays in single deployments lasting up to 30 days and provided the first remote detection of such phylogenetically diverse organisms and metabolites on one platform. Deep-water applications focused on detection of invertebrates associated with whale falls, using remotely operated vehicle-based operations lasting several days. Current work emphasizes incorporating a four-channel, real-time polymerase chain reaction module, extending operations to 4000-m water depth, and increasing deployment duration. C1 [Scholin, Christopher; Jensen, Scott; Roman, Brent; Pargett, Douglas; Marin, Roman, III; Preston, Christina; Everlove, Cheri; Alvarado, Nilo; Birch, James; Vrijenhoek, Robert] Monterey Bay Aquarium Res Inst, Moss Landing, CA USA. [Doucette, Gregory] NOAA, Natl Ocean Serv, Marine Biotoxins Program, Charleston, SC USA. [Jones, William] Univ S Carolina, Dept Environm Hlth Sci, Environm Genom Core Facil, Columbia, SC 29208 USA. [Greenfield, Dianne] Univ S Carolina, Belle Baruch Inst Marine & Coastal Sci, Columbia, SC 29208 USA. RP Scholin, C (reprint author), Monterey Bay Aquarium Res Inst, Moss Landing, CA USA. EM scholin@mbari.org NR 34 TC 62 Z9 67 U1 7 U2 30 PU OCEANOGRAPHY SOC PI ROCKVILLE PA P.O. BOX 1931, ROCKVILLE, MD USA SN 1042-8275 J9 OCEANOGRAPHY JI Oceanography PD JUN PY 2009 VL 22 IS 2 BP 158 EP 167 PG 10 WC Oceanography SC Oceanography GA 457WC UT WOS:000266964200020 ER PT J AU Dickey, T Bates, N Byrne, RH Chang, G Chavez, FP Feely, RA Hanson, AK Karl, DM Manov, D Moore, C Sabine, CL Wanninkhof, R AF Dickey, Tommy Bates, Nick Byrne, Robert H. Chang, Grace Chavez, Francisco P. Feely, Richard A. Hanson, Alfred K. Karl, David M. Manov, Derek Moore, Casey Sabine, Christopher L. Wanninkhof, Rik TI THE NOPP O-SCOPE AND MOSEAN PROJECTS ADVANCED SENSING FOR OCEAN OBSERVING SYSTEMS SO OCEANOGRAPHY LA English DT Article ID TESTBED MOORING SITE; TOTAL INORGANIC CARBON; IN-SITU; HIGH-RESOLUTION; VARIABILITY; SENSORS; SEAWATER; NITRATE; WATERS; BUOY AB The National Oceanographic Partnership Program (NOPP) consecutively sponsored the Ocean-Systems for Chemical, Optical, and Physical Experiments (O-SCOPE) and Multi-disciplinary Ocean Sensors for Environmental Analyses and Networks (MOSEAN) projects from 1998 through 2008. The O-SCOPE and MOSEAN projects focused on developing and testing new sensors and systems for autonomous, concurrent measurements of biological, chemical, optical, and physical variables from a diverse suite of stationary and mobile ocean platforms. Design considerations encompassed extended open-ocean and coastal deployments, instrument durability, biofouling mitigation, data accuracy and precision, near-real-time data telemetry, and economy-the latter being critical for widespread sensor and system utilization. The complementary O-SCOPE and MOSEAN projects increased ocean sensing and data telemetry capabilities for addressing many societally relevant problems such as global climate change, ocean carbon cycling and sequestration, acidification, eutrophication, anoxia, and ecosystem dynamics, including harmful algal blooms. NOPP support enabled O-SCOPE and MOSEAN to accelerate progress in achieving multiscale, multidisciplinary, sustained observations of the ocean environment. Importantly, both programs produced value-added scientific results, which demonstrated the utility of these new technologies. The NOPP framework fostered strong collaborations among academic, commercial, and government entities, and facilitated technology transfers to the general research community and to long-term observational and observatory programs. C1 [Dickey, Tommy] Univ Calif Santa Barbara, Dept Geog, Ocean Phys Lab, Santa Barbara, CA 93106 USA. [Bates, Nick] Bermuda Inst Ocean Sci, St Georges, Bermuda. [Byrne, Robert H.] Univ S Florida, Coll Marine Sci, St Petersburg, FL 33701 USA. [Chavez, Francisco P.] Monterey Bay Aquarium Res Inst, Moss Landing, CA USA. [Feely, Richard A.; Sabine, Christopher L.] NOAA, Pacific Marine Environm Lab, Carbon Grp, Seattle, WA 98115 USA. [Hanson, Alfred K.] SubChem Syst Inc, Narragansett, RI USA. [Karl, David M.] Univ Hawaii, Dept Oceanog, Honolulu, HI 96822 USA. [Moore, Casey] WET Labs Inc, Philomath, OR USA. [Wanninkhof, Rik] NOAA, Atlantic Oceanog & Meteorol Lab, Ocean Chem Div, Miami, FL 33149 USA. RP Dickey, T (reprint author), Univ Calif Santa Barbara, Dept Geog, Ocean Phys Lab, Santa Barbara, CA 93106 USA. EM tommy.dickey@opl.ucsb.edu NR 53 TC 7 Z9 7 U1 3 U2 15 PU OCEANOGRAPHY SOC PI ROCKVILLE PA P.O. BOX 1931, ROCKVILLE, MD USA SN 1042-8275 J9 OCEANOGRAPHY JI Oceanography PD JUN PY 2009 VL 22 IS 2 SI SI BP 168 EP 181 DI 10.5670/oceanog.2009.47 PG 14 WC Oceanography SC Oceanography GA 457WC UT WOS:000266964200021 ER PT J AU Chang, PS Jelenak, Z Sienkiewicz, JM Knabb, R Brennan, MJ Long, DG Freeberg, M AF Chang, Paul S. Jelenak, Zorana Sienkiewicz, Joseph M. Knabb, Richard Brennan, Michael J. Long, David G. Freeberg, Mark TI Operational Use and Impact of Satellite Remotely Sensed Ocean Surface Vector Winds in the Marine Warning and Forecasting Environment SO OCEANOGRAPHY LA English DT Article ID RESOLUTION AB In 2002, a National Oceanographic Partnership Program project was initiated with the ambitious objective of maximizing the use of currently and soon-to-be-available satellite ocean surface vector wind (OSVW) data, such as NASAs QuikSCAT scatterometer, in the operational weather forecasting and warning environment. This effort brought together people from the operational forecasting and satellite remote-sensing communities, academia, and the private sector. This diverse gathering of skill and experience yielded documentation of the impacts of these data in the operational short-term warning and forecasting environment of the National Oceanic and Atmospheric Administration's (NOAA's) National Weather Service, improvement in the use of these data in the public and private sectors, and the transition of promising research results into the operational environment. This project helped create momentum that has continued to grow long after the formal effort ended; today, NOAA uses QuikSCAT operationally and is investigating how to best establish a sustained satellite OSVW observing capability. C1 [Chang, Paul S.; Jelenak, Zorana] NOAA, NESDIS, Ctr Satellite Applicat & Res, NOAA Sci Ctr, Camp Springs, MD USA. [Sienkiewicz, Joseph M.] NOAA, NWS, NCEP, Ocean Predict Ctr, Camp Springs, MD USA. [Knabb, Richard] NOAA, NWS, Honolulu Weather Forecast Off, Honolulu, HI USA. [Brennan, Michael J.] NOAA, NWS, NCEP, Natl Hurricane Ctr, Miami, FL USA. [Long, David G.] Brigham Young Univ, BYU Ctr Remote Sensing, Provo, UT 84602 USA. [Long, David G.] Brigham Young Univ, Dept Elect & Comp Sci, Provo, UT 84602 USA. [Freeberg, Mark] Oceans & Coastal Environm Sensing Inc, Seattle, WA USA. RP Chang, PS (reprint author), NOAA, NESDIS, Ctr Satellite Applicat & Res, NOAA Sci Ctr, Camp Springs, MD USA. EM paul.s.chang@noaa.gov RI Jelenak, Zorana/F-5596-2010; Chang, Paul/F-5580-2010; Long, David/K-4908-2015 OI Jelenak, Zorana/0000-0003-0510-2973; Chang, Paul/0000-0001-5113-0938; Long, David/0000-0002-1852-3972 NR 28 TC 10 Z9 11 U1 0 U2 0 PU OCEANOGRAPHY SOC PI ROCKVILLE PA P.O. BOX 1931, ROCKVILLE, MD USA SN 1042-8275 J9 OCEANOGRAPHY JI Oceanography PD JUN PY 2009 VL 22 IS 2 BP 194 EP 207 PG 14 WC Oceanography SC Oceanography GA 457WC UT WOS:000266964200023 ER PT J AU Decker, CJ Reed, C AF Decker, Cynthia J. Reed, Colin TI The National Oceanographic Partnership Program A Decade of impacts on Oceanography SO OCEANOGRAPHY LA English DT Article ID OCEAN; BEHAVIOR; PREDATOR; MODEL; POPULATION; SYSTEM AB The National Oceanographic Partnership Program (NOPP) was created by the Fiscal Year 1997 Defense Authorization Act. It called for the establishment of a partnership program to promote the national goals of assuring national security, advancing economic development, protecting quality of life, and strengthening science education and communication through improved knowledge of the ocean. Fifteen US federal agencies comprise this partnership, which has expended more than $295M over ten years on a variety of activities. NOPP has been a true partnership among equals that has substantially moved the United States forward in the areas of ocean research, operations, technology, education, and natural resource management. NOPPs funding requirements have spurred the ocean research and education communities to develop strong, long-term collaborations among different sectors-academia, government, industry, and nongovernmental organizations. NOPP has allowed agencies to leverage their funds, increasing the impact of individual agency investment and accelerating the agencies' abilities to meet their high-priority goals. This leveraged investment results in more high-priority tasks getting done in the same time period than would occur if each agency were to fund the work individually. The combination of enhanced, effective partnerships among both funders and performers has resulted in accelerated research in some areas and a stronger voice for oceanography in the research and education Communities. This article provides a history of NOPP. It also identifies and discusses specific areas in which NOPP involvement and/or influence has led to significant accomplishment, both through funded research and through intellectual stimulation and inspiration. C1 [Decker, Cynthia J.] Natl Ocean & Atmospher Adm Sci Advisory Board, Silver Spring, MD USA. [Reed, Colin] Consortium Ocean Leadership, Natl Oceanog Partnership Program Off, Washington, DC USA. RP Decker, CJ (reprint author), Natl Ocean & Atmospher Adm Sci Advisory Board, Silver Spring, MD USA. EM cynthia.decker@nooo.gov NR 52 TC 1 Z9 1 U1 0 U2 2 PU OCEANOGRAPHY SOC PI ROCKVILLE PA P.O. BOX 1931, ROCKVILLE, MD USA SN 1042-8275 J9 OCEANOGRAPHY JI Oceanography PD JUN PY 2009 VL 22 IS 2 SI SI BP 208 EP 227 PG 20 WC Oceanography SC Oceanography GA 457WC UT WOS:000266964200024 ER PT J AU Parker, BA Christensen, TRL Heron, SF Morgan, JA Eakin, CM AF Parker, Britt-Anne Christensen, Tyler R. L. Heron, Scott F. Morgan, Jessica A. Eakin, C. Mark TI A Classroom Activity Using Satellite Sea Surface Temperatures to Predict Coral Bleaching SO OCEANOGRAPHY LA English DT Editorial Material ID CLIMATE-CHANGE; REEFS; STRESS C1 [Parker, Britt-Anne; Christensen, Tyler R. L.; Morgan, Jessica A.] NOAA Coral Reef Watch, IM Syst Grp, Silver Spring, MD USA. [Heron, Scott F.] NOAA Coral Reef Watch, Townsville, Qld, Australia. RP Parker, BA (reprint author), NOAA Coral Reef Watch, IM Syst Grp, Silver Spring, MD USA. EM britt.parker@noaa.gov RI Parker, Britt/E-7925-2011; Morgan, Jessica/E-7926-2011; Christensen, Tyler/E-7922-2011; Heron, Scott/E-7928-2011; Eakin, C. Mark/F-5585-2010 NR 16 TC 0 Z9 0 U1 0 U2 2 PU OCEANOGRAPHY SOC PI ROCKVILLE PA P.O. BOX 1931, ROCKVILLE, MD USA SN 1042-8275 J9 OCEANOGRAPHY JI Oceanography PD JUN PY 2009 VL 22 IS 2 BP 252 EP 257 PG 6 WC Oceanography SC Oceanography GA 457WC UT WOS:000266964200028 ER PT J AU Gao, GJ Lehan, JP Zhang, WW Griesmann, U Soons, JA AF Gao, Guangjun Lehan, John P. Zhang, William W. Griesmann, Ulf Soons, Johannes A. TI Computer-generated hologram cavity interferometry test for large x-ray mirror mandrels: design SO OPTICAL ENGINEERING LA English DT Article DE computer-generated hologram; mandrel; x-ray optics; optical testing; interferometry ID OBLIQUE-INCIDENCE INTERFEROMETER; NON-OPTICAL SURFACES AB A glancing-incidence interferometric test for large x-ray mirror mandrels, using two computer-generated holograms (CGHs), is described. The two CGHs are used to form a double-pass glancing-incidence system. One layout of the CGH-cavity glancing-incidence interferometer is studied and factors relating to its design are analyzed. A semianalytical expression for the phase function is derived that avoids high-order ripple errors and improves the efficiency of the CGH pattern generation. A system of coarse and fine fiducials for establishing the CGH-cavity and aligning the tested mandrel is discussed. Compared with traditional measurement devices, such as coordinate measuring machines (CMMs) or other scanning metrology systems, the CGH-cavity glancing-incidence interferometer can measure a mandrel surface without mechanical contact, at a high spatial sampling frequency, with lower uncertainty, and at high speed. (C) 2009 Society of Photo-Optical Instrumentation Engineers. [DOI: 10.1117/1.3153303] C1 [Gao, Guangjun; Griesmann, Ulf; Soons, Johannes A.] NIST, Mfg Engn Lab, Gaithersburg, MD 20899 USA. [Lehan, John P.; Zhang, William W.] NASA, Goddard Space Flight Ctr, Greenbelt, MD 20770 USA. [Lehan, John P.] Univ Maryland, Dept Phys, Baltimore, MD 21250 USA. RP Gao, GJ (reprint author), NIST, Mfg Engn Lab, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM Guangjun.gao@nist.gov FU NASA Goddard Space Flight Center FX The authors would like to thank the Innovative Partnership Program at NASA Goddard Space Flight Center for supporting a portion of this work. NR 16 TC 1 Z9 1 U1 0 U2 0 PU SPIE-SOC PHOTOPTICAL INSTRUMENTATION ENGINEERS PI BELLINGHAM PA 1000 20TH ST, PO BOX 10, BELLINGHAM, WA 98225 USA SN 0091-3286 J9 OPT ENG JI Opt. Eng. PD JUN PY 2009 VL 48 IS 6 AR 063602 DI 10.1117/1.3153303 PG 11 WC Optics SC Optics GA 477AE UT WOS:000268487500007 ER PT J AU Sandberg, RL Raymondson, DA La-o-Vorakiat, C Paul, A Raines, KS Miao, J Murnane, MM Kapteyn, HC Schlotter, WF AF Sandberg, R. L. Raymondson, D. A. La-o-Vorakiat, C. Paul, A. Raines, K. S. Miao, J. Murnane, M. M. Kapteyn, H. C. Schlotter, W. F. TI Tabletop soft-x-ray Fourier transform holography with 50 nm resolution SO OPTICS LETTERS LA English DT Article ID DIFFRACTION MICROSCOPY; COHERENT; WAVELENGTHS; LIGHT AB We present what we believe to be the first implementation of Fourier transform (FT) holography using a tabletop coherent x-ray source. By applying curvature correction to compensate for the large angles inherent in high-NA coherent imaging, we achieve image resolution of 89 nm using high-harmonic beams at a wavelength of 29 nm. Moreover, by combining holography with iterative phase retrieval, we improve the image resolution to <53 nm. We also demonstrate that FT holography can be used effectively with short exposure times of 30 s. This technique will enable biological and materials microscopy with simultaneously high spatial and temporal resolution on a tabletop soft-x-ray source. (C) 2009 Optical Society of America C1 [Sandberg, R. L.; Raymondson, D. A.; La-o-Vorakiat, C.; Paul, A.; Murnane, M. M.; Kapteyn, H. C.] Univ Colorado, Dept Phys, Boulder, CO 80309 USA. [Sandberg, R. L.; Raymondson, D. A.; La-o-Vorakiat, C.; Paul, A.; Murnane, M. M.; Kapteyn, H. C.] Univ Colorado, JILA, Boulder, CO 80309 USA. [Sandberg, R. L.; Raymondson, D. A.; La-o-Vorakiat, C.; Paul, A.; Murnane, M. M.; Kapteyn, H. C.] Natl Inst Stand & Technol, Boulder, CO 80309 USA. [Raines, K. S.; Miao, J.] Univ Calif Los Angeles, Dept Phys & Astron, Los Angeles, CA 90095 USA. [Raines, K. S.; Miao, J.] Univ Calif Los Angeles, Calif NanoSyst Inst, Los Angeles, CA 90095 USA. [Schlotter, W. F.] SLAC Natl Accelerator Lab, Stanford Synchrotron Radiat Lab, Menlo Pk, CA USA. [Schlotter, W. F.] Univ Hamburg, Inst Expt Phys, D-22761 Hamburg, Germany. RP Sandberg, RL (reprint author), Univ Colorado, Dept Phys, Boulder, CO 80309 USA. EM richard.sondberg@colorado.edu RI Sandberg, Richard/F-8790-2011; Kapteyn, Henry/H-6559-2011 OI Kapteyn, Henry/0000-0001-8386-6317 FU National Science Foundation (NSF); U.S. Department of Energy Office of Basic Energy Sciences (DOE-BES) FX The authors gratefully acknowledge funding from the National Science Foundation (NSF) and the U.S. Department of Energy Office of Basic Energy Sciences (DOE-BES). We thank Y. Liu and F. Salmassi for the multilayer mirrors, and we thank the JILA Instrument Shop. NR 21 TC 53 Z9 54 U1 1 U2 10 PU OPTICAL SOC AMER PI WASHINGTON PA 2010 MASSACHUSETTS AVE NW, WASHINGTON, DC 20036 USA SN 0146-9592 J9 OPT LETT JI Opt. Lett. PD JUN 1 PY 2009 VL 34 IS 11 BP 1618 EP 1620 PG 3 WC Optics SC Optics GA 463AR UT WOS:000267401200002 PM 19488126 ER PT J AU Malkova, N Hromada, I Wang, XS Bryant, G Chen, ZG AF Malkova, Natalia Hromada, Ivan Wang, Xiaosheng Bryant, Garnett Chen, Zhigang TI Observation of optical Shockley-like surface states in photonic superlattices SO OPTICS LETTERS LA English DT Article ID WAVE-GUIDE ARRAYS; SOLITONS AB We provide what we believe to be the first experimental demonstration of linear Shockley-like surface states in an optically induced semi-infinite photonic superlattice. Such surface states appear only when the induced superlattice consisting of alternating strong and weak bonds is terminated properly at the surface. Our experimental results are in good agreement with our theoretical analysis. (C) 2009 Optical Society of America C1 [Malkova, Natalia; Hromada, Ivan; Wang, Xiaosheng; Chen, Zhigang] San Francisco State Univ, Dept Phys & Astron, San Francisco, CA 94132 USA. [Malkova, Natalia; Bryant, Garnett] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. [Malkova, Natalia; Bryant, Garnett] Univ Maryland, Joint Quantum Inst, Gaithersburg, MD 20899 USA. [Chen, Zhigang] Nankai Univ, TEDA Appl Phys Sch, Tianjin 300457, Peoples R China. RP Chen, ZG (reprint author), San Francisco State Univ, Dept Phys & Astron, San Francisco, CA 94132 USA. EM zhigang@sfsu.edu RI Chen, Zhigang/B-2112-2010 FU National Science Foundation (NSF); U.S. Air Force Office of Scientific Research (AFOSR); 973 Program FX This work was supported by the National Science Foundation (NSF), the U.S. Air Force Office of Scientific Research (AFOSR), and the 973 Program. NR 18 TC 66 Z9 66 U1 2 U2 8 PU OPTICAL SOC AMER PI WASHINGTON PA 2010 MASSACHUSETTS AVE NW, WASHINGTON, DC 20036 USA SN 0146-9592 J9 OPT LETT JI Opt. Lett. PD JUN 1 PY 2009 VL 34 IS 11 BP 1633 EP 1635 PG 3 WC Optics SC Optics GA 463AR UT WOS:000267401200007 PM 19488131 ER PT J AU Biercuk, MJ Uys, H VanDevender, AP Shiga, N Itano, WM Bollinger, JJ AF Biercuk, Michael J. Uys, Hermann VanDevender, Aaron P. Shiga, Nobuyasu Itano, Wayne M. Bollinger, John J. TI Experimental Uhrig dynamical decoupling using trapped ions SO PHYSICAL REVIEW A LA English DT Article DE beryllium; information theory; noise; particle traps; quantum computing ID QUANTUM-SYSTEMS; PLASMAS; DECOHERENCE; ROTATION AB We present a detailed experimental study of the Uhrig dynamical decoupling (UDD) sequence in a variety of noise environments. Our qubit system consists of a crystalline array of (9)Be(+) ions confined in a Penning trap. We use an electron-spin-flip transition as our qubit manifold and drive qubit rotations using a 124 GHz microwave system. We study the effect of the UDD sequence in mitigating phase errors and compare against the well known Carr-Purcell-Meiboom-Gill-style multipulse spin echo as a function of pulse number, rotation axis, noise spectrum, and noise strength. Our results agree well with theoretical predictions for qubit decoherence in the presence of classical phase noise, accounting for the effect of finite-duration pi pulses. Finally, we demonstrate that the Uhrig sequence is more robust against systematic over- or under-rotation and detuning errors than is multipulse spin echo, despite the precise prescription for pulse timing in UDD. C1 [Biercuk, Michael J.; Uys, Hermann; VanDevender, Aaron P.; Shiga, Nobuyasu; Itano, Wayne M.; Bollinger, John J.] NIST, Div Time & Frequency, Boulder, CO 80305 USA. [Biercuk, Michael J.] Georgia Inst Technol, Atlanta, GA 30332 USA. [Uys, Hermann] CSIR, ZA-0001 Pretoria, South Africa. RP Biercuk, MJ (reprint author), NIST, Div Time & Frequency, Boulder, CO 80305 USA. EM biercuk@boulder.nist.gov RI Biercuk, Michael/B-4768-2010 FU IARPA; NIST; Georgia Tech; CSIR FX The authors thank L. Cywinski, S. Das Sarma, V. V. Dobrovitski, X. Hu, E. Knill, S. Lyon, G. Uhrig, and W. Witzel for useful discussions. We also thank Y. Colombe, D. Hanneke, and D. J. Wineland for their comments on the paper. We acknowledge research funding from IARPA and NIST Quantum Information Program. M. J. B. acknowledges support from IARPA and Georgia Tech and H. U. acknowledges support from CSIR. NR 33 TC 72 Z9 72 U1 0 U2 6 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1050-2947 J9 PHYS REV A JI Phys. Rev. A PD JUN PY 2009 VL 79 IS 6 AR 062324 DI 10.1103/PhysRevA.79.062324 PG 12 WC Optics; Physics, Atomic, Molecular & Chemical SC Optics; Physics GA 466XZ UT WOS:000267700100062 ER PT J AU Lin, YJ Perry, AR Compton, RL Spielman, IB Porto, JV AF Lin, Y. -J. Perry, A. R. Compton, R. L. Spielman, I. B. Porto, J. V. TI Rapid production of Rb-87 Bose-Einstein condensates in a combined magnetic and optical potential SO PHYSICAL REVIEW A LA English DT Article DE atom-photon collisions; Bose-Einstein condensation; magneto-optical effects; radiation pressure; rubidium ID ATOMIC-BEAM; NEUTRAL ATOMS; SODIUM ATOMS; TRAP; CANDLESTICK; GAS AB We describe an apparatus for quickly and simply producing Rb-87 Bose-Einstein condensates. It is based on a magnetic quadrupole trap and a red-detuned optical dipole trap. We collect atoms in a magneto-optical trap (MOT) and then capture the atoms in a magnetic quadrupole trap and force rf evaporation. We then transfer the resulting cold dense cloud into a spatially mode-matched optical dipole trap by lowering the quadrupole field gradient to below gravity. This technique combines the efficient capture of atoms from a MOT into a magnetic trap with the rapid evaporation of optical dipole traps; the approach is insensitive to the peak quadrupole gradient and the precise trapping beam waist. Our system reliably produces a condensate with N approximate to 2x10(6) atoms every 16 s. C1 [Lin, Y. -J.] NIST, Joint Quantum Inst, Gaithersburg, MD 20899 USA. Univ Maryland, Gaithersburg, MD 20899 USA. RP Lin, YJ (reprint author), NIST, Joint Quantum Inst, Gaithersburg, MD 20899 USA. EM ian.spielman@nist.gov; trey@nist.gov RI Perry, Abigail/C-6994-2011; Lin, Yu-Ju/F-7917-2012 FU ONR; ODNI; ARO; DARPA OLE program; NSF; NIST/NRC FX This work was partially supported by ONR, ODNI, ARO with funds from the DARPA OLE program, and the NSF through the JQI Physics Frontier Center. R. L. C. acknowledges supports from NIST/NRC. NR 26 TC 93 Z9 93 U1 1 U2 17 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1050-2947 J9 PHYS REV A JI Phys. Rev. A PD JUN PY 2009 VL 79 IS 6 AR 063631 DI 10.1103/PhysRevA.79.063631 PG 8 WC Optics; Physics, Atomic, Molecular & Chemical SC Optics; Physics GA 466XZ UT WOS:000267700100147 ER PT J AU Spielman, IB AF Spielman, I. B. TI Raman processes and effective gauge potentials SO PHYSICAL REVIEW A LA English DT Article DE atom-photon collisions; ground states; rubidium; vortices; Zeeman effect ID BOSE-EINSTEIN CONDENSATION; TONKS-GIRARDEAU GAS; ULTRACOLD ATOMS; QUANTUM AB A technique is described by which light-induced gauge potentials allow systems of ultracold neutral atoms to behave like charged particles in a magnetic field. Here, atoms move in a uniform laser field with a spatially varying Zeeman shift and experience an effective magnetic field. This technique is applicable for atoms with two or more internal ground states. Finally, an explicit model of the system using a single-mode two-dimensional Gross-Pitaevskii equation yields the expected vortex lattice. C1 [Spielman, I. B.] Univ Maryland, Gaithersburg, MD 20899 USA. RP Spielman, IB (reprint author), Natl Inst Stand & Technol, Joint Quantum Inst, Gaithersburg, MD 20899 USA. FU ONR; OLE program of DARPA; NSF FX I am deeply appreciative of conversations with V. Galitski, Y.-J. Lin, W. D. Phillips, J.V. Porto, J.Y. Vaishnav, C. A. R. Sa de Melo, and I. I. Satija, and acknowledge the financial support of ONR, OLE program of DARPA, and the NSF through the JQI Physics Frontier Center. NR 25 TC 116 Z9 117 U1 1 U2 12 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1050-2947 J9 PHYS REV A JI Phys. Rev. A PD JUN PY 2009 VL 79 IS 6 AR 063613 DI 10.1103/PhysRevA.79.063613 PG 7 WC Optics; Physics, Atomic, Molecular & Chemical SC Optics; Physics GA 466XZ UT WOS:000267700100129 ER PT J AU Gehring, PM Hiraka, H Stock, C Lee, SH Chen, W Ye, ZG Vakhrushev, SB Chowdhuri, Z AF Gehring, P. M. Hiraka, H. Stock, C. Lee, S. -H. Chen, W. Ye, Z. -G. Vakhrushev, S. B. Chowdhuri, Z. TI Reassessment of the Burns temperature and its relationship to the diffuse scattering, lattice dynamics, and thermal expansion in relaxor Pb(Mg1/3Nb2/3)O-3 SO PHYSICAL REVIEW B LA English DT Article DE lattice constants; lead compounds; magnesium compounds; neutron diffraction; phonons; relaxor ferroelectrics; thermal expansion ID GLASSY POLARIZATION BEHAVIOR; X-RAY-SCATTERING; NEUTRON-SCATTERING; FERROELECTRIC PBMG1/3NB2/3O3; PHASE-TRANSITIONS; LEAD MAGNONIOBATE; SINGLE-CRYSTALS; ELECTRIC-FIELD; SOFT MODE; PMN AB We have used neutron scattering techniques that probe time scales from 10(-12) to 10(-9) s to characterize the diffuse scattering and low-energy lattice dynamics in single crystals of the relaxor PbMg1/3Nb2/3O3 (PMN) from 10 to 900 K. Our study extends far below T-c=213 K, where long-range ferroelectric correlations have been reported under field-cooled conditions, and well above the nominal Burns temperature T-d approximate to 620 K, where optical measurements suggest the development of short-range polar correlations known as "polar nanoregions" (PNR). We observed two distinct types of diffuse scattering. The first is weak, relatively temperature independent, persists to at least 900 K, and forms bow-tie-shaped patterns in reciprocal space centered on (h00) Bragg peaks. We associate this primarily with chemical short-range order. The second is strong, temperature dependent, and forms butterfly-shaped patterns centered on (h00) Bragg peaks. This diffuse scattering has been attributed to the PNR because it responds to an electric field and vanishes near T-d approximate to 620 K when measured with thermal neutrons. Surprisingly, it vanishes at 420 K when measured with cold neutrons, which provide approximately four times superior energy resolution. That this onset temperature depends so strongly on the instrumental energy resolution indicates that the diffuse scattering has a quasielastic character and demands a reassessment of the Burns temperature T-d. Neutron backscattering measurements made with 300 times better energy resolution confirm the onset temperature of 420 +/- 20 K. The energy width of the diffuse scattering is resolution limited, indicating that the PNR are static on time scales of at least 2 ns between 420 and 10 K. Transverse acoustic (TA) phonon lifetimes, which are known to decrease dramatically for wave vectors q approximate to 0.2 A degrees(-1) and T-c < T < T-d, are temperature independent up to 900 K for q close to the zone center. This motivates a physical picture in which sufficiently long-wavelength TA phonons average over the PNR; only those TA phonons having wavelengths comparable to the size of the PNR are affected. Finally, the PMN lattice constant changes by less than 0.001 A degrees below 300 K but expands rapidly at a rate of 2.5x10(-5) K-1 at high temperature. These disparate regimes of low and high thermal expansions bracket the revised value of T-d, which suggests the anomalous thermal expansion results from the condensation of static PNR. C1 [Gehring, P. M.; Lee, S. -H.; Chowdhuri, Z.] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Hiraka, H.] Brookhaven Natl Lab, Dept Phys, Upton, NY 11973 USA. [Hiraka, H.] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan. [Stock, C.] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England. [Chen, W.; Ye, Z. -G.] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada. [Vakhrushev, S. B.] AF Ioffe Phys Tech Inst, St Petersburg 194021, Russia. RP Gehring, PM (reprint author), Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. RI Vakhrushev, Sergey/A-9855-2011; OI Vakhrushev, Sergey/0000-0003-4867-1404; Gehring, Peter/0000-0002-9236-2046 NR 87 TC 68 Z9 69 U1 3 U2 34 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 2469-9950 EI 2469-9969 J9 PHYS REV B JI Phys. Rev. B PD JUN PY 2009 VL 79 IS 22 AR 224109 DI 10.1103/PhysRevB.79.224109 PG 14 WC Physics, Condensed Matter SC Physics GA 466XS UT WOS:000267699300034 ER PT J AU Leighton, C Stauffer, DD Huang, Q Ren, Y El-Khatib, S Torija, MA Wu, J Lynn, JW Wang, L Frey, NA Srikanth, H Davies, JE Liu, K Mitchell, JF AF Leighton, C. Stauffer, D. D. Huang, Q. Ren, Y. El-Khatib, S. Torija, M. A. Wu, J. Lynn, J. W. Wang, L. Frey, N. A. Srikanth, H. Davies, J. E. Liu, Kai Mitchell, J. F. TI Coupled structural/magnetocrystalline anisotropy transitions in the doped perovskite cobaltite Pr1-xSrxCoO3 SO PHYSICAL REVIEW B LA English DT Article DE antiferromagnetic materials; doping profiles; magnetic anisotropy; magnetic transitions; magnetisation; praseodymium compounds; solid-state phase transformations; spin systems; strontium compounds ID MAGNETIC-PROPERTIES; SPIN DYNAMICS; MANGANITES; TRANSPORT; MULTIFERROICS; FERROELECTRICITY; CRYSTAL; PR; ND; LN AB Years of intensive work on perovskite manganites has led to a detailed understanding of the phenomena that emerge from competition between the electronic and lattice degrees of freedom in these correlated electron systems. It is well understood that the related cobaltites provide an additional spin-state degree of freedom. Here, we use the magnetic properties of a particular cobaltite, Pr1-xSrxCoO3, to demonstrate the vital role played by a further ingredient often negligible in manganites; magnetocrystalline anisotropy. Pr1-xSrxCoO3 exhibits an anomalous "double magnetic transition" that cannot be ascribed to a spin-state transition or the usual charge/orbital/antiferromagnetic ordering and has thus far evaded explanation. We show that this is actually due to a coupled structural/magnetocrystalline anisotropy transition driven, in this case, by Pr-O hybridization. The results point to the existence of a distinct class of phenomena in the cobaltites due to the unique interplay between structure and magnetic anisotropy. C1 [Leighton, C.; Stauffer, D. D.; El-Khatib, S.; Torija, M. A.; Wu, J.; Wang, L.] Univ Minnesota, Dept Chem Engn & Mat Sci, Minneapolis, MN 55455 USA. [Huang, Q.; El-Khatib, S.; Lynn, J. W.] Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Ren, Y.] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA. [Frey, N. A.; Srikanth, H.] Univ S Florida, Dept Phys, Tampa, FL 33620 USA. [Davies, J. E.; Liu, Kai] Univ Calif Davis, Dept Phys, Davis, CA 95616 USA. [Mitchell, J. F.] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA. RP Leighton, C (reprint author), Univ Minnesota, Dept Chem Engn & Mat Sci, 421 Washington Ave SE, Minneapolis, MN 55455 USA. EM leighton@umn.edu RI Davies, Joseph/C-4384-2008; Liu, Kai/B-1163-2008; Wang, Lan/B-6990-2011; OI Davies, Joseph/0000-0001-5727-2371; Liu, Kai/0000-0001-9413-6782; Wang, Lan/0000-0001-7124-2718; Wu, Jianzhong/0000-0002-4582-5941 NR 44 TC 32 Z9 32 U1 0 U2 18 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1098-0121 J9 PHYS REV B JI Phys. Rev. B PD JUN PY 2009 VL 79 IS 21 AR 214420 DI 10.1103/PhysRevB.79.214420 PG 7 WC Physics, Condensed Matter SC Physics GA 466XR UT WOS:000267699200081 ER PT J AU Swainson, IP Stock, C Gehring, PM Xu, GY Hirota, K Qiu, Y Luo, H Zhao, X Li, JF Viehland, D AF Swainson, I. P. Stock, C. Gehring, P. M. Xu, Guangyong Hirota, K. Qiu, Y. Luo, H. Zhao, X. Li, J. -F. Viehland, D. TI Soft phonon columns on the edge of the Brillouin zone in the relaxor PbMg1/3Nb2/3O3 SO PHYSICAL REVIEW B LA English DT Article ID INELASTIC NEUTRON-SCATTERING; LEAD MAGNESIUM NIOBATE; X-RAY-SCATTERING; LATTICE-DYNAMICS; SINGLE-CRYSTALS; PHASE-TRANSITIONS; FERROELECTRIC PBMG1/3NB2/3O3; PEROVSKITE STRUCTURE; PMN; PB(MG1/3NB2/3)O-3 AB We report lattice-dynamical measurements, made using neutron inelastic-scattering methods, of the relaxor perovskite PbMg1/3Nb2/3O3 (PMN) at momentum transfers near the edge of the Brillouin zone. Unusual "columns" of phonon scattering that are localized in momentum, but extended in energy, are seen at both high-symmetry points along the zone edge: (Q) over right arrowR= {1/2,1/2,1/2} and (Q) over right arrowM={1/2,1/2,0}. These columns soften at similar to 400 K which is similar to the onset temperature of the zone-center diffuse scattering, indicating a competition between ferroelectric and antiferroelectric distortions. We propose a model for the atomic displacements associated with these phonon modes that is based on a combination of structure factors and group theoretical analysis. This analysis suggests that the scattering is not from tilt modes (rotational modes of oxygen octahedra), but from zone-boundary optic modes that are associated with the displacement of Pb2+ and O2- ions. Whereas similar columns of scattering have been reported in metallic and (less commonly) molecular systems, they are unusual in insulating materials, particularly in ferroelectrics; therefore, the physical origin of this inelastic feature in PMN is unknown. We speculate that the underlying disorder contributes to this unique anomaly. C1 [Swainson, I. P.] CNR, Chalk River, ON KOJ 1JO, Canada. [Stock, C.] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England. [Gehring, P. M.; Qiu, Y.] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Xu, Guangyong] Brookhaven Natl Lab, Dept Condensed Matter Phys & Mat Sci, Upton, NY 11973 USA. [Hirota, K.] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan. [Qiu, Y.] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. [Luo, H.; Zhao, X.] Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 201800, Peoples R China. [Li, J. -F.; Viehland, D.] Virginia Tech, Dept Mat Sci & Engn, Blacksburg, VA 24061 USA. RP Swainson, IP (reprint author), CNR, Chalk River, ON KOJ 1JO, Canada. RI Xu, Guangyong/A-8707-2010; Zhao, Xiangyong/A-1743-2013; OI Xu, Guangyong/0000-0003-1441-8275; Gehring, Peter/0000-0002-9236-2046 FU Natural Science and Engineering Research Council of Canada (NSERC); U.S. National Science Foundation [DMR-0306940, DMR-9986442]; U.S. DOE [DE-AC0298CH10886]; Office of Naval Research [N00014-99-1-0738]; National Science Foundation [DMR-045467]; National Research Council (NRC) of Canada FX We thank R. Cowley, M. Gutmann, and J. Lynn for helpful discussions and B. Clow, T. Dodd, L. McEwan, R. Sammon, M. Watson, and T. Whan for technical support during experiments. We acknowledge financial support from the Natural Science and Engineering Research Council of Canada (NSERC), the U.S. National Science Foundation through Contract No. DMR-0306940 and No. DMR-9986442, the U.S. DOE under Contract No. DE-AC0298CH10886, and the Office of Naval Research under Grant No. N00014-99-1-0738. This work utilized facilities supported in part by the National Science Foundation under Agreement No. DMR-045467. Part of this work was also funded under the Graduate Supplement Scholarship program from the National Research Council (NRC) of Canada. NR 95 TC 30 Z9 30 U1 1 U2 16 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 2469-9950 EI 2469-9969 J9 PHYS REV B JI Phys. Rev. B PD JUN PY 2009 VL 79 IS 22 AR 224301 DI 10.1103/PhysRevB.79.224301 PG 14 WC Physics, Condensed Matter SC Physics GA 466XS UT WOS:000267699300049 ER PT J AU Phelps, AV AF Phelps, A. V. TI Energetic ion, atom, and molecule reactions and excitation in low-current H-2 discharges: Model SO PHYSICAL REVIEW E LA English DT Review ID BALMER-ALPHA-EMISSION; HYDROGEN GLOW-DISCHARGE; DIFFERENTIAL CROSS-SECTIONS; HIGH-ELECTRIC-FIELD; GAS-DENSITY RATIOS; LOW-PRESSURE; CHARGE-EXCHANGE; LYMAN-ALPHA; COLLISIONAL DEACTIVATION; VIBRATIONAL-EXCITATION AB Models of the elastic, inelastic, and reactive collisions of energetic hydrogen ions, atoms, and molecules are developed for predicting H-alpha and H-2 near-uv emission, H-alpha Doppler profiles, and ion energy distributions for low-pressure, low-current discharges in H2. The model is applied to spatially uniform electric field E to gas density N ratios of 350 Td <= E/N <= 45 kTd and 8 x 10(19) <= Nd <= 10 x 10(21) m(-2), where d is the electrode separation and 1 Td = 10(-21) V m(2). Mean ion energies at the cathode are 5-1500 eV. Cross sections for H+, H-2(+), H-3(+), H, H-2, and excited H(n = 3) collisions with H-2 and reflection probabilities from electrodes are updated and summarized. Spatial and energy distributions of ions and fast neutrals are calculated using a "multibeam" technique. At the lower E/N and Nd, electron excitation of H-alpha dominates near the anode. Excitation of H-alpha by fast H atoms near the cathode increases rapidly with pressure through a multistep reaction sequence. At higher E/N, fast H atoms produced at the cathode surface excite much of the H-alpha. The model agrees with experimental spatial distributions of H-alpha emission and Doppler profiles. Ion energy distributions agree with experiments only for H-2(+). Cross sections are derived for excitation of the near-uv continuum of H-2 by H atoms. C1 [Phelps, A. V.] Natl Inst Stand & Technol, JILA, Boulder, CO 80309 USA. [Phelps, A. V.] Univ Colorado, Boulder, CO 80309 USA. RP Phelps, AV (reprint author), Natl Inst Stand & Technol, JILA, Boulder, CO 80309 USA. NR 133 TC 36 Z9 38 U1 2 U2 8 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1539-3755 J9 PHYS REV E JI Phys. Rev. E PD JUN PY 2009 VL 79 IS 6 AR 066401 DI 10.1103/PhysRevE.79.066401 PN 2 PG 19 WC Physics, Fluids & Plasmas; Physics, Mathematical SC Physics GA 466XP UT WOS:000267698900061 PM 19658606 ER PT J AU Butler, J Montzka, S AF Butler, J. Montzka, S. TI The ozone hole: Anthropogenic sources of methyl bromide and recent data on atmospheric methyl bromide levels SO PHYTOPATHOLOGY LA English DT Meeting Abstract CT Annual Meeting of the American-Phytopathology-Society CY AUG 01-05, 2009 CL Portland, OR SP Amer Phytopathol Soc C1 [Butler, J.; Montzka, S.] Natl Ocean & Atmospher Adm, Boulder, CO USA. NR 0 TC 0 Z9 0 U1 0 U2 0 PU AMER PHYTOPATHOLOGICAL SOC PI ST PAUL PA 3340 PILOT KNOB ROAD, ST PAUL, MN 55121 USA SN 0031-949X J9 PHYTOPATHOLOGY JI Phytopathology PD JUN PY 2009 VL 99 IS 6 BP S173 EP S173 PG 1 WC Plant Sciences SC Plant Sciences GA 447SY UT WOS:000266213301021 ER PT J AU Peggs, GN Maropoulos, PG Hughes, EB Forbes, AB Robson, S Ziebart, M Muralikrishnan, B AF Peggs, G. N. Maropoulos, P. G. Hughes, E. B. Forbes, A. B. Robson, S. Ziebart, M. Muralikrishnan, B. TI Recent developments in large-scale dimensional metrology SO PROCEEDINGS OF THE INSTITUTION OF MECHANICAL ENGINEERS PART B-JOURNAL OF ENGINEERING MANUFACTURE LA English DT Review DE dimensional metrology; distance measurement; measurement uncertainty ID COORDINATE MEASURING MACHINE; SURFACE MEASURING MACHINE; TRACKING INTERFEROMETER; CULTURAL-HERITAGE; SELF-CALIBRATION; MESH GENERATION; DATA REDUCTION; LASER SCANNER; RANGE IMAGES; 3D DATA AB With ever-more demanding requirements for the accurate manufacture of large components, dimensional measuring techniques are becoming progressively more sophisticated. This review describes some of the more recently developed techniques and the state-of-the-art in the more well-known large-scale dimensional metrology methods. In some cases, the techniques are described in detail, or, where relevant specialist review papers exist, these are cited as further reading. The traceability of the measurement data collected is discussed with reference to new international standards that are emerging. In some cases, hybrid measurement techniques are finding specialized applications and these are referred to where appropriate. C1 [Peggs, G. N.; Maropoulos, P. G.] Univ Bath, Bath BA2 7AY, Avon, England. [Hughes, E. B.; Forbes, A. B.] Natl Phys Lab, Teddington TW11 0LW, Middx, England. [Robson, S.; Ziebart, M.] UCL, London, England. [Muralikrishnan, B.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Peggs, GN (reprint author), Univ Bath, Bath BA2 7AY, Avon, England. EM graham.peggs@btinternet.com OI Hughes, Ben/0000-0001-5084-8198; Maropoulos, Paul/0000-0001-6525-6216 FU National Measurement System's Engineering Measurement Programme which is part of the UK's Department of Innovation, Universities and Skills FX The contribution from NPL was funded by the National Measurement System's Engineering Measurement Programme which is part of the UK's Department of Innovation, Universities and Skills. The authors would like to thank Stephen Kyle (Senior Honorary Research Fellow in large-volume metrology matters at University College London) for his comments and suggestions. NR 160 TC 57 Z9 67 U1 4 U2 33 PU SAGE PUBLICATIONS LTD PI LONDON PA 1 OLIVERS YARD, 55 CITY ROAD, LONDON EC1Y 1SP, ENGLAND SN 0954-4054 EI 2041-2975 J9 P I MECH ENG B-J ENG JI Proc. Inst. Mech. Eng. Part B-J. Eng. Manuf. PD JUN PY 2009 VL 223 IS 6 BP 571 EP 595 DI 10.1243/09544054JEM1284 PG 25 WC Engineering, Manufacturing; Engineering, Mechanical SC Engineering GA 464LX UT WOS:000267507600001 ER PT J AU Simmonds, RW Allman, MS Altomare, F Cicak, K Osborn, KD Park, JA Sillanpaa, M Sirois, A Strong, JA Whittaker, JD AF Simmonds, R. W. Allman, M. S. Altomare, F. Cicak, K. Osborn, K. D. Park, J. A. Sillanpaa, M. Sirois, A. Strong, J. A. Whittaker, J. D. TI Coherent interactions between phase qubits, cavities, and TLS defects SO QUANTUM INFORMATION PROCESSING LA English DT Article DE Superconducting; Josephson junction; Quantum information; Quantum bits; Circuit qed; Cqed ID MACROSCOPIC QUANTUM STATES; SUPERCONDUCTING QUBITS; TUNNEL-JUNCTIONS; VITREOUS SILICA; CIRCUIT; SUPERPOSITION; SPECTROSCOPY AB We describe recent experiments developed for investigating the interactions between superconducting phase quantum bits (qubits) and resonant cavities. Two-level system (TLS) defects within the junction barrier also couple to the qubits, adding more degrees of freedom, creating a rich multi-particle system for study. C1 [Simmonds, R. W.; Allman, M. S.; Altomare, F.; Cicak, K.; Osborn, K. D.; Park, J. A.; Sillanpaa, M.; Sirois, A.; Strong, J. A.; Whittaker, J. D.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. [Allman, M. S.; Sirois, A.; Strong, J. A.; Whittaker, J. D.] Univ Colorado, Boulder, CO 80309 USA. [Sillanpaa, M.] Helsinki Univ Technol, FIN-02015 Espoo, Finland. [Osborn, K. D.] Lab Phys Sci, College Pk, MD 20740 USA. RP Simmonds, RW (reprint author), Natl Inst Stand & Technol, 325 Broadway St, Boulder, CO 80305 USA. EM simmonds@boulder.nist.gov RI Allman, Michael/E-5922-2011; Sillanpaa, Mika/A-3554-2013 FU NIST; IARPA [DNI-813268] FX We would like to thank NIST and IARPA (grant DNI-813268) for continuously funding this research as well as all our collaborators and colleagues advancing this exciting, ever- changing field. NR 42 TC 13 Z9 14 U1 3 U2 10 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 1570-0755 J9 QUANTUM INF PROCESS JI Quantum Inf. Process. PD JUN PY 2009 VL 8 IS 2-3 BP 117 EP 131 DI 10.1007/s11128-009-0095-z PG 15 WC Physics, Multidisciplinary; Physics, Mathematical SC Physics GA 420CS UT WOS:000264266600005 ER PT J AU Mann, JL Vocke, RD Kelly, WR AF Mann, Jacqueline L. Vocke, Robert D. Kelly, W. Robert TI Revised delta S-34 reference values for IAEA sulfur isotope reference materials S-2 and S-3 (vol 23, pg 1116, 2009) SO RAPID COMMUNICATIONS IN MASS SPECTROMETRY LA English DT Correction C1 [Mann, Jacqueline L.; Vocke, Robert D.; Kelly, W. Robert] NIST, Div Analyt Chem, Inorgan Chem Metrol Grp, Gaithersburg, MD 20899 USA. RP Mann, JL (reprint author), NIST, Div Analyt Chem, Inorgan Chem Metrol Grp, 100 Bur Dr,MS8391, Gaithersburg, MD 20899 USA. NR 1 TC 1 Z9 1 U1 0 U2 3 PU WILEY-BLACKWELL PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 0951-4198 J9 RAPID COMMUN MASS SP JI Rapid Commun. Mass Spectrom. PD JUN PY 2009 VL 23 IS 11 BP 1746 EP 1746 DI 10.1002/rcm.4090 PG 1 WC Biochemical Research Methods; Chemistry, Analytical; Spectroscopy SC Biochemistry & Molecular Biology; Chemistry; Spectroscopy GA 454ZN UT WOS:000266724000027 ER PT J AU Lakhankar, T Ghedira, H Temimi, M Azar, AE Khanbilvardi, R AF Lakhankar, Tarendra Ghedira, Hosni Temimi, Marouane Azar, Amir E. Khanbilvardi, Reza TI Effect of Land Cover Heterogeneity on Soil Moisture Retrieval Using Active Microwave Remote Sensing Data SO REMOTE SENSING LA English DT Article DE soil moisture; land-cover; heterogeneity; RADAR; neural network AB This study addresses the issue of the variability and heterogeneity problems that are expected from a sensor with a larger footprint having homogenous and heterogeneous sub-pixels. Improved understanding of spatial variability of soil surface characteristics such as land cover and vegetation in larger footprint are critical in remote sensing based soil moisture retrieval. This study analyzes the sub-pixel variability (standard deviation of sub-grid pixels) of Normalized Difference Vegetation Index and SAR backscatter. Back-propagation neural network was used for soil moisture retrieval from active microwave remote sensing data from Southern Great Plains of Oklahoma. The effect of land cover heterogeneity (number of different vegetation species within pixels) on soil moisture retrieval using active microwave remote sensing data was investigated. The presence of heterogeneous vegetation cover reduced the accuracy of the derived soil moisture using microwave remote sensing data. The results from this study can be used to characterize the uncertainty in soil moisture retrieval in the context of Soil Moisture Active and Passive (SMAP) mission which will have larger footprint. C1 [Lakhankar, Tarendra; Temimi, Marouane; Azar, Amir E.; Khanbilvardi, Reza] CUNY, NOAA Cooperat Remote Sensing Sci & Technol Ctr NO, New York, NY 10031 USA. [Ghedira, Hosni] Amer Univ Dubai, Dubai, U Arab Emirates. RP Lakhankar, T (reprint author), CUNY, NOAA Cooperat Remote Sensing Sci & Technol Ctr NO, New York, NY 10031 USA. EM tlakhankar@ccny.cuny.edu; hghedira@aud.edu; temimi@ce.ccny.cuny.edu; khanbilvardi@ccny.cuny.edu RI Lakhankar, Tarendra/F-9490-2011 OI Lakhankar, Tarendra/0000-0002-4759-2141 FU National Oceanic and Atmospheric Administration (NOAA) [NA06OAR4810162] FX This study was supported and monitored by National Oceanic and Atmospheric Administration (NOAA) under Grant NA06OAR4810162. The views, opinions, and findings contained in this report are those of the author(s) and should not be construed as an official National Oceanic and Atmospheric Administration or U.S. Government position, policy, or decision. NR 16 TC 14 Z9 14 U1 0 U2 9 PU MDPI AG PI BASEL PA POSTFACH, CH-4005 BASEL, SWITZERLAND SN 2072-4292 J9 REMOTE SENS-BASEL JI Remote Sens. PD JUN PY 2009 VL 1 IS 2 BP 80 EP 91 DI 10.3390/rs1020080 PG 12 WC Remote Sensing SC Remote Sensing GA V24HB UT WOS:000208400400004 ER PT J AU Weiner, J AF Weiner, J. TI The physics of light transmission through subwavelength apertures and aperture arrays SO REPORTS ON PROGRESS IN PHYSICS LA English DT Review ID EXTRAORDINARY OPTICAL-TRANSMISSION; EVANESCENT-WAVE MODEL; HOLE ARRAYS; PERIODIC ARRAY; SURFACE-WAVES; DIFFRACTION; SLITS; GRATINGS; FILMS; LOSSES AB The passage of light through apertures much smaller than the wavelength of the light has proved to be a surprisingly subtle phenomenon. This report describes how modern developments in nanofabrication, coherent light sources and numerical vector field simulations have led to the upending of early predictions from scalar diffraction theory and classical electrodynamics. Optical response of real materials to incident coherent radiation at petahertz frequencies leads to unexpected consequences for transmission and extinction of light through subwavelength aperture arrays. This paper is a report on progress in our understanding of this phenomenon over the past decade. C1 [Weiner, J.] Univ Sao Paulo, CePOF, IFSC, BR-13566590 Sao Carlos, SP, Brazil. RP Weiner, J (reprint author), Natl Inst Stand & Technol, Ctr Nanoscale Sci & Technol, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM johweiner@gmail.com RI Optica e fotonica, Inct/I-2419-2013 NR 49 TC 63 Z9 63 U1 3 U2 24 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0034-4885 J9 REP PROG PHYS JI Rep. Prog. Phys. PD JUN PY 2009 VL 72 IS 6 AR 064401 DI 10.1088/0034-4885/72/6/064401 PG 19 WC Physics, Multidisciplinary SC Physics GA 450NK UT WOS:000266407900001 ER PT J AU Chung, KH Shaw, GA Pratt, JR AF Chung, Koo-Hyun Shaw, Gordon A. Pratt, Jon R. TI Accurate noncontact calibration of colloidal probe sensitivities in atomic force microscopy SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article DE atomic force microscopy; calibration; colloids; displacement measurement; force sensors; measurement uncertainty; thermal noise ID SPRING CONSTANT; SURFACE FORCES; CANTILEVERS; FRICTION; METROLOGY; SI; STIFFNESS; STANDARD; ADHESION; CELL AB The absolute force sensitivities of colloidal probes comprised of atomic force microscope, or AFM, cantilevers with microspheres attached to their distal ends are measured. The force sensitivities are calibrated through reference to accurate electrostatic forces, the realizations of which are described in detail. Furthermore, the absolute accuracy of a common AFM force calibration scheme, known as the thermal noise method, is evaluated. It is demonstrated that the thermal noise method can be applied with great success to colloidal probe calibration in air and in liquid to yield force measurements with relative standard uncertainties below 5%. Techniques to combine the electrostatics-based determination of the AFM force sensitivity with measurements of the colloidal probe's thermal noise spectrum to compute noncontact estimates of the displacement sensitivity and spring constant are also developed. C1 [Chung, Koo-Hyun; Shaw, Gordon A.; Pratt, Jon R.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Pratt, JR (reprint author), Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. EM jon.pratt@nist.gov RI Chung, KooHyun/O-3042-2013 OI Chung, KooHyun/0000-0002-9092-6784 NR 47 TC 11 Z9 11 U1 2 U2 22 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 0034-6748 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD JUN PY 2009 VL 80 IS 6 AR 065107 DI 10.1063/1.3152335 PG 13 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 465PZ UT WOS:000267600600040 PM 19566226 ER PT J AU McIver, JW Erwin, R Chen, WC Gentile, TR AF McIver, J. W. Erwin, R. Chen, W. C. Gentile, T. R. TI End-compensated magnetostatic cavity for polarized He-3 neutron spin filters SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article DE neutron beams; neutron polarisation; solenoids ID RELAXATION; GAS; HE3 AB We have expanded upon the "Magic Box" concept, a coil driven magnetic parallel plate capacitor constructed out of mu-metal, by introducing compensation sections at the ends of the box that are tuned to limit end-effects similar to those of short solenoids. This ability has reduced the length of the magic box design without sacrificing any loss in field homogeneity, making the device far more applicable to the often space limited neutron beam line. The appeal of the design beyond affording longer polarized He-3 lifetimes is that it provides a vertical guide field, which facilitates neutron spin transport for typical polarized beam experiments. We have constructed two end-compensated magic boxes of dimensions 28.4x40x15 cm(3) (lengthxwidthxheight) with measured, normalized volume-averaged transverse field gradients ranging from 3.3x10(-4) to 6.3x10(-4) cm(-1) for cell sizes ranging from 8.1x6.0 to 12.0x7.9 cm(2) (diameterxlength), respectively. C1 [McIver, J. W.; Erwin, R.; Chen, W. C.; Gentile, T. R.] NIST, Gaithersburg, MD 20899 USA. [Chen, W. C.] Indiana Univ, Bloomington, IN 47408 USA. RP Chen, WC (reprint author), NIST, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM wcchen@nist.gov FU U. S. Dept. of Energy (Basic Energy Sciences) FX The authors thank Professor G. L. Jones of Hamilton College for great help in setting up the FID NMR measurement and J. Anderson of the NIST Optical Shop for assistance with cell fabrication. This work was supported in part by the U. S. Dept. of Energy (Basic Energy Sciences), in particular a portion of the relaxation measurements. NR 14 TC 12 Z9 12 U1 0 U2 4 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0034-6748 EI 1089-7623 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD JUN PY 2009 VL 80 IS 6 AR 063905 DI 10.1063/1.3154386 PG 8 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 465PZ UT WOS:000267600600027 PM 19566213 ER PT J AU Berntson, EA Moran, P AF Berntson, Ewann A. Moran, Paul TI The utility and limitations of genetic data for stock identification and management of North Pacific rockfish (Sebastes spp.) SO REVIEWS IN FISH BIOLOGY AND FISHERIES LA English DT Article DE Rockfish; Sebastes; Genetics; Microsatellite ID QUEEN-CHARLOTTE SOUND; OCEAN PERCH; POPULATION-STRUCTURE; GENUS SEBASTES; MICROSATELLITE VARIATION; ROUGHEYE ROCKFISH; MOLECULAR-IDENTIFICATION; SHORTRAKER ROCKFISH; LARVAL ROCKFISHES; BLACK ROCKFISH AB Rockfishes (Sebastes spp.) represent a speciose and ecologically important group of marine fishes found in both the Pacific and Atlantic oceans, with approximately 105 species found world-wide (Hyde and Vetter 2007). They also comprise the majority of species found in the Pacific groundfish fishery. Thorough species assessments in terms of harvest management have been done for only 11 species, and of the 11 species, seven have been declared overfished. Having accurate genetic information is critical to the continuing effort at stock assessments, but sampling is often difficult in marine fishes. Genetic techniques are a powerful tool in the effort to better characterize the ecology of these species. These techniques can be used to investigate multiple biological traits, including species identity, intra- and interspecific genetic variation, migration patterns, and effective population size. There are important caveats and limitations when applying specific genetic methods, especially in marine species that lack discrete spawning aggregates. Nevertheless, it is clear from a review of recent literature that genetic tools have already provided very specific insight regarding rockfish population dynamics. The results are diverse and difficult to synthesize; however, existing studies show five primary patterns to population groupings in rockfishes: no obvious pattern of structure, structure consistent with isolation by distance, structure evident but inconsistent with isolation by distance, structure that correlates to oceanographic features, and potential genetic introgression. Clearly the study of rockfish population genetics is poised for rapid expansion that will unquestionably aid management of the rockfish fisheries and general understanding of rockfish evolutionary systematics. A principle challenge at this point is to derive generalized inferences from such a diverse array of study results across the vast North Pacific range of Sebastes. This review summarizes existing genetic studies in Sebastes spp. in the North Pacific to assist in identifying knowledge gaps for this ecologically important and diverse group. C1 [Berntson, Ewann A.; Moran, Paul] Natl Marine Fisheries Serv, Conservat Biol Div, NW Fisheries Sci Ctr, Seattle, WA 98112 USA. RP Berntson, EA (reprint author), Natl Marine Fisheries Serv, Conservat Biol Div, NW Fisheries Sci Ctr, 2725 Montlake Blvd E, Seattle, WA 98112 USA. EM ewann.berntson@noaa.gov NR 70 TC 6 Z9 6 U1 1 U2 19 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0960-3166 J9 REV FISH BIOL FISHER JI Rev. Fish. Biol. Fish. PD JUN PY 2009 VL 19 IS 2 BP 233 EP 247 DI 10.1007/s11160-008-9101-2 PG 15 WC Fisheries; Marine & Freshwater Biology SC Fisheries; Marine & Freshwater Biology GA 442FW UT WOS:000265827200007 ER PT J AU Schiavone, A Corsolini, S Kannan, K Tao, L Trivelpiece, W Torres, D Focardi, S AF Schiavone, A. Corsolini, S. Kannan, K. Tao, L. Trivelpiece, W. Torres, D., Jr. Focardi, S. TI Perfluorinated contaminants in fur seal pups and penguin eggs from South Shetland, Antarctica SO SCIENCE OF THE TOTAL ENVIRONMENT LA English DT Article DE Perfluorinated compounds; Penguin; Egg; Seal; Antarctica ID ACTIVATED RECEPTOR-ALPHA; KING-GEORGE-ISLAND; PERFLUOROOCTANE SULFONATE; MARINE MAMMALS; TISSUE DISTRIBUTION; FLUORINATED HYDROCARBONS; NORTHERN BOBWHITE; PUSA-SIBIRICA; OCEAN WATERS; POLAR BEARS AB Perfluorinated compounds (PFCs) have emerged as a new class of global environmental pollutants. In this study, the presence of perfluorochemicals (PFCs) in penguin eggs and Antarctic fur seals was reported for the first time. Tissue samples from Antarctic fur seal pups and penguin eggs were collected during the 2003/04 breeding season. Ten PFC contaminants were determined in seal and penguin samples. The PFC concentrations in seal liver were in the decreasing order, PFOS>PFNA>PFHpA>PFUnDA while in Adelie penguin eggs were PFHpA>PFUnDA>PFDA>PFDoDA, and in Gentoo penguin eggs were PFUnDA>PFOS>PFDoDA>PFHpA. The PFC concentrations differed significantly between seals and penguins (p<0.005) and a species-specific difference was found between the two species of penguins (p<0.005). In our study we found a mean concentration of PFOS in seal muscle and liver samples of 1.3 ng/g and 9.4 ng/g wet wt, respectively, and a mean concentration in Gentoo and Adelie penguin eggs of 0.3 ng/g and 0.38 ng/g wet wt, respectively. PFCs detected in penguin eggs and seal pups suggested oviparous and viviparous transfer of PFOS to eggs and off-springs. (C) 2009 Elsevier B.V. All rights reserved. C1 [Schiavone, A.; Corsolini, S.; Focardi, S.] Univ Siena, Dept Environm Sci G Sarfattia, I-53100 Siena, Italy. [Kannan, K.; Tao, L.] SUNY Albany, Sch Publ Hlth, New York State Dept Hlth, Wadsworth Ctr, Albany, NY 12201 USA. [Kannan, K.; Tao, L.] SUNY Albany, Sch Publ Hlth, Dept Environm Hlth Sci, Albany, NY 12201 USA. [Trivelpiece, W.] SW Fisheries Sci Ctr, US Antarctic Marine Living Resources Div, La Jolla, CA 92037 USA. [Torres, D., Jr.] Inst Antartico Chileno INACH, Punta Arenas 1055, Chile. RP Schiavone, A (reprint author), Univ Siena, Dept Environm Sci G Sarfattia, Via PA Mattioli 4, I-53100 Siena, Italy. EM schiavone4@unisi.it RI Corsolini, Simonetta/B-9460-2012 OI Corsolini, Simonetta/0000-0002-9772-2362 FU Italian National Program of Research in Antarctica (PNRA); National Science Foundation FX This research was funded by the Italian National Program of Research in Antarctica (PNRA). The National Science Foundation supported S. Corsolini's stay and travel to and from King George Is. We are very grateful to Daniel Torres and Daniel Torres jr (Instituto Antarctico Chileno, Santiago, Chile) for collecting the fur seal samples during the 2003/04 expedition, and to Wayne Trivelpiece, and Susan Trivelpiece for collecting the penguin eggs samples. We thanks Roger Hewitt, the Agunsa (Punta Arenas, Chile) and Raytheon (USA) for their friendly logistic support. NR 45 TC 26 Z9 28 U1 4 U2 26 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0048-9697 J9 SCI TOTAL ENVIRON JI Sci. Total Environ. PD JUN 1 PY 2009 VL 407 IS 12 BP 3899 EP 3904 DI 10.1016/j.scitotenv.2008.12.058 PG 6 WC Environmental Sciences SC Environmental Sciences & Ecology GA 451BT UT WOS:000266446400032 PM 19321191 ER PT J AU Vesper, HW Bhasin, S Wang, C Tai, SS Dodge, LA Singh, RJ Nelson, J Ohorodnik, S Clarke, NJ Salameh, WA Parker, CR Razdan, R Monsell, EA Myers, GL AF Vesper, Hubert W. Bhasin, Shalender Wang, Christina Tai, Susan S. Dodge, Larry A. Singh, Ravinder J. Nelson, Judie Ohorodnik, Susan Clarke, Nigel J. Salameh, Wael A. Parker, C. Richard, Jr. Razdan, Raj Monsell, Elizabeth A. Myers, Gary L. TI Interlaboratory comparison study of serum total testoserone measurements performed by mass spectrometry methods SO STEROIDS LA English DT Article DE Testosterone; HPLC-MS/MS; Method comparison; Analytical variability ID CLINICAL-PRACTICE GUIDELINE; FREE TESTOSTERONE; GAS-CHROMATOGRAPHY; ADULT MEN; WOMEN; ASSAYS; ANDROSTENEDIONE; IMMUNOASSAYS; VALIDATION; THERAPY AB Background: Though mass spectrometry (MS) assays are increasingly used for routine clinical measurements of serum total testosterone (TT), information about the variability of results is limited. This study assessed the variability of TT measurement results from routine MS assays. Methods: Twenty serum samples (12 females, 8 males) were analyzed on 2 days by seven high performance liquid chromatography (HPLC), and one gas chromatography (GC)-tandem mass spectrometry (HPLC-MS/MS, CC-MS/MS) assays. Two samples (male and female) were provided in five replicates to assess the within-run variability. Results were compared against those obtained at National Institute of Standards and Technology (NIST). The within- and between-laboratory variability was assessed for each sample. Comparisons to the NIST results were performed using bias plot and Deming regression analysis. Results: The overall coefficient of variation of the results obtained with MS assays was <15%CV at >1.53 nmol/L and <34%CV at 0.3 nmol/L The between-assay variability was the major contributor to the overall variability. The assay precision was the highest (<3%CV) with assays using liquid-liquid extraction for sample preparation or GC-MS/MS. The mean percent difference to the reference assay was 11%. The slopes of Deming regression analysis of the MS assays were between 0.903 and 1.138 (correlation coefficient: >0.996). TT concentrations for one assay were above the measurement range. Conclusions: The variability of TT measurement results among MS assays is substantially smaller than that reported for immunoassays. The type of sample preparation may affect assay precision. Standardizing assays can further reduce the variability of measurement results. Published by Elsevier Inc. C1 [Vesper, Hubert W.; Razdan, Raj; Monsell, Elizabeth A.; Myers, Gary L.] Ctr Dis Control & Prevent, Atlanta, GA 30341 USA. [Bhasin, Shalender] Boston Univ, Sch Med, Boston, MA 02118 USA. [Wang, Christina] Univ Calif Los Angeles, Harbor Med Ctr, Sch Med, Torrance, CA 90509 USA. [Wang, Christina] Univ Calif Los Angeles, Sch Med, Los Angeles Biomed Res Inst, Torrance, CA 90509 USA. [Tai, Susan S.] NIST, Chem Sci & Technol Lab, Div Analyt Chem, Gaithersburg, MD 20899 USA. [Dodge, Larry A.; Singh, Ravinder J.] Mayo Clin & Mayo Fdn, Rochester, MN 55905 USA. [Nelson, Judie] Childrens & Womens Hlth Ctr BC, Newborn Screening Biochem Genet Labs, Vancouver, BC V6H 3V4, Canada. [Ohorodnik, Susan] Taylor Technol Inc, Princeton, NJ 08540 USA. [Clarke, Nigel J.; Salameh, Wael A.] QuestDiagnost Nichols Inst, Capistrano, CA 92675 USA. [Parker, C. Richard, Jr.] Univ Alabama, Dept Obstet & Gynecol, Birmingham, AL 35294 USA. RP Vesper, HW (reprint author), Ctr Dis Control & Prevent, 4770 Buford Highway,NE F25, Atlanta, GA 30341 USA. EM HVesper@cdc.gov FU Solvay Pharmaceutical through the CDC Foundation; National Center for Chronic Disease Prevention and Health Promotion FX Funding for this project is provided by Solvay Pharmaceutical through the CDC Foundation. The Division of Laboratory Sciences at the National Center for Environmental Health and the Division of Cancer Prevention and Control at the National Center for Chronic Disease Prevention and Health Promotion also contributed to this project. We would like to thank Dr. Sam Caudill for his assistance with the SAS calculations, and Dr. Julianne Bothelo, CDC and Christopher Shacklady, CDC for their contributions to manuscript preparation. NR 40 TC 75 Z9 78 U1 2 U2 7 PU ELSEVIER SCIENCE INC PI NEW YORK PA 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA SN 0039-128X J9 STEROIDS JI Steroids PD JUN PY 2009 VL 74 IS 6 BP 498 EP 503 DI 10.1016/j.steroids.2009.01.004 PG 6 WC Biochemistry & Molecular Biology; Endocrinology & Metabolism SC Biochemistry & Molecular Biology; Endocrinology & Metabolism GA 432JH UT WOS:000265128800002 PM 19428438 ER PT J AU van der Laan, DC AF van der Laan, D. C. TI YBa2Cu3O7-delta coated conductor cabling for low ac-loss and high-field magnet applications SO SUPERCONDUCTOR SCIENCE & TECHNOLOGY LA English DT Article ID PROGRESS AB The electromechanical properties of YBa2Cu3O7-delta coated conductors under high axial compressive strain are measured; they show no irreversible degradation in critical current up to -2% strain. The high degree of elasticity of the ceramic layers in these conductors is beneficial when used in high-field applications, but has not been fully exploited. The results presented here lead to the introduction of a new method of producing YBa2Cu3O7-delta coated conductor cabling for use in low ac-loss and high-field magnet applications, where coated conductors are wound around a former with a relatively small diameter. This concept allows for full transposition of the conductors, a high cable critical current, low inductance, and a relatively high engineering current density. The feasibility of the concept is demonstrated by constructing several prototype cables and by comparing the cable critical current to that of a straight sample under axial compression. C1 [van der Laan, D. C.] Univ Colorado, Dept Phys, Boulder, CO 80309 USA. [van der Laan, D. C.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP van der Laan, DC (reprint author), Univ Colorado, Dept Phys, Boulder, CO 80309 USA. EM danko@boulder.nist.gov RI van der Laan, Danko/L-5098-2016 FU US Department of Energy; Office of Electricity Delivery and Energy Reliability FX This work was supported in part by the US Department of Energy, Office of Electricity Delivery and Energy Reliability. NR 17 TC 50 Z9 50 U1 0 U2 9 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0953-2048 J9 SUPERCOND SCI TECH JI Supercond. Sci. Technol. PD JUN PY 2009 VL 22 IS 6 AR 065013 DI 10.1088/0953-2048/22/6/065013 PG 5 WC Physics, Applied; Physics, Condensed Matter SC Physics GA 447VF UT WOS:000266219400027 ER PT J AU Brennan, MJ Hennon, CC Knabb, RD AF Brennan, Michael J. Hennon, Christopher C. Knabb, Richard D. TI The Operational Use of QuikSCAT Ocean Surface Vector Winds at the National Hurricane Center SO WEATHER AND FORECASTING LA English DT Article ID WEATHER PREDICTION; SCATTEROMETER DATA; RAIN; RETRIEVALS; SEAWINDS; IMPACT AB The utility and shortcomings of near-real-time ocean surface vector wind retrievals from the NASA Quick Scatterometer (QuikSCAT) in operational forecast and analysis activities at the National Hurricane Center (NHC) are described. The use of QuikSCAT data in tropical cyclone (TC) analysis and forecasting for center location/identification, intensity (maximum sustained wind) estimation, and analysis of outer wind radii is presented, along with shortcomings of the data due to the effects of rain contamination and wind direction uncertainties. Automated QuikSCAT solutions in TCs often fail to show a closed circulation, and those that do are often biased to the southwest of the NHC best-track position. QuikSCAT winds show the greatest skill in TC intensity estimation in moderate to strong tropical storms. In tropical depressions, a positive bias in QuikSCAT winds is seen due to enhanced backscatter by rain, while in major hurricanes rain attenuation, resolution, and signal saturation result in a large negative bias in QuikSCAT intensity estimates. QuikSCAT wind data help overcome the large surface data void in the analysis and forecast area of NHC's Tropical Analysis and Forecast Branch (TAFB). These data have resulted in improved analyses of surface features, better definition of high wind areas, and improved forecasts of high-wind events. The development of a climatology of gap wind events in the Gulf of Tehuantepec has been possible due to QuikSCAT wind data in a largely data-void region. The shortcomings of ocean surface vector winds from QuikSCAT in the operational environment at NHC are described, along with requirements for future ocean surface vector wind missions. These include improvements in the timeliness and quality of the data, increasing the wind speed range over which the data are reliable, and decreasing the impact of rain to allow for accurate retrievals in all-weather conditions. C1 [Brennan, Michael J.; Knabb, Richard D.] NOAA, NWS NCEP, Natl Hurricane Ctr, Miami, FL 33165 USA. [Hennon, Christopher C.] Univ N Carolina, Dept Atmospher Sci, Asheville, NC 28804 USA. RP Brennan, MJ (reprint author), NOAA, NWS NCEP, Natl Hurricane Ctr, 11691 SW 17th St, Miami, FL 33165 USA. EM michael.j.brennan@noaa.gov FU National Ocean Partnership Program; NOAA/NESDIS FX Funding to support this research was provided by the National Ocean Partnership Program and by research to operations funding through NOAA/NESDIS. In addition, the first two authors conducted portions of this research while participating in the UCAR Visiting Scientist Program under the direction of the third author at the National Hurricane Center (NHC). Thanks to Joni David of NHC who provided assistance in creating Fig. 1. Thanks to Dr. Chris Landsea, Lt. Cdr. David Roberts, James Franklin, and Jamie Rhome of NHC for providing comments on this manuscript. Special appreciation is extended to Dr. Paul Chang and Dr. Zorana Jelenak (NOAA/NESDIS), James Franklin and Hugh Cobb (NHC), Joan Von Ahn and Joseph Sienkiewicz (Ocean Prediction Center), and Roger Edson (NWS Guam) who provided data, analysis, and valuable insights for this work. Finally, thanks is extended to three reviewers who provided many helpful suggestions to improve this manuscript. NR 40 TC 51 Z9 51 U1 0 U2 7 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0882-8156 J9 WEATHER FORECAST JI Weather Forecast. PD JUN PY 2009 VL 24 IS 3 BP 621 EP 645 DI 10.1175/2008WAF2222188.1 PG 25 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 467SQ UT WOS:000267763100001 ER PT J AU McCaul, EW Goodman, SJ LaCasse, KM Cecil, DJ AF McCaul, Eugene W., Jr. Goodman, Steven J. LaCasse, Katherine M. Cecil, Daniel J. TI Forecasting Lightning Threat Using Cloud-Resolving Model Simulations SO WEATHER AND FORECASTING LA English DT Article ID UNITED-STATES; MAPPING ARRAY; PART I; STORM; THUNDERSTORM; PARAMETERIZATION; ELECTRIFICATION; PREDICTION; FLORIDA; SCHEME AB Two new approaches are proposed and developed for making time- and space-dependent, quantitative short-term forecasts of lightning threats, and a blend of these approaches is devised that capitalizes on the strengths of each. The new methods are distinctive in that they are based entirely on the ice-phase hydrometeor fields generated by regional cloud-resolving numerical simulations, such as those produced by the Weather Research and Forecasting (WRF) model. These methods are justified by established observational evidence linking aspects of the precipitating ice hydrometeor fields to total flash rates. The methods are straightforward and easy to implement, and offer an effective near-term alternative to the incorporation of complex and costly cloud electrification schemes into numerical models. One method is based on upward fluxes of precipitating ice hydrometeors in the mixed-phase region at the -15 degrees C level, while the second method is based on the vertically integrated amounts of ice hydrometeors in each model grid column. Each method can be calibrated by comparing domain-wide statistics of the peak values of simulated flash-rate proxy fields against domain-wide peak total lightning flash-rate density data from observations. Tests show that the first method is able to capture much of the temporal variability of the lightning threat, while the second method does a better job of depicting the areal coverage of the threat. The blended solution proposed in this work is designed to retain most of the temporal sensitivity of the first method, while adding the improved spatial coverage of the second. Simulations of selected diverse North Alabama cases show that the WRF can distinguish the general character of most convective events, and that the methods employed herein show promise as a means of generating quantitatively realistic fields of lightning threat. However, because the models tend to have more difficulty in predicting the instantaneous placement of storms, forecasts of the detailed location of the lightning threat based on single simulations can be in error. Although these model shortcomings presently limit the precision of lightning threat forecasts from individual runs of current generation models, the techniques proposed herein should continue to be applicable as newer and more accurate physically based model versions, physical parameterizations, initialization techniques, and ensembles of forecasts become available. C1 [McCaul, Eugene W., Jr.] Univ Space Res Assoc, Huntsville, AL 35806 USA. [Goodman, Steven J.] NOAA, NESDIS, ORA, Camp Springs, MD USA. [LaCasse, Katherine M.; Cecil, Daniel J.] Univ Alabama, Huntsville, AL 35899 USA. RP McCaul, EW (reprint author), Univ Space Res Assoc, Bldg 4,Ste 450,6767 Old Madison Pike, Huntsville, AL 35806 USA. EM emccaul@usra.edu FU NASA Science Mission Directorate's Earth Science Division; NOAA GOES-R [NA07AANEG0284] FX This research was funded by the NASA Science Mission Directorate's Earth Science Division in support of the Short-term Prediction and Research Transition (SPoRT) Project at Marshall Space Flight Center, Huntsville, Alabama. We also thank the NOAA GOES-R program office for the funding it provided in support of GOES-R Lightning Mapper risk reduction science, under Space Act Agreement Order NA07AANEG0284. The authors have also benefited from helpful discussions with Paul Krehbiel and Ron Thomas, New Mexico Tech; Walt Petersen and Kevin Doty, UAH; Bill Koshak and Rich Blakeslee, NASA Marshall Space Flight Center; and Morris Weisman, NCAR, during the course of this research. Kelvin Droegemeier and Kevin Thomas, University of Oklahoma, provided sample high-resolution WRF datasets for test purposes early in the work. Jayanthi Srikishen, USRA Huntsville, assisted in the installation of the WRF model code. The views, opinions, and findings contained herein are those of the authors and should not be construed as an official NASA, NOAA, or U. S. government position, policy, or decision. Finally, we are grateful for the helpful comments made by Phil Shafer and two anonymous reviewers, which led to significant improvements in both the content and readability of the paper. NR 34 TC 53 Z9 56 U1 2 U2 11 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0882-8156 J9 WEATHER FORECAST JI Weather Forecast. PD JUN PY 2009 VL 24 IS 3 BP 709 EP 729 DI 10.1175/2008WAF2222152.1 PG 21 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 467SQ UT WOS:000267763100005 ER PT J AU Park, H Ryzhkov, AV Zrnic, DS Kim, KE AF Park, HyangSuk Ryzhkov, A. V. Zrnic, D. S. Kim, Kyung-Eak TI The Hydrometeor Classification Algorithm for the Polarimetric WSR-88D: Description and Application to an MCS SO WEATHER AND FORECASTING LA English DT Article ID DUAL-POLARIZATION RADAR; IN-SITU VERIFICATION; SYSTEMS AB This paper contains a description of the most recent version of the hydrometeor classification algorithm for polarimetric Weather Surveillance Radar-1988 Doppler (WSR-88D). This version contains several modifications and refinements of the previous echo classification algorithm based on the principles of fuzzy logic. These modifications include the estimation of confidence factors that characterize the possible impacts of all error sources on radar measurements, the assignment of the matrix of weights that characterizes the classification power of each variable with respect to every class of radar echo, and the implementation of a class designation system based on the distance from the radar and the parameters of the melting layer that are determined as functions of azimuth with polarimetric radar measurements. These additions provide considerable flexibility and improve the discrimination between liquid and frozen hydrometeors. The new classification scheme utilizes all available polarimetric variables and discerns 10 different classes of radar echoes. Furthermore, a methodology for the new fuzzy logic classification scheme is discussed and the results are illustrated using polarimetric radar data collected with the Norman, Oklahoma (KOUN), WSR-88D prototype radar during a mesoscale convective system event on 13 May 2005. C1 [Ryzhkov, A. V.] NOAA, Natl Severe Storms Lab, OAR, CIMMS, Norman, OK 73072 USA. [Park, HyangSuk; Kim, Kyung-Eak] Kyungpook Natl Univ, Dept Astron & Atmospher Sci, Taegu, South Korea. [Ryzhkov, A. V.] Univ Oklahoma, Cooperat Inst Mesoscale Meteorol Studies, Norman, OK 73019 USA. RP Ryzhkov, AV (reprint author), NOAA, Natl Severe Storms Lab, OAR, CIMMS, 120 David Boren Dr, Norman, OK 73072 USA. EM alexander.ryzhkov@noaa.gov FU NOAA/Office of Oceanic and Atmospheric Research [NA17RJ1227]; U.S. Department of Commerce; U.S. National Weather Service, Federal Aviation Administration, and Department of Defense; Korea Meteorological Administration Research and Development Program [CATER 2007-2104] FX We express out thanks to Scott Giangrande and Matthew Kumjian for helpful suggestions. Terry Schuur, Kimberly Elmore, and an anonymous reviewer provided comments that have strengthened this manuscript. Paul Schlatter's extensive and useful review is appreciated as it helped in improving the paper. This work was funded by the NOAA/Office of Oceanic and Atmospheric Research under NOAA-University of Oklahoma Cooperative Agreement NA17RJ1227, the U.S. Department of Commerce, and by the U.S. National Weather Service, Federal Aviation Administration, and Department of Defense program for modernization of NEXRAD radars. The lead author was partially supported by the Korea Meteorological Administration Research and Development Program under Grant CATER 2007-2104. The authors thank the NSSL/CIMMS employees who maintain and operate the KOUN polarimetric radar for research-grade applications. NR 31 TC 125 Z9 128 U1 3 U2 13 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0882-8156 J9 WEATHER FORECAST JI Weather Forecast. PD JUN PY 2009 VL 24 IS 3 BP 730 EP 748 DI 10.1175/2008WAF2222205.1 PG 19 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 467SQ UT WOS:000267763100006 ER PT J AU Vasiloff, SV Howard, KW AF Vasiloff, Steven V. Howard, Kenneth W. TI Investigation of a Severe Downburst Storm near Phoenix, Arizona, as Seen by a Mobile Doppler Radar and the KIWA WSR-88D SO WEATHER AND FORECASTING LA English DT Article ID WIND SHEAR DETECTION; MICROBURST ACTIVITY; FLORIDA AB A Shared Mobile Atmospheric Research and Teaching Radar (SMART-R) was deployed near Phoenix, Arizona, during the summer of 2004. The goal was to capture a severe microburst at close range to understand the low-altitude wind structure and evolution. During the evening of 27 July, a severe storm formed along the Estrella Mountains south of Phoenix and moved south of the SMART-R as well as the National Weather Service's (NWS) Weather Surveillance Radar-1988 Doppler (WSR-88D) in Phoenix (KIWA). Several microburst-downburst pulses were observed by radar and a surface wind gust of 67 mi h(-1) was reported. The radar data illustrate the finescale structure of the microburst pulses, with the SMART-R's higher-resolution data showing Doppler velocities 3-4 m s(-1) greater than the KIWA radar. SMART-R wind shear values were 2-3 times greater with the finer resolution of the SMART-R revealing smaller features in the surface outflow wind structure. Asymmetric outflow may have been a factor as well in the different divergence values. The evolution of the outflow was very rapid with the 5-min KIWA scan intervals being too course to sample the detailed evolution. The SMART-R scans were at 3-5-min intervals and also had difficulty resolving the event. The storm environment displayed characteristics of both moderate-to-high-reflectivity microbursts, typical of the high plains of Colorado. C1 [Vasiloff, Steven V.] NOAA, Natl Severe Storms Lab, NWS, Norman, OK 73702 USA. RP Vasiloff, SV (reprint author), NOAA, Natl Severe Storms Lab, NWS, 120 David L Boren Blvd, Norman, OK 73702 USA. EM steven.vasiloff@noaa.gov NR 19 TC 6 Z9 6 U1 0 U2 2 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0882-8156 J9 WEATHER FORECAST JI Weather Forecast. PD JUN PY 2009 VL 24 IS 3 BP 856 EP 867 DI 10.1175/2008WAF2222117.1 PG 12 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 467SQ UT WOS:000267763100014 ER PT J AU Powell, MD Uhlhorn, EW Kepert, JD AF Powell, Mark D. Uhlhorn, Eric W. Kepert, Jeffrey D. TI Estimating Maximum Surface Winds from Hurricane Reconnaissance Measurements SO WEATHER AND FORECASTING LA English DT Article ID SPECTRUM SPATIAL VARIATION; TROPICAL CYCLONE CORE; BOUNDARY-LAYER JETS; PART II; GPS DROPWINDSONDE; ISABEL 2003; INTENSITY; VORTEX; REANALYSIS; EVOLUTION AB Radial profiles of surface winds measured by the Stepped Frequency Microwave Radiometer (SFMR) are compared to radial profiles of flight-level winds to determine the slant ratio of the maximum surface wind speed to the maximum flight-level wind speed, for flight altitude ranges of 2-4 km. The radius of maximum surface wind is found on average to be 0.875 of the radius of the maximum flight-level wind, and very few cases have a surface wind maximum at greater radius than the flight-level maximum. The mean slant reduction factor is 0.84 with a standard deviation of 0.09 and varies with storm-relative azimuth from a maximum of 0.89 on the left side of the storm to a minimum of 0.79 on the right side. Larger slant reduction factors are found in small storms with large values of inertial stability and small values of relative angular momentum at the flight-level radius of maximum wind, which is consistent with Kepert's recent boundary layer theories. The global positioning system (GPS) dropwindsonde-based reduction factors that are assessed using this new dataset have a high bias and substantially larger RMS errors than the new technique. A new regression model for the slant reduction factor based upon SFMR data is presented, and used to make retrospective estimates of maximum surface wind speeds for significant Atlantic basin storms, including Hurricanes Allen (1980), Gilbert (1988), Hugo (1989), Andrew (1992), and Mitch (1998). C1 [Powell, Mark D.; Uhlhorn, Eric W.] NOAA, Atlantic Oceanog & Meteorol Lab, Hurricane Res Div, Miami, FL 33149 USA. [Kepert, Jeffrey D.] Ctr Australian Weather & Climate Res, Bur Meteorol, Melbourne, Vic, Australia. RP Powell, MD (reprint author), Florida State Univ, COAPS, 2035 E Paul Dirac Dr,200 RM Johnson Bldg, Tallahassee, FL 32306 USA. EM mark.powell@noaa.gov RI Powell, Mark/I-4963-2013; Kepert, Jeffrey/I-6786-2013; Uhlhorn, Eric/B-1336-2014 OI Powell, Mark/0000-0002-4890-8945; Kepert, Jeffrey/0000-0001-6771-0769; Uhlhorn, Eric/0000-0002-4759-5342 FU SFMR; NOAA 2006 Hurricane Supplemental; Army Corps of Engineers Hurricane Katrina Interagency Performance Evaluation Task Force FX We appreciate the efforts of our colleagues at HRD, NOAA's Aircraft Operations Center, and NHC, who persisted in exhaustive evaluations and calibrations of the SFMR during the 2005 Hurricane Field Program. Russell St. Fleur of the University of Miami Cooperative Institute for Marine and Atmospheric Studies helped assemble the eyewall GPS sonde dataset. We appreciate the suggestions of Jason Dunion and John Kaplan of HRD who provided internal reviews of the manuscript, as well as the three anonymous reviewers who made very helpful suggestions. This research was supported by the 2005 SFMR initiative, the NOAA 2006 Hurricane Supplemental, and the Army Corps of Engineers Hurricane Katrina Interagency Performance Evaluation Task Force. NR 38 TC 42 Z9 43 U1 2 U2 9 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0882-8156 J9 WEATHER FORECAST JI Weather Forecast. PD JUN PY 2009 VL 24 IS 3 BP 868 EP 883 DI 10.1175/2008WAF2007087.1 PG 16 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 467SQ UT WOS:000267763100015 ER PT J AU French, MM Bluestein, HB Wicker, LJ Dowell, DC Kramar, MR AF French, Michael M. Bluestein, Howard B. Wicker, Louis J. Dowell, David C. Kramar, Matthew R. TI An Example of the Use of Mobile, Doppler Radar Data for Tornado Verification SO WEATHER AND FORECASTING LA English DT Article ID HIGH-RESOLUTION; SOUTH-DAKOTA; 1998 SPENCER; PART II; STORM; SUPERCELLS; TEXAS; BAND AB On 16 May 2003, two ground-based, mobile, Doppler radars scanned a potentially tornadic supercell in the Texas Panhandle intermittently from similar to 0200 to 0330 UTC. The storm likely was tornadic, but because it was dark, visual confirmation of any tornadoes was not possible. A damage survey was completed after the storm moved through the area. The final conclusion of the damage survey prior to this analysis was that there were two tornadoes near Shamrock, Texas: one that formed prior to 0300 UTC and one that formed at or after 0300 UTC. High-resolution, mobile, Doppler radar data of the supercell were compared with the damage survey information at different times. The location of the first tornado damage path was not consistent with the locations of the low-level circulations in the supercell identified through the mobile, Doppler radar data. The damage within the first path, which consisted mostly of downed trees, may have been caused by straight-line winds in a squall line that moved through the area after the passage of the supercell. The mobile, Doppler radar data did not provide any supporting evidence for the first tornado, but the data did support the existence of the second tornado in Wheeler County on the evening of 15 May 2003. Ground-based, mobile, Doppler radar data may be used as an important tool to help to confirm (or deny) tornado damage reports in situations in which a damage survey cannot be completed or in which the survey does not provide clear evidence as to what phenomenon caused the damage. C1 [French, Michael M.; Bluestein, Howard B.] Univ Oklahoma, Sch Meteorol, Norman, OK 73072 USA. [Wicker, Louis J.] Natl Severe Storms Lab, Norman, OK 73069 USA. [Dowell, David C.] Cooperat Inst Mesoscale Meteorol Studies, Norman, OK USA. [Kramar, Matthew R.] NOAA, Natl Weather Serv Weather Forecast Off, Amarillo, TX USA. RP French, MM (reprint author), Univ Oklahoma, Sch Meteorol, 120 David L Boren Blvd,Suite 5900, Norman, OK 73072 USA. EM mfrench@ou.edu RI Dowell, David/E-7855-2015 FU NSF [ATM-0241037, ATM-0637148, ATM-0437898] FX The authors thank Michael Biggerstaff and Alan Shapiro, both of whom reviewed early drafts of this work within the first author's master's thesis at the University of Oklahoma. Thanks also are given to Curtis Alexander and Al Pietrycha, who provided useful damage information. This study was supported by NSF Grants ATM-0241037, ATM-0637148, and ATM-0437898 (DCD). NR 18 TC 3 Z9 3 U1 0 U2 1 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0882-8156 J9 WEATHER FORECAST JI Weather Forecast. PD JUN PY 2009 VL 24 IS 3 BP 884 EP 891 DI 10.1175/2008WAF2222147.1 PG 8 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 467SQ UT WOS:000267763100016 ER PT J AU Coston-Clements, L Waggett, RJ Tester, PA AF Coston-Clements, Linda Waggett, Rebecca J. Tester, Patricia A. TI Chaetognaths of the United States South Atlantic Bight: Distribution, abundance and potential interactions with newly spawned larval fish SO JOURNAL OF EXPERIMENTAL MARINE BIOLOGY AND ECOLOGY LA English DT Article DE Competition; Daily ration; Larval fish; Metabolic requirements; Predation; Sagitta enflata; Sagitta hispida; Sagitta tenuis; United States South Atlantic Bight ID NORTH-CAROLINA ESTUARY; LEIOSTOMUS-XANTHURUS; SAGITTA-ENFLATA; MICROPOGONIAS-UNDULATUS; VERTICAL-DISTRIBUTION; EUKROHNIA-HAMATA; BREVOORTIA-PATRONUS; FEEDING-BEHAVIOR; SARGASSO SEA; PREY SIZE AB Chaetognaths are one of the most numerous organisms in the zooplankton community off the coast of North Carolina. During two years of offshore sampling in the late winter to early spring, sixteen chaetognath species were identified, four of which had not previously been reported in the waters of the United States South Atlantic Bight. Offshore samples were dominated by Sagitta enflata Grassi, 1881, one of the larger species, which contributed >61% of total chaetognath abundance while dominant coastal species were S. tenuis Conant, 1896 and S. hispida Conant, 1895. Abundances, body sizes and spatial distributions were determined for the most abundant chaetognath species along with the overall abundance of three common co-occurring larval fish species (spot, Atlantic croaker and Atlantic menhaden). In addition, laboratory feeding experiments were conducted using S. tenuis and S. hispida to estimate the potential impact of chaetognath predation on representative North Carolina larval fish which spawn offshore and subsequently migrate into local estuaries. Feeding rates (no. prey items day(-1)) varied with prey type and the condition (starved/fed) of the chaetognath. Weight specific daily rations (SDR) were found to vary inversely with chaetognath size, decreasing exponentially with an increase in chaetognath length. The observed abundance and distribution data indicate that wintertime chaetognath populations in offshore waters of Onslow Bay, North Carolina have the potential to interact with recently spawned larval fish and may simultaneously act as competitors, predators, or prey. Furthermore, calculations using published values of chaetognath abundance, zooplankton standing crops, and our SDR estimates indicate that chaetognaths in a representative North Carolina estuary would require a minimum of 5.96 cal m(-3) day(-1) to sustain their biomass. Allowing for the reported spatial and temporal variability in zooplankton abundance in these systems, chaetognaths should consume 4.4%-20.9% of the estimated total zooplankton production day(-1). This further emphasizes the role of chaetognaths not only as predators, but also as competitors with larval fish for zooplankton food stocks in southeastern United Sates estuaries. Published by Elsevier B.V. C1 [Waggett, Rebecca J.; Tester, Patricia A.] Natl Ocean Serv, Natl Ocean & Atmospher Adm, Beaufort, NC 28516 USA. [Coston-Clements, Linda] Natl Marine Fisheries Serv, SE Fisheries Sci Ctr, Beaufort, NC 28516 USA. RP Tester, PA (reprint author), Natl Ocean Serv, Natl Ocean & Atmospher Adm, 101 Pivers Isl Rd, Beaufort, NC 28516 USA. EM Pat.Tester@noaa.gov FU National Marine Fisheries Service; NOAA; United States Department of Energy FX We are grateful to the scientists and crew aboard the R/V John de Wolf II, to A. Alvarino and G. Grant for identification of chaetognaths, to D. Colby, D. Peters, G. Bath-Martin and D. Ahrenholz for reviewing the manuscript, and to D. Hoss for encouragement and guidance during the study. This research was funded in part by a cooperative agreement between the National Marine Fisheries Service, NOAA and the United States Department of Energy. [SS] NR 85 TC 8 Z9 10 U1 3 U2 17 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-0981 EI 1879-1697 J9 J EXP MAR BIOL ECOL JI J. Exp. Mar. Biol. Ecol. PD MAY 31 PY 2009 VL 373 IS 2 BP 111 EP 123 DI 10.1016/j.jembe.2009.03.008 PG 13 WC Ecology; Marine & Freshwater Biology SC Environmental Sciences & Ecology; Marine & Freshwater Biology GA 457AQ UT WOS:000266897400005 ER PT J AU Stambulchik, E Bernshtam, V Weingarten, L Kroupp, E Fisher, D Maron, Y Zastrau, U Uschmann, I Zamponi, F Forster, E Sengebusch, A Reinholz, H Ropke, G Ralchenko, Y AF Stambulchik, E. Bernshtam, V. Weingarten, L. Kroupp, E. Fisher, D. Maron, Y. Zastrau, U. Uschmann, I. Zamponi, F. Foerster, E. Sengebusch, A. Reinholz, H. Roepke, G. Ralchenko, Yu TI Progress in line-shape modeling of K-shell transitions in warm dense titanium plasmas SO JOURNAL OF PHYSICS A-MATHEMATICAL AND THEORETICAL LA English DT Article; Proceedings Paper CT International Conference on Strongly Coupled Coulomb Systems CY JUL 29-AUG 02, 2008 CL Univ Camerino, Camerino, ITALY HO Univ Camerino ID EMISSION; STATES; IONS AB Modeling of x-ray spectra emitted from a solid-density strongly coupled plasma formed in short-duration, high-power laser-matter interactions represents a highly challenging task due to extreme conditions found in these experiments. In this paper we present recent progress in the modeling and analysis of K alpha emission from solid-density laser-produced titanium plasmas. The self-consistent modeling is based on collisional-radiative calculations that comprise many different processes and effects, such as satellite formation and blending, plasma polarization, Stark broadening, solid-density quantum effects and self-absorption. A rather strong dependence of the Ka shape on the bulk electron temperature is observed. Preliminary analysis of recently obtained experimental data shows a great utility of the calculations, allowing for inferring a temperature distribution of the bulk electrons from a single-shot measurement. C1 [Stambulchik, E.; Bernshtam, V.; Weingarten, L.; Kroupp, E.; Fisher, D.; Maron, Y.] Weizmann Inst Sci, Fac Phys, IL-76100 Rehovot, Israel. [Zastrau, U.; Uschmann, I.; Zamponi, F.; Foerster, E.] Univ Jena, Inst Opt & Quantum Elect, D-07743 Jena, Germany. [Sengebusch, A.; Reinholz, H.; Roepke, G.] Univ Rostock, Inst Phys, D-18051 Rostock, Germany. [Reinholz, H.] Univ Western Australia, Sch Phys, Crawley, WA 6009, Australia. [Ralchenko, Yu] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Stambulchik, E (reprint author), Weizmann Inst Sci, Fac Phys, IL-76100 Rehovot, Israel. EM Evgeny.Stambulchik@weizmann.ac.il RI Ralchenko, Yuri/B-7687-2011; Stambulchik, Evgeny/K-1816-2012; Ralchenko, Yuri/E-9297-2016 OI Stambulchik, Evgeny/0000-0002-7100-8793; Ralchenko, Yuri/0000-0003-0083-9554 NR 24 TC 13 Z9 13 U1 0 U2 2 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 1751-8113 J9 J PHYS A-MATH THEOR JI J. Phys. A-Math. Theor. PD MAY 29 PY 2009 VL 42 IS 21 AR 214056 DI 10.1088/1751-8113/42/21/214056 PG 10 WC Physics, Multidisciplinary; Physics, Mathematical SC Physics GA 446NX UT WOS:000266129400057 ER PT J AU Lester, SE Halpern, BS Grorud-Colvert, K Lubchenco, J Ruttenberg, BI Gaines, SD Airame, S Warner, RR AF Lester, Sarah E. Halpern, Benjamin S. Grorud-Colvert, Kirsten Lubchenco, Jane Ruttenberg, Benjamin I. Gaines, Steven D. Airame, Satie Warner, Robert R. TI Biological effects within no-take marine reserves: a global synthesis SO MARINE ECOLOGY PROGRESS SERIES LA English DT Article DE Marine reserves; Temperate; Tropical; Fishes; Invertebrates; Algae; Marine Protected Area; Conservation ID PROTECTED AREAS; FISH POPULATIONS; CORAL-REEFS; CONCHOLEPAS-CONCHOLEPAS; CONSERVATION BENEFITS; LARVAL DISPERSAL; CENTRAL CHILE; MANAGEMENT; RECOVERY; IMPACTS AB The study and implementation of no-take marine reserves have increased rapidly over the past decade, providing ample data on the biological effects of reserve protection for a wide range of geographic locations and organisms. The plethora of new studies affords the opportunity to re-evaluate previous findings and address formerly unanswered questions with extensive data syntheses. Our results show, on average, positive effects of reserve protection on the biomass, numerical density, species richness, and size of organisms within their boundaries which are remarkably similar to those of past syntheses despite a near doubling of data. New analyses indicate that (1) these results do not appear to be an artifact of reserves being sited in better locations; (2) results do not appear to be driven by displaced fishing effort outside of reserves; (3) contrary to often-made assertions, reserves have similar if not greater positive effects in temperate settings, at least for reef ecosystems; (4) even small reserves can produce significant biological responses irrespective of latitude, although more data are needed to test whether reserve effects scale with reserve size; and (5) effects of reserves vary for different taxonomic groups and for taxa with various characteristics, and not all species increase in response to reserve protection. There is considerable variation in the responses documented across all the reserves in our data set-variability which cannot be entirely explained by which species were studied. We suggest that reserve characteristics and context, particularly the intensity of fishing outside the reserve and inside the reserve before implementation, play key roles in determining the direction and magnitude of the reserve response. However, despite considerable variability, positive responses are far more common than no differences or negative responses, validating the potential for well designed and enforced reserves to serve as globally important conservation and management tools. C1 [Lester, Sarah E.; Gaines, Steven D.; Airame, Satie; Warner, Robert R.] Univ Calif Santa Barbara, Inst Marine Sci, Santa Barbara, CA 93106 USA. [Halpern, Benjamin S.] Natl Ctr Ecol Anal & Synth, Santa Barbara, CA 93101 USA. [Grorud-Colvert, Kirsten; Lubchenco, Jane] Oregon State Univ, Dept Zool, Corvallis, OR 97331 USA. [Ruttenberg, Benjamin I.] SE Fisheries Sci Ctr, Natl Marine Fisheries Serv, Miami, FL 33149 USA. [Gaines, Steven D.; Warner, Robert R.] Univ Calif Santa Barbara, Dept Ecol Evolut & Marine Biol, Santa Barbara, CA 93106 USA. RP Lester, SE (reprint author), Univ Calif Santa Barbara, Inst Marine Sci, Santa Barbara, CA 93106 USA. EM lester@msi.ucsb.edu RI Warner, Robert/M-5342-2013; Ruttenberg, Benjamin/D-2556-2012 OI Warner, Robert/0000-0002-3299-5685; FU David and Lucile Packard Foundation; Gordon and Betty Moore Foundation [335]; NOAA Dr, Nancy Foster Scholarship FX This work was supported by the Partnership for Interdisciplinary Studies of Coastal Oceans (PISCO), funded by the David and Lucile Packard Foundation and the Gordon and Betty Moore Foundation (contribution no. 335). This analysis contributed to The Science of Marine Reserves, an educational booklet funded by the David and Lucile Packard Foundation. S.E.L. was also supported by a NOAA Dr, Nancy Foster Scholarship. We thank S. Palumbi and P. Guarderas for discussions about the data set, W. McClintock for the global marine reserve map, A. Rassweiler for help with some analyses, and several anonymous reviewers for helpful comments on previous versions of the manuscript. NR 55 TC 434 Z9 437 U1 32 U2 271 PU INTER-RESEARCH PI OLDENDORF LUHE PA NORDBUNTE 23, D-21385 OLDENDORF LUHE, GERMANY SN 0171-8630 J9 MAR ECOL PROG SER JI Mar. Ecol.-Prog. Ser. PD MAY 29 PY 2009 VL 384 BP 33 EP 46 DI 10.3354/meps08029 PG 14 WC Ecology; Marine & Freshwater Biology; Oceanography SC Environmental Sciences & Ecology; Marine & Freshwater Biology; Oceanography GA 463BS UT WOS:000267404000004 ER PT J AU Clarke, LM Walther, BD Munch, SB Thorrold, SR Conover, DO AF Clarke, Lora M. Walther, Benjamin D. Munch, Stephan B. Thorrold, Simon R. Conover, David O. TI Chemical signatures in the otoliths of a coastal marine fish, Menidia menidia, from the northeastern United States: spatial and temporal differences SO MARINE ECOLOGY PROGRESS SERIES LA English DT Article DE Otolith chemistry; Menidia menidia; Population structure; Natural tag; Natal fingerprint ID COD GADUS-MORHUA; CORAL-REEF FISH; ATLANTIC SILVERSIDE; ELEMENTAL SIGNATURES; TRACE-ELEMENTS; GROWTH-RATE; ARAGONITIC OTOLITHS; QUALITY-ASSURANCE; SELF-RECRUITMENT; NURSERY HABITATS AB Knowledge of population structure in marine systems is fundamental to effective management and conservation. The geochemical signature of otoliths may provide a promising natural tag for quantifying population structure in marine fishes. However, the spatial scale at which chemical signatures differ among species from different environments and with different life histories is not yet clear. We examined chemical signatures in the otoliths of juvenile Menidia menidia, a ubiquitous nearshore marine species found along the east coast of North America that undergoes offshore winter migration. Specimens were collected from 16 locations in 2003 and from 9 locations in 2004 between New Jersey and Maine. Otolith geochemistry was analyzed using laser ablation inductively coupled plasma-mass spectrometry and isotope ratio mass spectrometry. Juvenile fish showed significant site-specific differences and were assigned to natal sites with 70% (2003) and 77% (2004) average cross-validated classification accuracies based on elemental (Mg, Mn, Sr, Ba, Cu, and Pb relative to Ca) and isotope (delta C-13, delta O-18) ratios using quadratic discriminant function analysis. Geochemical signatures showed significant interannual variation, suggesting natural tags are year-class specific. Results suggest enough heterogeneity exists in marine chemical signatures to track movements and determine whether M menidia return to their natal, nearshore location upon return from winter migration. Because M menidia show evidence of local adaptation, knowledge of this winter migration will have evolutionary and ecological implications. Geochemical signatures of otoliths will likely serve as a useful tool in species with similar life histories. C1 [Clarke, Lora M.; Munch, Stephan B.; Conover, David O.] SUNY Stony Brook, Marine Sci Res Ctr, Stony Brook, NY 11794 USA. [Walther, Benjamin D.; Thorrold, Simon R.] Woods Hole Oceanog Inst, Dept Biol, Woods Hole, MA 02543 USA. RP Clarke, LM (reprint author), NOAA Fisheries, 1315 EW Highway, Silver Spring, MD 20910 USA. EM lora_clarke@yahoo.com RI Walther, Benjamin/A-7284-2009; Thorrold, Simon/B-7565-2012 OI Walther, Benjamin/0000-0002-2902-4001; Thorrold, Simon/0000-0002-1533-7517 FU National Science Foundation [OCE-0425830, OCE-0134998]; New York State Department of Environmental Conservation; Woods Hole Oceanographic Institution Academic Programs Office FX This work was funded by the National Science Foundation (Grant OCE-0425830 to D.O.C. and OCE-0134998 to S.R.T.) and the New York State Department of Environmental Conservation. B.D.W. was supported by the Woods Hole Oceanographic Institution Academic Programs Office. We thank past and present members of the Conover Laboratory, K. Able, S. Hagan, R. Hagan, J. Socrates, and J. FitzGerald for help with sample collections. We thank S. Birdwhistell and D. Ostermann for assistance with the otolith analyses, and S. Sanudo for use of laboratory space. We also thank R. Cerrato for helpful comments on the manuscript. NR 57 TC 21 Z9 21 U1 0 U2 16 PU INTER-RESEARCH PI OLDENDORF LUHE PA NORDBUNTE 23, D-21385 OLDENDORF LUHE, GERMANY SN 0171-8630 J9 MAR ECOL PROG SER JI Mar. Ecol.-Prog. Ser. PD MAY 29 PY 2009 VL 384 BP 261 EP 271 DI 10.3354/meps07927 PG 11 WC Ecology; Marine & Freshwater Biology; Oceanography SC Environmental Sciences & Ecology; Marine & Freshwater Biology; Oceanography GA 463BS UT WOS:000267404000022 ER PT J AU Stone, KW Gundogdu, K Turner, DB Li, XQ Cundiff, ST Nelson, KA AF Stone, Katherine W. Gundogdu, Kenan Turner, Daniel B. Li, Xiaoqin Cundiff, Steven T. Nelson, Keith A. TI Two-Quantum 2D FT Electronic Spectroscopy of Biexcitons in GaAs Quantum Wells SO SCIENCE LA English DT Article ID 2-DIMENSIONAL INFRARED-SPECTROSCOPY; NONLINEAR-OPTICAL RESPONSE; HEAVY-HOLE; MANY-BODY; SEMICONDUCTORS; COHERENCES; EXCITONS AB The motions of electrons in solids may be highly correlated by strong, long-range Coulomb interactions. Correlated electron-hole pairs (excitons) are accessed spectroscopically through their allowed single-quantum transitions, but higher-order correlations that may strongly influence electronic and optical properties have been far more elusive to study. Here we report direct observation of bound exciton pairs (biexcitons) that provide incisive signatures of four-body correlations among electrons and holes in gallium arsenide (GaAs) quantum wells. Four distinct, mutually coherent, ultrashort optical pulses were used to create coherent exciton states, transform these successively into coherent biexciton states and then new radiative exciton states, and finally to read out the radiated signals, yielding biexciton binding energies through a technique closely analogous to multiple-quantum two-dimensional Fourier transform (2D FT) nuclear magnetic resonance spectroscopy. A measured variation of the biexciton dephasing rate indicated still higher-order correlations. C1 [Stone, Katherine W.; Gundogdu, Kenan; Turner, Daniel B.; Nelson, Keith A.] MIT, Dept Chem, Cambridge, MA 02139 USA. [Li, Xiaoqin] Univ Texas Austin, Dept Phys, Austin, TX 78712 USA. [Cundiff, Steven T.] Univ Colorado, JILA, Boulder, CO 80309 USA. [Cundiff, Steven T.] Natl Inst Stand & Technol, Boulder, CO 80309 USA. RP Nelson, KA (reprint author), MIT, Dept Chem, Cambridge, MA 02139 USA. EM kanelson@mit.edu RI Cundiff, Steven/B-4974-2009 OI Cundiff, Steven/0000-0002-7119-5197 FU NSF [CHE-0616939]; National Defense Science and Engineering Graduate Fellowship Program; Army Research Office; Welch Foundation FX This work was supported in part by NSF grant CHE-0616939. The authors thank M. Kira for helpful discussions. D.T. thanks the National Defense Science and Engineering Graduate Fellowship Program for financial support. X.L. acknowledges support from the Army Research Office and the Welch Foundation. A patent application for the optical setup presented here is currently being filed. NR 39 TC 146 Z9 147 U1 4 U2 49 PU AMER ASSOC ADVANCEMENT SCIENCE PI WASHINGTON PA 1200 NEW YORK AVE, NW, WASHINGTON, DC 20005 USA SN 0036-8075 J9 SCIENCE JI Science PD MAY 29 PY 2009 VL 324 IS 5931 BP 1169 EP 1173 DI 10.1126/science.1170274 PG 5 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA 450OG UT WOS:000266410100037 PM 19478176 ER PT J AU Zuerner, RL Cameron, CE Raverty, S Robinson, J Colegrove, KM Norman, SA Lambourn, D Jeffries, S Alt, DP Gulland, F AF Zuerner, Richard L. Cameron, Caroline E. Raverty, Stephen Robinson, John Colegrove, Kathleen M. Norman, Stephanie A. Lambourn, Dyanna Jeffries, Steven Alt, David P. Gulland, Frances TI Geographical dissemination of Leptospira interrogans serovar Pomona during seasonal migration of California sea lions SO VETERINARY MICROBIOLOGY LA English DT Article DE Leptospirosis; California sea lions; Zoonosis ID SURFACE-EXPOSED LIPOPROTEIN; GULF-OF-CALIFORNIA; PCR; IDENTIFICATION; DIFFERENTIATION; BORGPETERSENII; HYBRIDIZATION; INFECTION; HARDJO; GROWTH AB Leptospirosis is one of the most widespread bacterial zoonoses in the world and affects most mammalian species. Although leptospirosis is well documented and characterized in terrestrial species, less information is available regarding the distribution and impact of leptospirosis in marine mammals. Additionally, the role of animal migrations on the geographical spread of leptospirosis has not been reported. Periodic epizootic outbreaks of acute leptospirosis among California sea lions (Zalophus californianus) have been reported since 1971. In this study, we collected samples from California sea lions stranded along the Pacific coast of North America during the most recent epidemic in 2004, and maintained leptospirosis surveillance of the California sea lion population along the California coast through 2007. Several isolates of Leptospira interrogans serovar Pomona were obtained from kidney and urine samples collected during this study, a finding consistent with serological evidence that California sea lions are persistently exposed to this leptospiral serovar. Combined, these data support a model whereby California sea lions are maintenance hosts for L. interrogans serovar Pomona, yet periodically undergo outbreaks of acute infection. During the 2004 outbreak, the incidence of new leptospirosis cases among California sea lions coincided with the seasonal movement of male sea lions from rookeries along the coast of central and southern California north as far as British Columbia. These data show that seasonal animal movement contributes to the distribution of leptospirosis across a large geographical region. Published by Elsevier B.V. C1 [Zuerner, Richard L.; Alt, David P.] Natl Anim Dis Ctr, Ames, IA 50010 USA. [Cameron, Caroline E.] Univ Victoria, Dept Biochem & Microbiol, Victoria, BC V8W 3P6, Canada. [Raverty, Stephen; Robinson, John] Minist Agr Food & Fisheries, Abbotsford, BC V3G 2M3, Canada. [Colegrove, Kathleen M.] Univ Calif Davis, Vet Med Teaching Hosp, Davis, CA 95616 USA. [Norman, Stephanie A.] Natl Marine Fisheries Serv, NOAA, Protected Resources Div, Seattle, WA 98115 USA. [Lambourn, Dyanna; Jeffries, Steven] Wildlife Sci Program, Washington Dept Fish & Wildlife, Tacoma, WA 98498 USA. [Gulland, Frances] Marine Mammal Ctr, Sausalito, CA 94965 USA. RP Zuerner, RL (reprint author), Natl Anim Dis Ctr, POB 70, Ames, IA 50010 USA. EM Richard.Zuerner@ars.usda.gov NR 35 TC 10 Z9 10 U1 1 U2 19 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0378-1135 J9 VET MICROBIOL JI Vet. Microbiol. PD MAY 28 PY 2009 VL 137 IS 1-2 BP 105 EP 110 DI 10.1016/j.vetmic.2008.12.017 PG 6 WC Microbiology; Veterinary Sciences SC Microbiology; Veterinary Sciences GA 452YZ UT WOS:000266578400015 PM 19186009 ER PT J AU Oguchi, H Heilweil, EJ Josell, D Bendersky, LA AF Oguchi, H. Heilweil, E. J. Josell, D. Bendersky, L. A. TI Infrared emission imaging as a tool for characterization of hydrogen storage materials SO JOURNAL OF ALLOYS AND COMPOUNDS LA English DT Article DE Hydrogen storage; Combinatorial; IR emissivity; Films; Mg-Ni ID TITANIUM-ALUMINUM MULTILAYERS; SWITCHABLE OPTICAL-PROPERTIES; STRUCTURAL TRANSFORMATIONS; COMBINATORIAL APPROACH; METAL-HYDRIDES; THIN-FILMS; MAGNESIUM; MG; PRESSURE; DIFFRACTION AB Combinatorial thin films provide an opportunity for studying a variety of properties over a wide range of compositions and microstructures on a single substrate, allowing substantial acceleration of both the fabrication and study of materials and their properties. This paper details the use of infrared (IR) emissivity imaging for studying the in situ hydrogenation of MgxNi1-x films with hydrogen gas; the method is shown to be a powerful combinatorial screening tool for metal hydride storage materials. The 100 nm thick MgxNi1-x composition gradient films (0.4 < x < 0.9) capped with a Pd layer of varying thickness were deposited in a combinatorial electron-beam deposition chamber using a shutter-controlled multilayer technique. The microstructure of as-deposited and 250 degrees C-annealed films was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). TEM studies of the "X-ray amorphous" films show that the microstructure consists of nano-scale grains of a metastable fcc phase as well as Mg2Ni and MgNi2 phases over a broad range of higher Ni compositions. The metastable phase appears to be a Ni-stabilized fcc form of Mg. Hydrogenation differences between the studied films and bulk alloys are suggested to be associated primarily with crystallographic differences of the metallic and hydride phases. Hydrogen absorption and desorption of the films were monitored with an infrared camera capable of simultaneously imaging the entire composition spread. The observed changes in infrared intensity during hydrogen loading/unloading demonstrate the sensitivity of the method to hydrogen absorption behavior of different compositions and microstructures. (C) 2008 Elsevier B.V. All rights reserved. C1 [Josell, D.; Bendersky, L. A.] Natl Inst Stand & Technol, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA. [Heilweil, E. J.] Natl Inst Stand & Technol, Phys Lab, Gaithersburg, MD 20899 USA. [Oguchi, H.] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. RP Bendersky, LA (reprint author), Natl Inst Stand & Technol, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA. EM leoben@nist.gov RI Oguchi, Hiroyuki/R-5305-2016 NR 58 TC 10 Z9 10 U1 0 U2 11 PU ELSEVIER SCIENCE SA PI LAUSANNE PA PO BOX 564, 1001 LAUSANNE, SWITZERLAND SN 0925-8388 J9 J ALLOY COMPD JI J. Alloy. Compd. PD MAY 27 PY 2009 VL 477 IS 1-2 BP 8 EP 15 DI 10.1016/j.jallcom.2008.10.053 PG 8 WC Chemistry, Physical; Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Chemistry; Materials Science; Metallurgy & Metallurgical Engineering GA 450FM UT WOS:000266386400015 ER PT J AU Stalick, JK Waterstrat, RM AF Stalick, J. K. Waterstrat, R. M. TI The crystal structure of martensitic ZrIr and ZrRh SO JOURNAL OF ALLOYS AND COMPOUNDS LA English DT Article DE Shape memory alloys; Crystal structure; Neutron diffraction AB The crystal structures of the martensitic shape memory alloys ZrIr and ZrRh have been determined using neutron powder diffraction data. These materials belong to a new structure type space group, Cmcm,Z = 8, with a = 3.3686(4)angstrom, b = 19.608(3)angstrom, c = 4.3982(5)angstrom for ZrIr and a = 3.3394(4)angstrom b = 19 590(3)angstrom, c = 4.3940(5)angstrom for ZrRh. Published by Elsevier B.V. C1 [Stalick, J. K.] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Waterstrat, R. M.] Natl Inst Stand & Technol, Div Met, Gaithersburg, MD 20899 USA. RP Stalick, JK (reprint author), Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. EM judith.stalick@nist.gov NR 9 TC 3 Z9 3 U1 0 U2 1 PU ELSEVIER SCIENCE SA PI LAUSANNE PA PO BOX 564, 1001 LAUSANNE, SWITZERLAND SN 0925-8388 J9 J ALLOY COMPD JI J. Alloy. Compd. PD MAY 27 PY 2009 VL 477 IS 1-2 BP 123 EP 126 DI 10.1016/j.jallcom.2008.09.138 PG 4 WC Chemistry, Physical; Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Chemistry; Materials Science; Metallurgy & Metallurgical Engineering GA 450FM UT WOS:000266386400034 ER PT J AU Nan, SL Zhao, P Yang, S Chen, JM AF Nan, Sulan Zhao, Ping Yang, Song Chen, Junming TI Springtime tropospheric temperature over the Tibetan Plateau and evolutions of the tropical Pacific SST SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID ASIAN SUMMER MONSOON; SEA-SURFACE TEMPERATURE; INTERANNUAL TIME SCALES; TRADE-WIND SYSTEM; ATMOSPHERIC HEAT SOURCE/SINK; EL-NINO; SOUTHERN-OSCILLATION; CLIMATE MODEL; SNOW DEPTH; ENSO AB Using monthly mean data from the National Centers for Environmental Prediction-National Center for Atmospheric Research (NCAR) reanalysis and HadISST SST data sets, we investigate the relationship between springtime tropospheric temperature over the Tibetan Plateau and sea surface temperature (SST) over the equatorial Pacific and the associated physical processes. When the Tibetan temperature is low (high) in spring, positive (negative) SST anomalies appear over the tropical central-eastern Pacific in spring and summer. The relationship is explained by the Asian-Pacific Oscillation (APO) and the ocean-atmosphere interaction over the tropical Pacific. In the context of the APO, a lower spring Tibetan tropospheric temperature is associated with a higher tropospheric temperature over the subtropical North Pacific, which is accompanied by a weaker subtropical high over the eastern North Pacific. Accordingly, large-scale westerly anomalies appear in the lower troposphere of the equatorial central-eastern Pacific, resulting in an increase in SST over the equatorial central-eastern Pacific. Numerical simulations with both an ocean-atmosphere coupled model (the NCAR Community Climate System Model version 3) and an atmospheric model with a prescribed SST scheme (the NCAR Community Atmospheric Model version 3) demonstrate the impacts of the spring Tibetan thermal condition on the tropospheric temperature and atmospheric circulation over the Asian-Pacific sector and then on the SST over the equatorial eastern Pacific, better explaining the physical processes of the observed Tibetan temperature-Pacific SST relationship. C1 [Nan, Sulan; Chen, Junming] Chinese Acad Meteorol Sci, Inst Climate Syst, Beijing 100081, Peoples R China. [Yang, Song] NOAA, Climate Predict Ctr, Camp Springs, MD 20746 USA. [Zhao, Ping] China Meteorol Adm, Natl Meteorol Informat Ctr, Beijing 100081, Peoples R China. RP Nan, SL (reprint author), Chinese Acad Meteorol Sci, Inst Climate Syst, 46 Zhongguancun Nandajie, Beijing 100081, Peoples R China. EM zhaoping@cams.cma.gov.cn RI Yang, Song/B-4952-2009 FU National Basic Research Program of China [2009CB421402]; National Natural Science Foundation of China [40890052]; Chinese COPES [GYHY200706005] FX We thank the Climate Diagnostic Center/NOAA for providing the NCEP-NCAR reanalysis data and U. K. Meteorological Office, Hadley Center, for providing monthly mean HadISST data on their homepages. We also thank NCAR for providing the CCSM3 and CAM3 models on its homepage. This work was jointly sponsored by National Basic Research Program of China (2009CB421402), National Natural Science Foundation of China (40890052), and Chinese COPES project (GYHY200706005). NR 39 TC 25 Z9 27 U1 1 U2 13 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X EI 2169-8996 J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD MAY 23 PY 2009 VL 114 AR D10104 DI 10.1029/2008JD011559 PG 13 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 449XL UT WOS:000266364000007 ER PT J AU Neuman, JA Nowak, JB Zheng, W Flocke, F Ryerson, TB Trainer, M Holloway, JS Parrish, DD Frost, GJ Peischl, J Atlas, EL Bahreini, R Wollny, AG Fehsenfeld, FC AF Neuman, J. A. Nowak, J. B. Zheng, W. Flocke, F. Ryerson, T. B. Trainer, M. Holloway, J. S. Parrish, D. D. Frost, G. J. Peischl, J. Atlas, E. L. Bahreini, R. Wollny, A. G. Fehsenfeld, F. C. TI Relationship between photochemical ozone production and NOx oxidation in Houston, Texas SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID AIR-QUALITY; PRODUCTION EFFICIENCY; REACTIVE NITROGEN; CARBON-MONOXIDE; REGIONAL OZONE; DRY DEPOSITION; UNITED-STATES; EMISSIONS; PLUMES; URBAN AB An instrumented aircraft was used to study anthropogenic emissions and subsequent ozone and reactive nitrogen photochemistry in the continental boundary layer downwind of Houston, Texas. Measurements of ozone, carbon monoxide, NOx, and NOx oxidation products were conducted from the NOAA WP-3 aircraft during the 2006 Texas Air Quality Study under a variety of meteorological conditions. Sixty-five crosswind transects of plumes from Houston urban and industrial areas performed on 10 daytime flights from 13 September to 6 October 2006 are examined. Coincident measurements of NOx and its oxidation products show that NOx was oxidized predominately to nitric acid and peroxy acyl nitrates on time scales of a few hours. The observed relationships between O-3 and NOx oxidation products are affected by both photochemistry and mixing of different air masses. On four flights, background pollutant mixing ratios were constant and CO to NOy enhancement ratios in downwind plume transects remained at the emission ratio. The enhancement ratio of O-3 to NOx oxidation products was also nearly constant and could be used to derive ozone production efficiency (OPE) in plumes downwind from the Houston area. On the other flights, variable mixing of regionally polluted background air with plumes caused CO to NOy and O-3 to NOy - NOx enhancement ratios to increase as plumes were transported. In such cases, enhancement ratios do not solely reflect plume processing, and OPE could not be determined. The OPE averages 5.9 +/- 1.2 in coalesced plumes from urban and petrochemical industrial sources in Houston, with higher values in isolated plumes downwind from petrochemical facilities located along the Houston ship channel. C1 [Neuman, J. A.; Nowak, J. B.; Holloway, J. S.; Frost, G. J.; Peischl, J.; Bahreini, R.; Wollny, A. G.; Fehsenfeld, F. C.] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. [Atlas, E. L.] Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, Miami, FL 33149 USA. [Zheng, W.; Flocke, F.] Natl Ctr Atmospher Res, Div Atmospher Chem, Boulder, CO 80305 USA. [Neuman, J. A.; Nowak, J. B.; Ryerson, T. B.; Trainer, M.; Holloway, J. S.; Parrish, D. D.; Frost, G. J.; Peischl, J.; Bahreini, R.; Wollny, A. G.; Fehsenfeld, F. C.] NOAA, Earth Syst Res Lab, Boulder, CO 80305 USA. RP Neuman, JA (reprint author), Univ Colorado, Cooperat Inst Res Environm Sci, UCB 216, Boulder, CO 80309 USA. EM andy.neuman@noaa.gov RI Holloway, John/F-9911-2012; Trainer, Michael/H-5168-2013; Fehsenfeld, Frederick/I-4876-2013; Atlas, Elliot/J-8171-2015; Manager, CSD Publications/B-2789-2015; Parrish, David/E-8957-2010; Frost, Gregory/I-1958-2013; Peischl, Jeff/E-7454-2010; Nowak, John/B-1085-2008; Neuman, Andy/A-1393-2009; Ryerson, Tom/C-9611-2009 OI Holloway, John/0000-0002-4585-9594; Parrish, David/0000-0001-6312-2724; Peischl, Jeff/0000-0002-9320-7101; Nowak, John/0000-0002-5697-9807; Neuman, Andy/0000-0002-3986-1727; FU National Oceanic and Atmospheric Administration (NOAA); Texas Commission on Environmental Quality (TCEQ) [582-8-86246] FX The Air Quality and the Climate Research and Modeling Programs of the National Oceanic and Atmospheric Administration (NOAA) and the Texas Commission on Environmental Quality (TCEQ) supported the WP-3 measurements. Much of the analysis was supported by TCEQ under grant 582-8-86246. J.A.N. thanks Charles Brock and Ann Middlebrook for helpful discussions and for providing measurements of particle size and composition. NR 28 TC 19 Z9 19 U1 5 U2 17 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X EI 2169-8996 J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD MAY 23 PY 2009 VL 114 AR D00F08 DI 10.1029/2008JD011688 PG 12 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 449XL UT WOS:000266364000008 ER PT J AU Pierce, RB Al-Saadi, J Kittaka, C Schaack, T Lenzen, A Bowman, K Szykman, J Soja, A Ryerson, T Thompson, AM Bhartia, P Morris, GA AF Pierce, R. Bradley Al-Saadi, Jassim Kittaka, Chieko Schaack, Todd Lenzen, Allen Bowman, Kevin Szykman, Jim Soja, Amber Ryerson, Tom Thompson, Anne M. Bhartia, Pawan Morris, Gary A. TI Impacts of background ozone production on Houston and Dallas, Texas, air quality during the Second Texas Air Quality Study field mission SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID TROPOSPHERIC OZONE; MONITORING INSTRUMENT; AURA MISSION; OBJECTIVES; RETRIEVAL; MECHANISM; EMISSIONS; SYSTEM; ASIA; TES AB A major objective of the 2006 Second Texas Air Quality Study (TexAQS II) focused on understanding the effects of regional processes on Houston and Dallas ozone nonattainment areas. Here we quantify the contributions of background (continental scale) ozone production on Houston and Dallas air quality during TexAQS II using ensemble Lagrangian trajectories to identify remote source regions that impact Houston and Dallas background ozone distributions. Global-scale chemical analyses, constrained with composition measurements from instruments on the NASA Aura satellite, are used to provide estimates of background composition along ensemble back trajectories. Lagrangian averaged O-3 net photochemical production (production minus loss, P-L) rates along the back trajectories are used as a metric to classify back trajectories. Results show that the majority (6 out of 9 or 66%) of the periods of high ozone in Houston were associated with periods of enhanced background ozone production. Slightly less than 50% (7 out of 15) of the days with high ozone in the Dallas Metropolitan Statistical Area (MSA) show enhanced background ozone production. Source apportionment studies show that 5-day Lagrangian averaged O-3 P-L in excess of 15 ppbv/d can occur during continental-scale transport to Houston owing to NOy enhancements from emissions within the Southern Great Lakes as well as recirculation of the Houston emissions. Dallas background O-3 P-L is associated with NOy enhancements from emissions within Chicago and Houston. C1 [Pierce, R. Bradley] NOAA, NESDIS, Adv Satellite Prod Branch, Ctr Satellite Applicat & Res,Cooperat Res Program, Madison, WI 53706 USA. [Al-Saadi, Jassim] NASA, Langley Res Ctr, Chem & Dynam Branch, Sci Directorate, Hampton, VA 23681 USA. [Bhartia, Pawan] NASA, Goddard Space Flight Ctr, Atmospheres Lab, Code 613, Greenbelt, MD 20771 USA. [Bowman, Kevin] CALTECH, Jet Prop Lab, Pasadena, CA 91109 USA. [Kittaka, Chieko] Sci Syst & Applicat Inc, Hampton, VA 23666 USA. [Schaack, Todd; Lenzen, Allen] Univ Wisconsin, Ctr Space Sci & Engn, Madison, WI 53706 USA. [Morris, Gary A.] Valparaiso Univ, Dept Phys & Astron, Valparaiso, IN 46383 USA. [Ryerson, Tom] NOAA, Earth Syst Res Lab, Div Chem Sci, Boulder, CO 80305 USA. [Soja, Amber] Natl Inst Aerosp, Hampton, VA 23666 USA. [Thompson, Anne M.] Penn State Univ, Dept Meteorol, University Pk, PA 16802 USA. [Szykman, Jim] NASA, Langley Res Ctr, Natl Exposure Res Lab, Off Res & Dev,US EPA, Hampton, VA 23665 USA. RP Pierce, RB (reprint author), NOAA, NESDIS, Adv Satellite Prod Branch, Ctr Satellite Applicat & Res,Cooperat Res Program, 1225 W Dayton St, Madison, WI 53706 USA. EM brad.pierce@noaa.gov RI Pierce, Robert Bradley/F-5609-2010; Ryerson, Tom/C-9611-2009; Thompson, Anne /C-3649-2014 OI Pierce, Robert Bradley/0000-0002-2767-1643; Thompson, Anne /0000-0002-7829-0920 FU U.S. Department of Energy [DE-AC02-05CH11231] FX Thanks go to Bruce Doddridge of the National Aeronautics and Space Administration, Tropospheric Chemistry Program, and Fred Fehsenfeld of the National Oceanic and Atmospheric Administration Earth Systems Research Laboratory for coordinating the NASA involvement in the TexAQS II field mission. Thanks go to an anonymous reviewer for suggesting the sensitivity studies used to examine the role of intraregional transport during the Houston and Dallas high-ozone days. Support for IONS-06 and RAQMS came from the NASA Tropospheric Chemistry Program. The views, opinions, and findings contained in this report are those of the author(s) and should not be construed as an official National Oceanic and Atmospheric Administration or U. S. Government position, policy, or decision. This research used resources of the National Energy Research Scientific Computing Center, which is supported by the Office of Science of the U.S. Department of Energy under contract DE-AC02-05CH11231. NR 39 TC 21 Z9 21 U1 4 U2 12 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD MAY 23 PY 2009 VL 114 AR D00F09 DI 10.1029/2008JD011337 PG 14 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 449XL UT WOS:000266364000004 ER PT J AU Huber, MG Arif, M Black, TC Chen, WC Gentile, TR Hussey, DS Pushin, DA Wietfeldt, FE Yang, L AF Huber, M. G. Arif, M. Black, T. C. Chen, W. C. Gentile, T. R. Hussey, D. S. Pushin, D. A. Wietfeldt, F. E. Yang, L. TI Precision Measurement of the n-He-3 Incoherent Scattering Length Using Neutron Interferometry SO PHYSICAL REVIEW LETTERS LA English DT Article ID MONTE-CARLO CALCULATIONS; NUCLEI; HE-3 AB We report the first measurement of the low-energy neutron-He-3 incoherent scattering length using neutron interferometry: b(i)(')=(-2.512 +/- 0.012 stat +/- 0.014 syst) fm. This is in good agreement with a recent calculation using the AV18+3N potential. The neutron-He-3 scattering lengths are important for testing and developing nuclear potential models that include three-nucleon forces, effective field theories for few-body nuclear systems, and neutron scattering measurements of quantum excitations in liquid helium. This work demonstrates the first use of a polarized nuclear target in a neutron interferometer. C1 [Huber, M. G.; Wietfeldt, F. E.] Tulane Univ, New Orleans, LA 70118 USA. [Arif, M.; Chen, W. C.; Gentile, T. R.; Hussey, D. S.; Pushin, D. A.; Yang, L.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. [Black, T. C.] Univ N Carolina, Wilmington, NC 28403 USA. [Chen, W. C.] Indiana Univ, Bloomington, IN 47408 USA. RP Huber, MG (reprint author), Tulane Univ, New Orleans, LA 70118 USA. FU NIST (U.S. Department of Commerce); National Science Foundation [PHY-0555347]; U. S. Department of Energy, Basic Energy Sciences FX We are grateful to the NIST Center for Neutron Research for providing the neutron beam and technical support. We thank Sam Werner and Helmut Kaiser for helpful discussions This work was supported by NIST (U.S. Department of Commerce) and the National Science Foundation through Grant No. PHY-0555347. The development and application of the polarized 3He cells was supported in part by the U. S. Department of Energy, Basic Energy Sciences. NR 26 TC 17 Z9 17 U1 1 U2 2 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 0031-9007 EI 1079-7114 J9 PHYS REV LETT JI Phys. Rev. Lett. PD MAY 22 PY 2009 VL 102 IS 20 AR 200401 DI 10.1103/PhysRevLett.102.200401 PG 4 WC Physics, Multidisciplinary SC Physics GA 449CS UT WOS:000266309000001 PM 19519009 ER PT J AU Faraone, A Fratini, E Todea, AM Krebs, B Muller, A Baglioni, P AF Faraone, Antonio Fratini, Emiliano Todea, Ana Maria Krebs, Bernt Mueller, Achim Baglioni, Piero TI Dynamics of Water in Voids between Well-Defined and Densely Packed Spherical Nanocages Acting as Polyprotic Inorganic Acids SO JOURNAL OF PHYSICAL CHEMISTRY C LA English DT Article ID ELASTIC NEUTRON-SCATTERING; SINGLE-PARTICLE DYNAMICS; GLASS-FORMING POLYMERS; MOLECULAR-DYNAMICS; SUPERCOOLED WATER; CONFINED WATER; SPIN-ECHO; DIFFUSIVE MOTIONS; HYDRATION WATER; SLOW DYNAMICS AB Using quasielastic neutron scattering, we have investigated the water dynamics of powders of the compound with the stoichiometry of [Mo(72)Fe(30)O(252)(CH(3)COO)(12)[Mo(2)O(7)(H(2)O)](2)[H(2) Mo(2)O(8)(H(2)O)](H(2)O)(91)]center dot approximate to 150H(2)O. It contains about 150 crystal water molecules in the voids between the spherical {Mo(72)Fe(30)} nanocapsules, which are considered unique polytropic inorganic acids with well-defined hydrophilic surfaces due to the presence of H(2)O and O atoms. It has been proposed that {Mo(72)Fe(30)} can be used as a structurally well-constrained experimental model of oxide mineral surfaces for earth scientists.(I) In this respect, it is of fundamental importance to understand the dynamics of the water molecules at the surface of the nanoclusters. Our measurements show that the dynamics of these water molecules is as expected profoundly different from that of bulk water at the same temperature, especially because of the strong hydrogen bonding between the crystal and cluster surface water molecules. In fact, our data show a non-Debye relaxation behavior. The momentum transfer dependence of the dynamics is close to that expected for a purely diffusive motion. This suggests that the nonexponentiality of the dynamics originates from a distribution of relaxation times, probably related to the different local environments experienced by the water molecules. The dynamics of the crystal water in the voids between the well-defined and arrayed nanocages is significantly slower than that of bulk water at the same temperature that has often been reported for interfacial water. In the investigated range, the temperature dependence of the relaxation time can be described in terms of an Arrhenius law, indicating that the dynamics is triggered by the breaking of the bonds connecting the crystal water molecules with the hydrophilic nanocage surfaces. C1 [Faraone, Antonio] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Faraone, Antonio] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. [Fratini, Emiliano; Baglioni, Piero] Univ Florence, Dept Chem, I-50019 Florence, Italy. [Fratini, Emiliano; Baglioni, Piero] Univ Florence, CSGI, I-50019 Florence, Italy. [Todea, Ana Maria; Mueller, Achim] Univ Bielefeld, Fak Chem, D-33615 Bielefeld, Germany. [Krebs, Bernt] Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany. RP Faraone, A (reprint author), Natl Inst Stand & Technol, Ctr Neutron Res, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM afaraone@nist.gov; bagglioni@csgi.unifi.it RI Krebs, Bernt/B-9068-2011; Fratini, Emiliano/C-9983-2010; Baglioni, Piero/B-1208-2011 OI Fratini, Emiliano/0000-0001-7104-6530; Baglioni, Piero/0000-0003-1312-8700 FU National Science Foundation [DMR-0454672]; Consorzio Interuniversitario per lo Sviluppo dei Sistemi a Grande Interfase (CSGI); Ministero dell'Istruzione, Universita e della Ricerca Scientifica (MIUR); Deutsche Forschungsgemeinschaft; Fonds der Chemischen Industrie FX The authors are grateful to J. Copley, G. Gasparovic, V. Garcia-Sakai, and T. Jenkins for assistance with the data collection on the DCS and HFBS. The authors are also indebted to J. Copley for critical reading of the manuscript. This work utilized facilities supported in part by the National Science Foundation under Agreement DMR-0454672. E.F. and P.B. acknowledge financial support from the Consorzio Interuniversitario per lo Sviluppo dei Sistemi a Grande Interfase (CSGI) and the Ministero dell'Istruzione, Universita e della Ricerca Scientifica (MIUR, Grant PRIN-2007). A.M. thanks the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie for continuous support. NR 55 TC 5 Z9 5 U1 1 U2 7 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1932-7447 J9 J PHYS CHEM C JI J. Phys. Chem. C PD MAY 21 PY 2009 VL 113 IS 20 BP 8635 EP 8644 DI 10.1021/jp809555s PG 10 WC Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary SC Chemistry; Science & Technology - Other Topics; Materials Science GA 446AY UT WOS:000266093800017 ER PT J AU Shaver, J Srivastava, A Kono, J Crooker, SA Htoon, H Klimov, VI Fagan, JA Hobbie, EK Ubrig, N Portugall, O Perebeinos, V Avouris, PH AF Shaver, J. Srivastava, A. Kono, J. Crooker, S. A. Htoon, H. Klimov, V. I. Fagan, J. A. Hobbie, E. K. Ubrig, N. Portugall, O. Perebeinos, V. Avouris, P. H. TI HIGH FIELD MAGNETO-OPTICAL SPECTROSCOPY OF HIGHLY ALIGNED INDIVIDUAL AND ENSEMBLE SINGLE-WALLED CARBON NANOTUBES SO INTERNATIONAL JOURNAL OF MODERN PHYSICS B LA English DT Article; Proceedings Paper CT 18th International Conference on High Magnetic Fields in Semiconductor Physics and Nanotechnology CY AUG 03-08, 2008 CL Sao Pedro, BRAZIL DE Carbon Nanotubes; Aharonov-Bohm Phase; Excitons; One Dimensionality ID EXCITONS; ABSORPTION; MAGNETOPHOTOLUMINESCENCE; SEMICONDUCTORS; ANISOTROPY AB The tubular nature of single-walled carbon nanotube (SWCNT) crystals allows them to exhibit non-intuitive quantum phenomena when threaded by a magnetic flux, which breaks the time reversal symmetry and adds an Aharonov-Bohm phase to the circumferential boundary conditions on the electronic wave function. We demonstrate that such a symmetry-breaking magnetic field can dramatically "brighten" an optically-inactive, or dark, exciton state at low temperature. This phenomenon, magnetic brightening, can be understood as a consequence of interplay between the strong intervalley Coulomb mixing and field-induced lifting of valley degeneracy. Most recently, we made the direct observation of the dark excitonic state in individual SWCNTs using low-temperature micro-photoluminescence (PL) and and verified the importance of a parallel, tube-threading magentic field with ensemble spectroscopy. For micro-PL, a magnetic field up to 5 T, applied along the nanotube axis, brightened the dark state, leading to the emergence of a new emission peak. The peak rapidly grew in intensity with increasing field at the expense of the originally-dominant bright exciton peak and finally became dominant at fields > 3 T. The directly measured dark-bright splitting values were 1-4 meV for tube diameters 1.0-1.3 run. For ensemble PL, we used fields up to 55 T in two collection geometries to demonstrate the importance of the tube-threading component. These experiments have provided one of the most critical tests for recently-proposed theories of 1-D excitons taking into account the strong 1-D Coulomb interactions and unique band structure on an equal footing. C1 [Shaver, J.; Srivastava, A.; Kono, J.] Rice Univ, Dept Elect & Comp Engn, Houston, TX 77005 USA. [Crooker, S. A.] Los Alamos Natl Lab, Natl High Magnet Field, Los Alamos, NM 87545 USA. [Htoon, H.; Klimov, V. I.] Los Alamos Natl Lab, Ctr Integrated Nanotechnol, Los Alamos, NM 87545 USA. [Fagan, J. A.; Hobbie, E. K.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. [Ubrig, N.; Portugall, O.] Lab Natl Champs Magnet Pulses, F-31400 Toulouse, France. [Perebeinos, V.; Avouris, P. H.] IBM Corp, Div Res, TJ Watson Res Ctr, Yorktown Hts, NY 10598 USA. RP Kono, J (reprint author), Rice Univ, Dept Elect & Comp Engn, Houston, TX 77005 USA. EM kono@rice.edu RI Hobbie, Erik/C-8269-2013; Nicolas, Ubrig/N-9997-2014; OI Nicolas, Ubrig/0000-0002-1966-4435; Shaver, Jonah/0000-0002-9602-7798; Fagan, Jeffrey/0000-0003-1483-5554; Klimov, Victor/0000-0003-1158-3179; Htoon, Han/0000-0003-3696-2896 NR 35 TC 0 Z9 0 U1 0 U2 5 PU WORLD SCIENTIFIC PUBL CO PTE LTD PI SINGAPORE PA 5 TOH TUCK LINK, SINGAPORE 596224, SINGAPORE SN 0217-9792 J9 INT J MOD PHYS B JI Int. J. Mod. Phys. B PD MAY 20 PY 2009 VL 23 IS 12-13 BP 2667 EP 2675 PG 9 WC Physics, Applied; Physics, Condensed Matter; Physics, Mathematical SC Physics GA 457FD UT WOS:000266913000020 ER PT J AU Zikos, G Yang, K Bonesteel, NE Hormozi, L Simon, SH AF Zikos, G. Yang, K. Bonesteel, N. E. Hormozi, L. Simon, S. H. TI BRAIDING AND ENTANGLEMENT IN NONABELIAN QUANTUM HALL STATES SO INTERNATIONAL JOURNAL OF MODERN PHYSICS B LA English DT Article; Proceedings Paper CT 18th International Conference on High Magnetic Fields in Semiconductor Physics and Nanotechnology CY AUG 03-08, 2008 CL Sao Pedro, BRAZIL DE Quantum computation; Quantum Hall effect; Nonabelian statistics ID LANDAU-LEVEL; SPIN CHAINS; COMPUTATION; ANYONS; MODEL AB Certain fractional quantum Hall states, including the experimentally observed nu = 5/2 state, and, possibly, the nu = 12/5 state, may have a sufficiently rich form of topological order (i.e. they may be nonabelian) to be useful for quantum information processing. For example, in some cases they may be used for topological quantum computation, an intrinsically fault tolerant form of quantum computation which is carried out by braiding the world lines of quasiparticle excitations in 2+1 dimensional space time. Here we briefly review the relevant properties of nonabelian quantum Hall states and discuss some of the methods we have found for finding specific braiding patterns which can be used to carry out universal quantum computation using them. Recent work on one-dimensional chains of interacting quasiparticles in nonabelian states is also reviewed. C1 [Zikos, G.; Yang, K.; Bonesteel, N. E.] Florida State Univ, Dept Phys, Tallahassee, FL 32310 USA. [Zikos, G.; Yang, K.; Bonesteel, N. E.] Florida State Univ, NHMFL, Tallahassee, FL 32310 USA. [Hormozi, L.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. [Simon, S. H.] Alcatel Lucent, Murray Hill, NJ 07974 USA. RP Zikos, G (reprint author), Florida State Univ, Dept Phys, 1800 E Paul Dirac Dr, Tallahassee, FL 32310 USA. EM bonestee@magnet.fsu.edu RI Hormozi, Layla/G-6564-2011; Yang, Kun/J-8956-2016 NR 31 TC 2 Z9 2 U1 0 U2 1 PU WORLD SCIENTIFIC PUBL CO PTE LTD PI SINGAPORE PA 5 TOH TUCK LINK, SINGAPORE 596224, SINGAPORE SN 0217-9792 J9 INT J MOD PHYS B JI Int. J. Mod. Phys. B PD MAY 20 PY 2009 VL 23 IS 12-13 BP 2727 EP 2736 PG 10 WC Physics, Applied; Physics, Condensed Matter; Physics, Mathematical SC Physics GA 457FD UT WOS:000266913000032 ER PT J AU Smith, ZK Dryer, M McKenna-Lawlor, SMP Fry, CD Deehr, CS Sun, W AF Smith, Z. K. Dryer, M. McKenna-Lawlor, S. M. P. Fry, C. D. Deehr, C. S. Sun, W. TI Operational validation of HAFv2's predictions of interplanetary shock arrivals at Earth: Declining phase of Solar Cycle 23 SO JOURNAL OF GEOPHYSICAL RESEARCH-SPACE PHYSICS LA English DT Article ID SPACE WEATHER; WIND; MODELS; EVENTS AB This is the third in a series of papers showing the performance of the Hakamada-Akasofu-Fry version 2 (HAFv2) model in predicting, in the operational environment, the arrival of interplanetary shocks at Earth. The first and second studies covered the time of the rise and maximum of Solar Cycle 23. This study covers the declining phase, through December 2006. The prediction of shock arrivals is important in space weather applications because these events are often followed by geomagnetic disturbances that disrupt human technologies. The HAFv2 uses, for input, a continuously updating background solar wind onto which transient events (interplanetary shocks) are superimposed whenever near-real-time observations are reported of a metric type II radio burst and/or a halo or partial halo coronal mass ejection (CME). Supporting inputs are obtained from GOES 1-8 angstrom X-ray data and solar images. We present the performance of the model in standard meteorological forecast metrics and compare the accuracy of the three phases of Solar Cycle 23. We find that the accuracy of the model is consistent between the three periods. For this third phase, we show the added confidence in model predictions provided by the presence of halo/partial halo observations. Halo/partial halo CMEs were found to accompany approximately one half of the events. The predictions of this subset of events have a higher level of confidence and success. Thus the observation of a large CME should not be a requirement for a forecast but rather an indication that when one is observed, the confidence in the prediction is greatly increased. C1 [Smith, Z. K.; Dryer, M.] NOAA, Space Weather Predict Ctr, Boulder, CO 80305 USA. [Fry, C. D.] Explorat Phys Int Inc, Huntsville, AL 35806 USA. [McKenna-Lawlor, S. M. P.] Natl Univ Ireland, Maynooth, Kildare, Ireland. RP Smith, ZK (reprint author), NOAA, Space Weather Predict Ctr, 325 Broadway, Boulder, CO 80305 USA. EM zdenka.smith@noaa.gov RI xue, yansheng/A-9712-2012 FU National Geophysical Data Center (NGDC); U.S. Air Force; Air Force Weather Agency's Solar Electro-Optical Network FX We thank the ACE instrument teams for making their data available to the community and the SOHO/MDI instrument team for the helioseismology data (SOHO is a project of international cooperation between ESA and NASA). We also thank the National Geophysical Data Center (NGDC) for the archived data and the U.S. Air Force, Air Force Weather Agency's Solar Electro-Optical Network, and Radio Solar Telescope Network observing stations for their realtime solar radio spectrographic shock speed estimates. M. D. acknowledges the hospitality of the NOAA Space Weather Prediction Center. We thank Alysha Reinard and the two reviewers for their helpful suggestions and comments. NR 21 TC 26 Z9 28 U1 0 U2 0 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-9380 EI 2169-9402 J9 J GEOPHYS RES-SPACE JI J. Geophys. Res-Space Phys. PD MAY 20 PY 2009 VL 114 AR A05106 DI 10.1029/2008JA013836 PG 13 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA 449YD UT WOS:000266366100002 ER PT J AU Wu, H Zhou, W Wang, K Udovic, TJ Rush, JJ Yildirim, T Bendersky, LA Gross, AF Van Atta, SL Vajo, JJ Pinkerton, FE Meyer, MS AF Wu, Hui Zhou, Wei Wang, Ke Udovic, Terrence J. Rush, John J. Yildirim, Taner Bendersky, Leonid A. Gross, Adam F. Van Atta, Sky L. Vajo, John J. Pinkerton, Frederick E. Meyer, Martin S. TI Size effects on the hydrogen storage properties of nanoscaffolded Li3BN2H8 SO NANOTECHNOLOGY LA English DT Article ID ALUMINUM HYDRIDES; CRYSTAL-STRUCTURE; COMPLEX HYDRIDES; AMMONIA BORANE; RELEASE; DESORPTION; KINETICS; CARBON; LIB0.33N0.67H2.67; NANOPARTICLES AB The use of Li3BN2H8 complex hydride as a practical hydrogen storage material is limited by its high desorption temperature and poor reversibility. While certain catalysts have been shown to decrease the dehydrogenation temperature, no significant improvement in reversibility has been reported thus far. In this study, we demonstrated that tuning the particle size to the nanometer scale by infiltration into nanoporous carbon scaffolds leads to dramatic improvements in the reversibility of Li3BN2H8. Possible changes in the dehydrogenation path were also observed in the nanoscaffolded hydride. C1 [Wu, Hui; Zhou, Wei; Udovic, Terrence J.; Rush, John J.; Yildirim, Taner] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Wu, Hui; Zhou, Wei; Rush, John J.] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. [Wang, Ke; Bendersky, Leonid A.] NIST, Div Met, Gaithersburg, MD 20899 USA. [Yildirim, Taner] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA. [Gross, Adam F.; Van Atta, Sky L.; Vajo, John J.] HRL Labs LLC, Malibu, CA 90265 USA. [Pinkerton, Frederick E.; Meyer, Martin S.] Gen Motors Res & Dev Ctr, Warren, MI 48090 USA. RP Wu, H (reprint author), NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. EM huiwu@nist.gov RI Wu, Hui/C-6505-2008; Zhou, Wei/C-6504-2008; Wang, Ke/C-8021-2011; yildirim, taner/A-1290-2009 OI Wu, Hui/0000-0003-0296-5204; Zhou, Wei/0000-0002-5461-3617; FU DOE [AI-01-05EE11104, DE-FC36-05GO15067, DE-FG02-08ER46522] FX This work was partially supported by DOE through EERE Grant No. DE-AI-01-05EE11104 (TJU), Contract No. DE-FC36-05GO15067 (AFG, SLV, and JJV), and BES Grant No. DE-FG02-08ER46522 (TY). NR 31 TC 30 Z9 30 U1 3 U2 25 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0957-4484 J9 NANOTECHNOLOGY JI Nanotechnology PD MAY 20 PY 2009 VL 20 IS 20 AR 204002 DI 10.1088/0957-4484/20/20/204002 PG 7 WC Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied SC Science & Technology - Other Topics; Materials Science; Physics GA 438BR UT WOS:000265531400003 PM 19420650 ER PT J AU Liao, WL Dodder, NG Mast, N Pikuleva, IA Turko, IV AF Liao, Wei-Li Dodder, Nathan G. Mast, Natalia Pikuleva, Irina A. Turko, Illarion V. TI Steroid and Protein Ligand Binding to Cytochrome P450 46A1 as Assessed by Hydrogen-Deuterium Exchange and Mass Spectrometry SO BIOCHEMISTRY LA English DT Article ID MALDI-TOF MS; HYDROGEN/DEUTERIUM EXCHANGE; H/D EXCHANGE; CHOLESTEROL HOMEOSTASIS; ACTIVATION; THROMBIN; DYNAMICS; BRAIN; SPECIFICITY; SELECTION AB Cytochrome P450 46A1 (CYP46A1) is a key enzyme responsible for cholesterol elimination from the brain. This P450 can interact with different steroid substrates and protein redox partners. We utilized hydrogen-deuterium (H-D) exchange mass spectrometry for investigating CYP46A1-ligand interactions. First, we tested the applicability of the H-D exchange methodology and assessed the amide proton exchange in substrate-free and cholesterol-sulfate-bound P450. The results showed good correspondence to the available crystal structures and prompted investigation of the CYP46A1 interactions with the two steroid substrates cholesterol and 24S-hydroxycholesterol and the protein redox partner adrenodoxin (Adx). Compared to substrate-free P450, four peptides in cholesterol-bound CYP46A1 (65-80, 109-116, 151-164, and 351-361) and eight peptides in 24S-hydroxycholesterol-bound enzyme (50-64, 65-80, 109-116, 117-125, 129-143, 151-164, 260-270, and 364373) showed altered deuterium incorporation. Most of these peptides constitute the enzyme active site, whereas the 351-361 peptide is from the region putatively interacting with the redox partner Adx. This also defines the proximal (presumably water) channel that opens in CYP46A1 upon substrate binding. Reciprocal studies of Adx binding to substrate-free and cholesterol-sulfate-bound CYP46A1 revealed changes in the deuteration of the Adx-binding site 144-150 and 351-361 peptides, active site 225-239 and 301-313 peptides, and in the 265-276 peptide, whose functional role is not yet known. The data obtained provide structural insights into how substrate and redox partner binding are coordinated and linked to the hydration of the enzyme active site. C1 [Liao, Wei-Li; Turko, Illarion V.] Univ Maryland, Inst Biotechnol, Ctr Adv Res Biotechnol, Rockville, MD 20850 USA. [Liao, Wei-Li; Dodder, Nathan G.; Turko, Illarion V.] NIST, Gaithersburg, MD 20899 USA. [Mast, Natalia; Pikuleva, Irina A.] Case Western Reserve Univ, Dept Ophthalmol & Visual Sci, Cleveland, OH 44106 USA. RP Turko, IV (reprint author), Univ Maryland, Inst Biotechnol, Ctr Adv Res Biotechnol, Rockville, MD 20850 USA. EM turko@umbi.umd.edu RI Dodder, Nathan/C-7971-2015 OI Dodder, Nathan/0000-0001-5913-1767 FU National Institutes of Health [GM062882, AG024336]; Research to Prevent Blindness Foundation FX This work was supported in part by grants from the National Institutes of Health GM062882 and AG024336 (to I.A.P.) and by the Jules and Doris Stein Professorship from Research to Prevent Blindness Foundation (to I.A.P.). NR 40 TC 9 Z9 10 U1 1 U2 10 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0006-2960 J9 BIOCHEMISTRY-US JI Biochemistry PD MAY 19 PY 2009 VL 48 IS 19 BP 4150 EP 4158 DI 10.1021/bi900168m PG 9 WC Biochemistry & Molecular Biology SC Biochemistry & Molecular Biology GA 445JP UT WOS:000266047400014 PM 19317426 ER PT J AU Wild, M Truessel, B Ohmura, A Long, CN Konig-Langlo, G Dutton, EG Tsvetkov, A AF Wild, Martin Truessel, Barbara Ohmura, Atsumu Long, Charles N. Koenig-Langlo, Gert Dutton, Ellsworth G. Tsvetkov, Anatoly TI Global dimming and brightening: An update beyond 2000 SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID SURFACE SOLAR-RADIATION; EARTHS SURFACE; UNITED-STATES; TRENDS; CHINA; CLIMATE; BUDGET; REDUCTIONS; AEROSOLS; NETWORK AB This study investigates recent variations in downwelling surface solar radiation inferred from a comprehensive set of ground-based observational records updated for the period 2000-2005. Surface radiation data beyond the year 2000 are particularly interesting as they provide independent and complementary information to the ambitious satellite programs which became operational with the beginning of the new millennium. The surface records suggest a continuation of the surface solar brightening beyond 2000 at numerous stations in Europe and the United States, as well as parts of east Asia ( Korea). Surface solar radiation variations in Europe after 2000 are dominated by a large positive anomaly in the year 2003 with its unprecedented summer heat wave, exceeding 10 Wm(-2) on an annual and 20 Wm(-2) on a summer mean basis in central Europe. The brightening seen at sites in Antarctica during the 1990s, influenced by a recovery from the low atmospheric transparency after the Mount Pinatubo volcanic eruption in 1991, fades after 2000. The brightening tendency also seems to level off at sites in Japan. In China there is some indication for a renewed dimming, after the stabilization in the 1990s. A continuation of the long-lasting dimming is also noted at the sites in India. Overall, the available data suggest continuation of the brightening beyond the year 2000 at numerous locations, yet less pronounced and coherent than during the 1990s, with more regions with no clear changes or declines. Therefore, globally, greenhouse warming after 2000 may be less modulated by surface solar variations than in prior decades. C1 [Wild, Martin; Truessel, Barbara; Ohmura, Atsumu] ETH, Inst Atmospher & Climate Sci, CH-8092 Zurich, Switzerland. [Long, Charles N.] Pacific NW Natl Lab, Richland, WA 99352 USA. [Dutton, Ellsworth G.] NOAA, Climate Monitoring Diagnost Lab, Boulder, CO 80305 USA. [Koenig-Langlo, Gert] Alfred Wegener Inst Polar & Marine Res, D-27515 Bremerhaven, Germany. [Tsvetkov, Anatoly] AI Voeikov Main Geophys Observ, World Radiat Data Ctr, St Petersburg 194018, Russia. RP Wild, M (reprint author), ETH, Inst Atmospher & Climate Sci, Univ Str 16, CH-8092 Zurich, Switzerland. EM martin.wild@env.ethz.ch RI Wild, Martin/J-8977-2012; Konig-Langlo, Gert/K-5048-2012 OI Konig-Langlo, Gert/0000-0002-6100-4107 FU Swiss National Science Foundation FX This study is supported by the National Center for Competence in Climate Research (NCCR Climate) sponsored by the Swiss National Science Foundation. The first author would particularly like to thank C. Schar for his ongoing support. Guido Muller is highly acknowledged for his efforts to transfer the data updates into the GEBA database. C. N. Long acknowledges the support of the Climate Change Research Division of the U. S. Department of Energy as part of the Atmospheric Radiation Measurement (ARM) program. K. Makowski., M. Chiacchio, D. Folini, and M. Hakuba are acknowledged for proofreading of the manuscript. NR 49 TC 87 Z9 89 U1 5 U2 44 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD MAY 16 PY 2009 VL 114 AR D00D13 DI 10.1029/2008JD011382 PG 14 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 446DJ UT WOS:000266100300002 ER PT J AU Worthy, DEJ Chan, E Ishizawa, M Chan, D Poss, C Dlugokencky, EJ Maksyutov, S Levin, I AF Worthy, Douglas E. J. Chan, Elton Ishizawa, Misa Chan, Douglas Poss, Christian Dlugokencky, Edward J. Maksyutov, Shamil Levin, Ingeborg TI Decreasing anthropogenic methane emissions in Europe and Siberia inferred from continuous carbon dioxide and methane observations at Alert, Canada SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID ATMOSPHERIC METHANE; INTERANNUAL VARIABILITY; GROWTH-RATE; CLIMATE; MODEL AB The rate of increase in global atmospheric methane (CH4) abundance has steadily declined since the late 1980s with near zero increase from 1999 through 2006. At the Canadian Baseline Observatory at Alert, Canada (82 degrees 28'N, 62 degrees 30'W), continuous measurements of methane (CH4) and carbon dioxide (CO2) have been made since 1987. During winter, both gases are frequently highly correlated during well-defined episodes lasting from 2 to 5 days. We observe a gradual decrease in the ratios of CH4/CO2 during these episodes from similar to 16 ppb CH4 (ppm CO2)(-1) to similar to 12 ppb CH4 (ppm of CO2)(-1) over the entire record. An atmospheric transport model with prescribed CO2 and CH4 source distributions is used to partition simulated CH4 events into contributions by region. We show that anthropogenic emissions from Europe and Siberia account for more than 85% of the CO2 and CH4 enhancements simulated at Alert, but without a change in CH4 emissions, modeled CH4/CO2 ratios remain constant. To reproduce the observed trend in the ratio of CH4/CO2, the model requires a reduction in emissions of CH4 on the order of 30 Tg (13.6 to 33.4 Tg) in Europe and Siberia over the observational period. This is about twice the drop reported by the Emission Database for Global Atmospheric Research (EDGAR) emissions inventory and large enough to account for the leveling off of the global atmospheric CH4 burden observed over the past 20 years. C1 [Worthy, Douglas E. J.; Chan, Elton; Chan, Douglas] Environm Canada, Toronto, ON M3H 5T4, Canada. [Dlugokencky, Edward J.] NOAA, Earth Syst Res Lab, Boulder, CO 80305 USA. [Poss, Christian; Levin, Ingeborg] Heidelberg Univ, Inst Umweltphys, D-69120 Heidelberg, Germany. [Maksyutov, Shamil] Natl Inst Environm Studies, Tsukuba, Ibaraki 3058506, Japan. RP Worthy, DEJ (reprint author), Environm Canada, 4905 Dufferin St, Toronto, ON M3H 5T4, Canada. EM doug.worthy@ec.gc.ca RI Maksyutov, Shamil/G-6494-2011 OI Maksyutov, Shamil/0000-0002-1200-9577 NR 29 TC 15 Z9 15 U1 0 U2 8 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X EI 2169-8996 J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD MAY 16 PY 2009 VL 114 AR D10301 DI 10.1029/2008JD011239 PG 7 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 446DJ UT WOS:000266100300001 ER PT J AU Campbell, WH AF Campbell, Wallace H. TI Natural magnetic disturbance fields, not precursors, preceding the Loma Prieta earthquake SO JOURNAL OF GEOPHYSICAL RESEARCH-SPACE PHYSICS LA English DT Article ID IONOSPHERIC ABSORPTION; MICROPULSATIONS; PREDICTION; CALIFORNIA; MECHANISMS; EPICENTER AB Available records of the magnetic indices Dst and ap together with standard observatory recordings of 1-min field levels were examined for the period preceding the earthquake of October 1989, centered near Loma Prieta, California. The magnetic records showed that the Fraser-Smith et al. (1990) report claiming the existence of a 100-s (ultralow frequency) geomagnetic field precursor signal at Corralitos, California, foretelling a nearby earthquake is not valid. My study shows that the Stanford ULF signal was not local but rather widespread throughout the western United States and, therefore, expected to be due to a coincidental geomagnetic solar-terrestrial disturbance field. C1 NOAA, NGDC, Solar Terr Phys Div, Boulder, CO 80305 USA. RP Campbell, WH (reprint author), NOAA, NGDC, Solar Terr Phys Div, 3030 Galena Way, Boulder, CO 80305 USA. EM whcampbell@toast.net NR 27 TC 38 Z9 39 U1 0 U2 3 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0148-0227 J9 J GEOPHYS RES-SPACE JI J. Geophys. Res-Space Phys. PD MAY 16 PY 2009 VL 114 AR A05307 DI 10.1029/2008JA013932 PG 7 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA 446EJ UT WOS:000266103100001 ER PT J AU Rhoderick, GC Thorn, WJ Miller, WR Guenther, FR Gore, EJ Fish, TO AF Rhoderick, George C. Thorn, William J., III Miller, Walter R., Jr. Guenther, Franklin R. Gore, Eric J. Fish, Timothy O. TI Gas Standards Development in Support of NASA's Sensor Calibration Program Around the Space Shuttle SO ANALYTICAL CHEMISTRY LA English DT Article ID MASS-SPECTROMETER SYSTEM AB The National Aeronautics and Space Administration (NASA) Kennedy Space Center (KSC) requires accurate gas mixtures containing argon (Ar), helium (He), hydrogen (HA and oxygen (O(2)) in a balance of nitrogen (N(2)) to calibrate mass spectrometer-based sensors used around their manned and unmanned space vehicles. This also includes space shuttle monitoring around the launch area and inside the shuttle cabin. NASA was in need of these gas mixtures to ensure the safety of the shuttle cabin and the launch system. In 1993, the National Institute of Standards and Technology (NIST) was contracted by NASA to develop a suite of primary standard mixtures (PSMs) containing helium, hydrogen, argon, and oxygen in a balance gas of nitrogen. NIST proceeded to develop a suite of 20 new gravimetric primary PSMs. At the same time NIST contracted Scott Specialty Gases (Plumstead-ville, PA) to prepare 18 cylinder gas mixtures which were then sent to NIST. NIST used their newly prepared PSMs to assign concentration values ranging from 100 to 10 000 mu mol/mol with relative expanded uncertainties (95% confidence interval) of 0.8-10% to the 18 Scott Specialty Gases prepared mixtures. A total of 12 of the mixtures were sent to NASA as NIST traceable standards for calibration of their mass spectrometers. The remaining 6 AIRGAS mixtures were retained at NIST. In 2006, these original 12 gas standards at NASA had become low in pressure and additionally NASA needed a lower concentration level; therefore, NIST was contracted to certify three new sets of gas standards. NIST prepared a new suite of 22 PSMs with weighing uncertainties of <0.1%. These 22 PSMs were compared to some of the original 20 PSMs developed in 1993 and with the NIST valued assigned Scott Specialty Gas mixtures that NIST had retained. Results between the two suites of primary standards and the 1993 NASA mixtures agreed, verifying their stability. At the same time, NASA contracted AIRGAS (Chicago, Illinois) to prepare 45 cylinder gas mixtures which were then sent to NIST. Each of the 3 sets of standards contained 15 cylinder gas mixtures: set no. 1, He at 12 000 mu mol/mol, H(2) at 600 mu mol/mol, Ar at 100 mu mol/mol, and O(2) at 600 mu mol/mol; set no. 2, He at 15 000 mu mol/mol, H(2) at 5000 mu mol/mol, Ar at 1000 mu mol/mol, O(2) at 5000 mu mol/mol; and set no. 3, He at 50 mu mol/mol, H(2), Ar, and O(2) each at 25 mu mol/mol with a balance gas of N(2). NIST used their newly prepared primary standards to assign concentration values to each component in these three new mixture sets to relative expanded uncertainties of 0.5-2.2%. The NIST certified AIRGAS prepared mixtures were then sent to NASA to use as "working standards" to calibrate their mass spectrometers (MSs). C1 [Rhoderick, George C.; Thorn, William J., III; Miller, Walter R., Jr.; Guenther, Franklin R.] NIST, Div Analyt Chem, Gaithersburg, MD 20899 USA. [Gore, Eric J.; Fish, Timothy O.] NASA Hazardous Warning Syst, Kennedy Space Ctr, FL 32899 USA. RP Rhoderick, GC (reprint author), NIST, Div Analyt Chem, Gaithersburg, MD 20899 USA. EM george.rhoderick@nist.gov NR 11 TC 0 Z9 0 U1 0 U2 5 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0003-2700 J9 ANAL CHEM JI Anal. Chem. PD MAY 15 PY 2009 VL 81 IS 10 BP 3809 EP 3815 DI 10.1021/ac900168g PG 7 WC Chemistry, Analytical SC Chemistry GA 446BL UT WOS:000266095100014 PM 19344177 ER PT J AU Gornakov, VS Tikhomirov, OA Lee, CG Jung, JG Egelhoff, WF AF Gornakov, V. S. Tikhomirov, O. A. Lee, C. G. Jung, J. G. Egelhoff, W. F., Jr. TI Thickness and annealing temperature dependences of magnetization reversal and domain structures in exchange biased Co/Ir-Mn bilayers SO JOURNAL OF APPLIED PHYSICS LA English DT Article DE annealing; antiferromagnetic materials; cobalt; coercive force; exchange interactions (electron); ferromagnetic materials; iridium alloys; magnetic domain walls; magnetic multilayers; magnetic structure; magnetic thin films; magnetisation reversal; manganese alloys; nucleation; texture; X-ray diffraction ID THIN-FILMS; UNIDIRECTIONAL ANISOTROPY; SYSTEMS; NIO; ANTIFERROMAGNET; MECHANISMS; NUCLEATION; MICROSCOPY; INTERFACES; SUBSTRATE AB Domain structure and magnetization reversal process of exchange-coupled ferromagnet/antiferromagnet bilayers Co(x)/Ir-Mn(10 nm) were studied as a function of both thickness of the Co layer and annealing temperature. The exchange bias field of the thinnest film and the coercive field of the thicker films show monotonic increase at annealing temperature above 250 degrees C. In every case the bilayers are remagnetized by domain nucleation and domain wall motion. Domain size decreases rapidly for high annealing temperatures, while x-ray diffraction study indicated that the crystallographic texture did not change significantly. The observed features are discussed taking into account the magnetic structure at the interface and its evolution during annealing. C1 [Gornakov, V. S.; Tikhomirov, O. A.] Russian Acad Sci, Inst Solid State Phys, Chernogolovka 142432, Russia. [Lee, C. G.] Changwon Natl Univ, Chang Won 641773, Gyeongnam, South Korea. [Jung, J. G.] Siltron Inc, Gumi 730724, Gyeonbuk, South Korea. [Egelhoff, W. F., Jr.] NIST, Gaithersburg, MD 20899 USA. RP Gornakov, VS (reprint author), Russian Acad Sci, Inst Solid State Phys, Chernogolovka 142432, Russia. EM tikhomir@issp.ac.ru FU Russian Fund for Fundamental Research [08-02-01268]; Korea Foundation for International Cooperation of Science and Technology (KICOS); Korean Ministry of Education, Science and Technology (MEST) in 2007 [K20732000001] FX This work was supported in part by the Russian Fund for Fundamental Research ( Grant No. 08-02-01268) and by the Korea Foundation for International Cooperation of Science and Technology (KICOS) through a grant provided by the Korean Ministry of Education, Science and Technology (MEST) in 2007 (Grant No. K20732000001). NR 61 TC 5 Z9 5 U1 0 U2 7 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0021-8979 EI 1089-7550 J9 J APPL PHYS JI J. Appl. Phys. PD MAY 15 PY 2009 VL 105 IS 10 AR 103917 DI 10.1063/1.3130411 PG 9 WC Physics, Applied SC Physics GA 451VX UT WOS:000266500100123 ER PT J AU Green, ML Allen, AJ Jordan-Sweet, JL Ilavsky, J AF Green, M. L. Allen, A. J. Jordan-Sweet, J. L. Ilavsky, J. TI Annealing behavior of atomic layer deposited HfO2 films studied by synchrotron x-ray reflectivity and grazing incidence small angle scattering SO JOURNAL OF APPLIED PHYSICS LA English DT Article DE annealing; atomic layer deposition; crystal microstructure; dielectric thin films; diffusion; hafnium compounds; nanostructured materials; porosity; surface roughness; X-ray reflection ID GATE DIELECTRIC LAYERS; THIN-FILMS; ELECTRICAL-PROPERTIES; MICROELECTRONICS; CRYSTALLIZATION; MORPHOLOGY; BEAMLINE; SILICON; SIO2 AB New results are presented for the annealing behavior of ultrathin complementary-metal-oxide-semiconductor (CMOS) gate dielectric HfO2 films grown by atomic layer deposition (ALD). A series of ALD HfO2 dielectric films has been studied by a combination of x-ray reflectivity (XRR) and grazing-incidence small-angle x-ray scattering (GISAXS) measurements. By using these techniques together, we have shown that the surface, interfaces, and internal structure of thin ALD films can be characterized with unprecedented sensitivity. Changes in film thickness, film roughness, or diffuseness of the film/substrate interface as measured by XRR are correlated with the corresponding changes in the internal film nanostructure, as measured by GISAXS. Although the films are dense, an internal film structure is shown to exist, attributed primarily to approximate to 2 nm "missing island" porosity features close to the substrate; these are most likely associated with coalescence defects as a result of initial ALD growth, as they are not observed in the upper regions of the film. Some 8-9 nm heterogeneities are also present, which may indicate a widespread modulation in the film density pervading the entire film volume, and which likely also give rise to surface roughness. Comparison of the data between different scattering geometries and among a carefully designed sequence of samples has enabled important insights to be derived for the annealing behavior of the ALD HfO2 films. The main effects of single, brief, high temperature excursions to above 900 degrees C are to anneal out some of the fine voids and reduce the mean roughness and interfacial diffuseness of the film. These changes are indicative of densification. However, depending on the film thickness, the annealing behavior at temperatures between 650 and 800 degrees C is quite different for single excursion and cyclic anneals. Particularly for thin, just-coalesced films, XRR indicates marked increases in the film thickness and in the mean roughness/diffuseness dimension for cyclic anneals. GISAXS also shows an increase, rather than a reduction, in the void microstructure under these conditions. These changes in the film microstructure appear sufficient to overcome the expected film densification at elevated temperatures with implications for the gate dielectric performance of the films after extended high temperature exposure and cycling, as may occur during gate dielectric fabrication. C1 [Green, M. L.; Allen, A. J.] NIST, Gaithersburg, MD 20899 USA. [Jordan-Sweet, J. L.] IBM Corp, Thomas J Watson Res Ctr, Yorktown Hts, NY 10598 USA. [Ilavsky, J.] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA. RP Green, ML (reprint author), NIST, Gaithersburg, MD 20899 USA. EM martin.green@nist.gov RI USAXS, APS/D-4198-2013 NR 29 TC 3 Z9 3 U1 1 U2 29 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 0021-8979 J9 J APPL PHYS JI J. Appl. Phys. PD MAY 15 PY 2009 VL 105 IS 10 AR 103522 DI 10.1063/1.3125510 PG 11 WC Physics, Applied SC Physics GA 451VX UT WOS:000266500100091 ER PT J AU Uhlig, WC Donahue, MJ Pierce, DT Unguris, J AF Uhlig, W. C. Donahue, M. J. Pierce, D. T. Unguris, J. TI Direct imaging of current-driven domain walls in ferromagnetic nanostripes SO JOURNAL OF APPLIED PHYSICS LA English DT Article DE ferromagnetic materials; iron alloys; magnetic domain walls; nanostructured materials; nickel alloys; scanning electron microscopy; vortices ID SPIN-POLARIZED CURRENT; ELECTRIC-CURRENT; PULSED-CURRENT; MOTION; PROPAGATION; MULTILAYERS; NANOWIRES; STRIPS; MEMORY; FORCE AB To better understand the response of domain walls to current-induced spin transfer torques, we have directly imaged the internal magnetic structure of domain walls in current-carrying ferromagnetic nanostripes. Domain wall images were acquired both while a constant current was flowing through the wire, and after applying current pulses. Domain walls ranging from vortex walls in wide (1 mu m) wires to transverse walls in narrow (100 nm) wires were quantitatively analyzed using scanning electron microscopy with polarization analysis. The domain wall motion is characterized by strong interactions with random pinning sites along the wire. The walls either jump with the electron flow between pinning sites, or the pinned walls are distorted by the current. The domain wall propagation is also associated with transverse motion of the vortex core. C1 [Uhlig, W. C.; Donahue, M. J.; Pierce, D. T.; Unguris, J.] NIST, Gaithersburg, MD 20899 USA. RP Uhlig, WC (reprint author), USA, Res Lab, Aberdeen Proving Ground, MD 21005 USA. EM john.unguris@nist.gov RI Unguris, John/J-3989-2014 FU Office of Naval Research FX The authors thank Mark Stiles, Hongki Min, and Robert McMichael for many helpful discussions. This work was supported in part by the Office of Naval Research. Research performed at the NIST Center for Nanoscale Science and Technology. NR 50 TC 14 Z9 14 U1 2 U2 11 PU AMER INST PHYSICS PI MELVILLE PA 1305 WALT WHITMAN RD, STE 300, MELVILLE, NY 11747-4501 USA SN 0021-8979 EI 1089-7550 J9 J APPL PHYS JI J. Appl. Phys. PD MAY 15 PY 2009 VL 105 IS 10 AR 103902 DI 10.1063/1.3125526 PG 7 WC Physics, Applied SC Physics GA 451VX UT WOS:000266500100108 ER PT J AU Hotta, Y Komatsu, K Wang, FW AF Hotta, Yasuhiro Komatsu, Koichi Wang, Francis W. TI Novel Fluorescence Method for Cure Monitoring of Hydrosilation-Curable Silicones SO JOURNAL OF APPLIED POLYMER SCIENCE LA English DT Article DE curing of polymers; dental polymers; fluorescence; modulus; silicones ID PROBES; POLYMERIZATION; METHACRYLATE AB This study aimed to evaluate a reactive fluorescent probe, 9,10-bis-(phenylethynyl) anthracene (BPEA), for cure monitoring of hydrosilation-curable silicones. The hydrosilation-curable silicones consisted of a vinyl-terminated polydimethylsiloxane prepolymer, a methylhydrosiloxane-dimethylsiloxane copolymer, and an inhibitor, 1,3-divinyltetramethyldisiloxane. The hydrosilation reaction was catalyzed with the solution of a platinum catalyst in the prepolymer. The catalyst solution also contained a trace amount of the reactive fluorescent probe. Three hydrosilation-curable silicones, with the prepolymer of varying molar mass, were investigated. Each of the hydrosilation-curable silicones was mixed with the catalyst solution at the mass ratio of 1:1 to initiate the cure. During the cure of each mixture at 22 degrees C, the elastic modulus of the mixture and the fluorescence spectrum of the probe at the excitation wavelength of 360 nm were measured. Initially, the elastic modulus changed slowly, but then increased, rapidly as a result of the increase in molar mass. The elastic modulus, leveled off and reached a plateau value at the setting time. The ratio of the fluorescence intensities at 422 and 466 nm increased steadily, and then leveled off and reached a plateau value at the setting time, in agreement with the setting time determined from the change in elastic modulus. The reactive,e fluorescent probe, BPEA, can therefore be used for non-destructive,e fluorescence monitoring of hydrosilation-curable silicones. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 112: 2441-2444, 2009 C1 [Hotta, Yasuhiro; Komatsu, Koichi; Wang, Francis W.] Natl Inst Stand & Technol, Div Polymer, Gaithersburg, MD 20899 USA. [Hotta, Yasuhiro] Showa Univ, Sch Dent, Dept Oral Biomat & Technol, Tokyo 142, Japan. [Komatsu, Koichi] Nihon Univ, Sch Dent Matsudo, Dept Dent Mat, Chiba, Japan. RP Wang, FW (reprint author), Natl Inst Stand & Technol, Div Polymer, Gaithersburg, MD 20899 USA. EM francis.wang@nist.gov NR 15 TC 0 Z9 0 U1 1 U2 9 PU JOHN WILEY & SONS INC PI HOBOKEN PA 111 RIVER ST, HOBOKEN, NJ 07030 USA SN 0021-8995 J9 J APPL POLYM SCI JI J. Appl. Polym. Sci. PD MAY 15 PY 2009 VL 112 IS 4 BP 2441 EP 2444 DI 10.1002/app.29745 PG 4 WC Polymer Science SC Polymer Science GA 422TB UT WOS:000264449500069 ER PT J AU Wallace, BP Avens, L Braun-McNeill, J McClellan, CM AF Wallace, Bryan P. Avens, Larisa Braun-McNeill, Joanne McClellan, Catherine M. TI The diet composition of immature loggerheads: Insights on trophic niche, growth rates, and fisheries interactions SO JOURNAL OF EXPERIMENTAL MARINE BIOLOGY AND ECOLOGY LA English DT Article DE Fishery interactions; Marine turtles; Omnivory; Stable isotopes; Trophic niche ID TURTLES CARETTA-CARETTA; STABLE-ISOTOPE ANALYSES; GREAT-BARRIER-REEF; SEA-TURTLES; MARINE TURTLES; PROXIMATE; ECOLOGY; DISCRIMINATION; ASSUMPTIONS; DELTA-N-15 AB For immature animals, diet quality and composition influence expression of life history traits such as growth rates and ultimately life stage duration and age to maturity. Circumglobally distributed loggerhead turtles (Caretta caretta) exhibit a multi-decade immature stage that generally occupies neritic habitats and is characterized by slow growth and an omnivorous diet. Although adult nesting populations are geographically distinct, foraging areas for immature loggerheads show a high degree of mixing of individuals that originate from multiple nesting stocks. Furthermore, despite their generalist foraging ecology, immature loggerheads have been observed to supplement their natural diets with fish from fishery discards and/or caught in fishing gear. However, whether trophic opportunism results in variation in loggerhead growth rates within or among feeding areas has not been investigated. In Core Sound, North Carolina (NC), USA, immature loggerheads demonstrate highly variable size-specific growth rates, in contrast to other studies that report discernible somatic growth functions in immature marine turtles. To determine whether inter-individual variation in growth rates at this site was due to variation in diet composition, and specifically variation in consumption of fish, we analyzed carbon and nitrogen stable isotope ratios of loggerhead blood plasma and of tissue samples of putative loggerhead prey, as well as commercially important fish species. Our results indicated that growth rates were not related to trophic levels at which individual turtles fed, but rather probably reflected inter-individual variation in overwintering or foraging behavior (i.e. nearshore vs. offshore). Furthermore, loggerhead diets were highly diverse, and comprised mainly blue crabs and/or whelks, as well as small proportions of cannonball jellies. Fish were unimportant dietary components for loggerheads. Although loggerheads in NC do not appear to feed on fish catch or discards, immature turtles showed dietary preferences for prey items that are also valuable to or are commonly taken as bycatch in commercial fisheries (e.g. blue crabs and whelks, respectively) in the region. Thus, the status of these prey items/fishery stocks as well as trends in loggerhead populations should be monitored to mitigate potential competitive interactions between fisheries activities and loggerhead turtles. (C) 2009 Elsevier B.V. All rights reserved. C1 [Wallace, Bryan P.] Conservat Int, Ctr Appl Biodivers Sci, Arlington, VA 22202 USA. [Wallace, Bryan P.; McClellan, Catherine M.] Duke Univ, Marine Lab, Div Marine Sci & Conservat, Nicholas Sch Environm, Beaufort, NC 28516 USA. [Avens, Larisa; Braun-McNeill, Joanne] NOAA, Natl Marine Fisheries Serv, SE Fisheries Sci Ctr, Ctr Coastal Fisheries & Habitat Res, Beaufort, NC 28516 USA. RP Wallace, BP (reprint author), Conservat Int, Ctr Appl Biodivers Sci, 2011 Crystal Dr,Suite 500, Arlington, VA 22202 USA. EM b.wallace@conservation.org FU Oak Foundation; Duke Marine Laboratory FX We thank several people for their participation in sample collection, processing, and analyses, including A. Goodman, L Goshe, C. Currin, A. Hilting, A. Houston, T. Wohlford, L. Goodwin, P. Goodwin, and J. Karr. B.P.W. was partially supported by Project GloBAL, and C.M. M. was supported by the Oak Foundation and Duke Marine Laboratory. We thank J. Seminoff, P. Marraro, C. Currin, L Hansen, G.B. Martin, S. Epperly, A. Chester, G. Hays and an anonymous reviewer for constructive comments that improved the manuscript. [SS] NR 57 TC 29 Z9 31 U1 5 U2 37 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-0981 J9 J EXP MAR BIOL ECOL JI J. Exp. Mar. Biol. Ecol. PD MAY 15 PY 2009 VL 373 IS 1 BP 50 EP 57 DI 10.1016/j.jembe.2009.03.006 PG 8 WC Ecology; Marine & Freshwater Biology SC Environmental Sciences & Ecology; Marine & Freshwater Biology GA 448IL UT WOS:000266256200007 ER PT J AU Huang, WT Chu, XZ Wiig, J Tan, B Yamashita, C Yuan, T Yue, J Harrell, SD She, CY Williams, BP Friedman, JS Hardesty, RM AF Huang, Wentao Chu, Xinzhao Wiig, Johannes Tan, Bo Yamashita, Chihoko Yuan, T. Yue, J. Harrell, S. D. She, C. -Y. Williams, B. P. Friedman, J. S. Hardesty, R. M. TI Field demonstration of simultaneous wind and temperature measurements from 5 to 50 km with a Na double-edge magneto-optic filter in a multi-frequency Doppler lidar SO OPTICS LETTERS LA English DT Article AB We report the first (to our knowledge) field demonstration of simultaneous wind and temperature measurements with a Na double-edge magneto-optic filter implemented in the receiver of a three-frequency Na Doppler lidar. Reliable winds and temperatures were obtained in the altitude range of 10-45 km with I km resolution and 60 min integration under the conditions of 0.4 W lidar power and 75 cm telescope aperture. This edge filter with a multi-frequency lidar concept can be applied to other direct-detection Doppler lidars for profiling both wind and temperature simultaneously from the lower to the upper atmosphere. (C) 2009 Optical Society of America C1 [Huang, Wentao; Chu, Xinzhao; Wiig, Johannes; Tan, Bo; Yamashita, Chihoko] Univ Colorado, Boulder, CO 80309 USA. [Yuan, T.; Yue, J.; Harrell, S. D.; She, C. -Y.] Colorado State Univ, Ft Collins, CO 80523 USA. [Williams, B. P.] NW Res Associates Inc, Colorado Res Associates, Boulder, CO 80301 USA. [Friedman, J. S.] Natl Astron & Ionosphere Ctr, Arecibo Observ, Arecibo, PR 00612 USA. [Hardesty, R. M.] Natl Ocean & Atmospher Adm, Earth Syst Res Lab, Boulder, CO 80305 USA. RP Chu, XZ (reprint author), Univ Colorado, 216 UCB,CIRES, Boulder, CO 80309 USA. EM Xinzhao.Chu@Colorado.edu RI Friedman, Jonathan/E-4985-2011; Yue, Jia/D-8177-2011; Hardesty, Robert/H-9844-2013; Chu, Xinzhao/I-5670-2015 OI Friedman, Jonathan/0000-0002-9353-2377; Chu, Xinzhao/0000-0001-6147-1963 FU CIRES Innovative Research Program; National Science Foundation (NSF) [ATM-0545353, ATM-0545262, ATM-0545221, ATM-0645584, ATM-0723229] FX This research is supported by the CIRES Innovative Research Program, the National Science Foundation (NSF) ATM-0545353, ATM-0545262, and ATM-0545221, NSF CAREER ATM-0645584, and NSF ATM-0723229. NR 6 TC 11 Z9 11 U1 1 U2 7 PU OPTICAL SOC AMER PI WASHINGTON PA 2010 MASSACHUSETTS AVE NW, WASHINGTON, DC 20036 USA SN 0146-9592 J9 OPT LETT JI Opt. Lett. PD MAY 15 PY 2009 VL 34 IS 10 BP 1552 EP 1554 PG 3 WC Optics SC Optics GA 458YB UT WOS:000267064500021 PM 19448818 ER PT J AU Braje, D Hollberg, L Diddams, S AF Braje, Danielle Hollberg, Leo Diddams, Scott TI Brillouin-Enhanced Hyperparametric Generation of an Optical Frequency Comb in a Monolithic Highly Nonlinear Fiber Cavity Pumped by a cw Laser SO PHYSICAL REVIEW LETTERS LA English DT Article ID PARAMETRIC OSCILLATOR AB We demonstrate self-seeded generation of a broadband comb in a highly nonlinear fiber resonator. When pumped with a cw laser, the fiber cavity generates a comb with two characteristic spacings. Hyperparametric modes spaced by similar to 2 THz create the base structure of the comb, while commensurate Brillouin modes spaced by similar to 10 GHz populate the intermediate frequency gaps. The frequency modes are coherent, and the repetition rate of the comb has been locked to a microwave standard. C1 [Braje, Danielle; Hollberg, Leo; Diddams, Scott] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Braje, D (reprint author), Natl Inst Stand & Technol, 325 Broadway, Boulder, CO 80305 USA. EM braje@stanfordalumni.org RI Diddams, Scott/L-2819-2013 NR 28 TC 41 Z9 41 U1 3 U2 23 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 0031-9007 J9 PHYS REV LETT JI Phys. Rev. Lett. PD MAY 15 PY 2009 VL 102 IS 19 AR 193902 DI 10.1103/PhysRevLett.102.193902 PG 4 WC Physics, Multidisciplinary SC Physics GA 447QU UT WOS:000266207700026 PM 19518952 ER PT J AU Costa, BM Battista, TA Pittman, SJ AF Costa, B. M. Battista, T. A. Pittman, S. J. TI Comparative evaluation of airborne LiDAR and ship-based multibeam SoNAR bathymetry and intensity for mapping coral reef ecosystems SO REMOTE SENSING OF ENVIRONMENT LA English DT Article DE LiDAR; Laser altimetry; Multibeam SoNAR; MBES; Bathymetry; Intensity; Backscatter; Coral reef ecosystems; Benthic habitat mapping; Morphometrics ID GRAIN-SIZE DISTRIBUTION; BISCAYNE NATIONAL-PARK; MARINE-SEDIMENTS; BACKSCATTER; FLORIDA; ATTENUATION; RESOLUTION; HABITATS; RUGOSITY; TRACT AB Large areas of the world's coastal marine environments remain poorly characterized because they have not been mapped with sufficient accuracy and at spatial resolutions high enough to support a wide range of societal needs. Expediting the rate of seafloor mapping requires the collection of multi-use datasets that concurrently address hydrographic charting needs and support decision-making in ecosystem-based management. While active optical and acoustic sensors have previously been compared for the purpose of hydrographic charting, few studies have evaluated the performance and cost effectiveness of these systems for providing benthic habitat maps. Bathymetric and intensity data were collected in shallow water (<50 m depth) coral reef ecosystems using two conventional remote sensing technologies: (1) airborne Light Detection and Ranging (LiDAR), and (2) ship-based multibeam (MBES) Sound Navigation and Ranging (SoNAR). A comparative assessment using a suite of twelve metrics demonstrated that LiDAR and MBES were equally capable of discriminating seafloor topography (r = >0.9), although LiDAR depths were found to be consistently shallower than MBES depths. The intensity datasets were not significantly correlated at a broad 4 x 5 km spatial scale (r = -0.11), but were moderately correlated in flat areas at a fine 4 x 500 m spatial scale (r = 0.51), indicating that the LiDAR intensity algorithm needs to be improved before LiDAR intensity surfaces can be used for habitat mapping. LiDAR cost 6.6% less than MBES and required 40 fewer hours to map the same study area. MBES provided more detail about the seafloor by fully ensonifying high-relief features, by differentiating between fine and coarse sediments and by collecting data with higher spatial resolutions. Surface fractal dimensions and fast Fourier transformations emerged as useful methods for detecting artifacts in the datasets. Overall, LiDAR provided a more cost effective alternative to MBES for mapping and monitoring shallow water coral reef ecosystems (<50 m depth), although the unique advantages of MBES may make it a more appropriate choice for answering certain ecological or geological questions requiring very high resolution data. (C) 2009 Elsevier Inc. All rights reserved. C1 [Costa, B. M.; Battista, T. A.; Pittman, S. J.] NOAA, NOS, CCMA, Biogeog Branch, Silver Spring, MD 20910 USA. [Pittman, S. J.] Univ Virgin Isl, Ctr Marine Sci, St Thomas, VI 00802 USA. RP Costa, BM (reprint author), NOAA, NOS, CCMA, Biogeog Branch, 1305 East West Highway, Silver Spring, MD 20910 USA. EM bryan.costa@noaa.gov FU NOAA's Coral Reef Conservation Program FX The authors would like to thank NOAA's Coral Reef Conservation Program for their continued support of the CCMA Biogeography Branch's effort to characterize coral reef ecosystems in the U.S. Caribbean. We also thank Matthew Kendall and the three anonymous reviewers for their help in refining this manuscript. NR 51 TC 45 Z9 47 U1 8 U2 39 PU ELSEVIER SCIENCE INC PI NEW YORK PA 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA SN 0034-4257 J9 REMOTE SENS ENVIRON JI Remote Sens. Environ. PD MAY 15 PY 2009 VL 113 IS 5 BP 1082 EP 1100 DI 10.1016/j.rse.2009.01.015 PG 19 WC Environmental Sciences; Remote Sensing; Imaging Science & Photographic Technology SC Environmental Sciences & Ecology; Remote Sensing; Imaging Science & Photographic Technology GA 440QY UT WOS:000265716000017 ER PT J AU Miller, DL Kubista, KD Rutter, GM Ruan, M de Heer, WA First, PN Stroscio, JA AF Miller, David L. Kubista, Kevin D. Rutter, Gregory M. Ruan, Ming de Heer, Walt A. First, Phillip N. Stroscio, Joseph A. TI Observing the Quantization of Zero Mass Carriers in Graphene SO SCIENCE LA English DT Article ID EPITAXIAL GRAPHENE; DIRAC-FERMIONS; GRAPHITE; GAS AB Application of a magnetic field to conductors causes the charge carriers to circulate in cyclotron orbits with quantized energies called Landau levels (LLs). These are equally spaced in normal metals and two-dimensional electron gases. In graphene, however, the charge carrier velocity is independent of their energy (like massless photons). Consequently, the LL energies are not equally spaced and include a characteristic zero-energy state (the n = 0 LL). With the use of scanning tunneling spectroscopy of graphene grown on silicon carbide, we directly observed the discrete, non-equally-spaced energy-level spectrum of LLs, including the hallmark zero-energy state of graphene. We also detected characteristic magneto-oscillations in the tunneling conductance and mapped the electrostatic potential of graphene by measuring spatial variations in the energy of the n = 0 LL. C1 [Miller, David L.; Kubista, Kevin D.; Ruan, Ming; de Heer, Walt A.; First, Phillip N.] Georgia Inst Technol, Sch Phys, Atlanta, GA 30332 USA. [Rutter, Gregory M.; Stroscio, Joseph A.] NIST, Ctr Nanoscale Sci & Technol, Gaithersburg, MD 20899 USA. RP First, PN (reprint author), Georgia Inst Technol, Sch Phys, Atlanta, GA 30332 USA. EM first@physics.gatech.edu; joseph.stroscio@nist.gov FU NSF [ECCS-0804908, ECCS-0521041]; Semiconductor Research Corporation Nanoelectronics Research Initiative (INDEX program); W. M. Keck Foundation FX We thank A. MacDonald, H. Min, M. Stiles, and the NIST graphene team for valuable comments and discussions and C. Berger, N. Sharma, M. Sprinkle, S. Blankenship, A. Band, and F. Hess for their technical contributions to this work. Portions of this work were supported by NSF (grant ECCS-0804908), the Semiconductor Research Corporation Nanoelectronics Research Initiative (INDEX program), and the W. M. Keck Foundation. Graphene production facilities were developed under NSF grant ECCS-0521041. NR 31 TC 271 Z9 276 U1 11 U2 97 PU AMER ASSOC ADVANCEMENT SCIENCE PI WASHINGTON PA 1200 NEW YORK AVE, NW, WASHINGTON, DC 20005 USA SN 0036-8075 J9 SCIENCE JI Science PD MAY 15 PY 2009 VL 324 IS 5929 BP 924 EP 927 DI 10.1126/science.1171810 PG 4 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA 445KD UT WOS:000266048800034 PM 19443780 ER PT J AU Huang, XL Zhang, JZ AF Huang, Xiao-Lan Zhang, Jia-Zhong TI Neutral persulfate digestion at sub-boiling temperature in an oven for total dissolved phosphorus determination in natural waters SO TALANTA LA English DT Article DE Total dissolved phosphorus; Digestion; Molar absorptivity; Persulfate oxidation; pH; Sample matrix; Spectrophotometry ID FLOW-INJECTION ANALYSIS; ORGANIC PHOSPHORUS; PARTICULATE PHOSPHORUS; RELATIVE IMPORTANCE; NITROGEN; SAMPLES; QUANTIFICATION; SPECTROMETRY; PERFORMANCE; PHOSPHATE AB A simplified, easily performed persulfate digestion method has been developed to process a large number of water samples for routine determination of total dissolved phosphorus. A neutral potassium persulfate solution (5%, w/v, pH similar to 6.5) is added to the samples (at 10mg potassium persulfate per mL of Sample), which are then digested at 90 degrees C in an oven for 16 h. This method does not require pH adjustment after digestion because neither an acid nor a base is added to the samples prior to digestion. The full color of phosphoantimonylmolybdenum blue from the digested samples develops within 8 min. Compared with the autoclave method, digestion at sub-boiling temperatures in an oven is safer, and a large number of samples can be heated overnight requiring no constant monitoring. The apparent molar absorptivity (e) of nine organic phosphorus compounds and two condensed inorganic phosphates ranged from 1.17 x 10(4) to 1.82 x 10(4) Lmol(-1) cm(-1) in both distilled water and artificial seawater matrixes. The average recovery of these phosphorus compounds was 94 +/- 11% for the DIW matrix and 90 +/- 12% for the ASW matrix. No significant difference in molar absorptivity was observed between the undigested and digested phosphate, especially in the seawater matrix. It is, therefore, suggested that a phosphate solution be directly employed without digestion as the calibration standard for routine determination of total dissolved phosphorus. This method was used to study the spatial distribution of total dissolved phosphorus in the surface waters of Florida Bay. (c) 2009 Elsevier B.V. All rights reserved. C1 [Huang, Xiao-Lan] Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, CIMAS, 4600 Rickenbacker Causeway, Miami, FL 33149 USA. [Huang, Xiao-Lan; Zhang, Jia-Zhong] Natl Ocean & Atmospher Adm, Ocean Chem Div, Atlantic Oceanog & Meteorol Lab, Miami, FL 33149 USA. RP Huang, XL (reprint author), Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, CIMAS, 4600 Rickenbacker Causeway, Miami, FL 33149 USA. EM xiaolan.huang@ymail.com RI Zhang, Jia-Zhong/B-7708-2008; Huang, XiaoLan/G-6306-2012; Huang (黄), Xiao-Lan (晓澜)/E-9159-2010 OI Zhang, Jia-Zhong/0000-0002-1138-2556; Huang (黄), Xiao-Lan (晓澜)/0000-0002-3330-4858 FU NOAA; University of Miami; National Oceanic and Atmospheric Administration [NA67RJ0149] FX We thank Ms. Xiaosun Lu for her assistance with statistical analysis and Ms. Gail Derr for English editing. Financial support for this study was provided by NOAA's Coastal Ocean Program and Climate and Global Change Program. This research was carried out, in part, under the auspices of the Cooperative Institute for Marine and Atmospheric Studies (CIMAS), a joint institute of the University of Miami and the National Oceanic and Atmospheric Administration, cooperative agreement #NA67RJ0149. The statements, findings, conclusions, and recommendations are those of the authors and do not necessarily reflect the views of NOAA or the U.S. Department of Commerce. NR 41 TC 29 Z9 30 U1 3 U2 29 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0039-9140 EI 1873-3573 J9 TALANTA JI Talanta PD MAY 15 PY 2009 VL 78 IS 3 BP 1129 EP 1135 DI 10.1016/j.talanta.2009.01.029 PG 7 WC Chemistry, Analytical SC Chemistry GA 430GJ UT WOS:000264976600077 PM 19269482 ER PT J AU Stabeno, PJ Ladd, C Reed, RK AF Stabeno, P. J. Ladd, C. Reed, R. K. TI Observations of the Aleutian North Slope Current, Bering Sea, 1996-2001 SO JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS LA English DT Article ID CURRENT SYSTEM; OCEAN; CIRCULATION; ENVIRONMENT; PACIFIC; EASTERN; BASIN; FLOW; TOPEX/POSEIDON; VARIABILITY AB Cyclonic circulation dominates flow in the Bering Sea basin. The eastward flowing Aleutian North Slope Current (ANSC) flows along the north slope of the Aleutian Islands, turning northwestward in the southeast corner of the basin to form the Bering Slope Current (BSC). During the period 1997 to 2007, a pair of hydrographic lines was occupied 14 times in the southeastern portion of the basin. One transect was across the ANSC, and the second was across the BSC. In addition, a series of five yearlong moorings was deployed in a water depth of 1000 m in the ANSC, and a single yearlong mooring was deployed to the northeast in a water depth of 2200 m. At the primary mooring site, strong variability in temperature and salinity occurred at fortnightly and annual periods, while strong variability in the currents occurred at fortnightly and semiannual periods. The mean geostrophic flow relative to 1500 m, calculated from the 14 occupations of the hydrographic lines, was 3.1 x 10(6) m(3) s(-1) in the ANSC and 3.3 x 10(6) m(3) s(-1) in the BSC. A significant barotropic component, measured by the current meters, adds similar to 3 x 10(6) m(3) s(-1) to the transport. C1 [Stabeno, P. J.; Ladd, C.; Reed, R. K.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. RP Stabeno, PJ (reprint author), NOAA, Pacific Marine Environm Lab, 7600 Sand Point Way NE, Seattle, WA 98115 USA. EM stabeno@noaa.gov RI Ladd, Carol/M-6159-2014 OI Ladd, Carol/0000-0003-1065-430X NR 32 TC 23 Z9 23 U1 0 U2 10 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-9275 EI 2169-9291 J9 J GEOPHYS RES-OCEANS JI J. Geophys. Res.-Oceans PD MAY 14 PY 2009 VL 114 AR C05015 DI 10.1029/2007JC004705 PG 16 WC Oceanography SC Oceanography GA 446DS UT WOS:000266101200001 ER PT J AU Bohn, JL Cavagnero, M Ticknor, C AF Bohn, J. L. Cavagnero, M. Ticknor, C. TI Quasi-universal dipolar scattering in cold and ultracold gases SO NEW JOURNAL OF PHYSICS LA English DT Article ID POLAR-MOLECULES; COLLISIONS; PHYSICS; ATOMS; BOSE AB We investigate the scattering cross section of aligned dipolar molecules in low-temperature gases. Over a wide range of collision energies relevant to contemporary experiments, the cross section declines in inverse proportion to the collision speed, and is given nearly exactly by a simple semiclassical formula. At yet lower energies, the cross section becomes independent of energy, and is reproduced within the Born approximation to within corrections due to the s-wave scattering length. While these behaviors are universal for all polar molecules, nevertheless interesting deviations from universality are expected to occur in the intermediate energy range. C1 [Bohn, J. L.] Univ Colorado, NIST, Joint Inst Lab Astrophys, Boulder, CO 80309 USA. [Bohn, J. L.] Univ Colorado, Dept Phys, Boulder, CO 80309 USA. [Cavagnero, M.] Univ Kentucky, Dept Phys & Astron, Lexington, KY 40506 USA. [Ticknor, C.] Swinburne Univ Technol, ARC Ctr Excellence Quantum Atom Opt, Hawthorn, Vic 3122, Australia. [Ticknor, C.] Swinburne Univ Technol, Ctr Atom Opt & Ultrafast Spect, Hawthorn, Vic 3122, Australia. RP Bohn, JL (reprint author), Univ Colorado, NIST, Joint Inst Lab Astrophys, Boulder, CO 80309 USA. EM bohn@murphy.colorado.edu; mike@pa.uky.edu; cticknor@swin.edu.au RI Ticknor, Christopher/B-8651-2014 FU NSF; ARC; University of Kentucky FX We acknowledge the financial support from the NSF (J L B), the ARC (C T), and the University of Kentucky (M C), and also discussions with D DeMille. NR 41 TC 51 Z9 51 U1 0 U2 11 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 1367-2630 J9 NEW J PHYS JI New J. Phys. PD MAY 14 PY 2009 VL 11 AR 055039 DI 10.1088/1367-2630/11/5/055039 PG 18 WC Physics, Multidisciplinary SC Physics GA 448AW UT WOS:000266234500030 ER PT J AU Carr, LD DeMille, D Krems, RV Ye, J AF Carr, Lincoln D. DeMille, David Krems, Roman V. Ye, Jun TI Cold and ultracold molecules: science, technology and applications SO NEW JOURNAL OF PHYSICS LA English DT Review ID BOSE-EINSTEIN CONDENSATION; ELECTRIC DIPOLE MOMENT; NONLINEAR SCHRODINGER-EQUATION; FREQUENCY COMB SPECTROSCOPY; STOKES-RAMAN SCATTERING; GROUND-STATE MOLECULES; QUANTUM KINETIC-THEORY; LONG-RANGE MOLECULES; POLAR-MOLECULES; ATTRACTIVE INTERACTIONS AB This paper presents a review of the current state of the art in the research field of cold and ultracold molecules. It serves as an introduction to the focus issue of New Journal of Physics on Cold and Ultracold Molecules and describes new prospects for fundamental research and technological development. Cold and ultracold molecules may revolutionize physical chemistry and few-body physics, provide techniques for probing new states of quantum matter, allow for precision measurements of both fundamental and applied interest, and enable quantum simulations of condensed-matter phenomena. Ultracold molecules offer promising applications such as new platforms for quantum computing, precise control of molecular dynamics, nanolithography and Bose-enhanced chemistry. The discussion is based on recent experimental and theoretical work and concludes with a summary of anticipated future directions and open questions in this rapidly expanding research field. C1 [Carr, Lincoln D.] Colorado Sch Mines, Dept Phys, Golden, CO 80401 USA. [DeMille, David] Yale Univ, Dept Phys, New Haven, CT 06520 USA. [Krems, Roman V.] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada. [Ye, Jun] Univ Colorado, Natl Inst Stand & Technol, Joint Inst Lab Astrophys, Boulder, CO 80309 USA. [Ye, Jun] Univ Colorado, Dept Phys, Boulder, CO 80309 USA. RP Carr, LD (reprint author), Colorado Sch Mines, Dept Phys, Golden, CO 80401 USA. EM lcarr@mines.edu; david.demille@yale.edu; rkrems@chem.ubc.ca; Ye@jila.colorado.edu RI Ye, Jun/C-3312-2011; Carr, Lincoln/E-3819-2016 OI Carr, Lincoln/0000-0002-4848-7941 FU National Science Foundation [PHY-0547845, DMR-0653377, PHY-0758045]; DOE; ARO; NSERC of Canada; NIST FX LDC acknowledges support from the National Science Foundation under Grant PHY-0547845 as part of the NSF CAREER program. DD acknowledges support from NSF (DMR-0653377 and PHY-0758045), DOE and ARO. The work of RVK is supported by NSERC of Canada. JY acknowledges support from DOE, NIST and NSF and he thanks colleagues at JILA for their collaborations on cold and ultracold molecules over the last 9 years. NR 488 TC 626 Z9 630 U1 16 U2 165 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 1367-2630 J9 NEW J PHYS JI New J. Phys. PD MAY 14 PY 2009 VL 11 AR 055049 DI 10.1088/1367-2630/11/5/055049 PG 87 WC Physics, Multidisciplinary SC Physics GA 448AW UT WOS:000266234500040 ER PT J AU Kotochigova, S Tiesinga, E Julienne, PS AF Kotochigova, Svetlana Tiesinga, Eite Julienne, Paul S. TI Multi-channel modelling of the formation of vibrationally cold polar KRb molecules SO NEW JOURNAL OF PHYSICS LA English DT Article ID RELAXATION RATES; STATE; ATOMS; GAS AB We describe the theoretical advances that influenced the experimental creation of vibrationally and translationally cold polar (40)K(87)Rb molecules [1, 2]. Cold molecules were created from very-weakly bound molecules formed by magnetic field sweeps near a Feshbach resonance in collisions of ultra-cold (40)K and (87)Rb atoms. Our analysis include the multi-channel bound-state calculations of the hyperfine and Zeeman mixed X(1)Sigma(+) and a(3)Sigma(+) vibrational levels. We find excellent agreement with the hyperfine structure observed in experimental data. In addition, we studied the spin-orbit mixing in the intermediate state of the Raman transition. This allowed us to investigate its effect on the vibrationally averaged transition dipole moment to the lowest rovibrational level of the X(1)Sigma(+) state. Finally, we obtained an estimate of the polarizability of the initial and final rovibrational states of the Raman transition near frequencies relevant for optical trapping of the molecules. C1 [Kotochigova, Svetlana] Temple Univ, Dept Phys, Philadelphia, PA 19122 USA. [Tiesinga, Eite; Julienne, Paul S.] NIST, Joint Quantum Inst, Gaithersburg, MD 20899 USA. [Tiesinga, Eite; Julienne, Paul S.] Univ Maryland, Gaithersburg, MD 20899 USA. RP Kotochigova, S (reprint author), Temple Univ, Dept Phys, Philadelphia, PA 19122 USA. EM skotoch@temple.edu RI Julienne, Paul/E-9378-2012 OI Julienne, Paul/0000-0002-5494-1442 FU ARO; AFOSR; ONR FX SK acknowledges support from the ARO and AFOSR and PSJ acknowledges partial support from the ONR. NR 22 TC 16 Z9 16 U1 0 U2 9 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 1367-2630 J9 NEW J PHYS JI New J. Phys. PD MAY 14 PY 2009 VL 11 AR 055043 DI 10.1088/1367-2630/11/5/055043 PG 15 WC Physics, Multidisciplinary SC Physics GA 448AW UT WOS:000266234500034 ER PT J AU Parazzoli, LP Fitch, N Lobser, DS Lewandowski, HJ AF Parazzoli, L. P. Fitch, N. Lobser, D. S. Lewandowski, H. J. TI High-energy-resolution molecular beams for cold collision studies SO NEW JOURNAL OF PHYSICS LA English DT Article ID INTEGRAL CROSS-SECTIONS; INELASTIC-SCATTERING AB Stark deceleration allows for precise control over the velocity of a pulsed molecular beam and, by the nature of its limited phase-space acceptance, reduces the energy width of the decelerated packet. We describe an alternate method of operating a Stark decelerator that further reduces the energy spread over the standard method of operation. In this alternate mode of operation, we aggressively decelerate the molecular packet using a high phase angle. This technique brings the molecular packet to the desired velocity before it reaches the end of the decelerator; the remaining stages are then used to longitudinally and transversely guide the packet to the detection/interaction region. The result of the initial aggressive slowing is a reduction in the phase-space acceptance of the decelerator and thus a narrowing of the velocity spread of the molecular packet. In addition to the narrower energy spread, this method also results in a velocity spread that is nearly independent of the final velocity. Using the alternate deceleration technique, the energy resolution of molecular collision measurements can be improved considerably. C1 [Parazzoli, L. P.; Fitch, N.; Lobser, D. S.; Lewandowski, H. J.] Univ Colorado, Dept Phys, JILA, Natl Inst Stand & Technol, Boulder, CO 80309 USA. RP Parazzoli, LP (reprint author), Univ Colorado, Dept Phys, JILA, Natl Inst Stand & Technol, Boulder, CO 80309 USA. EM parazzoli@colorado.edu FU NSF; AFOSR; Petroleum Research Fund; Alfred P Sloan Foundation FX This work was supported by NSF, AFOSR, Petroleum Research Fund and the Alfred P Sloan Foundation. NR 25 TC 10 Z9 10 U1 0 U2 4 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 1367-2630 J9 NEW J PHYS JI New J. Phys. PD MAY 14 PY 2009 VL 11 AR 055031 DI 10.1088/1367-2630/11/5/055031 PG 12 WC Physics, Multidisciplinary SC Physics GA 448AW UT WOS:000266234500022 ER PT J AU Goddard, L DeWitt, DG Reynolds, RW AF Goddard, Lisa DeWitt, David G. Reynolds, Richard W. TI Practical implications of uncertainty in observed SSTs SO GEOPHYSICAL RESEARCH LETTERS LA English DT Article ID RECONSTRUCTION AB Uncertainties in the accuracy of observed sea surface temperature (SST) estimates limit a number of efforts relevant to seasonal-to-interannual climate variability and its prediction. Some of the efforts that may be hampered by uncertain SSTs include estimates of skill in predicted SSTs, attribution studies of seasonal climate anomalies, and calibration of probabilistic seasonal climate forecast systems. This study examines the explicit impact of SST uncertainties on the climate response from an atmospheric general circulation model. Uncertainties in Western Pacific SSTs play a substantial role in the sensitivity of the seasonal climate. Citation: Goddard, L., D. G. DeWitt, and R. W. Reynolds (2009), Practical implications of uncertainty in observed SSTs, Geophys. Res. Lett., 36, L09710, doi: 10.1029/2009GL037703. C1 [Goddard, Lisa; DeWitt, David G.] Columbia Univ, Earth Inst, Int Res Inst Climate & Soc, Palisades, NY 10964 USA. [Reynolds, Richard W.] NOAA, Natl Climate Data Ctr, Camp Springs, MD 20746 USA. RP Goddard, L (reprint author), Columbia Univ, Earth Inst, Int Res Inst Climate & Soc, 22 Monell Bldg,61 Route 9W, Palisades, NY 10964 USA. EM goddard@iri.columbia.edu FU NOAA's Office of Climate Observations [NA03OAR4320179]; Columbia University [NA05OAR4311004]; National Oceanic and Atmospheric Association FX The authors acknowledge helpful suggestions from Tom Smith and Simon Mason. We appreciate Xiaofeng Gong's help in running and processing the AGCM experiments. This work was funded under grant NA03OAR4320179 from NOAA's Office of Climate Observations and cooperative agreement NA05OAR4311004 between Columbia University and the National Oceanic and Atmospheric Association. NR 8 TC 3 Z9 3 U1 1 U2 4 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0094-8276 J9 GEOPHYS RES LETT JI Geophys. Res. Lett. PD MAY 13 PY 2009 VL 36 AR L09710 DI 10.1029/2009GL037703 PG 6 WC Geosciences, Multidisciplinary SC Geology GA 446CX UT WOS:000266099100005 ER PT J AU Ho, CR Zheng, QA Zheng, ZW Kuo, NJ Tai, CK Su, FC AF Ho, Chung-Ru Zheng, Quanan Zheng, Zhe-Wen Kuo, Nan-Jung Tai, C. -K. Su, Feng-Chun TI Reply to comment by A. Wada et al. on "Importance of pre-existing oceanic conditions to upper ocean response induced by Super Typhoon Hai-Tang" SO GEOPHYSICAL RESEARCH LETTERS LA English DT Editorial Material ID SEA C1 [Ho, Chung-Ru; Zheng, Zhe-Wen; Kuo, Nan-Jung] Natl Taiwan Ocean Univ, Dept Marine Environm Informat, Chilung 20224, Taiwan. [Zheng, Quanan] Univ Maryland, Dept Atmospher & Ocean Sci, College Pk, MD 20742 USA. [Tai, C. -K.] NOAA NESDIS, Camp Springs, MD 20746 USA. [Su, Feng-Chun] Natl Sun Yat Sen Univ, Dept Marine Biotechnol & Resources, Kaohsiung 80424, Taiwan. RP Ho, CR (reprint author), Natl Taiwan Ocean Univ, Dept Marine Environm Informat, Chilung 20224, Taiwan. EM b0211@mail.ntou.edu.tw RI Tai, C.K./F-5628-2010 NR 12 TC 5 Z9 6 U1 0 U2 7 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0094-8276 J9 GEOPHYS RES LETT JI Geophys. Res. Lett. PD MAY 13 PY 2009 VL 36 AR L09604 DI 10.1029/2009GL037443 PG 3 WC Geosciences, Multidisciplinary SC Geology GA 446CX UT WOS:000266099100002 ER PT J AU Li, ZL Li, J Menzel, WP Nelson, JP Schmit, TJ Weisz, E Ackerman, SA AF Li, Zhenglong Li, Jun Menzel, W. Paul Nelson, James P., III Schmit, Timothy J. Weisz, Elisabeth Ackerman, Steven A. TI Forecasting and nowcasting improvement in cloudy regions with high temporal GOES sounder infrared radiance measurements SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID RETRIEVAL; ALGORITHM; MODIS; AIRS; ASSIMILATION; TEMPERATURE; VALIDATION; PARAMETERS; SOUNDINGS; MOISTURE AB In an effort to extend the high temporal resolution Geostationary Operational Environmental Satellite (GOES) infrared sounding retrievals from clear to cloudy skies, a synthetic regression-based cloudy sounding retrieval algorithm has been developed and applied to GOES 12 sounder measurements. Comparisons against radiosondes at the Atmospheric Radiation Measurement Program at Southern Great Plains site from August 2006 to May 2007 and the conventional radiosondes network over the continental United States from January 2007 to November 2008 both show that the retrievals of moisture under thin cloud conditions perform similarly to those under the clear-sky conditions. The largest improvements are found in the upper level integrated precipitable water vapor (PW) or PW3. Also in the case of low thick clouds, PW3 is usually improved significantly. In addition, the retrieved cloud parameters are consistent with the false RGB composite images. With the addition of the soundings under low thick or thin cloud conditions, the area without soundings is reduced by 57% in the selected case. The application to a tornadic storm on 24 April 2007 reveals that the GOES cloudy sounding retrievals are more useful at the early stage of the storm, when nearby clouds are considered thin or broken. The GOES cloudy sounding algorithm reveals more pronounced and extensive convective instability, and it does so earlier than the clear-sky-only results. The cloudy sounding retrievals have the potential to provide an earlier warning to forecasters. C1 [Li, Zhenglong; Li, Jun; Menzel, W. Paul; Nelson, James P., III; Weisz, Elisabeth; Ackerman, Steven A.] Univ Wisconsin, Cooperat Inst Meteorol Satellite Studies, Madison, WI 53706 USA. [Schmit, Timothy J.] NOAA, Ctr Satellite Applicat & Res, Natl Environm Satellite Data & Informat Serv, Madison, WI 53706 USA. RP Li, ZL (reprint author), Univ Wisconsin, Cooperat Inst Meteorol Satellite Studies, 1225 W Dayton St, Madison, WI 53706 USA. EM zhenglong.li@ssec.wisc.edu RI Schmit, Timothy/F-5624-2010; Menzel, W. Paul/B-8306-2011; Ackerman, Steven/G-1640-2011; Li, Zhenglong/A-9375-2013; Li, Jun/H-3579-2015 OI Menzel, W. Paul/0000-0001-5690-1201; Ackerman, Steven/0000-0002-4476-0269; Li, Jun/0000-0001-5504-9627 FU CIMSS [NA06NES4400002]; GOES-R [NA07EC0676] FX The authors would like to thank Hal Woolf for providing the 101-level PFAAST radiative transfer model for GOES 12 sounder. Some data were obtained from the Atmospheric Radiation Measurement (ARM) Program sponsored by the U. S. Department of Energy, Office of Science, Office of Biological and Environmental Research, Environmental Sciences Division. This program is supported at CIMSS by NOAA GIMPAP program NA06NES4400002 and GOES-R program NA07EC0676. The views, opinions, and findings contained in this report are those of the authors and should not be construed as an official National Oceanic and Atmospheric Administration or U. S. Government position, policy, or decision. NR 34 TC 11 Z9 11 U1 0 U2 2 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD MAY 13 PY 2009 VL 114 AR D09216 DI 10.1029/2008JD010596 PG 15 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 446DH UT WOS:000266100100001 ER PT J AU Martinez, E Ganachaud, A Lefevre, J Maamaatuaiahutapu, K AF Martinez, Elodie Ganachaud, Alexandre Lefevre, Jerome Maamaatuaiahutapu, Keitapu TI Central South Pacific thermocline water circulation from a high-resolution ocean model validated against satellite data: Seasonal variability and El Nino 1997-1998 influence SO JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS LA English DT Article ID EASTERN TROPICAL PACIFIC; SUBSURFACE COUNTERCURRENTS; TUAMOTU ARCHIPELAGO; EQUATORIAL PACIFIC; FRENCH-POLYNESIA; SURFACE CURRENTS; AGULHAS CURRENT; DYNAMICS; ISLANDS; WIND AB The oceanic circulation in French Polynesia, central South Pacific, is investigated based on a high-resolution model validated with satellite data. We focus on the upper 500 m, where ocean current variability has been barely documented due to a lack of in situ measurements. Seasonal and El Nino-Southern Oscillation 1997-1999 variability of surface and subsurface currents are characterized. In the north, the South Equatorial Current (SEC) follows a seasonal cycle with winter enhancement corresponding to trade wind strengthening. During summer, the SEC slows and the eastward South Equatorial Countercurrent (SECC) appears across the domain north of an upward Ekman pumping region related to the South Pacific Convergence Zone development in the area. Around the Marquesas Islands, a wind curl dipole is suspected to create westward and eastward (Marquesas Countercurrent, MCC) jets. The eastward Subtropical Countercurrent (STCC) is found south of 20 degrees S. It is disturbed by eddies and broken into westward and eastward branches. During El Nino 1997-1998, due to the reversed winds in the equatorial band, the SEC weakened, while eastward countercurrents appeared. The SECC reinforced and moved northeastward in summer 1998. During La Nina 1998-1999, following the trade wind enhancement, the SEC strengthened. The countercurrents weakened or disappeared and the SECC moved southwestward in summer 1999. During both El Nino and La Nina events, the STCC eddy activity strengthened, while the MCC and associated westward jet were absent. These variations and their dynamical origins are discussed, and a coherent picture of the French Polynesian current system and its variations is proposed. C1 [Martinez, Elodie; Maamaatuaiahutapu, Keitapu] Univ Polynesie Francaise, Lab Terre Ocean, Faaa 98702, Fr Polynesia. [Ganachaud, Alexandre; Lefevre, Jerome] Inst Rech Dev, Lab Etud Geophys & Oceanog Spatiales, Noumea, New Caledonia. [Ganachaud, Alexandre; Lefevre, Jerome] Univ Toulouse 3, Lab Etud Geophys & Oceanog Spatiales, Observ Midi Pyrenees Phys Chim Automat, Toulouse, France. [Ganachaud, Alexandre] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. RP Martinez, E (reprint author), CNRS, UPMC, UMR7093, F-06230 Villefranche Sur Mer, France. EM martinez@obs-vlfr.fr RI martinez, elodie/E-3237-2012; Ganachaud, Alexandre/B-7556-2013; LEFEVRE, Jerome/L-8569-2015; OI martinez, elodie/0000-0001-6507-6119; Maamaatuaiahutapu, Keitapu/0000-0003-4071-0472 FU Joint Institute for the Study of the Atmosphere and Ocean (JISAO) [NA17RJ1232] FX The help and stimulating comments of W. Kessler and an anonymous reviewer were greatly appreciated. P. Marchesiello helped to set up the numerical simulation. Insightful comments of the two reviewers greatly helped improve the manuscript. E. M. was supported by a grant from the Research Ministry of French Polynesia. Support from the French Overseas Ministry allowed collaboration with the IRD Noumea LEGOS laboratory. This publication is partially funded by the Joint Institute for the Study of the Atmosphere and Ocean (JISAO) under NOAA Cooperative Agreement NA17RJ1232, contribution 1479, and the Pacific Marine Environmental Laboratory, contribution 3190. NR 54 TC 4 Z9 4 U1 0 U2 5 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0148-0227 J9 J GEOPHYS RES-OCEANS JI J. Geophys. Res.-Oceans PD MAY 13 PY 2009 VL 114 AR C05012 DI 10.1029/2008JC004824 PG 16 WC Oceanography SC Oceanography GA 446DQ UT WOS:000266101000002 ER PT J AU Janik, JA Zhou, HD Jo, YJ Balicas, L MacDougall, GJ Luke, GM Garrett, JD McClellan, KJ Bauer, ED Sarrao, JL Qiu, Y Copley, JRD Yamani, Z Buyers, WJL Wiebe, CR AF Janik, J. A. Zhou, H. D. Jo, Y-J Balicas, L. MacDougall, G. J. Luke, G. M. Garrett, J. D. McClellan, K. J. Bauer, E. D. Sarrao, J. L. Qiu, Y. Copley, J. R. D. Yamani, Z. Buyers, W. J. L. Wiebe, C. R. TI Itinerant spin excitations near the hidden order transition in URu2Si2 SO JOURNAL OF PHYSICS-CONDENSED MATTER LA English DT Article ID ELECTRON SUPERCONDUCTOR URU2SI2; MAGNETIC EXCITATIONS; NEUTRON-SCATTERING; FERMI-SURFACE; FLUCTUATIONS AB By means of neutron scattering we show that the high temperature precursor to the hidden order state of the heavy fermion superconductor URu2Si2 exhibits heavily damped incommensurate paramagnons whose strong energy dispersion is very similar to that of the long-lived longitudinal f spin excitations that appear below T-0. This suggests that there is a strongly hybridized character to the itinerant excitations observed previously above the hidden order transition. Here we present evidence that the itinerant excitations, like those in chromium, are due to Fermi surface nesting of hole and electron pockets; hence the hidden order phase probably originates from a Fermi surface instability. We identify wavevectors that span nested regions of a f-d hybridized band calculation and that match the neutron spin crossover from incommensurate to commensurate on approach to the hidden order phase. C1 [Janik, J. A.; Wiebe, C. R.] Florida State Univ, Dept Phys, Tallahassee, FL 32306 USA. [Janik, J. A.; Zhou, H. D.; Jo, Y-J; Balicas, L.; Wiebe, C. R.] Florida State Univ, Natl High Magnet Field Lab, Tallahassee, FL 32306 USA. [MacDougall, G. J.; Luke, G. M.] McMaster Univ, Dept Phys & Astron, Hamilton, ON L8S 4M1, Canada. [Luke, G. M.; Buyers, W. J. L.] Canadian Inst Adv Res, Toronto, ON M5G 1Z8, Canada. [Garrett, J. D.] McMaster Univ, Brockhouse Inst Mat Res, Hamilton, ON L8S 4M1, Canada. [McClellan, K. J.; Bauer, E. D.; Sarrao, J. L.] Los Alamos Natl Lab, Sci Technol & Engn Directorate, Los Alamos, NM 87545 USA. [Qiu, Y.; Copley, J. R. D.] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Qiu, Y.] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. [Yamani, Z.; Buyers, W. J. L.] CNBC, Natl Res Council, Chalk River, ON K0J 1J0, Canada. RP Janik, JA (reprint author), Carnegie Inst Washington, Geophys Lab, 5251 Broad Branch Rd NW, Washington, DC 20015 USA. EM cwiebe@magnet.fsu.edu RI Bauer, Eric/D-7212-2011; yamani, zahra/B-7892-2012; Luke, Graeme/A-9094-2010; Zhou, Haidong/O-4373-2016; OI Luke, Graeme/0000-0003-4762-1173; Bauer, Eric/0000-0003-0017-1937; MacDougall, Gregory/0000-0002-7490-9650 FU NSF [CDMR-0084173, DMR-0454672]; EIEG; State of Florida; NSERC; US DOE FX This work was supported by the NSF CDMR-0084173, DMR-0454672, the EIEG program (FSU) and the State of Florida. The work at McMaster is supported by NSERC and at Los Alamos by the US DOE. The authors are grateful for the local support staff at the NIST Center for Neutron Research and Chalk River Laboratories. The authors would also like to acknowledge the support of the UCGP at the NHMFL. NR 23 TC 19 Z9 19 U1 0 U2 9 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0953-8984 J9 J PHYS-CONDENS MAT JI J. Phys.-Condes. Matter PD MAY 13 PY 2009 VL 21 IS 19 AR 192202 DI 10.1088/0953-8984/21/19/192202 PG 4 WC Physics, Condensed Matter SC Physics GA 436MO UT WOS:000265418400002 PM 21825472 ER PT J AU Gibson, EA Shen, ZC Jimenez, R AF Gibson, Emily A. Shen, Zhaochuan Jimenez, Ralph TI Three-pulse photon echo peak shift spectroscopy as a probe of flexibility and conformational heterogeneity in protein folding SO CHEMICAL PHYSICS LETTERS LA English DT Article ID CYTOCHROME-C; SOLVATION DYNAMICS; STRUCTURAL-CHARACTERIZATION; FREQUENCY VIBRATIONS; CIRCULAR-DICHROISM; LANDSCAPE; KINETICS; 3RD-ORDER; COHERENCE; SPECTRA AB We investigate the equilibrium unfolding of Zn-cytochrome c in guanidine hydrochloride by three-pulse photon echo peak shift (3PEPS) spectroscopy. Unexpectedly, the measurements reveal that inhomogeneous broadening of the sample at the midpoint of the denaturation is larger than that of either native or unfolded states. To interpret this finding, we present simulations of the peak shift for both two-state and three-state unfolding models. Both the denaturant concentration dependence of the asymptotic peak shift (APS) and the wavelength dependence of the APS at the midpoint of the denaturation are different for the two models. Our data are consistent with two-state unfolding. Published by Elsevier B.V. C1 [Jimenez, Ralph] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA. [Gibson, Emily A.] Univ Colorado, Dept Phys, Denver, CO 80217 USA. [Shen, Zhaochuan] Univ Colorado, Dept Phys, Boulder, CO 80309 USA. [Shen, Zhaochuan; Jimenez, Ralph] Natl Inst Stand & Technol, JILA, Boulder, CO 80309 USA. RP Jimenez, R (reprint author), Univ Colorado, Dept Chem & Biochem, Campus Box 215, Boulder, CO 80309 USA. EM rjimenez@jila.colorado.edu FU National Science Foundation [DBI0454763]; Physics Frontier Center at JILA [PHY0551010]; NIH/CU Biophysics Training [T32 GM-065103]; Quantum Physics Division of NIST FX This work was supported by the National Science Foundation DBI0454763, the Physics Frontier Center at JILA (PHY0551010), and by NIH/CU Biophysics Training Grant (T32 GM-065103) (to Z.S.). R.J. is a staff member in the Quantum Physics Division of NIST. NR 34 TC 10 Z9 12 U1 0 U2 7 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0009-2614 J9 CHEM PHYS LETT JI Chem. Phys. Lett. PD MAY 12 PY 2009 VL 473 IS 4-6 BP 330 EP 335 DI 10.1016/j.cplett.2009.04.002 PG 6 WC Chemistry, Physical; Physics, Atomic, Molecular & Chemical SC Chemistry; Physics GA 443KM UT WOS:000265908600023 PM 21103002 ER PT J AU Mauldin, CE Puntambekar, K Murphy, AR Liao, F Subramanian, V Frechet, JMJ DeLongchamp, DM Fischer, DA Toney, MF AF Mauldin, Clayton E. Puntambekar, Kanan Murphy, Amanda R. Liao, Frank Subramanian, Vivek Frechet, Jean M. J. DeLongchamp, Dean M. Fischer, Daniel A. Toney, Michael F. TI Solution-Processable alpha,omega-Distyryl Oligothiophene Semiconductors with Enhanced Environmental Stability SO CHEMISTRY OF MATERIALS LA English DT Article ID FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; ORGANIC SEMICONDUCTORS; EFFECT MOBILITY; PERFORMANCE; THIOPHENE AB We describe the rational design of oligothiophene semiconductors to facilitate solution-based fabrication of environmentally stable organic field-effect transistors (OFETs). Ultrathin films of alpha,omega-distyryl quaterthiophene (DS4T), pentathiophene (DS5T), and sexithiophene (DS6T) were prepared via solution processing to probe the effect of styryl end groups, oligomer length, and thin film structure on air stability. These films were prepared via solution deposition and thermal annealing of precursors featuring thermally labile ester solubilizing groups. A detailed study of the thin film structure was performed using atomic force microscopy (AFM), near-edge X-ray absorption fine structure (NEXAFS) spectroscopy, and grazing incidence X-ray diffraction (GIXD). Functional OFETs were obtained for DS5T and DS6T and have, respectively, hole mobilities of 0.051 and 0.043 cm(2)/(V s) and on/off ratios of 1 x 10(5) to 1 x 10(6), whereas DS4T OFETs failed to function because of poor film continuity. The effect of both short-term and long-term exposure to air is tracked in OFETs revealing remarkable stability for both DS5T and DS6T. This stability is attributed to the elimination of reactive sites in alpha,omega-distyryl oligothiophenes and suggests that careful choice of end-group structure can stabilize these molecules against oxidative degradation. C1 [Mauldin, Clayton E.; Murphy, Amanda R.; Frechet, Jean M. J.] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA. [Puntambekar, Kanan; Liao, Frank; Subramanian, Vivek] Univ Calif Berkeley, Dept Elect Engn & Comp Sci, Berkeley, CA 94720 USA. [Mauldin, Clayton E.; Murphy, Amanda R.; Frechet, Jean M. J.] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA. [DeLongchamp, Dean M.; Fischer, Daniel A.] NIST, Div Polymers, Gaithersburg, MD 20899 USA. [Toney, Michael F.] Stanford Synchrotron Radiat Lab, Menlo Pk, CA USA. RP Frechet, JMJ (reprint author), Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA. EM frechet@berkeley.edu RI Subramanian, Vivek/K-9818-2016 OI Subramanian, Vivek/0000-0002-1783-8219 FU U.S. Department of Energy [DE-AC02-05CH11231] FX This work was supported by the Director, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division, of the U.S. Department of Energy under Contract DE-AC02-05CH11231. Portions of this research were carried out at the Stanford Synchrotron Radiation Laboratory, a national user facility operated by Stanford University on behalf of the U.S. Department of Energy, Office of Basic Energy Sciences. We acknowledge Daniel Poulsen for assistance with DFT calculations. NR 37 TC 26 Z9 26 U1 0 U2 11 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0897-4756 EI 1520-5002 J9 CHEM MATER JI Chem. Mat. PD MAY 12 PY 2009 VL 21 IS 9 BP 1927 EP 1938 DI 10.1021/cm900267v PG 12 WC Chemistry, Physical; Materials Science, Multidisciplinary SC Chemistry; Materials Science GA 441PK UT WOS:000265781000027 ER PT J AU Zhang, H Srolovitz, DJ Douglas, JF Warren, JA AF Zhang, Hao Srolovitz, David J. Douglas, Jack F. Warren, James A. TI Grain boundaries exhibit the dynamics of glass-forming liquids SO PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA LA English DT Article DE glass formation; grain-boundary mobility; molecular dynamics; polycrystalline materials; string-like collective motion ID STRUCTURAL RELAXATION; METALS; BEHAVIOR; TRANSITION; MIGRATION; MOTION AB Polycrystalline materials are composites of crystalline particles or "grains" separated by thin "amorphous" grain boundaries (GBs). Although GBs have been exhaustively investigated at low temperatures, at which these regions are relatively ordered, much less is known about them at higher temperatures, where they exhibit significant mobility and structural disorder and characterization methods are limited. The time and spatial scales accessible to molecular dynamics (MD) simulation are appropriate for investigating the dynamical and structural properties of GBs at elevated temperatures, and we exploit MD to explore basic aspects of GB dynamics as a function of temperature. It has long been hypothesized that GBs have features in common with glass-forming liquids based on the processing characteristics of polycrystalline materials. We find remarkable support for this suggestion, as evidenced by string-like collective atomic motion and transient caging of atomic motion, and a non-Arrhenius GB mobility describing the average rate of large-scale GB displacement. C1 [Douglas, Jack F.] Natl Inst Stand & Technol, Div Polymers, Gaithersburg, MD 20899 USA. [Warren, James A.] Natl Inst Stand & Technol, Div Met, Gaithersburg, MD 20899 USA. [Srolovitz, David J.] Yeshiva Univ, Yeshiva Coll, Dept Phys, New York, NY 10033 USA. [Zhang, Hao] Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 2V4, Canada. RP Douglas, JF (reprint author), Natl Inst Stand & Technol, Div Polymers, Gaithersburg, MD 20899 USA. EM jack.douglas@nist.gov RI Warren, James/B-1698-2008; Zhang, Hao/A-3272-2008 OI Warren, James/0000-0001-6887-1206; FU U.S. Department of Energy [DE-FG02-99ER45797]; National Institute of Standards and Technology FX We thank Robert Riggleman of the University of Wisconsin and Anneke Levelt Sengers of the National Institute of Standards and Technology for helpful comments and questions about the work, and we acknowledge the support of the U.S. Department of Energy (DE-FG02-99ER45797) and the National Institute of Standards and Technology. Useful group discussions were facilitated by the Department Of Energy Office of Basic Energy Sciences Computational Materials Science Network program. NR 39 TC 74 Z9 74 U1 1 U2 21 PU NATL ACAD SCIENCES PI WASHINGTON PA 2101 CONSTITUTION AVE NW, WASHINGTON, DC 20418 USA SN 0027-8424 J9 P NATL ACAD SCI USA JI Proc. Natl. Acad. Sci. U. S. A. PD MAY 12 PY 2009 VL 106 IS 19 BP 7735 EP 7740 DI 10.1073/pnas.0900227106 PG 6 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA 447RG UT WOS:000266208900013 PM 19416913 ER PT J AU Sparks, WB Hough, J Germer, TA Chen, F DasSarma, S DasSarma, P Robb, FT Manset, N Kolokolova, L Reid, N Macchetto, FD Martin, W AF Sparks, William B. Hough, James Germer, Thomas A. Chen, Feng DasSarma, Shiladitya DasSarma, Priya Robb, Frank T. Manset, Nadine Kolokolova, Ludmilla Reid, Neill Macchetto, F. Duccio Martin, William TI Detection of circular polarization in light scattered from photosynthetic microbes SO PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA LA English DT Article DE homochirality; life detection; remote sensing ID AMINO-ACIDS; SIGNATURES; ORGANISMS; DICHROISM; BIOFILMS; DIVERSE; PLANETS; EUROPA; MARS; LIFE AB The identification of a universal biosignature that could be sensed remotely is critical to the prospects for success in the search for life elsewhere in the universe. A candidate universal biosignature is homochirality, which is likely to be a generic property of all biochemical life. Because of the optical activity of chiral molecules, it has been hypothesized that this unique characteristic may provide a suitable remote sensing probe using circular polarization spectroscopy. Here, we report the detection of circular polarization in light scattered by photosynthetic microbes. We show that the circular polarization appears to arise from circular dichroism of the strong electronic transitions of photosynthetic absorption bands. We conclude that circular polarization spectroscopy could provide a powerful remote sensing technique for generic life searches. C1 [Sparks, William B.; Reid, Neill; Macchetto, F. Duccio] Space Telescope Sci Inst, Baltimore, MD 21218 USA. [Hough, James; Martin, William] Univ Hertfordshire, Ctr Astrophys Res, Hatfield AL10 9AB, Herts, England. [Germer, Thomas A.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. [Chen, Feng; DasSarma, Shiladitya; DasSarma, Priya; Robb, Frank T.] Univ Maryland, Ctr Marine Biotechnol, Inst Biotechnol, Baltimore, MD 21202 USA. [Manset, Nadine] Canada France Hawaii Telescope Corp, Kamuela, HI 96743 USA. [Kolokolova, Ludmilla] Univ Maryland, Dept Astron, College Pk, MD 20742 USA. RP Sparks, WB (reprint author), Space Telescope Sci Inst, 3700 San Martin Dr, Baltimore, MD 21218 USA. EM sparks@stsci.edu RI Chen, Feng/P-3088-2014; OI Robb, Frank/0000-0001-5833-6496 FU Space Telescope and Science Institute Director's Discretionary Research Fund [82374]; European Space Agency; National Aeronautics and Space Administration [NNX09AC68G] FX We acknowledge support for this work through the Space Telescope and Science Institute Director's Discretionary Research Fund Grant 82374, and by the European Space Agency and National Aeronautics and Space Administration Grant NNX09AC68G (to S. D.). NR 46 TC 26 Z9 26 U1 0 U2 10 PU NATL ACAD SCIENCES PI WASHINGTON PA 2101 CONSTITUTION AVE NW, WASHINGTON, DC 20418 USA SN 0027-8424 J9 P NATL ACAD SCI USA JI Proc. Natl. Acad. Sci. U. S. A. PD MAY 12 PY 2009 VL 106 IS 19 BP 7816 EP 7821 DI 10.1073/pnas.0810215106 PG 6 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA 447RG UT WOS:000266208900027 PM 19416893 ER PT J AU Zeng, HC Chambers, JQ Negron-Juarez, RI Hurtt, GC Baker, DB Powell, MD AF Zeng, Hongcheng Chambers, Jeffrey Q. Negron-Juarez, Robinson I. Hurtt, George C. Baker, David B. Powell, Mark D. TI Impacts of tropical cyclones on US forest tree mortality and carbon flux from 1851 to 2000 SO PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA LA English DT Article DE carbon balance; forest biomass; hurricanes; spatial-temporal dynamics; wind field ID HURRICANE ACTIVITY; SEQUESTRATION; DYNAMICS; BASIN; COAST AB Tropical cyclones cause extensive tree mortality and damage to forested ecosystems. A number of patterns in tropical cyclone frequency and intensity have been identified. There exist, however, few studies on the dynamic impacts of historical tropical cyclones at a continental scale. Here, we synthesized field measurements, satellite image analyses, and empirical models to evaluate forest and carbon cycle impacts for historical tropical cyclones from 1851 to 2000 over the continental U.S. Results demonstrated an average of 97 million trees affected each year over the entire United States, with a 53-Tg annual biomass loss, and an average carbon release of 25 Tg y(-1). Over the period 1980-1990, released CO(2) potentially offset the carbon sink in forest trees by 9-18% over the entire United States. U.S. forests also experienced twice the impact before 1900 than after 1900 because of more active tropical cyclones and a larger extent of forested areas. Forest impacts were primarily located in Gulf Coast areas, particularly southern Texas and Louisiana and south Florida, while significant impacts also occurred in eastern North Carolina. Results serve as an important baseline for evaluating how potential future changes in hurricane frequency and intensity will impact forest tree mortality and carbon balance. C1 [Zeng, Hongcheng; Chambers, Jeffrey Q.; Negron-Juarez, Robinson I.; Baker, David B.] Tulane Univ, Dept Ecol & Evolutionary Biol, New Orleans, LA 70118 USA. [Hurtt, George C.] Univ New Hampshire, Inst Study Earth Oceans & Space, Durham, NH 03824 USA. [Powell, Mark D.] Natl Ocean & Atmospher Adm, Hurricane Res Div, Miami, FL 33149 USA. RP Zeng, HC (reprint author), Tulane Univ, Dept Ecol & Evolutionary Biol, 400 Boggs Ctr, New Orleans, LA 70118 USA. EM hzeng@tulane.edu RI Hurtt, George/A-8450-2012; Powell, Mark/I-4963-2013; Chambers, Jeffrey/J-9021-2014 OI Powell, Mark/0000-0002-4890-8945; Chambers, Jeffrey/0000-0003-3983-7847 FU U.S. Department of Energy's Office of Science through the Coastal Center of the National Institute for Climatic Change Research at Tulane University; National Oceanic and Atmospheric Administration; United States Geological Survey; Tulane University's Research Enhancement Fund FX This work was supported by the U.S. Department of Energy's Office of Science through the Coastal Center of the National Institute for Climatic Change Research at Tulane University, the Long-Term Estuary Assessment Group with funding from the National Oceanic and Atmospheric Administration and the United States Geological Survey, and Tulane University's Research Enhancement Fund. We greatly appreciate discussions with Prof. Emery Boose from Harvard University, who was consulted on the meteorological model of HURRECON, and comments and suggestions from 2 anonymous reviewers. NR 27 TC 43 Z9 43 U1 2 U2 22 PU NATL ACAD SCIENCES PI WASHINGTON PA 2101 CONSTITUTION AVE NW, WASHINGTON, DC 20418 USA SN 0027-8424 J9 P NATL ACAD SCI USA JI Proc. Natl. Acad. Sci. U. S. A. PD MAY 12 PY 2009 VL 106 IS 19 BP 7888 EP 7892 DI 10.1073/pnas.0808914106 PG 5 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA 447RG UT WOS:000266208900039 PM 19416842 ER PT J AU Keller, MW Kos, AB Silva, TJ Rippard, WH Pufall, MR AF Keller, Mark W. Kos, A. B. Silva, T. J. Rippard, W. H. Pufall, M. R. TI Time domain measurement of phase noise in a spin torque oscillator SO APPLIED PHYSICS LETTERS LA English DT Article DE cobalt alloys; copper; iron alloys; nanocontacts; nickel alloys; phase locked loops; phase locked oscillators; phase noise; tantalum AB We measure oscillator phase from the zero crossings of the voltage versus time waveform of a spin torque nanocontact oscillating in a vortex mode. The power spectrum of the phase noise varies with Fourier frequency f as 1/f(2), consistent with frequency fluctuations driven by a thermal source. The linewidth implied by phase noise alone is about 70% of that measured using a spectrum analyzer. A phase-locked loop reduces the phase noise for frequencies within its 3 MHz bandwidth. C1 [Keller, Mark W.; Kos, A. B.; Silva, T. J.; Rippard, W. H.; Pufall, M. R.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Keller, MW (reprint author), Natl Inst Stand & Technol, Boulder, CO 80305 USA. EM mark.keller@boulder.nist.gov RI Silva, Thomas/C-7605-2013 OI Silva, Thomas/0000-0001-8164-9642 NR 13 TC 44 Z9 44 U1 0 U2 10 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 0003-6951 J9 APPL PHYS LETT JI Appl. Phys. Lett. PD MAY 11 PY 2009 VL 94 IS 19 AR 193105 DI 10.1063/1.3133356 PG 3 WC Physics, Applied SC Physics GA 448LF UT WOS:000266263400054 ER PT J AU Cui, XP Li, XF Zong, ZP AF Cui, Xiaopeng Li, Xiaofan Zong, Zhiping TI Cloud microphysical and rainfall responses to zonal perturbations of sea surface temperature: A cloud-resolving modeling study SO PROGRESS IN NATURAL SCIENCE LA English DT Article DE Cloud microphysical and rainfall responses; Sea surface temperature; Zonal perturbation; Cloud-resolving modeling study ID TROPICAL EQUILIBRIUM STATES; MICROSCALE STRUCTURE; DIURNAL-VARIATIONS; FRONTAL RAINBANDS; SST GRADIENTS; CONVECTION; RADIATION; MESOSCALE; WATER; PARAMETERIZATION AB The cloud microphysical and rainfall responses to zonal perturbations of sea surface temperature (SST) are investigated by analyzing the equilibrium simulation data (from day 31 40) obtained from a series of two-dimensional cloud-resolving simulations with a zonal model domain of 768 km. Four experiments imposed by zonal SST perturbations of wavenumbers 1 (SST29Z1), 2 (SST29Z2), 4 (SST29Z4), and 8 (SST29Z8) are compared to the control experiment imposed by zonally uniform SST (SST29). The model domain mean SST is 29 degrees C, and the two-dimensional cloud-resolving model with a cyclic lateral boundary is also imposed by zero vertical velocity and constant zonal wind. The time and model domain mean surface rain rates in SST29Z1, SST29Z2, and SST29Z8 are about 10% larger than those in SST29, whereas the mean surface rain rates in SST29Z4 and SST29 are similar. The analysis of mean surface rainfall budgets shows that local water vapor and hydrometeor changes play important roles in determining the differences and similarities in mean surface rain rate between the perturbation experiments and the control experiment. Both convective and stratiform rain rates are larger in SST29Z1 and SST29Z2 than in SST29 due to the smaller advection of rain from convective regions into raining stratiform regions and the larger vapor condensation rates associated with the larger water vapor convergence over raining stratiform regions in SST29Z1 and SST29Z2. The convective rain rates are larger in SST29Z4 and SST29Z8 than in SST29 because of the larger condensation rates associated with the larger water vapor convergence over convective regions in SST29Z4 and SST29Z8. The stratiform rain rates in SST29Z4 and SST29Z8 are smaller than in SST29 due to the smaller vapor condensation rates and smaller collection rates of cloud water by rain over raining stratiform regions in SST29Z4 and SST29Z8. (C) 2008 National Natural Science Foundation of China and Chinese Academy of Sciences. Published by Elsevier Limited and Science in China Press. All rights reserved. C1 [Cui, Xiaopeng] Chinese Acad Sci, Inst Atmospher Phys, Lab Cloud Precipitat Phys & Severe Storms LACS, Beijing 100029, Peoples R China. [Li, Xiaofan] Joint Ctr Satellite Data Assimilat, Camp Springs, MD USA. [Li, Xiaofan] NOAA NESDIS Off Res & Applicat, Camp Springs, MD USA. [Zong, Zhiping] China Meteorol Adm, Natl Meteorol Ctr, Beijing 100081, Peoples R China. RP Cui, XP (reprint author), Chinese Acad Sci, Inst Atmospher Phys, Lab Cloud Precipitat Phys & Severe Storms LACS, Beijing 100029, Peoples R China. EM xpcui@mail.iap.ac.cn RI Li, Xiaofan/F-5605-2010; Li, Xiaofan/G-2094-2014 FU National Basic Research Program of China [2009CB421505]; National Natural Sciences Foundation of China [40775036]; Knowledge Innovation Program of the Chinese Academy of Sciences [IAP07214] FX This work was supported by the National Basic Research Program of China (Grant No. 2009CB421505), National Natural Sciences Foundation of China (Grant No. 40775036), and the Knowledge Innovation Program of the Chinese Academy of Sciences (IAP07214). NR 25 TC 1 Z9 1 U1 0 U2 1 PU ELSEVIER SCIENCE INC PI NEW YORK PA 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA SN 1002-0071 J9 PROG NAT SCI JI Prog. Nat. Sci. PD MAY 10 PY 2009 VL 19 IS 5 BP 587 EP 594 DI 10.1016/j.pnsc.2008.08.003 PG 8 WC Materials Science, Multidisciplinary; Multidisciplinary Sciences SC Materials Science; Science & Technology - Other Topics GA 425TK UT WOS:000264659800009 ER PT J AU Iacovazzi, RA Cao, CY Boukabara, SA AF Iacovazzi, Robert A., Jr. Cao, Changyong Boukabara, Sid-Ahmed TI Analysis of Polar-orbiting Operational Environmental Satellite NOAA-14 MSU and NOAA-15 AMSU-A relative measurement biases for climate change detection SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID SIMULTANEOUS NADIR OBSERVATIONS; BRIGHTNESS TEMPERATURE BIASES; OVERPASSES; CHANNEL-2; WEATHER; TOVS AB In extending microwave sounding unit (MSU) brightness temperature (T-b) time series to Advanced MSU Series-A (AMSU-A) measurements, small discrepancies of channel frequency center and bandwidth between these two instruments can introduce T-b biases between them. In this study, the Microwave Integrated Retrieval System (MIRS), which includes the Community Radiative Transfer Model (CRTM), has been used to estimate, and then remove, this bias component from total T-b biases inferred between NOAA-14 MSU and NOAA-15 AMSU-A measurements using the simultaneous nadir overpass (SNO) method. Analysis results indicate a significant T-b bias of about 0.4 K between the NOAA-14 MSU and NOAA-15 AMSU-A 50.3-GHz channel observations. Meanwhile, the other MSU and AMSU-A channel pairs have frequency mismatches that lead to seasonal-and hemispheric-dependent T-b biases that can be larger than 1 K. Subtracting CRTM-estimated T-b biases related to frequency mismatch from SNO-deduced total T-b biases removes most seasonal-and hemispheric-dependent T-b biases, but some significant residual biases with magnitudes of about 0.4 K or less remain. These adjusted SNO-inferred T-b biases are attributed to a mix of uncaptured frequency-difference related, and calibration related, T-b biases. These two bias types are not separately quantified here, owing to indefinable uncertainties in the frequency-difference related T-b bias estimates. Thus techniques applied in this study to estimate calibration-related T-b biases between NOAA-14 MSU and NOAA-15 AMSU-A instruments can be useful in creating long-term temperature time series using NOAA microwave sounders, but a means to evaluate the indefinable uncertainties of frequency-difference related T-b bias estimates needs to be developed. C1 [Iacovazzi, Robert A., Jr.; Cao, Changyong; Boukabara, Sid-Ahmed] NOAA, NESDIS, Ctr Satellite Applicat & Res, Camp Springs, MD 20746 USA. [Iacovazzi, Robert A., Jr.] Earth Resources Technol Inc, Annapolis Jct, MD USA. RP Iacovazzi, RA (reprint author), NOAA, NESDIS, Ctr Satellite Applicat & Res, Room 712,World Weather Bldg,5200Auth Rd, Camp Springs, MD 20746 USA. EM bob.iacovazzi@noaa.gov RI Boukabara, Sid Ahmed/F-5577-2010; Cao, Changyong/F-5578-2010; Iacovazzi Jr, Robert/G-3867-2010 OI Boukabara, Sid Ahmed/0000-0002-1857-3806; FU NPP/NPOESS Integrated Program Office; National Oceanographic and Atmospheric Administration (NOAA); government of the United States of America FX The authors would like to thank Quanhua "Mark'' Liu for providing CRTM input transmittance functions for the MSU and AMSU-A instruments. We would also like to thank Cheng-Zhi Zou and Ping Jing for many constructive comments during the process of writing this paper. The research was supported by the NPP/NPOESS Integrated Program Office through the Internal Government Studies program. The contents of this paper represent the findings of the authors and do not constitute a viewpoint of the National Oceanographic and Atmospheric Administration (NOAA) or any other agency of the government of the United States of America. NR 22 TC 3 Z9 3 U1 0 U2 4 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD MAY 9 PY 2009 VL 114 AR D09107 DI 10.1029/2008JD011588 PG 12 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 443SI UT WOS:000265930500007 ER PT J AU Panday, AK Prinn, RG AF Panday, Arnico K. Prinn, Ronald G. TI Diurnal cycle of air pollution in the Kathmandu Valley, Nepal: Observations SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID OZONE DRY DEPOSITION; MEXICO-CITY BASIN; PHOTOCHEMICAL SMOG; BOUNDARY-LAYER; NUMERICAL-SIMULATION; METROPOLITAN-AREA; CARBON-MONOXIDE; LATE WINTERTIME; TRANSPORT; SANTIAGO AB During the dry season of 2004-2005 we carried out field measurements of air pollution and meteorology in the Kathmandu Valley, Nepal, a bowl-shaped urban basin in the Himalayan foothills of Nepal. We measured the trace gases carbon monoxide (CO) and ozone (O-3) and particulates (PM10), as well as meteorological variables. In our field observations we noted a very regular pattern of morning and evening peaks in CO and PM10 occurring daily in the valley bottom, interspersed with low values in the afternoons and at night. This pattern occurred even on days with unusual timing of emissions and was influenced by the timing of ventilation from the valley. Meteorological variables showed great day-to-day similarity, with a strong westerly wind blowing through the valley from late morning until dusk. We found that the air mass on nearby mountaintops was disconnected from pollution within the valley during the night, but received significant pollution during the morning, when up-slope flows began. At a pass on the western edge of the valley we found a diurnal switch in wind direction, with an inflow from late morning until late evening, and an outflow during the rest of the time. We found that part of the morning peak in pollution was caused by recirculation of pollutants emitted the night before, which spend the night in elevated layers over the valley. C1 [Panday, Arnico K.] Princeton Univ, Atmospher & Ocean Sci Program, Princeton, NJ 08540 USA. [Panday, Arnico K.; Prinn, Ronald G.] MIT, Ctr Global Change Sci, Cambridge, MA 02139 USA. RP Panday, AK (reprint author), Princeton Univ, Atmospher & Ocean Sci Program, GFDL Room 231,201 Forrestal Rd, Princeton, NJ 08540 USA. EM arnico@princeton.edu FU MIT Presidential Fellowship; Martin Fellowship for Sustainability; Alliance for Global Sustainability; PAOC Houghton Fund; TEPCO Chair account; NSF [ATM-0120468]; NASA [NAG5-12099, NAG5-12669]; Science and Policy of Global Change FX The research described in this paper were made possible through generous support from an MIT Presidential Fellowship, the Martin Fellowship for Sustainability, a pilot research project grant from the Alliance for Global Sustainability, the PAOC Houghton Fund, the TEPCO Chair account, NSF grant ATM-0120468 to MIT, NASA grants NAG5-12099 and NAG5-12669 to MIT, and the federal and industrial sponsors of the MIT Joint Program on the Science and Policy of Global Change. NR 79 TC 26 Z9 26 U1 1 U2 7 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X EI 2169-8996 J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD MAY 9 PY 2009 VL 114 AR D09305 DI 10.1029/2008JD009777 PG 19 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 443SI UT WOS:000265930500001 ER PT J AU Takahashi, K Berube, D Lee, DH Goldstein, J Singer, HJ Honary, F Moldwin, MB AF Takahashi, Kazue Berube, David Lee, Dong-Hun Goldstein, Jerry Singer, Howard J. Honary, Farideh Moldwin, Mark B. TI Possible evidence of virtual resonance in the dayside magnetosphere SO JOURNAL OF GEOPHYSICAL RESEARCH-SPACE PHYSICS LA English DT Article ID FIELD-LINE RESONANCES; INTERPLANETARY MAGNETIC-FIELD; PC3 GEOMAGNETIC-PULSATIONS; PI2 PULSATIONS; INNER MAGNETOSPHERE; GROUND STATIONS; MHD EIGENMODES; CAVITY MODES; ULF WAVES; BOW SHOCK AB On day 108, 2001, the Sub-Auroral Magnetometer Network (SAMNET) and Magnetometers along the Eastern Atlantic Seaboard for Undergraduate Research and Education ( MEASURE) magnetometer arrays detected dayside magnetic pulsations at a common frequency of similar to 15 mHz at all locations below L = 4. This global pulsation event was associated with alignment of the interplanetary magnetic field with the Sun-Earth axis, a condition known to generate ultralow-frequency (ULF) waves in front of the bow shock. The event occurred during the early recovery phase of a geomagnetic storm. Magnetic field measured by the GOES 8 geostationary satellite on the dayside indicated elevated broadband (7-80 mHz) ULF power in the compressional component without a strong peak at 15 mHz. These observations suggest that the global pulsations originated from a compressional magnetohydrodynamic eigenmode oscillation of the inner magnetosphere stimulated by a broadband external disturbance. The equatorial Alfven velocity corresponding to the toroidal frequencies that were determined with the cross-phase analysis of SAMNET and MEASURE data showed a gradual decrease of the velocity with L without a clear signature of a plasmapause. The observed properties of the global pulsations are consistent with virtual resonance in the inner magnetosphere. C1 [Takahashi, Kazue] Johns Hopkins Univ, Appl Phys Lab, Laurel, MD 20723 USA. [Berube, David] Loyola Marymount Univ, Dept Phys & Engn Phys, Los Angeles, CA 90045 USA. [Goldstein, Jerry] SW Res Inst, Dept Space Sci, San Antonio, TX 78238 USA. [Honary, Farideh] Univ Lancaster, Dept Commun Syst, InfoLab21, SW Res Inst, Lancaster LA1 4WA, England. [Lee, Dong-Hun] Kyung Hee Univ, Dept Astron & Space Sci, Yongin, South Korea. [Moldwin, Mark B.] Univ Calif Los Angeles, Inst Geophys & Planetary Phys, Los Angeles, CA 90095 USA. [Singer, Howard J.] NOAA, Natl Weather Serv, Natl Ctr Environm Predict, Space Weather Predict Ctr, Boulder, CO 80305 USA. RP Takahashi, K (reprint author), Johns Hopkins Univ, Appl Phys Lab, Johns Hopkins Rd,MS MP3-E128, Laurel, MD 20723 USA. EM kazue.takahashi@jhuapl.edu; dberube@lmu.edu; dhlee@khu.ac.kr; jgoldstein@swri.edu; howard.singer@noaa.gov; f.honary@lancaster.ac.uk; mmoldwin@ucla.edu RI Moldwin, Mark/F-8785-2011 OI Moldwin, Mark/0000-0003-0954-1770 FU NSF [ATM0632740, ATM-0750689]; Kyung Hee University; Korean Ministry of Education, Science and Technology [R31-10016] FX This work was supported NSF grants ATM0632740 and ATM-0750689. D. H. L. was supported in part by the research grant of Kyung Hee University (2008) and by the WCU grant (R31-10016) funded by the Korean Ministry of Education, Science and Technology. NR 55 TC 7 Z9 7 U1 1 U2 4 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0148-0227 J9 J GEOPHYS RES-SPACE JI J. Geophys. Res-Space Phys. PD MAY 8 PY 2009 VL 114 AR A05206 DI 10.1029/2008JA013898 PG 11 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA 443TB UT WOS:000265932500002 ER PT J AU Kiryukhin, V Lee, S Ratcliff, W Huang, Q Yi, HT Choi, YJ Cheong, SW AF Kiryukhin, V. Lee, Seongsu Ratcliff, W., II Huang, Q. Yi, H. T. Choi, Y. J. Cheong, S-W. TI Order by Static Disorder in the Ising Chain Magnet Ca3Co2-xMnxO6 SO PHYSICAL REVIEW LETTERS LA English DT Article AB Ising chain compound Ca3Co2-xMnxO6 exhibits up-up-down-down long-range magnetic order (LRO) in a broad range of 0.75 < x < 1. The LRO is abruptly lost in the narrow vicinity of x=1, and the magnetic state becomes incommensurate. The commensurate state (but not the LRO) is recovered for larger x. This is surprising because the stoichiometric x=1 state exhibits the best Co/Mn ionic order, and the magnetic LRO appears only in the samples with reduced ionic order. We argue that this "order-by-static-disorder" phenomenon may be related to the disruption of the long-range magnetic interactions by the magnetic-site disorder, reducing magnetic frustration. C1 [Kiryukhin, V.; Lee, Seongsu; Yi, H. T.; Choi, Y. J.; Cheong, S-W.] Rutgers State Univ, Dept Phys & Astron, Piscataway, NJ 08854 USA. [Kiryukhin, V.; Lee, Seongsu; Yi, H. T.; Choi, Y. J.; Cheong, S-W.] Rutgers State Univ, Rutgers Ctr Emergent Mat, Piscataway, NJ 08854 USA. [Lee, Seongsu] Korea Atom Energy Res Inst, Div Neutron Sci, Taejon 305353, South Korea. [Ratcliff, W., II; Huang, Q.] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. RP Kiryukhin, V (reprint author), Rutgers State Univ, Dept Phys & Astron, Piscataway, NJ 08854 USA. RI Yi, Hee Taek/F-6399-2010 FU DOE [DE-FG02-07ER46382] FX This work was supported by the DOE under Grant No. DE-FG02-07ER46382. NR 15 TC 33 Z9 34 U1 0 U2 14 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 0031-9007 J9 PHYS REV LETT JI Phys. Rev. Lett. PD MAY 8 PY 2009 VL 102 IS 18 AR 187202 DI 10.1103/PhysRevLett.102.187202 PG 4 WC Physics, Multidisciplinary SC Physics GA 443ZF UT WOS:000265948600062 PM 19518906 ER PT J AU Lee, M Kang, W Onose, Y Tokura, Y Ong, NP AF Lee, Minhyea Kang, W. Onose, Y. Tokura, Y. Ong, N. P. TI Unusual Hall Effect Anomaly in MnSi under Pressure SO PHYSICAL REVIEW LETTERS LA English DT Article ID ITINERANT FERROMAGNET MNSI; BERRY-PHASE; MAGNETORESISTANCE; CHIRALITY; CRYSTALS; DYNAMICS AB We report the observation of a highly unusual Hall current in the helical magnet MnSi in an applied pressure P=6-12 kbars. The Hall conductivity displays a distinctive stepwise field profile quite unlike any other Hall response observed in solids. We identify the origin of this Hall current with the effective real-space magnetic field due to chiral spin textures, which may be a precursor of the partial-order state at P > 14.6 kbar. We discuss evidence favoring the chiral spin mechanism for the origin of the observed Hall anomaly. C1 [Lee, Minhyea; Ong, N. P.] Princeton Univ, Dept Phys, Princeton, NJ 08544 USA. [Kang, W.] Univ Chicago, Dept Phys, Chicago, IL 60637 USA. [Onose, Y.; Tokura, Y.] Univ Tokyo, Dept Appl Phys, Tokyo 1138656, Japan. [Tokura, Y.] SSS, JST, ERATO, Tsukuba, Ibaraki 3058562, Japan. RP Lee, M (reprint author), Natl Inst Stand & Technol, Boulder, CO 80305 USA. RI Onose, Yoshinori/F-1977-2010; Tokura, Yoshinori/C-7352-2009 FU U. S. National Science Foundation [DMR 0213706] FX We thank B. Binz, A. Vishwanath, and M. Hermele for valuable discussions. The research at Princeton is supported by the U. S. National Science Foundation under MRSEC Grant No. DMR 0213706. NR 27 TC 128 Z9 129 U1 8 U2 56 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 0031-9007 EI 1079-7114 J9 PHYS REV LETT JI Phys. Rev. Lett. PD MAY 8 PY 2009 VL 102 IS 18 AR 186601 DI 10.1103/PhysRevLett.102.186601 PG 4 WC Physics, Multidisciplinary SC Physics GA 443ZF UT WOS:000265948600050 PM 19518894 ER PT J AU Evan, AT Vimont, DJ Heidinger, AK Kossin, JP Bennartz, R AF Evan, Amato T. Vimont, Daniel J. Heidinger, Andrew K. Kossin, James P. Bennartz, Ralf TI The Role of Aerosols in the Evolution of Tropical North Atlantic Ocean Temperature Anomalies SO SCIENCE LA English DT Article ID SEA-SURFACE TEMPERATURE; SAHARAN DUST; VARIABILITY; TRANSPORT; PRODUCT; IMPACT; SST AB Observations and models show that northern tropical Atlantic surface temperatures are sensitive to regional changes in stratospheric volcanic and tropospheric mineral aerosols. However, it is unknown whether the temporal variability of these aerosols is a key factor in the evolution of ocean temperature anomalies. We used a simple physical model, incorporating 26 years of satellite data, to estimate the temperature response of the ocean mixed layer to changes in aerosol loadings. Our results suggest that the mixed layer's response to regional variability in aerosols accounts for 69% of the recent upward trend, and 67% of the detrended and 5-year low pass-filtered variance, in northern tropical Atlantic Ocean temperatures. C1 [Evan, Amato T.] Univ Wisconsin, Cooperat Inst Meteorol Satellite Studies, Madison, WI 53706 USA. [Evan, Amato T.; Vimont, Daniel J.; Bennartz, Ralf] Univ Wisconsin, Dept Atmospher & Ocean Sci, Madison, WI 53706 USA. [Heidinger, Andrew K.] NOAA, NESDIS, Ctr Satellite Applicat & Res STAR, Madison, WI 53706 USA. [Kossin, James P.] NOAA, NESDIS, Natl Climat Data Ctr, Madison, WI 53706 USA. RP Evan, AT (reprint author), Univ Wisconsin, Cooperat Inst Meteorol Satellite Studies, Madison, WI 53706 USA. EM atevan@wisc.edu RI Kossin, James/D-3929-2011; Bennartz, Ralf/F-3760-2010; Heidinger, Andrew/F-5591-2010; Kossin, James/C-2022-2016 OI Heidinger, Andrew/0000-0001-7631-109X; Kossin, James/0000-0003-0461-9794 FU NOAA/NESDIS/STAR; Risk Prediction Initiative FX We thank three anonymous reviewers for their constructive comments. Supported by grants from NOAA/NESDIS/STAR and Risk Prediction Initiative. The views, opinions, and findings contained in this report are those of the authors and should not be construed as an official NOAA or U.S. government position, policy, or decision. NR 29 TC 80 Z9 81 U1 0 U2 21 PU AMER ASSOC ADVANCEMENT SCIENCE PI WASHINGTON PA 1200 NEW YORK AVE, NW, WASHINGTON, DC 20005 USA SN 0036-8075 EI 1095-9203 J9 SCIENCE JI Science PD MAY 8 PY 2009 VL 324 IS 5928 BP 778 EP 781 DI 10.1126/science.1167404 PG 4 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA 442HN UT WOS:000265832400044 PM 19325076 ER PT J AU Koeller, P Fuentes-Yaco, C Platt, T Sathyendranath, S Richards, A Ouellet, P Orr, D Skuladottir, U Wieland, K Savard, L Aschan, M AF Koeller, P. Fuentes-Yaco, C. Platt, T. Sathyendranath, S. Richards, A. Ouellet, P. Orr, D. Skuladottir, U. Wieland, K. Savard, L. Aschan, M. TI Basin-Scale Coherence in Phenology of Shrimps and Phytoplankton in the North Atlantic Ocean SO SCIENCE LA English DT Article ID PANDALUS-BOREALIS; RECRUITMENT; BLOOM; SEA AB Climate change could lead to mismatches between the reproductive cycles of marine organisms and their planktonic food. We tested this hypothesis by comparing shrimp (Pandalus borealis) egg hatching times and satellite-derived phytoplankton bloom dynamics throughout the North Atlantic. At large spatial and long temporal (10 years or longer) scales, hatching was correlated with the timing of the spring phytoplankton bloom. Annual egg development and hatching times were determined locally by bottom water temperature. We conclude that different populations of P. borealis have adapted to local temperatures and bloom timing, matching egg hatching to food availability under average conditions. This strategy is vulnerable to interannual oceanographic variability and long-term climatic changes. C1 [Koeller, P.; Fuentes-Yaco, C.; Platt, T.; Sathyendranath, S.] Bedford Inst Oceanog, Dept Fisheries & Oceans, Dartmouth, NS B2Y 4A2, Canada. [Fuentes-Yaco, C.; Sathyendranath, S.] Dalhousie Univ, Halifax, NS B3H 4R2, Canada. [Platt, T.; Sathyendranath, S.] Plymouth Marine Lab, Plymouth PL1 3, Devon, England. [Richards, A.] Natl Marine Fisheries Serv, NE Fisheries Sci Ctr, Woods Hole, MA 02543 USA. [Ouellet, P.; Savard, L.] Fisheries & Oceans Canada, Inst Maurice Lamontagne, Mont Joli, PQ G5H 3Z4, Canada. [Orr, D.] Fisheries & Oceans Canada, Dept Fisheries & Oceans, St John, NF A1C 5X1, Canada. [Skuladottir, U.] Marine Res Inst, IS-121 Reykjavik, Iceland. [Wieland, K.] Tech Univ Denmark, Natl Inst Aquat Resources, DK-9850 Hirtshals, Denmark. [Aschan, M.] Univ Tromso, Norwegian Coll Fisheries Sci, N-9037 Tromso, Norway. RP Koeller, P (reprint author), Bedford Inst Oceanog, Dept Fisheries & Oceans, POB 1006, Dartmouth, NS B2Y 4A2, Canada. EM koellerp@mar.dfo-mpo.gc.ca RI Brooks, Katya/J-4975-2014 FU Government Related Initiatives Program; Natural Sciences and Engineering Research Council of Canada; National Centre for Earth Observation; Natural Environment Research Council of the UK FX This analysis was made possible by the satellite data provided by NASA and the efforts of the technical personnel in six countries whose efforts at sea and in the laboratory provided the biological and physical oceanographic data. We also thank G. White III for extensive data preparation. This work was supported by the Canadian Space Agency through the Government Related Initiatives Program and by the Natural Sciences and Engineering Research Council of Canada through research grants to T.P. and S.S. This work is a contribution to the National Centre for Earth Observation and the Oceans 2025 programs of the Natural Environment Research Council of the UK. NR 20 TC 94 Z9 95 U1 2 U2 45 PU AMER ASSOC ADVANCEMENT SCIENCE PI WASHINGTON PA 1200 NEW YORK AVE, NW, WASHINGTON, DC 20005 USA SN 0036-8075 J9 SCIENCE JI Science PD MAY 8 PY 2009 VL 324 IS 5928 BP 791 EP 793 DI 10.1126/science.1170987 PG 3 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA 442HN UT WOS:000265832400048 PM 19423827 ER PT J AU Schneider, H Takahashi, K Skodje, RT Weber, JM AF Schneider, Holger Takahashi, Kaito Skodje, Rex T. Weber, J. Mathias TI Infrared spectra of SF6-center dot HCOOH center dot Ar-n (n=0-2): Infrared triggered reaction and Ar-induced reactive inhibition SO JOURNAL OF CHEMICAL PHYSICS LA English DT Article DE argon compounds; hydrogen bonds; infrared spectra; organic compounds; reaction kinetics theory; solvation; spectrochemical analysis; sulphur compounds; tunnelling ID VIBRATIONAL SPECTROSCOPY; ARGON PREDISSOCIATION; ATMOSPHERIC LIFETIMES; CORRELATION-ENERGY; PROTON-TRANSFER; BASIS-SETS; ELECTRON; SF6; CLUSTER; DENSITY AB We present the infrared spectra of SF6-center dot HCOOH center dot Ar-m (m=0-2) complexes. We find that the binding motif involves a single hydrogen bond between the SF6- anion and the OH group of the formic acid, with the CH group weakly tethered to a neighboring F atom. Similar to the case of hydrated SF6-, the SF bond involved in the (OH-F) bond is significantly stretched and weakened by the attachment of the HCOOH ligand. The bare complex undergoes reaction upon infrared absorption in the CH/OH stretching region of the formic acid moiety, leading predominantly to the formation of SF4 -+2HF+CO2. The reaction can be inhibited by attachment of two Ar atoms. We discuss a likely reaction mechanism in the framework of ab initio calculations, suggesting that reaction proceeds via tunneling through the potential barrier. C1 [Schneider, Holger; Takahashi, Kaito; Skodje, Rex T.; Weber, J. Mathias] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA. [Schneider, Holger; Weber, J. Mathias] Univ Colorado, JILA, NIST, Boulder, CO 80309 USA. RP Skodje, RT (reprint author), Univ Colorado, Dept Chem & Biochem, Campus Box 215, Boulder, CO 80309 USA. EM rex.skodje@colorado.edu; weberjm@jila.colorado.edu RI Takahashi, Kaito/F-7919-2012; Weber, J. Mathias/B-1618-2009 OI Weber, J. Mathias/0000-0002-5493-5886 FU JILA Atomic, Molecular, and Optical Physics Frontier Center of the National Science Foundation [PHY-0551010]; ACS FX Support for this work comes from the JILA Atomic, Molecular, and Optical Physics Frontier Center of the National Science Foundation (Grant No. PHY-0551010). R. T. S. and K. T. were partly supported by a grant from the Petroleum Research Fund administered by the ACS. NR 46 TC 6 Z9 6 U1 1 U2 1 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 0021-9606 J9 J CHEM PHYS JI J. Chem. Phys. PD MAY 7 PY 2009 VL 130 IS 17 AR 174302 DI 10.1063/1.3125960 PG 10 WC Chemistry, Physical; Physics, Atomic, Molecular & Chemical SC Chemistry; Physics GA 448LC UT WOS:000266263100011 PM 19425771 ER PT J AU Kocharov, L Pizzo, VJ Odstrcil, D Zwickl, RD AF Kocharov, L. Pizzo, V. J. Odstrcil, D. Zwickl, R. D. TI A unified model of solar energetic particle transport in structured solar wind SO JOURNAL OF GEOPHYSICAL RESEARCH-SPACE PHYSICS LA English DT Article ID INTERPLANETARY MAGNETIC LOOP; MONTE-CARLO SIMULATIONS; GAMMA-RAY EMISSION; COSMIC-RAYS; ADIABATIC DECELERATION; COMPRESSION REGIONS; EVENT; ACCELERATION; PROPAGATION; CONVECTION AB Solar energetic particle (SEP) fluxes, after their propagation from the particles' source to the Earth's orbit, depend on the state of solar wind, which is known to be highly variable in both time and space. Commonly used SEP transport models are based on the assumption of the standard interplanetary magnetic field, which would be the case for a uniform, steady state expansion of solar wind. Modeling of SEP transport in the standard solar wind can be facilitated by the use of a corotating reference frame, wherein the solar wind speed is parallel to interplanetary magnetic field at each point and the magnetic field is static. However, this approach is not possible in the realistic solar wind. This necessitates development of a more general SEP model applicable to particle transport in arbitrarily structured solar wind and in interplanetary coronal mass ejections, magnetic clouds, and shocks. In the framework of focused transport theory, we formulate a practical model of SEP transport in an evolving, structured solar wind. This unified model accommodates the results of three-dimensional MHD modeling of solar wind based on observations of the sun, solar wind, and SEPs in a particular event. A relation between the generalized focused transport model and the diffusion-convection equation of cosmic ray transport is discussed. C1 [Kocharov, L.; Pizzo, V. J.; Odstrcil, D.; Zwickl, R. D.] Natl Ocean & Atmospher Adm, Space Weather Predict Ctr, Boulder, CO USA. RP Kocharov, L (reprint author), Univ Turku, Dept Phys & Astron, Space Res Lab, Vesilinnantie 5, FIN-20014 Turku, Finland. EM kocharov@utu.fi; vic.pizzo@noaa.gov; dusan.odstrcil@noaa.gov; ron.d.zwickl@noaa.gov FU National Research Council Research Associateship Award FX This research was performed while the lead author held a National Research Council Research Associateship Award at the Space Weather Prediction Center of National Oceanic and Atmospheric Administration.; Amitava Bhattacharjee thanks the reviewers for their assistance in evaluating this paper. NR 34 TC 5 Z9 5 U1 0 U2 2 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-9380 EI 2169-9402 J9 J GEOPHYS RES-SPACE JI J. Geophys. Res-Space Phys. PD MAY 7 PY 2009 VL 114 AR A05102 DI 10.1029/2008JA013837 PG 11 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA 443TA UT WOS:000265932400002 ER PT J AU Velazquez, JM Jaye, C Fischer, DA Banerjee, S AF Velazquez, Jesus M. Jaye, Cherno Fischer, Daniel A. Banerjee, Sarbajit TI Near Edge X-ray Absorption Fine Structure Spectroscopy Studies of Single-Crystalline V2O5 Nanowire Arrays SO JOURNAL OF PHYSICAL CHEMISTRY C LA English DT Article ID TRANSITION-METAL OXIDES; INITIO DFT CLUSTER; VANADIUM PENTOXIDE; ELECTRONIC-STRUCTURE; V2O5(010) SURFACE; CARBON NANOTUBES; NEXAFS SPECTRA; LI INSERTION; K-EDGE; OXYGEN AB Near edge X-ray absorption fine structure (NEXAFS) spectroscopy is used to precisely probe the alignment, uniformity in crystal growth direction, and electronic structure of single-crystalline V2O5 nanowire arrays prepared by a cobalt-catalyzed vapor transport process. The dipole selection rules operational for core-level electron spectroscopy enable angle-dependent NEXAFS spectroscopy to be used as a sensitive probe of the anisotropy of these systems and provides detailed insight into bond orientation and the symmetry of the frontier orbital states. The experimental spectra are matched to previous theoretical predictions and allow experimental verification of features such as the origin of the split-off conduction band responsible for the semiconducting properties Of V2O5 and the strongly anisotropic nature of vanadyl-oxygen-derived.(V=O) states thought to be involved in catalysis. The strong anisotropy observed across thousands of nanowires in the NEXAFS measurements clearly demonstrates the uniformity of crystal growth direction in these nanowire arrays. C1 [Velazquez, Jesus M.; Banerjee, Sarbajit] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA. [Jaye, Cherno; Fischer, Daniel A.] Natl Inst Stand & Technol, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA. RP Banerjee, S (reprint author), SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA. EM sb244@buffalo.edu FU University at Buffalo; NSF FX S.B. acknowledges startup funding from the University at Buffalo for support of this work. J.M.V. acknowledges support from the NSF-funded LSAMP Bridge to the Doctorate program. Certain commercial names are presented in this manuscript for purposes Of illustration and do not constitute an endorsement by the National Institute of Standards and Technology. NR 46 TC 29 Z9 29 U1 3 U2 39 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1932-7447 J9 J PHYS CHEM C JI J. Phys. Chem. C PD MAY 7 PY 2009 VL 113 IS 18 BP 7639 EP 7645 DI 10.1021/jp900809y PG 7 WC Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary SC Chemistry; Science & Technology - Other Topics; Materials Science GA 440GA UT WOS:000265687600027 ER PT J AU Overland, JE AF Overland, James E. TI Meteorology of the Beaufort Sea SO JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS LA English DT Article ID ARCTIC-OCEAN; BUDGET; ICE; CIRCULATION; SHEBA AB The unique meteorology of the Beaufort Sea region is dominated by the presence of sea ice and a seasonal swing from a large heat loss in winter to a gain in summer. The primary determinant of this seasonal climate shift is the annual cycle of insolation from a maximum of 500 W/m(2) near the summer solstice to darkness in winter, as the Beaufort Sea lies north of Alaska and northwestern Canada beyond 72 degrees N. Even though the Sun angle is low in summer, the length of daylight provides as much energy to the surface as anywhere on the planet. As summer progresses, relative absorption of insolation at the surface increases as the albedo decreases due to snow and ice melt and increased open water area. This annual cycle results in a change from a winter continental-like air mass similar to the adjacent land areas to a summertime marine air mass characterized by low cloud and fogs. In winter the region is also influenced by the polar atmospheric vortex with strong westerly winds centered in the stratosphere, whose presence is felt at the surface. Recent sea ice losses are changing the climatology of the region, with extended periods of increased temperatures through the autumn months. C1 NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. RP Overland, JE (reprint author), NOAA, Pacific Marine Environm Lab, 7600 Sand Point Way Ne, Seattle, WA 98115 USA. EM james.e.overland@noaa.gov FU NOAA FX We appreciate the support from the NOAA Arctic Research in preparation of this paper. M. Wang helped with the preparation of Figures 1 - 11. The review was made possible by the many accomplishments of Arctic scientists in the last decade and beyond, as noted in the References and elsewhere. This paper is dedicated to the memory of Richard Reed, author of the 1960 paper on the summer Arctic. NR 22 TC 36 Z9 36 U1 2 U2 7 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0148-0227 J9 J GEOPHYS RES-OCEANS JI J. Geophys. Res.-Oceans PD MAY 6 PY 2009 VL 114 AR C00A07 DI 10.1029/2008JC004861 PG 10 WC Oceanography SC Oceanography GA 443ST UT WOS:000265931600001 ER PT J AU McComiskey, A Feingold, G Frisch, AS Turner, DD Miller, MA Chiu, JC Min, QL Ogren, JA AF McComiskey, Allison Feingold, Graham Frisch, A. Shelby Turner, David D. Miller, Mark A. Chiu, J. Christine Min, Qilong Ogren, John A. TI An assessment of aerosol-cloud interactions in marine stratus clouds based on surface remote sensing SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID SATELLITE-DERIVED CLOUD; LARGE-EDDY SIMULATIONS; BOUNDARY-LAYER; ALBEDO; CLIMATE; POLLUTION; MICROPHYSICS; PARAMETERS; TRANSPORT; FRACTION AB An assessment of aerosol-cloud interactions (ACI) from ground-based remote sensing under coastal stratiform clouds is presented. The assessment utilizes a long-term, high temporal resolution data set from the Atmospheric Radiation Measurement (ARM) Program deployment at Pt. Reyes, California, United States, in 2005 to provide statistically robust measures of ACI and to characterize the variability of the measures based on variability in environmental conditions and observational approaches. The average ACI(N) (= dlnN(d)/dln alpha, the change in cloud drop number concentration with aerosol concentration) is 0.48, within a physically plausible range of 0-1.0. Values vary between 0.18 and 0.69 with dependence on (1) the assumption of constant cloud liquid water path (LWP), (2) the relative value of cloud LWP, (3) methods for retrieving N-d, (4) aerosol size distribution, (5) updraft velocity, and (6) the scale and resolution of observations. The sensitivity of the local, diurnally averaged radiative forcing to this variability in ACI(N) values, assuming an aerosol perturbation of 500 cm(-3) relative to a background concentration of 100 cm(-3), ranges between -4 and -9 W m(-2). Further characterization of ACI and its variability is required to reduce uncertainties in global radiative forcing estimates. C1 [McComiskey, Allison] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. [McComiskey, Allison; Feingold, Graham; Frisch, A. Shelby] NOAA, Earth Syst Res Lab, Div Chem Sci, Boulder, CO 80305 USA. [Frisch, A. Shelby] Colorado State Univ, Cooperat Inst Res Atmosphere, Ft Collins, CO 80523 USA. [Turner, David D.] Univ Wisconsin, Ctr Space Sci & Engn, Madison, WI 53706 USA. [Miller, Mark A.] Rutgers State Univ, Dept Environm Sci, New Brunswick, NJ 08901 USA. [Chiu, J. Christine] Univ Maryland, Joint Ctr Earth Syst Technol, Baltimore, MD 21201 USA. [Chiu, J. Christine] NASA, Goddard Space Flight Ctr, Baltimore, MD USA. [Min, Qilong] SUNY Albany, Atmospher Sci Res Ctr, Albany, NY 12203 USA. [Ogren, John A.] NOAA, Earth Syst Res Lab, Global Monitoring Div, Boulder, CO 80305 USA. RP McComiskey, A (reprint author), Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. EM allison.mccomiskey@noaa.gov RI Feingold, Graham/B-6152-2009; Chiu, Christine/E-5649-2013; McComiskey, Allison/I-3933-2013; Ogren, John/M-8255-2015; Manager, CSD Publications/B-2789-2015 OI Chiu, Christine/0000-0002-8951-6913; McComiskey, Allison/0000-0002-6125-742X; Ogren, John/0000-0002-7895-9583; FU U.S. Department of Energy Office of Science [DE-AI02-06ER64215, DE-FG02-06ER64167, DE-FG0208ER64563, DE-FG02-03ER63531] FX This work was supported by the Atmospheric Radiation Measurement Program of the U.S. Department of Energy Office of Science under grants DE-AI02-06ER64215, DE-FG02-06ER64167, DE-FG0208ER64563, and DE-FG02-03ER63531. NR 55 TC 59 Z9 59 U1 1 U2 16 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD MAY 5 PY 2009 VL 114 AR D09203 DI 10.1029/2008JD011006 PG 15 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 443SB UT WOS:000265929800002 ER PT J AU Bacopoulos, P Funakoshi, Y Hagen, SC Cox, AT Cardone, VJ AF Bacopoulos, Peter Funakoshi, Yuji Hagen, Scott C. Cox, Andrew T. Cardone, Vincent J. TI The role of meteorological forcing on the St. Johns River (Northeastern Florida) SO JOURNAL OF HYDROLOGY LA English DT Article DE Storm surges; Astronomic tides; Two-dimensional models; Hydrodynamics; Coastal processes; Florida Coast ID UNSTRUCTURED MESH GENERATION; WIND; MODEL; HURRICANES; SIMULATION; EQUATION; DOMAIN; TIDE AB Water surface elevations in the St. Johns River (Northeastern Florida) are simulated over a 122-day time period spanning June 1-September 30, 2005, which relates to a particularly active hurricane season for the Atlantic basin, and includes Hurricane Ophelia that significantly impacted the St. Johns River. The hydrodynamic model employed for calculating two-dimensional flows is the ADCIRC (Advanced Circulation Model for Oceanic, Coastal, and Estuarine Waters) numerical code. The region of interest is modeled using three variations of an unstructured, finite element mesh: (1) a large-scale computational domain that hones in on the St. Johns River from the Western North Atlantic Ocean, Gulf of Mexico, and Caribbean Sea; (2) a shelf-based subset of the large domain; (3) an inlet-based subset of the large domain. Numerical experiments are then conducted in order to examine the relative importance of three long-wave forcing mechanisms for the St. Johns River: (1) astronomic tides; (2) freshwater river inflows; (3) winds and pressure variations. Two major findings result from the various modeling approaches considered in this study, and are applicable in general (e.g., over the entire 122-day time period) and even more so for extreme storm events (e.g., Hurricane Ophelia): (1) meteorological forcing for the St. Johns River is equal to or greater than that of astronomic tides and generally supersedes the impact of freshwater river inflows, while pressure variations provide minimal impact; (2) water Surface elevations in the St. Johns River are dependent upon the remote effects caused by winds occurring in the deep ocean, in addition to local wind effects. During periods of calm weather through the 122-day time period, water surface elevations in the St. Johns River were generally tidal in response, with amplitudes exceeding 1 m at the mouth and diminishing to less than 10 cm 150 km upriver. Considering an extreme storm event, the timing of Hurricane Ophelia occurred during the neap phase of the tidal cycle and at the mouth of the St. Johns River, the wind-driven storm Surge was near equal to the tidal component, each contributing about 0.5 m to the overall water surface elevation. However, 150 km upriver, meteorological forcing dominated, as over 90% of the total water Surface elevation was driven by winds and pressures. The simulation results replicate these behaviors well. As a supplement, it is shown that applying a hydrograph boundary condition, generated by a large domain, to a localized domain is highly beneficial towards accounting for the remote wind forcing. (C) 2009 Elsevier B.V. All rights reserved. C1 [Bacopoulos, Peter; Hagen, Scott C.] Univ Cent Florida, Orlando, FL 32816 USA. [Funakoshi, Yuji] NOAA, Natl Ocean Serv, Off Coast Survey, Silver Spring, MD 20910 USA. [Cox, Andrew T.; Cardone, Vincent J.] Oceanweather Inc, Cos Cob, CT 06807 USA. RP Bacopoulos, P (reprint author), Univ Cent Florida, 4000 Cent Florida Blvd,POB 162450, Orlando, FL 32816 USA. EM busy_child29@hotmail.com; yuji.funakoshi@noaa.gov; shagen@mail.ucf.edu; andrewc@oceanweather.com; vincec@oceanweather.com NR 29 TC 13 Z9 13 U1 0 U2 8 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-1694 J9 J HYDROL JI J. Hydrol. PD MAY 5 PY 2009 VL 369 IS 1-2 BP 55 EP 70 DI 10.1016/j.jhydrol.2009.02.027 PG 16 WC Engineering, Civil; Geosciences, Multidisciplinary; Water Resources SC Engineering; Geology; Water Resources GA 446OJ UT WOS:000266130600005 ER PT J AU Vanderah, DJ Vierling, RJ Walker, ML AF Vanderah, David J. Vierling, Ryan J. Walker, Marlon L. TI Oligo(ethylene oxide) Self-Assembled Monolayers, with Self-Limiting Packing Densities for the Inhibition of Nonspecific Protein Adsorption SO LANGMUIR LA English DT Article ID POLY(L-LYSINE)-G-POLY(ETHYLENE GLYCOL) LAYERS; POLY(ETHYLENE OXIDE); GRAFTED POLYMERS; 1-THIAHEXA(ETHYLENE OXIDE); NEUTRON REFLECTOMETRY; SURFACE INTERACTIONS; MOLECULAR-STRUCTURE; CHAIN DENSITY; RESISTANCE; GOLD AB We have created a molecule that forms self-assembled monolayers (SAMs) on Au, possessing the characteristics for inhibition of nonspecific protein adsorption, i.e., uniformly distributed, loosely packed, conformationally mobile, hydrated ethylene oxide (EO) chains of near optimal packing densities. SAMs of the bipodal molecule CH(3)O (CH(2)CH(2)O),CH(2)CON(CH(2)CH(2)CH(2)SCOCH(3))(2) [NN-(bis-3'-thioacetylpropyl)-3,6,9,12,15,18-hexaoxanonadecanamide (BTHA)] on polycrystalline Au are described. Spectroscopic ellipsometry (SE) and reflection-absorption infrared spectroscopy data indicate that BTHA SAM thickness and EO chain disorder closely match that of partially formed monothio-(EO)(5-6)CH(3) SAMs when they exhibit maximum inhibition of protein adsorption. However, in contrast to the monothio-(EO)(5-6)CH(3) SAMs, the BTHA SAM thickness and EO chain disorder remain constant in the presence of unbound molecules because of the structurally imposed upper limit of one EO chain per two Au occupancy sites. SE data indicate high resistance to protein adsorption for bovine serum albumin, fibrinogen, and a mixture of the two, suggesting uniform EO surface coverage on a length scale at least equal to the smallest dimension of these proteins. C1 [Vanderah, David J.; Vierling, Ryan J.] NIST, Div Biochem Sci, Gaithersburg, MD 20899 USA. [Walker, Marlon L.] NIST, Surface & Microanal Sci Div, Chem Sci & Technol Lab, Gaithersburg, MD 20899 USA. RP Vanderah, DJ (reprint author), NIST, Div Biochem Sci, Gaithersburg, MD 20899 USA. EM david.vanderah@nist.gov FU NIST FX R.J.V. was supported by the NIST summer undergraduate research fellow SURF) program (2006 and 2007). We thank Dr. Lee Richter for helpful discussions and use of instrumentation. NR 41 TC 14 Z9 14 U1 1 U2 17 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0743-7463 J9 LANGMUIR JI Langmuir PD MAY 5 PY 2009 VL 25 IS 9 BP 5026 EP 5030 DI 10.1021/la803896a PG 5 WC Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary SC Chemistry; Materials Science GA 438AP UT WOS:000265528600029 PM 19358588 ER PT J AU Kofu, M Qiu, Y Bao, W Lee, SH Chang, S Wu, T Wu, G Chen, XH AF Kofu, M. Qiu, Y. Bao, Wei Lee, S-H Chang, S. Wu, T. Wu, G. Chen, X. H. TI Neutron scattering investigation of the magnetic order in single crystalline BaFe2As2 SO NEW JOURNAL OF PHYSICS LA English DT Article ID LAYERED QUATERNARY COMPOUND; NODELESS SUPERCONDUCTING GAPS; ELECTRONIC-STRUCTURE; PHASE-DIAGRAM; EARTH; LIFEAS; METAL AB The magnetic structure of BaFe2As2 was determined from polycrystalline neutron diffraction measurements soon after the ThCr2Si2-type FeAs-based superconductors were discovered. Both the moment direction and the in-plane antiferromagnetic wavevector are along the longer a-axis of the orthorhombic unit cell. There is only one combined magnetostructural transition at similar to 140 K. However, a later single-crystal neutron diffraction work reported contradicting results. Here, we show neutron diffraction results from a single-crystal sample, grown by a self-flux method, that support the original polycrystalline work. C1 [Bao, Wei] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Kofu, M.; Lee, S-H] Univ Virginia, Dept Phys, Charlottesville, VA 22904 USA. [Qiu, Y.; Chang, S.] Natl Inst Stand & Technol, NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Qiu, Y.] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. [Wu, T.; Wu, G.; Chen, X. H.] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China. [Wu, T.; Wu, G.; Chen, X. H.] Univ Sci & Technol China, Dept Phys, Hefei 230026, Anhui, Peoples R China. RP Bao, W (reprint author), Los Alamos Natl Lab, POB 1663, Los Alamos, NM 87545 USA. EM wbao@lanl.gov RI Bao, Wei/E-9988-2011 OI Bao, Wei/0000-0002-2105-461X FU Natural Science Foundation of China; Ministry of Science and Technology of China [2006CB601001]; National Basic Research Program of China [2006CB922005]; US DOE [DE-FG02-07ER45384]; NSF [DMR-0454672] FX Work at LANL is supported by US DOE-OS-BES, at USTC by the Natural Science Foundation of China, Ministry of Science and Technology of China (973 Project No: 2006CB601001) and by the National Basic Research Program of China (2006CB922005), at UVA by the US DOE through DE-FG02-07ER45384. The SPINS at NIST is partially supported by NSF under Agreement No. DMR-0454672. NR 74 TC 35 Z9 37 U1 1 U2 14 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 1367-2630 J9 NEW J PHYS JI New J. Phys. PD MAY 5 PY 2009 VL 11 AR 055001 DI 10.1088/1367-2630/11/5/055001 PG 8 WC Physics, Multidisciplinary SC Physics GA 448AU UT WOS:000266234300001 ER PT J AU Chai, H Lee, JJW Constantino, PJ Lucas, PW Lawn, BR AF Chai, Herzl Lee, James J. -W. Constantino, Paul J. Lucas, Peter W. Lawn, Brian R. TI Remarkable resilience of teeth SO PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA LA English DT Article DE dental enamel; evolutionary biology; fracture; microstructure; tufts ID HUMAN ENAMEL; MECHANICAL-PROPERTIES; DENTAL ENAMEL; TOOTH ENAMEL; BITE FORCE; FRACTURE; EVOLUTION; FAILURE; DIET; DIFFERENTIATION AB Tooth enamel is inherently weak, with fracture toughness comparable with glass, yet it is remarkably resilient, surviving millions of functional contacts over a lifetime. We propose a microstructural mechanism of damage resistance, based on observations from ex situ loading of human and sea otter molars (teeth with strikingly similar structural features). Section views of the enamel implicate tufts, hypomineralized crack-like defects at the enamel-dentin junction, as primary fracture sources. We report a stabilization in the evolution of these defects, by "stress shielding'' from neighbors, by inhibition of ensuing crack extension from prism interweaving (decussation), and by self-healing. These factors, coupled with the capacity of the tooth configuration to limit the generation of tensile stresses in largely compressive biting, explain how teeth may absorb considerable damage over time without catastrophic failure, an outcome with strong implications concerning the adaptation of animal species to diet. C1 [Lee, James J. -W.; Lawn, Brian R.] Natl Inst Stand & Technol, Div Ceram, Gaithersburg, MD 20899 USA. [Chai, Herzl] Tel Aviv Univ, Sch Mech Engn, IL-69978 Tel Aviv, Israel. [Lee, James J. -W.; Constantino, Paul J.; Lucas, Peter W.] George Washington Univ, Dept Anthropol, Washington, DC 20052 USA. RP Lawn, BR (reprint author), Natl Inst Stand & Technol, Div Ceram, Gaithersburg, MD 20899 USA. EM brian.lawn@nist.gov FU Washington University Research Enhancement Fund FX We thank Sangwon Myoung for assistance with specimen preparation. This work was supported by the George Washington University Research Enhancement Fund (to P.J.C.). NR 44 TC 103 Z9 103 U1 7 U2 31 PU NATL ACAD SCIENCES PI WASHINGTON PA 2101 CONSTITUTION AVE NW, WASHINGTON, DC 20418 USA SN 0027-8424 J9 P NATL ACAD SCI USA JI Proc. Natl. Acad. Sci. U. S. A. PD MAY 5 PY 2009 VL 106 IS 18 BP 7289 EP 7293 DI 10.1073/pnas.0902466106 PG 5 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA 441QI UT WOS:000265783600006 PM 19365079 ER PT J AU Portmann, RW Solomon, S Hegerl, GC AF Portmann, Robert W. Solomon, Susan Hegerl, Gabriele C. TI Spatial and seasonal patterns in climate change, temperatures, and precipitation across the United States SO PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA LA English DT Article DE atmosphere; trends ID EXTREMES; 20TH-CENTURY AB Changes in climate during the 20th century differ from region to region across the United States. We provide strong evidence that spatial variations in US temperature trends are linked to the hydrologic cycle, and we also present unique information on the seasonal and latitudinal structure of the linkage. We show that there is a statistically significant inverse relationship between trends in daily temperature and average daily precipitation across regions. This linkage is most pronounced in the southern United States (30-40 degrees N) during the May-June time period and, to a lesser extent, in the northern United States (40-50 degrees N) during the July-August time period. It is strongest in trends in maximum temperatures (T-max) and 90th percentile exceedance trends (90PET), and less pronounced in the T-max 10PET and the corresponding T-min statistics, and it is robust to changes in analysis period. Although previous studies suggest that areas of increased precipitation may have reduced trends in temperature compared with drier regions, a change in sign from positive to negative trends suggests some additional cause. We show that trends in precipitation may account for some, but not likely all, of the cause point to evidence that shows that dynamical patterns (El Nino/Southern Oscillation, North Atlantic Oscillation, etc.) cannot account for the observed effects during May-June. We speculate that changing aerosols, perhaps related to vegetation changes, and increased strength of the aerosol direct and indirect effect may play a role in the observed linkages between these indices of temperature change and the hydrologic cycle. C1 [Portmann, Robert W.; Solomon, Susan] Natl Ocean & Atmospher Adm Earth Syst Res Lab, Div Chem Sci, Boulder, CO 80305 USA. [Hegerl, Gabriele C.] Univ Edinburgh, Sch Geosci, Edinburgh EH9 3JW, Midlothian, Scotland. RP Portmann, RW (reprint author), Natl Ocean & Atmospher Adm Earth Syst Res Lab, Div Chem Sci, Boulder, CO 80305 USA. EM robert.w.portmann@noaa.gov RI Portmann, Robert/C-4903-2009; Manager, CSD Publications/B-2789-2015 OI Portmann, Robert/0000-0002-0279-6087; NR 21 TC 109 Z9 109 U1 4 U2 47 PU NATL ACAD SCIENCES PI WASHINGTON PA 2101 CONSTITUTION AVE NW, WASHINGTON, DC 20418 USA SN 0027-8424 J9 P NATL ACAD SCI USA JI Proc. Natl. Acad. Sci. U. S. A. PD MAY 5 PY 2009 VL 106 IS 18 BP 7324 EP 7329 DI 10.1073/pnas.0808533106 PG 6 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA 441QI UT WOS:000265783600013 PM 19380730 ER PT J AU Zhang, Y Ma, L AF Zhang, Yu Ma, Li TI Optimization of ceramic strength using elastic gradients SO ACTA MATERIALIA LA English DT Article DE Functionally graded materials (FGM); Ceramic matrix composites (CMC); Modulus gradients; Flexure formulas; Stress dissipation ID CONTACT-DAMAGE RESISTANCE; FUNCTIONALLY GRADED BEAMS; CRACK; MODULUS; GLASS; DEFORMATION; INDENTATION; SURFACES; HARDNESS; ALUMINA AB We present a new concept for strengthening ceramics by utilizing a graded structure with a low elastic modulus at both top and bottom Surfaces sandwiching a high-modulus interior. Closed-form equations have been developed for stress analysis of simply supported graded sandwich beams subject to transverse center loads. Theory predicts that suitable modulus gradients at the ceramic surface call effectively reduce and spread the maximum bending stress front the surface into the interior. The magnitude of such stress dissipation is governed by the thickness ratio of the beam to the graded layers. We test Our concept by infiltrating both top and bottom surfaces of a strong class of zirconia ceramic with an in-house prepared glass of similar coefficient of thermal expansion and Poisson's ratio to zirconia, producing a controlled modulus gradient at the surface without significant long-range residual stresses. The resultant graded glass/zirconia/glass composite exhibits significantly higher load-bearing capacity than homogeneous zirconia. (C) 2009 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. C1 [Zhang, Yu] NYU, Coll Dent, Dept Biomat & Biomimet, New York, NY 10010 USA. [Ma, Li] NIST, Div Met, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA. RP Zhang, Y (reprint author), NYU, Coll Dent, Dept Biomat & Biomimet, 345 E 24th St,Room 813C, New York, NY 10010 USA. EM yz21@nyu.edu FU US Division of Civil, Mechanical & Manufacturing Innovation, National Science Foundation [CMMI-0758530]; US National Institute of Dental & Craniofacial Research, National Institutes of Health [1R01 DE017925] FX Valuable discussions with Drs. Brian R. Lawn and Lyle E. Levine are appreciated. This investigation was supported in part by Research Grant CMMI-0758530 (PI Zhang) from the US Division of Civil, Mechanical & Manufacturing Innovation, National Science Foundation and Research Grant 1R01 DE017925 (PI Zhang) from the US National Institute of Dental & Craniofacial Research, National Institutes of Health. NR 24 TC 29 Z9 30 U1 4 U2 12 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 1359-6454 J9 ACTA MATER JI Acta Mater. PD MAY PY 2009 VL 57 IS 9 BP 2721 EP 2729 DI 10.1016/j.actamat.2009.02.037 PG 9 WC Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering SC Materials Science; Metallurgy & Metallurgical Engineering GA 447GT UT WOS:000266180300014 PM 20161019 ER PT J AU Mertens, CJ Winick, JR Picard, RH Evans, DS Lopez-Puertas, M Wintersteiner, PP Xu, XJ Mlynczak, MG Russell, JM AF Mertens, Christopher J. Winick, Jeremy R. Picard, Richard H. Evans, David S. Lopez-Puertas, Manuel Wintersteiner, Peter P. Xu, Xiaojing Mlynczak, Martin G. Russell, James M., III TI Influence of solar-geomagnetic disturbances on SABER measurements of 4.3 mu m emission and the retrieval of kinetic temperature and carbon dioxide SO ADVANCES IN SPACE RESEARCH LA English DT Article DE SABER; Temperature; Carbon Dioxide (CO2); Infrared remote sensing; Non-LTE; Radiation Transfer; Ionosphere E-Region; Magnetic Storms; E-Region Ion-Neutral Chemistry ID RADIATIVE-TRANSFER MODEL; ROTATIONALLY EXCITED NO+; ION-MOLECULE REACTION; MIDDLE ATMOSPHERE; AURORAL ELECTRONS; UPPER MESOSPHERE; INFRARED BANDS; LIMB EMISSION; GROUND-STATE; CO2 AB Thermospheric infrared radiance at 4.3 mu m is susceptible to the influence of solar-geomagnetic disturbances. Ionization processes followed by ion-neutral chemical reactions lead to vibrationally excited NO+ (i.e., NO+(v)) and subsequent 4.3 mu m emission in the ionospheric E-region. Large enhancements of nighttime 4.3 mu m emission were observed by the TIMED/SABER instrument during the April 2002 and October-November 2003 solar storms. Global measurements of infrared 4.3 mu m emission provide an excellent proxy to observe the nighttime E-region response to auroral dosing and to conduct a detailed study of E-region ion-neutral chemistry and energy transfer mechanisms. Furthermore, we find that photoionization processes followed by ion-neutral reactions during quiescent. daytime conditions increase the NW concentration enough to introduce biases in the TIMED/SABER operational processing of kinetic temperature and CO2 data, with the largest effect at summer solstice. In this paper. we discuss solar storm enhancements of 4.3 mu m emission observed from SABER and assess the impact of NO+ (v) 4.3 mu m emission on quiescent. daytime retrievals of Tk/CO2 from the SABER instrument. Published by Elsevier Ltd. on behalf of COSPAR C1 [Mertens, Christopher J.] NASA, Langley Res Ctr, Hampton, VA 23681 USA. [Winick, Jeremy R.; Picard, Richard H.] USAF, Res Lab, Hanscom AFB, MA 01731 USA. [Evans, David S.] NOAA, Space Weather Predict Ctr, Boulder, CO 80303 USA. [Lopez-Puertas, Manuel] CSIC, Inst Astrofis Andalucia, E-18080 Granada, Spain. [Wintersteiner, Peter P.] ARCON Corp, Waltham, MA 02451 USA. [Xu, Xiaojing] SSAI Inc, Hampton, VA 23666 USA. [Mlynczak, Martin G.] NASA, Langley Res Ctr, Hampton, VA 23681 USA. [Russell, James M., III] Hampton Univ, Hampton, VA 23668 USA. RP Mertens, CJ (reprint author), NASA, Langley Res Ctr, 21 Langley Blvd,MS 401B, Hampton, VA 23681 USA. EM Christopher.J.Mertens@nasa.gov; jeremy.winick@hanscom.af.mil; richard.picard@hanscom.af.mil; David.S.Evans@noaa.gov; puertas@iaa.es; winters@arcon.com; xiaojing_xu@ssaihq.com; Martin.G.Mlynczak@nasa.gov; james.russell@hamptonu.edu RI Mlynczak, Martin/K-3396-2012; Lopez Puertas, Manuel/M-8219-2013 OI Lopez Puertas, Manuel/0000-0003-2941-7734 NR 51 TC 9 Z9 9 U1 0 U2 1 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0273-1177 EI 1879-1948 J9 ADV SPACE RES JI Adv. Space Res. PD MAY 1 PY 2009 VL 43 IS 9 BP 1325 EP 1336 DI 10.1016/j.asr.2008.10.029 PG 12 WC Astronomy & Astrophysics; Geosciences, Multidisciplinary; Meteorology & Atmospheric Sciences SC Astronomy & Astrophysics; Geology; Meteorology & Atmospheric Sciences GA 442DV UT WOS:000265821100003 ER PT J AU Rimmer, CA Sander, LC AF Rimmer, Catherine A. Sander, Lane C. TI Shape selectivity in embedded polar group stationary phases for liquid chromatography SO ANALYTICAL AND BIOANALYTICAL CHEMISTRY LA English DT Article DE Liquid chromatography; Shape selectivity; Embedded polar group ID PRINCIPAL COMPONENT ANALYSIS; AQUEOUS MOBILE PHASES; CONSTRAINED SOLUTES; RETENTION BEHAVIOR; BASIC COMPOUNDS; BONDED PHASES; HPLC; COLUMNS; CLASSIFICATION; PERFORMANCE AB Seven columns with embedded polar functionality were evaluated for use in liquid chromatography with a focus on molecular shape recognition. Tests based on Standard Reference Material 869b Column Selectivity Test Mixture for Liquid Chromatography and the Tanaka test indicate that only two of the phases are slightly shape selective at 20 degrees C. The shape recognition characteristics of the phases appear to be directly related to the density of the embedded polar ligands and the temperature of the separation, consistent with trends observed with conventional hydrocarbon phases. C1 [Rimmer, Catherine A.; Sander, Lane C.] Natl Inst Stand & Technol, Div Analyt Chem, Gaithersburg, MD 20899 USA. RP Rimmer, CA (reprint author), Natl Inst Stand & Technol, Div Analyt Chem, Gaithersburg, MD 20899 USA. EM catherine.rimmer@nist.gov NR 36 TC 17 Z9 17 U1 1 U2 10 PU SPRINGER HEIDELBERG PI HEIDELBERG PA TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY SN 1618-2642 J9 ANAL BIOANAL CHEM JI Anal. Bioanal. Chem. PD MAY PY 2009 VL 394 IS 1 BP 285 EP 291 DI 10.1007/s00216-009-2649-4 PG 7 WC Biochemical Research Methods; Chemistry, Analytical SC Biochemistry & Molecular Biology; Chemistry GA 431BG UT WOS:000265035700029 PM 19221720 ER PT J AU Brennan, RG Rabb, SA Holden, MJ Winchester, MR Turk, GC AF Brennan, Ryan G. Rabb, Savelas A. Holden, Marcia J. Winchester, Michael R. Turk, Gregory C. TI Potential Primary Measurement Tool for the Quantification of DNA SO ANALYTICAL CHEMISTRY LA English DT Article ID PLASMA-MASS SPECTROMETRY; HIGH-EFFICIENCY NEBULIZER; ELEMENTAL ANALYSIS; QUANTITATIVE DETECTION; NUCLEIC-ACIDS; ICP-OES; PHOSPHORUS; ASSAY; SPECTROSCOPY; PERFORMANCE AB An automated sample introduction system, utilizing a demountable direct injection high-efficiency nebulizer (d-DIHEN), is successfully incorporated for the first time with an inductively coupled plasma optical emission spectrometer (ICP-OES) for the measurement of the phosphorus content in acid-digested nucleotides and deoxyribonucleic acid (DNA). With this experimental setup, the solution uptake rate and volume are reduced from 170 to 30 mu L min(-1) and from 10, to 2.4 mL, respectively, thereby reducing the required DNA sample mass for solutions containing 3 mu g g(-1) P from 300 to 72 mu g of DNA, in comparison to previous analyses in our laboratory using a glass concentric nebulizer with cyclonic spray chamber arrangement The use of direct injection also improves P (1) 213.617 nm sensitivity by a factor of 4 on average. A high-performance (HP) methodology in combination with the previous sample introduction system and ICP-OES provides simultaneous, time-correlated internal standardization and drift correction resulting in relative expanded uncertainties (% U) for the P mass fractions in the range of 0.1-0.4 (95% confidence level) for most of the thymidine 5'-monophosphate (TMP), calf thymus DNA (CTDNA), and plasmid DNA (PLDNA) analyses. The d-DIHEN with HP-ICP-OES methodology allows for the quantification of DNA mass at P mass fractions as low as 0.5 mu g g(-1), further reducing the required DNA mass to 12 mu g, with small uncertainty (<= 0.4%). This successful approach will aid in the development and certification of nucleic acid certified reference materials (CRMs), particularly for these samples that are typically limited in volume. C1 [Brennan, Ryan G.; Rabb, Savelas A.; Winchester, Michael R.; Turk, Gregory C.] Natl Inst Stand & Technol, Div Analyt Chem, Gaithersburg, MD 20899 USA. [Holden, Marcia J.] Natl Inst Stand & Technol, Div Biochem Sci, Gaithersburg, MD 20899 USA. [Brennan, Ryan G.] George Washington Univ, Dept Chem, Washington, DC 20052 USA. RP Rabb, SA (reprint author), Natl Inst Stand & Technol, Div Analyt Chem, Gaithersburg, MD 20899 USA. EM savelas.rabb@nist.gov NR 35 TC 13 Z9 14 U1 1 U2 15 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0003-2700 J9 ANAL CHEM JI Anal. Chem. PD MAY 1 PY 2009 VL 81 IS 9 BP 3414 EP 3420 DI 10.1021/ac802688x PG 7 WC Chemistry, Analytical SC Chemistry GA 439MY UT WOS:000265632400031 PM 19344148 ER PT J AU Ritter, S Brennecke, F Baumann, K Donner, T Guerlin, C Esslinger, T AF Ritter, S. Brennecke, F. Baumann, K. Donner, T. Guerlin, C. Esslinger, T. TI Dynamical coupling between a Bose-Einstein condensate and a cavity optical lattice SO APPLIED PHYSICS B-LASERS AND OPTICS LA English DT Article; Proceedings Paper CT Spring Meeting of the Quantum Optics and Photonics Section of the German-Physical-Society CY MAR, 2008 CL Darmstadt, GERMANY SP German Phys Soc ID RADIATION-PRESSURE; SINGLE ATOMS; PHOTONS; OPTOMECHANICS; MICROMIRROR; BISTABILITY; RESONATOR; MIRROR AB A Bose-Einstein condensate is dispersively coupled to a single mode of an ultra-high finesse optical cavity. The system is governed by strong interactions between the atomic motion and the light field even at the level of single quanta. While coherently pumping the cavity mode the condensate is subject to the cavity optical lattice potential whose depth depends nonlinearly on the atomic density distribution. We observe optical bistability already below the single photon level and strong back-action dynamics which tunes the coupled system periodically out of resonance. C1 [Ritter, S.; Brennecke, F.; Baumann, K.; Donner, T.; Guerlin, C.; Esslinger, T.] ETH, Inst Quantum Elect, CH-8093 Zurich, Switzerland. [Ritter, S.] Max Planck Inst Quantum Opt, D-85748 Garching, Germany. [Donner, T.] Univ Colorado, JILA, Boulder, CO 80309 USA. [Donner, T.] Natl Inst Stand & Technol, Boulder, CO 80309 USA. RP Esslinger, T (reprint author), ETH, Inst Quantum Elect, CH-8093 Zurich, Switzerland. EM esslinger@phys.ethz.ch RI Donner, Tobias/A-2845-2011; Ritter, Stephan/F-1579-2010; Baumann, Kristian/M-9653-2013; Esslinger, Tilman/M-9022-2016 OI Donner, Tobias/0000-0001-7016-587X; Ritter, Stephan/0000-0001-9002-7407; Esslinger, Tilman/0000-0002-8333-107X NR 42 TC 64 Z9 65 U1 3 U2 11 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0946-2171 EI 1432-0649 J9 APPL PHYS B-LASERS O JI Appl. Phys. B-Lasers Opt. PD MAY PY 2009 VL 95 IS 2 BP 213 EP 218 DI 10.1007/s00340-009-3436-9 PG 6 WC Optics; Physics, Applied SC Optics; Physics GA 429TT UT WOS:000264943700005 ER PT J AU Inn, KGW LaRosa, J Nour, S Brooks, G Lamont, S Steiner, R Williams, R Patton, B Bostick, D Eiden, G Petersen, S Douglas, M Beals, D Cadieux, J Hall, G Goldberg, S Vogt, S AF Inn, Kenneth G. W. LaRosa, Jerome Nour, Svetlana Brooks, George Lamont, Steve Steiner, Rob Williams, Ross Patton, Brad Bostick, Debbie Eiden, Gregory Petersen, Steve Douglas, Matthew Beals, Donna Cadieux, James Hall, Greg Goldberg, Steve Vogt, Stephan TI Ultra-low level plutonium isotopes in the NIST SRM 4355A (Peruvian Soil-1) SO APPLIED RADIATION AND ISOTOPES LA English DT Article; Proceedings Paper CT 5th International Conference on Radionuclide Metrology-Low-Level Radioactivity Measurement Techniques CY SEP 22-26, 2008 CL Braunschweig, GERMANY DE Analytical blank; Inductively-couple-plasma mass spectrometry; Plutonium; Radiochemistry; Reference material; Sediment; Thermal-ionization mass spectrometry ID ATOM RATIOS; NP-237; PU; FALLOUT; SAMPLES AB For more than 20 years, countries and their agencies which monitor radionuclide discharge sites and storage facilities have relied on the National Institute of Standards and Technology (NIST) Standard Reference Material (SRM) 4355 Peruvian Soil. Its low fallout contamination makes it an ideal soil blank for measurements associated with terrestrial-pathway-to-man studies. Presently, SRM 4355 is out of stock, and a new batch of the Peruvian soil is currently under development as future NIST SRM 4355A. Both environmental radioanalytical laboratories and mass spectrometry communities will benefit from the use of this SRM. The former must assess their laboratory procedural contamination and measurement detection limits by measurement of blank sample material. The Peruvian Soil is so low in anthropogenic radionuclide content that it is a suitable virtual blank. On the other hand, mass spectrometric laboratories have high sensitivity instruments that are capable of quantitative isotopic measurements at low plutonium levels in the SRM 4355 (first Peruvian Soil SRM) that provided the mass spectrometric community with the calibration, quality control, and testing material needed for methods development and legal defensibility. The quantification of the ultra-low plutonium content in the SRM 4355A was a considerable challenge for the mass spectrometric laboratories. Careful blank control and correction, isobaric interferences, instrument stability, peak assessment, and detection assessment were necessary. Furthermore, a systematic statistical evaluation of the measurement results and considerable discussions with the mass spectroscopy metrologists were needed to derive the certified values and uncertainties. The one sided upper limit of the 95% tolerance with 95% confidence for the massic (239)Pu content in SRM 4355A is estimated to be 54,000 atoms/g. Published by Elsevier Ltd. C1 [Inn, Kenneth G. W.; LaRosa, Jerome; Nour, Svetlana] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. [Brooks, George; Lamont, Steve; Steiner, Rob] Los Alamos Natl Lab, Los Alamos, NM USA. [Williams, Ross] Lawrence Livermore Natl Lab, Livermore, CA USA. [Patton, Brad; Bostick, Debbie] Oak Ridge Natl Lab, Oak Ridge, TN USA. [Eiden, Gregory; Petersen, Steve; Douglas, Matthew] Pacific NW Natl Lab, Richland, WA 99352 USA. [Beals, Donna; Cadieux, James; Hall, Greg] Savannah River Natl Lab, Aiken, SC USA. [Goldberg, Steve; Vogt, Stephan] New Brunswick Lab, Argonne, IL USA. RP Inn, KGW (reprint author), Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. EM kenneth.inn@nist.gov OI Douglas, Matthew/0000-0001-9708-1780 NR 8 TC 3 Z9 3 U1 1 U2 4 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0969-8043 J9 APPL RADIAT ISOTOPES JI Appl. Radiat. Isot. PD MAY PY 2009 VL 67 IS 5 BP 667 EP 671 DI 10.1016/j.apradiso.2009.01.007 PG 5 WC Chemistry, Inorganic & Nuclear; Nuclear Science & Technology; Radiology, Nuclear Medicine & Medical Imaging SC Chemistry; Nuclear Science & Technology; Radiology, Nuclear Medicine & Medical Imaging GA 446OD UT WOS:000266130000002 PM 19264497 ER PT J AU Michaels, CA Masiello, T Chu, PM AF Michaels, Chris A. Masiello, Tony Chu, Pamela M. TI Fourier Transform Spectrometry with a Near-Infrared Supercontinuum Source SO APPLIED SPECTROSCOPY LA English DT Article DE Near-infrared spectroscopy; NIR spectroscopy; Supercontinuum radiation; Fourier transform infrared spectroscopy; FT-IR spectroscopy ID ZBLAN FLUORIDE FIBERS; ABSORPTION-SPECTROSCOPY; GENERATION; NM; BANDWIDTH; CELLS; BANDS AB Optical fiber based supercontinuum light sources combine the brightness of lasers with the broad bandwidth of incandescent lamps and thus are promising candidates for sources in spectroscopic applications requiring high brightness and broad bandwidth. Herein, near-infrared (IR) Fourier transform (FT) spectrometry with a supercontinuum (SC) light source is investigated. The efficient, collimated propagation of broad bandwidth SC light through an 18 m path length multipass cell is demonstrated. A normalized spectral difference is calculated for the SC spectrum on consecutive FT mirror scans and is found to vary by less than 0.5%, indicating excellent spectral stability. The rms noise on zero absorbance lines is obtained as a function of the number of mirror scans at 0.125, 2, and 16 cm(-1) resolution for both the SC and conventional tungsten lamp source. The SC source has approximately a factor of ten times more noise than the lamp under comparable conditions for each resolution and data acquisition time. This clearly indicates that spectral acquisition with the SC source is not detector noise limited. NIR-FT spectra of methane and methyl salicylate, acquired with both the SC and lamp source, are reported. These spectra illustrate the advantage the SC source has over the incandescent source in that it can efficiently traverse long path lengths, thus providing a sensitivity advantage. The spectra also demonstrate the disadvantage of the SC source with respect to the lamp in the increased level of amplitude noise. Prospects for the future use of SC sources in absorption spectroscopy, including possible noise mitigation strategies, are briefly discussed. C1 [Michaels, Chris A.; Masiello, Tony; Chu, Pamela M.] Natl Inst Stand & Technol, Chem Sci & Technol Lab, Gaithersburg, MD 20899 USA. RP Michaels, CA (reprint author), Natl Inst Stand & Technol, Chem Sci & Technol Lab, Gaithersburg, MD 20899 USA. EM chris.Michaels@nist.gov FU U.S. Department of Homeland Security Science and Technology Directorate FX The authors would like to thank Steve Brown for making the SC source available for these measurements. Additionally, the authors would like to thank the NIST Gas Metrology Group for the CH4 in N2 cylinder sample and the U.S. Department of Homeland Security Science and Technology Directorate for partial support of this work. NR 27 TC 7 Z9 8 U1 0 U2 10 PU SOC APPLIED SPECTROSCOPY PI FREDERICK PA 201B BROADWAY ST, FREDERICK, MD 21701 USA SN 0003-7028 J9 APPL SPECTROSC JI Appl. Spectrosc. PD MAY PY 2009 VL 63 IS 5 BP 538 EP 543 PG 6 WC Instruments & Instrumentation; Spectroscopy SC Instruments & Instrumentation; Spectroscopy GA 445LN UT WOS:000266052400008 PM 19470210 ER PT J AU Sokol, Z Kitzmiller, D Pesice, P Guan, S AF Sokol, Z. Kitzmiller, D. Pesice, P. Guan, S. TI Operational 0-3 h probabilistic quantitative precipitation forecasts: Recent performance and potential enhancements SO ATMOSPHERIC RESEARCH LA English DT Article; Proceedings Paper CT 7th International Workshop on Precipitation in Urban Areas CY DEC 07-10, 2006 CL St Moritz, SWITZERLAND DE Precipitation; Prediction; Convection; Radar; Nowcasting ID RADAR RAINFALL; ECONOMIC VALUE; PART I; WSR-88D; MODEL; IDENTIFICATION; PREDICTION; ALGORITHM; TRACKING; QPF AB The NOAA National Weather Service has maintained an automated. centralized 0-3 h prediction system for probabilistic quantitative precipitation forecasts since 2001. This advective-statistical system (ADSTAT) produces probabilities that rainfall will exceed multiple threshold values up to 50 mm at some location within a 40-km grid box. Operational characteristics and development methods for the system are described. Although development data were stratified by season and time of day, ADSTAT utilizes only a single set of nation-wide equations that relate predictor variables derived from radar reflectivity, lightning, satellite infrared temperatures, and numerical prediction model output to rainfall occurrence. A verification study documented herein showed that the operational ADSTAT reliably models regional variations in the relative frequency of heavy rain events. This was true even in the western United States, where no regional-scale, gridded hourly precipitation data were available during the development period in the 1990s. An effort was recently launched to improve the quality of ADSTAT forecasts by regionalizing the prediction equations and to adapt the model for application in the Czech Republic. We have experimented with incorporating various levels of regional specificity in the probability equations. The geographic localization study showed that in the warm season, regional climate differences and variations in the diurnal temperature cycle have a marked effect on the predictor-predictand relationships, and thus regionalization would lead to better statistical reliability in the forecasts. (C) 2009 Elsevier B.V. All rights reserved. C1 [Sokol, Z.; Pesice, P.] Inst Atmospher Phys AS CR, Prague, Czech Republic. [Kitzmiller, D.; Guan, S.] NOAA, Natl Weather Serv, Off Hydrol Dev, Silver Spring, MD 20910 USA. RP Sokol, Z (reprint author), Inst Atmospher Phys AS CR, Prague, Czech Republic. EM sokol@ufa.cas.cz; david.kitzmiller@noaa.gov RI Sokol, Zbynek/K-4382-2012; Pesice, Petr/F-5118-2014 OI Sokol, Zbynek/0000-0001-9408-9138; NR 43 TC 5 Z9 6 U1 0 U2 8 PU ELSEVIER SCIENCE INC PI NEW YORK PA 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA SN 0169-8095 J9 ATMOS RES JI Atmos. Res. PD MAY PY 2009 VL 92 IS 3 BP 318 EP 330 DI 10.1016/j.atmosres.2009.01.011 PG 13 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 437CU UT WOS:000265464600005 ER PT J AU Kramida, AE Shirai, T AF Kramida, A. E. Shirai, T. TI Energy levels and spectral lines of tungsten, W III through W LXXIV SO ATOMIC DATA AND NUCLEAR DATA TABLES LA English DT Review ID X-RAY-SPECTRA; I ISOELECTRONIC SEQUENCE; LASER-PRODUCED PLASMAS; HELIUM-LIKE IONS; DOUBLY IONIZED TUNGSTEN; NICKEL-LIKE IONS; ZN-LIKE IONS; IONIZATION ENERGIES; RESONANCE LINES; GROUND-STATE AB The energy levels and spectral lines of multiply ionized tungsten atoms, W(2+) through W(73+), have been compiled. Experimental data on spectral lines and energy levels exist for the spectra of W III through W VII, W XXVIII through W LI, W LIII, and W LV through LXV. For W VIII, the four lowest energy levels were derived from the series limits of W VII. For W LXIV (Na-like) and W LVI (K-like), We Supplement experimental data on energy levels and wavelengths with predicted values found by accurate interpolations and extrapolations along the isoelectronic sequences. For W LXXIII (He-like) and W LXXIV (H-like), theoretical data on energy levels and line wavelengths are compiled, For W III, we include experimentally determined radiative transition probabilities where available. The ground state configurations and terms were determined for all stages of ionization. A value of ionization energy is included for each ion. (C) 2008 Elsevier Inc. All rights reserved. C1 [Kramida, A. E.] Natl Inst Stand & Technol, Atom Phys Div, Gaithersburg, MD 20899 USA. [Shirai, T.] Japan Atom Energy Agcy, Naka Fus Res Estab, Naka, Ibaraki 3110193, Japan. RP Kramida, AE (reprint author), Natl Inst Stand & Technol, Atom Phys Div, 100 Bur Dr,Stop 8422, Gaithersburg, MD 20899 USA. EM Alexander.Kramida@nist.gov OI Kramida, Alexander/0000-0002-0788-8087 FU National Institute of Standards and Technology; Office of Fusion Energy Sciences of the U.S. Department of Energy FX One of the present authors (T. Shirai) participated in this work at an early stage of the project, until he died in 2002. The assistance of H. Kubo of the Japan Atomic Energy Agency with transferring the data preliminarily assembled by Dr. T. Shirai to the National Institute of Standards and Technology is gratefully acknowledged. The authors thank J. Reader, W.C. Martin, and Yu. Ralchenko for many helpful discussions. We are grateful to C. Biedermarm and T. Putterich for providing their data prior to publication. We also thank C. Biedermann for careful reading of the manuscript and valuable comments. This work was Supported in part by the Office of Fusion Energy Sciences of the U.S. Department of Energy. NR 88 TC 116 Z9 117 U1 3 U2 22 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0092-640X J9 ATOM DATA NUCL DATA JI Atom. Data Nucl. Data Tables PD MAY PY 2009 VL 95 IS 3 BP 305 EP 474 DI 10.1016/j.adt.2008.12.002 PG 170 WC Physics, Atomic, Molecular & Chemical; Physics, Nuclear SC Physics GA 442RH UT WOS:000265857800001 ER PT J AU Franaszek, M Cheok, GS Witzgall, C AF Franaszek, Marek Cheok, Geraldine S. Witzgall, Christoph TI Fast automatic registration of range images from 3D imaging systems using sphere targets SO AUTOMATION IN CONSTRUCTION LA English DT Article DE 3D imaging system; Automated object recognition; Sphere fitting; Target-based registration ID LEAST-SQUARES; CIRCLE; SEGMENTATION; PRIMITIVES AB The use of 3D imaging systems (e.g., laser scanners) in construction has grown significantly in the past decade. Range images acquired with such systems often require registration. This paper describes an automatic method to rapidly locate spheres and perform a registration based on three pairs of matching points (centers of fitted spheres) in two range images. The proposed method is directly applicable for regularly gridded datasets obtained with instruments that are typically used for construction applications and whose maximum ranges are greater than 50 m. A lab was scanned from two locations at three different scan densities. Four spheres were located in the lab, and the total number of points hitting the four spheres was a small fraction (<0.01%) of all the points in the dataset. At the highest scan density, the registration of two datasets with 6.4 x 10(6) and 3.4 x 10(6) points is obtained in less than 30 s. At the medium scan density, two range images with 1.6 x 10(6) and 0.8 x 10(6) points can be registered in less than 2 s. Published by Elsevier BY. C1 [Franaszek, Marek; Cheok, Geraldine S.] NIST, Construct Metrol & Automat Grp, Gaithersburg, MD 20899 USA. [Witzgall, Christoph] NIST, Math & Computat Sci Div, Gaithersburg, MD 20899 USA. RP Franaszek, M (reprint author), NIST, Construct Metrol & Automat Grp, Gaithersburg, MD 20899 USA. EM marek@nist.gov NR 32 TC 22 Z9 25 U1 1 U2 7 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0926-5805 J9 AUTOMAT CONSTR JI Autom. Constr. PD MAY PY 2009 VL 18 IS 3 BP 265 EP 274 DI 10.1016/j.autcon.2008.08.003 PG 10 WC Construction & Building Technology; Engineering, Civil SC Construction & Building Technology; Engineering GA 419HV UT WOS:000264211200004 ER PT J AU Kristiansen, T Jorgensen, C Lough, RG Vikebo, F Fiksen, O AF Kristiansen, T. Jorgensen, C. Lough, R. G. Vikebo, F. Fiksen, O. TI Modeling rule-based behavior: habitat selection and the growth-survival trade-off in larval cod SO BEHAVIORAL ECOLOGY LA English DT Article DE behavioral heuristics; diel vertical migration; individual-based model; larval cod; trade-off ID INDIVIDUAL-BASED MODELS; GADUS-MORHUA L; GEORGES-BANK; MARINE FISHES; LIFE-HISTORY; CLUPEA-HARENGUS; PREY SELECTION; MATCH-MISMATCH; CLIMATE-CHANGE; PELAGIC FISH AB Environmental variation can cause significant fluctuations in the survival of larval fish and plankton. Understanding these fluctuations is critical for developing more accurate fisheries models, which are needed for both scientific and socioeconomic research. Growth, survival, and dispersal of marine planktonic larvae rely strongly on their behavior. Larval fish change their vertical positioning due to strong vertical gradients in light, temperature, predation pressure, and prey availability. Here, we explore how various behavioral rules predict vertical distribution, growth, and survival of larval cod (Gadus morhua) in a numerical model. The rules determine the trade-offs between larval growth, feeding rate, and predation rate, including their dependence on gut fullness and body mass. We evaluated the survival through size classes for different rules and random behavior and compared model predictions with observed larval distribution patterns. The rules predicted the correct average depth position with larval size, but failed to predict the timing of the observed vertical distribution pattern. However, model simulations revealed significant increases in survival for larval and juvenile cod with active behavior compared with larvae with random behavior. Behavior was important across all sizes of fish, and this study illustrates the value or added information of incorporating behavior in biophysical models. C1 [Kristiansen, T.; Vikebo, F.] Inst Marine Res, N-5817 Bergen, Norway. [Jorgensen, C.; Fiksen, O.] Univ Bergen, Dept Biol, N-5020 Bergen, Norway. [Lough, R. G.] Natl Ocean & Atmospher Adm, Natl Marine Fisheries Serv, NE Fisheries Sci Ctr, Woods Hole, MA 02543 USA. RP Kristiansen, T (reprint author), Rutgers State Univ, Inst Marine & Coastal Sci, New Brunswick, NJ 08903 USA. EM trond.kristiansen@imr.no RI Fiksen, Oyvind/F-1771-2011; Jorgensen, Christian/B-4453-2009; OI Fiksen, Oyvind/0000-0002-9687-5842; Jorgensen, Christian/0000-0001-7087-4625; Kristiansen, Trond/0000-0001-6121-297X FU Norwegian Research Council [155930/700]; ECOBE (NORWAY-GLOBEC); US-GLOBEC FX Norwegian Research Council ( P. no. 155930/700) as part of the ECOBE (NORWAY-GLOBEC) program and US-GLOBEC Phase 4B program. NR 73 TC 31 Z9 31 U1 0 U2 16 PU OXFORD UNIV PRESS INC PI CARY PA JOURNALS DEPT, 2001 EVANS RD, CARY, NC 27513 USA SN 1045-2249 J9 BEHAV ECOL JI Behav. Ecol. PD MAY-JUN PY 2009 VL 20 IS 3 BP 490 EP 500 DI 10.1093/beheco/arp023 PG 11 WC Behavioral Sciences; Biology; Ecology; Zoology SC Behavioral Sciences; Life Sciences & Biomedicine - Other Topics; Environmental Sciences & Ecology; Zoology GA 443ZV UT WOS:000265950200005 ER PT J AU Plant, AL Bhadriraju, K Spurlin, TA Elliott, JT AF Plant, Anne L. Bhadriraju, Kiran Spurlin, Tighe A. Elliott, John T. TI Cell response to matrix mechanics: Focus on collagen SO BIOCHIMICA ET BIOPHYSICA ACTA-MOLECULAR CELL RESEARCH LA English DT Review DE Extracellular matrix; Collagen; Type 1 collagen; Collagen gel; Collagen thin film; Collagen fibril; Vascular smooth muscle cell; Integrin; Mechanical cue; Myosin light chain; Cell spreading; Actin cytoskeleton; Proliferation ID AUTOMATED FLUORESCENCE MICROSCOPY; LIGHT-CHAIN PHOSPHORYLATION; ATOMIC-FORCE MICROSCOPY; KINASE RHO-KINASE; EXTRACELLULAR-MATRIX; TENASCIN-C; I COLLAGEN; FIBRILLAR COLLAGEN; THIN-FILMS; ENDOTHELIAL-CELLS AB Many model systems and measurement tools have been engineered for observing and quantifying the effect of mechanics on cellular response. These have contributed greatly to our current knowledge of the molecular events by which mechanical cues affect cell biology. Cell responses to the mechanical properties of type 1 collagen gels are discussed, followed by a description of a model system of very thin, mechanically tunable collagen films that evoke similar responses from cells as do gel systems, but have additional advantages. Cell responses to thin films of collagen suggest that at least some of the mechanical cues that cells can respond to in their environment occur at the sub-micron scale. Mechanical properties of thin films of collagen can be tuned without altering integrin engagement, and in some cases without altering topology, making them useful in addressing questions regarding the roles of specific integrins in transducing or mitigating responses to mechanical cues. The temporal response of cells to differences in ECM may provide insight into mechanisms of signal transduction. (C) 2008 Published by Elsevier B.V. C1 [Plant, Anne L.; Spurlin, Tighe A.; Elliott, John T.] NIST, Div Biochem Sci, Gaithersburg, MD 20899 USA. [Bhadriraju, Kiran] SAIC, Arlington, VA 22203 USA. RP Plant, AL (reprint author), NIST, Div Biochem Sci, Gaithersburg, MD 20899 USA. EM Anne.plant@nist.gov NR 128 TC 49 Z9 53 U1 1 U2 27 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0167-4889 J9 BBA-MOL CELL RES JI Biochim. Biophys. Acta-Mol. Cell Res. PD MAY PY 2009 VL 1793 IS 5 BP 893 EP 902 DI 10.1016/j.bbamcr.2008.10.012 PG 10 WC Biochemistry & Molecular Biology; Cell Biology SC Biochemistry & Molecular Biology; Cell Biology GA 453YZ UT WOS:000266650100016 PM 19027042 ER PT J AU Lautenbacher, CC AF Lautenbacher, Conrad C., Jr. TI Ocean and Atmosphere-The Future SO BIOSCIENCE LA English DT Editorial Material C1 [Lautenbacher, Conrad C., Jr.] USN, Stennis Space Ctr, MS USA. [Lautenbacher, Conrad C., Jr.] NOAA, Washington, DC USA. EM clautenbache@csc.com NR 0 TC 2 Z9 2 U1 0 U2 2 PU AMER INST BIOLOGICAL SCI PI WASHINGTON PA 1444 EYE ST, NW, STE 200, WASHINGTON, DC 20005 USA SN 0006-3568 J9 BIOSCIENCE JI Bioscience PD MAY PY 2009 VL 59 IS 5 BP 366 EP 367 DI 10.1525/bio.2009.59.5.2 PG 2 WC Biology SC Life Sciences & Biomedicine - Other Topics GA 439HP UT WOS:000265618500002 ER PT J AU Hoolihan, JP Luo, JG Richardson, DE Snodgrass, D Orbesen, ES Prince, ED AF Hoolihan, John P. Luo, Jiangang Richardson, David E. Snodgrass, Derke Orbesen, Eric S. Prince, Eric D. TI VERTICAL MOVEMENT RATE ESTIMATES FOR ATLANTIC ISTIOPHORID BILLFISHES DERIVED FROM HIGH-RESOLUTION POP-UP SATELLITE ARCHIVAL DATA SO BULLETIN OF MARINE SCIENCE LA English DT Article ID BLUE MARLIN; SPORTFISHING GEAR; MAKAIRA-INDICA; BLACK MARLIN; ARABIAN GULF; HABITAT USE; PLATYPTERUS; TELEMETRY; BEHAVIOR C1 [Hoolihan, John P.; Snodgrass, Derke; Orbesen, Eric S.; Prince, Eric D.] NOAA, SE Fisheries Ctr, Miami, FL 33149 USA. [Luo, Jiangang] Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, Miami, FL 33149 USA. [Richardson, David E.] NOAA Fisheries, NE Fisheries Ctr, Narragansett, RI 02882 USA. RP Hoolihan, JP (reprint author), NOAA, SE Fisheries Ctr, Miami, FL 33149 USA. EM john.hoolihan@noaa.gov RI Orbesen, Eric/D-2220-2012 FU Billfish Foundation FX We acknowledge the captains, anglers, and other constituents of the Adopt-A-Billfish program for making the PSAT deployments possible. The Billfish Foundation was instrumental in PSAT project funding and support. The views expressed herein are those of the authors and do not necessarily reflect the views of NOAA or any of its sub-agencies. NR 14 TC 4 Z9 4 U1 1 U2 9 PU ROSENSTIEL SCH MAR ATMOS SCI PI MIAMI PA 4600 RICKENBACKER CAUSEWAY, MIAMI, FL 33149 USA SN 0007-4977 J9 B MAR SCI JI Bull. Mar. Sci. PD MAY PY 2009 VL 84 IS 3 BP 257 EP 264 PG 8 WC Marine & Freshwater Biology; Oceanography SC Marine & Freshwater Biology; Oceanography GA 454PE UT WOS:000266693800001 ER PT J AU Kendall, MS Bauer, LJ Jeffrey, CFG AF Kendall, Matthew S. Bauer, Laurie J. Jeffrey, Chris F. G. TI INFLUENCE OF HARD BOTTOM MORPHOLOGY ON FISH ASSEMBLAGES OF THE CONTINENTAL SHELF OFF GEORGIA, SOUTHEASTERN USA SO BULLETIN OF MARINE SCIENCE LA English DT Article ID SOUTH-ATLANTIC BIGHT; NORTH-CAROLINA; CORAL-REEF; UNITED-STATES; MYCTEROPERCA-MICROLEPIS; HABITAT CHARACTERISTICS; BENTHIC FEATURES; COMMUNITIES; PHENAX; REPRODUCTION AB Various reef types worldwide have inconsistent relationships among fish assemblage parameters and benthic characteristics, thus there is a need to identify factors driving assemblage structure specific to each reef type and locale. Limestone ledges are known to be key habitats for bottom fish on the continental shelf of the southeastern USA, however, the specific factors that link them to fish assemblages have not been quantified. Bottom fishes and habitat characteristics on ledges were surveyed at a study site located centrally in the southeastern USA continental shelf. Species richness, diversity, abundance, and biomass of fish were higher at ledges than on flat bottom. Species richness, abundance, and biomass of fish were well explained by ledge variables including percent cover of sessile invertebrates, total height, and height of undercut recesses. Multivariate analyses based on biomass of individual species at ledges revealed two fish assemblages associated with four ledge types. One assemblage was associated with ledges that were tall, heavily colonized with sessile invertebrates, large in area, and did or did not have undercuts. The other assemblage was associated with ledges that were short, not undercut, smaller in area, and were or were not heavily colonized by invertebrates. Seafloor classification schemes presently used in the region do not adequately capture hard bottom diversity to identify the location and extent of essential fish habitats for ecological and fisheries purposes. Given that ledges cover only similar to 1% to 5% of the southeastern USA continental shelf, they merit the highest levels of consideration in regional research, conservation, and management plans. C1 [Kendall, Matthew S.; Bauer, Laurie J.; Jeffrey, Chris F. G.] NOAA, NOS NCCOS CCMA, Biogeog Branch, Natl Ocean & Atmospher Adm, Silver Spring, MD 20910 USA. RP Kendall, MS (reprint author), NOAA, NOS NCCOS CCMA, Biogeog Branch, Natl Ocean & Atmospher Adm, 130 E W Highway, Silver Spring, MD 20910 USA. EM matt.kendall@noaa.gov FU GRNMS; NMSP/NCCOS Long Term Agreement FX C. Caldow, R. Clark, K. Gleason, J. Waddell, and K. Woody assisted the authors in the collection of field data. Boat captains K. Golden, J. Fripp, and T. Recicar as well as the officers and crew of the NOAA ship NANCY FOSTER for safe transport to field sites. S. Davidson-Hile organized and QAQCed the dataset. Thanks to the GRNMS staff, particularly G. McFall for logistical support throughout the study and G. Sedberry for providing helpful suggestions to improve the manuscript. Funding was provided by GRNMS and the NMSP/NCCOS Long Term Agreement. NR 42 TC 5 Z9 5 U1 0 U2 9 PU ROSENSTIEL SCH MAR ATMOS SCI PI MIAMI PA 4600 RICKENBACKER CAUSEWAY, MIAMI, FL 33149 USA SN 0007-4977 J9 B MAR SCI JI Bull. Mar. Sci. PD MAY PY 2009 VL 84 IS 3 BP 265 EP 286 PG 22 WC Marine & Freshwater Biology; Oceanography SC Marine & Freshwater Biology; Oceanography GA 454PE UT WOS:000266693800002 ER PT J AU Allman, RJ Goetz, LA AF Allman, R. J. Goetz, L. A. TI REGIONAL VARIATION IN THE POPULATION STRUCTURE OF GRAY SNAPPER, LUTJANUS GRISEUS, ALONG THE WEST FLORIDA SHELF SO BULLETIN OF MARINE SCIENCE LA English DT Article ID SOUTHEASTERN UNITED-STATES; GULF-OF-MEXICO; AGE-DETERMINATION; LIFE-HISTORY; FISH STOCKS; RED SNAPPER; EAST-COAST; GROWTH; REEF; MORTALITY AB We examined variation in life history traits of gray snapper [Lutjanus griseus (Linnaeus, 1758)] from three regions along the west Florida shelf with varying levels of fishing pressure. A total of 1132 gray snapper 254-724 mm TL were sampled from recreational and commercial fisheries. Overall the ratio of females to males was not significantly different from 1:1. Mean size decreased from north to middle to south (commercial 489-441 mm TL; recreational 501-345 mm TL). Gray snapper ages ranged from 2 to 26 yrs. Mean age decreased from north to middle to south (8.4 to 6.1 to 4.6 yrs) for the recreational fishery, while mean age in the commercial fishery was greatest in the middle region (9.4 yrs) and similar in the north (7.9 yrs) and south (7.6 yrs). Mean size-at-age for the most common ages (5-12 yrs) decreased from north to south. Von Bertalanffy growth curves differed between sexes with a greater L-infinity for males. Instantaneous mortality increased from north to south with the largest difference in the recreational fishery (Z = 0.14-0.55). Instantaneous natural mortality (M) estimates varied greatly by the method used (0.17-0.36): Hoenig's estimate of M using a maximum age of 26 yrs was 0.17; the Ralston estimate was 0.36 and the Pauly estimate was 0.24. Observed regional differences in size and age distributions as well as in growth and mortality rates are likely due to differences in exploitation rate. C1 [Allman, R. J.; Goetz, L. A.] SE Fisheries Sci Ctr, Natl Marine Fisheries Serv, Panama City, FL 32408 USA. RP Allman, RJ (reprint author), SE Fisheries Sci Ctr, Natl Marine Fisheries Serv, 3500 Delwood Beach Rd, Panama City, FL 32408 USA. EM robert.allman@noaa.gov FU Marine Fisheries Initiative (MARFIN) Program FX We wish to thank the many port agents who sampled gray snapper from the WFS. N. Evou, B. Farsky, and S. Garner processed otoliths in the laboratory and C. Gardner provided assistance with figures. D. DeVries, P. Sheridan, and two anonymous reviewers provided helpful comments. Funding for this project was partially provided by the Marine Fisheries Initiative (MARFIN) Program. NR 48 TC 6 Z9 7 U1 2 U2 7 PU ROSENSTIEL SCH MAR ATMOS SCI PI MIAMI PA 4600 RICKENBACKER CAUSEWAY, MIAMI, FL 33149 USA SN 0007-4977 EI 1553-6955 J9 B MAR SCI JI Bull. Mar. Sci. PD MAY PY 2009 VL 84 IS 3 BP 315 EP 330 PG 16 WC Marine & Freshwater Biology; Oceanography SC Marine & Freshwater Biology; Oceanography GA 454PE UT WOS:000266693800006 ER PT J AU Hillger, DW Schmit, TJ AF Hillger, Donald W. Schmit, Timothy J. TI The GOES-13 Science Test A Synopsis SO BULLETIN OF THE AMERICAN METEOROLOGICAL SOCIETY LA English DT Editorial Material C1 [Hillger, Donald W.] Colorado State Univ, NOAA, NESDIS, STAR,RAMMB, Ft Collins, CO 80523 USA. [Schmit, Timothy J.] NOAA, NESDIS, STAR, ASPB, Madison, WI USA. RP Hillger, DW (reprint author), Colorado State Univ, NOAA, NESDIS, STAR,RAMMB, CIRA 1375, Ft Collins, CO 80523 USA. EM hillger@cira.colostate.edu RI Schmit, Timothy/F-5624-2010; Hillger, Donald/F-5592-2010 OI Hillger, Donald/0000-0001-7297-2640 NR 4 TC 2 Z9 2 U1 0 U2 0 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0003-0007 J9 B AM METEOROL SOC JI Bull. Amer. Meteorol. Soc. PD MAY PY 2009 VL 90 IS 5 BP 592 EP 597 DI 10.1175/2008BAMS2564.1 PG 6 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 462LR UT WOS:000267354800001 ER PT J AU Quetelard, H Bessemoulin, P Cerveny, RS Peterson, TC Burton, A Boodhoo, Y AF Quetelard, Hubert Bessemoulin, Pierre Cerveny, Randall S. Peterson, Thomas C. Burton, Andrew Boodhoo, Yadowsun TI WORLD-RECORD RAINFALLS DURING TROPICAL CYCLONE GAMEDE SO BULLETIN OF THE AMERICAN METEOROLOGICAL SOCIETY LA English DT Editorial Material AB The World Meteorological Organization (WMO) Commission for Climatology (CCl) evaluation process is applied to two extreme rainfall records occurring at Cratere Commerson on La Reunion Island during the passage of the major Tropical Cyclone (TC) Gamede for inclusion into the WMO CCl World Weather and Climate Extremes Archive. In February 2007, TC Gamede made two approaches to La Reunion Island as it traversed a rather complex path in the Indian Ocean. Gamede's main feature was massive rainfall accumulation inland, with several 3- and 4-day rainfall totals exceeding 2 m. Specifically, an extreme rainfall rate of 3,929 mm over 72 h was recorded at Cratere Commerson, well above the previous world record of 3,240 mm that had been measured at Grand-Ilet during TC Hyacinthe in 1980. In addition, the Cratere Commerson rain gauge registered a rainfall total of 4,869 mm over 4 days; also well above the previous world record. The evaluation committee found that consistent regional rainfall measurements, reliable calibrated equipment, and correct recording procedures were followed throughout the event. Problems with potential wind-induced measurement errors were discussed, but the committee consensus is that such errors tend to underestimate rather than overestimate rainfall accumulations. As shown by analysis of this event, the validation process for the WMO CCl Weather and Climate Extremes Archive provides essential documentation and certification for weather extremes across the world. C1 [Cerveny, Randall S.] Arizona State Univ, Tempe, AZ 85287 USA. [Bessemoulin, Pierre] Meteo France, Paris, France. [Peterson, Thomas C.] NOAA, Natl Climat Data Ctr, Asheville, NC USA. [Burton, Andrew] Bur Meteorol, Melbourne, Vic, Australia. RP Cerveny, RS (reprint author), Arizona State Univ, POB 870104, Tempe, AZ 85287 USA. EM cerveny@asu.edu NR 6 TC 14 Z9 14 U1 1 U2 6 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0003-0007 EI 1520-0477 J9 B AM METEOROL SOC JI Bull. Amer. Meteorol. Soc. PD MAY PY 2009 VL 90 IS 5 BP 603 EP 607 DI 10.1175/2008BAMS2660.1 PG 5 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 462LR UT WOS:000267354800002 ER PT J AU Legg, S Briegleb, B Chang, Y Chassignet, EP Danabasoglu, G Ezer, T Gordon, AL Griffies, S Hallberg, R Jackson, L Large, W Ozgokmen, TM Peters, H Price, J Riemenschneider, U Wu, WL Xu, XB Yang, JY AF Legg, Sonya Briegleb, Bruce Chang, Yeon Chassignet, Eric P. Danabasoglu, Gokhan Ezer, Tal Gordon, Arnold L. Griffies, Stephen Hallberg, Robert Jackson, Laura Large, William Oezgoekmen, Tamay M. Peters, Hartmut Price, Jim Riemenschneider, Ulrike Wu, Wanli Xu, Xiaobiao Yang, Jiayan TI IMPROVING OCEANIC OVERFLOW REPRESENTATION IN CLIMATE MODELS The Gravity Current Entrainment Climate Process Team SO BULLETIN OF THE AMERICAN METEOROLOGICAL SOCIETY LA English DT Article ID SPECTRAL ELEMENT MODEL; BANK CHANNEL OVERFLOW; NORTH-ATLANTIC OCEAN; DENSITY CURRENTS; SEA OUTFLOW; THERMOHALINE CIRCULATION; MEDITERRANEAN OVERFLOW; TURBULENT ENTRAINMENT; DENMARK STRAIT; Z-COORDINATE AB Oceanic overflows are bottom-trapped density currents originating in semienclosed basins, such as the Nordic seas, or on continental shelves, such as the Antarctic shelf. Overflows are the source of most of the abyssal waters, and therefore play an important role in the large-scale ocean circulation, forming a component of the sinking branch of the thermohaline circulation. As they descend the continental slope, overflows mix vigorously with the surrounding oceanic waters, changing their density and transport significantly. These mixing processes occur on spatial scales well below the resolution of ocean climate models, with the result that deep waters and deep western boundary currents are simulated poorly. The Gravity Current Entrainment Climate Process Team was established by the U. S. Climate Variability and Prediction (CLIVAR) Program to accelerate the development and implementation of improved representations of overflows within large-scale climate models, bringing together climate model developers with those conducting observational, numerical, and laboratory process studies of overflows. Here, the organization of the Climate Process Team is described, and a few of the successes and lessons learned during this collaboration are highlighted, with some emphasis on the well-observed Mediterranean overflow. The Climate Process Team has developed several different overflow parameterizations, which are examined in a hierarchy of ocean models, from comparatively well-resolved regional models to the largest-scale global climate models. C1 [Legg, Sonya] Princeton Univ, NOAA, GFDL, Princeton, NJ 08540 USA. [Briegleb, Bruce; Danabasoglu, Gokhan; Large, William; Wu, Wanli] Natl Ctr Atmospher Res, Boulder, CO 80307 USA. [Chang, Yeon; Oezgoekmen, Tamay M.; Peters, Hartmut; Xu, Xiaobiao] Univ Miami, Miami, FL USA. [Chassignet, Eric P.] Florida State Univ, Tallahassee, FL 32306 USA. [Gordon, Arnold L.] Columbia Univ, Lamont Doherty Earth Observ, New York, NY USA. [Price, Jim; Riemenschneider, Ulrike; Yang, Jiayan] Woods Hole Oceanog Inst, Woods Hole, MA 02543 USA. [Ezer, Tal] Old Dominion Univ, Norfolk, VA USA. RP Legg, S (reprint author), Princeton Univ, NOAA, GFDL, Forrestal Campus,201 Forrestal Dr, Princeton, NJ 08540 USA. EM sonya.legg@noaa.gov RI Legg, Sonya/E-5995-2010; Gordon, Arnold/H-1049-2011; Jackson, Laura/J-6159-2013; OI Gordon, Arnold/0000-0001-6480-6095; Ezer, Tal/0000-0002-2018-6071 FU NSF [OCE-0336850, OCE-0611572]; NOAA FX The Gravity Current Entrainment Climate Process Team was funded by NSF grants OCE-0336850 and OCE-0611572 and NOAA as a contribution to U. S.CLIVAR. NR 59 TC 70 Z9 71 U1 2 U2 13 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0003-0007 EI 1520-0477 J9 B AM METEOROL SOC JI Bull. Amer. Meteorol. Soc. PD MAY PY 2009 VL 90 IS 5 BP 657 EP 670 DI 10.1175/2008BAMS2667.1 PG 14 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 462LR UT WOS:000267354800007 ER PT J AU Groisman, PY Clark, EA Kattsov, VM Lettenmaier, DP Sokolik, IN Aizen, VB Cartus, O Chen, JQ Conard, S Katzenberger, J Krankina, O Kukkonen, J Machida, T Maksyutov, S Ojima, D Qi, JG Romanovsky, VE Santoro, M Schmullius, CC Shiklomanov, AI Shimoyama, K Shugart, HH Shuman, JK Sofiev, MA Sukhinin, AI Vorosmarty, C Walker, D Wood, EF AF Groisman, Pavel Ya. Clark, Elizabeth A. Kattsov, Vladimir M. Lettenmaier, Dennis P. Sokolik, Irina N. Aizen, Vladimir B. Cartus, Oliver Chen, Jiquan Conard, Susan Katzenberger, John Krankina, Olga Kukkonen, Jaakko Machida, Toshinobu Maksyutov, Shamil Ojima, Dennis Qi, Jiaguo Romanovsky, Vladimir E. Santoro, Maurizio Schmullius, Christiane C. Shiklomanov, Alexander I. Shimoyama, Kou Shugart, Herman H. Shuman, Jacquelyn K. Sofiev, Mikhail A. Sukhinin, Anatoly I. Voeroesmarty, Charles Walker, Donald Wood, Eric F. TI THE NORTHERN EURASIA EARTH SCIENCE PARTNERSHIP An Example of Science Applied to Societal Needs SO BULLETIN OF THE AMERICAN METEOROLOGICAL SOCIETY LA English DT Article ID SURFACE; LAND; PRECIPITATION; DYNAMICS; SIBERIA; REGION; PRODUCTS; FORESTS; METHANE; EUROPE AB Northern Eurasia, the largest land-mass in the northern extratropics, accounts for similar to 20% of the global land area. However, little is known about how the biogeochemical cycles, energy and water cycles, and human activities specific to this carbon-rich, cold region interact with global climate. A major concern is that changes in the distribution of land-based life, as well as its interactions with the environment, may lead to a self-reinforcing cycle of accelerated regional and global warming. With this as its motivation, the Northern Eurasian Earth Science Partnership Initiative (NEESPI) was formed in 2004 to better understand and quantify feedbacks between northern Eurasian and global climates. The first group of NEESPI projects has mostly focused on assembling regional databases, organizing improved environmental monitoring of the region, and studying individual environmental processes. That was a starting point to addressing emerging challenges in the region related to rapidly and simultaneously changing climate, environmental, and societal systems. More recently, the NEESPI research focus has been moving toward integrative studies, including the development of modeling capabilities to project the future state of climate, environment, and societies in the NEESPI domain. This effort will require a high level of integration of observation programs, process studies, and modeling across disciplines. C1 [Groisman, Pavel Ya.] NOAA, UCAR, Natl Climat Data Ctr, Asheville, NC 28801 USA. [Clark, Elizabeth A.; Lettenmaier, Dennis P.] Univ Washington, Seattle, WA 98195 USA. [Kattsov, Vladimir M.] Voeikov Main Geophys Observ, St Petersburg, Russia. [Sokolik, Irina N.] Georgia Inst Technol, Atlanta, GA 30332 USA. [Aizen, Vladimir B.] Univ Idaho, Moscow, ID 83843 USA. [Cartus, Oliver; Schmullius, Christiane C.] Univ Jena, Jena, Germany. [Chen, Jiquan] Univ Toledo, Toledo, OH 43606 USA. [Conard, Susan] US Forest Serv, USDA, Arlington, VA USA. [Katzenberger, John] Aspen Global Change Inst, Aspen, CO USA. [Krankina, Olga] Oregon State Univ, Corvallis, OR 97331 USA. [Kukkonen, Jaakko; Sofiev, Mikhail A.] Finnish Meteorol Inst, FIN-00101 Helsinki, Finland. [Machida, Toshinobu; Maksyutov, Shamil] Natl Inst Environm Sci, Tsukuba, Ibaraki, Japan. [Ojima, Dennis] H John Heinz III Ctr Sci Econ & Environm, Washington, DC USA. [Qi, Jiaguo] Michigan State Univ, E Lansing, MI 48824 USA. [Romanovsky, Vladimir E.; Walker, Donald] Univ Alaska, Fairbanks, AK 99701 USA. [Santoro, Maurizio] Gamma Remote Sensing, Gumlingen, Switzerland. [Shiklomanov, Alexander I.; Voeroesmarty, Charles] Univ New Hampshire, Durham, NH 03824 USA. [Shimoyama, Kou] Hokkaido Univ, Sapporo, Hokkaido, Japan. [Shugart, Herman H.; Shuman, Jacquelyn K.] Univ Virginia, Charlottesville, VA USA. [Sukhinin, Anatoly I.] Russian Acad Sci, Forest Inst, Siberian Branch, Krasnoyarsk, Russia. [Wood, Eric F.] Princeton Univ, Princeton, NJ 08544 USA. RP Groisman, PY (reprint author), NOAA, UCAR, Natl Climat Data Ctr, 151 Patton Ave, Asheville, NC 28801 USA. EM pasha.groisman@noaa.gov RI Chen, Jiquan/D-1955-2009; Shimoyama, Kou/D-9823-2012; Conard, Susan/H-8158-2013; lettenmaier, dennis/F-8780-2011; Maksyutov, Shamil/G-6494-2011; Shugart, Herman/C-5156-2009; Sofiev, Mikhail/F-7606-2016; Ojima, Dennis/C-5272-2016 OI lettenmaier, dennis/0000-0003-3317-1327; Maksyutov, Shamil/0000-0002-1200-9577; Sofiev, Mikhail/0000-0001-9542-5746; NR 78 TC 24 Z9 24 U1 2 U2 11 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0003-0007 EI 1520-0477 J9 B AM METEOROL SOC JI Bull. Amer. Meteorol. Soc. PD MAY PY 2009 VL 90 IS 5 BP 671 EP 688 DI 10.1175/2008BAMS2556.1 PG 18 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 462LR UT WOS:000267354800008 ER PT J AU Bromage, TG Lacruz, RS Hogg, R Goldman, HM McFarlin, SC Warshaw, J Dirks, W Perez-Ochoa, A Smolyar, I Enlow, DH Boyde, A AF Bromage, Timothy G. Lacruz, Rodrigo S. Hogg, Russell Goldman, Haviva M. McFarlin, Shannon C. Warshaw, Johanna Dirks, Wendy Perez-Ochoa, Alejandro Smolyar, Igor Enlow, Donald H. Boyde, Alan TI Lamellar Bone is an Incremental Tissue Reconciling Enamel Rhythms, Body Size, and Organismal Life History SO CALCIFIED TISSUE INTERNATIONAL LA English DT Article DE Bone lamella; Enamel striae of Retzius; Chronobiology; Life history ID DENTAL DEVELOPMENT; OSTEOCYTE DENSITY; ELECTRON-MICROSCOPY; ENERGY-METABOLISM; SEXUAL DIMORPHISM; MASS; MICROSTRUCTURE; PRIMATES; TEETH; PERIODICITY AB Mammalian enamel formation is periodic, including fluctuations attributable to the daily biological clock as well as longer-period oscillations that enigmatically correlate with body mass. Because the scaling of bone mass to body mass is an axiom of vertebrate hard tissue biology, we consider that long-period enamel formation rhythms may reflect corresponding and heretofore unrecognized rhythms in bone growth. The principal aim of this study is to seek a rhythm in bone growth demonstrably related to enamel oscillatory development. Our analytical approach is based in morphology, using a variety of hard tissue microscopy techniques. We first ascertain the relationship among long-period enamel rhythms, the striae of Retzius, and body mass using a large sample of mammalian taxa. In addition, we test whether osteocyte lacuna density (a surrogate for rates of cell proliferation) in bone is correlated with mammalian body mass. Finally, using fluorescently labeled developing bone tissues, we investigate whether the bone lamella, a fundamental microanatomical unit of bone, relates to rhythmic enamel growth increments. Our results confirm a positive correlation between long-period enamel rhythms and body mass and a negative correlation between osteocyte density and body mass. We also confirm that lamellar bone is an incremental tissue, one lamella formed in the species-specific time dependency of striae of Retzius formation. We conclude by contextualizing our morphological research with a current understanding of autonomic regulatory control of the skeleton and body mass, suggesting a central contribution to the coordination of organismal life history and body mass. C1 [Bromage, Timothy G.] NYU, Coll Dent, Dept Biomat & Biomimet, New York, NY 10010 USA. [Lacruz, Rodrigo S.] Univ So Calif, Sch Dent, Ctr Craniofacial Mol Biol, Los Angeles, CA 90089 USA. [Lacruz, Rodrigo S.] Univ Witwatersrand, Sch Geosci, Inst Human Evolut, Johannesburg, South Africa. [Hogg, Russell] CUNY, Grad Ctr, Dept Anthropol, New York, NY USA. [Goldman, Haviva M.] Drexel Univ, Coll Med, Dept Neurobiol & Anat, Philadelphia, PA 19104 USA. [McFarlin, Shannon C.] George Washington Univ, Dept Anthropol, Washington, DC USA. [Warshaw, Johanna] NYU, Coll Dent, Dept Basic Sci & Craniofacial Biol, New York, NY USA. [Dirks, Wendy] Univ Newcastle, Sch Dent Sci, Newcastle Upon Tyne, Tyne & Wear, England. [Perez-Ochoa, Alejandro] Lasalle Univ, Ctr Super Estudios Univ, Madrid, Spain. [Smolyar, Igor] Natl Ocean & Atmospher Adm, Natl Oceanog Data Ctr, Silver Spring, MD USA. [Enlow, Donald H.] Case Western Reserve Univ, Case Sch Dent Med, Cleveland, OH 44106 USA. [Boyde, Alan] Queen Mary Univ London, Ctr Oral Growth & Dev, London, England. [Bromage, Timothy G.] NYU, Coll Dent, Dept Basic Sci, New York, NY 10010 USA. [Bromage, Timothy G.] NYU, Coll Dent, Dept Craniofacial Biol, New York, NY 10010 USA. [Lacruz, Rodrigo S.] Univ Witwatersrand, BPI Palaeontol, Johannesburg, South Africa. RP Bromage, TG (reprint author), NYU, Coll Dent, Dept Biomat & Biomimet, 345 East 24th St, New York, NY 10010 USA. EM tim.bromage@nyu.edu OI LACRUZ, RODRIGO/0000-0002-0776-6143 NR 90 TC 60 Z9 60 U1 0 U2 8 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0171-967X J9 CALCIFIED TISSUE INT JI Calcif. Tissue Int. PD MAY PY 2009 VL 84 IS 5 BP 388 EP 404 DI 10.1007/s00223-009-9221-2 PG 17 WC Endocrinology & Metabolism SC Endocrinology & Metabolism GA 438SE UT WOS:000265574900007 PM 19234658 ER PT J AU Hart, DR Chute, AS AF Hart, Deborah R. Chute, Antonie S. TI Verification of Atlantic sea scallop (Placopecten magellanicus) shell growth rings by tracking cohorts in fishery closed areas SO CANADIAN JOURNAL OF FISHERIES AND AQUATIC SCIENCES LA English DT Article ID LENGTH FREQUENCY DATA; MODELS AB We tracked the growth of large cohorts of sea scallops (Placopecten magellanicus) at four sites located in areas closed to scallop fishing and compared the observed growth with that inferred from rings on sea scallop shells collected at the same sites. Stochastic growth transition matrices were constructed for each site based on the shell growth increments, assuming annual ring formation. These matrices were used to predict the annual growth of the scallops, which were compared with direct observations of growth obtained by repeated sampling. Additionally, the observed growth of the scallops was used to estimate the parameters of a stochastic von Bertalanffy model for each site, which were used to estimate the mean annual growth increments as a function of starting shell height. These were compared with the mean growth increments on the shells. There was a close correspondence, in most cases, between the observed growth and the growth inferred from the shell rings, implying that the shell rings were formed annually. The lack of fishing mortality in the areas meant that there was no confounding of size-selective fishing with growth and allowed us to track cohorts longer than would otherwise have been possible. C1 [Hart, Deborah R.; Chute, Antonie S.] Natl Marine Fisheries Serv, NE Fisheries Sci Ctr, Woods Hole, MA 02543 USA. RP Hart, DR (reprint author), Natl Marine Fisheries Serv, NE Fisheries Sci Ctr, 166 Water St, Woods Hole, MA 02543 USA. EM Deborah.Hart@noaa.gov NR 17 TC 4 Z9 4 U1 0 U2 4 PU NATL RESEARCH COUNCIL CANADA-N R C RESEARCH PRESS PI OTTAWA PA BUILDING M 55, OTTAWA, ON K1A 0R6, CANADA SN 0706-652X J9 CAN J FISH AQUAT SCI JI Can. J. Fish. Aquat. Sci. PD MAY PY 2009 VL 66 IS 5 BP 751 EP 758 DI 10.1139/F09-033 PG 8 WC Fisheries; Marine & Freshwater Biology SC Fisheries; Marine & Freshwater Biology GA 468IT UT WOS:000267811500004 ER PT J AU Berejikian, BA Van Doornik, DM Scheurer, JA Bush, R AF Berejikian, Barry A. Van Doornik, Donald M. Scheurer, Julie A. Bush, Richard TI Reproductive behavior and relative reproductive success of natural- and hatchery-origin Hood Canal summer chum salmon (Oncorhynchus keta) SO CANADIAN JOURNAL OF FISHERIES AND AQUATIC SCIENCES LA English DT Article ID SPRING CHINOOK SALMON; CROSS-SPECIES AMPLIFICATION; WILD STEELHEAD TROUT; MICROSATELLITE LOCI; BREEDING SUCCESS; BODY-SIZE; 1ST-GENERATION HATCHERY; LIFETIME SUCCESS; ATLANTIC SALMON; SOCKEYE-SALMON AB Estimates of the relative fitness of hatchery- and natural-origin salmon can help determine the value of hatchery stocks in contributing to recovery efforts. This study compared the adult to fry reproductive success of natural-origin summer chum salmon (Oncorhynchus keta) with that of first- to third-generation hatchery-origin salmon in an experiment that included four replicate breeding groups. Hatchery- and natural-origin chum salmon exhibited similar reproductive success. Hatchery- and natural-origin males obtained similar access to nesting females, and females of both types exhibited similar breeding behaviors and durations. Male body size was positively correlated with access to nesting females and reproductive success. The estimates of relative reproductive success (hatchery/natural = 0.83) in this study were similar to those in other studies of other anadromous salmonids in which the hatchery population was founded from the local natural population and much higher than those in studies that evaluated the lifetime relative reproductive success of nonlocal hatchery populations. C1 [Berejikian, Barry A.; Scheurer, Julie A.; Bush, Richard] NOAA Fisheries, NW Fisheries Sci Ctr, Resource Enhancement & Utilizat Technol Div, Manchester Res Stn, Manchester, WA 98353 USA. [Van Doornik, Donald M.] NOAA Fisheries, NW Fisheries Sci Ctr, Conservat Biol Div, Manchester Res Stn, Manchester, WA 98353 USA. RP Berejikian, BA (reprint author), NOAA Fisheries, NW Fisheries Sci Ctr, Resource Enhancement & Utilizat Technol Div, Manchester Res Stn, POB 130, Manchester, WA 98353 USA. EM barry.berejikian@noaa.gov NR 39 TC 19 Z9 19 U1 1 U2 11 PU NATL RESEARCH COUNCIL CANADA-N R C RESEARCH PRESS PI OTTAWA PA BUILDING M 55, OTTAWA, ON K1A 0R6, CANADA SN 0706-652X J9 CAN J FISH AQUAT SCI JI Can. J. Fish. Aquat. Sci. PD MAY PY 2009 VL 66 IS 5 BP 781 EP 789 DI 10.1139/F09-041 PG 9 WC Fisheries; Marine & Freshwater Biology SC Fisheries; Marine & Freshwater Biology GA 468IT UT WOS:000267811500007 ER PT J AU Hannesson, R Herrick, S Field, J AF Hannesson, Rognvaldur Herrick, Samuel, Jr. Field, John TI Ecological and economic considerations in the conservation and management of the Pacific sardine (Sardinops sagax) SO CANADIAN JOURNAL OF FISHERIES AND AQUATIC SCIENCES LA English DT Article ID LIONS ZALOPHUS-CALIFORNIANUS; MARINE ECOSYSTEM; ABUNDANCE; MODELS; FISH; DIET; SEA; VARIABILITY; POPULATIONS; VALUATION AB In this paper, we consider economic and ecological issues associated with the Pacific sardine (Sardinops sagax) as a commercially harvested species relative to its importance as prey for species of commercial, recreational, and ecological significance. Using economic theory and ecosystem modeling results for the California Current, we investigate whether sardines might be more valuable as forage than as commercial landings. Our analysis considers various conditions under which this would be justified. For example, ex-vessel prices of commercially important sardine predators near the high end of their respective ranges in recent years and the ex-vessel price of sardine at the low end of its respective range would favor leaving more sardine as forage fish. However, even if it were advisable to reduce the volume of the sardine fishery to leave more forage for other, more valuable species, it does not necessarily imply that the sardine fishery should be shut down altogether. Rather, our results indicate that consideration of the trade-offs is a key element of ecosystem-based fishery management. C1 [Herrick, Samuel, Jr.] SW Fisheries Sci Ctr, Fisheries Res Div, La Jolla, CA 92037 USA. [Hannesson, Rognvaldur] NHH, Sch Econ & Business Adm, NO-5045 Bergen, Norway. [Field, John] SW Fisheries Sci Ctr, Santa Cruz, CA 95060 USA. RP Herrick, S (reprint author), SW Fisheries Sci Ctr, Fisheries Res Div, 8604 La Jolla Shores Dr, La Jolla, CA 92037 USA. EM sam.herrick@noaa.gov NR 50 TC 19 Z9 19 U1 0 U2 5 PU NATL RESEARCH COUNCIL CANADA-N R C RESEARCH PRESS PI OTTAWA PA BUILDING M 55, OTTAWA, ON K1A 0R6, CANADA SN 0706-652X J9 CAN J FISH AQUAT SCI JI Can. J. Fish. Aquat. Sci. PD MAY PY 2009 VL 66 IS 5 BP 859 EP 868 DI 10.1139/F09-045 PG 10 WC Fisheries; Marine & Freshwater Biology SC Fisheries; Marine & Freshwater Biology GA 468IT UT WOS:000267811500014 ER PT J AU Friedland, KD Hare, JA Wood, GB Col, LA Buckley, LJ Mountain, DG Kane, J Brodziak, J Lough, RG Pilskaln, CH AF Friedland, Kevin D. Hare, Jonathan A. Wood, Grayson B. Col, Laurel A. Buckley, Lawrence J. Mountain, David G. Kane, Joseph Brodziak, Jon Lough, R. Gregory Pilskaln, Cynthia H. TI Reply to the comment by Payne et al. on "Does the fall phytoplankton bloom control recruitment of Georges Bank haddock, Melanogrammus aeglefinus, through parental condition?" SO CANADIAN JOURNAL OF FISHERIES AND AQUATIC SCIENCES LA English DT Editorial Material AB Payne et al. (Can. J. Fish. Aquat. Sci. 66: 869-872, 2009) raised several points concerning the handling and interpretation of data that went into an analysis of the population dynamics of Georges Bank haddock that suggested a relationship between the fall phytoplankton bloom and recruitment (Can. J. Fish. Aquat. Sci. 65: 1076-1086, 2008). Their main points were the manner in which logarithmic transforms were applied, whether the 2003 year class was truly as large as estimated in a 2006 assessment, and if correlation analyses of zooplankton data should be reconsidered. The reply to these comments was aided by a new assessment which provided additional years of data and improved the quality of the recruitment time series. The reply analyses showed that the relationships were robust to the way the logarithmic transform was applied, the initial estimates of the size of the 2003 year class were correct, and relationships between recruitment and spring zooplankton biomass levels remain statistically insignificant. From these new analyses, the interpretations and conclusions reached in the original paper remain the same; the fall bloom has emerged as a candidate explanatory variable for the stock independent variation in haddock recruitment on Georges Bank. C1 [Friedland, Kevin D.; Hare, Jonathan A.; Wood, Grayson B.; Kane, Joseph] NOAA, Natl Marine Fisheries Serv, Narragansett, RI 02882 USA. [Col, Laurel A.; Mountain, David G.; Lough, R. Gregory] Natl Marine Fisheries Serv, Woods Hole, MA 02543 USA. [Buckley, Lawrence J.] Univ Rhode Isl, NOAA, Cooperat Marine Educ & Res Program, Grad Sch Oceanog, Narragansett, RI 02882 USA. [Brodziak, Jon] NOAA, NMFS Pacific Isl Fisheries Sci Ctr, Fish Biol & Stock Assessment Div, Honolulu, HI 96822 USA. [Pilskaln, Cynthia H.] Univ Massachusetts Dartmouth, Sch Marine Sci & Technol SMAST, New Bedford, MA 02744 USA. RP Friedland, KD (reprint author), NOAA, Natl Marine Fisheries Serv, 28 Tarzwell Dr, Narragansett, RI 02882 USA. EM kevin.friedland@noaa.gov NR 8 TC 5 Z9 5 U1 0 U2 2 PU CANADIAN SCIENCE PUBLISHING, NRC RESEARCH PRESS PI OTTAWA PA 1200 MONTREAL ROAD, BUILDING M-55, OTTAWA, ON K1A 0R6, CANADA SN 0706-652X EI 1205-7533 J9 CAN J FISH AQUAT SCI JI Can. J. Fish. Aquat. Sci. PD MAY PY 2009 VL 66 IS 5 BP 873 EP 877 DI 10.1139/F09-044 PG 5 WC Fisheries; Marine & Freshwater Biology SC Fisheries; Marine & Freshwater Biology GA 468IT UT WOS:000267811500016 ER PT J AU Sidorenko, V Dizdaroglu, M Zharkov, D AF Sidorenko, Viktoriya Dizdaroglu, Miral Zharkov, Dmitry TI Substrate specificity of naturally occurring and phosphomimetic mutants of human 8-oxoguanine-DNA glycosylase SO CANCER RESEARCH LA English DT Meeting Abstract C1 RAS, Inst Chem Biol & Fundamental Med, SB, Novosibirsk, Russia. NIST, Gaithersburg, MD 20899 USA. NR 0 TC 0 Z9 0 U1 0 U2 0 PU AMER ASSOC CANCER RESEARCH PI PHILADELPHIA PA 615 CHESTNUT ST, 17TH FLOOR, PHILADELPHIA, PA 19106-4404 USA SN 0008-5472 EI 1538-7445 J9 CANCER RES JI Cancer Res. PD MAY 1 PY 2009 VL 69 SU 9 MA 2020 PG 1 WC Oncology SC Oncology GA V43ST UT WOS:000209701800089 ER PT J AU Bentz, DP AF Bentz, Dale P. TI Influence of internal curing using lightweight aggregates on interfacial transition zone percolation and chloride ingress in mortars SO CEMENT & CONCRETE COMPOSITES LA English DT Article DE Building technology; Diffusion; Interfacial transition zone; Internal curing; Lightweight aggregate; Microstructure; Percolation ID AGNO3 SPRAY TESTS; CEMENT PASTE; SILICA FUME; CONCRETE; DIFFUSIVITY; WEAKNESSES; ADVANTAGES; STRENGTH AB The microstructure of the interfacial transition zone (ITZ) between cement paste and aggregate depends strongly on the nature of the aggregate, specifically its porosity and water absorption. Lightweight aggregates (LWA) with a porous surface layer have been noted to produce a dense ITZ microstructure that is equivalent to that of the bulk cement paste, as opposed to the more porous ITZ regions that typically surround normal weight aggregates. This ITZ microstructure can have a large influence on diffusive transport into a concrete, especially if the individual ITZ regions are percolated (connected) across the three-dimensional microstructure. In this paper, the substitution of LWA sand for a portion of the normal weight sand to provide internal curing (IC) for a mortar is examined with respect to its influence on ITZ percolation and chloride ingress. Experimental measurements of chloride ion penetration depths are combined with computer modeling of the ITZ percolation and random walk diffusion simulations to determine the magnitude of the reduced diffusivity provided in a mortar with IC vs. one with only normal weight sand. In this study, for a mixture of sands that is 31% LWA and 69% normal weight sand by volume, the chloride ion diffusivity is estimated to be reduced by 25% or more, based on the measured penetration depths. Published by Elsevier Ltd. C1 NIST, Bldg & Fire Res Lab, Gaithersburg, MD 20899 USA. RP Bentz, DP (reprint author), NIST, Bldg & Fire Res Lab, 100 Bur Dr,Stop 8615, Gaithersburg, MD 20899 USA. EM dale.bentz@nist.gov NR 30 TC 54 Z9 65 U1 8 U2 24 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0958-9465 J9 CEMENT CONCRETE COMP JI Cem. Concr. Compos. PD MAY PY 2009 VL 31 IS 5 BP 285 EP 289 DI 10.1016/j.cemconcomp.2009.03.001 PG 5 WC Construction & Building Technology; Materials Science, Composites SC Construction & Building Technology; Materials Science GA 459KR UT WOS:000267101500002 ER PT J AU Stoliarov, SI Crowley, S Lyon, RE Linteris, GT AF Stoliarov, Stanislav I. Crowley, Sean Lyon, Richard E. Linteris, Gregory T. TI Prediction of the burning rates of non-charring polymers SO COMBUSTION AND FLAME LA English DT Article DE Material flammability; Gasification; Cone calorimetry; Pyrolysis model; ThermaKin ID THERMAL-CONDUCTIVITY; MELTS; GASIFICATION; DEGRADATION; HEAT AB This study provides a thorough examination of whether a numerical pyrolysis model, which describes transient energy transport and chemical reactions taking place in a one-dimensional object, can be used as a practical tool for prediction and/or extrapolation of the results of fire calorimetry tests. The focus is on non-charring polymers, in particular - poly(methylmethacrylate), high-impact polystyrene, and high-density polyethylene. First, relevant properties of these materials were measured and/or obtained from the literature. Subsequently, the values of these properties were used to simulate gasification and cone calorimetry experiments, which were performed under a broad range of conditions. A comparison with the experimental results indicates that the model gives reasonably good predictions of the mass loss and heat release histories. It also predicts the evolution of temperature inside the material samples. (C) 2008 The Combustion Institute. Published by Elsevier Inc. All rights reserved. C1 [Stoliarov, Stanislav I.] SRA Int Inc, Egg Harbor Township, NJ 08234 USA. [Crowley, Sean; Lyon, Richard E.] Fed Aviat Adm WJ Hughes Tech Ctr, Airport & Aircraft Safety Res & Dev Div, Atlantic City, NJ 08405 USA. [Linteris, Gregory T.] NIST, Bldg & Fire Res Lab, Gaithersburg, MD 20899 USA. RP Stoliarov, SI (reprint author), SRA Int Inc, 3120 Fire Rd, Egg Harbor Township, NJ 08234 USA. EM stanislav.ctr.stoliarov@faa.gov NR 20 TC 60 Z9 60 U1 0 U2 14 PU ELSEVIER SCIENCE INC PI NEW YORK PA 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA SN 0010-2180 J9 COMBUST FLAME JI Combust. Flame PD MAY PY 2009 VL 156 IS 5 BP 1068 EP 1083 DI 10.1016/j.combustflame.2008.11.010 PG 16 WC Thermodynamics; Energy & Fuels; Engineering, Multidisciplinary; Engineering, Chemical; Engineering, Mechanical SC Thermodynamics; Energy & Fuels; Engineering GA 431GD UT WOS:000265048600013 ER PT J AU Winder, VL Sapozhnikova, Y Pennington, PL Wirth, EF AF Winder, V. L. Sapozhnikova, Y. Pennington, P. L. Wirth, E. F. TI Effects of fluoxetine exposure on serotonin-related activity in the sheepshead minnow (Cyprinodon variegatus) using LC/MS/MS detection and quantitation SO COMPARATIVE BIOCHEMISTRY AND PHYSIOLOGY C-TOXICOLOGY & PHARMACOLOGY LA English DT Article DE Fluoxetine; LC/MS/MS; Pharmaceuticals; Serotonin; minnow; Tryptophan ID CHAR SALVELINUS-ALPINUS; SEWAGE-TREATMENT PLANTS; PHARMACEUTICAL SUBSTANCES; FEEDING-BEHAVIOR; ARCTIC-CHARR; WHOLE-BLOOD; SOCIAL RANK; FISH; TOXICITY; SURFACE AB Fluoxetine (FLX) is a selective serotonin reuptake inhibitor and is among the top 100 drugs prescribed yearly in the United States and the United Kingdom. Tissue and water extraction methods were developed to detect and quantify FLX, norfluosetine and the associated biological compounds serotonin (5-HT), 5-hydroxyindole-3-acetic acid (5-HIAA), tryptophan (TRP) and melatonin (MEL) using LC/MS/MS. Acute mortality and sublethal physiological effects of FLX were assessed using standard static renewal toxicity tests in which juvenile sheepshead minnows (Cyprinodon variegatus) were exposed to FLX. Fluoxetine did not cause significant mortality at levels near currently reported environmental concentrations. Significant changes in neurotransmitter levels were observed within the serotonergic system in juvenile sheepshead minnows exposed at concentrations approximately one order of magnitude above those currently reported in the environment. Transformation activity ratios of a product to a precursor compound (5-HT/TRP, 5-HIAA/5-HT and MEL/5-HT) also exhibited significant changes with FIX treatment. Fluoxetine exposure did not only affect 5-HT but had additional effects both upstream and downstream of 5-HT within its synthesis and metabolic pathways. These sublethal changes within the serotonergic pathway may result in behavioral changes which could, in turn, have implications for the ecological response Of Populations to additional environmental stressors. (c) 2008 Elsevier Inc. All rights reserved. C1 [Winder, V. L.] Coll Charleston, Dept Biol, Grice Marine Lab, Charleston, SC 29412 USA. [Sapozhnikova, Y.; Pennington, P. L.] Jardon & Howard Technol Inc, Orlando, FL 32826 USA. [Wirth, E. F.] Natl Ocean & Atmospher Adm, Natl Ocean Serv, Charleston, SC 29412 USA. RP Winder, VL (reprint author), Ed Wirth 331 Ft Johnson Rd, Charleston, SC 29412 USA. EM vlw3056@uncw.edu OI Winder, Virginia/0000-0002-5756-3993 NR 25 TC 18 Z9 18 U1 4 U2 26 PU ELSEVIER SCIENCE INC PI NEW YORK PA 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA SN 1532-0456 J9 COMP BIOCHEM PHYS C JI Comp. Biochem. Physiol. C-Toxicol. Pharmacol. PD MAY PY 2009 VL 149 IS 4 BP 559 EP 565 DI 10.1016/j.cbpc.2008.12.008 PG 7 WC Biochemistry & Molecular Biology; Endocrinology & Metabolism; Toxicology; Zoology SC Biochemistry & Molecular Biology; Endocrinology & Metabolism; Toxicology; Zoology GA 441NS UT WOS:000265776500016 PM 19150510 ER PT J AU Beichl, I Sullivan, F AF Beichl, Isabel Sullivan, Francis TI CUT IT OUT! SO COMPUTING IN SCIENCE & ENGINEERING LA English DT Article AB This issue marks the return of the Computing Prescriptions department; here, the authors describe an algorithm for finding minimum cutsets in connected graphs. C1 [Beichl, Isabel] Natl Inst Stand & Technol, Informat Technol Lab, Gaithersburg, MD 20899 USA. [Sullivan, Francis] Ctr Comp Sci, Bowie, MD USA. RP Beichl, I (reprint author), Natl Inst Stand & Technol, Informat Technol Lab, Gaithersburg, MD 20899 USA. EM isabel.beichl@nist.gov; fran@super.org NR 2 TC 1 Z9 1 U1 0 U2 0 PU IEEE COMPUTER SOC PI LOS ALAMITOS PA 10662 LOS VAQUEROS CIRCLE, PO BOX 3014, LOS ALAMITOS, CA 90720-1314 USA SN 1521-9615 J9 COMPUT SCI ENG JI Comput. Sci. Eng. PD MAY-JUN PY 2009 VL 11 IS 3 BP 74 EP 78 PG 5 WC Computer Science, Interdisciplinary Applications SC Computer Science GA 433RB UT WOS:000265222400012 ER PT J AU Schmidt, JH Lindberg, MS Johnson, DS Schmutz, JA AF Schmidt, Joshua H. Lindberg, Mark S. Johnson, Devin S. Schmutz, Joel A. TI ENVIRONMENTAL AND HUMAN INFLUENCES ON TRUMPETER SWAN HABITAT OCCUPANCY IN ALASKA SO CONDOR LA English DT Article DE anthropogenic effects; Cygnus buccinator; habitat occupancy; Trumpeter Swan; wetland loss ID CLIMATE-CHANGE; NORTHERN ALASKA; BIRDS; LAKES AB Approximately 70-80% of the entire population of the Trumpeter Swan (Cygnus buccinator) depends for reproduction on wetlands in Alaska. This makes the identification of important habitat features and the effects of human interactions important for the species' long-term management. We analyzed the swan's habitat preferences in five areas throughout the state and found that swan broods occupied some wetland types, especially larger closed-basin wetlands such as lakes and ponds, at rates much higher than they occupied other wetland types, Such as shrubby or forested wetlands. We also found a negative effect of transportation infrastructure on occupancy by broods in and around the Minto Flats State Game Refuge, Kenai National Wildlife Refuge, and Tetlin National Wildlife Refuge. This finding is of particular interest because much of the Minto Flats refuge has recently been licensed for oil and gas exploration and parts of the Kenai refuge have been developed in the past. We also investigated the potential effects of the shrinkage of closed-basin ponds on habitat occupancy by nesting Trumpeter Swans. We compared nesting swans' use of ponds with changes in the ponds' size and other characteristics from 1982 to 1996 and found no relationships between occupancy and changes in pond size. However, we believe that the recent and rapid growth of Trumpeter Swan populations in Alaska may become limited by available breeding habitat, and anthropogenic and climate-induced changes to the swan's breeding habitats have the potential to limit future production. C1 [Schmidt, Joshua H.; Lindberg, Mark S.] Univ Alaska, Dept Biol & Wildlife, Fairbanks, AK 99775 USA. [Schmidt, Joshua H.; Lindberg, Mark S.] Univ Alaska, Inst Arctic Biol, Fairbanks, AK 99775 USA. [Johnson, Devin S.] NOAA, Alaska Fisheries Sci Ctr, Natl Marine Mammal Lab, Seattle, WA 98115 USA. [Schmutz, Joel A.] US Geol Survey, Alaska Sci Ctr, Anchorage, AK 99508 USA. RP Schmidt, JH (reprint author), Natl Pk Serv, 4175 Geist Rd, Fairbanks, AK 99709 USA. EM Joshua_Schmidt@nps.gov FU Alaska Department of Fish and Game; State Wildlife; Alaska EPScOR; University of Alaska; Fairbanks; Department of Biology and Wildlife and Institute of Arctic Biology FX Support for the first author was provided by the Alaska Department of Fish and Game, State Wildlife Grant, the Alaska EPScOR program, and the University of Alaska, Fairbanks, Department of Biology and Wildlife and Institute of Arctic Biology. USFWS Migratory Birds Management Division collected and graciously provided most of the data used in this manuscript. Staff at the Kenai NWR, J. Morton in particular, helped us investigate long-term data from that area. We thank D. Verbyla for comments on previous versions of this manuscript. NR 31 TC 1 Z9 1 U1 2 U2 20 PU COOPER ORNITHOLOGICAL SOC PI LAWRENCE PA ORNITHOLOGICAL SOC NORTH AMER PO BOX 1897, LAWRENCE, KS 66044-8897 USA SN 0010-5422 J9 CONDOR JI Condor PD MAY PY 2009 VL 111 IS 2 BP 266 EP 275 DI 10.1525/cond.2009.080102 PG 10 WC Ornithology SC Zoology GA 459KW UT WOS:000267102100006 ER PT J AU Gan, ZH Dong, WQ Qiu, LM Zhang, XB Sun, H He, YL Radebaugh, R AF Gan, Z. H. Dong, W. Q. Qiu, L. M. Zhang, X. B. Sun, H. He, Y. L. Radebaugh, R. TI A single-stage GM-type pulse tube cryocooler operating at 10.6 K SO CRYOGENICS LA English DT Article DE Pulse tube cryocooler; REGEN; Regenerator ID COOLER AB In order to explore the lowest attainable refrigeration temperature and improve cooling performance at temperatures around 20 K for a single-stage G-M type pulse tube cryocooler (PTC), numerical and experimental studies were performed. The National Institute of Standards and Technology (NIST) numerical model known as REGEN was applied to the simulation of a G-M type PTC for the first time. Based on the calculation results, a single-stage G-M type PTC was designed, fabricated and tested. The performance improvement of the regenerator in the temperature range of 10-80 K was investigated. The calculations predicted a lowest temperature of 10K. A lowest temperature of 10.6K was achieved experimentally with an input power of 7.5 kW, which is the lowest temperature ever achieved by a single-stage PTC. Further more, the cryocooler can provide a cooling power of 20 W at 20.6 K and 39.5 W at 30 K, respectively. (C) 2009 Elsevier Ltd. All rights reserved. C1 [Gan, Z. H.; Dong, W. Q.; Qiu, L. M.; Zhang, X. B.; Sun, H.; He, Y. L.] Zhejiang Univ, Inst Reffigerat & Cryogen Engn, Hangzhou 310027, Peoples R China. [Radebaugh, R.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Qiu, LM (reprint author), Zhejiang Univ, Inst Reffigerat & Cryogen Engn, Hangzhou 310027, Peoples R China. EM Limin.Qiu@zju.edu.cn OI GAN, Zhihua/0000-0003-4112-6745 FU Natural Science Foundation of China [50776076]; Science and Technology Department of Zhejiang Province, China [2006C24G2010027] FX This work was supported by Natural Science Foundation of China under Contract No. 50776076 and the Science and Technology Department of Zhejiang Province, China under Contract No. 2006C24G2010027. NR 13 TC 12 Z9 20 U1 1 U2 6 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0011-2275 J9 CRYOGENICS JI Cryogenics PD MAY PY 2009 VL 49 IS 5 BP 198 EP 201 DI 10.1016/j.cryogenics.2009.01.004 PG 4 WC Thermodynamics; Physics, Applied SC Thermodynamics; Physics GA 456NK UT WOS:000266853400007 ER PT J AU Johnson, GC Purkey, SG AF Johnson, Gregory C. Purkey, Sarah G. TI Deep Caribbean Sea warming SO DEEP-SEA RESEARCH PART I-OCEANOGRAPHIC RESEARCH PAPERS LA English DT Article DE Caribbean Sea; Climate change; Sea level rise; Ocean warming ID ANEGADA-JUNGFERN PASSAGE; HYDROGRAPHIC CHANGES; LABRADOR SEA; HEAT-FLOW; WATER; INFLOW AB Data collected from hydrographic stations occupied within the Venezuelan and Columbian basins of the Caribbean Sea from 1922 through 2003 are analyzed to study the decadal variability of deep temperature in the region. The analysis focuses on waters below the 1815-m sill depth of the Anegada-Jungfern Passage. Relatively dense waters (compared to those in the deep Caribbean) from the North Atlantic spill over this sill to ventilate the deep Caribbean Sea. Deep warming at a rate of over 0.01 degrees C decade(-1) below this sill depth appears to have commenced in the 1970s after a period of relatively constant deep Caribbean Sea temperatures extending at least as far back as the 1920s. Conductivity-temperature-depth station data from World Ocean Circulation Experiment Section A22 along 66 degrees W taken in 1997 and again in 2003 provide an especially precise, albeit geographically limited, estimate of this warming over that 6-year period. They also suggest a small (0.001 PSS-78, about the size of expected measurement biases) deep freshening. The warming is about 10 times larger than the size of geothermal heating in the region, and is of the same magnitude as the average global upper-ocean heat uptake over a recent 50-year period. Together with the freshening, the warming contributes about 0.012 m decade(-1) of sea level rise in portions of the Caribbean Sea with bottom depths around 5000 m. Published by Elsevier Ltd. C1 [Johnson, Gregory C.; Purkey, Sarah G.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. [Purkey, Sarah G.] Univ Washington, Sch Oceanog, Seattle, WA 98195 USA. RP Johnson, GC (reprint author), NOAA, Pacific Marine Environm Lab, 7600 Sand Point Way NE,Bldg 3, Seattle, WA 98115 USA. EM Gregory.C.johnson@noaa.gov RI Purkey, Sarah/K-1983-2012; Johnson, Gregory/I-6559-2012 OI Johnson, Gregory/0000-0002-8023-4020 NR 21 TC 4 Z9 4 U1 0 U2 7 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0967-0637 EI 1879-0119 J9 DEEP-SEA RES PT I JI Deep-Sea Res. Part I-Oceanogr. Res. Pap. PD MAY PY 2009 VL 56 IS 5 BP 827 EP 834 DI 10.1016/j.dsr.2008.12.011 PG 8 WC Oceanography SC Oceanography GA 440ZA UT WOS:000265737100013 ER PT J AU Corliss, BH Brown, CW Sun, X Showers, WJ AF Corliss, B. H. Brown, C. W. Sun, X. Showers, W. J. TI Deep-sea benthic diversity linked to seasonality of pelagic productivity SO DEEP-SEA RESEARCH PART I-OCEANOGRAPHIC RESEARCH PAPERS LA English DT Article DE Deep-sea diversity; Benthos; Foraminifera; Seasonality ID SPECIES-DIVERSITY; NORTH-ATLANTIC; CARBON FLUX; FORAMINIFERA; RICHNESS; DELTA-C-13; PATTERNS; WATER AB Latitudinal gradients in biodiversity are found in both terrestrial and marine environments, but little agreement exists on the mechanisms or ecological causes creating these patterns. Marine biodiversity patterns have been particularly challenging to document, because of the lack of appropriate data sets from ocean basins. We document latitudinal patterns of North Atlantic deep-sea benthic foraminifera and show that seasonality of primary productivity, as estimated from SeaWiFS satellite imagery, has a significant effect on diversity indices, with generally lower values of H(S), species #, and species equitability found with high seasonality between 40 and 60 degrees N. High foraminiferal diversity is not found in areas with phytodetritus deposition in the North Atlantic basin, which indicates that patch dynamics, biological disturbance, and sediment heterogeneity resulting from phytodetritus deposits do not create high deep-sea foraminiferal diversity. Annual resource stability, reflecting the timing of organic carbon flux and the mode of sedimentation, accounts for the benthic foraminiferal patterns found in this study and is an important variable structuring the deep-sea benthic foraminiferal community. (C) 2009 Elsevier Ltd. All rights reserved. C1 [Corliss, B. H.] Duke Univ, Nicholas Sch Environm, Div Earth & Ocean Sci, Durham, NC 27708 USA. [Brown, C. W.] Natl Ocean & Atmospher Adm, Cooperat Inst Climate Studies, College Pk, MD 20742 USA. [Sun, X.] Takeda Global Res & Dev, Global Hlth Econ & Outcomes Res, Deerfield, IL 60015 USA. [Showers, W. J.] N Carolina State Univ, Dept Marine Earth & Atmospher Sci, Raleigh, NC 27607 USA. RP Corliss, BH (reprint author), Duke Univ, Nicholas Sch Environm, Div Earth & Ocean Sci, Box 90227, Durham, NC 27708 USA. EM bruce.corliss@duke.edu RI Brown, Christopher/B-8213-2008 OI Brown, Christopher/0000-0002-9905-6391 FU National Science Foundation [OCE-0240771] FX We thank M.J. Behrenfeld and R-T. O'Malley for providing the estimates of 8-day primary productivity generated using their Vertically Generalized Production Model, M.P. Lutz and J.P. Dunne for providing their organic carbon flux data, and two anonymous reviewers and A.J. Gooday for helpful reviews. The views, opinions, and findings contained in this paper are those of the authors and should not be construed as an official National Oceanic and Atmospheric Administration or US Government position, policy, or decision. This research was supported by National Science Foundation Grant OCE-0240771. NR 42 TC 31 Z9 33 U1 1 U2 21 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0967-0637 J9 DEEP-SEA RES PT I JI Deep-Sea Res. Part I-Oceanogr. Res. Pap. PD MAY PY 2009 VL 56 IS 5 BP 835 EP 841 DI 10.1016/j.dsr.2008.12.009 PG 7 WC Oceanography SC Oceanography GA 440ZA UT WOS:000265737100014 ER PT J AU Kathe, SD Barrantes-Reynolds, R Jaruga, P Newton, MR Burrows, CJ Bandaru, V Dizdaroglu, M Bond, JP Wallace, SS AF Kathe, Scott D. Barrantes-Reynolds, Ramiro Jaruga, Pawel Newton, Michael R. Burrows, Cynthia J. Bandaru, Viswanath Dizdaroglu, Miral Bond, Jeffrey P. Wallace, Susan S. TI Plant and fungal Fpg homologs are formamidopyrimidine DNA glycosylases but not 8-oxoguanine DNA glycosylases SO DNA REPAIR LA English DT Article DE Base excision repair; DNA glycosylases; Phylogenetics; Formamidopyrimidine DNA glycosylase; Endonuclease VIII (Nei); Arabidopsis thaliana; Candida albicans; Guanidinohydantoin; Spiroiminodihydantoin ID BASE-EXCISION-REPAIR; COLI ENDONUCLEASE-VIII; OXIDATIVELY DAMAGED DNA; MULTIPLE SEQUENCE ALIGNMENT; SCHIZOSACCHAROMYCES-POMBE; SACCHAROMYCES-CEREVISIAE; SUBSTRATE-SPECIFICITY; ARABIDOPSIS-THALIANA; CRYSTAL-STRUCTURE; MAMMALIAN-CELLS AB Formamidopyrimidine DNA glycosylase (Fpg) and endonuclease VIII (Nei) share an overall common three-dimensional structure and primary amino acid sequence in conserved structural motifs but have different substrate specificities, with bacterial Fpg proteins recognizing formamidopyrimidines, 8-oxoguanine (8-oxoG) and its oxidation products guanidinohydantoin (Gh), and spiroiminodihydantoin (Sp) and bacterial Nei proteins recognizing primarily damaged pyrimidines. In addition to bacteria, Fpg has also been found in plants, while Nei is sparsely distributed among the prokaryotes and eukaryotes. Phylogenetic analysis of Fpg and Nei DNA glycosylases demonstrated, with 95% bootstrap support, a clade containing exclusively sequences from plants and fungi. Members of this clade exhibit sequence features closer to bacterial Fpg proteins than to any protein designated as Nei based on biochemical Studies. The Candida albicans (Cal) Fpg DNA glycosylase and a previously studied Arabidopsis thaliana (Ath) Fpg DNA glycosylase were expressed, purified and characterized. In oligodeoxynucleotides, the preferred glycosylase substrates for both enzymes were Gh and Sp, the oxidation products of 8-oxoG, with the best substrate being a site of base loss. GC/MS analysis of bases released from gamma-irradiated DNA show FapyAde and FapyGua to be excellent substrates as well. Studies carried out with oligodeoxynucleotide substrates demonstrate that both enzymes discriminated against A opposite the base lesion, characteristic of Fpg glycosylases. Single turnover kinetics with oligodeoxynucleotides showed that the plant and fungal glycosylases were most active on Gh and Sp, less active on oxidized pyrimidines and exhibited very little or no activity on 8-oxoG. Surprisingly, the activity of AthFpg1 on an AP site opposite a G was extremely robust with a k(obs) of over 2500 min(-1). (C) 2009 Elsevier B.V. All rights reserved. C1 [Kathe, Scott D.; Barrantes-Reynolds, Ramiro; Bandaru, Viswanath; Bond, Jeffrey P.; Wallace, Susan S.] Univ Vermont, Markey Ctr Mol Genet, Dept Microbiol & Mol Genet, Burlington, VT 05405 USA. [Jaruga, Pawel; Dizdaroglu, Miral] Natl Inst Stand & Technol, Chem Sci & Technol Lab, Gaithersburg, MD 20899 USA. [Newton, Michael R.; Burrows, Cynthia J.] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA. RP Bond, JP (reprint author), Univ Vermont, Markey Ctr Mol Genet, Dept Microbiol & Mol Genet, Stafford Hall,95 Carrigan Dr, Burlington, VT 05405 USA. EM jeffrey.bond@uvm.edu; susan.wallace@uvm.edu RI Jaruga, Pawel/M-4378-2015; OI Wallace, Susan S./0000-0002-3906-0321 FU NIH [P01 CA098993] FX Certain commercial equipment or materials are identified in this paper in order to specify adequately the experimental procedure. Such identification does not imply recommendation or endorsement by the National Institute of Standards and Technology, nor does it imply that the materials or equipment identified are necessarily the best available for the purpose. NR 57 TC 16 Z9 17 U1 0 U2 3 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 1568-7864 J9 DNA REPAIR JI DNA Repair PD MAY 1 PY 2009 VL 8 IS 5 BP 643 EP 653 DI 10.1016/j.dnarep.2008.12.013 PG 11 WC Genetics & Heredity; Toxicology SC Genetics & Heredity; Toxicology GA 440XD UT WOS:000265732100009 PM 19217358 ER PT J AU Huber, ML Lemmon, EW Ott, LS Bruno, TJ AF Huber, M. L. Lemmon, E. W. Ott, L. S. Bruno, T. J. TI Preliminary Surrogate Mixture Models for the Thermophysical Properties of Rocket Propellants RP-1 and RP-2 SO ENERGY & FUELS LA English DT Article ID ADVANCED DISTILLATION CURVE; THERMAL-DECOMPOSITION KINETICS; REFRIGERANT MIXTURES; JET FUEL; AVIATION FUEL; N-DODECANE; CONDUCTIVITY; IMPROVEMENTS; VISCOSITY; JP-8 AB We have developed surrogate mixture models to represent the thermophysical properties of two kerosene rocket propellants, RP-I and RP-2. The surrogates were developed with a procedure that incorporated experimental data for the density, sound speed, viscosity, thermal conductivity, and the advanced distillation curves for samples of the two fuels. The surrogate for RP-I contains four components (alpha-methyldecalin, n-dodecane, 5-methylnonane, and heptylcyclohexane), and the surrogate for RP-2 contains five components (alpha-methyldecatin, n-dodecane, 5-methylnonane, 2,4-dimethyinonane, and heptylcyclohexane). Comparisons with experimental data demonstrate that the models are able to represent the density, sound speed, viscosity, and thermal conductivity of both fuels to within (at a 95% confidence level) 0.4, 2, 2, and 4%, respectively. The volatility behavior, as measured by the advanced distillation curves, is reproduced to within 0.5%. C1 [Huber, M. L.; Lemmon, E. W.; Ott, L. S.; Bruno, T. J.] Natl Inst Stand & Technol, Thermophys Properties Div, Boulder, CO 80305 USA. RP Bruno, TJ (reprint author), Natl Inst Stand & Technol, Thermophys Properties Div, Boulder, CO 80305 USA. EM bruno@boulder.nist.gov FU Air Force Research Laboratory [MIPR F1SBAA8022G001] FX We gratefully acknowledge Mr. Matt Billingsley at AFRL, Edwards Air Force Base for the RP-2 sample, and Dr. Tim Edwards at AFRL, Wright Patterson Air Force Base for the RP-1 sample. Financial support of the Air Force Research Laboratory (MIPR F1SBAA8022G001) is gratefully acknowledged. In addition, we also thank our NIST colleagues Dr. A. Laesecke, Dr. R. Perkins, S. Outcalt, and Dr. M. McLinden for sharing their data prior to publication, helpful discussions, and assistance. NR 61 TC 51 Z9 52 U1 2 U2 11 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0887-0624 EI 1520-5029 J9 ENERG FUEL JI Energy Fuels PD MAY-JUN PY 2009 VL 23 BP 3083 EP 3088 DI 10.1021/ef900216z PG 6 WC Energy & Fuels; Engineering, Chemical SC Energy & Fuels; Engineering GA 463FX UT WOS:000267416600100 ER PT J AU Fett, T Rizzi, G Guin, JP Lopez-Cepero, JM Wiederhorn, SM AF Fett, T. Rizzi, G. Guin, J. P. Lopez-Cepero, J. M. Wiederhorn, S. M. TI A fracture mechanics analysis of the double cleavage drilled compression test specimen SO ENGINEERING FRACTURE MECHANICS LA English DT Article DE DCDC specimen; Stress intensity factor; Surface displacements; T-stress; Weight function ID CRACK; STRESS; GLASS; PROPAGATION AB The "double cleavage drilled compression" specimen is used for the determination of crack growth rates under mode-I and general mixed-mode loading conditions. In this paper, a fracture mechanics analysis is presented for the DCDC specimen, using a finite-element analysis to determine stresses, strains and surface displacements. Weight functions are derived, and the consequence of load misalignment is demonstrated. Finally, side-surface displacements at the crack terminating region are studied using a 3-dimensional, finite-element computation in combination with results from the literature that are based on an "asymptotic analysis". Calculated side-surface displacements in the vicinity of the crack tip are found to agree with published values obtained by others via measurements using the atomic force microscope. (C) 2009 Elsevier Ltd. All rights reserved. C1 [Fett, T.] Univ Karlsruhe, Inst Keramik Maschinenbau, D-76131 Karlsruhe, Germany. [Rizzi, G.] Inst Mat Forsch II, Forschungszentrum Karlsruhe, Karlsruhe, Germany. [Guin, J. P.] Univ Rennes 1, LARMAUR FRE CNRS 2717, Rennes, France. [Lopez-Cepero, J. M.; Wiederhorn, S. M.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Fett, T (reprint author), Univ Karlsruhe, Inst Keramik Maschinenbau, Haid & Neu Str 7, D-76131 Karlsruhe, Germany. EM theo.fett@ikm.uni-karlsruhe.de RI guin, jean-pierre/A-5969-2009 OI guin, jean-pierre/0000-0003-2480-5893 NR 29 TC 6 Z9 7 U1 0 U2 16 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0013-7944 J9 ENG FRACT MECH JI Eng. Fract. Mech. PD MAY PY 2009 VL 76 IS 7 BP 921 EP 934 DI 10.1016/j.engfracmech.2008.12.016 PG 14 WC Mechanics SC Mechanics GA 453QX UT WOS:000266627100008 ER PT J AU Morrow, JB Cole, KD AF Morrow, Jayne B. Cole, Kenneth D. TI Enhanced Decontamination of Bacillus Spores in a Simulated Drinking Water System by Germinant Addition SO ENVIRONMENTAL ENGINEERING SCIENCE LA English DT Article DE Bacillus spores; drinking water; disinfection; decontamination; fluid shear; germination; bioterrorism ID CHLORINE DIOXIDE; VEGETATIVE CELLS; STAINLESS-STEEL; CEREUS SPORES; BIOFILMS; DISINFECTION; MODEL; INACTIVATION; MONOCHLORAMINE; PENETRATION AB Contact with germinant solutions followed by commonly used disinfectants as a means to decontaminate Bacillus spores in a model drinking water system was investigated. Biofilms composed of indigenous water system bacteria were accumulated on materials commonly used for residential plumbing, polyvinyl chloride (PVC), and copper, in a continuously stirred tank reactor for controlled shear. Once the biofilms were established, Bacillus thuringiensis kurstaki or B. anthracis Sterne spores were added to the reactor. Pipe surfaces were studied for biofilm accumulation, spore adhesion, and disinfectant (chlorine and monochloramine) susceptibility before and after germinant (1 mM inosine and 8 mM L-alanine) addition. High disinfectant concentrations (up to 100 mg/L free chlorine and 10 mg/L monochloramine) yielded less than a 2 log(10) reduction in biofilm-associated viable spores after 60 min. A 4 log(10) reduction in the associated spores was observed when coupons were contacted with germinants (24 h) prior to sampling. Germinant contact followed by heat (50 degrees C, 25 min) or disinfection resulted in a greater than 4 log(10) reduction in the associated viable spores. Contact with germinants resulted in dramatically enhanced susceptibility of surface-associated spores to elevated water temperature and disinfectants. C1 [Morrow, Jayne B.; Cole, Kenneth D.] Natl Inst Stand & Technol, Div Biochem Sci, Gaithersburg, MD 20899 USA. RP Morrow, JB (reprint author), Natl Inst Stand & Technol, Div Biochem Sci, 100 Bur Dr MS 8312, Gaithersburg, MD 20899 USA. EM jayne.morrow@nist.gov FU National Homeland Security Research Center, EPA (Cincinnati, OH); Vince Gallardo FX Support for this work was provided by the National Homeland Security Research Center, EPA (Cincinnati, OH) and Vince Gallardo. We wish to thank Dr. Bruce Harper from Dugway Proving Grounds, Dugway, Utah, for providing the B. anthracis Sterne spore preparation. NR 38 TC 4 Z9 4 U1 0 U2 9 PU MARY ANN LIEBERT INC PI NEW ROCHELLE PA 140 HUGUENOT STREET, 3RD FL, NEW ROCHELLE, NY 10801 USA SN 1092-8758 J9 ENVIRON ENG SCI JI Environ. Eng. Sci. PD MAY PY 2009 VL 26 IS 5 BP 993 EP 1000 DI 10.1089/ees.2008.0309 PG 8 WC Engineering, Environmental; Environmental Sciences SC Engineering; Environmental Sciences & Ecology GA 436NA UT WOS:000265419600013 ER PT J AU Kish, A Kirkali, G Robinson, C Rosenblatt, R Jaruga, P Dizdaroglu, M DiRuggiero, J AF Kish, A. Kirkali, G. Robinson, C. Rosenblatt, R. Jaruga, P. Dizdaroglu, M. DiRuggiero, J. TI Salt shield: intracellular salts provide cellular protection against ionizing radiation in the halophilic archaeon, Halobacterium salinarum NRC-1 SO ENVIRONMENTAL MICROBIOLOGY LA English DT Article ID DNA-BASE DAMAGE; BACTERIUM DEINOCOCCUS-RADIODURANS; COLI FPG PROTEIN; GAMMA-IRRADIATION; OXIDATIVE STRESS; GENOME SEQUENCE; EXCISION-REPAIR; PURINE LESIONS; RESISTANCE; DESICCATION AB The halophilic archaeon Halobacterium salinarum NRC-1 was used as a model system to investigate cellular damage induced by exposure to high doses of ionizing radiation (IR). Oxidative damages are the main lesions from IR and result from free radicals production via radiolysis of water. This is the first study to quantify DNA base modification in a prokaryote, revealing a direct relationship between yield of DNA lesions and IR dose. Most importantly, our data demonstrate the significance of DNA radiation damage other than strand breaks on cell survival. We also report the first in vivo evidence of reactive oxygen species scavenging by intracellular halides in H. salinarum NRC-1, resulting in increased protection against nucleotide modification and carbonylation of protein residues. Bromide ions, which are highly reactive with hydroxyl radicals, provided the greatest protection to cellular macromolecules. Modified DNA bases were repaired in 2 h post irradiation, indicating effective DNA repair systems. In addition, measurements of H. salinarum NRC-1 cell interior revealed a high Mn/Fe ratio similar to that of Deinococcus radiodurans and other radiation-resistant microorganisms, which has been shown to provide a measure of protection for proteins against oxidative damage. The work presented here supports previous studies showing that radiation resistance is the product of mechanisms for cellular protection and detoxification, as well as for the repair of oxidative damage to cellular macromolecules. The finding that not only Mn/Fe but also the presence of halides can decrease the oxidative damage to DNA and proteins emphasizes the significance of the intracellular milieu in determining microbial radiation resistance. C1 [Kish, A.; Robinson, C.; Rosenblatt, R.; DiRuggiero, J.] Univ Maryland, Dept Cell Biol & Mol Genet, College Pk, MD 20742 USA. [Kirkali, G.; Jaruga, P.; Dizdaroglu, M.] Natl Inst Stand & Technol, Chem Sci & Technol Lab, Gaithersburg, MD 20899 USA. [Kirkali, G.] Dokuz Eylul Univ, Sch Med, Dept Biochem, Izmir, Turkey. RP DiRuggiero, J (reprint author), Johns Hopkins Univ, Baltimore, MD 21218 USA. EM jdiruggiero@jhu.edu RI Jaruga, Pawel/M-4378-2015 FU NASA [NNG05GN58G]; AFOSR [FA95500710158] FX Certain commercial equipment or materials are identified in this article in order to specify adequately the experimental procedure. Such identification does not imply recommendation or endorsement by the University of Maryland or the National Institute of Standards and Technology, nor does it imply that the materials or equipment identified are necessarily the best available for the purpose. NR 73 TC 28 Z9 30 U1 2 U2 12 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 1462-2912 J9 ENVIRON MICROBIOL JI Environ. Microbiol. PD MAY PY 2009 VL 11 IS 5 BP 1066 EP 1078 DI 10.1111/j.1462-2920.2008.01828.x PG 13 WC Microbiology SC Microbiology GA 437IW UT WOS:000265481600004 PM 19452594 ER PT J AU Webster, TF Harrad, S Millette, JR Holbrook, RD Davis, JM Stapleton, HM Allen, JG Mcclean, MD Ibarra, C Abdallah, MAE Covaci, A AF Webster, Thomas F. Harrad, Stuart Millette, James R. Holbrook, R. David Davis, Jeffrey M. Stapleton, Heather M. Allen, Joseph G. Mcclean, Michael D. Ibarra, Catalina Abdallah, Mohamed Abou-Elwafa Covaci, Adrian TI Identifying Transfer Mechanisms and Sources of Decabromodiphenyl Ether (BDE 209) in Indoor Environments Using Environmental Forensic Microscopy SO ENVIRONMENTAL SCIENCE & TECHNOLOGY LA English DT Article ID POLYBROMINATED DIPHENYL ETHERS; BROMINATED FLAME RETARDANTS; IN-HOUSE DUST; HUMAN EXPOSURE; UNITED-KINGDOM; POLYCHLORINATED-BIPHENYLS; CONSUMER PRODUCTS; AIR; PBDES; VARIABILITY AB Although the presence of polybrominated diphenyl ethers (PBDEs) in house dust has been linked to consumer products, the mechanism of transfer remains poorly understood. We conjecture that volatilized PBDEs will be associated with dust particles containing organic matter and will be homogeneously distributed in house dust. In contrast, PBDEs arising from weathering or abrasion of polymers should remain bound to particles of the original polymer matrix and will be heterogeneously distributed within the dust. We used scanning electron microscopy and other tools of environmental forensic microscopy to investigate PBDEs in dust, examining U.S. and U.K. dust samples with extremely high levels of BDE 209 (260-2600 mu g/g), a nonvolatile compound at room temperature. We found that the bromine in these samples was concentrated in widely scattered, highly contaminated particles. In the house dust samples from Boston (U.S.), bromine was associated with a polymer/organic matrix. These results suggest that the BDE 209 was transferred to dust via physical processes such as abrasion or weathering. In conjunction with more traditional tools of environmental chemistry, such as gas chromatography/mass spectrometry (GC/MS), environmental forensic microscopy provides novel insights into the origins of BDE 209 in dust and their mechanisms of transfer from products. C1 [Webster, Thomas F.; Mcclean, Michael D.] Boston Univ, Sch Publ Hlth, Dept Environm Hlth, Boston, MA 02118 USA. [Harrad, Stuart; Ibarra, Catalina; Abdallah, Mohamed Abou-Elwafa] Univ Birmingham, Div Environm Hlth & Risk Management, Birmingham B15 2TT, W Midlands, England. [Millette, James R.] MVA Sci Consultants, Duluth, GA 30096 USA. [Holbrook, R. David; Davis, Jeffrey M.] NIST, Sinface & Microanal Sci Div, Gaithersburg, MD 20899 USA. [Stapleton, Heather M.] Duke Univ, Nicholas Sch Environm, Durham, NC 27708 USA. [Allen, Joseph G.] Environm Hlth & Engn Inc, Needham, MA 02494 USA. [Abdallah, Mohamed Abou-Elwafa] Assiut Univ, Fac Pharm, Dept Analyt Chem, Assiut 71526, Egypt. [Covaci, Adrian] Univ Antwerp, Toxicol Ctr, B-2610 Antwerp, Belgium. RP Webster, TF (reprint author), Boston Univ, Sch Publ Hlth, Dept Environm Hlth, Boston, MA 02118 USA. EM twebster@bu.edu RI Covaci, Adrian/A-9058-2008; McClean, Michael/J-2934-2015; Abou-Elwafa Abdallah, Mohamed/P-8813-2014; OI Covaci, Adrian/0000-0003-0527-1136; Abou-Elwafa Abdallah, Mohamed/0000-0002-4624-4073; McClean, Michael/0000-0002-3902-8823; Harrad, Stuart/0000-0003-4650-0564 FU Boston University Center for Interdisciplinary Research in Environmental Exposures (CIREEH); National Institute of Environmental Health Sciences [R01ES015829]; Research Scientific Foundation-Flanders (FWO), Belgium; National Council of Science and Technology-Mexico (CONACYT); Egyptian government; Egyptian ministry Of higher education FX Pilot funding was provided by the Boston University Center for Interdisciplinary Research in Environmental Exposures (CIREEH). Drs. Webster and McClean are partly Supported by R01ES015829 from the National Institute of Environmental Health Sciences. The content is solely the responsibility of the authors and does not necessarily represent the official views of the National Institute of Environmental Health Sciences or the National Institutes of Health. Adrian Covaci was financially Supported through a postdoctoral fellowship from the Research Scientific Foundation-Flanders (FWO), Belgium. Catalina Ibarra and Mohamed Abdallah gratefully acknowledge the provision Of studentships from the National Council of Science and Technology-Mexico (CONACYT) (CI), and from the Egyptian government and Egyptian ministry Of higher education (MAA). We also thank Paul Stanley from the University of Birmingham's Centre for Electron Microscopy for technical assistance with ESEM analysis. Disclaimer: Certain commercial equipment, instruments, or materials are identified in this paper to specify adequately the experimental procedure. Such identification does not imply recommendation or endorsement by the National Institute of Standards and Technology (Gaithersburg, Maryland), nor does it imply that the materials or equipment identified are necessarily the best available for the purpose. NR 25 TC 109 Z9 110 U1 5 U2 52 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0013-936X J9 ENVIRON SCI TECHNOL JI Environ. Sci. Technol. PD MAY 1 PY 2009 VL 43 IS 9 BP 3067 EP 3072 DI 10.1021/es803139w PG 6 WC Engineering, Environmental; Environmental Sciences SC Engineering; Environmental Sciences & Ecology GA 441PL UT WOS:000265781100019 PM 19534115 ER PT J AU Dong, YL Zhu, EC Prasad, K AF Dong, Y. L. Zhu, E. C. Prasad, K. TI Thermal and structural response of two-storey two-bay composite steel frames under furnace loading SO FIRE SAFETY JOURNAL LA English DT Article DE Composite steel frame; Test; Thermal load; Furnace heating; Structural failure ID FIRE; BEHAVIOR AB The collapse of the World Trade Center Towers and other recent fires in tall buildings has motivated this study to understand the performance of structural frames under fire loading. Three two-storey, two-bay composite steel frames were constructed and subjected to dead loads by applying weight blocks, and to thermal load by placing the frame in a furnace. The furnace was specially designed to allow for controlled heating of the structural elements that formed the four compartments of the test frame. This paper describes the experimental results of furnace test conducted on the three full-scale composite frames. The three tests differed from each other in the number and location of compartments that were heated by the furnace. For each test, the structural elements were subjected to a heating-up phase followed by a cooling-down phase. The furnace temperatures and the steel and concrete temperatures recorded during the test are presented. The thermally induced horizontal displacements of the columns and vertical deflections of the composite beams are discussed. Observations on local buckling of the steel beam, cracking of the concrete slab and failure of the beam-to-column connections are tabulated. Experimental results of the three tests are compared with each other by studying the complete deformation process of the test frames over time. Results indicate that the deformation process of the test frames was highly dependent on the number and location of compartments that were subjected to thermal loading. (c) 2008 Elsevier Ltd. All rights reserved. C1 [Dong, Y. L.; Zhu, E. C.] Harbin Inst Technol, Sch Civil Engn, Harbin 150090, Peoples R China. [Prasad, K.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Dong, YL (reprint author), Harbin Inst Technol, Sch Civil Engn, POB 2554,202 Haihe Rd, Harbin 150090, Peoples R China. EM DongYL@hit.edu.cn FU National Basic Research Program 973 of China NKBRSF [2001CB409600]; Natural Science Foundation of China [50578078] FX The authors acknowledge with gratitude the sponsorships of this study from the National Basic Research Program 973 of China NKBRSF, project designated as 2001CB409600, and from the Natural Science Foundation of China, project designated as 50578078. NR 17 TC 9 Z9 10 U1 0 U2 9 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0379-7112 J9 FIRE SAFETY J JI Fire Saf. J. PD MAY PY 2009 VL 44 IS 4 BP 439 EP 450 DI 10.1016/j.firesaf.2008.09.005 PG 12 WC Engineering, Civil; Materials Science, Multidisciplinary SC Engineering; Materials Science GA 440YS UT WOS:000265736200001 ER PT J AU Kuligowski, ED Mileti, DS AF Kuligowski, Erica D. Mileti, Dennis S. TI Modeling pre-evacuation delay by occupants in World Trade Center Towers 1 and 2 on September 11, 2001 SO FIRE SAFETY JOURNAL LA English DT Review DE Evacuation; Path analysis; World Trade Center; Human behavior ID EVACUATION; RISK; COMMUNICATION; BEHAVIOR; PREPAREDNESS; WARNINGS; DISASTER; THREAT; EVENT; FIRE AB On September 11, 2001, two airplanes hit World Trade Center (WTC) I and 2 sixteen minutes apart, which forced one of the largest evacuations from high-rise buildings in US history. Path analysis is used to analyze telephone data obtained from WTC survivors to empirically determine if the theories from community evacuation hold true for building fires. Results show that community evacuation theories do hold true for building fires: specifically in WTC 1 and 2. In general, longer pre-evacuation times were predicted by witnessing a higher number of environmental cues, being on a lower floor in the building, obtaining more information, seeking additional information, and performing a higher number of pre-evacuation actions. A deeper understanding of human behavior in fire events can be gained by using path analysis techniques. which can ultimately improve evacuation education, training, and procedures for high-rise buildings across the world as well as future evacuation prediction techniques. Published by Elsevier Ltd. C1 [Kuligowski, Erica D.] NIST, Gaithersburg, MD 20899 USA. [Kuligowski, Erica D.; Mileti, Dennis S.] Univ Colorado, Boulder, CO 80309 USA. RP Kuligowski, ED (reprint author), NIST, 100 Bur Dr,Mailstop 8664, Gaithersburg, MD 20899 USA. EM erica.kuligowski@nist.gov FU US Congress to the National Institute for Standards and Technology (NIST); United States Department of Homeland Security through the National Consortium for the Study of Terrorism and Responses to Terrorism (START) [N00140510629] FX This research was supported with funds from the US Congress to the National Institute for Standards and Technology (NIST). Supplemental funding to work on this manuscript was provided by the United States Department of Homeland Security through the National Consortium for the Study of Terrorism and Responses to Terrorism (START), Grant no. N00140510629. However, any opinions, findings, and conclusions or recommendations in this document are those of the authors and do not necessarily reflect the views of the National Institute of Standards and Technology or the US Department of Homeland Security. The authors wish to thank Heather Contrino, Nancy McGuckin, Rob Santos, and Johanna Zmud with NuStats for their data collection and analysis assistance: and Jason Averill, Thomas Cleary, William Grosshandler, and Steve Gwynne for their comments on an earlier version of this manuscript. NR 101 TC 16 Z9 18 U1 1 U2 12 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0379-7112 J9 FIRE SAFETY J JI Fire Saf. J. PD MAY PY 2009 VL 44 IS 4 BP 487 EP 496 DI 10.1016/j.firesaf.2008.10.001 PG 10 WC Engineering, Civil; Materials Science, Multidisciplinary SC Engineering; Materials Science GA 440YS UT WOS:000265736200006 ER PT J AU Berkson, J Hunt, KM Whitehead, JC Murie, DJ Kwak, TJ Boreman, J AF Berkson, J. Hunt, K. M. Whitehead, J. C. Murie, D. J. Kwak, T. J. Boreman, J. TI Is There a Shortage of Fisheries Stock Assessment Scientists? SO FISHERIES LA English DT Editorial Material C1 [Berkson, J.] Virginia Tech, Natl Marine Fisheries Serv, SE Fisheries Sci Ctr, RTR Unit, Blacksburg, VA 24061 USA. [Hunt, K. M.] Mississippi State Univ, Dept Wildlife & Fisheries, Forest & Wildlife Res Ctr, Human Dimens & Conservat Law Enforcement Lab, Starkville, MS USA. [Whitehead, J. C.] Appalachian State Univ, Dept Econ, Boone, NC 28608 USA. [Murie, D. J.] Univ Florida, Sch Forest Resources & Conservat, Program Fisheries & Aquat Sci, Gainesville, FL 32611 USA. [Kwak, T. J.] N Carolina State Univ, Dept Biol, N Carolina Cooperat Fish & Wildlife Res Unit, US Geol Survey, Raleigh, NC 27695 USA. [Boreman, J.] Univ Massachusetts, Sch Marine Sci & Technol, New Bedford, MA USA. RP Berkson, J (reprint author), Virginia Tech, Natl Marine Fisheries Serv, SE Fisheries Sci Ctr, RTR Unit, Blacksburg, VA 24061 USA. EM Jim.Berkson@NOAA.gov NR 4 TC 3 Z9 3 U1 0 U2 1 PU AMER FISHERIES SOC PI BETHESDA PA 5410 GROSVENOR LANE SUITE 110, BETHESDA, MD 20814-2199 USA SN 0363-2415 J9 FISHERIES JI Fisheries PD MAY PY 2009 VL 34 IS 5 BP 217 EP 219 DI 10.1577/1548-8446-34.5.217 PG 3 WC Fisheries SC Fisheries GA 477ND UT WOS:000268524900002 ER PT J AU Berkson, J Hudy, SF McMullin, SL Murphy, BR Prager, MH Kelly, MJ Thompson, NB AF Berkson, J. Hudy, S. F. McMullin, S. L. Murphy, B. R. Prager, M. H. Kelly, M. J. Thompson, N. B. TI Addressing the Shortage of Stock Assessment Scientists through Undergraduate Workshops SO FISHERIES LA English DT Article AB A recent Congressional report identified a shortage of scientists entering the discipline of stock assessment. The Southeast Fisheries Science Center of NOAA's National Marine Fisheries Service and Virginia Tech created the Population Dynamics Recruiting Program (PDRP) to improve the quality of graduate students interested in entering the field. An annual week-tong workshop identifies top Students nationally with the potential to excel in Population dynamics and educates them about the discipline. Program evaluation indicates that between 25% and 33% of workshop participants have subsequently entered graduate school in the field. Sixty-nine percent of those Students knew little about the field before the workshop, and 85% reported wanting to pursue population dynamics because of their workshop experience. Continuing and strengthening the PDRP is an important component of a strategy to reduce the shortage of qualified stock assessment scientists. C1 [Berkson, J.] Virginia Tech, RTR Unit, SE Fisheries Sci Ctr, Natl Marine Fisheries Serv, Blacksburg, VA 24061 USA. [Hudy, S. F.; McMullin, S. L.; Murphy, B. R.; Kelly, M. J.] Virginia Tech, Dept Fisheries & Wildlife Sci, Blacksburg, VA USA. RP Berkson, J (reprint author), Virginia Tech, RTR Unit, SE Fisheries Sci Ctr, Natl Marine Fisheries Serv, Blacksburg, VA 24061 USA. EM Jim.Berkson@NOAA.gov RI Kelly, Marcella/B-4891-2011 NR 9 TC 1 Z9 1 U1 0 U2 2 PU AMER FISHERIES SOC PI BETHESDA PA 5410 GROSVENOR LANE SUITE 110, BETHESDA, MD 20814-2199 USA SN 0363-2415 J9 FISHERIES JI Fisheries PD MAY PY 2009 VL 34 IS 5 BP 220 EP 227 DI 10.1577/1548-8446-34.5.220 PG 8 WC Fisheries SC Fisheries GA 477ND UT WOS:000268524900003 ER PT J AU Palumbi, SR Sandifer, PA Allan, JD Beck, MW Fautin, DG Fogarty, MJ Halpern, BS Incze, LS Leong, JA Norse, E Stachowicz, JJ Wall, DH AF Palumbi, Stephen R. Sandifer, Paul A. Allan, J. David Beck, Michael W. Fautin, Daphne G. Fogarty, Michael J. Halpern, Benjamin S. Incze, Lewis S. Leong, Jo-Ann Norse, Elliott Stachowicz, John J. Wall, Diana H. TI Managing for ocean biodiversity to sustain marine ecosystem services SO FRONTIERS IN ECOLOGY AND THE ENVIRONMENT LA English DT Review ID DIVERSITY; ECOLOGY; MANAGEMENT; RESISTANCE; ENVIRONMENT; RESILIENCE; EVOLUTION; RECOVERY; WATER AB Managing a complex ecosystem to balance delivery of all of its services is at the heart of ecosystem-based management. But how can this balance be accomplished amidst the conflicting demands of stakeholders, managers, and policy makers? In marine ecosystems, several common ecological mechanisms link biodiversity to ecosystem functioning and to a complex of essential services. As a result, the effects of preserving diversity can be broadly beneficial to a wide spectrum of important ecosystem processes and services, including fisheries, water quality, recreation, and shoreline protection. A management system that conserves diversity will help to accrue more "ecoservice capital" for human use and will maintain a hedge against unanticipated ecosystem changes from natural or anthropogenic causes. Although maintenance of biodiversity cannot be the only goal for ecosystem-based management, it could provide a common currency for evaluating the impacts of different human activities on ecosystem functioning and can act as a critical indicator of ecosystem status. C1 [Palumbi, Stephen R.] Stanford Univ, Hopkins Marine Stn, Dept Biol, Pacific Grove, CA 93950 USA. [Sandifer, Paul A.] NOAA, Hollings Marine Lab, Charleston, SC USA. [Allan, J. David] Univ Michigan, Sch Nat Resources & Environm, Ann Arbor, MI 48109 USA. [Beck, Michael W.] Univ Calif Santa Cruz, Nat Conservancy, Santa Cruz, CA 95064 USA. [Fautin, Daphne G.] Univ Kansas, Div Biol Sci, Lawrence, KS 66045 USA. [Fogarty, Michael J.] NOAA, NE Fisheries Sci Ctr, Woods Hole, MA USA. [Halpern, Benjamin S.] Natl Ctr Ecol Anal & Synth, Santa Barbara, CA USA. [Incze, Lewis S.] Univ So Maine, Aquat Syst Grp, Portland, ME 04103 USA. [Leong, Jo-Ann] Univ Hawaii, Hawaii Inst Marine Biol, Kaneohe, HI USA. [Norse, Elliott] Marine Conservat Biol Inst, Bellevue, WA USA. [Stachowicz, John J.] Univ Calif Davis, Dept Ecol & Evolut, Davis, CA 95616 USA. [Wall, Diana H.] Colorado State Univ, Dept Biol, Ft Collins, CO 80523 USA. [Wall, Diana H.] Colorado State Univ, Nat Resource Ecol Lab, Ft Collins, CO 80523 USA. RP Palumbi, SR (reprint author), Stanford Univ, Hopkins Marine Stn, Dept Biol, Pacific Grove, CA 93950 USA. EM spalumbi@stanford.edu RI Wall, Diana/F-5491-2011 FU US National Committee for the Census of Marine Life; NOAA's Oceans and Human Health Initiative; Hollings Marine Laboratory, National Marine Fisheries Service; Office of Ocean Exploration and from the US Department of Energy; Alfred P Sloan Foundation; David and Lucile Packard Foundation; Betty and Gordon Moore Foundation FX This paper is based in part on ideas discussed at a workshop, Approaches for researching the roles of marine and coastal biodiversity in maintaining ecosystem services, sponsored by the US National Committee for the Census of Marine Life (September 11-13, 2006, in Washington, DC). Helpful comments from H Galindo, F Holland, T Hourigan, F Micheli, M Pinsky, A Rosenberg, M Vecchione, and C Woodley improved the manuscript. We gratefully acknowledge financial support from NOAA's Oceans and Human Health Initiative, Hollings Marine Laboratory, National Marine Fisheries Service, and Office of Ocean Exploration and from the US Department of Energy, the Alfred P Sloan Foundation, the David and Lucile Packard Foundation, and the Betty and Gordon Moore Foundation. NR 47 TC 78 Z9 80 U1 8 U2 89 PU ECOLOGICAL SOC AMER PI WASHINGTON PA 1990 M STREET NW, STE 700, WASHINGTON, DC 20036 USA SN 1540-9295 J9 FRONT ECOL ENVIRON JI Front. Ecol. Environ. PD MAY PY 2009 VL 7 IS 4 BP 204 EP 211 DI 10.1890/070135 PG 8 WC Ecology; Environmental Sciences SC Environmental Sciences & Ecology GA 444HK UT WOS:000265971200020 ER PT J AU Jiang, L Islam, S Guo, W Jutla, AS Senarath, SUS Ramsay, BH Eltahir, EAB AF Jiang, Le Islam, Shafiqul Guo, Wei Jutla, Antarpreet Singh Senarath, Sharika U. S. Ramsay, Bruce H. Eltahir, Elfatih A. B. TI A satellite-based Daily Actual Evapotranspiration estimation algorithm over South Florida SO GLOBAL AND PLANETARY CHANGE LA English DT Article; Proceedings Paper CT Fall Annual Meeting of the American-Geophysical-Union CY 2005 CL San Francisco, CA SP Amer Geophys Union DE remote sensing; evapotranspiration; AVHRR; Priestley-Taylor; Evaporative Fraction ID REMOTE-SENSING DATA; CLEAR-SKY DAYS; GREAT-PLAINS; HEAT-FLUX; VEGETATION; MODIS; PARAMETERS; SENSORS; INDEX; AREAS AB Water resources and agricultural applications require the knowledge of evapotranspiration (ET) over a range of spatial and temporal scales. Due to paucity of surface based hydro-meteorological stations, the spatial resolution of ET estimates is fairly coarse and is not particularly suitable or reliable for hydrologic modeling, water resources planning and decision making. An ET estimation algorithm has been developed by combining data from satellite and ground observations. The method extends the applicability of a commonly used energy balance formulation of ET and utilizes the contextual relationship between remotely sensed surface temperature and vegetation index. The required parameters are derived from the Advanced Very High Resolution Radiometer (AVHRR) aboard NOAA-14 satellite. First, the Evaporative Fraction (EF) is estimated by utilizing the relationship between a vegetation index and radiometric surface temperature observed from AVHRR for each day. Then spatio-temporal interpolation and filtering techniques are applied to obtain daily EF values for cloudy pixels to produce the EF map for the entire region. Daily Actual ET (DAET) maps are derived from these EF maps and net radiation maps obtained from ground-based observations. The comparisons between satellite derived DAFT and ground measurements showed overall low bias and root-mean-square-error for both clear and cloudy days at South Florida in 1998 and 1999. The proposed satellite-based DAFT (SatDAET) algorithm has its EF component primarily estimated from satellite data and the resulting DAET has been validated using multi-year ground observations over the South Florida region. The SatDAET algorithm appears to be robust and has the potential to provide near real-time land surface evapotranspiration monitoring over large heterogeneous areas at a very fine spatial and temporal resolution. (C) 2009 Elsevier B.V. All rights reserved. C1 [Islam, Shafiqul; Jutla, Antarpreet Singh] Tufts Univ, Dept Civil & Environm Engn, Medford, MA 02155 USA. [Jiang, Le; Guo, Wei] NOAA Sci Ctr, IMSG, NOAA NESDIS, Camp Springs, MD 20746 USA. [Ramsay, Bruce H.] NOAH Sci Ctr, NOAA NESDIS ORA, Camp Springs, MD 20746 USA. [Eltahir, Elfatih A. B.] MIT, Dept Civil & Environm Engn, Cambridge, MA 02139 USA. RP Islam, S (reprint author), Tufts Univ, Dept Civil & Environm Engn, 113 Anderson Hall,200 Coll Ave, Medford, MA 02155 USA. EM Shafiqul.Islam@tufts.edu RI Jutla, Antarpreet/E-8881-2010; Jutla, Antarpreet/A-9407-2010; Guo, Wei/E-7934-2011 OI Guo, Wei/0000-0003-3253-9441 NR 23 TC 48 Z9 56 U1 2 U2 12 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0921-8181 J9 GLOBAL PLANET CHANGE JI Glob. Planet. Change PD MAY PY 2009 VL 67 IS 1-2 BP 62 EP 77 DI 10.1016/j.gloplacha.2008.12.008 PG 16 WC Geography, Physical; Geosciences, Multidisciplinary SC Physical Geography; Geology GA 455JC UT WOS:000266754000008 ER PT J AU Gaumont-Guay, D Black, TA McCaughey, H Barr, AG Krishnan, P Jassal, RS Nesic, Z AF Gaumont-Guay, David Black, T. Andrew McCaughey, Harry Barr, Alan G. Krishnan, Praveena Jassal, Rachhpal S. Nesic, Zoran TI Soil CO2 efflux in contrasting boreal deciduous and coniferous stands and its contribution to the ecosystem carbon balance SO GLOBAL CHANGE BIOLOGY LA English DT Article DE carbon balance; drought; ecosystem respiration; gross ecosystem photosynthesis; gross forest-floor photosynthesis; Picea mariana; Pinus banksiana; Populus tremuloides; soil CO2 efflux; soil respiration ID DOUGLAS-FIR FOREST; LEAF-AREA INDEX; BLACK SPRUCE; ASPEN FOREST; CHAMBER MEASUREMENTS; SPATIAL VARIABILITY; DOMINATED FOREST; EDDY COVARIANCE; PINE PLANTATION; WATER-CONTENT AB Similar nonsteady-state automated chamber systems were used to measure and partition soil CO2 efflux in contrasting deciduous (trembling aspen) and coniferous (black spruce and jack pine) stands located within 100 km of each other near the southern edge of the Boreal forest in Canada. The stands were exposed to similar climate forcing in 2003, including marked seasonal variations in soil water availability, which provided a unique opportunity to investigate the influence of climate and stand characteristics on soil CO2 efflux and to quantify its contribution to the net ecosystem CO2 exchange (NEE) as measured with the eddy-covariance technique. Partitioning of soil CO2 efflux between soil respiration (including forest-floor vegetation) and forest-floor photosynthesis showed that short- and long-term temporal variations of soil CO2 efflux were related to the influence of (1) soil temperature and water content on soil respiration and (2) below-canopy light availability, plant water status and forest-floor plant species composition on forest-floor photosynthesis. Overall, the three stands were weak to moderate sinks for CO2 in 2003 (NEE of -103, -80 and -28 g C m(-2) yr(-1) for aspen, black spruce and jack pine, respectively). Forest-floor respiration accounted for 86%, 73% and 75% of annual ecosystem respiration, in the three respective stands, while forest-floor photosynthesis contributed to 11% and 14% of annual gross ecosystem photosynthesis in the black spruce and jack pine stands, respectively. The results emphasize the need to perform concomitant measurements of NEE and soil CO2 efflux at longer time scales in different ecosystems in order to better understand the impacts of future interannual climate variability and vegetation dynamics associated with climate change on each component of the carbon balance. C1 [Gaumont-Guay, David] Vancouver Isl Univ, Dept Biol, Vancouver, BC, Canada. [Black, T. Andrew; Jassal, Rachhpal S.; Nesic, Zoran] Univ British Columbia, Biometeorol & Soil Phys Grp, Vancouver, BC V5Z 1M9, Canada. [McCaughey, Harry] Queens Univ, Dept Geog, Kingston, ON K7L 3N6, Canada. [Krishnan, Praveena] Natl Ocean & Atmospher Adm, Atmospher Turbulence & Diffus Div, Oak Ridge, TN USA. RP Gaumont-Guay, D (reprint author), Vancouver Isl Univ, Dept Biol, Vancouver, BC, Canada. EM david.gaumont-guay@viu.ca RI Krishnan, Praveena/F-8169-2010; Barr, Alan/H-9939-2014; Nesic, Zoran/C-9655-2015 FU Fonds de Recherche sur la nature et les Technologies du QuEbec (FCAR); DGG and the Natural Sciences and Engineering Research Council of Canada (NSERC); Fluxnet Canada Research Network; NSERC, the Canadian Foundation for Climate and Atmospheric Sciences (CFCAS) and BIOCAP Canada; Meteorological Service of Canada; University of British Columbia FX This research was funded by the Fonds de Recherche sur la nature et les Technologies du QuEbec (FCAR) in the form of a 3-year graduate scholarship to DGG and the Natural Sciences and Engineering Research Council of Canada (NSERC) through an operating grant to TAB. Additional support was provided by the Fluxnet Canada Research Network [through NSERC, the Canadian Foundation for Climate and Atmospheric Sciences (CFCAS) and BIOCAP Canada] and the Meteorological Service of Canada through a Contribution Agreement to the University of British Columbia. The authors sincerely acknowledge the technical assistance of Andrew Sauter for the development of the automated chamber systems and the support from Werner Bauer and Dave Wieder for installing and maintaining the equipment in the field. NR 65 TC 25 Z9 32 U1 3 U2 42 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1354-1013 EI 1365-2486 J9 GLOBAL CHANGE BIOL JI Glob. Change Biol. PD MAY PY 2009 VL 15 IS 5 BP 1302 EP 1319 DI 10.1111/j.1365-2486.2008.01830.x PG 18 WC Biodiversity Conservation; Ecology; Environmental Sciences SC Biodiversity & Conservation; Environmental Sciences & Ecology GA 431AM UT WOS:000265033700018 ER PT J AU MacNeil, MA Carlson, JK Beerkircher, LR AF MacNeil, M. Aaron Carlson, John K. Beerkircher, Lawrence R. TI Shark depredation rates in pelagic longline fisheries: a case study from the Northwest Atlantic SO ICES JOURNAL OF MARINE SCIENCE LA English DT Article DE bycatch; fisheries; zero-inflated models ID ZERO-INFLATED POISSON; BINOMIAL REGRESSION; CATCH RATES; BYCATCH; MODELS; DEPTH; SWORDFISH; ABUNDANCE; GEAR; SEA AB A suite of modelling approaches was employed to analyse shark depredation rates from the US Atlantic pelagic longline fishery. As depredation events are relatively rare, there are a large number of zeroes in pelagic longline data and conventional generalized linear models (GLM5) may be ineffective as tools for statistical inference. GLMs (Poisson and negative binomial), two-part (delta-lognormal and truncated negative binomial, T-NB), and mixture models (zero-inflated Poisson, ZIP, and zero-inflated negative binomial, ZINB) were used to understand the factors that contributed most to the occurrence of depredation events that included a small proportion of whale damage. Of the six distribution forms used, only the ZIP and T-NB models performed adequately in describing depredation data, and the T-NB and ZINB models outperformed the ZIP models in bootstrap cross-validation estimates of prediction error. Candidate T-NB and ZINB model results showed that encounter probabilities were more strongly related to large-scale covariates (space, season) and that depredation counts were correlated with small-scale characteristics of the fishery (temperature, catch composition). Moreover, there was little evidence of historical trends in depredation rates. The results show that the factors contributing to most depredation events are those already controlled by ships' captains and, beyond novel technologies to repel sharks, there may be little more to do to reduce depredation loss in the fishery within current economic and operational constraints. C1 [MacNeil, M. Aaron] CNR, Panama City Lab, Panama City Beach, FL 32408 USA. [Carlson, John K.] NOAA, Natl Marine Fisheries Serv, Panama City Lab, Panama City Beach, FL 32408 USA. [Beerkircher, Lawrence R.] NOAA, Natl Marine Fisheries Serv, SE Fisheries Sci Ctr, Miami, FL 33149 USA. RP MacNeil, MA (reprint author), Australian Inst Marine Sci, PMB 3, Townsville, Qld 4810, Australia. EM macneil@glau.ca RI MacNeil, M Aaron/F-4680-2010; MacNeil, M. Aaron/E-8196-2017 OI MacNeil, M. Aaron/0000-0001-8406-325X FU National Research Council, USA FX We thank S. Gulak for informative discussions about observers and boat characteristics in pelagic longline fisheries, and K. Andrews for reviewing a previous draft of the manuscript. Special thanks are also due to A. Payne, P. Ward, and an anonymous reviewer for greatly improving the quality of the manuscript we submitted. The research was supported by funding from the National Research Council, USA. NR 39 TC 9 Z9 13 U1 1 U2 16 PU OXFORD UNIV PRESS PI OXFORD PA GREAT CLARENDON ST, OXFORD OX2 6DP, ENGLAND SN 1054-3139 J9 ICES J MAR SCI JI ICES J. Mar. Sci. PD MAY PY 2009 VL 66 IS 4 BP 708 EP 719 DI 10.1093/icesjms/fsp022 PG 12 WC Fisheries; Marine & Freshwater Biology; Oceanography SC Fisheries; Marine & Freshwater Biology; Oceanography GA 431WX UT WOS:000265096600011 ER PT J AU Churnside, JH Donaghay, PL AF Churnside, James H. Donaghay, Percy L. TI Thin scattering layers observed by airborne lidar SO ICES JOURNAL OF MARINE SCIENCE LA English DT Article DE internal waves; lidar; plankton layers; thin layers; upwelling ID ANOXIC ESTUARINE BASIN; PHYSICAL PROCESSES; FISH SCHOOLS; PHYTOPLANKTON; ZOOPLANKTON; PYCNOCLINE; PLANKTON; METHANE; BLOOM; OCEAN AB More than 2000 km of thin (<3 m) optical scattering layers were identified in 80 000 km of airborne lidar data collected from a variety of oceanic and coastal waters. The spatial characteristics of thin layers varied dramatically from (i) those that were self-contained features consistently <3-4 m thick over their 1-12 km extent to (ii) those that were clearly parts of much longer layers that had gaps and/or regions where the layer became more intense and much thicker than the 3-m criterion. The characteristics of the lidar signal suggest that plankton was the most likely source of scattering. Examples from upwelling regions, areas with large freshwater influx, and warm-core eddies are presented. The results are quite consistent with the characteristics observed in studies of thin plankton layers in fjords and near-coastal waters. These layers exhibit great spatial variability that is difficult to observe using traditional methods, and examples of layer perturbations by both linear and non-linear internal waves are presented. The results suggest that airborne lidar can be a powerful tool not only for detecting and mapping the spatial extent of thin scattering layers and linking their occurrence to larger scale physical processes, but also for tracking their evolution over time and guiding the ship-based sampling needed to understand their composition, dynamics, and impacts. Such a capability will be crucial in future studies designed to test the hypothesis that thin plankton layers have the spatial extent and intensity to play a key role in controlling the recruitment of fish larvae, biogeochemical cycling, trophic transfer processes, plankton biodiversity, and harmful algal bloom dynamics C1 [Churnside, James H.] NOAA, Earth Syst Res Lab, Boulder, CO 80305 USA. [Donaghay, Percy L.] Univ Rhode Isl, Grad Sch Oceanog, Narragansett, RI 02874 USA. RP Churnside, JH (reprint author), NOAA, Earth Syst Res Lab, 325 Broadway, Boulder, CO 80305 USA. EM james.h.churnside@noaa.gov RI Churnside, James/H-4873-2013; Manager, CSD Publications/B-2789-2015 FU Office of Naval Research Optics and Biology Program [N0001404IP20075, N000140410276] FX This analysis was partially supported by the Office of Naval Research Optics and Biology Program under Award Numbers N0001404IP20075 (JHC) and N000140410276 (PLD). The 2003 CTD data from the NE Pacific were provided by Dave Griffith of the NOAA Southwest Fisheries Science Center, the 2001 and 2002 CTD data from the area around Kodiak Island by Mike Guttormsen of the NOAA Alaska Fisheries Science Center, and the CTD data from the Norwegian Sea by Eirik Tenningen of the Norwegian Institute of Marine Research. Bill Pichel of the NOAA National Environmental Satellite and Information Service provided the satellite altimeter map. Jim Wilson of ESRL was the chief engineer for Fish Lidar during the entire period covered in this paper. Funding to pay the Open Access publication charges for this article was provided by the NOAA Science and Technology Infusion Program. NR 51 TC 42 Z9 42 U1 1 U2 17 PU OXFORD UNIV PRESS PI OXFORD PA GREAT CLARENDON ST, OXFORD OX2 6DP, ENGLAND SN 1054-3139 J9 ICES J MAR SCI JI ICES J. Mar. Sci. PD MAY PY 2009 VL 66 IS 4 BP 778 EP 789 DI 10.1093/icesjms/fsp029 PG 12 WC Fisheries; Marine & Freshwater Biology; Oceanography SC Fisheries; Marine & Freshwater Biology; Oceanography GA 431WX UT WOS:000265096600018 ER PT J AU Xu, F Jin, YQ AF Xu, Feng Jin, Ya-Qiu TI Bidirectional Analytic Ray Tracing for Fast Computation of Composite Scattering From Electric-Large Target Over a Randomly Rough Surface SO IEEE TRANSACTIONS ON ANTENNAS AND PROPAGATION LA English DT Article DE Bidirectional analytic ray tracing (BART); radar cross section (RCS) prediction; target and rough surface ID ELECTROMAGNETIC SCATTERING; POLARIMETRIC SAR; COMPLEX TARGETS; RCS; ALGORITHM; REDUCTION; CURRENTS; OBJECTS AB The bidirectional analytic ray tracing (BART) method is developed to rapidly calculate composite scattering from three-dimensional (3D) electrically large complex targets above a randomly rough surface. Ray tracing is carried out both along the incident (forward) direction and converse direction of scattering (backward) recording different orders of ray illumination on each facet or edge of the target and surface. Once a pair of forward and backward rays meet on a facet/edge, a scattering term is constructed using the diffused scattering/diffraction of this facet/edge and all reflections occurred on the tracing paths. The rough surface is modeled with "rough facets" including coherent scattering and diffused incoherent scattering, which can be directly calculated according to the IEM (integral equation method) of a randomly rough surface. Analytic tracing of polygon ray tubes is developed to precisely calculate the illumination and shadowing of facets, which exempt large patches of the target from any finer meshing. It significantly reduces the complexity relevant to the target electric-size. Higher orders of scattering and, in particular, interactions between the target and rough surface are then taken into account. The accuracy and performance of BART is validated and evaluated by comparing with exact computational electromagnetic methods for electrically small targets. Numerical examples of angularly composite scattering from a three-dimensional electrically large, e.g., a ship-like target over a randomly rough surface are presented and discussed. C1 [Xu, Feng] NOAA, Natl Environm Satellite Data & Informat Serv, Camp Springs, MD 20746 USA. [Jin, Ya-Qiu] Fudan Univ, Sch Informat Sci & Engn, Shanghai 200433, Peoples R China. [Jin, Ya-Qiu] Fudan Univ, Minist Educ, Key Lab Wave Scattering & Remote Sensing Informat, Shanghai 200433, Peoples R China. RP Xu, F (reprint author), NOAA, Natl Environm Satellite Data & Informat Serv, Camp Springs, MD 20746 USA. EM yqjin@fudan.ac.cn RI XU, Feng/A-4582-2010 OI XU, Feng/0000-0002-7015-1467 FU NSFC [40637033, 60571050]; SUMMA FX This work was supported by the NSFC under Grants 40637033, 60571050. The work of F. Xu was supported by a SUMMA Graduate Fellowship. NR 30 TC 50 Z9 62 U1 1 U2 6 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 0018-926X J9 IEEE T ANTENN PROPAG JI IEEE Trans. Antennas Propag. PD MAY PY 2009 VL 57 IS 5 BP 1495 EP 1505 DI 10.1109/TAP.2009.2016691 PG 11 WC Engineering, Electrical & Electronic; Telecommunications SC Engineering; Telecommunications GA 443UX UT WOS:000265937400022 ER PT J AU Holloway, CL Kuester, EF AF Holloway, Christopher L. Kuester, Edward F. TI DC Internal Inductance for a Conductor of Rectangular Cross Section SO IEEE TRANSACTIONS ON ELECTROMAGNETIC COMPATIBILITY LA English DT Article DE DC internal inductance; interconnect; printed circuit broads (PCB); rectangular conductor; signal integrity; transmission lines ID LOSSY TRANSMISSION-LINES; TRANSIENT ANALYSIS; SIMULATION; APPROXIMATION; MODEL AB In this paper, the dc internal inductance for conductors with rectangular cross section is investigated. Using a quasistatic Green's function, the magnetic fields inside a rectangular conductor are derived. These magnetic field expressions are used to formulate the internal inductance of the conductor. We present numerical results and closed-form expressions for the dc internal inductance for this geometry. Comparisons to various expressions found in the literature are made, and the inaccuracies of these other results are presented and discussed. Finally, we discuss some of the subtleties associated with the inductance of a single current path, in which we examine why the total and external inductances of a single infinitely long conductor have no physical meaning, whereas the internal inductance does. C1 [Holloway, Christopher L.] Natl Inst Stand & Technol, Electromagnet Div, US Dept Commerce, Boulder Labs, Boulder, CO 80305 USA. [Kuester, Edward F.] Univ Colorado, Dept Elect & Comp Engn, Boulder, CO 80309 USA. RP Holloway, CL (reprint author), Natl Inst Stand & Technol, Electromagnet Div, US Dept Commerce, Boulder Labs, Boulder, CO 80305 USA. EM holloway@boulder.nist.gov; edward.kuester@colorado.edu NR 39 TC 13 Z9 13 U1 0 U2 6 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 0018-9375 J9 IEEE T ELECTROMAGN C JI IEEE Trans. Electromagn. Compat. PD MAY PY 2009 VL 51 IS 2 BP 338 EP 344 DI 10.1109/TEMC.2009.2016104 PG 7 WC Engineering, Electrical & Electronic; Telecommunications SC Engineering; Telecommunications GA 449LV UT WOS:000266333000019 ER PT J AU Magdowski, M Hill, DA AF Magdowski, Mathias Hill, David A. TI Boundary Fields in Reverberation Chambers (vol 47, pg 281, 2005) SO IEEE TRANSACTIONS ON ELECTROMAGNETIC COMPATIBILITY LA English DT Correction C1 [Magdowski, Mathias] Otto VonGuericke Univ Magdegurg, D-39016 Magdeburg, Germany. [Hill, David A.] Natl Inst Stand & Technol, Electromagnet Div, Boulder, CO 80305 USA. RP Magdowski, M (reprint author), Otto VonGuericke Univ Magdegurg, D-39016 Magdeburg, Germany. EM mathias.magdowski@ovgu.de; dhill@boulder.nist.gov RI Magdowski, Mathias/F-1348-2013 OI Magdowski, Mathias/0000-0002-1512-5354 NR 2 TC 3 Z9 3 U1 0 U2 1 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 0018-9375 J9 IEEE T ELECTROMAGN C JI IEEE Trans. Electromagn. Compat. PD MAY PY 2009 VL 51 IS 2 BP 420 EP 421 DI 10.1109/TEMC.2009.2012870 PG 2 WC Engineering, Electrical & Electronic; Telecommunications SC Engineering; Telecommunications GA 449LV UT WOS:000266333000031 ER PT J AU Wang, WH Liang, SL Augustine, JA AF Wang, Wenhui Liang, Shunlin Augustine, John A. TI Estimating High Spatial Resolution Clear-Sky Land Surface Upwelling Longwave Radiation From MODIS Data SO IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING LA English DT Article DE Moderate Resolution Imaging Spectroradiometer (MODIS); neural networks; remote sensing; satellite applications; surface radiation budget (SRB); surface upwelling longwave radiation (LWUP) ID GROUND MEASUREMENTS; VALIDATION; TEMPERATURE; PRODUCTS; SIMULATIONS; SENSITIVITY; NETWORK; CLOUDS; CERES AB Surface upwelling longwave radiation (LWUP) is an important component in the surface radiation budget. Existing satellite-derived LWUP data sets are too coarse to support high-resolution numerical models, and their accuracy needs to be improved. In this paper, we evaluate three methods for estimating clear-sky land LWUP from the Moderate Resolution Imaging Spectroradiometer (MODIS) data at I-km spatial resolution. The three methods are as follows: 1) the temperature-emissivity method; 2) the linear model method; and 3) the artificial neural network (ANN) model method. Methods 2 and 3 are new methods based on extensive radiative transfer simulations and statistical analysis. We explicitly considered surface emissivity effects by incorporating the University of California Santa Barbara emissivity library in the radiative transfer simulation. The three methods were evaluated using ground-measured LWUP from six SURFRAD sites. Although methods 2 and 3 were developed using MODIS Terra atmospheric profiles, they were applied to both Terra and Aqua data because the designs of the two sensors are similar. The root mean squared errors (rmses) of the ANN model method are smaller than that or the other two methods at all sites. The averaged rmses of the ANN model method are 15.89 W/m(2) (Terra) and 14.57 W/m(2) (Aqua); the averaged biases are -8.67 W/m(2) (Terra) and -7.21 W/m(2) (Aqua). The biases and rmses for Aqua are similar to 1.3 W/m(2) smaller than that of Terra. The biases and rmses of the ANN model method are similar to 5 W/m(2) smaller than that of the temperature-emissivity method and similar to 2.5 W/m(2) smaller than that of the linear model method. C1 [Wang, Wenhui; Liang, Shunlin] Univ Maryland, Dept Geog, College Pk, MD 20742 USA. [Augustine, John A.] NOAA Earth Syst Res Lab, Global Monitoring Div, Boulder, CO 80305 USA. RP Wang, WH (reprint author), IM Syst Grp Inc, Camp Springs, MD 20746 USA. EM whwang1@umd.edu; sliang@geog.umd.edu; John.A.Augustine@noaa.gov RI Wang, Wenhui/D-3240-2012; liang, shunlin/C-2809-2015 FU NASA [NNX08AC53G] FX Manuscript received July 16, 2007; revised January 23, 2008 and May 21, 2008. First published December 9, 2008; current version published April 24, 2009. This work, was supported in part by NASA under Grant NNX08AC53G. NR 39 TC 24 Z9 24 U1 1 U2 8 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 0196-2892 J9 IEEE T GEOSCI REMOTE JI IEEE Trans. Geosci. Remote Sensing PD MAY PY 2009 VL 47 IS 5 BP 1559 EP 1570 DI 10.1109/TGRS.2008.2005206 PG 12 WC Geochemistry & Geophysics; Engineering, Electrical & Electronic; Remote Sensing; Imaging Science & Photographic Technology SC Geochemistry & Geophysics; Engineering; Remote Sensing; Imaging Science & Photographic Technology GA 437KT UT WOS:000265487100029 ER PT J AU Romero, HP Remley, KA Williams, DF Wang, CM AF Romero, Henry P. Remley, Kate A. Williams, Dylan F. Wang, Chih-Ming TI Electromagnetic Measurements for Counterfeit Detection of Radio Frequency Identification Cards SO IEEE TRANSACTIONS ON MICROWAVE THEORY AND TECHNIQUES LA English DT Article DE Authentication; electromagnetic signatures; radio frequency identification (RFID) ID SECURITY AB We investigate a technique for counterfeit detection of high-frequency radio frequency identification (RFID) cards based on the electromagnetic characteristics of the cards rather than the digital information that they transmit. We describe a method of quantifying the electromagnetic signature of an RFID card and identify a small set of features that is sufficient to correctly classify a test set of cards. Furthermore, we show that our measurements indicate that the features most useful for distinguishing cards are contained within the reader inquiry rather than the card response, a reflection of the near-field coupling nature of the RFID transactions in ISO 14443. C1 [Romero, Henry P.] Univ Colorado, Dept Appl Math, Boulder, CO 80309 USA. [Remley, Kate A.; Williams, Dylan F.; Wang, Chih-Ming] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Romero, HP (reprint author), Univ Colorado, Dept Appl Math, Boulder, CO 80309 USA. EM romeroh@colorado.edu; remley@boulder.nist.gov; dylan@boulder.nist.gov; jwang@boulder.nist.gov FU U.S. Government FX Manuscript received June 26, 2008; revised January 22, 2009. First published April 14, 2009; current version published May 06, 2009. This work was supported in part by the U.S. Government. NR 7 TC 12 Z9 12 U1 0 U2 3 PU IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC PI PISCATAWAY PA 445 HOES LANE, PISCATAWAY, NJ 08855 USA SN 0018-9480 J9 IEEE T MICROW THEORY JI IEEE Trans. Microw. Theory Tech. PD MAY PY 2009 VL 57 IS 5 BP 1383 EP 1387 DI 10.1109/TMTT.2009.2017318 PG 5 WC Engineering, Electrical & Electronic SC Engineering GA 445HD UT WOS:000266041000016 ER PT J AU Knaff, JA AF Knaff, John A. TI Revisiting the maximum intensity of recurving tropical cyclones SO INTERNATIONAL JOURNAL OF CLIMATOLOGY LA English DT Article DE tropical cyclone; hurricane; typhoon; recurvature; intensity; Atlantic; western North Pacific; Southern Hemisphere ID PREDICTION SCHEME AB Previous studies have indicated that recurving western North Pacific tropical cyclones, initially westward moving tropical cyclones that turn toward the east, often reach their maximum intensity close to the time of recurvature. Those results have often been cited in the literature and sometimes inferred to be valid in other tropical cyclone basins. This Study revisits this topic in the western North Pacific, North Atlantic and Southern Hemisphere tropical cyclone basins. The timing of lifetime maximum intensity associated with recurving tropical cyclones is examined using best track datasets from the United States' Joint Typhoon Warning Center and the National Hurricane Center, Miami during the period 1980-2006. Results reveal that tropical cyclones are less likely to experience peak intensity within 12 h and 24 h of recurvature than has been previously reported in the western North Pacific. Furthermore, it is shown that tropical cyclones that become most intense (i.e. intensities greater than 52 m s(-1)) have a greater tendency to reach peak intensity before recurvature than weaker storms save for in the South Pacific where the most intense storms have a slightly greater probability of reaching their maximum intensity following recurvature. It also appears that weak tropical cyclones (i.e. lifetime peak intensities less than 33 m s(-1)) often reach peak intensity prior to or close to recurvature in all tropical cyclone basins as others have reported. However, findings Suggest that the cumulative distributions of maximum intensity with respect to the time of recurvature can be quite different for other intensity ranges suggesting that a universal relationship between peak intensity and time of recurvature does not exist. Copyright (c) 2008 Royal Meteorological Society C1 Colorado State Univ, NOAA, NESDIS, Ctr Satellite Applicat & Res RAMMB,CIRA, Ft Collins, CO 80523 USA. RP Knaff, JA (reprint author), Colorado State Univ, NOAA, NESDIS, Ctr Satellite Applicat & Res RAMMB,CIRA, Foothills Campus Delivery 1375, Ft Collins, CO 80523 USA. EM John.Knaff@noaa.gov RI Knaff, John /F-5599-2010 OI Knaff, John /0000-0003-0427-1409 FU NOAA [NA17RJ1228]; National Oceanic and Atmospheric Administration; U.S. Government FX This research was partially supported by NOAA Grant NA17RJ1228. The author Would like to thank Andrea Schumacher, Ray Zehr and Buck Sampson and the anonymous reviewers for their helpful comments about this manuscript. The views, opinions, and findings contained in this report are those of the author(s) and should not be construed as an official National Oceanic and Atmospheric Administration or U.S. Government position, policy, or decision. NR 16 TC 13 Z9 13 U1 0 U2 0 PU JOHN WILEY & SONS LTD PI CHICHESTER PA THE ATRIUM, SOUTHERN GATE, CHICHESTER PO19 8SQ, W SUSSEX, ENGLAND SN 0899-8418 J9 INT J CLIMATOL JI Int. J. Climatol. PD MAY PY 2009 VL 29 IS 6 BP 827 EP 837 DI 10.1002/joc.1746 PG 11 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 441YW UT WOS:000265807500004 ER PT J AU Otani, M Thomas, EL Wong-Ng, W Schenck, PK Chang, KS Lowhorn, ND Green, ML Ohguchi, H AF Otani, Makoto Thomas, Evan L. Wong-Ng, Winnie Schenck, Peter K. Chang, Kao-Shuo Lowhorn, Nathan D. Green, Martin L. Ohguchi, Hiroyuki TI A High-Throughput Screening System for Thermoelectric Material Exploration Based on a Combinatorial Film Approach SO JAPANESE JOURNAL OF APPLIED PHYSICS LA English DT Article; Proceedings Paper CT 1st International Symposium on Thermal Design and Thermophysical Property for Electronics CY JUN 18-20, 2008 CL Tsukuba, JAPAN ID COMPOSITION-SPREAD APPROACH; GROWTH; MERIT AB A high-throughput system that consists of a combinatorial tool (a sputtering deposition tool and a pulsed laser deposition tool) and two developed property screening devices was used for thermoelectric material exploration. The thermoelectric power factor (S(2)sigma, S = Seebeck coefficient, sigma = electrical conductivity) screening device allows us to measure electrical conductivity and Seebeck coefficient of over 1000 sample-points within 6h. The thermal effusivity measurement system using the frequency domain thermoreflectance technique allows us to screen thermal conductivity of combinatorial/conventional films. Illustrations of these applications are provided with a Co-Sn-Ce/Si(100) film for power factor determination and with a Ba(2)YCu(3)O(7)/SrTiO(3)(100) film for thermal conductivity derivation. (C) 2009 The Japan Society of Applied Physics C1 [Otani, Makoto; Thomas, Evan L.; Wong-Ng, Winnie; Schenck, Peter K.; Chang, Kao-Shuo; Lowhorn, Nathan D.; Green, Martin L.; Ohguchi, Hiroyuki] NIST, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA. RP Otani, M (reprint author), NIST, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA. RI Oguchi, Hiroyuki/R-5305-2016 NR 21 TC 8 Z9 8 U1 2 U2 22 PU JAPAN SOCIETY APPLIED PHYSICS PI TOKYO PA KUDAN-KITA BUILDING 5TH FLOOR, 1-12-3 KUDAN-KITA, CHIYODA-KU, TOKYO, 102-0073, JAPAN SN 0021-4922 J9 JPN J APPL PHYS JI Jpn. J. Appl. Phys. PD MAY PY 2009 VL 48 IS 5 AR 05EB02 DI 10.1143/JJAP.48.05EB02 PG 4 WC Physics, Applied SC Physics GA 452WG UT WOS:000266571300005 ER PT J AU Kuhn, CE Crocker, DE Tremblay, Y Costa, DP AF Kuhn, Carey E. Crocker, Daniel E. Tremblay, Yann Costa, Daniel P. TI Time to eat: measurements of feeding behaviour in a large marine predator, the northern elephant seal Mirounga angustirostris SO JOURNAL OF ANIMAL ECOLOGY LA English DT Article DE dive behaviour; feeding success; foraging indicators; transit rate ID STOMACH TEMPERATURE; MOVEMENT PATTERNS; FORAGING BEHAVIOR; WANDERING ALBATROSSES; LEATHERBACK TURTLES; KING PENGUINS; PREY; PINNIPEDS; ECOLOGY; HABITAT AB The at-sea behaviour of marine predators is often described based on changes in behavioural states, such as transit, searching, and feeding. However, to distinguish between these behaviours, it is necessary to know the actual functions of the behaviours recorded. Specifically, to understand the foraging behaviour of marine predators, it is necessary to measure prey consumption. Therefore, the at-sea feeding behaviour of northern elephant seals (N = 13) was examined using satellite transmitters, time-depth recorders, and stomach temperature recorders. In addition, stomach temperature telemetry allowed for the validation of indirect measures of feeding behaviour used for marine predators, including decreases in transit rate and changes in dive shape. Feeding data were recorded for the early phase of the migration (2.2-21 days). The first feeding events occurred shortly after animals departed (4.0 +/- 1.5 h) and close to the rookery (58.6 +/- 21.9 km), but these feedings were followed by extended periods without prey consumption (14.5 +/- 2.5 h). Continuous (bout) feeding did not occur until on average 7.5 +/- 1.8 days after the females left the rookery. Females showed significant differences in the feeding rate while feeding in a bout (1.3-2.1 feeding events hour(-1)). There was a significant negative relationship between interpolated transit rate and feeding events (r(2) = 0.62, P < 0.01). Feeding, which was associated with all dive types, occurred most often during the foraging type dive shape (74.2%). Finally, successful feeding only occurred between 18-24% of the time when females displayed the foraging type dive shape suggesting that the use of dive shape alone, while indicative of behaviours associated with foraging (searching and catching prey) overestimates actual feeding behaviour. This study showed females not only feed extensively during the early migration, but there was individual variation in both foraging locations and foraging success. In addition, by combining direct and indirect measures of feeding, this study has provided support for the use of foraging indicators in marine predators. C1 [Kuhn, Carey E.] NOAA, Natl Marine Mammal Lab, Alaska Fisheries Sci Ctr, Seattle, WA 98115 USA. [Crocker, Daniel E.] Sonoma State Univ, Dept Biol, Rohnert Pk, CA 94928 USA. [Kuhn, Carey E.; Tremblay, Yann; Costa, Daniel P.] Univ Calif Santa Cruz, Dept Ecol & Evolutionary Biol, Santa Cruz, CA 95064 USA. RP Kuhn, CE (reprint author), NOAA, Natl Marine Mammal Lab, Alaska Fisheries Sci Ctr, 7600 Sand Point Way NE, Seattle, WA 98115 USA. EM carey.kuhn@noaa.gov FU National Ocean Partnership Program; Moore, Packard, and Sloan Foundations; Office of Naval Research FX This work would not have been possible without the support of numerous researchers and volunteers, especially J. Hassrick, B. McDonald, P. Morris, H. Mostman, P. Robinson, M. Rutishauser, S. Simmons, and S. Villegas. Research was supported by grants from the Mildred E. Mathias Foundation, Friends of Long Marine Lab, and the California Sea Grant College Program. This research was conducted as a part of the Tagging of Pacific Pelagics (TOPP) program, funded by the National Ocean Partnership Program, the Moore, Packard, and Sloan Foundations, and the Office of Naval Research. Animal handling procedures were approved by the UCSC Chancellors Animal Research Committee and permitted under NMFS permit #87-143. NR 51 TC 41 Z9 42 U1 1 U2 29 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 0021-8790 J9 J ANIM ECOL JI J. Anim. Ecol. PD MAY PY 2009 VL 78 IS 3 BP 513 EP 523 DI 10.1111/j.1365-2656.2008.01509.x PG 11 WC Ecology; Zoology SC Environmental Sciences & Ecology; Zoology GA 427NB UT WOS:000264784900004 PM 19040681 ER PT J AU Steiger, SM Hamilton, R Keeler, J Orville, RE AF Steiger, Scott M. Hamilton, Robert Keeler, Jason Orville, Richard E. TI Lake-Effect Thunderstorms in the Lower Great Lakes SO JOURNAL OF APPLIED METEOROLOGY AND CLIMATOLOGY LA English DT Article ID ELECTRIFICATION; WINTER; FLASH AB Cloud-to-ground (CG) lightning, radar, and radiosonde data were examined to determine how frequently lake-effect storms (rain/snow) with lightning occurred over and near the lower Great Lakes region (Lakes Erie and Ontario) from September 1995 through March 2007. On average, lake-effect lightning occurred on 7.9 days and with 5.8 storm events during a particular cool season (September-March). The CG lightning with these storms had little inland extent and was usually limited to a few flashes per storm. Some storms had considerably more, with the most intense storm (based on National Lightning Detection Network observations) producing 1551 CG flashes over a 4-day period. Thundersnow events were examined in more detail because of the rarity of this phenomenon across the United States. Most lake-effect thundersnow events (75%) occurred in November and December. An analysis of model sounding data using the Buffalo Toolkit for Lake Effect Snow (BUFKIT) software package in which lower boundary conditions can be modified by lake surfaces showed that thundersnow events had an 82% increase in the mean height of the -10 degrees C level when compared with nonelectrified lake-effect snowstorms (1.2 vs 0.7 km AGL), had higher lake-induced equilibrium levels (EL; above 3.6 km AGL) and convective available potential energy (CAPE; > 500 J kg(-1)), had low wind shear environments, and were intense, single-band storms. A nomogram of the altitude of the -10 degrees C isotherm and EL proved to be useful in predicting lake-effect thundersnowstorms. C1 [Steiger, Scott M.; Keeler, Jason] SUNY Coll Oswego, Dept Earth Sci, Oswego, NY 13126 USA. [Hamilton, Robert] Natl Weather Serv, Forecast Off, Buffalo, NY USA. [Orville, Richard E.] Texas A&M Univ, Dept Atmospher Sci, College Stn, TX USA. RP Steiger, SM (reprint author), SUNY Coll Oswego, Dept Earth Sci, Oswego, NY 13126 USA. EM steiger@oswego.edu RI Orville, Richard/G-9866-2012 OI Orville, Richard/0000-0003-0280-7169 FU The Student/ Faculty Collaborative Challenge Grant at SUNY Oswego FX Vaisala, Inc., generously provided the authors with the cloud-to-ground lightning data. Arthur Person (The Pennsylvania State University) provided the BUFKIT data used for our case studies. Thanks are given to Drs. Steven Skubis and Robert Ballentine (SUNY Oswego) for valuable discussion regarding the glaciation of lake-effect clouds and for editing of the manuscript. The Student/ Faculty Collaborative Challenge Grant at SUNY Oswego provided funding for this research, and we thank the SUNY Oswego Scholarly and Creative Activity Committee. The authors gratefully acknowledge Thomas Niziol, David Zaff, Jeff Waldstreicher, and David Novak of the National Weather Service and their spotters for their time and contributions to this research. Last, we thank the reviewers for their time and efforts in significantly improving this manuscript. NR 32 TC 8 Z9 9 U1 2 U2 16 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 1558-8424 J9 J APPL METEOROL CLIM JI J. Appl. Meteorol. Climatol. PD MAY PY 2009 VL 48 IS 5 BP 889 EP 902 DI 10.1175/2008JAMC1935.1 PG 14 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 452KE UT WOS:000266538100001 ER PT J AU Pomeroy, JM Grube, H AF Pomeroy, J. M. Grube, H. TI "Negative resistance" errors in four-point measurements of tunnel junctions and other crossed-wire devices SO JOURNAL OF APPLIED PHYSICS LA English DT Article ID MAGNETORESISTANCE; FILM; BARRIER AB "Negative resistance" errors due to nonuniform current distributions significantly distort the apparent electronic performance of devices formed with crossed wires, demonstrated here by resistance, magnetoresistance, current-voltage, and variable temperature measurements with and without corrections. Crossed-wire devices are frequently used in research settings for exploratory systems or rapid process recipe evolution due to the ease of depositing complete devices in situ through shadow masks. Unfortunately, this geometry suffers from a negative resistance effect that dominates the measurement when the device resistance is similar to or less than the wires' resistance. We use a finite-element model and experimental data to extend work (by others) to quantify these errors when (1) devices are not square in shape, (2) when the two wires are not in the same resistivity, and (3) when the junction resistance is nonlinear in voltage. Using this knowledge and pre-existing analytical work, a straightforward method for correcting experimental measurements is suggested and evaluated. Finally, we illustrate the importance of correcting the data in magnetoresistance, current-voltage, and temperature dependent transport measurements for correct physical interpretation. [DOI: 10.1063/1.3122503] C1 [Pomeroy, J. M.; Grube, H.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Pomeroy, JM (reprint author), Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. EM joshua.pomeroy@nist.gov NR 19 TC 7 Z9 7 U1 0 U2 7 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 0021-8979 J9 J APPL PHYS JI J. Appl. Phys. PD MAY 1 PY 2009 VL 105 IS 9 AR 094503 DI 10.1063/1.3122503 PG 8 WC Physics, Applied SC Physics GA 448LE UT WOS:000266263300163 ER PT J AU Ramadurai, K Cromer, CL Dillon, AC Mahajan, RL Lehman, JH AF Ramadurai, Krishna Cromer, Christopher L. Dillon, Anne C. Mahajan, Roop L. Lehman, John H. TI Raman and electron microscopy analysis of carbon nanotubes exposed to high power laser irradiance SO JOURNAL OF APPLIED PHYSICS LA English DT Article ID PYROELECTRIC DETECTOR; PURIFICATION; DEPOSITION; FILMS AB High power laser radiometry requires efficient and damage-resistant detectors. The current study explores the evolving nature of carbon nanotube coatings for such detectors upon their exposure to incrementally increasing laser power levels. Electron microscopy images along with the D-band to G-band intensity ratios from the Raman spectra from eight irradiance levels are used to evaluate changes before and after the exposure. Electron microscopy images of the exposed multiwalled carbon nanotubes revealed the formation of intermittent pockets of moundlike structures at high power densities exceeding 11 kW/cm(2). Raman spectroscopy measurements also demonstrated higher values for the ratio of the D-band intensity to that of the G-band, suggesting the possible transformation of nanotubes into structurally different forms of carbon. Exposure to a sample of single-walled nanotubes did not demonstrate the evolution of structural changes, which could be due in part to the higher irradiance levels relative to the damage threshold, employed in the experiment. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3116165] C1 [Ramadurai, Krishna] Univ Colorado, Dept Mech Engn, Boulder, CO 80309 USA. [Cromer, Christopher L.; Lehman, John H.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. [Dillon, Anne C.] Natl Renewable Energy Lab, Boulder, CO 80305 USA. [Mahajan, Roop L.] Virginia Tech, Dept Engn Sci & Mech, Blacksburg, VA 24060 USA. [Mahajan, Roop L.] Virginia Tech, Dept Mech Engn, ICTAS, Blacksburg, VA 24060 USA. RP Ramadurai, K (reprint author), Univ Colorado, Dept Mech Engn, Boulder, CO 80309 USA. EM krishna.ramadura@gmail.com FU CU-NIST FX We thank the CU-NIST seed grant program for providing financial support to this work. We also thank Dr. Xiaoyu Li (NIST, Boulder, CO) for his assistance with the experimental setup and Dr. Katie Hurst for her suggestions on the presented material. NR 17 TC 10 Z9 10 U1 2 U2 7 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 0021-8979 J9 J APPL PHYS JI J. Appl. Phys. PD MAY 1 PY 2009 VL 105 IS 9 AR 093106 DI 10.1063/1.3116165 PG 6 WC Physics, Applied SC Physics GA 448LE UT WOS:000266263300007 ER PT J AU Wood, VT Brown, RA Dowell, DC AF Wood, Vincent T. Brown, Rodger A. Dowell, David C. TI Simulated WSR-88D Velocity and Reflectivity Signatures of Numerically Modeled Tornadoes SO JOURNAL OF ATMOSPHERIC AND OCEANIC TECHNOLOGY LA English DT Article ID DOPPLER-RADAR OBSERVATIONS; MESOCYCLONE SIGNATURES; VORTEX STRUCTURE; MOBILE; RESOLUTION AB Low-altitude radar reflectivity measurements of tornadoes sometimes reveal a donut-shaped signature (low-reflectivity eye surrounded by a high-reflectivity annulus) and at other times reveal a high-reflectivity knob associated with the tornado. The differences appear to be due to such factors as (i) the radar's sampling resolution, (ii) the presence or absence of lofted debris and a low-reflectivity eye, (iii) whether measurements were made within the lowest few hundred meters where centrifuged hydrometeors and smaller debris particles were recycled back into the tornadic circulation, and (iv) the presence or absence of multiple vortices in the parent tornado. To explore the influences of some of these various factors on radar reflectivity and Doppler velocity signatures, a high-resolution tornado numerical model was used that incorporated the centrifuging of hydrometeors. A model reflectivity field was computed from the resulting concentration of hydrometeors. Then, the model reflectivity and velocity fields were scanned by a simulated Weather Surveillance Radar-1988 Doppler (WSR-88D) using both the legacy resolution and the new super-resolution sampling. Super-resolution reflectivity and Doppler velocity data are displayed at 0.5 degrees instead of 1.0 degrees azimuthal sampling intervals and reflectivity data are displayed at 0.25-km instead of 1.0-km range intervals. Since a mean Doppler velocity value is the reflectivity-weighted mean of the radial motion of all the radar scatterers within a radar beam, a nonuniform distribution of scatterers produces a different mean Doppler velocity value than does a uniform distribution of scatterers. Nonuniform reflectivities within the effective resolution volume of the radar beam can bias the indicated size and strength of the tornado's core region within the radius of the peak tangential velocities. As shown in the simulation results, the Doppler-indicated radius of the peak wind underestimates the true radius and true peak tangential velocity when the effective beamwidth is less than the tornado's core diameter and there is a weak-reflectivity eye at the center of the tornado. As the beam becomes significantly wider than the tornado's core diameter with increasing range, the peaks of the Doppler velocity profiles continue to decrease in magnitude but overestimate the tornado's true radius. With increasing range from the radar, the prominence of the weak-reflectivity eye at the center of the tornado is progressively lessened until it finally disappears. As to be expected, the Doppler velocity signatures and reflectivity eye signatures were more prominent and stronger with super-resolution sampling than those with legacy-resolution sampling. C1 [Wood, Vincent T.; Brown, Rodger A.; Dowell, David C.] NOAA, Natl Severe Storms Lab, Norman, OK 73072 USA. [Dowell, David C.] Univ Oklahoma, Cooperat Inst Mesoscale Meteorol Studies, Norman, OK 73019 USA. RP Wood, VT (reprint author), NOAA, Natl Severe Storms Lab, 120 David L Boren Blvd, Norman, OK 73072 USA. EM vincent.wood@noaa.gov RI Dowell, David/E-7855-2015 NR 31 TC 13 Z9 14 U1 0 U2 0 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0739-0572 J9 J ATMOS OCEAN TECH JI J. Atmos. Ocean. Technol. PD MAY PY 2009 VL 26 IS 5 BP 876 EP 893 DI 10.1175/2008JTECHA1181.1 PG 18 WC Engineering, Ocean; Meteorology & Atmospheric Sciences SC Engineering; Meteorology & Atmospheric Sciences GA 456HA UT WOS:000266833600002 ER PT J AU Isom, BM Palmer, RD Secrest, GS Rhoton, RD Saxion, D Allmon, TL Reed, J Crum, T Vogt, R AF Isom, B. M. Palmer, R. D. Secrest, G. S. Rhoton, R. D. Saxion, D. Allmon, T. L. Reed, J. Crum, T. Vogt, R. TI Detailed Observations of Wind Turbine Clutter with Scanning Weather Radars SO JOURNAL OF ATMOSPHERIC AND OCEANIC TECHNOLOGY LA English DT Article ID METEOROLOGICAL OBJECTIVE ANALYSIS; MULTIQUADRIC INTERPOLATION; ALGORITHM AB The wind power industry has seen tremendous growth over the past decade and with it has come the need for clutter mitigation techniques for nearby radar systems. Wind turbines can impart upon these radars a unique type of interference that is not removed with conventional clutter-filtering methods. Time series data from Weather Surveillance Radar-1988 Doppler (WSR-88D) stations near wind farms were collected and spectral analysis was used to investigate the detailed characteristics of wind turbine clutter. Techniques to mask wind turbine clutter were developed that utilize multiquadric interpolation in two and three dimensions and can be applied to both the spectral moments and spectral components. In an effort to improve performance, a nowcasting algorithm was incorporated into the interpolation scheme via a least mean squares criterion. The masking techniques described in this paper will be shown to reduce the impact of wind turbine clutter on weather radar systems at the expense of spatial resolution. C1 [Isom, B. M.; Palmer, R. D.] Univ Oklahoma, Sch Meteorol, Norman, OK 73072 USA. [Isom, B. M.] Univ Oklahoma, Sch Elect & Comp Engn, Norman, OK 73072 USA. [Isom, B. M.; Palmer, R. D.] Univ Oklahoma, Atmospher Radar Res Ctr, Norman, OK 73072 USA. [Secrest, G. S.; Saxion, D.; Allmon, T. L.; Reed, J.; Crum, T.; Vogt, R.] Radar Operat Ctr, NEXRAD, NWS, NOAA, Norman, OK USA. [Rhoton, R. D.] Wyle Informat Syst Inc, Norman, OK USA. RP Isom, BM (reprint author), Univ Oklahoma, Sch Meteorol, 120 David L Boren Blvd,Suite 5900, Norman, OK 73072 USA. EM bisom@ou.edu FU National Weather Service Radar Operations Cente [NA17RJ1227] FX This research was funded by the National Weather Service Radar Operations Center through Grant NA17RJ1227. NR 25 TC 34 Z9 35 U1 1 U2 9 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0739-0572 J9 J ATMOS OCEAN TECH JI J. Atmos. Ocean. Technol. PD MAY PY 2009 VL 26 IS 5 BP 894 EP 910 DI 10.1175/2008JTECHA1136.1 PG 17 WC Engineering, Ocean; Meteorology & Atmospheric Sciences SC Engineering; Meteorology & Atmospheric Sciences GA 456HA UT WOS:000266833600003 ER PT J AU Dowell, DC Wicker, LJ AF Dowell, David C. Wicker, Louis J. TI Additive Noise for Storm-Scale Ensemble Data Assimilation SO JOURNAL OF ATMOSPHERIC AND OCEANIC TECHNOLOGY LA English DT Article ID KALMAN FILTER; BULK PARAMETERIZATION; RADAR DATA; MODEL; PRECIPITATION; ERROR; MESOSCALE; SUPERCELL; EVOLUTION; OKLAHOMA AB An "additive noise'' method for initializing ensemble forecasts of convective storms and maintaining ensemble spread during data assimilation is developed and tested for a simplified numerical cloud model (no radiation, terrain, or surface fluxes) and radar observations of the 8 May 2003 Oklahoma City supercell. Every 5 min during a 90-min data-assimilation window, local perturbations in the wind, temperature, and water-vapor fields are added to each ensemble member where the reflectivity observations indicate precipitation. These perturbations are random but have been smoothed so that they have correlation length scales of a few kilometers. An ensemble Kalman filter technique is used to assimilate Doppler velocity observations into the cloud model. The supercell and other nearby cells that develop in the model are qualitatively similar to those that were observed. Relative to previous storm-scale ensemble methods, the additive-noise technique reduces the number of spurious cells and their negative consequences during the data assimilation. The additive-noise method is designed to maintain ensemble spread within convective storms during long periods of data assimilation, and it adapts to changing storm configurations. It would be straightforward to use this method in a mesoscale model with explicit convection and inhomogeneous storm environments. C1 [Dowell, David C.] Natl Ctr Atmospher Res, Boulder, CO 80307 USA. [Wicker, Louis J.] NOAA, Natl Severe Storms Lab, OAR, Norman, OK 73069 USA. RP Dowell, DC (reprint author), Natl Ctr Atmospher Res, POB 3000, Boulder, CO 80307 USA. EM ddowell@ucar.edu RI Dowell, David/E-7855-2015 FU National Science Foundation FX The National Center for Atmospheric Research is sponsored by the National Science Foundation. NR 37 TC 59 Z9 64 U1 0 U2 1 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0739-0572 J9 J ATMOS OCEAN TECH JI J. Atmos. Ocean. Technol. PD MAY PY 2009 VL 26 IS 5 BP 911 EP 927 DI 10.1175/2008JTECHA1156.1 PG 17 WC Engineering, Ocean; Meteorology & Atmospheric Sciences SC Engineering; Meteorology & Atmospheric Sciences GA 456HA UT WOS:000266833600004 ER PT J AU Castell, N Stein, AF Mantilla, E Salvador, R Millan, M AF Castell, Nuria Stein, Ariel F. Mantilla, Enrique Salvador, Rosa Millan, Millan TI Evaluation of the use of photochemical indicators to assess ozone-NOx-VOC sensitivity in the Southwestern Iberian Peninsula SO JOURNAL OF ATMOSPHERIC CHEMISTRY LA English DT Article DE O3-NOx-VOC sensitivity; Air quality modeling; Photochemical indicators; Complex industrial terrain ID SIMULATION; EMISSIONS; POLLUTION; MODELS; PART AB Understanding the chemical links between ozone (O(3)) and its two main precursors, nitrogen oxides (NOx) and volatile organic compounds (VOC), is important for designing effective photochemical smog reduction strategies. This chemical relationship will determine which precursor (NOx or VOC) emission reduction will be more effective for decreasing the ozone formation. Under certain conditions, ozone levels decrease as a result of a reduction in NOx emissions but do not respond significantly to changes in VOC emissions (NOx-sensitive condition), while under other conditions ozone concentrations decrease in response to reductions in VOCs and may even increase when NOx emissions are reduced (VOC-sensitive conditions). Indicator species can be used to assess the sensitivity of ozone to changes in the emissions of its precursors. These indicators are species or species ratios involved in ozone photochemistry which reflect the primary chemical process through which the ozone was formed. In this work we use the MM5-CAMx model system to explore the behaviour of various indicator species during two meteorological situations featuring different atmospheric conditions in a complex terrain area. The results show that indicators based on nitrogen compounds (i.e,. NOy and NOz) are suitable for defining the transition range from VOC- to NOx-sensitive chemistry, and that despite the uncertainties associated with the use of chemical indicators, the ratios O(3)/NOy and O(3)/NOz may provide a simple and useful way to summarize the response of ozone to changes in NOx and VOC emissions in Southwestern Spain. C1 [Castell, Nuria; Mantilla, Enrique; Salvador, Rosa; Millan, Millan] Fdn CEAM, Valencia, Spain. [Stein, Ariel F.] NOAA, Earth Resources & Technol Assignment, Air Resources Lab, Silver Spring, MD 20910 USA. RP Castell, N (reprint author), Fdn CEAM, Parque Tecnol C Charles R Darwin 14 Paterna, Valencia, Spain. EM nuria@ceam.es; ariel.stein@noaa.gov RI Stein, Ariel/G-1330-2012; Stein, Ariel F/L-9724-2014 OI Stein, Ariel F/0000-0002-9560-9198 FU Generalitat Valenciana and Bancaixa; CONSOLIDER-INGENIO FX The CEAM Foundation is co-financed by the Generalitat Valenciana and Bancaixa. This work is a contribution to the CONSOLIDER-INGENIO 2010 programme (GRACCIE research project) and to ACCENT. In addition, the authors would like to thank the referees for their comments and suggestions on this manuscript. NR 22 TC 4 Z9 4 U1 2 U2 23 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0167-7764 J9 J ATMOS CHEM JI J. Atmos. Chem. PD MAY PY 2009 VL 63 IS 1 BP 73 EP 91 DI 10.1007/s10874-010-9158-x PG 19 WC Environmental Sciences; Meteorology & Atmospheric Sciences SC Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences GA 607AO UT WOS:000278470800005 ER PT J AU Ballance, LT Ainley, DG Ballard, G Barton, K AF Ballance, Lisa T. Ainley, David G. Ballard, Grant Barton, Kerry TI An energetic correlate between colony size and foraging effort in seabirds, an example of the AdElie penguin Pygoscelis adeliae SO JOURNAL OF AVIAN BIOLOGY LA English DT Article ID BLACK-LEGGED KITTIWAKES; LEACHS STORM-PETRELS; EUDYPTULA-MINOR; WANDERING ALBATROSSES; TROPHIC CASCADES; LABELED WATER; ROSS SEA; REPRODUCTIVE ENERGETICS; GEOGRAPHIC STRUCTURE; ANTARCTIC PENINSULA AB Central-place foraging seabirds alter the availability of their prey around colonies, forming a "halo" of reduced prey access that ultimately constrains population size. This has been indicated indirectly by an inverse correlation between colony size and reproductive success, numbers of conspecifics at other colonies within foraging range, foraging effort (i.e. trip duration), diet quality and colony growth rate. Although ultimately mediated by density dependence relative to food through intraspecific exploitative or interference competition, the proximate mechanism involved has yet to be elucidated. Herein, we show that AdElie penguin Pygoscelis adeliae colony size positively correlates to foraging trip duration and metabolic rate, that the metabolic rate while foraging may be approaching an energetic ceiling for birds at the largest colonies, and that total energy expended increases with trip duration although uncompensated by increased mass gain. We propose that a competition-induced reduction in prey availability results in higher energy expenditure for birds foraging in the halo around large colonies, and that to escape the halo a bird must increase its foraging distance. Ultimately, the total energetic cost of a trip determines the maximum successful trip distance, as on longer trips food acquired is used more for self maintenance than for chick provisioning. When the net cost of foraging trips becomes too high, with chicks receiving insufficient food, chick survival suffers and subsequent colony growth is limited. Though the existence of energetic studies of the same species at multiple colonies is rare, because foraging metabolic rate increases with colony size in at least two other seabird species, we suggest that an energetic constraint to colony size may generally apply to other seabirds. C1 [Ballance, Lisa T.] NOAA Fisheries, SW Fish Sci Ctr, La Jolla, CA 92037 USA. [Ainley, David G.] HT Harvey & Associates, Los Gatos, CA 95032 USA. [Ballard, Grant] PRBO Conserv Sci, Petaluma, CA 94954 USA. [Ballard, Grant] Univ Auckland, Sch Biol Sci, Auckland 1, New Zealand. [Barton, Kerry] New Zealand Ltd, Landcare Res, Nelson, New Zealand. RP Ballance, LT (reprint author), NOAA Fisheries, SW Fish Sci Ctr, 8604 La Jolla Shores Dr, La Jolla, CA 92037 USA. EM lisa.ballance@noaa.gov FU US Antarctic Program; Office of Polar Programs; National Science Foundation [OPP 0125608, 0440643]; Southwest Fisheries Science Center of the National Oceanic and Atmospheric Administration; PRBO [1632] FX We thank S. Webb, T. Dorr, and S. Heath for efforts in the field, K. Nagy, C. Vleck, T. Reidarson, D. Croll, and T. Bucher for consultation on field methods, and D. Cairns, J. Chardine, D. Croll, J. Croxall, P. Dann, G. Gabrielsen, R. Gales, T. Gaston, I. Jones, F. Mehlum, W. Montevecchi, J. Piatt, D. Roby, and E. Woehler for unpublished information. K. Dugger helped with statistical insights. M. Hauber, T. Gaston, K. Hamer, T. Piersma and two anonymous reviewers provided valuable and detailed comments on our paper. This research was supported logistically by the US Antarctic Program and financially by the Office of Polar Programs, National Science Foundation (OPP 0125608, 0440643), and the Southwest Fisheries Science Center of the National Oceanic and Atmospheric Administration; conclusions reported herein are not those of these agencies. PRBO contribution #1632. NR 71 TC 45 Z9 47 U1 5 U2 45 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 0908-8857 J9 J AVIAN BIOL JI J. Avian Biol. PD MAY PY 2009 VL 40 IS 3 BP 279 EP 288 DI 10.1111/j.1600-048X.2008.04538.x PG 10 WC Ornithology SC Zoology GA 445CL UT WOS:000266027200008 ER PT J AU McDonald, MA Jankovic, L Shahzad, K Burcher, M Li, KCP AF McDonald, Michael A. Jankovic, Ladislav Shahzad, Khalid Burcher, Michael Li, King C. P. TI Acoustic fingerprints of dye-labeled protein submicrosphere photoacoustic contrast agents SO JOURNAL OF BIOMEDICAL OPTICS LA English DT Article; Proceedings Paper CT 8th Conference on Biomedical Thermoacoustics, Optoacoustics and Acousto-optics CY JAN 21-24, 2007 CL San Jose, CA SP SPIE, NIH, Fairway Med Technol DE photoacoustic; ultrasound; contrast agents; protein microspheres ID IN-VIVO; TOMOGRAPHY; RECONSTRUCTION; TISSUE; MEDIA; LIGHT AB Dye-labeled protein microspheres, submicron in size and capable of producing thermoelastically generated ultrasound in response to laser stimulation, are presented as contrast agents for photoacoustic imaging. Incident laser energy absorbed by fluorescein isothiocyanate (FITC)-labeled elastin submicrospheres results in thermoelastically generated sound production. Plotted A-line graphs reveal a distinctive morphology and a greater than two orders of magnitude increase in signal amplitude subsequent to converting FITC elastin into submicrospheres (despite a four orders of magnitude decrease in concentration). Evidence of nonlinearity and enhancement of ultrasound backscatter indicate a potential use in contrast-enhanced harmonic imaging. Photoacoustic and ultrasound imaging of FITC-elastin submicrospheres in a water-filled phantom vessel shows enhanced contrast at low concentration and clear delineation of the phantom vessel wall. (C) 2009 Society of Photo-Optical Instrumentation Engineers. [DOI: 10.1117/1.3155519] C1 [McDonald, Michael A.] Natl Inst Sci & Techn Creat, Chem Sci & Technol Lab, Gaithersburg, MD 20899 USA. [Jankovic, Ladislav; Shahzad, Khalid; Burcher, Michael] Philips Res USA, Briarcliff Manor, NY 10510 USA. [Li, King C. P.] Methodist Hosp, Dept Radiol, Houston, TX 77030 USA. RP McDonald, MA (reprint author), Natl Inst Sci & Techn Creat, Chem Sci & Technol Lab, 100 Bur Dr,Stop 8313, Gaithersburg, MD 20899 USA. EM michael.a.mcdonald@nist.gov NR 21 TC 4 Z9 4 U1 0 U2 1 PU SPIE-SOC PHOTOPTICAL INSTRUMENTATION ENGINEERS PI BELLINGHAM PA 1000 20TH ST, PO BOX 10, BELLINGHAM, WA 98225 USA SN 1083-3668 J9 J BIOMED OPT JI J. Biomed. Opt. PD MAY-JUN PY 2009 VL 14 IS 3 AR 034032 DI 10.1117/1.3155519 PG 7 WC Biochemical Research Methods; Optics; Radiology, Nuclear Medicine & Medical Imaging SC Biochemistry & Molecular Biology; Optics; Radiology, Nuclear Medicine & Medical Imaging GA 477RN UT WOS:000268536300041 PM 19566325 ER PT J AU Goldberg, RN Lang, BE Lo, C Ross, DJ Tewari, YB AF Goldberg, Robert N. Lang, Brian E. Lo, Catherine Ross, David J. Tewari, Yadu B. TI Thermodynamics of the hydrolysis reactions of alpha-D-galactose 1-phosphate, sn-glycerol 3-phosphate, 4-nitrophenyl phosphate, phosphocreatine, and 3-phospho-D-glycerate SO JOURNAL OF CHEMICAL THERMODYNAMICS LA English DT Article DE Alkaline phosphatase; Apparent equilibrium constants; alpha-D-Galactose 1-phosphate; sn-Glycerol 3-phosphate; 4-Nitrophenyl phosphate; Phosphocreatine; 3-Phospho-D-glycerate; calorimetry; Standard Gibbs free energy and enthalpy ID ENZYME-CATALYZED REACTIONS; APPARENT DISSOCIATION-CONSTANTS; STABILITY-CONSTANTS; ADENOSINE 5'-MONOPHOSPHATE; PHYSIOLOGICAL CONDITIONS; EQUILIBRIUM-CONSTANTS; ENTHALPY CHANGE; CREATINE; ACID; MAGNESIUM AB Microcalorimetry, high-performance liquid chromatography (h.p.l.c.), and in enzymatic assay have been used to conduct a thermodynamic investigation of five phosphate hydrolysis reactions: {alpha-D-galactose 1-phosphate(aq)+H(2)O(1) = D-galactose(aq) + orthophosphate(aq)} (1), {sn-glycerol 3-phosphate(aq) + H(2)O(1)=glycerol(aq) + orthophosphate(aq)} (2). {4-nitrophenyl phosphate(aq) + H(2)O(1) 4-nitrophenol(aq) + orthophosphate(aq)} (3), {phosphocreatine(aq) + H(2)O(1) = creatine(aq) + orthophosphate(aq)} (4), and {3-phospho=D-glycerate(aq) + H(2)O (1) =D-glycerate(aq) + orthophosphate(aq)} (5). Calorimetrically determined enthalpies of reaction Delta(r)H(cal) were measured for reactions (1)-(5) and the apparent equilibrium constant K' was measured for reaction (2). The pKs and standard enthalpies of reaction Delta(r)H for the H(+) and Mg(2+) binding reactions of the reactants and products in the aforementioned reactions were obtained either from the literature or by estimation. A chemical equilibrium model was then used to calculate standard equilibrium Constants K and standard enthalpies of reaction Delta(r)H for chemical reference reactions that correspond to the overall biochemical reactions that Were Studied experimentally. Property Values from the literature and thermodynamic network Calculations were used to obtain values of the equilibrium constants for the chemical reference reactions that correspond to the overall biochemical reactions (1). These values were compared with other results from the literature and also correlated With Structural features. The results obtained in this Study can be used in the chemical equilibrium model to calculate values of K', the standard apparent Gibbs free energy changes Delta(r)G', the standard apparent enthalpy changes Delta(r)H", changes in binding of the proton Delta(r)N(H(+)), and the position of equilibrium for the overall biochemical reactions considered in this study over a reasonably wide range of temperature. pH, pMg [.. log(10){m(Mg(2+))/m degrees}], and ionic strength I. Values of K' and Delta(r)G'degrees under approximately physiological conditions (T = 310.15 K, pH 7.0, pMg = 3.0, and I(m) = 0.25 mol . kg(-1)) have been calculated. (C) 2008 Elsevier Ltd. All rights reserved. C1 [Goldberg, Robert N.; Lang, Brian E.; Lo, Catherine; Ross, David J.; Tewari, Yadu B.] Natl Inst Stand & Technol, Div Biochem Sci, Gaithersburg, MD 20876 USA. [Goldberg, Robert N.] Univ Maryland, Dept Chem & Biochem, Baltimore, MD 21250 USA. RP Goldberg, RN (reprint author), Natl Inst Stand & Technol, Div Biochem Sci, Gaithersburg, MD 20876 USA. EM robert.goldberg@nist.gov; brian.lang@nist.gov; catherine.lo@nist.gov; david.ross@nist.gov; yadu.tewari@nist.gov NR 53 TC 1 Z9 1 U1 4 U2 7 PU ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD PI LONDON PA 24-28 OVAL RD, LONDON NW1 7DX, ENGLAND SN 0021-9614 J9 J CHEM THERMODYN JI J. Chem. Thermodyn. PD MAY PY 2009 VL 41 IS 5 BP 654 EP 665 DI 10.1016/j.jct.2008.12.017 PG 12 WC Thermodynamics; Chemistry, Physical SC Thermodynamics; Chemistry GA 429YQ UT WOS:000264956400014 ER PT J AU Seo, KH Wang, WQ Gottschalck, J Zhang, Q Schemm, JKE Higgins, WR Kumar, A AF Seo, Kyong-Hwan Wang, Wanqiu Gottschalck, Jon Zhang, Qin Schemm, Jae-Kyung E. Higgins, Wayne R. Kumar, Arun TI Evaluation of MJO Forecast Skill from Several Statistical and Dynamical Forecast Models SO JOURNAL OF CLIMATE LA English DT Article ID MADDEN-JULIAN OSCILLATION; SEA-SURFACE TEMPERATURE; OUTGOING LONGWAVE RADIATION; SUMMER INTRASEASONAL OSCILLATION; EXTENDED-RANGE PREDICTION; TROPICAL WESTERN PACIFIC; AMERICAN-MONSOON-SYSTEM; BOREAL SUMMER; EQUATORIAL WAVES; PRINCIPAL MODES AB This work examines the performance of Madden-Julian oscillation (MJO) forecasts from NCEP's coupled and uncoupled general circulation models (GCMs) and statistical models. The forecast skill from these methods is evaluated in near-real time. Using a projection of El Nino-Southern Oscillation (ENSO)-removed variables onto the principal patterns of MJO convection and upper- and lower-level circulations, MJO-related signals in the dynamical model forecasts are extracted. The operational NCEP atmosphere-ocean fully coupled Climate Forecast System (CFS) model has useful skill (> 0.5 correlation) out to similar to 15 days when the initial MJO convection is located over the Indian Ocean. The skill of the CFS hindcast dataset for the period from 1995 to 2004 is nearly comparable to that from a lagged multiple linear regression model, which uses information from the previous five pentads of the leading two principal components (PCs). In contrast, the real-time analysis for the MJO forecast skill for the period from January 2005 to February 2006 using the lagged multiple linear regression model is reduced to similar to 10-12 days. However, the operational CFS forecast for this period is skillful out to similar to 17 days for the winter season, implying that the coupled dynamical forecast has some usefulness in predicting the MJO compared to the statistical model. It is shown that the coupled CFS model consistently, but only slightly, outperforms the uncoupled atmospheric model (by one to two days), indicating that only limited improvement is gained from the inclusion of the coupled air-sea interaction in the MJO forecast in this model. This slight improvement may be the result of the existence of a propagation barrier around the Maritime Continent and the far western Pacific in the NCEP Global Forecast System (GFS) and CFS models, as shown in several previous studies. This work also suggests that the higher horizontal resolution and finer initial data might contribute to improving the forecast skill, presumably as a result of an enhanced representation of the Maritime Continent region. C1 [Seo, Kyong-Hwan] Pusan Natl Univ, Div Earth Environm Syst, Pusan 609735, South Korea. [Wang, Wanqiu; Gottschalck, Jon; Zhang, Qin; Schemm, Jae-Kyung E.; Higgins, Wayne R.; Kumar, Arun] NOAA, NWS, NCEP, Climate Predict Ctr, Camp Springs, MD USA. RP Seo, KH (reprint author), Pusan Natl Univ, Div Earth Environm Syst, Pusan 609735, South Korea. EM khseo@pusan.ac.kr FU Korea Meteorological Administration Research and Development Program [CATER 2007-4208]; NOAA Climate Program Office; Korea Institute of Science and Technology Information (KISTI) FX The authors thank Drs. Matt Wheeler and Paul Roundy for their valuable comments and suggestions. This work was funded by the Korea Meteorological Administration Research and Development Program under Grant CATER 2007-4208 and the NOAA Climate Program Office under the Climate Variability and Predictability (CLIVAR) program. KH Seo would like to acknowledge the support from the Korea Institute of Science and Technology Information (KISTI). NR 57 TC 68 Z9 78 U1 1 U2 14 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0894-8755 J9 J CLIMATE JI J. Clim. PD MAY PY 2009 VL 22 IS 9 BP 2372 EP 2388 DI 10.1175/2008JCLI2421.1 PG 17 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 448TT UT WOS:000266285600007 ER PT J AU Huang, HP Robertson, AW Kushnir, Y Peng, SL AF Huang, Huei-Ping Robertson, Andrew W. Kushnir, Yochanan Peng, Shiling TI Hindcasts of Tropical Atlantic SST Gradient and South American Precipitation: The Influences of the ENSO Forcing and the Atlantic Preconditioning SO JOURNAL OF CLIMATE LA English DT Article ID SEA-SURFACE TEMPERATURE; CLIMATE VARIABILITY; EL-NINO; OSCILLATION; TELECONNECTION; CIRCULATION; MECHANISMS; PREDICTION; NORDESTE; MODEL AB Hindcast experiments for the tropical Atlantic sea surface temperature (SST) gradient G1, defined as tropical North Atlantic SST anomaly minus tropical South Atlantic SST anomaly, are performed using an atmospheric general circulation model coupled to a mixed layer ocean over the Atlantic to quantify the contributions of the El Nino-Southern Oscillation (ENSO) forcing and the preconditioning in the Atlantic to G1 in boreal spring. The results confirm previous observational analyses that, in the years with a persistent ENSO SST anomaly from boreal winter to spring, the ENSO forcing plays a primary role in determining the tendency of G1 from winter to spring and the sign of G1 in late spring. In the hindcasts, the initial perturbations in Atlantic SST in boreal winter are found to generally persist beyond a season, leaving a secondary but nonnegligible contribution to the predicted Atlantic SST gradient in spring. For 1993/94, a neutral year with a large preexisting G1 in winter, the hindcast using the information of Atlantic preconditioning alone is found to reproduce the observed G1 in spring. The seasonal predictability in precipitation over South America is examined in the hindcast experiments. For the recent events that can be validated with high-quality observations, the hindcasts produced dryness in boreal spring 1983, wetness in spring 1996, and wetness in spring 1994 over northern Brazil that are qualitatively consistent with observations. An inclusion of the Atlantic preconditioning is found to help the prediction of South American rainfall in boreal spring. For the ENSO years, discrepancies remain between the hindcast and observed precipitation anomalies over northern and equatorial South America, an error that is partially attributed to the biased atmospheric response to ENSO forcing in the model. The hindcast of the 1993/94 neutral year does not suffer this error. It constitutes an intriguing example of useful seasonal forecast of G1 and South American rainfall anomalies without ENSO. C1 [Huang, Huei-Ping] Arizona State Univ, Dept Mech & Aerosp Engn, Tempe, AZ 85287 USA. [Robertson, Andrew W.] Columbia Univ, Internatl Res Inst Climate & Soc, New York, NY USA. [Kushnir, Yochanan] Columbia Univ, Lamont Doherty Earth Observ, Palisades, NY USA. [Peng, Shiling] Univ Colorado, Climate Diagnost Ctr, CIRES, Boulder, CO 80309 USA. [Peng, Shiling] Univ Colorado, NOAA, Earth Syst Res Lab, Div Phys Sci, Boulder, CO 80309 USA. RP Huang, HP (reprint author), Arizona State Univ, Dept Mech & Aerosp Engn, Tempe, AZ 85287 USA. EM hp.huang@asu.edu RI Kushnir, Yochanan/B-4472-2013; Robertson, Andrew/H-7138-2015 FU NSF [ATM-05-43256]; NOAA CLIVAR-Atlantic Program; NOAA CPPA Program; NOAA, U. S. Department of Commerce [NA03-OAR4320179] FX The authors thank Dr. Brant Liebmann for providing the South American precipitation dataset used in this study. The comments and suggestions from three anonymous reviewers helped improve the manuscript. This work was supported by NSF Grant ATM-05-43256, NOAA CLIVAR-Atlantic Program, NOAA CPPA Program, and the CICAR Award NA03-OAR4320179 from NOAA, U. S. Department of Commerce. NR 34 TC 2 Z9 2 U1 0 U2 5 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0894-8755 J9 J CLIMATE JI J. Clim. PD MAY PY 2009 VL 22 IS 9 BP 2405 EP 2421 DI 10.1175/2008JCLI2569.1 PG 17 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 448TT UT WOS:000266285600009 ER PT J AU Wang, HL Schubert, S Suarez, M Chen, JY Hoerling, M Kumar, A Pegion, P AF Wang, Hailan Schubert, Siegfried Suarez, Max Chen, Junye Hoerling, Martin Kumar, Arun Pegion, Philip TI Attribution of the Seasonality and Regionality in Climate Trends over the United States during 1950-2000 SO JOURNAL OF CLIMATE LA English DT Article ID GENERAL-CIRCULATION MODELS; SPATIOTEMPORAL STRUCTURE; COUPLED MODEL; SEA-ICE; PART I; SIMULATIONS; VARIABILITY; REANALYSES; US AB The observed climate trends over the United States during 1950-2000 exhibit distinct seasonality and regionality. The surface air temperature exhibits a warming trend during winter, spring, and early summer and a modest countrywide cooling trend in late summer and fall, with the strongest warming occurring over the northern United States in spring. Precipitation trends are positive in all seasons, with the largest trend occurring over the central and southern United States in fall. This study investigates the causes of the seasonality and regionality of those trends, with a focus on the cooling and wetting trends in the central United States during late summer and fall. In particular, the authors examine the link between the seasonality and regionality of the climate trends over the United States and the leading patterns of sea surface temperature (SST) variability, including a global warming (GW) pattern and a Pacific decadal variability (PDV) pattern. A series of idealized atmospheric general circulation model (AGCM) experiments were performed forced by SST trends associated with these leading SST patterns, as well as the residual trend pattern ( obtained by removing the GW and PDV contributions). The results show that the observed seasonal and spatial variations of the climate trends over the United States are to a large extent explained by changes in SST. Among the leading patterns of SST variability, the PDV pattern plays a prominent role in producing both the seasonality and regionality of the climate trends over the United States. In particular, it is the main contributor to the apparent cooling and wetting trends over the central United States. The residual SST trend, a manifestation of phase changes of the Atlantic multidecadal SST variation during 1950-2000, also exerts influences that show strong seasonality with important contributions to the central U. S. temperature and precipitation during the summer and fall seasons. In contrast, the response over the United States to the GW SST pattern is an overall warming with little seasonality or regional variation. These results highlight the important contributions of decadal and multidecadal variability in the Pacific and Atlantic in explaining the observed seasonality and regionality of the climate trends over the United States during the period of 1950-2000. C1 [Wang, Hailan] Univ Maryland, Goddard Earth Sci & Technol Ctr, Baltimore, MD 21201 USA. [Chen, Junye] Univ Maryland, Earth Syst Sci Interdisciplinary Ctr, College Pk, MD 20742 USA. [Kumar, Arun; Pegion, Philip] NOAA, Climate Predict Ctr, Natl Ctr Environm Predict, Boulder, CO USA. RP Wang, HL (reprint author), NASA, Goddard Space Flight Ctr, Global Modeling & Assimilat Off UMBC GEST, Code 610-1, Greenbelt, MD 20771 USA. EM hailan.wang@nasa.gov RI Chen, Junye/G-4301-2011; Pegion, Philip/E-5247-2012 FU NASA; Office of Science, U.S. Department of Energy FX This study is supported by the NASA Modeling, Analysis, and Prediction ( MAP) project on Climate Transitions in the 1970s. We wish to acknowledge the international modeling groups for providing their data for analysis, the Program for Climate Model Diagnosis and Intercomparison (PCMDI) for collecting and archiving the model data, the JSC/CLIVAR WGCM and their Coupled Model Intercomparison Project (CMIP) and Climate Simulation Panel for organizing the model data analysis activity, and the IPCC WG1 TSU for technical support. The IPCC Data Archive at Lawrence Livermore National Laboratory is supported by the Office of Science, U.S. Department of Energy. We thank two anonymous reviewers for their constructive comments and suggestions, which led to many improvements in the presentation of the results. NR 40 TC 57 Z9 57 U1 1 U2 15 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0894-8755 EI 1520-0442 J9 J CLIMATE JI J. Clim. PD MAY PY 2009 VL 22 IS 10 BP 2571 EP 2590 DI 10.1175/2008JCLI2359.1 PG 20 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 453CG UT WOS:000266587200006 ER PT J AU Caldwell, PC Vitousek, S Aucan, JP AF Caldwell, Patrick C. Vitousek, Sean Aucan, Jerome P. TI Frequency and Duration of Coinciding High Surf and Tides along the North Shore of Oahu, Hawaii, 1981-2007 SO JOURNAL OF COASTAL RESEARCH LA English DT Article DE Wave run-up; wave wash; tides; coastal flooding and erosion; buoy data ID WAVE HEIGHTS AB Wave run-up along the north shore of Oahu has an annual cycle with a maximum centered on boreal winter. An understanding of the variability of high wave wash is important for coastal planning, transportation, safety, and property protection. Wave run-up increases with increasing surf size and tidal height. This study analyzed hourly historic wave data and predicted tides from 1981 to 2007 to better understand wave run-up potential based on the frequency and duration (in hours) that high surf and tides coincided as categorized by thresholds of surf and tidal height. The Waimea buoy, located just 5 km offshore, was the primary source for deep-water wave height and period. However, this series only began in 2001. The National Data Buoy Center platform 51001 extends back to 1981. Its location is sufficiently remote from Oahu to warrant a correction in significant wave height. The correction was made based on a regression analysis between dadly mean wave heights from these two buoys. From the final, deep-water, nearshore Oahu, hourly series of swell height and period, surf heights were calculated using an empirical transformation scheme. Thresholds were defined for four surf heights and three tidal elevations. Recurrence was calculated for each of the 12 categories. Duration was computed by summing consecutive hours for each event above each threshold. Historical evidence of sand wash onto select portions of the coastal highway was used to qualitatively rank the 12 categories as marginal, significant, or extreme. One important application of these results would be improvement to surf-related coastal flood forecasts by the National Weather Service in pursuit of protection of life and property. For future design considerations, a joint probability model was constructed to better understand the annual average number of hours exceeding any given paired surf and tidal height. C1 [Caldwell, Patrick C.] Univ Hawaii Manoa, Natl Coastal Data Dev, Natl Ocean & Atmospher Adm, Honolulu, HI 96822 USA. [Vitousek, Sean] Univ Hawaii Manoa, Sch Ocean & Earth Sci & Technol, Dept Geol & Geophys, Honolulu, HI 96822 USA. [Aucan, Jerome P.] Univ Hawaii Manoa, Sch Ocean & Earth Sci & Technol, Dept Oceanog, Honolulu, HI 96822 USA. RP Caldwell, PC (reprint author), Univ Hawaii Manoa, Natl Coastal Data Dev, Natl Ocean & Atmospher Adm, 1000 Pope Rd,MSB 316, Honolulu, HI 96822 USA. EM patrick.caldwell@noaa.gov RI Aucan, Jerome/M-8378-2014 OI Aucan, Jerome/0000-0002-9883-0082 FU The NOAA Coastal Data Development Center FX The NOAA Coastal Data Development Center is greatly appreciated for support to the lead author. Thanks for buoy collection and maintenance are given to the NOAA NDBC, CDIP, and UH Department of Oceanography. Dr. Jerome Aucan deserves recognition for his diligence in keeping the Waimea buoy operational. The finalized NDBC data were acquired through the NOAA National Oceanographic Data Center. The NOAA National Ocean Service is appreciated for Mokuoloe tide gauge data and interannual variability graph. The Pacific Tsunami Warning Center and the Archive of Rapidly Sampled Sea Level Data (Doug Luther and Bernie Kilonsky at UH) are thanked for the Haleiwa sea-level data. The NOAA NWS is acknowledged for access to the Storm Data reports available online. Hawaii Department of Transportation is appreciated for access to reports of sand and debris on the highway. A summary of these data was prepared by Christopher P. Kontoes. Thanks are extended to Chip Fletcher of the UH Coastal Geology Group and Mark Merrifield of the UH Department of Oceanography for review of the analytical approach. This article was originally prepared for the 10th International Workshop on Wave Hindcasting and Forecasting and Coastal Hazards, Turtle Bay, Oahu, Hawaii, November 11-16, 2007. NR 21 TC 3 Z9 3 U1 0 U2 3 PU COASTAL EDUCATION & RESEARCH FOUNDATION PI LAWRENCE PA 810 EAST 10TH STREET, LAWRENCE, KS 66044 USA SN 0749-0208 J9 J COASTAL RES JI J. Coast. Res. PD MAY PY 2009 VL 25 IS 3 BP 734 EP 743 DI 10.2112/08-1004.1 PG 10 WC Environmental Sciences; Geography, Physical; Geosciences, Multidisciplinary SC Environmental Sciences & Ecology; Physical Geography; Geology GA 447HN UT WOS:000266182300017 ER PT J AU Stevens, BG AF Stevens, Bradley G. TI HARDENING OF RED KING CRAB PARALITHODES CAMTSCHATICUS (TILESIUS, 1815) SHELLS AFTER MOLTING SO JOURNAL OF CRUSTACEAN BIOLOGY LA English DT Article DE Anomura; molting; Paralithodes camtschaticus; red king crab; shell hardness ID MALE SNOW CRAB; CHIONOECETES-OPILIO; TERMINAL MOLT; TANNER CRABS; MATURITY; BAIRDI; CYCLE AB Shell hardness was measured with a durometer for female red king crabs, Paralithodes camtschaticus, held in the laboratory over variable periods up to 107 days after molting. The data were fit best by a hyperbolic equation, with parameters beta(0) = 0.216 and beta(1) = 0.019 (R(2) = 0.976, n = 199), and an asymptotic value of 50.7 durometer units (DU). The time required to reach 90% of complete shell hardness (H(90) = 45.6 DU) was calculated to be 74.2 days. Molting dates for all crabs were hindcast using the last measurement that was less than H(90) and mere within 2.5 +/- 6.4 days (mean +/- SE, n = 34) of the actual molting date. C1 [Stevens, Bradley G.] Natl Marine Fisheries Serv, Alaska Fisheries Sci Ctr, Kodiak Fishery Res Ctr, Kodiak, AK 99615 USA. RP Stevens, BG (reprint author), Univ Massachusetts Dartmouth, Sch Marine Sci & Technol, 706 S Rodney French Blvd, New Bedford, MA 02744 USA. EM bstevens@umassd.edu NR 26 TC 7 Z9 7 U1 0 U2 2 PU CRUSTACEAN SOC PI SAN ANTONIO PA 840 EAST MULBERRY, SAN ANTONIO, TX 78212 USA SN 0278-0372 J9 J CRUSTACEAN BIOL JI J. Crustac. Biol. PD MAY PY 2009 VL 29 IS 2 BP 157 EP 160 DI 10.1651/08-3039.1 PG 4 WC Marine & Freshwater Biology SC Marine & Freshwater Biology GA 432HW UT WOS:000265125100002 ER PT J AU Ozcam, AE Efimenko, K Jaye, C Spontak, RJ Fischer, DA Genzer, J AF Ozcam, Ali E. Efimenko, Kirill Jaye, Cherno Spontak, Richard J. Fischer, Daniel A. Genzer, Jan TI Modification of PET surfaces with self-assembled monolayers of organosilane precursors SO JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA LA English DT Article DE Poly(ethylene terephthalate) (PET); Ultraviolet/ozone (UVO); Polymer surface modification; SAM; NEXAFS ID RAY PHOTOELECTRON-SPECTROSCOPY; ATOMIC-FORCE MICROSCOPY; ALKALINE-HYDROLYSIS; POLYMER SURFACES; CONTACT-ANGLE; POLY(ETHYLENE-TEREPHTHALATE); POLYPROPYLENE; DISCHARGE; UV; PHOTOOXIDATION AB We report on a facile, robust and rapid method by which poly(ethylene terephthalate) (PET) surfaces can be chemically modified while avoiding chemical degradation. Specifically, we demonstrate that brief exposure of PET surfaces to ultraviolet/ozone (UVO) generates a large surface concentration of hydrophilic moieties that serve as points of chemical attachment, thereby facilitating subsequent chemisorption of organosilane precursors. The feasibility of this methodology is tested by decorating UVO-modified PET surfaces with semifluorinated organosilane (SFOS) molecules, which serve to alter the surface energy of PET without compromising its bulk characteristics. The physico-chemical properties of the SFOS layers attached to PET are studied with a palette of experimental probes, including near-edge X-ray absorption fine structure (NEXAFS) spectroscopy, X-ray photoelectron spectroscopy (XPS), contact angle, atomic force microscopy (AFM), and ellipsometry. Experimental results indicate that approximate to 2 min of UVO treatment is optimal for covering PET with dense self-assembled monolayers (SAMs) of SFOS. Longer UVO treatment times contaminate and correspondingly roughen PET surfaces with low-molecular-weight organic compounds (LMWOCs) generated from degradation of the topmost PET material. As a consequence. SFOS SAMs attached to the LMWOC layer readily wash off from UVO-treated PET. (C) 2009 Elsevier B.V. All rights reserved. C1 [Ozcam, Ali E.; Efimenko, Kirill; Spontak, Richard J.; Genzer, Jan] N Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA. [Jaye, Cherno; Fischer, Daniel A.] NIST, Div Ceram, Gaithersburg, MD 20899 USA. [Spontak, Richard J.] N Carolina State Univ, Dept Mat Sci & Engn, Raleigh, NC 27695 USA. RP Genzer, J (reprint author), N Carolina State Univ, Dept Chem & Biomol Engn, 911 Partners Way,POB 7905, Raleigh, NC 27695 USA. EM Jan_Genzer@ncsu.edu FU United Resource Recovery Corporation (URRC); U.S. Department of Energy, Division of Materials Sciences and Division of Chemical Sciences FX We thank the United Resource Recovery Corporation (URRC) for supporting this research and Dr. Ryan Fuierer from Asylum Research for his assistance with AFM measurements. The NEXAFS spectroscopy experiments were conducted at the National Synchrotron Light Source, Brookhaven National Laboratory, which is supported by the U.S. Department of Energy, Division of Materials Sciences and Division of Chemical Sciences. NR 37 TC 11 Z9 11 U1 0 U2 23 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0368-2048 EI 1873-2526 J9 J ELECTRON SPECTROSC JI J. Electron Spectrosc. Relat. Phenom. PD MAY PY 2009 VL 172 IS 1-3 SI SI BP 95 EP 103 DI 10.1016/j.elspec.2009.03.012 PG 9 WC Spectroscopy SC Spectroscopy GA 465DH UT WOS:000267561500014 ER PT J AU Wuenschel, MJ Able, KW Byrne, D AF Wuenschel, M. J. Able, K. W. Byrne, D. TI Seasonal patterns of winter flounder Pseudopleuronectes americanus abundance and reproductive condition on the New York Bight continental shelf SO JOURNAL OF FISH BIOLOGY LA English DT Article DE condition factor; energy allocation; gonado-somatic index; habitat; hepato-somatic index; spawning seasonality ID PLEURONECTES-PLATESSA L; COD GADUS-MORHUA; ENERGY CONTENT; ATLANTIC COD; GROWTH; FISHES; POPULATION; MATURATION; MOVEMENTS; PLAICE AB To resolve varied and sometimes conflicting accounts of spawning and habitat characteristics for winter flounder Pseudopleuronectes americanus, seasonal patterns in abundance and reproductive condition were investigated in the New York Bight, near the southern edge of their current reproductive range. Fish were collected from trawl surveys on the inner continental shelf from October 2006 to October 2007. Pseudopleuronectes americanus were most abundant during January and April surveys, were rarely collected in August, with intermediate abundances in June and October. Measurements of fish condition [hepato-somatic index (I(H)), condition factor (K) and the per cent dry mass of muscle tissue (%M(D))] and reproductive condition [gonado-somatic index (I(G))] were determined to evaluate seasonal changes in energy accumulation and depletion and reproduction. Males and females had similar patterns in body and reproductive condition, although the magnitude of change was greater for females. I(H) values were highest during spring and early summer, suggesting increased feeding following spawning. K and %M(D) increased through spring and summer then declined in the autumn and winter concurrent with gonadal development. Gonads began developing in the autumn, and in January, I(G) values approached spawning levels, with many spent individuals collected in spring. Within these general patterns, however, there was a large degree of variability among individuals, and a few mature non-reproductive ('skipped spawning') females were observed. In the period after spawning, increased energy intake, indicated by increased I(H), may influence reproductive output since this energy is gradually transferred to the muscle and used for gonadal development in the forthcoming year. The occurrence of ripening individuals on the inner continental shelf in January suggests that these fish either rapidly move into estuaries to spawn by February-March or they remain on the inner shelf to spawn, or some combination of these. Future studies should evaluate these possibilities, as both estuarine and inner shelf habitats are potentially affected by activities such as dredging, sand dredging and wind energy development. C1 [Wuenschel, M. J.; Able, K. W.] Rutgers State Univ, Marine Field Stn, Tuckerton, NJ 08087 USA. [Byrne, D.] New Jersey Dept Environm Protect, Nacote Creek Res Stn, Port Republic, NJ 08241 USA. RP Wuenschel, MJ (reprint author), Natl Marine Fisheries Serv, NE Fisheries Sci Ctr, Woods Hole Lab, 166 Water St, Woods Hole, MA 02543 USA. EM mark.wuenschel@noaa.gov FU Institute of Marine and Coastal Sciences, Rutgers University FX The authors thank New Jersey Department of Environmental Protection personnel (L. Barry, A. Mazzarella and S. Reap), the staff at the Rutgers University Marine Field Station and Captain S. Cluett and crew of the R.V. Seawolf for assistance. T. Grothues provided estuarine samples from the Navesink River. We also thank J. Burnett, T. Grothues, R. McBride, P. Scarlett, S. Cadrin and anonymous reviewers for comments on earlier drafts. The views expressed herein are those of the authors and do not necessarily reflect the views of NOAA or any of its subagencies. This paper is contribution No. 2009-1 from the Institute of Marine and Coastal Sciences, Rutgers University. NR 64 TC 20 Z9 21 U1 0 U2 6 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 0022-1112 J9 J FISH BIOL JI J. Fish Biol. PD MAY PY 2009 VL 74 IS 7 BP 1508 EP 1524 DI 10.1111/j.1095-8649.2009.02217.x PG 17 WC Fisheries; Marine & Freshwater Biology SC Fisheries; Marine & Freshwater Biology GA 438JB UT WOS:000265550600012 PM 20735650 ER PT J AU Richards, VP Henning, M Witzell, W Shivji, MS AF Richards, Vincent P. Henning, Marcy Witzell, Wayne Shivji, Mahmood S. TI Species Delineation and Evolutionary History of the Globally Distributed Spotted Eagle Ray (Aetobatus narinari) SO JOURNAL OF HEREDITY LA English DT Article DE batoid; conservation; evolutionary history; speciation ID MOLECULAR PHYLOGENETICS; TESTING HYPOTHESES; SEQUENCE ALIGNMENT; COMBINING DATA; RIBOSOMAL DNA; FRESH-WATER; GENE FLOW; PHYLOGEOGRAPHY; CONSERVATION; SPECIATION AB The spotted eagle ray (Aetobatus narinari), a large coral reef-associated batoid of conservation concern, is currently described as a single, circumglobally distributed species. However, geographic differences in its morphology and parasite diversity have raised unconfirmed suspicions that A. narinari may constitute a species complex. We used 1570 bp of mitochondrial and nuclear sequence data (cytochrome b, cytochrome c oxidase subunit I, and internal transcribed spacer 2) to assess the validity of A. narinari as a single cosmopolitan species and infer its evolutionary history. Specimens from 4 major geographic regions were examined: the Central Atlantic, Eastern Pacific, Western Pacific, and Central Pacific. Phylogenies described 3 distinct, reciprocally monophyletic lineages with no genetic exchange among regions. Based on combined genealogical concordance and genetic distance criteria, we recommend that the Western/Central Pacific lineage be recognized as a distinct species from lineages in the Central Atlantic and Eastern Pacific. The latter 2 lineages, separated by the Isthmus of Panama, are proposed as subspecies. A basal position in phylogenetic analyses and statistical parsimony results support an Indo-West Pacific origin for the A. narinari species complex, with subsequent westerly dispersal around the southern tip of Africa into the Atlantic and then into the Eastern Pacific. C1 [Richards, Vincent P.; Shivji, Mahmood S.] Nova SE Univ, Natl Coral Reef Inst, Oceanog Ctr, Dania, FL 33004 USA. [Richards, Vincent P.; Shivji, Mahmood S.] Nova SE Univ, Save Our Seas Shark Ctr, Oceanog Ctr, Dania, FL 33004 USA. [Henning, Marcy; Shivji, Mahmood S.] Nova SE Univ, Guy Harvey Res Inst, Oceanog Ctr, Dania, FL 33004 USA. [Witzell, Wayne] SE Fisheries Sci Ctr, Natl Marine Fisheries Serv, Miami, FL 33149 USA. RP Shivji, MS (reprint author), Nova SE Univ, Natl Coral Reef Inst, Oceanog Ctr, 8000 N Ocean Dr, Dania, FL 33004 USA. EM mahmood@nova.edu FU NOAA Center [NA04NOS4260065]; Save Our Seas Foundation [71]; Guy Harvey Research Institute operational funds FX NOAA Center for Sponsored Coastal Ocean Science award #NA04NOS4260065 to the National Coral Reef Institute; the Save Our Seas Foundation Project grant 71; the Guy Harvey Research Institute operational funds. This is NCRI publication No. 111. NR 77 TC 36 Z9 36 U1 1 U2 22 PU OXFORD UNIV PRESS INC PI CARY PA JOURNALS DEPT, 2001 EVANS RD, CARY, NC 27513 USA SN 0022-1503 EI 1465-7333 J9 J HERED JI J. Hered. PD MAY-JUN PY 2009 VL 100 IS 3 BP 273 EP 283 DI 10.1093/jhered/esp005 PG 11 WC Evolutionary Biology; Genetics & Heredity SC Evolutionary Biology; Genetics & Heredity GA 434JY UT WOS:000265272200001 PM 19304741 ER PT J AU Roden, SE Dutton, PH Morin, PA AF Roden, Suzanne E. Dutton, Peter H. Morin, Phillip A. TI AFLP Fragment Isolation Technique as a Method to Produce Random Sequences for Single Nucleotide Polymorphism Discovery in the Green Turtle, Chelonia mydas SO JOURNAL OF HEREDITY LA English DT Article DE AFLP; Chelonia mydas; green turtle; single nucleotide polymorphism; SNP ID POPULATION GENETIC-STRUCTURE; ANONYMOUS NUCLEAR LOCI; MICROSATELLITE LOCI; SNP; MARKERS; IDENTIFICATION; CONSERVATION; FLOW; DNA; MITOCHONDRIAL AB The green sea turtle, Chelonia mydas, was used as a case study for single nucleotide polymorphism (SNP) discovery in a species that has little genetic sequence information available. As green turtles have a complex population structure, additional nuclear markers other than microsatellites could add to our understanding of their complex life history. Amplified fragment length polymorphism technique was used to generate sets of random fragments of genomic DNA, which were then electrophoretically separated with precast gels, stained with SYBR green, excised, and directly sequenced. It was possible to perform this method without the use of polyacrylamide gels, radioactive or fluorescent labeled primers, or hybridization methods, reducing the time, expense, and safety hazards of SNP discovery. Within 13 loci, 2547 base pairs were screened, resulting in the discovery of 35 SNPs. Using this method, it was possible to yield a sufficient number of loci to screen for SNP markers without the availability of prior sequence information. C1 [Roden, Suzanne E.; Dutton, Peter H.; Morin, Phillip A.] Natl Marine Fisheries Serv, SW Fisheries Sci Ctr, La Jolla, CA 92037 USA. [Roden, Suzanne E.] Univ San Diego, Dept Marine Sci, San Diego, CA 92110 USA. RP Roden, SE (reprint author), Natl Marine Fisheries Serv, SW Fisheries Sci Ctr, 8604 La Jolla Shores Dr, La Jolla, CA 92037 USA. EM suzanne.roden@noaa.gov FU National Marine Fisheries Service; Southwest Fisheries Science Center FX National Marine Fisheries Service; Southwest Fisheries Science Center. NR 27 TC 9 Z9 9 U1 2 U2 11 PU OXFORD UNIV PRESS INC PI CARY PA JOURNALS DEPT, 2001 EVANS RD, CARY, NC 27513 USA SN 0022-1503 J9 J HERED JI J. Hered. PD MAY-JUN PY 2009 VL 100 IS 3 BP 390 EP 393 DI 10.1093/jhered/esn108 PG 4 WC Evolutionary Biology; Genetics & Heredity SC Evolutionary Biology; Genetics & Heredity GA 434JY UT WOS:000265272200014 PM 19074754 ER PT J AU Cheng, GJ Shull, RD Walker, ARH AF Cheng, Guangjun Shull, Robert D. Walker, A. R. Hight TI Dipolar chains formed by chemically synthesized cobalt nanocubes SO JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS LA English DT Article; Proceedings Paper CT 7th International Conference on Scientific and Clinical Applications of Magnetic Carriers CY MAY 20-24, 2008 CL Vancouver, CANADA DE Cobalt; Nanocubes; Magnetic nanoparticles; Dipolar chains; Magnetic property ID ELECTRON HOLOGRAPHY; NANOPARTICLES; ASSEMBLIES; SHAPE; NANOSCALE; MAGNETITE; SIZE AB Cobalt nanocubes with an average edge length of 50 nm and epsilon crystalline structure were synthesized via thermo-decomposition in 1,2-dichlorobenzene at 120 degrees C in the presence of surfactants. These nanocubes form dipolar chains upon drying in zero applied field and bundles of chains along the direction of an applied magnetic field. The magnetic measurements reveal strong interparticle couplings among the nanocubes in their dried magnetic-field-induced assemblies. The constricted hysteresis loops and near-zero coercivity indicate the existence of vortex states in the assemblies. Exposure to electron beam heats up the nanocubes and turns the dipolar chains into nanowires. (C) 2009 Elsevier B.V. All rights reserved. C1 [Cheng, Guangjun; Walker, A. R. Hight] NIST, Opt Technol Div, Gaithersburg, MD 20899 USA. [Shull, Robert D.] NIST, Div Met, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA. RP Cheng, GJ (reprint author), NIST, Opt Technol Div, Gaithersburg, MD 20899 USA. EM guangjun.cheng@nist.gov RI Shull, Robert/F-5971-2013; Hight Walker, Angela/C-3373-2009 OI Hight Walker, Angela/0000-0003-1385-0672 NR 25 TC 7 Z9 7 U1 2 U2 9 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0304-8853 J9 J MAGN MAGN MATER JI J. Magn. Magn. Mater. PD MAY PY 2009 VL 321 IS 10 BP 1351 EP 1355 DI 10.1016/j.jmmm.2009.02.037 PG 5 WC Materials Science, Multidisciplinary; Physics, Condensed Matter SC Materials Science; Physics GA 434ME UT WOS:000265278000005 ER PT J AU Maki, A Masiello, T Blake, TA Nibler, JW Weber, A AF Maki, Arthur Masiello, Tony Blake, Thomas A. Nibler, Joseph W. Weber, Alfons TI On the determination of C-0 (or A(0)), D-0(K), H-0(K), and some dark states for symmetric-top molecules from infrared spectra without the need for localized perturbations SO JOURNAL OF MOLECULAR SPECTROSCOPY LA English DT Article DE Spectroscopy; Infrared spectroscopy; Molecular structure; Rotational constants; Boron trifluoride; Sulfur trioxide; Cyclopropane; Allene ID MICROWAVE FOURIER-TRANSFORM; PURE ROTATIONAL SPECTRUM; DOUBLE-RESONANCE; 4600 CM(-1); SPECTROSCOPY; (BF3)-B-11; CONSTANTS; BANDS; AO; COMBINATION AB For symmetric-top molecules, the normal Delta k = 0, Delta l = 0 and Delta k = +/- 1, Delta l = +/- 1 selection rules for parallel and perpendicular bands, respectively, do not allow the determination of the K-dependent rotational constants, C-0 (or A(0)), D-0(K), H-0(K) However, we show here that several different combinations of allowed and apparently unperturbed rovibrational infrared transitions can give access to those constants. A necessary ingredient for the application of this technique is a band with selection rules Delta k = +/- 1 (or Delta k = 0). Delta l = -/+ 2, such as an overtone or difference band, and appropriate other bands. Bands with selection rules Delta k = +/- 2, Delta l = -/+ 1 are also useful but are seldom found. As a general rule, more than one vibrational transition is needed. Examples are given for boron trifluoride (BF3 Sulfur trioxide (SO3), and cyclopropane (C3H6) for which there are microwave measurements that provide a check on the derived constants. The technique is also extended to a D-2d molecule, allene, even though we have no measurements to use as an example, Examples are also given for the determination of dark states from difference bands, and/or hot bands, and also whole forbidden bands that arise from mixing with distant energy levels. (C) 2009 Elsevier Inc. All rights reserved. C1 [Masiello, Tony; Blake, Thomas A.] Pacific NW Natl Lab, Richland, WA 99352 USA. [Nibler, Joseph W.] Oregon State Univ, Dept Chem, Corvallis, OR 97332 USA. [Weber, Alfons] Natl Inst Stand & Technol, Opt Technol Div, Gaithersburg, MD 20899 USA. RP Masiello, T (reprint author), Calif State Univ Hayward, Dept Chem, East Bay,25800 Carlos Bee Blvd, Hayward, CA 94542 USA. EM tony.masiello@csueastbay.edu FU Department of Energy's Office of Biological and Environmental Research; Pacific Northwest National Laboratory; United States Department of Energy; Battelle Memorial Institute [AC05-76RL01830] FX The research described here was performed in the Environmental Molecular Sciences Laboratory, a National Scientific User Facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at the Pacific Northwest National Laboratory. The Pacific Northwest National Laboratory is operated for the United States Department of Energy by the Battelle Memorial Institute Linder contract number AC05-76RL01830. NR 22 TC 5 Z9 5 U1 0 U2 0 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0022-2852 J9 J MOL SPECTROSC JI J. Mol. Spectrosc. PD MAY PY 2009 VL 255 IS 1 BP 56 EP 62 DI 10.1016/j.jms.2009.02.004 PG 7 WC Physics, Atomic, Molecular & Chemical; Spectroscopy SC Physics; Spectroscopy GA 441GT UT WOS:000265758000008 ER PT J AU Cronin, MF Kessler, WS AF Cronin, Meghan F. Kessler, William S. TI Near-Surface Shear Flow in the Tropical Pacific Cold Tongue Front SO JOURNAL OF PHYSICAL OCEANOGRAPHY LA English DT Article ID EQUATORIAL PACIFIC; EKMAN BALANCE; UPPER OCEAN; DIAGNOSTIC MODEL; WIND STRESS; PARAMETERIZATION; SEA; VARIABILITY; TEMPERATURE; TURBULENCE AB Near-surface shear in the Pacific cold tongue front at 2 degrees N, 140 degrees W was measured using a set of five moored current meters between 5 and 25 m for nine months during 2004-05. Mean near-surface currents were strongly westward and only weakly northward (similar to 3 cm s(-1)). Mean near-surface shear was primarily westward and, thus, oriented to the left of the southeasterly trades. When the southwestward geostrophic shear was subtracted from the observed shear, the residual ageostrophic currents relative to 25 m were northward and had an Ekman-like spiral, in qualitative agreement with an Ekman model modified for regions with a vertically uniform front. According to this "frontal Ekman'' model, the ageostrophic Ekman spiral is forced by the portion of the wind stress that is not balanced by the surface geostrophic shear. Analysis of a composite tropical instability wave (TIW) confirms that ageostrophic shear is minimized when winds blow along the front, and strengthens when winds blow oblique to the front. Furthermore, the magnitude of the near-surface shear, both in the TIW and diurnal composites, was sensitive to near-surface stratification and mixing. A diurnal jet was observed that was on average 12 cm s(-1) stronger at 5 m than at 25 m, even though daytime stratification was weak. The resulting Richardson number indicates that turbulent viscosity is larger at night than daytime and decreases with depth. A "generalized Ekman'' model is also developed that assumes that viscosity becomes zero below a defined frictional layer. The generalized model reproduces many of the features of the observed mean shear and is valid both in frontal regions and at the equator. C1 [Cronin, Meghan F.; Kessler, William S.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. RP Cronin, MF (reprint author), NOAA, Pacific Marine Environm Lab, 7600 Sand Point Way NE, Seattle, WA 98115 USA. EM meghan.f.cronin@noaa.gov NR 40 TC 18 Z9 18 U1 1 U2 7 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0022-3670 J9 J PHYS OCEANOGR JI J. Phys. Oceanogr. PD MAY PY 2009 VL 39 IS 5 BP 1200 EP 1215 DI 10.1175/2008JPO4064.1 PG 16 WC Oceanography SC Oceanography GA 450EA UT WOS:000266382600008 ER PT J AU Pullela, SR Shen, JY Marquez, M Cheng, ZD AF Pullela, Srinivasa R. Shen, Jingyi Marquez, Manuel Cheng, Zhengdong TI A Comparative Study of Temperature Dependence of Induction Time and Oscillatory Frequency in Polymer-Immobilized and Free Catalyst Belousov-Zhabotinsky Reactions SO JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS LA English DT Article DE activation energy; Belousov-Zhabotinsky reaction; catalysts; induction time; microgels ID SOLUBLE-INSOLUBLE CHANGES; CHEMICAL OSCILLATION; SELF-OSCILLATION; MEMORY DEVICE; SYSTEM; WAVES; GEL; MOTION; PATTERNS; DRIVEN AB Environment-sensitive poly(N-isopropylacrylamide) (PNIPAM) microgel particles with covalently bonded ruthenium(4-vinyl-4'-methyl-2,2'-bipyridine) bis (2,2'-bipyridine) [Ru(vmbipy)(bipy)(2)] display periodic size changes when placed in Belousov-Zhabotinsky (BZ) reaction substrates. The temperature dependency of the induction time and oscillatory frequency of the BZ reaction in this polymer-immobilized catalyst system were compared to the bulk BZ reaction with the catalyst in the solution phase. Prolonged induction times are observed for the immobilized catalyst, compared with free catalyst, while little difference is observed on the oscillation frequency. The Arrbenius frequency factor calculated using the induction time for the immobilized catalyst BZ reaction is about seven times smaller than that for the free catalyst Ru(bipy)(3)(2+) case. On the other hand, the Arrhenius frequency factors calculated using the oscillatory frequency are almost the same, showing similar reaction kinetics during the BZ oscillations. The tunability of the induction time using a polymer matrix, as we observed here, while maintaining similar oscillatory behavior, should provide a new dimension to control the self-assembling of BZ active particles. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part 13: Polym Phys 47: 847-854, C1 [Pullela, Srinivasa R.; Shen, Jingyi; Cheng, Zhengdong] Texas A&M Univ, Artie McFerrin Dept Chem Engn, College Stn, TX 77843 USA. [Marquez, Manuel] Arizona State Univ, Harrington Dept Bioengn, Tempe, AZ 85287 USA. [Marquez, Manuel] NIST, Ctr Theoret & Computat Nanosci, Gaithersburg, MD 20899 USA. [Marquez, Manuel] Los Alamos Natl Lab, Ctr Integrated Nanotechnol, Los Alamos, NM 87545 USA. RP Cheng, ZD (reprint author), Texas A&M Univ, Artie McFerrin Dept Chem Engn, College Stn, TX 77843 USA. EM zhengdong.cheng@chemail.tamu.edu FU Texas Engineering Experiment Station (TEES); Texas AM University FX The authors thank Professors Michael Bevan and Arul Jayaraman for sharing their research equipment, and the Materials Characterization Facilities (MCF) center at Texas A&M University for its research facilities. The authors are also grateful to our colleagues, Dr. Dawei Luo, Peng He, Shannon Eichmann, and Richard Beckbam, for their help with the equipment. This work is supported by the startup fund of Texas Engineering Experiment Station (TEES), and Texas A&M University. NR 46 TC 4 Z9 5 U1 1 U2 17 PU JOHN WILEY & SONS INC PI HOBOKEN PA 111 RIVER ST, HOBOKEN, NJ 07030 USA SN 0887-6266 J9 J POLYM SCI POL PHYS JI J. Polym. Sci. Pt. B-Polym. Phys. PD MAY 1 PY 2009 VL 47 IS 9 BP 847 EP 854 DI 10.1002/polb.21682 PG 8 WC Polymer Science SC Polymer Science GA 435AZ UT WOS:000265316900001 ER PT J AU Colle, R AF Colle, R. TI Radionuclidic standardization by primary methods: An overview SO JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY LA English DT Article; Proceedings Paper CT 2nd International Nuclear Chemistry Congress (2nd-INCC) CY APR 13-17, 2008 CL Cancun, MEXICO ID METROLOGY; SYSTEM; RADON; NEEDS; NI-63; NBS AB Primary methods of radionuclidic standardization serve as the underlying basis of the physical measurement standards of activity that are needed in virtually every sub-discipline of radioanalytical and nuclear chemistry. Primary methods refer to the direct measurement of the number of nuclear transformations that occur per unit time, without recourse to other calibrations or standards. Such measurements, leading to the development and dissemination of radioactivity standards, are primarily performed under the purview of national metrology laboratories, like the National Institute of Standards and Technology (NIST) in the USA. This paper briefly reviews some of the various primary methods that have been developed by many such laboratories over many years. Their features and their role in ensuring the quality of radioactivity measurements are highlighted by several primary standardizations that have been recently performed at NIST. C1 NIST, Phys Lab, Gaithersburg, MD 20899 USA. RP Colle, R (reprint author), NIST, Phys Lab, Gaithersburg, MD 20899 USA. EM rcolle@nist.gov NR 45 TC 6 Z9 6 U1 0 U2 4 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0236-5731 J9 J RADIOANAL NUCL CH JI J. Radioanal. Nucl. Chem. PD MAY PY 2009 VL 280 IS 2 BP 265 EP 273 DI 10.1007/s10967-009-0509-5 PG 9 WC Chemistry, Analytical; Chemistry, Inorganic & Nuclear; Nuclear Science & Technology SC Chemistry; Nuclear Science & Technology GA 440QE UT WOS:000265714000010 ER PT J AU Jendzurski, J Paulter, NG AF Jendzurski, John Paulter, Nicholas G. TI Calibration of Speed Enforcement Down-The-Road Radars SO JOURNAL OF RESEARCH OF THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY LA English DT Article DE calibration; down the road radar; DTR radar; radar; traffic radar; uncertainty AB We examine the measurement uncertainty associated with different methods of calibrating the ubiquitous down-the-road (DTR) radar used in speed enforcement. These calibration methods include the use of audio frequency sources, tuning forks, a fifth wheel attached to the rear of the vehicle with the radar unit, and the speedometer of the vehicle. We also provide an analysis showing the effect of calibration uncertainty on DTR-radar speed measurement uncertainty. C1 [Jendzurski, John; Paulter, Nicholas G.] Natl Inst Stand & Technol, Off Law Enforcement Stand, Elect & Elect Engn Lab, US Dept Commerce, Gaithersburg, MD 20899 USA. RP Jendzurski, J (reprint author), Natl Inst Stand & Technol, Off Law Enforcement Stand, Elect & Elect Engn Lab, US Dept Commerce, Gaithersburg, MD 20899 USA. EM john.jendzurski@nist.gov; nicholas.paulter@nist.gov NR 5 TC 5 Z9 5 U1 0 U2 3 PU US GOVERNMENT PRINTING OFFICE PI WASHINGTON PA SUPERINTENDENT DOCUMENTS,, WASHINGTON, DC 20402-9325 USA SN 1044-677X J9 J RES NATL INST STAN JI J. Res. Natl. Inst. Stand. Technol. PD MAY-JUN PY 2009 VL 114 IS 3 BP 137 EP 148 DI 10.6028/jres.114.009 PG 12 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 485NT UT WOS:000269130900001 PM 27504217 ER PT J AU Ma, LJ Mink, A Tang, X AF Ma, Lijun Mink, Alan Tang, Xiao TI High Speed Quantum Key Distribution Over Optical Fiber Network System SO JOURNAL OF RESEARCH OF THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY LA English DT Article DE detection time bin shift; fiber network; frequency up-conversion detection; quantum key distribution; BB84; B92 ID GBPS CLOCK SYNCHRONIZATION; CRYPTOGRAPHY SYSTEMS; SHORT-WAVELENGTH; UP-CONVERSION; LIMITS AB The National Institute of Standards and Technology (NIST) has developed a number of complete fiber-based high-speed quantum key distribution (QKD) systems that includes an 850 nm QKD system for a local area network (LAN), a 1310 nm QKD system for a metropolitan area network ( MAN), and a 3-node quantum network controlled by a network manager. This paper discusses the key techniques used to implement these systems, which include polarization recovery, noise reduction, frequency up-conversion detection based on a periodically polled lithium nitrate (PPLN) waveguide, custom high-speed data handling boards and quantum network management. Using our quantum network, a QKD secured video surveillance application has been demonstrated. Our intention is to show the feasibility and sophistication of QKD systems based on current technology. C1 [Ma, Lijun; Mink, Alan; Tang, Xiao] Natl Inst Stand & Technol, Informat Technol Lab, Gaithersburg, MD 20899 USA. RP Ma, LJ (reprint author), Natl Inst Stand & Technol, Informat Technol Lab, Gaithersburg, MD 20899 USA. EM lijun.ma@nist.gov; alan.mink@nist.gov; xiao.tang@nist.gov FU NIST quantum information initiative FX This work was supported by the NIST quantum information initiative. This work is an extension of the QuIST program supported in part by the Defense Advanced Research Projects Agency (DARPA). We wish to acknowledge the important contributions from Hai Xu on the development of our 1310 nm QKD system, from Barry Hershman for fabrication and testing of our high-speed data handling boards and from Tassos Nakassis for his development of our error correction and privacy amplification algorithms. We would also like to thank Joshua Bienfang for his extensive technical discussions. NR 44 TC 1 Z9 2 U1 1 U2 7 PU US GOVERNMENT PRINTING OFFICE PI WASHINGTON PA SUPERINTENDENT DOCUMENTS,, WASHINGTON, DC 20402-9325 USA SN 1044-677X J9 J RES NATL INST STAN JI J. Res. Natl. Inst. Stand. Technol. PD MAY-JUN PY 2009 VL 114 IS 3 BP 149 EP 177 DI 10.6028/jres.114.010 PG 29 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 485NT UT WOS:000269130900002 PM 27504218 ER PT J AU Tarrio, C AF Tarrio, Charles TI Method for the Characterization of Extreme-Ultraviolet Photoresist Outgassing SO JOURNAL OF RESEARCH OF THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY LA English DT Article DE contamination; extreme ultraviolet; outgassing; photoresist; vacuum ID MULTILAYER MIRRORS; SURFACES AB Outgassing from photoresists illuminated by extreme ultraviolet radiation can lead to degradation of the very expensive multilayer-coated optics in an extreme ultraviolet stepper. Reliable quantification of the various organic molecules outgassed by photoresists has been a challenging goal. We have designed a compact system for this measurement. In the first step, the total number of molecules emitted by the photoresist is measured using a pressure-rise method in a closed vacuum chamber, with the pressure measured by mechanical means using a capacitance displacement gauge. To provide identification and relative abundances, the outgassed molecules are then collected in an evacuated trap cooled by liquid nitrogen for subsequent analysis by gas chromatography with mass spectrometry. We will discuss the design and performance of the system. C1 Natl Inst Stand & Technol, Div Electron & Opt Phys, Gaithersburg, MD 20899 USA. RP Tarrio, C (reprint author), Natl Inst Stand & Technol, Div Electron & Opt Phys, Gaithersburg, MD 20899 USA. EM charles.tarrio@nist.gov FU Intel Corporation FX This work was supported in part by Intel Corporation. NR 8 TC 5 Z9 5 U1 0 U2 6 PU US GOVERNMENT PRINTING OFFICE PI WASHINGTON PA SUPERINTENDENT DOCUMENTS,, WASHINGTON, DC 20402-9325 USA SN 1044-677X J9 J RES NATL INST STAN JI J. Res. Natl. Inst. Stand. Technol. PD MAY-JUN PY 2009 VL 114 IS 3 BP 179 EP 183 DI 10.6028/jres.114.011 PG 5 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 485NT UT WOS:000269130900003 PM 27504219 ER PT J AU Cooper, JW Coplan, MA Hughes, PP AF Cooper, John W. Coplan, Michael A. Hughes, Patrick P. TI The Detection of Lyman Alpha Radiation Formed by the Slowing Down of Protons and Tritons Produced by the He-3 (n,tp) Reaction-A Model Study SO JOURNAL OF RESEARCH OF THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY LA English DT Article DE charge exchange; computer modeling; Lyman alpha radiation; neutron detection AB The observation of Lyman alpha (L alpha) radiation produced by the end products of the He-3 (n,tp) reaction has suggested the possibility of a new method of cold thermal neutron detection. In order for this goal to be achieved, a basic understanding of how the L alpha radiation is formed and how it may be detected, is needed. The model study described here is an attempt to provide this basic understanding and to provide quantitative results that can be used in designing future experiments. C1 [Cooper, John W.; Coplan, Michael A.; Hughes, Patrick P.] Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA. [Hughes, Patrick P.] Natl Inst Stand & Technol, Ionizing Radiat Div, Gaithersburg, MD 20899 USA. RP Cooper, JW (reprint author), Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA. EM jwc@umd.edu; coplan@umd.edu; patrick.hughes@nist.gov FU OPM [CSA-3115486] FX Dr. Alan K. Thompson made a number of useful suggestions during the course of this work and substantially improved the quality of the presentation. J.W.C. acknowledges support from OPM under contract No. CSA-3115486. NR 11 TC 2 Z9 2 U1 0 U2 1 PU US GOVERNMENT PRINTING OFFICE PI WASHINGTON PA SUPERINTENDENT DOCUMENTS,, WASHINGTON, DC 20402-9325 USA SN 1044-677X J9 J RES NATL INST STAN JI J. Res. Natl. Inst. Stand. Technol. PD MAY-JUN PY 2009 VL 114 IS 3 BP 185 EP 194 DI 10.6028/jres.114.012 PG 10 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 485NT UT WOS:000269130900004 PM 27504220 ER PT J AU Gilliam, D Leigh, S Rukhin, A Strawderman, W AF Gilliam, David Leigh, Stefan Rukhin, Andrew Strawderman, William TI Pass-Fail Testing: Statistical Requirements and Interpretations SO JOURNAL OF RESEARCH OF THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY LA English DT Article DE binomial distribution; confidence bounds; confidence coefficient; critical value; probability of detection; probability of false alarm AB Performance standards for detector systems often include requirements for probability of detection and probability of false alarm at a specified level of statistical confidence. This paper reviews the accepted definitions of confidence level and of critical value. It describes the testing requirements for establishing either of these probabilities at a desired confidence level. These requirements are computable in terms of functions that are readily avail-able in statistical software packages and general spreadsheet applications. The statistical interpretations of the critical values are discussed. A table is included for illustration, and a plot is presented showing the minimum required numbers of pass-fail tests. The results given here are applicable to one-sided testing of any system with performance characteristics conforming to a binomial distribution. C1 [Gilliam, David; Leigh, Stefan; Rukhin, Andrew; Strawderman, William] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Gilliam, D (reprint author), Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. EM david.gilliam@nist.gov; stefan.leigh@nist.gov; andrew.rukhin@nist.gov; william.strawderman@nist.gov NR 5 TC 5 Z9 5 U1 0 U2 1 PU US GOVERNMENT PRINTING OFFICE PI WASHINGTON PA SUPERINTENDENT DOCUMENTS,, WASHINGTON, DC 20402-9325 USA SN 1044-677X J9 J RES NATL INST STAN JI J. Res. Natl. Inst. Stand. Technol. PD MAY-JUN PY 2009 VL 114 IS 3 BP 195 EP 199 DI 10.6028/jres.114.013 PG 5 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 485NT UT WOS:000269130900005 PM 27504221 ER PT J AU Fanney, AH Dougherty, BP Davis, MW AF Fanney, A. Hunter Dougherty, Brian P. Davis, Mark W. TI Comparison of Predicted to Measured Photovoltaic Module Performance SO JOURNAL OF SOLAR ENERGY ENGINEERING-TRANSACTIONS OF THE ASME LA English DT Article; Proceedings Paper CT Conference of the ASME Solar Energy Division and Advanced Energy Systems Division CY JUN 27-29, 2007 CL Long Beach, CA SP ASME, Solar Energy Div, ASME, Adv Energy Syst Div DE amorphous semiconductors; building integrated photovoltaics; copper compounds; elemental semiconductors; indium compounds; modules; polymer blends; power measurement; semiconductor device measurement; silicon; solar cells; ternary semiconductors ID PANELS AB To accurately predict the electrical performance of photovoltaic modules computer simulation models are essential. Without such models, potential purchasers of photovoltaic systems have insufficient information to judge the relative merits and cost effectiveness of photovoltaic systems. The purpose of this paper is to compare the predictions of a simulation model, developed by Sandia National Laboratories, to measurements from photovoltaic modules installed in a vertical wall facade in Gaithersburg, MD. The photovoltaic modules were fabricated using monocrystalline, polycrystalline, tandem-junction amorphous, and copper-indium diselenide cells. Polycrystalline modules were constructed using three different glazing materials: 6 mm low-iron glass, 0.05 mm ethylene-tetrafluoroethylene copolymer, and 0.05 mm polyvinylidene fluoride. In order to only assess the simulation model's ability to predict photovoltaic module performance, measured solar radiation data in the plane of the modules is initially used. Additional comparisons are made using horizontal radiation measurements. The ability of the model to accurately predict the temperature of the photovoltaic cells is investigated by comparing predicted energy production using measured versus predicted photovoltaic cell temperatures. The model was able to predict the measured annual energy production of the photovoltaic modules, with the exception of the tandem-junction amorphous modules, to within 6% using vertical irradiance measurements. The model overpredicted the annual energy production by approximately 14% for the tandem-junction amorphous panels. Using measured horizontal irradiance as input to the simulation model, the agreement between measured and predicted annual energy predictions varied between 1% and 8%, again with the exception of the tandem-junction amorphous silicon modules. The large difference between measured and predicted results for the tandem-junction modules is attributed to performance degradation. Power measurements of the tandem-junction amorphous modules at standard reporting conditions prior to and after exposure revealed a 12% decline. Supplying post exposure module parameters to the model resulted in energy predictions within 5% of measured values. C1 [Fanney, A. Hunter; Dougherty, Brian P.; Davis, Mark W.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Fanney, AH (reprint author), Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. NR 12 TC 5 Z9 5 U1 0 U2 14 PU ASME-AMER SOC MECHANICAL ENG PI NEW YORK PA THREE PARK AVE, NEW YORK, NY 10016-5990 USA SN 0199-6231 J9 J SOL ENERG-T ASME JI J. Sol. Energy Eng. Trans.-ASME PD MAY PY 2009 VL 131 IS 2 AR 021011 DI 10.1115/1.3090826 PG 10 WC Energy & Fuels; Engineering, Mechanical SC Energy & Fuels; Engineering GA 433SI UT WOS:000265225700011 ER PT J AU Yang, Z Wong-Ng, W Kaduk, JA Jang, M Liu, G AF Yang, Z. Wong-Ng, W. Kaduk, J. A. Jang, M. Liu, G. TI Phase equilibria and crystal chemistry of the R-Cu-Ti-O systems (R = lanthanides and Y) SO JOURNAL OF SOLID STATE CHEMISTRY LA English DT Article DE R-Cu-Ti-O (R = lanthanides); Coated conductors; Phase equilibria; Crystal chemistry; Reference X-ray powder patterns ID PEROVSKITE-LIKE COMPOUND; BOND-VALENCE PARAMETERS; BA2YCU3O7-X THIN-FILMS; EFFECTIVE IONIC-RADII; DIELECTRIC-CONSTANT; HTS WIRE; DEPOSITION; FABRICATION; SUPERCONDUCTORS; REFINEMENT AB As part of the study of interaction of the Ba(2)RCu(3)O(6+2) (R = lanthanides and Y) superconductor with SrTiO(3) buffer, phase equilibria of the subsystem, R(2)O(3)-TiO(2)-CuO (R = Nd, Y, and Yb), have been investigated in air at 960 degrees C. While the phase relationships of the two phase diagrams with smaller R (Y and Yb) are similar, substantial differences were found in the Nd(2)O(3)-TiO(2)-CuO system, partly due to different phase formation in the binary R(2)O(3)-TiO(2) and R(2)O(3)-CuO systems. R(2)CuTiO(6) and R(2)Cu(9)Ti(12)O(36) were the only ternary phases established in all the three diagrams. R(2)Cu(9)Ti(12)O(36) belongs to the perovskite-related [AC(3)](B(4))O(12) family which is cubic Im3. Depending on the size of R(3+), R(2)CuTiO(6) crystallizes in two crystal systems: Pnma (R = La-Gd), and P6(3)cm (R = Dy-Lu). The structure and crystal chemistry of the Pnma series of R(2)CuTiO(6) (R = La, Nd, Sm, Eu, and Gd) are discussed in detail in this paper. Patterns for selected members of R(2)CuTiO(6) have also been prepared and submitted for inclusion in the Powder Diffraction File (PDF). Published by Elsevier Inc. C1 [Wong-Ng, W.; Liu, G.] Natl Inst Stand & Technol, Div Ceram, Gaithersburg, MD 20899 USA. [Yang, Z.] Yunnan Normal Univ, Kunming 650092, Peoples R China. [Kaduk, J. A.] INEOS Technol, Naperville, IL 60563 USA. [Jang, M.] Yonsei Univ, Seoul 120740, South Korea. RP Wong-Ng, W (reprint author), Natl Inst Stand & Technol, Div Ceram, Gaithersburg, MD 20899 USA. EM Winnie.wong-ng@nist.gov FU US Department of Energy; International Centre for diffraction Data FX The authors acknowledge the partial financial support from the US Department of Energy and also from International Centre for diffraction Data. Mr. N. Swanson is thanked for his graphical assistance. NR 45 TC 3 Z9 3 U1 2 U2 9 PU ACADEMIC PRESS INC ELSEVIER SCIENCE PI SAN DIEGO PA 525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA SN 0022-4596 J9 J SOLID STATE CHEM JI J. Solid State Chem. PD MAY PY 2009 VL 182 IS 5 BP 1142 EP 1148 DI 10.1016/j.jssc.2008.11.010 PG 7 WC Chemistry, Inorganic & Nuclear; Chemistry, Physical SC Chemistry GA 443ET UT WOS:000265893700024 ER PT J AU Parrish, CE Nowak, RD AF Parrish, Christopher E. Nowak, Robert D. TI Improved Approach to LIDAR Airport Obstruction Surveying Using Full-Waveform Data SO JOURNAL OF SURVEYING ENGINEERING-ASCE LA English DT Article ID AIRBORNE LASER SCANNER; SMALL-FOOTPRINT; DECOMPOSITION AB Over the past decade, the National Oceanic and Atmospheric Administration's National Geodetic Survey, in collaboration with multiple organizations, has conducted research into airport obstruction surveying using airborne light detection and ranging (LIDAR). What was initially envisioned as a relatively straightforward demonstration of the utility of this emerging remote sensing technology for airport surveys was quickly shown to be a challenging undertaking fraught with both technical and practical issues. We provide a brief history of previous work in LIDAR airport obstruction surveying, including a discussion of both past achievements and previously unsolved problems. We then present a new processing workflow, specifically designed to overcome the remaining problems. A key facet of our approach is the use of a new LIDAR waveform deconvolution and georeferencing strategy that produces very dense, detailed point clouds in which the vertical structures of objects are well characterized. Additional processing steps have been carefully selected and ordered based on the objectives of meeting Federal Aviation Administration requirements and maximizing efficiency. Tests conducted using LIDAR waveform data for two project sites demonstrate the efficacy of the approach. C1 [Parrish, Christopher E.] NOAA, Natl Geodet Survey, Silver Spring, MD 20910 USA. [Nowak, Robert D.] Univ Wisconsin, Dept Elect & Comp Engn, Madison, WI 53706 USA. RP Parrish, CE (reprint author), NOAA, Natl Geodet Survey, 1315 East West Highway, Silver Spring, MD 20910 USA. EM chris.parrish@noaa.gov RI Rogers, King/G-5482-2010 NR 37 TC 21 Z9 22 U1 0 U2 6 PU ASCE-AMER SOC CIVIL ENGINEERS PI RESTON PA 1801 ALEXANDER BELL DR, RESTON, VA 20191-4400 USA SN 0733-9453 J9 J SURV ENG-ASCE JI J. Surv. Eng.-ASCE PD MAY PY 2009 VL 135 IS 2 BP 72 EP 82 DI 10.1061/(ASCE)0733-9453(2009)135:2(72) PG 11 WC Engineering, Civil SC Engineering GA 433ZA UT WOS:000265243100005 ER PT J AU Quinn, GD Sparenberg, BT Koshy, P Ives, LK Jahanmir, S Arola, DD AF Quinn, George D. Sparenberg, Brian T. Koshy, Philip Ives, Lewis K. Jahanmir, Said Arola, Dwayne D. TI Flexural Strength of Ceramic and Glass Rods SO JOURNAL OF TESTING AND EVALUATION LA English DT Article DE ASTM C-1684; ceramics; cradles; glass; flexural strength; three-point loading; four-point loading; brittle materials; standard; rods; cylindrical specimens; errors; silicon nitride; strain gage; Weibull statistics; wedging error; concentrated load error; friction error; large deflection; contact cracks; initial curvature error; eccentric loading error; wrong span error; poor articulation; contact point tangency shift error ID IN-GROUND CERAMICS; BRITTLE MATERIALS; BEND TESTS; FRACTURE; BEAMS AB Flexural testing is the most common method used to measure the uniaxial tensile strength of ceramics and glasses. Although standard test methods have been developed for rectangular specimens, cylindrical rod specimens may be preferred in many cases. This paper summarizes how, rods have been tested in the past, identifies key experimental errors and remedies, and serves as the foundation for a new standard test method for ceramics and glasses. C1 [Quinn, George D.; Ives, Lewis K.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. [Sparenberg, Brian T.; Arola, Dwayne D.] Univ Maryland, Baltimore, MD 21250 USA. RP Quinn, GD (reprint author), Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. FU U.S. Department of Energy; Office of Transportation Technologies; Heavy Vehicle Propulsion Systems Materials Program [DE-AC05-840R21400] FX Partial support for this project came from the U.S. Department of Energy, Office of Transportation Technologies, Heavy Vehicle Propulsion Systems Materials Program Under contract DE-AC05-840R21400 with Martin Marietta Energy Systems, Inc. The authors also thank the members of the NIST Ceramic Machining Consortium in the 1990s for their support of this project. NR 52 TC 3 Z9 3 U1 0 U2 5 PU AMER SOC TESTING MATERIALS PI W CONSHOHOCKEN PA 100 BARR HARBOR DR, W CONSHOHOCKEN, PA 19428-2959 USA SN 0090-3973 J9 J TEST EVAL JI J. Test. Eval. PD MAY PY 2009 VL 37 IS 3 BP 222 EP 244 PG 23 WC Materials Science, Characterization & Testing SC Materials Science GA 443HM UT WOS:000265900800004 ER PT J AU Hill, AA Feingold, G Jiang, HL AF Hill, Adrian A. Feingold, Graham Jiang, Hongli TI The Influence of Entrainment and Mixing Assumption on Aerosol-Cloud Interactions in Marine Stratocumulus SO JOURNAL OF THE ATMOSPHERIC SCIENCES LA English DT Article ID LARGE-EDDY SIMULATIONS; BOUNDARY-LAYER CLOUDS; TOPPED MIXED LAYERS; STRATIFORM CLOUDS; NONPRECIPITATING STRATOCUMULUS; CUMULUS CONVECTION; DRIVEN ENTRAINMENT; NUMERICAL-MODELS; DROPLET SPECTRA; DIURNAL CYCLE AB This study uses large-eddy simulation with bin microphysics to investigate the influence of entrainment and mixing on aerosol-cloud interactions in the context of idealized, nocturnal, nondrizzling marine stratocumulus (Sc). Of particular interest are (i) an evaporation-entrainment effect and a sedimentation-entrainment effect that result from increasing aerosol concentrations and (ii) the nature of mixing between clear and cloudy air, where homogeneous and extreme inhomogeneous mixing represent the bounding mixing types. Simulations are performed at low resolution (Delta z = 20 m; Delta x, y = 40 m) and high resolution (Delta z = 10 m; Delta x, y = 20 m). It is demonstrated that an increase in aerosol from clean conditions (100 cm(-3)) to polluted conditions (1000 cm(-3)) produces both an evaporation-entrainment and a sedimentation-entrainment effect, which couple to cause about a 10% decrease in liquid water path (LWP) when all warm microphysical processes are included. These dynamical effects are insensitive to both the resolutions tested and the mixing assumption. Regardless of resolution, assuming extreme inhomogeneous rather than homogeneous mixing results in a small reduction in cloud-averaged drop number concentration, a small increase in cloud drop effective radius, and; 1% decrease in cloud optical depth. For the case presented, these small changes play a negligible role when compared to the impact of increasing aerosol and the associated entrainment effects. Finally, it is demonstrated that although increasing resolution causes an increase in LWP and number concentration, the relative sensitivity of cloud optical depth to changes in aerosol is unaffected by resolution. C1 [Hill, Adrian A.; Feingold, Graham; Jiang, Hongli] NOAA, Earth Syst Res Lab, Boulder, CO USA. [Jiang, Hongli] Cooperat Inst Res Atmosphere, Boulder, CO USA. RP Hill, AA (reprint author), Met Off, Fitzroy Rd, Exeter EX1 3PB, Devon, England. EM adrian.hill@metoffice.gov.uk RI Feingold, Graham/B-6152-2009; Jiang, Hongli/N-3281-2014; Manager, CSD Publications/B-2789-2015 NR 48 TC 44 Z9 44 U1 2 U2 7 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0022-4928 EI 1520-0469 J9 J ATMOS SCI JI J. Atmos. Sci. PD MAY PY 2009 VL 66 IS 5 BP 1450 EP 1464 DI 10.1175/2008JAS2909.1 PG 15 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 452KI UT WOS:000266538500020 ER PT J AU Lehman, SY Roshko, A Mirin, RP Bertness, KA Harvey, TE Cobry, KD AF Lehman, S. Y. Roshko, A. Mirin, R. P. Bertness, K. A. Harvey, T. E. Cobry, K. D. TI Topography of epitaxial GaAs surfaces for growth SO JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B LA English DT Article DE ageing; atomic force microscopy; buffer layers; etching; gallium arsenide; III-V semiconductors; molecular beam epitaxial growth; semiconductor growth; surface roughness ID MOLECULAR-BEAM-EPITAXY; SCANNING-TUNNELING-MICROSCOPY; MIGRATION-ENHANCED EPITAXY; ATOMIC-FORCE MICROSCOPY; GAAS(001) HOMOEPITAXY; UNSTABLE GROWTH; MORPHOLOGY; HYDROGEN; DESORPTION; ALGAAS AB The topography and surface roughness of (100) GaAs substrates and buffers after different preparation procedures were determined from atomic force microscopy (AFM) measurements. In order to characterize the topography over a wide range of length scales, multiple large 5x5 mu m(2) AFM scans were acquired for each sample. These scans were analyzed both by histogramming the distribution of pixel heights and by finding the rms roughness at length scales from 10 nm to 5 mu m using a tiling analysis. The influence of substrate aging and chemical etching on buffers grown by molecular beam epitaxy was studied, as was the effect of different buffer growth procedures. Immediately after thermal desorption of the surface oxide, all wafers were extremely rough, as expected, with wafers etched in HCl:H(2)0 (1:1) somewhat smoother than untreated epiready wafers, while wafers etched in H(2)O(2):NH(4)OH:H(2)O (3:1:10) were rougher. After as little as 100 nm of buffer growth, however, there was no significant difference in roughness of etched or as-received substrates, and all samples were quite smooth with a rms roughness around 0.27 nm. The buffer growth conditions were found to significantly affect surface roughness. Interrupting the supply of Ga at the start of the growth enhanced mounding on the wafer surface, while postgrowth annealing at the growth temperature reduced the surface roughness and changed the characteristic topography of the surface. C1 [Lehman, S. Y.] Coll Wooster, Dept Phys, Wooster, OH 44691 USA. [Roshko, A.; Mirin, R. P.; Bertness, K. A.; Harvey, T. E.; Cobry, K. D.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Lehman, SY (reprint author), Coll Wooster, Dept Phys, Wooster, OH 44691 USA. EM slehman@wooster.edu; roshko@boulder.nist.gov RI Schaff, William/B-5839-2009; OI Mirin, Richard/0000-0002-4472-4655; Lehman, Susan/0000-0003-4735-1417 NR 35 TC 0 Z9 0 U1 3 U2 18 PU A V S AMER INST PHYSICS PI MELVILLE PA STE 1 NO 1, 2 HUNTINGTON QUADRANGLE, MELVILLE, NY 11747-4502 USA SN 1071-1023 J9 J VAC SCI TECHNOL B JI J. Vac. Sci. Technol. B PD MAY PY 2009 VL 27 IS 3 BP 1072 EP 1079 DI 10.1116/1.3119684 PG 8 WC Engineering, Electrical & Electronic; Nanoscience & Nanotechnology; Physics, Applied SC Engineering; Science & Technology - Other Topics; Physics GA 451VZ UT WOS:000266500300015 ER PT J AU Hart, DR AF Hart, Deborah R. TI Improving Utilization of the Atlantic Sea Scallop Resource: An Analysis of Rotational Management of Fishing Grounds: Comment SO LAND ECONOMICS LA English DT Article ID PLACOPECTEN-MAGELLANICUS AB Valderrama and Anderson (2007) presented an analysis of rotational fishing for sea scallops which unrealistically assumed high fixed price premiums for large sea scallops independent of their supply, and atypical initial conditions. These assumptions distort their results, leading them to suggest greater benefits for rotation than actually exist. This analysis was then used to criticize one aspect of current U.S. sea scallop management policy. However, their discussion ignores bycatch and possible habitat damage form scallop fishing. Including bycatch as external costs reduces the optimal fishing effort level from that which would otherwise he calculated. Finally a number of practical difficulties in applying formal optimization to fishery management are discussed. (JEL Q22) C1 Natl Marine Fisheries Serv, NE Fisheries Sci Ctr, Woods Hole, MA 02543 USA. RP Hart, DR (reprint author), Natl Marine Fisheries Serv, NE Fisheries Sci Ctr, Woods Hole, MA 02543 USA. NR 10 TC 0 Z9 0 U1 1 U2 6 PU UNIV WISCONSIN PI MADISON PA SOCIAL SCIENCE BLDG, MADISON, WI 53706 USA SN 0023-7639 J9 LAND ECON JI Land Econ. PD MAY PY 2009 VL 85 IS 2 BP 378 EP 382 PG 5 WC Economics; Environmental Studies SC Business & Economics; Environmental Sciences & Ecology GA 432SK UT WOS:000265154200011 ER PT J AU Rakher, MT AF Rakher, Matthew T. TI Quantum dots may hold the key to secure quantum cryptography SO LASER FOCUS WORLD LA English DT Article AB Quantum-dot-based single-photon sources are fast and efficient and remain at the forefront of candidates for use in quantum information schemes. C1 NIST, Ctr Nanoscale Sci & Technol, Gaithersburg, MD 20899 USA. RP Rakher, MT (reprint author), NIST, Ctr Nanoscale Sci & Technol, Gaithersburg, MD 20899 USA. EM mra-kher@nist.gov RI Rakher, Matthew/C-2287-2011 OI Rakher, Matthew/0000-0002-4490-4197 NR 10 TC 0 Z9 0 U1 0 U2 0 PU PENNWELL PUBL CO PI NASHUA PA 98 SPIT BROOK RD, NASHUA, NH 03062-2801 USA SN 1043-8092 J9 LASER FOCUS WORLD JI Laser Focus World PD MAY PY 2009 VL 45 IS 5 BP 63 EP + PG 5 WC Optics SC Optics GA 447YT UT WOS:000266228700020 ER PT J AU Ruttenberg, KC Ogawa, NO Tamburini, F Briggs, RA Colasacco, ND Joyce, E AF Ruttenberg, K. C. Ogawa, N. O. Tamburini, F. Briggs, R. A. Colasacco, N. D. Joyce, E. TI Improved, high-throughput approach for phosphorus speciation in natural sediments via the SEDEX sequential extraction method SO LIMNOLOGY AND OCEANOGRAPHY-METHODS LA English DT Article ID AUTHIGENIC APATITE FORMATION; IRON-BOUND PHOSPHORUS; MARINE-SEDIMENTS; REASSESSMENT; ESTUARY; RIVER AB A novel approach for implementation of sequential extraction methods using a multisample, solid-phase extraction manifold (SPExMan) successfully addresses several chronic problems typical of sequential extraction methods, including (1) sample loss during supernatant removal and (2) the time-and work-intensive nature of sequential extraction protocols. Supernatant is removed from SPExMan reaction vessels through an integrated filter base, eliminating the possibility of sample loss during supernatant collection. Vacuum manifold filtration makes it possible to filter multiple samples simultaneously. These two features of the design result in minimal residual volume between steps, eliminating the need for wash steps in between principle extraction steps and for residual volume correction. The SPExMan system was evaluated for the SEDEX method of quantifying different forms of phosphorus in sediments. Results from three different sediment samples analyzed via the classical centrifuge/syringe filtration SEDEX method and the SPExMan-SEDEX method agree well, indicating that the SPExMan design is robust for performance of sequential extraction methods, and that SPExMan-SEDEX data can be directly compared with classical SEDEX data. Overall, sample throughput is greatly increased by the SPExMan approach. Materials chosen for the SPExMan system are compatible with a wide range of chemical extractants, including corrosives and organic solvents. C1 [Ruttenberg, K. C.; Ogawa, N. O.; Tamburini, F.; Colasacco, N. D.; Joyce, E.] Woods Hole Oceanog Inst, Dept Marine Chem & Geochem, Woods Hole, MA 02543 USA. [Ruttenberg, K. C.; Briggs, R. A.] Univ Hawaii Manoa, Dept Oceanog, SOEST, Honolulu, HI 96822 USA. [Ruttenberg, K. C.; Briggs, R. A.] Univ Hawaii Manoa, Dept Geol & Geophys, SOEST, Honolulu, HI 96822 USA. [Ogawa, N. O.] JAMSTEC, IFREE, Yokosuka, Kanagawa, Japan. [Tamburini, F.] Swiss Fed Inst Technol, D AGRL, Inst Plant Sci, Lindau, Switzerland. [Colasacco, N. D.] Natl Ocean & Atmospher Adm, Honolulu, HI USA. [Joyce, E.] Marine Inst, Oranmore, County Galway, Ireland. RP Ruttenberg, KC (reprint author), Woods Hole Oceanog Inst, Dept Marine Chem & Geochem, Woods Hole, MA 02543 USA. EM kcr@soest.hawaii.edu FU NSF-EAR [80656500]; NSFOCE [81655300]; NSF-OCE [0550851]; Japan Postdoctoral Fellowship; Swiss NSF Postdoctoral Fellowship; National Oceanic and Atmospheric Administration [R/EL-42]; University of Hawaii Sea Grant College Program; SOEST; NOAA Office of Sea Grant [NA05OAR4171048] FX The authors gratefully acknowledge Mark St. Pierre, Steve Manganini, Ken Doherty, and Terry Hammar at Woods Hole Oceanographic Institution for assistance with design ideas and implementation; Zenshiro Heshiki and Mike Cole at UH-Manoa for final engineering drawings; and Marcie Grabowski for photographs. Research support included NSF-EAR# 80656500, NSFOCE#81655300, and NSF-OCE# 0550851 to K. C. R., N. D. C., and E. J. M.; Japan Postdoctoral Fellowship to N. O. O.; and Swiss NSF Postdoctoral Fellowship to F. T. R. A. B was supported in part by a grant/cooperative agreement from the National Oceanic and Atmospheric Administration, project R/EL-42, which is sponsored by the University of Hawaii Sea Grant College Program, SOEST, under Institutional Grant NA05OAR4171048 from NOAA Office of Sea Grant, Department of Commerce. The views expressed herein are those of the authors and do not necessarily reflect the views of NOAA or any of its subagencies. UNIHI-SEAGRANT-JC-08-18. This is SOEST contribution # 7609. NR 16 TC 17 Z9 17 U1 7 U2 40 PU AMER SOC LIMNOLOGY OCEANOGRAPHY PI WACO PA 5400 BOSQUE BLVD, STE 680, WACO, TX 76710-4446 USA SN 1541-5856 J9 LIMNOL OCEANOGR-METH JI Limnol. Oceanogr. Meth. PD MAY PY 2009 VL 7 BP 319 EP 333 PG 15 WC Limnology; Oceanography SC Marine & Freshwater Biology; Oceanography GA 458IO UT WOS:000267011000001 ER PT J AU Pierson, JJ Frost, BW Thoreson, D Leising, AW Postel, JR Nuwer, M AF Pierson, James J. Frost, Bruce W. Thoreson, David Leising, Andrew W. Postel, James R. Nuwer, Mikelle TI Trapping migrating zooplankton SO LIMNOLOGY AND OCEANOGRAPHY-METHODS LA English DT Article ID DIEL VERTICAL MIGRATION; CALANUS-FINMARCHICUS; ADAPTIVE SIGNIFICANCE; POPULATION-DYNAMICS; OPTIMIZATION MODEL; HABITAT SELECTION; MARINE COPEPOD; PREDATION RISK; SCOTIAN SHELF; LIFE-HISTORY AB We have developed a method to determine if individual zooplankton make short-duration migrations, on the order of meters to tens of meters in vertical extent, between food-rich surface water and deeper, food-poor water. To do this, we developed a zooplankton trapping system, consisting of paired traps to catch zooplankton migrating downward and an inverted ring net to catch zooplankton migrating upward. These two trap systems were deployed simultaneously with the openings at the same depth, to catch zooplankton crossing a particular depth horizon, and samples were immediately sorted to make morphological and physiological measurements of individuals. Initial tests showed that there were differences in the ability to capture upward-and downward-migrating marine zooplankton. In addition, physiological (gut contents) and morphological (prosome length) characteristics of individual copepods differed between those moving in opposite directions. These data support the hypothesis that copepods make repeated nighttime forays between deeper, food-poor water and the near-surface, food-rich waters. This is part of an ongoing study on the variability of this behavior in different conditions and over seasonal cycles, but the method may be applicable to other pelagic environments, to explore various ecological questions. C1 [Pierson, James J.] Univ Maryland, Horn Point Environm Lab, Ctr Environm Sci, Cambridge, MD 21613 USA. [Frost, Bruce W.; Thoreson, David; Postel, James R.; Nuwer, Mikelle] Univ Washington, Sch Oceanog, Seattle, WA 98195 USA. [Leising, Andrew W.] Natl Ocean & Atmospher Adm, SW Fisheries Sci Ctr, Div Environm Res, Pacific Grove, CA USA. RP Pierson, JJ (reprint author), Univ Maryland, Horn Point Environm Lab, Ctr Environm Sci, Cambridge, MD 21613 USA. EM jpierson@hpl.umces.edu RI Pierson, James/B-7278-2008 OI Pierson, James/0000-0002-5248-5850 FU National Science Foundation [OCE-0525943] FX The development and testing of these traps could not have been done without the assistance of Ray McQuin and Nikki Hix of the R/V Clifford A. Barnes. Statistical assistance was provided by Dr. Dave Kimmel. This manuscript was greatly improved by the comments of three anonymous reviewers. This work was supported by a grant from the National Science Foundation (OCE-0525943). This paper is contribution 4279 from the University of Maryland Center for Environmental Science. NR 41 TC 6 Z9 7 U1 0 U2 1 PU AMER SOC LIMNOLOGY OCEANOGRAPHY PI WACO PA 5400 BOSQUE BLVD, STE 680, WACO, TX 76710-4446 USA SN 1541-5856 J9 LIMNOL OCEANOGR-METH JI Limnol. Oceanogr. Meth. PD MAY PY 2009 VL 7 BP 334 EP 346 PG 13 WC Limnology; Oceanography SC Marine & Freshwater Biology; Oceanography GA 458IO UT WOS:000267011000002 ER PT J AU Jefferson, TA Fertl, D Bolanos-Jimenez, J Zerbini, AN AF Jefferson, Thomas A. Fertl, Dagmar Bolanos-Jimenez, Jaime Zerbini, Alexandre N. TI Distribution of common dolphins (Delphinus spp.) in the western Atlantic Ocean: a critical re-examination SO MARINE BIOLOGY LA English DT Review ID GULF-OF-MEXICO; NORTHEAST UNITED-STATES; LESSER ANTILLEAN ISLAND; CONTINENTAL-SHELF; RELATIVE ABUNDANCE; STENELLA-CLYMENE; SMALLER CETACEA; ST-VINCENT; WATERS; HABITAT AB Due to indications that misidentification (largely confusion among dolphins of the genera Delphinus and Stenella) in the past had led to erroneous assumptions of distribution of the two species of common dolphins (Delphinus delphis and D. capensis) in the western Atlantic Ocean, we conducted a critical re-examination of records of the genus Delphinus from this region. We compiled 460 'plottable' records, required support for confirmation of genus and species identifications, and found many records lacking (and some clearly misidentified). When we plotted only the valid records (n = 364), we found evidence of populations in only three areas, and apparent absence throughout much of the tropical/subtropical regions. Off the east coast of the US and Canada, D. delphis is found from the Georgia/South Carolina border (32A degrees N) north to about 47-50A degrees N off Newfoundland. Since the 1960s, they have apparently been absent from Florida waters. There is no evidence that dolphins of the genus occur in the Gulf of Mexico. Reports of common dolphins from most of the Caribbean Basin are also rejected, and the only place in that region where they are confirmed to occur is off central-eastern Venezuela (a coastal D. capensis population). Off eastern South America, common dolphins appear to be restricted to south of 20A degrees S. There is a coastal long-beaked population found in the South Brazil Bight, and one or more short-beaked populations south and offshore of this (ranging south to at least northern Argentina). The results are very different from commonly-accepted patterns of distribution for the genus in the Atlantic. Most areas of distribution coincide with moderate to strong upwelling and common dolphins appear to avoid warm, tropical waters. This study shows that great care must be taken in identification of similar-appearing long-beaked delphinids, and that uncritical acceptance of records at face value can lead to incorrect assumptions about the ranges of the species involved. C1 [Jefferson, Thomas A.] NMFS, SW Fisheries Sci Ctr, NOAA Fisheries, La Jolla, CA 92037 USA. [Fertl, Dagmar] Ziphius EcoServ, Plano, TX 75025 USA. [Bolanos-Jimenez, Jaime] Soc Ecol Venezolana Vida Marina Sea Vida, Cagua 2122, Estado Aragua, Venezuela. [Zerbini, Alexandre N.] Alaska Fisheries Sci Ctr, Natl Marine Mammal Lab, Seattle, WA 98115 USA. RP Jefferson, TA (reprint author), NMFS, SW Fisheries Sci Ctr, NOAA Fisheries, 3333 Torrey Pines Court, La Jolla, CA 92037 USA. EM sclymene@aol.com RI Zerbini, Alexandre/G-4138-2012 NR 146 TC 18 Z9 21 U1 1 U2 10 PU SPRINGER HEIDELBERG PI HEIDELBERG PA TIERGARTENSTRASSE 17, D-69121 HEIDELBERG, GERMANY SN 0025-3162 EI 1432-1793 J9 MAR BIOL JI Mar. Biol. PD MAY PY 2009 VL 156 IS 6 BP 1109 EP 1124 DI 10.1007/s00227-009-1152-y PG 16 WC Marine & Freshwater Biology SC Marine & Freshwater Biology GA 428TU UT WOS:000264873800002 ER PT J AU Freshwater, DW Hines, A Parham, S Wilbur, A Sabaoun, M Woodhead, J Akins, L Purdy, B Whitfield, PE Paris, CB AF Freshwater, D. Wilson Hines, Andrew Parham, Seth Wilbur, Ami Sabaoun, Michelle Woodhead, Jennifer Akins, Lad Purdy, Bruce Whitfield, Paula E. Paris, Claire B. TI Mitochondrial control region sequence analyses indicate dispersal from the US East Coast as the source of the invasive Indo-Pacific lionfish Pterois volitans in the Bahamas SO MARINE BIOLOGY LA English DT Article ID UNITED-STATES; SURFACE DRIFTERS; ATLANTIC COAST; NORTH-ATLANTIC; SCORPAENIDAE; FISHES; DNA; CONNECTIVITY; PHYLOGENY; COMPLEX AB Lionfish are popular aquarium fish from the Indo-Pacific that have invaded the western Atlantic. Two species, Pterois volitans and P. miles, were well established along the United States east coast before the first lionfish were reported from the Bahamas in 2004, where they quickly dispersed throughout the archipelago by 2007. The source of the Bahamian lionfish invasion has been in question because of the hypothesized low connectivity between Florida and Bahamas reef species as well as the temporal lag in their arrival in the Bahamas. Mitochondrial control region haplotypes (680 bp) were determined and analyzed for lionfish specimens from the Bahamas, North Carolina, and two sites within their native range (Indonesia and the Philippines). Exact tests, pairwise F (st) and AMOVA analyses all showed no significant differentiation between the Bahamas and North Carolina specimens. The similarity between the Bahamas and North Carolina lionfish was also reflected in a minimum spanning network and neighbor-joining distance tree generated from the data. Sequence analyses also revealed the presence of only Pterois volitans, as no P. miles were detected in the Bahamian sample. These results indicate that the source of the Bahamian lionfish is egg and larval dispersal from the United States east coast population, and support previous models of reef fish dispersal that suggest a low level of connectivity between the Bahamas and east coast of Florida. C1 [Freshwater, D. Wilson; Hines, Andrew; Parham, Seth; Wilbur, Ami] Ctr Marine Sci, Wilmington, NC 28409 USA. [Sabaoun, Michelle; Woodhead, Jennifer] Brunswick Community Coll, Supply, NC 28462 USA. [Akins, Lad] Reef Environm Educ Fdn, Key Largo, FL 33037 USA. [Purdy, Bruce] Blackbeards Cruises, Davie, FL 33314 USA. [Whitfield, Paula E.] NOAA Ctr Coastal Fisheries & Habitat Res, Beaufort, NC 28516 USA. [Paris, Claire B.] Univ Miami, Rosenstiel Sch Marine & Atmospher Sci, Miami, FL 33149 USA. RP Freshwater, DW (reprint author), Ctr Marine Sci, 5600 Marvin Moss Lane, Wilmington, NC 28409 USA. EM freshwaterw@uncw.edu OI Paris, Claire/0000-0002-0637-1334 FU NSF ROA [0618453]; UNCW's National Undersea Research Center; NOAA; REEF and Blackbeard's Cruises FX Participation in this study by UNCW students and Brunswick Community College faculty was supported by NSF ROA supplement award to MRI grant # 0618453. Additional funding was provided by NOAA's Invasive Species Program. Collection of North Carolina specimens was supported by UNCW's National Undersea Research Center and NOAA. Bahamas specimens were collected with the support of REEF and Blackbeard's Cruises. The excellent help provided by the many NURC, NOAA and REEF cruise divers is greatly appreciated and we wish to especially thank James Morris for his many eVorts to facilitate our Bahamas studies. The experiments in this study complied with the current laws of the Bahamas and United States of America, and all Bahamian lionWsh were collected under research permit MAF/FIS/12: MAF/FIS/17 to James Morris. NR 39 TC 49 Z9 50 U1 2 U2 50 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0025-3162 J9 MAR BIOL JI Mar. Biol. PD MAY PY 2009 VL 156 IS 6 BP 1213 EP 1221 DI 10.1007/s00227-009-1163-8 PG 9 WC Marine & Freshwater Biology SC Marine & Freshwater Biology GA 428TU UT WOS:000264873800011 ER PT J AU Springman, KR Short, J Rice, SD AF Springman, K. R. Short, J. Rice, S. D. TI Comments on the misuse of SPMDs in recent articles by Springman et al. (2008a,b) and Short et al. (2008) Response SO MARINE ENVIRONMENTAL RESEARCH LA English DT Letter ID PRINCE-WILLIAM-SOUND; EXXON-VALDEZ OIL; SEMIPERMEABLE-MEMBRANE DEVICES; SITE-SPECIFIC CONTAMINANTS; HYDROCARBON SOURCES; ALASKA; INDUCTION; SPILL; FISH; CYTOCHROME-P4501A C1 [Springman, K. R.] Univ Calif Davis, Littleriver, CA 95456 USA. [Short, J.; Rice, S. D.] NOAA, Alaska Fisheries Sci Ctr, Natl Marine Fisheries Serv, Juneau, AK 99801 USA. RP Springman, KR (reprint author), Univ Calif Davis, POB 315, Littleriver, CA 95456 USA. EM krspringman@gmail.com NR 21 TC 1 Z9 1 U1 1 U2 3 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0141-1136 J9 MAR ENVIRON RES JI Mar. Environ. Res. PD MAY-JUN PY 2009 VL 67 IS 4-5 BP 259 EP 261 DI 10.1016/j.marenvres.2009.03.004 PG 3 WC Environmental Sciences; Marine & Freshwater Biology; Toxicology SC Environmental Sciences & Ecology; Marine & Freshwater Biology; Toxicology GA 457DA UT WOS:000266904800011 ER PT J AU Farooqui, SA Doiron, T Sahay, C AF Farooqui, Sami A. Doiron, Ted Sahay, Chittaranjan TI Uncertainty analysis of cylindricity measurements using bootstrap method SO MEASUREMENT LA English DT Article DE Cylindricity; Uncertainty; Roundness measurements; Bootstrap method AB This paper describes a method for performing uncertainty analysis of cylindricity measurements Using bootstrap techniques. Errors in the Talyrond roundness measuring machine Were Studied and a variation was assigned to the roundness (r,0) as well as the centerline Position of the z-axis. The roundness data was dominated by air error that we characterized by a normal distribution with some standard deviation derived front repeated traces of the chosen artifact. The z-axis position error was also studied to provide a suitable distribution for these errors, A dataset was taken on the test artifact. Bootstrap datasets Were produced from the original dataset and were analyzed Using MATLAB. Uncertainty interval was determined front the cylindricity values obtained from the software. The uncertainty for the system was found to be +/- 0.092 mu m with 95% confidence level. Effects of noise and straightness error on cylindricity value Were also studied. (C) 2008 Elsevier Ltd. All rights reserved. C1 [Farooqui, Sami A.] Agilent Technol, Santa Rosa Metrol Serv, Santa Rosa, CA 95403 USA. [Doiron, Ted] NIST, Div Precis Engn, Gaithersburg, MD 20899 USA. [Sahay, Chittaranjan] Univ Hartford, Dept Mech Engn, Hartford, CT 06117 USA. RP Farooqui, SA (reprint author), Agilent Technol, Santa Rosa Metrol Serv, 1400 Fountaingrove Pkwy Stop 4LSG, Santa Rosa, CA 95403 USA. EM sami@agilent.com FU National Institute of Standards and Technology FX This research was supported by National Institute of Standards and Technology. We thank Dr. Jack Stone, John Stoup and Eric Stanfield of NIST for their assistance in the research. NR 11 TC 5 Z9 5 U1 1 U2 15 PU ELSEVIER SCI LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND SN 0263-2241 J9 MEASUREMENT JI Measurement PD MAY PY 2009 VL 42 IS 4 BP 524 EP 531 DI 10.1016/j.measurement.2008.09.008 PG 8 WC Engineering, Multidisciplinary; Instruments & Instrumentation SC Engineering; Instruments & Instrumentation GA 430CW UT WOS:000264967400005 ER PT J AU Waples, RS Faulkner, JR AF Waples, Robin S. Faulkner, James R. TI Modelling evolutionary processes in small populations: not as ideal as you think SO MOLECULAR ECOLOGY LA English DT Article DE bias; binomial sampling; computer simulations; effective population size; genetic drift; precision; pseudoreplication; variance in reproductive success ID APPROXIMATE BAYESIAN COMPUTATION; LINKAGE DISEQUILIBRIUM; SELECTIVE NEUTRALITY; ALLELE FREQUENCY; MIGRATION RATES; GENE FREQUENCY; F-ST; SIZE; PROGRAM; BIAS AB Evolutionary processes are routinely modelled using 'ideal' Wright-Fisher populations of constant size N in which each individual has an equal expectation of reproductive success. In a hypothetical ideal population, variance in reproductive success (V(k)) is binomial and effective population size (N(e)) = N. However, in any actual implementation of the Wright Fisher model (e. g., in a computer), V(k) is a random variable and its realized value in any given replicate generation (V(k)*) only rarely equals the binomial variance. Realized effective size (N(e)*) thus also varies randomly in modelled ideal populations, and the consequences of this have not been adequately explored in the literature. Analytical and numerical results show that random variation V(k)* and N(e)* can seriously distort analyses that evaluate precision or otherwise depend on the assumption that N(e)* is constant. We derive analytical expressions for Var(V(k)) [4(2N-1)(N-1)/N(3)] and Var(N(e)) [N(N-1)/(2N-1) approximate to N/2] in modelled ideal populations and show that, for a genetic metric G = f(N(e)), Var((G) over cap) has two components: Var(Gene) (due to variance across replicate samples of genes, given a specific N(e)*) and Var(Demo) (due to variance N(e)*). Var((G) over cap) is higher than it would be with constant Ne = N, as implicitly assumed by many standard models. We illustrate this with empirical examples based on F (standardized variance of allele frequency) and r(2) (a measure of linkage disequilibrium). Results demonstrate that in computer models that track multilocus genotypes, methods of replication and data analysis can strongly affect consequences of variation in N(e)*. These effects are more important when sampling error is small (large numbers of individuals, loci and alleles) and with relatively small populations (frequently modelled by those interested in conservation). C1 [Waples, Robin S.; Faulkner, James R.] NW Fisheries Sci Ctr, Seattle, WA 98112 USA. RP Waples, RS (reprint author), NW Fisheries Sci Ctr, 2725 Montlake Blvd E, Seattle, WA 98112 USA. EM robin.waples@noaa.gov RI Waples, Robin/K-1126-2016 NR 37 TC 9 Z9 9 U1 1 U2 14 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 0962-1083 J9 MOL ECOL JI Mol. Ecol. PD MAY PY 2009 VL 18 IS 9 BP 1834 EP 1847 DI 10.1111/j.1365-294X.2009.04157.x PG 14 WC Biochemistry & Molecular Biology; Ecology; Evolutionary Biology SC Biochemistry & Molecular Biology; Environmental Sciences & Ecology; Evolutionary Biology GA 433FJ UT WOS:000265189400005 PM 19344355 ER PT J AU Rollins, MF Vu, NV Spies, IB Kalinowski, ST AF Rollins, Maryclare F. Vu, Ninh V. Spies, Ingrid B. Kalinowski, Steven T. TI Twelve microsatellite loci for lake trout (Salvelinus namaycush) SO MOLECULAR ECOLOGY RESOURCES LA English DT Article DE Lake trout; microsatellite; primer; Salvelinus namaycush ID CUTTHROAT TROUT AB We describe 12 microsatellite loci isolated from lake trout (Salvelinus namaycush). The number of alleles at these loci ranged from two to 11 with an average of 5.3 alleles per locus. The expected heterozygosity ranged from 0.29 to 0.76, with an average of 0.68. Accidental (or illegal) introductions of lake trout into watersheds are decimating native trout populations in the northern Rocky Mountains, and these loci will be useful for identifying the source of these introductions and for estimating the number of founding individuals. C1 [Rollins, Maryclare F.; Vu, Ninh V.; Kalinowski, Steven T.] Montana State Univ, Dept Ecol, Bozeman, MT 59717 USA. [Spies, Ingrid B.] NOAA Fisheries, Alaska Fisheries Sci Ctr, Seattle, WA 98115 USA. RP Kalinowski, ST (reprint author), Montana State Univ, Dept Ecol, 310 Lewis Hall, Bozeman, MT 59717 USA. EM skalinowski@montana.edu FU Montana Fish Wildlife and Parks; National Science Foundation [DEB 071756] FX This work was primarily funded by Montana Fish Wildlife and Parks, with some support provided by the National Science Foundation (DEB 071756). We thank Clint Muhlfeld (US Geological Survey, Flathead, MT) and Ben Cox (Montana Cooperative Fishery Research Unit, Bozeman, MT) for providing tissue samples. Lastly, we thank Bob Sharrock (Montana State University, Plant Science and Plant Pathology, Bozeman, MT) for providing facilities and equipment needed to perform the microsatellite enrichment. NR 10 TC 6 Z9 7 U1 1 U2 6 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 1755-098X J9 MOL ECOL RESOUR JI Mol. Ecol. Resour. PD MAY PY 2009 VL 9 IS 3 BP 871 EP 873 DI 10.1111/j.1755-0998.2008.02403.x PG 3 WC Biochemistry & Molecular Biology; Ecology; Evolutionary Biology SC Biochemistry & Molecular Biology; Environmental Sciences & Ecology; Evolutionary Biology GA 443GC UT WOS:000265897200049 PM 21564773 ER PT J AU Roden, SE Dutton, PH Morin, PA AF Roden, Suzanne E. Dutton, Peter H. Morin, Phillip A. TI Characterization of single nucleotide polymorphism markers for the green sea turtle (Chelonia mydas) SO MOLECULAR ECOLOGY RESOURCES LA English DT Article DE allele-specific amplification; Amplifluor; Chelonia mydas; green turtle; single nucleotide polymorphism; SNP AB We present data on 29 new single nucleotide polymorphism assays for the green sea turtle, Chelonia mydas. DNA extracts from 39 green turtles were used for two methods of single nucleotide polymorphism discovery. The first approach employed an amplified fragment length polymorphism technique. The second technique screened a microsatellite library. Allele-specific amplification assays were developed for high-throughput single nucleotide polymorphism genotyping and tested on two Pacific C. mydas nesting populations. Observed heterozygosities ranged from 0 to 0.95 for a Hawaiian population and from 0 to 0.85 for a Galapagos population. Each of the populations had one locus out of Hardy-Weinberg equilibrium, SSCM2b and SSCM5 for Hawaii and Galapagos, respectively. No loci showed significant genotypic linkage disequilibrium across an expanded set of four Pacific nesting populations. However, two loci, SSCM4 and SSCM10b showed linkage disequilibrium across three populations indicating possible association. C1 [Roden, Suzanne E.; Dutton, Peter H.; Morin, Phillip A.] NOAA Fisheries, SW Fisheries Sci Ctr, La Jolla, CA 92037 USA. [Roden, Suzanne E.] Univ San Diego, San Diego, CA 92110 USA. RP Roden, SE (reprint author), NOAA Fisheries, SW Fisheries Sci Ctr, 8604 La Jolla Shores Dr, La Jolla, CA 92037 USA. EM suzanne.roden@noaa.gov NR 10 TC 5 Z9 5 U1 2 U2 16 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 1755-098X J9 MOL ECOL RESOUR JI Mol. Ecol. Resour. PD MAY PY 2009 VL 9 IS 3 BP 1055 EP 1060 DI 10.1111/j.1755-0998.2009.02573.x PG 6 WC Biochemistry & Molecular Biology; Ecology; Evolutionary Biology SC Biochemistry & Molecular Biology; Environmental Sciences & Ecology; Evolutionary Biology GA 443GC UT WOS:000265897200114 PM 21564838 ER PT J AU Weickmann, K Berry, E AF Weickmann, Klaus Berry, Edward TI The Tropical Madden-Julian Oscillation and the Global Wind Oscillation SO MONTHLY WEATHER REVIEW LA English DT Article ID ATMOSPHERIC ANGULAR-MOMENTUM; EXTRATROPICAL 40-DAY OSCILLATION; GENERAL-CIRCULATION MODEL; MEAN FLOW ANOMALIES; MOUNTAIN TORQUES; POLEWARD PROPAGATION; LENGTH; VARIABILITY; HEMISPHERE; TELECONNECTIONS AB The global wind oscillation (GWO) is a subseasonal phenomenon encompassing the tropical Madden-Julian oscillation (MJO) and midlatitude processes like meridional momentum transports and mountain torques. A phase space is defined for the GWO following the approach of Wheeler and Hendon for the MJO. In contrast to the oscillatory behavior of the MJO, two red noise processes define the GWO. The red noise spectra have variance at periods that bracket 30-60 or 30-80 days, which are bands used to define the MJO. The correlation between the MJO and GWO is; 0.5 and cross spectra show well-defined, coherent phase relations in similar frequency bands. However, considerable independent variance exists in the GWO. A basic dynamical distinction occurs in the direction of midlatitude wave energy dispersion, being predominantly meridional during a MJO and zonal during the GWO. This is primarily a winter season feature centered over the Pacific Ocean. A case study during April-May 2007 focuses on the GWO and two; 30-day duration orbits with extreme anomalies in GWO phase space. The MJO phase space projections for the same time were irregular and, it is argued, partially driven by mountain torques and meridional transports. The case study reveals that multiple physical processes and time scales act to create slowly evolving planetary-scale circulation and tropical convection anomalies. C1 [Weickmann, Klaus] NOAA, ESRL, Div Phys Sci, Boulder, CO 80305 USA. [Berry, Edward] NOAA Natl Weather Serv, Dodge City, KS USA. RP Weickmann, K (reprint author), NOAA, ESRL, Div Phys Sci, R PSD1,325 Broadway, Boulder, CO 80305 USA. EM klaus.weickmann@noaa.gov FU MIC; NOAA/NWS/WFOin Dodge City, Kansas FX Edward Berry expresses his appreciation to Larry J. Ruthi, MIC, NOAA/NWS/WFOin Dodge City, Kansas, for his support of the project. Encouragement and support from Robin Webb and Randy Dole are also appreciated. NR 34 TC 18 Z9 18 U1 0 U2 3 PU AMER METEOROLOGICAL SOC PI BOSTON PA 45 BEACON ST, BOSTON, MA 02108-3693 USA SN 0027-0644 J9 MON WEATHER REV JI Mon. Weather Rev. PD MAY PY 2009 VL 137 IS 5 BP 1601 EP 1614 DI 10.1175/2008MWR2686.1 PG 14 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 451UC UT WOS:000266495000007 ER PT J AU Cziczo, DJ Stetzer, O Worringen, A Ebert, M Weinbruch, S Kamphus, M Gallavardin, SJ Curtius, J Borrmann, S Froyd, KD Mertes, S Mohler, O Lohmann, U AF Cziczo, Daniel J. Stetzer, Olaf Worringen, Annette Ebert, Martin Weinbruch, Stephan Kamphus, Michael Gallavardin, Stephane J. Curtius, Joachim Borrmann, Stephan Froyd, Karl D. Mertes, Stephan Moehler, Ottmar Lohmann, Ulrike TI Inadvertent climate modification due to anthropogenic lead SO NATURE GEOSCIENCE LA English DT Article ID ICE NUCLEATION; MODEL ECHAM5-HAM; MINERAL DUST; PARTICLES; NUCLEI; CHAMBER; CLOUDS; IODINE; AIDA AB Aerosol particles can interact with water vapour in the atmosphere, facilitating the condensation of water and the formation of clouds. At temperatures below 273 K, a fraction of atmospheric particles act as sites for ice-crystal formation. Atmospheric ice crystals-which are incorporated into clouds that cover more than a third of the globe(1)-are thought to initiate most of the terrestrial precipitation(2). Before the switch to unleaded fuel last century, the atmosphere contained substantial quantities of particulate lead; whether this influenced ice-crystal formation is not clear. Here, we combine field observations of ice-crystal residues with laboratory measurements of artificial clouds, to show that anthropogenic lead-containing particles are among the most efficient ice-forming substances commonly found in the atmosphere(3). Using a global climate model, we estimate that up to 0.8 Wm(-2) more long-wave radiation is emitted when 100% of ice-forming particles contain lead, compared with when no particles contain lead. We suggest that post-industrial emissions of particulate lead may have offset a proportion of the warming attributed to greenhouse gases. C1 [Cziczo, Daniel J.] Pacific NW Natl Lab, Atmospher Sci & Global Change Div, Richland, WA 99354 USA. [Cziczo, Daniel J.; Stetzer, Olaf; Gallavardin, Stephane J.; Lohmann, Ulrike] ETH, Inst Atmospher & Climate Sci, CH-8092 Zurich, Switzerland. [Worringen, Annette; Ebert, Martin; Weinbruch, Stephan] Tech Univ Darmstadt, Inst Appl Geosci, D-64287 Darmstadt, Germany. [Kamphus, Michael; Gallavardin, Stephane J.; Curtius, Joachim; Borrmann, Stephan] Johannes Gutenberg Univ Mainz, Inst Atmospher Phys, D-55099 Mainz, Germany. [Curtius, Joachim] Goethe Univ Frankfurt, Inst Atmospher & Environm Sci, D-60438 Frankfurt, Germany. [Borrmann, Stephan] Max Planck Inst Chem, Particle Chem Dept, D-55128 Mainz, Germany. [Froyd, Karl D.] Natl Ocean & Atmospher Adm, Div Chem Sci, Boulder, CO 80305 USA. [Mertes, Stephan] Leibniz Inst Tropospher Res, D-04318 Leipzig, Germany. [Moehler, Ottmar] Forschungszentrum Karlsruhe, Inst Meteorol & Climate Res, D-76021 Karlsruhe, Germany. RP Cziczo, DJ (reprint author), Pacific NW Natl Lab, Atmospher Sci & Global Change Div, 902 Battelle Blvd, Richland, WA 99354 USA. EM daniel.cziczo@pnl.gov RI Borrmann, Stephan/E-3868-2010; Curtius, Joachim/A-2681-2011; Froyd, Karl/H-6607-2013; Weinbruch, Stephan/E-6141-2014; Mohler, Ottmar/J-9426-2012; Lohmann, Ulrike/B-6153-2009; Manager, CSD Publications/B-2789-2015 OI Curtius, Joachim/0000-0003-3153-4630; Lohmann, Ulrike/0000-0001-8885-3785; FU High Altitude Research Foundation Gomergrat; Atmospheric Composition Change the European Network for Excellence; German Research Foundation FX We thank P. J. DeMott, D. M. Murphy and D. S. Thomson for their assistance with the measurements. We also acknowledge the effort of all of the participants of the INSPECT and CLACE field studies, the support of the High Altitude Research Foundation Gomergrat and Jungfraujoch and the experimental group at AIDA. This research was supported by the Atmospheric Composition Change the European Network for Excellence, ETH Zurich, the German Research Foundation and Pacific Northwest National Laboratory directed research funding. NR 30 TC 45 Z9 45 U1 0 U2 30 PU NATURE PUBLISHING GROUP PI NEW YORK PA 75 VARICK ST, 9TH FLR, NEW YORK, NY 10013-1917 USA SN 1752-0894 EI 1752-0908 J9 NAT GEOSCI JI Nat. Geosci. PD MAY PY 2009 VL 2 IS 5 BP 333 EP 336 DI 10.1038/NGEO499 PG 4 WC Geosciences, Multidisciplinary SC Geology GA 452MA UT WOS:000266542900012 ER PT J AU Tunnicliffe, V Davies, KTA Butterfield, DA Embley, RW Rose, JM Chadwick, WW AF Tunnicliffe, Verena Davies, Kimberley T. A. Butterfield, David A. Embley, Robert W. Rose, Jonathan M. Chadwick, William W., Jr. TI Survival of mussels in extremely acidic waters on a submarine volcano SO NATURE GEOSCIENCE LA English DT Article ID SEA HYDROTHERMAL VENT; NORTH FIJI BASIN; OCEAN ACIDIFICATION; WESTERN PACIFIC; MYTILUS-EDULIS; GROWTH; IMPACT; CO2; HYPERCAPNIA; BIVALVIA AB Increasing atmospheric carbon dioxide levels are causing ocean acidification(1,2), compromising the ability of some marine organisms to build and maintain support structures(3) as the equilibrium state of inorganic carbon moves away from calcium carbonate(4). Few marine organisms tolerate conditions where ocean pH falls significantly below today's value of about 8.1 and aragonite and calcite saturation values below 1 (refs 5, 6). Here we report dense clusters of the vent mussel Bathymodiolus brevior in natural conditions of pH values between 5.36 and 7.29 on northwest Eifuku volcano, Mariana arc, where liquid carbon dioxide and hydrogen sulphide emerge in a hydrothermal setting. We find that both shell thickness and daily growth increments in shells from northwest Eifuku are only about half those recorded from mussels living in water with pH > 7.8. Low pH may therefore also be implicated in metabolic impairment(7). We identify four-decade-old mussels, but suggest that the mussels can survive for so long only if their protective shell covering remains intact: crabs that could expose the underlying calcium carbonate to dissolution are absent from this setting. The mussels' ability to precipitate shells in such low-pH conditions is remarkable. Nevertheless, the vulnerability of molluscs to predators is likely to increase in a future ocean with low pH. C1 [Tunnicliffe, Verena; Davies, Kimberley T. A.; Rose, Jonathan M.] Univ Victoria, Dept Biol, Victoria, BC V8W 3N5, Canada. [Tunnicliffe, Verena] Univ Victoria, Sch Earth & Ocean Sci, Victoria, BC V8W 3P6, Canada. [Butterfield, David A.] Univ Washington, Joint Inst Study Atmosphere & Oceans, Seattle, WA 98115 USA. [Embley, Robert W.] NOAA, Pacific Marine Environm Lab, Newport, OR 97365 USA. [Chadwick, William W., Jr.] Oregon State Univ, CIMRS, Newport, OR 97365 USA. RP Tunnicliffe, V (reprint author), Univ Victoria, Dept Biol, POB 3080, Victoria, BC V8W 3N5, Canada. EM verenat@uvic.ca RI Wright, Dawn/A-4518-2011; Tunnicliffe, Verena/D-1056-2014; Butterfield, David/H-3815-2016 OI Wright, Dawn/0000-0002-2997-7611; Butterfield, David/0000-0002-1595-9279 FU NOAA Ocean Exploration Program; NSERC Canada; BMBF [03G0192] FX We thank the following for help with sample collection: J. Jones, S. K. Juniper, C. Stevens and R. Vrijenhoek. M. Leybourne provided some shipboard water analyses and G. Yahel designed samplers. The operators of the ROVs ROPOS and Jason-II provided field support as did the crews of RVs Thompson, Melville and Sonne. We are grateful for operating permissions from the Kingdom of Tonga and from New Zealand. In the laboratory, we acknowledge the work of S. Merle, K. Roe, N. Buck, D. Eerkes-Medrano and C. Rideout. Expeditions were funded through the NOAA Ocean Exploration Program, the NOAA Vents Program, NSERC Canada and BMBF 03G0192 Project MANGO of Germany. Additional funding to V. T. from the Canada Research Chairs programme is acknowledged. NR 27 TC 81 Z9 84 U1 4 U2 57 PU NATURE PUBLISHING GROUP PI NEW YORK PA 75 VARICK ST, 9TH FLR, NEW YORK, NY 10013-1917 USA SN 1752-0894 EI 1752-0908 J9 NAT GEOSCI JI Nat. Geosci. PD MAY PY 2009 VL 2 IS 5 BP 344 EP 348 DI 10.1038/NGEO500 PG 5 WC Geosciences, Multidisciplinary SC Geology GA 452MA UT WOS:000266542900015 ER PT J AU Prabhu, VM Hudson, SD AF Prabhu, Vivek M. Hudson, Steven D. TI NANOPARTICLE ASSEMBLY DNA provides control SO NATURE MATERIALS LA English DT News Item ID CRYSTALLIZATION C1 [Prabhu, Vivek M.; Hudson, Steven D.] Natl Inst Stand & Technol, Div Polymers, Mat Sci & Engn Lab, Gaithersburg, MD 20889 USA. RP Prabhu, VM (reprint author), Natl Inst Stand & Technol, Div Polymers, Mat Sci & Engn Lab, Gaithersburg, MD 20889 USA. EM vprabhu@nist.gov; steven.hudson@nist.gov NR 7 TC 7 Z9 7 U1 1 U2 14 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 1476-1122 J9 NAT MATER JI Nat. Mater. PD MAY PY 2009 VL 8 IS 5 BP 365 EP 366 DI 10.1038/nmat2436 PG 2 WC Chemistry, Physical; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter SC Chemistry; Materials Science; Physics GA 441QH UT WOS:000265783500008 PM 19387446 ER PT J AU Chittaro, PM Finley, RJ Levin, PS AF Chittaro, Paul M. Finley, Rachel J. Levin, Phillip S. TI Spatial and temporal patterns in the contribution of fish from their nursery habitats SO OECOLOGIA LA English DT Article DE Nursery habitat; Otolith chemistry; English sole; Puget Sound ID SOLE PAROPHRYS-VETULUS; JUVENILE ENGLISH SOLE; PUGET-SOUND; ELEMENTAL COMPOSITION; PLEURONECTES-VETULUS; CHEMICAL SIGNATURES; MARINE CONSERVATION; OTOLITHS INDICATE; PAGRUS-AURATUS; WEST-COAST AB Because anthropogenic influences threaten the degradation of many ecosystems, determining where organisms live during early life-history stages and the extent to which different areas contribute individuals to adult populations is critical for the management and conservation of a species. Working in Puget Sound, Washington State in the United States, and using a common flatfish (English sole, Parophrys vetulus), we sought to establish (using otolith chemistry) which areas contribute age-0 fish to age-1 population(s), the extent to which this pattern was consistent between two years, and whether this spatial pattern of contribution coincides with surveys of age-0 fish and/or the available area of nearshore habitat. Our study indicated completely different spatial patterns of fish nursery use between the two years of sampling. We highlight that the contribution of individuals from nursery areas is not related to density of recently settled English sole or the available area of nearshore habitat (depth < 10 m) in Puget Sound, nor can we draw conclusions based on environmental data (precipitation, water salinity, light transmission, pH, dissolved oxygen, and water temperature). The results of this study highlight (1) the need for assessing the temporal patterns of nursery habitat use, and (2) that, in order to conservatively manage a species and its population(s), it may be necessary to protect several areas that are used intermittently by that species. C1 [Chittaro, Paul M.; Finley, Rachel J.; Levin, Phillip S.] NW Fisheries Sci Ctr, Natl Marine Fisheries Serv, Seattle, WA 98112 USA. RP Chittaro, PM (reprint author), NW Fisheries Sci Ctr, Natl Marine Fisheries Serv, 2725 Montlake Blvd E, Seattle, WA 98112 USA. EM Paul.Chittaro@noaa.gov NR 71 TC 29 Z9 29 U1 3 U2 17 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0029-8549 J9 OECOLOGIA JI Oecologia PD MAY PY 2009 VL 160 IS 1 BP 49 EP 61 DI 10.1007/s00442-009-1282-4 PG 13 WC Ecology SC Environmental Sciences & Ecology GA 431YK UT WOS:000265100500006 PM 19214587 ER PT J AU Samhouri, JF Vance, RR Forrester, GE Steele, MA AF Samhouri, Jameal F. Vance, Richard R. Forrester, Graham E. Steele, Mark A. TI Musical chairs mortality functions: density-dependent deaths caused by competition for unguarded refuges SO OECOLOGIA LA English DT Article DE Refuges; Mortality functions; Coral reef fish; Density dependence; Coryphopterus glaucofraenum ID CORAL-REEF FISH; PREY REFUGES; PREDATION RISK; SPOTTED SALAMANDERS; SEAGRASS LANDSCAPE; HABITAT SELECTION; PHASE-DEPENDENCE; TEMPERATE REEF; SPINY LOBSTER; SURVIVAL AB Structural refuges within which prey can escape from predators can be an important limiting resource for the prey. In a manner that resembles the childhood game of musical chairs, many prey species rapidly retreat to shared, unguarded refuges whenever a predator threatens, and only when refuges are relatively abundant do all prey individuals actually escape. The key feature of this process is that the per capita prey mortality rate depends on the ratio of prey individuals to refuges. We introduce a new class of mortality functions with this feature and then demonstrate statistically that they describe field mortality data from a well-studied coral reef fish species, the Caribbean bridled goby Coryphopterus glaucofraenum, substantially better than do several mortality functions of more conventional form. C1 [Samhouri, Jameal F.] NOAA Fisheries, NW Fisheries Sci Ctr, Seattle, WA 98112 USA. [Samhouri, Jameal F.; Vance, Richard R.] Univ Calif Los Angeles, Dept Ecol & Evolutionary Biol, Los Angeles, CA 90095 USA. [Forrester, Graham E.] Univ Rhode Isl, Dept Nat Resources Sci, Kingston, RI 02881 USA. [Steele, Mark A.] Calif State Univ Northridge, Dept Biol, Northridge, CA 91330 USA. RP Samhouri, JF (reprint author), NOAA Fisheries, NW Fisheries Sci Ctr, 2725 Montlake Blvd E, Seattle, WA 98112 USA. EM Jameal.Samhouri@noaa.gov OI Forrester, Graham/0000-0001-5253-773X FU NSF; AMNH Lerner-Grey Fund; ASIH Raney Fund; IWFA Ryan Kelley Memorial Scholarship; UCLA Department of Ecology and Evolutionary Biology; NOAA-NURP [CMRC05-PRRV-01-05A, CMRC-01-NRME-01-03C, CMRC-03-NRME-01-04A, CMRC-03-NRME-01-05C]; NSF [OCE 0222087] FX This research benefited greatly from discussions with S. Hamilton, K. Holsman, E. Landaw, C. Osenberg, S. Sandin, and W. White. Criticism of earlier drafts by M. Mangel, D. DeAngelis, J. Fryxell, Y. Lucero, J. Shima, C. Osenberg, and two anonymous reviewers improved the presentation. Financial support was provided by an NSF pre-doctoral fellowship, and grants from the AMNH Lerner-Grey Fund, the ASIH Raney Fund, IWFA Ryan Kelley Memorial Scholarship, Sigma Xi Grants-in-Aid of Research, UC Regents, and the UCLA Department of Ecology and Evolutionary Biology to J. F. S., a NOAA-NURP grant to R. R. V. and J. F. S. (CMRC05-PRRV-01-05A), and grants from NSF (OCE 0222087) and NOAA-NURP (CMRC-01-NRME-01-03C, CMRC-03-NRME-01-04A, CMRC-03-NRME-01-05C) to G. E. F., M. A. S., and R. R. V. Views expressed herein are those of the authors and do not necessarily reflect those of CMRC/NOAA. NR 54 TC 13 Z9 13 U1 2 U2 14 PU SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013 USA SN 0029-8549 J9 OECOLOGIA JI Oecologia PD MAY PY 2009 VL 160 IS 2 BP 257 EP 265 DI 10.1007/s00442-009-1307-z PG 9 WC Ecology SC Environmental Sciences & Ecology GA 444WI UT WOS:000266010700006 PM 19263085 ER PT J AU Adler, F Cossel, KC Thorpe, MJ Hartl, I Fermann, ME Ye, J AF Adler, Florian Cossel, Kevin C. Thorpe, Michael J. Hartl, Ingmar Fermann, Martin E. Ye, Jun TI Phase-stabilized, 1.5 W frequency comb at 2.8-4.8 mu m SO OPTICS LETTERS LA English DT Article ID OPTICAL PARAMETRIC OSCILLATOR; SPECTROSCOPY; GENERATION; LASER AB We present a high-power optical-parametric-oscillator (OPO) based frequency comb in the mid-IR wavelength region. The system employs periodically poled lithium niobate and is singly resonant for the signal. It is synchronously pumped by a 10 W femtosecond Yb:fiber laser centered at 1.07 mu m. The idler (signal) wavelength can be continuously tuned from 2.8 to 4.8 mu m (1.76 to 1.37 mu m) with a simultaneous bandwidth as high as 0.3 mu m and a maximum average idler output power of 1.50 W. We also demonstrate the performance of the stabilized comb by recording the heterodyne beat with a narrow-linewidth diode laser. This OPO is an ideal source for frequency comb spectroscopy in the mid-IR. (C) 2009 Optical Society of America C1 [Adler, Florian; Cossel, Kevin C.; Thorpe, Michael J.; Ye, Jun] Natl Inst Stand & Technol, JILA, Boulder, CO 80309 USA. [Adler, Florian; Cossel, Kevin C.; Thorpe, Michael J.; Ye, Jun] Univ Colorado, Dept Phys, Boulder, CO 80309 USA. [Hartl, Ingmar; Fermann, Martin E.] IMRA Amer Inc, Ann Arbor, MI 48105 USA. RP Adler, F (reprint author), Natl Inst Stand & Technol, JILA, 325 Broadway, Boulder, CO 80309 USA. EM fadler@jila.colorado.edu RI Ye, Jun/C-3312-2011 FU Alexander von Humboldt foundation; U.S. Air Force Office of Scientific Research (AFOSR); Defense Advanced Research Projects Agency (DARPA); National Institute of Standards and Technology (NIST); Agilent FX We thank D. C. Yost, M. J. Martin, and T. R. Schibli for valuable assistance. F. Adler acknowledges support by the Alexander von Humboldt foundation. This work is funded by U.S. Air Force Office of Scientific Research (AFOSR), the Defense Advanced Research Projects Agency (DARPA), the National Institute of Standards and Technology (NIST), and Agilent. NR 16 TC 171 Z9 173 U1 6 U2 54 PU OPTICAL SOC AMER PI WASHINGTON PA 2010 MASSACHUSETTS AVE NW, WASHINGTON, DC 20036 USA SN 0146-9592 J9 OPT LETT JI Opt. Lett. PD MAY 1 PY 2009 VL 34 IS 9 BP 1330 EP 1332 PG 3 WC Optics SC Optics GA 451MT UT WOS:000266475000013 PM 19412262 ER PT J AU Heilweil, EJ Maslar, JE Kimes, WA Bassim, ND Schenck, PK AF Heilweil, Edwin J. Maslar, James E. Kimes, William A. Bassim, Nabil D. Schenck, Peter K. TI Characterization of metal oxide nanofilm morphologies and composition by terahertz transmission spectroscopy SO OPTICS LETTERS LA English DT Article ID PULSED-LASER DEPOSITION; THIN-FILMS; TIO2; TEMPERATURE; RUTILE; MODES AB Am all-optical terahertz absorption technique for nondestructive characterization of nanometer-scale metal oxide thin films grown on silicon substrates is described. Example measurements of laser-deposited TiO(2) and atomic layer-deposited films of HfO(2) are presented to demonstrate applicability to pure Y(2)O(3), Al(2)O(3), and VO(x) and mixed combinatorial films as a function of deposition conditions and thickness. This technique is also found to be sensitive to HfO(2) phonon modes in films with a nominal thickness of 5 nm. C1 [Heilweil, Edwin J.] NIST, Opt Technol Div, Gaithersburg, MD 20899 USA. [Maslar, James E.; Kimes, William A.] NIST, Proc Measurements Div, Gaithersburg, MD 20899 USA. [Bassim, Nabil D.; Schenck, Peter K.] NIST, Div Ceram, Gaithersburg, MD 20899 USA. RP Heilweil, EJ (reprint author), NIST, Opt Technol Div, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM edwin.heilweil@nist.gov FU NIST Physics and Chemical Science and Technology Laboratories Scientific and Technical Research Services (STRS); Office of Microelectronics Programs FX This work was supported by the NIST Physics and Chemical Science and Technology Laboratories Scientific and Technical Research Services (STRS) funding and the Office of Microelectronics Programs. J. E. Maslar and W A. Kimes also gratefully acknowledge N. V. Nguyen for HfO2 deposition rate determinations and R. R. Fink and M. J. Carrier for technical assistance in HfO2 deposition. NR 15 TC 5 Z9 5 U1 1 U2 10 PU OPTICAL SOC AMER PI WASHINGTON PA 2010 MASSACHUSETTS AVE NW, WASHINGTON, DC 20036 USA SN 0146-9592 J9 OPT LETT JI Opt. Lett. PD MAY 1 PY 2009 VL 34 IS 9 BP 1360 EP 1362 PG 3 WC Optics SC Optics GA 451MT UT WOS:000266475000023 PM 19412272 ER PT J AU Liu, YX Lee, YJ Cicerone, MT AF Liu, Yuexin Lee, Young Jong Cicerone, Marcus T. TI Broadband CARS spectral phase retrieval using a time-domain Kramers-Kronig transform SO OPTICS LETTERS LA English DT Article ID STOKES-RAMAN SCATTERING; SPECTROSCOPY AB We describe a closed-form approach for performing a Kramers-Kronig (KK) transform that can be used to rapidly and reliably retrieve the phase, and thus the resonant imaginary component, from a broadband coherent anti-Stokes Raman scattering (CARS) spectrum with a nonflat background. In this approach we transform the frequency-domain data to the time domain, perform an operation that ensures a causality criterion is met, then transform back to the frequency domain. The fact that this method handles causality in the time domain allows us to conveniently account for spectrally varying nonresonant background from CARS as a response function with a finite rise time. A phase error accompanies KK transform of data with finite frequency range. In examples shown here, that phase error leads to small (<1%) errors in the retrieved resonant spectra. C1 [Liu, Yuexin; Lee, Young Jong; Cicerone, Marcus T.] NIST, Div Polymers, Gaithersburg, MD 20899 USA. RP Cicerone, MT (reprint author), NIST, Div Polymers, Gaithersburg, MD 20899 USA. EM cicerone@nist.gov RI Lee, Young Jong/B-7129-2008 OI Lee, Young Jong/0000-0001-7754-3001 FU NIBIB NIH HHS [R21 EB002468] NR 19 TC 87 Z9 88 U1 2 U2 13 PU OPTICAL SOC AMER PI WASHINGTON PA 2010 MASSACHUSETTS AVE NW, WASHINGTON, DC 20036 USA SN 0146-9592 J9 OPT LETT JI Opt. Lett. PD MAY 1 PY 2009 VL 34 IS 9 BP 1363 EP 1365 PG 3 WC Optics SC Optics GA 451MT UT WOS:000266475000024 PM 19412273 ER PT J AU Perez, FR Barrero, CA Arnache, O Sanchez, LC Garcia, KE Walker, ARH AF Perez, F. R. Barrero, C. A. Arnache, O. Sanchez, L. C. Garcia, K. E. Walker, A. R. Hight TI Structural properties of iron phases formed on low alloy steels immersed in sodium chloride-rich solutions SO PHYSICA B-CONDENSED MATTER LA English DT Article DE Corrosion and protection; Mossbauer spectrometry; X-ray diffraction; Raman and infrared spectroscopy ID WEATHERING STEEL; MOSSBAUER CHARACTERIZATION; PROTECTIVE ABILITY; LONG-TERM; CORROSION; MAGNETITE; NANOPARTICLES; ENVIRONMENTS; SPECTRA; OXIDES AB Products of corrosion were obtained from low alloy steels submitted to total immersion tests in solutions containing sodium chloride at different concentrations, during seven days. In order to properly characterize the adherent (AR) and the non-adherent rusts (NAR), a methodology including room temperature Mossbauer spectrometry, diffuse reflectance infrared Fourier transform spectroscopy, Raman spectroscopy, scanning electron microscopy and X-ray diffraction was addressed. The techniques showed that the AR samples were composed of non-stoichiometric magnetite, goethite, akaganeite and lepidocrocite. The composition of the NAR samples was the same, but with very small amounts of magnetite. Different cell parameters and mean crystallite sizes were found for all phases presented in AR and the NAR samples. The corrosion rates were higher than 580 mu m/y. The ratio of the abundances of goethite to the sum of lepidocrocite, akaganeite and magnetite were less than one. (C) 2008 Elsevier B.V. All rights reserved. C1 [Perez, F. R.] Univ Pontificia Bolivariana, Grp Opt & Espectroscopia, Medellin, Colombia. [Perez, F. R.; Barrero, C. A.; Arnache, O.; Sanchez, L. C.; Garcia, K. E.] Univ Antioquia, Grp Estado Solido, Medellin, Colombia. [Walker, A. R. Hight] NIST, Phys Lab, Gaithersburg, MD 20899 USA. RP Perez, FR (reprint author), Univ Pontificia Bolivariana, Grp Opt & Espectroscopia, AA 56006, Medellin, Colombia. EM fredy.perez@upb.edu.co RI Hight Walker, Angela/C-3373-2009 OI Hight Walker, Angela/0000-0003-1385-0672 FU CODI-Universidad de Antioquia [E01248CE]; CIDI-Universidad Pontificia Bolivariana [889-05/06-27] FX Authors greatly acknowledge to CODI-Universidad de Antioquia (Projects E01248CE and Sustainability Programs during 2007-2008 for both the Solid State and the Scientific Instrumentation and Microelectronic Groups) and CIDI-Universidad Pontificia Bolivariana (Project 889-05/06-27) for financial support. Thanks go to M. Perez of Universidad Nacional of Colombia Sede-Medellin for the SEM measurements. NR 29 TC 9 Z9 9 U1 0 U2 11 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0921-4526 J9 PHYSICA B JI Physica B PD MAY 1 PY 2009 VL 404 IS 8-11 BP 1347 EP 1353 DI 10.1016/j.physb.2008.12.020 PG 7 WC Physics, Condensed Matter SC Physics GA 443BV UT WOS:000265886100059 ER PT J AU Yildirim, T AF Yildirim, Taner TI Frustrated magnetic interactions, giant magneto-elastic coupling, and magnetic phonons in iron-pnictides SO PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS LA English DT Article DE Iron-pnictides; High-T(c) superconductors; First-principles calculations; Phonons; Magneto-elastic coupling; Electron-phonon coupling; Spin-waves; Frustration ID SUPERCONDUCTIVITY; INSTABILITY; DYNAMICS AB We present a detailed first-principles study of Fe-pnictides with particular emphasis on competing magnetic interactions, structural phase transition, giant magneto-elastic coupling and its effect on phonons. The exchange interactions J(ij)(R) are Calculated up to approximate to 12 angstrom from two different approaches based on direct spin-flip and infinitesimal spin-rotation. We find that J(ij)(R) has an oscillatory character with an envelop decaying as 1/R(3) along the stripe-direction while it is very short range along the diagonal direction and anti ferromagnetic. A brief discussion of the neutron scattering determination of these exchange constants from a single crystal sample with orthorhombic-twinning is given. The lattice parameter dependence of the exchange constants, dJ(ij)/da are calculated for a simple spin-Peierls like model to explain the fine details of the tetragonal-orthorhombic phase transition. We then discuss giant magneto-elastic effects in these systems. We show that when the Fe-spin is turned off the optimized c-values are shorter than experimental values by 1.4 angstrom for CaFe(2)As(2), by 0.4 angstrom for BaFe(2)As(2), and by 0.13 angstrom for LaOFeAs. We explain this strange behavior by unraveling surprisingly strong interactions between arsenic ions, the strength of which is controlled by the Fe-spin state through Fe-As hybridization. Reducing the Fe-magnetic moment, weakens the Fe-As bonding, and in turn, increases As-As interactions, causing a giant reduction in the c-axis. These findings also explain why the Fe-moment is so tightly coupled to the As-z position. Finally, we show that Fe-spin is also required to obtain the right phonon energies, in particular As c-polarized and Fe-Fe in-plane modes that have been recently observed by inelastic X-ray and neutron scattering but cannot be explained based on non-magnetic phonon calculations. Since treating iron as magnetic ion always gives Much better results than non-magnetic ones and since there is no large c-axis reduction during the normal to superconducting phase transition, the iron magnetic moment should be present in Fe-pnictides at all times. We discuss the implications of our results on the mechanism of superconductivity in these fascinating Fe-pnictide systems. (C) 2009 Published by Elsevier B.V. C1 [Yildirim, Taner] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Yildirim, Taner] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA. RP Yildirim, T (reprint author), Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. EM taner@nist.gov RI yildirim, taner/A-1290-2009 NR 78 TC 93 Z9 94 U1 2 U2 32 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0921-4534 J9 PHYSICA C JI Physica C PD MAY-JUN PY 2009 VL 469 IS 9-12 BP 425 EP 441 DI 10.1016/j.physc.2009.03.038 PG 17 WC Physics, Applied SC Physics GA 460MJ UT WOS:000267191500015 ER PT J AU Lynn, JW Dai, PC AF Lynn, Jeffrey W. Dai, Pengcheng TI Neutron studies of the iron-based family of high T-C magnetic superconductors SO PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS LA English DT Article DE Iron superconductors; Neutron scattering; Crystal and magnetic structures; Spin dynamics ID SCATTERING AB We review neutron scattering investigations of the crystal structures, magnetic structures, and spin dynamics of the iron-based RFe(As, P)(O, F) (R = La, Ce. Pr, Nd), (Ba,Sr,Ca)Fe2As2, and Fe1+x(Te-Se) systems. On cooling from room temperature all the undoped materials exhibit universal behavior, where a tetragonal-to-orthorhombic/monoclinic structural transition Occurs, below which the systems become antiferromagnets. For the first two classes of materials the magnetic structure within the a-b plane consists of chains of parallel Fe spins that are coupled antiferromagnetically in the orthogonal direction, with an ordered moment typically less than one Bohr magneton. Hence these are itinerant electron magnets, with a spin structure that is consistent with Fermi-surface nesting and a very energetic spin wave bandwidth similar to 0.2 eV. With doping, the structural and magnetic transitions are suppressed in favor of superconductivity, with Superconducting transition temperatures up to approximate to 55 K. Magnetic correlations are observed in the Superconducting regime, With a Magnetic resonance that follows the Superconducting order parameter just like the cuprates. The rare earth moments order antiferromagnetically at low T like 'conventional' Magnetic Superconductors, while the Cc crystal field linewidths are affected when superconductivity sets in. The application of pressure in CaFe2As2 transforms the system from a magnetically ordered orthorhombic material to a 'collapsed' non-magnetic tetragonal system. Tetragonal Fe1+xTe transforms to a low T monoclinic structure at small x that changes to orthorhombic at larger x, which is accompanied by a crossover from commensurate to incommensurate magnetic order. Se doping Suppresses the magnetic order, while incommensurate magnetic correlations are observed in the superconducting regime. (C) 2009 Elsevier B.V. All rights reserved. C1 [Lynn, Jeffrey W.] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Dai, Pengcheng] Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA. [Dai, Pengcheng] Oak Ridge Natl Lab, Neutron Scattering Sci Div, Oak Ridge, TN 37831 USA. RP Lynn, JW (reprint author), Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. EM Jeff.Lynn@nist.gov RI Dai, Pengcheng /C-9171-2012 OI Dai, Pengcheng /0000-0002-6088-3170 FU US Department of Energy, Division of Materials Science, Basic Energy Sciences [DE-FG02-05ER46202]; US National Science Foundation [DMR-0756568] FX The authors would like to express their sincere gratitude to all of their collaborators, as listed in the references, who have shared the research excitement of this new family Of Superconductors. We thank R.J. McQueeney for helpful discussions. P.D. is supported by the US Department of Energy, Division of Materials Science, Basic Energy Sciences, through DOE DE-FG02-05ER46202; and by the US National Science Foundation through DMR-0756568. This work is also Supported in part by the US Department of Energy, Division of Scientific User Facilities, Basic Energy Sciences. NR 52 TC 107 Z9 110 U1 4 U2 50 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0921-4534 EI 1873-2143 J9 PHYSICA C JI Physica C PD MAY-JUN PY 2009 VL 469 IS 9-12 BP 469 EP 476 DI 10.1016/j.physc.2009.03.046 PG 8 WC Physics, Applied SC Physics GA 460MJ UT WOS:000267191500020 ER PT J AU Fischer, CF AF Fischer, Charlotte Froese TI Evaluating the accuracy of theoretical transition data SO PHYSICA SCRIPTA LA English DT Article; Proceedings Paper CT 9th International Conference on Atomic Spectroscopy and Oscillator Strengths for Astrophysical and Laboratory Plasma CY AUG 07-10, 2007 CL Lund Univ, Lund Observatory & Phys Dept, Lund, SWEDEN HO Lund Univ, Lund Observatory & Phys Dept ID PAULI ENERGY-LEVELS; OSCILLATOR-STRENGTHS; C-III; INTERCOMBINATION LINE; LOWER BOUNDS; PROBABILITIES; LITHIUM; LIFETIMES; NITROGEN; CARBON AB As theory produces more and more transition probabilities for which experimental values are not available, an independent assessment of accuracy is needed. Factors affecting accuracy of theoretical results are discussed. It is shown how the accuracy of the transition energy and the discrepancy in the length and velocity form of the line strength, in a general way, can determine which of two ab initio sets of results are the more accurate. Some methods of estimating absolute accuracy are proposed and compared with the online Atomic Spectra Database assessments. C1 [Fischer, Charlotte Froese] NIST, Gaithersburg, MD 20899 USA. RP Fischer, CF (reprint author), NIST, Gaithersburg, MD 20899 USA. EM Charlotte.Fischer@Nist.Gov NR 39 TC 25 Z9 25 U1 1 U2 5 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0031-8949 J9 PHYS SCRIPTA JI Phys. Scr. PD MAY PY 2009 VL T134 AR 014019 DI 10.1088/0031-8949/2009/T134/014019 PG 6 WC Physics, Multidisciplinary SC Physics GA 465UG UT WOS:000267612800020 ER PT J AU Kerber, F Nave, G Sansonetti, CJ Bristow, P AF Kerber, Florian Nave, Gillian Sansonetti, Craig J. Bristow, Paul TI From laboratory to the sky: Th-Ar wavelength standards for the cryogenic infrared echelle spectrograph (CRIRES) SO PHYSICA SCRIPTA LA English DT Article; Proceedings Paper CT 9th International Conference on Atomic Spectroscopy and Oscillator Strengths for Astrophysical and Laboratory Plasma CY AUG 07-10, 2007 CL Lund Univ, Lund Observatory & Phys Dept, Lund, SWEDEN HO Lund Univ, Lund Observatory & Phys Dept ID RESOLUTION SPECTRAL ATLAS; HOLLOW-CATHODE LAMPS; OH-EMISSION LINES; ZINC ABUNDANCES; NM REGION; CALIBRATION; SULFUR; STARS; VLT AB We report on the collaborative effort of the European Southern Observatory (ESO) and the National Institute of Standards and Technology (NIST) to establish-through laboratory measurements-wavelength standards in the near-infrared (IR) emission line spectrum of a low current Th-Ar hollow cathode lamp. These standards are now routinely used for the wavelength calibration of the cryogenic infrared echelle spectrograph (CRIRES) operated at one of the unit telescopes of the very large telescope (VLT) at ESO's La Silla Paranal Observatory in Chile. The availability of highly accurate wavelength standards from a commercially available calibration source permits a shift to a new operational paradigm for high-resolution IR spectroscopy. Wavelength calibration no longer has to rely on atmospheric features but can make use of laboratory traceable reference data as is normally done in the ultraviolet and visible regions. This opens the door for more quantitative spectroscopic work in the near-IR. To illustrate the potential impact of this development, we briefly review the current state of affairs in IR astronomy and its projected future. With the advent of the next generation of extremely large ground-based telescopes the IR region will become the most powerful window on the universe within the next 10-15 years. We conclude with a short outlook on the contribution atomic physics can make to this evolution. C1 [Kerber, Florian; Bristow, Paul] European So Observ, D-85748 Garching, Germany. [Nave, Gillian; Sansonetti, Craig J.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Kerber, F (reprint author), European So Observ, Karl Schwarzschild Str 2, D-85748 Garching, Germany. EM fkerber@eso.org; gillian.nave@nist.gov; craig.sansonetti@nist.gov; bristowp@eso.org NR 30 TC 8 Z9 8 U1 1 U2 1 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0031-8949 J9 PHYS SCRIPTA JI Phys. Scr. PD MAY PY 2009 VL T134 AR 014007 DI 10.1088/0031-8949/2009/T134/014007 PG 8 WC Physics, Multidisciplinary SC Physics GA 465UG UT WOS:000267612800008 ER PT J AU Ralchenko, Y AF Ralchenko, Yuri TI Online databases and computational tools for non-LTE spectroscopy SO PHYSICA SCRIPTA LA English DT Article; Proceedings Paper CT 9th International Conference on Atomic Spectroscopy and Oscillator Strengths for Astrophysical and Laboratory Plasma CY AUG 07-10, 2007 CL Lund Univ, Lund Observatory & Phys Dept, Lund, SWEDEN HO Lund Univ, Lund Observatory & Phys Dept ID OPTICALLY THIN PLASMAS; IONIZATION EQUILIBRIUM; RATE COEFFICIENTS; WORKSHOP; IONS; BALANCE; ATOMS AB Atomic structure and collisional databases have been actively developed since the early era of the World Wide Web. It is only recently that a number of plasma kinetics databases have become available for the physics community. Moreover, it is now possible to perform advanced online collisional-radiative calculations for plasmas far from local thermodynamic equilibrium (LTE). We describe several online databases and tools that can be used in non-LTE research. Special attention is given to the new databases recently developed at the National Institute of Standards and Technology. C1 NIST, Atom Phys Div, Gaithersburg, MD 20899 USA. RP Ralchenko, Y (reprint author), NIST, Atom Phys Div, Gaithersburg, MD 20899 USA. EM yuri.ralchenko@nist.gov RI Ralchenko, Yuri/E-9297-2016; Ralchenko, Yuri/B-7687-2011 OI Ralchenko, Yuri/0000-0003-0083-9554; NR 21 TC 4 Z9 4 U1 0 U2 2 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0031-8949 J9 PHYS SCRIPTA JI Phys. Scr. PD MAY PY 2009 VL T134 AR 014025 DI 10.1088/0031-8949/2009/T134/014025 PG 8 WC Physics, Multidisciplinary SC Physics GA 465UG UT WOS:000267612800026 ER PT J AU Reader, J AF Reader, Joseph TI Spectral data for fusion energy: from W to W SO PHYSICA SCRIPTA LA English DT Article; Proceedings Paper CT 9th International Conference on Atomic Spectroscopy and Oscillator Strengths for Astrophysical and Laboratory Plasma CY AUG 07-10, 2007 CL Lund Univ, Lund Observatory & Phys Dept, Lund, SWEDEN HO Lund Univ, Lund Observatory & Phys Dept ID ZN-LIKE IONS; COPPER ISOELECTRONIC SEQUENCE; HIGHLY IONIZED TUNGSTEN; CHARGED CU-LIKE; TRANSITION-PROBABILITIES; TOKAMAK DISCHARGES; ATOMIC SPECTRA; CO-LIKE; WAVELENGTHS; RADIATION AB Experimental and theoretical techniques to produce spectral data for fusion energy have evolved greatly since the 1970s. Light sources have progressed from energetic sparks and laser-produced plasmas to electron beam ion traps (EBITs) and tokamaks themselves. Theory has advanced from non-relativistic Hartree-Fock to fully relativistic Dirac-Fock calculations and detailed collisional-radiative (CR) modeling of plasmas with codes generating large numbers of cross sections and other atomic data. A great deal of work of late has focused on tungsten, which although originally thought to be not usable for high-temperature machines, has now been selected to play an important role in ITER, the international tokamak reactor to be built in France. Work on tungsten from various laboratories and recent results for highly ionized W from the EBIT at the National Institute of Standards and Technology are discussed. C1 NIST, Gaithersburg, MD 20899 USA. RP Reader, J (reprint author), NIST, Gaithersburg, MD 20899 USA. EM joseph.reader@nist.gov NR 56 TC 29 Z9 29 U1 1 U2 8 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0031-8949 J9 PHYS SCRIPTA JI Phys. Scr. PD MAY PY 2009 VL T134 AR 014023 DI 10.1088/0031-8949/2009/T134/014023 PG 11 WC Physics, Multidisciplinary SC Physics GA 465UG UT WOS:000267612800024 ER PT J AU Bieron, J Fischer, CF Indelicato, P Jonsson, P Pyykko, P AF Bieron, Jacek Fischer, Charlotte Froese Indelicato, Paul Jonsson, Per Pyykko, Pekka TI Complete-active-space multiconfiguration Dirac-Hartree-Fock calculations of hyperfine-structure constants of the gold atom SO PHYSICAL REVIEW A LA English DT Article DE atomic moments; configuration interactions; Dirac-Fock calculations; electron correlations; gold; hyperfine structure; quadrupole moments ID SCALAR RELATIVISTIC CALCULATIONS; NUCLEAR-QUADRUPOLE MOMENTS; KROLL-HESS METHOD; THEORETICAL CHEMISTRY; CONFIGURATION; PROGRAM; LITHIUM; AU-197; STATES; MODEL AB The multiconfiguration Dirac-Hartree-Fock model has been employed to calculate the expectation values for the hyperfine splittings of the 5d(9)6s(2) D-2(3/2) and 5d(9)6s(2) D-2(5/2) levels of atomic gold. One-, two-, and three-body electron correlation effects involving all 79 electrons have been included in a systematic manner. The approximation employed in this study is equivalent to a complete-active-space approach. Calculated electric field gradients, together with experimental values of the electric quadrupole hyperfine-structure constants, allow us to extract a nuclear electric quadrupole moment Q(Au-197)=521.5(5.0) mb. C1 [Bieron, Jacek] Jagiellonian Univ, Inst Fizyki Imienia Mariana Smoluchowskiego, PL-30059 Krakow, Poland. [Fischer, Charlotte Froese] NIST, Gaithersburg, MD 20899 USA. [Indelicato, Paul] Univ Paris 06, CNRS, Ecole Normale Super, Lab Kastler Brossel, F-75252 Paris 05, France. [Jonsson, Per] Malmo Univ, S-20506 Malmo, Sweden. [Pyykko, Pekka] Univ Helsinki, Dept Chem, Helsinki, Finland. RP Bieron, J (reprint author), Jagiellonian Univ, Inst Fizyki Imienia Mariana Smoluchowskiego, Reymonta 4, PL-30059 Krakow, Poland. RI Indelicato, Paul/D-7636-2011; Jonsson, Per/L-3602-2013 OI Indelicato, Paul/0000-0003-4668-8958; Jonsson, Per/0000-0001-6818-9637 FU Polish Ministry of Science and Higher Education (MNiSW) [1 P03B 110 30]; Swedish Research Council; Academy of Finland; Helmholtz Association [HA-216] FX This work was supported by the Polish Ministry of Science and Higher Education (MNiSW) in the framework of scientific Grant No. 1 P03B 110 30 available for the years 2006-2009. P.J. acknowledges support from the Swedish Research Council (Vetenskapsradet). P.P. belongs to the Finnish Center of Excellence in Computational Molecular Science (CMS). The visits of J.B. at Helsinki were supported by The Academy of Finland. The large scale calculations were performed on the Raritan Linux cluster at the National Institute of Standards and Technology (NIST) in Gaithersburg, USA. J.B. would like to express his gratitude for the hospitality which was extended to him during his visits to the Chemistry Department of the University of Helsinki and the Atomic Spectroscopy Group at NIST. P.I. acknowledges the support of the Helmholtz Alliance Program of the Helmholtz Association under Contract No. HA-216 ("Extremes of Density and Temperature: Cosmic Matter in the Laboratory"). Laboratoire Kastler Brossel is "Unite Mixte de Recherche du CNRS, de l'ENS et de l'UPMC No. 8552." We thank the (anonymous) referee for pointing our attention to the structural differences between CI and CC methods. NR 46 TC 20 Z9 22 U1 1 U2 11 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1050-2947 EI 1094-1622 J9 PHYS REV A JI Phys. Rev. A PD MAY PY 2009 VL 79 IS 5 AR 052502 DI 10.1103/PhysRevA.79.052502 PG 10 WC Optics; Physics, Atomic, Molecular & Chemical SC Optics; Physics GA 451WF UT WOS:000266500900082 ER PT J AU Herrmann, M Haas, M Jentschura, UD Kottmann, F Leibfried, D Saathoff, G Gohle, C Ozawa, A Batteiger, V Knunz, S Kolachevsky, N Schussler, HA Hansch, TW Udem, T AF Herrmann, M. Haas, M. Jentschura, U. D. Kottmann, F. Leibfried, D. Saathoff, G. Gohle, C. Ozawa, A. Batteiger, V. Knuenz, S. Kolachevsky, N. Schuessler, H. A. Haensch, T. W. Udem, Th. TI Feasibility of coherent xuv spectroscopy on the 1S-2S transition in singly ionized helium SO PHYSICAL REVIEW A LA English DT Article DE atom-photon collisions; helium; Lamb shift; photoexcitation; photoionisation; positive ions; quantum electrodynamics; two-photon spectra; ultraviolet spectra ID HYPERFINE-STRUCTURE INTERVAL; ORDER HARMONIC-GENERATION; MAGNETIC-MOMENT; FREQUENCY COMB; 2-PHOTON SPECTROSCOPY; EXTREME-ULTRAVIOLET; MUONIC HELIUM; OPTICAL-FIELD; GROUND-STATE; LAMB-SHIFT AB The 1S-2S two-photon transition in singly ionized helium is a highly interesting candidate for precision tests of bound-state quantum electrodynamics (QED). With the recent advent of extreme ultraviolet frequency combs, highly coherent quasi-continuous-wave light sources at 61 nm have become available, and precision spectroscopy of this transition now comes into reach for the first time. We discuss quantitatively the feasibility of such an experiment by analyzing excitation and ionization rates, propose an experimental scheme, and explore the potential for QED tests. C1 [Herrmann, M.; Saathoff, G.; Gohle, C.; Ozawa, A.; Batteiger, V.; Knuenz, S.; Kolachevsky, N.; Haensch, T. W.; Udem, Th.] Max Planck Inst Quantum Opt, D-85748 Garching, Germany. [Haas, M.] Univ Hosp Freiburg, Dept Diagnost Radiol, D-79095 Freiburg, Germany. [Jentschura, U. D.] Missouri Univ Sci & Technol, Dept Phys, Rolla, MO 65409 USA. [Kottmann, F.] ETH, Inst Teilchenphys, CH-8093 Zurich, Switzerland. [Leibfried, D.] NIST, Boulder, CO 80305 USA. [Schuessler, H. A.] Texas A&M Univ, Dept Phys, College Stn, TX 77843 USA. [Haensch, T. W.] Univ Munich, D-80539 Munich, Germany. [Kolachevsky, N.] PN Lebedev Phys Inst, Moscow 119991, Russia. RP Herrmann, M (reprint author), Max Planck Inst Quantum Opt, D-85748 Garching, Germany. RI Herrmann, Maximilian/B-2315-2008; Saathoff, Guido/B-1234-2009; Kolachevsky, Nikolai/D-2448-2013 OI Kolachevsky, Nikolai/0000-0001-9587-4955 FU DFG; Max-Planck Foundation FX This research was supported by the DFG cluster of excellence "Munich Centre for Advanced Photonics." T. W. H. gratefully acknowledges support by the Max-Planck Foundation. NR 70 TC 52 Z9 53 U1 0 U2 10 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1050-2947 J9 PHYS REV A JI Phys. Rev. A PD MAY PY 2009 VL 79 IS 5 AR 052505 DI 10.1103/PhysRevA.79.052505 PG 15 WC Optics; Physics, Atomic, Molecular & Chemical SC Optics; Physics GA 451WF UT WOS:000266500900085 ER PT J AU Iskin, M Freericks, JK AF Iskin, M. Freericks, J. K. TI Strong-coupling perturbation theory for the extended Bose-Hubbard model SO PHYSICAL REVIEW A LA English DT Article DE boson systems; charge density waves; ground states; Hubbard model; localised states; optical lattices; perturbation theory ID INSULATOR TRANSITION; PHASE-TRANSITIONS; OPTICAL LATTICE; MOTT-INSULATOR; SUPERFLUID; GAS; MOLECULES; BOSONS; ATOMS AB We develop a strong-coupling perturbation theory for the extended Bose-Hubbard model with on-site and nearest-neighbor boson-boson repulsions on (d>1)-dimensional hypercubic lattices. Analytical expressions for the ground-state phase boundaries between the incompressible (Mott or charge-density-wave insulators) and the compressible (superfluid or supersolid) phases are derived up to third order in the hopping t. We also briefly discuss possible implications of our results in the context of ultracold dipolar Bose gases with dipole-dipole interactions loaded into optical lattices. C1 [Iskin, M.] Natl Inst Stand & Technol, Joint Quantum Inst, Gaithersburg, MD 20899 USA. [Iskin, M.] Univ Maryland, Gaithersburg, MD 20899 USA. [Freericks, J. K.] Georgetown Univ, Dept Phys, Washington, DC 20057 USA. RP Iskin, M (reprint author), Natl Inst Stand & Technol, Joint Quantum Inst, Gaithersburg, MD 20899 USA. RI Freericks, James/D-7502-2011; OI Freericks, James/0000-0002-6232-9165 FU DARPA OLE Program [W911NF0710576] FX We would like to thank E. Tiesinga for many useful discussions. J. K. F. acknowledges support under USARO Grant No. W911NF0710576 with funds from the DARPA OLE Program. NR 29 TC 18 Z9 19 U1 0 U2 3 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1050-2947 J9 PHYS REV A JI Phys. Rev. A PD MAY PY 2009 VL 79 IS 5 AR 053634 DI 10.1103/PhysRevA.79.053634 PG 9 WC Optics; Physics, Atomic, Molecular & Chemical SC Optics; Physics GA 451WF UT WOS:000266500900163 ER PT J AU Iskin, M Tiesinga, E AF Iskin, M. Tiesinga, E. TI Rotation-induced superfluid-normal phase separation in trapped Fermi gases SO PHYSICAL REVIEW A LA English DT Article DE fermion systems; ground states; phase separation; superfluidity; vortices AB We use the Bogoliubov-de Gennes formalism to analyze the effects of rotation on the ground-state phases of harmonically trapped Fermi gases, under the assumption that quantized vortices are not excited. We find that the rotation breaks Cooper pairs that are located near the trap edge, and that this leads to a phase separation between the nonrotating superfluid (fully paired) atoms located around the trap center and the rigidly rotating normal (nonpaired) atoms located toward the trap edge, with a coexistence (partially paired) region in between. Furthermore, we show that the superfluid phase that occurs in the coexistence region is characterized by a gapless excitation spectrum, and that it is distinct from the gapped phase that occurs near the trap center. C1 [Iskin, M.] Natl Inst Stand & Technol, Joint Quantum Inst, Gaithersburg, MD 20899 USA. Univ Maryland, Gaithersburg, MD 20899 USA. RP Iskin, M (reprint author), Natl Inst Stand & Technol, Joint Quantum Inst, Gaithersburg, MD 20899 USA. NR 20 TC 9 Z9 9 U1 0 U2 3 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1050-2947 J9 PHYS REV A JI Phys. Rev. A PD MAY PY 2009 VL 79 IS 5 AR 053621 DI 10.1103/PhysRevA.79.053621 PG 5 WC Optics; Physics, Atomic, Molecular & Chemical SC Optics; Physics GA 451WF UT WOS:000266500900150 ER PT J AU Lisak, D Havey, DK Hodges, JT AF Lisak, D. Havey, D. K. Hodges, J. T. TI Spectroscopic line parameters of water vapor for rotation-vibration transitions near 7180 cm(-1) SO PHYSICAL REVIEW A LA English DT Article DE infrared spectra; measurement standards; rotational-vibrational states; spectral line intensity; spectral line narrowing; spectral line shift; water ID RING-DOWN SPECTROSCOPY; DEPENDENT COLLISIONAL WIDTH; TUNABLE DIODE-LASER; MU-M REGION; ABSORPTION-SPECTROSCOPY; COMBUSTION GASES; SPECTRAL-LINES; MULTISPECTRUM FITS; HIGH-TEMPERATURE; SPECIALTY GASES AB We present low uncertainty measurements of line parameters for 15 rotation-vibration transitions of water vapor in the wave number range of 7170.27-7183.02 cm(-1). These experiments incorporated frequency-stabilized cavity ring-down spectroscopy and a primary standard humidity generator which produced a stable and accurately known amount of water vapor in a nitrogen carrier gas stream. Intensities and line shape factors were derived by fitting high-resolution spectra to spectral models that account for collisional narrowing and speed-dependent broadening and shifting effects. For most transitions reported here, we estimate the relative combined standard uncertainty of the line intensities to be < 0.4%, of which approximately one half this value we ascribe to limited knowledge of the line shape. Our measured intensities and broadening parameters are compared to experimental and theoretical literature values. Agreement between our experimental intensity measurements and those derived by recent ab initio calculations of the dipole moment surface of water vapor is within 1.5%. C1 [Lisak, D.] Uniwersytet Mik Kopern, Inst Fizyki, PL-87100 Torun, Poland. [Havey, D. K.; Hodges, J. T.] NIST, Proc Measurements Div, Gaithersburg, MD 20899 USA. RP Lisak, D (reprint author), Uniwersytet Mik Kopern, Inst Fizyki, Ul Grudziadzka 5-7, PL-87100 Torun, Poland. RI Havey, Daniel/C-1997-2009; Hodges, Joseph/B-4578-2009; Lisak, Daniel/E-1470-2014 FU NIST Office of Microelectronics Program; Polish budget funds FX We thank Professor Jonathan Tennyson of University College London for kindly providing the ab initio intensity calculations, Gregory E. Scace of NIST for operation of the standard humidity generator, and David A. Long of the California Institute of Technology for helping construct the insulated enclosure for the ring-down cavity. The authors also acknowledge the NIST Office of Microelectronics Program for partial support of this research, as well as support by the Polish budget funds for scientific research projects in years 2008-2010. NR 63 TC 60 Z9 59 U1 4 U2 26 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1050-2947 J9 PHYS REV A JI Phys. Rev. A PD MAY PY 2009 VL 79 IS 5 AR 052507 DI 10.1103/PhysRevA.79.052507 PG 10 WC Optics; Physics, Atomic, Molecular & Chemical SC Optics; Physics GA 451WF UT WOS:000266500900087 ER PT J AU Mitra, K Williams, CJ de Melo, CARS AF Mitra, Kaushik Williams, C. J. de Melo, C. A. R. Sa TI Superfluid and Fermi-liquid phases of Bose-Fermi mixtures in optical lattices SO PHYSICAL REVIEW A LA English DT Article DE angular momentum; boson systems; Fermi liquid; localised states; optical lattices; superfluidity AB We describe interacting mixtures of ultracold bosonic and fermionic atoms in harmonically confined optical lattices. For a suitable choice of parameters we study the emergence of superfluid and Fermi-liquid (noninsulating) regions out of Bose-Mott and Fermi-band insulators due to finite boson and fermion hoppings. We obtain the shell structure for the system and show that angular momentum can be transferred to the noninsulating regions from Laguerre-Gaussian beams, which combined with Bragg spectroscopy can reveal all superfluid and Fermi-liquid shells. C1 [Mitra, Kaushik] Univ Maryland, Joint Quantum Inst, College Pk, MD 20742 USA. NIST, Gaithersburg, MD 20899 USA. RP Mitra, K (reprint author), Univ Maryland, Joint Quantum Inst, College Pk, MD 20742 USA. RI Williams, Carl/B-5877-2009 NR 10 TC 0 Z9 0 U1 0 U2 0 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1050-2947 J9 PHYS REV A JI Phys. Rev. A PD MAY PY 2009 VL 79 IS 5 AR 055601 DI 10.1103/PhysRevA.79.055601 PG 4 WC Optics; Physics, Atomic, Molecular & Chemical SC Optics; Physics GA 451WF UT WOS:000266500900246 ER PT J AU Pushin, DA Arif, M Cory, DG AF Pushin, D. A. Arif, M. Cory, D. G. TI Decoherence-free neutron interferometry SO PHYSICAL REVIEW A LA English DT Article DE particle interferometry; vibration isolation ID QUANTUM COMPUTATION; MOVING LATTICES; SYSTEMS AB Perfect single-crystal neutron interferometers are adversely sensitive to environmental disturbances, particularly mechanical vibrations. The sensitivity to vibrations results from the slow velocity of thermal neutrons and the long measurement time that are encountered in a typical experiment. Consequently, to achieve a good interference solutions for reducing vibration other than those normally used in optical experiments must be explored. Here we introduce a geometry for a neutron interferometer that is less sensitive to low-frequency vibrations. This design may be compared with both dynamical decoupling methods and decoherence-free subspaces that are described in quantum information processing. By removing the need for bulky vibration isolation setups, this design will make it easier to adopt neutron interferometry to a wide range of applications and increase its sensitivity. C1 [Pushin, D. A.; Cory, D. G.] MIT, Cambridge, MA 02139 USA. [Arif, M.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Pushin, DA (reprint author), MIT, 77 Massachusetts Ave, Cambridge, MA 02139 USA. EM mitja@mit.edu OI Pushin, Dmitry/0000-0002-4594-3403 FU NIST FX Support provided by NIST is gratefully acknowledged. The authors are grateful for discussions with D. L. Jacobson, R. Laflamme, B. Levi, and C. Ramanathan. Discussion with S. A. Werner about an earlier idea of a four-blade interferometer for use in gravity and spin-rotation [7] experiments is gratefully appreciated. NR 15 TC 10 Z9 10 U1 0 U2 1 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1050-2947 J9 PHYS REV A JI Phys. Rev. A PD MAY PY 2009 VL 79 IS 5 AR 053635 DI 10.1103/PhysRevA.79.053635 PG 6 WC Optics; Physics, Atomic, Molecular & Chemical SC Optics; Physics GA 451WF UT WOS:000266500900164 ER PT J AU Stanescu, TD Galitski, V Vaishnav, JY Clark, CW Das Sarma, S AF Stanescu, Tudor D. Galitski, Victor Vaishnav, J. Y. Clark, Charles W. Das Sarma, S. TI Topological insulators and metals in atomic optical lattices SO PHYSICAL REVIEW A LA English DT Article DE boson systems; optical lattices; topology ID HALL; STATE AB We propose the realization of topological quantum states in a cold-atom system, using a two-dimensional hexagonal optical lattice and a light-induced periodic vector potential. A necessary condition for observing the topological states is the realization of a confining potential with a flat bottom and sharp boundaries. To probe the topological states, we propose to load bosons into the characteristic edge states and image them directly. The possibility of mapping out the edge states and controlling the optical lattice and vector potentials offers opportunities for exploring topological phases with no equivalent in condensed-matter systems. C1 [Stanescu, Tudor D.; Galitski, Victor; Das Sarma, S.] Univ Maryland, Dept Phys, Joint Quantum Inst, College Pk, MD 20742 USA. [Stanescu, Tudor D.; Galitski, Victor; Das Sarma, S.] Univ Maryland, Condensed Matter Theory Ctr, College Pk, MD 20742 USA. [Vaishnav, J. Y.; Clark, Charles W.] Natl Inst Stand & Technol, Joint Quantum Inst, Gaithersburg, MD 20899 USA. RP Stanescu, TD (reprint author), Univ Maryland, Dept Phys, Joint Quantum Inst, College Pk, MD 20742 USA. RI Clark, Charles/A-8594-2009; Das Sarma, Sankar/B-2400-2009 OI Clark, Charles/0000-0001-8724-9885; Das Sarma, Sankar/0000-0002-0439-986X FU NSF FX This work is supported by NSF through JQI-PFC, DARPA, and USARO. NR 28 TC 70 Z9 70 U1 0 U2 7 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1050-2947 J9 PHYS REV A JI Phys. Rev. A PD MAY PY 2009 VL 79 IS 5 AR 053639 DI 10.1103/PhysRevA.79.053639 PG 5 WC Optics; Physics, Atomic, Molecular & Chemical SC Optics; Physics GA 451WF UT WOS:000266500900168 ER PT J AU Li, JY Jensen, TBS Andersen, NH Zarestky, JL McCallum, RW Chung, JH Lynn, JW Vaknin, D AF Li, Jiying Jensen, Thomas B. S. Andersen, Niels H. Zarestky, Jerel L. McCallum, R. William Chung, Jae-Ho Lynn, Jeffrey W. Vaknin, David TI Tweaking the spin-wave dispersion and suppressing the incommensurate phase in LiNiPO4 by iron substitution SO PHYSICAL REVIEW B LA English DT Article DE commensurate-incommensurate transformations; energy gap; exchange interactions (electron); frustration; Heisenberg model; iron compounds; lithium compounds; magnetic structure; magnetic transitions; neutron diffraction; nickel compounds; spin Hamiltonians; spin waves ID INELASTIC NEUTRON-SCATTERING; WEAK FERROMAGNETISM; MAGNETIC-PROPERTIES; ANTIFERROMAGNETISM; TRANSFORMATION; ANISOTROPY AB Elastic and inelastic neutron-scattering studies of Li(Ni1-xFex)PO4 single crystals reveal anomalous spin-wave dispersions along the crystallographic direction parallel to the characteristic wave vector of the magnetic incommensurate phase. The anomalous spin-wave dispersion (magnetic soft mode) indicates the instability of the Ising-type ground state that eventually evolves into the incommensurate phase as the temperature is raised. The pure LiNiPO4 system (x=0) undergoes a first-order magnetic phase transition from a long-range incommensurate phase to an antiferromagnetic (AFM) ground state at T-N=20.8 K. At 20% Fe concentrations, although the AFM ground state is to a large extent preserved as that of the pure system, the phase transition is second order, and the incommensurate phase is completely suppressed. Analysis of the dispersion curves using a Heisenberg spin Hamiltonian that includes interplane and in-plane nearest- and next-nearest-neighbor couplings reveals frustration due to strong competing interactions between nearest- and next-nearest-neighbor sites, consistent with the observed incommensurate structure. The Fe substitution only slightly lowers the extent of the frustration, sufficient to suppress the incommensurate phase. An energy gap in the dispersion curves gradually decreases with the increase in Fe content from similar to 2 meV for the pure system (x=0) to similar to 0.9 meV for x=0.2. C1 [Li, Jiying; Zarestky, Jerel L.; McCallum, R. William; Vaknin, David] Iowa State Univ, Ames Lab, Ames, IA 50011 USA. [Li, Jiying; Zarestky, Jerel L.; Vaknin, David] Iowa State Univ, Dept Phys & Astron, Ames, IA 50011 USA. [Li, Jiying; Lynn, Jeffrey W.] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Li, Jiying] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. [Jensen, Thomas B. S.; Andersen, Niels H.] Tech Univ Denmark, Mat Res Div, Riso DTU, DK-4000 Roskilde, Denmark. [McCallum, R. William] Iowa State Univ, Dept Mat Sci & Engn, Ames, IA 50011 USA. [Chung, Jae-Ho] Korea Univ, Dept Phys, Seoul 136713, South Korea. RP Vaknin, D (reprint author), Iowa State Univ, Ames Lab, Ames, IA 50011 USA. EM vaknin@ameslab.gov RI Andersen, Niels/A-3872-2012; Vaknin, David/B-3302-2009 OI Vaknin, David/0000-0002-0899-9248 NR 37 TC 9 Z9 9 U1 0 U2 11 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1098-0121 J9 PHYS REV B JI Phys. Rev. B PD MAY PY 2009 VL 79 IS 17 AR 174435 DI 10.1103/PhysRevB.79.174435 PG 7 WC Physics, Condensed Matter SC Physics GA 451WH UT WOS:000266501100088 ER PT J AU Li, SL Chen, Y Chang, S Lynn, JW Li, LJ Luo, YK Cao, GH Xu, ZA Dai, PC AF Li, Shiliang Chen, Ying Chang, Sung Lynn, Jeffrey W. Li, Linjun Luo, Yongkang Cao, Guanghan Xu, Zhu'an Dai, Pengcheng TI Spin gap and magnetic resonance in superconducting BaFe1.9Ni0.1As2 SO PHYSICAL REVIEW B LA English DT Article DE antiferrimagnetism; arsenic alloys; barium alloys; iron alloys; magnetic resonance; neutron spectra; nickel alloys; photoemission; superconducting energy gap; superconducting materials ID IRON-BASED SUPERCONDUCTORS; TEMPERATURE SUPERCONDUCTOR; NEUTRON-SCATTERING; BA0.6K0.4FE2AS2; EXCITATIONS; SPECTRA AB We use neutron spectroscopy to determine the nature of the magnetic excitations in superconducting BaFe1.9Ni0.1As2(T-c=20 K). Above T-c the excitations are gapless and centered at the commensurate antiferromagnetic wave vector of the parent compound, while the intensity exhibits a sinusoidal modulation along the c axis. As the superconducting state is entered a spin gap gradually opens, whose magnitude tracks the T dependence of the superconducting gap as observed by angle-resolved photoemission. Both the spin-gap and magnetic-resonance energies are temperature and wave-vector dependent, but their ratio is the same within uncertainties. These results suggest that the spin resonance is a singlet-triplet excitation related to electron pairing and superconductivity. C1 [Li, Shiliang; Dai, Pengcheng] Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA. [Chen, Ying; Chang, Sung; Lynn, Jeffrey W.] Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Li, Linjun; Luo, Yongkang; Cao, Guanghan; Xu, Zhu'an] Zhejiang Univ, Dept Phys, Hangzhou 310027, Peoples R China. [Dai, Pengcheng] Oak Ridge Natl Lab, Neutron Scattering Sci Div, Oak Ridge, TN 37831 USA. RP Li, SL (reprint author), Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA. EM daip@ornl.gov RI Li, Shiliang/B-9379-2009; Cao, Guanghan/C-4753-2008; Dai, Pengcheng /C-9171-2012 OI Dai, Pengcheng /0000-0002-6088-3170 FU U.S. DOE BES [DE-FG02-05ER46202]; NSF [DMR-0756568, DMR-0454672] FX We thank Songxue Chi, Jun Zhao, and Leland Harriger for coaligning some of the single crystals used in the present experiment. This work is supported by the U.S. DOE BES under Grant No. DE-FG02-05ER46202, NSF under Grant No. DMR-0756568, and in part by the U. S. DOE, Division of Scientific User Facilities. The work at Zhejiang University is supported by the NSF of China. This work utilized facilities supported in part by the National Science Foundation under Agreement No. DMR-0454672. NR 35 TC 56 Z9 56 U1 0 U2 5 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1098-0121 J9 PHYS REV B JI Phys. Rev. B PD MAY PY 2009 VL 79 IS 17 AR 174527 DI 10.1103/PhysRevB.79.174527 PG 5 WC Physics, Condensed Matter SC Physics GA 451WH UT WOS:000266501100117 ER PT J AU Magyar, RJ AF Magyar, R. J. TI Ground and excited-state fermions in a one-dimensional double-well: Exact and density-functional solutions SO PHYSICAL REVIEW B LA English DT Article DE density functional theory; eigenvalues and eigenfunctions; excited states; fermions; ground states; Hubbard model; hydrogen neutral molecules; one-dimensional conductivity ID ELECTRON-GAS; SYSTEMS; MODEL AB Two of the most popular quantum-mechanical models of interacting fermions are compared to each other and to potentially exact solutions for a pair of contact-interacting fermions trapped in a one-dimensional (1D) double-well potential, a model of atoms in a quasi-1D optical lattice, or electrons of a hydrogen molecule in a strong magnetic field. An exact few-body Hamiltonian is solved numerically in momentum space yielding a highly correlated eigenspectrum. Additionally, approximate ground-state energies are obtained using both density-functional theory (DFT) functional and two-site Hubbard models. A 1D adiabatic local-density approximation kernel is constructed for use in time-dependent density-functional theory (TDDFT) and the resulting excited-state spectrum is compared to the exact and Hubbard results. DFT is shown to give accurate results for wells with small separations but fails to describe localization of opposite spin fermions to different sites. A locally cognizant density functional based on an effective local fermion number would provide a solution to this problem, and an approximate treatment presented here compares favorably to the exact and Hubbard results. The TDDFT excited-state spectrum is accurate in the small parameter regime with nonadiabatic effects accounting for any deviations. As expected, the ground-state Hubbard model outperforms DFT at large separations but breaks down at intermediate separations due to improper scaling to the united-atom limit. At strong coupling, both Hubbard and TDDFT methods fail to capture the appropriate energetics. C1 [Magyar, R. J.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Magyar, RJ (reprint author), Sandia Natl Labs, POB 5800, Albuquerque, NM 87185 USA. NR 27 TC 9 Z9 9 U1 1 U2 8 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1098-0121 EI 1550-235X J9 PHYS REV B JI Phys. Rev. B PD MAY PY 2009 VL 79 IS 19 AR 195127 DI 10.1103/PhysRevB.79.195127 PG 14 WC Physics, Condensed Matter SC Physics GA 451WJ UT WOS:000266501300056 ER PT J AU McQueen, TM Klimczuk, T Williams, AJ Huang, Q Cava, RJ AF McQueen, T. M. Klimczuk, T. Williams, A. J. Huang, Q. Cava, R. J. TI Stoichiometry, spin fluctuations, and superconductivity in LaNiPO SO PHYSICAL REVIEW B LA English DT Article DE band structure; fluctuations in superconductors; lanthanum compounds; nickel compounds; specific heat; spin fluctuations; stoichiometry ID LAYERED QUATERNARY COMPOUND; CRYSTAL-STRUCTURE; MAGNETIC-PROPERTIES; PHASE-DIAGRAM; HEAT AB Superconductivity in LaNiPO is disrupted by small (similar to 5%) amounts of nonstoichiometry on the lanthanum site, even though the electronic contribution to the heat capacity increases with increasing nonstoichiometry. All samples also exhibit specific-heat anomalies consistent with the presence of ferromagnetic spin fluctuations (T(sf)approximate to 14 K). Comparison of layered nickel phosphide and nickel borocarbide superconductors reveals different structure-property correlations in the two families. C1 [McQueen, T. M.; Williams, A. J.; Cava, R. J.] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA. [Klimczuk, T.] Los Alamos Natl Lab, Los Alamos, NM 87545 USA. [Klimczuk, T.] Gdansk Univ Technol, Fac Appl Phys & Math, PL-80952 Gdansk, Poland. [Huang, Q.] Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. RP McQueen, TM (reprint author), Princeton Univ, Dept Chem, Princeton, NJ 08544 USA. RI Klimczuk, Tomasz/M-1716-2013 OI Klimczuk, Tomasz/0000-0003-2602-5049 FU National Science Foundation Graduate Research Program; Department of Energy, Division of Basic Energy Sciences [DE-FG02-98ER45706] FX T. M. M. gratefully acknowledges support of the National Science Foundation Graduate Research Program. The work at Princeton was supported by the Department of Energy, Division of Basic Energy Sciences, under Grant No. DE-FG02-98ER45706. NR 34 TC 10 Z9 10 U1 2 U2 19 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1098-0121 J9 PHYS REV B JI Phys. Rev. B PD MAY PY 2009 VL 79 IS 17 AR 172502 DI 10.1103/PhysRevB.79.172502 PG 4 WC Physics, Condensed Matter SC Physics GA 451WH UT WOS:000266501100020 ER PT J AU Moore, RG Lumsden, MD Stone, MB Zhang, JD Chen, Y Lynn, JW Jin, R Mandrus, D Plummer, EW AF Moore, R. G. Lumsden, M. D. Stone, M. B. Zhang, Jiandi Chen, Y. Lynn, J. W. Jin, R. Mandrus, D. Plummer, E. W. TI Phonon softening and anomalous mode near the x(c)=0.5 quantum critical point in Ca2-xSrxRuO4 SO PHYSICAL REVIEW B LA English DT Article DE calcium compounds; critical points; doping; phonon dispersion relations; soft modes; solid-state phase transformations; strontium compounds ID STRUCTURAL PHASE-TRANSITIONS; MOTT TRANSITION; SOFT-PHONON; LA2CUO4; SUPERCONDUCTIVITY; CA2-XSR(X)RUO4; SR2IRO4 AB Inelastic neutron scattering is used to measure the temperature-dependent phonon dispersion in Ca2-xSrxRuO4 (x=0.4,0.6). The in-plane Sigma(4) octahedral tilt mode softens significantly at the zone boundary of the high-temperature tetragonal (HTT) I4(1)/acd structure as the temperature approaches the transition to a low-temperature orthorhombic (LTO) Pbca phase. This behavior is similar to that in La2CuO4, but an inelastic feature that is not found in the cuprate is present. An anomalous phonon mode is observed at energy transfers greater than the Sigma(4), albeit with similar dispersion. This anomalous phonon mode never softens below similar to 5 meV, even for temperatures below the HTT-LTO transition. This mode is attributed to the presence of intrinsic structural disorder within the I4(1)/acd tetragonal structure of the doped ruthenate. C1 [Lumsden, M. D.; Stone, M. B.] Oak Ridge Natl Lab, Neutron Scattering Sci Div, Oak Ridge, TN 37831 USA. [Zhang, Jiandi] Florida Int Univ, Dept Phys, Miami, FL 33199 USA. [Chen, Y.; Lynn, J. W.] Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Jin, R.; Mandrus, D.] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA. [Moore, R. G.; Jin, R.; Mandrus, D.; Plummer, E. W.] Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA. RP Moore, RG (reprint author), SLAC Natl Accelerator Lab, Stanford Synchrotron Radiat Lightsource, Menlo Pk, CA 94025 USA. RI Stone, Matthew/G-3275-2011; Mandrus, David/H-3090-2014; Lumsden, Mark/F-5366-2012 OI Stone, Matthew/0000-0001-7884-9715; Lumsden, Mark/0000-0002-5472-9660 FU NSF [DMR-0346826, DMR-0353108, DMR-0451163]; DOE [DE-FG02-04ER46125]; DOE DMS; ORAU faculty summer research program; Scientific User Facilities Division, Office of Basic Energy Sciences, DOE; Division of Materials Sciences and Engineering, Office of Basic Energy Sciences, DOE [DE-AC05-00OR22725] FX We thank I. A. Sergienko for helpful discussions. This work was supported by NSF Grants No. DMR-0346826, No. DMR-0353108, and No. DMR-0451163; DOE Grant No. DE-FG02-04ER46125; DOE DMS; and ORAU faculty summer research program. A portion of this research at Oak Ridge National Laboratory's High Flux Isotope Reactor was sponsored by the Scientific User Facilities Division, Office of Basic Energy Sciences, DOE. The work at Oak Ridge National Laboratory was supported through the Division of Materials Sciences and Engineering, Office of Basic Energy Sciences, DOE, under Contract No. DE-AC05-00OR22725. NR 25 TC 0 Z9 0 U1 3 U2 17 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1098-0121 J9 PHYS REV B JI Phys. Rev. B PD MAY PY 2009 VL 79 IS 17 AR 172301 DI 10.1103/PhysRevB.79.172301 PG 4 WC Physics, Condensed Matter SC Physics GA 451WH UT WOS:000266501100005 ER PT J AU Shaw, JM Silva, TJ Schneider, ML McMichael, RD AF Shaw, Justin M. Silva, T. J. Schneider, Michael L. McMichael, Robert D. TI Spin dynamics and mode structure in nanomagnet arrays: Effects of size and thickness on linewidth and damping SO PHYSICAL REVIEW B LA English DT Article DE damping; iron alloys; Kerr magneto-optical effect; magnetic particles; nanomagnetics; nanopatterning; nanostructured materials; nickel alloys; spin dynamics ID MAGNETIZATION; DRIVEN; FILMS AB We use frequency resolved magneto-optic Kerr effect to probe the spin dynamics and mode structure in 50-200-nm-diameter Ni(80)Fe(20) nanomagnets ranging from 3 to 10 nm in thickness. We find that the intrinsic Gilbert damping parameter is largely unaffected by the nanopatterning process despite a large linewidth dependence on the size of the nanomagnets. In the larger nanomagnets, both end and center modes are observed. The linewidth of these two modes differ considerably, which is most likely the result of the sensitivity of the end mode to small variations and imperfection of the shape and edge materials. We show that this effect can be exploited as a means to separately characterize the magnetic properties of the nanomagnets as well as the size and shape variations within the array. C1 [Shaw, Justin M.; Silva, T. J.] Natl Inst Stand & Technol, Electromagnet Div, Boulder, CO 80305 USA. [Schneider, Michael L.] Univ Montana, Dept Phys & Astron, Missoula, MT 59812 USA. [McMichael, Robert D.] Natl Inst Stand & Technol, Ctr Nanoscale Sci & Technol, Gaithersburg, MD 20899 USA. RP Shaw, JM (reprint author), Natl Inst Stand & Technol, Electromagnet Div, Boulder, CO 80305 USA. RI Shaw, Justin/C-1845-2008; McMichael, Robert/J-8688-2012; Silva, Thomas/C-7605-2013; OI Shaw, Justin/0000-0003-2027-1521; Silva, Thomas/0000-0001-8164-9642; McMichael, Robert/0000-0002-1372-664X NR 47 TC 58 Z9 58 U1 1 U2 30 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1098-0121 J9 PHYS REV B JI Phys. Rev. B PD MAY PY 2009 VL 79 IS 18 AR 184404 DI 10.1103/PhysRevB.79.184404 PG 10 WC Physics, Condensed Matter SC Physics GA 451WI UT WOS:000266501200057 ER PT J AU Stock, C Buyers, WJL Rule, KC Chung, JH Liang, R Bonn, D Hardy, WN AF Stock, C. Buyers, W. J. L. Rule, K. C. Chung, J. -H. Liang, R. Bonn, D. Hardy, W. N. TI Magnetic field resonantly enhanced free spins in heavily underdoped YBa2Cu3O6+x SO PHYSICAL REVIEW B LA English DT Article DE barium compounds; fluctuations in superconductors; high-temperature superconductors; mixed state; monolayers; neutron diffraction; spin fluctuations; yttrium compounds; Zeeman effect ID HIGH-TEMPERATURE SUPERCONDUCTOR; PHASE-TRANSITIONS; ANISOTROPY; ORDER; YBA2CU3O7-DELTA; CRYSTAL AB Using neutron scattering, we investigate the effect of a magnetic field on the static and dynamic spin response in heavily underdoped superconducting YBa2Cu3O6+x (YBCO6+x) with x=0.33 (T-c=8 K) and 0.35 (T-c=18 K). In contrast to the heavily doped and superconducting monolayer cuprates, the elastic central peak characterizing static spin correlations does not respond observably to a magnetic field which suppresses superconductivity. Instead, we find a magnetic-field-induced resonant enhancement of the spin fluctuations. The energy scale of the enhanced fluctuations matches the Zeeman energy within both the normal and vortex phases, while the momentum dependence is the same as the zero-field bilayer response. The magnitude of the enhancement is very similar in both phases with a fractional intensity change of (I/I-0-1)similar to 0.1. We suggest that the enhancement is not directly correlated with superconductivity but is the result of almost free spins located near hole-rich regions. C1 [Stock, C.] Rutherford Appleton Labs, ISIS Facil, Didcot OX11 0QX, Oxon, England. [Buyers, W. J. L.] CNR, Chalk River, ON K0J 1J0, Canada. [Buyers, W. J. L.; Liang, R.; Bonn, D.; Hardy, W. N.] Canadian Inst Adv Res, Toronto, ON M5G 1Z8, Canada. [Rule, K. C.] Helmholtz Zentrum Berlin, D-14109 Berlin, Germany. [Chung, J. -H.] NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Chung, J. -H.] Korea Univ, Dept Phys, Seoul 136701, South Korea. [Liang, R.; Bonn, D.; Hardy, W. N.] Univ British Columbia, Dept Phys, Vancouver, BC V6T 2E7, Canada. RP Stock, C (reprint author), Rutherford Appleton Labs, ISIS Facil, Didcot OX11 0QX, Oxon, England. FU Natural Science and Engineering Research Council (NSERC) of Canada; U.S. National Science Foundation [DMR-0306940, DMR-0454672] FX We thank R. A. Cowley, R. J. Birgeneau, C. Broholm, G. Xu, Z. Yamani, S. Dunsiger, and J. Tranquada for helpful discussions. We acknowledge financial support from the Natural Science and Engineering Research Council (NSERC) of Canada and the U.S. National Science Foundation through Grant No. DMR-0306940. This work utilized facilities supported in part by the National Science Foundation under Agreement No. DMR-0454672. NR 57 TC 9 Z9 9 U1 0 U2 1 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1098-0121 J9 PHYS REV B JI Phys. Rev. B PD MAY PY 2009 VL 79 IS 18 AR 184514 DI 10.1103/PhysRevB.79.184514 PG 8 WC Physics, Condensed Matter SC Physics GA 451WI UT WOS:000266501200099 ER PT J AU Mamontov, E Vlcek, L Wesolowski, DJ Cummings, PT Rosenqvist, J Wang, W Cole, DR Anovitz, LM Gasparovic, G AF Mamontov, Eugene Vlcek, Lukas Wesolowski, David J. Cummings, Peter T. Rosenqvist, Joergen Wang, Wei Cole, David R. Anovitz, Lawrence M. Gasparovic, Goran TI Suppression of the dynamic transition in surface water at low hydration levels: A study of water on rutile SO PHYSICAL REVIEW E LA English DT Article DE molecular dynamics method; solvation; surface waves (fluid); titanium compounds; water ID BACKSCATTERING NEUTRON SPECTROSCOPY; MOLECULAR-DYNAMICS; PROTEIN HYDRATION; CONFINED WATER; DIELECTRIC-RELAXATION; SILICA MATRICES; SCATTERING; CROSSOVER; LYSOZYME; SYSTEMS AB Our quasielastic neutron-scattering experiments and molecular-dynamics simulations probing surface water on rutile (TiO2) have demonstrated that a sufficiently high hydration level is a prerequisite for the temperature-dependent crossover in the nanosecond dynamics of hydration water. Below the monolayer coverage of mobile surface water, a weak temperature dependence of the relaxation times with no apparent crossover is observed. We associate the dynamic crossover with interlayer jumps of the mobile water molecules, which become possible only at a sufficiently high hydration level. C1 [Mamontov, Eugene] Oak Ridge Natl Lab, Neutron Scattering Sci Div, Oak Ridge, TN 37831 USA. [Vlcek, Lukas; Cummings, Peter T.] Vanderbilt Univ, Dept Chem Engn, Nashville, TN 37235 USA. [Wesolowski, David J.; Rosenqvist, Joergen; Cole, David R.; Anovitz, Lawrence M.] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA. [Cummings, Peter T.] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA. [Wang, Wei] Oak Ridge Natl Lab, Div Environm Sci, Oak Ridge, TN 37831 USA. [Gasparovic, Goran] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Gasparovic, Goran] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. RP Mamontov, E (reprint author), Oak Ridge Natl Lab, Neutron Scattering Sci Div, Oak Ridge, TN 37831 USA. RI Wang, Wei/B-5924-2012; Cummings, Peter/B-8762-2013; Vlcek, Lukas/N-7090-2013; Mamontov, Eugene/Q-1003-2015; Anovitz, Lawrence/P-3144-2016 OI Cummings, Peter/0000-0002-9766-2216; Vlcek, Lukas/0000-0003-4782-7702; Mamontov, Eugene/0000-0002-5684-2675; Anovitz, Lawrence/0000-0002-2609-8750 FU U. S. DOE, BES, Division of Chemical Sciences, Geosciences, and Biosciences [ERKCC41]; Oak Ridge National Laboratory; U. S. DOE [DE-AC05-00OR22725] FX The authors are thankful to K. W. Herwig and M. Zamponi for critical reading of the paper. We used the resource of the Computing Center for Research and Education at Vanderbilt University and the Institutional Computational Cluster at ORNL's Chemical Sciences Division. This work was supported by the U. S. DOE, BES, Division of Chemical Sciences, Geosciences, and Biosciences through the project "Nanoscale Complexity at the Oxide/Water Interface" (Project No. ERKCC41) and by Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U. S. DOE under Contract No. DE-AC05-00OR22725. NR 48 TC 39 Z9 39 U1 4 U2 20 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 1539-3755 EI 1550-2376 J9 PHYS REV E JI Phys. Rev. E PD MAY PY 2009 VL 79 IS 5 AR 051504 DI 10.1103/PhysRevE.79.051504 PN 1 PG 6 WC Physics, Fluids & Plasmas; Physics, Mathematical SC Physics GA 451WD UT WOS:000266500700064 PM 19518459 ER PT J AU Clade, P Ryu, C Ramanathan, A Helmerson, K Phillips, WD AF Clade, P. Ryu, C. Ramanathan, A. Helmerson, K. Phillips, W. D. TI Observation of a 2D Bose Gas: From Thermal to Quasicondensate to Superfluid SO PHYSICAL REVIEW LETTERS LA English DT Article ID 2-DIMENSIONAL SYSTEMS; EINSTEIN CONDENSATION; TRAPPED GASES; TRANSITION AB We present experimental results on a Bose gas in a quasi-2D geometry near the Berezinskii, Kosterlitz, and Thouless (BKT) transition temperature. By measuring the density profile after time of flight and the coherence length, we identify different states of the gas. We observe that the gas develops a bimodal distribution without long range order. In this regime, the gas presents a longer coherence length than the thermal cloud; it is quasicondensed but is not superfluid. Experimental evidence indicates that we also observe the superfluid transition (BKT transition). For a sufficiently long time of flight, we observe a trimodal distribution when the gas has developed a superfluid component. C1 [Clade, P.] Natl Inst Stand & Technol, Atom Phys Div, Gaithersburg, MD 20899 USA. [Clade, P.] UPMC, CNRS, ENS, Lab Kastler Brossel, Paris, France. Univ Maryland, College Pk, MD 20742 USA. NIST, Joint Quantum Inst, College Pk, MD 20742 USA. RP Clade, P (reprint author), Natl Inst Stand & Technol, Atom Phys Div, Gaithersburg, MD 20899 USA. RI Helmerson, Kristian/E-3683-2013; OI Ramanathan, Anand/0000-0002-1865-0904 NR 25 TC 125 Z9 127 U1 1 U2 11 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 0031-9007 J9 PHYS REV LETT JI Phys. Rev. Lett. PD MAY 1 PY 2009 VL 102 IS 17 AR 170401 DI 10.1103/PhysRevLett.102.170401 PG 4 WC Physics, Multidisciplinary SC Physics GA 443ZC UT WOS:000265948300001 PM 19518764 ER PT J AU Rea, LD Berman-Kowalewski, M Rosen, DAS Trites, AW AF Rea, Lorrie D. Berman-Kowalewski, Michelle Rosen, David A. S. Trites, Andrew W. TI Seasonal Differences in Biochemical Adaptation to Fasting in Juvenile and Subadult Steller Sea Lions (Eumetopias jubatus) SO PHYSIOLOGICAL AND BIOCHEMICAL ZOOLOGY LA English DT Article ID NORTHERN ELEPHANT SEAL; POSTWEANING FAST; BLOOD-CHEMISTRY; MIROUNGA-ANGUSTIROSTRIS; ATTENDANCE PATTERNS; PROTEIN-UTILIZATION; EMPEROR PENGUINS; BODY-COMPOSITION; FUR SEALS; PUPS AB Nine Steller sea lions (Eumetopias jubatus) aged 1.75-6 yr were experimentally fasted for 7-14 d during the breeding and non-breeding seasons to identify changes in plasma metabolites that are indicative of fasting and to determine whether the ability of sea lions to fast varies seasonally or with age. Although some animals approached the limit of their protein-sparing ability by the end of our fasting experiments, there was no sign of irreversible starvation biochemistry. Plasma blood urea nitrogen (BUN) concentrations decreased in all animals within the first week of fasting, reflecting a shift to a fasting-adapted state; however, significant increases in plasma BUN concentration at the end of the nonbreeding season fasts suggest that subadult Steller sea lions were not able to maintain a protein-sparing metabolism for a full 14 d during the nonbreeding season. In contrast, juveniles were able to enter protein sparing sooner during the nonbreeding season when they had slightly higher initial percent total body lipid stores than during the breeding season. Subadult and juvenile sea lions had low circulating ketone body concentrations compared with young sea lion pups, suggesting an age-related difference in how body reserves are utilized during fasting or how the resulting metabolites are circulated and catabolized. Our data suggest that metabolite concentrations from a single blood sample cannot be used to accurately predict the duration of fast; however, threshold metabolite concentrations may still be useful for assessing whether periods of fasting in the wild are unusually long compared with those normally experienced. C1 [Rea, Lorrie D.] NOAA, Natl Marine Mammal Lab, Natl Marine Fisheries Serv, Seattle, WA 98115 USA. [Rea, Lorrie D.] Univ Alaska, Alaska Dept Fish & Game, Fairbanks, AK 99775 USA. [Rea, Lorrie D.; Berman-Kowalewski, Michelle] Univ Cent Florida, Dept Biol, Orlando, FL 32816 USA. [Rosen, David A. S.; Trites, Andrew W.] Univ British Columbia, Aquat Ecosyst Res Lab, Fisheries Ctr, Marine Mammal Res Unit, Vancouver, BC V6T 1Z4, Canada. RP Rea, LD (reprint author), NOAA, Natl Marine Mammal Lab, Natl Marine Fisheries Serv, Seattle, WA 98115 USA. EM lorrie.rea@alaska.gov RI Trites, Andrew/K-5648-2012 FU National Fish and Wildlife Foundation [98-244-008]; National Oceanic and Atmospheric Administration; North Pacific Marine Science Foundation to the North Pacific Universities Marine Mammal Research Consortium FX This study was authorized under the Marine Mammal Protection Act Permit (881-1443) held by the Alaska SeaLife Center (ASLC) and by Institutional Animal Care and Use Committee Protocols approved by the University of British Columbia (UBC), the ASLC (98-007), and the University of Central Florida (9807). This research was funded by the National Marine Mammal Laboratory Steller sea lion research program, through a grant to L. D. R. from the National Fish and Wildlife Foundation (98-244-008), and through grants from the National Oceanic and Atmospheric Administration and the North Pacific Marine Science Foundation to the North Pacific Universities Marine Mammal Research Consortium to support the UBC Steller sea lion program. We wish to thank D. Christen, C. Porter, T. Shannon, and G. Shephard, whose training skills and inventiveness made our study possible, as well as the staff at both the Vancouver Aquarium and the ASLC for their assistance with our study. We are also grateful to the late P. Hochachka for access to his analytical laboratory at UBC and wish to acknowledge the tireless laboratory assistance of M. Citron, T. Haase, K. Kimble, J. Richmond, and J. Smith. This manuscript was improved through the comments of two anonymous reviewers, and special thanks are extended NR 50 TC 7 Z9 7 U1 0 U2 7 PU UNIV CHICAGO PRESS PI CHICAGO PA 1427 E 60TH ST, CHICAGO, IL 60637-2954 USA SN 1522-2152 J9 PHYSIOL BIOCHEM ZOOL JI Physiol. Biochem. Zool. PD MAY-JUN PY 2009 VL 82 IS 3 BP 236 EP 247 DI 10.1086/597528 PG 12 WC Physiology; Zoology SC Physiology; Zoology GA 431DZ UT WOS:000265042800004 PM 19323643 ER PT J AU Galli, GLJ Shiels, HA Brill, RW AF Galli, Gina L. J. Shiels, Holly A. Brill, Richard W. TI Temperature Sensitivity of Cardiac Function in Pelagic Fishes with Different Vertical Mobilities: Yellowfin Tuna (Thunnus albacares), Bigeye Tuna (Thunnus obesus), Mahimahi (Coryphaena hippurus), and Swordfish (Xiphias gladius) SO PHYSIOLOGICAL AND BIOCHEMICAL ZOOLOGY LA English DT Article ID TROUT ONCORHYNCHUS-MYKISS; ISOLATED VENTRICULAR TRABECULAE; FORCE FREQUENCY RELATIONSHIPS; ATLANTIC BLUEFIN TUNA; SARCOPLASMIC-RETICULUM; RAINBOW-TROUT; ADRENERGIC-STIMULATION; THERMAL-ACCLIMATION; CALCIUM CHANNELS; HAWAIIAN-ISLANDS AB We measured the temperature sensitivity, adrenergic sensitivity, and dependence on sarcoplasmic reticulum (SR) Ca(2+) of ventricular muscle from pelagic fishes with different vertical mobility patterns: bigeye tuna (Thunnus obesus), yellowfin tuna (Thunnus albacares), and mahimahi (Coryphaena hippurus) and a single specimen from swordfish (Xiphias gladius). Ventricular muscle from the bigeye tuna and mahimahi exhibited a biphasic response to an acute decrease in temperature (from 26 degrees to 7 degrees C); twitch force and kinetic parameters initially increased and then declined. The magnitude of this response was larger in the bigeye tuna than in the mahimahi. Under steady state conditions at 26 degrees C, inhibition of SR Ca(2+) release and reuptake with ryanodine and thapsigargin decreased twitch force and kinetic parameters, respectively, in the bigeye tuna only. However, the initial inotropy associated with decreasing temperature was abolished by SR inhibition in both the bigeye tuna and the mahimahi. Application of adrenaline completely reversed the effects of ryanodine and thapsigargin, but this effect was diminished at cold temperatures. In the yellowfin tuna, temperature and SR inhibition had minor effects on twitch force and kinetics, while adrenaline significantly increased these parameters. Limited data suggest that swordfish ventricular muscle responds to acute temperature reduction, SR inhibition, and adrenergic stimulation in a manner similar to that of bigeye tuna ventricular muscle. In aggregate, our results show that the temperature sensitivity, SR dependence, and adrenergic sensitivity of pelagic fish hearts are species specific and that these differences reflect species-specific vertical mobility patterns. C1 [Galli, Gina L. J.; Shiels, Holly A.] Univ Manchester, Fac Life Sci, Core Technol Facil, Manchester M13 9NT, Lancs, England. [Brill, Richard W.] Virginia Inst Marine Sci, Natl Marine Fisheries Serv, NE Fisheries Sci Ctr, Cooperat Marine Educ & Res Program, Gloucester Point, VA 23062 USA. RP Galli, GLJ (reprint author), Univ British Columbia, 2357 Main Mall, Vancouver, BC V6T 1Z4, Canada. EM ggalli@interchange.ubc.ca FU Biotechnology and Biological Sciences Research Council NR 68 TC 19 Z9 19 U1 0 U2 9 PU UNIV CHICAGO PRESS PI CHICAGO PA 1427 E 60TH ST, CHICAGO, IL 60637-2954 USA SN 1522-2152 J9 PHYSIOL BIOCHEM ZOOL JI Physiol. Biochem. Zool. PD MAY-JUN PY 2009 VL 82 IS 3 BP 280 EP 290 DI 10.1086/597484 PG 11 WC Physiology; Zoology SC Physiology; Zoology GA 431DZ UT WOS:000265042800008 PM 19284308 ER PT J AU Casteleyn, G Adams, NG Vanormelingen, P Debeer, AE Sabbe, K Vyverman, W AF Casteleyn, Griet Adams, Nicolaus G. Vanormelingen, Pieter Debeer, Ann-Eline Sabbe, Koen Vyverman, Wim TI Natural Hybrids in the Marine Diatom Pseudo-nitzschia pungens (Bacillariophyceae): Genetic and Morphological Evidence SO PROTIST LA English DT Article DE diatoms; hybridization; ITS rDNA; morphology; Pseudo-nitzschia; rbcL ID MOLECULAR PHYLOGENY; CONCERTED EVOLUTION; HYBRIDIZATION; PCR; INTROGRESSION; SEQUENCES; WATERS; RDNA; SEA; ULTRASTRUCTURE AB Hybridization between genetically distinguishable taxa provides opportunities for investigating speciation. While hybridization is a common phenomenon in various macro-organisms, natural hybridization among micro-eukaryotes is barely studied. Here we used a nuclear and a chloroplast molecular marker and morphology to demonstrate the presence of natural hybrids between two genetically and morphologically distinct varieties of the marine planktonic diatom Pseudo-nitzschia pungens (vars. pungens and cingulata) in a contact zone in the northeast Pacific. Cloning and sequencing of the rDNA internal transcribed spacer region revealed strains containing ribotypes from both varieties, indicating hybridization. Both varieties were found to also have different chloroplast-encoded rbcL sequences. Hybrid strains were either hetero- or homoplastidial, as demonstrated by denaturing gradient gel electrophoresis, which is in accordance with expectations based on the mode of chloroplast inheritance in Pseudo-nitzschia. While most hybrids are probably first generation, there are also indications for further hybridization. Morphologically, the hybrids resembled var. pungens for most characters rather than having an intermediate morphology. Further research should focus on the hybridization frequency, by assessing the spatial and temporal extent of the contact zone, and hybrid fitness, to determine the amount of gene flow between the two varieties and its evolutionary consequences. (C) 2008 Elsevier GmbH. All rights reserved. C1 [Casteleyn, Griet; Vanormelingen, Pieter; Debeer, Ann-Eline; Sabbe, Koen; Vyverman, Wim] Univ Ghent, Dept Biol, Lab Protistol & Aquat Ecol, B-9000 Ghent, Belgium. [Adams, Nicolaus G.] Fisheries Serv, NOAA, NW Fisheries Sci Ctr, Environm Conservat Div,Marine Biotoxin Program, Seattle, WA 98112 USA. RP Vyverman, W (reprint author), Univ Ghent, Dept Biol, Lab Protistol & Aquat Ecol, Krijgslaan 281-S8, B-9000 Ghent, Belgium. EM Wim.Vyverman@ugent.be RI Dasseville, Renaat /B-3561-2010 FU Flemish Fund for Scientific Research (FWO) [0292.00, 0197.05]; Ghent University [GOA 12050398]; Flemish Institute for the Promotion of Innovation by Science and Technology (IWT); National Science Foundation's (NSF) ECOHAB [OCE-0234587]; NOAA ECOHAB [NA16OP1450] FX Financial support for this research was provided by the Research Programmes G. 0292.00 and G. 0197.05 of the Flemish Fund for Scientific Research (FWO) and the BOF-Project GOA 12050398 of Ghent University. G. C. is funded by the Flemish Institute for the Promotion of Innovation by Science and Technology (IWT). The P. pungens isolates used in this study were collected as part of the Ecology and Oceanography of Harmful Algal Blooms in the Pacific Northwest (ECOHAB-PNW) project that was funded by the National Science Foundation's (NSF) ECOHAB Project OCE-0234587 and NOAA ECOHAB Grant NA16OP1450. We thank V. Creach, N. Lundholm, M. Lastra, S. Bates, Y. Kotaki and L. Rhodes for providing strains from other areas. NR 43 TC 38 Z9 38 U1 1 U2 13 PU ELSEVIER GMBH, URBAN & FISCHER VERLAG PI JENA PA OFFICE JENA, P O BOX 100537, 07705 JENA, GERMANY SN 1434-4610 J9 PROTIST JI Protist PD MAY PY 2009 VL 160 IS 2 BP 343 EP 354 DI 10.1016/j.protis.2008.11.002 PG 12 WC Microbiology SC Microbiology GA 431QW UT WOS:000265079100013 PM 19162539 ER PT J AU Marsh, KN Brennecke, JF Chirico, RD Frenkel, M Heintz, A Magee, JW Peters, CJ Rebelo, LPN Seddon, KR AF Marsh, Kenneth N. Brennecke, Joan F. Chirico, Robert D. Frenkel, Michael Heintz, Andreas Magee, Joseph W. Peters, Cor J. Rebelo, Luis Paulo N. Seddon, Kenneth R. TI THERMODYNAMIC AND THERMOPHYSICAL PROPERTIES OF THE REFERENCE IONIC LIQUID: 1-HEXYL-3-METHYLIMIDAZOLIUM BIS[(TRIFLUOROMETHYL)SULFONYL]AMIDE (INCLUDING MIXTURES) PART 1. EXPERIMENTAL METHODS AND RESULTS (IUPAC Technical Report) SO PURE AND APPLIED CHEMISTRY LA English DT Article DE 1-hexyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]amide; ionic liquids; experimental measurements; thermodynamic properties; thermophysical properties; transport properties; uncertainties; IUPAC Physical and Biophysical Chemistry Division ID ELECTROLYTIC CONDUCTIVITY; HEAT-CAPACITIES; CARBON-DIOXIDE; SOLUBILITY; TEMPERATURES; BIS(TRIFLUOROMETHYLSULFONYL)IMIDE; ENTHALPIES; PRESSURES; VISCOSITY; DENSITY AB This article summarizes the results of IUPAC Project 2002-005-1-100 (Thermodynamics of ionic liquids, ionic liquid mixtures, and the development of standardized systems). The methods used by the various contributors to measure the thermophysical and phase equilibrium properties of the reference sample of the ionic liquid 1-hexyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]amide and its mixtures are summarized along with the uncertainties estimated by the contributors. Some results not previously published are presented. Properties of the pure ionic liquid included thermal properties (triple-point temperature, glass-transition temperature, enthalpy of fusion, heat capacities of condensed states), volumetric properties, speeds of sound, viscosities, electrolytic conductivities, and relative permittivities. Properties for mixtures included gas solubilities, solute activity coefficients at infinite dilution, liquid-liquid equilibrium (LLE) temperatures, and excess volumes. The companion article (Part 2) provides a critical evaluation of the data and recommended values with estimated combined expanded uncertainties. C1 [Marsh, Kenneth N.] Univ Canterbury, Dept Chem & Proc Engn, Christchurch 8140, New Zealand. [Brennecke, Joan F.] Univ Notre Dame, Dept Chem & Biochem Engn, Notre Dame, IN 46556 USA. [Chirico, Robert D.; Frenkel, Michael; Magee, Joseph W.] Natl Inst Stand & Technol, Thermophys Properties Div, Boulder, CO 80305 USA. [Heintz, Andreas] Univ Rostock, Dept Chem, D-18055 Rostock, Germany. [Peters, Cor J.] Delft Univ Technol, Dept Proc & Energy, Fac Mech Maritime & Mat Engn, NL-2628 CA Delft, Netherlands. [Peters, Cor J.] Petr Inst, Dept Chem Engn, Abu Dhabi, U Arab Emirates. [Rebelo, Luis Paulo N.] Univ Nova Lisboa, Inst Tecnol Quim Biol, P-2780901 Oeiras, Portugal. [Seddon, Kenneth R.] Queens Univ Belfast, Sch Chem & Chem Engn, QUILL, Belfast BT9 5AG, Antrim, North Ireland. RP Marsh, KN (reprint author), Univ Canterbury, Dept Chem & Proc Engn, Private Bag 4800, Christchurch 8140, New Zealand. RI Magee, Joseph/A-8496-2009; Rebelo, Luis Paulo/B-5285-2008; OI Magee, Joseph/0000-0002-9312-8593; Rebelo, Luis Paulo/0000-0002-5247-2443 NR 26 TC 77 Z9 77 U1 4 U2 39 PU INT UNION PURE APPLIED CHEMISTRY PI RES TRIANGLE PK PA 104 TW ALEXANDER DR, PO BOX 13757, RES TRIANGLE PK, NC 27709-3757 USA SN 0033-4545 J9 PURE APPL CHEM JI Pure Appl. Chem. PD MAY PY 2009 VL 81 IS 5 BP 781 EP 790 DI 10.1351/PAC-REP-08-09-21 PG 10 WC Chemistry, Multidisciplinary SC Chemistry GA 443LE UT WOS:000265910500001 ER PT J AU Chirico, RD Diky, V Magee, JW Frenkel, M Marsh, KN AF Chirico, Robert D. Diky, Vladimir Magee, Joseph W. Frenkel, Michael Marsh, Kenneth N. TI THERMODYNAMIC AND THERMOPHYSICAL PROPERTIES OF THE REFERENCE IONIC LIQUID: 1-HEXYL-3-METHYLIMIDAZOLIUM BIS[(TRIFLUOROMETHYL)SULFONYL]AMIDE (INCLUDING MIXTURES). PART 2. CRITICAL EVALUATION AND RECOMMENDED PROPERTY VALUES (IUPAC Technical Report) SO PURE AND APPLIED CHEMISTRY LA English DT Article DE thermodynamic properties; transport properties; recommended values; critical evaluation; ionic liquids; IUPAC Physical and Biophysical Chemistry Division ID PRESSURE PHASE-BEHAVIOR; THERMODATA ENGINE TDE; CARBON-DIOXIDE; ACTIVITY-COEFFICIENTS; INFINITE DILUTION; HEAT-CAPACITIES; 1-ALKYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE; PHYSICOCHEMICAL PROPERTIES; ELECTROLYTIC CONDUCTIVITY; SOFTWARE IMPLEMENTATION AB This article is a product of IUPAC Project 2002-005-1-100 (Thermodynamics of ionic liquids, ionic liquid mixtures, and the development of standardized systems). Experimental results of thermodynamic, transport, and phase equilibrium studies made on a reference sample of the ionic liquid 1-hexyl--methylimidazolium bis[(trifluoromethyl)sulfonyl]amide are summarized, compared, and critically evaluated to provide recommended values with uncertainties for the properties measured. Properties measured included thermal properties (triple-point temperature, glass-transition temperature, enthalpy of fusion, heat capacities of condensed states), volumetric properties, speeds of sound, viscosities, electrolytic conductivities, relative permittivities, as well as properties for mixtures, such as gas solubilities (solubility pressures), solute activity coefficients at infinite dilution, and liquid-liquid equilibrium temperatures. Recommended values with uncertainties are provided for the properties studied experimentally. The effect of the presence of water on the property values is discussed. C1 [Chirico, Robert D.; Diky, Vladimir; Magee, Joseph W.; Frenkel, Michael] Natl Inst Stand & Technol, Thermophys Properties Div, Boulder, CO 80305 USA. [Marsh, Kenneth N.] Univ Canterbury, Dept Chem & Proc Engn, Christchurch 1, New Zealand. RP Chirico, RD (reprint author), Natl Inst Stand & Technol, Thermophys Properties Div, Boulder, CO 80305 USA. RI Magee, Joseph/A-8496-2009 OI Magee, Joseph/0000-0002-9312-8593 NR 63 TC 77 Z9 77 U1 1 U2 21 PU INT UNION PURE APPLIED CHEMISTRY PI RES TRIANGLE PK PA 104 TW ALEXANDER DR, PO BOX 13757, RES TRIANGLE PK, NC 27709-3757 USA SN 0033-4545 J9 PURE APPL CHEM JI Pure Appl. Chem. PD MAY PY 2009 VL 81 IS 5 BP 791 EP 828 DI 10.1351/PAC-REP-08-09-22 PG 38 WC Chemistry, Multidisciplinary SC Chemistry GA 443LE UT WOS:000265910500002 ER PT J AU Bullock, SS O'Leary, DP AF Bullock, Stephen S. O'Leary, Dianne P. TI LOCALITY BOUNDS ON HAMILTONIANS FOR STABILIZER CODES SO QUANTUM INFORMATION & COMPUTATION LA English DT Article AB In this paper, we study the complexity of Hamiltonians whose groundstate is a stabilizer code. We introduce various notions of k-locality of a stabilizer code, inherited from the associated stabilizer group. A choice of generators leads to a Hamiltonian with the code in its groundspace. We establish bounds on the locality of any other Hamiltonian whose groundspace contains such a code, whether or not its Pauli tenser summands commute. Our results provide insight into the cost of creating an energy gap for passive error correction and for adiabatic quantum computing. The results simplify in the cases of XZ-split codes such as Calderbank-Shor-Steane stabilizer codes and topologically-ordered stabilizer codes arising from surface cellulations. C1 [Bullock, Stephen S.] Inst Def Anal, Ctr Comp Sci, Bowie, MD 20715 USA. [O'Leary, Dianne P.] Univ Maryland, Dept Comp Sci, College Pk, MD 20742 USA. [O'Leary, Dianne P.] Univ Maryland, Inst Adv Comp Studies, College Pk, MD 20742 USA. [O'Leary, Dianne P.] Natl Inst Stand & Technol, MCSD Div 891, Gaithersburg, MD 20899 USA. RP Bullock, SS (reprint author), Inst Def Anal, Ctr Comp Sci, Bowie, MD 20715 USA. EM ssbullo@super.org; oleary@cs.umd.edu FU National Science Foundation [CCF 0514213] FX We are grateful to the anonymous referees for their suggestions. The work of the second author was supported in part by the National Science Foundation under Grant CCF 0514213. NR 16 TC 1 Z9 1 U1 0 U2 1 PU RINTON PRESS, INC PI PARAMUS PA 565 EDMUND TERRACE, PARAMUS, NJ 07652 USA SN 1533-7146 J9 QUANTUM INF COMPUT JI Quantum Inform. Comput. PD MAY PY 2009 VL 9 IS 5-6 BP 487 EP 499 PG 13 WC Computer Science, Theory & Methods; Physics, Particles & Fields; Physics, Mathematical SC Computer Science; Physics GA 429RK UT WOS:000264937600009 ER PT J AU Uhrin, AV Hall, MO Merello, MF Fonseca, MS AF Uhrin, Amy V. Hall, Margaret O. Merello, Manuel F. Fonseca, Mark S. TI Survival and Expansion of Mechanically Transplanted Seagrass Sods SO RESTORATION ECOLOGY LA English DT Article DE Halodule wrightii; mechanized planting; restoration; Shoal grass; Thalassia testudinum; transplanting; Turtle grass ID WESTERN-AUSTRALIA; ZOSTERA-MARINA; TAMPA BAY; EELGRASS; RESTORATION; COMMUNITY; FLORIDA; GROWTH; USA; COLONIZATION AB Although planting seagrass is not technically complex, the ability to plant large areas is limited by the time-consuming nature of manual methods. Additionally, manual methods use small, spatially isolated planting units (PUs; shoot bundles or plugs/cores) that are often highly susceptible to disturbance. The likelihood for harvesting intact apical meristems may be higher with large sods compared to smaller units, thus increasing survival and expansion rates. Here, we examined the survival and expansion of large units (1.5 x 1.2 m) of seagrass transplanted using a mechanized planting boat (Giga Unit Transplant System; GUTS). Twenty-seven units of seagrass (18 Halodule wrightii and 9 Thalassia testudinum) were transplanted and monitored for survival, shoot density, and expansion. After 3 years, 74.1% of the units had survived (66.7% H. wrightii and 88.9% T. testudinum) with 12 H. wrightii units having expanded substantially beyond the bounds of the original PU, merging with adjacent units to form spatially continuous patches of seagrass. High survival rates for T. testudinum should be interpreted in light of concomitant declines in density and lack of significant expansion after 3 years. In its tested configuration, the GUTS was a viable method for transplanting H. wrightii where donor and receiver sites were in close proximity (< 2 km; a current limitation of the GUTS design used here). However, based on the reduced density and lack of significant expansion of T. testudinum that has persisted 3 years post-transplant, the GUTS cannot yet be fully recommended for transplanting this species. C1 [Uhrin, Amy V.; Fonseca, Mark S.] NOAA, NOS, NCCOS, Ctr Coastal Fisheries & Habitat Res, Beaufort, NC 28516 USA. [Hall, Margaret O.; Merello, Manuel F.] Florida Fish & Wildlife Conservat Commiss, Florida Wildlife Res Inst, St Petersburg, FL 33701 USA. RP Uhrin, AV (reprint author), NOAA, NOS, NCCOS, Ctr Coastal Fisheries & Habitat Res, Beaufort, NC 28516 USA. EM amy.uhrin@noaa.gov FU Florida Fish and Wildlife Conservation Commission; NOAA; National Ocean Service; Center for Coastal Fisheries and Habitat Research FX We appreciate the assistance of J. Anderson, B. Williams, and the staff of Seagrass Recovery, Inc., for providing and operating the GUTS. We recognize D. Berns, J. Bowles, K. Ferenc, F. Hall, J. Hyniova, J. Kunzelman, B. Robbins, and S. Slade for field assistance. Special thanks to B. Heckert, R. Lewis, R. Poynor, T. Reis, and B. Upcavage for graciously providing data for Table 2 and to Seagrass Technologies, LLC for allowing the use of their schematic diagrams of the GUTS bucket. We are especially grateful for the statistical guidance provided by W. J. Conover. We also acknowledge A. Malhotra for calculating wave exposures. The manuscript was improved by comments from S. Bell, E. Griffith, K. Hammerstrom, D. Johnson, J. Kenworthy, K. Kiehl, P. Marraro, V. McDonough, G. Piniak, J. VanderPluym, B. Williams, and three anonymous reviewers. The views contained in this manuscript do not necessarily reflect the view of NOAA. This study was funded by the Florida Fish and Wildlife Conservation Commission and the NOAA, National Ocean Service, Center for Coastal Fisheries and Habitat Research. NR 42 TC 5 Z9 5 U1 3 U2 21 PU WILEY-BLACKWELL PUBLISHING, INC PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 1061-2971 J9 RESTOR ECOL JI Restor. Ecol. PD MAY PY 2009 VL 17 IS 3 BP 359 EP 368 DI 10.1111/j.1526-100X.2008.00376.x PG 10 WC Ecology SC Environmental Sciences & Ecology GA 440PV UT WOS:000265713100007 ER PT J AU Rogers, DJ Richardson, CJK Goldhar, J Clark, CW AF Rogers, Daniel J. Richardson, Christopher J. K. Goldhar, Julius Clark, Charles W. TI Measurement of small birefringence and loss in a nonlinear single-mode waveguide SO REVIEW OF SCIENTIFIC INSTRUMENTS LA English DT Article DE birefringence; nonlinear optics; optical design techniques; optical fabrication; optical loss measurement; optical losses; optical variables measurement; optical waveguides ID WAVELENGTH CONVERSION; CORRELATED PHOTONS; GENERATION; FIBERS; GAAS AB We design and fabricate a birefringent semiconductor waveguide for application to nonlinear photonics, demonstrating that it is possible to engineer a small birefringence into such a device using multiple core layers. We also demonstrate a simple technique to accurately determine small waveguide birefringence using a differential measurement, present useful methods for coupling light into and out of the device, and make estimates of coupling and linear device losses. C1 [Rogers, Daniel J.; Clark, Charles W.] Natl Inst Stand & Technol, Joint Quantum Inst, Gaithersburg, MD 20899 USA. [Richardson, Christopher J. K.] Lab Phys Sci, College Pk, MD 20740 USA. [Goldhar, Julius] Univ Maryland, Dept Elect & Comp Engn, College Pk, MD 20742 USA. RP Rogers, DJ (reprint author), Natl Inst Stand & Technol, Joint Quantum Inst, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM daniel.rogers@nist.gov RI Clark, Charles/A-8594-2009 OI Clark, Charles/0000-0001-8724-9885 NR 23 TC 1 Z9 1 U1 0 U2 1 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 0034-6748 J9 REV SCI INSTRUM JI Rev. Sci. Instrum. PD MAY PY 2009 VL 80 IS 5 AR 053107 DI 10.1063/1.3124798 PG 6 WC Instruments & Instrumentation; Physics, Applied SC Instruments & Instrumentation; Physics GA 451AG UT WOS:000266442500007 PM 19485492 ER PT J AU Kiffney, PM Pess, GR Anderson, JH Faulds, P Burton, K Riley, SC AF Kiffney, Peter M. Pess, George R. Anderson, Joseph H. Faulds, P. Burton, K. Riley, Stephen C. TI CHANGES IN FISH COMMUNITIES FOLLOWING RECOLONIZATION OF THE CEDAR RIVER, WA, USA BY PACIFIC SALMON AFTER 103 YEARS OF LOCAL EXTIRPATION SO RIVER RESEARCH AND APPLICATIONS LA English DT Article DE barriers; habitat fragmentation; migration corridors; fish; river landscapes; salmon; trout ID JUVENILE COHO SALMON; TROUT ONCORHYNCHUS-CLARKI; NEWLY ACCESSIBLE HABITAT; CUTTHROAT TROUT; CHINOOK SALMON; STREAM; COLONIZATION; RESTORATION; POPULATION; ECOSYSTEMS AB Migration barriers are a major reason for species loss and population decline of freshwater organisms. Significant efforts have been made to remove or provide passage around these barriers; however, our understanding of the ecological effects of these efforts is minimal. Installation of a fish passage facility at the Landsburg Dam, WA, USA provided migratory fish access to habitat from which they had been excluded for over 100 years. Relying on voluntary recruitment, we examined the effectiveness of this facility in restoring coho (Oncorhynchus kisutch) salmon populations above the diversion, and whether reintroduction of native anadromous species affected the distribution and abundance of resident trout (O. mykiss and O. clarki). Before the ladder, late summer total salmonid (trout only) density increased with distance from the dam. This pattern was reversed after the ladder was opened, as total salmonid density (salmon + trout) approximately doubled in the three reaches closest to the dam. These changes were primarily due to the addition of coho, but small trout density also increased in lower reaches and decreased in upper reaches. A nearby source population, dispersal by adults and juveniles, low density of resident trout and high quality habitat above the barrier likely promoted rapid colonization of targeted species. Our results suggest that barrier removal creates an opportunity for migratory species to re-establish populations leading to range expansion and potentially to increased population size. Copyright (C) 2008 John Wiley & Sons, Ltd. C1 [Kiffney, Peter M.] NW Fisheries Sci Ctr, Mukilteo Field Stn, Mukilteo, WA 98275 USA. [Pess, George R.] NW Fisheries Sci Ctr, Seattle, WA 98112 USA. [Anderson, Joseph H.] Univ Washington, Sch Aquat & Fishery Sci, Seattle, WA 98195 USA. [Faulds, P.; Burton, K.] Seattle Publ Util, Seattle, WA 98124 USA. [Riley, Stephen C.] US Geol Survey, Great Lakes Sci Ctr, Ann Arbor, MI 48105 USA. RP Kiffney, PM (reprint author), NW Fisheries Sci Ctr, Mukilteo Field Stn, 10 Pk Ave,Bldg B, Mukilteo, WA 98275 USA. EM peter.kiffney@noaa.gov FU Cedar River Anadrornous Fish Commission; SPU; NWFSC; Washington Sea Grant, University of Washington; National Oceanic and Atmospheric Administration (NOAA) [NA040AR4170032, R/F-148]; Smith College-NOAA internship program FX A number of people have helped with this project over the years especially individuals from the Northwest Fisheries Science Center (NWFSC) and Seattle Public Utilities (SPU), and the University of Washington. We especially recognize the contributions of B. Bachen, H. Barnett, D. Chapin, D. Paige, and R. Little from SPU, K. Bartz, T. Bennett, E. Buhle, J. Crarn, K. Kloehn, M. Liermann, R. Klett, C. Inman, S. Morley, B. Reichart, A. Robinson, and M. Ruckelshaus from the NWFSC, and T. Quinn from University of Washington. Funding was provided by the Cedar River Anadrornous Fish Commission; SPU; the NWFSC; Washington Sea Grant, University of Washington, pursuant to National Oceanic and Atmospheric Administration (NOAA) Award Number NA040AR4170032 and Project Number R/F-148; and the Smith College-NOAA internship program. NR 63 TC 30 Z9 31 U1 5 U2 68 PU WILEY-BLACKWELL PI HOBOKEN PA 111 RIVER ST, HOBOKEN 07030-5774, NJ USA SN 1535-1459 EI 1535-1467 J9 RIVER RES APPL JI River Res. Appl. PD MAY PY 2009 VL 25 IS 4 BP 438 EP 452 DI 10.1002/rra.1174 PG 15 WC Environmental Sciences; Water Resources SC Environmental Sciences & Ecology; Water Resources GA 447IY UT WOS:000266186000006 ER PT J AU Permyakov, PA Burkanov, VN AF Permyakov, P. A. Burkanov, V. N. TI Interactions between killer whales (Orcinus orca) and Steller sea lions (Eumetopias jubatus) in the vicinity of Brat Chirpoev Island, Kuril Islands SO RUSSIAN JOURNAL OF MARINE BIOLOGY LA English DT Article DE Steller sea lion; killer whale; predator-prey; hunting behavior; defensive tactics ID BEHAVIOR; DECLINE; ALASKA; NUMBER AB The behaviors of breeding Steller sea lions in response to encounters with killer whales near the shore were observed on Brat Chirpoev Island, Kuril Islands between May and July 2002-2007. Approaches by killer whales and sea lion behavior was observed visually and recorded. Killer whales approached the rookery 104 times during the entire period of observations (289 days). In most cases (n = 95), beached sea lions did not show any apparent reactions to the presence of killer whales, and there were no observed interactions. Sea lions showed agitation during nine of the approaches; five of these events were considered to be predation attempts. The killer whales attacked the sea lions three times, however all the attacks were unsuccessful. We recorded two different types of responses towards the killer whales: (1) beaching on the shore (three times) and (2) mass exodus from the rookery with subsequent formation of a tight, actively swimming and vocalizing group (six times). The latter is the first recorded observation of this behavior for Steller sea lions. The observation suggests a low degree of interactions between these two species near the studied rookery. Despite the numerous observations of killer whales near the rookery, there were no observations of direct predation on sea lions. It is likely the killer whale predation has little or no direct impact on the Steller sea lion population on Brat Chirpoev Islands during the breeding period. C1 [Permyakov, P. A.] Russian Acad Sci, Pacific Oceanol Inst, Far Eastern Branch, Vladivostok 690041, Russia. [Burkanov, V. N.] Russian Acad Sci, Kamchatka Branch, Pacific Inst Geog, Petropavlovsk Kamchatski 683000, Russia. [Burkanov, V. N.] NOAA, Natl Marine Mammal Lab, AFSC, NMFS, Seattle, WA 98115 USA. RP Permyakov, PA (reprint author), Russian Acad Sci, Pacific Oceanol Inst, Far Eastern Branch, Vladivostok 690041, Russia. EM ampermax@mail.ru; Vladimir.Burkanov@noaa.gov FU National Marine Mammal Laboratory (AFSC/NMFS/NOAA); Alaska SeaLife Center, USA. FX The authors are sincerely grateful to V.S. Dyachkov, V.V. Koscheev, and P.G. Parshut for the assistance they rendered during observations, as well as to V.A. Burkanova, E. Gurarie, Ye.G. Mamaev, V.V. Melnikov, A.M. Trukhin, and T.S. Shulezhko for valuable discussions and help. NR 17 TC 2 Z9 2 U1 1 U2 17 PU MAIK NAUKA/INTERPERIODICA/SPRINGER PI NEW YORK PA 233 SPRING ST, NEW YORK, NY 10013-1578 USA SN 1063-0740 J9 RUSS J MAR BIOL + JI Russ. J. Mar. Biol. PD MAY PY 2009 VL 35 IS 3 BP 255 EP 258 DI 10.1134/S1063074009030109 PG 4 WC Marine & Freshwater Biology SC Marine & Freshwater Biology GA 469RA UT WOS:000267916400010 ER PT J AU Newbury, DE AF Newbury, Dale E. TI Mistakes Encountered During Automatic Peak Identification of Minor and Trace Constituents in Electron-Excited Energy Dispersive X-Ray Microanalysis SO SCANNING LA English DT Article DE energy dispersive X-ray spectrometry; automatic peak identification; peak fitting; qualitative analysis; scanning electron microscopy; trace elements; X-ray microanalysis AB Automated peak identification in electron beam-excited X-ray microanalysis with energy dispersive X-ray spectrometry has been shown to be subject to occasional mistakes even on well-separated, high-intensity peaks arising from major constituents (arbitrarily defined as a concentration, C, which exceeds a mass fraction of 0.1). The peak identification problem becomes even more problematic for constituents present at minor (0.01 <= C <= 0.1) and trace (C<0.01) levels. "Problem elements" subject to misidentification as major constituents are even more vulnerable to misidentifcation when present at low concentrations in the minor and trace ranges. Additional misidentifications attributed to trace elements include minor X-ray family members associated with major constituents but not assigned properly, escape and coincidence peaks associated with major constituents, and false peaks owing to chance groupings of counts in spectra with poor counting statistics. A strategy for robust identification of minor and trace elements can be based on application of automatic peak identification with careful inspection of the results followed by multiple linear least-squares peak fitting with complete peak references to systematically remove each identified major element from the spectrum before attempting to assign remaining peaks to minor and trace constituents. SCANNING 31: 91-101, 2009. (dagger)Published by Wiley Periodicals, Inc. C1 Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Newbury, DE (reprint author), Natl Inst Stand & Technol, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM dale.newbury@nist.gov NR 7 TC 5 Z9 5 U1 3 U2 11 PU JOHN WILEY & SONS INC PI HOBOKEN PA 111 RIVER ST, HOBOKEN, NJ 07030 USA SN 0161-0457 J9 SCANNING JI Scanning PD MAY-JUN PY 2009 VL 31 IS 3 BP 91 EP 101 DI 10.1002/sca.20151 PG 11 WC Instruments & Instrumentation; Microscopy SC Instruments & Instrumentation; Microscopy GA 476GF UT WOS:000268426100001 PM 19533682 ER PT J AU Willis, Z Jensen, R Burnett, W AF Willis, Zdenka Jensen, Robert Burnett, William TI The First National Operational Wave Observation Plan A Comprehensive Surface-Wave Monitoring Network That Addresses the Requirements of the Maritime User Community SO SEA TECHNOLOGY LA English DT Article C1 [Willis, Zdenka] NOAA, Integrated Ocean Observing Syst Program, Silver Spring, MD USA. [Jensen, Robert] USA, Corps Engineers, Vicksburg, MS 39180 USA. [Burnett, William] NOAA, Natl Data Buoy Ctr, Stennis Space Ctr, MS USA. RP Willis, Z (reprint author), NOAA, Integrated Ocean Observing Syst Program, Silver Spring, MD USA. NR 0 TC 0 Z9 0 U1 0 U2 0 PU COMPASS PUBLICATIONS, INC PI ARLINGTON PA 1501 WILSON BLVD., STE 1001, ARLINGTON, VA 22209-2403 USA SN 0093-3651 J9 SEA TECHNOL JI Sea Technol. PD MAY PY 2009 VL 50 IS 5 BP 41 EP 45 PG 5 WC Engineering, Ocean SC Engineering GA 450VT UT WOS:000266430000006 ER PT J AU de Koning, CA Pizzo, VJ Biesecker, DA AF de Koning, Curt A. Pizzo, V. J. Biesecker, D. A. TI Geometric Localization of CMEs in 3D Space Using STEREO Beacon Data: First Results SO SOLAR PHYSICS LA English DT Article AB The geometric localization technique (Pizzo and Biesecker, Geophys. Res. Lett. 31, 21802, 2004) can readily be used with Solar Terrestrial Relations Observatory (STEREO) Space Weather Beacon data to observe coronal mass ejection (CME) propagation within three-dimensional space in near-real time. This technique is based upon simple triangulation concepts and utilizes a series of lines of sight from two space-based observatories to determine gross characteristics of CMEs, such as location and velocity. Since this work is aimed at space weather applications, the emphasis is on use of COR2 coronagraph data, which has a field of view from 2.5R (aS (TM)) to 15R (aS (TM)); this spatial coverage allows us to observe the early temporal development of a CME, and hence to calculate its velocity, even for very fast CMEs. We apply this technique to highly-compressed COR2 beacon images for several CMEs at various spacecraft separation angles: 21 August 2007, when the separation angle between the two spacecraft was 26A degrees; 31 December 2007 and 2 January 2008, when the separation angle was 44A degrees; and 17 October 2008, when the spacecraft separation was 79A degrees. We present results on the speed and direction of propagation for these events and discuss the error associated with this technique. We also compare our results to the two-dimensional plane-of-sky speeds calculated from STEREO and SOHO. C1 [de Koning, Curt A.] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. [de Koning, Curt A.; Pizzo, V. J.; Biesecker, D. A.] NOAA, Space Weather Predict Ctr, Boulder, CO USA. RP de Koning, CA (reprint author), Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. EM curt.a.dekoning@noaa.gov FU NASA [NNH05AB491] FX The research at NOAA/SWPC was supported by NASA Living With a Star TR&T grant No. NNH05AB491. This paper uses data from the CACTus CME catalog, generated and maintained by the SIDC at the Royal Observatory of Belgium. This paper also uses data from the SEEDS CME catalog, generated and maintained by the Space Weather Laboratory at George Mason University. The LASCO CME catalog referred to in this paper is generated and maintained at the CDAW Data Center by NASA and The Catholic University of America in cooperation with the Naval Research Laboratory. SOHO is a project of international cooperation between ESA and NASA. NR 16 TC 35 Z9 35 U1 2 U2 2 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0038-0938 J9 SOL PHYS JI Sol. Phys. PD MAY PY 2009 VL 256 IS 1-2 BP 167 EP 181 DI 10.1007/s11207-009-9344-7 PG 15 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA 438OC UT WOS:000265563900011 ER PT J AU Webb, DF Howard, TA Fry, CD Kuchar, TA Odstrcil, D Jackson, BV Bisi, MM Harrison, RA Morrill, JS Howard, RA Johnston, JC AF Webb, D. F. Howard, T. A. Fry, C. D. Kuchar, T. A. Odstrcil, D. Jackson, B. V. Bisi, M. M. Harrison, R. A. Morrill, J. S. Howard, R. A. Johnston, J. C. TI Study of CME Propagation in the Inner Heliosphere: SOHO LASCO, SMEI and STEREO HI Observations of the January 2007 Events SO SOLAR PHYSICS LA English DT Article DE Coronal mass ejections; Corona; Interplanetary plasma ID CORONAL MASS EJECTIONS; INTERPLANETARY SCINTILLATION; IMAGER SMEI; MISSION; SUN; DISTURBANCES; BRIGHTNESS; VELOCITIES; TRANSIENT; SECCHI AB We are investigating the geometric and kinematic characteristics of interplanetary coronal mass ejections (ICMEs) using data obtained by the LASCO coronagraphs, the Solar Mass Ejection Imager (SMEI), and the SECCHI imaging experiments on the STEREO spacecraft. The early evolution of CMEs can be tracked by the LASCO C2 and C3 and SECCHI COR1 and COR2 coronagraphs, and the HI and SMEI instruments can track their ICME counterparts through the inner heliosphere. The HI fields of view (4 -aEuro parts per thousand 90A degrees) overlap with the SMEI field of view (> 20A degrees to all sky) and, thus, both instrument sets can observe the same ICME. In this paper we present results for ICMEs observed on 24 -aEuro parts per thousand 29 January 2007, when the STEREO spacecraft were still near Earth so that both the SMEI and STEREO views of large ICMEs in the inner heliosphere coincided. These results include measurements of the structural and kinematic evolution of two ICMEs and comparisons with drive/drag kinematic, 3D tomographic reconstruction, the HAFv2 kinematic, and the ENLIL MHD models. We find it encouraging that the four model runs generally were in agreement on both the kinematic evolution and appearance of the events. Because it is essential to understand the effects of projection across large distances, that are not generally crucial for events observed closer to the Sun, we discuss our analysis procedure in some detail. C1 [Webb, D. F.; Kuchar, T. A.] Boston Coll, Inst Sci Res, Chestnut Hill, MA 02167 USA. [Webb, D. F.; Kuchar, T. A.; Johnston, J. C.] Space Vehicles Directorate, AF Res Lab, Hanscom AFB, MA USA. [Howard, T. A.] Natl Solar Observ, AF Res Lab, Sunspot, NM 88349 USA. [Fry, C. D.] Explorat Phys Int Inc, Huntsville, AL USA. [Odstrcil, D.] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. [Odstrcil, D.] Natl Ocean & Atmospher Adm, Space Weather Predict Ctr, Boulder, CO USA. [Jackson, B. V.; Bisi, M. M.] Univ Calif San Diego, Ctr Astrophys & Space Sci, La Jolla, CA 92093 USA. [Harrison, R. A.] Rutherford Appleton Lab, Space Sci & Technol Dept, Space Phys Div, Didcot OX11 0QX, Oxon, England. [Morrill, J. S.; Howard, R. A.] USN, Res Lab, Div Space Sci, Washington, DC 20375 USA. RP Webb, DF (reprint author), Boston Coll, Inst Sci Res, Chestnut Hill, MA 02167 USA. EM david.webb@hanscom.af.mil RI Bisi, Mario/C-6376-2009 FU Air Force; University of Birmingham; NASA [NNG05GG45G, NNGO5GF98G]; AFOSR [F49620-02C-0015]; AFRL [FA9550-06-1-0107, FA8718-06-C-0015, F61775-02-WE043]; NSF [ATM-0331513]; AURA [C10562N]; Navy grants [N00173-01-1-G013, N00173-07-1-G016]; AFOSR/MURI; NASA/LWS; NSF/CISM FX We acknowledge P. P. Hick and A. Buffington for their efforts in the calibration and processing of SMEI data at UCSD. We thank C. Eyles of the University of Birmingham, UK, for SECCHI HI data, J. Davies of the Rutherford Appleton Laboratory for HI image processing, and V. Kunkel of NRL for SECCHI distance-time measurements. SMEI is a collaborative project of the US Air Force Research Laboratory, NASA, the University of California at San Diego, the University of Birmingham, UK, Boston College, and Boston University. Financial support has been provided by the Air Force, the University of Birmingham, and NASA. The Heliospheric Imager (HI) instrument was developed by a collaboration that included the Rutherford Appleton Laboratory and the University of Birmingham, both in the United Kingdom, the Centre Spatial de Liege (CSL), Belgium, and the US Naval Research Laboratory (NRL), Washington DC, USA. The STEREO/SECCHI project is an international consortium of the Naval Research Laboratory (USA), Lockheed Martin Solar and Astrophysics Lab (USA), NASA Goddard Space Flight Center (USA), Rutherford Appleton Laboratory (UK), University of Birmingham (UK), Max-Planck-Institut fur Sonnen-systemforschung (Germany), Centre Spatial de Liege (Belgium), Institut d'Optique Theorique et Appliquee (France), and Institut d'Astrophysique Spatiale (France). We also acknowledge use of the CME catalog that is generated and maintained at the CDAW Data Center by NASA and The Catholic University of America in cooperation with the Naval Research Laboratory. SOHO is a project of international cooperation between ESA and NASA. This work was supported for each coauthor by these sources: T. A. H. by the National Research Council Fellowship Program, funded by AFOSR contract F49620-02C-0015; B. V. J. and M. M. B. at UCSD by AFRL contract FA9550-06-1-0107, NSF grant ATM-0331513 and NASA grant NNG05GG45G; D. F. W., T. A. K. and D. R. M. at Boston College by AFRL contract FA8718-06-C-0015; S. J. T. under contract F61775-02-WE043 to the University of Birmingham; and C. D. F. at EXPI by AURA contract C10562N. D. F. W., T. A. H. and B. V. J. also were supported by NASA grant NNGO5GF98G, and D. F. W. by Navy grants N00173-01-1-G013 and N00173-07-1-G016. D.O. was supported by AFOSR/MURI, NASA/LWS, and NSF/CISM grants. NR 60 TC 45 Z9 48 U1 0 U2 4 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0038-0938 J9 SOL PHYS JI Sol. Phys. PD MAY PY 2009 VL 256 IS 1-2 BP 239 EP 267 DI 10.1007/s11207-009-9351-8 PG 29 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA 438OC UT WOS:000265563900015 ER PT J AU Millican, JN Phelan, D Thomas, EL Leao, JB Carpenter, E AF Millican, Jasmine N. Phelan, Daniel Thomas, Evan L. Leao, Juscelino B. Carpenter, Elisabeth TI Pressure-induced effects on the structure of the FeSe superconductor SO SOLID STATE COMMUNICATIONS LA English DT Article DE Superconductors; Crystal structure and symmetry; Phase transitions; Neutron scattering ID 43 K AB A polycrystalline sample of FeSe, which adopts the tetragonal PbO-type structure (P(4)/nmm) at room temperature, has been prepared using solid state reaction. We have investigated pressure-induced structural changes in tetragonal FeSe at varying hydrostatic pressures up to 0.6 GPa in the orthorhombic (T = 50 K) and tetragonal (T = 190 K) phases using high resolution neutron powder diffraction. We report that the structure is quite compressible with a Bulk modulus approximate to 31 GPa to 33 GPa and that the pressure response is anisotropic with a larger compressibility along the c-axis. Key bond angles of the SeFe(4) pyramids and FeSe(4) tetrahedra are also determined as a function of pressure. Published by Elsevier Ltd C1 [Millican, Jasmine N.; Phelan, Daniel; Leao, Juscelino B.; Carpenter, Elisabeth] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Thomas, Evan L.] Natl Inst Stand & Technol, Div Ceram, Gaithersburg, MD 20899 USA. RP Millican, JN (reprint author), Natl Inst Stand & Technol, Ctr Neutron Res, 100 Bur Dr MS 6102, Gaithersburg, MD 20899 USA. EM jasmine.millican@nist.gov NR 20 TC 44 Z9 44 U1 6 U2 44 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0038-1098 J9 SOLID STATE COMMUN JI Solid State Commun. PD MAY PY 2009 VL 149 IS 17-18 BP 707 EP 710 DI 10.1016/j.ssc.2009.02.011 PG 4 WC Physics, Condensed Matter SC Physics GA 440WJ UT WOS:000265730100012 ER PT J AU Seah, MP Unger, WES Wang, H Jordaan, W Gross, T Dura, JA Moon, DW Totarong, P Krumrey, M Hauert, R Mo, ZQ AF Seah, M. P. Unger, W. E. S. Wang, Hai Jordaan, W. Gross, Th. Dura, J. A. Moon, Dae Won Totarong, P. Krumrey, M. Hauert, R. Mo Zhiqiang TI Ultra-thin SiO2 on Si IX: absolute measurements of the amount of silicon oxide as a thickness of SiO2 on Si SO SURFACE AND INTERFACE ANALYSIS LA English DT Article DE attenuation length; calibration; silicon dioxide; thickness; ultra-thin oxide ID X-RAY REFLECTOMETRY; GAS-ADSORPTION; XPS; FILMS; ELLIPSOMETRY; LINEARITY; STANDARDS; ACCURACY; SURFACES AB Results from a study conducted between National Metrology Institutes (NMIs) for the measurements of the absolute thicknesses of ultra-thin layers Of SiO2 on Si are reported. These results are from a key comparison and associated pilot study under the auspices of the Consultative Committee for Amount of Substance. 'Amount of substance' may be expressed in many ways, and here the measurand is the thickness of the silicon oxide layers with nominal thicknesses in the range 1.5-8 nm on Si substrates, expressed as the thickness Of SiO2. Separate samples were provided to each institute in containers that limited the carbonaceous contamination to approximately < 0.3 nm. The SiO2 samples were of ultra-thin on (100) and (111) orientated wafers of Si. The measurements from the laboratories which participated in the study were conducted using ellipsometry, neutron reflectivity, X-ray photoelectron spectroscopy or X-ray reflectivity, guided by the protocol developed in an earlier pilot study. A very minor correction was made in the different samples that each laboratory received. Where appropriate, method offset values attributed to the effects of contaminations, from the earlier pilot study, were subtracted. Values for the key comparison reference values (agreed best values from a Consultative Committee study) and their associated uncertainties for these samples are then made from the weighted means and the expanded weighted standard deviations of the means of these data. These results show a dramatic improvement on previous comparisons, leading to 95% uncertainties in the range 0.09-0.27 nm, equivalent to 0.4-1.0 monolayers over the 1.5-8.0 nm nominal thickness range studied. If the sample-to-sample uncertainty is reduced from its maximum estimate to the most likely value, these uncertainties reduce to 0.05-0.25 nm or similar to 1.4% relative standard uncertainties. The best results achieve similar to 1% relative standard uncertainty. It is concluded that XPS has now been made fully traceable to the SI, for ultra-thin thermal SiO2 on Si layers, by calibration using wavelength methods in an approach that may be extended to other material systems. (C) Crown copyright 2009. Reproduced with the permission of Her Majesty's Stationery Office. Published by John Wiley & Sons, Ltd. C1 [Seah, M. P.] Natl Phys Lab, Qual Life Div, Teddington TW11 0LW, Middx, England. [Unger, W. E. S.; Gross, Th.] Bundesanstalt Mat Forsch & Pruefung, D-12200 Berlin, Germany. [Wang, Hai] NRCCRM, Physicochem & Chem Engn Div, Beijing 100013, Peoples R China. [Jordaan, W.] Natl Metrol Inst S Africa Surface & Microanal, ZA-0040 Pretoria, South Africa. [Dura, J. A.] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Moon, Dae Won] KRISS, Div Chem Metrol & Mat Evaluat, Taejon 305600, South Korea. [Totarong, P.] NIMT, Klongluang 12120, Pathumthanee, Thailand. [Totarong, P.] Minist Sci & Technol, Natl Sci & Technol Dev Agcy, Ctr Microelect, Natl Elect & Comp Technol Ctr, Amphur Mueng Chachoengsa 24000, Thailand. [Krumrey, M.] PTB, D-10587 Berlin, Germany. [Hauert, R.] Swiss Fed Labs Mat Testing & Res EMPA, CH-8600 Dubendorf, Switzerland. [Mo Zhiqiang] PSB Corp, Chem & Mat, Singapore 118221, Singapore. RP Seah, MP (reprint author), Natl Phys Lab, Qual Life Div, Teddington TW11 0LW, Middx, England. EM martin.seah@npl.co.uk RI Dura, Joseph/B-8452-2008; Krumrey, Michael/G-6295-2011; Unger, Wolfgang/A-9317-2009; OI Dura, Joseph/0000-0001-6877-959X; Unger, Wolfgang/0000-0002-7670-4042; Hauert, Roland/0000-0001-6154-9337 NR 31 TC 15 Z9 18 U1 2 U2 12 PU WILEY-BLACKWELL PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 0142-2421 J9 SURF INTERFACE ANAL JI Surf. Interface Anal. PD MAY PY 2009 VL 41 IS 5 BP 430 EP 439 DI 10.1002/sia.3045 PG 10 WC Chemistry, Physical SC Chemistry GA 438GB UT WOS:000265542800013 ER PT J AU Tatara, CP Riley, SC Scheurer, JA AF Tatara, Christopher P. Riley, Stephen C. Scheurer, Julie A. TI Growth, Survival, and Habitat Use of Naturally Reared and Hatchery Steelhead Fry in Streams: Effects of an Enriched Hatchery Rearing Environment SO TRANSACTIONS OF THE AMERICAN FISHERIES SOCIETY LA English DT Article ID MIGRATING JUVENILE SALMONIDS; TROUT ONCORHYNCHUS-MYKISS; SPRING CHINOOK SALMON; DOMINANCE HIERARCHIES; ANADROMOUS SALMONIDS; POSTRELEASE SURVIVAL; WASHINGTON STREAMS; BRITISH-COLUMBIA; ATLANTIC SALMON; BROWN TROUT AB After hatchery-reared salmonids are released into file Wild. their Survival and performance are frequently lower than those of wild conspecifies. Additionally, negative effects of hatchery fish oil wild fish are cited as factors affecting the recovery of salmonid populations. Alternative hatchery rearing environments and release practices have been proposed to mitigate both problems. We investigated the postrelease growth, Survival, habitat use, and spatial distribution of hatchery steelhead Oncorhynchus mykiss fry reared in convention at and enriched environments and compared their performance with thin of naturally reared steelhead try horn the same parent Population in two streams. Average instantaneous growth rates differed between streams bill not among file three rearing groups. The survival of naturally reared fry was significantly greater than that of both types of hatchery fry (relative survival = 0.33) but did not differ between the, conventional and enriched environments. Naturally reared fry grew and survived equally well regardless of the type of hatchery fry with which they were stocked. Supplementation increased Cry population size in all stream sections but produced hatchery-biased Populations. Steelhead fry preferred pool habitat within stream Sections, but Pool use was affected by all interaction between rearing environment and stream. Hatchery fry had more clumped spatial distributions than naturally reared fry, Which were affected by a significant interaction between rearing type and stream. Hatchery rearing type and stream had no effect on the spatial distribution of naturally reared fry. We conclude that (1) hatchery, steelhead fry released in streams grow as well as naturally reared fry but do not survive as well, (2) enriched hatchery environments do not improve postrelease growth or survival, and (3) upon release, fry raised in enriched hatchery environments affect the growth and survival of naturally reared Cry in much the same way as fry reared in conventional hatchery environments. C1 [Tatara, Christopher P.] NOAA, NW Fisheries Sci Ctr, Manchester Res Stn, Manchester, WA 98353 USA. [Riley, Stephen C.] US Geol Survey, Great Lakes Sci Ctr, Ann Arbor, MI 48105 USA. [Scheurer, Julie A.] NOAA, NW Fisheries Sci Ctr, Newport Res Stn, Newport, OR 97365 USA. RP Tatara, CP (reprint author), NOAA, NW Fisheries Sci Ctr, Manchester Res Stn, POB 130, Manchester, WA 98353 USA. EM chris.p.tatara@noaa.gov NR 57 TC 18 Z9 18 U1 0 U2 15 PU TAYLOR & FRANCIS INC PI PHILADELPHIA PA 530 WALNUT STREET, STE 850, PHILADELPHIA, PA 19106 USA SN 0002-8487 EI 1548-8659 J9 T AM FISH SOC JI Trans. Am. Fish. Soc. PD MAY PY 2009 VL 138 IS 3 BP 441 EP 457 DI 10.1577/T07-260.1 PG 17 WC Fisheries SC Fisheries GA 477EJ UT WOS:000268501100001 ER PT J AU Johnson, DR Perry, HM Lyczkowski-Shultz, J Hanisko, D AF Johnson, Donald R. Perry, Harriet M. Lyczkowski-Shultz, Joanne Hanisko, David TI Red Snapper Larval Transport in the Northern Gulf of Mexico SO TRANSACTIONS OF THE AMERICAN FISHERIES SOCIETY LA English DT Article ID WEST FLORIDA SHELF; LUTJANUS-CAMPECHANUS; CONTINENTAL-SHELF; MITOCHONDRIAL-DNA; CIRCULATION; MOVEMENT; HABITAT; PLUME AB This study examines the advection of red snapper Lutjanus campechanus larvae in the northern Gulf of Mexico. The potential for repopulating the eastern Gulf stock through larval transport from the more populous western stock is addressed. Transport pathways across topographic features that inhibit alongshelf flow (e.g., the Mississippi River delta. DeSoto Canyon, and the Apalachicola peninsula) and interregional larval transport are considered. An advective field of currents is developed front a large database of drifter and moored Currents. augmented by an operational model to fill gaps. The starting points for larval transport are the locations and day of the year of larval captures from the Southeast Area Monitoring and Assessment program ichthyoplankton surveys. Because the Field Of Currents is derived front near-surface observations and the depth distribution of larvae is uncertain. findings are expressed in terms of maximal transport pathways. Transport pathways were principally vectored toward the west during September. October, and May under the influence of relatively strong climatological westward wind stress. Eastward pathways Occurred in June. July. and August under the influence of weaker shoreward wind stress. Westward transport pathways past the Mississippi delta were found near the delta. whereas eastward transport pathways were found in deeper waters beyond the continental shelf break, away front typical juvenile settlement habitat. Water movement front east to west across the Apalachicola peninsula occurred in the fall. suggesting the potential for genetic exchange front the eastern to the western Gulf. Eastward water movement across the Apalachicola peninsula occurred in July. but only along the outer shelf. C1 [Johnson, Donald R.; Perry, Harriet M.] Univ So Mississippi, Gulf Coast Res Lab, Ocean Springs, MS 39564 USA. [Lyczkowski-Shultz, Joanne; Hanisko, David] Natl Marine Fisheries Serv, SE Fisheries Sci Ctr, Pascagoula, MS 39567 USA. RP Johnson, DR (reprint author), Univ So Mississippi, Gulf Coast Res Lab, 703 E Beach Dr, Ocean Springs, MS 39564 USA. EM donald.r.johnson@usm.edu FU National Marine Fisheries Service's Southeastern Regional Office FX We gratefully acknowledge funding for this study from the Marine Fisheries Initiative program of the National Marine Fisheries Service's Southeastern Regional Office. The Study would not have been possible without the generous contributions of data from a number of research scientists. Many of the Current observations are from several large Minerals Management Service (MMS) projects in the northern Gulf Of Mexico. We would especially like to acknowledge W. Johnson (MMS) and P. Niiler (Scripps Institution of Oceanography). Other programs involved Florida State University and the University of South Florida. Drifter and moored current data were provided by J. Blaha. C. Szczechowski, and S. Dinnel (Naval Oceanographic Office). Research scientists at Texas A&M and Louisiana State universities contributed ton CD-ROM data set that is available through the National Oceanographic Data Center. We are grateful to J. Waters and D. Carter (National Oceanic and Atmospheric Administration) for discussions Oil the impact of recreational fisheries. Finally, we acknowledge L. Kantha, who has,generously Shared his Model data archive for several different fisheries Studies, including this one. NR 33 TC 9 Z9 9 U1 0 U2 13 PU AMER FISHERIES SOC PI BETHESDA PA 5410 GROSVENOR LANE SUITE 110, BETHESDA, MD 20814-2199 USA SN 0002-8487 J9 T AM FISH SOC JI Trans. Am. Fish. Soc. PD MAY PY 2009 VL 138 IS 3 BP 458 EP 470 DI 10.1577/T08-008.1 PG 11 WC Fisheries SC Fisheries GA 477EJ UT WOS:000268501100002 ER PT J AU Moss, JH Farley, EV Feldmann, AM Ianelli, JN AF Moss, Jamal H. Farley, Edward V., Jr. Feldmann, Angela M. Ianelli, James N. TI Spatial Distribution, Energetic Status, and Food Habits of Eastern Bering Sea Age-0 Walleye Pollock SO TRANSACTIONS OF THE AMERICAN FISHERIES SOCIETY LA English DT Article ID EARLY MARINE GROWTH; THERAGRA-CHALCOGRAMMA; PRIBILOF ISLANDS; PELAGIC ECOSYSTEM; CLASS STRENGTH; SALMON; SIZE; ALASKA; SHELF; ZOOPLANKTON AB Age-0 walleye pollock Theragra chalcogramma were collected from the eastern Bering Sea during years when ocean temperatures were anomalously warm (2004-2005) and cool (2006-2007). Variability in spatial distribution, food habits, energetic condition, and recruitment to the age-1 life stage was investigated in relation to thermal regime. Age-0 walleye pollock were large in size and widely distributed during warm years, whereas they were small and largely confined to the middle domain of the eastern Bering Sea during cool years. Energy density as positively correlated with body weight and was greater during years when conditions were anomalously cool. The proportion of smaller age-0 walleye pollock in the diet of larger individuals was high when conditions were warm (21.9% of diet by weight), and euphausiids were the most important prey (36.5% of diet by weight) when conditions were cool. Eastern Bering Sea age-0 walleye pollock were abundant and broadly distributed from Bristol Bay to offshore and northern locations during warm years: during cool years, age-0 fish were less abundant and their distribution was constricted to the southeastern Bering Sea. An inverse relationship between brood year abundance and survival from age 0 to age 1 was found. Our results indicate that when spring (summer) sea temperatures on the eastern Bering, Sea shelf are very warm and when the water column is highly stratified during summer, age-0 walleye pollock allocate more energy to growth than to lipid storage. leading to low energy density before winter and thus to higher overwinter mortality. C1 [Moss, Jamal H.; Farley, Edward V., Jr.; Feldmann, Angela M.] Ted Stevens Marine Res Inst, Natl Marine Fisheries Serv, Alaska Fisheries Sci Ctr, Auke Bay Labs, Juneau, AK 99801 USA. [Ianelli, James N.] Natl Marine Fisheries Serv, Alaska Fisheries Sci Ctr, Seattle, WA 98115 USA. RP Moss, JH (reprint author), Ted Stevens Marine Res Inst, Natl Marine Fisheries Serv, Alaska Fisheries Sci Ctr, Auke Bay Labs, 17109 Point Lena Loop Rd, Juneau, AK 99801 USA. EM jamal.moss@noaa.gov NR 46 TC 42 Z9 45 U1 0 U2 14 PU AMER FISHERIES SOC PI BETHESDA PA 5410 GROSVENOR LANE SUITE 110, BETHESDA, MD 20814-2199 USA SN 0002-8487 J9 T AM FISH SOC JI Trans. Am. Fish. Soc. PD MAY PY 2009 VL 138 IS 3 BP 497 EP 505 DI 10.1577/T08-126.1 PG 9 WC Fisheries SC Fisheries GA 477EJ UT WOS:000268501100005 ER PT J AU Satterthwaite, WH Beakes, MP Collins, EM Swank, DR Merz, JE Titus, RG Sogard, SM Mangel, M AF Satterthwaite, William H. Beakes, Michael P. Collins, Erin M. Swank, David R. Merz, Joseph E. Titus, Robert G. Sogard, Susan M. Mangel, Marc TI Steelhead Life History on California's Central Coast: Insights from a State-Dependent Model SO TRANSACTIONS OF THE AMERICAN FISHERIES SOCIETY LA English DT Article ID SALMON SALMO-SALAR; TROUT ONCORHYNCHUS-MYKISS; ATLANTIC SALMON; KEOGH RIVER; REPRODUCTIVE SUCCESS; GENETIC ARCHITECTURE; SEXUAL-MATURATION; RAINBOW-TROUT; SMOLT SIZE; GROWTH AB Steelhead Oncorhynchus mykiss display a dizzying array of lite history variation (including the purely resident form, rainbow trout), We developed a model for female steelhead in coastal California (close to the southern boundary of their range) in small coastal streams. We combined proximate (physiological) and ultimate (expected reproductive success) considerations to generalize the notion of a threshold size for emigration or maturity through the development of a state-dependent life history theory. The model involves strategies that depend on age, size or condition, and recent rates of change in size or condition during specific periods (decision windows) in advance of the actual smolting or spawning event. This is the first study in which such a model is fully parameterized based oil data collected entirely front California steelhead populations, the majority of data coming from two watersheds the rnouths of whose rivers are separated by less than 8 kin along the coast of Santa Cruz County. We predicted the occurrence of resident life histories and the distribution of sizes and ages at smolting for steelhead rearing in the upstream habitats of these streams. We compared these predictions with empirical results and show that the theory call explain the observed pattern and variation. C1 [Satterthwaite, William H.; Beakes, Michael P.; Swank, David R.; Mangel, Marc] Univ Calif Santa Cruz, Dept Appl Math & Stat, Ctr Stock Assessment Res, Santa Cruz, CA 95064 USA. [Beakes, Michael P.; Swank, David R.; Sogard, Susan M.] Natl Marine Fisheries Serv, Santa Cruz, CA 95060 USA. [Collins, Erin M.; Titus, Robert G.] Calif Dept Fish & Game, Sacramento, CA 95826 USA. [Merz, Joseph E.] Univ Calif Santa Cruz, Inst Marine Sci, Santa Cruz, CA 95064 USA. [Merz, Joseph E.] Cramer Fish Sci, Auburn, CA 95603 USA. RP Satterthwaite, WH (reprint author), Univ Calif Santa Cruz, Dept Appl Math & Stat, Ctr Stock Assessment Res, Santa Cruz, CA 95064 USA. EM satterth@darwin.ucsc.edu FU CALFED Science Program [SCI-05-140, U-05-SC-40] FX This material is based upon work Supported by the CALFED Science Program Under grant SCI-05-140, grantee agreement U-05-SC-40. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the CALFED Science Program. We also thank S. Hayes, M. Bond, and C. Hanson for sharing Unpublished data and ideas and B. Ward for helpful discussions. NR 64 TC 39 Z9 40 U1 0 U2 18 PU AMER FISHERIES SOC PI BETHESDA PA 5410 GROSVENOR LANE SUITE 110, BETHESDA, MD 20814-2199 USA SN 0002-8487 J9 T AM FISH SOC JI Trans. Am. Fish. Soc. PD MAY PY 2009 VL 138 IS 3 BP 532 EP 548 DI 10.1577/T08-164.1 PG 17 WC Fisheries SC Fisheries GA 477EJ UT WOS:000268501100008 ER PT J AU Sogard, SM Williams, TH Fish, H AF Sogard, Susan M. Williams, Thomas H. Fish, Heidi TI Seasonal Patterns of Abundance, Growth, and Site Fidelity of Juvenile Steelhead in a Small Coastal California Stream SO TRANSACTIONS OF THE AMERICAN FISHERIES SOCIETY LA English DT Article ID TROUT ONCORHYNCHUS-MYKISS; RAINBOW-TROUT; POPULATION-DENSITY; FOOD-CONSUMPTION; SALMO-GAIRDNERI; SURVIVAL; SIZE; TERRESTRIAL; TEMPERATURE; RIVER AB Populations of steelhead Oncorhynchus mykiss throughout the central California coast are currently listed as threatened under the federal Endangered Species Act. To better understand demographic processes during the juvenile freshwater stage. we quantified abundance, movement, and growth of juvenile steelhead among five reaches in it primary spawning area of Soquel Creek. We used mark-recapture methods to examine seasonal, density-dependent. and size-dependent patterns in these Population metrics. Many trends were stronger in age-0 fish than in age-I and older fish. Estimated survival and retention Within it reach were generally highest ill summer and lowest in winter-spring. Density dependence was evident only in age-0 fish. with lower survival Occurring an higher densities. Survival was typically size-dependent. with lower survival of smaller fish in both age-classes. Immigration. based oil movement of untagged fish into our sites between sampling periods. wits higher in winter-spring compared With summer and fall. Immigration was generally independent of density but was size-dependent, with smaller fish more liked, to move than larger fish. Average growth rates were low, rarely exceeding 0.3 mm/d. Growth was fastest in winter-spring, potentially it function of higher flow rates and increased food availability. Growth was generally size-dependent, with smaller fish growing faster than larger fish, A negative effect of fish density on growth was apparent only for age-0 fish in summer. High site fidelity was evident in high recapture rates of tagged fish. Recaptures over periods of up to 4 years Suggested likely expression of a nonanadromous life history by some individuals. The growth rates in this system suggest that fish rearing in upstream habitats cannot undergo smoltification and emigrate until they are at least age 2. Our results provide it valuable baseline of demographic patterns for juvenile steelhead in representative freshwater habitat of the Central California Coast steellhead Distinct population segment. C1 [Sogard, Susan M.; Williams, Thomas H.; Fish, Heidi] Natl Marine Fisheries Serv, SW Fisheries Sci Ctr, Santa Cruz, CA 95066 USA. RP Sogard, SM (reprint author), Natl Marine Fisheries Serv, SW Fisheries Sci Ctr, 110 Shaffer Rd, Santa Cruz, CA 95066 USA. EM susan.sogard@noaa.gov NR 44 TC 17 Z9 17 U1 5 U2 27 PU AMER FISHERIES SOC PI BETHESDA PA 5410 GROSVENOR LANE SUITE 110, BETHESDA, MD 20814-2199 USA SN 0002-8487 J9 T AM FISH SOC JI Trans. Am. Fish. Soc. PD MAY PY 2009 VL 138 IS 3 BP 549 EP 563 DI 10.1577/T08-172.1 PG 15 WC Fisheries SC Fisheries GA 477EJ UT WOS:000268501100009 ER PT J AU O'Neill, SM West, JE AF O'Neill, Sandra M. West, James E. TI Marine Distribution, Life History Traits, and the Accumulation of Polychlorinated Biphenyls in Chinook Salmon from Puget Sound, Washington SO TRANSACTIONS OF THE AMERICAN FISHERIES SOCIETY LA English DT Article ID PERSISTENT ORGANIC POLLUTANTS; TROUT SALVELINUS-NAMAYCUSH; LAKE-MICHIGAN SALMONIDS; WHALES ORCINUS-ORCA; BRITISH-COLUMBIA; ONCORHYNCHUS-TSHAWYTSCHA; SOCKEYE-SALMON; KILLER WHALES; BALTIC SEA; GLOBAL FRACTIONATION AB Polychlorinated biphenyl (PCB) levels and the factors affecting PCB accumulation in subadult and maturing Chinook salmon Oncorhynchus tshawytscha from Puget Sound were characterized. Specifically, we (1) determined PCB levels in Chinook salmon from Puget Sound and compared them with levels in Chinook salmon front other West Coast populations, (2) determined whether PCB accumulation mainly occurred in the freshwater or marine habitats, and (3) quantified the relative importance of fish age, fish size (fork length), lipid content. and saltwater age (the number of winters spent in saltwater) on PCB concentration. The average PCB concentration measured in skinless muscle tissue samples of subadult and maturing Chinook salmon collected from Puget Sound was 53 ng/g (wet weight), which was 3-5 times higher than those measured in six other populations of Chinook salmon on the West Coast of North America. Concentrations in the Puget Sound samples varied from 10 to 220 ng/g. A comparison of PCB body burdens between subyearling smolts and returning adults revealed that almost all of the PCBs (>96%) were accumulated in the marine habitats. Surprisingly. although PCBs were mostly accumulated in marine habitats. PCB exposure was lowest in the largest fish that spent the most little in saltwater. Collectively, saltwater age. fish size, and lipids only accounted for 37% of the observed variation in PCB concentration, indicating that some other attribute of the fish's marine ecology accounted for the variation in PCB levels among Puget Sound Chinook salmon and for their elevated PCB levels relative to other West Coast populations. We hypothesized that residency in the contaminated Puget Sound environment was a major factor contributing to the higher and more variable PCB concentrations in these fish. This hypothesis was supported with an independent data set from a fishery assessment model, which estimated that 29% of subyearling Chinook-salmon and 45% of yearling out-migrants from Puget Sound displayed resident behavior. C1 [O'Neill, Sandra M.; West, James E.] Washington Dept Fish & Wildlife, Olympia, WA 98501 USA. RP O'Neill, SM (reprint author), NOAA, Natl Marine Fisheries Serv, NW Fisheries Sci Ctr, 2725 Montlake Blvd E, Seattle, WA 98112 USA. EM sandie.oneill@noaa.gov NR 83 TC 19 Z9 21 U1 5 U2 31 PU TAYLOR & FRANCIS INC PI PHILADELPHIA PA 530 WALNUT STREET, STE 850, PHILADELPHIA, PA 19106 USA SN 0002-8487 EI 1548-8659 J9 T AM FISH SOC JI Trans. Am. Fish. Soc. PD MAY PY 2009 VL 138 IS 3 BP 616 EP 632 DI 10.1577/T08-003.1 PG 17 WC Fisheries SC Fisheries GA 477EJ UT WOS:000268501100014 ER PT J AU Sturdevant, MV Sigler, MF Orsi, JA AF Sturdevant, M. V. Sigler, M. F. Orsi, J. A. TI Sablefish Predation on Juvenile Pacific Salmon in the Coastal Marine Waters of Southeast Alaska in 1999 SO TRANSACTIONS OF THE AMERICAN FISHERIES SOCIETY LA English DT Review ID EARLY-LIFE-HISTORY; WHITING MERLANGIUS-MERLANGUS; PINK ONCORHYNCHUS-GORBUSCHA; ANOPLOPOMA-FIMBRIA PALLAS; SIZE-SELECTIVE MORTALITY; COD GADUS-MORHUA; GASTRIC EVACUATION; CHUM SALMON; DAILY RATION; COHO SALMON AB A1-sea observations of predation by age-1 and older (age-1+) sablefish Anoplopoma fimbria oil juvenile Pacific salmon Oncorhynchus spp. were combined with laboratory studies to determine gastric evacuation rates and were used to estimate summer predation impact in file northern region of Southeast Alaska. In June and July 1999, tip to 63% of sablefish examined from trawl catches in strait habitat had each consumed one to four juvenile pink salmon O. gorbuscha, chum salmon O. keta, or sockeye salmon O. nerka. In two laboratory experiments, field-captured sablefish were acclimated without food in compartmentalized flow-through tanks with conditions manipulated to reflect the photoperiod and temperature regimes of summer. These sablefish were each offered one whole, preweighed juvenile chum salmon: Consumption events were observed, and the sablefish were then sacrificed at predetermined time intervals. Prey biomass remaining in the stomach of each sablefish predator was weighed, and all exponential model of the decline in percent biomass over time was used to yield instantaneous evacuation rates of 0.049 at 12 degrees C and 0.027 at 7 degrees C. From field data combined with model-derived estimates of meal frequency, we estimated that 0.8-6.0 million juvenile salmon were Consumed by age-1+ sablefish in the 500-km(2) area of Icy Strait during a 33-d period. Moreover, a 10-year time series of catches indicated that 1999 was a year of unusually high age-1+ sablefish abundance and relatively low juvenile salmon abundance. We speculate that sablefish predation in 1999 Could have affected abundance of out-migrating juveniles and contributed to low harvests Of returning, adult pink salmon in 2000 and adult churn salmon in 2002. Our results suggest that sablefish predation oil juvenile Pacific salmon call occur during episodic strong year-classes of sablefish and may affect adult salmon returns. C1 [Sturdevant, M. V.; Sigler, M. F.; Orsi, J. A.] Natl Marine Fisheries Serv, Alaska Fisheries Sci Ctr, Auke Bay Labs, Juneau, AK 99801 USA. RP Sturdevant, MV (reprint author), Natl Marine Fisheries Serv, Alaska Fisheries Sci Ctr, Auke Bay Labs, 17109 Point Lena Loop Rd, Juneau, AK 99801 USA. EM molly.sturdevant@noaa.gov NR 126 TC 6 Z9 7 U1 0 U2 1 PU TAYLOR & FRANCIS INC PI PHILADELPHIA PA 530 WALNUT STREET, STE 850, PHILADELPHIA, PA 19106 USA SN 0002-8487 EI 1548-8659 J9 T AM FISH SOC JI Trans. Am. Fish. Soc. PD MAY PY 2009 VL 138 IS 3 BP 675 EP 691 DI 10.1577/T08-157.1 PG 17 WC Fisheries SC Fisheries GA 477EJ UT WOS:000268501100019 ER PT J AU Moore, MJ Bogomolni, AL Dennison, SE Early, G Garner, MM Hayward, BA Lentell, BJ Rotstein, DS AF Moore, M. J. Bogomolni, A. L. Dennison, S. E. Early, G. Garner, M. M. Hayward, B. A. Lentell, B. J. Rotstein, D. S. TI Gas Bubbles in Seals, Dolphins, and Porpoises Entangled and Drowned at Depth in Gillnets SO VETERINARY PATHOLOGY LA English DT Article DE Bubbles; computed tomography; dolphins; histopathology; necropsy; porpoises; seals ID BEAKED-WHALES; NITROGEN TENSIONS; DIVING BEHAVIOR; MASS MORTALITY; FISHING GEAR; DIVES; CETACEANS; LESIONS; COLLAPSE; ENGLAND AB Gas bubbles were found in 15 of 23 gillnet-drowned bycaught harp (Pagophilus groenlandicus), harbor (Phoca vitulina) and gray (Halichoerus grypus) seals, common (Delphinus delphis) and white-sided (Lagenorhyncus acutus) dolphins, and harbor porpoises (Phocaena phocaena) but in only I of 41 stranded marine mammals. Cases with minimal scavenging and bloating were chilled as practical and necropsied within 24 to 72 hours of collection. Bubbles were commonly visible grossly and histologically in bycaught cases. Affected tissues included lung, liver, heart, brain, skeletal muscle, gonad, lymph nodes, blood, intestine, pancreas, spleen, and eye. Computed tomography performed on 4 animals also identified gas bubbles in various tissues. Mean +/- SD net lead line depths (m) were 92 +/- 44 and ascent rates (ms(-1)) 0.3 +/- 0.2 for affected animals and 76 +/- 33 and 0.2 +/- 0.1, respectively, for unaffected animals. The relatively good carcass condition of these cases, comparable to 2 stranded cases that showed no gas formation on computed tomography (even after 3 days of refrigeration in one case), along with the histologic absence of bacteria and autolytic changes, indicate that peri- or postmortem phase change of supersaturated blood and tissues is most likely. Studies have suggested that under some circumstances, diving mammals are routinely supersaturated and that these mammals presumably manage gas exchange and decompression anatomically and behaviorally. This study provides a unique illustration of such supersaturated tissues. We suggest that greater attention be paid to the radiology and pathology of bycatch mortality as a possible model to better understand gas bubble disease in marine mammals. C1 [Moore, M. J.; Bogomolni, A. L.; Early, G.] Woods Hole Oceanog Inst, Dept Biol, Woods Hole, MA 02543 USA. [Dennison, S. E.] Univ Wisconsin, Sch Vet Med, Dept Surg Sci Radiol, Madison, WI 53706 USA. [Garner, M. M.] NW ZooPath, Monroe, WA 98272 USA. [Hayward, B. A.; Lentell, B. J.] NOAA Fisheries, Woods Hole, MA 02543 USA. [Rotstein, D. S.] Univ Tennessee, NOAA Cooperat Ctr Marine Anim Hlth, Knoxville, TN 37996 USA. [Rotstein, D. S.] Univ Tennessee, Coll Vet Med, Knoxville, TN 37996 USA. RP Moore, MJ (reprint author), Woods Hole Oceanog Inst, Dept Biol, Mailstop 50, Woods Hole, MA 02543 USA. EM mmoore@whoi.edu RI Moore, Michael/E-1707-2015 OI Moore, Michael/0000-0003-3074-6631 FU NOAA [NA05NOS4781247, 939-1680-00]; Office of Naval Research Award [N00014-08-1-1220]; Woods Hole Oceanographic Institution Ocean Life Institute; MS Worthington Foundation; NOAA North East Region in Gloucester, MA, USA FX We thank the many fishermen and NOAA Fisheries Observers and Observer Program staff who went to great trouble to bring these animals ashore and the Cape Cod Stranding Network for the beach-stranded cases. We also thank our colleagues of the WHOI CT scanner facility, Darlene Ketten, Julie Arruda, and Scott Cramer. We thank the Histopathology Department at the University of Tennessee, College of Veterinary Medicine Histopathology Laboratory, in particular Dee Stephenson, and the North Carolina State College of Veterinary Medicine University Histopathology Laboratory. We also thank Judy St Leger and anonymous reviewers for valuable comments. This study was funded by NOAA Grant No. NA05NOS4781247, Office of Naval Research Award No. N00014-08-1-1220, Woods Hole Oceanographic Institution Ocean Life Institute, and the MS Worthington Foundation. Samples from bycatch were collected under NOAA Permit 939-1680-00 and from stranded animals by authorization of the NOAA North East Region in Gloucester, MA, USA. NR 41 TC 25 Z9 25 U1 1 U2 44 PU AMER COLL VET PATHOLOGIST PI LAWRENCE PA 810 EAST 10TH STREET, LAWRENCE, KS 66044 USA SN 0300-9858 J9 VET PATHOL JI Vet. Pathol. PD MAY PY 2009 VL 46 IS 3 BP 536 EP 547 DI 10.1354/vp.08-VP-0065-M-FL PG 12 WC Pathology; Veterinary Sciences SC Pathology; Veterinary Sciences GA 443JY UT WOS:000265907200023 PM 19176498 ER PT J AU Yoo, SJ Cypher, D Golmie, N AF Yoo, Sang-Jo Cypher, David Golmie, Nada TI Predictive link trigger mechanism for seamless handovers in heterogeneous wireless networks SO WIRELESS COMMUNICATIONS & MOBILE COMPUTING LA English DT Article DE seamless handover; link triggers; prediction; WLAN; WiMax; heterogeneous wireless networks ID CHALLENGES AB Effective and timely link-layer trigger mechanisms can significantly influence the handover performance. The handover process will not perform the correct decision and execution unless adequate and timely link-layer trigger information is delivered. In this paper, a predictive link trigger mechanism for seamless horizontal and vertical handovers in heterogeneous wireless networks is proposed. Unlike previous link trigger algorithms based on pre-defined signal level thresholds, the link layer triggers in this study are adaptively and timely fired in accordance with the network conditions. Firstly, the time required to perform a handover is estimated based on the neighboring network conditions. Secondly, the time to trigger a Link-Going-Down to initiate a handover is determined using a least mean square linear prediction in which the prediction interval (k(h)) is dynamically determined based oil the estimated handover time. An upper bound for the packet loss rate during a handover is derived for a Gaussian shadowing channel. A manner in which this approach can be applied to IEEE 802.21 is shown in media independent handover scenarios. Simulation results of the proposed predictive link triggering mechanism show that it provides a timely proactive handover. The packet loss rate observed in a Gaussian shadowing channel remains low during a handover. Copyright (c) 2008 John Wiley & Sons, Ltd. C, C1 [Yoo, Sang-Jo] Inha Univ, Inchon 402751, South Korea. [Cypher, David; Golmie, Nada] NIST, Gaithersburg, MD 20899 USA. RP Yoo, SJ (reprint author), Inha Univ, 253 Yonghyun Dong, Inchon 402751, South Korea. EM sjyoo@inha.ac.kr FU NIST/Office of Law Enforcement Standards (OLES) FX This research was supported by the NIST/Office of Law Enforcement Standards (OLES). NR 30 TC 16 Z9 17 U1 0 U2 2 PU JOHN WILEY & SONS INC PI HOBOKEN PA 111 RIVER ST, HOBOKEN, NJ 07030 USA SN 1530-8669 J9 WIREL COMMUN MOB COM JI Wirel. Commun. Mob. Comput. PD MAY PY 2009 VL 9 IS 5 BP 685 EP 703 DI 10.1002/wcm.620 PG 19 WC Computer Science, Information Systems; Engineering, Electrical & Electronic; Telecommunications SC Computer Science; Engineering; Telecommunications GA 436RA UT WOS:000265431200006 ER PT J AU Tapella, F Romero, MC Stevens, BG Buck, CL AF Tapella, Federico Carolina Romero, M. Stevens, Bradley G. Buck, C. Loren TI Substrate preferences and redistribution of blue king crab Paralithodes platypus glaucothoe and first crab on natural substrates in the laboratory SO JOURNAL OF EXPERIMENTAL MARINE BIOLOGY AND ECOLOGY LA English DT Article DE Habitat selection; Lithodids; Stock enhancement ID CALLINECTES-SAPIDUS MEGALOPAE; GULF-OF-MEXICO; HABITAT SELECTION; SETTLING BEHAVIOR; AMERICAN LOBSTER; NURSERY HABITATS; CARCINUS-MAENAS; SETTLEMENT; CAMTSCHATICUS; RECRUITMENT AB Despite the importance of blue king crab (BKC) to the Bering Sea fishery, there has been no detailed study of juvenile habitat preferences. Such information is critical for understanding life history and for development of stock enhancement programs. The aims of this study were to determine the natural substrata that glaucothoe prefer to settle on, and whether they or subsequent crab 1 stage (C1) redistribute to different habitats over time. A laboratory experiment was performed in 24 round containers divided in four equal quadrants each filled with one of the following natural substrata: beach sand, gravel, shells and cobble. Containers were assigned to 8 groups of 3 replicates each and were kept at similar to 6-8 degrees C. Twenty five glaucothoe were released in each container on day 0, and one group of three replicates was removed for examination at each of the following intervals: 24 h, 7,14, 21, 28, 35, 42 and 49 days. Numbers of swimming and settled specimens on each substrate and period were recorded. Glaucothoe began to settle immediately after being released since no swimming larvae were found during any sampling periods. Substrata complexity was important for the habitat selection and distribution of blue king crab glaucothoe and crab I stage. During the glaucothoe stage, beach sand was rejected and cobble, shell and gravel were chosen equally. After glaucothoe molted to crab 1 stage and became bigger, animals preferred cobble and shell instead of gravel and beach sand. Understanding habitat selection is useful not only for management of crab populations, but also for assessing the potential of various habitats for stock enhancement of blue king crabs. (C) 2009 Elsevier B.V. All rights reserved. C1 [Tapella, Federico; Carolina Romero, M.; Stevens, Bradley G.] Kodiak Fisheries Res Ctr, Alaska Fisheries Sci Ctr, Natl Marine Fisheries Serv, Kodiak, AK 99615 USA. [Buck, C. Loren] Univ Alaska Fairbanks, Sch Fisheries & Ocean Sci, Fishery Ind Technol Ctr, Kodiak, AK 99615 USA. RP Tapella, F (reprint author), CADIC, CONICET, Houssay 200,V9410CAB, Ushuaia, Tierra Fuego, Argentina. EM ftapella@gmail.com FU North Pacific Research Board (NPRB) [R0507] FX We are grateful to S. Persselin, S. Van Sant and K. Swiney for laboratory assistance and to those people from the Kodiak Fisheries Research Center (KFRC) and the Fishery Industrial Technology Center (FITC) for their friendly relationship with MCR and Fr. This project was supported by grant No R0507 from the North Pacific Research Board (NPRB) to CLB and BGS. We also wish to thank the University of Alaska Sea Grant Program for supplementary funding. MCR and Fr thank to Consejo Federal Pesquero and Gobierno of Tierra del Fuego from Argentina providing the air tickets from Ushuaia to Kodiak. [SS], [RH] and [ST]. NR 33 TC 20 Z9 22 U1 1 U2 19 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-0981 J9 J EXP MAR BIOL ECOL JI J. Exp. Mar. Biol. Ecol. PD APR 30 PY 2009 VL 372 IS 1-2 BP 31 EP 35 DI 10.1016/j.jembe.2009.02.003 PG 5 WC Ecology; Marine & Freshwater Biology SC Environmental Sciences & Ecology; Marine & Freshwater Biology GA 438JW UT WOS:000265552700004 ER PT J AU Pillsbury, NR Muller, CW Meerts, WL Plusquellic, DF Zwier, TS AF Pillsbury, Nathan R. Muller, Christian W. Meerts, W. Leo Plusquellic, David F. Zwier, Timothy S. TI Conformational Effects on Excitonic Interactions in a Prototypical H-Bonded Bichromophore: Bis(2-hydroxyphenyl)methane SO JOURNAL OF PHYSICAL CHEMISTRY A LA English DT Article ID GAS-PHASE; ELECTRONIC SPECTROSCOPY; ROTATIONAL ISOMERS; BUILDING-BLOCKS; PHENOL DIMER; MP2 ENERGY; SPECTRA; ISOMERIZATION; PREFERENCES; CRESOL AB Laser-induced fluorescence, single-vibronic level fluorescence (SVLF), UV hole burning, and fluorescence dip infrared (FDIR) spectroscopy have been carried out on bis-(2-hydroxyphenyl)methane in order to characterize the ground-state and first excited-state vibronic spectroscopy of this model flexible bichromophore. These studies identified the presence of two conformational isomers. The FDIR spectra in the OH-stretch region determine that conformer A is an OH center dot center dot center dot O H-bonded conformer, while conformer B is a doubly OH center dot center dot center dot pi H-bonded conformer with C(2) symmetry. High-resolution ultraviolet spectra (similar to 50 MHz resolution) of a series of vibronic bands of both conformers confirm and refine these assignments. The transition dipole moment (TDM) direction in conformer A is consistent with electronic excitation that is primarily localized on the donor phenol ring. A tentative assignment of the S(1) origin is made to a set of transitions similar to 400 cm(-1) above S(1). In conformer B, the TDM direction firmly establishes C(2) symmetry for the conformer in its S(1) state and establishes the electronic excitation as delocalized over the two rings, as the lower member of an excitonic pair. The S(2) state has not been clearly identified in the spectrum. Based on CIS calculations, the S(2) state is postulated to be several times weaker than S(1), making it difficult to identify, especially in the midst of overlap from vibronic bands due to conformer A. SVLF spectra show highly unusual vibronic intensity patterns, particularly in conformer B, which cannot be understood by simple harmonic Franck-Condon models, even in the presence of Duschinsky mixing. We postulate that these model flexible bichromophores have TDMs that are extraordinarily sensitive to the distance and orientation of the two aromatic rings, highlighting the need to map out the TDM surface and its dependence on the (up to) five torsional and bending coordinates in order to understand the observations. C1 [Plusquellic, David F.] Natl Inst Stand & Technol, Biophys Grp, Phys Lab, Gaithersburg, MD 20899 USA. [Meerts, W. Leo] Radboud Univ Nijmegen, Mol & Biophys Grp, Inst Mol & Mat, NL-6500 GL Nijmegen, Netherlands. [Pillsbury, Nathan R.; Muller, Christian W.; Zwier, Timothy S.] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA. RP Zwier, TS (reprint author), Natl Inst Stand & Technol, Biophys Grp, Phys Lab, Gaithersburg, MD 20899 USA. EM david.plusquellic@nist.gov; zwier@purdue.edu RI Meerts, W. Leo/B-6172-2008 OI Meerts, W. Leo/0000-0001-6457-3797 FU Department of Energy Basic Energy Sciences; Division of Chemical Sciences [DE-FG02-96ER14656]; "Deutsche Akademie der Naturforscher Leopoldina" [BMBF-LPD 9901/8-159] FX This work was supported by the Department of Energy Basic Energy Sciences, Division of Chemical Sciences under Grant No. DE-FG02-96ER14656. D.F.P. would like to express thanks to Kevin O. Douglass for providing us with the MW data. N.R.P. acknowledges Purdue University and the Andrews family for the Frederick N. Andrews Fellowship. C.W.M. would like to thank the "Deutsche Akademie der Naturforscher Leopoldina" for a postdoctoral scholarship (grant number BMBF-LPD 9901/8-159 of the "Bundesministerium fur Bildung und Forschung"). NR 55 TC 19 Z9 19 U1 1 U2 15 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1089-5639 J9 J PHYS CHEM A JI J. Phys. Chem. A PD APR 30 PY 2009 VL 113 IS 17 BP 5000 EP 5012 DI 10.1021/jp8098686 PG 13 WC Chemistry, Physical; Physics, Atomic, Molecular & Chemical SC Chemistry; Physics GA 438BB UT WOS:000265529800026 PM 19348452 ER PT J AU Nikoobakht, B Eustis, S Herzing, A AF Nikoobakht, Babak Eustis, Susie Herzing, Andrew TI Strain-Driven Growth of Zinc Oxide Nanowires on Sapphire: Transition from Horizontal to Standing Growth SO JOURNAL OF PHYSICAL CHEMISTRY C LA English DT Article ID EPITAXY; ZNO; DEVICES AB Recently, we showed large-scale fabrication of field-effect transistors from horizontal ZnO nanowires (NWs) on a-plane sapphire. Here, in examining the cross sections of such nanodevices, we use high-resolution transmission electron microscopy (HRTEM) and large-angle, convergent-beam electron diffraction (LACBED). We show how horizontally grown ZnO NWs influence their underlying sapphire surface and how substrate influences the growth directionality of the NWs. As a NW grows on sapphire, the substrate experiences a compressive strain of approximate to 7% in its [0001](sap) direction (along the width of a NW) to minimize its lattice mismatch with the ZnO NW. Accordingly, ZnO expands along its width to improve its lattice match with the sapphire. The growth direction of (1 (1) over bar 00) is suggested to be the direction that produces a lower lattice strain between ZnO and sapphire. Analyses of NW/sapphire interfaces show that single-crystal NWs grow epitaxially and semicoherently with many fewer misfit dislocations than theoretically expected. We attribute the formation of fewer dislocations at the interface to local relaxation of zinc oxide strain into the sapphire surface. This relaxation is in agreement with the observed deformation of the sapphire underneath the NWs. We also define a critical NW thickness beyond which the growth mode changes from horizontal to standing. Results indicate that below this thickness, gold nanodroplets partially wet both sapphire and ZnO crystals. Above the critical thickness, gold preferentially wets the ZnO nanocrystal, and formation of misfit dislocations at the interface becomes energetically favorable. Combination of these two effects is used to explain the observed change in the growth modes of the NWs. C1 [Nikoobakht, Babak] NIST, Surface & Microanal Sci Div, Gaithersburg, MD 20899 USA. RP Nikoobakht, B (reprint author), NIST, Surface & Microanal Sci Div, 100 Bureau Dr Stop 8372, Gaithersburg, MD 20899 USA. EM babakn@nist.gov RI Herzing, Andrew/D-6239-2012 NR 25 TC 18 Z9 18 U1 4 U2 17 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1932-7447 J9 J PHYS CHEM C JI J. Phys. Chem. C PD APR 30 PY 2009 VL 113 IS 17 BP 7031 EP 7037 DI 10.1021/jp810831z PG 7 WC Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary SC Chemistry; Science & Technology - Other Topics; Materials Science GA 438BA UT WOS:000265529700024 ER PT J AU Laurenza, M Cliver, EW Hewitt, J Storini, M Ling, AG Balch, CC Kaiser, ML AF Laurenza, M. Cliver, E. W. Hewitt, J. Storini, M. Ling, A. G. Balch, C. C. Kaiser, M. L. TI A technique for short-term warning of solar energetic particle events based on flare location, flare size, and evidence of particle escape SO SPACE WEATHER-THE INTERNATIONAL JOURNAL OF RESEARCH AND APPLICATIONS LA English DT Article ID CORONAL MASS EJECTIONS; III RADIO-BURSTS; X-RAY FLARES; PROTON EVENTS; MICROWAVE BURSTS; ACCELERATION; EMISSION; ELECTRON; DENSITY; SHOCKS AB We have developed a technique to provide short-term warnings of solar energetic proton (SEP) events that meet or exceed the Space Weather Prediction Center threshold of J (>10 MeV) = 10 pr cm(-2) s(-1) sr(-1). The method is based on flare location, flare size, and evidence of particle acceleration/escape as parameterized by flare longitude, time-integrated soft X-ray intensity, and time-integrated intensity of type III radio emission at similar to 1 MHz, respectively. In this technique, warnings are issued 10 min after the maximum of >= M2 soft X-ray flares. For the solar cycle 23 (1995-2005) data on which it was developed, the method has a probability of detection of 63% (47/75), a false alarm rate of 42% (34/81), and a median warning time of similar to 55 min for the 19 events successfully predicted by our technique for which SEP event onset times were provided by Posner (2007). These measures meet or exceed verification results for competing automated SEP warning techniques but, at the present stage of space weather forecasting, fall well short of those achieved with a human (aided by techniques such as ours) making the ultimate yes/no SEP event prediction. We give some suggestions as to how our method could be improved and provide our flare and SEP event database in the auxiliary material to facilitate quantitative comparisons with techniques developed in the future. C1 [Laurenza, M.; Storini, M.] INAF, Inst Interplanetary Space Phys, I-00133 Rome, Italy. [Balch, C. C.] NOAA, Space Weather Predict Ctr, Boulder, CO 80305 USA. [Cliver, E. W.; Hewitt, J.] AFRL, Space Vehicles Directorate, Hanscom AFB, MA 01731 USA. [Ling, A. G.] Atmospher Environm Res Inc, Lexington, MA 02421 USA. [Kaiser, M. L.] NASA, Goddard Space Flight Ctr, Greenbelt, MD 20771 USA. RP Laurenza, M (reprint author), INAF, Inst Interplanetary Space Phys, Via Fosso Cavaliere 100, I-00133 Rome, Italy. EM monica.laurenza@ifsi-roma.inaf.it FU ASI [I/090/06/0]; European Office of Aerospace Research and Development FX Part of the work by M. L. and M. S. was performed under COST 724 Action and part under the ASI contract I/090/06/0. E. W. C. was supported through the Window on Europe program of the European Office of Aerospace Research and Development. We acknowledge a helpful discussion with Kent Doggett of the SWPC. NR 71 TC 28 Z9 28 U1 0 U2 1 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 1542-7390 J9 SPACE WEATHER JI Space Weather PD APR 30 PY 2009 VL 7 AR S04008 DI 10.1029/2007SW000379 PG 18 WC Astronomy & Astrophysics; Geochemistry & Geophysics; Meteorology & Atmospheric Sciences SC Astronomy & Astrophysics; Geochemistry & Geophysics; Meteorology & Atmospheric Sciences GA 440CQ UT WOS:000265676400001 ER PT J AU Skripov, AV Udovic, TJ Cook, JC Hempelmann, R Rempel, AA Gusev, AI AF Skripov, A. V. Udovic, T. J. Cook, J. C. Hempelmann, R. Rempel, A. A. Gusev, A. I. TI Quasielastic neutron scattering study of hydrogen motion in NbC0.71H0.28 SO JOURNAL OF PHYSICS-CONDENSED MATTER LA English DT Article ID CARBOHYDRIDES; DIFFRACTION AB In order to study the mechanism and parameters of H jump motion in the nonstoichiometric Nb carbides, we have performed quasielastic neutron scattering (QENS) measurements for NbC0.71H0.28 over the temperature range 11-475 K. Our results indicate that about 30% of H atoms in this system participate in a fast diffusive motion. The temperature dependence of the corresponding H jump rate in the range 298-475 K follows the Arrhenius law with an activation energy of 328 +/- 9 meV. The Q dependence of the QENS data suggests that the observed jump motion corresponds to long-range diffusion of H atoms along chains of the off-centre sites in carbon vacancies. C1 [Skripov, A. V.] Russian Acad Sci, Inst Met Phys, Ural Div, Ekaterinburg 620041, Russia. [Udovic, T. J.; Cook, J. C.] NIST, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Hempelmann, R.] Univ Saarland, Inst Phys Chem, D-66041 Saarbrucken, Germany. [Rempel, A. A.; Gusev, A. I.] Russian Acad Sci, Ural Div, Inst Solid State Chem, Ekaterinburg 620041, Russia. RP Skripov, AV (reprint author), Russian Acad Sci, Inst Met Phys, Ural Div, Ekaterinburg 620041, Russia. RI Skripov, Alexander/K-4525-2013 OI Skripov, Alexander/0000-0002-0610-5538 FU National Science Foundation [DMR-0454672]; NATO Linkage [HTECH LG 973890]; Russian Foundation for Basic Research [09-02-00159, 09-03-00010]; Russian Academy of Sciences; Ural Division of the Russian Academy of Sciences FX The authors are grateful to J Combet for assistance with the measurements at ILL. This work utilized facilities supported in part by the National Science Foundation under agreement no. DMR-0454672. This work was also supported by the NATO Linkage grant no. HTECH LG 973890, the Russian Foundation for Basic Research (grant nos. 09-02-00159 and 09-03-00010), the Priority Programme 'Basics of Development of Energy Systems and Technologies' of the Russian Academy of Sciences and the Interdisciplinary Project 'Short- and Long-Range Order in Nonstoichiometric Transition Metal Carbides, Carbohydrides and Oxides: Neutron Scattering and Nuclear Magnetic Resonance' of the Ural Division of the Russian Academy of Sciences. NR 16 TC 1 Z9 1 U1 0 U2 3 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0953-8984 J9 J PHYS-CONDENS MAT JI J. Phys.-Condes. Matter PD APR 29 PY 2009 VL 21 IS 17 AR 175410 DI 10.1088/0953-8984/21/17/175410 PG 5 WC Physics, Condensed Matter SC Physics GA 427LD UT WOS:000264779900023 PM 21825425 ER PT J AU Dudowicz, J Douglas, JF Freed, KF AF Dudowicz, Jacek Douglas, Jack F. Freed, Karl F. TI Equilibrium polymerization models of re-entrant self-assembly SO JOURNAL OF CHEMICAL PHYSICS LA English DT Article ID AQUEOUS-SOLUTIONS; ACTIN POLYMERIZATION; PHASE-SEPARATION; PEG AB As is well known, liquid-liquid phase separation can occur either upon heating or cooling, corresponding to lower and upper critical solution phase boundaries, respectively. Likewise, self-assembly transitions from a monomeric state to an organized polymeric state can proceed either upon increasing or decreasing temperature, and the concentration dependent ordering temperature is correspondingly called the "floor" or "ceiling" temperature. Motivated by the fact that some phase separating systems exhibit closed loop phase boundaries with two critical points, the present paper analyzes self-assembly analogs of re-entrant phase separation, i.e., re-entrant self-assembly. In particular, re-entrant self-assembly transitions are demonstrated to arise in thermally activated equilibrium self-assembling systems, when thermal activation is more favorable than chain propagation, and in equilibrium self-assembly near an adsorbing boundary where strong competition exists between adsorption and self-assembly. Apparently, the competition between interactions or equilibria generally underlies re-entrant behavior in both liquid-liquid phase separation and self-assembly transitions. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3118671] C1 [Dudowicz, Jacek; Freed, Karl F.] Univ Chicago, James Franck Inst, Chicago, IL 60637 USA. [Dudowicz, Jacek; Freed, Karl F.] Univ Chicago, Dept Chem, Chicago, IL 60637 USA. [Douglas, Jack F.] NIST, Div Polymers, Gaithersburg, MD 20899 USA. RP Dudowicz, J (reprint author), Univ Chicago, James Franck Inst, 5640 S Ellis Ave, Chicago, IL 60637 USA. EM dudowicz@jfi.uchicago.edu; jack.douglas@nist.gov; freed@uchicago.edu FU NSF [CHE-0749788] FX We thank Sandra Greer for helpful discussions. This research was supported, in part, by the NSF under Grant No. CHE-0749788. NR 31 TC 13 Z9 13 U1 0 U2 5 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 0021-9606 J9 J CHEM PHYS JI J. Chem. Phys. PD APR 28 PY 2009 VL 130 IS 16 AR 164905 DI 10.1063/1.3118671 PG 8 WC Chemistry, Physical; Physics, Atomic, Molecular & Chemical SC Chemistry; Physics GA 456XD UT WOS:000266885200075 PM 19405628 ER PT J AU Kubyshkina, M Sergeev, V Tsyganenko, N Angelopoulos, V Runov, A Singer, H Glassmeier, KH Auster, HU Baumjohann, W AF Kubyshkina, M. Sergeev, V. Tsyganenko, N. Angelopoulos, V. Runov, A. Singer, H. Glassmeier, K. H. Auster, H. U. Baumjohann, W. TI Toward adapted time-dependent magnetospheric models: A simple approach based on tuning the standard model SO JOURNAL OF GEOPHYSICAL RESEARCH-SPACE PHYSICS LA English DT Article ID INTERPLANETARY MAGNETIC-FIELD; WIND DYNAMIC PRESSURE; DAWN-DUSK ASYMMETRY; Y-COMPONENT; CONFIGURATION; MAGNETOTAIL; SPACECRAFT; ALGORITHM; GROWTH; PHASE AB We suggest and test a simple procedure to adapt a magnetic field model by fitting it to observations made simultaneously by several spacecraft. This is done by varying input parameters of a standard model (T96) to find the best fit to the observed field at each time step. As a result we obtain a time-dependent model which can be used for evaluating the quality of the standard model and of the mapping at any particular time, to navigate in the magnetosphere and reproduce its variable configuration during large-scale dynamical events. This procedure was tested using observations made by five Time History of Events and Macroscale Interactions during Substorms (THEMIS) and other complementary ( e. g., GOES) spacecraft during the tail season of THEMIS mission (January-March 2008), for which a simplest version of the adapted model was routinely calculated and has been made publicly available. We also use the proton isotropic boundaries observed by low-altitude NOAA spacecraft for independent evaluation of the obtained field models. We found that in quiet conditions deviations of ionospheric footprints between standard and adapted models are generally small ( within 1 degrees of latitude), whereas during substorms they may be as large as several degrees, because of stretching and dipolarizations of magnetospheric configuration. We found that the variable tilt of the tail current sheet, partly caused by variations of nonradial component of the solar wind flow, is an additional important factor influencing the modeling result and the mapping quality. By analyzing the adapted models constructed at the time of auroral breakup onset, we conclude that this simple approach is not yet sufficiently accurate to evaluate the source distance in the magnetotail. C1 [Kubyshkina, M.; Sergeev, V.; Tsyganenko, N.] St Petersburg State Univ, Inst Phys, St Petersburg 198504, Russia. [Angelopoulos, V.; Runov, A.] Univ Calif Los Angeles, Inst Geophys & Planetary Phys, Los Angeles, CA 90095 USA. [Glassmeier, K. H.; Auster, H. U.] Tech Univ Carolo Wilhelmina Braunschweig, Inst Geophys & Extraterrestr Phys, D-38106 Braunschweig, Germany. [Baumjohann, W.] Austrian Acad Sci, Space Res Inst, A-8042 Graz, Austria. [Singer, H.] NOAA, Space Weather Predict Ctr, Boulder, CO 80305 USA. RP Kubyshkina, M (reprint author), St Petersburg State Univ, Inst Phys, St Petersburg 198504, Russia. EM kubysh@geo.phys.spbu.ru RI Baumjohann, Wolfgang/A-1012-2010; Tsyganenko, Nikolai/J-7377-2012; Kubyshkina, Marina/G-9436-2013; Sergeev, Victor/H-1173-2013 OI Baumjohann, Wolfgang/0000-0001-6271-0110; Tsyganenko, Nikolai/0000-0002-5938-1579; Kubyshkina, Marina/0000-0001-5897-9547; Sergeev, Victor/0000-0002-4569-9631 FU THEMIS [NAS5-02099]; Russian Ministry of Science grants; RFBR [0702-91703, 07-05-91109]; CRDF [2861] FX The energetic particles observations on board the polar NOAA spacecraft have been made available by NOAA, and solar wind observations from Wind spacecraft have been made available via CDAWeb and OMNI Web sites. We thank Amanda Prentice for her help in preparing the manuscript. The work was supported by the THEMIS contract NAS5-02099. The work by V. S. and M. K. was also supported by Russian Ministry of Science grants, by the RFBR grants 0702-91703 and 07-05-91109, and CRDF grant 2861. We thank both referees for fruitful discussion and help in evaluating the manuscript. NR 27 TC 38 Z9 38 U1 0 U2 3 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0148-0227 J9 J GEOPHYS RES-SPACE JI J. Geophys. Res-Space Phys. PD APR 28 PY 2009 VL 114 AR A00C21 DI 10.1029/2008JA013547 PG 15 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA 440CI UT WOS:000265675600001 ER PT J AU Ding, YF Pawlus, S Sokolov, AP Douglas, JF Karim, A Soles, CL AF Ding, Yifu Pawlus, Sebastian Sokolov, Alexei P. Douglas, Jack F. Karim, Alamgir Soles, Christopher L. TI Dielectric Spectroscopy Investigation of Relaxation in C-60-Polyisoprene Nanocomposites SO MACROMOLECULES LA English DT Article ID THIN POLYMER-FILMS; CIS-POLYISOPRENE; TEMPERATURE-DEPENDENCE; PRESSURE-DEPENDENCE; GLASS-TRANSITION; CHAIN DYNAMICS; MIXTURES; C-60; PHOTOLUMINESCENCE; NANOPARTICLES AB We investigate the influence of adding C-60 nanoparticles on the dielectric relaxation spectra of both unentangled and entangled polyisoprene (PIP). Relaxation modes corresponding to both the segmental and chain relaxation were analyzed over a broad temperature and frequency range. Regardless of whether the chains were entangled or not, both relaxation processes slowed down with the addition of C-60, reflecting an increase of the nanocomposite glass transition temperature. However, C-60 affects the segmental relaxation more strongly than the large-scale chain relaxation, both in terms of the relaxation time and strength, suggesting that the effect of the nanoparticles on the polymer dynamics is scale dependent. This effect is attributed to a difference in packing frustration at different length scales, a phenomenon also relevant to understanding the difference between the temperature dependence of the segmental and chain relaxation processes in neat polymer materials. Further evidence of this scale dependence is indicated by the observation that the secondary relaxation time of the high molecular mass PIP decreases with an addition of C-60. These observations indicate that C-60 has an effect opposite to antiplasticizing additives that slow down the secondary relaxation (stiffening the material) in the glass state, while at the same time reducing the alpha relaxation time associated with cooperative segmental and chain motions. Recent incoherent neutron scattering measurements have indicated that C-60 can have a similar effect on polystyrene. C1 [Ding, Yifu] Univ Colorado, Dept Mech Engn, Boulder, CO 80309 USA. [Pawlus, Sebastian; Sokolov, Alexei P.] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA. [Pawlus, Sebastian] Univ Silesia, Inst Phys, PL-40007 Katowice, Poland. [Douglas, Jack F.; Karim, Alamgir; Soles, Christopher L.] Natl Inst Stand & Technol, Div Polymers, Gaithersburg, MD 20899 USA. RP Ding, YF (reprint author), Univ Colorado, Dept Mech Engn, Boulder, CO 80309 USA. EM yifu.ding@colorado.edu; jack.douglas@nist.gov FU FNP HOMING program [2008]; European Economic Area Financial Mechanism; NSF; University of Colorado at Boulder; National Institute of Standards and Technology FX S.P. acknowledges the financial assistance from FNP HOMING program (2008) supported by the European Economic Area Financial Mechanism. A.P.S. thanks the NSF for financial support. Y.D. acknowledges the startup funding support from University of Colorado at Boulder. Certain commercial materials and equipment are identified in this paper in order to specify adequately the experimental procedure. In no case does such identification imply recommendation by the National Institute of Standards and Technology nor does it imply that the material or equipment identified is necessarily the best available for this purpose. NR 63 TC 26 Z9 26 U1 3 U2 28 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0024-9297 J9 MACROMOLECULES JI Macromolecules PD APR 28 PY 2009 VL 42 IS 8 BP 3201 EP 3206 DI 10.1021/ma8024333 PG 6 WC Polymer Science SC Polymer Science GA 436JW UT WOS:000265411400045 ER PT J AU Wong-Ng, W Otani, M Levin, I Schenck, P Yang, Z Liu, G Cook, LP Feenstra, R Zhang, W Rupich, MW AF Wong-Ng, W. Otani, M. Levin, I. Schenck, P. Yang, Z. Liu, G. Cook, L. P. Feenstra, R. Zhang, W. Rupich, M. W. TI A phase relation study of Ba-Y-Cu-O coated-conductor films using the combinatorial approach SO APPLIED PHYSICS LETTERS LA English DT Article DE annealing; barium compounds; flux pinning; high-temperature superconductors; reaction kinetics; superconducting thin films; yttrium compounds ID THIN-FILMS; SUPERCONDUCTORS; DEPOSITION; PROGRESS; GROWTH; SYSTEM AB Phase relationships in bulk and thin film Ba-Y-Cu-O high-T(c) superconductor system were determined at processing conditions relevant for industrial production of coated conductors. Our results demonstrated that the absence of BaY(2)CuO(5) (which has a critical effect on flux pinning) at 735 degrees C-a typical temperature employed in production of coated conductors-in thin films processed in situ from the BaF(2) precursor is caused by the sluggish reaction kinetics rather than by the presence of fluorine in the system. Thermodynamic calculations combined with annealing experiments confirmed that BaY(2)CuO(5) is thermodynamically stable but forms at temperatures higher than 735 degrees C. C1 [Wong-Ng, W.; Otani, M.; Levin, I.; Schenck, P.; Yang, Z.; Liu, G.; Cook, L. P.] NIST, Div Ceram, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA. [Feenstra, R.] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA. [Zhang, W.; Rupich, M. W.] Amer Superconductor Corp, Westborough, MA 01581 USA. RP Wong-Ng, W (reprint author), NIST, Div Ceram, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA. EM winnie.wong-ng@nist.gov RI Levin, Igor/F-8588-2010 FU U.S. Department of Energy FX This work was partially supported by the U.S. Department of Energy. NR 21 TC 4 Z9 5 U1 0 U2 7 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 0003-6951 J9 APPL PHYS LETT JI Appl. Phys. Lett. PD APR 27 PY 2009 VL 94 IS 17 AR 171910 DI 10.1063/1.3127222 PG 3 WC Physics, Applied SC Physics GA 440ZP UT WOS:000265738700029 ER PT J AU Easterling, DR Wehner, MF AF Easterling, David R. Wehner, Michael F. TI Is the climate warming or cooling? SO GEOPHYSICAL RESEARCH LETTERS LA English DT Article AB Numerous websites, blogs and articles in the media have claimed that the climate is no longer warming, and is now cooling. Here we show that periods of no trend or even cooling of the globally averaged surface air temperature are found in the last 34 years of the observed record, and in climate model simulations of the 20(th) and 21(st) century forced with increasing greenhouse gases. We show that the climate over the 21(st) century can and likely will produce periods of a decade or two where the globally averaged surface air temperature shows no trend or even slight cooling in the presence of longer-term warming. Citation: Easterling, D. R., and M. F. Wehner (2009), Is the climate warming or cooling?, Geophys. Res. Lett., 36, L08706, doi: 10.1029/2009GL037810. C1 [Easterling, David R.] NOAA, Natl Climat Data Ctr, Asheville, NC 28801 USA. [Wehner, Michael F.] Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA. RP Easterling, DR (reprint author), NOAA, Natl Climat Data Ctr, 151 Pattom Ave, Asheville, NC 28801 USA. EM david.easterling@noaa.gov; mfwehner@lbl.gov FU Climate Change Prediction Program; Office of Science; U.S. Department of Energy; Office of Biological and Environmental Sciences; U.S. Department of Energy [DE-AI02-96ER62276] FX We acknowledge the modeling groups, the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and the World Climate Research Program's (WCRP) Working Group on Coupled Modeling (WGCM) for their roles in making available the WCRP CMIP3 multi-model dataset. Support of this dataset and support for this analysis is provided by the Climate Change Prediction Program, Office of Science, and the U.S. Department of Energy. Additional support to DRE was provided by the Office of Biological and Environmental Sciences, U.S. Department of Energy under Interagency Agreement DE-AI02-96ER62276. NR 6 TC 193 Z9 210 U1 6 U2 77 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0094-8276 J9 GEOPHYS RES LETT JI Geophys. Res. Lett. PD APR 25 PY 2009 VL 36 AR L08706 DI 10.1029/2009GL037810 PG 3 WC Geosciences, Multidisciplinary SC Geology GA 438CT UT WOS:000265534200004 ER PT J AU Henson, SA Dunne, JP Sarmiento, JL AF Henson, Stephanie A. Dunne, John P. Sarmiento, Jorge L. TI Decadal variability in North Atlantic phytoplankton blooms SO JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS LA English DT Article ID PLANKTON RECORDER SURVEY; LONG-TERM; CALANUS-FINMARCHICUS; INTERANNUAL VARIABILITY; REGIME SHIFT; SPRING BLOOM; CLIMATE; OCEAN; SEA; OSCILLATION AB The interannual to decadal variability in the timing and magnitude of the North Atlantic phytoplankton bloom is examined using a combination of satellite data and output from an ocean biogeochemistry general circulation model. The timing of the bloom as estimated from satellite chlorophyll data is used as a novel metric for validating the model's skill. Maps of bloom timing reveal that the subtropical bloom begins in winter and progresses northward starting in May in subpolar regions. A transition zone, which experiences substantial interannual variability in bloom timing, separates the two regions. Time series of the modeled decadal (1959-2004) variability in bloom timing show no long-term trend toward earlier or delayed blooms in any of the three regions considered here. However, the timing of the subpolar bloom does show distinct decadal- scale periodicity, which is found to be correlated with the North Atlantic Oscillation (NAO) index. The mechanism underpinning the relationship is identified as anomalous wind-driven mixing conditions associated with the NAO. In positive NAO phases, stronger westerly winds result in deeper mixed layers, delaying the start of the subpolar spring bloom by 2-3 weeks. The subpolar region also expands during positive phases, pushing the transition zone further south in the central North Atlantic. The magnitude of the bloom is found to be only weakly dependent on bloom timing, but is more strongly correlated with mixed layer depth. The extensive interannual variability in the timing of the bloom, particularly in the transition region, is expected to strongly impact the availability of food to higher trophic levels. C1 [Henson, Stephanie A.; Sarmiento, Jorge L.] Princeton Univ, Atmospher & Ocean Sci Program, Princeton, NJ 08544 USA. [Dunne, John P.] NOAA, Geophys Fluid Dynam Lab, Princeton, NJ 08544 USA. RP Henson, SA (reprint author), Princeton Univ, Atmospher & Ocean Sci Program, Princeton, NJ 08544 USA. EM shenson@princeton.edu RI Dunne, John/F-8086-2012 OI Dunne, John/0000-0002-8794-0489 FU NASA [NNG06GE77G] FX SeaWiFS data were provided by GSFC/NASA in accordance with the SeaWiFS Research Data Use Terms and Conditions Agreement. Argo float data were collected and made freely available by the International Argo Project and supplied by the Coriolis project. NAO index data were provided by the Climate Analysis Section, NCAR, Boulder. This work was funded by NASA grant NNG06GE77G to J. L. S. NR 66 TC 101 Z9 103 U1 5 U2 40 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-9275 EI 2169-9291 J9 J GEOPHYS RES-OCEANS JI J. Geophys. Res.-Oceans PD APR 25 PY 2009 VL 114 AR C04013 DI 10.1029/2008JC005139 PG 11 WC Oceanography SC Oceanography GA 438DX UT WOS:000265537200009 ER PT J AU Jin, MB Deal, C Wang, J McRoy, CP AF Jin, Meibing Deal, Clara Wang, Jia McRoy, C. Peter TI Response of lower trophic level production to long-term climate change in the southeastern Bering Sea SO JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS LA English DT Article ID SPRING PHYTOPLANKTON DYNAMICS; NORTH PACIFIC; MARINE ECOSYSTEM; MIDDLE SHELF; ICE-EDGE; VARIABILITY; OCEAN; REGIME; GROWTH; BLOOM AB The Bering Sea ecosystem has undergone profound changes in response to climate regime shifts in the past decades. Here, lower trophic level production is assessed with a vertically one-dimensional (1-D) coupled ice-ocean ecosystem model, which was applied to data collected by a National Oceanic and Atmospheric Administration (NOAA)/Pacific Marine Environmental Laboratory (PMEL) mooring from 1995 to 2005. The physical model is forced by sea surface winds, heat and salt fluxes, tides, and sea ice. The biological model includes coupled pelagic and ice algae components. Model results are validated with daily mooring temperature, fluorometer, and daily Sea-viewing Wide Field-of-view Sensor (SeaWiFS) chlorophyll data. Two distinct ocean conditions and phytoplankton bloom patterns are related to the Pacific Decadal Oscillation (PDO) Index regimes: warmer temperature and later warm-water phytoplankton species bloom in PDO > 1 year; colder temperature and earlier cold-water phytoplankton species bloom in PDO < -1 year. Productivity of different phytoplankton species changed dramatically after the 1976 climate shift, but the total annual net primary production (NPP) remained flat over the past four decades under similar nutrient regulation. Climate shift also affected the vertical distribution of lower trophic level production and energy flow to the upper ocean pelagic ecosystem or the benthic community. A long-term PDO regime shift occurred in 1976, and a short-term PDO reversal occurred in 1998. Phytoplankton biomass responded promptly to both short- and long-term climate changes. Zooplankton biomass responded more to the long-term than to the short- term climate shift. The model results captured observed trends of zooplankton abundance changes from the 1990s to 2004. C1 [Jin, Meibing; Deal, Clara; McRoy, C. Peter] Univ Alaska Fairbanks, Int Arct Res Ctr, Fairbanks, AK 99775 USA. [Wang, Jia] NOAA, Great Lakes Environm Res Lab, Ann Arbor, MI 48108 USA. RP Jin, MB (reprint author), Univ Alaska Fairbanks, Int Arct Res Ctr, 930 Koyukuk Dr, Fairbanks, AK 99775 USA. EM ffjm@uaf.edu RI Jin, Meibing/F-7666-2010 FU North Pacific Research Board (NPRB) [607]; JAMSTEC-IARC Research Agreement; NSF [ARC-0652838] FX We are grateful to Phyllis Stabeno and Sigrid Sallo, PMEL/NOAA, Seattle, Washington, for providing the M2 buoy and mooring data. This study was supported by North Pacific Research Board (NPRB) grant 607 awarded to Jin, Deal, and Wang. The International Arctic Research Center, University of Alaska Fairbanks, supported this study through the JAMSTEC-IARC Research Agreement and NSF ARC-0652838. This is NPRB contribution 194 and NOAA GLERL contribution 1494. NR 39 TC 18 Z9 18 U1 3 U2 13 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-9275 EI 2169-9291 J9 J GEOPHYS RES-OCEANS JI J. Geophys. Res.-Oceans PD APR 25 PY 2009 VL 114 AR C04010 DI 10.1029/2008JC005105 PG 10 WC Oceanography SC Oceanography GA 438DX UT WOS:000265537200008 ER PT J AU Veneziani, M Edwards, CA Doyle, JD Foley, D AF Veneziani, M. Edwards, C. A. Doyle, J. D. Foley, D. TI A central California coastal ocean modeling study: 1. Forward model and the influence of realistic versus climatological forcing SO JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS LA English DT Article ID WIND STRESS CURL; CURRENT SYSTEM; SURFACE CIRCULATION; NORTHERN CALIFORNIA; DYNAMICS EXPERIMENT; BULK PARAMETERIZATION; PRESSURE-GRADIENT; SHELF CIRCULATION; DATA ASSIMILATION; UPWELLING JET AB We report on a numerical simulation of the California Current circulation using the Regional Ocean Modeling System model, focusing on the region of northern and central California during the 5-year period from 2000 to 2004. Unlike previous model studies of the California Current System, the present configuration is characterized by both realistic external forcing and a spatial domain covering most of the North American West Coast. Specifically, this configuration is driven at the surface by high-resolution meteorological fields from the Coupled Ocean-Atmosphere Mesoscale Prediction System and at the lateral open boundaries by output from the project Estimating the Circulation and Climate of the Ocean supported by the Global Ocean Data Assimilation Experiment. The simulation is evaluated favorably through quantitative comparisons with the California Cooperative Fisheries Investigations data set, satellite-derived sea surface temperature, and surface drifters-derived eddy kinetic energy. The impact of adopting realistic versus climatological surface forcing is demonstrated by comparing mean and mesoscale circulation characteristics. Realistic surface forcing qualitatively alters the seasonal cycle of the mean along shore jet and better reproduces the summer spatial structure and intensity of the eddy kinetic energy field along the central California coast. C1 [Veneziani, M.; Edwards, C. A.] Univ Calif Santa Cruz, Ocean Sci Dept, Santa Cruz, CA 95064 USA. [Doyle, J. D.] USN, Res Lab, Monterey, CA 93943 USA. [Foley, D.] NOAA, Div Environm Res, SW Fisheries Sci Ctr, Pacific Grove, CA 93950 USA. RP Veneziani, M (reprint author), Univ Calif Santa Cruz, Ocean Sci Dept, Santa Cruz, CA 95064 USA. EM milena@ucsc.edu FU National Oceanographic Partnership Program (NOPP); NOPP [NA05NOS4731242] FX The authors wish to thank Patrick Heimbach for his helpful comments on the paper and Gregoire Broquet and Enrique Curchitser for useful scientific discussions. The ECCO-GODAE data was provided by the ECCO Consortium for Estimating the Circulation and Climate of the Ocean funded by the National Oceanographic Partnership Program (NOPP). This research was funded by NOPP project NA05NOS4731242. NR 72 TC 32 Z9 32 U1 1 U2 3 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-9275 J9 J GEOPHYS RES-OCEANS JI J. Geophys. Res.-Oceans PD APR 25 PY 2009 VL 114 AR C04015 DI 10.1029/2008JC004774 PG 16 WC Oceanography SC Oceanography GA 438DX UT WOS:000265537200002 ER PT J AU Meiser, D Ye, J Carlson, DR Holland, MJ AF Meiser, D. Ye, Jun Carlson, D. R. Holland, M. J. TI Prospects for a Millihertz-Linewidth Laser SO PHYSICAL REVIEW LETTERS LA English DT Article ID CAVITY; STATISTICS; METROLOGY; CLOCKS AB We propose a new light source based on having alkaline-earth atoms in an optical lattice collectively emit photons on an ultranarrow clock transition into the mode of a high Q resonator. The resultant optical radiation has an extremely narrow linewidth in the mHz range, even smaller than that of the clock transition itself due to collective effects. A power level of order 10(-12) W is possible, sufficient for phase locking a slave optical local oscillator. Realizing this light source has the potential to improve the stability of the best clocks by 2 orders of magnitude. C1 [Meiser, D.] Univ Colorado, Natl Inst Stand & Technol, JILA, Boulder, CO 80309 USA. Univ Colorado, Dept Phys, Boulder, CO 80309 USA. RP Meiser, D (reprint author), Univ Colorado, Natl Inst Stand & Technol, JILA, Boulder, CO 80309 USA. RI Ye, Jun/C-3312-2011; OI Carlson, David/0000-0002-0067-2400 FU DFG; DARPA; NIST; DOE; NSF FX We gratefully acknowledge stimulating discussions with D. Kleppner, J. K. Thompson, and J. Cooper. This work was supported by DFG, DARPA, NIST, DOE, and NSF. NR 23 TC 102 Z9 105 U1 1 U2 13 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 0031-9007 J9 PHYS REV LETT JI Phys. Rev. Lett. PD APR 24 PY 2009 VL 102 IS 16 AR 163601 DI 10.1103/PhysRevLett.102.163601 PG 4 WC Physics, Multidisciplinary SC Physics GA 437IC UT WOS:000265479300025 PM 19518709 ER PT J AU Lea, MA Johnson, D Ream, R Sterling, J Melin, S Gelatt, T AF Lea, Mary-Anne Johnson, Devin Ream, Rolf Sterling, Jeremy Melin, Sharon Gelatt, Tom TI Extreme weather events influence dispersal of naive northern fur seals SO BIOLOGY LETTERS LA English DT Article DE migration; Alaska; storms; Bering Sea ID CALLORHINUS-URSINUS; PRIBILOF ISLANDS; MIGRATION; PUPS; CAPABILITIES; ALASKA AB Since 1975, northern fur seal (Callorhinus ursinus) numbers at the Pribilof Islands (PI) in the Bering Sea have declined rapidly for unknown reasons. Migratory dispersal and habitat choice may affect first-year survivorship, thereby contributing to this decline. We compared migratory behaviour of 166 naive pups during 2 years from islands with disparate population trends (increasing: Bogoslof and San Miguel Islands; declining: PI), hypothesizing that climatic conditions at weaning may differentially affect dispersal and survival. Atmospheric conditions (Bering Sea) in autumn 2005-2006 were anomalously cold, while 2006-2007 was considerably warmer and less stormy. In 2005, pups departed earlier at all sites, and the majority of PI pups (68-85%) departed within 1 day of Arctic storms and dispersed quickly, travelling southwards through the Aleutian Islands. Tailwinds enabled faster rates of travel than headwinds, a trend not previously shown for marine mammals. Weather effects were less pronounced at Bogoslof Island (approx. 400 km further south), and, at San Miguel Island, (California) departures were more gradual, and only influenced by wind and air pressure in 2005. We suggest that increasingly variable climatic conditions at weaning, particularly timing, frequency and intensity of autumnal storms in the Bering Sea, may alter timing, direction of dispersal and potentially survival of pups. C1 [Lea, Mary-Anne; Johnson, Devin; Ream, Rolf; Sterling, Jeremy; Melin, Sharon; Gelatt, Tom] Alaska Fisheries Sci Ctr, Natl Marine Mammal Lab, Seattle, WA 98115 USA. RP Lea, MA (reprint author), Univ Tasmania, Antarctic Wildlife Res Unit, PB5, Hobart, Tas 7000, Australia. EM ma_lea@utas.edu.au RI Lea, Mary-Anne/E-9054-2013 OI Lea, Mary-Anne/0000-0001-8318-9299 NR 21 TC 27 Z9 28 U1 2 U2 8 PU ROYAL SOC PI LONDON PA 6-9 CARLTON HOUSE TERRACE, LONDON SW1Y 5AG, ENGLAND SN 1744-9561 J9 BIOL LETTERS JI Biol. Lett. PD APR 23 PY 2009 VL 5 IS 2 BP 252 EP 257 DI 10.1098/rsbl.2008.0643 PG 6 WC Biology; Ecology; Evolutionary Biology SC Life Sciences & Biomedicine - Other Topics; Environmental Sciences & Ecology; Evolutionary Biology GA 421PX UT WOS:000264371900032 PM 19147444 ER PT J AU Farrell, SL Laxon, SW McAdoo, DC Yi, DH Zwally, HJ AF Farrell, Sinead L. Laxon, Seymour W. McAdoo, David C. Yi, Donghui Zwally, H. J. TI Five years of Arctic sea ice freeboard measurements from the Ice, Cloud and land Elevation Satellite SO JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS LA English DT Article ID CLIMATE-CHANGE; OCEAN; TEMPERATURE; VARIABILITY; THICKNESS; LASER; SHEET AB Using data from the first Earth-orbiting laser altimeter, the Geoscience Laser Altimeter System (GLAS), onboard the Ice, Cloud and land Elevation Satellite (ICESat), we analyze sea ice freeboard in the Arctic Ocean. We describe a new method for sea surface height retrieval, which relies on an algorithm that discriminates laser pulse reflections originating over leads or thin ice. The lead detection algorithm is based on surface reflectivity and analysis of parameters associated with the shape of reflected waveforms. Using knowledge of the local sea surface height and sea ice elevation, we estimate sea ice freeboard and present, for the first time, a time series of Arctic freeboard spanning 5 years between March 2003 and 2008. While the autumn (October-November) and winter (February-March) data illustrate the seasonal and interannual variations in freeboard, following the September 2007 record minimum sea ice extent, the autumn 2007 and winter 2008 spatially averaged freeboards are below the seasonal means at -4.5 cm and -6.8 cm, respectively. Over the observation period, mean freeboard has declined at a rate of similar to-1.8 cm/a during the autumn period and similar to-1.6 cm/a during the winter period, in the region bounded by the northern limit of ICESat coverage at 86 degrees N. Because of the short 5-year observation period, it is unclear whether these results represent a long-term, downward trend in Arctic freeboard or are part of a natural variability. Furthermore, since the variability of snow thickness is included in the ICESat freeboard signal, a decrease in the freeboard cannot wholly be attributed to a decrease in sea ice thickness. C1 [Farrell, Sinead L.; McAdoo, David C.] NOAA, Lab Satellite Altimetry, Silver Spring, MD 20910 USA. [Laxon, Seymour W.] UCL, Ctr Polar Observat & Modelling, London WC1E 6BT, England. [Yi, Donghui] SGT Inc, Greenbelt, MD USA. [Yi, Donghui; Zwally, H. J.] Goddard Space Flight Ctr, Cryospher Sci Branch, Greenbelt, MD 20771 USA. RP Farrell, SL (reprint author), NOAA, Lab Satellite Altimetry, 1335 EW Highway, Silver Spring, MD 20910 USA. EM sinead.farrell@noaa.gov RI Laxon, Seymour/C-1644-2008; Farrell, Sinead/F-5586-2010; McAdoo, Dave/F-5612-2010 OI Farrell, Sinead/0000-0003-3222-2751; McAdoo, Dave/0000-0002-7533-5564 FU NASA's ICESat Science Project; National Research Council; Research Associateship [0625390]; National Oceanographic and Atmospheric Administration (NOAA); National Environment Research Council studentship [NER/S/A/2002/10425] FX We gratefully acknowledge NASA's ICESat Science Project and the NSIDC for distribution of the ICESat data (see http://nsidc.org/data/icesat/). We thank Laury Miller of the NOAA Laboratory for Satellite Altimetry and Andy Ridout of the Centre for Polar Observation and Modeling, UCL, for their helpful advice and discussions. We also thank both the Associate Editor and two anonymous referees for their most careful and helpful reviews. Support for SLF has been provided by the National Research Council, Research Associateship 0625390, under funding from the National Oceanographic and Atmospheric Administration (NOAA) and previously under National Environment Research Council studentship NER/S/A/2002/10425. The views, opinions, and findings contained in this report are those of the authors and should not be construed as an official National Oceanic and Atmospheric Administration or U. S. Government position, policy, or decision. NR 43 TC 33 Z9 34 U1 2 U2 13 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-9275 EI 2169-9291 J9 J GEOPHYS RES-OCEANS JI J. Geophys. Res.-Oceans PD APR 23 PY 2009 VL 114 AR C04008 DI 10.1029/2008JC005074 PG 17 WC Oceanography SC Oceanography GA 438DW UT WOS:000265537100002 ER PT J AU Nogueira, JJ Vazquez, SA Mazyar, OA Hase, WL Perkins, BG Nesbitt, DJ Martinez-Nunez, E AF Nogueira, Juan J. Vazquez, Saulo A. Mazyar, Oleg A. Hase, William L. Perkins, Bradford G., Jr. Nesbitt, David J. Martinez-Nunez, Emilio TI Dynamics of CO2 Scattering off a Perfluorinated Self-Assembled Monolayer. Influence of the Incident Collision Energy, Mass Effects, and Use of Different Surface Models SO JOURNAL OF PHYSICAL CHEMISTRY A LA English DT Article ID GAS-LIQUID INTERFACE; NE-ATOM COLLISIONS; INELASTIC-SCATTERING; RESOLVED SCATTERING; TRAPPING-DESORPTION; HYDROCARBON SURFACE; CHEMICAL-DYNAMICS; MOLECULAR-BEAM; APROTIC GASES; H EXCHANGE AB The dynamics of collisions of CO2 with a perfluorinated alkanethiol self-assembled monolayer (F-SAM) on gold were investigated by classical trajectory calculations using explicit atom (EA) and united atom (UA) models to represent the F-SAM surface. The CO2 Molecule was directed perpendicularly to the surface at initial collision energies of 1.6, 4.7, 7.7, and 10.6 kcal/mol. Rotational distributions of the scattered CO2 molecules are in agreement with experimental distributions determined for collisions of CO2 with liquid surfaces of perfluoropolyether. The agreement is especially good for the EA model. The role of the mass in the efficiency of the energy transfer was investigated in separate simulations in which the mass of the F atoms was replaced by either that of hydrogen or chlorine, while keeping the potential energy function unchanged. The calculations predict the observed trend that less energy is transferred to the surface as the mass of the alkyl chains increases. Significant discrepancies were found between results obtained with the EA and UA models. The UA surface leads to an enhancement of the energy transfer efficiency in comparison with the EA surface. The reason for this is in the softer structure of the UA surface, which facilitates transfer from translation to interchain vibrational modes. C1 [Hase, William L.] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA. [Nogueira, Juan J.; Vazquez, Saulo A.; Martinez-Nunez, Emilio] Univ Santiago de Compostela, Dept Quim Fis, Santiago De Compostela 15782, Spain. [Perkins, Bradford G., Jr.; Nesbitt, David J.] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA. [Perkins, Bradford G., Jr.; Nesbitt, David J.] Univ Colorado, JILA, Boulder, CO 80309 USA. [Perkins, Bradford G., Jr.; Nesbitt, David J.] Natl Inst Stand & Technol, Boulder, CO 80309 USA. RP Hase, WL (reprint author), Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA. RI Martinez-Nunez, Emilio/A-7790-2010; Vazquez, Saulo/A-2866-2015 OI Martinez-Nunez, Emilio/0000-0001-6221-4977; Vazquez, Saulo/0000-0002-2473-4557 NR 57 TC 33 Z9 33 U1 1 U2 23 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1089-5639 J9 J PHYS CHEM A JI J. Phys. Chem. A PD APR 23 PY 2009 VL 113 IS 16 BP 3850 EP 3865 DI 10.1021/jp809756f PG 16 WC Chemistry, Physical; Physics, Atomic, Molecular & Chemical SC Chemistry; Physics GA 435ZU UT WOS:000265383200019 PM 19182968 ER PT J AU Perkins, BG Nesbitt, DJ AF Perkins, Bradford G., Jr. Nesbitt, David J. TI Toward Three-Dimensional Quantum State-Resolved Collision Dynamics at the Gas-Liquid Interface: Theoretical Investigation of Incident Angle SO JOURNAL OF PHYSICAL CHEMISTRY A LA English DT Article ID SELF-ASSEMBLED MONOLAYER; CO2 SCATTERING DYNAMICS; SURFACE ENERGY-EXCHANGE; INELASTIC-SCATTERING; CHEMICAL-DYNAMICS; MOLECULAR-BEAM; HETEROGENEOUS CATALYSIS; TRANSLATIONAL ENERGY; HYDROCARBON SURFACE; APROTIC GASES AB Quantum state-resolved energy transfer dynamics at the gas-liquid interface are explored through a comparison of classical molecular dynamics (MD) simulations and previously reported experimental studies (Perkins, B. G.; et al. J. Phys. Chem. A 2008, 112, 9234). Theoretically, large scale MD trajectory calculations have been performed for collisions Of CO2 with a model fluorinated self-assembled monolayer surface (F-SAMs), based on an explicit atom-atom interaction potential obtained from earlier theoretical studies (Martfnez-Nunez, E.; et al. J. Phys. Chem. C 2007, 711, 354). Initial conditions for the simulations match those in the experimental studies where high-energy jet-cooled CO2 molecules (E-inc = 10.6(8) kcal/mol, approximate to 10 cm(-1)) are scattered from a 300 K perfluorinated liquid surface (PFPE) from a range of incident angles (theta(inc) = 0-60 degrees). Nascent CO2 rotational distributions prove to be remarkably well characterized by a simple two-temperature trapping-desorption (TD) and impulsive scattering (IS) model with nearly quantitative agreement between experimental and theoretical column integrated densities. Furthermore, three-dimensional (313) quantum state resolved flux maps for glancing incident angles (theta(inc) approximate to 60 degrees) reveal broad, lobular distributions peaking strongly in the forward subspecular direction as cos(n)(theta(scat) - theta') with n approximate to 5.6(1.2) and theta' approximate to 49(2)degrees. C1 [Nesbitt, David J.] Univ Colorado, Joint Inst Lab Astrophys, Boulder, CO 80309 USA. Univ Colorado, Natl Inst Stand & Technol, Boulder, CO 80309 USA. Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA. RP Nesbitt, DJ (reprint author), Univ Colorado, Joint Inst Lab Astrophys, Boulder, CO 80309 USA. EM djn@jila.colorado.edu FU Air Force Office of Scientific Research; National Science Foundation FX Primary support for this work is provided by the Air Force Office of Scientific Research with initial equipment and computer resource funding provided by the National Science Foundation. We would also like to thank Professors Bill Hase and Emilio Martinez-Nunez for their development of high quality CO2-PFPE gas-liquid scattering potentials as well as many useful and stimulating discussions. Finally, we congratulate Professor George Schatz for his fireless efforts and numerous insightful contributions to the field of physical chemistry and chemical physics; we all owe him a great debt of gratitude. NR 68 TC 14 Z9 14 U1 0 U2 6 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1089-5639 J9 J PHYS CHEM A JI J. Phys. Chem. A PD APR 23 PY 2009 VL 113 IS 16 BP 4613 EP 4625 DI 10.1021/jp811322y PG 13 WC Chemistry, Physical; Physics, Atomic, Molecular & Chemical SC Chemistry; Physics GA 435ZU UT WOS:000265383200109 PM 19334697 ER PT J AU Biercuk, MJ Uys, H VanDevender, AP Shiga, N Itano, WM Bollinger, JJ AF Biercuk, Michael J. Uys, Hermann VanDevender, Aaron P. Shiga, Nobuyasu Itano, Wayne M. Bollinger, John J. TI Optimized dynamical decoupling in a model quantum memory SO NATURE LA English DT Article ID CRYSTALLIZED ION PLASMAS; DECOHERENCE; SYSTEMS AB Any quantum system, such as those used in quantum information or magnetic resonance, is subject to random phase errors that can dramatically affect the fidelity of a desired quantum operation or measurement(1). In the context of quantum information, quantum error correction techniques have been developed to correct these errors, but resource requirements are extraordinary. The realization of a physically tractable quantum information system will therefore be facilitated if qubit (quantum bit) error rates are far below the so-called fault-tolerance error threshold(1), predicted to be of the order of 10(-3)-10(-6). The need to realize such low error rates motivates a search for alternative strategies to suppress dephasing in quantum systems(2). Here we experimentally demonstrate massive suppression of qubit error rates by the application of optimized dynamical decoupling(3-8) pulse sequences, using a model quantum system capable of simulating a variety of qubit technologies. We demonstrate an analytically derived pulse sequence(9), UDD, and find novel sequences through active, real-time experimental feedback. The latter sequences are tailored to maximize error suppression without the need for a priori knowledge of the ambient noise environment, and are capable of suppressing errors by orders of magnitude compared to other existing sequences (including the benchmark multi-pulse spin echo(10,11)). Our work includes the extension of a treatment to predict qubit decoherence(12,13) under realistic conditions, yielding strong agreement between experimental data and theory for arbitrary pulse sequences incorporating nonidealized control pulses. These results demonstrate the robustness of qubit memory error suppression through dynamical decoupling techniques across a variety of qubit technologies(11,14-16). C1 [Biercuk, Michael J.; Uys, Hermann; VanDevender, Aaron P.; Shiga, Nobuyasu; Itano, Wayne M.; Bollinger, John J.] NIST, Div Time & Frequency, Boulder, CO 80305 USA. [Biercuk, Michael J.] Georgia Inst Technol, Atlanta, GA USA. [Uys, Hermann] CSIR, ZA-0001 Pretoria, South Africa. RP Biercuk, MJ (reprint author), NIST, Div Time & Frequency, Boulder, CO 80305 USA. EM biercuk@boulder.nist.gov RI Biercuk, Michael/B-4768-2010 FU IARPA; NIST; Georgia Tech.; CSIR FX We thank L. Cywinski, S. Das Sarma, V. V. Dobrovitski, X. Hu, E. Knill, S. Lyon, G. Uhrig, and W. Witzel for discussions. We also thank D. Hanneke, C. Ospelkaus and D. J. Wineland for comments on the manuscript, and C. Nelson for technical assistance. We acknowledge research funding from IARPA and the NIST Quantum Information Program. M. J. B. acknowledges fellowship support from IARPA and Georgia Tech., and H. U. acknowledges support from CSIR. This manuscript is a contribution of the US NIST and is not subject to US copyright. NR 30 TC 290 Z9 292 U1 5 U2 40 PU NATURE PUBLISHING GROUP PI LONDON PA MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND SN 0028-0836 J9 NATURE JI Nature PD APR 23 PY 2009 VL 458 IS 7241 BP 996 EP 1000 DI 10.1038/nature07951 PG 5 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA 436KL UT WOS:000265412900035 PM 19396139 ER PT J AU Radebaugh, R AF Radebaugh, Ray TI Cryocoolers: the state of the art and recent developments SO JOURNAL OF PHYSICS-CONDENSED MATTER LA English DT Article; Proceedings Paper CT 25th International Conference on Low Temperature Physics (LT25) CY AUG 06-13, 2008 CL Leiden Inst Phys, Kamerlingh Onnes Lab, Amsterdam, NETHERLANDS HO Leiden Inst Phys, Kamerlingh Onnes Lab ID PULSE TUBE REFRIGERATORS; TEMPERATURE; SYSTEM AB Cryocooler performance and reliability are continually improving. Consequently, they are more and more frequently implemented by physicists in their laboratory experiments or for commercial and space applications. The five kinds of cryocoolers most commonly used to provide cryogenic temperatures for various applications are the Joule-Thomson, Brayton, Stirling, Gifford-McMahon, and pulse tube cryocoolers. Many advances in all types have occurred in the past 20 years that have allowed all of them to be used for a wide variety of applications. The present state of the art and on-going developments of these cryocoolers are reviewed in this paper. In the past five years new research on these cryocoolers has offered the potential to significantly improve them and make them suitable for even more applications. The general trend of this new cryocooler research is also presented. C1 Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Radebaugh, R (reprint author), Natl Inst Stand & Technol, Boulder, CO 80305 USA. EM radebaugh@boulder.nist.gov NR 47 TC 75 Z9 88 U1 8 U2 42 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0953-8984 J9 J PHYS-CONDENS MAT JI J. Phys.-Condes. Matter PD APR 22 PY 2009 VL 21 IS 16 AR 164219 DI 10.1088/0953-8984/21/16/164219 PG 9 WC Physics, Condensed Matter SC Physics GA 426ZH UT WOS:000264746900022 PM 21825399 ER PT J AU Sengers, JL AF Sengers, Johanna Levelt TI A gas that sinks in a liquid-the first helium experiment published by Kamerlingh Onnes SO JOURNAL OF PHYSICS-CONDENSED MATTER LA English DT Article; Proceedings Paper CT 25th International Conference on Low Temperature Physics (LT25) CY AUG 06-13, 2008 CL Leiden Inst Phys, Kamerlingh Onnes Lab, Amsterdam, NETHERLANDS HO Leiden Inst Phys, Kamerlingh Onnes Lab ID NORMAL SUBSTANCES; MIXTURES; LINE AB The year 1906 was a year of many remarkable achievements in the laboratory of Kamerlingh Onnes and his staff. They put into operation a hydrogen liquefier producing 4 1 h(-1), followed by a liquid-hydrogen cryostat for work below 21 K. They prepared their first sample of 2 1 of helium gas. Pressure-volume-temperature measurements down to 54 K were in progress for hydrogen, and initiated for helium, in order to obtain an estimate for the critical temperature of helium; this estimate was urgently needed for design of a helium liquefier. Towards the end of 1906, Kamerlingh Onnes performed the first helium experiment at liquid-hydrogen temperature: a test of the phase behaviour of a mixture of hydrogen and helium. In the process, he discovered what he termed the barotropic effect: at increasing pressure, the helium-rich vapour phase sank to the bottom, having become heavier than the hydrogen-rich liquid phase. This paper describes the experiment and the resulting flurry of activity by Van der Waals, Kamerlingh Onnes, Keesom and Van Laar, all trying to understand and model the curious phase behaviour, as well as earlier relevant work by Van der Waals, Korteweg, Kuenen and Van Laar. C1 Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Sengers, JL (reprint author), Natl Inst Stand & Technol, Mail Stop 8320,100 Bur Dr, Gaithersburg, MD 20899 USA. EM johanna.sengers@nist.gov NR 25 TC 2 Z9 2 U1 0 U2 1 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0953-8984 J9 J PHYS-CONDENS MAT JI J. Phys.-Condes. Matter PD APR 22 PY 2009 VL 21 IS 16 AR 164222 DI 10.1088/0953-8984/21/16/164222 PG 10 WC Physics, Condensed Matter SC Physics GA 426ZH UT WOS:000264746900025 PM 21825402 ER PT J AU Stavis, SM Strychalski, EA Gaitan, M AF Stavis, Samuel M. Strychalski, Elizabeth A. Gaitan, Michael TI Nanofluidic structures with complex three-dimensional surfaces SO NANOTECHNOLOGY LA English DT Article ID SILICON MEMS STRUCTURES; DNA ANALYSIS; MICROFLUIDIC STRUCTURES; NANOSLITS; LENGTH; NANOSTRUCTURES; LITHOGRAPHY; SEPARATION; MOLECULES; DYNAMICS AB Nanofluidic devices have typically explored a design space of patterns limited by a single nanoscale structure depth. A method is presented here for fabricating nanofluidic structures with complex three-dimensional (3D) surfaces, utilizing a single layer of grayscale photolithography and standard integrated circuit manufacturing tools. This method is applied to construct nanofluidic devices with numerous (30) structure depths controlled from approximate to 10 to approximate to 620 nm with an average standard deviation of < 10 nm over distances of > 1 cm. A prototype 3D nanofluidic device is demonstrated that implements size exclusion of rigid nanoparticles and variable nanoscale confinement and deformation of biomolecules. C1 [Stavis, Samuel M.; Gaitan, Michael] Natl Inst Stand & Technol, Div Semicond Elect, Gaithersburg, MD 20899 USA. [Strychalski, Elizabeth A.] Cornell Univ, Dept Phys, Ithaca, NY 14853 USA. RP Stavis, SM (reprint author), Natl Inst Stand & Technol, Div Semicond Elect, Gaithersburg, MD 20899 USA. EM samuel.stavis@nist.gov; eas58@cornell.edu; michael.gaitan@nist.gov FU NSF FX This research was performed while Samuel Stavis held a National Research Council Research Associateship Award at the National Institute of Standards and Technology (NIST), and while Elizabeth Strychalski was supported by the Nanobiotechnology Center, a Science and Technology Center Program of the National Science Foundation (NSF). Device fabrication was performed at the Cornell Nanoscale Science and Technology Facility (CNF), a member of the National Nanotechnology Infrastructure Network, and the Cornell Center for Materials Research, both supported by the NSF. Device characterization was performed in part at the NIST Center for Nanoscale Science and Technology. The authors thank the CNF staff for assistance with device fabrication, and Jon Geist, Laurie Locascio, and Javier Atencia for helpful discussions. NR 31 TC 24 Z9 24 U1 0 U2 15 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0957-4484 EI 1361-6528 J9 NANOTECHNOLOGY JI Nanotechnology PD APR 22 PY 2009 VL 20 IS 16 AR 165302 DI 10.1088/0957-4484/20/16/165302 PG 7 WC Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied SC Science & Technology - Other Topics; Materials Science; Physics GA 427LG UT WOS:000264780200007 PM 19420567 ER PT J AU Maus, S Silva, L Hulot, G AF Maus, Stefan Silva, Luis Hulot, Gauthier TI Reply to comment by V. Lesur et al. on "Can core-surface flow models be used to improve the forecast of the Earth's main magnetic field'' SO JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH LA English DT Editorial Material ID SATELLITE C1 [Maus, Stefan] Univ Colorado, CIRES, Boulder, CO 80309 USA. [Maus, Stefan] NOAA, Natl Geophys Data Ctr, Boulder, CO 80305 USA. [Maus, Stefan; Silva, Luis; Hulot, Gauthier] Univ Paris Diderot, CNRS, F-75252 Paris 05, France. [Maus, Stefan; Silva, Luis; Hulot, Gauthier] Inst Phys Globe, Equipe Geomagnetisme, F-75252 Paris 05, France. RP Maus, S (reprint author), Univ Colorado, CIRES, Boulder, CO 80309 USA. EM Stefan.Maus@noaa.gov RI Hulot, Gauthier/A-5627-2011; Silva, Luis/D-3883-2011; OI Silva, Luis/0000-0003-3421-0009; Maus, Stefan/0000-0002-9604-3878 NR 9 TC 1 Z9 1 U1 0 U2 2 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-9313 EI 2169-9356 J9 J GEOPHYS RES-SOL EA JI J. Geophys. Res.-Solid Earth PD APR 21 PY 2009 VL 114 AR B04105 DI 10.1029/2008JB006242 PG 3 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 438EI UT WOS:000265538300003 ER PT J AU Smith, JR Cicerone, MT Meuse, CW AF Smith, Jack R. Cicerone, Marcus T. Meuse, Curtis W. TI Tertiary Structure Changes in Albumin upon Surface Adsorption Observed via Fourier Transform Infrared Spectroscopy SO LANGMUIR LA English DT Article ID SELF-ASSEMBLED MONOLAYERS; HUMAN-SERUM-ALBUMIN; SCANNING TUNNELING MICROSCOPY; ATOMIC-FORCE MICROSCOPY; X-RAY REFLECTIVITY; PROTEIN ADSORPTION; HYDROGEN-EXCHANGE; CELL-ADHESION; COMPETITIVE BEHAVIOR; RELAXATION KINETICS AB A nondestructive Fourier transform infrared (FTIR) spectroscopy assay, amenable to exploring a wide range of proteins and polymers, is used to measure changes in the tertiary structure of bovine serum albumin (BSA) adsorbed to three surfaces: gold, polystyrene (PS), and poly(D,L-lactic acid) (PDLLA). Tertiary structural analysis is important because typical secondary structural analysis (FTIR and CD) is not always sensitive enough to distinguish between the sometimes subtle protein structural changes caused by adsorption. The polymers are spin-coated onto a gold surface, exposed to protein, and then immersed in a deuterated buffer solution to probe the protein's tertiary structure before the sample is removed from its aqueous environment. Infrared band intensities, related to the exchange of amide hydrogen for deuterium (HDX), as a function of the immersion time in deuterated buffer, are used to determine the extent of amide solvent exposure. Analysis of the results in terms of a single exponential decay shows that enough amides undergo a measurable amount of exchange in 60 min to quantify relative changes in BSA solvent exposure on different surfaces. In addition, substantial fractions undergo HDX at a rate too fast or too slow to be followed with our experimental protocol. The proportions of these quickly and slowly exchanging amide groups also provide information about relative changes in the BSA structure on different surfaces. Adsorption was found to increase the extent of HDX over that observed for BSA in solution, consistent with surface-induced unfolding and a loss of tertiary structure. Changes in HDX were found to be more sensitive to which surface was absorbing the protein than the typical FTIR secondary structural analysis obtained from fitting the amide I band. HDX was greatest for BSA adsorbed to the surface of PDLLA and least in the case of BSA adsorbed to gold, which indicates the greatest and least degree of unfolding, respectively. C1 [Smith, Jack R.; Cicerone, Marcus T.] NIST, Div Polymers, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA. [Meuse, Curtis W.] NIST, Div Biochem Sci, Chem Sci & Technol Lab, Gaithersburg, MD 20899 USA. RP Meuse, CW (reprint author), 100 Bur Dr,Stop 8313, Gaithersburg, MD 20899 USA. EM curtis.meuse@nist.gov FU National Academy of Sciences/National Research Council FX Funding for J.R.S. was provided by a National Academy of Sciences/National Research Council Postdoctoral Fellowship. NR 66 TC 14 Z9 14 U1 2 U2 12 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0743-7463 J9 LANGMUIR JI Langmuir PD APR 21 PY 2009 VL 25 IS 8 BP 4571 EP 4578 DI 10.1021/la802955w PG 8 WC Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary SC Chemistry; Materials Science GA 434NP UT WOS:000265281700055 PM 19366224 ER PT J AU Schexnailder, P Loizou, E Porcar, L Butler, P Schmidt, G AF Schexnailder, Patrick Loizou, Elena Porcar, Lionel Butler, Paul Schmidt, Gudrun TI Heterogeneity in nanocomposite hydrogels from poly(ethylene oxide) cross-linked with silicate nanoparticles SO PHYSICAL CHEMISTRY CHEMICAL PHYSICS LA English DT Article ID ANGLE NEUTRON-SCATTERING; POLYMER-CLAY SOLUTIONS; LAPONITE-PEO MIXTURES; LIGHT-SCATTERING; FLUOROGENIC SUBSTRATE; FLOW-BIREFRINGENCE; LENGTH SCALE; SHAKE-GELS; DISPERSIONS; RHEOLOGY AB We investigate the influence of ionic strength on the structural heterogeneity and viscoelastic properties of nanocomposite hydrogels. We use small-angle scattering and rheology to monitor Structural changes as a function of ionic strength. Increasing ionic strength makes the nanocomposite gels macroscopically heterogeneous, stiffer and more turbid. At high shear rates, nanometre Structures rearrange within aggregates and orient ill the flow direction. The changing structural properties that develop with ionic strength are due to increased heterogeneity of nanoparticle distribution and polymer-nanoparticle interactions as well as to the formation of PEO [poly(ethylene oxide)] aggregates interacting with sodium cations. which reinforce the overall hydrogel network. C1 [Schexnailder, Patrick; Schmidt, Gudrun] Purdue Univ, Weldon Sch Biomed Engn, W Lafayette, IN 47907 USA. [Loizou, Elena; Porcar, Lionel; Butler, Paul] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. RP Schmidt, G (reprint author), Purdue Univ, Weldon Sch Biomed Engn, W Lafayette, IN 47907 USA. EM gudrun@purdue.edu RI Butler, Paul/D-7368-2011 NR 48 TC 16 Z9 16 U1 2 U2 29 PU ROYAL SOC CHEMISTRY PI CAMBRIDGE PA THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND SN 1463-9076 J9 PHYS CHEM CHEM PHYS JI Phys. Chem. Chem. Phys. PD APR 21 PY 2009 VL 11 IS 15 BP 2760 EP 2766 DI 10.1039/b820452g PG 7 WC Chemistry, Physical; Physics, Atomic, Molecular & Chemical SC Chemistry; Physics GA 442IY UT WOS:000265836100022 PM 19421534 ER PT J AU Helmig, D Cohen, LD Bocquet, F Oltmans, S Grachev, A Neff, W AF Helmig, Detlev Cohen, Lana D. Bocquet, Florence Oltmans, Samuel Grachev, Andrey Neff, William TI Spring and summertime diurnal surface ozone fluxes over the polar snow at Summit, Greenland SO GEOPHYSICAL RESEARCH LETTERS LA English DT Article ID SPRUCE-FIR FOREST; BOUNDARY-LAYER; SOUTH-POLE; INTERSTITIAL AIR; NOX AB Continuous surface-layer ozone flux measurements over the polar, year-round snowpack at Summit, Greenland, resulted in deposition velocities (v(d)) that were smaller than most previous assumptions and model inputs. Substantial seasonal differences were seen in the ozone v(d) behavior. Spring, daytime ozone v(d) values showed low variability and were consistently <= 0.01 cm s(-1). During summer, ozone fluxes displayed distinct diurnal cycles, and evidence for regular occurrences of bi-directional behavior. Summer, daytime v(d) ranged between similar to 0.01 to 0.07 cm s(-1). Maximum summertime downward fluxes (ozone deposition) coincided with the hours of maximum solar radiation, i.e., noon afternoon. During summer nighttime hours upward ozone fluxes were observed. These upward fluxes were interpreted as ozone production in a shallow layer near and above the snow surface with resulting upward ozone fluxes out of the shallow surface layer. Comparisons with published observations from temperate, midlatitude sites suggest different controls and behavior of ozone fluxes, and that ozone fluxes over snow depend on a myriad of parameters, including solar irradiance, snow chemical and physical properties, snowpack depth, and the type of substrate underneath the snow. Citation: Helmig, D., L. D. Cohen, F. Bocquet, S. Oltmans, A. Grachev, and W. Neff (2009), Spring and summertime diurnal surface ozone fluxes over the polar snow at Summit, Greenland, Geophys. Res. Lett., 36, L08809, doi:10.1029/2008GL036549. C1 [Helmig, Detlev; Cohen, Lana D.; Bocquet, Florence] Univ Colorado, INSTAAR, Inst Arctic & Alpine Res, Boulder, CO 80309 USA. [Bocquet, Florence; Grachev, Andrey] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. [Oltmans, Samuel; Grachev, Andrey; Neff, William] NOAA, ESRL, Boulder, CO 80305 USA. [Helmig, Detlev; Cohen, Lana D.; Bocquet, Florence] Univ Colorado, Dept Atmospher & Ocean Sci, Boulder, CO 80309 USA. RP Helmig, D (reprint author), Univ Colorado, INSTAAR, Inst Arctic & Alpine Res, 1560 30th St, Boulder, CO 80309 USA. EM detlev.helmig@colorado.edu RI Neff, William/E-2725-2010; OI Neff, William/0000-0003-4047-7076; GRACHEV, ANDREY/0000-0002-7143-0820 FU NSF-OPP [0240976] FX S. Oncley assisted in evaluation of sonic anemometer data; K. Steffen and N. Cullen advised in the interpretation of flux measurements. This research was funded by NSF-OPP grant 0240976. Any opinions, findings, and conclusions expressed in this material are those of the authors and do not necessarily reflect the views of NSF. Logistical support was provided by VECO Polar Resources and the U. S. 109th Air National Guard. We also thank the Danish Commission for Scientific Research for providing access to the Summit research site. NR 27 TC 14 Z9 14 U1 1 U2 10 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0094-8276 J9 GEOPHYS RES LETT JI Geophys. Res. Lett. PD APR 18 PY 2009 VL 36 AR L08809 DI 10.1029/2008GL036549 PG 5 WC Geosciences, Multidisciplinary SC Geology GA 435FC UT WOS:000265328300002 ER PT J AU Blakestad, RB Ospelkaus, C VanDevender, AP Amini, JM Britton, J Leibfried, D Wineland, DJ AF Blakestad, R. B. Ospelkaus, C. VanDevender, A. P. Amini, J. M. Britton, J. Leibfried, D. Wineland, D. J. TI High-Fidelity Transport of Trapped-Ion Qubits through an X-Junction Trap Array SO PHYSICAL REVIEW LETTERS LA English DT Article ID QUANTUM COMPUTER; ATOMIC IONS; STATES; ARCHITECTURE AB We report reliable transport of (9)Be(+) ions through an "X junction" in a 2D trap array that includes a separate loading and reservoir zone. During transport the ion's kinetic energy in its local well increases by only a few motional quanta and internal-state coherences are preserved. We also examine two sources of energy gain during transport: a particular radio-frequency noise heating mechanism and digital sampling noise. Such studies are important to achieve scaling in a trapped-ion quantum information processor. C1 [Blakestad, R. B.; Ospelkaus, C.; VanDevender, A. P.; Amini, J. M.; Britton, J.; Leibfried, D.; Wineland, D. J.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. RP Blakestad, RB (reprint author), Natl Inst Stand & Technol, 325 Broadway, Boulder, CO 80305 USA. RI Ospelkaus, Christian/C-3612-2009; OI Ospelkaus, Christian/0000-0002-4170-2936; Britton, Joe/0000-0001-8103-7347 FU IARPA; ONR; NIST FX We thank J. J. Bollinger and Y. Colombe for helpful comments on the manuscript and acknowledge the support of IARPA, ONR, and the NIST Quantum Information program. This Letter is a contribution of NIST and not subject to U. S. copyright. NR 27 TC 55 Z9 55 U1 0 U2 7 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 0031-9007 J9 PHYS REV LETT JI Phys. Rev. Lett. PD APR 17 PY 2009 VL 102 IS 15 AR 153002 DI 10.1103/PhysRevLett.102.153002 PG 4 WC Physics, Multidisciplinary SC Physics GA 434PD UT WOS:000265285700024 PM 19518628 ER PT J AU Campbell, GK Boyd, MM Thomsen, JW Martin, MJ Blatt, S Swallows, MD Nicholson, TL Fortier, T Oates, CW Diddams, SA Lemke, ND Naidon, P Julienne, P Ye, J Ludlow, AD AF Campbell, G. K. Boyd, M. M. Thomsen, J. W. Martin, M. J. Blatt, S. Swallows, M. D. Nicholson, T. L. Fortier, T. Oates, C. W. Diddams, S. A. Lemke, N. D. Naidon, P. Julienne, P. Ye, Jun Ludlow, A. D. TI Probing Interactions Between Ultracold Fermions SO SCIENCE LA English DT Article ID BOSE-EINSTEIN CONDENSATION; FREQUENCY-SHIFTS; NOBEL LECTURE; CLOCKS; ATOMS; LASER; COLLISIONS; WAVE; GAS AB At ultracold temperatures, the Pauli exclusion principle suppresses collisions between identical fermions. This has motivated the development of atomic clocks with fermionic isotopes. However, by probing an optical clock transition with thousands of lattice-confined, ultracold fermionic strontium atoms, we observed density-dependent collisional frequency shifts. These collision effects were measured systematically and are supported by a theoretical description attributing them to inhomogeneities in the probe excitation process that render the atoms distinguishable. This work also yields insights for zeroing the clock density shift. C1 [Campbell, G. K.; Boyd, M. M.; Thomsen, J. W.; Martin, M. J.; Blatt, S.; Swallows, M. D.; Nicholson, T. L.; Ye, Jun; Ludlow, A. D.] Univ Colorado, Natl Inst Stand & Technol, JILA, Boulder, CO 80309 USA. [Campbell, G. K.; Boyd, M. M.; Thomsen, J. W.; Martin, M. J.; Blatt, S.; Swallows, M. D.; Nicholson, T. L.; Ye, Jun; Ludlow, A. D.] Univ Colorado, Dept Phys, Boulder, CO 80309 USA. [Fortier, T.; Oates, C. W.; Diddams, S. A.; Lemke, N. D.] NIST, Div Time & Frequency, Boulder, CO 80302 USA. [Naidon, P.; Julienne, P.] NIST, Atom Phys Div, Gaithersburg, MD 20899 USA. [Naidon, P.; Julienne, P.] NIST, Joint Quantum Inst, Gaithersburg, MD 20899 USA. RP Ye, J (reprint author), Univ Colorado, Natl Inst Stand & Technol, JILA, Boulder, CO 80309 USA. EM junye@jilau1.colorado.edu RI Campbell, Gretchen/E-8338-2010; Ye, Jun/C-3312-2011; Blatt, Sebastian/F-8986-2012; Diddams, Scott/L-2819-2013; Lemke, Nathan/L-9059-2013; Thomsen, Jan W./M-9087-2016; Julienne, Paul/E-9378-2012; OI Campbell, Gretchen/0000-0003-2596-1919; Blatt, Sebastian/0000-0003-2466-9967; Lemke, Nathan/0000-0003-4165-0715; Thomsen, Jan W./0000-0003-3423-6989; Julienne, Paul/0000-0002-5494-1442; Nicholson, Travis/0000-0002-0503-7991 FU NIST; NSF; Office of Naval Research; Defense Advanced Projects Research Agency; National Research Council postdoctoral fellowships FX We appreciate technical contributions of T. Zelevinsky and insightful discussions with K. Gibble, W. Ketterle, M. Zwierlein, E. Cornell, and S. Kokkelmans. We acknowledge funding support from NIST, NSF, Office of Naval Research, and Defense Advanced Projects Research Agency. G.K.C. and A.D.L. are supported by National Research Council postdoctoral fellowships. J.W.T. is a JILA visiting fellow, with a permanent address: The Niels Bohr Institute, Universitetsparken 5, 2100 Copenhagen, Denmark. NR 23 TC 66 Z9 67 U1 0 U2 19 PU AMER ASSOC ADVANCEMENT SCIENCE PI WASHINGTON PA 1200 NEW YORK AVE, NW, WASHINGTON, DC 20005 USA SN 0036-8075 J9 SCIENCE JI Science PD APR 17 PY 2009 VL 324 IS 5925 BP 360 EP 363 DI 10.1126/science.1169724 PG 4 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA 433QT UT WOS:000265221600034 PM 19372424 ER PT J AU Warusawithana, MP Cen, C Sleasman, CR Woicik, JC Li, YL Kourkoutis, LF Klug, JA Li, H Ryan, P Wang, LP Bedzyk, M Muller, DA Chen, LQ Levy, J Schlom, DG AF Warusawithana, Maitri P. Cen, Cheng Sleasman, Charles R. Woicik, Joseph C. Li, Yulan Kourkoutis, Lena Fitting Klug, Jeffrey A. Li, Hao Ryan, Philip Wang, Li-Peng Bedzyk, Michael Muller, David A. Chen, Long-Qing Levy, Jeremy Schlom, Darrell G. TI A Ferroelectric Oxide Made Directly on Silicon SO SCIENCE LA English DT Article ID THIN-FILMS; PEROVSKITE FILMS; ULTRATHIN FILMS; SRTIO3; MULTILAYERS; THICKNESS; GROWTH AB Metal oxide semiconductor field-effect transistors, formed using silicon dioxide and silicon, have undergone four decades of staggering technological advancement. With fundamental limits to this technology close at hand, alternatives to silicon dioxide are being pursued to enable new functionality and device architectures. We achieved ferroelectric functionality in intimate contact with silicon by growing coherently strained strontium titanate (SrTiO3) films via oxide molecular beam epitaxy in direct contact with silicon, with no interfacial silicon dioxide. We observed ferroelectricity in these ultrathin SrTiO3 layers by means of piezoresponse force microscopy. Stable ferroelectric nanodomains created in SrTiO3 were observed at temperatures as high as 400 kelvin. C1 [Warusawithana, Maitri P.; Schlom, Darrell G.] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA. [Cen, Cheng; Sleasman, Charles R.; Levy, Jeremy] Univ Pittsburgh, Dept Phys & Astron, Pittsburgh, PA 15260 USA. [Woicik, Joseph C.] NIST, Gaithersburg, MD 20899 USA. [Li, Yulan; Chen, Long-Qing] Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA. [Kourkoutis, Lena Fitting; Muller, David A.] Cornell Univ, Sch Appl & Engn Phys, Ithaca, NY 14853 USA. [Klug, Jeffrey A.; Bedzyk, Michael] Northwestern Univ, Dept Phys & Astron, Evanston, IL 60208 USA. [Li, Hao] Motorola Inc, Appl Res & Technol Ctr, Tempe, AZ 85284 USA. [Ryan, Philip] Ames Lab, Ames, IA 50011 USA. [Wang, Li-Peng] Intel Corp, Santa Clara, CA 95052 USA. [Wang, Li-Peng] TricornTech, San Jose, CA 95129 USA. [Bedzyk, Michael] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA. RP Schlom, DG (reprint author), Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA. EM schlom@cornell.edu RI Schlom, Darrell/J-2412-2013; Bedzyk, Michael/B-7503-2009; Bedzyk, Michael/K-6903-2013; Chen, LongQing/I-7536-2012; Levy, Jeremy/A-2081-2009; Muller, David/A-7745-2010; Klug, Jeffrey/A-3653-2013 OI Schlom, Darrell/0000-0003-2493-6113; Chen, LongQing/0000-0003-3359-3781; Levy, Jeremy/0000-0002-5700-2977; Muller, David/0000-0003-4129-0473; Kourkoutis, Lena/0000-0002-1303-1362; FU Office of Naval Research [N00014-04-1-0426]; NSF [DMR-0507146, DMR-0704022]; Materials Research Science and Engineering Center [DMR-0520404, DMR-0520513, DMR-0820404]; U.S. Department of Energy, Basic Energy Sciences, Office of Science [W-31-109-ENG-38] FX We thank C. H. Ahn, O. Auciello, V. Gopalan, D. A. Tenne, and F. J. Walker for stimulating discussions and interactions during the course of this work. Supported by Office of Naval Research grant N00014-04-1-0426 (M.P.W., L.F.K., D.A.M., and D.G.S.), NSF grants DMR-0507146 and DMR-0704022, Materials Research Science and Engineering Center program grants DMR-0520404, DMR-0520513, and DMR-0820404, and, for the work performed at Argonne National Laboratory, the U.S. Department of Energy, Basic Energy Sciences, Materials Sciences. Diffraction data were taken at sector 33BM of the Advanced Photon Source, which is supported by the U.S. Department of Energy, Basic Energy Sciences, Office of Science under contract W-31-109-ENG-38. NR 32 TC 204 Z9 205 U1 16 U2 214 PU AMER ASSOC ADVANCEMENT SCIENCE PI WASHINGTON PA 1200 NEW YORK AVE, NW, WASHINGTON, DC 20005 USA SN 0036-8075 EI 1095-9203 J9 SCIENCE JI Science PD APR 17 PY 2009 VL 324 IS 5925 BP 367 EP 370 DI 10.1126/science.1169678 PG 4 WC Multidisciplinary Sciences SC Science & Technology - Other Topics GA 433QT UT WOS:000265221600036 PM 19372426 ER PT J AU Bronnimann, S Stickler, A Griesser, T Ewen, T Grant, AN Fischer, AM Schraner, M Peter, T Rozanov, E Ross, T AF Broennimann, S. Stickler, A. Griesser, T. Ewen, T. Grant, A. N. Fischer, A. M. Schraner, M. Peter, T. Rozanov, E. Ross, T. TI Exceptional atmospheric circulation during the "Dust Bowl" SO GEOPHYSICAL RESEARCH LETTERS LA English DT Article ID LOW-LEVEL JET; CHEMISTRY-CLIMATE MODEL; NORTH-AMERICAN DROUGHT; CENTRAL UNITED-STATES; GREAT-PLAINS; HEAT WAVES; VARIABILITY; SUMMER; TRANSPORT; MOISTURE AB The three-dimensional, regional and large-scale atmospheric circulation during the "Dust Bowl" is analyzed based on newly available historical upper-air data and reconstructed upper-level fields. The Great Plains Low Level Jet, transporting moisture into the region, was weakened on its eastern side, shallower, and penetrated less far north than during wet years. Nocturnal convection was likely suppressed by increased stability. Strong mid-tropospheric ridging was found over the Great Plains, and upper-tropospheric flow anomalies extended from the North Pacific across North America to the Atlantic. These findings provide a dynamical view of the "Dust Bowl" droughts, some aspects of which are distinct from other droughts. It is demonstrated that this is important for assessing predictive capabilities of current modeling systems. Citation: Bronnimann, S., A. Stickler, T. Griesser, T. Ewen, A. N. Grant, A. M. Fischer, M. Schraner, T. Peter, E. Rozanov, and T. Ross (2009), Exceptional atmospheric circulation during the "Dust Bowl," Geophys. Res. Lett., 36, L08802, doi:10.1029/2009GL037612. C1 [Broennimann, S.; Stickler, A.; Griesser, T.; Ewen, T.; Grant, A. N.; Fischer, A. M.; Schraner, M.; Peter, T.; Rozanov, E.] ETH, Inst Atmospher & Climate Sci, CH-8092 Zurich, Switzerland. [Rozanov, E.] WRC, PMOD, CH-7260 Davos, Switzerland. [Ross, T.] NOAA, Natl Climat Data Ctr, Asheville, NC 28801 USA. RP Bronnimann, S (reprint author), ETH, Inst Atmospher & Climate Sci, Univ Str 16, CH-8092 Zurich, Switzerland. EM broennimann@env.ethz.ch RI Bronnimann, Stefan/A-5737-2008; Grant, Andrea/A-1693-2008; Rozanov, Eugene/A-9857-2012; OI Grant, Andrea/0000-0002-1553-596X; Rozanov, Eugene/0000-0003-0479-4488; Bronnimann, Stefan/0000-0001-9502-7991 FU Swiss National Science Foundation [PP002-102731]; ETH FX The work was funded by the Swiss National Science Foundation (PP002-102731) and ETH research grants CASTRO and VSGC-II. ERA-40 and ERA-interim data were downloaded from the ECMWF server. NR 29 TC 12 Z9 12 U1 1 U2 16 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0094-8276 J9 GEOPHYS RES LETT JI Geophys. Res. Lett. PD APR 16 PY 2009 VL 36 AR L08802 DI 10.1029/2009GL037612 PG 6 WC Geosciences, Multidisciplinary SC Geology GA 435EY UT WOS:000265327900007 ER PT J AU Massoli, P Bates, TS Quinn, PK Lack, DA Baynard, T Lerner, BM Tucker, SC Brioude, J Stohl, A Williams, EJ AF Massoli, P. Bates, T. S. Quinn, P. K. Lack, D. A. Baynard, T. Lerner, B. M. Tucker, S. C. Brioude, J. Stohl, A. Williams, E. J. TI Aerosol optical and hygroscopic properties during TexAQS-GoMACCS 2006 and their impact on aerosol direct radiative forcing SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID PARTICLE DISPERSION MODEL; SINGLE SCATTERING ALBEDO; INDUSTRIAL EMISSIONS; SIZE DISTRIBUTIONS; ORGANIC AEROSOL; ATLANTIC; HOUSTON; URBAN; EXTINCTION; ABSORPTION AB In situ measurements of aerosol optical and hygroscopic properties were made on board the National Oceanic and Atmospheric Administration R/V Ronald H. Brown during the Texas Air Quality Study-Gulf of Mexico Atmospheric Composition and Climate Study (TexAQS-GoMACCS). The aerosol light extinction coefficient (sigma(ep)) was measured at 355, 532, and 1064 nm at 25%, 60%, and 85% relative humidity (RII) for both sub-1- and sub-10-eta m-diameter particles with a cavity ring-down aerosol extinction spectrometer. The 532-nm sigma(ep) was coupled with the 532-nm light absorption coefficient (sigma(ap)) measured with a photoacoustic absorption spectrometer to calculate the aerosol single scattering albedo (omega) with absolute uncertainty < 0.01. The sigma(ep) dependence on RII was expressed in terms of gamma (gamma). The sampled aerosols covered a broad spectrum of gamma and omega values; aerosols from traffic emissions were hydrophobic and highly light-absorbing with gamma similar to 0.4 and omega similar to 0.6, whereas the regional aerosols exhibited variable values of both g and w. Aerosols with the highest sulfate content also had the highest gamma and omega values (>0.65 and >0.9, respectively). The optical data were used to estimate local, top of atmosphere aerosol-induced climate forcing (Delta F-R). The Delta F-R calculations were performed using both omega values measured at 25% RII and omega values converted to ambient RII. The calculated ambient Delta F-R ranged from -7 to -40 W/m(2) with absolute uncertainty between 0.7 and 2.5 W/m(2). The results show that including aerosol hygroscopic properties in climate calculations is critical for improving estimates of aerosol forcing on climate. C1 [Massoli, P.; Lack, D. A.; Baynard, T.; Lerner, B. M.; Tucker, S. C.; Brioude, J.; Williams, E. J.] NOAA, Div Chem Sci, Earth Syst Res Lab, Boulder, CO 80309 USA. [Bates, T. S.; Quinn, P. K.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. [Stohl, A.] Norwegian Inst Air Res, Dept Reg & Global Pollut Issues, N-2027 Kjeller, Norway. [Massoli, P.; Lack, D. A.; Baynard, T.; Lerner, B. M.; Tucker, S. C.; Brioude, J.; Williams, E. J.] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. RP Massoli, P (reprint author), NOAA, Div Chem Sci, Earth Syst Res Lab, 325 Broadway, Boulder, CO 80309 USA. EM pmassoli@aerodyne.com RI Williams, Eric/F-1184-2010; Stohl, Andreas/A-7535-2008; Brioude, Jerome/E-4629-2011; Lack, Daniel/I-9053-2012; Lerner, Brian/H-6556-2013; Bates, Timothy/L-6080-2016; Quinn, Patricia/R-1493-2016; Manager, CSD Publications/B-2789-2015 OI Stohl, Andreas/0000-0002-2524-5755; Lerner, Brian/0000-0001-8721-8165; Quinn, Patricia/0000-0003-0337-4895; FU NOAA Climate and Global Change Program; NOAA Office of Oceanic and Atmospheric Research; NOAA Health of the Atmosphere Program; Texas Air Quality Study FX This project was funded by the NOAA Climate and Global Change Program, the NOAA Office of Oceanic and Atmospheric Research, the NOAA Health of the Atmosphere Program, and the Texas Air Quality Study. Certain commercial equipment, instruments, or materials are identified in this article in order to adequately specify the experimental procedure. Such identification does not imply recognition or endorsement by the National Oceanic and Atmospheric Administration, nor does it imply that the material or equipment identified are necessarily the best available for the purpose. NR 56 TC 36 Z9 37 U1 2 U2 40 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X EI 2169-8996 J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD APR 16 PY 2009 VL 114 AR D00F07 DI 10.1029/2008JD011604 PG 17 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 435FL UT WOS:000265329200004 ER PT J AU Chu, XQ Faraone, A Kim, C Fratini, E Baglioni, P Leao, JB Chen, SH AF Chu, Xiang-qiang Faraone, Antonio Kim, Chansoo Fratini, Emiliano Baglioni, Piero Leao, Juscelino B. Chen, Sow-Hsin TI Proteins Remain Soft at Lower Temperatures under Pressure SO JOURNAL OF PHYSICAL CHEMISTRY B LA English DT Article ID INELASTIC NEUTRON-SCATTERING; HYDRATION-WATER; DYNAMICAL TRANSITION; LIQUID-PHASE; LYSOZYME; BIOCHEMISTRY; SIMULATIONS; MYOGLOBIN; CROSSOVER; SOLVENT AB The low-temperature behavior of proteins under high pressure is not as extensively investigated as that at ambient pressure. In this paper, we study the dynamics of a hydrated protein under moderately high pressures at low temperatures using the quasielastic neutron scattering method. We show that when applying pressure to the protein-water system, the dynamics of the protein hydration water does not slow down but becomes faster instead. The degree of "softness" of the protein, which is intimately related to the enzymatic activity of the protein, shows the same trend as its hydration water as a function of temperature at different pressures. These two results taken together suggest that at lower temperatures, the protein remains soft and active under pressure. C1 [Chu, Xiang-qiang; Kim, Chansoo; Chen, Sow-Hsin] MIT, Dept Nucl Sci & Engn, Cambridge, MA 02139 USA. [Kim, Chansoo] Korea Inst Sci & Technol, Computat Sci Ctr, Seoul, South Korea. [Faraone, Antonio; Leao, Juscelino B.] NIST, Ctr Nuetron Res, Gaithersburg, MD 20899 USA. [Faraone, Antonio] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. [Kim, Chansoo] Univ Florence, Dept Chem, I-50019 Florence, Italy. [Kim, Chansoo] Univ Florence, CSGI, I-50019 Florence, Italy. RP Chen, SH (reprint author), MIT, Dept Nucl Sci & Engn, 77 Massachusetts Ave, Cambridge, MA 02139 USA. EM sowhsin@mit.edu RI Chu, Xiangqiang/A-1572-2011; Fratini, Emiliano/C-9983-2010; Baglioni, Piero/B-1208-2011; OI Fratini, Emiliano/0000-0001-7104-6530; Baglioni, Piero/0000-0003-1312-8700; Chu, Xiang-qiang/0000-0003-4320-5316 FU DOE [DE-FG02-90ER45429]; National Science Foundation [DNM-0086210]; NIST Center for Neutron Research.; CSGI; MIUR FX The research at MIT is supported by DOE Grants No. DE-FG02-90ER45429. This work utilized facilities supported in part by the National Science Foundation under Agreement No. DNM-0086210. We appreciate technical support during experiments from V. Garcia-Sakai, T. Jenkins, M. Tyagi, and S. Poulton of the NIST Center for Neutron Research. E.F. and P.B. acknowledge financial support from CSGI and MIUR We benefited from affiliation with EU funded Mari-Curie Research and Training Network on Arrested Matter. NR 45 TC 34 Z9 34 U1 0 U2 5 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1520-6106 J9 J PHYS CHEM B JI J. Phys. Chem. B PD APR 16 PY 2009 VL 113 IS 15 BP 5001 EP 5006 DI 10.1021/jp900557w PG 6 WC Chemistry, Physical SC Chemistry GA 430ZG UT WOS:000265030500005 PM 19323465 ER PT J AU Phelan, FR Bauer, BJ AF Phelan, Frederick R., Jr. Bauer, Barry J. TI Comparison of steric effects in the modeling of spheres and rodlike particles in field-flow fractionation SO CHEMICAL ENGINEERING SCIENCE LA English DT Article DE Separations; Complex fluids; Fluid mechanics; Hydrodynamics; Mathematical modelling; Simulation; Brownian dynamics; Field-flow fractionation; Nanotubes; Steric inversion; SWNTs ID HYDRODYNAMIC LIFT FORCES; WALLED CARBON NANOTUBES; SEPARATION; SIZE; CHANNELS; BEHAVIOR; CELLS AB The elution of spheres and rods in field-flow fractionation (FFF) is studied using a Brownian dynamics method. The particle motions for spheres are governed by a familiar Langevin equation which models drag force and diffusion. The rods are modeled as prolate ellipsoids and the particle motions are governed by a similar but orientation dependent Langevin equation, and the Jeffrey equation with rotational diffusion. Modeling of particle elution for spheres from 10 to 1000 nm was examined. The simulation captures the steric transition, and results for mean elution time are in good agreement with the steric inversion theory of Giddings [Giddings, J.C., 2000. In: Field-Flow Fractionation Handbook, Wiley-Interscience; Giddings, J.C., 1978. Separation Science and Technology 13, 241; Giddings, J.C., Myers, M.N., 1978. Separation Science and Technology 13, 637]. The sphere simulations are compared with simulations for rods of equal diffusivity, as under "normal mode" conditions (i.e., diffusion controlled) such particles should elute at the same rate. The results for rods show that nanotube size particles elute by a normal mode mechanism up to a size of about 500 nm (based on a particle diameter of I nm). At larger sizes, the rods begin to deviate from normal mode theory, but less strongly and in the opposite sense as for spheres. While the steric effect for spheres causes larger spheres to elute faster than predicted by normal mode theory, an inverse steric effect occurs for rods in which larger rods move increasingly slower than predicted by theory. The difference is attributed to the fact that the speed up observed for spheres is dictated by size exclusion of the particles at the boundary, while rods slow down due to increasing alignment at the boundary. Spheres and rods of equivalent diffusivity elute at the same rate up to a sphere size of approximately 90 nm (500 nm rods), at which point there are increasingly greater differences in mean elution times. While this affects the calibration of such operations, it also indicates that length based separations for nanotubes are not bound by the same limitation as occurs for spheres due to steric inversion. Published by Elsevier Ltd. C1 [Phelan, Frederick R., Jr.; Bauer, Barry J.] NIST, Div Polymers, Gaithersburg, MD 20899 USA. RP Phelan, FR (reprint author), NIST, Div Polymers, Gaithersburg, MD 20899 USA. EM frederick.phelan@nist.gov NR 31 TC 10 Z9 10 U1 2 U2 11 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0009-2509 J9 CHEM ENG SCI JI Chem. Eng. Sci. PD APR 15 PY 2009 VL 64 IS 8 BP 1747 EP 1758 DI 10.1016/j.ces.2008.10.006 PG 12 WC Engineering, Chemical SC Engineering GA 435AX UT WOS:000265316700012 ER PT J AU Manning, JP McGillicuddy, DJ Pettigrew, NR Churchill, JH Incze, LS AF Manning, J. P. McGillicuddy, D. J., Jr. Pettigrew, N. R. Churchill, J. H. Incze, L. S. TI Drifter observations of the Gulf of Maine Coastal Current SO CONTINENTAL SHELF RESEARCH LA English DT Article DE Lagrangian drifting buoys; Coastal current measurement; Transport processes; Drogues; Gulf of Maine; Georges Bank ID GEORGES BANK; CIRCULATION; TRANSPORT; POPULATIONS; PATTERNS; BLOOM; PLUME; MODEL AB Two-hundred and twenty seven satellite-tracked drifters were deployed in the Gulf of Maine (GoM) from 1988 to 2007, primarily during spring and summer. The archive of tracks includes over 100,000 km logged thus far. Statistics such as transit times, mean velocities, response to wind events, and preferred pathways are compiled for various areas of the coastal GoM. We compare Lagrangian flow with Eulerian estimates from nearby moorings and evaluate drifter trajectories using Ekman theory and 3-D ocean circulation models. Results indicate that the Gulf of Maine Coastal Current is a strong and persistent feature centered on the 94 +/- 23 m isobath, but that particles: (a) deviate from the seasonal-mean core fairly regularly, and are often re-entrained; (b) follow a slower (9 cm/s), less-constrained path in the western portion off the coast of Maine relative to the eastern (16 cm/s) section; and (c) can be affected by wind events and small-scale baroclinic structures. Residence times calculated for each 1/2 degrees grid cell throughout the GoM depict some regions (Eastern Maine and Western Nova Scotia) as being relatively steady, flow-through systems, while others (Penobscot, Great South Channel) have more variable, branching pathways. Travel times for drifters that are retained within the coastal current along the entire western side of the Gulf of Maine are typically less than two months (55 days). Published by Elsevier Ltd. C1 [Manning, J. P.] NOAA, NE Fisheries Sci Ctr, Woods Hole, MA 02543 USA. [McGillicuddy, D. J., Jr.; Churchill, J. H.] Woods Hole Oceanog Inst, Woods Hole, MA 02543 USA. [Pettigrew, N. R.] Univ Maine, Sch Marine Sci, Orono, ME 04469 USA. [Incze, L. S.] Univ So Maine, Aquat Syst Grp, Portland, ME 04101 USA. RP Manning, JP (reprint author), NOAA, NE Fisheries Sci Ctr, 166 Water St, Woods Hole, MA 02543 USA. EM james.manning@noaa.gov; dmcgillicuddy@whoi.edu; nealp@maine.edu; jchurchill@whoi.edu; lincze@usm.maine.edu NR 33 TC 35 Z9 35 U1 2 U2 13 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0278-4343 J9 CONT SHELF RES JI Cont. Shelf Res. PD APR 15 PY 2009 VL 29 IS 7 BP 835 EP 845 DI 10.1016/j.csr.2008.12.008 PG 11 WC Oceanography SC Oceanography GA 438QU UT WOS:000265571300001 ER PT J AU Murphy, DM AF Murphy, Daniel M. TI Effect of Stratospheric Aerosols on Direct Sunlight and Implications for Concentrating Solar Power SO ENVIRONMENTAL SCIENCE & TECHNOLOGY LA English DT Article AB Light scattering calculations and data show that stratospheric aerosols reduce direct sunlight by about 4 W for every watt reflected to outer space. The balance becomes diffuse sunlight. One consequence of deliberate enhancement of the stratospheric aerosol layer would be a significant reduction in the efficiency of solar power generation systems using parabolic or other concentrating optics. There also would be a reduction in the effectiveness of passive solar design. C1 NOAA, Earth Syst Res Lab, Div Chem Sci, Boulder, CO 80305 USA. RP Murphy, DM (reprint author), NOAA, Earth Syst Res Lab, Div Chem Sci, 325 Broadway, Boulder, CO 80305 USA. EM daniel.m.murphy@noaa.gov RI Murphy, Daniel/J-4357-2012; Manager, CSD Publications/B-2789-2015 OI Murphy, Daniel/0000-0002-8091-7235; NR 11 TC 18 Z9 18 U1 0 U2 6 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0013-936X J9 ENVIRON SCI TECHNOL JI Environ. Sci. Technol. PD APR 15 PY 2009 VL 43 IS 8 BP 2784 EP 2786 DI 10.1021/es802206b PG 3 WC Engineering, Environmental; Environmental Sciences SC Engineering; Environmental Sciences & Ecology GA 432ZK UT WOS:000265172800022 PM 19475950 ER PT J AU Gurfinkel, M Potbhare, S Xiong, HD Suehle, JS Shapira, Y Lelis, AJ Habersat, D Goldsman, N AF Gurfinkel, M. Potbhare, S. Xiong, H. D. Suehle, J. S. Shapira, Yoram Lelis, A. J. Habersat, D. Goldsman, N. TI Ion implantation and SiC transistor performance SO JOURNAL OF APPLIED PHYSICS LA English DT Article DE annealing; electron mobility; interface states; ion implantation; MOSFET; oxidation; semiconductor doping; semiconductor epitaxial layers; silicon compounds; wide band gap semiconductors ID CHANNEL MOBILITY; 4H-SIC MOSFETS; MOS CAPACITORS; OXIDE; DMOSFETS; SILICON AB SiC metal oxide semiconductor field effect transistors grown on low-doped epilayer channels and on ion-implanted channels with either "as grown" or NO annealed thermal oxides have been electrically characterized. The threshold voltage, effective electron mobility, as well as fixed charge, oxide trap, and interface trap concentrations have been separately obtained using conventional dc sweep, capacitance-voltage (C-V), fast current-voltage (I-V), and low frequency noise measurements. The results show that devices with as grown SiO(2) have a much higher density of "slow" bulk oxide traps than devices after postoxidation annealing in NO. The oxide fixed charge density is unaffected by the annealing process. Devices fabricated on ion-implanted channels exhibit only a small increase in the slow bulk oxide trap density and the fixed charge. However, the density of the "fast" interface traps increases dramatically. This suggests that the damage due to the ion-implantation process is mainly interfacial. In contrast to Si devices, this ion-implantation damage is not completely repaired even after annealing. C1 [Gurfinkel, M.; Shapira, Yoram] Tel Aviv Univ, Sch Elect Engn, IL-69978 Tel Aviv, Israel. [Potbhare, S.; Goldsman, N.] Univ Maryland, College Pk, MD 20742 USA. [Xiong, H. D.; Suehle, J. S.] NIST, Div Semicond Elect, Gaithersburg, MD 20899 USA. [Lelis, A. J.; Habersat, D.] USA, Res Lab, Adelphi, MD 20783 USA. RP Gurfinkel, M (reprint author), Tel Aviv Univ, Sch Elect Engn, IL-69978 Tel Aviv, Israel. EM moshegur@post.tau.ac.il FU NIST Office of Microelectronics Programs (OMP) FX We would like to thank Cree, Inc. for supplying the samples for this work. This work was funded by the NIST Office of Microelectronics Programs (OMP). NR 14 TC 5 Z9 5 U1 3 U2 9 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 0021-8979 J9 J APPL PHYS JI J. Appl. Phys. PD APR 15 PY 2009 VL 105 IS 8 AR 084511 DI 10.1063/1.3110071 PG 4 WC Physics, Applied SC Physics GA 471NH UT WOS:000268064700169 ER PT J AU Hegaret, H da Silva, PM Sunila, I Shumway, SE Dixon, MS Alix, J Wikfors, GH Soudant, P AF Hegaret, Helene da Silva, Patricia Mirella Sunila, Inke Shumway, Sandra E. Dixon, Mark S. Alix, Jennifer Wikfors, Gary H. Soudant, Philippe TI Perkinsosis in the Manila clam Ruditapes philippinarum affects responses to the harmful-alga, Prorocentrum minimum SO JOURNAL OF EXPERIMENTAL MARINE BIOLOGY AND ECOLOGY LA English DT Article DE Bivalve; Harmful algal bloom; Hemocyte; Perkinsus olseni; Prorocentrum minimum; Ruditapes philippinarum ID FLOW-CYTOMETRIC ANALYSIS; CRASSOSTREA-VIRGINICA; EASTERN OYSTERS; IMMUNOLOGICAL PARAMETERS; VARYING PARASITE; CULTURED STRAIN; HEMOCYTES; PROTOZOAN; MARINUS; TAPES AB The dinoflagellate Prorocentrum minimum is increasingly recognized as a harmful algal bloom (HAB) species that affects filter-feeding shellfish. An experiment was done to investigate possible interactions between parasitic diseases and exposure to P. minimum in Manila clams, Ruditapes philippinarum. Manila clams, with variable levels of infection with Perkinsus olseni, were exposed for three or six days to the benign phytoplankton species Chaetoceros neogracile or a mixed diet of C. neogracile and P minimum. After three or six days of exposure, clams were assessed individually for condition index, parasite status, and plasma and hemocyte parameters (morphological and functional) using flow-cytometry. Histological evaluation was also performed on individual clams to assess prevalence and intensity of parasitic infection, as well as other pathological conditions. Prorocentrum minimum caused several changes in Manila clams, especially after six days of exposure, such as decreased hemocyte phagocytosis and size and clam condition index. Pathological conditions observed in Manila clams exposed to P. minimum were hemocyte infiltration in the intestine and gonad follicles, myopathy, and necrosis of the intestine epithelial cells. The parasite P. olseni alone had no significant effect on Manila clams, nor did it modulate the hemocyte variables in clams exposed to P. minimum; however, the parasite did affect the pathological status of Manila clams exposed to the P. minimum culture, by causing atrophy and degeneration of residual ova in the gonadal follicles and hyaline degeneration of the muscle fibers, indicating synergistic effects of both stressors on the host over a short period of time. Additionally, an in vitro experiment also demonstrated detrimental effects of P. minimum and exudates upon R olseni cells, thus suggesting HAB antagonistic suppression of transmission and proliferation of the parasite in the natural environment over a longer period of time. The results of this experiment demonstrate the complexity of interactions between host, parasite, and HAB. (C) 2009 Elsevier B.V. All rights reserved. C1 [Hegaret, Helene; Shumway, Sandra E.] Univ Connecticut, Dept Marine Sci, Groton, CT 06340 USA. [da Silva, Patricia Mirella; Soudant, Philippe] Univ Bretagne Occidentale, IUEM, LEMAR, CNRS,UMR 6539, F-29280 Plouzane, France. [Sunila, Inke] Bur Aquaculture, Dept Agr, Milford, CT 06460 USA. [Dixon, Mark S.; Alix, Jennifer; Wikfors, Gary H.] NOAA, NE Fisheries Sci Ctr, Natl Marine Fisheries Serv, Milford, CT 06460 USA. RP Hegaret, H (reprint author), Univ Connecticut, Dept Marine Sci, 1080 Shennecossett Rd, Groton, CT 06340 USA. EM helene.hegaret@gmail.com RI Hegaret, Helene/B-7206-2008 OI Hegaret, Helene/0000-0003-4639-9013 FU American Museum of Natural History; National Shellfisheries Association; Sigma Xi; Connecticut Sea Grant; EPA/ECOHAB [523792] FX We thank Marcos Paiva Scardua, Nelly Le Goic, Christophe Lambert, Thibaud de Bettignies, Hansy Haberkorn, Agnes Travers, Christian Mingant, Isabelle Queau, Stephane Pouvreau, jean Rene Le Coz, Philippe Miner, Alain Marhic, Anne Donval, and Barry C. Smith for their help during the experiment. This work was supported by the Lerner Gray Fund for Marine Research from the American Museum of Natural History, the National Shellfisheries Association, Sigma Xi, the Connecticut Sea Grant, and the EPA/ECOHAB grant number 523792. NR 48 TC 26 Z9 26 U1 0 U2 10 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-0981 EI 1879-1697 J9 J EXP MAR BIOL ECOL JI J. Exp. Mar. Biol. Ecol. PD APR 15 PY 2009 VL 371 IS 2 BP 112 EP 120 DI 10.1016/j.jembe.2009.01.016 PG 9 WC Ecology; Marine & Freshwater Biology SC Environmental Sciences & Ecology; Marine & Freshwater Biology GA 437DK UT WOS:000265466200002 ER PT J AU Lovejoy, S Tuck, AF Hovde, SJ Schertzer, D AF Lovejoy, S. Tuck, A. F. Hovde, S. J. Schertzer, D. TI Vertical cascade structure of the atmosphere and multifractal dropsonde outages SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID GRAVITY-WAVE SPECTRA; LIDAR DATA; UNIVERSAL SPECTRUM; STRATIFICATION; TEMPERATURE; TURBULENCE; DIMENSION; PROFILES; SHEETS AB We use 220 atmospheric profiles from state-of-the-art dropsondes to test the predictions of multiplicative cascade models of the atmosphere on the horizontal velocity, pressure, temperature, log potential temperature, log equivalent potential temperature, air density, humidity, and vertical sonde velocity. We found that the predictions were accurately verified (to within +/- 1 to +/- 2% over 10 m to 1 km for the statistical moments up to second order); the effective outer cascade scale L-eff was in the range 1-30 km. In order to perform the analyses and to correctly interpret the results, we needed to overcome technical difficulties caused by the sonde's highly intermittent sampling. This intermittency is the result of both data outages and variable sonde fall speeds; we (surprisingly) found that the outages also had a cascade structure. The wide-range scaling of the sampling rate implies a variable sonde resolution, so that interpolation onto regular grids should generally be avoided (e.g., it would give rise to serious artifacts in estimating the corresponding spectra). In earlier studies, before the cascade nature of the outages was understood, interpolation was avoided by studying the fluctuations using all the pairs of measurement points; this was adequate for fluctuation scaling exponents in the range 0 <= H <= 1. However, determining the cascade structure involves systematically degrading the resolution of fluxes (not fluctuations) so that the variable resolution and their attendant biases could not be avoided. We therefore developed a new method of estimating the fluxes and theoretically determined the corrections necessary to estimate the unbiased exponents. The resulting sonde cascade picture was given further support by (much more straightforward) analysis of uniformly sampled vertical cross sections of the atmosphere obtained from airborne lidar. Using the turbulent fluxes obtained from these various sources, we determined the corresponding cascade regimes and the corresponding exponents as well as the small deviations from the theoretical behavior. In addition to the fluxes, we also studied the fluctuations. To do this we generalized the data point pair method (restricted to nonconservation parameters 0 <= H <= 1) to data triplets (extending the method to 0 <= H <= 2). The resulting fluctuations were analyzed using (generalized) structure functions. We found that while the scaling of the fluxes often broke down at scales greater than about 1 km, the scaling of the fluctuations extended over the entire range 10 m to 10 km. C1 [Lovejoy, S.] McGill Univ, Dept Phys, Montreal, PQ H3A 2T8, Canada. [Tuck, A. F.; Hovde, S. J.] NOAA, Earth Syst Res Lab, Div Chem Sci, Boulder, CO 80305 USA. [Schertzer, D.] Univ Paris Est, CEREVE, F-77455 Marne La Vallee 2, France. [Schertzer, D.] Meteo France, Paris, France. RP Lovejoy, S (reprint author), McGill Univ, Dept Phys, 3600 Univ St, Montreal, PQ H3A 2T8, Canada. EM lovejoy@physics.mcgill.ca; dr.adrian.tuck@sciencespectrum.co.uk; Daniel.Schertzer@cereve.enpc.fr RI Lovejoy, Shaun/E-8019-2011; Tuck, Adrian/F-6024-2011; Manager, CSD Publications/B-2789-2015 OI Lovejoy, Shaun/0000-0002-9367-3137; Tuck, Adrian/0000-0002-2074-0538; NR 30 TC 17 Z9 17 U1 0 U2 0 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD APR 15 PY 2009 VL 114 AR D07111 DI 10.1029/2008JD010651 PG 17 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 435FH UT WOS:000265328800001 ER PT J AU Seo, DJ Cajina, L Corby, R Howieson, T AF Seo, Dong-Jun Cajina, Lee Corby, Robert Howieson, Tracy TI Automatic state updating for operational streamflow forecasting via variational data assimilation SO JOURNAL OF HYDROLOGY LA English DT Article DE Streamflow forecasting; Hydrologic modeling; Data assimilation; State updating; Parameter estimation ID PARAMETER-ESTIMATION; THEORETICAL ASPECTS; HYDROLOGIC MODEL; OPTIMIZATION; CALIBRATION; ADJOINT; PERFORMANCE; FILTER; RIVER; BIAS AB In operational hydrologic forecasting, to account for errors in the initial and boundary conditions, and in parameters and structures of the hydrologic models, the forecasters routinely make adjustments in real-time to the hydrometeorological input, hydrologic model states and, in certain cases, model parameters based on streamflow observations. Though a great deal of effort has been made in recent years to automate such "run-time modifications" (MOD) by human forecasters to a possible extent, automatic state updating of hydrologic models is yet to be widely accepted or routinely practiced in operational hydrology for a range of reasons. In this paper, we describe a state updating procedure intended specifically for operational streamflow forecasting for gauged headwater basins, and compare its performance with human forecaster MOD through a real-time forecasting experiment. The procedure is based on variational assimilation (VAR) of streamflow, precipitation and potential evaporation (PE) data into lumped soil moisture accounting and routing models operating at a 1-h timestep. The procedure has been in experimental operation since 2003 at the National Weather Service's (NWS) West Gulf River Forecast Center (WGRFC) in Fort Worth, TX. Also described is a novel parameter estimation and optimization tool, the Adjoint-Based OPTimizer (AB-OPT), used for lumped hydrologic modeling at a 1-h timestep necessary for VAR. (C) 2009 Elsevier B.V. All rights reserved. C1 [Seo, Dong-Jun; Cajina, Lee] NOAA, Natl Weather Serv, Off Hydrol Dev, Silver Spring, MD 20910 USA. [Seo, Dong-Jun] Univ Corp Atmospher Res, Boulder, CO USA. [Corby, Robert; Howieson, Tracy] NOAA, Natl Weather Serv, W Gulf River Forecast Ctr, Ft Worth, TX USA. RP Seo, DJ (reprint author), NOAA, Natl Weather Serv, Off Hydrol Dev, W OHD12,1325 East-West Highway, Silver Spring, MD 20910 USA. EM dongjun.seo@noaa.gov FU Advanced Hydrologic Prediction Service (AHPS) of the National Weather Service (NWS); Climate Prediction Program for the Americas (CPPA) of the Climate Program Office (NCPO); National Oceanic and Atmospheric Administration (NOAA); Integrated Systems Solutions component of the Decision Support through Earth Science Results Cooperative Agreement Notice (CAN) National Aeronautic and Space Administration (NASA) [NN-H-04-Z-YO-010-C] FX This work is supported the Advanced Hydrologic Prediction Service (AHPS) of the National Weather Service (NWS) and by the Climate Prediction Program for the Americas (CPPA) of the Climate Program Office (NCPO), both of the National Oceanic and Atmospheric Administration (NOAA), and by the Integrated Systems Solutions component of the Decision Support through Earth Science Results Cooperative Agreement Notice (CAN) NN-H-04-Z-YO-010-C of the National Aeronautic and Space Administration (NASA). These supports are gratefully acknowledged. This paper has benefited greatly from the comments of two anonymous reviewers. NR 45 TC 59 Z9 60 U1 1 U2 15 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0022-1694 J9 J HYDROL JI J. Hydrol. PD APR 15 PY 2009 VL 367 IS 3-4 BP 255 EP 275 DI 10.1016/j.jhydrol.2009.01.019 PG 21 WC Engineering, Civil; Geosciences, Multidisciplinary; Water Resources SC Engineering; Geology; Water Resources GA 432IC UT WOS:000265125700009 ER PT J AU Hyett, G Green, MA Parkin, IR AF Hyett, Geoffrey Green, Mark A. Parkin, Ivan R. TI Ultra-violet light activated photocatalysis in thin films of the titanium oxynitride, Ti3-delta O4N SO JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY LA English DT Article DE Photocatalysis; Titanium oxynitirde; Titanium dioxide; Raman; X-ray diffraction ID CHEMICAL-VAPOR-DEPOSITION; SEMICONDUCTOR PHOTOCATALYSIS; TIO2; GLASS; WATER; ORIENTATION; APCVD AB A film of the recently reported material Ti3-delta O4N has been shown to be more photocatalytically active than a comparable film of TiO2. The photocatalytic ability was determined using the stearic acid degradation test with 254 nm UV light. Both films were made using atmospheric pressure chemical vapour deposition (APCVD) at 630 C from titanium (IV) chloride and ethyl acetate, with the oxynitride additionally using ammonia as a nitrogen Source. The films were characterised by XRD and spectroscopic methods. The Raman pattern of Ti3-delta O4N is also reported here for the first time. (C) 2009 Elsevier B.V. All rights reserved. C1 [Hyett, Geoffrey; Parkin, Ivan R.] UCL, Christopher Ingold Lab, London WC1H 0AJ, England. [Green, Mark A.] Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. RP Parkin, IR (reprint author), UCL, Christopher Ingold Lab, 20 Gordon St, London WC1H 0AJ, England. EM i.p.parkin@ucl.ac.uk RI Hyett, Geoffrey/C-1793-2008; OI Hyett, Geoffrey/0000-0001-9302-9723; Parkin, Ivan/0000-0002-4072-6610 NR 22 TC 18 Z9 18 U1 1 U2 7 PU ELSEVIER SCIENCE SA PI LAUSANNE PA PO BOX 564, 1001 LAUSANNE, SWITZERLAND SN 1010-6030 J9 J PHOTOCH PHOTOBIO A JI J. Photochem. Photobiol. A-Chem. PD APR 15 PY 2009 VL 203 IS 2-3 BP 199 EP 203 DI 10.1016/j.jphotochem.2009.01.020 PG 5 WC Chemistry, Physical SC Chemistry GA 439WT UT WOS:000265659000019 ER PT J AU Yi, Z Nagao, M Bossev, DP AF Yi, Zheng Nagao, Michihiro Bossev, Dobrin P. TI Bending elasticity of saturated and monounsaturated phospholipid membranes studied by the neutron spin echo technique SO JOURNAL OF PHYSICS-CONDENSED MATTER LA English DT Article ID LIPID-BILAYER; CHAIN-LENGTH; BIOLOGICAL MEMBRANES; SPECTROSCOPY; THICKNESS; VESICLES; PROTEIN; MODEL; PHOSPHATIDYLCHOLINE; UNSATURATION AB We have used neutron spin echo (NSE) spectroscopy to study the effect of bilayer thickness and monounsaturation (existence of a single double bond on one of the aliphatic chains) on the physical properties of unilamellar vesicles. The bending elasticity of saturated and monounsaturated phospholipid bilayers made of phospholipids with alkyl chain length ranging from 14 to 20 carbons was investigated. The bending elasticity kappa(c) of phosphatidylcholines (PCs) in the liquid crystalline (L(alpha)) phase ranges from 0.38 x 10(-19) J for 1,2-dimyristoyl-sn-glycero-3-phosphocholine to 0.64 x 10(-19) J for 1,2-dieicosenoyl-sn-glycero-3-phosphocholine. It was confirmed that, contrary to the strong effect on the main transition temperature, the monounsaturation has a limited influence on the bending elasticity of lipid bilayers. In addition, when the area modulus K(A) varies little with chain unsaturation or length, the elastic ratios(kappa c/K(A))(1/2) of saturated and monounsaturated phospholipid bilayers varies linearly with lipid hydrophobic thickness d which agrees well with the theory of ideal fluid membranes. C1 [Yi, Zheng; Bossev, Dobrin P.] Indiana Univ, Dept Phys, Bloomington, IN 47405 USA. [Yi, Zheng; Nagao, Michihiro] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Nagao, Michihiro] Indiana Univ, Cyclotron Facil, Bloomington, IN 47408 USA. RP Yi, Z (reprint author), Indiana Univ, Dept Phys, Bloomington, IN 47405 USA. EM dbossev@indiana.edu RI Yi, Zheng/F-7539-2011; Wunder, Stephanie/B-5066-2012; Zdilla, Michael/B-4145-2011 FU National Science Foundation [DMR-0454672] FX This work utilized facilities supported in part by the National Science Foundation under Agreement No. DMR-0454672. We acknowledge the support of the National Institute of Standards and Technology, US Department of Commerce, in providing the neutron research facilities used in this work. We thank Antonio Faraone for valuable discussions and his help with the data collection at NCNR and Larry Kneller for his support in our data analysis. NR 38 TC 30 Z9 30 U1 2 U2 23 PU IOP PUBLISHING LTD PI BRISTOL PA DIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND SN 0953-8984 J9 J PHYS-CONDENS MAT JI J. Phys.-Condes. Matter PD APR 15 PY 2009 VL 21 IS 15 AR 155104 DI 10.1088/0953-8984/21/15/155104 PG 7 WC Physics, Condensed Matter SC Physics GA 426LA UT WOS:000264708600004 PM 21825357 ER PT J AU Rukhin, AL AF Rukhin, Andrew L. TI Identities for negative moments of quadratic forms in normal variables SO STATISTICS & PROBABILITY LETTERS LA English DT Article ID RATIOS AB Two formulas for the central inverse moments of a quadratic form in normal variables and of the ratio of such forms are established. They relate the quadratic form determined by a positive definite matrix to that defined by the inverse matrix. Published by Elsevier B.V. C1 Univ Maryland Baltimore Cty, Stat Engn Div, NIST, Gaithersburg, MD 20899 USA. RP Rukhin, AL (reprint author), Univ Maryland Baltimore Cty, Stat Engn Div, NIST, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM andrew.rukhin@nist.gov NR 8 TC 0 Z9 0 U1 0 U2 0 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0167-7152 J9 STAT PROBABIL LETT JI Stat. Probab. Lett. PD APR 15 PY 2009 VL 79 IS 8 BP 1004 EP 1007 DI 10.1016/j.spl.2008.12.004 PG 4 WC Statistics & Probability SC Mathematics GA 429UR UT WOS:000264946100002 ER PT J AU Paddack, MJ Reynolds, JD Aguilar, C Appeldoorn, RS Beets, J Burkett, EW Chittaro, PM Clarke, K Esteves, R Fonseca, AC Forrester, GE Friedlander, AM Garcia-Sais, J Gonzalez-Sanson, G Jordan, LKB McClellan, DB Miller, MW Molloy, PP Mumby, PJ Nagelkerken, I Nemeth, M Navas-Camacho, R Pitt, J Polunin, NVC Reyes-Nivia, MC Robertson, DR Rodriguez-Ramirez, A Salas, E Smith, SR Spieler, RE Steele, MA Williams, ID Wormald, CL Watkinson, AR Cote, IM AF Paddack, Michelle J. Reynolds, John D. Aguilar, Consuelo Appeldoorn, Richard S. Beets, Jim Burkett, Edward W. Chittaro, Paul M. Clarke, Kristen Esteves, Rene Fonseca, Ana C. Forrester, Graham E. Friedlander, Alan M. Garcia-Sais, Jorge Gonzalez-Sanson, Gaspar Jordan, Lance K. B. McClellan, David B. Miller, Margaret W. Molloy, Philip P. Mumby, Peter J. Nagelkerken, Ivan Nemeth, Michael Navas-Camacho, Raul Pitt, Joanna Polunin, Nicholas V. C. Reyes-Nivia, Maria Catalina Robertson, D. Ross Rodriguez-Ramirez, Alberto Salas, Eva Smith, Struan R. Spieler, Richard E. Steele, Mark A. Williams, Ivor D. Wormald, Clare L. Watkinson, Andrew R. Cote, Isabelle M. TI Recent Region-wide Declines in Caribbean Reef Fish Abundance SO CURRENT BIOLOGY LA English DT Article ID GREAT-BARRIER-REEF; MASS MORTALITY; CORAL-REEFS; DIADEMA-ANTILLARUM; TROPHIC CASCADES; MARINE RESERVES; PROTECTED AREAS; COMMUNITIES; POPULATIONS; ECOSYSTEMS AB Profound ecological changes are occurring on coral reefs throughout the tropics [1-3], with marked coral cover losses and concomitant algal increases, particularly in the Caribbean region [4]. Historical declines in the abundance of large Caribbean reef fishes likely reflect centuries of overexploitation [5-7]. However, effects of drastic recent degradation of reef habitats on reef fish assemblages have yet to be established. By using meta.-analysis, we analyzed time series of reef fish density obtained from 48 studies that include 318 reefs across the Caribbean and span the time period 1955-2007. Our analyses show that overall reef fish density has been declining significantly for more than a decade, at rates that are consistent across all subregions of the Caribbean basin (2.7% to 6.0% loss per year) and in three of six trophic groups. Changes in fish density over the past half-century are modest relative to concurrent changes in benthic cover on Caribbean reefs. However, the recent significant decline in overall fish abunclance and its consistency across several trophic groups. and among both fished and nonfished species indicate that Caribbean fishes have begun to respond negatively to habitat degradation. C1 [Paddack, Michelle J.; Reynolds, John D.; Molloy, Philip P.; Cote, Isabelle M.] Simon Fraser Univ, Dept Biol Sci, Burnaby, BC V5A 1S6, Canada. [Paddack, Michelle J.; Watkinson, Andrew R.] Univ E Anglia, Sch Environm Sci, Norwich NR4 7TJ, Norfolk, England. [Aguilar, Consuelo; Gonzalez-Sanson, Gaspar] Univ La Habana, Ctr Invest Marinas, Havana, Cuba. [Appeldoorn, Richard S.; Esteves, Rene; Garcia-Sais, Jorge; Nemeth, Michael] Univ Puerto Rico, Dept Marine Sci, Mayaguez, PR 00681 USA. [Beets, Jim] Univ Hawaii, Dept Marine Sci, Hilo, HI 96720 USA. [Burkett, Edward W.] Univ Wisconsin, Dept Biol & Earth Sci, Superior, WI 54880 USA. [Chittaro, Paul M.] Natl Marine Fisheries Serv, NW Fisheries Sci Ctr, Seattle, WA 98112 USA. [Clarke, Kristen] Univ W Indies, Ctr Marine Sci, Mona, Jamaica. [Fonseca, Ana C.; Salas, Eva] Univ Costa Rica, Ctr Invest Ciencias Mar & Limnol, San Jose, Costa Rica. [Forrester, Graham E.] Univ Rhode Isl, Dept Nat Resources Sci, Kingston, RI 02881 USA. [Friedlander, Alan M.] Univ Hawaii, Dept Zool, Hawaii Cooperat Fishery Res Unit, Honolulu, HI 96822 USA. [Jordan, Lance K. B.; Spieler, Richard E.] Nova SE Univ, Oceanog Ctr, Dania, FL 33004 USA. [Jordan, Lance K. B.; Spieler, Richard E.] Nova SE Univ, Natl Coral Reef Inst, Dania, FL 33004 USA. [McClellan, David B.; Miller, Margaret W.] NOAA Fisheries, SE Fisheries Sci Ctr, Miami, FL 33149 USA. [Mumby, Peter J.] Univ Exeter, Marine Spatial Ecol Lab, Sch BioSci, Exeter EX4 4PS, Devon, England. [Nagelkerken, Ivan] Radboud Univ Nijmegen, Fac Sci, Inst Water & Wetland Res, Dept Anim Ecol & Ecophysiol, NL-6500 GL Nijmegen, Netherlands. [Navas-Camacho, Raul; Reyes-Nivia, Maria Catalina; Rodriguez-Ramirez, Alberto] Inst Invest Marinas & Costeras INVEMAR, Programa Biodiversidad & Ecosistemas Marinos, Santa Marta, Colombia. [Pitt, Joanna] Bermuda Govt, Environm Protect Dept, Marine Resources Sect, Coney Isl, Bermuda. [Polunin, Nicholas V. C.] Newcastle Univ, Sch Marine Sci & Technol, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England. [Reyes-Nivia, Maria Catalina] Univ Amsterdam, Inst Biodivers & Ecosyst Dynam, NL-1090 GT Amsterdam, Netherlands. [Robertson, D. Ross] Smithsonian Trop Res Inst Panama, Unit 0948, Miami, FL 34002 USA. [Smith, Struan R.] Georgia State Univ, Dept Biol, Atlanta, GA 30302 USA. [Steele, Mark A.; Wormald, Clare L.] Calif State Univ Northridge, Dept Biol, Northridge, CA 91330 USA. [Williams, Ivor D.] Hawaii Cooperat Fishery Res Unit, Kailua Kona, HI 96740 USA. [Williams, Ivor D.] Hawaii Div Aquat Resources, Kailua Kona, HI 96740 USA. RP Paddack, MJ (reprint author), Simon Fraser Univ, Dept Biol Sci, Burnaby, BC V5A 1S6, Canada. EM michelle.paddack@gmail.com RI Mumby, Peter/F-9914-2010; Nagelkerken, Ivan/E-1093-2011; Watkinson, Andrew/N-1649-2013; Reynolds, John/L-6345-2015; OI Nagelkerken, Ivan/0000-0003-4499-3940; Reynolds, John/0000-0002-0459-0074; Salas De la Fuente, Eva Maria/0000-0002-6941-0548; Forrester, Graham/0000-0001-5253-773X; Gonzalez-Sanson, Gaspar/0000-0002-8555-2685 FU UK's Natural Environment Resource Council [NE/CO04442/1]; National Park Service, USGS; NOAA- Biogeography Branch; National Science and Engineering Research Council of Canada [OGP01 5284]; Puerto Rico National Coral Reef Monitoring Program; Department of Natural and Environmental Resources; Lianna Jarecki for logistical support; NOAA Coral Reef Conservation Program; BBSRC (Biotechnology and Biological Sciences Research Council) [01/Al/S/08113]; Netherlands Organisation for Scientific Research; MAVDT; COLCIENCIAS; UNEP-CAR/RCU; CORALINA; CEINER; UAESPNN; CARICOMP; UK DFID; The Smithsonian Tropical Research Institute; Government of the Republic of Panama; Kuna General Congress FX This project was funded by the UK's Natural Environment Resource Council, NE/CO04442/1. J.B. and A.M.F. acknowledge the National Park Service, USGS, and NOAA- Biogeography Branch. P.M.C. was supported by the National Science and Engineering Research Council of Canada (Grant # OGP01 5284). R.E. and J.G.-S. were supported by the Puerto Rico National Coral Reef Monitoring Program sponsored by NOAA and administered by the P.R. Department of Natural and Environmental Resources (PRIDNER). A.C.F. and E.S. thank CARICOMP and Jorge Cortes. G.E.F. acknowledges Falconwood Corporation for funding and Lianna Jarecki for logistical support. M.W.M. and D.B.M. were supported by NOAA Coral Reef Conservation Program. P.P.M. was supported by BBSRC (Biotechnology and Biological Sciences Research Council) studentship # 01/Al/S/08113 and the John and Pamela Salter Charitable Trust. I.N. was supported by a Vidi grant from the Netherlands Organisation for Scientific Research (NWO). M.G.G. Grol is thanked for help with the field work in Grand Cayman. R.N.-C., A.R.-R., and M.C.R.-N. were funded by MAVDT, COLCIENCIAS. and UNEP-CAR/RCU. CORALINA, CEINER, UAESPNN, and CARICOMP contributed with funds and logistical support. N.V.C.P. was supported by UK DFID. D.R.R. was supported by The Smithsonian Tropical Research Institute, the Government of the Republic of Panama, the Kuna General Congress. Field assistance to D.R.R.: E. Pena, A. Cedeno. M.A.S., C.L.W., and G.E.F. appreciate long-term financial support from the National Science Foundation; financial and logistical support from the NOAA National Undersea Research Program; and the help of numerous field assistants. I.M.C. was supported by the National Science and Engineering Research Council of Canada. NR 48 TC 121 Z9 124 U1 3 U2 73 PU CELL PRESS PI CAMBRIDGE PA 600 TECHNOLOGY SQUARE, 5TH FLOOR, CAMBRIDGE, MA 02139 USA SN 0960-9822 EI 1879-0445 J9 CURR BIOL JI Curr. Biol. PD APR 14 PY 2009 VL 19 IS 7 BP 590 EP 595 DI 10.1016/j.cub.2009.02.041 PG 6 WC Biochemistry & Molecular Biology; Cell Biology SC Biochemistry & Molecular Biology; Cell Biology GA 434HX UT WOS:000265266900029 PM 19303296 ER PT J AU Akmaev, RA Wu, F Fuller-Rowell, TJ Wang, H AF Akmaev, R. A. Wu, F. Fuller-Rowell, T. J. Wang, H. TI Midnight temperature maximum (MTM) in Whole Atmosphere Model (WAM) simulations SO GEOPHYSICAL RESEARCH LETTERS LA English DT Article ID THERMOSPHERE; WINDS AB Discovered almost four decades ago, the midnight temperature maximum (MTM) with typical magnitudes of 50-100 K has been regularly observed by satellite and ground-based instruments in the tropical upper thermosphere. Although several mechanisms have been suggested to explain the phenomenon, previous attempts to reproduce it with comprehensive thermosphere-ionosphere models have been unsuccessful. First long-term simulations with the Whole Atmosphere Model (WAM) reveal the presence of a realistically prominent MTM and reproduce the salient features of its daily, seasonal, and latitudinal variability. Preliminary analysis indicates that the feature may be traced down to the lower thermosphere, where it is manifested primarily in the form of an upward propagating terdiurnal tidal wave. Its spectrum expands to higher-order zonal wavenumbers and frequencies and its phase advances to near midnight higher up in the thermosphere. Possible mechanisms generating this wave may involve nonlinear interactions between other tidal harmonics originating in the middle and lower atmosphere. Our results thus suggest that the MTM is yet another phenomenon driven by dynamical links between the lower and upper atmosphere and ionosphere. Citation: Akmaev, R. A., F. Wu, T. J. Fuller-Rowell, and H. Wang (2009), Midnight temperature maximum (MTM) in Whole Atmosphere Model (WAM) simulations, Geophys. Res. Lett., 36, L07108, doi:10.1029/2009GL037759. C1 [Akmaev, R. A.] NOAA, Space Weather Predict Ctr, Boulder, CO 80305 USA. [Wu, F.; Fuller-Rowell, T. J.; Wang, H.] Univ Colorado, CIRES, Boulder, CO 80309 USA. RP Akmaev, RA (reprint author), NOAA, Space Weather Predict Ctr, W-NP9,325 Broadway, Boulder, CO 80305 USA. EM rashid.akmaev@noaa.gov FU NASA; Air Force Office of Scientific Research (AFOSR) FX We thank H. J. Singer and an anonymous reviewer for helpful comments. This work has been supported by the NASA Heliophysics Theory and Living With a Star (LWS) programs as well as the Air Force Office of Scientific Research (AFOSR) Multidisciplinary University Research Initiative (MURI) program. NR 16 TC 25 Z9 25 U1 0 U2 2 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0094-8276 J9 GEOPHYS RES LETT JI Geophys. Res. Lett. PD APR 14 PY 2009 VL 36 AR L07108 DI 10.1029/2009GL037759 PG 5 WC Geosciences, Multidisciplinary SC Geology GA 435EW UT WOS:000265327700008 ER PT J AU Grieshaber, SE Farran, AJE Lin-Gibson, S Kiick, KL Jia, XQ AF Grieshaber, Sarah E. Farran, Alexandra J. E. Lin-Gibson, Sheng Kiick, Kristi L. Jia, Xinqiao TI Synthesis and Characterization of Elastin-Mimetic Hybrid Polymers with Multiblock, Alternating Molecular Architecture and Elastomeric Properties SO MACROMOLECULES LA English DT Article ID STRESS-STRAIN BEHAVIOR; HUMAN VOCAL FOLDS; CLICK CHEMISTRY; BLOCK-COPOLYMERS; MECHANICAL-PROPERTIES; RAFT POLYMERIZATION; HUMAN TROPOELASTIN; CROSS-LINKING; PROTEIN; TISSUE AB We are interested in developing elastin-mimetic hybrid polymers (EMHPs) that capture the multiblock molecular architecture of tropoelastin as well as the remarkable elasticity of mature elastin. In this study, multiblock EMHPs containing flexible synthetic segments based on poly(ethylene glycol) (PEG) alternating with alanine-rich, lysine-containing peptides were synthesized by step-growth polymerization using alpha,omega-azido-PEG and alkyne-terminated AKA(3)KA (K = lysine, A = alanine) peptide, employing orthogonal click chemistry. The resulting EMHPs contain an estimated three to five repeats of PEG and AKA3KA and have an average molecular weight of 34 kDa. While the peptide alone exhibited alpha-helical structures at high pH, the fractional helicity for EMHPs was reduced. Covalent cross-linking of EMHPs with hexamethylene diisocyanate (HMDI) through the lysine residue in the peptide domain afforded an elastomeric hydrogel (xEMHP) with a compressive modulus of 0.12 MPa when hydrated. The mechanical properties of xEMHP are comparable to a commercial polyurethane elastomer (Tecoflex SG80A) under the same conditions. In vitro toxicity studies showed that while the soluble EMHPs inhibited the growth of primary porcine vocal fold fibroblasts (PVFFs) at concentrations > 0.2 mg/mL, the cross-linked hybrid elastomers did not leach out any toxic reagents and allowed PVFFs to grow and proliferate normally. The hybrid and modular approach provides a new strategy for developing elastomeric scaffolds for tissue engineering. C1 [Grieshaber, Sarah E.; Farran, Alexandra J. E.; Kiick, Kristi L.; Jia, Xinqiao] Univ Delaware, Dept Mat Sci & Engn, Delaware Biotechnol Inst, Newark, DE 19716 USA. [Lin-Gibson, Sheng] NIST, Div Polymers, Gaithersburg, MD 20899 USA. RP Kiick, KL (reprint author), Univ Delaware, Dept Mat Sci & Engn, Delaware Biotechnol Inst, Newark, DE 19716 USA. EM kiick@udel.edu; xjia@udel.edu FU NSF/DMR Biomaterials Program [0643226]; NSF-Integrative Graduate Education & Research Traineeship (IGERT) program; National Institute of Health [R01 DC008965, 2P20P-R017716]; Center for Neutron Science at the University of Delaware [70NANB7H6178] FX We thank Carl Giller for his help with acquiring the ATR-IR spectrum, The authors thank the NSF/DMR Biomaterials Program (Jia, Career: 0643226) and the NSF-Integrative Graduate Education & Research Traineeship (IGERT) program for funding. This work was also supported in part by National Institute of Health (R01 DC008965, 2P20P-R017716) and the Center for Neutron Science at the University of Delaware (US Department of Commerce, #70NANB7H6178). NR 71 TC 52 Z9 53 U1 7 U2 70 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0024-9297 J9 MACROMOLECULES JI Macromolecules PD APR 14 PY 2009 VL 42 IS 7 BP 2532 EP 2541 DI 10.1021/ma802791z PG 10 WC Polymer Science SC Polymer Science GA 430MD UT WOS:000264992300033 PM 19763157 ER PT J AU Doe, C Jang, HS Kline, SR Choi, SM AF Doe, Changwoo Jang, Hyung-Sik Kline, Steven R. Choi, Sung-Min TI Subdomain Structures of Lamellar and Reverse Hexagonal Pluronic Ternary Systems Investigated by Small Angle Neutron Scattering SO MACROMOLECULES LA English DT Article ID AMPHIPHILIC BLOCK-COPOLYMERS; PHASE-BEHAVIOR; SELECTIVE SOLVENTS; MICELLAR-SOLUTIONS; WATER; OIL; SIZE; MICROEMULSIONS; NANOPARTICLES; TEMPERATURE AB The subdomain Structures of lamellar and reverse hexagonal phases of P84/water/p-xylene ternary system have been investigated by contrast varied small angle neutron scattering (SANS) measurements. As the neutron scattering length density of either polar or apolar domain was varied, the scattering intensities of the first Bragg peaks changed as expected, but the intensities of the second Bragg peaks did not change significantly. This variation of the relative peak intensities can not be explained by the typical simple models where the polar and apolar domains are regarded as homogeneous Mixtures of PEO + water and PPO + oil, respectively, in which case the relative intensities of Bragg peaks do not change. For both lamellar and reverse hexagonal Pluronic ternary systems, the analysis of the contrast varied SANS intensities with subdomain structure models reproduce the experimental data very successfully, showing that a water-rich layer exists in the middle of the polar domain and water- and oil-depleted layers exist at the polar/apolar interfaces. C1 [Doe, Changwoo; Jang, Hyung-Sik; Choi, Sung-Min] Korea Adv Inst Sci & Technol, Dept Nucl & Quantum Engn, Taejon 305701, South Korea. [Kline, Steven R.] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. RP Choi, SM (reprint author), Korea Adv Inst Sci & Technol, Dept Nucl & Quantum Engn, 373-1 Guseong Dong, Taejon 305701, South Korea. EM sungmin@kaist.ac.kr RI Do, Changwoo/A-9670-2011 OI Do, Changwoo/0000-0001-8358-8417 FU Ministry of Education, Science and Technology of Korea through the Basic Atomic Energy Research Institute (BAERI) program; basic science research program [R01-2008-000-10219-0]; CNRF; National Science Foundation [DMR-0454672] FX This work is supported by the Ministry of Education, Science and Technology of Korea through the Basic Atomic Energy Research Institute (BAERI) program, the basic science research program (R01-2008-000-10219-0), and the CNRF project. We thank M.-J. Woo, M.-H. Lee, and H.-S. Kim for their assistance with the X-ray measurements. This work utilized facilities supported in part by the National Science Foundation under Agreement No. DMR-0454672. The mention of commercial products does not imply endorsement by NIST, nor does it imply that the materials or equipment identified are necessarily the best available for the purpose. NR 33 TC 4 Z9 4 U1 0 U2 5 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0024-9297 J9 MACROMOLECULES JI Macromolecules PD APR 14 PY 2009 VL 42 IS 7 BP 2645 EP 2650 DI 10.1021/ma802296u PG 6 WC Polymer Science SC Polymer Science GA 430MD UT WOS:000264992300047 ER PT J AU Page, KA Park, JK Moore, RB Sakai, VG AF Page, Kirt A. Park, Jong Kenn Moore, Robert B. Sakai, Victoria Garcia TI Direct Analysis of the Ion-Hopping Process Associated with the alpha-Relaxation in Perfluorosulfonate Ionomers Using Quasielastic Neutron Scattering SO MACROMOLECULES LA English DT Article ID SULFONATED POLYSTYRENE IONOMERS; GLASS-TRANSITION; ACID IONOMER; VISCOELASTIC PROPERTIES; NAFION MEMBRANE; MELT RHEOLOGY; DYNAMICS; BEHAVIOR; ELECTROLYTE; DIFFUSION AB This work demonstrates the ability of quasielastic neutron scattering (QENS) to measure the dynamics associated with counterions in perfluorosulfonate ionomers (PFSIs). PFSI membranes were prepared by neutralizing with hydrogenated alkyl ammonium counterions. Counterion dynamics were measured using the High-Flux Backscattering Spectrometer at the National Institute of Standards and Technology (NIST) Center for Neutron Research (NCNR). Long-range mobility of the counterions was closely linked with the alpha-relaxation in these materials measured by dynamic mechanical analysis (DMA). The counterion motions in the membrane were found to follow a mechanism of random jump-diffusion within a confined spatial region with diffusion coefficients on the order of 10(-7) cm(2) s(-1). These data are presented along with variable temperature X-ray scattering investigations of the melting behavior of these materials. Altogether, the data presented here show the link between the onset of long-range counterion mobility and the mechanical properties of these materials. These data provide further fundamental understanding of the link between electrostatic interactions and dynamics in PFSI materials. C1 [Page, Kirt A.] Natl Inst Stand & Technol, Div Polymer, Gaithersburg, MD 20899 USA. [Park, Jong Kenn; Moore, Robert B.] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA. [Sakai, Victoria Garcia] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Sakai, Victoria Garcia] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. RP Page, KA (reprint author), Natl Inst Stand & Technol, Div Polymer, Gaithersburg, MD 20899 USA. EM kirt.page@nist.gov RI Moore, Robert/E-9619-2011 OI Moore, Robert/0000-0001-9057-7695 FU National Research Council-NIST Associateship; National Science Foundation [CMMI-0707364, CBET-0756439]; National Science Foundation under Agreement [DMR-0454672]; U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]; U.S. Department of Energy, Division of Materials Sciences and Division of Chemical Sciences [DE-AC02-98CCCCH10886] FX K.A.P. gratefully acknowledges support from the National Research Council-NIST Associateship program. Additional support for this work has been provided by the National Science Foundation CMMI-0707364 and CBET-0756439. This work utilized facilities supported in part by the National Science Foundation under Agreement No. DMR-0454672. Use of the Advanced Photon Source was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. SAXS data was collected at the National Synchrotron Light Source, Brookhaven National Laboratory (supported in part by the U.S. Department of Energy, Division of Materials Sciences and Division of Chemical Sciences, under Contract No. DE-AC02-98CCCCH10886). Certain equipment, instruments, or materials are identified in this paper in order to adequately specify the experimental details. Such identification does not imply recommendation by the National Institute of Standards and Technology nor does it imply the materials are necessarily the best available for the purpose. NR 51 TC 29 Z9 30 U1 1 U2 23 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0024-9297 J9 MACROMOLECULES JI Macromolecules PD APR 14 PY 2009 VL 42 IS 7 BP 2729 EP 2736 DI 10.1021/ma801533h PG 8 WC Polymer Science SC Polymer Science GA 430MD UT WOS:000264992300059 ER PT J AU Schafer, D Gibson, EA Salim, EA Palmer, AE Jimenez, R Squier, J AF Schafer, Dawn Gibson, Emily A. Salim, Evan A. Palmer, Amy E. Jimenez, Ralph Squier, Jeff TI Microfluidic cell counter with embedded optical fibers fabricated by femtosecond laser ablation and anodic bonding SO OPTICS EXPRESS LA English DT Article ID FLUORESCENCE DETECTION SYSTEM; ON-A-CHIP; FLOW CYTOMETERS; FUSED-SILICA; INTEGRATION; POLY(DIMETHYLSILOXANE); NETWORKS; DEVICES; LIGHT AB A simple fabrication technique to create all silicon/glass microfluidic devices is demonstrated using femtosecond laser ablation and anodic bonding. In a first application, we constructed a cell counting device based on small angle light scattering. The counter featured embedded optical fibers for multiangle excitation and detection of scattered light and/or fluorescence. The performance of the microfluidic cell counter was benchmarked against a commercial fluorescence-activated cell sorter. (C) 2009 Optical Society of America C1 [Schafer, Dawn; Squier, Jeff] Colorado Sch Mines, Dept Phys, Golden, CO 80401 USA. [Gibson, Emily A.; Palmer, Amy E.; Jimenez, Ralph] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA. [Salim, Evan A.] Univ Colorado, Dept Phys, Boulder, CO 80309 USA. [Salim, Evan A.; Jimenez, Ralph] Natl Inst Stand & Technol, Boulder, CO 80309 USA. [Salim, Evan A.; Jimenez, Ralph] Univ Colorado, JILA, Boulder, CO 80309 USA. RP Schafer, D (reprint author), Colorado Sch Mines, Dept Phys, Golden, CO 80401 USA. EM dschafer@mines.edu FU NIGMS NIH HHS [GM084027, R01 GM084027, R01 GM084027-02] NR 24 TC 25 Z9 25 U1 4 U2 15 PU OPTICAL SOC AMER PI WASHINGTON PA 2010 MASSACHUSETTS AVE NW, WASHINGTON, DC 20036 USA SN 1094-4087 J9 OPT EXPRESS JI Opt. Express PD APR 13 PY 2009 VL 17 IS 8 BP 6068 EP 6073 DI 10.1364/OE.17.006068 PG 6 WC Optics SC Optics GA 432BQ UT WOS:000265108900020 PM 19365429 ER PT J AU Chen, J Pearlman, AJ Ling, A Fan, JY Migdall, A AF Chen, Jun Pearlman, Aaron J. Ling, Alexander Fan, Jingyun Migdall, Alan TI A versatile waveguide source of photon pairs for chip-scale quantum information processing SO OPTICS EXPRESS LA English DT Article ID PARAMETRIC DOWN-CONVERSION; DISPERSION-SHIFTED FIBER; 2ND HARMONIC-GENERATION; ENTANGLED PHOTONS; HIGH-EFFICIENCY; DOWNCONVERSION; NOISE; KTP AB We demonstrate a bright, bandwidth-tunable, quasi-phase-matched single-waveguide source generating photon pairs near 900 nm and 1300 nm. Two-photon coincidence spectra are measured at a range of operating temperatures of a periodically-poled KTiOPO4 (PPKTP) waveguide, which supports both type-0 and type-II spontaneous parametric down-conversion. We map out relative contributions of two-photon to one-photon fluorescence for a range of operating parameters. Such a versatile device is highly promising for future chip-scale quantum information processing. Work of U. S. government; not subject to U. S. copyright. C1 [Chen, Jun; Pearlman, Aaron J.; Ling, Alexander; Fan, Jingyun; Migdall, Alan] Natl Inst Stand & Technol, Opt Technol Div, Gaithersburg, MD 20899 USA. [Chen, Jun; Ling, Alexander; Fan, Jingyun; Migdall, Alan] Univ Maryland, Joint Quantum Inst, College Pk, MD 20742 USA. RP Chen, J (reprint author), Natl Inst Stand & Technol, Opt Technol Div, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM jun.chen@nist.gov; jfan@nist.gov RI Pearlman, Aaron/L-8912-2013; Ling, Alexander/G-7331-2012 OI Pearlman, Aaron/0000-0002-4498-2208; Ling, Alexander/0000-0001-5866-1141 FU University Research Initiative Center for Photonic Quantum Information Systems [DAAD19- 03-1-0199] FX We thank Dr. Tracy Clement for supplying the Matlab codes for calculating the Schmidt numbers and the values for entropy of entanglement, and Dr. Sergey Polyakov and Dr. Wei Fang for helpful discussions. This work has been supported in part by the Intelligence Advanced Research Projects Activity (IARPA) Polarization-Entangled Photon Source Program, and the Multidisciplinary University Research Initiative Center for Photonic Quantum Information Systems (Army Research Office/ IARPA program DAAD19- 03-1-0199). A. J. P. acknowledges support from the Intelligence Community Postdoctoral Research Associateship Program. NR 44 TC 45 Z9 45 U1 1 U2 13 PU OPTICAL SOC AMER PI WASHINGTON PA 2010 MASSACHUSETTS AVE NW, WASHINGTON, DC 20036 USA SN 1094-4087 J9 OPT EXPRESS JI Opt. Express PD APR 13 PY 2009 VL 17 IS 8 BP 6727 EP 6740 DI 10.1364/OE.17.006727 PG 14 WC Optics SC Optics GA 432BQ UT WOS:000265108900092 PM 19365501 ER PT J AU Levitus, S Antonov, JI Boyer, TP Locarnini, RA Garcia, HE Mishonov, AV AF Levitus, S. Antonov, J. I. Boyer, T. P. Locarnini, R. A. Garcia, H. E. Mishonov, A. V. TI Global ocean heat content 1955-2008 in light of recently revealed instrumentation problems SO GEOPHYSICAL RESEARCH LETTERS LA English DT Article ID SEA-LEVEL RISE; WORLDS OCEANS AB We provide estimates of the warming of the world ocean for 1955-2008 based on historical data not previously available, additional modern data, correcting for instrumental biases of bathythermograph data, and correcting or excluding some Argo float data. The strong interdecadal variability of global ocean heat content reported previously by us is reduced in magnitude but the linear trend in ocean heat content remain similar to our earlier estimate. Citation: Levitus, S., J. I. Antonov, T. P. Boyer, R. A. Locarnini, H. E. Garcia, and A. V. Mishonov (2009), Global ocean heat content 1955-2008 in light of recently revealed instrumentation problems, Geophys. Res. Lett., 36, L07608, doi: 10.1029/2008GL037155. C1 [Levitus, S.; Antonov, J. I.; Boyer, T. P.; Locarnini, R. A.; Garcia, H. E.; Mishonov, A. V.] NOAA, Natl Oceanog Data Ctr, Silver Spring, MD 20910 USA. RP Levitus, S (reprint author), NOAA, Natl Oceanog Data Ctr, 1315 EW Highway,Room 4326, Silver Spring, MD 20910 USA. EM sydney.levitus@noaa.gov RI Mishonov, Alexey/F-3211-2011 OI Mishonov, Alexey/0000-0002-2958-8747 NR 14 TC 329 Z9 339 U1 5 U2 98 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0094-8276 EI 1944-8007 J9 GEOPHYS RES LETT JI Geophys. Res. Lett. PD APR 11 PY 2009 VL 36 AR L07608 DI 10.1029/2008GL037155 PG 5 WC Geosciences, Multidisciplinary SC Geology GA 431YU UT WOS:000265101500001 ER PT J AU Quay, PD Stutsman, J Feely, RA Juranek, LW AF Quay, P. D. Stutsman, J. Feely, R. A. Juranek, L. W. TI Net community production rates across the subtropical and equatorial Pacific Ocean estimated from air-sea delta C-13 disequilibrium SO GLOBAL BIOGEOCHEMICAL CYCLES LA English DT Article ID DISSOLVED INORGANIC CARBON; ORGANIC-CARBON; GAS-EXCHANGE; EXPORT PRODUCTION; SURFACE WATERS; SARGASSO SEA; OXYGEN; CO2; BALANCE; TEMPERATURE AB Rates of net community production (NCP) in the mixed layer were estimated using measurements of the C-13/C-12 of dissolved inorganic carbon (DIC) in surface waters of the subtropical and equatorial Pacific Ocean on samples collected during nine container ship cruises between California and Australia in 2004-2005. The rate of NCP in the surface mixed layer was determined from the magnitude of the air-sea delta C-13 disequilibrium using mixed layer DIC and DIC13 budgets. The estimated NCP rates between 30 degrees N and 30 degrees S varied from 1.9 to 3.9 mols C m(-2) a(-1) with a mean value of 2.9 +/- 0.8 mols C m(-2) a(-1). NCP rates in the equatorial ocean (3.4 +/- 0.6 mols C m(-2) a(-1)) were higher than in subtropical gyres (2.6 +/- 0.6 mols C m(-2) a(-1)). These rates of NCP were significantly higher than NCP rates previously estimated from DIC drawdown and satellite algorithms of productivity but consistent with NCP estimates from oxygen budgets and inverse models. In this region of the Pacific Ocean the estimated NCP rate was 3.6 Pg C a(-1) C1 [Quay, P. D.; Stutsman, J.] Univ Washington, Sch Oceanog, Seattle, WA 98195 USA. [Feely, R. A.; Juranek, L. W.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. RP Quay, PD (reprint author), Univ Washington, Sch Oceanog, MS 355351, Seattle, WA 98195 USA. EM pdquay@u.washington.edu FU NSF Ocean Sciences [OCE 0327006]; NOAA Office of Global Programs [NA17RJ1232] FX We thank the Alpha Ship company for allowing us to participate in the Columbus Waikato cruises and Carrie Wolf and Dave Wisegarver for helping to collect seawater samples during these cruises. We especially appreciated the efforts of Jackie Leung and the many UW undergraduate students who helped with sample preparation in our laboratory. We thank Reiner Schlitzer and Kitack Lee for making available their NCP estimates along the Columbus Waikato cruise track. In particular, we want to acknowledge the financial support by NSF Ocean Sciences under grant OCE 0327006 and by NOAA Office of Global Programs under grant NA17RJ1232. NR 47 TC 17 Z9 18 U1 2 U2 14 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0886-6236 EI 1944-9224 J9 GLOBAL BIOGEOCHEM CY JI Glob. Biogeochem. Cycle PD APR 11 PY 2009 VL 23 AR GB2006 DI 10.1029/2008GB003193 PG 15 WC Environmental Sciences; Geosciences, Multidisciplinary; Meteorology & Atmospheric Sciences SC Environmental Sciences & Ecology; Geology; Meteorology & Atmospheric Sciences GA 431YX UT WOS:000265101800001 ER PT J AU Shi, W Wang, MH AF Shi, Wei Wang, Menghua TI Satellite observations of flood-driven Mississippi River plume in the spring of 2008 SO GEOPHYSICAL RESEARCH LETTERS LA English DT Article ID IMAGERY; VARIABILITY; OCEANS AB Satellite measurements from the Moderate Resolution Imaging Spectroradiometer (MODIS) on Aqua were used to quantify the Mississippi River plume following the intense rainfall and massive flood along the Mississippi River and its tributaries during the spring of 2008. The shortwave infrared (SWIR) atmospheric correction algorithm has been used to derive the total suspended matter (TSM) concentration and the spectral optical features of the Mississippi River plume. Following a significantly increased river discharge, the observed Mississippi River plume was considerably large relative to climatological monthly Mississippi River plume data, which were derived from the six-year MODIS-Aqua time series from 2002-2008. The areal coverage of the Mississippi River plume was double compared to the six-year mean value, with plume areal coverage of 5859, 4984, 4366, and 3050 km 2 for the months of April, May, June, and July in 2008, respectively. Within the plume, significantly elevated TSM concentration was observed with the pronounced normalized water-leaving reflectance at the green, red, and near-infrared wavelengths in the northern Gulf of Mexico. Near the coast, the satellite-observed TSM concentration in April had increased approximately from the 20 mg/l six-year mean value to over 30 mg/ l in the April of 2008. Citation: Shi, W., and M. Wang (2009), Satellite observations of flood-driven Mississippi River plume in the spring of 2008, Geophys. Res. Lett., 36, L07607, doi: 10.1029/2009GL037210. C1 [Shi, Wei; Wang, Menghua] NOAA, Ctr Satellite Applicat & Res, Natl Environm Satellite Data & Informat Serv, Camp Springs, MD 20746 USA. [Shi, Wei] Colorado State Univ, CIRA, Ft Collins, CO 80523 USA. RP Shi, W (reprint author), NOAA, Ctr Satellite Applicat & Res, Natl Environm Satellite Data & Informat Serv, 5200 Auth Rd,E RA3,Room 102, Camp Springs, MD 20746 USA. EM menghua.wang@noaa.gov RI Shi, Wei/F-5625-2010; Wang, Menghua/F-5631-2010 OI Wang, Menghua/0000-0001-7019-3125 FU NASA; NOAA FX This research was supported by the NASA and NOAA funding and grants. The MODIS L1B data and the Mississippi River discharge data were obtained from NASA/GSFC MODAPS Services website and the USGS National Water Information System, respectively. We thank two anonymous reviewers for their useful comments. The views, opinions, and findings contained in this paper are those of the authors and should not be construed as an official NOAA or U. S. Government position, policy, or decision. NR 20 TC 35 Z9 36 U1 1 U2 11 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0094-8276 J9 GEOPHYS RES LETT JI Geophys. Res. Lett. PD APR 10 PY 2009 VL 36 AR L07607 DI 10.1029/2009GL037210 PG 5 WC Geosciences, Multidisciplinary SC Geology GA 431YT UT WOS:000265101400003 ER PT J AU VanOudenhove, J Anderson, E Krueger, S Cole, JL AF VanOudenhove, Jennifer Anderson, Eric Krueger, Susan Cole, James L. TI Analysis of PKR Structure by Small-Angle Scattering SO JOURNAL OF MOLECULAR BIOLOGY LA English DT Article DE SAXS; SANS; protein kinase; innate immunity ID DOUBLE-STRANDED-RNA; PROTEIN-KINASE PKR; X-RAY-SCATTERING; INTRINSICALLY UNSTRUCTURED PROTEINS; NEUTRON-SCATTERING; FLEXIBLE PROTEINS; MESSENGER-RNA; ACTIVATION; DSRNA; DIMERIZATION AB Protein kinase R (PKR) is a key component of the interferon antiviral defense pathway. Upon binding double-stranded RNA, PKR undergoes autophosphorylation reactions that activate the kinase. PKR contains an N-terminal double-stranded RNA binding domain, which consists of two tandem double-stranded RNA binding motifs, and a C-terminal kinase domain. We have used small-angle X-ray scattering and small-angle neutron scattering to define the conformation of latent PKR in solution. Guinier analysis indicates a radius of gyration of about 35 angstrom. The p(r) distance distribution function exhibits a peak near 30 angstrom, with a broad shoulder extending to longer distances. Good fits to the scattering data require models that incorporate multiple compact and extended conformations of the two interdomain linker regions. Thus, PKR belongs to the growing family of proteins that contain intrinsically Unstructured regions. We propose that the flexible linkers may allow PKR to productively dimerize upon interaction with RNA activators that have diverse structures. (C) 2009 Elsevier Ltd. All rights reserved. C1 [VanOudenhove, Jennifer; Anderson, Eric; Cole, James L.] Univ Connecticut, Dept Mol & Cell Biol, Storrs, CT 06269 USA. [Krueger, Susan] NIST, Ctr Neutron Res, Gaithersburg, MD 21702 USA. [Cole, James L.] Univ Connecticut, Dept Chem, Storrs, CT 06269 USA. RP Cole, JL (reprint author), Univ Connecticut, Dept Mol & Cell Biol, 91 N Eagleville Rd,U-3125, Storrs, CT 06269 USA. EM james.cole@uconn.edu RI Cole, James/G-2586-2011; ID, BioCAT/D-2459-2012 FU National Institutes of Health [AT-53615]; US Department of Energy, Basic Energy Sciences; Office of Science [W-31-109-ENG-38]; BioCAT is a research center [RR-08630]; National Institutes of Health; National Science Foundation [DMR-0454672] FX We thank Liang Guo for assistance with the SAXS data collection and Pascal Lapierre for assistance with computations. This work was supported by grant no. AT-53615 from the National Institutes of Health (J.L.C.). Use of the Advanced Photon Source was Supported by the US Department of Energy, Basic Energy Sciences, Office of Science, under contract no. W-31-109-ENG-38. BioCAT is a research center (RR-08630) supported by the National Institutes of Health. The neutron scattering Studies Utilized facilities supported, in part, by the National Science Foundation under agreement no. DMR-0454672. NR 52 TC 28 Z9 28 U1 2 U2 8 PU ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD PI LONDON PA 24-28 OVAL RD, LONDON NW1 7DX, ENGLAND SN 0022-2836 J9 J MOL BIOL JI J. Mol. Biol. PD APR 10 PY 2009 VL 387 IS 4 BP 910 EP 920 DI 10.1016/j.jmb.2009.02.019 PG 11 WC Biochemistry & Molecular Biology SC Biochemistry & Molecular Biology GA 434VR UT WOS:000265302700010 PM 19232355 ER PT J AU Ferlaino, F Knoop, S Berninger, M Harm, W D'Incao, JP Nagerl, HC Grimm, R AF Ferlaino, F. Knoop, S. Berninger, M. Harm, W. D'Incao, J. P. Naegerl, H. -C. Grimm, R. TI Evidence for Universal Four-Body States Tied to an Efimov Trimer SO PHYSICAL REVIEW LETTERS LA English DT Article ID LARGE SCATTERING LENGTH; QUANTUM STATES; ATOMS; RECOMBINATION; RESONANCE; SYSTEM; CESIUM AB We report on the measurement of four-body recombination rate coefficients in an atomic gas. Our results obtained with an ultracold sample of cesium atoms at negative scattering lengths show a resonant enhancement of losses and provide strong evidence for the existence of a pair of four-body states, which is strictly connected to Efimov trimers via universal relations. Our findings confirm recent theoretical predictions and demonstrate the enrichment of the Efimov scenario when a fourth particle is added to the generic three-body problem. C1 [Ferlaino, F.; Knoop, S.; Berninger, M.; Harm, W.; Naegerl, H. -C.; Grimm, R.] Univ Innsbruck, Inst Expt Phys, A-6020 Innsbruck, Austria. [Ferlaino, F.; Knoop, S.; Berninger, M.; Harm, W.; Naegerl, H. -C.; Grimm, R.] Univ Innsbruck, Zentrum Quantenphys, A-6020 Innsbruck, Austria. [D'Incao, J. P.; Grimm, R.] Austrian Acad Sci, Inst Quantenopt & Quanteninformat, A-6020 Innsbruck, Austria. [D'Incao, J. P.] Univ Colorado, JILA, Boulder, CO 80309 USA. [D'Incao, J. P.] NIST, Boulder, CO 80309 USA. RP Ferlaino, F (reprint author), Univ Innsbruck, Inst Expt Phys, A-6020 Innsbruck, Austria. RI Grimm, Rudolf/D-2864-2009; Naegerl, Hanns-Christoph/E-7329-2010; D'Incao, Jose/B-1289-2010; Ferlaino, francesca/E-6726-2012; Knoop, Steven/N-6919-2013 OI Grimm, Rudolf/0000-0003-1085-5558; Naegerl, Hanns-Christoph/0000-0002-7789-4431; Knoop, Steven/0000-0002-5090-6295 FU Austrian Science Fund (FWF) [SFB 15]; Lise Meitner program of the FWF; NSF FX We acknowledge support by the Austrian Science Fund (FWF) within SFB 15. F.F. is supported within the Lise Meitner program of the FWF. J.P.D's contribution was supported in part by the NSF. NR 27 TC 142 Z9 142 U1 1 U2 6 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 0031-9007 J9 PHYS REV LETT JI Phys. Rev. Lett. PD APR 10 PY 2009 VL 102 IS 14 AR 140401 DI 10.1103/PhysRevLett.102.140401 PG 4 WC Physics, Multidisciplinary SC Physics GA 431SA UT WOS:000265082500001 PM 19392415 ER PT J AU Kiladis, GN Wheeler, MC Haertel, PT Straub, KH Roundy, PE AF Kiladis, George N. Wheeler, Matthew C. Haertel, Patrick T. Straub, Katherine H. Roundy, Paul E. TI CONVECTIVELY COUPLED EQUATORIAL WAVES SO REVIEWS OF GEOPHYSICS LA English DT Review ID MADDEN-JULIAN OSCILLATION; SYNOPTIC-SCALE DISTURBANCES; ROSSBY-GRAVITY-WAVES; GENERAL-CIRCULATION MODEL; TROPICAL WESTERN PACIFIC; AFRICAN EASTERLY WAVES; SUMMER INTRASEASONAL OSCILLATION; INTERTROPICAL CONVERGENCE ZONE; MERIDIONAL WIND OSCILLATIONS; WAVENUMBER-FREQUENCY DOMAIN AB Convectively coupled equatorial waves (CCEWs) control a substantial fraction of tropical rainfall variability. Their horizontal structures and dispersion characteristics correspond to Matsuno's (1966) solutions of the shallow water equations on an equatorial beta plane, namely, Kelvin, equatorial Rossby, mixed Rossby-gravity, and inertio-gravity waves. Because of moist processes, the tilted vertical structures of CCEWs are complex, and their scales do not correspond to that expected from the linear theory of dry waves. The dynamical structures and cloud morphology of CCEWs display a large degree of self-similarity over a surprisingly wide range of scales, with shallow convection at their leading edge, followed by deep convection and then stratiform precipitation, mirroring that of individual mesoscale convective complexes. CCEWs have broad impacts within the tropics, and their simulation in general circulation models is still problematic, although progress has been made using simpler models. A complete understanding of CCEWs remains a challenge in tropical meteorology. C1 [Kiladis, George N.] NOAA, Earth Syst Res Lab, Boulder, CO 80305 USA. [Wheeler, Matthew C.] Ctr Australian Weather & Climate Res, Bur Meteorol, Melbourne, Vic 3001, Australia. [Haertel, Patrick T.] Yale Univ, Dept Geol & Geophys, New Haven, CT 06520 USA. [Straub, Katherine H.] Susquehanna Univ, Dept Earth & Environm Sci, Selinsgrove, PA 17870 USA. [Roundy, Paul E.] SUNY Albany, Dept Atmospher & Environm Sci, Albany, NY 12222 USA. RP Kiladis, GN (reprint author), NOAA, Earth Syst Res Lab, 325 Broadway, Boulder, CO 80305 USA. EM george.kiladis@noaa.gov RI Wheeler, Matthew/C-9038-2011 OI Wheeler, Matthew/0000-0002-9769-1973 NR 228 TC 281 Z9 283 U1 6 U2 43 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 8755-1209 EI 1944-9208 J9 REV GEOPHYS JI Rev. Geophys. PD APR 10 PY 2009 VL 47 AR RG2003 DI 10.1029/2008RG000266 PG 42 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 432AM UT WOS:000265105900001 ER PT J AU Seaborn, GT Smith, TIJ Denson, MR Walker, AB Berlinsky, DL AF Seaborn, Gloria T. Smith, Theodore I. J. Denson, Michael R. Walker, Abigail B. Berlinsky, David L. TI Comparative fatty acid composition of eggs from wild and captive black sea bass, Centropristis striata L. SO AQUACULTURE RESEARCH LA English DT Article DE black sea bass; fatty acids; egg composition; broodstock diets ID SPARUS-AURATA L.; REPRODUCTIVE-PERFORMANCE; HORMONE-ANALOG; DICENTRARCHUS-LABRAX; ARACHIDONIC-ACID; MARINE FISH; OVULATION INDUCTION; LIPID-COMPOSITION; BROODSTOCK DIETS; HATCHING SUCCESS AB Lipid content, lipid class and fatty acid compositions were determined in eggs from wild and captive black sea bass, Centropristis striata L., from northern (New England) and southern (South Carolina) regions to determine the effects of diet on egg composition and fertilization success. The formulated diets fed to the northern captive (NC) fish were higher in total lipids (22%) compared with the cut fish and squid diet fed to the southern fish (SC; 3.3% lipid) and had a higher relative amount of linoleic acid (LA) and lower relative amounts of docosahexaenoic acid (DHA) and arachidonic acid (AA). These dietary differences were broadly reflected in the egg lipid composition. The LA levels were higher in all lipid classes in eggs of NC fish while AA levels were lower. The DHA was higher in the major polar lipids (PL) (phosphatidylcholine and phosphatidylethanolamine) of SC eggs compared with NC. Compared with wild fish, both captive groups produced eggs with PLs richer in LA and lower in DHA and AA. Over all fish groups, fertilization success was directly correlated with levels of DHA and AA in the PLs and was inversely correlated with LA levels. C1 [Walker, Abigail B.; Berlinsky, David L.] Univ New Hampshire, Dept Zool, Durham, NH 03824 USA. [Seaborn, Gloria T.] Ctr Coastal Environm Hlth & Biomol Res, Natl Ocean & Atmospher Adm, Charleston, SC USA. [Smith, Theodore I. J.; Denson, Michael R.] Marine Resources Res Inst, S Carolina Dept Nat Resources, Charleston, SC 29412 USA. RP Berlinsky, DL (reprint author), Univ New Hampshire, Dept Zool, 46 Coll Rd, Durham, NH 03824 USA. EM david.berlinsky@unh.edu FU NH Sea Grant FX We thank Tom Brown and Joe Wade for technical assistance and Margaret Holbrook and Dr Jesus Venero for helpful suggestions with this manuscript. This study was partially funded by NH Sea Grant. This publication does not constitute an endorsement of any commercial product or intend to be an opinion beyond scientific or other results obtained by the NOAA. No reference shall be made to NOAA, or this publication furnished by NOAA, to any advertising or sales promotion that would indicate or imply that NOAA recommends or endorses any proprietary product mentioned herein, or which has as its purpose an interest to cause the advertised product to be used or purchased because of this publication. NR 58 TC 7 Z9 8 U1 0 U2 6 PU WILEY-BLACKWELL PI MALDEN PA COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA SN 1355-557X J9 AQUAC RES JI Aquac. Res. PD APR 9 PY 2009 VL 40 IS 6 BP 656 EP 668 DI 10.1111/j.1365-2109.2008.02141.x PG 13 WC Fisheries SC Fisheries GA 426TG UT WOS:000264730100003 ER PT J AU Contescu, CI Brown, CM Liu, Y Bhat, VV Gallego, NC AF Contescu, Cristian I. Brown, Craig M. Liu, Yun Bhat, Vinay V. Gallego, Nidia C. TI Detection of Hydrogen Spillover in Palladium-Modified Activated Carbon Fibers during Hydrogen Adsorption SO JOURNAL OF PHYSICAL CHEMISTRY C LA English DT Article ID INELASTIC NEUTRON-SCATTERING; HETEROGENEOUS CATALYSIS; PLATINUM NANOPARTICLES; STORAGE; NANOTUBES; GRAPHITE; SPECTRA; STATES AB Palladium-modified activated carbon fibers (Pd-ACF) are being evaluated for adsorptive hydrogen storage at near-ambient conditions because of their enhanced hydrogen uptake in comparison to Pd-free ACF. The net uptake enhancement (at room temperature and 2 MPa) is in excess of the amount corresponding to formation of beta-Pd hydride and is usually attributed to hydrogen spillover. In this paper, inelastic neutron scattering was used to investigate the state of hydrogen in Pd-containing activated carbon fibers loaded at 77 K with 2.5 wt % H(2). It was found that new C-H bonds were formed, at the expense of physisorbed H(2), during prolonged in situ exposure to 1.6 MPa hydrogen at 20 degrees C. This finding is a postfacturn proof of the atomic nature of H species formed in presence of a Pd catalyst and of their subsequent spillover and binding to the carbon support. Chemisorption of hydrogen may explain the reduction in hydrogen uptake from first to second adsorption cycle. C1 [Contescu, Cristian I.; Bhat, Vinay V.; Gallego, Nidia C.] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA. [Brown, Craig M.; Liu, Yun] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Liu, Yun] Univ Maryland, College Pk, MD 20742 USA. RP Contescu, CI (reprint author), Oak Ridge Natl Lab, 1 Bethel Valley Rd,POB 2008,MS-6087, Oak Ridge, TN 37831 USA. EM contescuci@ornl.gov RI Liu, Yun/A-2478-2010; Contescu, Cristian/E-8880-2011; Liu, Yun/F-6516-2012; Brown, Craig/B-5430-2009; OI Liu, Yun/0000-0002-0944-3153; Contescu, Cristian/0000-0002-7450-3722; Liu, Yun/0000-0002-0944-3153; Brown, Craig/0000-0002-9637-9355; Gallego, Nidia/0000-0002-8252-0194 NR 38 TC 89 Z9 90 U1 7 U2 45 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1932-7447 J9 J PHYS CHEM C JI J. Phys. Chem. C PD APR 9 PY 2009 VL 113 IS 14 BP 5886 EP 5890 DI 10.1021/jp900121k PG 5 WC Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary SC Chemistry; Science & Technology - Other Topics; Materials Science GA 427UX UT WOS:000264805700075 ER PT J AU Roh, JH Briber, RM Damjanovic, A Thirumalai, D Woodson, SA Sokolov, AP AF Roh, J. H. Briber, R. M. Damjanovic, A. Thirumalai, D. Woodson, S. A. Sokolov, A. P. TI Dynamics of tRNA at Different Levels of Hydration SO BIOPHYSICAL JOURNAL LA English DT Article ID MOLECULAR-DYNAMICS; NEUTRON-SCATTERING; PROTEIN DYNAMICS; ENZYME-ACTIVITY; TRANSITION; WATER; SOLVENT; MOTIONS; DNA; FLUCTUATIONS AB The influence of hydration on the nanosecond timescale dynamics of tRNA is investigated using neutron scattering spectroscopy. Unlike protein dynamics, the dynamics of tRNA is not affected by methyl group rotation. This allows for a simpler analysis of the influence of hydration on the conformational motions in RNA. We find that hydration affects the dynamics of tRNA significantly more than that of lysozyme. Both the characteristic length scale and the timescale of the conformational motions in tRNA depend strongly on hydration. Even the characteristic temperature of the so-called "dynamical transition" appears to be hydration-dependent in tRNA. The amplitude of the conformational motions in fully hydrated tRNA is almost twice as large as in hydrated lysozyme. We ascribe these differences to a more open and flexible structure of hydrated RNA, and to a larger fraction and different nature of hydrophilic sites. The latter leads to a higher density of water that makes the biomolecule more flexible. All-atom molecular-dynamics simulations are used to show that the extent of hydration is greater in tRNA than in lysozyme. We propose that water acts as a "lubricant" in facilitating enhanced motion in solvated RNA molecules. C1 [Roh, J. H.; Briber, R. M.] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. [Thirumalai, D.] Univ Maryland, Inst Phys Sci & Technol, Biophys Program, College Pk, MD 20742 USA. [Roh, J. H.; Woodson, S. A.] Johns Hopkins Univ, TC Jenkins Dept Biophys, Baltimore, MD USA. [Sokolov, A. P.] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA. [Roh, J. H.] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. RP Roh, JH (reprint author), Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. EM rohmio1973@gmail.com RI Briber, Robert/A-3588-2012; OI Briber, Robert/0000-0002-8358-5942; Woodson, Sarah/0000-0003-0170-1987 NR 51 TC 54 Z9 54 U1 0 U2 13 PU CELL PRESS PI CAMBRIDGE PA 600 TECHNOLOGY SQUARE, 5TH FLOOR, CAMBRIDGE, MA 02139 USA SN 0006-3495 EI 1542-0086 J9 BIOPHYS J JI Biophys. J. PD APR 8 PY 2009 VL 96 IS 7 BP 2755 EP 2762 DI 10.1016/j.bpj.2008.12.3895 PG 8 WC Biophysics SC Biophysics GA 450BV UT WOS:000266376900020 PM 19348758 ER PT J AU Carter, AR Seol, Y Perkins, TT AF Carter, Ashley R. Seol, Yeonee Perkins, Thomas T. TI Precision Surface-Coupled Optical-Trapping Assay with One-Basepair Resolution SO BIOPHYSICAL JOURNAL LA English DT Article ID SINGLE-MOLECULE; STRETCHING DNA; FORCE; TWEEZERS; DYNAMICS; RNA; MICROSCOPE; MOTION; TRAPS AB The most commonly used optical-trapping assays are coupled to surfaces, yet such assays lack atomic-scale (similar to 0.1 nm) spatial resolution due to drift between the surface and trap. We used active stabilization techniques to minimize surface motion to 0.1 nm in three dimensions and decrease multiple types of trap laser noise (pointing, intensity, mode, and polarization). As a result, we achieved nearly the thermal limit (<0.05 nm) of bead detection over abroad range of trap stiffness (k(T) = 0.05-0.5 pN/nm) and frequency (Delta f = 0.03-100 Hz). We next demonstrated sensitivity to one-basepair (0.34-nm) steps along DNA in a surface-coupled assay at moderate force (6 pN). Moreover, basepair stability was achieved immediately after substantial (3.4 pN) changes in force. Active intensity stabilization also led to enhanced force precision (similar to 0.01%) that resolved 0.1-pN force-induced changes in DNA hairpin unfolding dynamics. This work brings the benefit of atomic-scale resolution, currently limited to dual-beam trapping assays, along with enhanced force precision to the widely used, surface-coupled optical-trapping assay. C1 [Carter, Ashley R.; Seol, Yeonee; Perkins, Thomas T.] Univ Colorado, Natl Inst Stand & Technol, JILA, Boulder, CO 80309 USA. [Carter, Ashley R.] Univ Colorado, Dept Phys, Boulder, CO 80309 USA. [Perkins, Thomas T.] Univ Colorado, Dept Mol Cellular & Dev Biol, Boulder, CO 80309 USA. RP Perkins, TT (reprint author), Univ Colorado, Natl Inst Stand & Technol, JILA, Boulder, CO 80309 USA. EM tperkins@jila.colorado.edu OI Perkins, Thomas/0000-0003-4826-9490 NR 31 TC 38 Z9 40 U1 0 U2 9 PU CELL PRESS PI CAMBRIDGE PA 600 TECHNOLOGY SQUARE, 5TH FLOOR, CAMBRIDGE, MA 02139 USA SN 0006-3495 J9 BIOPHYS J JI Biophys. J. PD APR 8 PY 2009 VL 96 IS 7 BP 2926 EP 2934 DI 10.1016/j.bpj.2008.12.3933 PG 9 WC Biophysics SC Biophysics GA 450BV UT WOS:000266376900036 PM 19348774 ER PT J AU Duewer, DL Jones, WD Reid, LH Salit, M AF Duewer, David L. Jones, Wendell D. Reid, Laura H. Salit, Marc TI Learning from microarray interlaboratory studies: measures of precision for gene expression SO BMC GENOMICS LA English DT Article ID QUALITY-ASSURANCE PROGRAM; MEASUREMENT PERFORMANCE; REPRODUCIBILITY; PLATFORMS; MODEL; TIME AB Background: The ability to demonstrate the reproducibility of gene expression microarray results is a critical consideration for the use of microarray technology in clinical applications. While studies have asserted that microarray data can be "highly reproducible" under given conditions, there is little ability to quantitatively compare amongst the various metrics and terminology used to characterize and express measurement performance. Use of standardized conceptual tools can greatly facilitate communication among the user, developer, and regulator stakeholders of the microarray community. While shaped by less highly multiplexed systems, measurement science (metrology) is devoted to establishing a coherent and internationally recognized vocabulary and quantitative practice for the characterization of measurement processes. Results: The two independent aspects of the metrological concept of "accuracy" are "trueness" (closeness of a measurement to an accepted reference value) and "precision" (the closeness of measurement results to each other). A carefully designed collaborative study enables estimation of a variety of gene expression measurement precision metrics: repeatability, several flavors of intermediate precision, and reproducibility. The three 2004 Expression Analysis Pilot Proficiency Test collaborative studies, each with 13 to 16 participants, provide triplicate microarray measurements on each of two reference RNA pools. Using and modestly extending the consensus ISO 5725 documentary standard, we evaluate the metrological precision figures of merit for individual microarray signal measurement, building from calculations appropriate to single measurement processes, such as technical replicate expression values for individual probes on a microarray, to the estimation and display of precision functions representing all of the probes in a given platform. Conclusion: With only modest extensions, the established metrological framework can be fruitfully used to characterize the measurement performance of microarray and other highly multiplexed systems. Precision functions, summarizing routine precision metrics estimated from appropriately repeated measurements of one or more reference materials as functions of signal level, are demonstrated and merit further development for characterizing measurement platforms, monitoring changes in measurement system performance, and comparing performance among laboratories or analysts. C1 [Duewer, David L.] Natl Inst Stand & Technol, Div Analyt Chem, Gaithersburg, MD 20899 USA. [Jones, Wendell D.; Reid, Laura H.] Express Anal, Durham, NC 27713 USA. [Salit, Marc] Natl Inst Stand & Technol, Div Biochem Sci, Gaithersburg, MD 20899 USA. RP Duewer, DL (reprint author), Natl Inst Stand & Technol, Div Analyt Chem, Gaithersburg, MD 20899 USA. EM david.duewer@nist.gov; wjones@ExpressionAnalysis.com; Lreid2012@nc.rr.com; marc.salit@nist.gov NR 29 TC 4 Z9 4 U1 0 U2 0 PU BIOMED CENTRAL LTD PI LONDON PA CURRENT SCIENCE GROUP, MIDDLESEX HOUSE, 34-42 CLEVELAND ST, LONDON W1T 4LB, ENGLAND SN 1471-2164 J9 BMC GENOMICS JI BMC Genomics PD APR 8 PY 2009 VL 10 AR 153 DI 10.1186/1471-2164-10-153 PG 15 WC Biotechnology & Applied Microbiology; Genetics & Heredity SC Biotechnology & Applied Microbiology; Genetics & Heredity GA 455YH UT WOS:000266804400003 PM 19356252 ER PT J AU Angell, JK Free, M AF Angell, James K. Free, Melissa TI Ground-based observations of the slowdown in ozone decline and onset of ozone increase SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID STRATOSPHERIC OZONE; VERTICAL-DISTRIBUTION; EL CHICHON; RECOVERY; TRENDS; PROFILES; PINATUBO; IMPACT AB This paper presents the evidence for a slowdown in ozone decline and subsequent ozone increase using ground-based data, i.e., Dobson, Brewer, and Russian filter ozonometer total-ozone data and Umkehr and ozonesonde-derived layer-ozone data. The impacts of quasi-biennial oscillation (QBO) and 11-year solar cycle were minimized by determining 5-year trends based on 11-year running means. On the basis of 50-60 total-ozone stations, the global trends vary from a maximum negative value of -2.1 +/- 0.6%/decade in 1988 to a value of 0.7 +/- 0.5%/decade at the end of the record in 2000, where the confidence intervals are 2 standard deviations of the mean of the individual station trends. Because of the use of 5-year trends and 11-year running means, the actual year of slowdown in total-ozone decline may be up to 7 years later than the year of maximum negative trend in Our analysis, or close to the 1993-1995 peak, in ozone-depleting substances (ODS) in the atmosphere. Umkehr and ozonesonde-derived layer-ozone trends were determined for 32- to 53-, 24- to 32-, 19- to 24-, 10- to 19-, and 0- to 10-km layers of the north temperate zone. On the basis of four Umkehr stations and about five ozonesonde stations, the integrated layer-weighted Umkehr trends vary from a maximum negative value of -3.8 +/- 0.3%/decade in 1989 to a value of 1.2 +/- 2.1%/decade in 2000, while the integrated sonde trends vary from a maximum negative value of -4.8 +/- 1.6%/decade in 1989 to a value of 1.8 +/- 2.1/decade in 2000. Both Umkehr and sonde data show that nearly half of the increase in north temperate total-ozone trend between 1989 and 2000 is due to trend increase in the low-stratospheric 10- to 19-km layer, with the troposphere contributing only about 5%. C1 [Angell, James K.; Free, Melissa] NOAA, Air Resources Lab, Silver Spring, MD 20910 USA. RP Angell, JK (reprint author), NOAA, Air Resources Lab, Silver Spring, MD 20910 USA. EM melissa.free@noaa.gov NR 30 TC 9 Z9 10 U1 4 U2 7 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD APR 8 PY 2009 VL 114 AR D07303 DI 10.1029/2008JD010860 PG 9 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 431YZ UT WOS:000265102000002 ER PT J AU Gilman, JB Kuster, WC Goldan, PD Herndon, SC Zahniser, MS Tucker, SC Brewer, WA Lerner, BM Williams, EJ Harley, RA Fehsenfeld, FC Warneke, C de Gouw, JA AF Gilman, Jessica B. Kuster, William C. Goldan, Paul D. Herndon, Scott C. Zahniser, Mark S. Tucker, Sara C. Brewer, W. Alan Lerner, Brian M. Williams, Eric J. Harley, Robert A. Fehsenfeld, Fred C. Warneke, Carsten de Gouw, Joost A. TI Measurements of volatile organic compounds during the 2006 TexAQS/GoMACCS campaign: Industrial influences, regional characteristics, and diurnal dependencies of the OH reactivity SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID TEXAS AIR-QUALITY; GAS-PHASE REACTIONS; MOTOR-VEHICLE EMISSIONS; OZONE FORMATION; BOUNDARY-LAYER; NONMETHANE HYDROCARBONS; HYDROXYL RADICALS; AMBIENT CONCENTRATIONS; STAGNATION EPISODE; PHOTOLYSIS SYSTEM AB An extensive set of volatile organic (VOCs) and other gas phase species were measured in situ aboard the NOAA R/V Ronald H. Brown as the ship sailed in the Gulf of Mexico and the Houston and Galveston Bay (HGB) area as part of the Texas Air Quality (TexAQS)/Gulf of Mexico Atmospheric Composition and Climate Study (GoMACCS) conducted from July-September 2006. The magnitudes of the reactivities of CH4, CO, VOCs, and NO2 with the hydroxyl radical, OH were determined in order to quantify the contributions of these compounds to potential ozone formation. The average total OH reactivity (R-OH,R-TOTAL) increased from 1.01 s(-1) in the central gulf to 10.1 s(-1) in the HGB area as a result of the substantial increase in the contribution from VOCs in the HGB area compared to the gulf was explained by the impact of industrial emissions, the regional distribution of VOCs, and the effects of local meteorology. By compensating for the effects of boundary layer mixing, the diurnal profiles of the OH reactivity were used to characterize the source signatures and relative magnitudes of biogenic, anthropogenic (urban + industrial), and oxygenated VOCs as a function of the time of day. The source of reactive oxygenated VOCs (e.g., for formaldehyde) was determined to be almost entirely from secondary production. The secondary formation of oxygenated VOCs, in addition to the continued emissions of reactive anthropogenic VOCs, served to sustain elevated levels of OH reactivity throughout the time of peak ozone production. C1 [Gilman, Jessica B.; Kuster, William C.; Goldan, Paul D.; Tucker, Sara C.; Brewer, W. Alan; Lerner, Brian M.; Williams, Eric J.; Fehsenfeld, Fred C.; Warneke, Carsten; de Gouw, Joost A.] NOAA, Earth Syst Res Lab, Div Chem Sci, Boulder, CO 80305 USA. [Herndon, Scott C.; Zahniser, Mark S.] Aerodyne Res Inc, Billerica, MA 01821 USA. [Harley, Robert A.] Univ Calif Berkeley, Dept Civil & Environm Engn, Berkeley, CA 94720 USA. [Gilman, Jessica B.; Goldan, Paul D.; Tucker, Sara C.; Lerner, Brian M.; Williams, Eric J.; Fehsenfeld, Fred C.; Warneke, Carsten; de Gouw, Joost A.] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. RP Gilman, JB (reprint author), NOAA, Earth Syst Res Lab, Div Chem Sci, 325 Broadway, Boulder, CO 80305 USA. EM jessica.gilman@noaa.gov RI Williams, Eric/F-1184-2010; Warneke, Carsten/E-7174-2010; Kuster, William/E-7421-2010; Gilman, Jessica/E-7751-2010; Brewer, Wm Alan/I-3920-2013; Fehsenfeld, Frederick/I-4876-2013; Lerner, Brian/H-6556-2013; de Gouw, Joost/A-9675-2008; Harley, Robert/C-9177-2016; Manager, CSD Publications/B-2789-2015 OI Kuster, William/0000-0002-8788-8588; Gilman, Jessica/0000-0002-7899-9948; Lerner, Brian/0000-0001-8721-8165; de Gouw, Joost/0000-0002-0385-1826; Harley, Robert/0000-0002-0559-1917; FU Texas Commission on Environmental Quality (TCEQ) FX The authors would like to gratefully acknowledge the crew of the NOA A R/V Brown, NOAA Air Quality and Climate Research and Modeling Programs, and funding from the Texas Commission on Environmental Quality (TCEQ). J. Gilman would like to thank J. Roberts and D. Welsh-Bon of the NOAA/ESRL: H. Osthoff of the University of Calgary for helpful discussions and D. Hamilton, D. Coffman, and T. S. Bates of NOAA/PMEL. for their help and expertise provided throughout the campaign. NR 79 TC 49 Z9 50 U1 2 U2 40 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X EI 2169-8996 J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD APR 8 PY 2009 VL 114 AR D00F06 DI 10.1029/2008JD011525 PG 17 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 431YZ UT WOS:000265102000006 ER PT J AU Long, CN Dutton, EG Augustine, JA Wiscombe, W Wild, M McFarlane, SA Flynn, CJ AF Long, C. N. Dutton, E. G. Augustine, J. A. Wiscombe, W. Wild, M. McFarlane, S. A. Flynn, C. J. TI Significant decadal brightening of downwelling shortwave in the continental United States SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID RADIATION BUDGET NETWORK; SURFACE SOLAR-RADIATION; OPTICAL DEPTH; EARTHS SURFACE; TRENDS; IRRADIANCE; RADIOMETER; SURFRAD; COVER; TESTS AB We conduct analyses of all-sky and clear-sky surface downwelling shortwave radiation and bulk cloud properties using data from several Department of Energy Atmospheric Radiation Measurement (ARM) Program and National Oceanic and Atmospheric Administration Surface Radiation (SURFRAD) network sites spanning the years 1995 through 2007. Five ARM sites are aggregated to study downwelling shortwave tendencies on global circulation model grid scales, and then six SURFRAD sites plus the central ARM site are aggregated to study the wider scale of the continental United States. We show that widespread brightening has occurred over the continental United States as represented by these measurements over the 12 years of the study, averaging,about 8 W m(2)/decade for the all-sky shortwave and 5 W m2/decade for the clear-sky shortwave. This all-sky increase is substantially greater than the 2 W m(2)/decade previously reported over much more of the globe as represented by data from the Global Energy Balance Archive spanning 1986-2000 and is more than twice the magnitude of the corresponding 1986-2000 2-3 W m(2)/decade increase in downwelling longwave. Our results show that changes in dry aerosols and/or direct aerosol effects alone cannot explain the observed changes in surface shortwave (SW) radiation, but it is likely that changes in cloudiness play a significant role. These SW increases are accompanied by decreasing tendencies in cloudiness, and an increasing tendency in the clear-sky SW diffuse/direct ratio that is often associated with atmospheric turbidity. However, given the many local influences, evidence presented here suggests that the determination of the causes of decadal changes in the downwelling solar radiation at the surface are better studied locally and regionally, rather than on a global or continental scale. C1 [Long, C. N.; McFarlane, S. A.; Flynn, C. J.] Pacific NW Natl Lab, Climate Phys Grp, Richland, WA 99352 USA. [Dutton, E. G.; Augustine, J. A.] NOAA, ESRL, Global Monitoring Div, Boulder, CO 80305 USA. [Wild, M.] ETH, Inst Atmospher & Climate Sci, CH-8092 Zurich, Switzerland. [Wiscombe, W.] Brookhaven Natl Lab, Upton, NY 11973 USA. RP Long, CN (reprint author), Pacific NW Natl Lab, Climate Phys Grp, POB 999,MS K9-24, Richland, WA 99352 USA. EM chuck.long@pnl.gov; ells.dutton@noaa.gov; john.a.augustine@noaa.gov; wwiscomb@bnl.gov; martin.wild@env.ethz.ch; sally.mcfarlane@pnl.gov; connor.flynn@pnl.gov RI McFarlane, Sally/C-3944-2008; Wild, Martin/J-8977-2012; Wiscombe, Warren/D-4665-2012 OI Wiscombe, Warren/0000-0001-6844-9849 FU Office of Science (BER) of the U.S. Department of Energy; OAA Climate Goal; NASA Radiation Projects Office; Swiss National Centre for Competence in Climate Research (NCCR Climate) FX The authors acknowledge the support of the Office of Science (BER) of the U.S. Department of Energy as part of the ARM Program. The NOAA contributions are supported by the NOAA Climate Goal and the NASA Radiation Projects Office. M. Wild acknowledges the support of the Swiss National Centre for Competence in Climate Research (NCCR Climate). Recognition is also extended to those responsible for the operation and maintenance of the instruments that produced die data used in this study; their diligent and dedicated efforts are often underappreciated. NR 50 TC 53 Z9 53 U1 1 U2 8 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X EI 2169-8996 J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD APR 8 PY 2009 VL 114 AR D00D06 DI 10.1029/2008JD011263 PG 20 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 431YZ UT WOS:000265102000004 ER PT J AU Miyagawa, K Sasaki, T Nakane, H Petropavlovskikh, I Evans, RD AF Miyagawa, Koji Sasaki, Tom Nakane, Hideaki Petropavlovskikh, Irina Evans, Robert D. TI Reevaluation of long-term Umkehr data and ozone profiles at Japanese stations SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID DIFFERENTIAL-ABSORPTION LIDAR; ALGORITHM; TSUKUBA; DIOXIDE; TRENDS AB Umkehr observations have been routinely conducted at Japanese stations, Sapporo, Tsukuba, Kagoshima, and Naha, and the Antarctic station, Syowa, for more than 50 years. Umkehr data are a valuable source of information on long-term changes in the ozone vertical profile; however, the Umkehr record at Japanese stations has evident discontinuities. The majority of the discontinuities are related to the exchange of instruments for calibration (for total ozone measurements) and the replacement of instruments. These discontinuities may be related to the difference in instrument characteristics. In this article, reevaluation of the long-term Umkehr data in Japanese network is done by assessment of instrument-related changes in compared N values that exhibit solar zenith angle and total ozone dependence in addition to the step changes. The systematic errors are evaluated by simultaneous intercomparisons of each instrument with the reference instrument. Through this reevaluation, most discontinuities in a station's Umkehr time series are successfully corrected, and new sets of ozone vertical profiles are derived. The ozone profiles retrieved by two available Umkehr retrieval algorithms are compared with ozonesonde observations at every station and ozone lidar observations at Tsukuba. ne results show that the revised Umkehr ozone profiles show improved consistency with both types of auxiliary ozone observations as compared to the old data sets, especially with regard to ozonesonde observations (difference of less than 5%). Trend analyses of the revised Umkehr ozone profile time series show a significant decrease in stratospheric ozone over Japan during the 1980s. It also varies between stations, with Naha showing the least significant trend among Japanese stations and Sapporo exhibiting as much as 6% of ozone decline per decade. In addition, a positive and statistically significant trend is detected in tropospheric ozone column it Naha (similar to 5.5% per decade) and Tsukuba (similar to 3.5% per decade) stations over the last 20 years, but no significant trend is observed over Sapporo. C1 [Miyagawa, Koji] Japan Meteorol Agcy, Tsukuba, Ibaraki 3050052, Japan. [Evans, Robert D.] NOAA, ESRL, OAR, Climate Monitoring Div, Boulder, CO 80305 USA. [Nakane, Hideaki] Natl Inst Environm Studies, Tsukuba, Ibaraki 3050053, Japan. [Petropavlovskikh, Irina] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. [Sasaki, Tom] Japan Meteorol Agcy, Utsunomiya, Tochigi 3200845, Japan. RP Miyagawa, K (reprint author), Japan Meteorol Agcy, Tsukuba, Ibaraki 3050052, Japan. EM miyagawa@met.kishou.go.jp; tsasaki@met.kishou.go.jp; nakane18@nies.go.jp; irina.petro@noaa.gov; robert.d.evans@noaa.gov RI Evans, Robert/D-4731-2016; OI Evans, Robert/0000-0002-8693-9769; Nakane, Hideaki/0000-0002-9032-6105 NR 33 TC 9 Z9 10 U1 2 U2 4 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD APR 8 PY 2009 VL 114 AR D07108 DI 10.1029/2008JD010658 PG 21 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 431YZ UT WOS:000265102000001 ER PT J AU Wu, H Zhou, W Yildirim, T AF Wu, Hui Zhou, Wei Yildirim, Taner TI High-Capacity Methane Storage in Metal-Organic Frameworks M-2(dhtp): The Important Role of Open Metal Sites SO JOURNAL OF THE AMERICAN CHEMICAL SOCIETY LA English DT Article ID HYDROGEN STORAGE; ADSORPTION PROPERTIES; COORDINATION POLYMER; CARBON-DIOXIDE; GAS-STORAGE; BINDING; DESIGN AB We found that metal-organic framework (MOF) compounds M-2(dhtp) (open metal M = Mg, Mn, Co, Ni, Zn; dhtp = 2,5-dihydroxyterephthalate) possess exceptionally large densities of open metal sites. By adsorbing one CH4 molecule per open metal, these sites alone can generate very large methane storage capacities, 160-174 cm(3)(STP)/cm(3), approaching the DOE target of 180 cm(3)(STP)/cm(3) for material-based methane storage at room temperature. Our adsorption isotherm measurements at 298 K and 35 bar for the five M-2(dhtp) compounds yield excess methane adsorption capacities ranging from 149 to 190 cm(3)(STP)/cm(3) (derived using their crystal densities), indeed roughly equal to the predicted, maximal adsorption capacities of the open metals (within +/-10%) in these MOFs. Among the five isostructural MOFs studied, Ni-2(dhtp) exhibits the highest methane storage capacity, similar to 200 cm(3)(STP)/cm(3) in terms of absolute adsorption, potentially surpassing the DOE target by similar to 10%. Our neutron diffraction experiments clearly reveal that the primary CH4 adsorption occurs directly on the open metal sites. Initial first-principles calculations show that the binding energies of CH4 on the open metal sites are significantly higher than those on typical adsorption sites in classical MOFs, consistent with the measured large heats of methane adsorption for these materials. We attribute the enhancement of the binding strength to the unscreened electrostatic interaction between CH4 and the coordinatively unsaturated metal ions. C1 [Wu, Hui; Zhou, Wei; Yildirim, Taner] Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Wu, Hui; Zhou, Wei] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. [Yildirim, Taner] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA. RP Zhou, W (reprint author), Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. EM wzhou@nist.gov RI Wu, Hui/C-6505-2008; Zhou, Wei/C-6504-2008; yildirim, taner/A-1290-2009 OI Wu, Hui/0000-0003-0296-5204; Zhou, Wei/0000-0002-5461-3617; FU DOE through BES [DE-FG02-08ER46522] FX The authors thank Dr. Jason Simmons for helpful discussions. This work was partially supported by DOE through BES Grant No. DE-FG02-08ER46522 (T.Y.). NR 33 TC 313 Z9 317 U1 30 U2 212 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0002-7863 J9 J AM CHEM SOC JI J. Am. Chem. Soc. PD APR 8 PY 2009 VL 131 IS 13 BP 4995 EP 5000 DI 10.1021/ja900258t PG 6 WC Chemistry, Multidisciplinary SC Chemistry GA 427VD UT WOS:000264806300075 PM 19275154 ER PT J AU Faraone, A Liu, KH Mou, CY Zhang, Y Chen, SH AF Faraone, Antonio Liu, Kao-Hsiang Mou, Chung-Yuan Zhang, Yang Chen, Sow-Hsin TI Single particle dynamics of water confined in a hydrophobically modified MCM-41-S nanoporous matrix SO JOURNAL OF CHEMICAL PHYSICS LA English DT Article DE hydrophobicity; molecular dynamics method; neutron diffraction; water ID ELASTIC NEUTRON-SCATTERING; STRONG LIQUID TRANSITION; HYDROGEN-BONDED LIQUIDS; GLASS-FORMING POLYMERS; SUPERCOOLED WATER; MESOPOROUS SILICA; MESOSCOPIC CONFINEMENT; DIFFUSIVE MOTIONS; PROTEIN SURFACES; HYDRATION WATER AB The single particle dynamics of water confined in a hydrophobically modified MCM-41-S sample has been studied using three high resolution quasielastic neutron scattering spectrometers in the temperature range from 300 to 210 K. A careful modeling of the dynamics allowed us to obtain good agreement among the results obtained with the three instruments, which have very different energy resolutions. The picture arising from the data is that, because of the heterogenous environment experienced by the water molecules, the dynamics show a broad distribution of relaxation times. However, the Fickian diffusive behavior is retained. In the investigated temperature range we found no evidence of the dynamic crossover, from a non-Arrhenius to an Arrhenius behavior, which was detected for water confined in hydrophilic MCM-41-S. This finding is in agreement with what was reported by Chu [Phys. Rev. E 76, 021505 (2007)] for water confined in other hydrophobic confining media that the dynamic crossover takes place at a much lower temperature. The results reported in the paper help clarify the role that the chemical interaction between the water molecules and the walls of the confining host plays in determining the characteristics of the water dynamics, as compared to purely geometric constraints such as the size and shape of the pores. C1 [Faraone, Antonio] Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Faraone, Antonio] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA. [Liu, Kao-Hsiang; Mou, Chung-Yuan] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan. [Zhang, Yang; Chen, Sow-Hsin] MIT, Dept Nucl Sci & Engn, Cambridge, MA 02139 USA. RP Faraone, A (reprint author), Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA. EM afaraone@nist.gov RI Zhang, Yang/A-7975-2012; OI Zhang, Yang/0000-0002-7339-8342; MOU, CHUNG-YUAN/0000-0001-7060-9899 FU National Science Foundation [DMR-0454672] FX This work utilized facilities supported in part by the National Science Foundation under Agreement No. DMR-0454672. The authors are grateful to J. Copley, G. Gasparovic, and V. Garcia-Sakai for assistance with the data collection on DCS and HFBS. We are also indebted to M. Nagao and W. Kamitakahara for critical reading of the manuscript. NR 58 TC 33 Z9 33 U1 4 U2 18 PU AMER INST PHYSICS PI MELVILLE PA CIRCULATION & FULFILLMENT DIV, 2 HUNTINGTON QUADRANGLE, STE 1 N O 1, MELVILLE, NY 11747-4501 USA SN 0021-9606 J9 J CHEM PHYS JI J. Chem. Phys. PD APR 7 PY 2009 VL 130 IS 13 AR 134512 DI 10.1063/1.3097800 PG 10 WC Chemistry, Physical; Physics, Atomic, Molecular & Chemical SC Chemistry; Physics GA 431HW UT WOS:000265053200047 PM 19355756 ER PT J AU Collilieux, X Altamimi, Z Ray, J van Dam, T Wu, X AF Collilieux, X. Altamimi, Z. Ray, J. van Dam, T. Wu, X. TI Effect of the satellite laser ranging network distribution on geocenter motion estimation SO JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH LA English DT Article ID TERRESTRIAL REFERENCE FRAME; SURFACE MASS VARIATIONS; LOADING DATA; ENERGY BALANCES; TIME-SERIES; LAND WATER; EARTH; DEFORMATION; DORIS; DEFINITION AB SLR network translations estimated between a quasi-instantaneous station position set, theoretically expressed with respect to the center of mass of the Earth ( CM), and a secular reference frame are the signature of the motion of the CM with respect to the Earth crust. Geocenter motion is defined here to be the motion of the CM with respect to the geometric center of the solid Earth surface (CF). SLR translational variations cannot be rigorously interpreted as identical to geocenter motion due to the sparse and nonuniform distribution of the SLR network. Their difference is called the network effect, which should be dominated at subdecadal timescales by loading signals. We have computed translation time series of the SLR network using two independent geophysically based loading models. One is a displacement model estimated from surface fluid data ( Green's function approach), called forward model, and the other is a displacement model estimated from GPS and ocean bottom pressure (OBP) data, called inverse model. The translation models have been subtracted from their respective geocenter motion models computed from degree-1 mass load coefficients in order to evaluate their network effect biases. Scatter due to the SLR network effect is at the level of 1.5 mm RMS. It could slightly shift the phase of the annual SLR geocenter motion estimate by less than 1 month and could affect X and Z annual geocenter motion amplitudes at the 1-mm level, which is about one third of the expected signal. Two distinct methods are suggested to account for network effect when comparing SLR translations to geocenter motion models. The first is to add the network effect term predicted by a displacement model to the geocenter motion loading model. The second relies on an adequate combination of SLR and GPS products to estimate SLR translation that could be better compared with geocenter motion. C1 [Collilieux, X.; Altamimi, Z.] Inst Geog Natl, Lab Rech Geodesie, F-77455 Marne La Vallee 2, France. [Ray, J.] NOAA, Natl Geodet Survey, Silver Spring, MD 20910 USA. [van Dam, T.] Univ Luxembourg, Dept Phys & Mat Sci, L-1511 Luxembourg, Luxembourg. [Wu, X.] CALTECH, Jet Prop Lab, Pasadena, CA 91109 USA. RP Collilieux, X (reprint author), Inst Geog Natl, Lab Rech Geodesie, 6-8 Ave Blaise Pascal, F-77455 Marne La Vallee 2, France. EM xavier.collilieux@ign.fr; tonie.vandam@uni.lu; Xiaoping.Wu@jpl.nasa.gov RI Altamimi, Zuheir/A-4168-2009 NR 48 TC 31 Z9 33 U1 1 U2 14 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-9313 EI 2169-9356 J9 J GEOPHYS RES-SOL EA JI J. Geophys. Res.-Solid Earth PD APR 7 PY 2009 VL 114 AR B04402 DI 10.1029/2008JB005727 PG 17 WC Geochemistry & Geophysics SC Geochemistry & Geophysics GA 431ZQ UT WOS:000265103700001 ER PT J AU Jackson, AJ Li, PX Dong, CC Thomas, RK Penfold, J AF Jackson, A. J. Li, P. X. Dong, C. C. Thomas, R. K. Penfold, J. TI Structure of Partially Fluorinated Surfactant Monolayers at the Air-Water Interface SO LANGMUIR LA English DT Article ID NEUTRON REFLECTION; AIR/WATER INTERFACE; HEXADECYLTRIMETHYLAMMONIUM BROMIDE; HYDROCARBON SURFACTANTS; TENSION; LAYERS; MIXTURES; FLUOROCARBON; NONIDEALITY; ADSORPTION AB Partially fluorinated cationic surfactants of the form C(n)F(2n+1)C(m)H(2m)N(CH(3))Br have been prepared, and their behavior at the air-water interface has been studied using surface tension measurements and neutron reflectometry. The degree of fluorination has been varied while keeping the overall chain lengths similar. The results are compared with those previously obtained for C(16)H(33)N(CH(3))Br (C(16)TAB). The structural studies show a decrease in molecular orientation with increasing fluorination. The mean tilt away from the surface normal varies from 55 degrees for C16TAB to 25 degrees for C(8)F(17)C(6)H(12)N(CH(3))Br. The interfacial layer roughness is observed to be lower than that expected for a pure fluorocarbon surfactant. C1 [Jackson, A. J.; Li, P. X.; Dong, C. C.; Thomas, R. K.] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England. [Penfold, J.] Rutherford Appleton Lab, ISIS, Didcot OX11 0QX, Oxon, England. RP Jackson, AJ (reprint author), NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. EM ajj@nist.gov RI Jackson, Andrew/B-9793-2008 OI Jackson, Andrew/0000-0002-6296-0336 NR 34 TC 14 Z9 14 U1 2 U2 8 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0743-7463 J9 LANGMUIR JI Langmuir PD APR 7 PY 2009 VL 25 IS 7 BP 3957 EP 3965 DI 10.1021/la802928f PG 9 WC Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary SC Chemistry; Materials Science GA 427RY UT WOS:000264798000008 PM 19714885 ER PT J AU Berk, NF Majkrzak, CF AF Berk, N. F. Majkrzak, C. F. TI Statistical Analysis of Phase-Inversion Neutron Specular Reflectivity SO LANGMUIR LA English DT Article ID REFLECTOMETRY AB The phase-inversion approach to neutron specular reflection is elucidated in a formal setting, in order to emphasize its conceptual coherence and to facilitate study of some of its statistical properties in the context of real data. An operational notion of data degradation is introduced and illustrated with the randomizing effects of shot noise ("counting" noise) and the systematic "bias" induced by data truncation. Some basic statistical effects of phase-inversion are worked out in the new formalism and illustrated by simulated examples. A principal is advanced that phase-inversion sets the limit of available information from specular reflection. C1 [Berk, N. F.] Univ Maryland, Gaithersburg, MD 20899 USA. [Berk, N. F.; Majkrzak, C. F.] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. RP Berk, NF (reprint author), Univ Maryland, 100 Bur Dr,Stop 6102, Gaithersburg, MD 20899 USA. EM nberk@nist.gov NR 14 TC 9 Z9 9 U1 0 U2 4 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0743-7463 J9 LANGMUIR JI Langmuir PD APR 7 PY 2009 VL 25 IS 7 BP 4132 EP 4144 DI 10.1021/la802779r PG 13 WC Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary SC Chemistry; Materials Science GA 427RY UT WOS:000264798000030 PM 19714896 ER PT J AU Berk, NF Majkrzak, CF AF Berk, N. F. Majkrzak, C. F. TI Analysis of Multibeam Data for Neutron Reflectivity SO LANGMUIR LA English DT Article AB We offer mathematical proof that multiple-beam neutron reflectivity, corresponding to simultaneous collection of data at multiple angles (wavevector transfers) does not perform better, errorwise for counting noise, than single-beam data collection for the same total number of reflected neutrons-and may perform much worse, depending on the beam modulation strategy used. The basic idea is that the nominal statistical benefit of summing data at, say, N different wavevector transfers is undone by needing to collect N differently modulated (i.e., weighted) sums in order to extract the reflectivities. To our knowledge, a general proof of this behavior for arbitrary strategies has been lacking. The formal result can be summarized by saying that the best nondiagonal matrix modulation strategies are orthogonal (unitary) matrices, or constant multiples thereof, and that these can do no better than diagonal-i.e., single-beam-strategies. C1 [Berk, N. F.] Univ Maryland, Dept Mat Sci & Engn, Gaithersburg, MD 20899 USA. [Berk, N. F.; Majkrzak, C. F.] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. RP Berk, NF (reprint author), Univ Maryland, Dept Mat Sci & Engn, 100 Bur Dr,Stop 6102, Gaithersburg, MD 20899 USA. EM nberk@nist.gov NR 4 TC 0 Z9 0 U1 0 U2 0 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0743-7463 J9 LANGMUIR JI Langmuir PD APR 7 PY 2009 VL 25 IS 7 BP 4145 EP 4153 DI 10.1021/la802780v PG 9 WC Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary SC Chemistry; Materials Science GA 427RY UT WOS:000264798000031 PM 19714833 ER PT J AU Majkrzak, CF Berk, NF Kienzle, P Perez-Salas, U AF Majkrzak, C. F. Berk, N. F. Kienzle, P. Perez-Salas, U. TI Progress in the Development of Phase-Sensitive Neutron Reflectometry Methods SO LANGMUIR LA English DT Article AB It has been a number of years since phase-sensitive specular neutron reflectometry (PSNR) methods employing reference layers were first introduced to help remove the ambiguity inherent in the reconstruction of scattering length density (SLD) depth profiles (Majkrzak, C. F.; Berk, N. F. Physica B 2003, 336, 27) from specular reflectivity measurements. Although a number of scientific applications of PSNR techniques have now been successfully realized (Majkrzak, C. F.; Berk, N. F.; Perez-Salas, U. A. Langmuir 2003, 19, 7796 and references therein), in certain cases practical difficulties remain. In this article, we describe possible solutions to two specific problems: (1) the need for explicit, detailed knowledge of the SLD profile of a given reference layer of finite thickness; and (2) for a reference layer of finite thickness in which only two density variations are possible, how to identify which of two mathematical solutions corresponds to the true physical structure. C1 [Majkrzak, C. F.; Berk, N. F.; Kienzle, P.] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Perez-Salas, U.] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA. RP Majkrzak, CF (reprint author), NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. EM charles.majkrzak@nist.gov NR 15 TC 10 Z9 10 U1 0 U2 4 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0743-7463 J9 LANGMUIR JI Langmuir PD APR 7 PY 2009 VL 25 IS 7 BP 4154 EP 4161 DI 10.1021/la802838t PG 8 WC Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary SC Chemistry; Materials Science GA 427RY UT WOS:000264798000032 PM 19714897 ER PT J AU Heinrich, F Ng, T Vanderah, DJ Shekhar, P Mihailescu, M Nanda, H Losche, M AF Heinrich, Frank Ng, Tiffany Vanderah, David J. Shekhar, Prabhanshu Mihailescu, Mihaela Nanda, Hirsh Losche, Mathias TI A New Lipid Anchor for Sparsely Tethered Bilayer Lipid Membranes SO LANGMUIR LA English DT Article ID SELF-ASSEMBLED MONOLAYERS; 1-THIAHEXA(ETHYLENE OXIDE); POLY(ETHYLENE OXIDE); SUPPORTED MEMBRANES; NEUTRON REFLECTION; PROTEIN ADSORPTION; SURFACE; PHOSPHATIDYLCHOLINE; INTERFACE; INSERTION AB Mixed self-assembled monolayers (SAMs) of beta-mercaptoethanol and the new synthetic lipid 1,2-dipalmityl-3[omega-mercaptonona(ethylene oxide)] glycerol (FC16) were investigated for their ability to form sparsely tethered bilayer lipid membranes (stBLMs) completed with various phospholipids. We investigated the structural and functional properties of FC16-based stBLMs and compared these to stBLMs prepared using a previously characterized synthetic lipid, 1,2-dimyristyl-3-[omega-mercaptohexa(ethylene oxide)] glycerol (WC14). FC16-based stBLMs show increased resistivity to ion transfer and an increase in the submembrane space of similar to 0.5 rim. Importantly, FC16-based stBLMs formed well-defined, complete bilayers with charged phospholipids such as 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphoglycerol (POPG). In these, POPG incorporates into the outer monolayer leaflet in the same ratio as in the immersion solution but is excluded from the inner leaflet. In all cases that we have investigated thus far, the area densities of the lipids within the bilayers were on average close to those in free bilayer membranes. For charged phospholipids, FC16 appears to provide a distinct advantage over WC14 for the formation of well-defined stBLMs. C1 [Heinrich, Frank; Mihailescu, Mihaela; Nanda, Hirsh; Losche, Mathias] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Vanderah, David J.] NIST, Chem Sci & Technol Lab, Gaithersburg, MD 20899 USA. [Heinrich, Frank; Shekhar, Prabhanshu; Losche, Mathias] Carnegie Mellon Univ, Dept Phys, Pittsburgh, PA 15213 USA. [Ng, Tiffany] Johns Hopkins Univ, Dept Biomed Engn, Baltimore, MD 21218 USA. [Mihailescu, Mihaela] Univ Calif Irvine, Sch Med, Dept Physiol & Biophys, Irvine, CA 92697 USA. RP Losche, M (reprint author), Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA. EM quench@cmu.edu RI Heinrich, Frank/A-5339-2010; Losche, Mathias/J-2986-2013 OI Heinrich, Frank/0000-0002-8579-553X; Losche, Mathias/0000-0001-6666-916X FU National Institute of Standards and Technology; NSF [DMR-0454672, CBET-0555201]; American Health Assistance Foundation [A2008-307] FX Support by the National Institute of Standards and Technology (U.S. DOC) in providing the neutron research facilities used in this work is gratefully acknowledged. T.N. was supported by the SURF program funded in part by the NSF (DMR-0454672). This work was further supported by the NSF (CBET-0555201) and the American Health Assistance Foundation (A2008-307). Fruitful discussions with Duncan McGillivray, Gintaras Valincius and support from Paul Kienzle in software implementation are gratefully acknowledged. NR 36 TC 69 Z9 69 U1 2 U2 36 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0743-7463 J9 LANGMUIR JI Langmuir PD APR 7 PY 2009 VL 25 IS 7 BP 4219 EP 4229 DI 10.1021/la8033275 PG 11 WC Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary SC Chemistry; Materials Science GA 427RY UT WOS:000264798000040 PM 19714901 ER PT J AU Chung, JY Nolte, AJ Stafford, CM AF Chung, Jun Young Nolte, Adam J. Stafford, Christopher M. TI Diffusion-Controlled, Self-Organized Growth of Symmetric Wrinkling Patterns SO ADVANCED MATERIALS LA English DT Article ID THIN-FILMS; ELASTOMERIC POLYMER; ORDERED STRUCTURES; SURFACE; MECHANICS; SOLVENT; SKINS AB Symmetric instability patterns in the UV-ozone crosslinked surface of a polystyrene film grow radially outward from local defect sites in the presence of solvent vapor. The diffusion kinetics of the solvent governs the pattern morphology by establishing stress fields that favor the orientation of wrinkles in a dendritic-like spoke pattern (left) or in a target pattern consisting of concentric rings (right). C1 [Chung, Jun Young; Nolte, Adam J.; Stafford, Christopher M.] Natl Inst Stand & Technol, Div Polymers, Gaithersburg, MD 20899 USA. RP Stafford, CM (reprint author), Natl Inst Stand & Technol, Div Polymers, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM chris.stafford@nist.gov NR 35 TC 97 Z9 98 U1 9 U2 67 PU WILEY-V C H VERLAG GMBH PI WEINHEIM PA PO BOX 10 11 61, D-69451 WEINHEIM, GERMANY SN 0935-9648 J9 ADV MATER JI Adv. Mater. PD APR 6 PY 2009 VL 21 IS 13 BP 1358 EP 1362 DI 10.1002/adma.200803209 PG 5 WC Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter SC Chemistry; Science & Technology - Other Topics; Materials Science; Physics GA 436RM UT WOS:000265432700009 ER PT J AU Patridge, CJ Jaye, C Zhang, HS Marschilok, AC Fischer, DA Takeuchi, ES Banerjee, S AF Patridge, Christopher J. Jaye, Cherno Zhang, Hengsong Marschilok, Amy C. Fischer, Daniel A. Takeuchi, Esther S. Banerjee, Sarbajit TI Synthesis, Structural Characterization, and Electronic Structure of Single-Crystalline CuxV2O5 Nanowires SO INORGANIC CHEMISTRY LA English DT Article ID COPPER-VANADIUM BRONZE; X-RAY; LITHIUM INTERCALATION; CHARGE DISPROPORTIONATION; OXIDE CATALYSTS; V2O5; CU; BETA'-CUXV2O5; 2-PROPANOL; OXIDATION AB Single-crystalline copper vanadium oxide nanowires beta'-CuxV2O5 (x similar to 0.60) have been synthesized by the hydrothermal reduction of bulk CuV2O6 using small-molecule aliphatic alcohols as reducing agents. The prepared copper vanadium bronze nanowires are metallic in nature and exhibit aspect ratios as high as 300. The recent discovery of superconductivity and charge disproportionation in bulk beta'-CuxV2O5 has led to renewed interest in these one-dimensional metallic systems. Scaling these systems to nanoscale dimensions offers the potential for further tunability of electronic transport and Li-ion intercalation kinetics. A combination of spectroscopic and electrical measurement methods has been used to provide evidence for the metallic nature and the presence of room-temperature charge disproportionation in these nanowires. C1 [Patridge, Christopher J.; Zhang, Hengsong; Takeuchi, Esther S.; Banerjee, Sarbajit] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA. [Jaye, Cherno; Fischer, Daniel A.] NIST, Mat Sci & Engn Lab, Gaithersburg, MD 20899 USA. [Marschilok, Amy C.; Takeuchi, Esther S.] SUNY Buffalo, Dept Elect Engn, Buffalo, NY 14260 USA. [Takeuchi, Esther S.] SUNY Buffalo, Dept Chem & Biol Engn, Buffalo, NY 14260 USA. RP Banerjee, S (reprint author), SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA. EM sb244@buffalo.edu RI Marschilok, Amy/D-1821-2014; Takeuchi, Esther/D-1825-2014 NR 48 TC 27 Z9 27 U1 1 U2 32 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 0020-1669 J9 INORG CHEM JI Inorg. Chem. PD APR 6 PY 2009 VL 48 IS 7 BP 3145 EP 3152 DI 10.1021/ic802408c PG 8 WC Chemistry, Inorganic & Nuclear SC Chemistry GA 427DH UT WOS:000264759500053 PM 19260681 ER PT J AU Schmidt, KS Feingold, G Pilewskie, P Jiang, H Coddington, O Wendisch, M AF Schmidt, K. S. Feingold, G. Pilewskie, P. Jiang, H. Coddington, O. Wendisch, M. TI Irradiance in polluted cumulus fields: Measured and modeled cloud-aerosol effects SO GEOPHYSICAL RESEARCH LETTERS LA English DT Article AB We present a new strategy to validate modeled spectral irradiance of shallow cumulus cloud fields in a polluted background with airborne measurements. The concept is based on a spectral distinction of effects associated with heterogeneous clouds, aerosol particles, and surface albedo. We use measurements from the Gulf of Mexico Atmospheric Composition and Climate Study, conducted in the urban-industrial Houston area. Modeled irradiance fields were obtained from extensive three-dimensional radiative transfer calculations applied to the output of large eddy simulations. We show that the measurements below clouds or cloud gaps can only be reproduced by the calculations when including the aerosol radiative effects. The technique enables the derivation of measurement-based spectral forcing and absorption of the cloud-aerosol system which will help substantiate model calculations. At 400 nm wavelength, the inclusion of aerosol increases forcing of the cloud-aerosol system by 8%, and absorption by 20%. Citation: Schmidt, K. S., G. Feingold, P. Pilewskie, H. Jiang, O. Coddington, and M. Wendisch (2009), Irradiance in polluted cumulus fields: Measured and modeled cloud-aerosol effects, Geophys. Res. Lett., 36, L07804, doi: 10.1029/2008GL036848. C1 [Schmidt, K. S.; Pilewskie, P.; Coddington, O.] Univ Colorado, Atmospher & Space Phys Lab, Boulder, CO 80309 USA. [Feingold, G.; Jiang, H.] NOAA Earth Syst Res Lab, Div Chem Sci, Boulder, CO 80305 USA. [Wendisch, M.] Johannes Gutenberg Univ Mainz, Inst Atmospher Phys, D-55099 Mainz, Germany. RP Schmidt, KS (reprint author), Univ Colorado, Atmospher & Space Phys Lab, 392 Campus Box, Boulder, CO 80309 USA. EM sebastian.schmidt@lasp.colorado.edu RI Coddington, Odele/F-6342-2012; SCHMIDT, KONRAD SEBASTIAN/C-1258-2013; Feingold, Graham/B-6152-2009; Wendisch, Manfred/E-4175-2013; Jiang, Hongli/N-3281-2014; Manager, CSD Publications/B-2789-2015 OI Coddington, Odele/0000-0002-4338-7028; SCHMIDT, KONRAD SEBASTIAN/0000-0003-3899-228X; Wendisch, Manfred/0000-0002-4652-5561; FU NOAA [NA06OAR4310085, NA06OAR4310082]; NASA's Radiation Sciences Program and the Office of Science (BER); U. S. Department of Energy [DE-AI02-05ER63985] FX We are grateful to the CIRPAS Twin-Otter and California Institute of Technology for their help during GoMACCS. This work was supported by NOAA grants NA06OAR4310085 and NA06OAR4310082. We thank Warren Gore and Tony Trias, NASA Ames Research Center, for their technical support before and during GoMACCS. We thank Barry Lefer and staff for establishing and maintaining the Houston University AERONET site and Dean Atkinson from Portland State University for the in- situ aerosol data. Acquisition of the aerosol extinction profiles with the NASA LaRC HSRL was supported by NASA's Radiation Sciences Program and the Office of Science (BER), U. S. Department of Energy, interagency agreement DE-AI02-05ER63985. Bernhard Mayer, DLR Oberpfaffenhofen, Germany, provided the 3D-RTM MYSTIC. NR 18 TC 9 Z9 9 U1 0 U2 7 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0094-8276 J9 GEOPHYS RES LETT JI Geophys. Res. Lett. PD APR 4 PY 2009 VL 36 AR L07804 DI 10.1029/2008GL036848 PG 4 WC Geosciences, Multidisciplinary SC Geology GA 428PH UT WOS:000264860600002 ER PT J AU Vargas, M Kogan, F Guo, W AF Vargas, M. Kogan, F. Guo, W. TI Empirical normalization for the effect of volcanic stratospheric aerosols on AVHRR NDVI SO GEOPHYSICAL RESEARCH LETTERS LA English DT Article ID SURFACE TEMPERATURES; VEGETATION; ERUPTIONS; LAYER; CLOUDS AB The 1982 El Chichon and 1991 Mount Pinatubo volcanic eruptions produced large volumes of stratospheric aerosols that affected the environmental indices estimated from the Advanced Very High Resolution Radiometer (AVHRR) sensor. As a result the Normalized Difference Vegetation Index (NDVI) used to derive several vegetation health products exhibits a negative bias between approximately 20 degrees N and 20 degrees S during the post eruption years. In this work a statistical method based on Empirical Distribution Functions (EDF) and simple assumptions regarding the state of global vegetation is used to reduce these biases. Results show that the statistical technique effectively reduces the biases allowing the construction of consistent time series from this historical dataset for climate studies. Citation: Vargas, M., F. Kogan, and W. Guo (2009), Empirical normalization for the effect of volcanic stratospheric aerosols on AVHRR NDVI, Geophys. Res. Lett., 36, L07701, doi: 10.1029/2009GL037717. C1 [Vargas, M.; Kogan, F.] NOAA, Ctr Satellite Applicat & Res, Camp Springs, MD 20746 USA. [Guo, W.] IMSG, Camp Springs, MD 20746 USA. RP Vargas, M (reprint author), NOAA, Ctr Satellite Applicat & Res, 5200 Auth Rd,Suite 712, Camp Springs, MD 20746 USA. EM marco.vargas@noaa.gov RI Kogan, Felix/F-5600-2010; Vargas, Marco/F-5629-2010; Guo, Wei/E-7934-2011 OI Kogan, Felix/0000-0001-8216-900X; Vargas, Marco/0000-0001-6103-7278; Guo, Wei/0000-0003-3253-9441 FU Center for Satellite Applications and Research of NOAA FX This study was supported by the Center for Satellite Applications and Research of NOAA. The views, opinions, and findings contained in this report are those of the author(s) and should not be construed as an official NOAA or U. S. Government position, policy, or decision. NR 25 TC 3 Z9 3 U1 0 U2 0 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0094-8276 J9 GEOPHYS RES LETT JI Geophys. Res. Lett. PD APR 4 PY 2009 VL 36 AR L07701 DI 10.1029/2009GL037717 PG 4 WC Geosciences, Multidisciplinary SC Geology GA 428PH UT WOS:000264860600004 ER PT J AU Hudman, RC Murray, LT Jacob, DJ Turquety, S Wu, S Millet, DB Avery, M Goldstein, AH Holloway, J AF Hudman, R. C. Murray, L. T. Jacob, D. J. Turquety, S. Wu, S. Millet, D. B. Avery, M. Goldstein, A. H. Holloway, J. TI North American influence on tropospheric ozone and the effects of recent emission reductions: Constraints from ICARTT observations SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID CARBON-MONOXIDE; SURFACE OZONE; POLLUTION; ATLANTIC; METEOROLOGY; MODEL AB We use observations from the International Consortium for Atmospheric Research on Transport and Transformation (ICARTT) campaign over eastern North America in summer 2004, interpreted with a global 3-D model of tropospheric chemistry (GEOS-Chem), to improve and update estimates of North American influence on global tropospheric ozone and the effect of recent U. S. anthropogenic reductions on surface ozone pollution. We find that the 50% decrease in U. S. stationary NOx sources since 1999 has decreased mean U. S. boundary layer ozone concentrations by 6-8 ppbv in the southeast and 4-6 ppbv in the Midwest. The observed dO(3)/dCO molar enhancement ratio in the U. S. boundary layer during ICARTT was 0.46 mol mol(-1), larger than the range of 0.3-0.4 from studies in the early 1990s, possibly reflecting the decrease in the NOx/CO emission ratio as well as an increase in the ozone production efficiency per unit NOx. North American NOx emissions during summer 2004 as constrained by the ICARTT observations (0.72 Tg N fossil fuel, 0.11 Tg N biomass burning, 0.28 Tg N lightning for 1 July to 15 August) enhanced the hemispheric tropospheric ozone burden by 12.4%, with comparable contributions from fossil fuel and lightning (5-6%), but only 1% from biomass burning emissions despite 2004 being a record fire year over Alaska and western Canada. C1 [Avery, M.] NASA, Langley Res Ctr, Div Atmospher Sci, Hampton, VA 23681 USA. [Goldstein, A. H.] Univ Calif Berkeley, Dept Environm Sci Policy & Management, Berkeley, CA 94720 USA. [Holloway, J.] NOAA, Earth Syst Res Lab, Boulder, CO 80305 USA. [Hudman, R. C.; Murray, L. T.; Jacob, D. J.; Turquety, S.; Wu, S.; Millet, D. B.] Harvard Univ, Sch Engn & Appl Sci, Cambridge, MA 02138 USA. [Hudman, R. C.; Murray, L. T.; Jacob, D. J.; Turquety, S.; Wu, S.; Millet, D. B.] Harvard Univ, Dept Earth & Planetary Sci, Cambridge, MA 02138 USA. [Holloway, J.] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. RP Hudman, RC (reprint author), Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA. EM hudman@berkeley.edu RI Hudman, Rynda/C-6118-2009; Goldstein, Allen/A-6857-2011; Millet, Dylan/G-5832-2012; Holloway, John/F-9911-2012; Murray, Lee/F-2296-2014; Chem, GEOS/C-5595-2014 OI Goldstein, Allen/0000-0003-4014-4896; Holloway, John/0000-0002-4585-9594; Murray, Lee/0000-0002-3447-3952; FU NASA Global Tropospheric Chemistry Program; NOAA Office of Global Programs FX This work was funded by the NASA Global Tropospheric Chemistry Program and by the NOAA Office of Global Programs. Aboard the NOAA WP-3D aircraft measurements were provided for ozone, NO, NO2 (Tom Ryerson, NOAA ESRL), acetonitrile (Joost De Gouw, CIRES/NOAA ESRL), HNO3 (Andy Neuman, NOAA CIRES/ESRL), and PAN (Frank Flocke and Aaron Swanson, NCAR) and aboard the NASA DC-8 aircraft for HCN and PAN (Hanwant Singh, NASA Ames), NO2 (Ron Cohen and Tim Bertram, University of California, Berkeley), and NO (Bill Brune and Xinrong Ren). NR 49 TC 31 Z9 31 U1 1 U2 24 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X EI 2169-8996 J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD APR 4 PY 2009 VL 114 AR D07302 DI 10.1029/2008JD010126 PG 9 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 428QE UT WOS:000264863100001 ER PT J AU Russell, LM Takahama, S Liu, S Hawkins, LN Covert, DS Quinn, PK Bates, TS AF Russell, L. M. Takahama, S. Liu, S. Hawkins, L. N. Covert, D. S. Quinn, P. K. Bates, T. S. TI Oxygenated fraction and mass of organic aerosol from direct emission and atmospheric processing measured on the R/V Ronald Brown during TEXAQS/GoMACCS 2006 SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID CLOUD CONDENSATION NUCLEI; LIQUID SAMPLER PILS; CHEMICAL-COMPOSITION; FUNCTIONAL-GROUPS; AMBIENT AEROSOL; SPECTROMETER; PARTICLES; GROWTH; HYGROSCOPICITY; PACIFIC AB Submicron particles collected on Teflon filters aboard the R/V Ronald Brown during the Texas Air Quality Study and Gulf of Mexico Atmospheric Composition and Climate Study (TexAQS/GoMACCS) 2006 in and around the port of Houston, Texas, were measured by Fourier transform infrared (FTIR) and X-ray fluorescence for organic functional groups and elemental composition. Organic mass (OM) concentrations (1-25 mu g m(-3)) for ambient particle samples measured by FTIR showed good agreement with measurements made with an aerosol mass spectrometer. The fractions of organic mass identified as alkane and carboxylic acid groups were 47% and 32%, respectively. Three different types of air masses were identified on the basis of the air mass origin and the radon concentration, with significantly higher carboxylic acid group mass fractions in air masses from the north (35%) than the south (29%) or Gulf of Mexico (26%). Positive matrix factorization analysis attributed carboxylic acid fractions of 30-35% to factors with mild or strong correlations (r > 0.5) to elemental signatures of oil combustion and 9-24% to wood smoke, indicating that part of the carboxylic acid fraction of OM was formed by the same sources that controlled the metal emissions, namely the oil and wood combustion activities. The implication is that a substantial part of the measured carboxylic acid contribution was formed independently of traditionally "secondary" processes, which would be affected by atmospheric (both photochemical and meteorological) conditions and other emission sources. The carboxylic acid group fractions in the Gulf of Mexico and south air masses (GAM and SAM, respectively) were largely oil combustion emissions from ships as well as background marine sources, with only limited recent land influences (based on radon concentrations). Alcohol groups accounted for 14% of OM (mostly associated with oil combustion emissions and background sources), and amine groups accounted for 4% of OM in all air masses. Organosulfate groups were found in GAM and SAM, accounting for 1% and 3% of OM, respectively. Two thirds of the OM and oxygen-to-carbon (O/C) measured could be attributed to oil and wood combustion sources on the basis of mild or strong correlations to coemitted, nonvolatile trace metals, with the remaining one third being associated with atmospherically processed organic aerosol. The cloud condensation nuclei (CCN) fraction (normalized by total condensation nuclei) had weak correlations to the alcohol and amine group fractions and mild correlation with O/C, also varying inversely with alkane group fraction. The chemical components that influenced f(RH) were sulfate, organic, and nitrate fraction, but this contrast is consistent with the size-distribution dependence of CCN counters and nephelometers. C1 [Russell, L. M.; Takahama, S.; Liu, S.; Hawkins, L. N.] Univ Calif San Diego, Scripps Inst Oceanog, La Jolla, CA 92093 USA. [Covert, D. S.] Univ Washington, Joint Inst Study Atmospheres & Oceans, Seattle, WA 98195 USA. [Quinn, P. K.; Bates, T. S.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. RP Russell, LM (reprint author), Univ Calif San Diego, Scripps Inst Oceanog, 9500 Gilman Dr,Mail Code 0221, La Jolla, CA 92093 USA. EM lmrussell@ucsd.edu; stakahama@ucsd.edu; liushang@ucsd.edu; lnhawkins@ucsd.edu RI Liu, Shang/F-9085-2011; Bates, Timothy/L-6080-2016; Quinn, Patricia/R-1493-2016 OI Liu, Shang/0000-0002-3403-8651; Quinn, Patricia/0000-0003-0337-4895 FU National Oceanic and Atmospheric Administration [NA17RJ1231]; James S. McDonnell Foundation FX Sample collection and preliminary analysis were supported by the National Oceanic and Atmospheric Administration NA17RJ1231; method development and statistical analysis to quantify anthropogenic organic components were supported by an award from the James S. McDonnell Foundation. We thank Stefania Gilardoni, Derek Coffman, Drew Hamilton, Catherine Hoyle, and the crew of the NOAA R/V Ronald Brown for assistance in preparing and collecting filters for FTIR and XRF analysis. We also acknowledge helpful comments from Matt Fraser, Pentti Paatero, Greg Frost, Jose Jimenez, and Doug Worsnop. NR 57 TC 63 Z9 63 U1 5 U2 43 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X EI 2169-8996 J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD APR 4 PY 2009 VL 114 AR D00F05 DI 10.1029/2008JD011275 PG 15 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 428QE UT WOS:000264863100006 ER PT J AU Ferreira, JG Sequeira, A Hawkins, AJS Newton, A Nickell, TD Pastres, R Forte, J Bodoy, A Bricker, SB AF Ferreira, J. G. Sequeira, A. Hawkins, A. J. S. Newton, A. Nickell, T. D. Pastres, R. Forte, J. Bodoy, A. Bricker, S. B. TI Analysis of coastal and offshore aquaculture: Application of the FARM model to multiple systems and shellfish species SO AQUACULTURE LA English DT Article DE FARM; ASSETS; Farm-scale; Model; Aquaculture; Shellfish; Eutrophication; Emissions trading; Estuary; Bay ID CARRYING-CAPACITY; BIVALVE SHELLFISH; MYTILUS-EDULIS; SUSTAINABLE MANAGEMENT; TAPES-PHILIPPINARUM; MARINE AQUACULTURE; BOTTOM CULTURE; BOX MODEL; MUSSEL; GROWTH AB The Farm Aquaculture Resource Management (FARM) model has been applied to several shellfish species and aquaculture types. The performance of the FARM model, developed to simulate potential harvest, key financial data, and water quality impacts at the farm-scale, was tested in five systems in the European Union: Loch Cretan, Scotland (Pacific oyster), Pertuis Breton, France (blue mussel), Bay of Piran, Slovenia (Mediterranean mussel), Chioggia, Italy (Mediterranean mussel) and Ria Formosa, Portugal (Manila clam). These systems range from open coasts to estuaries, and are used for shellfish aquaculture by means of different cultivation techniques (e.g. oyster bottom culture in Loch Cretan and mussel longlines and poles in Pertuis Breton). The drivers for the FARM model were supplied by measured data, outputs of system-scale models or a combination of both. The results (given in total fresh weight) generally show good agreement with reported annual production (shown in brackets) at each farm: simulated production of 134 tons of Pacific oyster in Loch Cretan (150 tons, -10%), 2691 tons of blue mussel in Pertuis Breton (2304 tons, +17%), 314 tons of Mediterranean mussel in the Bay of Piran (200 tons, +57%), 545 tons of Mediterranean mussel in Chioggia (660 tons, -17%) and 119 tons of Manila clam in Ria Formosa (104 tons, +15%). The nitrogen mass balance for each farm was also determined with the FARM model. The net removal of nitrogen (N) by the farms was estimated to correspond to 1206 population equivalents per year (PEQ y(-1)) in Loch Cretan, 93503 PEQ y(-1) in Pertuis Breton, 9196 PEQ y(-1) in the Bay of Piran, 97916 PEQ y(-1) in Chioggia and 8613 PEQ y(-1) in Ria Formosa. The aggregate income due to both the shellfish sale and substitution value of land-based fertilizer reduction or nutrient treatment was estimated to be about 700 k(sic)y(-1) in Loch Cretan, 30,706 k(sic)y(-1) in Pertuis Breton, 3000 k(sic)y(-1) in the Bay of Piran, 30,000 k(sic)y(-1) in Chioggia, and 5000 k(sic)y(-1) in Ria Formosa. Outputs of FARM may be used to analyse the farm production potential and profit maximization according to seeding densities and/or spatial distribution. Results of a marginal analysis for all the study sites were determined. As an example, profit maximization in Loch Cretan was obtained with 97 tons of seed, resulting in a total production of 440 tons (profit of 2100 k(sic) for a culture period of about 2 years). FARM additionally integrates the well-known ASSETS model, for assessment of farm-related eutrophication impacts. The assessment results for the five study sites show that water quality is either maintained or improved in all farms under standard conditions of culture practice. FARM results may be used by farmers to analyse farm production potential and by managers for environmental assessment of farm-related water quality impacts, whether positive or negative. It is a useful tool for all stakeholders for the valuation of nitrogen credits, which may be traded as part of an integrated catchment management plan. The FARM results were scaled up to determine a net value of 11-17 billion (sic)y(-1) of ecosystem goods and services, provided by shellfish culture towards reducing eutrophication in the coastal waters of the European Union. These numbers highlight the role that extractive organic aquaculture plays in integrated coastal zone and nutrient emissions management. (C) 2009 Elsevier B.V. All rights reserved. C1 [Ferreira, J. G.; Sequeira, A.] FCT, DCEA, IMAR, CMA,Inst Marine Res,Ctr Ocean & Environm, P-2829516 Qta Torre, Monte Caparica, Portugal. [Hawkins, A. J. S.] Plymouth Marine Lab, Plymouth PL1 3DH, Devon, England. [Newton, A.] Univ Algarve, FCT, IMAR, P-8000117 Faro, Portugal. [Nickell, T. D.] Dunstaffnage Marine Lab Oban, Scottish Assoc Marine Sci, Oban PA37 1QA, Argyll, Scotland. [Pastres, R.] Univ Venice Ca Foscari, I-2137 Venice, Italy. [Bodoy, A.] IFREMER, CREMA, F-17137 Lhoumeau, France. [Bricker, S. B.] NCCOS, Natl Ocean Serv, NOAA, Silver Spring, MD 20910 USA. RP Ferreira, JG (reprint author), FCT, DCEA, IMAR, CMA,Inst Marine Res,Ctr Ocean & Environm, P-2829516 Qta Torre, Monte Caparica, Portugal. EM joao@hoomi.com RI Nickell, Thomas/A-9068-2010; OI Ferreira, Joao/0000-0001-9614-142X; Newton, Alice/0000-0001-9286-5914 FU EU [006540, INCO-CT-2004-510706]; KEYZONES FX The authors acknowledge the financial support of EU contracts 006540 (SSP8) (ECASA), INCO-CT-2004-510706 (SPEAR) and KEYZONES (CRAFF). We are grateful to P. Tett and H. Vaik for data on Loch Creran, D. Brigolin for data on Chioggia and to all the farmers and others who assisted in data collection for the study areas. We would like to thank three anonymous reviewers who suggested a number of improvements to the first draft of this paper. NR 56 TC 30 Z9 31 U1 8 U2 62 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0044-8486 J9 AQUACULTURE JI Aquaculture PD APR 3 PY 2009 VL 289 IS 1-2 BP 32 EP 41 DI 10.1016/j.aquaculture.2008.12.017 PG 10 WC Fisheries; Marine & Freshwater Biology SC Fisheries; Marine & Freshwater Biology GA 429TG UT WOS:000264942400006 ER PT J AU Wang, MY Overland, JE AF Wang, Muyin Overland, James E. TI A sea ice free summer Arctic within 30 years? SO GEOPHYSICAL RESEARCH LETTERS LA English DT Article ID SURFACE-TEMPERATURE; MODEL SIMULATIONS AB September 2008 followed 2007 as the second sequential year with an extreme summer Arctic sea ice extent minimum. Although such a sea ice loss was not indicated until much later in the century in the Intergovernmental Panel on Climate Change 4th Assessment Report, many models show an accelerating decline in the summer minimum sea ice extent during the 21st century. Using the observed 2007/2008 September sea ice extents as a starting point, we predict an expected value for a nearly sea ice free Arctic in September by the year 2037. The first quartile of the distribution for the timing of September sea ice loss will be reached by 2028. Our analysis is based on projections from six IPCC models, selected subject to an observational constraints. Uncertainty in the timing of a sea ice free Arctic in September is determined based on both within-model contributions from natural variability and between-model differences. Citation: Wang, M., and J. E. Overland (2009), A sea ice free summer Arctic within 30 years?, Geophys. Res. Lett., 36, L07502, doi: 10.1029/2009GL037820. C1 [Wang, Muyin] Univ Washington, Joint Inst Study Atmosphere & Oceans, Seattle, WA 98115 USA. [Overland, James E.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. RP Wang, MY (reprint author), Univ Washington, Joint Inst Study Atmosphere & Oceans, Seattle, WA 98115 USA. EM muyin.wang@noaa.gov RI Wang, Muyin/K-4006-2014 FU NOAA; Joint Institute for the Study of the Atmosphere and Ocean (JISAO) [NA17RJ1232]; U. S. Department of Energy FX We appreciate the support of NOAA Arctic Research of the Climate Program Office and discussions on this topic with many Arctic colleagues. This publication is partially funded by the Joint Institute for the Study of the Atmosphere and Ocean (JISAO) under NOAA Cooperative Agreement NA17RJ1232, contribution 1605. PMEL contribution 3261. We also like to thank Qiang Fu for his comments and suggestions on the manuscript. We acknowledge the modeling groups, the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and the World Climate Research Programme (WCRP)'s Working Group on Coupled Modelling (WGCM) for their roles in making available the WCRP CMIP3 multi-model dataset. We would like to thank the two anonymous reviewers and the editor for their valuable comments. Support of this dataset is provided by the Office of Science, U. S. Department of Energy. NR 25 TC 291 Z9 315 U1 16 U2 85 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 0094-8276 EI 1944-8007 J9 GEOPHYS RES LETT JI Geophys. Res. Lett. PD APR 3 PY 2009 VL 36 AR L07502 DI 10.1029/2009GL037820 PG 5 WC Geosciences, Multidisciplinary SC Geology GA 428PG UT WOS:000264860500007 ER PT J AU Muftuoglu, M de Souza-Pinto, NC Dogan, A Aamann, M Stevnsner, T Rybanska, I Kirkali, G Dizdaroglu, M Bohr, VA AF Muftuoglu, Meltem de Souza-Pinto, Nadja C. Dogan, Arin Aamann, Maria Stevnsner, Tinna Rybanska, Ivana Kirkali, Gueldal Dizdaroglu, Miral Bohr, Vilhelm A. TI Cockayne Syndrome Group B Protein Stimulates Repair of Formamidopyrimidines by NEIL1 DNA Glycosylase SO JOURNAL OF BIOLOGICAL CHEMISTRY LA English DT Article ID OXIDATIVELY DAMAGED DNA; BASE EXCISION-REPAIR; RNA-POLYMERASE-II; TRANSCRIPTION-COUPLED REPAIR; GENE-PRODUCT; CSB PROTEIN; SUBSTRATE-SPECIFICITY; XERODERMA-PIGMENTOSUM; HELICASE DOMAIN; OXIDIZED BASES AB Cockayne syndrome (CS) is a premature aging condition characterized by sensitivity to UV radiation. However, this phenotype does not explain the progressive neurodegeneration in CS patients. It could be due to the hypersensitivity of CSB-deficient cells to oxidative stress. So far most studies on the role of CSB in repair of oxidatively induced DNA lesions have focused on 7,8-dihydro-8-oxoguanine. This study examines the role of CSB in the repair of formamidopyrimidines 2,6-diamino-4-hydroxy-5-formamidopyrimidine (FapyGua) and 4,6-diamino-5-formamidopyrimidine (FapyAde), which are substrates for endonuclease VIII-like (NEIL1) DNA glycosylase. Results presented here show that csb(-/-) mice have a higher level of endogenous FapyAde and FapyGua in DNA from brain and kidney than wild type mice as well as higher levels of endogenous FapyAde in genomic DNA and mtDNA from liver. In addition, CSB stimulates NEIL1 incision activity in vitro, and CSB and NEIL1 co-immunoprecipitate and co-localize in HeLa cells. When CSB and NEIL1 are depleted from HeLa cells by short hairpin RNA knockdown, repair of induced FapyGua is strongly inhibited. These results suggest that CSB plays a role in repair of formamidopyrimidines, possibly by interacting with and stimulating NEIL1, and that accumulation of such modifications may have a causal role in the pathogenesis of CS. C1 [Muftuoglu, Meltem; de Souza-Pinto, Nadja C.; Dogan, Arin; Aamann, Maria; Rybanska, Ivana; Bohr, Vilhelm A.] NIA, Lab Mol Gerontol, Intramural Res Program, NIH, Baltimore, MD 21224 USA. [Stevnsner, Tinna] Aarhus Univ, Dept Mol Biol, Danish Aging Res Ctr, DK-8000 Aarhus, Denmark. [Stevnsner, Tinna] Aarhus Univ, Danish Ctr Mol Gerontol, DK-8000 Aarhus, Denmark. [Kirkali, Gueldal; Dizdaroglu, Miral] NIST, Chem Sci & Technol Lab, Gaithersburg, MD 20899 USA. [Dogan, Arin; Kirkali, Gueldal] Dokuz Eylul Univ, Fac Med, Dept Biochem, TR-35340 Izmir, Turkey. [Muftuoglu, Meltem] Univ Copenhagen, Ctr Healthy Ageing, DK-2200 Copenhagen, Denmark. RP Bohr, VA (reprint author), NIA, Lab Mol Gerontol, Intramural Res Program, NIH, 5600 Nathan Shock Dr, Baltimore, MD 21224 USA. EM vbohr@nih.gov RI Souza-Pinto, Nadja/C-3462-2013; 3, INCT/H-4497-2013; Redoxoma, Inct/H-9962-2013; Dogan, Arin/L-6443-2015 OI Souza-Pinto, Nadja/0000-0003-4206-964X; Dogan, Arin/0000-0002-5362-5501 FU National Institutes of Health; National Institute on Aging; National Institute of Standards and Technology FX This work was supported, in whole or in part, by the Intramural Research Program of the National Institutes of Health, National Institute on Aging, and National Institute of Standards and Technology. NR 55 TC 59 Z9 61 U1 1 U2 4 PU AMER SOC BIOCHEMISTRY MOLECULAR BIOLOGY INC PI BETHESDA PA 9650 ROCKVILLE PIKE, BETHESDA, MD 20814-3996 USA SN 0021-9258 J9 J BIOL CHEM JI J. Biol. Chem. PD APR 3 PY 2009 VL 284 IS 14 BP 9270 EP 9279 DI 10.1074/jbc.M807006200 PG 10 WC Biochemistry & Molecular Biology SC Biochemistry & Molecular Biology GA 425WS UT WOS:000264669100033 PM 19179336 ER PT J AU Lin, YJ Compton, RL Perry, AR Phillips, WD Porto, JV Spielman, IB AF Lin, Y. -J. Compton, R. L. Perry, A. R. Phillips, W. D. Porto, J. V. Spielman, I. B. CA BABAR Collaboration TI Bose-Einstein Condensate in a Uniform Light-Induced Vector Potential SO PHYSICAL REVIEW LETTERS LA English DT Article ID TONKS-GIRARDEAU GAS; ULTRACOLD ATOMS; LATTICES AB We use a two-photon dressing field to create an effective vector gauge potential for Bose-Einstein-condensed Rb-87 atoms in the F=1 hyperfine ground state. These Raman-dressed states are spin and momentum superpositions, and we adiabatically load the atoms into the lowest energy dressed state. The effective Hamiltonian of these neutral atoms is like that of charged particles in a uniform magnetic vector potential whose magnitude is set by the strength and detuning of the Raman coupling. The spin and momentum decomposition of the dressed states reveals the strength of the effective vector potential, and our measurements agree quantitatively with a simple single-particle model. While the uniform effective vector potential described here corresponds to zero magnetic field, our technique can be extended to nonuniform vector potentials, giving nonzero effective magnetic fields. C1 [Lin, Y. -J.] Natl Inst Stand & Technol, Joint Quantum Inst, Gaithersburg, MD 20899 USA. Univ Maryland, Gaithersburg, MD 20899 USA. RP Lin, YJ (reprint author), Natl Inst Stand & Technol, Joint Quantum Inst, Gaithersburg, MD 20899 USA. EM ian.spielman@nist.gov RI Perry, Abigail/C-6994-2011; Lin, Yu-Ju/F-7917-2012 FU NSF; NIST-NRC FX This work was partially supported by ONR, ODNI, ARO with funds from the DARPA OLE program, and the NSF through the JQI Physics Frontier Center. R. L. C. acknowledges support from NIST-NRC. NR 21 TC 315 Z9 319 U1 2 U2 27 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 0031-9007 J9 PHYS REV LETT JI Phys. Rev. Lett. PD APR 3 PY 2009 VL 102 IS 13 AR 130401 DI 10.1103/PhysRevLett.102.130401 PG 4 WC Physics, Multidisciplinary SC Physics GA 428YS UT WOS:000264888600001 PM 19392335 ER PT J AU Muhlbauer, S Pfleiderer, C Boni, P Laver, M Forgan, EM Fort, D Keiderling, U Behr, G AF Muehlbauer, S. Pfleiderer, C. Boeni, P. Laver, M. Forgan, E. M. Fort, D. Keiderling, U. Behr, G. TI Morphology of the Superconducting Vortex Lattice in Ultrapure Niobium SO PHYSICAL REVIEW LETTERS LA English DT Article ID FIELD GALVANOMAGNETIC PROPERTIES; ENERGY-GAP; STATE AB The morphology of the superconducting flux line lattice (FLL) of Nb comprises gradual variations with various lock-in transitions and symmetry breaking rotations. We report a comprehensive small-angle neutron scattering study of the FLL in an ultrapure single crystal of Nb as a function of the orientation of the applied magnetic field. We attribute the general morphology of the FLL and its orientation to three dominant mechanisms; first, nonlocal contributions, second, the transition between open and closed Fermi surface sheets and, third, the intermediate mixed state between the Meissner and the Shubnikov phase. C1 [Muehlbauer, S.; Pfleiderer, C.; Boeni, P.] Tech Univ Munich, Phy Dept E21, D-85748 Garching, Germany. [Muehlbauer, S.] Forsch Neutronenquelle Heinz Maier Leibnitz, D-85748 Garching, Germany. [Laver, M.] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA. [Laver, M.] Univ Maryland, College Pk, MD 20742 USA. [Keiderling, U.] BENSC, Helmholtz Zentrum Berlin, D-14109 Berlin, Germany. [Behr, G.] Leibnitz Inst Festkorper & Werkstoffforsch IFW, D-01069 Dresden, Germany. [Forgan, E. M.] Univ Birmingham, Sch Phys & Astron, Birmingham B15 2TT, W Midlands, England. RP Muhlbauer, S (reprint author), Tech Univ Munich, Phy Dept E21, D-85748 Garching, Germany. RI Pfleiderer, Christian/P-3575-2014 NR 22 TC 18 Z9 18 U1 1 U2 9 PU AMER PHYSICAL SOC PI COLLEGE PK PA ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA SN 0031-9007 J9 PHYS REV LETT JI Phys. Rev. Lett. PD APR 3 PY 2009 VL 102 IS 13 AR 136408 DI 10.1103/PhysRevLett.102.136408 PG 4 WC Physics, Multidisciplinary SC Physics GA 428YS UT WOS:000264888600049 PM 19392383 ER PT J AU Osthoff, HD Bates, TS Johnson, JE Kuster, WC Goldan, P Sommariva, R Williams, EJ Lerner, BM Warneke, C de Gouw, JA Pettersson, A Baynard, T Meagher, JF Fehsenfeld, FC Ravishankara, AR Brown, SS AF Osthoff, Hans D. Bates, Timothy S. Johnson, James E. Kuster, William C. Goldan, Paul Sommariva, Roberto Williams, Eric J. Lerner, Brian M. Warneke, Carsten de Gouw, Joost A. Pettersson, Anders Baynard, Tahllee Meagher, James F. Fehsenfeld, Frederick C. Ravishankara, A. R. Brown, Steven S. TI Regional variation of the dimethyl sulfide oxidation mechanism in the summertime marine boundary layer in the Gulf of Maine SO JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES LA English DT Article ID VOLATILE ORGANIC-COMPOUNDS; MASTER CHEMICAL MECHANISM; EXPERIMENT ACE 1; MCM V3 PART; TROPOSPHERIC DEGRADATION; ATMOSPHERIC SULFUR; CHEMISTRY; MODEL; PRODUCTS; NO3 AB Mixing ratios of dimethyl sulfide (DMS) and its nighttime oxidant, the nitrate radical (NO3), were measured in the summertime marine boundary layer (MBL) of the Gulf of Maine during the New England Air Quality Study-International Transport and Chemical Transformation campaign in 2004. DMS fluxes from the ocean were derived from simultaneous measurements of the wind speed and DMS in seawater. Day and night DMS oxidation rates were determined from modeled OH and measured NO3 concentrations. The average DMS lifetime with respect to oxidation by OH at noon was 13.5 +/- 3.4 (1 sigma) h, while at night, DMS lifetimes with respect to NO3 oxidation varied by sampling region from 11 min to 28 h. Oxidation by photochemically generated halogen species likely also played a role during the day, although the nature and extent of the halogen species is more difficult to predict due to lack of halogen measurements. Closure of the DMS budget in the MBL required a vertical entrainment velocity of similar to 0.4 cm s(-1). This study suggests that entrainment of DMS out of the MBL competes with daytime oxidation and that the presence of pollution in the form of NOx and O-3 in near-coastal regions at night results in nearly complete DMS oxidation within the MBL via reaction with NO3, with a much smaller contribution from entrainment. One potential implication of near-complete DMS oxidation within the MBL is a reduction of the amount of sulfur available for aerosol formation and growth at higher altitudes in the atmosphere. C1 [Osthoff, Hans D.; Kuster, William C.; Goldan, Paul; Sommariva, Roberto; Williams, Eric J.; Lerner, Brian M.; Warneke, Carsten; de Gouw, Joost A.; Pettersson, Anders; Baynard, Tahllee; Meagher, James F.; Fehsenfeld, Frederick C.; Ravishankara, A. R.; Brown, Steven S.] NOAA, Div Chem Sci, Earth Syst Res Lab, Boulder, CO 80305 USA. [Bates, Timothy S.; Johnson, James E.] NOAA, Pacific Marine Environm Lab, Seattle, WA 98115 USA. [Osthoff, Hans D.; Goldan, Paul; Sommariva, Roberto; Williams, Eric J.; Lerner, Brian M.; Warneke, Carsten; de Gouw, Joost A.; Pettersson, Anders; Baynard, Tahllee; Fehsenfeld, Frederick C.; Ravishankara, A. R.] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA. [Johnson, James E.] Univ Washington, Joint Inst Study Atmosphere & Oceans, Seattle, WA 98195 USA. [Ravishankara, A. R.] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA. RP Osthoff, HD (reprint author), Univ Calgary, Dept Chem, 2500 Univ Dr NW, Calgary, AB T2N 1N4, Canada. EM steven.s.brown@noaa.gov RI Williams, Eric/F-1184-2010; Warneke, Carsten/E-7174-2010; Kuster, William/E-7421-2010; Brown, Steven/I-1762-2013; Ravishankara, Akkihebbal/A-2914-2011; Fehsenfeld, Frederick/I-4876-2013; Manager, CSD Publications/B-2789-2015; Lerner, Brian/H-6556-2013; Sommariva, Roberto/M-5361-2014; de Gouw, Joost/A-9675-2008; Bates, Timothy/L-6080-2016 OI Osthoff, Hans/0000-0001-7155-6493; Kuster, William/0000-0002-8788-8588; Lerner, Brian/0000-0001-8721-8165; Sommariva, Roberto/0000-0002-2728-5814; de Gouw, Joost/0000-0002-0385-1826; FU NOAA's Health of the Atmosphere program FX The authors thank the crew and fellow scientists on board R/V Brown during NEAQS-ITCT 2004 and Roland von Glasow and Harald Stark for useful discussions in the preparation of this manuscript. Funding was provided in part by NOAA's Health of the Atmosphere program and in part by NOAA's Atmospheric Composition and Climate program. NR 50 TC 14 Z9 14 U1 2 U2 26 PU AMER GEOPHYSICAL UNION PI WASHINGTON PA 2000 FLORIDA AVE NW, WASHINGTON, DC 20009 USA SN 2169-897X EI 2169-8996 J9 J GEOPHYS RES-ATMOS JI J. Geophys. Res.-Atmos. PD APR 2 PY 2009 VL 114 AR D07301 DI 10.1029/2008JD010990 PG 13 WC Meteorology & Atmospheric Sciences SC Meteorology & Atmospheric Sciences GA 428PU UT WOS:000264862000004 ER PT J AU Raman, B Meier, DC Evju, JK Semancik, S AF Raman, Baranidharan Meier, Douglas C. Evju, Jon K. Semancik, Steve TI Designing and optimizing microsensor arrays for recognizing chemical hazards in complex environments SO SENSORS AND ACTUATORS B-CHEMICAL LA English DT Article DE Microsensor arrays; Metal oxide sensors; Toxic industrial chemicals; Statistical analysis; Material evaluation; Selection and optimization ID MASS-SPECTROMETRY; WARFARE AGENTS; PATTERN-RECOGNITION; SENSOR ARRAYS; CHROMATOGRAPHY; FUTURE AB A generic approach to designing microsensor arrays for complex chemical sensing tasks is described and demonstrated for the problem of recognizing chemical hazards at sublethal concentrations, under varying ambient conditions, and in the presence of interfering chemicals. We present statistical methods to systematically assess the analytical information obtained from the conductometric responses of chemiresistive elements at different operating temperatures, test their reproducibility, and determine an optimal set of material compositions to be incorporated within an array for individual species recognition. These advances are critical to the production of pre-programmed microsensors for non-invasive trace analyte detection relevant to homeland security, medical diagnostics, and other applications. (C) 2008 Elsevier B.V. All rights reserved. C1 [Raman, Baranidharan; Meier, Douglas C.; Evju, Jon K.; Semancik, Steve] Natl Inst Stand & Technol, Chem Sci & Technol Lab, Gaithersburg, MD 20899 USA. [Raman, Baranidharan] NICHD, Lab Cellular & Synapt Neurophysiol, NIH, Bethesda, MD 20892 USA. RP Semancik, S (reprint author), Natl Inst Stand & Technol, Chem Sci & Technol Lab, 100 Bur Dr MS8362, Gaithersburg, MD 20899 USA. EM steves@nist.gov FU U.S. Department of Homeland Security, Science and Technology Directorate; NIH(NIBIB)-NIST FX We acknowledge partial financial support of this project by the U.S. Department of Homeland Security, Science and Technology Directorate. BR was supported by a NIH(NIBIB)-NIST joint Postdoctoral Associateship Award administered through the National Research Council. We thank Kurt Benkstein, Mike Carrier, Steve Fick, Jim Melvin, Wyatt Miller, Chip Montgomery, Casey Mungle, Jim Yost, Blaine Young, and Li Zhang for their valuable contributions to this project. We are grateful to Mark Stopfer for helpful comments on an earlier version of this manuscript. NR 33 TC 41 Z9 41 U1 1 U2 8 PU ELSEVIER SCIENCE SA PI LAUSANNE PA PO BOX 564, 1001 LAUSANNE, SWITZERLAND SN 0925-4005 J9 SENSOR ACTUAT B-CHEM JI Sens. Actuator B-Chem. PD APR 2 PY 2009 VL 137 IS 2 BP 617 EP 629 DI 10.1016/j.snb.2008.11.053 PG 13 WC Chemistry, Analytical; Electrochemistry; Instruments & Instrumentation SC Chemistry; Electrochemistry; Instruments & Instrumentation GA 435EI UT WOS:000265326100036 ER PT J AU DeLongchamp, DM Kline, RJ Jung, Y Germack, DS Lin, EK Moad, AJ Richter, LJ Toney, MF Heeney, M McCulloch, I AF DeLongchamp, Dean M. Kline, R. Joseph Jung, Youngsuk Germack, David S. Lin, Eric K. Moad, Andrew J. Richter, Lee J. Toney, Michael F. Heeney, Martin McCulloch, Iain TI Controlling the Orientation of Terraced Nanoscale "Ribbons" of a Poly(thiophene) Semiconductor SO ACS NANO LA English DT Article DE polythiophene; crystal; nanoribbon; orientation; organic semiconductor ID LIQUID-CRYSTALLINE POLYFLUORENE; FIELD-EFFECT MOBILITY; REGIOREGULAR POLY(3-HEXYL THIOPHENE); MOLECULAR-WEIGHT POLYETHYLENE; ORIENTED THIN-FILMS; POLARIZED ELECTROLUMINESCENCE; THERMOTROPIC ALIGNMENT; TEMPERATURE-GRADIENT; CONJUGATED POLYMER; EFFECT TRANSISTORS AB The large-scale manufacture of organic electronics devices becomes more feasible if the molecular orientation and morphology of the semiconductor can be controlled. Here, we report on a previously unidentified crystal shape of terraced nanoscale "ribbons" in thin films of poly(2,5-bis(3-alkylthiophen-2-yl)thieno[3,2-b]thiophene) (pBTTT). The ribbons form after a pBTTT film is heated above its highest temperature phase transition. In contrast to the wide terrace crystal shape previously reported, terraced ribbons have lateral widths of approximate to 60 nm and lengths greater than 10 mu m, with a common orientation between adjacent ribbons. Further, we report a simple and scalable flow coating process that can control the ribbon orientation without requiring special substrates or external fields. The degree of molecular orientation is small after coating but increases dramatically after the terraced ribbons are formed, indicating that an oriented minority templates the whole film structure. The large extent of orientation obtained in these polythiophene crystallites provides potential opportunities to exploit anisotropic electrical properties and to obtain detailed information about the structure of organic semiconductor thin films. C1 [DeLongchamp, Dean M.; Kline, R. Joseph; Jung, Youngsuk; Germack, David S.; Lin, Eric K.; Moad, Andrew J.; Richter, Lee J.] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. [Heeney, Martin] Univ London, London E1 4NS, England. [McCulloch, Iain] Univ London Imperial Coll Sci Technol & Med, London SW7 2AZ, England. RP DeLongchamp, DM (reprint author), Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA. EM dean.delongchamp@nist.gov RI Kline, Regis/B-8557-2008; Heeney, Martin/O-1916-2013; Richter, Lee/N-7730-2016 OI Heeney, Martin/0000-0001-6879-5020; Richter, Lee/0000-0002-9433-3724 NR 46 TC 84 Z9 84 U1 7 U2 65 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1936-0851 J9 ACS NANO JI ACS Nano PD APR PY 2009 VL 3 IS 4 BP 780 EP 787 DI 10.1021/nn800574f PG 8 WC Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary SC Chemistry; Science & Technology - Other Topics; Materials Science GA 439HR UT WOS:000265618700009 PM 19317410 ER PT J AU Chung, JY Chastek, TQ Fasolka, MJ Ro, HW Stafford, CM AF Chung, Jun Young Chastek, Thomas Q. Fasolka, Michael J. Ro, Hyun Wook Stafford, Christopher M. TI Quantifying Residual Stress in Nanoscale Thin Polymer Films via Surface Wrinkling SO ACS NANO LA English DT Article DE coatings; mechanical properties; nanoscale thin films; polymers; residual stress; small-angle light scattering; surface wrinkling ID GLASS-TRANSITION TEMPERATURE; INTERNAL-STRESS; SPIN-CAST; BUCKLING INSTABILITY; THERMAL-STRESS; ELASTIC-MODULI; COATINGS; SOLVENT; BEHAVIOR; PLATES AB Residual stress, a pervasive consequence of solid materials processing, is stress that remains in a material after external forces have been removed. In polymeric materials, residual stress results from processes, such as film formation, that force and then trap polymer chains into nonequilibrium stressed conformations. In solvent-cast films, which are central to a wide range of technologies, residual stress can cause detrimental effects, including microscopic defect formation and macroscopic dimensional changes. Since residual stress is difficult to measure accurately, particularly in nanoscale thin polymer films, it remains a challenge to understand and control. We present here a quantitative method of assessing residual stress in polymer thin films by monitoring the onset of strain-induced wrinkling instabilities. Using this approach, we show that thin (> 100 nm) polystyrene films prepared via spin-coating possess residual stresses of approximate to 30 MPa, close to the crazing and yield stress. In contrast to conventional stress measurement techniques such as wafer curvature, our technique has the resolution to measure residual stress in films as thin as 25 nm. Furthermore, we measure the dissipation of residual stress through two relaxation mechanisms: thermal annealing and plasticizer addition. In quantifying the amount of residual stress in these films, we find that the residual stress gradually decreases with increasing annealing time and plasticizer amounts. Our robust and simple route to measure residual stress adds a key component to the understanding of polymer thin film behavior and will enable identification of more effective processing routes that mitigate the detrimental effects of residual stress. C1 [Chung, Jun Young; Chastek, Thomas Q.; Fasolka, Michael J.; Ro, Hyun Wook; Stafford, Christopher M.] Natl Inst Stand & Technol, Div Polymers, Gaithersburg, MD 20899 USA. RP Stafford, CM (reprint author), Natl Inst Stand & Technol, Div Polymers, 100 Bur Dr, Gaithersburg, MD 20899 USA. EM chris.stafford@nist.gov NR 53 TC 64 Z9 64 U1 7 U2 84 PU AMER CHEMICAL SOC PI WASHINGTON PA 1155 16TH ST, NW, WASHINGTON, DC 20036 USA SN 1936-0851 J9 ACS NANO JI ACS Nano PD APR PY 2009 VL 3 IS 4 BP 844 EP 852 DI 10.1021/nn800853y PG 9 WC Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary SC Chemistry; Science & Technology - Other Topics; Materials Science GA 439HR UT WOS:000265618700016 PM 19298053 ER PT J AU Carr, LD McKagan, SB AF Carr, L. D. McKagan, S. B. TI Graduate quantum mechanics reform SO AMERICAN JOURNAL OF PHYSICS LA English DT Article DE physics education; quantum theory; teaching ID RELATIVE STATE FORMULATION; PHYSICS; MODELS; TIME AB We address four main areas in which graduate quantum mechanics education can be improved: course content, textbook, teaching methods, and assessment tools. We report on a three year longitudinal study at the Colorado School of Mines using innovations in all these areas. In particular, we have modified the content of the course to reflect progress in the field of quantum mechanics over the last 50 years, used textbooks that include such content, incorporated a variety of teaching techniques based on physics education research, and used a variety of assessment tools to study the effectiveness of these reforms. We present a new assessment tool, the Graduate Quantum Mechanics Conceptual Survey, and further testing of a previously developed assessment tool, the Quantum Mechanics Conceptual Survey. We find that graduate students respond well to research-based techniques that have been tested mainly in introductory courses, and that they learn much of the new content introduced in each version of the course. We also find that students' ability to answer conceptual questions about graduate quantum mechanics is highly correlated with their ability to solve calculational problems on the same topics. In contrast, we find that students' understanding of basic undergraduate quantum mechanics concepts at the modern physics level is not improved by instruction at the graduate level. C1 [Carr, L. D.] Colorado Sch Mines, Dept Phys, Golden, CO 80401 USA. [McKagan, S. B.] Univ Colorado, JILA, Boulder, CO 80309 USA. [McKagan, S. B.] NIST, Boulder, CO 80309 USA. RP Carr, LD (reprint author), Colorado Sch Mines, Dept Phys, Golden, CO 80401 USA. RI Carr, Lincoln/E-3819-2016 OI Carr, Lincoln/0000-0002-4848-7941 NR 50 TC 18 Z9 18 U1 1 U2 8 PU AMER ASSOC PHYSICS TEACHERS AMER INST PHYSICS PI MELVILLE PA STE 1 NO 1, 2 HUNTINGTON QUADRANGLE, MELVILLE, NY 11747-4502 USA SN 0002-9505 J9 AM J PHYS JI Am. J. Phys. PD APR PY 2009 VL 77 IS 4 BP 308 EP 319 DI 10.1119/1.3079689 PG 12 WC Education, Scientific Disciplines; Physics, Multidisciplinary SC Education & Educational Research; Physics GA 420MP UT WOS:000264294200004 ER PT J AU Parsons, KM Balcomb, KC Ford, JKB Durban, JW AF Parsons, K. M. Balcomb, K. C., III Ford, J. K. B. Durban, J. W. TI The social dynamics of southern resident killer whales and conservation implications for this endangered population SO ANIMAL BEHAVIOUR LA English DT Article DE association; conservation; endangered; killer whale; mammal; Orcinus orca; social dynamic; social structure ID BOTTLE-NOSED DOLPHINS; ORCINUS-ORCA; GROUP-SIZE; CULTURAL TRANSMISSION; ORGANIZATION; BEHAVIOR; ECOLOGY; EVOLUTION; SYSTEMS; ASSOCIATION AB Quantitatively characterizing the social structure of a population provides important insight into the forces shaping key population processes. Moreover, long-term social dynamics provide an avenue for understanding population-level responses to changes in socioecological conditions. This is particularly true for species that show natal philopatry and highly stable hierarchically structured social units, such as the piscivorous resident killer whales of the northeast Pacific. The southern resident killer whale population is a small, demographically closed population, comprising three commonly recognized pods (J,K and L pods), that has recently been listed as endangered throughout its range in both Canadian and U. S. A. waters. In this study, we quantitatively assessed social structure in this population from 29 years of photo-identification data to characterize significant temporal changes in sociality. Preferential affiliation among killer whales within both genealogical matrilines and pods was supported by two different analytical methods and, despite interannual variability, these social clusters persisted throughout the study. All three pods experienced fluctuations in social cohesion over time, but the overall rate of intrapod affiliation was consistently lowest within L pod, the largest of the southern resident pods. The most recent increase in fluidity within social units, occurring in the mid to late 1990s, was coincident with a significant decline in population size, suggesting a possible common response to external stressors. Quantifying these trends in social structure is the first step towards understanding the causes and consequences of long-term changes in killer whale social structure. (C) 2009 The Association for the Study of Animal Behaviour. Published by Elsevier Ltd. All rights reserved. C1 [Parsons, K. M.; Durban, J. W.] Natl Marine Fisheries Serv, NMML, Alaska Fisheries Sci Ctr, Seattle, WA 98115 USA. [Parsons, K. M.] Natl Marine Fisheries Serv, NW Fisheries Sci Ctr, Seattle, WA 98115 USA. [Parsons, K. M.; Balcomb, K. C., III] Ctr Whale Res, Friday Harbor, WA USA. [Ford, J. K. B.] Fisheries & Oceans Canada, Pacific Biol Stn, Nanaimo, BC V9R 5K6, Canada. RP Parsons, KM (reprint author), Natl Marine Fisheries Serv, NMML, Alaska Fisheries Sci Ctr, 7600 Sandpoint Way NE, Seattle, WA 98115 USA. EM kim.parsons@mail.com RI Parsons, Kim/A-8050-2011 FU Fisheries and Oceans Canada (DFO); Earthwatch Institute; Northwest Fisheries Science Center (NOAA Fisheries) FX The data used in this study are the result of many years of collaborative fieldwork. We are indebted to the many colleagues and volunteers that participated in both fieldwork and data entry and made this project possible. A special note of credit goes to the late M. A. Bigg, and to G. Ellis, D. Ellifrit, A. van Ginneken. The longterm killer whale studies have been supported by Fisheries and Oceans Canada (DFO) and research grants from Earthwatch Institute. This publication was completed as part of K. M. P.' s National Research Council postdoctoral fellowship hosted by the Northwest Fisheries Science Center (NOAA Fisheries). NR 82 TC 30 Z9 32 U1 10 U2 82 PU ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD PI LONDON PA 24-28 OVAL RD, LONDON NW1 7DX, ENGLAND SN 0003-3472 J9 ANIM BEHAV JI Anim. Behav. PD APR PY 2009 VL 77 IS 4 BP 963 EP 971 DI 10.1016/j.anbehav.2009.01.018 PG 9 WC Behavioral Sciences; Zoology SC Behavioral Sciences; Zoology GA 420YO UT WOS:000264325300024 ER PT J AU Near, TJ Jones, CD Eastman, JT AF Near, Thomas J. Jones, Christopher D. Eastman, Joseph T. TI Geographic intraspecific variation in buoyancy within Antarctic notothenioid fishes SO ANTARCTIC SCIENCE LA English DT Article DE Gymnodraco; ontogenetic variation; Pleuragramma; Trematomus ID TERRA-NOVA BAY; SOUTH SHETLAND ISLANDS; MCMURDO SOUND; ROSS SEA; PLEURAGRAMMA-ANTARCTICUM; TREMATOMUS HANSONI; DIET; PISCES; SWIMBLADDER; PERCIFORMES AB We investigated intraspecific geographic variation in buoyancy by obtaining percentage buoyancy (%B) measurements for the Antarctic notothenioid species Pleuragramma antarcticum, Trematomus hansoni, T. bernacchii and Gymnodraco acuticeps from both McMurdo Sound in East Antarctica and the South Shetland Islands in West Antarctica. Mean percentage buoyancies in these species ranged from 0.22-0.52% in the neutrally buoyant P. antarcticum to 3.34-3.67% in the benthic T bernacchii. Dispersion (I standard deviation) of percentage buoyancy (%B) values around the mean was +/- 0.2-0.5 %B units for the entire sample. Although intraspecific differences in mean percentage buoyancy were statistically significant (P < 0.05) in P. antarcticum and T hansoni, we consider these differences as normal variation without substantive biological significance. The dispersion in buoyancy measurements during adult life reflects the density of the fish and this may be influenced, in both the short- and long-term, by gut contents, nutritional condition, and reproductive state. Mitigation of the effects of these variables is not biologically realistic because they constitute normal aspects of the daily and yearly life cycles. The results of our measurements of buoyancy are consistent with what is known about the ecology of these four species and this is considered in the discussion. C1 [Eastman, Joseph T.] Ohio Univ, Dept Biomed Sci, Athens, OH 45701 USA. [Near, Thomas J.] Yale Univ, Dept Ecol & Evolutionary Biol, New Haven, CT 06520 USA. [Near, Thomas J.] Yale Univ, Peabody Museum Nat Hist, New Haven, CT 06520 USA. [Jones, Christopher D.] Natl Marine Fisheries Serv, SW Fisheries Sci Ctr, Natl Ocean & Atmospher Adm, La Jolla, CA 92037 USA. RP Eastman, JT (reprint author), Ohio Univ, Dept Biomed Sci, Athens, OH 45701 USA. EM eastman@ohiou.edu RI Eastman, Joseph/A-9786-2008 FU NSF [ANT 04-36190] FX We thank the officers and crew of the RV Yuzhmorgeologiya. Support for collecting in the South Shetland Islands was provided by the United States Antarctic Marine Living Resources (AMLR) Program. A.L. DeVries assisted in the some of the data collection in the South Shetlands. B.M. Fitzpatrick provided helpful comments on the manuscript. We are grateful to Danette Pratt for producing Fig. 1. JTE was supported by NSF grant ANT 04-36190. NR 43 TC 9 Z9 9 U1 1 U2 6 PU CAMBRIDGE UNIV PRESS PI NEW YORK PA 32 AVENUE OF THE AMERICAS, NEW YORK, NY 10013-2473 USA SN 0954-1020 EI 1365-2079 J9 ANTARCT SCI JI Antarct. Sci. PD APR PY 2009 VL 21 IS 2 BP 123 EP 129 DI 10.1017/S0954102008001661 PG 7 WC Environmental Sciences; Geography, Physical; Geosciences, Multidisciplinary SC Environmental Sciences & Ecology; Physical Geography; Geology GA 425QM UT WOS:000264652200004 ER PT J AU Pibida, L Fitzgerald, R Unterweger, M Hammond, MM Golas, D AF Pibida, L. Fitzgerald, R. Unterweger, M. Hammond, M. M. Golas, D. TI Measurements of the (82)Sr half-life SO APPLIED RADIATION AND ISOTOPES LA English DT Article DE (82)Sr half-life; Gamma-ray spectrometry; Ionization chamber AB Half-life of (82)Sr was measured at the National Institute of Standards and Technology (NIST) using gamma-ray spectrometry and a 4 pi gamma pressurized ionization chamber. The (82)Sr half-life was found to be 25.36 +/- 0.03 days (k = 1) according to gamma-ray spectrometry and 25.34 +/- 0.02 days (k = 1) according to the 4 pi gamma pressurized ionization chamber measurements. Published by Elsevier Ltd. C1 [Pibida, L.; Fitzgerald, R.; Unterweger, M.; Hammond, M. M.] NIST, Gaithersburg, MD 20899 USA. [Golas, D.] Nucl Energy Inst, Washington, DC 20006 USA. RP Pibida, L (reprint author), NIST, 100 Bur Dr,Stop 8462, Gaithersburg, MD 20899 USA. EM leticia.pibida@nist.gov RI Fitzgerald, Ryan/H-6132-2016 NR 16 TC 3 Z9 3 U1 0 U2 1 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 0969-8043 J9 APPL RADIAT ISOTOPES JI Appl. Radiat. Isot. PD APR PY 2009 VL 67 IS 4 BP 636 EP 640 DI 10.1016/j.apradiso.2008.11.017 PG 5 WC Chemistry, Inorganic & Nuclear; Nuclear Science & Technology; Radiology, Nuclear Medicine & Medical Imaging SC Chemistry; Nuclear Science & Technology; Radiology, Nuclear Medicine & Medical Imaging GA 420QY UT WOS:000264305500026 PM 19155178 ER PT J AU Tipping, PW Bauer, L Martin, MR Center, TD AF Tipping, Philip W. Bauer, Laurie Martin, Melissa R. Center, Ted D. TI Competition between Salvinia minima and Spirodela polyrhiza mediated by nutrient levels and herbivory SO AQUATIC BOTANY LA English DT Article DE Salvinia minima; Spirodela polyrhiza; Competition; Herbivory; Nutrient ID VALLISNERIA-AMERICANA; HYDRILLA-VERTICILLATA; POPULATION-DYNAMICS; BIOLOGICAL-CONTROL; AQUATIC PLANTS; COMMUNITIES; VEGETATION; DUCKWEED; FOREST; WATER AB We investigated the effects of initial biomass, nutrients, herbivory, and competition with Spirodela polyrhiza (L) Schleid on Salvinia minima Baker biomass and density. S. minima populations were subjected to two levels of herbivory (control vs. two adults per plant) from the weevil Cyrtobagous salviniae Calder and Sands and eight levels of competition from S. polyrhiza, while growing in high (5 mg N l(-1)) or low (0.5 mg N l(-1)) nutrient conditions. Herbivory was the most important factor in S. minima biomass production while competition or fertility had no measurable impact. In contrast, S. polyrhiza biomass was mediated primarily by nutrients, not competition. There was no herbivory treatment for this plant. S. polyrhiza was superior to S. minima at converting nutrients to biomass but this did not give it a competitive advantage since S. minima biomass was unchanged when herbivory was absent. S. minima can generally overtop S. polyrhiza which, in turn, can form multiple layers within its mat. These characteristics may act to lessen competition between these species, thereby permitting their habitat sharing. Published by Elsevier B.V. C1 [Tipping, Philip W.; Center, Ted D.] ARS, USDA, Invas Plant Res Lab, Ft Lauderdale, FL USA. [Bauer, Laurie] Natl Ocean Serv, Ctr Coastal Monitoring & Assessment, Silver Spring, MD USA. [Martin, Melissa R.] Univ Florida, Dept Soil & Water Sci, Gainesville, FL USA. RP Tipping, PW (reprint author), ARS, USDA, Invas Plant Res Lab, Ft Lauderdale, FL USA. EM Philip.tipping@ars.usda.gov NR 40 TC 7 Z9 7 U1 4 U2 24 PU ELSEVIER SCIENCE BV PI AMSTERDAM PA PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS SN 0304-3770 J9 AQUAT BOT JI Aquat. Bot. PD APR PY 2009 VL 90 IS 3 BP 231 EP 234 DI 10.1016/j.aquabot.2008.10.004 PG 4 WC Plant Sciences; Marine & Freshwater Biology SC Plant Sciences; Marine & Freshwater Biology GA 425ZO UT WOS:000264677200003 ER PT J AU Siringo, G Kreysa, E Kovacs, A Schuller, F Weiss, A Esch, W Gemund, HP Jethava, N Lundershausen, G Colin, A Gusten, R Menten, KM Beelen, A Bertoldi, F Beeman, JW Haller, EE AF Siringo, G. Kreysa, E. Kovacs, A. Schuller, F. Weiss, A. Esch, W. Gemuend, H. -P. Jethava, N. Lundershausen, G. Colin, A. Guesten, R. Menten, K. M. Beelen, A. Bertoldi, F. Beeman, J. W. Haller, E. E. TI The Large APEX BOlometer CAmera LABOCA SO ASTRONOMY & ASTROPHYSICS LA English DT Article DE instrumentation: detectors; instrumentation: photometers; submillimeter; methods: observational ID MILLIMETER OBSERVATIONS; STAR-FORMATION; DUST EMISSION; MU-M; SUBMILLIMETER; CONTINUUM; GALAXIES; QUASARS; CLOUD; SCUBA AB The Large APEX BOlometer CAmera, LABOCA, has been commissioned for operation as a new facility instrument at the Atacama Pathfinder Experiment 12m submillimeter telescope. This new 295-bolometer total power camera, operating in the 870 mu m atmospheric window, combined with the high efficiency of APEX and the excellent atmospheric transmission at the site, offers unprecedented capability in mapping submillimeter continuum emission for a wide range of astronomical purposes. C1 [Siringo, G.; Kreysa, E.; Kovacs, A.; Schuller, F.; Weiss, A.; Esch, W.; Gemuend, H. -P.; Lundershausen, G.; Guesten, R.; Menten, K. M.] Max Planck Inst Radioastron, D-53121 Bonn, Germany. [Jethava, N.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. [Colin, A.] CSIC UC, Inst Fis Cantabria, Santander 39005, Spain. [Beelen, A.] Univ Paris 11, Inst Astrophys Spatiale, F-91405 Orsay, France. [Bertoldi, F.] Univ Bonn, Argelander Inst Astron, D-53121 Bonn, Germany. [Beeman, J. W.; Haller, E. E.] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA. RP Siringo, G (reprint author), Max Planck Inst Radioastron, Hugel 69, D-53121 Bonn, Germany. EM gsiringo@mpifr-bonn.mpg.de RI Kovacs, Attila/C-1171-2010 OI Kovacs, Attila/0000-0001-8991-9088 NR 38 TC 186 Z9 186 U1 0 U2 1 PU EDP SCIENCES S A PI LES ULIS CEDEX A PA 17, AVE DU HOGGAR, PA COURTABOEUF, BP 112, F-91944 LES ULIS CEDEX A, FRANCE SN 0004-6361 J9 ASTRON ASTROPHYS JI Astron. Astrophys. PD APR PY 2009 VL 497 IS 3 BP 945 EP 962 DI 10.1051/0004-6361/200811454 PG 18 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA 434ND UT WOS:000265280500027 ER PT J AU Jimenez, R Spergel, DN Niemack, MD Menanteau, F Hughes, JP Verde, L Kosowsky, A AF Jimenez, Raul Spergel, David N. Niemack, Michael D. Menanteau, Felipe Hughes, John P. Verde, Licia Kosowsky, Arthur TI SOUTHERN COSMOLOGY SURVEY. III. QSOs FROM COMBINED GALEX AND OPTICAL PHOTOMETRY SO ASTROPHYSICAL JOURNAL SUPPLEMENT SERIES LA English DT Article DE atomic processes; cosmology: theory; early universe; intergalactic medium ID DIGITAL-SKY-SURVEY; GALAXY-EVOLUTION-EXPLORER; DATA RELEASE; CLASSIFICATION; SELECTION; FEEDBACK; QUASARS AB We present catalogs of QSO candidates selected using photometry from Galaxy Evolution Explorer (GALEX) combined with the Sloan Digital Sky Survey (SDSS) in the Stripe 82 region and Blanco Cosmology Survey (BCS) near declination -55 degrees. The SDSS region contains similar or equal to 700 objects with magnitude i < 20 and similar or equal to 3600 objects with i < 21.5 in a similar or equal to 60 deg(2) sky region, while the BCS region contains similar or equal to 280 objects with magnitude i < 20 and similar to 2000 objects with i < 21.5 for a 11 deg(2) sky region that is being observed by three current microwave Sunyaev-Zeldovich surveys. Our QSO catalog is the first one in the BCS region. Deep GALEX exposures (greater than or similar to 2000 s in F-UV and N-UV, except in three fields) provide high signal-to-noise photometry in the GALEX bands (F-UV, N-UV < 24.5 mag). From this data, we select QSO candidates using only GALEX and optical r-band photometry, using the method given by Atlee & Gould. In the Stripe 82 field, 60% (30%) of the GALEX-selected QSOs with optical magnitude i < 20 (i < 21.5) also appear in the Richards et al. QSO catalog constructed using five-band optical SDSS photometry. Comparison with the same catalog by Richards et al. shows that the completeness of the sample is approximately 40% (25%). However, for regions of the sky with very low dust extinction, like the BCS 23-hr field and the Stripe 82 between 0 degrees and 10 degrees in R. A., our completeness is close to 95%, demonstrating that deep GALEX observations are almost as efficient as multiwavelength observations at finding QSOs. GALEX observations thus provide a viable alternate route to QSO catalogs in sky regions where u-band optical photometry is not available. The full catalog is available at http://www.ice.csic.es/personal/jimenez/PHOTOZ. C1 [Jimenez, Raul; Verde, Licia] CSIC IEEC, ICREA & Inst Space Sci, Bellaterra 08193, Spain. [Jimenez, Raul; Spergel, David N.; Verde, Licia] Princeton Univ, Dept Astrophys Sci, Princeton, NJ 08544 USA. [Niemack, Michael D.] Natl Inst Stand & Technol, Boulder, CO 80305 USA. [Menanteau, Felipe; Hughes, John P.] Rutgers State Univ, Dept Phys & Astron, Piscataway, NJ 08854 USA. [Kosowsky, Arthur] Univ Pittsburgh, Dept Phys & Astron, Pittsburgh, PA 15208 USA. RP Jimenez, R (reprint author), CSIC IEEC, ICREA & Inst Space Sci, Campus UAB, Bellaterra 08193, Spain. EM raulj@astro.princeton.edu RI Spergel, David/A-4410-2011; OI Menanteau, Felipe/0000-0002-1372-2534; Verde, Licia/0000-0003-2601-8770; Jimenez, Raul/0000-0002-3370-3103 FU GALEX [GI3-095]; Spanish Ministry for Science and Innovation; European Union; NSF [PIRE-0507768, AST-0546035]; CSIC I3 [200750I034]; [FP7-PEOPLE-2007-4-3-IRGn202182] FX We thank Gordon Richards for useful comments. This work has been supported by GALEX grant GI3-095. The work of R.J. is supported by grants from the Spanish Ministry for Science and Innovation and the European Union (FP7 program). R.J., D.N.S., J.P.H., and F. M. are partially supported by NSF grant PIRE-0507768. L. V. acknowledges support by FP7-PEOPLE-2007-4-3-IRGn202182 and CSIC I3 grant 200750I034. A. K. was partly supported by NSF grant AST-0546035. NR 15 TC 3 Z9 3 U1 0 U2 1 PU IOP PUBLISHING LTD PI BRISTOL PA TEMPLE CIRCUS, TEMPLE WAY, BRISTOL BS1 6BE, ENGLAND SN 0067-0049 EI 1538-4365 J9 ASTROPHYS J SUPPL S JI Astrophys. J. Suppl. Ser. PD APR PY 2009 VL 181 IS 2 BP 439 EP 443 DI 10.1088/0067-0049/181/2/439 PG 5 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA 426ZF UT WOS:000264746700009 ER PT J AU Linsky, J AF Linsky, Jeffrey L. TI Summary of the First NUVA Conference Space Astronomy: the UV Window to the Universe SO ASTROPHYSICS AND SPACE SCIENCE LA English DT Article; Proceedings Paper CT Conference on Network for Ultra Violet Astronomy CY JUN, 2007 CL Madrid, SPAIN DE Ultraviolet: spectra; Ultraviolet: ISM; Ultraviolet: stars; Techniques: spectroscopic AB In this summary of the conference Space Astronomy: the UV Window to the Universe, held in El Escorial, Spain, May 28 to June 1, 2007, I identify the important scientific questions posed by the speakers and the corresponding discoveries that future ultraviolet space instruments should enable. The science objectives described by the various speakers naturally fall into groups according to the needed instrumental requirements: wavelength coverage, spectral resolution, sensitivity, rapid access to targets, monitoring, and signal/noise. Although most of the science objectives presented during the conference require UV spectra in the 1,170-3,200 A... range, there are important science objectives that require spectra in the 912-1,170 A... range and at shorter wavelengths. I identify the limitations of present instruments for meeting these requirements. To avoid the upcoming UV dark age, important work must be done to properly build the World Space Observatory (WSO) and to plan future space missions. C1 [Linsky, Jeffrey L.] Univ Colorado, JILA, Boulder, CO 80309 USA. [Linsky, Jeffrey L.] NIST, Boulder, CO 80309 USA. RP Linsky, J (reprint author), Univ Colorado, JILA, Boulder, CO 80309 USA. EM jlinsky@jila.colorado.edu NR 2 TC 0 Z9 0 U1 0 U2 1 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0004-640X J9 ASTROPHYS SPACE SCI JI Astrophys. Space Sci. PD APR PY 2009 VL 320 IS 1-3 BP 3 EP 9 DI 10.1007/s10509-007-9706-2 PG 7 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA 418UK UT WOS:000264174700002 ER PT J AU Linsky, J AF Linsky, Jeffrey L. TI Solving the mysteries of the diffuse interstellar medium with high-resolution UV spectroscopy SO ASTROPHYSICS AND SPACE SCIENCE LA English DT Article; Proceedings Paper CT Conference on Network for Ultra Violet Astronomy CY JUN, 2007 CL Madrid, SPAIN DE Ultraviolet: spectra; Ultraviolet: ISM; Techniques: spectroscopic ID LOCAL BUBBLE; FINE-STRUCTURE; ORIGIN; GALAXY; CLOUD; GAS AB Understanding the complex structure, dynamics, and ionization of gas in the nearby interstellar medium is required before one can realistically model interstellar gas in other galaxies. High-resolution ultraviolet spectra provide the essential data for such studies because the resonance lines of most important atoms, ions, and molecules are located in the ultraviolet, and high spectral resolution is needed to resolve line profiles and determine the velocity structure along a line of sight. I list ten important physical questions concerning interstellar gas that require a more sensitive spectrometer than STIS and the desired spectral resolution to answer these questions. C1 [Linsky, Jeffrey L.] Univ Colorado, JILA, Boulder, CO 80309 USA. [Linsky, Jeffrey L.] Natl Inst Stand & Technol, Boulder, CO 80309 USA. RP Linsky, J (reprint author), Univ Colorado, JILA, Boulder, CO 80309 USA. EM jlinsky@jila.colorado.edu NR 15 TC 1 Z9 1 U1 0 U2 1 PU SPRINGER PI DORDRECHT PA VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS SN 0004-640X J9 ASTROPHYS SPACE SCI JI Astrophys. Space Sci. PD APR PY 2009 VL 320 IS 1-3 BP 85 EP 90 DI 10.1007/s10509-009-9992-y PG 6 WC Astronomy & Astrophysics SC Astronomy & Astrophysics GA 418UK UT WOS:000264174700015 ER PT J AU Hofmann, DJ Butler, JH Tans, PP AF Hofmann, David J. Butler, James H. Tans, Pieter P. TI A new look at atmospheric carbon dioxide SO ATMOSPHERIC ENVIRONMENT LA English DT Article DE Climate change; Carbon dioxide ID SOUTHERN-OSCILLATION; CLIMATE; FOREST; CO2 AB Carbon dioxide is increasing in the atmosphere and is of considerable concern in global climate change because of its greenhouse gas warming potential. The rate of increase has accelerated since measurements began at Mauna Loa Observatory in 1958 where carbon dioxide increased from less than 1 part per million per year (ppm yr(-1)) prior to 1970 to more than 2 ppm yr(-1) in recent years. Here we show that the anthropogenic component (atmospheric value reduced by the pre-industrial value of 280 ppm) of atmospheric carbon dioxide has been increasing exponentially with a doubling time of about 30 years since the beginning of the industrial revolution (similar to 1800). Even during the 1970s, when fossil fuel emissions dropped sharply in response to the "oil crisis" of 1973, the anthropogenic atmospheric carbon dioxide level continued increasing exponentially at Mauna Loa Observatory. Since the growth rate (time derivative) of an exponential has the same characteristic lifetime as the function itself, the carbon dioxide growth rate is also doubling at the same rate. This explains the observation that the linear growth rate of carbon dioxide has more than doubled in the past 40 years. The accelerating growth rate is simply the outcome of exponential growth in carbon dioxide with a nearly constant doubling time of about 30 years (about 2%/yr) and appears to have tracked human population since the pre-industrial era. (c) 2008 Elsevier Ltd. All rights reserved. C1 [Hofmann, David J.; Butler, James H.; Tans, Pieter P.] NOAA, Earth Syst Res Lab, Global Monitoring Div, Boulder, CO 80305 USA. RP Hofmann, DJ (reprint author), NOAA, Earth Syst Res Lab, Global Monitoring Div, Boulder, CO 80305 USA. EM david.j.hofmann@noaa.gov NR 19 TC 61 Z9 65 U1 9 U2 75 PU PERGAMON-ELSEVIER SCIENCE LTD PI OXFORD PA THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND SN 1352-2310 J9 ATMOS ENVIRON JI Atmos. Environ. PD APR PY 2009 VL 43 IS 12 BP 2084 EP 2086 DI 10.1016/j.atmosenv.2008.12.028 PG 3 WC Environmental Sciences; Meteorology & Atmospheric Sciences SC Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences GA 430PB UT WOS:000264999900017 ER EF